MULTI-LAYERED LIGHT DIFFUSION PLATE AND LIQUID CRYSTAL DISPLAY DEVICE COMPRISING THE SAME

Disclosed herein is a multi-layered light diffusion plate, in which the multi-layered light diffusion plate is manufactured by coextruding a transparent layer comprising an amorphous transparent thermoplastic resin and a light diffusion layer comprising an amorphous transparent thermoplastic resin and transparent particles, so that the manufacturing process thereof is simple and efficient, and which has excellent light transmissivity and light diffusivity, high brightness, and high brightness uniformity, thereby improving viewing angle characteristics, and to a liquid crystal display device comprising the same. 1. A multi-layered light diffusion plate comprising a coextruded transparent layer , and a light diffusion layer , wherein the transparent layer comprises an amorphous transparent thermoplastic resin and the light diffusion layer comprises an amorphous transparent thermoplastic resin and transparent particles.2. The multi-layered light diffusion plate of claim 1 , wherein the amorphous transparent thermoplastic resin is selected from the group consisting of polyalkyl(meth)acrylate claim 1 , an alkyl(meth)acrylate-styrene copolymer claim 1 , polycarbonate claim 1 , polyvinylchloride claim 1 , a styrene-acrylonitrile copolymer claim 1 , a styrene-maleic anhydride copolymer claim 1 , a styrene-maleic anhydride derivative copolymer claim 1 , a cycloolefin copolymer claim 1 , polyacrylonitrile claim 1 , polystyrene claim 1 , polysulfone claim 1 , polyethersulfone claim 1 , polyarylate and a mixture thereof.3. The multi-layered light diffusion plate of claim 2 , wherein the amorphous transparent thermoplastic resin is selected from the group consisting of polymethyl(meth)acrylate claim 2 , a methyl(meth)acrylate-styrene copolymer claim 2 , polycarbonate claim 2 , polystyrene and a mixture thereof.4. The multi-layered light diffusion plate of claim 1 , wherein the transparent particles are inorganic particles claim 1 , organic particles or a mixture thereof.5. The ...

Multi-layered light diffusion plate and liquid crystal display device comprising the same

Disclosed herein is a multi-layered light diffusion plate, in which the multi-layered light diffusion plate is manufactured by coextruding a transparent layer comprising an amorphous transparent thermoplastic resin and a light diffusion layer comprising an amorphous transparent thermoplastic resin and transparent particles, so that the manufacturing process thereof is simple and efficient, and which has excellent light transmissivity and light diffusivity, high brightness, and high brightness uniformity, thereby improving viewing angle characteristics, and to a liquid crystal display device comprising the same.

Multi-Layered Light Diffusion Plate and Liquid Crystal Display Device Comprising the Same

Disclosed herein is a multi-layerd light diffusion plate, in which the multi-layered light diffusion plate is manufactured by coextruding a transparent layer comprising an amorphous transparent thermoplastic resin and a light diffusion layer comprising an amorphous transparent thermoplastic resin and transparent particles, so that the manufacturing process thereof is simple and efficient, and which has excellent light transmissivity and light diffusivity, high brightness, and high brightness uniformity, thereby improving viewing angle characteristics, and to a liquid crystal display device comprising the same.

Thermoplastic resin composition and molded article

The present invention relates to a thermoplastic resin composition and a molded article manufactured thereofrom. In accordance with the present invention, a thermoplastic resin composition providing higher chemical resistance with respect to a blowing agent while providing the same impact strength, gloss, and vacuum moldability as existing resin compositions when used to produce an inner case of a refrigerator, and a molded article manufactured from the same are provided.

THERMOPLASTIC RESIN COMPOSITION

The present invention provides a thermoplastic resin and a molded article using the same, wherein the thermoplastic resin comprises: (A) 10 parts by weight to less than 30 parts by weight of a butadiene-based graft copolymer; (B) 5 parts by weight or more to less than 30 parts by weight of an acrylate-based graft copolymer; (C) 35 parts by weight to 65 parts by weight of a vinyl cyanide-aromatic vinyl-based copolymer; (D) 1 part by weight to 10 parts by weight of an ethylene-alkyl acrylate-based copolymer elastomer based on the total 100 parts by weight of (A), (B), and (C); and (E) 1 part by weight to 10 parts by weight of a polyester-based elastomer. 1. A resin composition comprising:(A) 10 parts by weight to less than 30 parts by weight of a butadiene-based graft copolymer including 30 wt % to 70 wt % of a butadiene-based rubber polymer core, and 30 wt % to wt % of a graft shell having a vinyl cyanide monomer-derived unit and an aromatic vinyl monomer-derived unit;(B) 5 parts by weight or more to less than 30 parts by weight of an acrylate-based graft copolymer including 30 wt % to 70 wt % of an acrylate-based rubber polymer core, and 30 wt % to 70 wt % of a graft shell having a vinyl cyanide monomer-derived unit and an aromatic vinyl monomer-derived unit;(C) 35 parts by weight to 65 parts by weight of a vinyl cyanide-aromatic vinyl-based copolymer;(D) 1 part by weight to 10 parts by weight of an ethylene-alkyl acrylate-based copolymer elastomer based on the total 100 parts by weight of (A), (B), and (C); and(E) 1 part by weight to 10 parts by weight of a polyester-based elastomer.2. The resin composition of claim 1 , wherein the ethylene-alkyl acrylate-based copolymer elastomer comprises one or more selected from the group consisting of an ethylene methylacrylate copolymer claim 1 , an ethylene ethylacrylate copolymer claim 1 , and an ethylene butylacrylate copolymer.3. The resin composition of claim 1 , wherein the resin composition comprises the polyester- ...

THERMOPLASTIC RESIN COMPOSITION

The present invention provides a thermoplastic resin composition which includes: a first copolymer including a core including a conjugated diene-based polymer and a shell including an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; and a second copolymer including an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit, wherein the first copolymer has a degree of grafting of 32 to 50%, the second copolymer has a weight-average molecular weight of 85,000 to 115,000 g/mol, and the thermoplastic resin composition includes the first copolymer at 30 wt % or less and an oligomer residue at 1.1 wt % or less. Specifically, the thermoplastic resin composition can shorten an injection molding time. 1. A thermoplastic resin composition comprising:a first copolymer including a conjugated diene-based polymer, an aromatic vinyl-based monomer unit, and a vinyl cyan-based monomer unit; anda second copolymer including an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit,wherein the first copolymer has a degree of grafting of 32 to 50%,the second copolymer has a weight-average molecular weight of 85,000 to 115,000 g/mol, andthe thermoplastic resin composition includes the first copolymer at 30 wt % or less and an oligomer residue at 1.1 wt % or less.2. The thermoplastic resin composition of claim 1 , wherein the second copolymer is 90 claim 1 ,000 g/mol to 115 claim 1 ,000 g/mol.3. The thermoplastic resin composition of claim 1 , which includes an oligomer residue at 1 wt % or less.4. The thermoplastic resin composition of claim 1 , which has a melt flow index of 30 g/10 min or more claim 1 , as measured at 220° C. and 10 kg.5. The thermoplastic resin composition of claim 1 , which has a melt flow index of 30 to 50 g/10 min claim 1 , as measured at 220° C. and 10 kg.6. The thermoplastic resin composition of claim 1 , wherein the first copolymer has a degree of grafting of 35 to 45%.7. The thermoplastic resin composition of ...

Thermoplastic resin composition, method of preparing thermoplastic resin composition, and metal-plated molded article manufactured using thermoplastic resin composition

A thermoplastic resin composition includes 100 parts by weight of a base resin including 5 to 40% by weight of a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound graft copolymer (a) containing conjugated diene rubber having a particle diameter of 0.05 μm to 0.2 μm, 5 to 40% by weight of a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound graft copolymer (b) containing conjugated diene rubber having a particle diameter of greater than 0.2 μm and less than or equal to 0.5 μm, and 50 to 80% by weight of an aromatic vinyl compound-vinyl cyanide compound copolymer (c); and more than 0.01 parts by weight and less than 2 parts by weight of a compound having a kinematic viscosity (25° C.) greater than 5 cSt and less than 200 cSt. The resin composition has excellent plating characteristics.

THERMOPLASTIC RESIN COMPOSITION, METHOD OF PREPARING THE SAME, AND MOLDED ARTICLE INCLUDING THE SAME

Disclosed is a thermoplastic resin composition, a method of preparing the same, and a molded article including the same, including a thermoplastic resin composition including 100 parts by weight of a base resin including 20 to 90% by weight of a non-recycled thermoplastic resin (A) and 10 to 80% by weight of a recycled thermoplastic resin (B); 1 to 10 parts by weight of an ethylene compound-vinyl acetate compound copolymer (C); and 0.01 to 10 parts by weight of an inorganic pigment (D), wherein the inorganic pigment (D) has a refractive index of 1.65 or more and an average particle diameter of 10 to 500 nm. 1. A thermoplastic resin composition , comprising:100 parts by weight of a base resin comprising 20 to 90% by weight of a non-recycled thermoplastic resin (A) and 10 to 80% by weight of a recycled thermoplastic resin (B);1 to 10 parts by weight of an ethylene compound-vinyl acetate compound copolymer (C); and0.01 to 10 parts by weight of an inorganic pigment (D),wherein the inorganic pigment (D) has a refractive index of 1.65 or more and an average particle diameter of 10 to 500 nm.2. The thermoplastic resin composition according to claim 1 , wherein {'br': None, 'sub': n+5', 'n, 'Melt index retention rate (%)=[MI/MI]×100,\u2003\u2003[Equation 1]'}, 'the thermoplastic resin composition has a melt index retention rate of 80% or more as calculated by Equation 1 below{'sub': n', 'n+5, 'wherein MIis a melt index value (g/10 min) as measured at 220° C. under a load of 10 kg according to ASTM D1238 after extruding the thermoplastic resin composition n times at 200 to 250° C. and 250 to 400 rpm, and MIis a melt index value (g/10 min) as measured after repeatedly performing extrusion n+5 times under the same conditions, wherein n is an integer from 1 to 10.'}3. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has an impact strength retention rate of 80% or more as calculated by Equation 2 below:{'br': None, 'sub': n+5 ...

Thermoplastic resin composition

The present invention provides a thermoplastic resin and a molded article using the same, wherein the thermoplastic resin comprises: (A) 10 parts by weight to less than 30 parts by weight of a butadiene-based graft copolymer; (B) 5 parts by weight or more to less than 30 parts by weight of an acrylate-based graft copolymer; (C) 35 parts by weight to 65 parts by weight of a vinyl cyanide-aromatic vinyl-based copolymer; (D) 1 part by weight to 10 parts by weight of an ethylene-alkyl acrylate-based copolymer elastomer based on the total 100 parts by weight of (A), (B), and (C); and (E) 1 part by weight to 10 parts by weight of a polyester-based elastomer.

Thermoplastic resin composition, method for manufacturing same, and molded article comprising same

The present invention relates to a thermoplastic resin composition, a method of preparing the same, and a molded article including the same. More specifically, the present invention provides a thermoplastic resin composition including a base resin including a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound graft copolymer, an alkyl acrylate rubber-vinyl cyanide compound-aromatic vinyl compound graft copolymer, and an aromatic vinyl compound-vinyl cyanide compound copolymer and a polysiloxane in a predetermined composition ratio, wherein the alkyl acrylate rubber-vinyl cyanide compound-aromatic vinyl compound graft copolymer has a grafting degree of 42 % or more and is included in an amount of 0.1 to 10 % by weight based on 100 % by weight in total of the base resin.In addition to excellent colorability, the thermoplastic resin composition of the present invention exhibits low clutch force and has excellent clutch force retention due to excellent dimensional stability against thermal aging.

Thermoplastic resin composition

Thermoplastic resin composition

Multi-layered light diffusion plate and liquid crystal display device comprising the same

Disclosed herein is a multi-layered light diffusion plate, in which the multi-layered light diffusion plate is manufactured by coextruding a transparent layer comprising an amorphous transparent thermoplastic resin and a light diffusion layer comprising an amorphous transparent thermoplastic resin and transparent particles, so that the manufacturing process thereof is simple and efficient, and which has excellent light transmissivity and light diffusivity, high brightness, and high brightness uniformity, thereby improving viewing angle characteristics, and to a liquid crystal display device comprising the same.

Method for preparing recycled abs resin

Provided is a method for preparing a recycled ABS resin, and the method for preparing a recycled ABS resin includes: preparing an extrusion feed including an acrylonitrile butadiene styrene (ABS) base resin including polyurethane, a metal carboxylic acid salt, and a polyhydric alcohol; and supplying the extrusion feed to an extruder to perform a depolymerization reaction of the polyurethane and extruding the extrusion feed.

熱可塑性樹脂組成物、その製造方法及びそれを含む成形品

【課題】熱可塑性樹脂本来の機能が良好に発現されると共に、初期抗菌性と抗菌持続性が優れた熱可塑性樹脂の開発が至急な実情である。【解決手段】本発明は、熱可塑性樹脂組成物、その製造方法及びそれを含む成形品に関し、より詳細には、Ａ）ビニルシアン化合物－共役ジエン化合物－芳香族ビニル化合物グラフト共重合体（Ａ－１）及び芳香族ビニル化合物－ビニルシアン化合物共重合体（Ａ－２）を含むベース樹脂１００重量部と；Ｂ）重量平均分子量５００，０００ｇ／ｍｏｌ超の非共有電子対を含む重合体０．１～３２重量部と；Ｃ）リン酸ガラス、シリカゲル、リン酸カルシウム及びリン酸ジルコニウムナトリウムからなる群から選択された１種以上の担持体を含む無機抗菌剤０．１～５重量部と；Ｄ）ＢＥＴ表面積２８ｍ２／ｇ以上の酸化亜鉛０．２～１０重量部とを含む熱可塑性樹脂組成物、その製造方法及びそれを含む成形品に関する。【選択図】なし

Thermoplastic resin composition

Thermoplastic resin composition, method for manufacturing same, and molded article comprising same

Thermoplastic resin composition

The present disclosure relates to a thermoplastic resin composition including: a diene-based graft polymer; an acrylic graft polymer; a vinyl-based polymer including a vinyl aromatic monomer unit and a vinyl cyanide-based monomer unit; a polyamide elastomer; an olefin-based polymer including a vinyl acetate monomer unit; an inorganic antibacterial agent including a metal ion supported on a glass carrier; and a zinc oxide having a BET specific surface area of 11 to 28 m 2 /g.

Thermoplastic resin composition, method for manufacturing same, and metal-plated molded product manufactured from same

The present invention relates to a thermoplastic resin composition, a method of preparing the thermoplastic resin composition, and a metal-plated molded article manufactured using the thermoplastic resin composition. More specifically, the thermoplastic resin composition of the present invention includes 100 parts by weight of a base resin including 5 to 40 % by weight of a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound graft copolymer (a) containing conjugated diene rubber having a particle diameter of 0.05 µm to 0.2 µm, 5 to 40 % by weight of a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound graft copolymer (b) containing conjugated diene rubber having a particle diameter of greater than 0.2 µm and less than or equal to 0.5 µm, and 50 to 80 % by weight of an aromatic vinyl compound-vinyl cyanide compound copolymer (c); and more than 0.01 parts by weight and less than 2 parts by weight of the compound represented by Formula 1 having a kinematic viscosity (25 °C) greater than 5 cSt and less than 200 cSt. According to the present invention, when the thermoplastic resin composition of the present invention is plated, non-plating may be prevented even under conditions, such as reduced etching time, that promote the occurrence of a non-plating phenomenon. In addition, the thermoplastic resin composition of the present invention has mechanical properties equal or superior to those of conventional resins and excellent thermal properties and plating adhesion. Accordingly, after the thermoplastic resin composition is plated, the thermoplastic resin composition has an excellent appearance.

Thermoplastic resin composition, preparation method therefor, and molded product comprising same

Thermoplastic resin composition

Thermoplastic resin composition

The present invention provides a thermoplastic resin composition which includes: a first copolymer including a core including a conjugated diene-based polymer and a shell including an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; and a second copolymer including an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit, wherein the first copolymer has a degree of grafting of 32 to 50%, the second copolymer has a weight-average molecular weight of 85,000 to 115,000 g/mol, and the thermoplastic resin composition includes the first copolymer at 30 wt % or less and an oligomer residue at 1.1 wt % or less. Specifically, the thermoplastic resin composition can shorten an injection molding time.

Thermoplastic resin composition