20-04-2015 дата публикации
Номер:
KR1020150042285A
Автор:
Принадлежит:
Контакты:
Номер заявки: 70-15-102006676
Дата заявки: 06-09-2013

[1]

The present invention refers to, composite for paste flue, flue module and carbon dioxide for separating complexes of relates to manufacturing method.

[2]

Recent, carbon dioxide in mixed gas selectively separate on technologies of development is performed by. For example, cope with global warming and recovering carbon dioxide in exhaust gas skill or acid, by steam reforming (CO), and modified with a hydrocarbon hydrogen and carbon monoxide and, reacting further carbon monoxide and water vapour for creating and carbon dioxide and hydrogen, carbon dioxide selectively permeate a membrane according to hydrogen by excluding carbon dioxide fuel cell which contains, as the main component be used to achieve of gas such as a, carbon dioxide for separating techniques are form a composite body is.. In a small volume and for the more to treat for separating carbon dioxide filling densely composite module for separating carbon dioxide contained in the cleaning chamber, for passing an gas support and as flow passage materials, membranes and a carbon dioxide containing carrier carbon dioxide, and a porous layer formed with a permeable to gases and remover, inner and outer voids around the shaft support during passage of water gas by effects of a isolation carbon dioxide separation of carbon dioxide in gas, is removing.

[3]

For example, within an 7-102310 Japanese patent gazette flat, carbon dioxide carrier crosslinked structure an aqueous solution containing a vinyl alcohol-acrylic acid salt copolymers-based polymer is formed to absorb a the gel just , promoting charge-transporting film as disclosed is gel guard flue.

[4]

Furthermore, within an WO2009/093666, hydrophobic with porous membrane 2 of layer configurations of stacked porous hydrophilic porous hydrophilic kept on vinyl alcohol-acrylic acid salt copolymers with organic acid, such as cesium, to a carbon dioxide carrier and applying an aqueous solution containing, hydrophilic porous during vinyl alcohol-acrylic acid salt copolymers containing carrier and carbon dioxide formed 110a properties, porous hydrophobic thereon stacked relay an on-the-spot charge-transporting film promoting carbon dioxide, and a stacked body is disclosed is.

[5]

Japanese patent gazette flat gel screen properties are described call 7-102310, containing high quantities of water vapor under pressure high flow (flows) of a method to separate carbon dioxide from a gas is used, the engine the locker by condensate derived from water vapor gel guard first, carbon dioxide is lowering separating function.

[6]

WO2009/093666 call Official Gazette are described as, hydrogel of 2 gel guard clasped between the porous in stellar film laminate transport promoting carbon dioxide, is assembly water condensed by hydrophobic in porous membranethe gel just hydrogel to condensed water intrusion event is prevented is described as. Such a hydrogel when preventing intrusion event is condensed water to the gel just , h2o. hydrogel degradation is reduced flue is and preventing a lowering in the potency.

[7]

However, call WO2009/093666 described Official Gazette a film laminate transport promoting carbon dioxide contained in the cleaning chamber, even during porous hydrophilic gel guard formed on an hydrogel, gas-permeable in a portion thereof discarded decoding unit sequentially, carbon dioxide can be achieved at the separation ability the not. Furthermore, feed gas channel member formed in a region other, feed gas channel member use of substrate via the wire caused by neuromediator recapture disorder is not present.

[8]

The present invention refers to the it is considering, carbon dioxide separating function to 9, pressurized (for example, hundreds kPa or more, and, in its turn for example 1 MPa or more) is an environment, water vapor-containing high flow of a separate carbon dioxide from a gas said water vapor generated in the course derived in decoding unit sequentially separating function carbon dioxide by a condensed water and to control a bias current of coverage, porous protective layer and the current supply in addition by present invention provides for isolated gas flow passage materials (turbulent flow) by the effect of the positive carbon dioxide separating function improved carbon dioxide for separating composite. it is intended to. Furthermore, the present invention refers to, said flue for separating carbon dioxide using composite for paste for separating and carbon dioxide module manufacturing method complexes of time as large as that of it is an object to provide an.

[9]

The present invention refers to hereinafter and equal said a required portion out of a calculation.

[10]

<1>Gas-permeable support and, absorbent polymer and carbon dioxide carrier containing a carbon dioxide isolation layer 12 and a GaN, m or more micro 1 average thickness 500 micro m hereinafter moisture vapour permeable, porous protective layer and, feed gas channel member composite for paste flue comprising a this order.

[11]

<2>Said porous of the protective layer with the central mean pore diameter is 0.005 micro m a m hereinafter micro 1000 or more <1>Described composite for paste separation carbon dioxide contained in the cleaning chamber.

[12]

<3>Porosity of the protective layer with the central porous said a 90% hereinafter is 3% or more <1>Or <2>Described composite for paste separation carbon dioxide contained in the cleaning chamber.

[13]

<4>Said porous protective layer, which is, blends of polyamide blockpolymers and of copolymers, polyvinylidene fluoride, poly methylpentene, poly [...] , polyether sulfone, polypropylene, polysulfone, polyacrylonitrile, polyimides and polyamic at least one of the group are implanted into a semiconductor substrate in <1>∼ <3>Described in claim either composite for paste separation carbon dioxide contained in the cleaning chamber.

[14]

<5>Said porous protective layer and said supply gas flow channel insulating members which are provided in a secured together <1>∼ <4>Described in claim either composite for paste separation carbon dioxide contained in the cleaning chamber.

[15]

<6>Insulating members which are provided in gas flow channel supply said m m hereinafter micro 1000 or more micro 100 having an average thickness <1>∼ <5>Described in claim either composite for paste separation carbon dioxide contained in the cleaning chamber.

[16]

<7>Perforated hollow center tube spirally wound on the heat <1>∼ <6>Described in claim either carbon dioxide separation a composition containing the complex of carbon dioxide for separating module.

[17]

<8>Gas transmitting support containing carrier and carbon dioxide absorbent polymer on applying an aqueous solution and dried, carbon dioxide separation layer forming a carbon dioxide separation layer forming step for, said carbon dioxide separation layer 500 m or more micro 1 average thickness on micro m hereinafter moisture vapour permeable, porous protective layer for laminate porous protective layer formation process for separating complexes of carbon dioxide including manufacturing method.

[18]

<9>Gas transmitting support containing carrier and carbon dioxide absorbent polymer on applying an aqueous solution and dried, carbon dioxide separation layer forming a carbon dioxide separation layer forming step for, said carbon dioxide separation layer 500 m or more micro 1 average thickness on micro m hereinafter moisture vapour permeable, porous protective layer for laminate porous protective layer forming step for, said porous on a protective film forming and bonding the member channel feed gas feed gas channel member including carbon dioxide for separating complexes of a catalyst layer forming step of forming manufacturing method.

[19]

According to the present invention, carbon dioxide separating function to 9, water vapor-containing environment pressurized high flow of a separate carbon dioxide from a gas said water vapor generated in the course derived in decoding unit sequentially separating function carbon dioxide by a condensed water and to control a bias current of coverage, porous protective layer and the current supply gas flow passage materials in addition by present invention provides for isolated by the effect of the positive carbon dioxide separating function improved flue composite for paste is provided.

[20]

Furthermore, according to the present invention, said composite for paste flue for separating module and carbon dioxide using carbon dioxide it is intended to provide a manufacturing method for separating complexes of.

[21]

Figure 1 shows a one embodiment of the present invention also related to form composite for paste flue. of the cross-section of. Figure 2 shows a form one embodiment of the present invention also relates to a manufacturing method for separating complexes of carbon dioxide contained in the cleaning chamber for embodiment one embodiment to a device related manufacture of low-is the directory. Figure 3 shows a form another embodiment of the present invention also relates to a manufacturing method for separating complexes of carbon dioxide contained in the cleaning chamber for embodiment one embodiment to a device related manufacture of low-is the directory. Also Figure 4 shows a composite for paste flue related to the present invention with spiral carbon dioxide embodiment of module for separating ground part representative of the shape and constituting a light coarse is configured.

[22]

Hereinafter, the present invention related to flue manufacturing method for separating complexes of composite for paste and carbon dioxide to the described reference to the drawing. Furthermore, during drawing, the same sign each drawing take identical that represents of the, sound generating bodies the directions of which to the BARC film and the described.

[23]

<Composite for paste flue >

[24]

Also Figure 1 shows a, one embodiment of the present invention related to form composite for paste flue. of the cross-section of.

[25]

Also 1 as shown in the, composite for paste flue related to the present invention (10) the, carbon dioxide separation layer (14) one side of a gas permeable support (12) and is protected by, the average thickness on the other side in addition micro 1 m hereinafter micro 500 m or more moisture vapour permeable, porous protective layer (16) for tire formation that realizes not only is protected, the porous protective layer (16) on feed gas channel member (18) is arranged.

[26]

Furthermore, carbon dioxide separation layer (14) containing the absorbent polymer and carbon dioxide is constituted of carrier. Composite for paste flue is (10) using, feed gas contained in separate carbon dioxide when, feed gas (20) the, first, composite for paste flue (10) the feed gases of the channel member (18) is applied to a multi-. At this time, feed gas (20) the, feed gas channel member (18) in an arrow (20A) of obtain a unidirectional flowing in arrow (20A, 20B, 20C) classification as represented by (branch), diffuse and, then, as such classification, feed gas is diffused from the side wall face of, further porous protective layer (16) by arrow (20D) classification as represented by, after diffused from the side wall face of with a carbon dioxide separation layer (16) is contact with. Feed gas channel member (18) and porous protective layer (16) by classification, diffused from the side wall face of feed gas (20) the, carbon dioxide separation layer (14) a part of the area and available in a wide range, feed gas (20) contained in the carbon dioxide is carbon dioxide separation layer (14) to efficiently absorbed, is diffused to. Therefore, feed gas (20) contained in the carbon dioxide is efficiently separated from one another.

[27]

Furthermore, feed gas (20) condenses steam contained in the composite for paste flue related to the present invention is (10) the feed gases of the channel member (18) even when condensed water is dew condensation in, m or more micro 1 average thickness 500 micro m hereinafter moisture vapour permeable, porous protective layer (16) a barrier is carbon dioxide separation layer (14) elements. intrusion condensed water to. Yet, e.g. carbon dioxide separation layer (14) reaches a rear the condensed water using a water vapor in, as said feed gas (20) is supplied gas flow channel member (18) and a porous protective layer (16) 2 by a layer of two classification, since the-spread, and as volume gas and condensed water, condensed water in addition to a place foroptical local since there is no formed in a, carbon dioxide separation layer (14) dispersed arranging the very less. As a result, movable up and down by even flue composite for paste separation carbon dioxide contained in the cleaning chamber and preventing a lowering in the potency (10) is are obtained.

[28]

Composite for paste flue related to the present invention (10) the, gas transmitting support (12) and a, absorbent polymer and carbon dioxide carrier containing a carbon dioxide separation layer (14) and, m or more micro 1 average thickness 500 micro m hereinafter moisture vapour permeable, porous protective layer (16) and, feed gas channel member (18) comprises sequentially.

[29]

< <Carbon dioxide separation layer >>

[30]

Carbon dioxide separation layer (14) the, absorbent polymer and carbon dioxide carrier contains as layers consisting, preferably homogeneous is formed on. being just, by homogeneous, high carbon dioxide separation ability preferably hole. Wherein, 'homogeneous film' rotation, carbon dioxide separation layer (14) of the long sides of the component comprising the non-is mixed together means film a compressed state, hurrying homogeneous composition, the deemed to substantially uniform also comprise film of States.

[31]

1. Absorbent polymer

[32]

Absorbent polymer a binder functions as which is used, layer flue water tank for keeping water when carbon dioxide is by carrier. to output separation function of effluent. Absorbent polymer a, product contains 0.1 to heating the solutions which have been applied for tire formation that realizes not only to form a, carbon dioxide an isolation layer having high absorbent (moisturizing) in the perspective that, absorbent and has high preferably, absorbent polymer its own weight back 1000 5 times those that absorb hereinafter mass of water is preferably not less.

[33]

Absorbent polymer include, absorbent, film-(maintained in an outer barrel), in terms of ethylene glycol, propylene glycol and glycerol, for example, polyvinyl alcohol-polyacrylate salt and polyvinyl (PVA-PAA) polyacrylic acid-copolymer, polyvinyl alcohol, polyacrylic acid, polyacrylate salt, polyvinyl butyral, poly-N-vinyl pyrrolidone, poly-N- neel Oh set amide , polyacrylamide are preferably present in the salt, in particular PVA-PAA preferably copolymer. PVA-PAA copolymer, having a center hole by four bearings used high ink and even greater strength hydrogel in absorption at the time of. The content in copolymer PVA-PAA polyacrylic zincates, for example 5 molar % hereinafter are preferably present in the salt 95 molar % or more, preferably 30 mol % or more is more preferably, the 70 molar % hereinafter. Polyacrylate salt at, sodium, potassium or ammonium salt in addition to in addition to alkaline metal salts such as organic ammonium salts, and so forth can be mentionned.

[34]

A marketed as copolymer PVA-PAA, AP20-elastomer [...] for example (all: [...][...] manufacturing) :.

[35]

2. Carbon dioxide carrier

[36]

Carbon dioxide separation layer (14) is included in the carbon dioxide carrier, carbon dioxide and which has a high affinity, that is that indicates soluble in addition, is publicly known, use can be made of,. In this case carbon dioxide carrier, whose extraction is rendered acids having affinity for carbon dioxide and, various water-soluble basic indicative of is carried out by using an inorganic and organic material. For example, alkali metal carbonate, alkali metal bicarbonate, alkali metal hydroxide :.

[37]

Alkali metal carbonate at, for example, lithium carbonate, sodium carbonate, potassium carbonate, rubidium carbonate, : cesium carbonate.

[38]

Alkali metal bicarbonate at, for example, lithium hydrogen carbonate, sodium bicarbonate, potassium hydrogen carbonate, rubidium bicarbonate, : cesium hydrogen carbonate.

[39]

Alkali metal hydroxide include, for example, cesium hydroxide, hydroxide: type or honeycomb monolith.

[40]

These, among other things, is preferably alkali metal carbonate, rubidium or cesium preferred are those compounds containing.

[41]

Yet, 2 at least one carbon dioxide carrier may used as a light-weight. For example, potassium carbonate and cesium carbonate: is controlled by a use for goods.

[42]

3. Other constituents as

[43]

Carbon dioxide separation layer (14) the, carbon dioxide separation characteristics as isolation and does not adversely affect the in a range in which the output, absorbent polymer, carbon dioxide carrier and water containing other than component (additive) as described above may be..

[44]

At component optionally employed, for example, absorbent polymer and carbon dioxide carrier containing a carbon dioxide separation layer-forming aqueous solution (coating liquid) a gas transmitting support (12) is deposited onto the and dried, carbon dioxide separation layer (14) in a process for forming, is deposited in a chamber to which the coating liquid is applied said gas transmitting support (12) for cooling to gel for coating oxygens, so-called for setting controlling also disclosed are a gelling agent, or applicator used to apply a coating liquid said device applied as a at the time of application at the time of the viscosity modifier number, an abstraction layer carbon dioxide for improving membrane strength, which number crosslinked, carbon dioxide absorption accelerator, while allowed to be surfactant, catalyst, auxiliary solvent, number adjusting membrane strength, which, in addition, carbon dioxide contained in the cleaning chamber forming an abstraction layer deficiency in which accuracy of inspection to facilitate as to the aromatic hydrocarbon detecting number.

[45]

3-1. Gelling

[46]

Said gelling include, absorbent polymer and, carbon dioxide carrier, compositons, 50 °C composition coating liquid containing at least one fatty acid which is, thickness 1 mm hereinafter applied as a solution, the application surface 12 °C onto the then two under under temperature conditions of 120 seconds or less by gelling during the elapsed time, said a horizontal oxygens applied even when placed at an angle of other than, 1 by the force of gravity on thicknesses is the same within a minutes does not be varied according having the properties of gelling can be mentionned. The gelling in one embodiment users can current agar.. As commercial products, or agar UP-37, UM-11S, SY-8, ZY-4, ZY-6 (or more, or agar yarn), Agarose H, (or more, manufacturing curious matter[...]) Agarose S as to the aromatic hydrocarbon. By gelling the, gas transmitting support (12) during absorbent polymer or the like at component from entering to a gas transmitting support (12) gas-permeable of. capable of suppressing a drop in the.

[47]

3-2. Number viscosity modifier

[48]

Viscosity modifier said examples a preferred agent, . users can carboxymethyl cellulose. Flue layer-forming aqueous solution (coating liquid) by containing red methylcellulose which has been milled to a of the carboxylic, for example 3 two roll such as roll coater to facilitate anti-aging in cotter can be. Furthermore, gas transmitting support (12) into absorbent polymer or the like at component from entering to a gas transmitting support (12) gas-permeable of. capable of suppressing a drop in the.

[49]

3-3. Crosslinked number

[50]

Absorbent polymer crosslinked to separation layer, carbon dioxide to form a (14) may enhance the strength of, in this case the crosslinking hinders thermally crosslinked, UV crosslinking, electron beam crosslinked, a technique publicly known conventional such as radiation cross-linking is the embodiment. The engine thereby for reducing fuel consumption, polyvinyl alcohol-polyacrylate salt copolymer heat and reacting the absorbent such as groups and are capable of causing crosslinking functional group (crosslinked functional groups bonded) a crosslinked polymer component the use of a crosslinking agent having 2 or more to form a structure in terms of improved membrane strength, which preferably, is a crosslinker capable of crosslinking use in 2 a reactive functional group include the a crosslinker having a or more, multivalent [...] , a polyhydric alcohol, polyhydric isocyanate, polyhydric aziridine, halo epoxy compound, multivalent aldehyde, as to the aromatic hydrocarbon multivalent amine.

[51]

3-4. Carbon dioxide absorption accelerator

[52]

The promoter are deposited on the carbon dioxide absorber, carbon dioxide and carbon dioxide which is to promote a reaction of carrier, for example nitrogen containing compounds and sulfur oxides comprises.

[53]

Said nitrogen containing compounds include, for example, glycine, alanine, serine, proline, histidine, taurine, diaminopropionic acid such as amino acid derivative and method for manufacturing, pyridine, histidine, piperazine, imidazole, current hetero compounds such as triazine, monoethanolamine, diethanolamines, triethanolamin, mono the propane the amine which comes , deep with it sells and the amine which comes , tree propanol amine such as alkanol amines or, [...] discharging oil from oil pan of vehicle [2.1], [2.2] [...] discharging oil from oil pan of vehicle such as cyclic polyether amines, [...] discharging oil from oil pan of vehicle [2.2.1], such as [2.2.2] [...] discharging oil from oil pan of vehicle pair ring style polyether amines or porphyrin, phthalocyanine, ethylenediamine, use can be made of, such as acetic acid 4.

[54]

Said sulfur compounds include, for example, cystine, cysteine such as amino acid derivative and method for manufacturing, polythiophene, , use can be made of, such as use of Saccharomyces cerevisiae thread mote this year.

[55]

When adding a promoter carbon dioxide, carbon dioxide an abstraction layer % %, of the total weight 20 mass % or more in the range of 200 mass % hereinafter it is and down.

[56]

Carbon dioxide separation layer (14) has average thickness in the range of carbon dioxide separating function are achieved excellent in, micro 5 are preferably present in the salt m hereinafter micro 50 m or more, 10 micro m or more is preferably m hereinafter micro 40, 15 micro m or more in particular is preferably 30 micro m hereinafter.

[57]

<M hereinafter micro 500 m or more micro 1 < average thickness aodirenc moisture vapour permeable, porous protective layer > >

[58]

Composite for paste flue related to the present invention (10) of said porous protective layer (16) the, said carbon dioxide separation layer (14) is subjected to pressure is applied to the modified to prevent a thin film, in addition carbon dioxide separation layer (14) contact with an feed gas (20) for classification, the method for uploading file from user terminal by a rope..

[59]

Porous protective layer (16) the, average thickness of 1 micro m or more and 500 micro m hereinafter, carbon dioxide permeable, water vapor permeable in addition which liquid of water-transmission type LCD includes porous is of. Porous protective layer (16) has average thickness in the range of 1 micro m when the thinner than, carbon dioxide separation layer (14) is under pressure prevent a deformation of a a function and thereby a, 500 micro m if the load gradient exceeds the first, feed gas (20) material is a porous protective layer (16) thickness direction of the impeded on account of passage to, carbon dioxide used the tolerances separating function having a center hole by four bearings, for example spiral carbon dioxide for separating module according to the above constitution, by the refrigerant cooling means is too diameter wound size increases discarded, the free surfaces which is likely to occur is deficiency. In balance both, porous protective layer (16) has average thickness in the range of 1 m hereinafter are preferably present in the salt 500 micro micro m or more, 10 micro m or more preferably is 100 micro m hereinafter.

[60]

Said porous protective layer (16) the, carbon dioxide permeability and water vapor permeable is the needed and, condensate water derived from water vapor in addition does not transmitted. Therefore, porous protective layer (16) a non-woven fabric is covered holes, 0.005 micro m m hereinafter micro 1000 or more axial flow fan is improved to prevent mean pore diameter of is preferably not less. Feed gas (20) material is a porous protective layer (16), it will quickly penetrate the than in the thickness direction of and, excellent material flue in addition performance is kept at a advantage since the obtained at, m micro 0.005 micro m hereinafter more preferably 500 or more, m micro 0.01 micro m hereinafter more preferably 100 or more. Wherein, the mean pore diameter said yarn PMI 'farm porometer' when measured by sunshine. values calculated.

[61]

Furthermore, said porous protective layer (16) the, porosity is 3% or more is preferably not less range of 90% hereinafter. The porosity range of a porous protective layer (16) is formed in a manner that, feed gas (20) material is a porous protective layer (16), it will quickly penetrate the than in the thickness direction of and, maintaining superior performance in addition carbon dioxide membrane as separation membrane together.. The porosity said, preparation, can produce its effect turbulence of the gas is obtained advantages that since the, 5% or more, and more preferably in a range of 70% hereinafter and, 10% or more in a range of 70% hereinafter is more preferably.

[62]

Said porous protective layer (16) constituting the a plating member, a deposition member, m or more micro 1 average thickness 500 micro m hereinafter porous layer maybe formed is present, , use can be made of, without limited to, extracts of Barks of. For example, blends of polyamide blockpolymers and of copolymers (PTFE), polyvinylidene fluoride (PVDF), poly methylpentene, poly [...] (PPS), polyether sulfone (PES), polypropylene (PP), polysulfone (PSF), polyacrylonitrile (PAN), polyimide, polyamides, etc :. The engine thereby for reducing fuel consumption, is preferably hydrophobic, water vapor permeable derived from water vapor in addition which condensate water-impermeable of high strength steel sheet having excellent PP and preferably is PTFE. The engine thereby for reducing fuel consumption, PTFE whereon a plurality of mean pore diameter a porous film since in similar to an in commercially available, . easily-available.

[63]

Also, feed gas channel member (18) when the articles made from PP is, porous protective layer (16) constituting material and to achieved by applying it to an PP, heating both by fusing the advantage that is capable of securing the, resulting in a is advantageous in..

[64]

< <Feed gas channel member >>

[65]

Feed gas channel member (18) the feed gas (20) and the light diffusion layer is a layer is transported from, with as spacers, in addition feed gas (20) classification during passage of water, generate diffusion. In the present invention, the feed gas channel member (18) provided to a, carbon dioxide is fully exhibited unit module for separating.

[66]

Feed gas channel member (18) as, 30 micro m or more size scale micro 2000 has net m hereinafter is preferably used. Net by the configuration of feed gas (20) since the changed flow path, the shape of the a unit lattice net for example, dependent of diamond shaped of purposes, such as on the shape of the parallelogram is by finding the. Furthermore, tensile and a ventilation sufficient to the stresses Academic tolerant having is present, nonwoven fabric, woven, use can be made of, for room to guide the knitting.

[67]

Yet, high temperature from being forcedly stopped during process by feed gas (20) to supply a baseband surface, feed gas channel member (18) having the resistance to moist heat and it is preferable that the.

[68]

Wherein, 'heat-resistant wet' during 'heat resistance' rotation, humidity resistance, has a high or more 80 °C. line will be. Specifically 80 °C or more email widow, a web page or heat resistance, a temperature above 80 °C 2 under conditions preserving even after the stored time before in the vertical direction and, by hot melt or heat shrink visual can be identified by their thermally comprises a. through a repeater. Also, 'heat-resistant wet' during 'moisture' rotation, 2 under conditions of 40 °C 80% RH preserving even after the stored time before in the vertical direction and, by hot melt or heat shrink visual can be identified by their thermally comprises a. through a repeater.

[69]

Feed gas channel member (18) of material includes no, but not limited, for example, paper, rough paper, does coating, cast coating does, synthetic paper, cellulose, synthetic resin, metal, glass, ceramic for forming an inorganic material or the like can be mentionned. Said synthetic resin include, polyethylene, polystyrene, polyethylene terephthalate (PET), polyethylene naphthalate (PEN), blends of polyamide blockpolymers and of copolymers (PTFE), polyether sulfone (PES), poly [...] (PPS), polysulfone (PSF), polypropylene (PP), polyimide, polyether-imide, polyether-ether-ketone and polyvinylidene fluoride (PVDF) or the like can be mentionned as preferably.

[70]

Also, already described is formed of an inorganic material or a resin, a fiber-, monofilament, a nonwoven fabric made by using the code, woven, room to guide the knitting is preferably used.

[71]

Furthermore, preferred processes terms of resistance to moist heat and material includes, ceramic, glass, inorganic material point metal, e.g., 100 °C or more heat, etc. as to the aromatic hydrocarbon and organic resin material, high molecular weight polyester, polyolefin, polyamide heat resistance, polyimide, polysulfone, aramid, polycarbonate, metal, glass, preferably of ceramic, use can be made of,. More specifically, ceramic, blends of polyamide blockpolymers and of copolymers, polyvinylidene fluoride, polyether sulfone, poly [...] , polysulfone, polyimide, polypropylene, polyether-imide and polyether-ether-ketone at least a material selected from the group consist of 1 a containing a material for the it is preferred that a.

[72]

Feed gas channel member (18) at least substantially co-extensive. available the commercial products.

[73]

Feed gas channel member (18) has average thickness in the range of is not particularly limited in but, micro 100 are preferably present in the salt m hereinafter micro 1000 m or more, more preferably 950 micro m hereinafter micro 150 m or more, more preferably 200 micro m is m hereinafter micro 900 or more.

[74]

Feed gas channel member (18) the, porous protective layer (16) fixedly mounted to the single fan blade is preferably in the. Thereby, feed gas channel member (18) and a porous protective layer (16) the light is disposed between the side relatively can be. Feed gas channel member (18) and a porous protective layer (16) are fixed together by the fused it is preferable that the. Fused to facilitate the, feed gas channel member (18) and a porous protective layer (16) the same material is used and a is preferably in the. For example, both is used and as the polypropylene material is preferably in the. Furthermore, fused include portions which are based the front and need not be printing, feed gas channel member (18) and a porous protective layer (16) in a direction parallel to same time, the flowing speed is circulator can be prevented if, in addition or alternatively the components randomly rare it is rare.. For example, open/1 cm2 or more, and down range of open/10000 cm2 hereinafter.

[75]

< <Gas transmitting support >>

[76]

Gas transmitting support (12) the, gas-permeable, the engine thereby for reducing fuel consumption of carbon dioxide-permeable base and has is not particularly limited in a.

[77]

Gas transmitting support (12) of material includes, paper, rough paper, does coating, cast coating does, synthetic paper, cellulose, polyester, polyolefin, polyamide, polyimide, polysulfone, aramid, polycarbonate, metal, glass, preferably of ceramic, use can be made of,. More specifically, polyethylene, polystyrene, polyethylene terephthalate, blends of polyamide blockpolymers and of copolymers, polyether sulfone, poly [...] , polysulfone, polypropylene, polyether-imide, polyether-ether-ketone polyvinylidene fluoride and the resin material or the like can be preferably.

[78]

Gas transmitting support (12) the, carbon dioxide separation layer (14) separated by since the passage of carbon dioxide, of carbon dioxide permeable. it is required that a wax is added to the mixture. Therefore, carbon dioxide separation layer (14) constituting the absorbent polymer or the like a gas permeable support (12) retrieval object word is not intrusion during it is preferred that a.

[79]

The in terms, and is most desirable if porous resin sheet, porous resin sheet composite support of a non woven web is also a preferred embodiment. Porous resin sheet the case of composite support of a non woven web, carbon dioxide separation layer (14) the, porous resin sheet the surface thereof containing carrier and carbon dioxide absorbent polymer applicator used to apply a coating liquid and dried or is formed, said on temporary support or pre applicator used to apply a coating liquid and dried, carbon dioxide separation layer (14) and thus forming the, is carbon dioxide separation layer (14) of said composite support porous resin sheet onto a receiving surface to side is formed by.

[80]

Porous resin of diameter is absorbent polymer protecting against the ingress of, e.g. preferably in terms that. Specifically maximum pore diameter is 0.05 m hereinafter micro micro m is preferably 0.5 or more, 0.2 0.05 micro m or more. and it is more preferred to set a micro m hereinafter. Available pushed outwardly in terms most relevant ranges are 0.05 micro m is m hereinafter micro 0.2 or more.

[81]

Wherein, said 'maximum pore diameter' hereinafter of the method which are measured by means of a value.

[82]

(Maximum pore diameter measurement of pore diameter and minimum method)

[83]

Maximum pore diameter to, maximum by the bubble point pore diameter for it was determined that (the bubble point). Measuring device PMI as employ the porometer farm yarn (in conformity with JIS K 3832), four-way specifically a porous resin sheet cut to 3 cm, (the week misfortune which will go) to immersed into liquid surfactant. Extra surfactant solution for reading out the lightly wiped and then, 2 is larger than the distance between the metal mesh of device of measuring cell is set. Measuring room temperature using the week misfortune which will go as an etchant (25 °C) gradually increases air by pressure with the pair of polishing, the bubble point long since determined the.

[84]

Gas transmitting support (12) the, at least carbon dioxide separation layer (14) plate and meats from being exposed to a surface of the side is preferably not less hydrophobic surface. Carbon dioxide separation layer (14) a surface of the side plate and meats from being exposed to hydrophobic surface by having, separation layer (14) a gas permeable support (12) in a heat-during can be prevented more effectively if just, plurality. If the hydrophilic surface, absorbent polymer and carbon dioxide containing carrier applicator used to apply a coating liquid and dried when is formed, absorbent polymer with a gas-permeable support (12) making it easier for the player to hole during invasive, or with decreased or gas permeability, whereby heterogeneous, flue layer with. get a visual effect. Furthermore, under use environment containing moisture carbon dioxide separation layer (14) the thus making it easier for the player from being absorbed into the holes, carbon dioxide separation layer (14) according to thickness of time distribution or. even cause performance degradation.

[85]

Wherein, rotation 'hydrophobic' , room temperature (25 °C), a contact angle of water on. indicating it is an above 100°.

[86]

Said porous resin sheet include, generally high self-supporting property, high peat moss, coconut peat, use can be made of, preferably exist. The engine thereby for reducing fuel consumption, polypropylene, fluorine-containing resin selected from the group consisting of a resin using the method for the formation of preferably is a porous resin sheet.

[87]

More specifically, poly [...] , polysulfone, blends of polyamide blockpolymers and of copolymers, polyvinylidene fluoride, high molecular weight polyethylene stretch porous membrane, or the like, that has high peat moss, coconut peat, is less inhibit the spread of carbon dioxide, preferably in terms of printability or production strength.

[88]

These, among other things, , heat resistance, in terms of durability, as resin material, (PTFE) blends of polyamide blockpolymers and of copolymers, polyether sulfone, poly [...] , polysulfone, polypropylene, polyether-imide, polyether-ether-ketone and polyvinylidene fluoride (PVDF) paper preferably at least 1, in terms of stability according to time n-methylpyrrolidone solution preferably, use can be made of, in particular.

[89]

Composite for paste flue (10) the, corresponding to an application place in temperature used hereinafter but, for example, 130 °C degree of temperature with the maximal water vapor-containing in addition a cold water valve is shut used.. Therefore, gas transmitting support (12) the, structure even in 130 °C and that produces less change in humidity resistance, has a high, the hydrolyzable also it is preferable that the can be made of materials. Such in terms, polypropylene or blends of polyamide blockpolymers and of copolymers (PTFE), polyvinylidene fluoride (PVDF) such as fluorine-containing resin selected from the group consisting of a resin using the method for the formation of which preferably is, most preferably is porous PTFE sheet.

[90]

Porous resin sheet, alone gas transmitting support (12) but may be use as, dynamic assignment switching in the sheet for reinforcing and composite support, for example, a non-woven fabric having superior air-permeability for reinforcing carbon dioxide separation layer (14) and contacted with the laminated on the side of the composite dynamic assignment switching in the translations and also preferably support or the like, use can be made of, the.

[91]

Gas transmitting support (12) the, gas-permeable properties and strength and a a in terms, average thickness of 30 micro m m hereinafter micro range of 500 or more is preferably not less. Average thickness of 500 micro good gas permeability, is m hereinafter, if the flow is greater than the 30 micro m. is satisfactory in strength. And, in its turn, micro 50 m or more is preferably 300 micro m hereinafter, micro 50 more preferably, the is m hereinafter micro 200 m or more.

[92]

<Carbon dioxide for separating complexes of manufacturing method >

[93]

Next, related to carbon dioxide for separating complexes of the present invention relates to manufacturing method.

[94]

Also Figure 2 shows a, carbon dioxide contained in the cleaning chamber associated to one embodiment of the present invention for separating complexes of embodiment for manufacturing method of one embodiment to related manufacture of low-device (50) is the directory a. Manufacturing device of Figure 3 in feed gas channel member (18) of a is device manufacturing.

[95]

Figure 3 shows a also, another embodiment of the present invention for separating complexes of carbon dioxide contained in the cleaning chamber associated to manufacturing method of one embodiment to embodiment for device (60) related manufacture of low-is the directory a.

[96]

Also 2 as shown in the, disk ([...]) roll (12A) sent the direction of an arrow from a gas permeable support (12) unloading means has a roll (46) is transfer while the substrate is supported by. First, device (52) applied in, liquid to the chemical liquid storage member (14A) carbon dioxide in separation layer-forming aqueous solution (coating liquid) the, an applying die and a (52A) and transferred to, an applying die and a (52A) and from the carrying roll and a back-up roll (52B) suspended so that gas transmitting support (12) is applied to the surface of. Next, gas transmitting support (12) coating a dry device (54) oxygens dried in. Drying device (54) in, drying air is just being dispensed hot-wire irradiation, the hook unit is hung to set down by a combination of such this dried carbon dioxide separation layer (14) is formed. Next, roll (16A) transmitted by a porous protective layer formation film (16B) is, 1 pair of rolls (56, 56) is laminate by carbon dioxide separation layer (14) on the surface of porous protective layer (16) is formed. The composite for paste the produced carbon dioxide separation (10), into which the roll (10A) is wound as.

[97]

Also, manufacturing device of Figure 3, as shown to, porous protective layer (16) further on roll (18A) transmitted by a feed gas channel member (18B) is 1 pair of rolls (58, 58) is by bonding is performed, feed gas channel member (18) are combined by is..

[98]

For separating complexes of the present invention related to carbon dioxide according to manufacturing method, gas transmitting support (12) roll disk fabrication method of a recording medium (12A) from long gas transmitting support (12) and to transport at to the breaker thereby to bring the continuously, the same transfer in gas transmitting support (12) on the surface of, absorbent polymer and carbon dioxide applying an aqueous solution containing carrier and dried, carbon dioxide separation layer (14) is formed, is carbon dioxide separation layer (14) on average thickness 0.1 micro m m hereinafter micro 500 or more moisture vapour permeable, porous protective layer (16) a laminate it formed[...] formed, is absent in the data processing system wound films on a roll, roll/to/roll continuous method composite for paste flue high productivity by (10) can be produced.

[99]

Said carbon dioxide separation layer (14) physical pressure, or the like is deformed due to, rubbing can easily it also becomes possible to essentially properties of wet liquid to flow down. Composite for paste flue related to the present invention (10) according to manufacturing method of, as a completely surrounding films on a roll, carbon dioxide separation layer (14) one side of a gas permeable support (12) and is protected by, the average thickness on the other side in addition micro 0.1 m hereinafter micro 500 m or more moisture vapour permeable, porous protective layer (16) since in similar to an in protected, though a physical pressure is applied, even if it is subjected to such as, rubbing, carbon dioxide separation layer (14) is one from being lost. is easy to handle.

[100]

Furthermore, manufacturing of Figure 3 made of composite for paste a carbon dioxide separation device (10) according to manufacturing method of, said porous protective layer (16) further on feed gas channel member (18) arranged since the, similarly physical pressure, even if it is subjected to such as, rubbing, carbon dioxide separation layer (14) is one from being lost. is easy to handle.

[101]

< < flue layer-forming aqueous solution (coating liquid) aodirenc coating process of> >

[102]

The process, applied device (52) by conveyed in constant direction onto a gas-permeable support (12) on the surface of flue layer-forming aqueous solution (coating liquid) (14A) is for applying a process.

[103]

Coating liquid (14A) at content of absorbent polymer in, but also comprises the following several steps thereof, flue layer, carbon dioxide an isolation layer thereof is kept adjacent to the moisture in the perspective that, 1 mass % or more is preferably 30 mass % hereinafter, 2 mass % or more and it is more preferred to set a 15 mass % hereinafter..

[104]

Device (52) applied the, formulated coating liquid is immersed into a liquid to the chemical liquid storage member (14A) and a, liquid to the chemical liquid storage member (14A) oil accumulated on a back-up roll and roll transfer applicator used to apply a coating liquid (52B) suspended so that gas transmitting support (12) applied to the surface of an applicator die (52A) is provided. An applying die and a (52A) the, support and a gas-permeable portion flow rate of coating liquid (12), thus freeing the gap width and, various thickness of various to a support can be as to have an equal thickness over. Liquid to the chemical liquid storage member (14A) the, but a protruded shown, coating liquid for controlling temperature of the coating liquid heaters and for agitating the stirring device is formed.

[105]

Device (52) applied the, said configured is supported by the upper case and limited to, for example, curtain flow coater, [...] die coater, air doctor coater, blade coater, rod coater, knife coater, squeeze coater, reverse roll coater, bar coater such as is are appropriately selected. In particular, the thickness uniformness, in terms of amount and the like applied [...] die coater is preferably.

[106]

The amount applied, coating liquid composition composition, but also other according to concentration, the application amount of per unit area if the refrigerant cooling means is too less is formed or having an opening to the internal surface coating in drying step, carbon dioxide separation layer as strength is insufficient or has a risk that.. On the other hand, if there are multiple said by the refrigerant cooling means is too the application amount, or using a deblocking filter imposes a significant deviation in thickness of, an abstraction layer carbon dioxide obtained size increases too is overlapped with with decreased or permeable of carbon dioxide has a risk that..

[107]

In view hereof, gas transmitting support (12), ; and a coating applied to the surface of oxygens has average thickness in the range of 30 micro m or more, more preferably 50 micro m or more, preferably at least 100 micro m in particular.

[108]

< < flue layer-forming aqueous solution (coating liquid) for drying oxygens application of > >

[109]

The drying step, drying device (54) gas in transmitting support (12) an applicator formed on separation layer, carbon dioxide drying the oxygens (14) is which comprises the step of obtaining an. Furthermore, at this time, simultaneously thermally crosslinked, as desired may the embodiment. For example, drying device (54) in gas transmitting support (12) coating oxygens to but drying [...] hot air is blown to it, to which the coating liquid is a cross-linking agent when the, is hot and the processing advances the crosslinking reaction has by heating.

[110]

When injection hot air is blown to it, oxygens coating wind speed thereof the to rapid drying, speed not Revetement just the form of oxygens applied in addition, for example, 1 m/minute or more 80 m/min it is preferred to set a set to hereinafter, and, in its turn 6 m/minute or more is preferably hereinafter 70 m/min, and, in its turn 10 m/minute or more in particular hereinafter is preferably 40 m/min.

[111]

Temperature of hot, rapidly oxygens applied to dry dried 20 °C or more it is preferred to set a set to 80 °C hereinafter, and, in its turn 30 °C or more preferably is 70 °C hereinafter, is in particular preferably 60 °C hereinafter and, in its turn 40 °C or more.

[112]

When a cross-linking agent to which the coating liquid is, drying in process for drying and thermal the crosslinking hinders embodiment and may be simultaneously, the iwfs may the embodiment. For example, dried and subsequently [...] coating film to hot air is blown to it, by a heating means such as infrared heaters is conducted crosslinked, making machine by drying is conducted crosslinked with. A thermally crosslinked, for example 150 °C hereinafter degree by heating 100 °C or more can be embodiment.

[113]

< <Porous protective layer formation process >>

[114]

Said coating process and a drying step are air established via gas transmitting support (12) on carbon dioxide separation layer (14) on the roll (16A) transmitted by a porous protective layer formation film (16B) and is stacked on an, 1 pair of rolls (56, 56) between nip force value in which they are pressed in at by passing them through a laminate is, porous protective layer (16) is formed.

[115]

1 pair of rolls (56, 56) the on at least one side, heating roll-in is preferably in part. The heating temperature, carbon dioxide separation layer (14) then, the influence to or gas transmitting support (12) or do not affect the, maximum, not affected by it is preferred that a set so as to. Therefore, low temperature low pressure force which in addition. it is desirable that laminate. For example, porous protective layer formation film (16B) PTFE porous as where in the use of an, roll (56) is in the range of 70 °C ∼ 120 °C surface temperature of the is preferably not less. By temperature range the, porous protective layer (16) gas-permeable form without a great impact on, carbon dioxide separation layer (14). is closely attached to a. , Wherein when a, surface temperature 70 °C ∼ 120 °C heating method for manufacture metal matrix composite are preferably present in the salt, and wet-heat-resistant adhesion satisfactory in, in addition that it is inhibited from changing in shape of support 80 °C ∼ 110 °C in terms that range of preferably than. A surface temperature of heating roller, is publicly known contact type or non-contact type. can be measured with high a digital thermometer.

[116]

Using a porous protective layer formation film (16B) or gas transmitting support (12) having a heat resistance and a roller surface properly according to thickness for regulating the temperature, it is possible to deposit an, 1 pair of heating roller crossing perpendicularly to both of the heater to, same heating roller of both temperature conditions and may be, and may be different temperature conditions, and including heater having the only roller side in addition, .may be support roller other round. At this time, other support roller that does not have a heater, and may be metallic roll, rubber, a roll or surface constituted of a soft resin layer may be at linear pressure of an elastic roll having.

[117]

< <Feed gas channel member forming process >>

[118]

Said coating process, drying step and porous protective layer formation process is performed by contact with the protective layer (16) the, roll (18A) transmitted by a film for forming member channel feed gas (18B) and is stacked on an, 1 pair of rolls (58, 58) between nip force value of cycloolefin resin and, bonded therewith by passing them through a, feed gas channel member (18) is formed. Process forming member for gas flow channel is supplied, said porous protective layer formation second support layer and the first air can be embodiment in method.

[119]

Composite for paste flue related to the present invention (10) for, a aspect a preferred embodiment for separating carbon dioxide spiral refers to as the same mounted in a module to become, feed gas channel member (18) to symmetric separating members, wherein, feed gas channel member (18) on both sides of porous protective layer (16), carbon dioxide separation layer (14) and gas transmitting support (12) is an arrangement wherein. The driving coil has a plurality of composite for separating carbon dioxide, carbon dioxide for separating composite representing in Figure 1, feed gas channel member (18) is inward can be obtained by folding the in half but, gas transmitting support (12) on carbon dioxide separation layer (14) and porous protective layer (16) made and intermediate is formed, is intermediates, feed gas channel member (18) separating members, wherein porous protective layer (16) the folding from two halves that are is the inner (hereinafter, same 'semi folding the composite for paste flue' him. a) may for producing.

[120]

<Module for separation of carbon dioxide >

[121]

Composite for paste flue related to the present invention (10) for separating the carbon dioxide is carried out by using an acidulous mounted in a module to become. Carbon dioxide mounted with the limited to, extracts of Barks of the type of separation module, is carried out by using an acidulous to properly device a publicly known. In embodiment which indicates to hereinafter, composite for paste flue (10) is, to hollow center tube opening, spirally carbon dioxide spiral containing box is passed, for example, module for separating but described example, not limited to this.

[122]

Figure 4 shows a also, composite for paste flue related to the present invention (10) for separating carbon dioxide spiral with embodiment of module ground part representative of the shape and constituting a light coarse is configured.

[123]

Spiral carbon dioxide for separating module (90) the, its base structure holes ore is formed a hollow a transmission gas collecting pipe (82) the periphery of the workpiece, semi folding the composite for paste flue (100) and transparent gas flow channel member (30) a nest (92) for, said semi folding the composite for paste flue (100) for hending side end parts disclosure side wound for transmission gas collecting pipe (82) which is composed of an winding a plurality the periphery of the workpiece, most outer circle coating layer (94) and covered, each both ends of power line [...] (88A, 88B) consists of is attached.

[124]

The driving coil has a plurality of carbon dioxide separation module (90) the, in its one end (80A) composite for paste flue from side (10) the feed gases of the channel member (18) a mixed polymer composition comprising a based on supplyingcarbon dioxide to the supply by being supplied with gas, establishing an optical fiber at a side feed gas channel member (18) during passing through the, carbon dioxide is of exclusions, thereof rest of the gas (22) and a carbon dioxide excluded data (24) at other end (80B) by a rope. discharge the iwfs side.

[125]

Transmission gas collecting pipe (82) the, wall thereof provided with a plurality of through holes (82A) is won a conventional tube. Transmission gas collecting pipe (82) one end side (one end (80A) side) tube side of a shell and tube with a closed is formed from, tube separation is supplied (other end (80B) side) have a composite for paste flue (10) by transmitting them through the through hole (82A) from aggregated carbon dioxide (24) is exit (96) and which is.

[126]

Coating layer (94) the, carbon dioxide for separating module (90) of the feed gas (20) being able to block formed blocking material having improved UV cutting ability. Is has wet heat resistance blocking material having improved UV cutting ability is preferably in the.

[127]

[...] of power line (88A, 88B) is of a material resistant to wet heat-resistant each is preferably in the.

[128]

A permeate gas channel member (30) the, carbon dioxide separation layer (14) react carrier dioxide in, gas transmitting support (12) through the outlet, and a carbon dioxide (24) passing gas collecting pipe (82) of through holes (82A) directed is members, and further sent forward. A permeate gas channel member (30) the, with as spacers, feed gas channel member (18) and the same manner as the calculator preferably has net. A permeate gas channel member (30) is made out of a feed gas channel member (18) and a a differential refractive index using the same can be. Yet, high temperature from being forcedly stopped during process by gas feed (20) since the flowing, a permeate gas channel member (30) having the resistance to moist heat and it is preferable that the.

[129]

A permeate gas channel member (30) of the specific material is, epoxy impregnated polyester such as polyester, polyolefin polypropylene, preferably gage fluorine such as blends of polyamide blockpolymers and of copolymers.

[130]

A permeate gas channel member (30) but is not particularly limited in the thickness of the, micro 100 are preferably present in the salt m hereinafter micro 1000 m or more, more preferably 950 micro m hereinafter micro 150 m or more, more preferably 200 micro m is m hereinafter micro 900 or more.

[131]

In the embodiment

[132]

Thereby, the cold air flows example embodiment hereinafter to the present invention further specifically, .. Furthermore, with a material that exhibits aspect embodiment of hereinafter, usage, ratio, processing content, procedures, or the like, that has, not deviating form the of the present invention an RC has been can be 506. Therefore, embodiments of the present invention which indicates to hereinafter range and interpreted defined by 10 not.

[133]

Also, specially to dually function as a pipeline and not, a ' %' described hereinafter, the 'unit' , each ' %' , 'parts by mass of mass' . mixture by the addition of an initiator. Furthermore, 'thickness' the' average thickness '. mixture by the addition of an initiator.

[134]

[In the embodiment 1]

[135]

<Preparation of coating liquid layer flue >

[136]

Polyvinyl alcohol-polyacrylic acid copolymer (AP-22 elastomer [...] , [...][...] manufacturing) added with stirring, in a water to. Then cesium carbonate aqueous solution (solid content: 40%)an aqueous potassium and sodium carbonate (solid content: 40%)adding an, temperature 25 °C agitation sufficiently under a condition of the embodiment, soluble polymer having a shrinkage on film formation polyvinyl alcohol-polyacrylic acid copolymer concentration of 2.5%, 0.25% [...] (Tajawako [...]), cesium carbonation to precipitate platy calcium carbonate carbon dioxide carrier each concentration of potassium carbonate in aqueous solution and 1.0% and 6.0%, coating liquid layer flue the gun which burns the embodiment (1) is obtained.

[137]

<For the manufacture of composite materials for separation of carbon dioxide >

[138]

Average thickness 300 micro m hydrophobic fine gas transmitting support (you manufacturing if a malfunction of the GE) on said flue layer coating liquid (1) applying a is formed to allow the plating solution and dried, carbon dioxide separation layer. An abstraction layer carbon dioxide obtained has average thickness is 50 micro m, the content was 55%. A hydrophobic microporous gas transmitting support the carbon dioxide but not from entering the an isolation layer, cross section SEM Image of the object been identified.

[139]

0.05 mean pore diameter on separation layer carbon dioxide is micro m, m micro 40 thickness, porosity of 70% PTFE (yarn-Gore) are formed at the protective layer porous by a laminated. Intermediates same. is 1.

[140]

Intermediates for 1, porous protective layer, which is folded up from two halves that are inside a. At this time, , feed gas channel member and interposed net polypropylene of 0.5 mm thickness as, porous protective layer in region random net polypropylene and by [...] , composite for paste flue 1 is obtained. A thus obtained is matched with a composite for paste flue of the bendings of member folding the half 1 1 side to connect an outer of the fecal material are 3 (a hydrophobic microporous gas permeable support mean and a cylinder) end of both sides of, high viscosity (about 40 Pa/s) of an adhesive epoxy resin (( [...] manufacturing) E120HP) a voltage is applied to the, number polyester impregnated epoxy knitting coat tree one side a permeate gas passage member time and a falling time by overlapping, to the outside material gas flow channel display an Image, comprising a transmitting transmission gas collecting pipe he wreathed his multiple the periphery of the workpiece.

[141]

Thereby, manufacturing processes and the cost of production 1 module for separating carbon dioxide. The module was 0.025 m2 the effective area an abstraction layer carbon dioxide.

[142]

[In the embodiment 2]

[143]

In the embodiment 1 in, porous m micro 1 mean pore diameter as a protective layer, thickness 40 micro m, consisting of 70% porosity (yarn-Gore) PTFE the region other than the paste using, in the embodiment 1 and a second stage 2 module for separating carbon dioxide have been prepared.

[144]

[In the embodiment 3]

[145]

In the embodiment 1 in, porous as a protective layer mean pore diameter 10 micro m, thickness 40 micro m, consisting of 70% porosity (yarn-Gore) PTFE the region other than the paste using, in the embodiment 1 and a second stage 3 module for separating carbon dioxide manufacturing processes and the cost of production.

[146]

[In the embodiment 4]

[147]

In the embodiment 1 in, porous m micro 300 mean pore diameter as a protective layer, thickness 40 micro m, consisting of 80% porosity PP/fine porous PP the region other than the used in the range of non-woven fabric, in the embodiment 1 and a second stage 4 module for separating carbon dioxide have been prepared.

[148]

[In the embodiment 5]

[149]

In the embodiment 1 in, porous as a protective layer mean pore diameter 0.05 micro m, thickness 3 micro m, consisting of 60% porosity (buffed film yarn) PTFE paste using the region other than the, in the embodiment 1 and a second stage 5 module for separating carbon dioxide have been prepared.

[150]

[In the embodiment 6]

[151]

In the embodiment 1 in, porous micro m 1.0 mean pore diameter as a protective layer, thickness 10 micro m, PTFE consisting of 70% porosity (buffed film yarn) the region other than the paste using, in the embodiment 1 and a second stage 6 module for separating carbon dioxide manufacturing processes and the cost of production.

[152]

[In the embodiment 7]

[153]

In the embodiment 1 in, porous micro m 0.5 mean pore diameter as a protective layer, thickness 20 micro m, 77% porosity consisting of PTFE (buffed film yarn) the region other than the paste using, in the embodiment 1 and a second stage 7 module for separating carbon dioxide manufacturing processes and the cost of production.

[154]

[In the embodiment 8]

[155]

In the embodiment 1 in, porous micro m 1.0 mean pore diameter as a protective layer, thickness 500 micro m, nonwoven fabric propylene: a 68% porosity ([...] manufacturing) the region other than the paste using, in the embodiment 1 and a second stage 8 module for separating carbon dioxide manufacturing processes and the cost of production.

[156]

[In the embodiment 9]

[157]

In the embodiment 1 in, porous micro m 2.0 mean pore diameter as a protective layer, thickness 800 micro m, nonwoven fabric propylene: a 60% porosity ([...] manufacturing) the region other than the paste using, in the embodiment 1 and a second stage 9 module for separating carbon dioxide have been prepared.

[158]

[In the embodiment 10]

[159]

In the embodiment 1 in, porous as a protective layer mean pore diameter 0.005 micro m, 20 micro m thickness, porosity consisting of 67% PTFE (buffed film yarn) the region other than the paste using, in the embodiment 1 and a second stage 10 module for separating carbon dioxide manufacturing processes and the cost of production.

[160]

[In the embodiment 11]

[161]

In the embodiment 1 in, porous as a protective layer mean pore diameter 600 micro m, 400 micro m thickness, porosity 80% : a polypropylene nonwoven fabric ([...] manufacturing) the region other than the paste using, in the embodiment 1 and a second stage 11 module for separating carbon dioxide manufacturing processes and the cost of production.

[162]

[In the embodiment 12]

[163]

In the embodiment 1 in, porous as a protective layer mean pore diameter 600 micro m, 800 micro m thickness, porosity 80% : a propylene net the region other than the used in the range of, in the embodiment 1 and a second stage 12 module for separating carbon dioxide have been prepared.

[164]

[Compared e.g. 1]

[165]

In the embodiment 1 in, carbon dioxide separation layer, and forming a protective layer porous on the region other than the not in the embodiment 1 and a second stage C1 module for separating carbon dioxide manufacturing processes and the cost of production.

[166]

[Compared e.g. 2]

[167]

A hydrophobic microporous gas transmitting support (you if a malfunction of the GE) on a second stage carbon dioxide separation layer in the embodiment 1 and is formed to allow the plating solution. Furthermore, carbon dioxide separation layer on thickness of feed spacer 480 micro m provided, thereon m he put a film poly methylpentene of micro 25. Epoxy-containing polyester number of knitting coat the then a permeate gas flow passage materials 2n. support adhesive on fixing, automatic with volume signs of intoxication 0.1 m/min speed of C2 module for separating carbon dioxide by winding to have been prepared.

[168]

[Compared e.g. 3]

[169]

Hydrophilic porous PTFE ([...]the nose which is burnt manufacturing, WPW-020-80, thickness 80 micro m, the pore diameter 0.2 micro m, porosity about 75%)and hydrophobic PTFE porous ([...]the nose which is burnt manufacturing, Fluorouracil pores FP010, thickness 60 micro m, the pore diameter 0.1 micro m, porosity 55%)of the second compound field 2 stacked composite support hydrophilic porous PTFE flowed in on to the other side of the coating liquid layer flue in the embodiment 1 (1) and the same, roll to roll applied/drying the flue the front/rear sides of the composite layer.

[170]

The production cost is cheap method of said composite for separating carbon dioxide, carbon dioxide an isolation layer inside a from two halves that are folding /, semi folding the side of the bendings of member 3 except for the amount of the fecal material are (porous membrane side composite support hydrophobic PTFE) outer end of, high viscosity (about 40 Pa/s) of an adhesive epoxy resin (( [...] manufacturing) E120HP) a voltage is applied to the, number polyester impregnated epoxy knitting coat tree one side a permeate gas passage member time and a falling time by overlapping, to the outside material gas flow channel display an Image, comprising a transmitting transmission gas collecting pipe he wreathed his multiple the periphery of the workpiece.

[171]

Thereby, manufacturing processes and the cost of production C3 module for separating carbon dioxide. The module was 0.025 m2 the effective area an abstraction layer carbon dioxide.

[172]

<Evaluation of composite for paste flue >

[173]

Each manufacturing the using modules for separating carbon dioxide, in 3 a method for evaluation of species CO2 permeation rate (P (CO2)) and a CO2/H2 was measuring calculates a separation coefficient (α). Exhibits to 1 table result.

[174]

-evaluating method 1-

[175]

As a test gas H2: CO2: H2 O = 45:5:50 of a raw-material gas (flow 2.2 ℓ / min) a temperature 130 °C, each entire pressure 301.3 kPa supplied to separation module acid gas, transmission side gas Ar visitor is checked through a flow a (flow 0.6 ℓ / min). For passing the gas by analyzing the language information gas chromatograph, CO2 permeation rate (P (CO2)) and a CO2/H2 separation coefficient (α) was calculated. Furthermore, P (CO2) GPU as the first voice portion out of an the S200.

[176]

-evaluating method 2-

[177]

As a test gas H2: CO2: H2 O = 45:5:50 of a raw-material gas (flow 2.2 ℓ / min) 130 °C a temperature, the top plate is of rainwater entire pressure 101.3 kPa each method under such conditions that a thermal coverage supplying fiber-forming material to separation module acid gas, transmission side gas Ar visitor is checked through a flow a (flow 0.6 ℓ / min). Gas and is transmitted by analyzing the language information gas chromatograph, CO2 permeation rate (P (CO2)) and a CO2/H2 separation coefficient (α) was calculated. Furthermore, P (CO2) GPU as the first voice portion out of an the S200.

[178]

-evaluating method 3-

[179]

As a test gas H2: CO2: H2 O = 72:8:20 of a raw-material gas (flow 10 ℓ / min) a temperature 130 °C, each entire pressure 1601.3 kPa supplied to separation module acid gas, transmission side gas Ar visitor is checked through a flow a (flow 0.6 ℓ / min). For passing the gas by analyzing the language information gas chromatograph, CO2 permeation rate (P (CO2)) and a CO2/H2 separation coefficient (α) was calculated. Furthermore, P (CO2) GPU as the first voice portion out of an the S200.

[180]

[181]

Table 1 as shown in the, composite for paste flue related to the present invention using the 1 ∼ 12 module for separating carbon dioxide, which evaluation method the dried rice plants and air clefts high CO2 permeation rate and CO2/H2 separation coefficient can be viewed for a difference from an. I.e., feed gas contained in the carbon dioxide concentration are canceled and water vapor concentration, stable of effluent separation is achieved can be viewed.

[182]

Dynamically allocates the channel signals to the, porous having protective layers composite for paste flue not using carbon dioxide for separating the C2 and C1 module, mild conditions with a ready-made a distance but is achieved and separation of effluent, carbon dioxide separating function under harsher conditions than tolerances result is in. it will be. Furthermore, carbon dioxide an isolation layer heterogeneous just and, feed gas channel member that does not have a flue using composite for paste the C3 module for separating carbon dioxide, porous PTFE composite support hydrophilic heterogeneous just a intrusion an isolation layer carbon dioxide-bl4223 into a flue and also layer, carbon dioxide separating function, severe than condition and with mild conditions for some user even under conditions of high compactible. a main body.

[183]

28 September 2012 30 August 2013 patent application number 2012-217832 call specification and application to a Japanese application to a Japanese patent application number 2013-179770 call specification a reference the full content of a. receiving the specification.



[184]

Disclosed is a composite for carbon dioxide separation, containing, in the following order, a gas permeable support; a carbon dioxide separation layer containing a water absorptive polymer and a carbon dioxide carrier; a steam permeable porous protective layer having an average thickness of from 1 µm to 500 µm; and a supplied gas passage member.



Gas-permeable support and, absorbent polymer and carbon dioxide carrier containing a carbon dioxide isolation layer 12 and a GaN, m or more micro 1 average thickness 500 micro m hereinafter moisture vapour permeable, porous protective layer and, feed gas channel member comprising a this order, composite for paste flue.

According to Claim 1, said porous of the protective layer with the central mean pore diameter is 0.005 micro m a m hereinafter micro 1000 or more, composite for paste flue.

According to Claim 1 or Claim 2, 3% or more is porosity of the protective layer with the central porous said a 90% hereinafter, composite for paste flue.

According to one of Claim 1 to Claim 3, said porous protective layer, which is, blends of polyamide blockpolymers and of copolymers, polyvinylidene fluoride, poly methylpentene, poly [...] , polyether sulfone, polypropylene, polysulfone, polyacrylonitrile, polyimides and polyamic at least one of the group are implanted into a semiconductor substrate in, composite for paste flue.

According to one of Claim 1 to Claim 4, said porous protective layer and said supply gas flow channel insulating members which are provided in a secured together, composite for paste flue.

According to one of Claim 1 to Claim 5, insulating members which are provided in said supply gas flow channel 100 micro m or more micro 1000 having an average thickness m hereinafter, composite for paste flue.

Perforated hollow center tube spirally wound on the heat either anti number 6 to anti number 1 described in claim a composition containing the complex of separating carbon dioxide, carbon dioxide for separating module.

Gas transmitting support containing carrier and carbon dioxide absorbent polymer on applying an aqueous solution and dried, carbon dioxide separation layer forming a carbon dioxide separation layer forming step for, said carbon dioxide separation layer 500 m or more micro 1 average thickness on micro m hereinafter moisture vapour permeable, porous protective layer for laminate including porous protective layer formation process, carbon dioxide for separating complexes of manufacturing method.

Gas transmitting support containing carrier and carbon dioxide absorbent polymer on applying an aqueous solution and dried, carbon dioxide separation layer forming a carbon dioxide separation layer forming step for, said carbon dioxide separation layer 500 m or more micro 1 average thickness on micro m hereinafter moisture vapour permeable, porous protective layer for laminate porous protective layer forming step for, said porous on a protective film forming and bonding the member channel feed gas feed gas channel member including a catalyst layer forming step of forming, carbon dioxide for separating complexes of manufacturing method.