19-04-2012 дата публикации
Номер: US20120094205A1
A solid oxide fuel cell stack having a plurality of cassettes and a compliant glass seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The compliant glass seal may include a glass, at least one metal selected from Groups 9, 10, and 11 of the periodic table, and fibers of yttria-stabilized zirconia (YSZ) to enhance the desirable properties of the compliant glass seal. The combined weight percentage of the at least one metal and YSZ in the compliant glass seal is 30 to 42.5 weight percent, preferably 37.5 percent. 1. A solid oxide fuel cell stack comprising:a first cassette having a first sealing surface;a second cassette having a second sealing surface complementary to said first sealing surface, wherein said second cassette is disposed proximate to said first cassette such that said second sealing surface is oriented toward said first sealing surface; anda compliant glass seal disposed between said first and second sealing surfaces, thereby joining said first cassette to said second cassette;wherein said compliant glass seal comprises at least one metal selected from a group consisting of metals in Groups 9, 10, and 11 of the Periodic Table, and a plurality of fibers disposed within an alkaline earth aluminosilicate (AEAS) glass.2. The solid fuel cell stack of claim 1 , wherein said plurality of fibers includes a material selected from a group consisting of zirconium oxide claim 1 , aluminum oxide claim 1 , and yttria-stabilized zirconia (YSZ).3. The solid oxide fuel cell stack of claim 2 , wherein said plurality of fibers includes YSZ.4. The solid oxide fuel cell stack of claim 3 , wherein said at least one metal is selected from a group consisting of Ag claim 3 , Ni claim 3 , Pd claim 3 , Pt claim 3 , and Rh.5. The solid oxide fuel cell stack of claim 4 , wherein at said least one metal is Ag.6. The solid oxide fuel cell stack of includes:a combined weight percentage of said ...
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