23-04-2020 дата публикации
Номер: US20200122114A1
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The objective of the present invention is to provide a method for producing a fluorinated carbonate derivative in a safe and efficient manner. The method for producing a fluorinated carbonate derivative according to the present invention is characterized in comprising irradiating light on a composition containing a Chalogenated hydrocarbon having one or more kinds of halogen atoms selected from the group consisting of a chlorine atom, a bromine atom and an iodine atom, a fluorine-containing compound having a nucleophilic functional group and a base in the presence of oxygen. 2: The method according to claim 1 , wherein the fluorine-containing compound is a compound represented by formula (i-1) and the fluorinated carbonate derivative is a fluorinated carbonate derivative represented by formula (I-1) claim 1 , the fluorine-containing compound is a compound represented by formula (i-2) and the fluorinated carbonate derivative is a fluorinated carbonate derivative represented by formula (I-2) claim 1 , or the fluorine-containing compound is a compound represented by formula (i-3) and the fluorinated carbonate derivative is a fluorinated carbonate derivative represented by formula (I-3):{'br': None, 'sup': 'F11', 'sub': '2', 'RCH-A-H\u2003\u2003(i-1)'}{'br': None, 'sup': 'F12', 'sub': '2', '(R)CH-A-H\u2003\u2003(i-2)'}{'br': None, 'sup': 'F13', 'sub': '3', '(R)C-A-H\u2003\u2003(i-3)'}{'br': None, 'sup': F11', 'F11, 'sub': 2', '2, 'RCH-A-C(═O)-A-CH—R\u2003\u2003(I-1)'}{'br': None, 'sup': 12', 'F12, 'sub': 2', '2, '(R)CH-A-C(═O)-A-CH(R)\u2003\u2003(I-2)'}{'br': None, 'sup': F13', 'F13, 'sub': 3', '3, '(R)C-A-C(═O)-A-C(R)\u2003\u2003(I-3)'}whereinA is O, S or NH,{'sup': 'F11', 'sub': 1-10', '6-14', '4-14', '2-24, 'Ris a Cfluoroalkyl group, a Cfluoroaryl group, a Cfluoroheteroaryl group or a Cfluoro(alkylpolyoxyalkylene) group,'}{'sup': F12', 'F12', 'F12, 'sub': 1-10', '1-10', '6-14', '6-14', '4-14', '4-14', '2-24', '2-24', '1-10', '6-14', '4-14', '2-24', '2-6, 'two Rare ...
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