14-11-2013 дата публикации
Номер: US20130302754A1
Poly(hydridocarbyne) (PHC) is synthesized by a hybrid, active-metal/electrochemical method by applying a voltage to the electrodes at least one of which is an active-metal, the electrodes being immersed in a trisubstituted halomethane solution. The active-metal electrode and halomethane solution both partake in the electrochemical reaction. 1. A method for making poly(hydridocarbyne) (PHC) comprising using at least one active-metal electrode immersed in a trisubstituted halomethane solution in an electrochemical cell containing a conductive electrolyte.2. The method of wherein the active-metal electrode partakes in a reaction with said halomethane solution.3. The method of wherein said active-metal electrode is comprised of one or more elements or alloys thereof selected from among the class of elements consisting of lithium claim 1 , sodium claim 1 , potassium claim 1 , calcium claim 1 , magnesium claim 1 , zinc claim 1 , aluminum and silver.4. The method of wherein said trisubstituted halomethane solution comprises one or more trisubstituted halomethanes selected from among the group consisting of CHF claim 1 , CHClF claim 1 , CHBrF claim 1 , CHBrF claim 1 , CHCl claim 1 , CHBrCl claim 1 , CHBrCl claim 1 , CHBr claim 1 , CHI claim 1 , CHF claim 1 , CHCl claim 1 , CHBrand CHI.5. The method of wherein said conductive electrolyte is comprised of one or more salts claim 1 , said salts being at least somewhat soluble in said trisubstituted halomethane.6. The method of wherein said salt is a halide salt.7. The method of wherein said halide salt is selected from the group consisting of LiF claim 6 , NaF claim 6 , MgF claim 6 , CaF claim 6 , ZnF claim 6 , AlF claim 6 , AgF; LiCl claim 6 , NaCl claim 6 , MgCl claim 6 , CaCl claim 6 , ZnCl claim 6 , AlCl claim 6 , AgCl; LiBr claim 6 , NaBr claim 6 , MgBr claim 6 , CaBr claim 6 , ZnBr claim 6 , AlBr claim 6 , AgBr; LiI claim 6 , NaI claim 6 , MgI claim 6 , CaI claim 6 , ZnI claim 6 , AlIand AgI.8. The method of wherein said ...
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