13-10-2016 дата публикации
Номер: US20160297992A1
Принадлежит:
Provided are polytriglyceride-AAG compositions, and corresponding coatings and coated articles. Also provided are methods for preparing the polytriglyceride-AAG compositions, and corresponding reagents including β-ketoimide compositions and triglyceride-AAG (acetoacetyl group) compositions. Coatings using the polytriglyceride-AAG compositions may be useful for, e.g., replacing bisphenol-A cross-linked coatings used in food and beverage containers, coating metal articles, and the like. 2. The method of claim 1 , the epoxidized triglyceride composition comprising epoxidized chains of fatty acid esters derived from one or more of: linolenic acid claim 1 , linoleic acid claim 1 , oleic acid claim 1 , myristoleic acid claim 1 , palmitoleic acid claim 1 , sapienic acid claim 1 , elaidic acid claim 1 , vaccenic acid claim 1 , linoelaidic acid claim 1 , α-linolenic acid claim 1 , arachidonic acid claim 1 , eicosapentanenoic acid claim 1 , erucic acid claim 1 , docosahexaenoic acid claim 1 , ricinoleic acid claim 1 , coconut oil claim 1 , palm kernel oil claim 1 , palm oil claim 1 , cottonseed oil claim 1 , wheat germ oil claim 1 , soybean oil claim 1 , olive oil claim 1 , corn oil claim 1 , sunflower oil claim 1 , safflower oil claim 1 , hemp oil claim 1 , canola/rapeseed oil claim 1 , castor oil claim 1 , oil of legume seeds claim 1 , oil of non-legume seeds claim 1 , animal fat claim 1 , and soybean oil.5. The method of claim 1 , further comprising contacting the epoxidized triglyceride composition and the epoxy-reactive nucleophilic compound in the presence of one of an acid catalyst and a base.6. The method of claim 1 , the triglyceride-AAG composition comprising: a fatty acid ester;', 'at least one hydroxyl group bonded to an alkyl chain of the fatty acid ester; and', 'a β-ketoester group, the β-ketoester group bonded to a carbon atom alpha to a carbon atom bearing the hydroxyl group., 'a triglyceride-AAG comprising7. The method of claim 1 , the AAG-substituted epoxy- ...
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