Thermochromic Compositions From Trisubstituted Pyridine Leuco Dyes

A thermochromic leuco dye composition contains a leuco dye moiety including one or more tri-aryl substituted pyridines, a UVA developer moiety including at least one UVA developer selected from the group consisting of salicylic acid and derivatives thereof, and biphenyls and derivatives thereof, and a carrier selected from the group consisting of a fatty ester, fatty alcohol, fatty amide, and combinations thereof.

POLYMERIC MATERIALS WITH THERMOCHROMIC PIGMENTS

Compositions and methods related to polymeric materials with thermochromic pigments are generally described. 1. A polymeric composition that has a first color at a first temperature , comprising:a polymerized component, a first thermochromic pigment, a second thermochromic pigment, and a third thermochromic pigment;wherein the first thermochromic pigment, second thermochromic pigment and/or third thermochromic pigment cause the polymeric composition to have a second color at a second temperature, a third color and a third temperature, and/or a fourth color at a fourth temperature.2. The polymeric composition of claim 1 , wherein the polymerized component comprises silicone oil.3. The polymeric composition of wherein the silicone oil comprises a siloxane.4. The polymeric composition of claim 2 , wherein the silicone oil is polydimethylsiloxane.5. The polymeric composition of claim 2 , wherein the silicone oil comprises dimethylsiloxane.6. The polymeric composition of claim 1 , wherein the polymeric composition comprises boric acid.7. The polymeric composition of claim 1 , wherein the polymeric composition is a silicone oil-based putty composition.8. The polymeric composition of claim 2 , wherein the composition comprises silicone oil in a range of 50 wt. % to 95 wt. % versus the total weight of the composition.9. The polymeric composition of claim 1 , wherein the polymerized component comprises an organic polymer.10. The polymeric composition of claim 9 , wherein the organic polymer comprises polyvinyl alcohol claim 9 , polyvinyl acetate claim 9 , polysaccharide guar gum claim 9 , methylcellulose claim 9 , cornstarch claim 9 , and/or derivatives thereof.11. The polymeric composition of claim 9 , further comprising water.12. The polymeric composition of claim 9 , further comprising an initiator.13. The polymeric composition of claim 12 , wherein the initiator is sodium borate and/or sodium tetraborate.14. The polymeric composition of claim 1 , wherein the polymeric ...

Temperature Detecting Material, Temperature Detecting Ink Using Same, Temperature Indicator, and Product Control System

Please substitute the new Abstract submitted herewith for the original Abstract: A temperature detecting material comprises a first material containing a first temperature indicating material and a second material containing a second temperature indicating material, wherein the first temperature indicating material and the second temperature indicating material contain a leuco dye, a color developing agent, and a decoloring agent, and have a hysteresis characteristic in their color density-temperature curves, wherein the first temperature indicating material has a color developing temperature in a temperature increase process lower than a decoloring temperature in the temperature increase process, and turns to a non-crystalline state and is kept in a decoloring state when cooled down below the color developing temperature in the temperature increase process with a predetermined cooling speed or more after melting, wherein the second temperature indicating material, a color developing temperature is lower than a decoloring temperature in the temperature increase process, and wherein the color developing temperature in the temperature increase process is lower than the decoloring temperature in the temperature increase process and the color developing temperature is lower than the color developing temperature in the temperature increase process. 1. A temperature detecting material comprising a first material containing a first temperature indicating material and a second material containing a second temperature indicating material ,whereinthe first temperature indicating material and the second temperature indicating material respectively contain a leuco dye, a color developing agent, and a decoloring agent, and respectively have hysteresis characteristics in their color density-temperature curves,wherein{'sub': a1', 'di', 'a1, 'the first temperature indicating material has a color developing temperature Tin a temperature increase process, which is lower than a ...

ELECTRONIC DEVICE HOUSINGS

The present disclosure is drawn to an electronic device housing that can include a heat sensitive coating and a second heat sensitive coating applied to an electronic device housing. The heat sensitive coating or portion thereof can include a thermochromatic colorant having a color-changing activation temperature, and the second heat sensitive coating or portion thereof can include a second thermochromatic colorant having a second color-changing activation temperature. The color-changing activation temperature can be a temperature from 30° C. to about 100° C., and the second color-changing activation temperature can be at least 5° C. greater than the color-changing activation temperature. 1. An electronic device housing , comprising:a heat sensitive coating applied to an electronic device housing surface, the heat sensitive coating or portion thereof comprising a thermochromatic colorant having a color-changing activation temperature;a second heat sensitive coating applied to the electronic device housing surface, the second heat sensitive coating or portion thereof comprising a second thermochromatic colorant having a second color-changing activation temperature;wherein the color-changing activation temperature is at a temperature from 30° C. to about 100° C., and the second color-changing activation temperature is at least 5° C. greater than the color-changing activation temperature.2. The electronic device housing of claim 1 , wherein the thermochromatic colorant is a reversible thermochromatic colorant claim 1 , and the second thermochromatic colorant is an irreversible thermochromatic colorant.3. The electronic device housing of claim 1 , wherein the thermochromatic colorant is a reversible thermochromatic colorant claim 1 , and the second thermochromatic colorant is also a reversible thermochromatic colorant.4. The electronic device housing of claim 1 , wherein the heat sensitive coating and the second heat sensitive coating are applied to the electronic ...

REACTIVE LEUCO COMPOUNDS AND COMPOSITIONS COMPRISING THE SAME

A leuco composition comprises at least one reactive leuco compound, which reactive leuco compound comprises a leuco moiety and at least one reactive moiety covalently bound to the leuco moiety. A laundry care composition comprises a laundry care ingredient and a leuco composition. A method of treating a textile comprises the steps of (i) treating a textile with an aqueous solution containing a leuco composition, (ii) optionally, rinsing the textile, and (iii) drying the textile. 1. A leuco composition comprising at least one reactive leuco compound , wherein the reactive leuco compound comprises a leuco moiety and at least one reactive moiety covalently bound to the leuco moiety , wherein the reactive moiety is sufficiently electrophilic to react with a nucleophilic moiety , and wherein the ratio of the amount of the reactive leuco compound present in the leuco composition to the amount of a colored form of the reactive leuco compound present in the leuco composition is about 1:9 or more.2. The leuco composition of claim 1 , wherein the leuco moiety is selected from the group consisting of diarylmethane leuco moieties claim 1 , triarylmethane leuco moieties claim 1 , oxazine moieties claim 1 , thiazine moieties claim 1 , hydroquinone moieties claim 1 , and arylaminophenol moieties.4. The leuco composition of claim 3 , wherein the leuco moiety conforms to the structure of Formula (I).5. The leuco composition of claim 4 , wherein two Rgroups on different A claim 4 , B and C rings combine to form a fused ring of five or more members.6. The leuco composition of claim 5 , wherein the fused ring is six or more members and two Rgroups on different A claim 5 , B and C rings combine to form an organic linker containing one or more heteroatoms.7. The leuco composition of claim 6 , wherein two Ron different A claim 6 , B and C rings combine to form a heteroatom bridge selected from —O— and —S— to create a six member fused ring.8. The leuco composition of claim 4 , wherein ...

Leuco polymers as bluing agents in laundry care compositions

A leuco polymer includes a leuco monomer and an alkene. The leuco polymer has a molecular weight of at least 500 and is obtainable by polymerization of the leuco monomer and one or more alkene co-monomers. The leuco monomer consists of an alkene covalently bound to a leuco moiety and the leuco monomer has a molar extinction coefficient at a wavelength in the range 400 to 750nm of less than 1000 M −1 cm −1 . The alkene monomer(s) have a molar extinction coefficient at a wavelength in the range 400 to 750nm that is less than 100 M −1 cm −1 . Methods of making the leuco polymer, laundry care compositions comprising the leuco polymer and methods of treating textiles with such laundry care compositions.

LEUCO POLYMERS AS BLUING AGENTS IN LAUNDRY CARE COMPOSITIONS

A leuco polymer comprising a polyethylenimine and at least one leuco moiety covalently bound to the polyethylenimine, wherein the polyethylenimine comprises three or more amine nitrogen atoms and 1 mol. % or more of amine hydrogen atoms in the polyethylenimine are replaced with a moiety selected from the group consisting of 2-hydroxypropyl, 1-hydroxypropane-2-yl, and polyalkoxy groups. Methods of making the leuco polymer, laundry care compositions comprising the leuco polymer and methods of treating textiles with such laundry care compositions. 1. A leuco polymer comprising a polyethylenimine and at least one leuco moiety covalently bound to the polyethylenimine , wherein the polyethylenimine comprises three or more amine nitrogen atoms and 1 mol. % or more of amine hydrogen atoms in the polyethylenimine are replaced with a moiety selected from the group consisting of 2-hydroxypropyl , 1-hydroxypropane-2-yl , and polyalkoxy groups.2. The leuco polymer of claim 1 , wherein the polyethylenimine comprises about 6 to about 1 claim 1 ,000 claim 1 ,000 amine nitrogen atoms.3. The leuco polymer of claim 1 , wherein the polyethylenimine comprises about 15 to about 45 amine nitrogen atoms.4. The leuco polymer of claim 1 , wherein about 20 mol. % to about 95 mol. % of amine hydrogen atoms in the polyethylenimine are replaced with 2-hydroxypropyl groups.5. The leuco polymer of claim 4 , wherein about 57 mol. % to about 80 mol. % of amine hydrogen atoms in the polyethylenimine are replaced with 2-hydroxypropyl groups.6. The leuco polymer of claim 1 , wherein about 3 mol. % to about 15 mol. % of amine hydrogen atoms in the polyethylenimine are replaced with polyalkoxy groups.7. The leuco polymer of claim 1 , wherein the polyalkoxy group comprises alkoxy groups selected from the group consisting of ethoxy and propoxy.8. The leuco polymer of claim 1 , wherein the polyalkoxy group comprises 3 or more repeating alkoxy groups.9. The leuco polymer of claim 8 , wherein the polyalkoxy ...

LEUCO POLYMERS AS BLUING AGENTS IN LAUNDRY CARE COMPOSITIONS

A laundry care composition including at least one laundry care ingredient and at least one leuco polymer including a polymeric carbohydrate and a leuco moiety. The polymeric carbohydrate and the leuco moiety are covalently bound. Methods of making the leuco polymer, laundry care compositions comprising the leuco polymer and methods of treating textiles with such laundry care compositions. 1. A laundry care composition comprising: (a) at least one laundry care ingredient and (b) at least one leuco polymer comprising a polymeric carbohydrate and a leuco moiety , wherein the polymeric carbohydrate and the leuco moiety are covalently bound.2. A laundry care composition according to claim 1 , wherein the leuco moiety is selected from the group consisting of diarylmethane leuco moieties claim 1 , triarylmethane leuco moieties claim 1 , oxazine moieties claim 1 , thiazine moieties claim 1 , hydroquinone moieties claim 1 , and arylaminophenol moieties.3. A laundry care composition according to claim 1 , wherein the polymeric carbohydrate is selected from the group consisting of cellulose claim 1 , a cellulose ether claim 1 , an esterified cellulose claim 1 , starch claim 1 , guar gum and mixtures thereof.4. A laundry carecomposition according to claim 1 , wherein the polymeric carbohydrate is selected from the group consisting of chitosan claim 1 , carboxymethyl cellulose claim 1 , methyl cellulose claim 1 , hydroxyl ethyl cellulose claim 1 , methyl hydroxyethylcellulose claim 1 , methyl hydroxypropylcellulose claim 1 , methyl caroboxymethyl cellulose claim 1 , fatty ester modified celluloses claim 1 , phosphorylated cellulose claim 1 , cationic starch claim 1 , uncharged starch claim 1 , and the salts thereof.6. A laundry care composition according to claim 5 , wherein the leuco is a univalent or polyvalent moiety derived by removal of one or more hydrogen atoms from a compound conforming to a structure of Formula (I) claim 5 , (II) claim 5 , or (IV).7. The laundry care ...

LEUCO COLORANTS AND COMPOSITIONS

A leuco composition comprises at least one leuco compound, the leuco compound comprising a leuco moiety and a polyalkyleneoxy moiety covalently bound to the leuco moiety. The polyalkyleneoxy moiety comprises at least one ethylene oxide group and at least one propylene oxide group. A laundry care composition comprises (a) at least one laundry care ingredient and (b) a leuco composition as described above. A method of treating a textile includes the steps of (a) providing such a laundry care composition; (b) adding the laundry care composition to a liquid medium; (c) placing textile articles in the liquid medium; (d) optionally, rinsing the textile; and (e) drying the textile articles. 1. A leuco composition comprising at least one leuco compound , the leuco compound comprising a leuco moiety and a alkyleneoxy moiety covalently bound to the leuco moiety , wherein the alkyleneoxy moiety comprises at least one ethylene oxide group and at least one propylene oxide group.2. The leuco composition of claim 1 , wherein the leuco moiety is selected from the group consisting of diarylmethane leuco moieties claim 1 , triarylmethane leuco moieties claim 1 , oxazine moieties claim 1 , thiazine moieties claim 1 , hydroquinone moieties claim 1 , and arylaminophenol moieties claim 1 ,3. The leuco composition of claim 2 , wherein the leuco moiety is a triarylmethane leuco moiety.4. The leuco composition of claim 1 , wherein the alkyleneoxy moiety comprises from 1 to about 20 ethylene oxide groups and from 1 to about 20 propylene oxide groups.5. The leuco composition of claim 1 , wherein the alkyleneoxy moiety is covalently bound to the leuco moiety through a nitrogen atom claim 1 , the nitrogen atom and the alkyleneoxy moiety together having the structure —NR(CHO)(CHO)H claim 1 , where n and q are independently selected from integers from 1 to 5 claim 1 , and Ris selected from the group consisting of hydrogen claim 1 , alkyl claim 1 , substituted alkyl claim 1 , aryl claim 1 , ...

LEUCO COMPOUNDS AND COMPOSITIONS COMPRISING THE SAME

A leuco compound comprises an antioxidant moiety covalently bonded to a leuco moiety. A laundry care composition comprises (a) at least one laundry care ingredient and (b) a leuco compound as described above. A method of treating a textile comprises the steps of (a) providing such a laundry care composition; (b) adding the laundry care composition to a liquid medium; (c) placing textile articles in the liquid medium; (d) optionally, rinsing the textile; and (e) drying the textile articles. 1. A leuco compound comprising at least one antioxidant moiety covalently bound to at least one leuco moiety , provided , when the leuco moiety is a triphenylmethane leuco moiety , the leuco moiety comprises a pendant group covalently bound to an phenyl moiety of the triphenylmethane leuco moiety , wherein the pendant group is independently selected from the group consisting of halogens , nitro , alkyl , substituted alkyl , aryl , substituted aryl , alkaryl , substituted alkaryl , —(CH)—O—R , —(CH)—NRR—C(O)R , —C(O)OR , —C(O)O , —C(O)NRR , —OC(O)R , —OC(O)OR , —OC(O)NRR , —S(O)R , —S(O)OR , —S(O)O , —S(O)NRR , —NRC(O)R , —NRC(O)OR , —NRC(O)SR , —NRC(O)NRR , —P(O)R , —P(O)(OR) , —P(O)(OR)O , and —P(O)(O); wherein the index n is an integer from 0 to 4; wherein any two of R , Rand Rattached to the same heteroatom can combine to form a ring of five or more members optionally comprising one or more additional heteroatoms selected from the group consisting of —O— , —NR— , and —S—; and wherein R , R , R , and Rare independently selected from the group consisting of hydrogen , alkyl , substituted alkyl , aryl , substituted aryl , alkaryl , substituted alkaryl , and R; and Ris an organic group composed of one or more organic monomers with said monomer molecular weights ranging from 28 to 500.2. The leuco compound of claim 1 , wherein the leuco moiety is selected from the group consisting of diarylmethane leuco moieties claim 1 , triarylmethane leuco moieties claim 1 , oxazine moieties ...

Camouflage Pattern With Extended Infrared Reflectance Separation

Fabrics containing camouflage patterns are produced from dyes wherein at least certain of the colors contained in the pattern contain a low reflectance dye. The low reflectance dye is added to one or more colors in the pattern in order to preserve the camouflage pattern when viewed through night vision goggles as relatively long wavelengths, such at wavelengths greater than 900 nm. In one embodiment, the low reflectance dye comprises a thiazine. The low reflectance dye is blended with other dyes to produce colors in the pattern. By altering the concentration of the low reflectance dye in each of the colors, the colors contained in the camouflage pattern remain separate and distinct even at relatively long wavelengths.

AEROSOL-GENERATING ARTICLE COMPRISING A THERMAL INDICATOR

An aerosol generating article is provided, including a combustible carbonaceous heat source; an aerosol-forming substrate; and a thermal indicator provided on an outer surface of the aerosol-generating article downstream of the combustible carbonaceous heat source. The thermal indicator includes at least one reversible thermochromic material that undergoes a first reversible visible colour change when a temperature of the thermal indicator rises to a first switching temperature and a second reversible visible colour change when a temperature of the thermal indicator falls to a second switching temperature. The first switching temperature is below about 80° C. and the second switching temperature is lower than or equal to the first switching temperature. 115.-. (canceled)16. An aerosol generating article , comprising:a combustible carbonaceous heat source;an aerosol-forming substrate; anda thermal indicator provided on an outer surface of the aerosol-generating article downstream of the combustible carbonaceous heat source, the thermal indicator comprising at least one reversible thermochromic material that undergoes a first reversible visible colour change when a temperature of the thermal indicator rises to a first switching temperature and a second reversible visible colour change when a temperature of the thermal indicator falls to a second switching temperature,wherein the first switching temperature is below about 80° C. and the second switching temperature is lower than or equal to the first switching temperature.17. The aerosol-generating article according to claim 16 , wherein the first switching temperature is between about 30° C. and about 80° C.18. The aerosol-generating article according to claim 17 , wherein the first switching temperature is between about 30° C. and about 60° C.19. The aerosol-generating article according to claim 16 , wherein the second switching temperature is between about 3° C. and about 15° C. lower than the first switching ...

ARTICLE WITH A COLOR-TUNING LAYER

A flake including a reflector layer having a first surface, and a second surface opposite the first surface; and a first selective light modulator layer external to the first surface; wherein the first selective light modulator layer includes a colorant having a first color that changes to a second color upon application of energy is disclosed. A method of making a composition is also disclosed. 1. A flake comprising:a reflector layer having a first surface, and a second surface opposite the first surface; anda first selective light modulator layer external to the first surface;wherein the first selective light modulator layer includes a colorant having a first color that changes to a second color upon application of energy.2. The flake of claim 1 , wherein the colorant is a thermochromic dye.3. The flake of claim 1 , wherein the colorant is a photochromic dye.4. The flake of claim 1 , wherein the colorant includes two or more colorants.5. The flake of claim 4 , wherein each of the two or more colorants independently have a first color that changes to a second color upon application of energy.6. The flake of claim 2 , wherein the thermochromic dye is a leuco dye.7. The flake of claim 3 , wherein the photochromic dye is a spiropyran.8. The flake of claim 1 , further comprising a second selective light modulator layer external to the second surface.9. The flake of claim 8 , wherein the second selective light modulator layer includes a colorant having a first color that changes to a second color upon application of energy.10. The flake of claim 1 , further comprising a stack of selective light modulator layers on the second surface claim 1 , and wherein each layer of the stack of the selective light modulator layers includes a colorant having a first color that changes to a second color upon application of energy.11. The flake of claim 1 , further comprising a second selective light modulator layer that is different from the first selective light modulator layer.12. ...

Thermochromic Temperature Sensor

A temperature sensor, and methods of making and using such a temperature sensor, whereby the temperature sensor includes a reversible thermochromic color-changing system having a dye, a developer, and a solvent. Upon exposure to a preselected temperature threshold, association or disassociation of the dye and the developer results in a visible color change. Further, the color-changing system includes a color-memory property which facilitates retention of the color change to effectively record exposure to the temperature threshold. 1. A temperature sensor comprising: a dye;', 'a developer; and', 'a solvent;, 'a reversible thermochromic color-changing system comprisingwherein upon exposure to a preselected temperature threshold, association or disassociation of said dye and said developer results in a visible color change; andwherein said color-changing system comprises a color-memory property which facilitates retention of said color change to record said exposure to said temperature threshold.2. The temperature sensor of claim 1 , wherein said dye comprises a leuco dye.3. The temperature sensor of claim 2 , wherein said leuco dye reversibly changes between a substantially colorless state and a visibly colored state.4. The temperature sensor of claim 3 , wherein said color-changing system comprises:a coloration temperature at which said leuco dye changes to said colored state; anda decoloration temperature at which said leuco dye changes from said colored state;wherein said coloration temperature differs from said decoloration temperature.5. The temperature sensor of claim 4 , wherein said color-changing system comprises:a coloration temperature at which said leuco dye changes to said colored state; anda decoloration temperature at which said leuco dye changes to said colorless state;wherein said coloration temperature differs from said decoloration temperature.6. The temperature sensor of claim 5 , wherein said coloration temperature is less than said decoloration ...

LEUCO POLYMERS AS BLUING AGENTS IN LAUNDRY CARE COMPOSITIONS

A leuco polymer includes a leuco monomer and an alkene. The leuco polymer has a molecular weight of at least 500 and is obtainable by polymerization of the leuco monomer and one or more alkene co-monomers. The leuco monomer consists of an alkene covalently bound to a leuco moiety and the leuco monomer has a molar extinction coefficient at a wavelength in the range 400 to 750 nm of less than 1000 Mcm. The alkene monomer(s) have a molar extinction coefficient at a wavelength in the range 400 to 750 nm that is less than 100 Mcm. Methods of making the leuco polymer, laundry care compositions comprising the leuco polymer and methods of treating textiles with such laundry care compositions. 1. A leuco polymer comprising a leuco monomer and an alkene , wherein the leuco polymer has a molecular weight of at least 500 and is obtainable by polymerization of the leuco monomer and one or more alkene co-monomers , wherein the leuco monomer consists of an alkene covalently bound to a leuco moiety and the leuco monomer has a maximum molar extinction coefficient at a wavelength in the range 400 to 750 nm of less than 1000 Mcm , wherein the alkene co-monomer(s) have a maximum molar extinction coefficient at a wavelength in the range 400 to 750 nm that is less than 100 Mcm.2. The leuco polymer of claim 1 , wherein the leuco moiety is selected from the group consisting of diarylmethane leuco moieties claim 1 , triarylmethane leuco moieties claim 1 , oxazine moieties claim 1 , thiazine moieties claim 1 , hydroquinone moieties claim 1 , and arylaminophenol moieties.4. The leuco polymer of claim 1 , wherein the organic bridging group is selected from: —CON(R)— claim 1 , —CO— claim 1 , —N(R)— claim 1 , —O— claim 1 , —S— claim 1 , —SO— claim 1 , —SON(R)— claim 1 , —N(COR)— claim 1 , and —N(SOR)—; wherein Ris selected from the group consisting of H claim 1 , phenyl claim 1 , benzyl and unsubstituted or substituted C-Cbranched or linear alkyl wherein the substituent of said linear or ...

衣物洗涤护理组合物中作为上蓝剂的隐色着色剂

一种衣物洗涤护理组合物包含：(a)至少一种衣物洗涤护理成分和(b)隐色组合物。衣物洗涤护理组合物在25℃下储存30天之后，在洗涤时提供给棉的增白有益效果大于初始增白有益效果。用此类衣物洗涤护理组合物处理纺织物的方法。

Leuco colorants as bluing agents in laundry care compositions

A laundry care composition including: (a) at least one laundry care ingredient and (b) a leuco composition. The laundry care composition has a ΔHA of at least 10. Methods of treating textiles with such laundry care compositions.

Method for synthesis of acid disulfoacid ester disodium salt of leuco compound benz-1-chloro-6,7-benzo-2-thionaphthene-5-bromo-2- -indoleindigo

Изобретение относитс  к анилинокра- сочной промышленности, в частности к способу получени  динатриевой соли кислого дисернокислого эфира лейкосоединени  бенз-1-хлор-6,7-бензо-2-тионафтен-5-бром -2-индолиндиго (кубозол  серого С), примен емого дл  крашени  хлопка, шерсти, шелка . Предлагаемый способ позвол ет повысить выход целевого продукта с 64,5 до 88,0-88,3% и его крас щую концентрацию со 100 до 110% за счет того, что восстановление и этерификацию ведут при мол рном соотношении компонентов бенз-1-хлор-6,7- бензо-2-тионафтен-5-бром-2-индолиндиго, хлорсульфоновой кислоты, железного порошка , равном 1:3,43-3,63:2,96-3,13, в присутствии 5,5,7,7 -тетраброминдиго в количестве 2,0-2,5% от массы бенз-1-хлор- 6,7-бензо-2-тионафтен-5-бром-2-индолин- диго. 1 табл. The invention relates to the aniline dye industry, in particular, to a method for producing the disodium salt of the acid disulfate ester leico benzo-1-chloro-6,7-benzo-2-thioneften-5-bromo-2-indolindo (gray cubozol C), used for dyeing cotton, wool, silk. The proposed method allows to increase the yield of the target product from 64.5 to 88.0-88.3% and its dye concentration from 100 to 110% due to the fact that the reduction and esterification is carried out at the molar ratio of the components benz-1-chloro -6,7- benzo-2-thionaphthen-5-bromo-2-indolindigo, chlorosulfonic acid, iron powder, equal to 1: 3.43-3.63: 2.96-3.13, in the presence of 5.5, 7.7 -tetrabromindigo in the amount of 2.0-2.5% by weight of benz-1-chloro-6,7-benzo-2-thioneften-5-bromo-2-indoline-digo. 1 tab.

Leuco polymers as bluing agents in laundry care compositions

A leuco polymer includes a leuco monomer and an alkene. The leuco polymer has a molecular weight of at least 500 and is obtainable by polymerization of the leuco monomer and one or more alkene co-monomers. The leuco monomer consists of an alkene covalently bound to a leuco moiety and the leuco monomer has a molar extinction coefficient at a wavelength in the range 400 to 750nm of less than 1000 M -1 cm -1 . The alkene monomer(s) have a molar extinction coefficient at a wavelength in the range 400 to 750nm that is less than 100 M -1 cm -1 . Methods of making the leuco polymer, laundry care compositions comprising the leuco polymer and methods of treating textiles with such laundry care compositions.

Reactive leuco compounds and compositions comprising the same

A leuco composition comprises at least one reactive leuco compound, which reactive leuco compound comprises a leuco moiety and at least one reactive moiety covalently bound to the leuco moiety. A laundry care composition comprises a laundry care ingredient and a leuco composition. A method of treating a textile comprises the steps of (i) treating a textile with an aqueous solution containing a leuco composition, (ii) optionally, rinsing the textile, and (iii) drying the textile.

Leuco polymers as bluing agents in laundry care compositions

A laundry care composition including at least one laundry care ingredient and at least one leuco polymer including a polymeric carbohydrate and a leuco moiety. The polymeric carbohydrate and the leuco moiety are covalently bound. Methods of making the leuco polymer, laundry care compositions comprising the leuco polymer and methods of treating textiles with such laundry care compositions.

Reactive leuco compounds and compositions comprising the same

A leuco composition comprises at least one reactive leuco compound, which reactive leuco compound comprises a leuco moiety and at least one reactive moiety covalently bound to the leuco moiety. A laundry care composition comprises a laundry care ingredient and a leuco composition. A method of treating a textile comprises the steps of (i) treating a textile with an aqueous solution containing a leuco composition, (ii) optionally, rinsing the textile, and (iii) drying the textile.

Methods of using leuco colorants as bluing agents in laundry care compositions

A method for treating textile articles includes the steps of: (a) providing a laundry care composition comprising a leuco composition; (b) adding the laundry care composition to a liquid medium; (c) placing the textile articles in contact with the liquid medium; (d) depositing at least some portion of the leuco composition onto the textile articles; (e) optionally, rinsing the textile; and (f) drying the textile articles, wherein the textile articles after 1 day of storage provide a whiteness benefit to cotton that is greater than the initial whiteness benefit achieved after drying.

Leuco polymers as bluing agents in laundry care compositions

A leuco polymer comprising a polyethylenimine and at least one leuco moiety covalently bound to the polyethylenimine, wherein the polyethylenimine comprises three or more amine nitrogen atoms and 1 mol.% or more of amine hydrogen atoms in the polyethylenimine are replaced with a moiety selected from the group consisting of 2-hydroxypropyl, 1 hydroxypropane-2-yl, and polyalkoxy groups. Methods of making the leuco polymer, laundry care compositions comprising the leuco polymer and methods of treating textiles with such laundry care compositions.

Leuco colorants as bluing agents in laundry care compositions

A laundry care composition including: (a) at least one laundry care ingredient and (b) a leuco composition. The laundry care composition after 30 days of storage at 25 °C provides a whiteness benefit to cotton upon washing that is greater than the initial whiteness benefit. Methods of treating textiles with such laundry care compositions.

Process for dyeing and printing fibrous materials

Process for the preparation of salts of sulfuric leucoesters from difficult to esterify vat dyes of the anthraquinone series

Process for preparing leuco esters of vat dyes

Process for the preparation of salts of sulfuric esters of leucos derivatives of difficult to esterify anthraquinone vat dyes

Process for obtaining dry preparations of dyes

Process for preparing sulfuric leucoesters of vat dyes

Thermal marking of 3D printed objects

本发明公开了一种用于标记打印对象的方法。例如，该方法包括：经由熔丝制造(FFF)打印机打印三维(3D)对象；接收待标记在3D对象的表面上的期望的颜色标记；以及根据期望的颜色标记来控制点能量源以在3D对象的热处理层上发射能量。

Sulfuric leucoesters of vat dyes and their preparation

Process for the manufacture of nitro arylamino derivatives of leuco sulphuric acid esters of anthraquinonoid and indigoid compounds

Leuco compounds of anthraquinonoid and indigoid compounds, esters of.--N-substitution products of leuco sulphuric esters of anthraquinonoid and indigoid compounds containing amino groups are obtained by treating the esters with nitrohalogenaryls, containing labile halogen, in the presence of acid-fixing agents. In examples (1) the potassium salt of the leuco sulphuric ester of b -aminoanthraquinone is condensed with 2 : 4-dinitrochlorbenzene in presence of magnesia; the product, when treated with acid oxidizing agents on the fibre, gives fast yellow shades; (2) the sodium salt of the leuco sulphuric ester of 5-aminoindole-4<1>-chlornaphthalene-indigo (made by coupling 5-nitroisatin chloride with 4-chlornaphthol, esterifying the product as described in Specification 360,958, and reducing in an alkaline medium) is similarly condensed with 2 : 4-dinitrochlorbenzene; the product, when oxidized on the fibre, gives fast olive-green shades; (3) the leuco sulphuric ester of 2-(5-aminoindole)-2<1>-anthraceneindigo (made from 5-nitroisatin chloride and a -anthrol, by the process described in example (2)) is condensed with 4 : 4<1>-dichlor - 3 : 3<1> dinitrodiphenylsulphone; the product, when oxidized on the fibre, dyes in olive-green shades; (4) the leuco sulphuric ester obtained by condensing 5-nitro-3-oxythionaphthene with the p-dimethylaminoanil of 4 : 5-benzo-3-oxythionaphthene, and esterifying and reducing the product, is condensed with 2-nitro-1-chlorbenzene-4-sulphodimethylamide or with p 1-chlor-2-nitrobenzene-4-carboxylic dimethylamide; products giving violet-brown shades when treated with acid oxidizing agents on the fibre are obtained; and (5) the leuco sulphuric ester of 5-amino-6<1>-methoxy-bis-thionaphtheneindigo (made by the method described in example (2) from 5-nitro-3-oxythionaphthene and the p-dimethylaminoanil of 6-methoxy-3-oxythionaphthene) is condensed with 2 : 4-dinitrochlorbenzene; the product, when oxidized on the fibre, ...

Colorants manufacturing process

Process for the preparation of Kuepen dye derivatives

New water-soluble leuco-sulphuric acid ester salts of vat dyestuffs of the anthraquinone series and a process of making same

The invention comprises water-soluble leucosulphuric acid ester salts which in the form of their free acids have the formula <FORM:0961885/C4-C5/1> in which each x is hydrogen, chlorine or -NH aroyl, each y is hydrogen or chlorine, one z is -NH aroyl and both other z's are hydrogen, R is -NH2, -NH alkyl, -N (alkyl)2, -NH cyclohexyl, -NH aryl, -O alkyl, -O aryl, phenyl, piperidino or morpholino, at least 6 hydrogen atoms being bound directly to each anthracene nucleus and the alkyl radicals containing 1 to 6 carbon atoms. The dyes are made by reacting in an aqueous medium and in the presence of an acid-binding agent, one mol. of a compound of the formula <FORM:0961885/C4-C5/2> where R1 is chlorine or has one of the values of R above, and, in any sequence, one mol. of a compound of the formula <FORM:0961885/C4-C5/3> where x and y are as above and one mol. of a compound of the formula <FORM:0961885/C4-C5/4> in which the symbols z are as above, and, when a chlorine atom is present in the triazine nucleus, reacting the product with one mol. of a compound of the formula R-H, where R has one of the values given above but not phenyl. The leuco esters are used to dye and print cotton in red to yellow shades.

Improvements to coloring materials and dyeing

Improvements in and relating to the preparation of dyes

258,626. Scottish Dyes, Ltd., Thomas, J., Harris, J. E. G., and Wylam, B. March 17, 1925. Leuco compounds of vat dyes, esters of.-Leuco compounds of vat-dyes, which may contain some unreduced vat-dye, are converted into water-soluble derivatives by treating them with one of the following reagents in presence of a metal and an organic base :-chlorsulphonic acid and its salts, oleum and its salts, alkylsulphuric halides, sulphuric anhydride, phosphorus oxychloride, alkyl phosphoric halides. The addition of the metal renders unnecessary the use of a closed vessel or an inert atmosphere. Examples are given of the production of stable derivatives from the leuco compounds of the following dyestuffs :-indigo, thioindigo, indanthrone, flavanthrone, and dimethoxydibenzanthrone, the preparation of the various leuco compounds is also described. As reagents are specified chlorsulphonic acid and methylsulphuric acid chloride, and as metals zinc, tin, magnesium, and copper bronze or a mixture of the latter with zinc. The products may be used for dyeing and printing without the use of vats. Specifications 23396/99, 186,057, 202,630. 202,632, 231,889, 245,587, 247,787, 248,802, and 251,491 are referred to.

Manufacture of dyestuffs and intermediates

Sulphuric esters and salts of leuco compounds of dye intermediates of the anthraquinone series or complexes comprising such salts are made by treating the vat dye with a metal in presence of an organic quaternary ammonium halide and a hydrocarbon or substituted hydrocarbon free from acidic or basic groups, followed by treatment of the salt or complex so obtained with a sulphating agent, e.g. an addition compound of sulphur trioxide and an organic amide derived from a secondary amine. In the first step, a weakly acidic substance may be used, such as a phenol, an amide derived from ammonia or a primary amine, an organic acid or a 1,3-diketone, with or without a nitrogenous base such as cyclohexylamine, ammonia, methylamine, isopropylamine or picoline. Hydrocarbons specified are benzene, hexane, or cyclohexane, and substituted hydrocarbons specified are ethylene dichloride, acetone, benzonitrile and acetonitrile. In an example, anthraquinone is reacted with zinc dust in acetonitrile and in presence of tetraethylammonium bromide or chloride, followed by sulphation with dimethylformamide-sulphur trioxide. Specifications 274,156, [Class 2 (iii)], 610,117 and 633,513 are referred to.ALSO:Sulphuric esters and salts of leuco compounds of vat dyes of the anthraquinone series or complexes comprising such salts are made by treating the vat dye with a metal in presence of an organic quaternary ammonium halide and a hydrocarbon or substituted hydrocarbon free from acidic or basic groups, followed by treatment of the salt or complex so obtained with a sulphating agent, e.g. an addition compound of sulphur trioxide and an organic amide derived from a secondary amine. In the first step, a weakly acidic substance may be used, such as a phenol, an amide derived from ammonia or a primary amine, an organic acid or a 1,3-diketone, with or without a nitrogenous base such as cyclohexylamine, ammonia, methylamine, isopropylamine or a -picoline. In examples, the following are reacted in ...

Improvements in and relating to dyes and dyeing

251,491. Morton, J., Jones, J. I. M., Wylam, B., Harris, J. E. G., and Morton Sundour Fabrics, Ltd. Nov. 1, 1924. Leuco compounds of vat-dyes, esters of.-Vat dyestuffs are converted into soluble derivatives by treating in the presence of a metal and a tertiary base with chlorsulphonic acid or its salts, fuming sulphuric acid, sulphuric anhydride, or salts of pyrosulphuric acid; the dyestuff, metal, and base may be heated together prior to the addition of the chlorsulphonic acid etc.; the reaction is in some cases facilitated by an addition of an acid or a salt. The products may be isolated by filtration after addition of a little water; the solid residue may be further dissolved in dilute alkali and reprecipitated by addition of salt. The following parent materials are specified:-as tertiary bases, pyridine, quinoline, dimethylaniline, or a homologue or substitution product thereof; as metals, copper, zinc, and magnesium; as acids or acid salts, stannous chloride; as vat dyestuffs, flavanthrone, indanthrone, dibenzanthrone, dichlor-isodibenzanthrone, dimethoxy-dibenzanthrone, anthraquinone-1(NH)-2(CO)-naphthacridone, indigo, and dichlor- or dibrom-indigo. Specifications 186,057, 202,630, and 202,632 are referred to.

Method of preparing sulfuric acid half esters of leuco anthraquinones in mildly alkaline aqueous medium

Process for the preparation of a leuco-sulfuric acid ester of the isodibenzanthrone series

Preparation of sulfuric esters of leuco vat dyes

Leuco polymers as bluing agents in laundry care compositions

A leuco polymer includes a leuco monomer and an alkene. The leuco polymer has a molecular weight of at least 500 and is obtainable by polymerization of the leuco monomer and one or more alkene co-monomers. The leuco monomer consists of an alkene covalently bound to a leuco moiety and the leuco monomer has a molar extinction coefficient at a wavelength in the range 400 to 750nm of less than 1000 M -1 cm -1 . The alkene monomer(s) have a molar extinction coefficient at a wavelength in the range 400 to 750nm that is less than 100 M -1 cm -1 . Methods of making the leuco polymer, laundry care compositions comprising the leuco polymer and methods of treating textiles with such laundry care compositions.

Process of preparing vat-dyestuff derivatives from vat dyestuffs and alkyl esters of monochloracetic acid

leuco reactive compounds and compositions comprising the same

a presente invenção refere-se à composição leuco compreende pelo menos um composto leuco reativo, cujo composto leuco reativo compreende uma porção leuco e pelo menos uma porção reativa covalentemente ligada a uma porção leuco. uma composição de cuidado de lavanderia compreende um ingrediente de cuidado de lavanderia e uma composição leuco. um método de tratamento de um têxtil que compreende as etapas de (i) tratar um têxtil com uma solução aquosa contendo uma composição leuco, (ii) opcionalmente, enxaguar o têxtil, e (iii) secar o têxtil. The present invention relates to the leukoic composition comprising at least one reactive leukoic compound, whose reactive leukoic compound comprises a leuko portion and at least one reactive moiety covalently linked to a leuko portion. A laundry care composition comprises a laundry care ingredient and a leuco composition. A method of treating a textile comprising the steps of (i) treating a textile with an aqueous solution containing a leuco composition, (ii) optionally rinsing the textile, and (iii) drying the textile.

Aerosol-generating article comprising thermal indicator

FIELD: aerosol generating products.SUBSTANCE: aerosol-generating article (2) containing: combustible carbon-containing heat source (4); aerosol-forming substrate (10); and a heat indicator provided on the outer surface of the aerosol-generating article downstream of the combustible carbon-containing heat source. Thermal indicator comprises at least one reversible thermochromatic material which performs the first reversible visible colour change with rise of the temperature indicator temperature to the first change temperature and the second reversible visible colour change as the temperature indicator temperature drops to the second variation temperature. First change temperature is less than approximately 80 °C, and second variation temperature is less than or equal to first change temperature.EFFECT: disclosed is an aerosol-generating article having a thermal indicator.15 cl, 2 dwg РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 722 123 C2 (51) МПК A24D 1/02 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК A24D 1/02 (2020.02) (21)(22) Заявка: 2018127845, 29.12.2016 (24) Дата начала отсчета срока действия патента: (73) Патентообладатель(и): ФИЛИП МОРРИС ПРОДАКТС С.А. (CH) Дата регистрации: 26.05.2020 Приоритет(ы): (30) Конвенционный приоритет: 31.12.2015 EP 15203266.0 (43) Дата публикации заявки: 04.02.2020 Бюл. № 4 (45) Опубликовано: 26.05.2020 Бюл. № 15 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 31.07.2018 2 7 2 2 1 2 3 (56) Список документов, цитированных в отчете о поиске: US 2015201670 A1, 23.07.2015. WO 2014045024 A2, 27.03.2014. EP 2798968 A1, 05.11.2014. EP 409566 A1, 23.01.1991. R U 29.12.2016 (72) Автор(ы): ЛАВАНЧИ Фредерик (CH) EP 2016/082836 (29.12.2016) C 2 C 2 (86) Заявка PCT: (87) Публикация заявки PCT: R U 2 7 2 2 1 2 3 WO 2017/114895 (06.07.2017) Адрес для переписки: 129090, Москва, ул. Б. Спасская, 25, стр. 3, ООО "Юридическая фирма Городисский и Партнеры" (54) ИЗДЕЛИЕ, ...

Process for the manufacture of sulphuric acid ester salts of leuco vat dyestuffs of the anthraquinone series

Leuco-vat dyes difficult to esterify, as defined in the parent Specification, are treated in a mixture of 2-methyl-5-ethyl-pyridine with diethyl-cyclohexylamine and/or at least one diethyl-(monomethyl-cyclohexyl)-amine, the proportion of said amine or amines amounting to 10-60 per cent by weight of the mixture thereof with 2-methyl-5-ethyl-pyridine, in presence of finely divided copper, brass, iron, cobalt, or nickel, with chlorsulphonic acid in the form of its addition products with said bases. The minimum proportions correspond to those of the parent Specification. In examples 1.5- and 1.4-dibenzoylaminoanthraquinone, carbazo - lized di-(51benzoylamino-1-anthraquinonyl)-2, 8-diaminochrysene and the anthrimide from 1, 3-dichloro-2-methyl-anthraquinone and 1, 4-monobenzoyl-diamino-anthraquinone are each converted to their leuco sulphuric esters. Specifications 745,365 and 745,368 also are referred to.

New vat dyes and processes for their manufacture

The invention comprises vat dyes containing at least 5 or at the most 6 condensed rings fused together, at least one stable sulphonic acid group and at least one carboxylic acid amide group. The term "vat dyes" is defined as including dyes that can be converted by reduction into a leuco form, which has better affinity for natural or regenerated cellulose fibres than the unreduced dye and which can be reconverted into the original chromophore system by oxidation. The dyes may be prepared by reacting a suitable vat dye, i.e. one containing at least 5 or at the most 6 condensed rings fused together and (a) at least one carboxylic acid amide group with a sulphonating agent so as to introduce at least one SO3H group or (b) at least one carboxylic acid amide group and at least one sulphonic acid halide group with a mild hydrolysing agent, or (c) at least one acylatable amino group with an acylating agent which, if the dye does not contain a sulphonic acid group, contains a sulphonic acid group or a derivative thereof which is converted into a sulphonic acid group under the reaction conditions, or (d) at least one carboxylic acid amide group and at least one mercapto group with an oxidizing agent. In examples, the preparation of vat dyes containing di-(acylamino-anthraquinonylamino) - anthanthrone, anthraquinone - benzacridone and dibenzpyrene-quinone residues is specified. Specified acylating agents include diphenyl - 4 - carboxylic acid chloride, thiophene - 2 - carboxylic acid 4 - sulphochloride, terephthaloyl and isophthaloyl chlorides, oxalyl chloride, succinyl chloride, naphthalene-2,6-dicarboxylic acid chloride, 4,41-diphenyl- or -diphenylsulphone- or -diphenylmethane- or -diphenylamine - dicarboxylic acid chloride, azobenzene - 2,21 - dicarboxylic acid chloride, pyridine-2,6-dicarboxylic acid chloride, benzoic acid-m-sulphochloride and 2-mercaptobenzthiazole-6-carboxylic acid chloride. Many alternative reactants are specified in examples. Specification 891, ...

Authraquinone dyes free from acid groups which solubilize them in water and process for preparing them

Novel anthraquinone dyes and process for their preparation

Leuco colorants as bluing agents in laundry care compositions

A laundry care composition including: (a) at least one laundry care ingredient and (b) a leuco composition. The laundry care composition after 30 days of storage at 25° C. provides a whiteness benefit to cotton upon washing that is greater than the initial whiteness benefit. Methods of treating textiles with such laundry care compositions.

Manufacture of sulphuric acid esters suitable for use in dyeing and printing textilefibres

The process described in the parent Specification, whereby 1 : 2 : 2<1> : 1<1>-dianthraquinoneazine is reduced and esterified with the aid of an addition product of a tertiary base and sulphur trioxide, in presence of an excess of tertiary base and in presence of a metal, with complete exclusion of free acid, is applied to a halogen derivative of a 1 : 2 : 2<1> : 1<1>-dianthraquinoneazine. Polyesters (apparently mixtures of tri-and tetra-esters) are obtained, which are suitable for printing purposes on account of their good solubility and small sensitivity to overoxidation. In an example, dichloro-1 : 2 : 2<1> : 1<1>-dianthraquinoneazine (cf. German Specification 229,166) is treated with pyridine-sulphur trioxide, pyridine and copper power in an atmosphere of nitrogen and at 70 DEG C. ; caustic potash is added and the solution on concentrating precipitates a tri-ester ; the filtrate yields on evaporation a freely-soluble product which appears to be a tetra-ester. By adding caustic soda solution instead of caustic potash, warming, filtering and evaporating, a paste of the sodium salts of these two esters is obtained, which is suitable for printing purposes. In a similar manner a mixture of the polyesters of a trichloro derivative of 1 : 2 : 2<1> : 1<1>-dianthraquinoneazine is obtained. Specifications 247,787, 251,491, and 261,139, [all in Class 2 (iii), Dyes &c.], also are referred to.

Tinting hydrogel materials with vat dyes

Aerosol including heat indicator generates product

一种气溶胶生成制品(2)包括：可燃含碳热源(4)；气溶胶形成基质(10)；以及热指示器，其在所述可燃含碳热源的下游设置于所述气溶胶生成制品的外表面上。所述热指示器包括至少一种可逆热变色材料，所述至少一种可逆热变色材料在所述热指示器的温度上升到第一切换温度时经受第一可逆可见颜色变化，且在所述热指示器的所述温度下降到第二切换温度时经受第二可逆可见颜色变化。所述第一切换温度低于约80℃，且所述第二切换温度小于或等于所述第一切换温度。

System and method for autogenerating simulations for process control system checkout and operator training

A method and system for automatically generating simulations for a distributed control system is disclosed herein. A programmed process model generator automatically incorporates a variety of process model data from pre-defined model libraries into descriptions of process equipment including control devices to render simulation models of various degrees of fidelity.

Improvements to intermediate coloring materials

System and method for autogenerating simulations for process control system checkout and operator training

A method and system for automatically generating simulations for a distributed control system is disclosed herein. A programmed process model generator automatically incorporates a variety of process model data from pre-defined model libraries into descriptions of process equipment including control devices to render simulation models of various degrees of fidelity.

Esters of leucoacylamino-anthrapyrimidines

Process for the preparation of salts of sulfuric esters of leucos derivatives of difficult to esterify anthraquinone vat dyes

Improvements to dyeing processes and dye products

Procrypsis colorant is as blueing agent for the method in laundry care composition

本发明提供一种用于处理纺织制品的方法，该方法包括以下步骤：(a)提供包含隐色组合物的衣物洗涤护理组合物；(b)将衣物洗涤护理组合物添加至液体介质；(c)将纺织制品放置成与液体介质接触；(d)使隐色组合物的至少一些部分沉积到纺织制品上；(e)任选地，漂洗纺织物；以及(f)干燥纺织制品，其中纺织制品在储存1天之后提供给棉的增白有益效果大于干燥之后实现的初始增白有益效果。

Camouflage pattern with extended infrared reflectance separation

Fabrics containing camouflage patterns are produced from dyes wherein at least certain of the colors contained in the pattern contain a low reflectance dye. The low reflectance dye is added to one or more colors in the pattern in order to preserve the camouflage pattern when viewed through night vision goggles as relatively long wavelengths, such at wavelengths greater than 900 nm. In one embodiment, the low reflectance dye comprises a thiazine. The low reflectance dye is blended with other dyes to produce colors in the pattern. By altering the concentration of the low reflectance dye in each of the colors, the colors contained in the camouflage pattern remain separate and distinct even at relatively long wavelengths.

Polymorph of a yellow diarylide pigment

The present invention provides a novel polymorphic form of Colour Index Pigment Yellow 12 in a crystalline form which exhibits an X-ray diffraction pattern having three prominent X-ray diffraction lines corresponding to "d" spacings of 11.82, 7.71 and 3.32 x 10 -10 metres.

Process for the production of leuco-sulfuric acid esters of the anthraquinone and indigo series which can be linked

Light sensitive substances and materials and their preparation process

Thermochromic compositions from trisubstituted pyridine leuco dyes.

Una composición de leucotinte termocrómica contiene una porción de leucotinte que incluye una o más piridinas tri-sustituidas con arilo, una porción reveladora de UVA que incluye por lo menos un revelador de UVA seleccionado del grupo que consiste de ácido salicílico y derivados del mismo, y bifenilos y derivados de los mismos, y un portador seleccionado del grupo que consiste de un éster graso, alcohol graso, amida grasa y combinaciones de los mismos.

Microcapsule having core-shell structure, and production method for same

Proposed are a microcapsule having a core-shell structure that has high-temperature durability and solvent resistance and is environment-friendly. The microcapsule includes a core portion containing a hydrophobic active component and a shell portion surrounding the core portion and containing a silane crosslinkable polyurethane-based resin derived from a crosslinkable alkoxy silane group-terminated prepolymer.

Preparation of sulfuric acid half esters of leuco vat dyes

Camouflage pattern with extended infrared reflectance separation

Fabrics containing camouflage patterns are produced from dyes wherein at least certain of the colors contained in the pattern contain a low reflectance dye. The low reflectance dye is added to one or more colors in the pattern in order to preserve the camouflage pattern when viewed through night vision goggles as relatively long wavelengths, such at wavelengths greater than 900 nm. In one embodiment, the low reflectance dye comprises a thiazine. The low reflectance dye is blended with other dyes to produce colors in the pattern. By altering the concentration of the low reflectance dye in each of the colors, the colors contained in the camouflage pattern remain separate and distinct even at relatively long wavelengths.

Leuco colorants as bluing agents in laundry care compositions

A laundry care composition including: (a) at least one laundry care ingredient and (b) a leuco composition. The laundry care composition after 30 days of storage at 25 °C provides a whiteness benefit to cotton upon washing that is greater than the initial whiteness benefit. Methods of treating textiles with such laundry care compositions.

Process for the preparation of the tetrasulfuric acid ester of 3, 3'-ditrifluoromethyl-1, 2, 2 ', 1'-anthrahydroquinonazine

Aerosol-generating articles, including thermal indicators

에어로졸 발생 물품(2)은 가연성 탄소질 열원(4); 에어로졸 형성 기재(10); 및 가연성 탄소질 열원의 하류에서 에어로졸 발생 물품의 외부 표면에 제공되는 열 표시기를 포함한다. 열 표시기는 열 표시기의 온도가 제1 스위칭 온도로 상승할 때 제1 가역 가시적 색 변화 및 열 표시기의 온도가 제2 스위칭 온도로 떨어질 때 제2 가역 가시적 색 변화를 겪는 적어도 하나의 가역 열 변색 물질을 포함한다. 제1 스위칭 온도는 약 80℃ 미만이며 제2 스위칭 온도는 제1 스위칭 온도보다 더 낮거나 같다.

New water-soluble leuco-sulphuric acid ester salts of vat dyestuffs and the anthraquinone series and a process of making same

The invention comprises water-soluble leucosulphuric acid ester salts which contain a single anthraquinone nucleus and have, in the form of the free acid, the formula <FORM:0961884/C4-C5/1> where each x is hydrogen or chlorine or -NH aroyl, each y is hydrogen or chlorine, R1 is -NH2, -NH alkyl, -N (alkyl)2, -NH cyclohexyl, -NH aryl, -O alkyl, -O aryl, piperidino or morpholino and where at least 6 hydrogen atoms are attached to the anthracene nucleus and wherein the alkyl groups contain 1 to 6 carbon atoms. The dyes are made by reacting, in an aqueous medium and in the presence of an acid-binding agent, 1 mol. of a compound of the formula <FORM:0961884/C4-C5/2> where R3 is chlorine or has one of the values of R1 above and R4 is chlorine or has one of the values of R2 above, with 1 mol. of a compound of the formula <FORM:0961884/C4-C5/3> where x and y are as above, and when one or two chlorine atoms are present in the triazine ring, the product is reacted with one or two mols. respectively of a compound of the formula H-R1. The leuco-sulphuric esters are used to dye and print cotton in red and yellow shades.

PROCESS FOR THE PREPARATION OF A HYDROGENATED INDANOL DERIVATIVE AND PROCEDURE FOR THE PREPARATION OF A FRAGRANCE MIXTURE.

Leuco colorants as bluing agents in laundry care compositions

A laundry care composition including: (a) at least one laundry care ingredient and (b) a leuco composition. The laundry care composition has a ?HA of at least 10. Methods of treating textiles with such laundry care compositions.

Process for the preparation of sulfuric acid ethers of leuco bonds of indigoid tank dyes containing nitro groups

Acid sulphuric acid esters of leuco derivatives of vat dyestuffs

Leuco colorant as bluing agent in laundry care composition

【課題】所望の白色度によって得られる消費者利益を提供するだけでなく、様々な色及び形態を選択できる柔軟性を有する洗濯ケア組成物を提供する。【解決手段】（ａ）少なくとも１つの洗濯ケア成分と、（ｂ）ロイコ着色剤と、を含む洗濯ケア組成物。洗濯ケア組成物は、少なくとも１０のΔＨＡを有する。このような洗濯ケア組成物で布地を処理する方法も提供する。【選択図】なし

Pigment

본 발명은 11.82,7.71 및 3.32×10 -10 m의 “d” 간격에 상응하는 3개의 주요 X-선 회절선을 갖는 X-선 회절도를 나타내는 결정 형태의 색지수 안료 옐로우 12의 신규 다형체를 제공한다.

Process for the production of vat dyes

Aerosol-generating article comprising a thermal indicator and method of use thereof

一种气溶胶生成制品(2)包括：可燃含碳热源(4)；气溶胶形成基质(10)；以及热指示器，其在所述可燃含碳热源的下游设置于所述气溶胶生成制品的外表面上。所述热指示器包括至少一种可逆热变色材料，所述至少一种可逆热变色材料在所述热指示器的温度上升到第一切换温度时经受第一可逆可见颜色变化，且在所述热指示器的所述温度下降到第二切换温度时经受第二可逆可见颜色变化。所述第一切换温度低于约80℃，且所述第二切换温度小于或等于所述第一切换温度。

Process for obtaining leuco-derivatives of oxygen-acylated vat dyes

A process for the manufacture and production of new compounds from vat dyestuffs

331,842. Johnson, J. Y., (I. G. Farbenindustric Akt.-Ges.). March 9, 1929. Leuco compounds of vat dyes, derivatives of.- Aryl ethers of the leuco compounds of vat dyes are obtained by heating the leuco compounds, or the vat dyes themselves in presence of reducing agents such as metals, with alkali phenolates preferably in an inert solvent or excess of the phenol. The products may also be obtained from intermediate compounds which are convertible into hydro-compounds of the vat dyes under the conditions employed. The products may be employed as intermediates for dyestuffs, for the purification of dyestuffs, and in part for dyeing directly. According to examples, (1) pyranthrone is heated with excess of phenol, zinc dust, or other finely-divided metals such as copper or iron, or with trichlorbenzene as diluent instead of excess of phenol, to give a phenyl ether; the same product may be obtained by using 2: 2<1>- dimethyt-1 : 1<1>-dianthraquinonyl instead of pyranthrones; (2) pyranthrone is reduced with sodium carbonate and hydrosulphite, then heated with potassium hydroxide and phenol to give the monophenylether of dihydropyranthrone. which dyes vegetable fibre cherry red shades which are converted into green-brown shades on exposure to air and by treatment with acid oxidizing agents into the shade of pyranthrone; (3) flavanthrone heated with phenol, sodium carbonate, and zinc dust, gives a product which forms a blue hydrochloride; and (4) the diphenyl ethers of indigo, dibenzanthrone, Bz2: Bz2<1>-dimethoxydibenzanthrone, prepared in a similar manner, are described.

New Indan connections

Pigment

Process for the preparation of sulfuric leucoesters from vat dyes

Process for the preparation of salts of sulfuric esters of leuco-derivatives of anthraquinone azo dyes

Process for the production of vat dyes

Sulfuric leucoesters of vat dyes and their preparation

Process for the preparation of salts of sulfuric esters of leucos derivatives of difficult to esterify anthraquinone vat dyes

System And Method For Autogenerating Simulations For Process Control System Checkout And Operator Training

A method and system for automatically generating simulations for a distributed control system is disclosed herein. A programmed process model generator automatically incorporates a variety of process model data from pre-defined model libraries into descriptions of process equipment including control devices to render simulation models of various degrees of fidelity.

Patent FR2058364A1

Patent BE494152A

DYING HYDROGEL MATERIALS WITH COLORS OF CUBA.

SE DESCRIBEN PROCEDIMIENTOS DE TEÑIDO DE MATERIALES DE HIDROGEL, P.EJ. LENTES DE CONTACTO, MEDIANTE DISOLUCION DE UN ESTER DE LEUCO SULFATO DE UN TINTE DE CUBA EN UNA SOLUCION DE MONOMERO COMPATIBLE, ADICION DE UN INICIADOR DE OXIDACION A DICHA SOLUCION DE MONOMERO, Y OXIDACION Y POLIMERIZACION DE LA SOLUCION MONOMERICA Y DEL TINTE EN LA MISMA SOLUCION. EN UNA REALIZACION DE LA INVENCION, LA OXIDACION Y POLIMERIZACION SE LLEVAN A CABO SIMULTANEAMENTE, MIENTRAS QUE EN OTRA REALIZACION, LA OXIDACION DEL ESTER DE LEUCO SULFATO DEL TINTE DE CUBA AL TINTE DE CUBA INSOLUBLE Y LA POLIMERIZACION, SE LLEVAN A CABO SECUENCIALMENTE EN EL MISMO MEDIO DE REACCION. PROCEDURES FOR DYING MATERIALS OF HIDROGEL, P.EJ. CONTACT LENSES, BY DISSOLUTION OF A LEUCO ESTER SULFATE OF A CUBA DYE IN A COMPATIBLE MONOMERO SOLUTION, ADDITION OF AN OXIDATION INITIATOR TO SUCH MONOMERO SOLUTION, AND OXIDATION AND POLYMERIZATION OF THE MONOMERIC SOLUTION AND THE MOMMAIS SOLUTION SOLUTION. IN AN EMBODIMENT OF THE INVENTION, OXIDATION AND POLYMERIZATION ARE CARRIED OUT SIMULTANEOUSLY, WHILE IN ANOTHER EMBODIMENT, OXIDATION OF THE ESTER OF LEUCO SULPHATE OF CUBA TO DYE OF INSOLUBLE CUBA AND POLYMERIZATION, ARE CARRIED OUT SAME MEANS OF REACTION.

Improvements in the preparation of tetrasulfuric leucoesters of indanthrone

Process for bonding to oilcloth or other similar articles, labels, etc.

Actuated electrode lead in minimally invasive cochlear implant surgery

An implantable electrode arrangement for a cochlear implant system is described. An electrode lead contains a lead structure control element configured to control a lead shape of the electrode lead between an insertion state wherein the electrode lead within a mastoid tunnel has a longitudinal lead axis lying entirely along the tunnel axis, and a post-insertion state wherein a facial recess portion of the electrode lead fitting within a limited diameter portion of the mastoid tunnel associated with a facial recess portion of the mastoid bone has a longitudinal lead axis along the tunnel axis, and a storage portion of the electrode lead fitting within an enlarged diameter portion of the mastoid tunnel lateral to the facial recess portion has a longitudinal lead axis coiled in a helical shape radially around the tunnel axis.

Method and composition for coloring a keratinous substrate using solubilized vat dyes

The disclosure relates to methods for coloring keratinous substrates using solubilized vat dyes, as well as compositions and kits suitable for carrying out the methods. The disclosure also relates to novel solubilized vat dyes.