07-01-2016 дата публикации
Номер: US20160002394A1
A polymer comprises reaction product of (a) one or more diacid, diester thereof, glycolide, and (b) one or more polyol, wherein component (a) comprises glycolide or combinations thereof, and component (b) comprises one or more polyol comprising a mixture of 1,3-cyclohexanedimethanol and 1,4-cyclohexanedimethanol, or 2,2,4,4-tetramethyl-1,3-cyclobutanediol, or combinations thereof. 1. A polymer comprising reaction product of component (a) comprises glycolide , and component (b) one or more polyol comprising a mixture of 1 ,3-cyclohexanedimethanol and 1 ,4-cyclohexanedimethanol , or 2 ,2 ,4 ,4-tetramethyl-1 ,3-cyclobutanediol , or combinations thereof.2. The polymer of wherein component (a) further comprises 0.1 to 95 mol. % claim 1 , based on the total amount of component (a) of furan dicarboxylic acid (FDCA) or 1 claim 1 ,5-naphthalene dicarboxylic acid (NDCA) claim 1 , one or more Cto Calkyl diester thereof claim 1 , or combinations thereof.3. The polymer of wherein component (a) comprises dimethyl furanoate (DMF).4. The polymer of wherein component (a) comprises dimethyl naphthanoate (DMN).5. The polymer of wherein component (a) comprises 10 to 90 mol. % of glycolide and 10 to 90 mol. % of one or more Cto Calkyl diester of FDCA or NDCA or combinations thereof claim 2 , based on the total amount of component (a).6. The polymer of wherein component (b) further comprises 10-90 mol. % claim 1 , based on the total amount of component (b) polyol claim 1 , of ethylene glycol.7. The polymer of wherein component (b) comprises 25 to 75 mol. % claim 1 , based on the total amount of component (b) claim 1 , of 1 claim 1 ,3-cyclohexanedimethanol and 25 to 75 mol. % claim 1 , based on the total amount of component (b) claim 1 , of 1 claim 1 ,4-cyclohexanedimethanol.8. The polymer of wherein component (b) comprises 45 to 65 mol. % claim 7 , based on the total amount of component (b) claim 7 , of 1 claim 7 ,3-cyclohexanedimethanol and 35 to 55 mol. % claim 7 , based on the total ...
Подробнее