05-10-2017 дата публикации
Номер: US20170283721A1
Принадлежит:
A two-reactor catalytic system including a catalytic membrane gasification reactor and a catalytic membrane water gas shift reactor. The catalytic system, for converting biomass to hydrogen gas, features a novel gasification reactor containing both hollow fiber membranes that selectively allow Oto permeate therethrough and a catalyst that facilitates tar reformation. Also disclosed is a process of converting biomass to H2. The process includes the steps of, among others, introducing air into a hollow fiber membrane; mixing the Opermeating through the hollow fiber membrane and steam to react with biomass to produce syngas and tar; and reforming the tar in the presence of a catalyst to produce more syngas. 1. A catalytic membrane system for converting biomass to H , the system comprising:{'sub': 2', '2, 'a gasification reactor disposed in which are one or more hollow fiber membranes for receiving air, one or more first containers, and a first catalyst confined in the one or more first containers, the one or more hollow fiber membranes selectively allowing O, not N, to permeate therethrough and the first catalyst capable of facilitating a reaction between the tar and steam,'}{'sub': 2', '2', '2, 'whereby, upon introduction of both air, through the one or more hollow fiber membranes, and steam, directly, to the gasification reactor, biomass placed in the gasification reactor reacts with steam and the Opermeating through the one or more hollow fiber membranes to produce tar and a syngas containing Hand CO; and the tar thus produced, in the presence of the first catalyst, reacts with the steam to produce more syngas containing Hand CO.'}2. The catalytic membrane system of claim 1 , further comprising:{'sub': 2', '2, 'a water gas shift reactor disposed in which are one or more second containers, a second catalyst confined in the one or more second containers, and one or more hollow metal-based membranes, the second catalyst capable of facilitating a reaction between a ...
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