Preparation method of nickel-containing coordinate polymer

Technical Field

A nickel-containing polymer preparation method.

Background Art

Nickel-containing coordination polymer is in recent years metal polymer research in the field of focus, currently in the industry has not yet been found very good synthetic way.

Content of the invention

A nickel-containing coordination polymer of preparation method, including:

Step 1: will be 200 g of Under the protection of nitrogen, added to the 1500 ml of ethyl ether in;

Step 2: stirring and adding 40 g sodium hydroxide;

Step 3: added dropwise 20 ml of the sodium bicarbonate solution, the concentration of the sodium bicarbonate solution is 7.2 g/L;

Step 4: adding 212 g iodine, and then adding 2 L of ethyl ether, in the extractor extracting 5 hours to obtain ;

Step 5: taking 4.1 g steps 5 made In 5 ml fully dissolved in the water add 6 ml jing, stirring 2 hours, methanol to the product for the recrystallization, steaming and product, to obtain ;

Step 6: taking 3.2 mg steps 5 made Into 20 ml of N, N - diethyl formamide in, stirring and adding 2.5 mg six hydrated nickel chloride;

Step 7: in 120 °C reaction in a reaction tank 12 hours, generating green crystal nickel-containing coordination polymer.

The nickel-containing coordination polymer of this invention can be used for high temperature-resistant coating.

Mode of execution

Embodiment 1

A nickel-containing coordination polymer of preparation method, including:

Step 1: will be 200 g of Under the protection of nitrogen, added to the 1500 ml of ethyl ether in;

Step 2: stirring and adding 40 g sodium hydroxide;

Step 3: added dropwise 20 ml of the sodium bicarbonate solution, the concentration of the sodium bicarbonate solution is 7.2 g/L;

Step 4: adding 212 g iodine, and then adding 2 L of ethyl ether, in the extractor extracting 5 hours to obtain ;

Step 5: taking 4.1 g steps 5 made In 5 ml fully dissolved in the water add 6 ml jing, stirring 2 hours, methanol to the product for the recrystallization, steaming and product, to obtain ;

Step 6: taking 3.2 mg steps 5 made Into 20 ml of N, N - diethyl formamide in, stirring and adding 2.5 mg six hydrated nickel chloride;

Step 7: in 120 °C reaction in a reaction tank 12 hours, generating green crystal nickel-containing coordination polymer.

The nickel-containing coordination polymer of this invention can be used for high temperature-resistant coating.

Embodiment 2

A nickel-containing coordination polymer of preparation method, including:

Step 1: will be 200 g of Under the protection of nitrogen, added to the 1500 ml of ethyl ether in;

Step 2: stirring and adding 40 g sodium hydroxide;

Step 3: added dropwise 20 ml of the sodium bicarbonate solution, the concentration of the sodium bicarbonate solution is 7.2 g/L;

Step 4: adding 212 g iodine, and then adding 2 L of ethyl ether, in the extractor extracting 5 hours to obtain ;

Step 5: taking 4.2 g steps 5 made In 5 ml fully dissolved in the water add 6 ml jing, stirring 2 hours, methanol to the product for the recrystallization, steaming and product, to obtain ;

Step 6: taking 3.2 mg steps 5 made Into 20 ml of N, N - diethyl formamide in, stirring and adding 2.5 mg six hydrated nickel chloride;

Step 7: in 120 °C reaction in a reaction tank 12 hours, generating green crystal nickel-containing coordination polymer.

The nickel-containing coordination polymer of this invention can be used for high temperature-resistant coating.

Embodiment 3

A nickel-containing coordination polymer of preparation method, including:

Step 1: will be 200 g of Under the protection of nitrogen, added to the 1500 ml of ethyl ether in;

Step 2: stirring and adding 40 g sodium hydroxide;

Step 3: added dropwise 20 ml of the sodium bicarbonate solution, the concentration of the sodium bicarbonate solution is 7.2 g/L;

Step 4: adding 212 g iodine, and then adding 2 L of ethyl ether, in the extractor extracting 5 hours to obtain ;

Step 5: taking 4.3 g steps 5 made In 5 ml fully dissolved in the water add 6 ml jing, stirring 2 hours, methanol to the product for the recrystallization, steaming and product, to obtain ;

Step 6: taking 3.2 mg steps 5 made Into 20 ml of N, N - diethyl formamide in, stirring and adding 2.5 mg six hydrated nickel chloride;

Step 7: in 120 °C reaction in a reaction tank 12 hours, generating green crystal nickel-containing coordination polymer.

The nickel-containing coordination polymer of this invention can be used for high temperature-resistant coating.

Embodiment 4

A nickel-containing coordination polymer of preparation method, including:

Step 1: will be 200 g of Under the protection of nitrogen, added to the 1500 ml of ethyl ether in;

Step 2: stirring and adding 40 g sodium hydroxide;

Step 3: added dropwise 20 ml of the sodium bicarbonate solution, the concentration of the sodium bicarbonate solution is 7.2 g/L;

Step 4: adding 212 g iodine, and then adding 2 L of ethyl ether, in the extractor extracting 5 hours to obtain ;

Step 5: taking 4.4 g steps 5 made In 5 ml fully dissolved in the water add 6 ml jing, stirring 2 hours, methanol to the product for the recrystallization, steaming and product, to obtain ;

Step 6: taking 3.2 mg steps 5 made Into 20 ml of N, N - diethyl formamide in, stirring and adding 2.5 mg six hydrated nickel chloride;

Step 7: in 120 °C reaction in a reaction tank 12 hours, generating green crystal nickel-containing coordination polymer.

The nickel-containing coordination polymer of this invention can be used for high temperature-resistant coating.

Embodiment 5

A nickel-containing coordination polymer of preparation method, including:

Step 1: will be 200 g of Under the protection of nitrogen, added to the 1500 ml of ethyl ether in;

Step 2: stirring and adding 40 g sodium hydroxide;

Step 3: added dropwise 20 ml of the sodium bicarbonate solution, the concentration of the sodium bicarbonate solution is 7.2 g/L;

Step 4: adding 212 g iodine, and then adding 2 L of ethyl ether, in the extractor extracting 5 hours to obtain ;

Step 5: taking 4.5 g steps 5 made In 5 ml fully dissolved in the water add 6 ml jing, stirring 2 hours, methanol to the product for the recrystallization, steaming and product, to obtain ;

Step 6: taking 3.2 mg steps 5 made Into 20 ml of N, N - diethyl formamide in, stirring and adding 2.5 mg six hydrated nickel chloride;

Step 7: in 120 °C reaction in a reaction tank 12 hours, generating green crystal nickel-containing coordination polymer.

The nickel-containing coordination polymer of this invention can be used for high temperature-resistant coating.