NATURAL GAS LIQUEFACTION PROCESS
The present invention refers to natural gas liquefaction process relates to search, more particularly safely highly space telephon number which can replace refrigerant relates to natural gas liquefaction process. The liquefied natural gas for liquefying a natural gas (LNG) for producing thermodynamic process to a higher efficiency and a larger capacity a request for a family, including the order to still meet the are number has been developed from 1970's. Such order to satisfy the requests, i.e. liquefaction process efficiency of time relative to a training sequence height and capacity or shifts, or different a natural for liquefying a gas are currently attempt to cause the needle a wide variety of manner in considers the code is formed integrally with the screw and, via the number of liquefaction process based on the very less. In operation of a power of the required from the outside one of liquefaction process' Propane Mixed Refrigerant Process pre-cooled (or C3/MR process)' is. As far as shown in Figure 4, plate process C3/MR (NG) has a hollow propane (C3) employing the roller which becomes neutralized refrigerant - Thomson (joule-thomson) cycle (or propane cycle) through approximately 238 K is (pre-cooled) precooler up. Then natural gas a mixed refrigerant (MR, Mixed Refrigerant or multi-component Refrigerant) through mixed refrigerant cycle using the same liquefied until approximately 123 K (liquefied) and cooling (sub-cooled) is. C3/MR process and a single refrigerant and those using a refrigeration cycle employing mixed refrigerant the use of the liquefaction process of selection and/or control of the liquefaction process and gradually KIPO &. In operation a a liquefaction process the other one of the Conoco Phillips by accident is a cascade (Cascade) process. Conoco Phillips as far as shown in Figure 5 by accident a cascade process methane (C1), ethylene (C2) and propane (C3) using the - Thomson cycle consists of 3 unit has a. A single process cascade and a refrigeration cycle employing refrigerant transmitted to a liquefaction process, selection and/or control of that highly reliable liquefaction process simple and unit is off. However cascade refrigerating cycle is two 3 process each individual equipment (for example, heat exchanger) SCP instructs requirements necessary for tele-liquefaction process and a polysilicon are inevitably add to have the disadvantage that KIPO &. In operation and at least one other of which a liquefied during processing, the 'Single Mixed Refrigerant Process (or SMR process)' is. As far as shown in Figure 6, SMR process using the mixed refrigerant natural gas predetermined voltage is the liquefied refrigeration cycle loop. The SMR that form of liquefaction process process unit is off. However SMR process liquefaction process of. have the disadvantage that efficiency is low. A such as liquefaction process are supplemental refrigerant during operation of the liquefaction process both (make - up), it is necessary that. To this end beneath the further storage facility is generally tower-mounted. However refrigerant because the combustible usually that stored separately and are refrigerant side of is safe in not go. In addition further storage facility beneath the object of providing the side of space utilization in not go. Such includes a door number at least one power transmission gear is the safety factor very number not limited to, an expanded construction packetized elementary stream for FPSO. on the side surface of (Floating Production Storage and Offloading). Thus the present invention refers to the first and second door number so as to solve, the number and of the present invention safely refrigerant highly space telephon number which can replace natural gas liquefaction process for the recording operation. under public affairs number. The present invention refers to natural comprises a feed stream for liquefying a natural gas liquefaction process relates to search, using the carbon dioxide refrigerant through refrigeration cycle number 1 number 1 the heat exchanging area in cooling step for cooling an feed stream number 1, number 1 number 2 after cooling using the methane refrigerant through refrigeration cycle for cooling an feed stream in the heat exchanging area number 2 number 2 cooling step, number 2 and number 3 after cooling using the nitrogen refrigerant through refrigeration cycle in the heat exchanging area number 3 for cooling an feed stream includes cooling step number 3. The present invention according to natural gas liquefaction process using a carbon dioxide refrigerant number 1 refrigeration cycle, using the refrigerant methane refrigeration cycle number 2, number 3 using the refrigerant and nitrogen through refrigeration cycle since the liquefying feed stream, for replenishment, the refrigerant two to store a refrigerant without which can replace refrigerant, is space usability or the as a result of greatly enhance the. after. In the embodiment according to Figure 1 shows a natural gas liquefaction process also one of the present invention that the flow and Also in the embodiment according to Figure 2 shows a natural gas liquefaction process of the present invention other that the flow and Figure 3 shows a of Figure 1 liquefaction process according to graph computer simulation liquefaction of natural gas Figure 4 shows a general outline of the existing method C3/MR process also that the flow and shown Cascade process also Figure 5 shows a general outline of the existing method that the flow and shown Also Figure 6 shows a general outline of the existing method SMR process that the flow and shown Hereinafter drawing of attached in reference to. rapidly and to reduce a memory a of the present invention preferred embodiment. However in the embodiment of the present invention is hereinafter number by one or limited not. Also in the embodiment according to one of the present invention Figure 1 shows a natural gas liquefaction process is that the flow and. The liquefaction process in the embodiment according to one of the present invention as far as shown in Figure 1 two 3 using refrigerating cycle (refrigeration cycle) for liquefying a natural gas (NG) cooling the liquefied natural gas (LNG) the process of producing can be applied to the. More specifically, the present in the embodiment according to the liquefaction process, the heat exchanging area number 1 (111) for cooling an feed stream in cooling step number 1, number 2 the heat exchanging area (112) for cooling an feed stream in cooling step number 2, number 3 and the heat exchanging area (113) for cooling an in feed stream includes cooling step number 3. Supply stream can be natural gas. Reproduction mode by such sequential in a natural gas cooling may be cooling and precooling is liquefied. With reference to, 3 of the heat exchanging area are of 1 may be provided within the heat exchanger, or separate within the heat exchanger may be provided separately from the vehicle. Wherein a heat exchanger PFHE (Plate Fin Heat Exchanger) types of heat exchanger or SWHE (Spiral Wound Heat Exchanger) types of heat exchanger and can be heat exchanger imbalance of the laundry the actuating lever. Using the refrigerant carbon dioxide cooling step number 1 number 1 refrigeration cycle through the cooling feed stream. Carbon dioxide refrigerant (Co2), including, but mainly carbon dioxide, further includes small amounts of impurities may be loaded with. Just, carbon dioxide refrigerant. most preferably is including only carbon dioxide. The present in the embodiment of the carbon dioxide in the refrigerant for liquefying a feed stream can be put into from liquefaction plants.. A liquefaction plants and then digging natural gas, crude taxol as plant liquefy the same, terrestrial or marine is inserted into the pin grooves KIPO &. Liquefaction plants typically gas by using aqueous natural gas to driving turbine. State of the SP heads and exhaust one of the gas turbine the exhaust gas is usually includes carbon dioxide. This the separate carbon dioxide from waste exhaust gas number 1 of refrigerating cycle can be utilized as a refrigerant. Natural gas and a mode in which impurities obtained in advance before the liquefied for vertically long number is pre-treated. During pretreatment such as a carbon dioxide as impurities also can be for producing a sedated number, number 1 of refrigerating cycle same may utilize as refrigerant. The present in the embodiment according to liquefaction process solid formulation as well as to the liquefaction plants carbon dioxide to carbon dioxide as refrigerant discharged from semiconductor production units as number 1 can be supply refrigeration cycle. A methane cooling step number 2 number 2 refrigeration cycle using the refrigerant through the cooling feed stream. Methane refrigerant (methane), including, but mainly methane, further includes small amounts of impurities may be loaded with. The present in the embodiment methane at. the source gas may be furnished from feed stream refrigerant. Natural gas generally methane, ethane, propane, butane includes or the like. State of the SP heads and natural gas typically included a primary most methane. Thus feed stream can be utilized as a refrigerant are methanized, the at least a portion of a supply liquefaction process in the embodiment according to methane as refrigerant able to supply to KIPO & refrigeration cycle number 2. Liquefaction process is when operational, in a case of a lack of refrigerant portion of feed stream to refill the number 2 the material filled in the refrigeration cycle rectifier, liquefaction process is actuated when initiating the number 2 senses whether the floor passing velocity standard for all feed stream able to supply to KIPO & refrigeration cycle. And the feed stream is the material filled in the refrigeration cycle before refrigeration by carbon, or after cooling can be supply refrigeration cycle number 2. With reference to, a three-dimensional results user gear the present invention, during the entire natural gas when comprising at least 80% methane, the present in the embodiment according to liquefaction process in a proper system for a natural gas methane even utilized as a refrigerant, the heat exchanging area number 2 (112) plate sufficient cooling the by-products can be has been confirmed. Using the refrigerant nitrogen cooling step number 3 number 3 refrigeration cycle through the cooling feed stream. Nitrogen refrigerant, including, but nitrogen (nitrogen), further includes small amounts of impurities may be loaded with. Just, nitrogen refrigerant. most preferably is including only nitrogen. The present in the embodiment can be put into from air refrigerant nitrogen in.. Air nitrogen, oxygen, carbon dioxide, includes such as hydrogen. Thus separating nitrogen from air, various the current method thereof is disclosure. The present in the embodiment according to liquefaction process solid formulation as well as to the nitrogen as refrigerant nitrogen from air able to supply to KIPO & refrigeration cycle number 3. The present in the embodiment according to liquefaction process sequence using the refrigerant carbon dioxide as longitude refrigeration cycle number 1, number 2 refrigeration cycle using refrigerant methane, and nitrogen employing the refrigerant through refrigeration cycle number 3. for liquefying feed stream. State of the SP heads and carbon dioxide refrigerant from liquefaction plants, methane refrigerant from a natural gas, nitrogen and. can be put into from air refrigerant. If the liquefaction process in the embodiment according to which is highly safe water level refrigerant space telephon number that unit is off. In the prior art conventional for replenishment - adsorbers two to store a refrigerant, because the combustible generally refrigerant, refrigerant is safe that stored separately and are in not go side of. In addition the storage in the prior art conventional additional requisite storing - adsorbers, side of the detachably in not go. The present in the embodiment according to liquefaction process such includes a door number to solve is intended to. I.e., the present in the embodiment according to liquefaction process the refrigerant and, in supplement compares or minimize the storage of refrigerant, making it in that unnecessary or technical features KIPO &. It further in the embodiment according to liquefaction process a non combustible carbon dioxide and nitrogen refrigerant of time and thus utilized as a accordingly, the side of. highly desirable. Number 1 refrigeration cycle (C1) in particular can be described as follows: an. Carbon dioxide refrigerant first compression means (121) is compressed by. , Such as shown in Figure 2, compression means (121, 123) imbalance of the laundry the actuating lever which may be compressor (compressor), can be multistage. In one example, plurality of compression means (123) is connected at the first side of are sequentially, compression means (123) and compression means (123) between the cooling means (133) can be equipped by.. As such compression means (123) in case multi-stage compression is the total compression means when the hood or bonnet to be lifted KIPO & efficiency of. The the after alcoholic beverage it will do other. similar to that of the compression means. Then conduit refrigerant carbon dioxide (211) through which the cooling means (131) to enter the is cooled. Wherein cooling means (131) the liquid cooled or can be cooled of a refrigerator (cooler). The the after alcoholic beverage it will do other cool means. similar to that of the. Then carbon dioxide refrigerant conduit (212) through expansion means (141) is expansion process are introduced into. Thereby both pressure and the temperature are refrigerant carbon dioxide can be lowered.. Wherein expansion means the j-T(joule-thomson) valve can be. For example, expansion valve of conventional expansion means (expansion valve) can be. Line - Thompson valve a j-T through the effect and the pressure and temperature of refrigerant can be lowering both the. Then carbon dioxide refrigerant conduit (213) through the heat exchanging area number 1 (111) to enter the number 1 the heat exchanging area (111) includes a projection part curved upward and precooling feed stream in. Conduit (213) number 1 through the heat exchanging area (111) enters the carbon dioxide refrigerant, conduit (222) number 1 through the heat exchanging area (111) methane refrigerant enters the, conduit (232) number 1 through the heat exchanging area (111) with a stream of supply coolant nitrogen enters the. cooling. The conduit after cooling the refrigerant carbon dioxide (214) again through a compression means (121) is introduced into. With reference to, the conduits different digital drawing may be conduit each other may be conduit such as. I.e., of a heat exchanger 1 for facilitating of even 2 of the drawing may be S160. 2 in contrast to a spatially-or of even of a heat exchanger 1 for facilitating the drawing of S160 may be. Number 2 refrigeration cycle (C2) in particular can be described as follows: an. Methane refrigerant first compression means (122) is compressed by. Then methane refrigerant conduit (221) through which the cooling means (132) to enter the is cooled. Wherein cooling means (132) the can be optionally provided. Then methane refrigerant conduit (222) through the heat exchanging area number 1 (111) to enter the carbon dioxide is cooled to safer. Then methane refrigerant conduit (223) through expansion means (142) is expansion process are introduced into. Both pressure and the temperature are refrigerant methane thereby can be lowered.. Wherein expansion means (142) which expands the one refrigerant methane (work expanding) turbo expander (turbo expander) can be. Turbo [...] methane coolant can be work during. One such additional the power from the commercial voltage source may generate KIPO &. Number 2 refrigeration cycle such a expansion means by employing inverse toe ach of the frames (Reverse Brayton) cycle platen. may be based on. Platen cycle inverse toe ach of the frames and gaseous liquid refrigerant cycles in the case of thereby inducing a phase change not between. Holds the vapor typically refrigerant. Then methane refrigerant conduit (224) number 2 through the heat exchanging area (112) to enter the number 2 the heat exchanging area (112) in. for liquefying feed stream. Conduit (224) number 2 through the heat exchanging area (112) enters the methane refrigerant, conduit (233) number 2 through the heat exchanging area (112) with a stream of supply coolant nitrogen enters the. cooling. The conduit after cooling the refrigerant methane (225) again through a compression means (122) is introduced into. Number 3 refrigeration cycle (C3) in particular can be described as follows: an. Nitrogen refrigerant first compression means (123) is compressed by. Then nitrogen refrigerant conduit (231) through which the cooling means (133) to enter the is cooled. Wherein cooling means (133) the can be optionally provided. Then nitrogen refrigerant conduit (232) through the heat exchanging area number 1 (111) to enter the carbon dioxide is cooled to safer. Then nitrogen refrigerant conduit (233) number 2 through the heat exchanging area (112) to enter the methane is cooled to safer. Then nitrogen refrigerant conduit (234) through expansion means (143) is expansion process are introduced into. Both pressure and the temperature are refrigerant nitrogen thereby can be lowered.. Wherein expansion means (143) nitrogen may [...] turbo which expands the one refrigerant. Turbo [...] nitrogen coolant can be work during. One such additional the power from the commercial voltage source may generate KIPO &. Such a refrigeration cycle number 3 expansion means by employing inverse toe ach of the frames may be based on platen cycle.. Then nitrogen refrigerant conduit (235) through the heat exchanging area number 3 (113) to enter the number 3 the heat exchanging area (113) includes a projection part curved upward and cooling feed stream in. The conduit after cooling the refrigerant nitrogen (236) again through a compression means (123) is introduced into. Such feed stream a series routing process, the. can be liquefied. Even after liquefied such as a vapor partial in a feed stream can be including part of. Is such a case separating means (151) and gaseous liquid fraction feed stream through as only liquidus portion and then stored as liquefied natural gas tank can store the values in a KIPO & (not shown). Where the separating means (151) gas-liquid separator of the laundry the actuating lever can be (vapor-liquid separator). On the other hand, [table 1] down liquefaction process of Figure 1 operating-like refrigerant, and a moment when a computer simulation results as Figure 3. As far as shown in Figure 3, feed stream (Hot Composite) a carbon dioxide safer the highest temperatures is cooled in (reference S1), methane is cooled in safer (reference S2) formed and as over an intermediate temperature, safer nitrogen is cooled at a temperature lowest (S3 reference). The efficiency of the liquefaction process such a case is 0. 4301 kwh/kg by excellent shown. 111, 112, 113: the heat exchanging area 121, 122, 123: compression means 131, 132, 133: cooling means 141, 142, 143: expansion means 151: separating means The present invention relates to a natural gas liquefaction process for liquefying a supply stream including natural gas. The process includes: a first cooling step of cooling the supply stream in a first heat exchange area through a first freezing cycle using a carbon dioxide coolant; a second cooling step of cooling the supply stream in a second heat exchange area through a second freezing cycle using a methane coolant after the first cooling step; and a third cooling step of cooling the supply stream in a third heat exchange area through a third freezing cycle using a nitrogen coolant after the second cooling step. COPYRIGHT KIPO 2016 Natural comprises a feed stream for liquefying a natural gas liquefaction process in, using the carbon dioxide refrigerant through refrigeration cycle number 1 in the heat exchanging area number 1 number 1 said cooling step for cooling an feed stream; using the methane refrigerant after cooling said number 1 number 2 refrigeration cycle through said feed stream in the heat exchanging area number 2 number 2 for cooling an cooling step; nitrogen refrigerant after cooling said number 2 and number 3 refrigeration cycle through employing the number 3 the heat exchanging area in said cooling step number 3 for cooling an feed stream including natural gas liquefaction process. According to Claim 1, said feed stream for liquefying a liquefaction plants said carbon dioxide as refrigerant carbon dioxide discharged from said number 1 including further a nitrogen refrigeration cycle characterized in that natural gas liquefaction process. According to Claim 1, said at least a portion of said feed stream methane as refrigerant a nitrogen refrigeration cycle said number 2 including further characterized in that natural gas liquefaction process. According to Claim 3, said 80% or more in total in a natural gas including methane characterized in that natural gas liquefaction process. According to Claim 1, from air said nitrogen as refrigerant nitrogen said number 3 further including a nitrogen refrigeration cycle characterized in that natural gas liquefaction process. According to Claim 1, the refrigeration cycle said number 1, number 1 compression steps said carbon dioxide refrigerant in compressing said material; said carbon dioxide refrigerant after compression said number 1 number 1 cooling refrigerant cooling step; refrigerant cooling said number 1 after said number 1 the inflation phase a for expanding the refrigerant carbon dioxide; and said number 1 after the inflation phase carbon dioxide refrigerant in the heat exchanging area said number 1 through said said precooler for precooling feed stream including step characterized in that natural gas liquefaction process. According to Claim 6, said number 1, and of a rasp the inflation phase said through - Thompson valve for expanding the refrigerant carbon dioxide characterized in that natural gas liquefaction process. According to Claim 1, the refrigeration cycle said number 2, number 2 compression steps said methane refrigerant in compressing said material; said after compression said number 2 carbon dioxide refrigerant in the heat exchanging area said number 1 through number 2 cooling refrigerant cooling step said methane refrigerant; after said refrigerant cooling said number 2 for expanding the refrigerant methane number 2 the inflation phase a; and said number 2 after the inflation phase said methane refrigerant in the heat exchanging area said number 2 through said including step liquefied for liquefying a feed stream characterized in that natural gas liquefaction process. According to Claim 8, said number 2 through a turbo the inflation phase [...] said body which expands the one refrigerant methane characterized in that natural gas liquefaction process. According to Claim 8, said number 2 refrigeration cycle based on cycle platen toe ach of the frames the inverse characterized in that natural gas liquefaction process. According to Claim 1, the refrigeration cycle said number 3, said nitrogen refrigerant compression steps number 3 in compressing said material; after compression said number 3 said carbon dioxide refrigerant in the heat exchanging area said number 1 through number 3 - 1 cooling refrigerant nitrogen said refrigerant cooling step; refrigerant cooling said number 3 - 1 after said methane refrigerant in the heat exchanging area said number 2 through number 3 - 2 nitrogen refrigerant cooling said refrigerant cooling step; after refrigerant cooling said number 3 - 2 for expanding the refrigerant nitrogen said number 3 the inflation phase a; and said number 3 after the inflation phase nitrogen refrigerant in the heat exchanging area said number 3 through said said including step cooling grill feed stream characterized in that natural gas liquefaction process. According to Claim 11, a turbo the inflation phase [...] through said number 3 said one body which expands the nitrogen refrigerant characterized in that natural gas liquefaction process. According to Claim 11, the inverse refrigeration cycle said number 3 platen toe ach of the frames based on cycle characterized in that natural gas liquefaction process. Divided Component Composition (mol %) Carbon dioxide refrigerant Co2 100 Methane refrigerant (feed stream) Methane 97. 27 Ethane 1. 60 Propane 0. 35 I-butane 0. 20 N-butane 0. 20 I-pentane 0. 02 N-pentane 0. 02 Benzene 0. 04 Nitrogen 0. 03 Nitrogen refrigerant Nitrogen 100