Preparation method of europium-doped yttrium borate thin film

25-03-2015 дата публикации
Номер:
CN104449716A
Контакты:
Номер заявки: 67-10-20149845
Дата заявки: 24-11-2014



[1]

The invention discloses a preparation method of a europium-doped yttrium borate thin film. The preparation method comprises the following steps: 1) mixing a water-soluble europium salt, a water-soluble yttrium salt, boric acid, water and an alcohols solvent, and mixing and dissolving the alcohols solvent with water; 2) adding a chelating agent and a cross-linking agent into the mixed system obtained in the step 1); 3) reacting the mixed system obtained in the step 2) for 3-5 hours, and leaving the mixed system subjected to reaction to stand for 24-48 hours; 4) performing film coating in a dipping and pulling manner: immersing a silicon substrate into a beaker with a solution according to a film coating speed of 0.3-0.5 cm/s, then performing standing for 5-10 seconds, and pulling the substrate according to the equal speed, so as to finish film coating; 5) after film coating of the silicon substrate, placing the coated silicon substrate into a muffle furnace, calcining the substrate at 400-600 DEG C for 10-15 minutes, and annealing at 400-1000 DEG C for 1-2 hours, so as to obtain the YBO3:Eu<3+> thin film. The preparation method disclosed by the invention has the advantages that the sol-gel dipping and pulling film coating method for preparing the YBO3:Eu<3+> nanomaterial is simple in equipment, low in cost and low in reaction temperature, and can easily control chemical components.



1. A europium doped yttrium borate thin film preparation method, including

1) water-soluble europium salt, water-soluble illinium salt, boric acid, water and alcohol solvent, the alcohol solvent and water;

2) to the step 1) by adding the chelating agent in the mixed system and cross-linking agent;

3) step 2) by the reaction of a mixture system of 3-5h the 24-48h;

4) the manner of coating, silicon film to 0.3-0.5 cm/s immersed in the plating speed in a beaker filled with solution, standing 5-10s, with the same pulling the completion of the speed of the coating film;

5) after plating film silicon film 400-600 the calcining [...] 10-15min, 400-1000 the annealing [...] 1-2h, get YBO3: Eu3+ thin film.

2. Method according to Claim 1, characterized in that the hydrated europium nitrate for the six [...] , the six states the yttrium salt by the hydrated yttrium nitrate, the alcohol solvent is methanol, ethanol and/or isopropyl alcohol.

3. Method as in Claim 1 or Claim 2, characterized in that [...] , illinium salt and the mass ratio of the borate 10-15:1-5: 1-8.

4. Method as in Claim 1 or Claim 2, characterized in that the alcohol solvent is ethanol.

5. Method as in Claim 1 or Claim 2, characterized in that the chelating agent is citric acid, the cross-linking agent is PEG.