23-05-2013 дата публикации
Номер: US20130131292A1
Disclosed is a catalyst for the polymerization of olefins comprising thienyl-substituted silanes, which comprises a solid titanium catalyst component containing titanium, magnesium and a halogen as the main components, an alkylaluminum compound, and a component of organosiloxane compound comprising two thienyl as substituents represented by general formula (I). The molar ratio of each catalyst component is 1:50-150:5-50 based on titanium:aluminum:silicon. When the catalyst is used in the polymerization of propylene, the polymerisate obtained has very high degree of isotacticity, and the yield is high. 2. The olefin polymerization catalyst comprising thienyl-substituted silane according to claim 1 , wherein in General Formula (I) representing the organosiloxane compound comprising two thienyl substituents claim 1 , Rto Rare the same or different claim 1 , and are selected from hydrogen claim 1 , methyl claim 1 , ethyl claim 1 , propyl or isopropyl.3. The olefin polymerization catalyst comprising thienyl-substituted silane according to claim 1 , wherein in General Formula (I) representing the organosiloxane compound comprising two thienyl substituents claim 1 , Rand Rare the same or different claim 1 , and are methyl or ethyl.4. The olefin polymerization catalyst comprising thienyl-substituted silane according to claim 1 , wherein the organosiloxane compound comprising two thienyl substituents is synthesized as follows: with protection of an inert gas claim 1 , magnesium powder claim 1 , halogenated thiophene and a tetrahydrofuran solvent are mixed and refluxed claim 1 , followed by addition of an iodine initiator until the reaction gets severe; after the reaction is stable claim 1 , a mixed solution containing halogenated thiophene claim 1 , tetrahydrofuran and tetraalkoxysilane is added slowly claim 1 , heated claim 1 , stirred and refluxed for a period of time claim 1 , then cooled slowly to room temperature claim 1 , filtered claim 1 , washed claim 1 , and ...
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