Acid-lead battery electrode comprising a network of pores passing therethrough, and production method

A structure including a network of parallel, homogeneous pores extending through the structure, and an outer frame around the lateral faces of the structure. The structure and the frame are made of carbon. The electrode is covered by a layer based on lead. The pores are filled with an active material based on lead.

Porous articles, methods, and apparatuses for forming same

A mold for forming a porous article can include a first material having a first thermal conductivity and a second material having a second thermal conductivity different from the first thermal conductivity. The first material may be at least partially embedded within the second material and configured to create regions of different thermal conductivity in the body, such as configured to create distinct nucleation regions within a material formed within the mold. A method for forming a porous article can include providing a slurry within a mold and freeze-casting the slurry to form a porous article having a burst-like distribution of porosity. A porous article according to embodiments herein can include a burst-like distribution of porosity.

CERAMIC BINDER COMPOSITION FOR CERAMIC COATED SEPARATOR FOR LITHIUM ION BATTERIES, METHODS OF PRODUCING SAME, AND USES THEREOF

A ceramic binder composition is disclosed as well as a method of making and using the same. Additionally, a ceramic coated separator used in, for example but without limitation, lithium ion batteries is disclosed. 1. A ceramic binder composition , comprising:at least one ceramic particle; anda binder comprising a polymer at least partially crosslinked with a crosslinking agent, wherein the polymer is a copolymer produced from monomers comprising (i) vinylpyrrolidone and (ii) at least one monomer having a functionality selected from the group consisting of an amine, an epoxide, and combinations thereof.2. The composition of claim 1 , wherein the at least one ceramic particle is selected from the group consisting of alumina claim 1 , alumina oxide hydroxide claim 1 , SiO claim 1 , BaSO claim 1 , TiO claim 1 , SnO claim 1 , CeO claim 1 , ZrO claim 1 , BaTiO claim 1 , YO claim 1 , BO claim 1 , and combinations thereof.35.-. (canceled)6. The composition of claim 1 , wherein the polymer is a copolymer produced from monomers comprising vinylpyrrolidone and at least one monomer having at least one amine functional group.7. The composition of claim 6 , wherein the polymer is selected from the group consisting of (a) a copolymer produced from monomers comprising vinylpyrrolidone and dimethylaminopropyl methacrylamide (DMAPMA) claim 6 , (b) a copolymer produced from monomers comprising vinylpyrrolidone and dimethylaminoethyl methacrylate (DMAEMA) claim 6 , (c) a copolymer produced from monomers comprising vinylpyrrolidone claim 6 , vinylcaprolactam claim 6 , and DMAEMA claim 6 , (d) a copolymer produced from monomers comprising vinylpyrrolidone claim 6 , vinylcaprolactam claim 6 , and DMAPMA claim 6 , and (e) combinations thereof.811-. (canceled)12. The composition of claim 6 , wherein the crosslinking agent comprises a compound comprising at least two epoxide groups.13. The composition of claim 12 , wherein the crosslinking agent comprises at least one water dispersible multi ...

Interconnector material, intercellular separation structure, and solid electrolyte fuel cell

Provided is an interconnector material which is chemically stable in both oxidation atmospheres and reduction atmospheres, has a high electron conductivity (electric conductivity), a low ionic conductivity, does not contain Cr, and enables a reduction in sintering temperature. The interconnector material is arranged between a plurality of cells each composed of an anode layer, a solid electrolyte layer, and a cathode layer stacked sequentially, and electrically connects the plurality of cells to each other in series in a solid electrolyte fuel cell. The interconnector is formed of a ceramic composition represented by the composition formula La(Fe 1-x Al x )O 3 in which 0<x<0.5.

SEPARATORS FOR ELECTROCHEMICAL CELLS

Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic subsituents. Also provided are electrochemical cells comprising such separators. 120-. (canceled)21. A porous separator for an electrochemical cell , the separator comprising: aluminum boehmite,', 'an organic polymer, and', 'a reaction product of an organic carbonate that is covalently bonded to the aluminum boehmite., 'an inorganic oxide layer comprising22. The separator of claim 21 , wherein the organic carbonate is ethylene carbonate.23. The separator of claim 21 , wherein the organic carbonate is propylene carbonate.24. The separator of claim 21 , wherein the separator has a tensile strength between about 100 kg/cmto about 500 kg/cmat 2 percent elongation.25. The separator of claim 21 , wherein the separator does not melt at temperatures lower than 300° C.26. The separator of claim 21 , wherein the thickness of the inorganic oxide layer is from 2 microns to 25 microns.27. The separator of claim 21 , wherein the separator is nanoporous.28. The separator of claim 21 , wherein the average pore diameter of the separator is 30 nm to 50 nm.29. The separator of claim 21 , wherein the separator comprises an aluminum boehmite xerogel layer.30. An electrochemical cell comprising:an anode,a cathode, and aluminum boehmite,', 'an organic polymer, and', 'a reaction product of an organic carbonate that is covalently bonded to the aluminum boehmite., 'an inorganic oxide layer comprising, 'a separator interposed between the anode and the cathode, the separator comprising31. The electrochemical cell of claim 30 , wherein the organic carbonate is ethylene carbonate.32. The electrochemical cell of claim 30 , wherein the organic carbonate is propylene carbonate.33. The electrochemical cell of claim 30 , wherein the separator does not melt at temperatures lower than 300° C.34. The electrochemical cell of claim 30 , ...

Polyimide bead materials and methods of manufacture thereof

Nanoporous carbon-based scaffolds or structures, and specifically carbon aerogels and their manufacture and use thereof are provided. Embodiments include a silicon-doped anode material for a lithium-ion battery, where the anode material includes beads of a polyimide-derived carbon aerogel. The carbon aerogel may further include silicon particles and accommodates expansion of the silicon particles during lithiation. The anode material provides optimal properties for use within the lithium-ion battery.

ELECTROREFINING OF MAGNESIUM FROM SCRAP METAL ALUMINUM OR MAGNESIUM ALLOYS

The invention comprises methods and apparatuses for the electrorefining of Mg from Al or Mg alloy scrap. The invention utilizes the density and charge features of Mg present in a melted alloy to continuously extract Mg and Mg alloys from a melted Al alloy feed. 134-. (canceled)35. A method of removing Mg from Al scrap while recovering primary quality Mg master alloys , comprising:a. melting Al scrap in a melter;b. delivering melted Al scrap to a Mg recovery electrorefiner including an anode and a cathode; andc. extracting from the melted Al scrap a Mg—Al alloy product at said cathode and an Al alloy product at said anode by applying a current between the cathode and the anode.36. The method of claim 35 , further comprising recirculation of the melted Al scrap between the melter and the electrorefiner so as to provide adequate time for the electrorefining to remove and recover Mg from the Al alloy melt.37. The method of claim 36 , further comprising introducing a fluoride-based molten salt electrolyte.38. The method of claim 37 , further comprising:(a) circulating said electrolyte molten salt to an electrolytic compartment;(b) increasing a temperature of said electrolyte molten salt to dissolve oxide contamination of said electrolyte molten salt; and{'sub': '2', '(c) electrolyzing said dissolved oxide to produce CO/CO gas on a sacrificial carbon anode and Mg or Al at the cathode.'}3945-. (canceled)46. A method for refining Mg from Al alloy scrap metal claim 37 , comprising:a. simultaneously melting scrap metal in a melter and continuously recirculating molten Al alloy between the melter and an electrorefining cell;b. flowing the molten Al alloy through the electrorefining cell, wherein the electrorefining cell comprises an upper cathode current supply block and a lower anode current collection block and a Mg product collection chamber above the upper cathode current supply block;c. maintaining the level of the molten Al alloy below the cathode current supply block ...

NOVEL MATERIALS WITH EXTREMELY DURABLE INTERCALATION OF LITHIUM AND MANUFACTURING METHODS THEREOF

Composites of silicon and various porous scaffold materials, such as carbon material comprising micro-, meso- and/or macropores, and methods for manufacturing the same are provided. The compositions find utility in various applications, including electrical energy storage electrodes and devices comprising the same. 182-. (canceled)83. A process for preparing silicon-carbon composite particles , the process comprising:a. providing a porous carbon framework comprising micropores, mesopores, or both, wherein the porous carbon framework comprises particles with a Dv,50 of 1 to 1000 microns;b. heating the porous carbon framework at an elevated temperature in the presence of a silicon-containing gas to impregnate silicon within the porous carbon framework; andc. performing a particle size reduction to provide the silicon-carbon composite particles.84. The process according to wherein the silicon impregnated within the porous carbon framework is nano sized claim 83 , and resides within pores of the porous carbon framework.85. The process according to wherein the porous carbon framework comprises pyrolyzed carbon material.86. The process according to wherein the porous carbon framework comprises pyrolyzed and activated carbon material.87. The process according to claim 83 , wherein the particle size reduction is performed by jet milling.88. The process according to claim 87 , wherein the jet milling is performed in the presence of nitrogen gas.89. The process according to claim 83 , wherein the elevated temperature is between 300 and 900° C.90. The process according to claim 83 , wherein the porous carbon framework comprises a pore volume greater than 0.5 cm/g.91. The process according to claim 83 , wherein the porous carbon framework comprises a surface area greater than 500 m/g.92. The process according to claim 83 , wherein the porous carbon framework comprises a surface area greater than 750 m/g.93. The process according to claim 83 , wherein the silicon-carbon ...

MASTERBATCH OF CARBON-BASED CONDUCTIVE FILLERS FOR LIQUID FORMULATIONS, ESPECIALLY IN LI-ON BATTERIES

A masterbatch in agglomerated solid form including carbon nanofibers and/or nanotubes and/or carbon black, the content of which is between 15 wt % and 40 wt %, preferably between 20 wt % and 35 wt %, relative to the total weight of the masterbatch; at least one solvent; at least one polymer binder, which represents from 1 wt % to 40 wt %, preferably from 2 wt % to 30 wt % relative to the total weight of the masterbatch. Also, a concentrated masterbatch, characterized in that it is obtained by eliminating all or part of the solvent from the masterbatch described previously. Also, a process for preparing said masterbatches and to the uses of the latter, especially in the manufacture of an electrode or of a composite material for an electrode. 1a) carbon nanofibers and/or nanotubes and/or carbon black, the content of which is between 15 wt % and 40 wt %, preferably between 20 wt % and 35 wt %, relative to the total weight of the masterbatch;b) at least one solvent;c) at least one polymer binder, which represents from 1 wt % to 40 wt %, preferably from 2 wt % to 30 wt % relative to the total weight of the masterbatch.. A masterbatch in agglomerated solid form comprising: The present application is a continuation of U.S. application Ser. No. 13/052,276, filed on Mar. 21, 2011, which claims the benefit of French Application No. 10.57669, filed on Sep. 23, 2010 and the benefit of French Application No. 10.52091, filed on Mar. 23, 2010. The entire contents of each of U.S. application Ser. No. 13/052,276, French Application No. 10.57669, and French Application No. 10.52091 are hereby incorporated herein by reference in their entirety.The present invention relates to a masterbatch containing carbon-based conductive fillers, such as carbon nanotubes, and also to its preparation method and to the use of this masterbatch for the manufacture of components of Li-ion batteries and of supercapacitors, and more generally for integrating carbon nanotubes into aqueous-based or organic- ...

Calcium silicate hydrate anion exchange membrane useful for water electrolysis and fuel cells and a process for the preparation thereof

The present invention relates to a process for the preparation of Calcium Silicate Hydrate anion exchange membrane (cement paste) with an ionic conductivity of the order of 10 −3 S/cm. The membrane can be formulated by mixing Ordinary Portland Cement (OPC) and water with the cement to water ratio of 1:0.45. After initial setting time, the membrane undergoes curing in 7% calcium chloride solution and the Cl − ions in the membrane is converted to OH − form by immersing into saturated Ca(OH) 2 solution with pH 14 and it has been washed to remove the excess alkali. This membrane has high mechanical strength (Ultimate Tensile Strength: 6.3 MPa) and does not deteriorate even at high temperature (up to 450° C.) and alkaline atmosphere (pH 11.5-14). Also disclosed is a method of producing in-situ formation of membrane electrode assembly. This invention encompasses a process for producing and using the membrane in water electrolysis and fuel cell.

Nitrogen-containing porous carbon material, and capacitor and manufacturing method thereof

A nitrogen-containing porous carbon material, and a capacitor and a manufacturing method thereof are provided. A carbon material, a macromolecular material and a modified material are mixed into a preform. The modified material includes nitrogen. A formation process is performed on the preform to obtain a formed object. High-temperature sintering is performed on the formed object to decompose and remove a part of the macromolecular material, while the other part of the macromolecular material and the carbon material together form a backbone structure including a plurality of pores. As such, the nitrogen becomes attached to the backbone structure to form a hydrogen-containing functional group to further obtain the nitrogen-containing porous carbon material. The nitrogen-containing porous carbon material may form a first nitrogen-containing porous carbon plate and a second nitrogen-containing porous carbon plate, which are placed in seawater to form a storage capacitor for seawater.

Hierarchical composite structures based on graphene foam or graphene-like foam

The present invention relates to a hierarchical composite structure comprising an open cell graphene foam or graphene-like foam, wherein the graphene foam or graphene-like foam is coated with a conductive nanoporous spongy structure and wherein at least 10 % v/v of the hollow of the pores of the graphene foam or graphene-like foam is filled with the conductive nanoporous spongy structure. The invention also relates to a process for preparing a hierarchical composite structure wherein a conductive nanoporous spongy structure is electrodeposited so as to coat the open-cell graphene foam or graphene-like foam and to partially fill the hollow of the pores of the graphene foam or graphene-like foam.

Method for forming a nanoporous grain boundary structure

Gadolinium-doped cerium oxide slurries used to form a patchwork type surface structure with nanoporous grain boundary prepared by mixing gadolinium-doped cerium oxide and a polymer binder to form a first mixture; wet-atomizing the first mixture under a pressure of at least 100 MPa to obtain a second mixture; coating the second mixture to a substrate to form in a coated substrate; and sintering the coated substrate. The patchwork type structure is a polygonal or honeycomb structure having a size of from 0.1 μm to 3 μm.

Carbon foam, stack carbon foam, and method of manufacturing stack carbon foam

It is an object of the present disclosure to provide a thin-film carbon foam and a method of manufacture the same. It is another object of the present disclosure to provide a stack carbon foam having fewer through holes and a method of manufacturing the same. The carbon foam of the present disclosure is, for example, a stack carbon foam being a stack of at least two monolayer carbon foams stacked one another, each monolayer carbon foam comprising linear portions and node portions joining the linear portions, or a carbon foam comprising linear portions and node portions joining the linear portions, wherein the ratio of the number of large through holes having a diameter of 1 mm or more to the surface area of the carbon foam is 0.0003/mm2 or less.

Lithium composite oxide sintered body plate

A lithium composite oxide sintered body plate includes a porous structure in which a plurality of primary particles of a lithium composite oxide having a layered rock-salt structure are bonded is included, in which a porosity is 15 to 50%, a ratio of the primary particles whose average inclination angle being an average value of angles between a (003) plane of the plurality of primary particles and a plate surface of the sintered body plate is more than 0° and 30° or less is 60% or more, one or more additive elements selected from Nb, Ti, W are contained, and an addition amount of the one or more additive elements to an entire of the sintered body plate is 0.01 wt % or more and 2.0 wt % or less.

Composition for an Organic Gel and the Pyrolysate Thereof, Production Method Thereof, Electrode Formed by the Pyrolysate and Supercapacitor Containing Same

A non-crosslinked, gelled carbonaceous composition and a pyrolysed composition respectively forming an aqueous polymer gel and the pyrolysate thereof in the form of porous carbon is provided. Also provided is a production method thereof, to a porous carbon electrode formed by the pyrolysed composition, and to a supercapacitor containing the electrodes. The gelled, non-crosslinked composition (G2) is based on a resin created at least partly from polyhydroxybenzene(s) R and formaldehyde(s) F and comprises at least one hydrosoluble cationic polyelectrolyte P. The composition forms a rheofluidifying physical gel. A pyrolysed carbonaceous composition having a carbon monolith, is the product of coating, crosslinking, drying then pyrolysis of the non-crosslinked gelled composition, the carbon monolith being predominantly microporous and able to form a supercapacitor electrode having a thickness of less than 1 mm.

Process for manufacturing composite consisting of graphene monolith and silicon

Disclosed is a process of manufacturing a chemically reduced graphene oxide/silicon nanowire composite. The formation of the three-dimensional monolith and the chemical reduction of graphene oxide by a reducing agent selected from hydrazine hydrate, ethylene diamine and 1,4-diaminebutane are in one step. Also disclosed is a chemically reduced graphene oxide/silicon nanowire composite that can be obtained by the disclosed process. The composite is a three-dimensional monolith in which the two components are covalently linked each other, having a high degree of reduction with a C/O ratio of 1-50, preferably from 10 to 25, more preferably 16.7, having a porous structure and a high specific surface area of 50-5,000 m2/g, preferably 800-2,500 m2/g, more preferably 1,433 m2/g and having a low resistance to charge transfer from 0.1 to 5 Ω, preferably from 0.3 to 1.5 Ω. Also disclosed is a lithium-ion battery or a supercapacitor including the composite (or monolith).

Pozzolan Polymer Modified Portland Cement Bound Graphite Composition of Matter

A composition of matter for use as an electrode in batteries, fuel cells and other applications, that may or may not be primarily composed of graphite, Portland Cement, pozzolans and water. Organic polymers, additives, reinforcements, fillers, catalysts, current collectors, and other materials may be included in vast ranges and proportions. Large graphite electrodes and other useful products are fabricated integrating concrete with chemical and electrical sciences. Batteries, fuel cells, thermal energy systems, conductive paints, fireproof coatings, metal casting forms, crucibles, fire bricks, graphite electrodes for electroplating, electric arc furnaces, and other applications may make use of the composition. For example, an air battery cathode composed of 50 grams white portland cement, 7 grams metakaolin pozzolan, and 700 grams of properly mixed graphite particle sizes. Dry components mixed with a water based liquid component start the cementing reactions. Mixing, forming and curing play important roles in the final composition properties.

CATHODES FOR LI-S BATTERIES

The present invention concerns a process for the preparation of a porous carbon structure comprising the steps: a) providing a template comprising voids, b) filling of at least part of the voids with a precursor for the formation of the porous carbon structure, c) carbonizing the precursor for the formation of the porous carbon structure and d) removing at least part of the template. In preferred embodiments the precursor for the formation of the porous carbon structure is a formaldehyde-phenol resin, especially a cross-linked resorcinol-formaldehyde resin. The template further preferably comprises a block copolymer and an amphiphilic molecule, wherein the block copolymer comprises polymeric units of at least one lipophilic monomer and polymeric units of at least one hydrophilic monomer. Further preferred is a process wherein the template comprises a bimodal mixture of particles of silicon dioxide. 1. Process for the preparation of a porous carbon structure comprising the following steps:a) providing a template comprising voids,b) filling at least part of the voids with a precursor for the formation of the porous carbon structure,c) carbonizing the precursor for the formation of the porous carbon structure, andd) removing at least part of the template.2. Process according to further comprising the following steps:providing a solution comprising a solvent, a block copolymer and an amphiphilic molecule,producing a body by evaporation of the solvent, removing the amphiphilic molecule to produce the template comprising voids, andafter carbonizing the precursor for the formation of the porous carbon structure, removing the block copolymer by heating,wherein the block copolymer comprises polymeric units of at least one lipophilic monomer and polymeric units of at least one hydrophilic monomer.3. Process according to wherein the amphiphilic molecule is removed by soaking the body in a solvent claim 2 , optionally an ethanol/water or methanol/water mixture.4. Process ...

Lithium composite oxide sintered body plate

Provided is a lithium complex oxide sintered plate for use in a positive electrode of a lithium secondary battery. The lithium complex oxide sintered plate has a structure in which a plurality of primary grains having a layered rock-salt structure are bonded, and has a porosity of 3 to 40%, a mean pore diameter of 15 μm or less, an open porosity of 70% or more, and a thickness of 15 to 200 μm. The plurality of primary grains has a primary grain diameter, i.e., a mean diameter of the primary grains, of 20 μm or less and a mean tilt angle of more than 0° to 30° or less. The mean tilt angle is a mean value of the angles defined by the (003) planes of the primary grains and the plate face of the lithium complex oxide sintered plate.

Graphene

Graphene having a plurality of cavities therein is described. There is also described a process for producing graphene wherein a metal, for example an alkali metal, is reacted with an alcohol to produce a solvothermal product comprising a metal alkoxide. The solvothermal product is then pyrolysed to produce the graphene.

Mesoporous carbon materials

A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.

Nonaqueous electrolyte secondary battery

The electrode of a nonaqueous solvent secondary battery is made of porous material which is produced by baking active material to reduce the volume of dead spaces in the electrode in the battery casing and the electrical capacity per unit volume is increased. By using the porous material as the electrode material instead of powder material, the active material can be sufficiently brought into electrical contact with electrolyte and, on the other hand, metal foil or conductive material which is required for forming collectors can be reduced or eliminated and hence an electrical capacity per unit weight can be larger than the capacity of a conventional constitution. If the porous material is sintered into a plate, the plate has a thickness of 100 νm - 2 mm and holes whose diameters are 0.1 νm - 100 νm. The total volume of the holes is 15 - 60 % of the whole volume and thicknesses between the hollow holes are not larger than 40 νm.

Porous geopolymer materials

Preparing porous materials includes forming a mixture including a geopolymer resin and a liquid between which a nanoscale (1-1000 nm), microscale (1-1000 m), and/or milliscale (1-10 mm) phase separation occurs. The mixture is solidified (e.g., at an ambient temperature or a relatively low temperature), and a portion (e.g., a majority or a significant majority) of the liquid is removed from the solidified mixture. The liquid can include organic liquids from agricultural, geological, industrial, or household sources. The porous materials have accessible pores with a range of pore sizes including nanoscale pore sizes, microscale pore sizes, milliscale pore sizes, or a combination thereof. The porous material may be treated further to form another material, such as a composite.

Carbonaceous materials coated with a metal or metal oxide, a preparation method thereof, and a composite electrode and lithium secondary battery comprising the same

A carbon anode active material for lithium secondary battery comprising a cluster or thin film layer of a metal or metal oxide coated onto the surface of the carbon active material, a preparation method thereof, and a metal-carbon hybrid electrode and a lithium secondary battery comprising the same. The carbon active material is prepared through a gas suspension spray coating method. An electrode comprising the carbon active material according to the present invention shows excellent conductivity, high rate charge/discharge characteristics, cycle life characteristics and electrode capacity close to theoretical value.

Carbonaceous materials coated with a metal or metal oxide, a preparation method thereof, and a composite electrode and lithium secondary battery comprising the same

A carbon anode active material for lithium secondary battery comprising a cluster or thin film layer of a metal or metal oxide coated onto the surface of the carbon active material, a preparation method thereof, and a metal-carbon hybrid electrode and a lithium secondary battery comprising the same. The carbon active material is prepared through a gas suspension spray coating method. An electrode comprising the carbon active material according to the present invention shows excellent conductivity, high rate charge/discharge characteristics, cycle life characteristics and electrode capacity close to theoretical value.

Metal-coated carbon, preparation method thereof, and composite electrode and lithium secondary batteries comprising the same

본 발명은 탄소 활물질의 표면에 금속 또는 금속 산화물의 클러스터 또는 박막 층이 형성된 형태의 리튬이차전지용 음극 활물질, 이의 제조방법, 및 이를 포함하는 금속-탄소 하이브리드 전극 및 리튬이차전지에 관한 것이다. 본 발명의 탄소계 음극 활물질은 기체 유동층 분사 코팅법(Gas Suspension Spray Coating)에 의하여 제조되며, 본 발명에 따라 제조된 신소재 탄소 활물질을 포함하는 전극은 전도성, 고율 충방전 특성 및 싸이클 수명 특성이 우수하고, 이론 용량에 가까운 전극 용량을 나타낸다. The present invention relates to a negative electrode active material for a lithium secondary battery, a method of manufacturing the same, and a metal-carbon hybrid electrode and a lithium secondary battery including a metal or metal oxide cluster or a thin film layer formed on a surface of a carbon active material. The carbon-based negative electrode active material of the present invention is prepared by Gas Suspension Spray Coating, and the electrode including the new material carbon active material prepared according to the present invention has excellent conductivity, high rate charge / discharge characteristics, and cycle life characteristics. The electrode capacity close to the theoretical capacity is shown.

Manufacturing method of mesoporous carbon structure with spray drying or spray pyrolysis and composition thereof

본 발명은 (a) 탄소 전구체, 탄소 전구체가 탄화되는 온도 범위에서 열분해되거나 또는 탄화 이후 후처리에 의해 제거되어 기공을 형성하는 주형 물질(template) 및 용매를 혼합하여 분무 용액을 제조하는 단계; 및 (b) 상기 분무 용액을 분무 열처리하거나 또는 분무 건조 후 열처리하여 탄화된 탄소 구조체를 형성한 후, 주형 물질을 제거하는 단계를 포함하는 다공성 탄소 구조체의 제조방법을 제공한다. The present invention provides a spray solution comprising: (a) mixing a carbon precursor, a template material which is pyrolyzed in a temperature range in which the carbon precursor is carbonized, or is removed by post-treatment after carbonization to form pores, and a solvent; And (b) spray-treating the spray solution or heat-drying after spray drying to form a carbonized carbon structure, and then removing the template material. 본 발명의 제조방법에 따라 제조되는 중형 다공성 구형 탄소(mesoporous spherical carbon)는 주형 물질(template)의 종류, 이들의 농도 조절을 통해 넓은 비표면적, 큰 세공부피를 가질 수 있으며, 이를 통해 촉매, 흡착제, 전극물질, 분리 및 정제용이나 수소 및 약물의 저장용과 같은 광범위한 용도로 널리 이용될 수 있다 Mesoporous spherical carbon prepared according to the method of the present invention may have a large specific surface area and a large pore volume by controlling the concentration of the template material and the concentration thereof, and thus, a catalyst and an adsorbent. It can be widely used for a wide range of applications such as electrode materials, separation and purification, or storage of hydrogen and drugs. 중형 다공성 탄소, 분무 건조, 기공 형성 물질, 제조방법 Medium porous carbon, spray drying, pore forming material, manufacturing method

Mother stock of carbon conducting filler for liquid compositions, particularly in lithium-ion batteries

FIELD: chemistry. SUBSTANCE: present invention relates to a mother stock in a solid agglomerated form for electrolytes of lithium-ion batteries or supercapacitors, a method of producing said mother stock, a concentrated mother stock, a method of making an electrode, an electrode made using said method, a method of producing an active composite material for an electrode, an active composite material for an electrode made using said method and to the use of the mother stock. The mother stock contains: a) carbon nanofibres and/or nanotubes and/or carbon black, the content of which is 15-40 wt %, preferably 20-25 wt % of the total weight of the mother stock; b) at least one solvent; c) at least one polymer binder in amount of 1-40 wt %, preferably 2-30 wt % of the total weight of the mother stock. The solvent is an organic solvent, water or a mixture thereof and is in amount of 20-84 wt % of the total weight of the mother stock. EFFECT: obtaining a mother stock and articles based thereon, which solves the task of adding carbon nanotubes to water- or organic-based liquid compositions. 16 cl, 4 dwg, 11 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК H01M 4/62 H01B 1/20 C08J 3/20 C08J 5/00 B82Y 30/00 (13) 2 564 029 C2 (2006.01) (2006.01) (2006.01) (2006.01) (2011.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2012144793/04, 22.03.2011 (24) Дата начала отсчета срока действия патента: 22.03.2011 Приоритет(ы): (30) Конвенционный приоритет: (73) Патентообладатель(и): АРКЕМА ФРАНС (FR) R U 23.03.2010 FR 1052091; 23.09.2010 FR 1057669 (72) Автор(ы): НИКОЛЯ Серж (FR), КОРЖЕНКО Александр (FR), МЕРСЕРОН Амели (FR), АВЕЛЬ Микаэль (FR), ЛЕКОНТ Иван (FR) (43) Дата публикации заявки: 27.04.2014 Бюл. № 12 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 23.10.2012 C 2 C 2 (56) Список документов, цитированных в отчете о поиске: JP 10255844 A 25.09.1998 . FR 1307346 A 26.10.1962. EP 2081244 A1 22.07.2009. FR ...

A sintered refractory material based on silicon carbide with a silicon nitride binder

본 발명은 질화규소 바인더(Si 3 N 4 )를 형성하기 위하여 1,100℃ 내지 1,700℃ 사이에서 반응성 소결된 탄화규소(SiC)를 기저로 하고, 0.05% 내지 1.5%의 붕소를 포함하며, Si 3 N 4 /SiC 중량 비율이 0.05 내지 0.45 범위에 있는 소결 물질, 특히 알루미늄 전기분해 셀(cell) 제조를 위한 소결 물질에 관한 것이다. 본 발명은 특히, 전기분해 셀(cell)에 대한 응용에 관한 것이다. The invention comprises a silicon nitride binder (Si 3 N 4) formed to the reactive sintered silicon carbide (SiC) as base, and boron of 0.05% to 1.5% among 1,100 ℃ to 1,700 ℃ to, Si 3 N 4 / SiC weight ratio in the range of 0.05 to 0.45, particularly sintered materials for the production of aluminum electrolysis cells. The present invention relates in particular to the application to electrolysis cells.

A process for manufacturing a tank or container by using a polymer concrete mixture.

A process for manufacturing a corrosion resistant tank or container comprises the steps of mixing a filler material consisting of a corrosion resistant aggregate with a corrosion resistant resin binder and a polypropylene based fibre material to form a polymer concrete mixture and, introducing this mixture into a mould and allowing it to cure, the mould being optionally vibrated to produce a homogenous casting. The corrosion resistant tank or container is preferably a corrosion resistant electrolytic cell used in the electrolylic treatment of metals and salts.

Coating method of metal oxide superfine particles on the surface of metal oxide and coating produced therefrom

A method of coating metal oxide superfine particles on the surface of metal oxides and a coating produced therefrom are provided to obtain a core shell type coating by uniformly coating nano-sized superfine particles on the surface of the metal oxides. A method of coating metal oxide superfine particles on the surface of metal oxides comprises the steps of: (i) contacting metal(M1) oxides with an aqueous solution of metal(M2) salt to be coated on the metal oxides to provide a mixed solution; and (ii) continuously mixing and reacting the mixed solution with water at a temperature of 200 to 700 deg.C and a pressure of 180 to 550 bars. The method further comprises a step of adding a precipitant to the mixed solution between the step(i) and the step(ii). The precipitant is ammonia water. The metal(M1) of the metal(M1) oxides is at least one selected from Si, Al, Li, Mg, Ca, Sr, Ba, Y, Nb, La, Ti, Zr, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn, Ce and Pr. The metal(M2) of the metal(M2) salt is at least one selected from Si, Al, Sc, Ga, Li, Mg, Ca, Sr, Ba, Y, Nb, La, Ti, Zr, Cr, Mo, W, Mn, Fe, Ru, Rh, Pd, Ir, Pt, Co, Ni, Cu, Ag, Zn, Cd, Ce, Pr, Nd, Sm, Eu and Gd.

Electrochemical cell, method for producing the same, and electrochemical device

SINTERED POROUS STRUCTURE AND METHOD FOR PRODUCING SUCH STRUCTURE

1. Способ изготовления пористой сети, где указанный способ содержит: ! создание большого числа неспеченных несферических элементов, причем каждый несферический элемент содержит частицы; ! упорядочение несферических элементов в форме требуемой сети для формования неспеченного пористого тела; и ! одновременное спекание частиц одной с другой для формования спеченных несферических элементов и спекание несферических элементов одного с другим для формования пористой сети. ! 2. Способ по п.1, отличающийся тем, что до спекания несферические элементы подвергают соединению одного с другим. ! 3. Способ по п.2, отличающийся тем, что соединение несферических элементов содержит, по меньшей мере, одно из: бисквитный обжиг несферических элементов, сжатие несферических элементов, нанесение на элементы протравной грунтовки или суспензионного покрытия со связующим или частицами и воздействие на несферические элементы, по меньшей мере, одним из: теплотой, растворителем, светом и ультразвуковыми волнами. ! 4. Способ по п.2, отличающийся тем, что несферические элементы содержат полимер, а соединение несферических элементов содержит отверждение или термоотверждение полимера. ! 5. Способ по любому из пп.1-4, отличающийся тем, что дополнительно содержит нанесение добавки на упорядоченные несферические элементы для усиления связывания несферических элементов одного с другим. ! 6. Способ по п.1, отличающийся тем, что упорядочение несферических элементов содержит загрузку несферических элементов в штамп или пресс-форму путем одного из: инжекция, подача под действием силы тяжести, реактивное распыление и экструдирование. ! 7. Способ по п РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2010 129 965 (13) A (51) МПК B29C 65/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2010129965/05, 21.12.2007 (71) Заявитель(и): ЧЛЕНЫ ПРАВЛЕНИЯ УНИВЕРСИТЕТА КАЛИФОРНИИ (US) Приоритет(ы): (30) Конвенционный приоритет: 20.12.2007 US 60/015,621 (85) Дата начала ...

Graphene

Graphene having a plurality of cavities therein is described. There is also described a process for producing graphene wherein a metal, for example an alkali metal, is reacted with an alcohol to produce a solvothermal product comprising a metal alkoxide. The solvothermal product is then pyrolysed to produce the graphene.

Solid electrolytic capacitor with improved Leakage Current

提供了甚至在多种条件下也能够呈现良好电性质的电容器组件。更特别地，电容器含有电容器元件，电容器元件包括烧结的多孔阳极体的、覆于阳极体之上的电介质和覆于电介质之上且由有机金属化合物形成的预涂层。含有内层和外层的固体电解质覆于预涂层之上，其中内层由原位聚合的导电聚合物形成并且外层由预聚合的导电聚合物颗粒形成。

Method for manufacturing composite materials

本方法包括预浸渍产物的制备，压制，硬化和碳化，其特征在于预浸渍产物制备后，对其进行热处理，温度在70和1100摄氏度之间，并且嵌入包含填充物和聚合物粘接剂的惰性物质，此物质的量大于单层纱线的空洞的体积，并可以通过公式[1]计算得出。其中，m n 是惰性物质的质量，d n 是惰性物质的密度，a是预浸渍产物的长度，b是预浸渍产物的宽度，h是预浸渍产物的厚度，m pr 是预浸渍产物的质量，d fib 是纤维密度。并在160和200摄氏度之间加热，同时施加在1和5MPa之间的压力。本方法用于制造基体含碳和可变气孔率的复合材料，例如，带有电极聚集体的燃料电池集流器、多孔电化学电极和过滤元件。

Sintered silicon carbide-based refractory material with silicon nitride as binder

FIELD: chemistry. SUBSTANCE: invention relates to sintered silicon carbide (SiC) based material which is used as furnace refractory or other sintered support structures: block, slab or pipe of a heat exchanger, heat recuperator, incinerator, glass furnace, metallurgical furnace, skid pipes of a metallurgical furnace, thermocouple pipes, immersion heater or pipes for transporting molten metal. A moulded silicon carbide-based refractory article is obtained by reaction sintering of a mixture containing silicon carbide grains, silicon metal and 0.05-1.5% boron, at temperature of 1100-1700°C to form silicon nitride (Si 3 N 4 ) binder. The weight ratio Si 3 N 4 /SiC of the sintered material is in the range of 0.05-0.45. EFFECT: high resistance to cyclic temperature changes in fields of application where in any cycle, temperature changes by at least 1000°C and any cycle is more than 1 hour long. 30 cl, 5 tbl, 2 dwg РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 496 745 (13) C2 (51) МПК C04B 35/573 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2010132899/03, 05.02.2009 (24) Дата начала отсчета срока действия патента: 05.02.2009 (43) Дата публикации заявки: 20.03.2012 Бюл. № 8 (73) Патентообладатель(и): СЕН-ГОБЕН САНТР ДЕ РЕШЕРШ Э Д'ЭТЮД ЭРОПЕН (FR) C 2 2 4 9 6 7 4 5 R U C 2 (56) Список документов, цитированных в отчете о поиске: Химическая технология керамики./Под ред. Гузмана И.Я. - М.: OOO РИФ "Стройматериалы", 2003, с.369, абзац 4, 6, с.370, абзац 1, с.436, абзац 4, с. 437 абзац 6,7. БУЛАВИН И.А. и др. Технология фарфорового и фаянсового производства. М.: Лёгкая индустрия, 1975, с.368, табл.XVI. 1. US 2007/0264576 A1, 15.11.2007. JP 2000302554 A, 31.10.2000. US 2005/0008878 A1, 13.01.2005. SU 1039925 A, 07.19.1983. (85) Дата начала рассмотрения заявки PCT на национальной фазе: 08.09.2010 (86) Заявка PCT: IB 2009/050480 (05.02.2009) (87) Публикация заявки РСТ: WO 2009/098657 (13.08.2009) Адрес для переписки: ...

Carbon material and manufacturing method therefor

The object of the invention is to produce a porous carbon material with appropriate spacing and having excellent graphite crystallinity and good carrier mobility; a porous carbon material having the edge of carbon hexagonal planes positioned on the outer surface of particles and structures; and graphene-like flaky graphite. A carbon material having a closed pore ratio within the material and residual hydrogen content set to appropriate levels is subjected to hot isostatic pressing, thereby causing a vapour-phase growth reaction in the graphite with the closed pores as nuclei, said reaction being caused by the carbon and hydrocarbons generated from within the carbon material. This enables the inexpensive mass production of the target porous carbon material. Graphene-like graphite flakes are produced by subjecting the porous graphite material thus obtained to physical impact, or by generating a graphite intercalantional compound with the porous carbon material as a host, and then subjecting this compound to flash heating.

Carbon material and method for producing same

Provided are a mass of crystalline graphite flakes or the like, which is useful as an electrode material for lithium ion batteries, hybrid capacitors and so on, a method for efficiently producing the same at a high productivity, etc. Specifically disclosed is a method for producing a mass of crystalline graphite flakes or the like which consists of flaky graphite crystals extending outward from the inside and aggregating together, comprising, for example, air-tightly sealing a powder of an organic compound, which has been calcined while allowing hydrogen to remain therein, in a graphite container, and then subjecting the powder, as in the state of being sealed in said container, to a hot isostatic pressing (HIP) treatment using a pressurized atmosphere under definite conditions.

Carbon material and method for producing same

A porous carbon material having excellent graphite crystallinity, good carrier mobility and proper porosity, a porous carbon material having edges of carbon hexagonal planes located on outer surfaces of particle and structure, and flaky graphite being similar to graphene are produced. By subjecting a carbon material, in which a closed-pore-ratio and an amount of remaining hydrogen in the material are set to be within a proper range, to hot isostatic pressing treatment, a vapor phase growth reaction of graphite is generated in closed pores as nuclei using hydrogen and hydrocarbon generated from the carbon material, thereby producing a large amount of targeted porous carbon material at low cost. Flaky graphite being similar to graphene is produced by applying physical impact to the obtained porous carbon material or by generating a graphite intercalation compound using the porous carbon material as a host and then quickly heating the compound.

Carbon material and method for producing same

(Problem) A porous carbon material having excellent graphite crystallinity, good carrier mobility and proper porosity, a porous carbon material having edges of carbon hexagonal planes located on outer surfaces of particle and structure, and flaky graphite being similar to graphene are produced. (Means to Solve) By subjecting a carbon material, in which a closed-pore-ratio and an amount of remaining hydrogen in the material are set to be within a proper range, to hot isostatic pressing treatment, a vapor phase growth reaction of graphite is generated in closed pores as nuclei using hydrogen and hydrocarbon generated from the carbon material, thereby producing a large amount of targeted porous carbon material at low cost. Flaky graphite being similar to graphene is produced by applying physical impact to the obtained porous carbon material or by generating a graphite intercalation compound using the porous carbon material as a host and then quickly heating the compound.

Carbon material and production method of the same

【課題】リチウムイオン電池，ハイブリッドキャパシターなどの電極材料などとして有用な，薄片状黒鉛結晶塊など及びそれらの効率的で生産性が高い製造方法などを提供する。【解決手段】残留水素を含むように仮焼きした有機化合物の粉粒体を，黒鉛製の容器に密閉し，所定の条件下，該容器ごと加圧された雰囲気を使用した熱間静水圧加圧処理（ＨＩＰ処理）することなどによる，内側から外方へと延びた薄片状の黒鉛結晶が集合してなる薄片状黒鉛結晶塊などの製造方法。【選択図】図１５

Carbon material and method for producing same

There are provided a cluster of thin sheet graphite crystals or the like which is useful as an electrode material for lithium ion batteries, hybrid capacitors and the like, and a method for efficiently producing the same at high productivity. The method is one for producing a cluster of thin sheet graphite crystals composed of aggregates in such a state that thin sheet graphite crystals extend from the inside toward the outside, comprising charging a powdery and/or particulate material of an organic compound pre-baked to an extent of containing remaining hydrogen in a graphite vessel, and subjecting the powdery and/or particulate material together with the vessel to hot isostatic pressing treatment (HIP treatment) using a compressed gas atmosphere under the predetermined conditions.

Carbon material and method for producing same

[과제] 리튬 이온 전지, 하이브리드 축전기 등의 전극 재료 등으로서 유용한, 박편상(薄片狀) 흑연 결정괴(結晶塊) 등 및 이들을 효율적으로 또한 높은 생산성으로 제조하는 제조 방법 등을 제공한다. [해결 수단] 잔류 수소를 포함하도록 가소(假燒)한 유기 화합물의 분립체(粉粒體)를, 흑연제의 용기에 밀폐하고, 소정 조건 하에서, 상기 용기마다 가압된 분위기를 사용한 열간 정수압 가압 처리(HIP 처리)하는 것 등에 의한, 내측으로부터 외측으로 연장된 박편상 흑연 결정이 집합하여 이루어지는 박편상 흑연 결정괴 등의 제조 방법. [PROBLEMS] To provide a thin graphite crystal ingot useful as an electrode material for lithium ion batteries, hybrid capacitors and the like, and a production method for efficiently and high productivity. [MEANS FOR SOLVING PROBLEMS] A powdered organic compound, which is calcined to contain residual hydrogen, is sealed in a graphite container and subjected to a hot hydrostatic pressure Shaped graphite crystal mass in which thin flaky graphite crystals extending from the inside to outside are gathered by a treatment (HIP treatment) or the like.

Carbon material and manufacturing method therefor

本发明提供制造石墨晶体性优异、且含有具有良好的载流子迁移率的适度的空间的多孔质碳材料，碳六边形网面的端部位于粒子及结构体的外表面的多孔质碳材料、类似石墨烯的薄片状石墨。通过对在适当的范围设定了材料中的闭气孔率、残留氢量的碳材料进行热等静压加压处理，由此发生以从碳材料中产生的氢、烃形成的闭气孔为核的石墨的气相生长反应，从而廉价且大量地制造目标的多孔质碳材料。通过对得到的多孔质碳材料施加物理性冲击、或生成以多孔质碳材料为主体的石墨层间化合物后再进行急速加热，由此可制造类石墨烯的石墨薄片。

Masterbatch for the carbon-based conductive filler in liquid adjustments, particularly lithium ion battery

本发明涉及用于液体配制剂、特别是锂离子电池中的碳基导电填料的母料。本发明涉及附聚的固体形式的母料，包含：a)碳纳米纤维和/或纳米管和/或炭黑，其含量相对于母料的总重量为15重量％‑40重量％，优选为20重量％‑35重量％；b)至少一种溶剂；c)至少一种聚合物粘合剂，其相对于母料的总重量占1重量％至40重量％，优选2重量％‑30重量％。本发明还涉及浓缩的母料，其特征在于其通过从前述母料中除去全部或部分的溶剂而获得。本发明还涉及制备所述母料的方法和所述母料的用途，特别是在制造电极或电极用复合材料中的用途。

Honeycomb structure

触媒担体であると共に電圧を印加することによりヒーターとしても機能し、発熱時における温度分布の偏りの少ないハニカム構造体を提供する。複数のセル２を区画形成する多孔質の隔壁１と、外周壁３とを有する筒状のハニカム構造部４と、ハニカム構造部４の側面５に配設された一対の電極部２１とを備え、ハニカム構造部４の電気抵抗率が１〜２００Ωｃｍであり、一対の電極部２１のそれぞれが、二以上の電極体３１ａ，３１ｂの積層体からなり、最も外周壁側寄りに配設された電極体３１ａの面積が、その他の電極体３１ｂの面積よりも大きく、且つ、セルの延びる方向に直交する断面における、最も外周壁側寄りに配設された電極体３１ａの中心角が、その他の電極体３１ｂの中心角よりも大きいハニカム構造体１００。 Provided is a honeycomb structure that is a catalyst carrier and also functions as a heater by applying a voltage, and has less deviation in temperature distribution during heat generation. A cylindrical honeycomb structure portion 4 having a porous partition wall 1 for partitioning a plurality of cells 2, an outer peripheral wall 3, and a pair of electrode portions 21 disposed on a side surface 5 of the honeycomb structure portion 4. The honeycomb structure part 4 has an electrical resistivity of 1 to 200 Ωcm, and each of the pair of electrode parts 21 is composed of a laminate of two or more electrode bodies 31a and 31b, and is disposed closest to the outer peripheral wall side. The area of the body 31a is larger than the area of the other electrode body 31b, and the central angle of the electrode body 31a disposed closest to the outer peripheral wall in the cross section perpendicular to the cell extending direction is the other electrode. Honeycomb structure 100 larger than the central angle of body 31b.

Method for deposition of ceramic films

本发明涉及用于在陶瓷或金属表面上沉积陶瓷膜的方法，尤其是沉积亚微米厚度的陶瓷膜的方法，陶瓷膜诸如稳定的氧化锆和诸如CGO(铈钆氧化物)的掺杂的二氧化铈的膜。本发明尤其用于制造高温和中温运行的燃料电池，包括固体氧化物燃料电池(SOFC)且还有在450℃-650℃范围内运行的金属支撑的中温SOFC。

Method for producing carbon active material coated with metal or metal oxide

Carbon material and manufacturing method therefor

[과제] 흑연 결정성이 우수하고, 양호한 캐리어 이동도를 가지고 적절한 공간을 가지는 다공질 탄소 재료, 탄소 육각망면의 단부(端部)가 입자 및 구조체의 외표면에 위치하는 다공질 탄소 재료, 그래핀 유사 박편상 흑연을 제조한다. [해결 수단] 재료 중의 폐기공율(閉氣孔率), 잔류 수소량을 적절한 범위로 설정한 탄소 재료를, 열간 정수압 가압 처리함으로써 탄소 재료 중에서 발생하는 수소, 탄화수소에 의한, 폐기공을 핵으로 한 흑연의 기상 성장 반응이 일어나게 하여, 목적으로 하는 다공질 탄소 재료를 염가로 대량으로 제조한다. 얻어진 다공질 탄소 재료에 대하여 물리적인 충격을 인가하거나, 다공질 탄소 재료를 호스트로 하는 흑연 층간 화합물을 생성시키고 이어서 급속 가열함으로써 그래핀 유사 흑연 박편을 제조한다. [assignment] A porous carbon material having excellent crystallinity of graphite and having an adequate space with good carrier mobility, a porous carbon material having end portions of the carbon hexagonal surface located on the outer surfaces of the particles and the structure, graphite- . [Solution] Vapor growth reaction of graphite made of hydrogen and hydrocarbons generated in a carbon material by using a waste gas as a nucleus by subjecting a carbon material having a closed porosity and an amount of residual hydrogen in a suitable range to hydrothermal pressure treatment So that a desired porous carbon material can be mass-produced at low cost. A graphene-like graphite flake is prepared by applying a physical impact to the obtained porous carbon material, or by forming a graphite interlayer compound using the porous carbon material as a host and then rapidly heating it.

The anode of solid oxide fuel cell with networking structure and the preparing method of it

본 발명은 상호침투형 복합구조를 가지는 고체산화물 연료전지(SOFC)의 연료극 및 이의 제조방법에 관한 것으로서, 더욱 상세하게는 세라믹 분말 입자 주위에 니켈 분말이 침착된 코아-쉘 구조로 된 복합분말을 이용하여 제조되어 그 구성상인 세라믹 결정립, 니켈의 결정립 및 기공이 균일한 크기를 가지고, 상기 구성상 상호간의 연속적인 네트워크 형태로 구성된 상호침투형 복합구조를 가짐으로써, 장기 안정성, 열 싸이클 안정성, 산화환원 안정성 및 기계적 물성이 현저히 향상된, 상호침투형 복합구조를 가지는 고체산화물 연료전지의 연료극 및 이의 제조방법에 관한 것이다. The present invention relates to an anode of a solid oxide fuel cell (SOFC) having an interpenetrating composite structure and a method of manufacturing the same. More specifically, the present invention relates to a composite powder having a core-shell structure in which nickel powder is deposited around ceramic powder particles. It is manufactured by using the same type of ceramic grains, nickel crystal grains and pores with uniform size and interpenetrating composite structure composed of a continuous network form in the composition, so that long-term stability, thermal cycle stability, oxidation The present invention relates to a fuel electrode of a solid oxide fuel cell having an interpenetrating composite structure, which has remarkably improved reduction stability and mechanical properties, and a method of manufacturing the same. 연료극, 상호침투형 복합구조, 안정성, 기계적 물성 Anode, interpenetrating composite structure, stability, mechanical properties

Three dimensional macroscupic assemblages of randomly oriented carbon fibrils and composites containing same

3-차 어셈블리지의 1차, 바람직하게 2차 및 가장 바람직하게 3-차 축을 따라 비교적 균일한 물리적 특성을 갖는 랜덤하게 배향된 탄소 피브릴의 매우 유리한 3-차 가시 어셈블리지가 제조될 수 있다는 것이 이제 알려졌다. 본 발명의 방법에 따라 제조된 바람직한 조성물은 적어도 1차 축을 따라 균일한 물리적 특성을 가지고, 어셈블리지의 적어도 한 평면에서 비교적 등방성이고, 가장 바람직하게 전체 3-차 구조를 통해 등방성인 물리적 특성을 가진다. It is now possible that very advantageous third-order visible assembly papers of randomly oriented carbon fibrils having relatively uniform physical properties along the primary, preferably secondary and most preferably third-order axes of the third-order assembly paper can be produced. Became known. Preferred compositions prepared according to the process of the present invention have uniform physical properties along at least the primary axis, are relatively isotropic in at least one plane of the assembly paper, and most preferably have isotropic properties throughout the entire tertiary structure.

BATTERY OF FUEL CELLS AND METHOD FOR ITS FORMATION (OPTIONS)

ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß (19) RU (11) 2004 126 863 (13) A (51) ÌÏÊ H01M 2/00 (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÇÀßÂÊÀ ÍÀ ÈÇÎÁÐÅÒÅÍÈÅ (21), (22) Çà âêà: 2004126863/09, 14.02.2003 (71) Çà âèòåëü(è): ÀËÜÁÅÐÒÀ ÐÅÑÅ× ÊÀÓÍÑÈË ÈÍÊ. (CA) (30) Ïðèîðèòåò: 14.02.2002 US 10/078,548 (43) Äàòà ïóáëèêàöèè çà âêè: 10.02.2006 Áþë. ¹ 4 (86) Çà âêà PCT: CA 03/00216 (14.02.2003) (74) Ïàòåíòíûé ïîâåðåííûé: Äåìåíòüåâ Âëàäèìèð Íèêîëàåâè÷ Àäðåñ äë ïåðåïèñêè: 119034, Ìîñêâà, Ïðå÷èñòåíñêèé ïåð., 14, ñòð.1, 4 ýòàæ, "Ãîóëèíãç Èíòåðíýøíë Èíê.", Â.Í.Äåìåíòüåâó R U Ôîðìóëà èçîáðåòåíè 1. Áàòàðå òîïëèâíûõ ýëåìåíòîâ, êîòîðà âêëþ÷àåò â ñåá (a) ìíîæåñòâî òðóá÷àòûõ òîïëèâíûõ ýëåìåíòîâ, ïðè÷åì êàæäûé òîïëèâíûé ýëåìåíò âêëþ÷àåò â ñåá ñëîé âíóòðåííåãî ýëåêòðîäà, ñëîé âíåøíåãî ýëåêòðîäà è ñëîé ýëåêòðîëèòà, îáðàçóþùèå ìíîãîñëîéíóþ ñòðóêòóðó ìåæäó ñëî ìè âíóòðåííåãî è âíåøíåãî ýëåêòðîäîâ; (b) ñïëîøíóþ òâåðäîôàçíóþ ïîðèñòóþ ìàòðèöó, â êîòîðóþ âñòðîåíû òîïëèâíûå ýëåìåíòû; ïðè÷åì ïåðâûé ðåàãåíò ïðîòåêàåò ÷åðåç ìàòðèöó â ñëîé âíåøíåãî ýëåêòðîäà ïî ìåíüøåé ìåðå îäíîãî èç òîïëèâíûõ ýëåìåíòîâ, à âòîðîé ðåàãåíò ïðîòåêàåò ÷åðåç âíóòðåííåå ïðîñòðàíñòâî ïî ìåíüøåé ìåðå îäíîãî èç òîïëèâíûõ ýëåìåíòîâ ê åãî âíóòðåííåìó ýëåêòðîäó. 2. Áàòàðå òîïëèâíûõ ýëåìåíòîâ ïî ï.1, â êîòîðîé ìàòðèöà ïðåäñòàâë åò ñîáîé òâåðäîòåëüíûé ïîðîïëàñò. 3. Áàòàðå òîïëèâíûõ ýëåìåíòîâ ïî ï.2, â êîòîðîé ìàòðèöà èìååò ïîðèñòîñòü îò 25 äî 95%. 4. Áàòàðå òîïëèâíûõ ýëåìåíòîâ ïî ï.3, â êîòîðîé ìàòðèöà èìååò ïîðèñòîñòü îò 40 äî 95%. 5. Áàòàðå òîïëèâíûõ ýëåìåíòîâ ïî ï.4, â êîòîðîé ìàòðèöà èìååò ïîðèñòîñòü îêîëî 60%. 6. Áàòàðå òîïëèâíûõ ýëåìåíòîâ ïî ï.1, â êîòîðîé ñëîé âíóòðåííåãî ýëåêòðîäà ïðåäñòàâë åò ñîáîé àíîä, à ñëîé âíåøíåãî ýëåêòðîäà ïðåäñòàâë åò ñîáîé êàòîä, ïðè÷åì ïåðâûé ðåàãåíò ïðåäñòàâë åò ñîáîé îêèñëèòåëü, à âòîðîé ðåàãåíò ïðåäñòàâë åò ñîáîé Ñòðàíèöà: 1 RU A 2 0 0 4 1 2 6 8 6 3 A (54) ÁÀÒÀÐÅß ÒÎÏËÈÂÍÛÕ ÝËÅÌÅÍÒÎÂ È ÑÏÎÑÎÁ ÅÅ ÔÎÐÌÈÐÎÂÀÍÈß (ÂÀÐÈÀÍÒÛ) 2 0 0 4 1 2 6 8 6 3 (87) Ïóáëèêàöè PCT: ...

Blend for manufacturing ceramic foam material (versions)

FIELD: ceramics. SUBSTANCE: invention relates to high-porous ceramic foam composites that can be used as catalyst carriers, hot gas filters, porous electrodes, and noise-suppression devices. Blend contains, wt. %: carbon, phenol-formaldehyde, or cresol microspheres, 3-35; liquid carbonizable binder, 12-35; and fine powder containing titanium oxide, in particular, leucoxene concentrate (oil-bearing titanium-containing ore), 30-85; or fine powder of leucoxene concentrate, 25-74; and fine powder of titanium or silicon metal, 5-11. EFFECT: significantly increased conductance and strength of material. 3 cl, 1 tbl, 6 ex ССС ПЧ ГЭ РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (19) (51) МПК? ВИ "” 21445 313 ' 13) С1 С 04 В 35/46, 38/08 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 98107609/03, 21.04.1998 (24) Дата начала действия патента: 21.04.1998 (46) Дата публикации: 10.02.2000 (56) Ссылки: КУ 2057740 СЛ, 27.09.97. КУ 2055053 СЛ, 27.02.96. КЦ 2051100 СЛ, 27.03.96. КУ 2091303 СЛ, 27.09.97. ЕК 2110123 АЛ, 02.05.72. ОЕ 4228433 АД, 03.03.94. \О 97/43229 АЛ, 20.11.97. (98) Адрес для переписки: 620219, Екатеринбург, ул.Первомайская Э1, ИХТГ Уро РАН, Патентный отдел (71) Заявитель: Институт химии твердого тела Уральского отделения РАН (72) Изобретатель: Тимощук Т.А., Швейкин Г.П. (73) Патентообладатель: Институт химии твердого тела Уральского отделения РАН (54) ШИХТА ДЛЯ ПОЛУЧЕНИЯ ПЕНОКЕРАМИЧЕСКОГО МАТЕРИАЛА (ВАРИАНТЫ) (57) Реферат: Изобретение относится к области неорганической химии, в частности к пенокерамическим высокопористым композиционным материалам, которые могут быть использованы в качестве носителей катализаторов, фильтров для нагретого газа, пористых электродов, шумопоглощающих устройств. Шихта для получения пенокерамического материала содержит 3 - 35 мас.% углеродных, фенолформальдегидных или крезо-микросфер, 12 - 35 мас.% жидкого карбонизующегося связующего и 30 - 85 мас.% мелкодисперсного порошка, содержащего оксид титана, в ...

Porous carbon sheet and process for production thereof

A porous carbon sheet obtained by binding separate carbon short fibers with a carbonization product of a resin, wherein the pore mode diameter of the sheet is 45 to 90μm and the mean fiber diameter of the carbon short fibers is 5 to 20μm. The sheet can be produced by thermoforming a precursor fiber sheet comprising carbon short fibers of 15 to 30g/m2 in basis weight and a thermosetting resin of 30 to 80g/m2 in basis weight by hot plates having a certain clearance and carbonizing the thermosetting resin contained in the thermoformed precursor fiber sheet.

Porous carbon base material, method for preparation thereof, gas-diffusing material film-electrode jointed article, and fuel cell

A porous carbon base material includes a sheet containing carbon short fibers dispersed randomly and a carbonized resin, in which the carbon short fibers are bound by the carbonized resin and the volume of pores having a pore diameter of 10 μm or less is 0.05 to 0.16 cc/g. A method for producing this porous carbon base material includes intermittently transporting a precursor fiber sheet including short carbon fibers dispersed randomly and a resin to a space between heated plates, subjecting the precursor to a heating and pressuring treatment by the heated plates while the transformation stops, carrying out the transportation of the sheet after the treatment, and then carrying out a heat treatment, to thereby carbonize the resin in the sheet.

Porous electrode substrate, method for manufacturing same, precursor sheet, membrane electrode assembly, and polymer electrolyte fuel cell

According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher. The present invention also relates to a porous electrode substrate obtained by such a manufacturing method as well as a precursor sheet to be used for manufacturing the substrate, a membrane electrode assembly and a polymer electrolyte fuel cell.

Porous carbonaceous material and a method for producing the same

A slurry containing a precursor fiber convertible to carbon fiber and/or a carbon fiber and a thermosetting resin is processed into a random web. The web is hot-pressed between a pair of belts while curing of the resin is inhibited to prepare a prepreg sheet. The sheet is disposed, leaving a clearance, in a mold having ribs on a molding surface and heated over the melting point of the resin for expansion and complete cure to provide a porous composite sheet equipped with grooves. This porous composite sheet is carbonized or graphitized to produce a porous carbonaceous material for use as a fuel cell electrode material and so on. This porous carbonaceous material has high homogeneity, gas permeability, electrical conductivity, heat conductivity and mechanical strength.

Porous electrode substrate, method for manufacturing same, precursor sheet, membrane electrode assembly, and polymer electrolyte fuel cell

According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher. The present invention also relates to a porous electrode substrate obtained by such a manufacturing method as well as a precursor sheet to be used for manufacturing the substrate, a membrane electrode assembly and a polymer electrolyte fuel cell.

Electrode substrate for polymer electrolyte fuel cell and method for producing the same

METHOD FOR PRODUCING CARBON-CONTAINING COMPOSITE

1. Способ производства углеродсодержащего композита, который включает стадию(а) пиролиза пористой металлоорганической каркасной структуры, содержащей по меньшей мере одно по меньшей мере бидентатное органическое соединение, координированное с по меньшей мере одним ионом металла, в защитной газовой атмосфере, где по меньшей мере одно по меньшей мере бидентатное органическое соединение является свободным от азота.2. Способ по п.1, в котором пиролиз проводят при, по меньшей мере, 500°C.3. Способ по п.1 или 2, в котором защитная газовая атмосфера содержит азот.4. Способ по п.1 или 2, в котором по меньшей мере один ион металла представляет собой ион, выбранный из группы металлов, состоящей из Mg, Al, Zr, Ti, V, Cr, Mo, Fe, Co, Cu, Mi и Zn.5. Способ по п.1 или 2, в котором свободное от азота по меньшей мере одно по меньшей мере бидентатное органическое соединение является производным дикарбоновой, трикарбоновой или тетракарбоновой кислоты.6. Способ по п.1, который включает дальнейшую стадию(б) по меньшей мере частичного удаления одного или более металлических компонентов из композита, полученного на стадии (а).7. Способ по п.6, в котором один или более металлических компонентов содержит по меньшей мере один оксид металла.8. Способ по п.6 или 7, в котором по меньшей мере частичное удаление проводят промыванием посредством щелочной или кислотной жидкости.9. Способ по п.1 или 6, который включает дальнейшую стадию(в) импрегнирования композита, полученного на стадии (а) или (б), серой.10. Способ по п.9, в котором импрегнирование проводят смешиванием и последующим нагреванием.11. Способ по п.9 или 10, в котором серу используют в виде твердого вещества или в растворе.12. Пр РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2013 114 186 A (51) МПК C07C 51/41 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2013114186/04, 18.08.2011 (71) Заявитель(и): БАСФ СЕ (DE) Приоритет(ы): (30) Конвенционный приоритет: 01.09.2010 EP 10174939.8 ( ...

Process for producing a porous carbon product

Verfahren zur Herstellung eines porösen Kohlenstofferzeugnisses, umfassend folgende Verfahrensschritte:(a) Bereitstellen eines Templats aus anorganischem Templatmaterial, das miteinander verbundene Poren aufweist,(b) Bereitstellen einer Vorläufersubstanz für Kohlenstoff,(c) Infiltrieren der Poren des Templats mit der Vorläufersubstanz,(d) Carbonisieren der Vorläufersubstanz,(e) Entfernen des Templats unter Bildung des porösen Kohlenstofferzeugnisses. dadurch gekennzeichnet, dass Vorläufersubstanz-Partikel aus schmelzbarem Werkstoff und Templat-Partikel bereitgestellt und aus den Partikeln eine Pulvermischung erzeugt wird, und dass die Pulvermischung vor oder beim Carbonisieren gemäß Verfahrensschritt (d) derart erhitzt wird, dass Vorläufersubstanzschmelze in die Poren der Templat-Partikel eindringt, wobei das Bereitstellen der Templat-Partikel einen Soot-Abscheideprozess umfasst, bei dem ein Einsatzmaterial durch Hydrolyse oder Pyrolyse zu Templatmaterialteilchen umgesetzt wird. A method of producing a porous carbon product, comprising the steps of: (a) providing a template of inorganic template material having interconnected pores; (b) providing a precursor for carbon, (c) infiltrating the pores of the template with the precursor substance, (i ) Carbonizing the precursor substance, (e) removing the template to form the porous carbon product. characterized in that precursor substance particles of fusible material and template particles are provided and a powder mixture is produced from the particles, and that the powder mixture is heated before or during carbonization according to process step (d) such that precursor melt into the pores of the template particles wherein the providing of the template particles comprises a soot deposition process in which a feedstock is converted to template material particles by hydrolysis or pyrolysis.

Mesoporous carbon materials

The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

CARBON MATERIALS FROM LATEX

Mesoporous carbon materials

The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

Mesoporous carbon materials

The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than −2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

Mesoporous carbon materials

The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than −2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

Mesoporous carbon materials

The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than −2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

Carbon material and manufacturing method therefor

本发明提供制造石墨晶体性优异、且含有具有良好的载流子迁移率的适度的空间的多孔质碳材料，碳六边形网面的端部位于粒子及结构体的外表面的多孔质碳材料、类似石墨烯的薄片状石墨。通过对在适当的范围设定了材料中的闭气孔率、残留氢量的碳材料进行热等静压加压处理，由此发生以从碳材料中产生的氢、烃形成的闭气孔为核的石墨的气相生长反应，从而廉价且大量地制造目标的多孔质碳材料。通过对得到的多孔质碳材料施加物理性冲击、或生成以多孔质碳材料为主体的石墨层间化合物后再进行急速加热，由此可制造类石墨烯的石墨薄片。

CARBON-CONTAINING MATERIALS PRODUCED FROM LATEX

1. Углеродсодержащий материал, который может быть получен пиролизом ксерогеля из по меньшей мере одного гидрофильного полимера и по меньшей мере одного азотсодержащего латекса, причем полимер и латекс являются совместно поперечно сшитыми, отличающийся тем, что он представляет собой монолит углерода, содержащий от 0,1 до 20% графита по массе от общей массы материала. ! 2. Углеродсодержащий материал по п.1, отличающийся наличием по меньшей мере 3 последовательных пиков в спектре рентгеновской дифракции, измеренном на дифрактометре в конфигурации тета-тета, снабженном медным антикатодом и выраженном в терминах угла Брэгга 2-тета: ! Угол 2-тета ! 26,2 (*) ! 54,4 (*) ! 56,1 (**) ! ** значения ±0,5° ! * значение ±1° ! 3. Углеродсодержащий материал по п.1 или 2, который содержит систему пор, из которых по меньшей мере 10% являются мезопорами, и объем пор составляет от 0,4 до 1 см3/г. ! 4. Углеродсодержащий материал по п.1 или 2, имеющий полную удельную емкость, измеренную в одномолярном водном растворе H2SO4, больше или равную 75 ф/г. ! 5. Способ получения углеродсодержащего материала по одному из пп.1-4, причем способ включает в себя этап нагревания ксерогеля, полученного из по меньшей мере одного гидрофильного полимера и по меньшей мере одного азотсодержащего латекса до температуры, составляющей от 700 до 1050°С, в течение периода от 5 до 8 ч. ! 6. Способ по п.5, в котором ксерогель получен способом, содержащим этапы: ! (i) смешивание в водном растворе мономеров, входящих в состав гидрофильного полимера; ! (ii) введение латекса и перемешивание; ! (iii) добавление водного раствора основания для установления рН на значение, составляющее от 5,5 до 7,5; ! (iv) образование геля; ! (v РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2010 143 551 (13) A (51) МПК B01J 20/20 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (71) Заявитель(и): ХАТЧИНСОН (FR) (21)(22) Заявка: 2010143551/05, 26.03.2009 Приоритет(ы): (30) Конвенционный приоритет: 26.03.2008 ...

Macroreticular carbonaceous materials useful in energy storage devices

The present invention relates to an energy storage device comprising a macroreticular carbonaceous material having a distribution of micropores, mesopores and macropores wherein the macroreticular carbonaceous material has a total surface area of from greater than 500 m 2 /g to 2500 m 2 /g and wherein 20% to 80% of the total surface area is due to pores with diameters of from 17 angstroms to 100,000 angstroms. In addition, the present invention relates to an energy storage device comprising a macroreticular carbonaceous material having at least one first distinct peak representing a pore size of less than or equal to 20 angstroms when measured utilizing H-K dv/dlog(W) pore size distribution and at least one second distinct peak representing a pore size greater than 20 angstroms when measured utilizing BJH dv/dlog(D) pore size distribution.

Graphene materials with randomly distributed two-dimensional structural defects

Carbon foam, laminated carbon foam, and method for producing laminated carbon foam

本发明的目的在于提供薄膜的碳泡沫及其制造方法。本发明的目的还在于提供贯通孔少的层积碳泡沫及其制造方法。本发明的碳泡沫例如是至少2层的单层碳泡沫经层积而成的层积体，该单层碳泡沫具有线状部和结合该线状部的结合部；例如是具有线状部和结合该线状部的结合部的碳泡沫，直径1mm以上的大贯通孔的数目相对于碳泡沫的表面积的比例为0.0003个/mm 2 以下。

Fiber networks and method and device for continuous or batch production of fiber networks

Process for the preparation of nanostructured materials

The present invention comprises a novel process for the preparation of carbon based structured materials with controlled topology, morphology and functionality. The nanostructured materials are prepared by controlled carbonization, or pyrolysis, of precursors comprising phase separated copolymers. The precursor materials are selected to phase separate and self organize in bulk, in solution, in the presence of phase selective solvents, at surfaces, interfaces or during fabrication, into articles, fibers or films exhibiting well-defined, self-organized morphology or precursors of well-defined, self-organized, bi- or tri-phasic morphology. Compositional control over the (co)polymers provides control over the structure of the phase separated precursor whose organization therein dictates the nanostructure of the material obtained after carbonization or pyrolysis, wherein each dimension of the formed structure can be predetermined. When the precursor morphology is selected to comprise cylindrical domains this procedure additionally allows for the direct formation of two dimensional nanowire grids or arrays of oriented nanostructures on surfaces. When these nanowire grids or arrays are perpendicularly oriented to the surface applications include field emitters, high surface area electrodes, electronic devices such as diodes and transistors, tools for AMF tips and elements of molecular electronics. When the first nanostructured morphology is selected to form cylinders parallel to the surface then nanowire arrays are formed after pyrolysis. When the composition of the first nanostructured morphology is selected to comprise a continuous precursor matrix then a continuous carbon based nanostructured material is formed. The internal structure of the carbon based material can be selected to comprise perpendicular pores or an interconnected array of pores. The carbon based structures can additionally find application in photovoltaics, supercapacitors, batteries, fuel cells, ...

COMPOSITION FOR ORGANIC GEL OR ITS PYROLYSAT, PROCESS FOR PREPARING THE SAME, PYROLYSAT ELECTRODE COMPRISING THE COMPRESSOR AND INCORPORATING THE SAME.

PROCESS FOR PREPARING A CARBON MONOLITH OR ALVEOLAR CERAMIC COMPRISING A HIERARCHISED POROUS NETWORK

Electrically conductive ceramics

A metal oxide ceramic material such as alumina or chromia which has been rendered electrically conductive through its thickness by the incorporation of silver into the material. The metal oxide ceramic material may be in the form of a layer on a substrate such as a bipolar plate or other component for a fuel cell assembly. The electrical conductivity may be achieved by heating the ceramic material and a silver-containing material in contact with each other to at least 750 °C such that silver migrates from the silver-containing material into the metal oxide ceramic material and creates electrically conductive pathways through the ceramic material. In a particular embodiment, the substrate is a steel which forms an alumina, chromia or alumina-rich or chromia-rich surface layer in oxidising atmosphere and the silver-containing material is heated in an oxidising atmosphere in contact with the steel to cause the surface layer to form on the steel and to cause silver from the silver-containing material to occur in and create the electrically conductive pathways through the layer. The silver-containing material may be commercially pure silver or other forms of silver.

ELECTROCHEMICAL CELL WITH ELECTROLYTE FLOW COMPRISING THROUGH ELECTRODES AND METHOD OF MANUFACTURE

LEAD ACID BATTERY ELECTRODE COMPRISING A THROUGH PORE NETWORK AND METHOD FOR MANUFACTURING THE SAME

L'électrode comporte une structure 1 comportant un réseau de pores 1a traversants, parallèles et homogènes, et une armature externe 2 autour des faces latérales de la structure 1. La structure 1 et l'armature 2 sont en carbone. L'électrode est recouverte d'un couche à base de plomb. Les pores 1 a sont remplis d'un matériau actif à base de plomb. The electrode comprises a structure 1 comprising a network of pores 1a through, parallel and homogeneous, and an outer armature 2 around the lateral faces of the structure 1. The structure 1 and the armature 2 are made of carbon. The electrode is covered with a lead-based layer. The pores 1a are filled with an active material based on lead.

A ceramic plate with reflective film and method of manufacturing the same

MASTER MIXTURE OF CARBON NANOTUBES FOR LIQUID FORMULATIONS, PARTICULARLY IN LI-ION BATTERIES

The present invention relates to a masterbatch in agglomerated solid form comprising: a) carbon nanofibers and/or nanotubes and/or carbon black, the content of which is between 15 wt % and 40 wt %, preferably between 20 wt % and 35 wt %, relative to the total weight of the masterbatch; b) at least one solvent; c) at least one polymer binder, which represents from 1 wt % to 40 wt %, preferably from 2 wt % to 30 wt % relative to the total weight of the masterbatch. The present invention also relates to a concentrated masterbatch, characterized in that it is obtained by eliminating all or part of the solvent from the masterbatch described previously. It also relates to a process for preparing said masterbatches and to the uses of the latter, especially in the manufacture of an electrode or of a composite material for an electrode.

Positive electrode of lithium secondary battery and lithium secondary battery

Separator for fuel cell and manufacturing method for the same

A separator for a fuel cell is manufactured by preparing a raw material powder, uniformly mixing the prepared raw material to be formed into a slurry, and charging the raw material powder derived from granulation into a metal mold for heat press forming. The raw material is obtained by adding to carbon powder a binder containing a mixture of phenolic resin and epoxy resin. Therefore the heat press forming step does not cause the binder to generate gas, thus allowing manufacturing of a separator exhibiting sufficient gas-impermeability.

POROUS CARBON COMPOSITIONS

1. Состав отверждаемого жидкого углеродного прекурсора для приготовления пористой углеродной композиции, включающий в себя (a) по меньшей мере одну ароматическую эпоксидную смолу; (b)(i) по меньшей мере один ароматический сореакционный отвердитель, (b)(ii) по меньшей мере один каталитический отвердитель или (b)(iii) их смесь; и (c) по меньшей мере один порообразователь; причем жидкая композиция имеет чистую вязкость меньше чем 10000 мПа·с при температуре 25°C до добавления порообразователя, до добавления дополнительных компонентов, до отверждения, а также до карбонизации; и при этом отверждаемая жидкая композиция имеет выход углерода по меньшей мере 35 масс.% без учета массы порообразователя и любых дополнительных компонентов, присутствующих в композиции.2. Состав по п. 1, в котором порообразователь включает в себя пенообразующее вещество, диспергированный газ, временный шаблон, полый материал или их комбинации.3. Состав по п. 2, в котором пенообразующее вещество включает в себя жидкость, имеющую температуру кипения меньше чем 150ºC; и в котором жидкость включает в себя жидкий углеводород, фторзамещенный углеводород, хлорзамещенный углеводород, хлорфторзамещенный углеводород, а также их смеси.4. Состав по п. 2, в котором диспергированный газ включает в себя газ, имеющий температуру кипения меньше чем 20ºC; и в котором диспергированный газ содержит воздух, азот, газообразные углеводороды, двуокись углерода, а также их смеси.5. Состав по п. 2, в котором временный шаблон включает в себя полимерную частицу, имеющую температуру термического разложения меньше чем 600ºC.6. Состав по п. 2, в котором полый материал включает в себя любую форму, такую как сферы, трубы, цилиндры, диски, кубы, звезды, а также их РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2015 101 129 A (51) МПК C01B 31/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2015101129, 17.05.2013 (71) Заявитель(и): БЛЮ КЬЮБ АйПи ЭлЭлСи (US) Приоритет(ы): (30) ...

NEW PROCESS FOR MANUFACTURING HIGHLY CARBON MATERIALS AND HIGHLY CARBON MATERIAL OBTAINED

L'invention porte sur un procédé de fabrication (1) de matériau hautement carboné (2), caractérisé en ce qu'il comprend la combinaison (100) d'un précurseur structuré (10) comportant une fibre ou un ensemble de fibres et d'un précurseur non structuré (15), se présentant sous la forme d'un fluide, et comportant au moins un composé organique cyclique ou aromatique à l'état fondu ou en solution à une concentration en masse inférieure ou égale à 65 %, de façon à obtenir un précurseur combiné (20) correspondant au précurseur structuré (10) recouvert par le précurseur non structuré (15), ledit procédé comprenant en outre les étapes suivantes : - une étape de stabilisation thermique et dimensionnelle (200) du précurseur combiné (20) de façon à obtenir une fibre ou un ensemble de fibres recouvertes d'un dépôt de composé organique cyclique ou aromatique (30), et - une étape de carbonisation (300) de la fibre ou de l'ensemble de fibres recouvertes d'un dépôt de composé organique cyclique ou aromatique (30) de façon à obtenir un matériau hautement carboné (2). The invention relates to a method for the production (1) of highly carbonaceous material (2), characterized in that it comprises the combination (100) of a structured precursor (10) comprising a fiber or a set of fibers and an unstructured precursor (15), in the form of a fluid, and comprising at least one cyclic or aromatic organic compound in the molten state or in solution at a mass concentration of not more than 65%, of to obtain a combined precursor (20) corresponding to the structured precursor (10) covered by the unstructured precursor (15), said method further comprising the following steps: - a thermal and dimensional stabilization step (200) of the combined precursor ( 20) to obtain a fiber or a set of fibers covered with a cyclic or aromatic organic compound deposit (30), and - a carbonization step (300) of the fiber or set of fibers coated with a depot t cyclic or aromatic ...

PROCESS FOR THE PREPARATION OF A MULTIMODAL POROSITY MONOLITE

Procédé de préparation d'un monolithe poreux comprenant entre 10 et 100% en poids d'un semi-conducteur par rapport au poids total du monolithe poreux, lequel procédé comprend les étapes suivantes : a) on prépare une première suspension aqueuse contenant des particules de polymère ; b) on prépare une seconde suspension aqueuse contenant des particules d'au moins un semi-conducteur inorganique ; c) on mélange les deux suspensions aqueuses préparées à l'étape a) et b) pour obtenir une pâte ; d) on réalise un traitement thermique de la pâte obtenue à l'étape c) pour obtenir le monolithe à porosité multimodale. Process for the preparation of a porous monolith comprising between 10 and 100% by weight of a semiconductor relative to the total weight of the porous monolith, which process comprises the following steps: a) a first aqueous suspension containing particles of polymer; b) preparing a second aqueous suspension containing particles of at least one inorganic semiconductor; c) the two aqueous suspensions prepared in step a) and b) are mixed to obtain a paste; d) a heat treatment of the paste obtained in step c) is carried out to obtain the monolith with multimodal porosity.

A Negative Electrode Active Material for an Electricity Storage Device and Method for Manufacturing the Same

The invention provides a negative electrode active material for an electricity storage device, which has considerably enhanced low-temperature characteristics, increased energy density, and increased output power. A negative electrode active material is made of a carbon composite containing carbon particles as a core and a fibrous carbon having a graphene structure, which is formed on the surfaces and/or the inside of the carbon particles, wherein the carbon composite has a volume of all mesopores within 0.005 to 1.0 cm 3 /g, and a volume of the mesopores each with a pore diameter ranging from 100 to 400 Å of not less than 25% of the volume of all mesopores.

Porous alumina free-standing film, alumina sol and methods for producing same

The present invention provides a porous alumina self-supporting film which has a sufficient strength to be used as a self-supporting film, is flexible and has a high transparency; an alumina sol that is composed of fibrous or needle-like boehmite particles dispersed in a solution and that has a high storage stability; and methods for producing such a film and such an alumina sol. More specifically, the invention provides a porous alumina self-supporting film which is composed of a collection of fibrous or needle-like alumina hydrate particles or alumina particles having an average breadth of 1 to 10 nm, an average aspect ratio (length/breadth) of 30 to 5,000 and an average length of 100 to 10,000 nm, has an orientation, has a pore distribution with a pore diameter d peak of 0.5 to 20 nm, is flexible, has a high transparency, and has the ability to luminesce when excited by ultraviolet light; an alumina sol which has a Na, K and SO 4 content of 0 to 1 ppm, has an orientation when the particles are collected, and luminesces when excited by ultraviolet light after being fired at 250 to 900°C; and methods for producing such a film and such an alumina sol.

Masterbatch of carbon-based conductive fillers for liquid formulations, especially in li-ion batteries

본 발명은 하기를 포함하는 응집된 고체 형태의 마스터배치에 관한 것이다: a) 마스터배치의 전체 중량에 대해 함량이 15 중량% 내지 40 중량%, 바람직하게는 20 중량% 내지 35 중량% 인 탄소나노섬유 및/또는 나노튜브 및/또는 카본 블랙; b) 하나 이상의 용매; c) 마스터배치의 전체 중량에 대해 1 중량% 내지 40 중량%, 바람직하게는 2 중량% 내지 30 중량% 를 나타내는 하나 이상의 중합체 바인더. 본 발명은 또한 앞서 기술된 마스터배치로부터 모든 또는 일부의 용매를 제거함으로써 얻어지는 것을 특징으로 하는 농축된 마스터배치에 관한 것이다. 이는 또한 상기 마스터배치의 제조방법 및 특별하게는 전극 또는 전극용 복합 재료의 제조에서의 후자의 용도에 관한 것이다.

PROCESS FOR THE PREPARATION OF OXIDE LAYERS OF METAL ELEMENTS

Procédé de préparation d'une couche d'oxyde d'élément métallique sur un substrat dans lequel on réalise les étapes successives suivantes :a) dispersion d'une poudre d'oxyde d'élément métallique dans un milieu liquide comprenant un solvant de dispersion et un dispersant, ledit milieu liquide ne comprenant ni plastifiant, ni liant, moyennant quoi l'on obtient une suspension A de ladite poudre dans ledit milieu liquide ;b) on ajoute à ladite suspension A, une solution d'au moins un polymère dans un solvant, moyennant quoi, on obtient une suspension B ;c) on effectue le dépôt de la suspension B sur le substrat par un procédé de revêtement par immersion-retrait (« dip coating »), moyennant quoi, on obtient une couche crue ;d) on sèche la couche crue obtenue dans l'étape c) ;e) on calcine la couche séchée obtenue dans l'étape d). Process for the preparation of a layer of metal element oxide on a substrate in which the following successive steps are carried out: a) dispersion of a powder of metal element oxide in a liquid medium comprising a dispersion solvent and a dispersant, said liquid medium comprising neither plasticizer nor binder, whereby a suspension A of said powder is obtained in said liquid medium; b) a solution of at least one polymer in a solvent, whereby a suspension B is obtained; c) the suspension B is deposited on the substrate by a dip coating process, whereby a raw layer is obtained; ) the raw layer obtained in step c) is dried; e) the dried layer obtained in step d) is calcined.

PROCESS FOR THE PREPARATION OF A LOW THICKNESS CERAMIC MATERIAL WITH CONTROLLED SURFACE POROSITY GRADIENT, CERAMIC MATERIAL OBTAINED, ELECTROCHEMICAL CELL AND CERAMIC MEMBRANE COMPRISING THE SAME

MATERIAL WITH TUBULAR PORES

Produit constitué en un matériau céramique, au moins une partie dudit produit présentant une teneur massique en zircone supérieure à 1,5% et inférieure à 40% et/ou n'étant pas constitué de silice amorphe et comportant des pores et respectant les critères suivants (a), (b), et (c) : (a) au moins 70% en nombre desdits pores sont des pores tubulaires tronconiques s'étendant sensiblement parallèlement les uns aux autres suivant une direction longitudinale ; (b) dans au moins un plan de coupe transversal, la taille moyenne des sections transversales desdits pores, est supérieure à 0,15 µm et inférieure à 300 µm ; (c) dans au moins un plan de coupe transversal, au moins 50% en nombre des pores présentent un indice de convexité le supérieur à 87%, l'indice de convexité d'un pore étant égal au rapport Sp/Sc des surfaces Sp et Se délimitées par le périmètre et par l'enveloppe convexe dudit pore, respectivement. Product made of a ceramic material, at least a part of said product having a zirconia content by mass greater than 1.5% and less than 40% and / or not consisting of amorphous silica and having pores and meeting the following criteria (a), (b), and (c): (a) at least 70% by number of said pores are frustoconical tubular pores extending substantially parallel to each other in a longitudinal direction; (b) in at least one cross-sectional plane, the average size of the cross-sections of said pores is greater than 0.15 μm and less than 300 μm; (c) in at least one transverse cross-sectional plane, at least 50% by number of the pores have a convexity index greater than 87%, the convexity index of a pore being equal to the Sp / Sc ratio of the Sp surfaces and delimited by the perimeter and the convex hull of said pore, respectively.

LEAD ACID BATTERY ELECTRODE COMPRISING A THROUGH PORE NETWORK AND METHOD FOR MANUFACTURING THE SAME

Ceramic-based composite material impregnated with phase change material and flame retardant fillers and provided with two flame retardant layers, and its method of manufacture

Titre : Matériau composite à base de céramique imprégné d’un matériau à changement de phase et de charges ignifugeantes et doté de deux couches ignifugeantes, ainsi que son procédé de fabrication Un matériau composite comprenant un support poreux (1) à base de céramique dans lequel les pores (3) du support poreux comprennent au moins un matériau à changement de phase (4) et au moins un type de charges ignifugeantes (5), le support poreux comportant deux faces, chaque face étant revêtue d’une couche ignifugeante (2a, 2b). Un procédé de préparation de ce matériau composite. Une batterie (6) comprenant : (i) un coffre (7) présentant un fond et plusieurs parois latérales, (ii) au moins deux éléments électrochimiques (8-1, 8-2, 8-3), et (iii) le matériau composite, ledit matériau composite étant disposé entre lesdits au moins deux éléments électrochimiques, et/ou entre le fond du coffre et au moins un élément électrochimique, et/ou entre une ou plusieurs des parois latérales et au moins un élément électrochimique. Ce matériau composite combine les propriétés de bonne gestion thermique en fonctionnement normal des éléments et de barrière thermique contre la propagation d’un emballement thermique. Figure d’abrégé : Figure 1 Title: Ceramic-based composite material impregnated with a phase-change material and flame-retardant fillers and provided with two flame-retardant layers, and its manufacturing method A composite material comprising a porous ceramic-based support (1) in which the pores (3) of the porous support comprise at least one phase change material (4) and at least one type of flame retardant fillers (5), the porous support having two faces, each face being coated with a flame retardant layer (2a , 2b). A process for preparing this composite material. A battery (6) comprising: (i) a case (7) having a bottom and a plurality of side walls, (ii) at least two electrochemical elements (8-1, 8-2, 8-3), and (iii) the composite material, said composite material being ...

Mesoporous carbon materials

The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a tem-plating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde compo-nent, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step com-prises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

METHOD FOR STORING HYDROGEN IN POROUS MONOLITHIC MATERIAL, COMPOSITE MATERIAL OBTAINED AND APPLICATIONS

PROCESS FOR PREPARING A CARBON MONOLITH OR ALVEOLAR CERAMIC COMPRISING A HIERARCHISED POROUS NETWORK

La présente invention est relative à des matériaux monolithiques de carbone ou céramiques à structure poreuse hiérarchisée M2 (Macroporeux/Microporeux), à leur procédé de préparation à partir d'une empreinte de silice macro/méso/microporeuse, ainsi qu'à leur utilisation, notamment pour la fabrication d'épurateurs d'hydrogène, de super-condensateurs ou d'électrodes ou bien pour la réalisation de réactions chimiques catalysées en phase hétérogène. The present invention relates to monolithic carbon or ceramic materials having a hierarchical M2 (Macroporous / Microporous) porous structure, to their process of preparation starting from a macro / meso / microporous silica footprint, as well as to their use, in particular for the manufacture of hydrogen purifiers, super-capacitors or electrodes or for the realization of catalyzed chemical reactions in heterogeneous phase.

Electrolytic cell diaphragm/membrane

This invention is directed toward process and material optimization of electrolytic cell separation processes designed to generate consistent electrolytic solutions in a better salt-converting and efficient manner, as well as to increase the amount of free available chlorine generated by the electro-chemical activation of the salt. This is generally accomplished by provision of ceramic diaphragm and/or polymer membranes characterized by optimal design, construction, manufacturing, and assemblage to exacting and precise specifications with respect to chemical and material compositions, slurry formulations, ceramic mold tolerances, ceramic firing and curing conditions, dimensional measurements for thickness, dimensional measurements for gapping and placement between the anode and cathode electrodes, and machining tolerance control.