22-06-2017 дата публикации
Номер: US20170173866A1
Принадлежит:
Disclosed herein are curable resins incorporating a radiation-cured network and a heat-cured thermoset with a cyanate ester to allow the creation of three-dimensional printed parts. These parts exhibit desirable mechanical properties, desirable thermal properties, and/or desirable dielectric properties. Methods of forming a three-dimensional object making use thereof are also described. 2. The method of claim 1 , wherein said object comprises an injection mold.3. The method of claim 1 , wherein said object has at least one claim 1 , or a plurality of claim 1 , cooling channels formed therein.4. The method of claim 1 , wherein said cavity filler material comprises an organic or inorganic particulate.5. The method of claim 1 , wherein said cavity filler material comprises a polymerizable resin.6. The method of claim 1 , wherein said cavity filler material comprises an inert liquid.7. The method of claim 1 , wherein R is a phenyl claim 1 , naphthyl claim 1 , anthryl claim 1 , phenanthryl claim 1 , or pyrenyl group.8. The method of claim 1 , wherein R is a phenyl claim 1 , biphenyl claim 1 , naphthyl claim 1 , bis(phenyl)methane claim 1 , bis(phenyl)ethane claim 1 , bis(phenyl)propane claim 1 , bis(phenyl)butane claim 1 , bis(phenyl)ether claim 1 , bis(phenyl)thioether claim 1 , bis(phenyl)sulfone claim 1 , bis(phenyl) phosphine oxide claim 1 , bis(phenyl)silane claim 1 , bis(phenyl)hexafluoropropane claim 1 , bis(phenyl)trifluoroethane claim 1 , or bis(phenyl)dicyclopentadiene group claim 1 , or a phenol formaldehyde resin.9. The method of claim 1 , wherein said at least one cyanate ester compound is selected from the group consisting of: 1 claim 1 ,3- claim 1 , or 1 claim 1 ,4-dicyanatobenzene; 1 claim 1 ,3 claim 1 ,5-tricyanatobenzene; 1 claim 1 ,3- claim 1 , 1 claim 1 ,4- claim 1 , 1 claim 1 ,6- claim 1 , 1 claim 1 ,8- claim 1 , 2 claim 1 ,6- or 2 claim 1 ,7-dicyanatonaphthalene; 1 claim 1 ,3 claim 1 ,6-tricyanatoaphthalene; 2 claim 1 ,2′ or 4 claim 1 ,4′- ...
Подробнее