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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 3984. Отображено 100.
26-01-2012 дата публикации

Flame-retardant poly lactic acid-containing film or sheet, and method for manufacturing thereof

Номер: US20120021202A1
Автор: Hiroki Senda, Shigeki Ishiguro
Принадлежит: Nitto Denko Corp

Provided is a film or sheet composed of a resin composition that includes a poly lactic acid (A), an acidic functional group-modified olefinic polymer (B) including an acidic functional group and having an acid value of 10 to 70 mg KOH/g and a weight average molecular weight of 10,000 to 80,000, a tetrafluoroethylene polymer (C), and an aromatic cyclic phosphazene-containing flame retardant (D) including a compound of General Formula (I) and in which the aromatic cyclic phosphazene-containing flame retardant (D) is included in an amount of 10 to 70 parts by weight based on 100 parts by weight of the poly lactic acid (A), and a method for manufacturing the film or sheet by melt film formation. Each sign in Formula is as described in the specification.

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Номер записи: 1
16-02-2012 дата публикации

Resin composition and resin molded article

Номер: US20120041114A1
Автор: Masahiro Moriyama, Masaya Ikuno
Принадлежит: Fuji Xerox Co Ltd

A resin composition includes a polylactic acid, a monocarbodiimide compound and a phosphazene.

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Номер записи: 2
14-06-2012 дата публикации

Dual cure adhesive formulations

Номер: US20120145312A1
Автор: Mark W. Pressley
Принадлежит: Lord Corp

An adhesive composition comprising as principal components, a polymerizable component, an ambient temperature radical polymerization catalyst system and a photoinitiator. The adhesive may optionally comprise an adhesion promoter, a toughener, an epoxy, and a filler material. Further, a two-part reactive adhesive comprising, a first part comprising, (i) at least one free radical-polymerizable monomer, (ii) at least one reducing agent, and (iii) a photoinitiator, and a second part comprising an oxidizing agent that is reactive at ambient temperature with the reducing agent to produce free radicals that are capable of initiating and propagating free radical polymerization.

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Номер записи: 3
05-07-2012 дата публикации

Flame retardant system

Номер: US20120172467A1
Автор: Christoph Fleckenstein, Ciesielski Michael, Geert Janssens, Hartmut Denecke, Ingo Bellin, Jochen Wagner, Klaus Hahn, Klemens Massonne, Manfred DÖRING, Maximilian Hofmann, Patrick Spies, Peter Deglmann, Rainer Ostermann, Sabine Fuchs
Принадлежит: BASF SE

The invention relates to a flame retardant comprising a) at least one sulfur compound of the formula (I) b) at least one halogen-free organophosphorus compound with phosphorus content in the range from 0.5 to 40% by weight, based on the phosphorus compound.

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Номер записи: 4
04-10-2012 дата публикации

Derivatives of diphosphines as flame retardants in aromatic and/or heteroaromatic epoxy resins

Номер: US20120251810A1
Автор: Alexander Tishkov, Christoph Fleckenstein, Hartmut Denecke, Heinz Herbst, Matthias Maase, Norbert Gutfrucht, Rainer Xalter
Принадлежит: BASF SE

The present invention is related to the use of specific derivatives of diphosphines as flame retardants in aromatic and heteroaromatic epoxy resins and to a method for reducing the flammability of organic material comprising aromatic and/or heteroaromatic epoxy resins in which the specific derivates of diphosphines are incorporated. Moreover, the invention is related to an aromatic and/or heteroaromatic epoxy resin composition containing aromatic and heteroaromatic epoxy resin as such or in processed form and incorporated in the aromatic and/or heteroaromatic epoxy resin at least one of the derivatives of diphosphines in an amount of from 1 to 35% by weight, based on the weight of the aromatic and/or heteroaromatic epoxy resin.

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Номер записи: 5
15-11-2012 дата публикации

Flame-retardant thermoplastic molding composition

Номер: US20120289634A1
Автор: Alexander König
Принадлежит: BASF SE

The invention relates to a thermoplastic molding composition comprising a) from 30 to 95% by weight of at least one aliphatic polyamide or copolyamide, as component A, b) from 1 to 15% by weight of at least one cyclic phenoxyphosphazene having at least 3 phenoxyphosphazene units, as component B, c) from 3 to 20% by weight of at least one (di)phosphinate salt, as component C, d) from 1 to 15% by weight of at least one reaction product of melamine with a phosphorus acid, as component D, e) from 0 to 5% by weight of at least one metal borate, as component E, f) from 0 to 20% by weight of at least one impact-modifying polymer, as component F, g) from 0 to 50% by weight of glass fibers, as component G, and h) from 0 to 30% by weight of further additives, as component H, where the total amount of components A to H gives 100% by weight.

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Номер записи: 6
22-11-2012 дата публикации

Photocurable resin composition and light-emitting element sealant

Номер: US20120296000A1
Автор: Kiyohiko Atami, Naoyuki Oomori, Toshihiko Kurata
Принадлежит: Bridgestone Corp

Provided are a photocurable resin composition which has a short time required for curing to make it possible to enhance the productivity and which can provide a light-emitting element sealant having an excellent heat resistance and an excellent optical transparency and a light-emitting element sealant prepared by using the above photocurable resin composition. To be specific, provided are a photocurable resin composition comprising 100 parts by mass of an end-modified hydrogenated styrene-butadiene rubber (A) and 0.1 to 13 parts by mass of an α-hydroxyalkylphenone base photopolymerization initiator and/or an acylphosphine oxide base photopolymerization initiator and a light-emitting element sealant prepared by using the above photocurable resin composition (B).

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Номер записи: 7
29-11-2012 дата публикации

Phosphorous flame retardant and application thereof to polymer

Номер: US20120302669A1
Автор: Jiang-Jen Lin, Yi-Lin Liao, Yu-Min Chen
Принадлежит: National Taiwan University NTU

A phosphorous flame retardant primarily includes hexachlorotriphosphazene (HCP) having poly(oxyalkylene)amine substitutes. The poly(oxyalkylene)amine includes at least two end groups. The phosphorous flame retardant can further include layered silicate clay. The layered silicate clay can be intercalated and modified with the poly(oxyalkylene)amine substitutes of HCP to effectively promote thermal stability. The flame retardant, phosphazene-poly(oxyalkylene)amine adducts, can be applied to a polymer. By the cross-linking between them, the flame-retarding property of the polymer can be improved. Also provided is a method for producing the flame retardant of phosphazene-poly(oxyalkylene)amine adducts and application thereof to a polymer.

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Номер записи: 8
25-04-2013 дата публикации

Curable polysiloxane coating composition

Номер: US20130101840A1
Автор: George G.I. Moore, Kanta Kumar, Larry D. Boardman, Michael A. Semonick, Michele A. Craton, Yu Yang
Принадлежит: 3M Innovative Properties Co

A curable composition comprises (a) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydroxysilyl moieties; (b) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydrosilyl moieties; and (c) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; wherein at least one of the components (a) and (b) has an average reactive silane functionality of at least three.

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Номер записи: 9
16-05-2013 дата публикации

FLAME RETARDANT POLYAMIDE COMPOSITIONS

Номер: US20130123402A1
Автор: FREITAG Dieter, GO Pin, JEONG Youmi, KAGUMBA Lawino
Принадлежит: FRX POLYMERS, INC.

Predominately amino terminated phosphonamide oligomers and their use as flame retardant additives in polyamides and copolyamides without detracting from melt processability are described herein. Other important properties such as strength, modulus, dyeing and thermal stability are maintained. 1. A polymer composition comprising at least one phosphonamide oligomer having amino end groups and one or more polyamides , copolyamides or combinations thereof.3. The composition of claim 1 , wherein at least 50% of available end groups of the phosphonamide oligomer are amine groups.4. The composition of claim 1 , wherein the phosphonamide oligomer comprises a molecular weight of about 200 g/mole to about 10 claim 1 ,000 g/mole using polystyrene standards.5. The composition of claim 1 , wherein the composition comprises about 2 wt. % to about 50 wt % phosphonamide oligomer.6. The composition of claim 1 , wherein the one or more polyamides claim 1 , copolyamides or combinations thereof are selected from the group consisting of polyhexamethylene adipamide claim 1 , polyhexamethylene sebacamide claim 1 , polycaprolactam claim 1 , and copolyamide 6/66 claim 1 , nylon-4 claim 1 , nylon-6 claim 1 , nylon-6 claim 1 ,6 claim 1 , nylon-6 claim 1 ,10 claim 1 , nylon-6 claim 1 ,9 claim 1 , nylon-6 claim 1 ,12 claim 1 , nylon-4 claim 1 ,6 claim 1 , nylon-12 claim 1 ,12 claim 1 , nylon-11 claim 1 , nylon-12 claim 1 , aromatic polyamides based on m-xylene claim 1 , diamine and adipic acid; polyamides prepared from hexamethylenediamine and terephthalic acid and/or isoterephthalic acid.7. The composition of claim 1 , further comprising one or more elastomers.8. The composition of claim 7 , wherein the one or more elastomers are selected from the group consisting of poly-2 claim 7 ,4 claim 7 ,4-trimethylhexamethylene-terephthalamide or poly-m-phenyleneisophthalamide.9. The composition of claim 1 , wherein the one or more polyamides claim 1 , copolyamides or combinations thereof comprise block ...

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Номер записи: 10
30-05-2013 дата публикации

PHOSPHINIC ACID HYDRAZIDE FLAME RETARDANT COMPOSITIONS

Номер: US20130137800A1
Автор: Kniesel Simon, Xalter Rainer
Принадлежит: BASF SE

The invention relates to flame retardant compositions, wherein a phosphinic acid hydrazide is present in a polymer substrate. The combination with >NOR-compounds improves the flame retardant properties. 4. A composition according to claim 1 , which comprises as Component a) a compound (I) claim 1 , wherein{'sub': 1', '2', '1', '20', '6', '20', '1', '12', '6', '20', '6', '20', '1', '4, 'Both Rand Rindependently of one another represent substituents selected from the group consisting of C-Calkyl, C-Caryl, C-Calkyl-C-Caryl and C-Caryl-C-Calkyl; and'}R represents hydrogen or a group of the partial formula (A),{'sub': 1', '2', '1', '2, 'Wherein R′ and R′ are defined as Rand R,'}or a salt thereof.5. A composition according to claim 1 , which comprises as Component a) a compound (I) claim 1 , wherein{'sub': 1', '2', '1', '8, 'Both Rand Rindependently of one another represent substituents selected from the group consisting of C-Calkyl and phenyl; and'}R represents hydrogen or a group of the partial formula (A),{'sub': 1', '2', '1', '2, 'Wherein R′ and R′ are defined as Rand R,'}or a salt thereof.6. A composition according to claim 1 , which comprises{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a) A compound (I) according to , wherein'}{'sub': 1', '2', '1', '8, 'Both Rand Rindependently of one another represent substituents selected from the group consisting of C-Calkyl and phenyl; and'}R represents hydrogen or a group of the partial formula (A), wherein{'sub': 1', '2', '1', '2, 'R′ and R′ are defined as Rand R,'}or a salt thereof; andb) A thermoplastic polymer substrate.7. A composition according to claim 1 , which further comprises an additional flame retardant or an additive selected from the group consisting of polymer stabilizers claim 1 , tetraalkylpiperidine derivatives and tetraalkylpiperazine derivatives.8. A composition according to claim 1 , which comprises as an additional flame retardant a nitrogen containing compound selected from the group consisting of ...

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Номер записи: 11
25-07-2013 дата публикации

Polyolefin Compositions for Film, Fiber and Molded Articles

Номер: US20130190434A1
Автор: Zahalka Hayder
Принадлежит: CHEMTURA CORPORATION

Polyolefin compositions prepared by processing a polyolefin resin and a mixture of a select hindered phenol and select liquid phosphite above the melting point of the polyolefin contain a higher amount of retained active phosphorus than when other common phosphites are used. The compositions, and films, fibers and other molded articles prepared from the compositions show improved stabilization against NOX discoloration and long term oxidation. The select liquid phosphite consists mainly of a mixture of triphenyl phosphite derivatives wherein the phenyl groups are substituted by different numbers of butyl and/or amyl substituents. 3. A film or fiber prepared from a composition according to .4. The composition according to wherein said liquid phosphite comprises a mixture consisting of:from 0 to 20 weight percent based on the total weight of phosphite of tris(di-t-amylphenyl)phosphite;from 20 to 70 weight percent based on the total weight of the phosphite of tris(mono-t-amylphenyl)phosphite;from 2 to 20 weight percent based on the total weight of the phosphite of bis(di-t-amylphenyl)mono-t-amylphenyl phosphite; andfrom 15 to 60 weight percent based on the total weight of the phosphite of a bis(mono-t-amylphenyl)di-t-amylphenyl phosphite,which mixture which is liquid at 25° C. makes up at least 90% by weight of all phosphites present in the composition.5. The composition according to wherein said liquid phosphite comprises a mixture consisting of:from 0 to 3 weight percent based on the total weight of phosphite of tris(di-t-butylphenyl)phosphite;from 35 to 75 weight percent based on the total weight of the phosphite of tris(mono-t-butylphenyl)phosphite;from 5 to 15 weight percent based on the total weight of the phosphite of bis(di-t-butylphenyl)monobutylphenyl phosphite; andfrom 21 to 47 weight percent based on the total weight of the phosphite of bis(mono-t-butylphenyl)dibutylphenyl phosphite,which mixture which is liquid at 25° C. makes up at least 90% by weight of ...

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Номер записи: 12
15-08-2013 дата публикации

Flame-Retardant Polyester Compounds

Номер: US20130210968A1
Автор: Hoerold Sebastian, Nass Bernd, Schlosser Elke, Wanzke Wolfgang
Принадлежит: CLARIANT FINANCE (BVI) LIMITED

The invention relates to flame-retardant polyester compounds comprising as component A 40% to 89.9% by weight of thermoplastic polyesters, as component B 5% to 25% by weight of phosphinic salt of the formula (V) and/or diphosphinic salt of the formula (VI) and/or polymers thereof, in which Rand Rare H or C-C-alkyl and/or aryl; Ris C-C-alkylene, C-C-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; and x is 1 to 4, and as component C 5% to 25% by weight of a phosphazene, as component D 0% to 15% by weight of reaction products of melamine with phosphoric acid and/or condensed phosphoric acids, as component E 0% to 45% by weight of reinforcing agents, and as component F 0.1% to 3% by weight of further additives, the sum of the components by weight being 100% by weight. 2. The flame-retardant compounded polyester material as claimed in claim 1 , wherein Rand Rare identical or different and are methyl claim 1 , ethyl claim 1 , n-propyl claim 1 , isopropyl claim 1 , n-butyl claim 1 , tert-butyl claim 1 , n-pentyl claim 1 , phenyl or a mixture thereof.3. The flame-retardant compounded polyester material as claimed in claim 1 , wherein Ris methylene claim 1 , ethylene claim 1 , n-propylene claim 1 , isopropylene claim 1 , n-butylene claim 1 , tert-butylene claim 1 , n-pentylene claim 1 , n-octylene claim 1 , or n-dodecylene; phenylene claim 1 , or naphthylene; methylphenylene claim 1 , ethylphenylene claim 1 , tert-butylphenylene claim 1 , methylnaphthylene claim 1 , ethylnaphthylene claim 1 , ec tert-butylnaphthylene; phenylmethylene claim 1 , phenylethylene claim 1 , phenylpropylene or phenylbutylene.4. The flame-retardant compounded polyester material as claimed in claim 1 , comprising from 40 to 74.9% by weight of component A claim 1 , from 5 to 25% by weight of component B claim 1 , from 5 to 15% by weight of component C claim 1 , from 0 to 10% by ...

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Номер записи: 13
29-08-2013 дата публикации

THERMOPLASTIC POLYCARBONATE COPOLYMER COMPOSITIONS, METHODS OF THEIR MANUFACTURE, AND ARTICLES THEREOF

Номер: US20130224461A1
Автор: Assink Roland Sebastian, Sybert Paul Dean, van de Grampel Robert Dirk, van der Mee Mark Adrianus Johannes
Принадлежит: SABIC INNOVATIVE PLASTICS IP B.V.

A thermoplastic composition includes a poly(carbonate-arylate ester); and an organophosphorus compound in an amount effective to provide 0.1 to 1.0 wt % phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after four minutes (Ds-4) of less than or equal to 300 determined according to ISO 5659-2 on a 3 mm thick plaque and a maximum average rate of heat release emission (MAHRE) of less than or equal to 90 kW/mdetermined according to ISO 5660-1 on a 3 mm thick plaque. 1. A thermoplastic composition comprisinga poly(carbonate-arylate ester); andan organophosphorus compound in an amount effective to provide 0.1 to 1.0 wt % of phosphorus, based on the total weight of the composition; [{'sup': '2', 'a maximum average heat release (MAHRE) of less than or equal to 90 kW/mdetermined according to ISO 5660-1 on a 3 mm thick plaque, and'}, 'a smoke density after 4 minutes (Ds-4) of less than or equal to 300 determined according to ISO 5659-2 on a 3 mm thick plaque., 'wherein an article molded from the composition has'}2. The composition of claim 1 , wherein an article molded from the composition has{'sup': '2', 'a maximum average heat release (MAHRE) of less than or equal to 60 kW/mdetermined according to ISO 5660-1 on a 3 mm thick plaque; and'}a smoke density after 4 minutes (Ds-4) of less than or equal to 150 determined according to ISO 5659-2 on a 3 mm thick plaque.3. The composition of claim 1 , wherein the poly(carbonate-arylate ester) is a poly(carbonate-bisphenol arylate ester) claim 1 , a poly(carbonate-monoaryl arylate ester) claim 1 , a poly(carbonate-monoaryl arylate ester) comprising siloxane units claim 1 , or a combination comprising at least one of the foregoing.5. The composition of claim 4 , wherein{'sup': a', 'b, 'sub': '1-3', 'Rand Rare each independently a Calkyl,'}p and q are each independently 0 or 1, and{'sup': a', 'c', 'd', 'c', 'd, 'sub': '1-6', 'Xis alkylidene of formula —C(R)(R)— ...

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Номер записи: 14
28-11-2013 дата публикации

FLAME RETARDANT POLYCARBONATE COMPOSITIONS, METHODS OF MANUFACTURE THEREOF AND ARTICLES COMPRISING THE SAME

Номер: US20130317144A1
Автор: LI Ying, Lin Yegang, Wu Tong
Принадлежит:

Disclosed herein is a flame retardant composition comprising 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a laser activatable additive; the laser activatable additive being operative to plate the flame retardant composition upon being activated by a laser; and 1 to 20 weight percent of a phosphazene compound; where all weight percents are based on the total weight of the flame retardant composition. Disclosed herein too is a method comprising blending 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a laser activatable additive; the laser activatable additive being operative to plate the flame retardant composition upon being activated by a laser; and 1 to 20 weight percent of a phosphazene compound to produce a flame retardant composition; where all weight percents are based on the total weight of the flame retardant composition; and extruding the flame retardant composition. 1. A flame retardant composition comprising:20 to 80 weight percent of a polycarbonate composition;1 to 20 weight percent of a laser activatable additive; the laser activatable additive being operative to plate the flame retardant composition upon being activated by a laser; and1 to 20 weight percent of a phosphazene compound; where all weight percents are based on the total weight of the flame retardant composition.2. The flame retardant composition of claim 1 , further comprising a mineral filler in an amount of 1 to 10 weight percent based on the total weight of the flame retardant composition.3. The flame retardant composition of claim 1 , comprising 1 to 5 weight percent of the phosphazene compound.4. The flame retardant composition of claim 1 , where the polycarbonate composition comprises a polycarbonate having a weight average molecular weight of 15 claim 1 ,000 to 40 claim 1 ,000 Daltons.5. The flame retardant composition of claim 1 , where the polycarbonate composition comprises a copolyestercarbonate.6. The flame retardant composition of ...

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Номер записи: 15
05-12-2013 дата публикации

INTEGRATED MOLDED PRODUCT

Номер: US20130324649A1
Автор: Doi Kumiko, Sakata Kouichi
Принадлежит: Win Tech Polymer Ltd.

Provided is an integrated molded product in which a molded resin product containing a phosphorus compound is used and an addition-reactive silicone adhesive agent is used to achieve strong bonding. The integrated molded product comprises a thermoplastic resin molded product made of a thermoplastic resin composition comprising a polybutylene terephthalate resin and a phosphorus compound, the content of the phosphorus compound being 0.5% by mass or less; an addition-reactive silicone composition; and a member; and the thermoplastic resin molded product and the addition-reactive silicone composition are brought into contact with each other. The phosphorus compound to be used is preferably a trivalent phosphorous compound. 105. An integrated molded product comprising a thermoplastic resin molded product made of a thermoplastic resin composition comprising a polybutylene terephthalate resin and a phosphorus compound , the content of the phosphorus compound being .% by mass or less;an addition-reactive silicone composition; anda member;wherein the thermoplastic resin molded product and the addition-reactive silicone-based composition are brought into contact with each other.2. The integrated molded product according to claim 1 , wherein the phosphorus compound is a trivalent phosphorus compound.3. The integrated molded product according to claim 2 , wherein the trivalent phosphorus compound is a phosphonite-based compound and/or a phosphite-based compound.4. The integrated molded product according to any one of to claim 2 , wherein the content of the polybutylene terephthalate resin in the thermoplastic resin composition is 40% by mass or more. A resin molded product obtained by molding a thermoplastic resin is used for various products and parts since it has features such as easy molding and light-weight. Among thermoplastic resins, a polybutylene terephthalate resin has particularly excellent mechanical strength, electrical properties, and physical and chemical ...

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Номер записи: 16
23-01-2014 дата публикации

METHOD FOR DEFOAMING A VINYL CHLORIDE RESIN SLURRY

Номер: US20140024755A1
Автор: KIM Kun Ji, KIM Yong Jin
Принадлежит: LG CHEM, LTD.

Disclosed is a method for defoaming a vinyl chloride resin slurry. The agent of the present invention may prevent generation of Fish eyes and deteriorate in production efficiency caused by slurry foams without inhibiting inherent transparency of vinyl chloride resins, in the process of preparing the vinyl chloride resins by polymerizing a monomer mixture containing vinyl chloride as a main component in a polymerization reactor. 2. The method for defoaming a vinyl chloride resin slurry according to claim 1 , wherein claim 1 , in Formula 1 claim 1 , the number of carbon atoms in the alkyl group is an integer of 4 to 18.3. The method for defoaming a vinyl chloride resin slurry according to claim 1 , a is an integer of 1 to 15.4. The method for defoaming a vinyl chloride resin slurry according to claim 1 , b is an integer of 10 to 100.5. The method for defoaming a vinyl chloride resin slurry according to claim 1 , the number of carbon atoms in the alkyl group is an integer of 4 to 18.6. The method for defoaming a vinyl chloride resin slurry according to wherein the compound of Formula 1 and the compound of Formula 2 are mixed at a weight ratio of 9:1 to 3:7.7. The method for defoaming a vinyl chloride resin slurry according to further comprising a polyvinyl acetate compound having a partial saponification degree of 90% or less.8. The method for defoaming a vinyl chloride resin slurry according to wherein the partially saponified polyvinyl acetate compound has a partial saponification degree of 30% to 90%.9. The method for defoaming a vinyl chloride resin slurry according to wherein the partially saponified polyvinyl acetate compound has a weight average molecular weight (Mw) of 7 claim 1 ,000 to 20 claim 1 ,000.10. The method for defoaming a vinyl chloride resin slurry according to claim 7 , wherein a weight ratio of the at least one compound selected from the compound of Formula 1 and the compound of Formula 2 claim 7 , and the partially saponified polyvinyl acetate ...

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Номер записи: 17
27-02-2014 дата публикации

PHOSPHOROUS-CONTAINING FLAME RETARDANTS FOR POLYURETHANE FOAMS

Номер: US20140058035A1
Автор: Qi Yudong, Tai Xiangyang
Принадлежит: Dow Global Technologies LLC

Embodiments of the invention include a phosphorus containing flame retardant which may be the reaction product of a reaction mixture where the reaction mixture includes at least one active hydrogen-containing compound and at least one phosphorus containing compound. The at least one active hydrogen-containing compound is selected from the group of a first polyol having a hydroxyl functionality of at least 3, a polyamine having an amine functionality of at least 2, and an amino alcohol having a combined amine and hydroxyl functionality of at least 2. The at least one phosphorus containing compound has the general formula (1), (2) or combination thereof: 3. The phosphorus containing flame retardant of claim 1 , wherein R is at least one of propylene claim 1 , 2-methylpropylene claim 1 , neopentylene claim 1 , and 2-butyl-2-ethylpropylene.4. The phosphonate flame retardant of claim 1 , wherein X is selected from the group consisting of Cl claim 1 , Br claim 1 , and I claim 1 , and sulfonate.5. The phosphorus containing flame retardant of claim 1 , wherein the phosphorus containing compound is 2-Chloro-5 claim 1 ,5-dimethyl-1 claim 1 ,3 claim 1 ,2-dioxaphosphinane claim 1 , 2-chloro-5 claim 1 ,5-dimethyl-1 claim 1 ,3 claim 1 ,2-dioxaphosphinane 2-oxide claim 1 , diethyl phosphorochloridite claim 1 , or diethyl phosphorochloridate.6. The phosphorus containing flame retardant of claim 1 , wherein the at least one first polyol comprises at least one of polyoxalkylene polyol having an equivalent weight about 60-2500.7. The phosphorus containing flame retardant of claim 6 , wherein the at least one polyoxalkylene polyol is initiated with glycerol claim 6 , sucrose claim 6 , sorbitol claim 6 , or a combination thereof claim 6 , and the polyoxalkylene comprises at least one of polyoxyethylene and polyoxypropylene.8. The phosphorus containing flame retardant of claim 1 , wherein the first polyol comprises a sorbitol initiated polyoxypropylene polyol with an equivalent weight of ...

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Номер записи: 18
04-01-2018 дата публикации

Phosphazene compound containing ester group, preparation method and use thereof

Номер: US20180002360A1
Автор: Qingchong PAN
Принадлежит: Guangdong Guangshan New Material Co Ltd

The present invention relates to a phosphazene compound containing an ester group having a structure of formula (I). The present invention grafts ester groups to phosphazene compounds and makes terminal grafted hydroxyl and carboxyl groups reacted with polymer matrix, producing an improvement of flame retardancy and a reduction of dielectric constant at the same time when the phosphazene compound is introduced into polymer matrix. Since N and P atoms are directly bonded into the polymer matrix by a reaction rather than addition and combination means in the prior art, there is no reduced mechanical properties of the matrix due to the addition of flame retardants.

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Номер записи: 19
04-01-2018 дата публикации

MODIFIED POLYMER COMPOSITION AND STABILIZER MIXTURE FOR MAKING THE SAME

Номер: US20180002511A1
Автор: Chen Chen-Kai, Lee Kun-Chang, Wang Jen-Fu
Принадлежит:

Disclosed herein is a stabilizer mixture for modifying an olefin-based polymer, which comprises at least one organic phosphorus-containing antioxidant represented by a formula selected from the group consisting of formulae (1), (2), (3), (4), (5), (6), (7), and (8), as well as at least one sulfur-containing carboxylate salt represented by a formula selected from the group consisting of formulae (9), (10), (11), and (12). Also disclosed herein is a modified polymer composition prepared from an olefin-based polymer using the stabilizer mixture. The olefin-based polymer is selected from the group consisting of polyolefin, ethylene-vinyl acetate copolymer, and a combination thereof. 2. The stabilizer mixture according to claim 1 , wherein:{'sup': '91', 'Rrepresents hydrogen, and'}{'sup': '92', 'sub': 1', '18', '6', '18, 'Ris selected from the group consisting of a C-Calkyl group and a C-Caryl group.'}3. The stabilizer mixture according to claim 2 , wherein{'sup': '92', 'Ris dodecyl.'}4. The stabilizer mixture according to claim 1 , further comprising an antioxidant that is selected from the group consisting of a hindered phenolic antioxidant claim 1 , a benzofuranone-based antioxidant claim 1 , an amine oxide-based antioxidant claim 1 , and combinations thereof.5. The stabilizer mixture according to claim 4 , wherein the hindered phenolic antioxidant is selected from the group consisting of pentaerythritol-tetra-[β-(3 claim 4 ,5-di-tert-butyl-4-hydroxyphenyl)-propionate] claim 4 , ethylenebis(oxyethylene)bis[β-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionate] claim 4 , 1 claim 4 ,3 claim 4 ,5-trimethyl-2 claim 4 ,4 claim 4 ,6-tris(3 claim 4 ,5-di-tert-butyl-4-hydroxybenzyl)benzene claim 4 , 1 claim 4 ,3 claim 4 ,5-tris(3 claim 4 ,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate claim 4 , tris(butylcresol)butane claim 4 , 4 claim 4 ,4′-butylidenebis(6-tert-butyl-3-methylphenol) claim 4 , N claim 4 ,N′-bis[3-(3 claim 4 ,5-di-tert-butyl-4-hydroxyphenyl)propionyl]hydrazide ...

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Номер записи: 20
04-01-2018 дата публикации

Flame retardant treating agent for kapok-fiber or kapok-nonwoven fabric

Номер: US20180002548A1
Автор: Da Som YANG, Oh Deok KWON, Won Jin Seo, Won Suk CHAE
Принадлежит: Hyundai Motor Co

Provided herein is a flame retardant agent that is useful for treating kapok-fiber or kapok-nonwoven fabric. Kapok-fiber or kapok-nonwoven fabric when treated with the flame retardant agent is capable of reducing the impact of fire and providing flame retardancy. The flame retardant treated kapok-fiber or kapok-nonwoven fabric has desired properties including acid resistance, light resistance, absence of stickiness, and absence of a glaucous appearance. Thus, the flame retardant treating agent is suitable for use with materials used in vehicles, clothes, bedclothes, and the like.

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Номер записи: 21
02-01-2020 дата публикации

PHOTOCURABLE COATING COMPOSITION AND APPLICATION THEREOF

Номер: US20200002545A1
Автор: LIN CHIAO-YANG, WANG HUNG-YU, YANG KUN-FU, YEN TE-SHENG
Принадлежит: ETERNAL MATERIALS CO., LTD.

The present disclosure provides a photocurable coating composition, including: (a) a (meth)acrylate monomer or oligomer with at least four functional groups; (b) a difunctional (meth)acrylate monomer, (c) a monofunctional (meth)acrylate monomer, and (d) an initiator. The difunctional (meth)acrylate monomer is present in an amount of 30 to 70 wt % based on the total weight of the photocurable coating composition. The present disclosure also provides an optical film having a microstructure layer made from the photocurable coating composition. The optical film can be as a light guide film in a back light module of a display. 4. The photocurable coating composition according to claim 1 , wherein the composition has a viscosity of 100 to 2000 cps at 25° C.5. The photocurable coating composition according to claim 1 , wherein the (meth)acrylate monomer or oligomer with at least four functional groups is present in an amount of 5 wt % to 25 wt % based on the total weight of the photocurable coating composition.6. The photocurable coating composition according to claim 1 , wherein the (meth)acrylate monomer with at least four functional groups comprises pentaerythritol tetraacrylate claim 1 , ethoxylated pentaerythritol tetraacrylate claim 1 , propoxylated pentaerythritol tetraacrylate claim 1 , dipentaerythritol hexaacrylate or caprolactone modified dipentaerythritol hexaacrylate.7. The photocurable coating composition according to claim 1 , wherein the (meth)acrylate oligomer with at least four functional groups comprises a hyperbranched polyurethane (meth)acrylate or a hyperbranched polyester (meth)acrylate.8. The photocurable coating composition according to claim 1 , wherein the (meth)acrylate oligomer with at least four functional groups has not more than twenty functional groups and has a number average molecular weight between 2000 and 5000.9. The photocurable coating composition according to claim 1 , wherein the monofunctional (meth)acrylate monomer is present in ...

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Номер записи: 22
08-01-2015 дата публикации

Blended Thermoplastic Compositions With Improved Optical Properties and Flame Retardance

Номер: US20150011688A1
Автор: An Narong, Iida Hiroshi, Ishida Hiromi, Shen Dake, Sun Pei
Принадлежит:

The present disclosure relates to blended thermoplastic compositions comprising at least one polycarbonate component, at least one reinforcing filler, at least one phosphorus-containing flame retardant component. The resulting thermoplastic composition can be used in the manufacture of articles requiring materials with improved flame retardancy and optical properties such as light transmittance, while retaining required modulus and impact properties. 1. A blended thermoplastic composition comprising:a) from about 47 wt % to about 91.5 wt % of a polycarbonate polymer component;b) from about 5 wt % to about 50 wt % of a reinforcing filler; and wherein the combined weight percent value of all components does not exceed about 100 wt %; and', 'wherein all weight percent values are based on the total weight of the composition., 'c) from about 3 wt % to about 7 wt % of a flame retardant;'}2. The blended thermoplastic composition of claim 1 , wherein the polycarbonate polymer component comprises a linear polycarbonate claim 1 , a polycarbonate-polysiloxane copolymer claim 1 , or a combination thereof.3. The blended thermoplastic composition of claim 1 , wherein the polycarbonate polymer component comprises a bisphenol A polycarbonate polymer.4. The blended thermoplastic composition of claim 1 , wherein the reinforcing fiber comprises a glass fiber having an refractive index “n” that is at least substantially similar to the refractive index of the polycarbonate polysiloxane copolymer.5. The blended thermoplastic composition of claim 1 , wherein the flame retardant comprises a phosphorous containing flame retardant.6. The blended thermoplastic composition of claim 5 , wherein the phosphorous containing flame retardant comprises an organophosphorous compound.7. The blended thermoplastic composition of claim 6 , wherein the organophosphorous compound comprises a bisphenol A diphosphate polymer or a phenoxyphosphazene claim 6 , or a combination thereof.8. The blended ...

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Номер записи: 23
14-01-2021 дата публикации

SULFUR- AND PHOSPHORUS-CONTAINING POLYMERS, AND METHODS OF PRODUCING THEREOF

Номер: US20210009753A1
Автор: Lee Han, Sookraj Sadesh H., Tseitlin Alexander
Принадлежит:

Provided are methods of producing sulfur- and phosphorus-containing polymers from beta-lactones. The sulfur- and phosphorus-containing polymers include bio-based sulfur- and phosphorus-containing polymers that may be obtained from renewable sources. 1. A method , comprising:combining a beta-lactone with a dithionite compound to produce a sulfonyl-dialkanoic acid; andcombining the sulfonyl-dialkanoic acid with a diol compound to produce a polymer by condensation polymerization,wherein the polymer comprises repeating sulfonyl-dialkanoic acid moieties.2. The method of claim 1 , wherein the beta-lactone combined with the dithionite compound produces a salt of the sulfonyl-dialkanoic acid claim 1 , and wherein the method further comprises neutralizing the salt of the sulfonyl-dialkanoic acid to produce the sulfonyl-dialkanoic acid.3. The method of claim 1 , wherein the beta-lactone is beta-propiolactone claim 1 , beta-butyrolactone claim 1 , or beta-valerolactone claim 1 , and wherein the dithionite compound is sodium dithionite or potassium dithionite.45-. (canceled)6. The method of claim 1 , wherein the diol compound is ethylene glycol.7. (canceled)9. (canceled)10. The method of claim 8 , wherein Ris alkyl or H claim 8 , and R claim 8 , R claim 8 , and Rare all H.11. The method of claim 10 , wherein Ris methyl or ethyl claim 10 , and Ris -alkyl-.1213-. (canceled)14. A method claim 10 , comprising:combining a beta-lactone with (i) hydrogen sulfide or a salt thereof, or (ii) a thiol compound to produce a sulfur-containing alkanoic acid; andpolymerizing the sulfur-containing alkanoic acid to produce a sulfur-containing polymer.1517-. (canceled)19. (canceled)20. The method of claim 18 , wherein Ris H or -alkyl claim 18 , and R claim 18 , Rand Rare all H claim 18 , Ris —Calkyl claim 18 , and Rv is unsubstituted -alkyl- or -alkyl- substituted with one or more substituents selected from the group consisting of —OH and —COOH.2224-. (canceled)25. The method of claim 20 , ...

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Номер записи: 24
14-01-2021 дата публикации

METHODS AND PRODUCTS FOR TRANSFECTING CELLS

Номер: US20210009955A1
Автор: Angel Matthew, Rohde Christopher
Принадлежит:

The present invention relates in part to nucleic acids encoding proteins, nucleic acids containing non-canonical nucleotides, therapeutics comprising nucleic acids, methods, kits, and devices for inducing cells to express proteins, methods, kits, and devices for transfecting, gene editing, and reprogramming cells, and cells, organisms, and therapeutics produced using these methods, kits, and devices. Methods for inducing cells to express proteins and for reprogramming and gene-editing cells using RNA are disclosed. Methods for producing cells from patient samples, cells produced using these methods, and therapeutics comprising cells produced using these methods are also disclosed. 161-. (canceled)62. A method for producing a gene-edited cell , comprising:(a) culturing a cell comprising a target DNA sequence; and i. a first synthetic RNA molecule encoding a first fusion protein comprising a DNA-binding domain and a catalytic domain of a nuclease; and', the first fusion protein and the second fusion protein are independently a transcription activator-like effector nuclease (TALEN);', 'the transfecting results in the cell expressing the first fusion protein and the second fusion protein to result in a double-strand break in the target DNA sequence; and', 'the first synthetic RNA molecule and the second synthetic RNA molecule are independently synthesized by in vitro transcription from a DNA template., 'ii. a second synthetic RNA molecule encoding a second fusion protein comprising a DNA-binding domain and a catalytic domain of a nuclease; wherein], '(b) transfecting the cell with a plurality of synthetic RNA molecules, wherein the synthetic RNA molecules include63. The method of claim 62 , further comprising contacting the cell with at least one of poly-L-lysine claim 62 , poly-L-ornithine claim 62 , RGD peptide claim 62 , fibronectin claim 62 , vitronectin claim 62 , collagen claim 62 , and laminin.64. The method of claim 62 , further comprising contacting the cell ...

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Номер записи: 25
09-01-2020 дата публикации

POWDER COATING COMPOSITION

Номер: US20200010717A1
Автор: BRÜSTLE Bernhard, SCHLAGER Gerd
Принадлежит:

The invention relates to a powder coating composition containing a binder combination. The binder combination comprises the following components: A) 15 to 70 wt. % of the binder of one or more amorphous carboxyl group-containing polyester resins, having an arithmetically averaged acid number of 50 to 100 mg KOH/g, B) 20 to 50 wt. % of the binder of one or more epoxide group-containing polymers with an arithmetically averaged epoxide equivalent weight of 350 to 650 g/eq, preferably 400 to 650 g/eq, preferably based on bisphenol A and phenol novolak, C) 5 to 55 wt. % of the binder of one or more crystalline or semi-crystalline carboxyl group-containing polyester resins, having an arithmetically averaged acid number of 15 to 00 mg KOH/g, D) 0.5 to 6 wt. % (based on the entire formulation) of one or more catalysts (accelerants) for the crosslinking reaction(s), and optionally E) 0 to 10 wt. % (based on the entire formulation) of one or more components with reactive groups for the crosslinking reaction(s) with the carboxyl groups and/or epoxide groups of the components A), B), and C). The polyester resins according to A) and. C) contain a sum of 15 to 75 wt. %, preferably 15 to 60 wt. % and particularly preferably 20 to 50 wt. %, based on the monomers used for the synthesis, of linear and unbranched aliphatic diols or the derivatives thereof and/or linear and unbranched aliphatic dicarboxylic acids or the derivatives thereof. The invention additionally relates to a method for producing such a powder coating composition and to the use thereof. 122-. (canceled)23. Powder coating compositions containing a binder combination , characterized in that the binder combination comprises the following components:A) 15% to 70% by weight of the binder formed by one or more amorphous polyester resins containing carboxy groups, with an arithmetically averaged acid value of 50 to 100 mg KOH/g,B) 20% to 50% by weight of the binder formed by one or more polymers containing epoxy groups ...

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Номер записи: 26
03-02-2022 дата публикации

Moisture-curable one-pack composition and method for joining, casting and coating using the composition

Номер: US20220033697A1
Автор: EHRET Markus, SÜ-VEGES Bastian, TRUE Markus
Принадлежит:

A composition that can be activated by irradiation and cured by moisture comprises (A) one or more moisture-curable compounds from the group of alkoxy silanes, (B) at least one acid generator releasing an acid when exposed to actinic radiation, and (C) at least one carbonyl compound and/or carbonyl derivative selected from the group of aldehydes, ketones, hemiacetals and hemiketals. Moreover, the compositions according to the present invention can additionally contain an alcohol and/or thiol (D), a catalyst for moisture-curing (E), a radiation-curable compound (F), a photoinitiator for radical polymerization (G), and further additives (H). After activation of the acid generator the composition cures even in high layer thicknesses independently of the ingress of external moisture. 1. A moisture-curable one-pack composition that can be activated by irradiation with actinic radiation , comprisingone or more moisture-curable compounds (A) selected from the group of alkoxy silanes;at least one acid generator (B) releasing an acid when exposed to actinic radiation, andat least one carbonyl compound and/or carbonyl derivative (C) selected from the group of aldehydes, ketones, hemiacetals or hemiketals.2. The one-pack composition according to claim 1 , characterized in that the one-pack composition cures without the ingress of external moisture after activation of the composition by irradiation.3. The one-pack composition according to claim 1 , characterized in that the alkoxy silane of component (A) comprises an at least bifunctional alkoxy silane claim 1 , preferably a bifunctional α-alkoxy silane.4. The one-pack composition according to claim 1 , characterized in that the one-pack composition additionally comprises at least one catalyst (E) for silane crosslinking claim 1 , preferably an acid catalyst.5. The one-pack composition according to claim 1 , characterized in that the one-pack composition additionally comprises at least one radiation-curable compound (F) and at ...

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Номер записи: 27
18-01-2018 дата публикации

Organic silicon resin composition, white prepreg and white laminate using same

Номер: US20180016436A1
Автор: Guofang Tang, Peng Sun, Suwen YE
Принадлежит: Shengyi Technology Co Ltd

Provided are an organic silicon resin composition, prepreg and laminate using the same. The organic silicon resin composition glue solution contains a condensation silicon resin, a catalyst, an auxiliary agent, a white filler and a solvent as necessary components, and is impregnated in a reinforced material such as a sheet-like fiberglass fiber base material and then dried to prepare the prepreg. The prepreg has a net structure via crosslinking of the silicon resin using a condensation reaction. Since the organic silicon resin has ultrahigh heat resistance and yellowing resistance, the present invention applies the silicon resin to a white LED copper-clad laminate instead of a traditional organic resin, satisfying the demand for high heat resistance, and replacing the ceramic substrate to be a new heat-dissipating substrate base material.

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Номер записи: 28
15-01-2015 дата публикации

MODIFIED POLYPROPYLENE COMPOSITIONS FOR REDUCED NECKING IN EXTRUSION FILM CASTING OR EXTRUSION COATING PROCESSES

Номер: US20150018463A1
Автор: AHMAD Zubair, Chikhalikar Kalyani Suresh, Jadhav Kishor Shankar, Lele Ashish Kishore, Mahajan Sunil Janardan, Pol Harshwardhan Vinayak
Принадлежит:

The present invention discloses modified polypropylene composition with higher flow activation energy and reduced necking in extrusion film/coat, wherein composition comprises long chain branch of polypropylene; free radical initiator; primary antioxidant; secondary antioxidant; acid neutralizer; optionally multifunctional monomer. Further the said composition of polypropylene shows higher sensitivity of viscosity to temperature, with improved stretchability. 1. A modified polypropylene composition comprising long chain branch of polypropylene; free radical initiator; primary antioxidant; secondary anti-oxidant; acid neutralizer , characterized in that the flow activation energy of the composition is in the range of 40-60 kJ/mole.2. The modified polypropylene composition according to claim 1 , wherein the polypropylene is impact copolymer (ICP) claim 1 , having a density range from 0.9 to 0.95 g/cmand the melt flow rate or index of impact copolymer (ICP) claim 1 , is in the range from 0.5 to 2.5 g/10 min.3. The modified polypropylene composition according to claim 1 , wherein free radical initiator is selected from is selected from the group consisting of peroxidicarbonates of formula R′—OCOOCO—R claim 1 , wherein R and R′ are identical or different and independently selected from branched or linear (C1-C5) alkyl claim 1 , (C6-C12) alicyclic claim 1 , cetyl claim 1 , [3-(isobutyryloxy)-2 claim 1 ,2 claim 1 ,4-trimethylpentyl]; in the range of 2000-8000 ppm by wt. preferably 4000-6000 ppm by wt.4. The modified polypropylene composition according to claim 9 , wherein the half-life of peroxidicarbonates is in the range of 0.1-1 min at the extrusion temperature of polypropylene.5. The modified polypropylene composition according to claim 1 , wherein said primary antioxidant is hindered phenolic-type antioxidants selected from the group Pentaerythritol Tetrakis(3-(3 claim 1 ,5-di-tert-butyl-4-hydroxyphenyl)propionate); IRGANOX 1010 FF; IRGANOX 1010 DD; 1 claim 1 ,3 claim ...

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Номер записи: 29
21-01-2021 дата публикации

PRINTABLE RESINS AND USES OF SAME

Номер: US20210017302A1
Автор: CHENG Chong, Rzayev Javid, SCHOFIELD Jason, ZHOU Chi
Принадлежит:

Provided are resin compositions, which may be used for 3D printing. The resins may be colorless and/or transparent. The resins include a photoinitiator and one or more hard cross-linker. The resins may also include one or more of soft cross-linker(s), reactive diluent(s), filler(s), and additive(s). Also provided are articles of manufacture and methods of making articles of manufacture using one or more of the resins. The articles of manufacture may have one or more desirable mechanical and/or one or more desirable biocompatibility properties. The articles of manufacture may be colorless and/or transparent. The articles of manufacture may be produced using a method of the present disclosure. 1. A resin composition comprising:one or more photoinitiator;one or more hard cross-linker, wherein the one or more hard cross-linker has at least two reactive groups and is present at 20-75 wt % (based on the total weight of the composition); andone or more soft cross-linker and/or one or more reactive diluent, wherein the one or more soft cross-linker has at least two reactive groups is present at 2-70 wt % (based on the total weight of the composition) and/or the one or more reactive diluent has only one reactive group and is present at 2-70 wt % (based on the total weight of the composition).2. The resin composition of claim 1 , wherein the resin composition further comprises one or more soft cross-linker and one or more reactive diluent.3. The resin composition of claim 1 , wherein the resin composition further comprises:one or more filler; and/orone or more additive.4. The resin composition of claim 1 , wherein the one or more photoinitiator is diphenyl(2 claim 1 ,4 claim 1 ,6-trimethylbenzoyl)phosphine oxide (TPO) claim 1 , 1-phenyl-1 claim 1 ,2-propanedione/triame (PPD/TA) claim 1 , camphoroquinone claim 1 , Irgacure 819 claim 1 , henanthrenequinone claim 1 , or a combination thereof.5. The resin composition of claim 1 , wherein the hard cross-linker has a molecular ...

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Номер записи: 30
21-01-2016 дата публикации

LOW DIALECTRIC COMPOSITE MATERIAL AND LAMINATE AND PRINTED CIRCUIT BOARD THEREOF

Номер: US20160021739A1
Автор: CAI Lianhui, Chen Hao, HSIEH CHEN-YU, LI Changyuan, LI Xiangnan
Принадлежит: Elite Electronic Material (Zhong Shan) Co., Ltd.

The present invention belongs to the technical field of resin composite materials, in particular relates to a low dielectric composite material and a laminate and printed circuit board prepared therefrom. The composite material is obtained by adhering a low dielectric resin composition with phosphorus-containing flame retardant onto a substrate; the composition comprises the following components: (A) phosphorus-containing flame retardant; (B) vinyl compound. The phosphorus-containing flame retardant has a structure as shown in formula (I).

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Номер записи: 31
16-01-2020 дата публикации

PHOTOSENSITIVE RESIN COMPOSITION, SOLDER RESIST FILM USING SAID PHOTOSENSITIVE RESIN COMPOSITION, FLEXIBLE PRINTED CIRCUIT AND IMAGE DISPLAY DEVICE

Номер: US20200019054A1
Автор: GONDAIRA Takashi, Tai Makoto
Принадлежит:

This photosensitive resin composition comprises: a photosensitive prepolymer having a carboxyl group and an ethylenically unsaturated group; a photopolymerization initiator; a thermosetting agent; and a pigment. The thermosetting agent is a polycarbodiimide compound represented by formula (1), in which a carbodiimide group is protected by an amino group that dissociates at temperatures of 80□ or greater. The polycarbodiimide compound has a weight average molecular weight of 300-3000, and a carbodiimide equivalent weight of 150-600. When formed into a film having a dry film thickness of 10-40 μm, the maximum value of the transmittance of the photosensitive resin composition is at least 7% for the transmission spectrum of at least some of the wavelength from 350-430 nm. (In formula (1), R, R, X, X, and n are as defined in the description.) 2. The photosensitive resin composition according to claim 1 ,wherein a brightness L* in an L*a*b* color system is 30 or less when the photosensitive resin composition is formed to the film having a dry film thickness of 10 μm to 40 μm.3. The photosensitive resin composition according to claim 1 ,wherein a brightness L* in the L*a*b* color system is 30 or less at a surface of the film of the photosensitive resin composition having a cured film thickness of 10 μm to 40 μm formed on a glossy side of a copper foil.4. The photosensitive resin composition according to claim 1 ,wherein the pigment contains, as a main pigment, at least one selected from the group consisting of C. I. Pigment Violet 3, C. I. Pigment Violet 15, C. I. Pigment Violet 19, C. I. Pigment Violet 23, C. I. Pigment Violet 29, C. I. Pigment Violet 37, C. I. Pigment Violet 50, azomethine azo black, and perylene black.5. The photosensitive resin composition according to claim 4 ,wherein the pigment further contains, as a toning pigment, at least one selected from the group consisting of a yellow pigment, a blue pigment and a green pigment.6. The photosensitive resin ...

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Номер записи: 32
17-04-2014 дата публикации

High-Heat Polycarbonate Blends That Are Halogen-Free and Flame Retardant

Номер: US20140107264A1
Автор: Lohmeijer Jan, van der Weele Chris, van Zyl Andre
Принадлежит: SABIC INNOVATIVE PLASTICS

The present invention is directed to a composition comprising: 1. A composition comprising:(a) 10 to 50 percent by weight of a polyester;(b) 20 to 70 percent by weight of Polycarbonate A which is a copolycarbonate of 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP) and another bisphenol;(c) 10 to 60 percent by weight of Polycarbonate B, which is a polycarbonate-polysiloxane copolymer; and(d) 4 to 10 percent by weight of a non-halogenated flame retardant provided that when the non-halogenated flame retardant is an organophosphate, organophosphonate, or organophosphinate, the weight percent is 4 to 7 percent by weight; wherein: (i) the Ball Pressure Test according to (IEC) DIN EN 60695-10-2, VDE 0471 Part 10-2 or (IEC) DIN EN 60335-1 at 125° C.; or', '(ii) the Glow Wire Flammability Test (IEC) 60695-2-12 at 850° C.; and', '(iii) has a UL94 Vertical Flame Rating, V-0 at 1.5 mm., 'the weight percents are based on the total weight of the composition and the composition passes the following tests2. The composition of claim 1 , comprising:(a) 14 to 30 percent by weight of a polyester;(b) 30 to 60 percent by weight of Polycarbonate A; and(c) 20 to 50 percent by weight of Polycarbonate B.3. The composition of claim 2 , comprising:(a) 15 to 28 percent by weight of a polyester;(b) 32 to 68 percent by weight of Polycarbonate A; and(c) 22 to 48 percent by weight of Polycarbonate B.4. The composition of claim 3 , comprising:(a) 15 to 28 percent by weight of a polyester;(b) 32 to 68 percent by weight of Polycarbonate A; and(c) 22 to 40 percent by weight of Polycarbonate B.54. The composition of - claims 1 , wherein(a) the polyester is polyethylene terephthalate (PET) or polybutylene terephthalate (PBT);(b) Polycarbonate A is a copolymer of PPPBP and bisphenol-A;(c) Polycarbonate B is a polycarbonate/polydimethylsiloxane (PC/PDMS) copolymer.(d) the non-halogenated flame retardant is selected from the group consisting of bisphenol-A bis(diphenylphosphate (BPADP), ...

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Номер записи: 33
24-04-2014 дата публикации

FLAMEPROOFED ALICYCLIC POLYIMIDE RESIN COMPOSITION AND THIN-WALLED MOLDED BODY OF SAME

Номер: US20140114000A1
Автор: MAKINOSHIMA Takashi
Принадлежит: MITSUBISHI GAS CHEMICAL COMPANY, INC.

The present invention relates to an alicyclic polyimide resin composition including 100 parts by mass of an alicyclic polyimide resin (A) having a specific structure and from 1 to 13 parts by mass of a cyano-modified cyclic phenoxy phosphazene compound (B), and a thin-wall molded article formed of the alicyclic polyimide resin composition which is produced by casting a solution of the resin composition and then heating the cast solution. The present invention aims at obtaining an alicyclic polyimide resin composition that is imparted with a good flame retardancy without adding a halogen-based flame retardant, an antimony-based flame retardant, an inorganic metal hydrate, a phosphoric acid salt, etc., thereto, and also is excellent in transparency, heat resistance and insulating property, and a thin-wall molded article obtained from the resin composition. 3. The alicyclic polyimide resin composition according to claim 1 , wherein in the general formulae (1) and (3) claim 1 , Ris a divalent aromatic hydrocarbon group having 6 to 27 carbon atoms claim 1 , and a nitrogen atom bonded to Ris directly bonded to an aromatic ring of R.4. A thin-wall molded article comprising the alicyclic polyimide resin composition as defined in claim 1 , which is produced by casting a solution of the alicyclic polyimide resin composition prepared by dissolving the alicyclic polyimide resin composition in an organic solvent and then heating the cast solution.5. The alicyclic polyimide resin composition according to claim 2 , wherein in the general formulae (1) and (3) claim 2 , Ris a divalent aromatic hydrocarbon group having 6 to 27 carbon atoms claim 2 , and a nitrogen atom bonded to Ris directly bonded to an aromatic ring of R.6. A thin-wall molded article comprising the alicyclic polyimide resin composition as defined in claim 2 , which is produced by casting a solution of the alicyclic polyimide resin composition prepared by dissolving the alicyclic polyimide resin composition in an ...

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Номер записи: 34
29-01-2015 дата публикации

Phosphorus Containing Flame Retardants

Номер: US20150031805A1
Автор: Fielding William R., Hanson Mark V., Narayan Subramaniam, Stockdale Zachary D., Timberlake Larry D.
Принадлежит: CHEMTURA CORPORATION

Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants. 2. The flame retardant polymer composition according to wherein M in formula (I) is Li claim 1 , K claim 1 , Na claim 1 , Mg claim 1 , Ca claim 1 , Ba claim 1 , Zn claim 1 , Zr claim 1 , B claim 1 , Al claim 1 , Si claim 1 , Ti claim 1 , Sn or Sb.3. The flame retardant polymer composition according to wherein M in formula (I) is Al or Ca.4. The flame retardant polymer composition according to wherein in formula (I) R is unsubstituted Calkyl claim 1 , Caryl claim 1 , Calkylaryl claim 1 , or Carylalkyl.5. The flame retardant polymer composition according to wherein R is methyl claim 4 , ethyl claim 4 , propyl claim 4 , isopropyl claim 4 , benzyl or phenyl.6. The flame retardant polymer composition according to wherein M in formula (I) is Al or Ca.7. The flame retardant polymer composition according to wherein the thermoset or thermoplastic polymer comprises one or more of a polyolefin homopolymer claim 1 , polyolefin copolymer claim 1 , rubber claim 1 , epoxy resin claim 1 , polyester claim 1 , polyurethane claim 1 , polysulfone claim 1 , polyimide claim 1 , polyphenylene ether claim 1 , styrenic polymer claim 1 , styrenic copolymer claim 1 , polycarbonate claim 1 , acrylic polymer claim 1 , polyamide claim 1 , polyacetal claim 1 , epoxy resin claim 1 , biodegradable polymer or a blend thereof.8. The flame retardant polymer composition according to wherein the thermoset or thermoplastic polymer comprises one or more of a polyphenylene ether/styrenic resin blend claim 1 , ABS claim 1 , polyvinyl chloride/ABS blend claim 1 , methacrylonitrile containing ABS claim 1 , a-methylstyrene containing ABS claim 1 , ...

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Номер записи: 35
17-02-2022 дата публикации

CROSS-LINKED POLYMERIC MATERIALS AND ARTICLES

Номер: US20220049041A1
Автор: Alamri Haleema, Almaghrabi Maryah
Принадлежит: Saudi Arabian Oil Company

Reprocessable materials are provided that include a product of cross-linking a glycidyl methacrylate grafted high-density polyethylene (HDPE-g-GMA) with a polymacrolactone of formula (II) to form a cross-linked polymer exhibiting vitrimer characteristics. Methods for preparing the cross-linked polymer materials include reacting the glycidyl methacrylate grafted high-density polyethylene of with the polymacrolactone in the presence of a first catalyst under conditions that initiate cross-linking of HDPE-g-GMA with the polymacrolactone. Mechanically reprocessable articles include a structural element that is or includes the cross-linked polymer material. Examples of the mechanically reprocessable articles include pallets or molded structures formed from the material and configured to support a load of at least 1000 kg without bending. 2. The vitrimer of claim 1 , wherein a+b=1.3. The vitrimer of claim 1 , wherein the HDPE-g-GMA has a molecular weight from 10 claim 1 ,000 g/mol to 100 claim 1 ,000 g/mol.4. The vitrimer of claim 1 , wherein the polymacrolactone has a molecular weight from 900 g/mol to 10 claim 1 ,000 g/mol.5. The vitrimer of claim 1 , wherein the vitrimer has a molecular weight from 10 claim 1 ,000 g/mol to 100 claim 1 ,000 g/mol.6. The vitrimer of claim 1 , wherein the vitrimer is from 0.1% to 0.5% cross-linked.7. The vitrimer of claim 1 , wherein m is 11.8. A method for preparing a vitrimer according to claim 1 , the method comprising:reacting a glycidyl methacrylate grafted high-density polyethylene of formula (I) with a polymacrolactone of formula (II) in the presence of a first catalyst under conditions that initiate cross-linking of HDPE-g-GMA with the polymacrolactone.9. The method of claim 8 , wherein the catalyst is a phosphazene.10. The method of claim 8 , wherein the catalyst comprises 1-tert-Butyl-2 claim 8 ,2 claim 8 ,4 claim 8 ,4 claim 8 ,4-pentakis(dimethylamino)-2λ claim 8 ,4λ-catenadi(phosphazene) claim 8 , 1-tert-Butyl-4 claim 8 ,4 ...

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Номер записи: 36
17-02-2022 дата публикации

Ethylene-Based Polymer Composition Containing a Phosphine Oxide

Номер: US20220049076A1
Автор: Bharat I. Chaudhary, Charles Liotta, Jeffrey M. Cogen, Pamela Pollet, Sarath SARNGADHARAN
Принадлежит: Dow Global Technologies LLC, Georgia Tech Research Corp

The present disclosure provides a composition. The composition includes (i) an ethylene-based polymer; (ii) an organic peroxide, (iii) a phosphine oxide, and (iv) a protic acid-source compound (“PASC”) selected from a protic acid, a protic acid-generator compound (“PAGC”), and combinations thereof. The present disclosure also provides a coated conductor. The coated conductor includes a conductor and a coating on the conductor, the coating containing a composition including (i) an ethylene-based polymer; (ii) an organic peroxide, (iii) a phosphine oxide, and (iv) a protic acid-source compound (“PASC”) selected from a protic acid, a protic acid-generator compound (“PAGC”), and combinations thereof.

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Номер записи: 37
04-02-2021 дата публикации

RESIN COMPOSITION, KIT, METHOD FOR MANUFACTURING RESIN COMPOSITION, METHOD FOR MANUFACTURING FORMED ARTICLE, AND FORMED ARTICLE

Номер: US20210032468A1
Автор: OKAMOTO Fumihito
Принадлежит: Mitsubishi Engineering-Plastics Corporation

To provide a resin composition having large light transmittance and capable of providing a molded article which is highly laser-weldable to an absorbing resin member, as well as a kit, a method for manufacturing the resin composition, a method for manufacturing a formed article, and a formed article. The resin composition contains a polyamide resin, a maleic anhydride-modified polyphenylene ether-based resin, a phosphazene-based flame retardant, a zinc metal oxide, and a light transmitting dye. 113.-. (canceled)14. A resin composition comprising a polyamide resin , a maleic anhydride-modified polyphenylene ether-based resin , a phosphazene-based flame retardant , a zinc metal oxide , and a light transmitting dye.15. The resin composition of claim 14 , demonstrating a transmittance of 40% or larger claim 14 , when formed into a 1-mm thick specimen and measured at a wavelength of 1070 nm in compliance with ISO 13468-2.16. The resin composition of claim 14 , wherein the polyamide resin contains a semi-aromatic polyamide resin.17. The resin composition of claim 14 , wherein the polyamide resin contains a polyamide resin contains a structural unit derive from a diamine and a structural unit derive from a dicarboxylic acid claim 14 , 50 mol % or more of the structural unit derive from a diamine being derived from xylylenediamine claim 14 , and 50 mol % or more of the structural unit derive from a dicarboxylic acid being derived from a straight-chain aliphatic α claim 14 ,ω-dicarboxylic acid having 4 to 20 carbon atoms.18. The resin composition of claim 14 , wherein the zinc metal oxide contains zinc borate.19. The resin composition of claim 14 , further comprising a glass fiber.20. The resin composition of claim 15 , wherein the polyamide resin contains a polyamide resin contains a structural unit derive from a diamine and a structural unit derive from a dicarboxylic acid claim 15 , 50 mol % or more of the structural unit derive from a diamine being derived from ...

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Номер записи: 38
04-02-2021 дата публикации

Adhesive sheet for temporary attachment and method for producing semiconductor device using the same

Номер: US20210032501A1
Автор: Ji Ho HAN, Kwang Joo Lee, Mi Jang, Sera Kim
Принадлежит: LG Chem Ltd

The present disclosure relates to an adhesive sheet for temporary attachment which is excellent in heat resistance and can realize sufficient adhesive strength even when being subjected to a high temperature process during the semiconductor production process, and can exhibit a sufficient reduction in adhesive strength due to photocuring in a peeling step, and a method for producing a semiconductor device using the same.

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Номер записи: 39
18-02-2021 дата публикации

MAINTENANCE LIQUID AND MAINTENANCE METHOD

Номер: US20210047592A1
Автор: Nakano Keitaro, Sato Chigusa, Yoshizawa Mitsuaki
Принадлежит:

There is provided a maintenance liquid, which is used in maintenance of a device equipped with a discharge head for discharging an ultraviolet ray curable-type composition containing the acyl phosphine oxide-based photopolymerization initiator toward an attachment object, including a polymerizable compound in which a saturation solubility of an acyl phosphine oxide-based photopolymerization initiator at 20° C. is equal to or greater than 5.0% by mass. 1. A maintenance method , comprising: {'br': None, 'sub': '2', 'sup': 1', '2', '3, 'CH═CR—COOR—O—CH═CH—R\u2003\u2003(1)'}, 'performing maintenance of a device equipped with a discharge head for discharging an ultraviolet ray curable-type composition containing an acyl phosphine oxide-based photopolymerization initiator toward an attachment object using a maintenance liquid having a polymerizable compound in which a saturation solubility of an acyl phosphine oxide-based photopolymerization initiator at 20° C. is equal to or greater than 5.0% by mass, wherein the polymerizable compound includes at least any one of vinyl ether group-containing (meth)acrylic acid ester represented by the following general formula (1) and a monofunctional (meth)acrylate compound having an aromatic ring'}{'sup': 1', '2', '3, 'wherein Rrepresents a hydrogen atom or a methyl group, Rrepresents a divalent organic residue having 2 to 20 carbon atoms, and Rrepresents a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms.'}2. The method according to claim 1 , wherein the viscosity of the polymerizable compound at 20° C. is equal to or less than 30 mPa·s.3. The maintenance method according to claim 1 ,wherein a content of the polymerizable compound is equal to or greater than 40% by mass with respect to the total amount of the maintenance liquid.4. The maintenance method according to claim 1 ,wherein the viscosity at 20° C. is equal to or less than 20 mPa·s.5. The maintenance method according to claim 1 ,wherein the viscosity ...

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Номер записи: 40
25-02-2016 дата публикации

Polylactic Acid Resin Composition

Номер: US20160053089A1
Автор: Chung Jae-Il, Jeon Sung-Wan, KIM Min-Young, LEE Kye Yune, Yoo Young-Man
Принадлежит:

The present invention relates to a polylactic acid resin composition having eco-friendly properties, which can be effectively used as a packaging material due to improved flexibility and moisture resistance, as well as superior general properties such as mechanical properties, transparency, heat resistance, an anti-blocking property, and film processability. 1. A polylactic acid resin composition comprising:{'sub': 'bio', 'a polylactic acid resin comprising a hard segment comprising a polylactic acid repeating unit of Formula 1 and a soft segment comprising a polyolefin-based polyol repeating unit in which polyolefin-based polyol structural units of Formula 2 are linked in a linear or branched manner via a urethane bond or an ester bond, wherein the organic carbon content (% C) of biomass-based carbon, as defined in Equation 1, is at least 60 wt %, wherein, in Formulae 1 and 2, n is an integer from 700 to 5,000, and m+1 is an integer from 5 to 200; and'} {'chemistry': {'@id': 'CHEM-US-00003', '@num': '00003', 'img': {'@id': 'EMI-C00003', '@he': '48.51mm', '@wi': '69.85mm', '@file': 'US20160053089A1-20160225-C00003.TIF', '@alt': 'embedded image', '@img-content': 'chem', '@img-format': 'tif'}}, 'br': None, 'sub': 'bio', 'sup': 14', '12', '14', '12, '% C=(weight ratio of C isotope to C of the total carbon content in the polylactic acid resin)/(weight ratio of C isotope to C of the total carbon content in a biomass-based carbon standard material). \u2003\u2003[Equation 1]'}, 'an antioxidant2. The polylactic acid resin composition of claim 1 , wherein the C isotope content based on the total weight of carbon in the polylactic acid resin is 7.2×10to 1.2×10wt %.3. The polylactic acid resin composition of claim 1 , wherein the soft segment has the organic carbon content (% C) of biomass-based carbon claim 1 , as defined in Equation 1 claim 1 , of at least 70 wt %.4. The polylactic acid resin composition of claim 1 , wherein the polylactic acid resin has a number average ...

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Номер записи: 41
25-02-2021 дата публикации

HIGHLY HYGROSCOPIC SEA-ISLAND TYPE COMPOSITE FIBER, FIBER STRUCTURE, AND POLYESTER COMPOSITION

Номер: US20210054188A1
Автор: Makino Masataka, Mochizuki Katsuhiko, Nakagawa Junichi, Tanaka Yoichiro
Принадлежит: Toray Industries, Inc.

A highly hygroscopic sea-island type composite fiber has characteristics (1)-(4) below: (1) the island component in a polymer has hygroscopicity; (2) the ratio of the outermost layer thickness T to the fiber diameter R in a cross section of the fiber is 0.05-0.25; (3) the difference (ΔMR) in moisture absorption rate after hot water treatment is 2.0-10.0%; and (4) the content of a phenol group is 16-160 mmol/kg, wherein the outermost layer thickness is the difference between the radius of the fiber and the radius of a circumscribed circle connecting the vertices of the island component disposed at the outermost circumference, and represents the thickness of the sea component present in the outermost layer. 113-. (canceled)14. A highly hygroscopic sea-island type composite fiber having (1) to (4):(1) a polymer in which the island component has hygroscopicity,(2) a T/R ratio of 0.05 to 0.25, wherein T and R are outermost layer thickness and fiber diameter, respectively, in a cross section of the fiber,(3) a difference in moisture absorbing rate (ΔMR) between before and after hot water treatment of 2.0 to 10.0%, and(4) a content of phenolic groups of 16 to 160 mmol/kg,the outermost layer thickness being a difference between a radius of the fiber and a radius of a circumscribed circle that connects apexes of island components disposed along an outermost periphery, which represents the thickness of the sea component present in the outermost layer.16. The highly hygroscopic sea-island type composite fiber as set forth in claim 14 , wherein the phosphorous atom content is 3 to 30 mmol/kg.17. The highly hygroscopic sea-island type composite fiber as set forth claim 14 , wherein the hydrophilic polymer is a polymer copolymerized with polyethylene glycol.18. A fiber structure at least partly comprising the highly hygroscopic sea-island type composite fiber as set forth in .20. The polyester composition as set forth in claim 19 , wherein 50 mol % or more of the aromatic ...

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Номер записи: 42
08-05-2014 дата публикации

REINFORCED POLY(PHENYLENE ETHER)-POLYSILOXANE BLOCK COPOLYMER COMPOSITION, AND ARTICLE COMPRISING SAME

Номер: US20140128522A1
Автор: Lietzau Christian, Sato Sho
Принадлежит: SABIC INNOVATIVE PLASTICS IP B.V.

A reinforced poly(phenylene ether)-polysiloxane block copolymer composition includes specific amounts of a poly(phenylene ether)-polysiloxane block copolymer reaction product, a flame retardant, and a reinforcing filler. The composition exhibits a desirable balance of flame retardancy, heat resistance, and stiffness relative to a corresponding poly(phenylene ether) composition, and it is useful to fabricate articles including fuser holders for electrophotographic copiers. 1. A composition , comprising:0.5 to 91 weight percent of a poly(phenylene ether)-polysiloxane block copolymer reaction product comprising a first poly(phenylene ether) and a poly(phenylene ether)-polysiloxane block copolymer;4 to 25 weight percent of a flame retardant comprising an organophosphate ester, a phosphazene, or a combination thereof; and5 to 40 weight percent of a reinforcing filler;wherein all weight percents are based on the total weight of the composition.2. The composition of claim 1 , exhibitinga flammability rating of V-0 at a sample thickness less than or equal to 1.5 millimeters in the 20 millimeter Vertical Burning Flame Test of Underwriter's Laboratory Bulletin 94 “Tests for Flammability of Plastic Materials, UL 94”,a heat deflection temperature of at least 110° C. determined according to ASTM D 648-07 using a stress of 1.82 megapascals (MPa) and a sample thickness of 6.4 millimeters, anda flexural modulus of at least 3,500 megapascals measured at 23° C. according to ASTM D 790-07e1 using a sample thickness of 6.4 millimeters.3. The composition of claim 1 , further comprising 5 to 90.5 weight percent of a second poly(phenylene ether).4. The composition of claim 3 , comprising 0.5 to 5 weight percent of the poly(phenylene ether)-polysiloxane block copolymer reaction product claim 3 , and 30 to 90.5 weight percent of the second poly(phenylene ether).6. The composition of claim 1 , wherein the poly(phenylene ether)-polysiloxane block copolymer contributes 0.025 to 5 weight ...

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Номер записи: 43
22-02-2018 дата публикации

COPOLYMERIZATION OF CARBON DIOXIDE AND CYCLIC MONOMERS TO FORM POLYCARBONATES

Номер: US20180051134A1
Автор: ALZAHRANY Yahya, BOOPATHI Senthil, FENG Xiaoshuang, GNANOU Yves, HADJICHRISTIDIS Nikolaos, ZHANG Dongyue
Принадлежит:

Embodiments of the present disclosure describe initiating systems comprising an activator and an initiator, wherein the activator includes an alkyl borane or alkyl aluminum, wherein the initiator includes an organic cation and either an alkali metal or a compound containing an active protic hydrogen. Embodiments of the present disclosure further describe methods of making a polycarbonate comprising contacting a cyclic monomer and carbon dioxide in the presence of an activator and an initiator to form a polycarbonate, wherein the catalyst is one or more of an alkyl borane and alkyl aluminum, wherein the initiator includes an organic cation and either an alkali metal or a compound containing an active protic hydrogen. 1. A method of making a polycarbonate , comprising:contacting an epoxide monomer and carbon dioxide in the presence of an activator and an initiator to form a polycarbonate,wherein the activator is trialkyl borane,wherein the initiator includes an alkali metal and an organic cation.2. The method of claim 1 , wherein the epoxide monomer is one or more of propylene oxide claim 1 , cyclohexene oxide claim 1 , ethylene oxide claim 1 , styrene oxide claim 1 , butyl glycidyl ether claim 1 , and allyl glycidyl ether.3. The method of claim 1 , wherein the activator is one or more of triethyl borane claim 1 , trimethyl borane claim 1 , triisobutylborane claim 1 , and triphenylborane.4. The method of claim 1 , wherein the alkali metal is one or more of lithium claim 1 , potassium claim 1 , and sodium.5. The method of claim 1 , wherein the organic cation is one or more of phosphazenium claim 1 , ammonium claim 1 , and phosphonium.6. The method of claim 1 , wherein the initiator is characterized by the formula:{'br': None, 'sup': −', '+', '−, 'R—O{Li/t-Bu-Py}, where R—O is an anion of any lithium alkoxide and Y is 1, 2, or 4.'}7. The method of claim 1 , wherein the initiator is characterized by the formula:{'br': None, 'sup': −', '+', '−, 'R—C{Li/t-Bu-Py}, R—C is ...

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Номер записи: 44
22-02-2018 дата публикации

Epoxy resin composition

Номер: US20180051167A1
Автор: Chihiro ASAKURA, Ken-Ichi Tamaso, Kozo Matsumoto, Ryo Ogawa, Takeshi Endo
Принадлежит: Adeka Corp

An epoxy resin composition comprising an epoxy resin (A), a curing agent (B) and a phosphorous-containing compound (C) indicated by the following general formula (1) and also, if necessary, a flame retardant (D), and a laminated plate comprising said resin composition; wherein m indicates an integer from 2 to 10, R 1 to R 4 each independently indicate a hydrogen atom, an alkyl group or an aryl group, R 5 indicates a hydrocarbon group that may contain an oxygen atom, a sulfur atom or a nitrogen atom, X indicates an oxygen atom or a sulfur atom, Y indicates an oxygen atom, a sulfur atom or —NR 6 —, and R 6 indicates a hydrogen atom, an alkyl group or an aryl group.

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Номер записи: 45
10-03-2022 дата публикации

POLYARYLATE RESIN COMPOSITION AND MOLDED ARTICLE USING THE SAME

Номер: US20220073731A1
Автор: MURAKAMI Takatoshi, NAGAHATA Toshiki
Принадлежит: UNITIKA LTD.

The present invention provides a polyarylate resin composition sufficiently excellent in heat resistance, transparency, heat discoloration resistance and moist heat resistance, and a molded article made of the same. The present invention relates to a polyarylate resin composition containing 0.005˜5 parts by mass of a silane compound (C) with a boiling point of 200° C. or more, based on 100 parts by mass of the total of a polyarylate resin (A) and a polycarbonate resin (B), a content ratio of the polyarylate resin (A) and the polycarbonate resin (B) being 5/95 to 95/5 (mass ratio). 1. A polyarylate resin composition; comprising 0.005˜5 parts by mass of a silane compound (C) with a boiling point of 200° C. or more , based on 100 parts by mass of the total of a polyarylate resin (A) and a polycarbonate resin (B) , a content ratio of the polyarylate resin (A) and the polycarbonate resin (B) being 5/95 to 95/5 (mass ratio).3. A polyarylate resin composition of claim 1 , further comprising a phosphorus-based compound (D).4. A polyarylate resin composition of claim 3 , wherein a content of the phosphorus-based compound (D) is 0.01 to 1 parts by mass based on 100 parts by mass of the total of the polyarylate resin (A) and the polycarbonate resin (B).5. A polyarylate resin composition of claim 3 , wherein the phosphorus-based compound (D) is selected from phosphite compounds claim 3 , tertiary phosphines claim 3 , phosphonite compounds.6. A molded article claim 1 , being obtained from the polyarylate resin composition of .6. A molded article of claim 6 , wherein the molded article is a lamp peripheral part. The present invention relates to a polyarylate resin composition excellent in heat resistance, transparency, heat discoloration resistance and moist heat resistance, and a molded article made of the same.Conventionally, polyarylate resins and polycarbonate resins have been used for lamp covers, lenses and the like for automotive use because they are excellent in heat ...

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Номер записи: 46
10-03-2022 дата публикации

Ink Composition

Номер: US20220073767A1
Автор: Goddard Simon, Harries Josephine, Jeremic Natasha, JOHNSON Amber, Kyriacou Andrew, Lake Thomas, Matsushita Yuichi, Thompson Martin
Принадлежит:

Provided is an ink composition for use in drop on demand inkjet printing such as piezoelectric drop on demand inkjet printing. The ink composition has a phosphine oxide initiator and benzyl acrylate. The amount of benzyl acrylate is less than 40 wt % based on the total weight of the ink composition and the total amount of mono-functional monomers is less than 45 wt % based on the total weight of the ink composition. The phosphine oxide initiator is a bis-acyl phosphine oxide, a benzoyl alkyl phosphinate, or a mixture thereof. The ink compositions are suitable for radiation curing and have good cure properties or good adhesion properties. 1. An ink composition comprising a phosphine oxide initiator and benzyl acrylate , wherein:the amount of benzyl acrylate is less than 40 wt % based on the total weight of the ink composition and the total amount of mono-functional monomers is less than 45 wt % based on the total weight of the ink composition; and whereinthe phosphine oxide initiator is a bis-acyl phosphine oxide, a benzoyl alkyl phosphinate, or a mixture thereof.2. The ink composition of wherein the benzyl acrylate is present at from 10 to 35 wt % based on the total weight of the ink composition3. The ink composition of claim 1 , wherein the phosphine oxide initiator is a dibenzoyl phosphine oxide claim 1 , a benzoyl alkyl phosphinate claim 1 , or a mixture thereof.4. The ink composition of wherein the phosphine oxide initiator is a combination of phenylbis (2 claim 3 ,4 claim 3 ,6 trimethylbenzoyl) phosphine oxide and ethyl (2 claim 3 ,4 claim 3 ,6-trimethylbenzoyl) phenylphosphinate.5. The ink composition of wherein the phosphine oxide initiator is phenylbis (2 claim 3 ,4 claim 3 ,6 trimethylbenzoyl) phosphine oxide.6. The ink composition of claim 1 , wherein the phosphine oxide initiator is present at 1 to 7 wt % based on the total weight of the ink composition.7. The ink composition of claim 1 , further comprising a multi-functional monomer and/or a colorant.8. ...

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Номер записи: 47
03-03-2016 дата публикации

THERMOSETTING RESIN COMPOSITION, PREPREG, METAL CLAD LAMINATE PLATE, AND PRINTED WIRING BOARD

Номер: US20160060429A1
Автор: FUJIWARA Hiroaki, KITAI YUKI, SAITO Hirosuke
Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

A thermosetting resin composition contains a thermosetting resin, a hardener capable of reacting with the thermosetting resin, and a flame retardant. The flame retardant contains a first phosphor compound compatible with a mixture of the thermosetting resin and the hardener, and a second phosphor compound incompatible with the mixture. 1. A thermosetting resin composition comprising:a thermosetting resin;a hardener capable of reacting with the thermosetting resin; anda flame retardant containing a first phosphor compound compatible with a mixture of the thermosetting resin and the hardener, and a second phosphor compound incompatible with the mixture,wherein the thermosetting resin contains a modified polyphenylene ether compound terminal-modified by one or more substituents having carbon-carbon unsaturated double bonds; andthe hardener contains a cross-linking hardener having carbon-carbon unsaturated double bonds in a molecule.2. The thermosetting resin composition according to claim 1 ,wherein a mass ratio of the first phosphor compound is 20% to 80%, inclusive, with respect to a total of the first and second phosphor compounds.3. The thermosetting resin composition according to claim 1 ,wherein a content of phosphorus atoms is in a range from 1.8 to 5.2 parts, inclusive, by mass with respect to 100 parts by mass of a total of the flame retardant and organic components other than the flame retardant.4. The thermosetting resin composition according to claim 1 ,wherein the first phosphor compound is at least one selected from the group consisting of phosphate compounds, phosphazene compounds, phosphite compounds, and phosphine compounds; andthe second phosphor compound is at least one selected from the group consisting of phosphinate compounds, polyphosphate compounds, and phosphonium salt compounds.5. The thermosetting resin composition according to claim 1 , further comprising as a filler at least one selected from the group consisting of silicas claim 1 , micas ...

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Номер записи: 48
21-02-2019 дата публикации

ION DIPOLES CONTAINING POLYMER COMPOSITIONS

Номер: US20190058108A1
Автор: Bella Redha, GUHATHAKURTA Soma, HOEKS THEO
Принадлежит:

A dielectric polymer, methods of making the dielectric polymer, and uses thereof (e.g. piezoelectric sensors and/or actuators) are described. The dielectric polymer includes a polymeric matrix (e.g. a copolymers of styrene and acrylonitrile SAN, or a terpolymer of the former with methyl methacrylate MMA-SAN) derived from at least one polymerizable vinyl monomer and an ionic liquid that includes an organic cation and a balancing anion (e.g. 1-butyl-3-methylimidazolium hexafluorophosphate BMMMPF6). The ionic liquid is compatible with the at least one polymerizable vinyl monomer and the concentration of the ionic liquid in the dielectric polymeric composition ranges from 0.5 wt. % to less than 30 wt. %. 1. A dielectric polymeric composition comprising:(a) a polymeric matrix, wherein the polymeric matrix is derived from at least one polymerizable vinyl monomer; and(b) an ionic liquid comprising an organic cation and a balancing anion,wherein the ionic liquid is compatible with the at least one polymerizable vinyl monomer,wherein the concentration of the ionic liquid in the dielectric polymeric composition ranges from 0.5 wt. % to less than 30 wt. %.2. The dielectric polymeric composition of claim 1 , wherein the dielectric polymeric composition is capable of a polarization of greater than 30 μC/cmupon the application of an electric field of less than 30 kilovolts/centimeter.3. The dielectric polymeric composition of claim 1 , wherein the ionic liquid is incorporated into the polymeric matrix.4. The dielectric polymeric composition of claim 1 , wherein the polymeric matrix is formed claim 1 , in situ claim 1 , in the presence of the ionic liquid and in the absence of a solvent.5. The dielectric polymeric composition of claim 1 , wherein the ionic liquid concentration ranges from 5 wt. % to 20 wt. %.6. The dielectric polymer composition of claim 1 , wherein the dielectric polymeric composition is a Tg miscible blend.7. The dielectric polymer composition of claim 1 , ...

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Номер записи: 49
28-02-2019 дата публикации

CURABLE COMPOSITION

Номер: US20190062477A1
Автор: Fried Wolfgang, Klemm Elisabeth, Tittel Martin
Принадлежит:

The present invention relates to a curable composition which can be cured by radiation and/or the influence of temperature; a cured product which is obtained from such a composition; an object and a composite which have the cured composition; and a method for producing the same. The cured composition has a high refractive index. 2. A curable composition as in claim 1 , comprising the following quantities of compounds (1) claim 1 , (2) as well as (3) and/or (4):Compound (1): 64 to 89 wt %Compound (2): 9 to 28 wt %Compound (3) and/or (4): 2 to 8 wt %.3. A curable composition as in claim 1 , where Ris —R—S-naphthyl claim 1 , —CHor phenyl.4. A curable composition as in claim 1 , where Ris a group having the formula —CHCH— or —CHCHCH—.5. A curable composition as in claim 1 , where Ris a group having the formula —CH—CH(OH)—CH—.6. A curable composition as in claim 1 , where Ris methyl.7. Curable A curable composition as in claim 1 , comprising a photoinitiator selected from a hydroxy ketone claim 1 , a monoacyl phosphine claim 1 , a bisacyl phosphine or a benzoyl derivative or a mixture of one or several thereof.8. A curable composition as in claim 1 , where the photoinitiator is selected from 1-hydroxy-cyclohexyl-phenyl ketone claim 1 , 2 claim 1 ,4 claim 1 ,6-trimethylbenzoylbisphenylphosphine oxide claim 1 , bis(2 claim 1 ,4 claim 1 ,6-trimethylbenzoyl)phenylphosphine oxide claim 1 , 2-hydroxy-2-methyl-1-phenylpropane-2-one claim 1 , benzophenone or a mixture of one or several thereof.9. A curable composition as in claim 1 , comprising a light-stabilization agent selected from bis(1-octyloxy-2 claim 1 ,2 claim 1 ,6 claim 1 ,6-tetramethyl-4-piperidyl)sebacate claim 1 , hydroxyphenylbenzotriazole claim 1 , 2-hydroxy-benzophenone and/or 2-hydroxyphenyltriazine.10. A curable composition as in claim 1 , comprising a thermally splittable initiator from the group of catalysts known in atom transfer radical techniques or from peroxide compounds.11. A cured product obtained by ...

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Номер записи: 50
17-03-2022 дата публикации

PROCESSING AIDS FOR DIE LIP BUILDUP SUPPRESSION AND USES THEREOF

Номер: US20220081557A1
Автор: Guo Mingcheng
Принадлежит:

Disclosed herein is a composition for suppressed die lip buildup. The composition may comprise from about 20 wt. % to about 98 wt. % of a polycarbonate; from about 0.01 wt. % to about 30 wt. % of a polybutylene terephthalate; from about 0.5 wt. % to about 60 wt. % of a functional filler; from about 0.1 wt. % to about 5 wt. % of an ultra-high molecular weight polydimethylsiloxane; and from about 0.01 wt. % to about 30 wt. % of a flame retardant component. The composition may exhibit a notched Izod impact strength of greater than 30 J/m when tested in accordance with ASTM D256 and may exhibit less die buildup during a continuous extrusion process when compared to a substantially similar reference composition in the absence of the ultra-high molecular weight polydimethylsiloxane. 1. A composition for suppressed die lip buildup , the composition comprising:from about 20 wt. % to about 98 wt. % of a polycarbonate;from about 0.01 wt. % to about 30 wt. % of a polybutylene terephthalate;from about 0.5 wt. % to about 60 wt. % of a functional filler;from about 0.1 wt. % to about 5 wt. % of an ultra-high molecular weight polydimethylsiloxane; andfrom about 0.01 wt. % to about 30 wt. % of a flame retardant component,wherein the combined weight percent value of all components does not exceed 100 wt. %, and all weight percent values are based on the total weight of the composition,wherein the composition exhibits a notched Izod impact strength of greater than 30 μm when tested in accordance with ASTM D256, andwherein the composition exhibits less die buildup during a continuous extrusion process when compared to a substantially similar reference composition in the absence of the ultra-high molecular weight polydimethylsiloxane.2. The composition of claim 1 , wherein the ultra-high molecular weight polydimethylsiloxane is present in an amount from 0.1 wt. % to 2 wt. %.3. A composition for suppressed die lip buildup claim 1 , the composition comprising:from about 20 wt. % to about ...

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Номер записи: 51
11-03-2021 дата публикации

PHOTOCURABLE COMPOSITION

Номер: US20210070894A1
Автор: Arai Yoshihide, Koga Yoshiaki, UENO Kazuyuki
Принадлежит: THREEBOND CO., LTD.

Conventionally, a photocurable composition to which an ultraviolet absorber is added is difficult to form a colorless and transparent cured resin because the ultraviolet absorber itself is colored, and thus the photocurable composition is hardly to be used in a display apparatus required for colorlessness and transparency. Provided is a photocurable composition including a specific compound, wherein a light transmittance of 385 nm is 50% or less and a yellowness index is 3.0 or less in a state in which a cured resin having a thickness of 200 μm or less is interposed between alkali free glass plates each having a thickness of 0.7 mm. 115-. (canceled)17. The photocurable composition according to claim 16 , wherein a light transmittance of 385 nm is 30% or less and a yellowness index is 3.0 or less in a state in which a cured resin of the photocurable composition with a thickness of 200 μm or less is interposed between alkali free glass plates each having a thickness of 0.7 mm.18. The photocurable composition according to claim 16 , further comprising: a (meth)acrylate compound as a component (B); a film-forming resin as a component (C); and a photoinitiator as a component (D).19. The photocurable composition according to claim 18 , wherein the component (B) includes a (meth)acrylate oligomer and a (meth)acrylate monomer.20. The photocurable composition according to claim 19 , wherein the (meth)acrylate oligomer is a urethane-modified (meth)acrylate oligomer.21. The photocurable composition according to claim 20 , wherein a main skeleton of the urethane-modified (meth)acrylate oligomer is polycarbonate.22. The photocurable composition according to claim 19 , wherein a main skeleton of the (meth)acrylate monomer is polyether.23. The photocurable composition according to claim 18 , wherein the component (C) is a phenoxy resin.24. The photocurable composition according to claim 18 , wherein the component (D) includes an acylphosphineoxide-based photoinitiator.25. The ...

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Номер записи: 52
15-03-2018 дата публикации

Flame-Retardant Polyamide Composition

Номер: US20180072873A1
Автор: Elke Schlosser, Sebastian Hoerold
Принадлежит: Clariant Plastics and Coatings Ltd

The invention relates to a flame-retardant polyamide composition comprising as component A) 1 to 96 wt % of one or more thermoplastic polyamides, as component B) 2 to 25 wt % of a dialkylphosphinic salt of the formula (I), and/or of a diphosphinic salt of the formula (II), and/or of polymers thereof, in which R 1 and R 2 are identical or different and are C 1 -C 6 -alkyl, linear, or branched, or H; R 3 is C 1 -C 10 -alkylene, linear, or branched, C 6 -C 10 -arylene, C 7 -C 20 -alkylarylene, or C 7 -C 20 -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component C) 1 to 20 wt % of a salt of phosphorous acid, as component D) 1 to 20 wt % of a phosphazene, as component E) 0 to 50 wt % of filler or reinforcing agent, as component F) 0 to 1 wt % of a phosphonite or of a mixture of a phosphonite and a phosphite, and as component G) 0 to 1 wt % of an ester or salt of long-chain aliphatic carboxylic acids (fatty acids), which typically have chain lengths of C 14 to C 40 , the sum of the components always being 100 wt %.

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Номер записи: 53
07-03-2019 дата публикации

FLAME-RETARDANT MICROCAPSULE CONTAINING CYCLIC PHOSPHAZENE

Номер: US20190071557A1
Автор: Kobilka Brandon M., Kuczynski Joseph, PORTER Jacob T., Wertz Jason T.
Принадлежит:

A flame-retardant microcapsule with a shell containing a cyclic phosphazene molecule, a process for forming a flame-retardant microcapsule with a shell containing a cyclic phosphazene molecule, and an article of manufacture including a flame-retardant microcapsule with a shell containing a cyclic phosphazene molecule are disclosed. The process for forming the flame-retardant microcapsule with the shell containing the cyclic phosphazene molecule may include providing a cyclic phosphazene molecule, forming an aqueous mixture containing the cyclic phosphazene molecule, adding a payload agent into the aqueous mixture, and adding a curing agent into the aqueous mixture. 2. The flame-retardant microcapsule of claim 1 , wherein the M has a formula of:{'br': None, '. . . O-L'}wherein L is a second variable substituent.4. The flame-retardant microcapsule of claim 3 , wherein the R is a substituent comprising at least one of:a hydrogen molecule, a vinyl group, an allyl group, an epoxy group, an acrylate group, a phenyl acrylic acid, and an acryloyl acid.5. The flame-retardant microcapsule of claim 3 , wherein the fourth variable substituent X is a substituent comprising at least one of:the R, a hydroxide molecule, and an amidogen molecule.6. The flame-retardant microcapsule of claim 1 , wherein the cyclic phosphazene molecule has orthogonal functionality.7. The flame-retardant microcapsule of claim 6 , wherein the cyclic phosphazene molecule is covalently bonded into a polymeric matrix.8. A process of forming a flame-retardant microcapsule with a shell containing a cyclic phosphazene molecule claim 6 , comprising:providing the cyclic phosphazene molecule;forming an aqueous mixture containing the cyclic phosphazene molecule;adding a payload agent into the aqueous mixture; andadding a curing agent into the aqueous mixture.9. The process of claim 8 , wherein providing the cyclic phosphazene molecule includes functionalizing an unfunctionalized cyclic phosphazene molecule claim 8 ...

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Номер записи: 54
07-03-2019 дата публикации

Pipe produced with a polymer composition comprising a polyethylen

Номер: US20190071561A1
Автор: Henrica Norberta Alberta Maria Steenbakkers-Menting, Mark Johannes Boerakker, Patrick Elisabeth Luc Voets, Sarah Van Mierloo
Принадлежит: SABIC Global Technologies BV

The invention relates a pipe for the transport of water with improved resistance to chlorinated disinfectants. The pipe is produced with a polymer composition comprising polyethylene and zinc sulfide.

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Номер записи: 55
05-03-2020 дата публикации

POLYCARBONATE ARTICLES FOR CONSUMER ELECTRONICS

Номер: US20200070204A1
Автор: Fang Yapeng, Lai Hengjie, Niu Yaming, Zhang Fen
Принадлежит:

A polycarbonate article comprises: a substrate comprising a poly(carbonate-bisphenol arylate ester) composition that comprises, based on the total weight of the poly(carbonate-bisphenol arylate ester) composition, 90 to 99.9 wt. %, preferably 95 to 99.9 wt. % of a poly(carbonate-bisphenol arylate ester), and 0.1 to 10 wt. %, preferably 0.1 to 5 wt. % of an additive comprising at least one of a processing aid, a heat stabilizer, an antioxidant, and an ultra violet light absorber; and a siloxane urethane acrylate coating disposed on at least a portion of a surface of the substrate, the siloxane urethane acrylate coating having a thickness of greater than or equal to 8 micrometers; wherein the article has a pencil hardness of 2H or harder when measured according to ASTM D3363-00 at 1,000 g force on the siloxane urethane acrylate coating. 2. The polycarbonate article of claim 1 , wherein the siloxane urethane acrylate coating has a thickness of greater than 8 micrometers to less than 30 micrometers on the siloxane urethane acrylate coating.3. The polycarbonate article of claim 1 , wherein the siloxane urethane acrylate coating has a thickness of 10 micrometers to 18 micrometers; and the polycarbonate article has a pencil hardness of 3H to 4H when measured according to ASTM D3363-00 at 1 claim 1 ,000 grams force on the siloxane urethane acrylate coating.4. The polycarbonate article of claim 1 , exhibiting a cross hatch tape test rating of Grade 5B based on ASTM D3359-09.6. The polycarbonate article of claim 5 , wherein the poly(carbonate-bisphenol arylate ester) comprises1 to 20 mol % of bisphenol A carbonate units,60 to 98 mol % of the arylate ester units of formula (5) wherein u is zero, andoptionally, 1 to 20 mol % resorcinol carbonate units, isophthalic acid-terephthalic acid-bisphenol A ester phthalate units, or a combination thereof.7. The polycarbonate article of claim 1 , wherein the poly(carbonate-bisphenol arylate ester) composition has one or more of the ...

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Номер записи: 56
05-03-2020 дата публикации

HALOGEN-FREE LOW DIELECTRIC RESIN COMPOSITION, AND PRE-PREG, METAL-CLAD LAMINATE, AND PRINTED CIRCUIT BOARD USING THE SAME

Номер: US20200071477A1
Автор: CHEN Meng-Huei, HUNG Chin-Hsien, LIU Shur-Fen
Принадлежит:

A halogen-free low dielectric resin composition is provided. The halogen-free low dielectric resin composition includes: 2. The halogen-free low dielectric resin composition of claim 1 , further comprising a reactive phosphorus compound having an unsaturated functional group.3. The halogen-free low dielectric resin composition of claim 2 , wherein the weight ratio of the phosphorus-containing compound (C) represented by formula (I) to the reactive phosphorus compound is from 4:1 to 1:4.4. The halogen-free low dielectric resin composition of claim 2 , wherein the reative phosphorus compound is an allyl cyclophosphazene compound.6. The halogen-free low dielectric resin composition of claim 1 , wherein the cross-linking agent (B) is selected from the group consisting of a polyfunctional allylic compound claim 1 , a polyfunctional acrylate claim 1 , a polyfunctional acrylamide claim 1 , a polyfunctional styrenic compound claim 1 , a bismaleimide compound claim 1 , and combinations thereof.7. The halogen-free low dielectric resin composition of claim 1 , wherein the cross-linking agent (B) is selected from the group consisting of triallyl isocyanurate (TAIC) claim 1 , triallyl cyanurate (TAC) claim 1 , prepolymers thereof claim 1 , and combinations thereof.8. The halogen-free low dielectric resin composition of claim 1 , further comprising a phosphorus-containing additive flame retardant selected from the group consisting of a phosphinate salt claim 1 , a polyphosphate salt claim 1 , a phosphonium salt claim 1 , a phosphate ester claim 1 , a phosphazene claim 1 , a phosphite ester claim 1 , a phosphine oxide claim 1 , and combinations thereof.9. The halogen-free low dielectric resin composition of claim 1 , further comprising a vinyl-containing elastomer.10. The halogen-free low dielectric resin composition of claim 9 , wherein the vinyl-containing elastomer is selected from the group consisting of polybutadiene claim 9 , styrene-butadiene (SB) copolymer claim 9 , ...

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Номер записи: 57
18-03-2021 дата публикации

RESIN COMPOSITION, PREPREG, FILM INCLUDING RESIN, METAL FOIL INCLUDING RESIN, METAL-CLAD LAMINATE, AND WIRING BOARD

Номер: US20210079215A1
Автор: Araki Shunji, ARISAWA TATSUYA, GOTO Hirohisa, INOUE YUKI, Suzuki Fumito
Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

Provided is a resin composition containing: a modified polyphenylene ether compound terminally modified with a substituent having an unsaturated carbon-carbon double bond; a cross-linking curing agent having an unsaturated carbon-carbon double bond in its molecule; a silane coupling agent having a phenylamino group in its molecule; and silica. A content of the silica is 60 to 250 parts by mass with respect to a total of 100 parts by mass of the modified polyphenylene ether compound and the cross-linking curing agent. 1. A resin composition comprising:a modified polyphenylene ether compound terminally modified with a substituent having an unsaturated carbon-carbon double bond;a cross-linking curing agent having an unsaturated carbon-carbon double bond in its molecule;a silane coupling agent having a phenylamino group in its molecule; andsilica,wherein a content of the silica is 60 to 250 parts by mass with respect to a total of 100 parts by mass of the modified polyphenylene ether compound and the cross-linking curing agent.2. The resin composition according to claim 1 , wherein a content of the silane coupling agent is 0.3 to 5 parts by mass with respect to 100 parts by mass of the silica.3. The resin composition according to claim 1 , further comprising a flame retardant claim 1 , whereinthe flame retardant contains a compatible phosphorus compound that is compatible with a mixture of the modified polyphenylene ether compound and the cross-linking curing agent, and an incompatible phosphorus compound that is incompatible with the mixture.4. The resin composition according to claim 3 , wherein a content of the compatible phosphorus compound is 3 to 19% by mass with respect to a total content of the compatible phosphorus compound and the incompatible phosphorus compound.5. The resin composition according to claim 3 , wherein the compatible phosphorus compound contains a phosphazene compound.6. The resin composition according to claim 1 , wherein the substituent ...

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Номер записи: 58
14-03-2019 дата публикации

FLAME-RETARDANT POLYCARBONATE-POLYESTER COMPOSITIONS

Номер: US20190077953A1
Автор: ECKEL Thomas, Hufen Ralf, JUNG Mathieu
Принадлежит:

Compositions comprising 2. The composition as claimed in claim 1 , characterized in that the proportions of the components are as followsA) 40 to 98 parts by weightB) 1 to 60 parts by weightC) 1 to 20 parts by weightD) 0 to 20 parts by weightE) 0 to 20 parts by weight 'and wherein the sum of the parts by weight of the composition is normalized to 100.', 'F) 0 to 30 parts by weight'}3. The composition as claimed in any of the preceding claims claim 1 , characterized in that the proportions of the components are as followsA) 50 to 85 parts by weightB) 5 to 45 parts by weightC) 3 to 12 parts by weightD) 0 to 10 parts by weightE) 0 to 10 parts by weight 'and wherein the sum of the parts by weight of the composition is normalized to 100.', 'F) 0.2 to 10 parts by weight'}4. The composition as claimed in any of the preceding claims claim 1 , characterized in that the polyester is derived from aliphatic or aromatic diols and as the dicarboxylic acid only from succinic acid.5. The composition as claimed in claim 4 , characterized in that the diols are aliphatic.6. The composition as claimed in claim 5 , characterized in that the diol is butanediol.7. The composition as claimed in any of the preceding claims claim 5 , characterized in that k is a whole number from 1 to 5.8. The composition as claimed in any of the preceding claims claim 5 , characterized in that the proportion of the trimers (k=1) is from 50 to 98 mol % of the component C.9. The composition as claimed in any of the preceding claims claim 5 , characterized in that the proportion of the trimers (k=1) is from 70 to 85 mol % of the component C.10. The composition as claimed in any of the preceding claims claim 5 , characterized in that the component C is selected from the group comprising propoxyphosphazenes claim 5 , phenoxyphosphazenes claim 5 , methylphenoxyphosphazenes claim 5 , aminophosphazenes and fluoralkylphosphazenes.11. The composition as claimed in any of the preceding claims claim 5 , characterized ...

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Номер записи: 59
23-03-2017 дата публикации

DOPO-Based Hybrid Flame Retardants

Номер: US20170081590A1
Автор: BOMMER Lea, BUCZKO Aleksandra, GAAN Sabyasachi, STELZIG Timea
Принадлежит: EMPA EIDGENOSSISCHE MATERIAL-PRUFUNGS- UND FORSCHUNGSANSTALT

The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: Rand Rare independently hydrogen, C-Calkyl, —P(O)(OR), —P(O)ORR, or —P(O)R, wherein Rand Rare independently C-Calkyl, C-Caryl, C-Caralkyl or C-Calkaryl; or Rand Rtaken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C-Calkylene, Carylene, C-Caralkylene, C-Calkarylene, oxygen (O), nitrogen (NR), wherein R is H or C-Calkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C-Calkylene, Carylene, C-Caralkylene or C-Cis alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C-Calkylene; t is an integer from 1 to 2; W is oxygen (O) or sulphur (S). The compounds are particularly suited as flame retardant additives for thermoplastic polyesters. 2. A flame retardant compound according to claim 1 , selected from the group consisting of:DOPO-PEPA, andDOPS-PEPA.3. A polymeric material with improved flame resistance claim 1 , comprising at least one thermoplastic polymer resin claim 1 , at least one flame retardant compound according to or claim 1 , and optionally any conventional additives.4. The polymeric material according to claim 3 , wherein the thermoplastic polymer resin is a thermoplastic polyester resin.5. The polymeric material according to or claim 3 , further comprising a nitrogen based flame retardant agent claim 3 , as a second flame retardant component.6. The polymeric material according to one of to claim 3 , in the form of granules or in moulded form.7. The polymeric material according to claim 6 , wherein the total content of the flame retardant component (I) is 14% to 30% by weight of the total weight of the ...

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Номер записи: 60
31-03-2022 дата публикации

DUAL-MEDIATED POLYMERIZABLE COMPOSITE FOR ADDITIVE MANUFACTURING

Номер: US20220098335A1
Автор: Dubov Aleksei, Ivanova Anna, Korshikov Vasily, Kovalev Igor, Solonitsyn Slava, Starodubtsev Dmitry, Trushina Anna
Принадлежит:

A formulation for a photopolymer composite material for a 3D printing system includes an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator. In the formulation the acrylate monomer or the acrylate oligomer may be between about 10.0-30.0 w % of the formulation. The thermal initiator may be between about 0.001-0.05 w %, the co-initiator may be between about 0.001-0.05 w %, and the UV initiator may be between about 0.001-0.2 w % of the formulation. A method of generating a formulation of a photopolymer composite material for use in a 3D printing system includes using an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator. 1. A method of generating a large-scale three-dimensional (3D) printed structure , the method comprising:generating a resin premix by blending a formulation of an acrylate monomer, acrylate oligomer, an ultraviolet (UV) initiator, an inorganic hydrate, a co-initiator, and a reinforcing filler through operation of a mixing system for a first amount of time, the mixing system comprising a blender;combining a thermal initiator with the resin premix; andgenerating a photopolymer composite resin by blending the thermal initiator and the resin premix through operation of the blender for a second amount of time;extruding the photopolymer composite resin via a 3D printing system; andapplying a UV LED light source to the extruded photopolymer composite to initiate the hardening of the photopolymer composite by activating the thermal reaction.2. The method of claim 1 , wherein the an acrylate monomer and an acrylate oligomer are in the range between about 10.0-30.0 w % of the formulation claim 1 , the UV initiator is in the range between about 0.001-0.2 w % of the formulation claim 1 , the co-initiator in the range between about 0.001-0.05 w of the ...

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Номер записи: 61
31-03-2016 дата публикации

FLAME RETARDANT, FLAME RETARDANT COMPOSITION, AND MOLDED PRODUCT AND MANUFACTURING METHOD THEREOF

Номер: US20160090468A1
Автор: Chen Chiung-Ta, Chien Ming-Yang, Lin Chih-Wei, LIN Liang, Tsay Maw-Der, Tu Kuan-Ju, Wang En-Ching
Принадлежит:

The invention provides a flame retardant, a flame retardant composition, and a molded product and a manufacturing method thereof. The flame retardant has a structure shown in formula (1): 2. The flame retardant of claim 1 , wherein in formula (1) claim 1 , Y claim 1 , Y claim 1 , and Yeach independently represent an oxygen atom; R claim 1 , R claim 1 , and Reach independently represent a Cto Calkyl group claim 1 , a phenyl group claim 1 , or a phenyl group in which an arbitrary hydrogen atom is substituted by an alkyl group or a nitro group.4. A flame retardant composition claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the flame retardant of ; and'}a polymer.5. The flame retardant composition of claim 4 , wherein based on 100 parts by weight of the flame retardant composition claim 4 , a content of the polymer is 65 parts by weight to 90 parts by weight claim 4 , and a content of the flame retardant is greater than 5 parts by weight and less than or equal to 35 parts by weight.6. The flame retardant composition of claim 4 , wherein the polymer comprises an acrylonitrile-butadiene-styrene copolymer claim 4 , thermoplastic polyurethane claim 4 , polyethylene claim 4 , polypropylene claim 4 , polystyrene claim 4 , polymethyl methacrylate claim 4 , polyvinyl chloride claim 4 , nylon claim 4 , polycarbonate claim 4 , polyurethane claim 4 , polyoxymethylene claim 4 , polytetrafluoroethylene claim 4 , polyethylene terephthalate claim 4 , polyisoprene claim 4 , styrene-butadiene rubber claim 4 , butyl rubber claim 4 , polybutadiene rubber claim 4 , chloroprene rubber claim 4 , ethylene propylene diene monomer claim 4 , polyacrylate rubber claim 4 , urethane rubber claim 4 , silicone rubber claim 4 , fluorinated rubber claim 4 , or a combination thereof.7. The flame retardant composition of claim 4 , further comprising an antioxidant claim 4 , a heat stabilizer claim 4 , a UV absorber claim 4 , a light stabilizer claim 4 , a colorant claim 4 , or a ...

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Номер записи: 62
21-03-2019 дата публикации

FLAME RETARDANT ADDITIVE FOR A LOW SMOKE, ZERO HALOGEN COMPOUND

Номер: US20190085154A1
Автор: Jiang Dayue, Vasilakos Kevin Andrew
Принадлежит:

A low smoke, zero halogen (LSZH) polymer composition is provided. The LSZH polymer composition includes a polymer resin, and a flame retardant package dispersed within the polymer resin. Less than 25% by weight of the polymer composition is the flame retardant package. The flame retardant package includes an acid source, a carbon source, and an LSZH additive. The LSZH additive includes a polyoxometalate ionic liquid and a synergist carrier. The LSZH polymer composition has a limiting oxygen index of greater than 31%. The LSZH polymer compound is suitable for use in electrical or tele-communication cables. 1. A low smoke , zero halogen (LSZH) polymer composition , comprising:a polymer resin; and an acid source;', 'a carbon source; and', a polyoxometalate ionic liquid; and', 'a synergist carrier,, 'an LSZH additive, comprising, 'wherein the LSZH polymer composition has a limiting oxygen index of greater than 31%., 'a flame retardant package dispersed within the polymer resin, wherein less than 25% by weight of the polymer composition is the flame retardant package and wherein the flame retardant package comprises2. The LSZH polymer composition of claim 1 , wherein the polyoxometalate ionic liquid is formed from an ionic liquid selected from the group consisting of 1-ethyl-3-methyl-imidazolium ethylsulfate claim 1 , 1-butyl-3-methylimidazolium hexafluorophosphate claim 1 , 1-butyl-3-methylimidazolium tetrafluoroborate claim 1 , 1-hexyl-3-methylimidazolium hexafluorophosphate claim 1 , 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide claim 1 , 1-ethyl-3-methylimidazolium trifluoromethanesulfonate claim 1 , scandium(III) trifluoromethanesulfonate claim 1 , praseodymium (III) trifluoromethanesulfonate claim 1 , 1 claim 1 ,3-dialkyl-1 claim 1 ,2 claim 1 ,3-triazolium hexafluorophosphate claim 1 , 1 claim 1 ,3-dialkyl-1 claim 1 ,2 claim 1 ,3-triazolium bis(trifluoromethanesulfonyl)imide claim 1 , 1 claim 1 ,2 claim 1 ,4-trimethylpyrazolium methylsulfate claim ...

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Номер записи: 63
30-03-2017 дата публикации

PHOSPHORUS-CONTAINING POLYPHENYLENE OXIDE RESIN, ITS PREPARATION METHOD, METHOD FOR PREPARING PREPOLYMER OF PHOSPHORUS-CONTAINING POLYPHENYLENE OXIDE, RESIN COMPOSITION AND ITS APPLICATION

Номер: US20170088669A1
Автор: HSIEH CHEN-YU, LEE Tse-An, SHIH Hui-Ting
Принадлежит:

The present invention relates to a phosphorus-containing polyphenylene oxide resin, its preparation method, a method for preparing the prepolymer of the phosphorus-containing polyphenylene oxide, a resin composition and an article thereof, wherein the phosphorus-containing polyphenylene oxide resin has a chemical structure represented by the following formula (I): 2. The phosphorus-containing polyphenylene oxide resin of claim 1 , wherein A is a covalent bond claim 1 , —CH— claim 1 , —CH(CH)— claim 1 , —C(CH)— or carbonyl; b is a positive integer of 1 to 5; each of m and n independently represents a positive integer of 1 to 10; each of Q and W independently represents an aliphatic group having a carbon number of 1 to 3.5. A method for preparing a phosphorus-containing polyphenylene oxide resin claim 1 , comprising:reacting a di(chloromethyl) compound with dihydroxyl polyphenylene oxide to obtain a first intermediate product; and{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'reacting the first intermediate product with a phosphorus-containing compound to obtain the phosphorus-containing polyphenylene oxide resin of .'}6. The method of claim 5 , wherein the method comprises reacting the di(chloromethyl) compound with dihydroxyl polyphenylene oxide in the presence of a phase transfer catalyst to obtain a first intermediate product claim 5 , reacting the first intermediate product with a phosphorus-containing compound in an alkaline condition to obtain the phosphorus-containing polyphenylene oxide resin; wherein the di(chloromethyl) compound is di(chloromethyl)benzene claim 5 , di(chloromethyl) biphenyl claim 5 , di(chloromethyl)ether or a combination thereof; the phosphorus-containing compound is 2-(10H-9-oxa-10-phospha-1-phenanthryl)hydroquinone phosphorus oxide claim 5 , 2-(10H-9-oxa-10-phospha-1-phenanthryl)naphthoquinone phosphorus oxide claim 5 , or 2-(diphenylphosphinyl) hydroquinoneor2-(diphenylphosphinyl)naphthoquinone; the phase transfer catalyst is ...

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Номер записи: 64
05-05-2022 дата публикации

MULTILAYER COMPOSITE MATERIAL CONTAINING SPECIAL POLYCARBONATE COMPOSITIONS AS A MATRIX MATERIAL

Номер: US20220135754A1
Автор: Bauer John, BOUMANS Anke, Heuer Helmut Werner, Wehrmann Rolf
Принадлежит:

The present invention relates to a composite material comprising one or more fibre layers composed of a fibre material and an aromatic polycarbonate-based matrix material. The fibre layer(s) is/are embedded in the matrix material. The present invention further relates to a process for producing these fibre composite materials, to multilayer composite materials comprising several layers of fibre composite material, and to the use of the composite materials for production of components or housing components or housings, and to the components, housing components or housings themselves.

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Номер записи: 65
05-05-2022 дата публикации

Phosphonite compounds as process stabilizers

Номер: US20220135771A1
Автор: Damien BISSESSAR, Pascal Steffanut, Stephane Bellemin-Laponnaz, Thierry ACHARD
Принадлежит: CLARIANT INTERNATIONAL LTD

The present invention relates to a composition comprising one or more (co)polymers and one or more phosphonite compounds that contain cardanol moieties. Moreover, the present invention also refers to the use of the phosphonite compounds as process stabilizers, in particular refers to the use of such compounds for stabilizing and/or reducing the Yellowness Index of a (co)polymer composition exposed to heat and/or mechanical stress.

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Номер записи: 66
19-06-2014 дата публикации

POLYOLEFIN RESIN FOAM PARTICLES AND IN-MOLD FOAMING MOLDED BODY OF SAME

Номер: US20140171534A1
Автор: Fukuzawa Jun
Принадлежит: KANEKA CORPORATION

In order to obtain a flame-retardant polyolefin resin expanding molded product which has excellent in-mold moldability and excellent surface appearance and satisfies the FMVSS flammability even if carbon black is added, polyolefin resin particles containing, with respect to 100 parts by weight of polyolefin resin, (i) 0.03 part by weight to 5 parts by weight of phosphorous flame retardant having a phosphorous content of 7% by weight or more, a melting point of 120° C. or more, and a 5% by weight decomposition temperature within a range of 240° C. to 320° C. and (ii) 0.5 part by weight to 20 parts by weight of carbon black are expanded. 1. Polyolefin resin expanded particles , obtainable by expanding polyolefin resin particles which contains , with respect to 100 parts by weight of polyolefin resin , (i) 0.03 part by weight to 5 parts by weight of a phosphorous flame retardant having a phosphorous content of 7% by weight or more , a melting point of 120° C. or more , and a 5% by weight decomposition temperature within a range of 240° C. to 320° C. and (ii) 0.5 part by weight to 20 parts by weight of carbon black.2. Polyolefin resin expanded particles as set forth in claim 1 ,wherein the phosphorous flame retardant having the phosphorous content of 7% by weight or more, the melting point of 120° C. or more, and the 5% by weight decomposition temperature within the range of 240° C. to 320° C. is a triphenyl phosphine oxide or 2-diphenyl phosphonyl hydroquinone.3. Polyolefin resin expanded particles as set forth in claim 1 ,wherein diameters of particles of the carbon black in the polyolefin resin expanded particles fall within a range of 20 nm to 100 nm.4. Polyolefin resin expanded particles as set forth in claim 1 ,wherein the polyolefin resin expanded particles contain 0.01 part by weight to 0.2 part by weight of a sterically hindered amine ether flame retardant as another flame retardant.5. Polyolefin resin expanded particles as set forth in claim 1 ,wherein the ...

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Номер записи: 67
01-04-2021 дата публикации

PHOTOCURABLE HARDCOAT COMPOSITIONS, METHODS, AND ARTICLES DERIVED THEREFROM

Номер: US20210095133A1
Автор: HALL Thomas N., Jones, JR. Charles E., JR. Mervin G., SITZMANN Eugene V., TAHIR Zulfiqar A., Wood, YU Ziniu
Принадлежит:

A photocurable hardcoat composition includes certain red-shifted ultraviolet light absorbers (UVA) that include a combination of a-hydroxy ketone and bisacylphosphine oxide photoinitiators. 4. The composition of claim 1 , wherein:{'sub': '1', 'Ris hydrogen, straight or branched chain alkyl of 1 to 12 carbon atoms or phenylalkyl of 7 to 15 carbon atoms;'}{'sub': '2', 'Ris straight or branched chain alkyl of 1 to 12 carbon atoms or phenylalkyl of 7 to 15 carbon atoms, phenyl, or the phenyl or the phenylalkyl substituted on the phenyl ring by 1 to 3 alkyl of 1 to 4 carbon atoms;'}{'sub': 5', '6, 'Rand Rare hydrogen or one of both is Cl or Br;'}{'sub': 7', '8, 'Rand Rare independently hydrogen, Cl or Br;'}{'sub': '1', 'X is O or NE;'}{'sub': 1', '1', '6', '3', '7', '9, 'Eis hydrogen, straight or branched chain C-Calkyl, which is unsubstituted or substituted by 1 to 4 OH, phenyl which is unsubstituted or substituted by F, CF, CN or Cl, or C-Cphenylalkyl.'}5. The composition of claim 1 , wherein the red-shifted hydroxyphenylbenzotriazoles are of Formula (I).7. The composition of comprising the red-shifted UV absorber of Formula III which is 2 claim 1 ,4-bis(2-hydroxy-4-n-butyloxyphenyl)-6-(2 claim 1 ,4-di-n-butyloxyphenyl)-s-triazine; 2 claim 1 ,4 claim 1 ,6-tris(2-hydroxy-4-isooctyloxycarbonylisopropylideneoxyphenyl)-s-triazine; 2 claim 1 ,4 claim 1 ,6-tris[2-hydroxy-4-(3-sec-butyloxy-2-hydroxypropyloxy)phenyl]-1 claim 1 ,3 claim 1 ,5-triazine; 2-(2 claim 1 ,4dihydroxyphenyl)-4 claim 1 ,6-bis(2-hydroxy-4(1-methoxycarbonylpentoxy)phenyl)-1 claim 1 ,3 claim 1 ,5-triazine; 2 claim 1 ,4 claim 1 ,6-tris(2-hydroxy-4-(1-methoxycarbonyl-pentoxy)phenyl)-1 claim 1 ,3 claim 1 ,5triazine; 2-(2 claim 1 ,4-di(methoxycarbonylpentoxy)phenyl)-4 claim 1 ,6-bis(2-hydroxy-4-(1-methoxycarbonylpentoxy)phenyl)-1 claim 1 ,3 claim 1 ,5-triazine; 2-(2 claim 1 ,4-dihydroxyphenyl)-4 claim 1 ,6-bis-(2-hydroxy-4-(1-hydroxycarbonylpentoxy)phenyl)-1 claim 1 ,3 claim 1 ,5-triazine; 2 claim 1 ,4 claim 1 ...

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Номер записи: 68
12-05-2022 дата публикации

ENERGY-SENSITIVE COMPOSITION, CURED PRODUCT, AND FORMING METHOD OF CURED PRODUCT

Номер: US20220145011A1
Автор: Chisaka Hiroki, Noda Kunihiro, Shiota Dai, SOMEYA Kazuya
Принадлежит:

An energy-sensitive composition that yields a cured product with excellent thermal resistance and crack resistance, a cured product of the composition, and a method of forming a cured product. The energy-sensitive composition includes a polysilane and a thermal base generator, in which the thermal base generator includes an ionic compound and a nonionic compound. An anion moiety in the ionic compound preferably includes at least one of an anion having an oxaxanthone skeleton, an anion having a ketoprofen skeleton, and an anion having a fluorenone skeleton. 1. An energy-sensitive composition comprising a polysilane (A) and a thermal base generator (B) , wherein the thermal base generator (B) comprises an ionic compound (B1) , and a nonionic compound (B2).2. The energy-sensitive composition according to claim 1 , wherein an anion moiety in the ionic compound (B1) comprises at least one anion selected from the group consisting of an anion having an oxaxanthone skeleton claim 1 , an anion having a ketoprofen skeleton claim 1 , and an anion having a fluorenone skeleton.3. The energy-sensitive composition according to claim 2 , wherein a cation moiety in the ionic compound (B1) comprises at least one cation selected from the group consisting of a phosphazene compound cation and an amidine compound cation.6. The energy-sensitive composition according to claim 1 , wherein a proportion of a mass of the ionic compound (B1) is 10% by mass or more and 95% by mass or less claim 1 , based on a sum of the mass of the ionic compound (B1) and a mass of the nonionic compound (B2).7. A cured product of the energy-sensitive composition according to .8. A method for forming a cured product claim 1 , comprising applying the energy-sensitive composition according to onto a substrate to form a coating film claim 1 , and heating the coating film for curing. This application claims priority to Japanese Patent Application No. 2020-185799, filed Nov. 6, 2020, the entire content of which is ...

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Номер записи: 69
02-06-2022 дата публикации

THERMOSETTING COATING COMPOSITION AND COATED ARTICLE

Номер: US20220169883A1
Автор: OGASAWARA Mutsumi, YAMASHITA Fumio
Принадлежит: KANSAI PAINT CO., LTD.

A thermosetting coating composition includes a hydroxyl group-containing resin, a curing agent, a phosphazene compound, and a solvent. The curing agent is a polyisocyanate curing agent and/or a blocked polyisocyanate curing agent. 1. A thermosetting coating composition , comprising:a hydroxyl group-containing resin;a curing agent;a phosphazene compound; anda solvent,wherein the curing agent is a polyisocyanate curing agent and/or a blocked polyisocyanate curing agent.2. The thermosetting coating composition according to claim 1 , wherein the phosphazene compound has a number average molecular weight of 400 or more.3. The thermosetting coating composition according to claim 1 , wherein the content of the phosphazene compound is 0.1 parts by mass or more and 30 parts by mass or less based on 100 parts by mass of resin solids of the thermosetting coating composition.4. The thermosetting coating composition according to claim 1 , wherein the hydroxyl group-containing resin is at least one selected from the group consisting of an acrylic resin claim 1 , a polyester resin claim 1 , and an epoxy resin.5. The thermosetting coating composition according to claim 1 , wherein the solvent is water claim 1 , and the solvent is contained in the thermosetting coating composition in an amount of 70% by mass or more based on the total mass of the thermosetting coating composition.6. The thermosetting coating composition according to claim 5 , wherein the hydroxyl group-containing resin is water dispersible or water dissoluble.7. A coated article obtained by applying the thermosetting coating composition according to to an article to be coated.8. A coated article claim 1 , comprising a multilayer coating film obtained by applying the thermosetting coating composition according to to an article to be coated; and applying a top coat composition to the article to be coated. The present disclosure relates to a thermosetting coating composition and a coated article.Isocyanate curing ...

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Номер записи: 70
29-04-2021 дата публикации

HIGH PERFORMANCE AND RECYCLABLE THERMOSET INK FOR 3D OR 4D PRINTING

Номер: US20210122865A1
Автор: LI Ang, Li Guoqiang
Принадлежит: Board of Supervisors of Louisiana State University and Agricultural and Mechanical College

A UV-curable and recyclable thermoset shape memory polymer is provided. The polymer includes a vitrimer-based monomer and a photoinitiator. The vitrimer-based monomer includes a first unit rendering a high chain stiffness upon polymerization of the monomer, and a second photopolymerizable unit for photopolymerization of the monomer under a UV irradiation. The polymer has high strength, high stiffness, high recovery stress, high energy storage, reasonable recycling efficiency, and is printable using SLA with high resolution. 1. A UV-curable and recyclable thermoset shape memory polymer comprising:a vitrimer-based monomer; anda photoinitiatorwherein the vitrimer-based monomer comprises a first unit rendering a high chain stiffness upon polymerization of the monomer; and a second unit comprising a photopolymerizable unit for photopolymerization of the monomer under a UV irradiation.2. The polymer of claim 1 , wherein the first unit rendering a high chain stiffness comprises a bisphenol A unit.3. The polymer of claim 1 , wherein the photopolymerizable unit comprises an acrylate claim 1 , a methacrylate claim 1 , epoxide claim 1 , thiol claim 1 , thiol and alkene claim 1 , thiol and alkyne claim 1 , thiol and acrylate/methacrylate.4. The polymer of claim 1 , wherein the vitrimer-based monomer is a bisphenol A glycerolate dimethacrylate (BPAGMA) monomer.5. The polymer of claim 1 , wherein the photoinitiator comprises 2-hydroxy-4′-(2-hydroxyethoxy)-2-methylpropiophenone.6. The polymer of claim 5 , wherein the 2-hydroxy-4′-(2-hydroxyethoxy)-2-methylpropiophenone is present in the polymer in an amount of about 3 wt %.7. The polymer of claim 4 , wherein the photoinitiator comprises 2-Hydroxy-2-methyl-1-phenyl-propan-1-one.8. The polymer of claim 7 , wherein the 2-Hydroxy-2-methyl-1-phenyl-propan-1-one is present in the polymer in an amount of about 3.5 wt %.9. The polymer of claim 8 , further comprising Bis(2 claim 8 ,4 claim 8 ,6-trimethylbenzoyl)-phenylphosphineoxide.10. ...

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Номер записи: 71
02-04-2020 дата публикации

COMPOSITIONS USEFUL FOR FORMING SOFT TOUCH COATINGS

Номер: US20200102472A1
Автор: GUPTA Manjuli, Klang Jeffrey A., SPAGNOLA Lisa Marie, WOLF William C.
Принадлежит:

“Soft feel” coatings are obtained by curing a coating composition containing a) at least one (meth)acrylate-functionalized oxetane/oxolane oligomer such as a (meth)acrylate-functionalized polytetramethylene ether, b) at least one radiation-curable compound (other than (meth)acrylate-functionalized oxetane/oxolane oligomer) and c) at least one surface conditioner additive selected from the group consisting of particulate surface modification agents and slip additives. As a consequence of containing (meth)acrylate-functionalized oxetane/oxolane oligomer, the coating composition has advantageously low viscosity and yet is capable of providing a cured coating having excellent haptic properties. 1. A coating composition useful for forming a soft touch coating on a surface of a substrate , wherein the coating composition comprises:a) at least one (meth)acrylate-functionalized oxetane/oxolane oligomer selected from the group consisting of (meth)acrylate-functionalized polytrimethylene ethers, (meth)acrylate-functionalized polytetramethylene ethers, (meth)acrylate-functionalized poly-co-tetramethylene-trimethylene ethers;b) at least one radiation-curable compound other than (meth)acrylate-functionalized oxetane/oxolane oligomer; andc) at least one surface conditioner additive selected from the group consisting of slip additives and particulate surface modification agentsd) optionally, at least one photoinitiator, said photoinitiator d) being either one photoinitiator which absorbs both long and short wavelength ultraviolet radiation or said photoinitiator d) is comprising a first photoinitiator which absorbs long wavelength ultraviolet radiation and a second photoinitiator which absorbs short wavelength ultraviolet radiation.2. The coating composition of claim 1 , wherein the coating composition comprises at least one photoinitiator d).3. The coating composition of claim 1 , wherein the at least one (meth)acrylate-functionalized oxetane/oxolane oligomer a) is a di(meth) ...

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Номер записи: 72
18-04-2019 дата публикации

IMPACT RESISTANT CYCLIC PHOSPHAZENES

Номер: US20190112452A1
Автор: Kobilka Brandon M., Kuczynski Joseph, PORTER Jacob T., Wertz Jason T.
Принадлежит:

impact-modified composition and a method of making an impact-modified composition are provided. In an embodiment, the method includes reacting a phosphazene material with an acrylamide material to form a functionalized phosphazene material; initiating a polymerization reaction on a reaction mixture comprising the functionalized phosphazene material and one or more monomers to form an impact-modified phosphazene material; and adding the an impact-modified phosphazene material to a polymeric material. 2. The composition of claim 1 , wherein the vinyl polymer comprises an acrylate monomer claim 1 , acrylamide monomer claim 1 , styrenic monomer claim 1 , other vinylic monomer claim 1 , or a combination thereof.4. The composition of claim 1 , wherein the vinyl polymer is 1 to 40 wt % of the composition.5. The composition of claim 1 , further comprising a polymeric material.6. The composition of claim 5 , wherein the polymeric material includes a polylactic acid (PLA) homopolymer or a blend that includes a PLA polymer and a polycarbonate (PC) polymer.7. A method of forming an impact-modified phosphazene material comprising:reacting a phosphazene material with a acrylamide material to form a functionalized phosphazene material; andinitiating a polymerization reaction on a reaction mixture comprising the functionalized phosphazene material and one or more monomers to form an impact-modified phosphazene material.8. The method of claim 7 , wherein the polymerization reaction comprises adding an ultraviolet initiator claim 7 , a thermal initiator claim 7 , or a radical polymerization initiator.9. The method of claim 7 , further comprising heating a second reaction mixture comprising the impact-modified phosphazene material.10. The method of claim 7 , wherein the one or more monomers are selected from the group consisting of an acrylate monomer material claim 7 , acrylamide monomer material claim 7 , styrenic monomer material claim 7 , other vinylic monomer material claim 7 , ...

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Номер записи: 73
13-05-2021 дата публикации

Novel Triazine Compounds, Compositions, and Methods

Номер: US20210139673A1
Автор: Lee Arthur, Lee Duk Hi
Принадлежит:

Trisubstituted triazines having the formula: 26. A flame retardant claim 1 , epoxy and/or cyclic carbonate curing composition of matter comprising a compound of and a carrier or solvent therefor.27. A composition of matter comprising a curable epoxy and a flame retardant claim 26 , epoxy curing amount of a composition of .28. A composition of matter comprising a curable cyclic carbonate and a flame retardant claim 26 , cyclic carbonate curing amount of a composition of claim 26 , wherein Y is CH—NH.29. A method of curing an epoxy comprising admixing therewith a flame retardant claim 27 , epoxy curing amount of a composition of .30. A method of curing a cyclic carbonate comprising admixing therewith a flame retardant claim 28 , cyclic carbonate curing amount of a composition of .31. An article of manufacture comprising packaging material containing the composition of claim 26 , said packaging material containing instructions for the use thereof. The invention relates to novel trisubstituted triazines, and their uses as epoxy and cyclic carbonate curing agents.An embodiment of the invention relates to compounds having the formula:wherein:Y is OH, NHor CHNH,when Q is P, R is phenyl, when Q is P═O, Z is R or OR, and R is alky or phenyl, when Q is CH, Z is PO(R)or PO(OR), and when Q is N, Z is R.An additional embodiment of the invention is directed to methods for curing epoxy and/or cyclic carbonates employing the above compounds as curing agents.Still further embodiments of the invention relate toThe present invention is predicated on the unexpected discovery that certain novel tri-substituted triazines function as curing agents for epoxy and/or cyclic carbonates while also providing significant flame-retardant properties thereto.Exemplary compounds of the invention described by the above generic formula include, but are not limited to:The compounds of the invention may be synthesized according to the reaction schemes set forth in . Referring to , the reaction of 1 and ...

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Номер записи: 74
09-04-2020 дата публикации

UV CURABLE SILICONE TERMINAL SEALANT

Номер: US20200109285A1
Автор: Chen Qi, Fang Lei, Wei Peng, Zhao Yi
Принадлежит:

A UV curable silicone composition, comprising: A) an alkenyl-containing organopolysiloxane that has at least two alkenyl groups in each molecule, at least one alkenyl group on each terminus; B) a photoinitiator; C) a mercapto-functional organopolysiloxane that comprises 2 or more mercapto groups per molecule; D) a pigment; and one or both of E) and F), where E) is a silica and F) is a solvent comprising a organopolysiloxane having ≤12 silicon atoms. 1. A UV curable silicone composition , comprising:A) an alkenyl-containing organopolysiloxane that has at least two alkenyl groups in each molecule, at least one alkenyl group on each terminus;B) a photoinitiator;C) a mercapto-functional organopolysiloxane that comprises 2 or more mercapto groups per molecule;D) a pigment; andone or both of E) and F), where E) is a silica and F) is a solvent comprising a organopolysiloxane having ≤12 silicon atoms.2. The composition according to claim 1 , wherein the composition comprises both E) and F).3. The composition according to claim 1 , wherein the alkenyl-containing organopolysiloxane has a viscosity of up to 25000 cPs.4. The composition according to claim 1 , wherein the alkenyl-containing organopolysiloxane vinyldimethylsiloxy-terminated polydimethylsiloxane.5. The composition according to claim 1 , wherein the mercapto-functional organopolysiloxane is according to the following formula (I){'br': None, 'sup': 1', '1', '2', '1, 'sub': 3', '1/2', 'x', '2/2', 'y', '2', '2/2', 'x, '(I) [RSiO][R(HSR)SiO][RSiO],'}{'sup': 1', '2, 'wherein x, y, and z are all >0, each Rindependently is hydrocarbyl having from 1 to 8 carbon atoms, Ris hydrocarbylene having from 1 to 8 carbon atoms.'}6. The composition according to claim 5 , wherein Ris methyl and Ris propylene.7. The composition according to claim 1 , the composition comprises 20 to 40% (w/w) of the alkenyl containing organopolysiloxane.8. The composition according to claim 1 , wherein the silica is hexamethyldisilazane-treated fumed ...

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Номер записи: 75
05-05-2016 дата публикации

LOW DISSIPATION FACTOR RESIN COMPOSITION AND PRODUCT MADE THEREBY

Номер: US20160122521A1
Автор: GAO Yu, HSIEH CHEN-YU, JIA Ningning, LV Wenfeng, MA Ziqian, TIAN Wenjun, WANG Rongtao
Принадлежит:

A low dissipation factor resin composition comprises: (A) 100 to 150 parts by weight of a vinyl-containing compound or a polymer thereof; (B) 0 to 75 parts by weight of styrene-butadiene-divinylbenzene terpolymer, styrene-butadiene-maleic anhydride terpolymer, vinyl functional polybutadiene urethane oligomer or a combination thereof; (C) 30 to 150 parts by weight of flame retardant; and (D) 0.1 to 10 parts by weight of peroxide. The resin composition and a product made thereby are applicable to a copper-clad laminate and a printed circuit board, characterized by having low dissipation factor at high frequency and satisfactory thermal resistance and thermal expansion. 1. A low dissipation factor resin composition , comprising the following components:(A) 100 to 150 parts by weight of a vinyl-containing compound or a polymer thereof;(B) 0 to 75 parts by weight of styrene-butadiene-divinylbenzene terpolymer, styrene-butadiene-maleic anhydride terpolymer, vinyl functional polybutadiene urethane oligomer or a combination thereof;(C) 30 to 150 parts by weight of flame retardant; and(D) 0.1 to 10 parts by weight of peroxide.2. The resin composition of claim 1 , wherein the vinyl-containing compound or a polymer thereof (A) is selected from maleimide claim 1 , divinylbenzene claim 1 , bis(vinylbenzyl) ether claim 1 , triallyl isocyanurate claim 1 , diallyl bisphenol A claim 1 , vinyl-containing polyphenylene oxide claim 1 , maleimide prepolymer claim 1 , vinyl-containing polymer with a number average molecular weight less than 1000 and a combination thereof.3. The resin composition of claim 2 , wherein the vinyl-containing polymer with a number average molecular weight less than 1000 is formed by a monomer selected from divinylbenzene claim 2 , bis(vinylbenzyl) ether claim 2 , triallyl isocyanurate claim 2 , diallyl bisphenol A claim 2 , styrene claim 2 , brominated styrene claim 2 , 2-propenoic acid-1 claim 2 ,1′-[(octahydro-4 claim 2 ,7-methano-1H-indene-5 claim 2 ,6-diyl ...

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Номер записи: 76
16-04-2020 дата публикации

FLAME RETARDANT TREATMENT OF POLYESTER BASED SYNTHETIC FIBER STRUCTURE

Номер: US20200115527A1
Автор: IWAKI Terufumu, KOYAMA Shigeto, Tada Yuji
Принадлежит:

The invention provides a flame retardant for a polyester based synthetic fiber structure comprising aminopentaphenoxycyclotriphosphazene, and a flame retardant treatment agent for a polyester based synthetic fiber structure comprising the flame retardant dispersed in a solvent in the presence of a surfactant. 2. A flame retardant treatment agent for a polyester based synthetic fiber structure comprising the flame retardant according to dispersed in a solvent in the presence of a surfactant.3. The flame retardant treatment agent for a polyester based synthetic fiber structure according to claim 2 , wherein the solvent is water.4. A polyester based synthetic fiber structure flame retarded with the flame retardant according to .5. A method for flame retardant treatment of a polyester based synthetic fiber structure comprising subjecting a polyester based synthetic fiber structure to flame retarding treatment with the flame retardant treatment agent according to .6. A method for flame retardant treatment of a polyester based synthetic fiber structure comprising providing a polyester based synthetic fiber structure with the flame retardant treatment agent according to claim 2 , drying claim 2 , and then heat treating at a temperature of 80 to 200° C.7. A polyester based synthetic fiber structure flame retarded by the method according to .8. A method for flame retardant treatment of a polyester based synthetic fiber structure comprising subjecting a polyester based synthetic fiber structure to flame retarding treatment with the flame retardant treatment agent according to .9. A method for flame retardant treatment of a polyester based synthetic fiber structure comprising providing a polyester based synthetic fiber structure with the flame retardant treatment agent according to claim 3 , drying claim 3 , and then heat treating at a temperature of 80 to 200° C.10. A polyester based synthetic fiber structure flame retarded by the method according to . The present invention ...

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Номер записи: 77
23-04-2020 дата публикации

THERMAL-CURABLE RESIN COMPOSITION, AND PRE-PREG, METAL-CLAD LAMINATE AND PRINTED CIRCUIT BOARD MANUFACTURED USING THE SAME

Номер: US20200123307A1
Автор: HUANG JU-MING, Liao Chih-Wei, TSENG Guan-Syun, YANG CHANG-CHIEN, Yu Chen-Hua
Принадлежит:

A thermal-curable resin composition is provided. The thermal-curable resin composition comprises: 1. A thermal-curable resin composition , comprising: (a1) a bismaleimide resin;', '(a2) a cyanate ester resin; and', '(a3) an epoxy resin,', 'wherein the cyanate ester resin (a2) and the epoxy resin (a3) are respectively in an amount ranging from 50 parts by weight to 150 parts by weight and from 24 parts by weight to 51 parts by weight per 100 parts by weight of the bismaleimide resin (a1); and, '(A) a thermal-curable resin component, which comprises(B) a filler,wherein the filler (B) is in an amount ranging from 40 parts by weight to 55 parts by weight per 100 parts by weight of the dry weight of the resin composition; andwherein the thermal-curable resin composition has a dynamic viscosity of not higher than 800 Pa·s after being brought into a semi-cured state (B-stage), and the thermal-curable resin composition has a dissipation factor (Df) of not higher than 0.006 at 10 GHz after being cured completely.4. The thermal-curable resin composition of claim 1 , wherein the cyanate ester resin (a2) is selected from the group consisting of 2 claim 1 ,2-bis(4-cyanooxyphenyl)propane claim 1 , 4 claim 1 ,4′-ethylidene bisphenylenecyanate claim 1 , 4 claim 1 ,4′-dicyanooxybiphenyl claim 1 , bis(4-cyanooxy-3 claim 1 ,5-dimethylphenyl)methane claim 1 , bis(4-cyanooxyphenyl) sulfide claim 1 , bis(4-cyanooxyphenyl) ether claim 1 , a prepolymer of bisphenol A dicyanate ester claim 1 , 1 claim 1 ,1-bis(4-cyanooxyphenyl)ethane claim 1 , 1 claim 1 ,1-bis(4-cyanooxyphenyl)methane claim 1 , 1 claim 1 ,3-bis(4-cyanooxyphenyl-1-(methylethylidene)) benzene claim 1 , bis(4-cyanooxyphenyl)-2 claim 1 ,2-butane claim 1 , 1 claim 1 ,3-bis[2-(4-cyanooxyphenyl)propyl]benzene claim 1 , tris(4-cyanooxy phenyl)ethane claim 1 , cyanated phenol claim 1 , an adduct of cyanated phenol dicyclopentadiene claim 1 , and combinations thereof.5. The thermal-curable resin composition of claim 4 , wherein the ...

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Номер записи: 78
19-05-2016 дата публикации

FLAME RETARDANT FIBRE-MATRIX SEMIFINISHED PRODUCTS

Номер: US20160137817A1
Автор: BIENMUELLER Matthias, ENDTNER JOCHEN, ENZ Matthias
Принадлежит:

Flame retardant fibre-matrix semifinished products include a polycarbonate as the thermoplastic matrix material and may be used in components subject to increased flame retardancy requirements, such as casing materials for electrical or electronic parts, IT equipment such as flatscreen monitors, notebooks, mobile telephones or tablet computers, fittings for shielding, inter alia, short-circuit induced arc flash in circuit breakers, and flame barriers in buildings, passenger vehicles, commercial vehicles and in shipping applications and in means of public transport. 4. The fibre-matrix product according to claim 1 , wherein R claim 1 , R claim 1 , Rand Rrepresent aryl and/or alkylaryl.5. The fibre-matrix product according to claim 1 , wherein component B comprises phosphazenes of formula (I) where a is an integer of 3 to 8.6. The fibre-matrix product according to claim 1 , wherein component B comprises phosphazenes of formula (II) where b is an integer of 3 to 1000.7. The fibre-matrix product according to claim 1 , further comprising claim 1 , in addition to the components A) and B) claim 1 , component C) 0.001 to 2 wt % of at least one thermal stabilizer from the group of aliphatically or aromatically substituted phosphites claim 1 , wherein at least one of the components A) or B) is to be varied within the scope of the specified ranges such that the sum of all percentages by weight for the components A) claim 1 , B) and C) based on the thermoplastic matrix ii) always amounts to 100.8. The fibre-matrix product according to claim 7 , wherein the molecular weight of the thermal stabilizer is greater than 650 g/mol.10. The fibre-matrix product according to claim 7 , wherein component C) is bis(2 claim 7 ,4-dicumylpheny)pentaerythritol diphosphite or tetrakis(2 claim 7 ,4-di-tert-butylphenyl)-1 claim 7 ,1-biphenyl-4 claim 7 ,4′-diylbisphosphonite.11. The fibre-matrix product according to claim 1 , wherein the thermoplastic matrix ii) further comprises claim 1 , in ...

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Номер записи: 79
03-06-2021 дата публикации

OLEFIN METATHESIS PHOTOPOLYMERS

Номер: US20210163676A1
Автор: BALASUBRAMANIAN Aditya, WEITEKAMP Raymond A.
Принадлежит:

Described herein are compositions and methods for processing photopolymers based on olefin metathesis. The compositions and methods comprise latent ruthenium complexes and photoacids and/or photoacid generators. 174-. (canceled)75. A method for generating a polymer , comprising:(a) providing a mixture comprising (i) a latent ruthenium (Ru) complex; (ii) an initiator that is an iodonium salt or a sulfonium salt; and (iii) at least one polymer precursor; and(b) exposing said mixture to electromagnetic radiation to activate said initiator, wherein upon activation, said initiator reacts with said latent Ru complex to generate an activated Ru complex, which activated Ru complex reacts with said at least one polymer precursor to generate at least a portion of said polymer.76. The method of claim 75 , wherein said electromagnetic radiation is emitted from a laser claim 75 , a digital light processing (DLP) projector claim 75 , a lamp claim 75 , a light emitting diode (LED) claim 75 , a mercury arc lamp claim 75 , a fiber optic claim 75 , or a liquid crystal display (LCD).77. The method of claim 75 , wherein said electromagnetic radiation is emitted at a wavelength of 350 nanometers (nm) to 465 nm.78. The method of claim 75 , wherein said mixture is exposed to said electromagnetic radiation from 100 millijoules (mJ)/centimeters(cm) to 1 claim 75 ,000 mJ/cm.79. The method of claim 75 , wherein said mixture further comprises a sensitizer that sensitizes said initiator.80. The method of claim 79 , wherein said sensitizer is configured to transfer or disperse the energy of electromagnetic radiation claim 79 , thereby sensitizing said initiator.81. The method of claim 79 , wherein said sensitizer is a conjugated aromatic molecule claim 79 , a phenothiazine claim 79 , a thioxanthone claim 79 , a coumarin claim 79 , an indoline claim 79 , a porphyrin claim 79 , a rhodamine claim 79 , a pyrylium claim 79 , a phenazine claim 79 , a phenoxazine claim 79 , an alpha hydroxy ketone ...

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Номер записи: 80
21-05-2015 дата публикации

PROCESS FOR THE PREPARATION OF TRIS(PERFLUOROALKYL)PHOSPHINE OXIDES AND BIS(PERFLUOROALKYL)PHOSPHINIC ACIDS

Номер: US20150141698A1
Автор: Frank Walter, Ignatyev Nikolai (Mykola), Koppe Karsten
Принадлежит: Merck Patent GmBH

The invention relates to a method for producing tris(perfluoroalkyl)phosphine oxides and bis(perfluoroalkyl)phosphinic acids by reacting tris(perfluoroalkyl)difluorophosphorane or bis(perfluoroalkyl)trifluorophosphorane with non-metal oxides, metalloid oxides or organic compounds with basic oxygen residues. 1. Process for the preparation of compounds of the formula (I){'br': None, 'sub': x', '2x+1', 'n', '3-n, '(CF)P(O)(F)\u2003\u2003(I)'} {'br': None, 'sub': x', '2x+1', 'n', '3-n, '(CF)P(O)(OH)\u2003\u2003(II)'}, 'or of compounds of the formula (I) and compounds of the formula (II)'}where, in the formulae (I) and (II), x is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12 and n=2 or 3, {'br': None, 'sub': x', '2x+1', 'n', '5-n, '(CF)P(F)\u2003\u2003(III),'}, 'comprising at least the reaction of compounds of the formula (III)'}where x and n have one of the meanings indicated above,with non-metal oxides, semimetal oxides or organic compounds containing basic oxygen residues, where the reaction is optionally carried out in the presence of water.2. Process according to claim 1 , characterised in that compounds of the formula (III) where x denotes 2 claim 1 , 3 claim 1 , 4 claim 1 , 5 or 6 are employed.3. Process according to claim 1 , characterised in that compounds of the formula (II) are selected from tris(pentafluoroethyl)difluorophosphorane claim 1 , tris(heptafluoropropyl)difluorophosphorane claim 1 , tris(nonafluorobutyl)difluorophosphorane claim 1 , tris(undecafluoropentyl)difluorophosphorane claim 1 , tris(tridecafluorohexyl)difluorophosphorane claim 1 , bis(heptafluoropropyl)trifluorophosphorane claim 1 , bis(nonafluorobutyl)trifluorophosphorane and bis(tridecafluorohexyl)trifluorophosphorane.4. Process according to claim 1 , characterised in that non-metal oxides or semimetal oxides are used.5. Process according to claim 1 , characterised in that SO claim 1 , POCl claim 1 , PO claim 1 , COor SeOis used.6. Process according to claim 1 , characterised in that SO claim 1 ...

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Номер записи: 81
18-05-2017 дата публикации

FLAMEPROOF, ALIPHATIC POLYKETONE MATERIALS, MOULDED ARTICLES PRODUCED THEREFROM AND ALSO METHOD FOR THE PRODUCTION THEREOF

Номер: US20170137608A1
Автор: STOPPELMANN Georg
Принадлежит: EMS-PATENT AG

The present invention relates to polyketone moulding compounds based on partially crystalline, aliphatic polyketones. In particular, it relates to halogen-free, flameproof moulding compounds based on aliphatic polyketones which preferably comprise salts of phosphinic acids as flame retardant. The moulding compounds fulfil the fire protection classification V0 according to UL94 and display good mechanical properties. These moulding compounds are suitable for the production of in particular thin-walled moulded articles for the electrical and electronics industry, such as for example housings, housing components or connectors. 116-. (canceled)17. A flameproof polyketone moulding compound comprising or consisting of{'sub': 'm', '(A) 30-94% by weight of at least one partially crystalline, aliphatic polyketone with a melting temperature (T) in the range of 180° C.-280° C., measured by means of DSC according to ISO 11357-3 and at a heating rate of 20 K/min;'}(B) 0-50% by weight of at least one filling- and reinforcing means;(C) 6-15% by weight of at least one halogen-free flame retardant;(D) 0-2.0% by weight of at least one organic phosphite and/or phosphonite; and(E) 0-10% by weight of at least one additive;the percentages by weight of components (A) to (E) together producing 100%.18. The polyketone moulding compound according to claim 17 , wherein claim 17 , independently of each other or in combination with each other claim 17 , the content(A) of the at least one aliphatic polyketone is 35-83.85% by weight,(B) of the at least one filling- or reinforcing material is 10-50% by weight,(C) of the at least one halogen-free flame retardant is 7-12% by weight,(D) of the at least one organic phosphite and/or phosphonite is 0.05 to 1.5% by weight, and/or(E) of the at least one additive is 0.1-5% by weight.19. The polyketone moulding compound according to claim 17 , wherein the at least one polyketone (A) is a polymer of carbon monoxide and at least one olefinically unsaturated ...

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Номер записи: 82
18-05-2017 дата публикации

POLYKETONE MOULDING COMPOUNDS WITH IMPROVED PROPERTIES, MOULDED ARTICLES PRODUCED THEREFROM AND ALSO METHOD FOR THE PRODUCTION THEREOF

Номер: US20170137609A1
Автор: STOPPELMANN Georg
Принадлежит: EMS-PATENT AG

The present invention relates to polyketone moulding compounds based on partially crystalline, aliphatic polyketones. In particular, it relates to fibre-reinforced moulding compounds based on aliphatic polyketones which preferably comprise small quantities of phosphinic acid or the salts thereof. The moulding compounds are distinguished by improved mechanical properties and good processability in injection moulding. These moulding compounds are suitable for the production of in particular thin-walled moulded articles for the electrical and electronics industry, such as for example housings, housing components or connectors. 114-. (canceled)15. A polyketone moulding compound comprising or consisting of(A) 25-99.9% by weight of at least one aliphatic polyketone;(B) 0-70% by weight of filling- or reinforcing materials; (C1) 0-6% by weight of at least one phosphinic acid or at least one diphosphinic acid, a metal salt and/or an organic derivative thereof;', '(C2) 0-2% by weight of at least one organic phosphite or phosphonite,, '(C) 0.1-6% by weight of at least one phosphorus-containing compound, selected from the group consisting of'}wherein at least one of the phosphorus-containing compounds (C1) and (C2) is present in the polyketone moulding compound, so that the sum of the phosphorus-containing compounds (C1) and (C2) is at least 0.1% by weight, and(D) 0-20% by weight of at least one additive,the sum of (A) to (D) producing 100% by weight, the amounts for (A) to (D) including (C1) and (C2) respectively relating to the moulding compound or the sum of (A) to (D).16. The polyketone moulding compound according to claim 15 , wherein claim 15 , respectively independently of each other or in combination with each other claim 15 , the amount(A) of the at least one aliphatic polyketone is 32 to 89.7% by weight,(B) of the filling- or reinforcing materials is 10 to 60% by weight,(C) of the at least one phosphorus-containing compound is 0.2 to 4% by weight, and(D) of the at ...

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Номер записи: 83
08-09-2022 дата публикации

Ethylene-Based Polymer Composition Containing a Triorganoaminophosphine

Номер: US20220282073A1
Автор: Chaudhary Bharat I., Cogen Jeffrey M., LIOTTA Charles, Pollet Pamela, Sarngadharan Sarath Chand
Принадлежит:

The present disclosure provides a composition. The composition includes (i) an ethylene-based polymer; (ii) an organic peroxide, (iii) a triorganoaminophosphine, and (iv) a protic acid-source compound (“PASC”) selected from a protic acid, a protic acid-generator compound (“PAGC”), and combinations thereof. The present disclosure also provides a coated conductor. The coated conductor includes a conductor and a coating on the conductor, the coating containing a composition including (i) an ethylene-based polymer; (ii) an organic peroxide, (iii) a triorganoaminophosphine, and (iv) a protic acid-source compound (“PASC”) selected from a protic acid, a protic acid-generator compound (“PAGC”), and combinations thereof. 2. The composition of claim 1 , wherein the PASC is the protic acid; andthe composition has a Retained Peroxide Percentage from 12% to 100% after the composition has been heated at 100° C. for 2 hours in an air atmosphere, and the peroxide content of the resulting headed composition is measured using liquid chromatography.3. The composition of claim 1 , wherein the PASC is the protic acid claim 1 , and the protic acid is selected from the group consisting of a sulfonic acid claim 1 , a sulfenic acid claim 1 , a sulfinic acid claim 1 , a carboxylic acid claim 1 , a phosphorus-based acid claim 1 , and a combination thereof.4. The composition of wherein the PASC is the PAGC claim 1 , and the PAGC is an antioxidant.5. The composition of wherein the antioxidant is a sulfur-based antioxidant.6. The composition of claim 1 , wherein Rand Reach is independently selected from the group consisting of a phenyl group claim 1 , a N claim 1 ,N-diethylamino group claim 1 , a pyrrolidinyl group claim 1 , a 4-(N claim 1 ,N-dimethylamino)phenyl group claim 1 , and a cyclohexyl group; and{'sup': '3', 'Ris selected from the group consisting of a N,N-diethylamino group, a pyrrolidinyl group, and a 4-(N,N-dimethylamino)phenyl group.'}76. The composition of claim 1 , wherein at ...

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Номер записи: 84
30-04-2020 дата публикации

INK COMPOSITION FOR 3D PRINTING SUPPORTER AND 3D PRINTING PRODUCTION METHOD USING SAME

Номер: US20200131386A1
Автор: Back Seung-A, Kim Joon-Hyung, KIM Mi-Kyoung, PARK Sung-Eun
Принадлежит: LG CHEM, LTD.

Disclosed is an ink composition for a 3D printing supporter and a 3D printing production method using the same, in which the ink composition is usable for an inkjet 3D printer, has excellent jetting properties and is easily dissolved in water after curing so that a supporter can be easily removed. The ink composition for a 3D printing supporter comprises: an amine-containing monomer, a curing agent, and a water-soluble polymer having an amine-containing polymer. 1. An ink composition for a 3D printing supporter comprising:an amine-containing monomer;a curing agent; anda water-soluble polymer containing an amine-containing polymer.2. The ink composition for a 3D printing supporter according to claim 1 , characterized in that the content of the amine-containing monomer is 10 to 99.9% by weight based on the total weight of the ink composition for a 3D printing supporter.3. The ink composition for a 3D printing supporter according to claim 1 , characterized in that the content of the curing agent is 0.01 to 20% by weight based on the total weight of the ink composition for a 3D printing supporter.4. The ink composition for a 3D printing supporter according to claim 1 , characterized in that the content of the water-soluble polymer is 0.01 to 30% by weight based on the total weight of the ink composition for a 3D printing supporter.5. The ink composition for a 3D printing supporter according to claim 1 , characterized in that the amine-containing monomer is a monomer having 1 to 30 carbon atoms and containing at least one amine group.6. The ink composition for a 3D printing supporter according to claim 1 , characterized in that the amine-containing monomer is selected from the group consisting of N claim 1 ,N-dimethylacrylamide claim 1 , diacetone acrylamide claim 1 , N-[3-(dimethylamino)propyl]methacrylamide claim 1 , N-methyl-N-vinylacetamide claim 1 , 2-(dimethylamino)ethylacrylate claim 1 , N-vinylpyrrolidone claim 1 , 4-acryloylmorpholine claim 1 , N- ...

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Номер записи: 85
10-06-2021 дата публикации

FLAME RETARDANT COMPOSITION AND FLAME-RETARDANT THERMOPLASTIC RESIN COMPOSITION CONTAINING SAID FLAME RETARDANT COMPOSITION

Номер: US20210171735A1
Автор: Fujimoto Kazuo, Tsuji Hiroshi
Принадлежит:

The present invention provides a non-halogen-based flame retardant composition and flame retardant resin composition wherein a small amount of addition achieves an excellent flame retardancy, an amount of elution of a flame retardant from the thermoplastic resin is extremely small even under high temperature and high humidity, and it has water-resistant property. A phosphate ester amide compound of general formula (I), a nitrogen-containing compound having a 1,3,5-triazine structure or 1,3,5-triazine fused ring structure, and optionally, a metal oxide or metal salt are used together. Further optionally, a dripping inhibitor is blended. 2. The flame retardant composition according to claim 1 , wherein a value of a blending ratio (A)/(B) (mass ratio) of the component (A) and component (B) is larger than 1.3. The flame retardant composition according to claim 1 , wherein claim 1 , in the general formula (I) claim 1 , R claim 1 , R claim 1 , Rand Rare each a methyl group claim 1 , and R claim 1 , R claim 1 , Rand Rare each a methylene group.4. The flame retardant composition according to claim 1 , wherein in the general formula (I) claim 1 , Ris an ethylene group.5. The flame retardant composition according to claim 1 , wherein in the general formula (I) claim 1 , Rand Rare each a hydrogen atom.6. The flame retardant composition according to claim 1 , wherein the nitrogen-containing compound of the component (B) is a phosphate salt claim 1 , pyrophosphate salt or polyphosphate salt of an amine compound having a 1 claim 1 ,3 claim 1 ,5-triazine structure or a 1 claim 1 ,3 claim 1 ,5-triazine fused ring structure.7. The flame retardant composition according to claim 6 , wherein the nitrogen-containing compound of the component (B) is a polyphosphate salt of an amine compound having a 1 claim 6 ,3 claim 6 ,5-triazine structure or a 1 claim 6 ,3 claim 6 ,5-triazine fused ring structure.8. The flame retardant composition according to claim 6 , wherein the nitrogen-containing ...

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Номер записи: 86
24-05-2018 дата публикации

FLAME RETARDANT COMPOSITION, METHODS OF MANUFACTURE THEREOF AND ARTICLES COMPRISING THE SAME

Номер: US20180142079A1
Автор: Chen Lin, SHI Hongtao, Zhang Chunjie, Zheng Yun
Принадлежит:

Disclosed herein is a flame retardant composition comprising 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a halogenated phenoxyphosphazene flame retardant, where all weight percents are based on a total weight of the flame retardant composition. Disclosed herein too is a method comprising blending a 20 to 80 weight percent of a polycarbonate; and 1 to 20 weight percent of a halogenated phenoxyphosphazene flame retardant to produce a flame retardant composition, where all weight percents are based on a total weight of the flame retardant composition. 1. A flame retardant composition comprising:20 to 80 weight percent of a polycarbonate; and1 to 20 weight percent of a halogenated phenoxyphosphazene flame retardant, where all weight percentages are based on a total weight of the flame retardant composition.2. The flame retardant composition of claim 1 , further comprising 1 to 30 wt % of an impact modifier.3. The flame retardant composition of claim 1 , where the impact modifier is methyl methacrylate-butadiene-styrene claim 1 , acrylonitrile-styrene-butyl acrylate claim 1 , methyl methacrylate-butadiene claim 1 , methyl methacrylate-acrylonitrile-butadiene-styrene claim 1 , acrylonitrile-ethylene-propylene-diene-styrene claim 1 , acrylonitrile-butadiene-styrene claim 1 , or a combination thereof.4. The flame retardant composition of claim 1 , further comprising a polyester; where the polyester is blended with the polycarbonate or copolymerized with the polycarbonate and where the polyester is present in an amount of 10 to 60 wt % claim 1 , based on the total weight of the flame retardant composition.5. The flame retardant composition of claim 4 , where the polyester is poly(ethylene terephthalate) claim 4 , poly(1 claim 4 ,4-butylene terephthalate) claim 4 , poly(propylene terephthalate) claim 4 , poly(alkylene naphthoates) claim 4 , poly(ethylene naphthanoate) claim 4 , poly(butylene naphthanoate) claim 4 , poly(cyclohexanedimethylene ...

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Номер записи: 87
02-06-2016 дата публикации

Polymer Composition with Improved Flammability Performance

Номер: US20160152801A1
Автор: Tyler Mark Allen, Yu Yuehua
Принадлежит:

A polymer composition for use in a molded part is provided. The composition comprises a highly flowable, liquid crystalline polymer blended with a relatively small amount of an inorganic filler (e.g., glass fibers, mineral filler, etc.). Although the composition contains only a small amount of the filler, the resulting molded part can still exhibited improved flammability performance. More particularly, the present inventors have surprisingly discovered that the use of an organophosphorous compound within a certain concentration can improve the flammability properties of the composition without sacrificing other properties of the part, such as blister resistance. 1. A polymer composition comprising a liquid crystalline polymer having a melt viscosity of about 50 Pa-s or less as determined in accordance with ISO Test No. 11443 at a shear rate of 1000 secondsand temperature that is 15° C. above the melting temperature of the polymer , wherein the polymer is melt blended with an inorganic filler in an amount of from about 0.1 to about 35 parts per 100 parts of the polymer and an organophosphorous compound in an amount of from about 0.01 to about 5 parts per 100 parts of the polymer.2. The polymer composition of claim 1 , wherein the polymer composition has a melt viscosity of about 80 Pa-s or less claim 1 , as determined in accordance with ISO Test No. 11443 at a shear rate of 1000 secondsand temperature that is 15° C. above the melting temperature of the composition.3. The polymer composition of claim 1 , wherein the polymer has a total amount of repeating units derived from naphthenic hydroxcarboxylic and/or naphthenic dicarboxylic acids of more than 15 mol. %.4. The polymer composition of claim 3 , wherein the polymer contains monomer units derived from 2 claim 3 ,6-naphthalenedicarboxylic acid.5. The polymer composition of claim 3 , wherein the polymer contains monomer units derived from 4-hydroxybenzoic acid claim 3 , terephthalic acid claim 3 , isophthalic acid ...

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Номер записи: 88
07-05-2020 дата публикации

Flexible foam with halogen-free flame retardant

Номер: US20200140640A1
Автор: Petra VENNER, Rolf Albach
Принадлежит: Covestro Deutschland AG

The invention relates to flame-retardant flexible polyurethane foams with phosphazene and to methods for producing PUR flexible foams by reacting a component A containing: A1, an isocyanate-reactive component, A2, a propellant containing water, A3, optionally auxiliary agents and additives, and A4, a flame retardant, with B, an isocyanate component. The invention is characterized in that the flame retardant A4 contains a phosphazene according to the formula (I): [PmNmXk] (I), where X independently of one another represents O-aryl or NR-aryl, at least one aryl group is substituted, X can represent a bridge, R is selected from the group of H, C1-C4 alkyl, and aryl, and m represents a number from 1 to 5, particularly preferably 3 or 4, k depends on m and represents a number from 0 to 2m, and the phosphazene does not have any groups which are reactive towards isocyanates.

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Номер записи: 89
07-05-2020 дата публикации

IMPACT RESISTANT CYCLIC PHOSPHAZENES

Номер: US20200140654A1
Автор: Kobilka Brandon M., Kuczynski Joseph, PORTER Jacob T., Wertz Jason T.
Принадлежит:

An impact-modified composition and a method of making an impact-modified composition are provided. In an embodiment, the method includes reacting a phosphazene material with an acrylamide material to form a functionalized phosphazene material; initiating a polymerization reaction on a reaction mixture comprising the functionalized phosphazene material and one or more monomers to form an impact-modified phosphazene material; and adding the an impact-modified phosphazene material to a polymeric material. 1. A method of forming an impact-modified phosphazene material comprising:reacting a phosphazene material with an acrylamide material to form a functionalized phosphazene material; andinitiating a polymerization reaction on a reaction mixture comprising the functionalized phosphazene material and one or more monomers to form an impact-modified phosphazene material.2. The method of claim 1 , wherein the polymerization reaction comprises adding an ultraviolet initiator claim 1 , a thermal initiator claim 1 , or a radical polymerization initiator.3. The method of claim 1 , further comprising heating a second reaction mixture comprising the impact-modified phosphazene material.4. The method of claim 1 , wherein the one or more monomers are selected from the group consisting of an acrylate monomer material claim 1 , acrylamide monomer material claim 1 , styrenic monomer material claim 1 , other vinylic monomer material claim 1 , or a combination thereof.5. The method of claim 1 , wherein the reaction mixture further comprises a phosphorous-containing monomer.6. The method of claim 5 , wherein the phosphorous-containing monomer includes a phosphorous-containing styrenic monomer.9. A method of forming an impact-modified polymeric material comprisingreacting a phosphazene material with an acrylamide material to form a functionalized phosphazene material;initiating a polymerization reaction on a reaction mixture comprising the functionalized phosphazene material and one or ...

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Номер записи: 90
01-06-2017 дата публикации

Resin composition, molded body, electronic component, electronic apparatus, and electronic office apparatus

Номер: US20170152368A1
Автор: Tadakatsu Harada, Yasuo Kurachi, Yasushi Akiba
Принадлежит: Ricoh Co Ltd

Provided is a resin composition including a polycarbonate and a phosphorus-containing compound, wherein a content rate of the phosphorus-containing compound in the resin composition is less than 14 percent by mass, wherein the phosphorus-containing compound includes a phosphazene derivative represented by general formula (1) below and a phosphoric acid ester, wherein a content rate of the phosphazene derivative in the resin composition is 0.1 percent by mass or greater but less than 3.0 percent by mass, and wherein a resin specific gravity (D0) of the resin composition before burned in a UL94V test and a resin specific gravity (D1) of the resin composition after burned in the UL94V test satisfy a relationship of D1/D0>0.85, where in general formula (1), R 1 and R 2 each independently represent an aromatic ring-containing group free of a halogen atom, and m represents any of from 3 through 8.

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Номер записи: 91
09-06-2016 дата публикации

AROMATIC TETRAFUNCTIONAL VINYLBENZYL RESIN COMPOSITION AND USE THEREOF

Номер: US20160160008A1
Автор: GAO Yu, HSIEH CHEN-YU, JIA Ningning, LV Wenfeng, MA Ziqian, TIAN Wenjun, WANG Rongtao
Принадлежит:

A low dissipation factor resin composition comprises the following components: (A) an aromatic tetrafunctional vinylbenzyl monomer, its prepolymer or a combination thereof, the aromatic tetrafunctional vinylbenzyl monomer having a structure shown below; (B) flame retardant; and (C) peroxide. 2. The low dissipation factor resin composition of claim 1 , wherein the aromatic tetrafunctional vinylbenzyl prepolymer has a number average molecular weight less than 2000.5. The low dissipation factor resin composition of claim 1 , further comprising styrene-butadiene-divinylbenzene terpolymer claim 1 , styrene-butadiene-maleic anhydride terpolymer claim 1 , vinyl functional polybutadiene urethane oligomer claim 1 , or a combination thereof.6. The low dissipation factor resin composition of claim 1 , further comprising a vinyl-containing compound or a polymer thereof which comprises maleimide claim 1 , divinylbenzene claim 1 , bis(vinylbenzyl)ether claim 1 , triallyl isocyanurate claim 1 , diallyl bisphenol A claim 1 , vinyl-containing polyphenylene oxide claim 1 , maleimide prepolymer claim 1 , a vinyl-containing polymer with a number average molecular weight less than 1000 claim 1 , or a combination thereof.8. A product made from the low dissipation factor resin composition of claim 1 , which comprises a resin film claim 1 , a prepreg claim 1 , a laminate or a printed circuit board.9. The product of claim 8 , wherein the laminate or the printed circuit board has a dissipation factor of less than or equal to 0.0060 at 10 GHz.10. The product of claim 8 , wherein the laminate or the printed circuit board has a glass transition temperature greater than 195° C. as measured by DMA according to IPC-TM-650 2.4.24.4 claim 8 , a T288 greater than 60 minutes without delamination claim 8 , and a solder dip test cycle greater than 20 without delamination. This Application claims priority to Chinese Patent Application No. 201410736496.9, filed on Dec. 5, 2014, the entirety of which is ...

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Номер записи: 92
22-09-2022 дата публикации

Active Energy Ray Curable Composition

Номер: US20220298269A1
Автор: KUNIYASU Satoshi, Tanaka Kazuhiro
Принадлежит:

Provided is an active energy ray curable composition cured by irradiation of active energy rays. The active energy ray curable composition contains an (A) radical polymerizable compound, a (B) photopolymerization initiator, and a (C) amine compound. The (B) photopolymerization initiator includes a (B1) sulfur compound and a (B2) acyl phosphine oxide compound. The (B1) sulfur compound is at least one of a sulfone compound and a thiobenzoyl compound. 1. An active energy ray curable composition cured by irradiation of active energy rays , comprising an (A) radical polymerizable compound , a (B) photopolymerization initiator , and a (C) amine compound , whereinthe (B) photopolymerization initiator includes a (B1) sulfur compound and a (B2) acyl phosphine oxide compound, andthe (B1) sulfur compound is at least one of a sulfone compound and a thiobenzoyl compound.2. The active energy ray curable composition according to claim 1 , whereinthe (C) amine compound includes at least one of a (C1) amino modified compound and a (C2) aromatic amine compound, andthe (C1) amino modified compound is at least one of an amino modified acrylate oligomer and an amino modified acrylate polymer.3. The active energy ray curable composition according to claim 1 , whereinthe active energy ray curable composition has a content of the (B) photopolymerization initiator of not less than 4.2% by mass,the active energy ray curable composition has a content of the (B1) sulfur compound of not less than 0.4% by mass, andthe active energy ray curable composition has a content of the (B2) acyl phosphine oxide compound of not less than 0.7% by mass.4. The active energy ray curable composition according to claim 1 , whereinthe (B) photopolymerization initiator further includes a (B3) thioxanthone compound, andthe active energy ray curable composition has a content of the (B3) thioxanthone compound of not more than 1.0% by mass.5. The active energy ray curable composition according to claim 1 , whereinthe ...

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Номер записи: 93
23-05-2019 дата публикации

FLAME RETARDANT ULTRAVIOLET LIGHT STABILIZING MOLECULES

Номер: US20190153198A1
Автор: Campbell Eric J., Czaplewski-Campbell Sarah K., Kobilka Brandon M., Wertz Jason T.
Принадлежит:

A flame retardant ultraviolet (UV) light stabilizing molecule includes a phosphorus-containing flame retardant moiety and a hydroxyphenyl-benzotriazole (HPB) moiety. 1. A flame retardant ultraviolet (UV) light stabilizing molecule that includes a phosphorus-containing flame retardant moiety and a hydroxyphenyl-benzotriazole (HPB) moiety.2. The flame retardant UV light stabilizing molecule of claim 1 , further comprising a matrix bonding functionality.3. The flame retardant UV light stabilizing molecule of claim 2 , wherein the matrix bonding functionality includes vinyl groups claim 2 , amine groups claim 2 , epoxy groups claim 2 , allyl groups claim 2 , or acrylate groups.4. The flame retardant UV light stabilizing molecule of claim 1 , further comprising a triazine moiety.5. The flame retardant UV light stabilizing molecule of claim 4 , further comprising a plasticizer bound to the triazine moiety via an aliphatic ester linkage or an aliphatic amide linkage.6. The flame retardant UV light stabilizing molecule of claim 5 , further comprising a second triazine moiety bound to the plasticizer via a second aliphatic ester linkage or a second aliphatic amide linkage.7. The flame retardant UV light stabilizing molecule of claim 1 , further comprising a plasticizer bound to the HPB moiety via an aliphatic amide linkage.8. The flame retardant UV light stabilizing molecule of claim 7 , further comprising a second HPB moiety bound to the plasticizer via a second aliphatic amide linkage.9. A process comprising:forming a flame retardant ultraviolet (UV) light stabilizing molecule that includes a phosphorus-containing flame retardant moiety and a hydroxyphenyl-benzotriazole (HPB) moiety; andutilizing the flame retardant UV light stabilizing molecule as a polymeric additive to impart flame retardant characteristics and UV light stabilization characteristics to a polymeric material.10. The process of claim 9 , wherein the flame retardant UV light stabilizing molecule further ...

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Номер записи: 94
14-05-2020 дата публикации

PHOTOCURABLE INKJET PRINTING INK COMPOSITION

Номер: US20200148903A1
Автор: MYOSE Takuya, NAKASHIMA Okinori, SATO Yoichi
Принадлежит:

An object is to provide an ink composition for inkjet printing that permits inkjet printing, particularly on metal surfaces, wherein such ink composition possesses sufficiently high adhesion and heat resistance with respect to metal surfaces. As a means for achieving the object, a photocurable inkjet printing ink composition is provided, which contains, relative to the entire ink composition, 0.1 percent by mass or more of an acid-modified acrylic monomer and 10 to 30 percent by mass of a monofunctional monomer with a Tg of 100° C. or above, wherein the monofunctional monomer accounts for 80 percent by mass or more of all monomers. 1. A photocurable inkjet printing ink composition , containing , relative to an entire ink composition:0.1 percent by mass or more of an acid-modified acrylic monomer; and10 to 30 percent by mass of a monofunctional monomer with a Tg (glass transition temperature) of 100° C. or above;wherein the monofunctional monomer accounts for 80 percent by mass or more of all monomers.2. The photocurable inkjet printing ink composition according to claim 1 , wherein the monofunctional monomer with a Tg of 100° C. or above is a monofunctional monomer with a Tg of 120° C. or above. The present invention relates to a photocurable inkjet printing ink composition for metals.UV-curable inkjet offset inks containing acid-modified acrylic monomers are known, as described in Patent Literatures 1 and 2.However, these inks containing acid-modified acrylic monomers, although they may be non-problematic when used as offset printing inks for printing on papers, do not have sufficient adhesion or heat resistance with respect to the surfaces of printing objects when the printing objects are made of metals such as metal sheets.In light of the above, an object of the present invention is to provide an ink composition for inkjet printing that permits inkjet printing, particularly on metal surfaces, wherein such ink composition possesses sufficiently high adhesion and ...

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Номер записи: 95
18-06-2015 дата публикации

Process for regenerating sulfur-crosslinked rubber vulcanizates to give regenerates

Номер: US20150166759A1
Автор: Carla Recker, Lena Mueller, Thomas Voelker
Принадлежит: CONTINENTAL REIFEN DEUTSCHLAND GMBH

A process for regenerating sulfur-crosslinked rubber vulcanizates to regenerates, wherein at least one regenerating agent is used in the regeneration. The regenerating agent is selected from the group consisting of dithiophosphoryl polysulfides and/or silanes having a polysulfane group. Regenerates which have been produced by means of the process lead to improved or equal rolling resistance indicators and a lower compression set in vulcanized rubber mixtures compared to regenerates known in the prior art.

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Номер записи: 96
18-06-2015 дата публикации

METHOD FOR PRODUCING STABILIZED AMORPHOUS CALCIUM CARBONATE

Номер: US20150166762A1
Автор: Ashkenazi Binyamin, MEIRON Oren
Принадлежит:

Provided is a method for preparing a stable amorphous calcium carbonate (ACC), which can be obtained either in suspension or as a powder. The method comprises stepwise combination of a soluble calcium salt, a soluble carbonate, a first and second stabilizer, and a water miscible organic solvent as described herein. The present invention further relates to stable ACC suspensions and dry powders produced by the method of the present invention. 149-. (canceled)50. A method of preparing amorphous calcium carbonate (ACC) , the method comprising:i) combining an aqueous solution comprising a soluble calcium salt and a first stabilizer with an aqueous solution comprising a soluble carbonate so as to form an ACC suspension; andii) adding a water miscible organic solvent and a solution comprising a second stabilizer, substantially simultaneously or sequentially in any order, thereby obtaining a stabilized suspension of ACC;wherein the first stabilizer and the second stabilizer are the same or different; andwherein a total amount of first and second stabilizers constitutes up to about 12 weight % (wt %) of the stabilized ACC suspension, and the water miscible organic solvent constitutes at least about 5 wt % of the stabilized ACC suspension.51. The method according to claim 50 , wherein said second stabilizer and water miscible organic solvent contact said ACC suspension within about 2 minutes of formation thereof.52. The method according to claim 50 , further comprising:i) preparing an aqueous solution comprising a soluble calcium salt and a first stabilizer;ii) preparing an aqueous solution comprising a soluble carbonate;iii) preparing an aqueous solution comprising a second stabilizer;iv) preparing a solution comprising a water miscible organic solvent; andv) combining the aqueous solution prepared in step ii) with the aqueous solution prepared in step i) so as to form an ACC suspension, followed by adding the solutions prepared in steps iii) and iv), substantially ...

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Номер записи: 97
28-08-2014 дата публикации

P-piperazine compounds as flame retardants

Номер: US20140243455A1
Автор: Manfred Doering, Michael Ciesielski, Michael Roth, Rainer Xalter, Sebastian Wagner
Принадлежит: BASF SE

The present invention relates to the use of aromatic P-piperazine-compounds in flame retardant polymer compositions. These compositions are especially useful for the manufacture of flame retardant compositions based on thermoplastic polymers, especially polyolefin homo- and copolymers, polycondensates, such as polyamines or polyesters and duroplastic polymers, such as polyepoxides.

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Номер записи: 98
28-08-2014 дата публикации

REINFORCED POLY(PHENYLENE ETHER)-POLYSILOXANE BLOCK COPOLYMER COMPOSITION, AND ARTICLE COMPRISING SAME

Номер: US20140243460A1
Автор: Lietzau Christian, Sato Sho
Принадлежит:

A reinforced poly(phenylene ether)-polysiloxane block copolymer composition includes specific amounts of a poly(phenylene ether)-polysiloxane block copolymer reaction product, a flame retardant, and a reinforcing filler. The composition exhibits a desirable balance of flame retardancy, heat resistance, and stiffness relative to a corresponding poly(phenylene ether) composition, and it is useful to fabricate articles including fuser holders for electrophotographic copiers. 1. A composition , comprising:30 to 91 weight percent of a poly(phenylene ether)-polysiloxane block copolymer reaction product comprising a poly(phenylene ether) and a poly(phenylene ether)-polysiloxane block copolymer;4 to 25 weight percent of a flame retardant comprising an organophosphate ester, a phosphazene, or a combination thereof; and5 to 40 weight percent of a reinforcing filler;wherein all weight percents are based on the total weight of the composition.2. The composition of claim 1 , exhibitinga flammability rating of V-0 at a sample thickness less than or equal to 1.5 millimeters in the 20 millimeter Vertical Burning Flame Test of Underwriter's Laboratory Bulletin 94 “Tests for Flammability of Plastic Materials, UL 94”,a heat deflection temperature of at least 110° C. determined according to ASTM D 648-07 using a stress of 1.82 megapascals (MPa) and a sample thickness of 6.4 millimeters, anda flexural modulus of at least 3,500 megapascals measured at 23° C. according to ASTM D 790-07e1 using a sample thickness of 6.4 millimeters.4. The composition of claim 1 , wherein the poly(phenylene ether)-polysiloxane block copolymer contributes 1 to 5 weight percent of polysiloxane to the composition.5. The composition of claim 1 , wherein the flame retardant comprises an organophosphate ester.6. The composition of claim 1 , wherein the flame retardant comprises a phosphazene.7. The composition of claim 1 , wherein the reinforcing filler is selected from the group consisting of glass fibers claim ...

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Номер записи: 99
24-06-2021 дата публикации

CURABLE COMPOSITIONS FOR PRESSURE-SENSITIVE ADHESIVES

Номер: US20210189042A1
Автор: Ellis Mark F., Nelson Eric W., Pope Christopher C., Seth Jayshree, Venne Janet A., Wessel Matthew H.
Принадлежит:

Curable compositions, cured compositions, articles containing the curable or cured compositions, and methods of making the articles are provided. More particularly, the curable compositions contain a (meth)acrylate-based polymer having pendant (meth)acryloyl groups, at least one monomer having a single ethylenically unsaturated group, a photoinitiator that includes an acyl phosphine oxide, and a thixotropic agent. The curable compositions can be printed or dispensed, if desired, and the cured compositions are pressure-sensitive adhesives. 1. A curable composition comprising:a) a (meth)acrylate-based polymer having multiple pendant (meth)acryloyl groups, the (meth)acrylate-based polymer having a weight average molecular weight in a range of 25,000 to 400,000 Daltons;b) at least one monomer having a single ethylenically unsaturated group;c) a photoinitiator comprising an acyl phosphine oxide compound;d) a thixotropic agent comprising inorganic oxide particles,wherein the curable composition is free or substantially free of an epoxy resin.2. The curable composition of claim 1 , wherein the (meth)acrylate-based polymer having multiple pendant (meth)acryloyl groups further comprises monomeric units having pendant hydroxy groups.3. The curable composition of claim 1 , wherein the photoinitiator further comprises a second photoinitiator that absorbs wavelengths of light less than 300 nanometers.4. The curable composition of claim 3 , wherein the photoinitiator is a mixture of diphenyl (2 claim 3 ,4 claim 3 ,6-trimethylbenzoyl) phosphine oxide and methyl benzoylformate.5. The curable composition of claim 1 , wherein the (meth)acrylate-based polymer having pendant (meth)acryloyl groups has 1 to 20 pendant (meth)acryloyl groups per chain on average.6. The curable composition of claim 1 , wherein the (meth)acrylate-based polymer having pendant (meth)acryloyl group comprises 50 to 99.9 weight percent monomeric units derived from a (hetero)alkyl (meth)acrylate claim 1 , 0.1 to ...

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Номер записи: 100