12-04-2012 дата публикации
Номер: US20120086761A1
This disclosure is generally directed to curable phase change inks, such as radiation-curable phase change inks, and their use in forming images, such as through inkjet printing. More specifically, this disclosure is directed to radiation-curable phase change inks, such as ultraviolet-light-curable phase change inks, that an ink vehicle and at least one crystalline polyester resin. 1. A curable phase change ink composition , the ink composition comprising an ink vehicle and at least one crystalline polyester resin.2. The curable phase change ink composition of claim 1 , wherein the at least one crystalline polyester resin has a weight average molecular weight (M) of from about 10 claim 1 ,000 Dalton (Da) to about 60 claim 1 ,000 Da claim 1 , a number average molecular weight (M) of from about 5 claim 1 ,000 Da to about 12 claim 1 ,000 Da and a polydispersity of from about 2.0 to about 5.0.3. The curable phase change ink composition of claim 1 , wherein the at least one crystalline polyester resin has a weight average molecular weight (M) of from about 20 claim 1 ,000 Da to about 22 claim 1 ,000 Da claim 1 , a number average molecular weight (M) of from about 9 claim 1 ,000 Da to about 11 claim 1 ,000 Da and a polydispersity of from about 2.0 to about 2.2.4. The curable phase change ink composition of claim 1 , wherein the at least one crystalline polyester is formed by reacting at least one organic diol with at least one organic diacid claim 1 ,{'sup': '2,6', 'the organic diol being selected from the group consisting of ethylene glycol, propylene glycol, tetrafluoro-1,4-butanediol, diethylene glycol, 2,2-dimethyl-1,3-propanediol, cyclohexanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, triethylene glycol, dimer diol, 1,7-heptanediol, benzenedimethanol, cyclohexanedimethanol, 2,2-dibutyl-1,3-propanediol, 2,8-bis(hydroxymethyl) tricycle [5.2.1.0]decane, 1,16-hexadecanediol and 2-phenyl-1,3-propanediol, and'}the organic diacid being selected from the group ...
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