Composite membranes for membrane distillation and related methods of manufacture

The present invention relates to a membrane distillation system comprising a flat-sheet composite mixed matrix hydrophilic/hydrophobic membrane having at least a hydrophilic layer and a hydrophobic layer. The hydrophilic layer comprises a hydrophilic polymer and inorganic nanoparticles having high thermal conductivity. The hydrophobic layer comprises fluorinated surface-modifying macromolecules (SMM). Also disclosed is a phase inversion method for manufacturing the membrane.