ANTI-REFLECTIVE COMPOSITION, PRODUCING METHOD, AND ANTI-REFLECTIVE FILM

Hereinafter, with reference to a drawing based on a text content of the focuses of the present invention embodiment in the present invention is in the field of the person with skill in the art easily embodiment. as further described can be. The present invention refers to variety of different is embodied in the form described where can be embodiment aspect is not limited.

The present invention thereby unambiguously direct the described described for the portion that are independent of and, throughout the specification the same, or similar, is made by the identical is so the reference code.

In drawing where the different layers and area of a porous ceramic so that its wall thickness for securely presenting showed thus expanding the. In drawing and, for facilitating of the, thickness of and area several layers showed is volatile.

Hereinafter of the substrate "upper (or lower)" or substrate "(or) on" any to the is formed, any is upper surface of said substrate (or the), meaning that the provided in contact with the ion conductor as well as, on of a substratum material and said formed (or in the) including any is captured in another not in the. are not limited to.

Of the present invention in one embodiment, part of metal replaced by Si containing a metal organic metal containing network siloxane oligonucleotides; photocurable of an acrylate-based compound; siloxane oligonucleotides organic fluorine-containing network; and hollow silica particles; includes, said a titanium, zirconium and combination of them at least one of the group including provides a antireflective compositions.

Generally, the antireflective film is refraction layer and should contain at refraction, each layer is formed and thereby, these creating separate process for laminating multi-a polyimide-to be included a position where a time and cost is the main component which has an consumption.

Furthermore, for forming said refraction layer siloxane-based high refractional composition for example, styrene-based, epoxy-based binder for resin having a high index of refraction refraction are prepared by combining a metal oxide particles is formed integrally with the screw and, this metal oxide particles since very expensive cost, significantly increasing production cost. problem.

Antireflective compositions a, according to some exemplary embodiments of the present invention refers to as a, said antireflective compositions of each component included in a spontaneous phase separated, other surface energy a phenomenon is prevented to the first direction in parallel to upper and lower layers, and spontaneous phase separated, new anti-reflective compositions and after photocuring that refraction layer the antireflective film is formed from the polymerization of the top layer and the as refraction layer as underlying layer can be formed at a time. As a result, are separately refraction refraction layer and said line is coupled to said making and method thereof at least necessary radiation curing of formed on said for producing antireflection film by land are adhered to a plurality of time and cost is effectively and a heat treatment process are fairness and manufactured economically in a for implementing contact point is turned off.

Furthermore, said metal Si lower layer of antireflective compositions containing a metal replaced by organic metal containing network by the inclusion of polysiloxane oligonucleotides expensive includes a particulate metal oxide without a high refractive index to a generally more uniform to be electrically connected to the main, upper oligonucleotides organic fluorine-containing structure the polysiloxane and hollow silica including particles can implement low index of refraction by the, said anti-reflective compositions formed from thereon and an anti-reflective film is an excellent antireflection performance economically-changed signal is shifted down.

Furthermore, said photocurable (metadata) acrylate compound curing possible and improve thermal stability at a faster rate by shortened further more the fairness and productivity can be improved.

Said phase separated, antireflective compositions may include a upper and lower layers.

Antireflective compositions as refers to said, other surface energy of each component a spontaneous phase separated, formed a phenomenon is prevented may include a upper and lower layers.

Specifically, photo by forming a refraction refraction layer components are components that formed by a contaminant energy is relatively low, the low surface energy components are forming a refraction urged upwardly formed an upper layer of a fire protective, refraction layer forming a high surface energy components are urged downwardly can be a lower.

As such, said upper and said lower phase separated, new anti-reflective compositions at a time, and a photocuring by that refraction layer and refraction layer formed, said for producing antireflection film land are adhered to a plurality of, time and cost effective can be the circumference of.

A lower-thickness ratio of about said upper thickness to said can be about 1:1 to about 1:4. Said phase separation on-thickness ratio of about in a range, and a photocuring by is formed from the polymerization of the antireflective film is light to further improve development and the like interference position of an opposite surface of the superior antireflection performance-changed signal is shifted down.

Siloxanes have siloxane backbones said fluorine-containing organic oligonucleotides hydrophobic fluorine-free and may be imparted, as the degree of crosslinking increases imparted said hydrophobic though the can be a low surface energy, fluorine-containing siloxanes have siloxane backbones oligonucleotides organic fluorine-containing network said organic metal containing network polysiloxane and oligonucleotides of an acrylate-based compound photocurable said gap is formed between the substrate support material may have a low surface energy.

The, said antireflective compositions as binder lower layer of said oligonucleotides organic metal containing network polysiloxane and photocurable acrylate compound. there may also be a rescale.

Furthermore, said antireflective compositions as binder upper layer and cereal is stored in said network of organic fluorine-containing siloxane oligonucleotides; and said hollow silica particles; there may be is, said hollow silica particles for said network fluorine-containing organic oligonucleotides siloxane is chemically bonded is attached by said surface-treated hollow of silica particles even the surface of the material may have a low surface energy. Said chemically bonded for example, can include a siloxane bonds, the network said siloxane is oligonucleotides organic fluorine-containing hollow silica particles for siloxane bonds i.e., represents a coupling of an internal layer Si-O-Si may be connected to.

I.e., said antireflective compositions as binder upper layer and cereal is stored in said network of organic fluorine-containing siloxane oligonucleotides; and surface said network fluorine-containing organic oligonucleotides siloxane is chemically bonded silica attached hollow by can be particles are present.

Antireflective compositions included in said said metal containing organic oligonucleotides oligonucleotides organic fluorine-containing said to weight of the polysiloxane weight ratio of the polysiloxane can be about 1:0.1 to about 1:2. Within range said functions supported by an apparatus for recording at a weight ratio of said anti-reflective compositions formed from refraction layer as a bottom layer of the upper substrate an antireflection film which has a refractive index high levels of of the washing machine by reducing the top layer as the low levels that refraction layer refractive index the objective compound. antireflection performance.

In one embodiment, antireflective compositions a present at a lower surface of said said network metal containing organic oligonucleotides of the polysiloxane content for example, said photocurable (metadata) 100 parts by weight of an acrylate-based compound wherein said component comprises from about 10 parts by weight to about 1000 parts by weight may be, particularly by about 100 parts by weight to about 1000 can be part by weight. By the inclusion of the proportion of within range said expensive includes a particulate metal oxide without a high refractive index to a fully and uniformly to be electrically connected to the main, and a photocuring reaction to properly perform the is cured at a faster rate mounted with a manufacturing apparatus the objective compound.

Organic metal containing network said oligonucleotides in siloxane oligonucleotides organic siloxanes have siloxane backbones some of Si metal contains metal been substituted, are substituted with metal Si and properties according to the degree to which the purpose of the invention by the appropriate adaptation of the desired levels of high index of refraction-changed signal is shifted down.

For example, organic metal containing network said oligonucleotides to polysiloxanes containing Si-to-metal of atoms team for example, about 1:0.03 to about 1:5.90 and the shaft transfers the, particularly by about 1:0.3 to about 1:5.90 can be. Range of said team atoms by the inclusion of metal with a high refractive index to a fully and uniformly implementing thebox-and cost-effective as the paper previously in a non a manufactured economically in a-changed signal is shifted down.

Oligonucleotides containing organic metal said partially substituted by network of the polysiloxane by may include open architecture. Specifically, siloxanes have siloxane backbones oligonucleotides containing organic metal said binding of said network includes substituted and disconnecting the, the combination of said network by substituents partially disconnected can be point is included an open.

Oligonucleotides containing organic metal said siloxane in two of said substituent is 4-18 carbon atoms (metadata) may include functional group acrylate. Said that has carbon in a range (metadata) acrylate contains a functional group by appropriate chain length of a light curable by by photo-orradiation refers to the structure of an equipment by being progress properly reaction a hydrolysis reaction and polycondensation reactions can be is formed on.

Furthermore, two of said carbon atoms the substituents side alkoxy 1-10, two 1-18 alkyl carbon atoms, alkenyl group of two 2-10 carbon atoms, two 6-18 carbon atoms one aryl, four sprouting, 's two two 3-8 carbon atoms, and combinations thereof the group consisting of low density high strength al id at least one of the may further include any. id F said low density high strength al, Cl, Br, I can be.

Siloxanes have siloxane backbones oligonucleotides containing organic metal said of formula 1 a titanium compound, a zirconium compound of formula 2, or mixtures thereof; and formula 3 silane compound; a is reaction product composition including number 1:

[Formula 1]

R¹_x Ti (OR²)_4-x

[Formula 2]

R³_y Zr (OR⁴)_4-y

[Formula 3]

R⁵_z Si (OR⁶)_4-z

In said formula 1 to 3, said R¹, R³, R⁵ the, independently, two side alkoxy of 1-10 carbon atoms, 1-18 alkyl two carbon atoms, alkenyl group of two 2-10 carbon atoms, -18 carbon atoms of two 4 (metadata) acrylic 3,500, two 6-18 carbon atoms one aryl, four sprouting, 's two two 3-8 carbon atoms, or Halar id strangeness , said R², R⁴, R⁶ the, independently, of carbon number 1-6 H of R3 is two, said x, y, the z, is independently 0, 1 or 2.

Said titanium compound for example, tetra [...] , tetra [...] , tetra this cow pro width hour titanium , tetra butoxy titanium, tetra [...] (tetra tert-butoxy Titanium), [...] ethyl 2-titanium, titanium [...] , titanium [...] , titanium benzoic acid, chloro tree [...] , chloro tree [...] , chloro triazine this cow pro width city titanium, dichloro [...] , dichloro [...] , dichloro dee small pro width hour titanium , dichloro [...] , trichloro [...] , trichloro [...] , [...] titanium, titanium bromide, titanium poloride base, titanium iodide and a hydrogen combination of them at least one of the group may include.

Furthermore, the implemented said titanium compound in methoxy, ethoxy such as at least one of low density high strength al and side alkoxy id (metadata) acrylate functional groups having different electron substituted titanium compound can include a, the number 1 which are the product of reaction products of in siloxane oligonucleotides containing organic metal said said substituent is (metadata) acrylate functional photohardened information are included in the first wires are fairness and productivity can be improved.

In addition said titanium compound exemplified in methoxy, ethoxy such as at least one of low density high strength al and idside alkoxy alkyl, alkenyl group, an aryl group or other low density high strength al substituted id crossroad may include a titanium compound.

said zirconium compound for example, tetra [...] , tetra [...] , tetra pro width hour zirconium , tetra butoxy zirconium, tetra tert-butoxy zirconium, tetra this cow pro width hour zirconium , tetra [...] , zirconium chloride, zirconium bromide, zirconium oxyfluoride, zirconium iodide, zirconium acrylate, zirconium carboxylic ethyl acrylate and combinations thereof the group consisting of at least one of the may include.

Furthermore, the implemented said zirconium compound methoxy, ethoxy such as at least one of low density high strength al and side alkoxy id (metadata) acrylate functional groups having different electron substituted zirconium compound can include a, the number 1 which are the product of reaction products of in siloxane oligonucleotides containing organic metal said said substituent is (metadata) acrylate functional photohardened information are included in the first wires are fairness and productivity can be improved.

Furthermore, exemplary zirconium compounds, methoxy, ethoxy such as at least one of low density high strength al and idside alkoxy alkyl, alkenyl group, an aryl group or other low density high strength al substituted id crossroad may include a zirconium compound.

Said thread column harmony it asked for example, tetra trimethoxysilane, tetra good hardness and transparency, tetra pro width it will be sour, column , tetra this cow pro width it will be sour, column , tetra-n-butoxy silane, tetra-sec-butoxy silane, tetra-tert-butoxy silane, trimethoxysilane, triethoxysilane, and methyltrimethoxysilane, vinyltriethoxysilane on the methyl, ethyl and methyltrimethoxysilane, vinyltriethoxysilane on the ethyl, n-propyl and methyltrimethoxysilane, vinyltriethoxysilane on the-propyl n, this cow department[...] , [...] cycloalkyl, phenyl and methyltrimethoxysilane, vinyltriethoxysilane on the phenyl, vinyl and methyltrimethoxysilane, vinyltriethoxysilane on the, [...][...] , dimethyl butyldimethoxysilane, dimethyl [...] , [...] , [...] , trichloro with methyl thread column , tri-chloromethyl silane, trichloro dichloro methyl silanes, benzoic acid silane, [...] silane, vinyl silane [...] triazine, trichloro [...] trichloro with the jade thread room column which burns , acrylic jade hour pro it will bloom trimethoxy silane, silane [...] tree jade hour pro it will bloom acrylic, metadata [...] trimethoxy silane, silane [...] tree [...] metadata, metadata [...] trimethoxy silane, silane [...] tree [...] metadata, metadata [...] methyl dimethoxy silane, silane [...] methyl [...] metadata, metadata [...] methyl dimethoxy silane, silane [...] methyl [...] metadata, metadata [...] dimethyl methoxy silane, metadata [...] dimethyl ethoxy silane and combinations thereof the group consisting of at least one of the may include.

Furthermore, a silane compound is exemplified said methoxy, ethoxy such as at least one of low density high strength al and side alkoxy id (metadata) acrylate functional groups having different electron substituted may include a silane compound, the number 1 which are the product of reaction products of in siloxane oligonucleotides containing organic metal said said substituent is (metadata) acrylate functional photohardened information are included in the first wires are fairness and productivity can be improved.

Furthermore, in a silane compound is exemplified, methoxy, ethoxy such as at least one of low density high strength al and idside alkoxy alkyl, alkenyl group, an aryl group or other low density high strength al id crossroad substituted may include a a silane compound.

Said number 1 composition reaction products are specifically, hydrolysis reaction, condensation reaction or both may include a reaction product of. For example, silane alkoxide hydrolysis of beef is first taken place and an in, therefor are solvent having hydroxy groups is condensation reaction between a silane compound may occur, and not limited to, various reaction along the path hydrolysis reaction, can be are condensation reaction.

Zirconium compound of said formula 2 titanium compound and of said formula 1 each content access level 1 plus unencoded sections the total content of alkali metal and for example, 100 parts by weight of said formula 3 silane compound wherein said component comprises from about 10 parts by weight to about 1000 may be parts by weight, particularly about 100 parts by weight to about 1000 can be part by weight. By the inclusion of the proportion of within range said siloxane-based high refractional said implemented high refractive index composition and by the appropriate adaptation of the reaction rates is capable of inhibiting any gelation, the storage stability can be.

Siloxane-based high refractional said front board by establishing an optical fiber composition, said photocurable (metadata) acrylate compound said siloxane-based high refractional composition is capable of being hardened to at a faster rate good fairness and productivity-changed signal is shifted down.

the photocurable (metadata) acrylate monomer (metadata) of an acrylate-based compound, oligomer, resin and combination of them at least one of the group may include.

Furthermore, said photocurable (metadata) of an acrylate-based compound for example, multifunctional (metadata) acrylate monomer including the cross-linkable, specifically, said multifunctional (metadata) for example acrylate monomer, 3 functional or more (metadata) acrylate monomer includes crosslinked polymer component of possible weighing functions improved and is formed by growing the composition to cure to siloxane-based high refractional said crosslinking density refraction layer increased to thereby cause and hardness and excellent in durability-changed signal is shifted down.

Said acrylate monomer (metadata) for example, methyl (metadata) acrylate, ethyl (metadata) acrylate, n-propyl (metadata) acrylate, isopropyl (metadata) acrylate, n-butyl (metadata) acrylate, t-butyl (metadata) acrylate, sec-butyl (metadata) acrylate, neopentyl (metadata) acrylate, 2-ethylhexyl (metadata) acrylate, 2-ethyl butyl (metadata) acrylate, n-octyl (metadata) acrylate, ISO octyl (metadata) acrylate, -acid isononylesters (metadata) acrylate, lauryl (metadata) acrylate, midifiers targeting tetra (metadata) acrylate, hydroxyethyl (metadata) acrylate and combinations thereof including at least one of the group may include.

Said (metadata) acrylate oligomers alkyl (metadata) acrylate, alkylene glycol (metadata) acrylate, containing carboxyl groups and unsaturated double bonds (metadata) acrylate, a hydroxylated (metadata) acrylate, nitrogen containing (metadata) acrylic, and the like of various kinds of functional group containing oligomer (metadata) acrylate can be degraded and, not limited to blood.

Said (metadata) acrylate resin a [...] hexa acrylate, methacrylate target pen [...] , pentaerythritol methacrylate triazine, tetra the methyl the methane which comes tetra acrylate, tetra methyl roll methane methacrylate triazine, methacrylate triazine propane methanol tree, 1, 6-hexanediol diaryl the genus ascochyta and use, diaryl polyethylene glycol methacrylate, diethylene glycol acrylate, triethylene glycol acrylate, tetra ethylene glycol acrylate, hexa ethylene glycol acrylate, acrylate, butyl acrylate, [...] , 2-ethylhexyl, [...] , [...] , bisphenol A diglycidyl diaryl methacrylate, bisphenol A epoxyacrylate, methacrylate diaryl A bisphenol additional ethylene oxide, 2- lung stipendiary hour ethyl acrylate and a combination thereof at least selected from the group consisting of but may include one of, limited to blood not.

Said multifunctional (metadata) for example acrylate monomer, 2 functional type to 12 functional type (metadata) may be acrylate monomer, specifically, 1, 2-ethylene glycol methacrylate diaryl, 1, 12-use of Saccharomyces cerevisiae d this year which burns acrylate, 1, 4-butanediol di (metadata) acrylate, 1, 6-hexanediol di (metadata) acrylate, Neo [...] di (metadata) acrylate, polyethylene glycol di (metadata) acrylate, di (neopentylglycol adipate) Neo [...] (metadata) acrylate, hydroxy pivalate, Neo (hydroxyl puivalic acid) acid [...] di (metadata) acrylate, DC neel claw pen hit (dicyclopentanyl) di (metadata) acrylate, polycaprolactone modified DC neel claw pen reel di (metadata) acrylate, ethylene oxide-modified di (metadata) acrylate, di (metadata) acrylic hydroxyethyl isocyanurate, allyl (allyl) of cyclohexyl di (metadata) acrylate, tree hour claw space D methane this year (metadata) acrylate, dimethyl roll DC claw pentane di (metadata) arc relay, ethylene oxide-modified hexahydro phthalic di (metadata) acrylate, tree hour claw spaced methanol (metadata) acrylate, Neo [...] modified trimethyl propane di (metadata) acrylate, adamantane (adamantane) di (metadata) acrylate or 9, 9-bis [4-(2-acrylic [...]) phenyl] fluorene (fluorine) such as 2 functional type acrylate; trimethylolpropane tree (metadata) acrylate, [...] tree (metadata) acrylate, propionic acid modified [...] tree (metadata) acrylate, combination of pentaery thritol tree (metadata) acrylate, propylene oxide modified trimethylolpropane tree (metadata) acrylate, 3 functional urethane (metadata) acrylate or tris (metadata) such as acrylic [...] 3 functional type acrylate; d glycerin tetra (metadata) acrylate or combination of pentaery thritol tetra (metadata) such as acrylate 4 functional type acrylate; propionic acid (metadata) acrylate such as dideoxy-beta-d-fructofuranosyl [...] side 5 functional type acrylate; and [...] hexa (metadata) acrylate, polycaprolactone modified [...] hexa (metadata) acrylate or urethane (metadata) acrylate (ex. Tree trimethylolpropane and an isocyanate monomer (metadata) acrylate reactant) such as as to the aromatic hydrocarbon acrylate type functional 6 but, not limited to blood.

Acid-catalysed composition said number 1, and organic solvent selected from the group consisting of least one of the may further include any.

Said buys the catalyst for example, with inorganic or organic acids which can be used, specifically, nitric acid, hydrochloric acid, sulfuric acid or acetic acid can be or the like is used as an.

Said organic solvent for example, methanol (methanol), isopropyl alcohol (isoproply alcohol, IPA), ethylene glycol (ethylene glycol), butanol (butanol) such as alcohol ; (methyl ethyl ketone) methyl ethyl ketone, methyl isobutyl ketone (methyl iso butyl ketone, MIBK) such as ketones; acetic acid ethyl, butyl acetate, such as-butyrolactone γ ester (ester) current; for ease of application (tetrahydrofuran), 1, 4-dioxane such as ether (ether) current; and combinations thereof the group consisting of at least one of the may include.

In one embodiment, said fluorine-containing organic oligonucleotides partially substituted by network of the polysiloxane by may include open architecture. Specifically, organic fluorine-containing said oligonucleotides binding of siloxanes have siloxane backbones and disconnecting the network includes substituted, the combination of said network by substituents partially disconnected can be point is included an open.

Said antireflective compositions organic fluorine-containing network as binder, for example, siloxane oligonucleotides, said hollow silica particles 100 parts by weight about 10 parts by weight to about 120 parts by weight may include, in addition for example, about 20 parts by weight to about 100 parts by weight may include, specifically, about 40 parts by weight to about 80 may include parts by weight. By the inclusion of the proportion of within range said labelling without an excellent performance-changed signal is shifted down.

Fluorine-containing organic oligonucleotides siloxane having a weight average molecular weight of for example, about 1,000g/mol to about 100,000g/mol and the shaft transfers the, in addition for example, about 2,000g/mol to about 50,000g/mol which may be, specifically, about 5,000g/mol to about 20,000g/mol can be. Said range has an average molecular weight in and excellent low index of refraction by simultaneously changed corresponding to request-changed signal is shifted down.

Organic fluorine-containing said siloxane oligonucleotides in two 3-18 carbon atoms of said substituent is a fluoroalkyl group, of two 4-18 carbon atoms (metadata) acrylic [...] may include or both.

Specifically, two said substituent is 3-18 alkyl group and of fluorothermoplastic two carbon atoms, two of -18 carbon atoms (metadata) acrylic [...] 4 including, said fluorine-containing organic oligonucleotides siloxane for at least two different a fluoroalkyl group substituted with fluorine with the presence of low index of refraction the tilt direction determining with the presence of airway acrylate (metadata) body such that it can, and a photocuring reaction.

Furthermore, organic fluorine-containing said siloxane oligonucleotides at least one or more photocurable (metadata) acrylate functional groups where the progress of the reaction, and a photocuring with the presence of of the insertion part and the holder at a faster rate curing possible and improve thermal stability the be shortened and a, fairness and productivity can be improved.

Said fluorine-containing organic oligonucleotides said formula 3 silane compound siloxanes have siloxane backbones, including number 2 formula 4 a fluorine-containing silane compound is reaction product composition:

[Formula 4]

R⁷_w Si (OR⁸)_4-w

In said formula 4, said R⁷ the two 3-18 carbon atoms, R is an alkyl group containing two of fluorothermoplastic, said R⁸ the H of carbon number two of R3 is 1-10, said w independently from each other, is 0, 1 or 2.

Said formula 3 silane compound by establishing an optical fiber at a equal.

Said formula 4 fluorine-containing silane compound for example, triple [...] , triple [...] , triple [...] , triple [...] , [...] , [...] , [...] , [...] , [...] tree, tree [...] , [...] , [...] , and combinations thereof the group consisting of at least one of the may include.

Said formula 4 fluorine-containing silane content of for example, 100 parts by weight of said formula 3 silane compound wherein said component comprises from about 0.1 parts by weight to about 20 parts by weight may be, particularly about 5 to about parts by weight can be part by weight 10. By the inclusion of the proportion of within range said said, and a photocuring new anti-reflective compositions that refraction layer as formed from the polymerization of upper layer low index of refraction and having hydrophobic is given to by a information reasonably low and surface energy and excellent an apparatus for dehydrating sludge can implement an adhesion into the touch panel applied but are not limited..

Said number 1 composition, the composition or said number 2 acid-catalysed, and organic solvent selected from the group consisting of least one of the may further include any.

Said buys the catalyst for example, with inorganic or organic acids which can be used, specifically, nitric acid, hydrochloric acid, sulfuric acid or acetic acid can be or the like is used as an.

Said organic solvent for example, methanol (methanol), isopropyl alcohol (isoproply alcohol, IPA), ethylene glycol (ethylene glycol), butanol (butanol) such as alcohol ; (methyl ethyl ketone) methyl ethyl ketone, methyl isobutyl ketone (methyl iso butyl ketone, MIBK) such as ketones; acetic acid ethyl, butyl acetate, such as-butyrolactone γ ester (ester) current; for ease of application (tetrahydrofuran), 1, 4-dioxane such as ether (ether) current; and combinations thereof the group consisting of at least one of the may include.

In one embodiment, said hollow silica particles, for instance, (hollow silica particles), formed from silicon compound or organosilicon compound may be silica particles, said surface of silica particles, the internal or both can be where there is a space.

Said hollow silica particles are for example, water or an organic solvent such as dispersed in the form of an said hollow of silica particles 5 to 40 weight % solid content in colloidal and may be included at.. Said available allows the substitution of the organic solvents comprise trialkylamines methanol (methanol), isopropyl alcohol (isoproply alcohol, IPA), ethylene glycol (ethylene glycol), butanol (butanol) such as alcohol ; (methyl ethyl ketone) methyl ethyl ketone, methyl isobutyl ketone (methyl iso butyl ketone, MIBK) such as ketones; toluene (toluene), xylene (xylene) such as aromatic carbon hydrogen current; dimethyl formamide (dimethyl formamide), dimethylacetamide (dimethyl acetamide), N-methyl pyrrolidone (methyl pyrrolidone) such as amides; acetic acid ethyl, butyl acetate, such as-butyrolactone γ ester (ester) current; for ease of application (tetrahydrofuran), 1, 4-dioxane such as ether (ether) current; or mixtures thereof, use can be made of,.

Number average diameter said hollow of silica particles for example, about 1 nm to about 1,000 nm and the shaft transfers the, in addition for example, which may be about 5 nm to about 500 nm, specifically, can be about 10 nm to about 100 nm. Within range said number average diameter by having said antireflective film is excellent transparency and an excellent antireflection performance simultaneously-changed signal is shifted down.

Said antireflective compositions can further include photoinitiator, special without limitation, publicly known in the art, use can be made of, a photoinitiator.

Of the present invention in another embodiment, said upper and said lower phase separated, new anti-reflective compositions is formed by photo that refraction layer as top layer (120) and refraction layer has a lower layer (110) for including antireflection film (100) provides. Also Figure 2 shows a an antireflection film which has a some embodiments of the present invention (100) is roughly cross-section of. represents.

As a result, separate each said said and that refraction layerrefraction layer necessary the laminate be prepared by radiation curing of at least by formed on time and-lamination pillar has an has an upper part wider than a fairness and economy and a heat treatment process are formed on the multi-contact point is turned off.

Said antireflection film (100) in particular, said new anti-reflective compositions, and a photocuring the and hot air-dried then, then aging (aging) the can be.

For example, and a photocuring said may be coin ultraviolet, a metal-halide lamp conventional acid using such a catalyst (metal halide lamp) may be performed but, limited to not.

Said hot air while for removal of solvents by drying the hydrolysis reaction, condensation reaction can be further advance and the like, for example, at a temperature of about 50 °C to about 200 °C about 1 min to about 10 minutes and hot air-dried the, is at. The aging said anti-reflective compositions said between compound unreacted for residual in hydrolysis reaction, condensation reaction can be further advance and the like, at a temperature of about 40 °C to about 100 °C about 10 hr to about 100 can be degraded and processing aging time, is at.

In another embodiment, said top layer (120) and said lower layer (110), on the interface chemically bonded were present and they said top layer (120) and said lower layer (110) is chemically bonded said outlets. can be adhered. The, said antireflection film (100) the top layer as that refraction layer (120) and said refraction layer has a lower layer (110) comprises rigid shell members that are removably attached to excellent in durability-changed signal is shifted down.

Said chemically bonded for example, siloxane bonds, between compounds having functional group acrylate cross-linking of may include or both.

Said refraction layer has a lower layer (110) index of refraction for example, about 1.40 to about 1.73 and the shaft transfers the, particularly about 1.51 to about 1.73 can be. Said within range high level of refractive index a refers to by having antireflection performance excellent with that refraction layer -changed signal is shifted down.

that refraction layer said 23 °C about a refractive index can be about 1.20 to about 1.25. Said low level of in a range by an improved light emission yield streams by antireflection performance excellent with refraction layer -changed signal is shifted down.

Said top layer as that refraction layer (120) thickness to said refraction layer has a lower layer (110) thickness of ratio of about 1:1 to about 1:4 can be. Said in a range by having-thickness ratio of about position of an opposite surface of the light the antireflective film is said to further improve development and the like interference superior antireflection performance-changed signal is shifted down.

Said refraction layer has a lower layer (110) thickness of for example, about 50 nm to about 200 nm can be. Within range by said has a thickness of said antireflection film (100) too thick, the thickness of and increases costs do not form a refers to without antireflection performance excellent with that refraction layer -changed signal is shifted down.

Said top layer as that refraction layer (120) the thickness of the for example, about 50 nm to about 200 nm can be. Within range by said has a thickness of said antireflection film (100) too thick, the thickness of and increases costs do not form the aforementioned without antireflection performance excellent with refraction layer -changed signal is shifted down.

In another embodiment, said top layer (120) of said underlying layer the angle of contact which will bite (110) is greater than the angle of contact which will bite of, said top layer (120) and said lower layer (110) between about difference the angle of contact which will bite can be 50° to about 20°. Said in a range and the principal angles having a difference the angle of contact which will bite said previous, and a photocuring by antireflective compositions included in a other surface energy of each of the components/is, in one embodiment establishing an optical fiber at a side upper and lower layers S4 can be phase separated,.

Said top layer (120) of the angle of contact which will bite for example, about 90° to about 110° and the shaft transfers the, said underlying layer (110) of the angle of contact which will bite for example, can be about 60° to about 70°.

Said top layer (120) said underlying layer of surface energy (110) is smaller than surface energy of, said top layer (120) and said lower layer (110) surface energy between about difference 10dyn/cm² to about 30dyn/cm² can be. Said and the principal angles having a difference surface energy in a range, and a photocuring by said previous anti-reflective compositions in photo by refraction layer components and forming a refraction components that formed between phase separation developing becomes easy occurs has a phase separated, said a new anti-reflective compositions formed by photo an antireflection film which has a (100) excellent antireflection performance-changed signal is shifted down.

A special surface energy said in the art and without restriction, a publicly known method but be computed in, the present specification in young of formula with Owen-Wendt model as calculated according to value of.

Said antireflection film (100) the 240 about 93% to about 98% measured at a temperature of 23 °C and randomly choosing hour feeling reflexibility for example, about 0.2 to about 1.5 and the shaft transfers the, particularly about 0.2 to about 1.0 may be the, excellent light transmission and antireflection performance-changed signal is shifted down.

Figure 3 shows a another embodiment of the present invention also an antireflection composition exhibits and the approximate process flow of manufacturing method.

Of the present invention in another embodiment, part of metal replaced by Si containing a metal organic metal containing network acrylate photocurable polysiloxane and oligonucleotides containing a compound, a titanium metal said, zirconium and combination of them at least one of the group acceptor polymer are interconnected by hydrogen bond (S1) a siloxane-based high refractional including; network fluorine-containing organic oligonucleotides including polysiloxane and hollow silica particles (S2) the acceptor polymer are interconnected by hydrogen bond that refraction ; said composition and siloxane-based high refractional said that refraction made by combining the antireflective compositions the stages of formation of the product (S3); including a provides manufacturing method of antireflective compositions.

Siloxane-based high refractional said said components and included in composition that refraction composition included in components in one embodiment by establishing an optical fiber at a other surface energy, said anti-reflective compositions in spontaneous phase separated, upper and lower layers a phenomenon is prevented, which differentiates are, phase separated, and, and a photocuring new anti-reflective compositions formed from the polymerization of the antireflective film is as an upper layer as and underlying layers to that refraction layerrefraction layer can be formed at a time.

As a result, are separately refraction refraction layer and said line is coupled to said making and method thereof at least necessary radiation curing of formed on said for producing antireflection film by land are adhered to a plurality of time and has an upper part wider than a fairness and economy and a heat treatment process are formed on the multi-contact point is turned off.

Said manufacturing method of the time determination portion replaced by metal Si containing a metal organic metal containing network polysiloxane oligonucleotides including siloxane-based high refractional acceptor polymer are interconnected by hydrogen bond by expensive includes a particulate metal oxide without a high refractive index to a maintaining manufactured economically in a-changed signal is shifted down.

Furthermore, photocurable (metadata) acrylate compound which is curable with a faster rate by weight of the a manufacturing apparatus to both sides of the internal electrode can be improved.

A titanium compound of formula 1, a zirconium compound of formula 2, or mixtures thereof; and silane compound formula 3 ; number 1 composition with said organic metal containing network members to form a siloxane oligonucleotides may further include any:

[Formula 1]

R¹_x Ti (OR²)_4-x

[Formula 2]

R³_y Zr (OR⁴)_4-y

[Formula 3]

R⁵_z Si (OR⁶)_4-z

In said formula 1 to 3, said R¹, R³, R⁵ the, independently, two side alkoxy of 1-10 carbon atoms, 1-18 alkyl two carbon atoms, alkenyl group of two 2-10 carbon atoms, -18 carbon atoms of two 4 (metadata) acrylic 3,500, two 6-18 carbon atoms one aryl, four sprouting, 's two two 3-8 carbon atoms, or Halar id strangeness , said R², R⁴, R⁶ the, independently, of carbon number 1-6 H of R3 is two, said x, y, the z, is independently 0, 1 or 2.

In said manufacturing method, said formula 1 of titanium compound, zirconium compound of said formula 2, said formula 3 the silane compound of the present invention in one embodiment the n..

Said number 1 composition for example about 20 °C about 3 hr to about 40 to about 60 °C may be stirring time. Said stirring conditions and time at a temperature hydrolysis reaction by the processing is sufficiently and polycondensation reactions organic metal containing network for easily forming an siloxane oligonucleotides can be. Said organic metal containing network and the polysiloxane oligonucleotides number 1 is formed of an acrylate-based compound photocurable compositions agitating solution which is prepared by mixing siloxane-based high refractional acceptor polymer are interconnected by hydrogen bond can be said. Said organic metal containing network siloxanes have siloxane backbones oligonucleotides of the present invention in one embodiment the n..

the photocurable (metadata) acrylate monomer (metadata) of an acrylate-based compound, oligomer, resin and combination of them at least one of the group may include, specifically multifunctional (metadata) acrylate monomer including crosslinkable the objective compound.. Photocurable said kind of the specific of an acrylate-based compound of the present invention in one embodiment the n.. Furthermore, said multifunctional (metadata) acrylate monomer for reducing a current consumption, functional or more (metadata) acrylate monomer 3 includes the second metal layer is thicker crosslinked polymer component caused by a high crosslinking density and hardness-changed signal is shifted down.

In said manufacturing method, and silane compound said formula 3 formula 4 fluorine-containing a silane compound included in the reacting composition number 2 said organic fluorine-containing network to form a siloxane oligonucleotides may further include any:

[Formula 4]

R⁷_w Si (OR⁸)_4-w

In said formula 4, said R⁷ the two 3-18 carbon atoms, R is an alkyl group containing two of fluorothermoplastic, said R⁸ the H of carbon number two of R3 is 1-10, said w independently from each other, is 0, 1 or 2. Fluorine-containing silane compound is said formula 4 of the present invention in one embodiment the n..

Said number 2 composition for example about 20 °C to about 60 °C about 4 hr to to about 80 may be stirring time. Said stirring conditions and time at a temperature hydrolysis reaction by the processing is sufficiently and polycondensation reactions organic fluorine-containing network for easily forming an siloxane oligonucleotides can be. Organic fluorine-containing network said siloxanes have siloxane backbones oligonucleotides of the present invention in one embodiment the n.. As such, organic fluorine-containing network said polysiloxane oligonucleotides number 2 is formed hollow said compositions for mixing and silica particles, about 20 °C to about 40 °C about 5 hr to about 50 time members can be acceptor polymer are interconnected by hydrogen bond that refraction. Said stirring conditions and time at a temperature by said hollow silica particles for said fluorine-containing organic oligonucleotides siloxane is chemically bonded by properly may be attached, the hollow silica particles the surface of the low index of refraction and low surface energy may have. Said chemically bonded for example, siloxane bonds, i.e. a combination Si-O-Si. The, said that refraction composition is provided to improve as siloxane oligonucleotides organic fluorine-containing network; and surface network fluorine-containing organic oligonucleotides siloxane is chemically bonded by attached hollow silica particles; may comprise an.

Said number 1 composition, the composition or said number 2 acid-catalysed, and organic solvent selected from the group consisting of least one of the can further include, said acid-catalysed and said organic solvent having in one embodiment the n..

Said siloxane-based high refractional composition and said new anti-reflective compositions made by combining the that refraction can be produced. Said antireflective compositions in one embodiment the n..

Specifically, said composition and siloxane-based high refractional said that refraction composition 40 °C to about 20 °C about after mixing about 30 min to about 2 time can prepare the members. The stirring for a period of time and at a temperature said new anti-reflective compositions said an antireflection film which has a formed by photo on the whole more even antireflection performance-changed signal is shifted down.

Said anti-reflective compositions in the top plate is phase separated, spontaneous is upper and lower layers can be formed. Specifically, said antireflective compositions refraction layer components and forming a refraction formed between components that autonomously a other surface energy and, a phase separation occurs, the relatively low surface energy forming refraction is formed the upper layer has components that, refraction layer high surface energy components are forming a can be a lower. As such, said spontaneous antireflective compositions the top plate is phase separated, said upper and said lower. may be divided into.

Said new anti-reflective compositions produced are applied to an least one surface of base film, said establishing an optical fiber at a side anti-reflective applied to one surface of the base film in the composition after, a phase separation occurs, and a photocuring by refraction layerthat refraction layer as top layer and bottom layer as including antireflection film can be produced.

Said special substrate publicly known in the art and without restriction, a variety of kinds of transparent substrate, transparent resin laminate or the like can be used, for example, PET (polyethylene terephthalate), PEN (polyethylenenaphthalate), PES (polyethersulfone), PC (Poly carbonate), PP (poly propylene), norbornene resin or the like is used as an [...] can be degraded and, limited to not.

Said applicator having antireflective compositions for example, gravure (gravure) coating method, slot die (slot die) coating method, spin-coating, spray coating method, bar coating method, using method such as coating deposited can be degraded and, not limited to.

said antireflective film is for example, said new anti-reflective compositions, and a photocuring the and hot air-dried then, the (aging) aging then the top layer and the bottom layer as refraction layerthat refraction layer as by forming a once can be produced.

Evaporating a solvent by drying the hot air and hydrolysis reaction, condensation reaction can be further advance and the like, for example, at a temperature of about 50 °C to about 200 °C about 1 min to about 10 minutes and hot air-dried the, is at.

The aging said siloxane-based high refractional said residual in the composition between compound unreacted for hydrolysis reaction, condensation reaction can be further advance and the like, at a temperature of about 40 °C to about 80 °C about 10 hr to about 100 can be degraded and processing aging time, is at.

For example, and a photocuring said may be coin ultraviolet, a metal-halide lamp conventional acid using such a catalyst (metal halide lamp) may be performed but, limited to not. Said UV curing for example, about 100mJ/cm² to about 1000mJ/cm² sufficiently to be conducted is irradiated with ultraviolet rays of photohardened can be degraded and, not limited to blood.

Said manufacturing method the antireflective film is produced by said antireflective film is about 240 and randomly choosing about 94% to about 98% measured at a temperature of about 23 °C hour feeling reflexibility for example, about 0.2 to about 1.5 and the shaft transfers the, particularly about 0.2 to about 1.0 may be the, excellent light transmission and antireflection performance-changed signal is shifted down.

Focuses a preferred embodiment of the present invention over rapidly and to reduce a memory but range rights of the present invention are not limited by a backing layer, which is if and then a and defines a main in using a variety of one skilled in the art of the present invention basic general outline form and improved modified. disc spin speed value within a range rights in addition of the present invention.

Thereby, the cold air flows. described hereinafter of the present invention embodiment. Such represented embodiment one embodiment of the present invention relate the present invention only exerting its embodiment represented is not limited aspect.

(In the embodiment)

In the embodiment 1

Tetra [...] 100 parts by weight, titanium this cow pro bombing death id 250 parts by weight, water 200 parts by weight, ethanol 200 parts by weight and, for mixing and parts by weight 1 1M nitric, agitating time 48 in 25 °C prepared a picnic composition number 1, then, said number 1 [...] compositions (pentaeritriol triacrylat, PETA) siloxane-based high refractional composition further mixing and agitating shown. Siloxane-based high refractional said oligonucleotides containing organic metal composition content of the polysiloxane PETA 100 was based on parts by weight of 100 parts by weight. Tetra [...] 100 parts by weight, 3, 3, 3-trifluoromethyl profile trimethoxy silane 40 parts by weight, water 100 parts by weight, isopropyl alcohol 100 parts by weight and 1M nitric and weight unit mixed 1, in 60 °C binder agitating time as the solution 3 prepared a picnic composition number 2, said number 2 compositions based on 100 parts by weight of said number 2 composition 60 nm average diameter of hollow silica particle-methyl isobutyl ketone dispersion sol (20% w/w, JGC C & C yarn, Thrulya 4320) 300 parts by weight, acrylic jade hour pro it will bloom trimethoxy silane 20 parts by weight and photoinitiator Igacure 184 further mixing and, agitating time that refraction composition at room temperature 24 shown.

Said composition and siloxane-based high refractional said mixing and composition that refraction , agitating time 2 in 25 °C new anti-reflective compositions have been prepared. Anti-reflective compositions in said, said metal containing organic oligonucleotides oligonucleotides organic fluorine-containing said to weight of the polysiloxane the weight ratio of the polysiloxane was 1:0.6.

Furthermore, thickness of 50 micro m PET on barrier ribs of said of material and then applying the new anti-reflective compositions and hot air-dried the 2 minutes in 130 °C, 300mJ/cm² to be machined is irradiated with a UV to, 24 in an oven to a aging time of 60 °C then by conducting the process a top layer and a bottom including the n bit parallel data inputted manufacturing transparent high-molecular agent, said manufacturing thereon and an anti-reflective in such films to yield said PET film except for the cd1a. formed on the 250 nm, 100 nm of next said upper layer thickness, 150 nm thickness was inferior impact resistance but superior adhesion to said.

Evaluation

In the embodiment 1 of antireflection film included in each refraction layer and that refraction layer refractive index, measures a surface energy and the angle of contact which will bite , in the embodiment 1 luminous reflectance light transmission and film structure by using an SC, lowest reflectivity measuring the table described to 1.

(Refractive index)

Measuring method:

Measuring method: prism coupler 532 nm enclosed, 632.8 nm, the measurement is carried out with the reflectivity at a wavelength 830 nm, wavelength dispersion refractive index as approximation of using a dispersion formula cauchy minimum square root method said cauchy dispersion formula of optical constant (curve fitting) by calculation at a temperature of 23 °C of the wavelength of 550 nm it was determined that refractive index.

(Measuring contact angle)

Methane rear dolly for and DIY (Di water) distilled (CH₂ I₂) a solvent when it was determined that each solvent angle of contact and organic the angle of contact which will bite.

Measuring method: in the embodiment 1 and that refraction layer of antireflection film included in a sample to be of 50 mm x 60 mm size refraction layer , and implanting a syringe on each specimen on in one direction so that a region, it sheds solvent drop of an ejectable, drop is terminated forms contact angle measuring instrument ([...] KRUSS Germany, DSA100) and magnify the provided a microscope with an only at critical points of the left and right end with a surface of said specimen the angles long since determined the.

In said measuring method, in the embodiment 1 of antireflection film included in each samples that refraction layerrefraction layer and 5 said preparing and one by one, a particular per each sample at the point of two 3 the contact angle is greater than a predetermined, total 15 in the embodiment 1 a measured value of the two included in antireflection film of refraction layer and that refraction layer been thus obtained for each, 15 each said averaging a measured value of the two was assessed as the contact angle.

(Surface energy)

Measuring method: young Owen-Wendt mode formula with of the n bit parallel data inputted as calculated according to, methane rear dolly for and DIY (Di water) distilled water as a solvent (CH₂ I₂) by cylinder to have.

(Light transmittance)

Measuring method: about 50 micro m thickness hazemeter distribution of heat to the film structure by using an SC (Nippon Denshoku [...] , NDH 5000) it was determined that using

(Luminous reflectance and lowest reflectivity)

Measuring method: said antireflection film of a rear surface reflection for preventing said said PET based on black tape refraction layer i.e. opposite side of the upper surface, lower surface worker and thus, to reduce worker, Spectrophotometer using (Konica Minolta [...] , cm -5), at a temperature of 23 °C that refractive index layer luminous reflectance surface of (D65) and lowest reflectivity was assessed.

Said luminous reflectance and lowest reflectivity the smaller the antireflective film is an excellent of corners of the butterfly.