Anschmelzung zwischen einem Metall- und einem Glasteil

SEMICONDUCTOR DEVICE MOUNT CAPS

... 1403837 Glass to metal seals STANDARD TELEPHONES & CABLES Ltd 4 May 1973 21244/73 Heading C1M A cylindrical cap for a semi-conductor device mount has a metal tube 32 sealed to a flat disc 30 of a first glass whose curved edge is coated with a second glass 31 having a flow temperature (viscosity 105 poises) lower than the transformation temperature (viscosity 1013 poises) of the first glass. The cap is formed by fitting the disc into the oxide coated tube and heating to the flow temperature of the second glass. A preferred first glass comprises in percentage by weight SiO 2 56À5; B 2 O 3 4À0; Al 2 O 3 16À5; MgO 7À5; CaO 9À0; BaO 6À5; (transformation temperature 720‹ C.); while a preferred second glass comprises SiO 2 27À2; B 2 O 3 5À0; Al 2 O 3 11À7; Pb 2 O 3 51À8; CdO 3À8; Sb 2 O 3 0À5 (flow temperature 650‹ C.). The thermal expansion coefficiency are 53 x 10-7 per ‹ C. and 54 x 10-7 per ‹ C. respectively so that a matched seal is produced. The tube is ...

Improvements relating to methods of attaching a vitreous surface to a metal or vitreous surface

... 651,492. Discharge lamps. GENERAL ELECTRIC CO., Ltd., and MILES, E. E. Aug. 16, 1948, No. 21589. [Class 39 (i)] A thin metal starting conductor is attached to the exterior surface of the glass envelope of an electric discharge lamp by introducing polyethylene in a plastic or liquid condition between the conductor and the surface of the envelope and solidifying the polyethylene. The attachment may be effected by placing solid polyethylene between the conductor and the envelope, rendering the polythene plastic or liquid by heating the envelope or using a preheated envelope and pressing the conductor against the glass surface with a roller. Alternatively the conductor may be embedded in the polythene by placing a layer of the polythene on the conductor as well as between the conductor and envelope, e.g. using a length of polyethylene coated strip or wire and pressing the strip against the preheated envelope surface.

Improvements in or relating to the application of glass coatings to metals

... 686,519. Coating surfaces with glass. SHEPHERD, G. R. (Westinghouse Electric International Co.). Oct. 5, 1951, No. 23229/51. Drawings to Specification. Class 56. [Also in Group XXXVI] Molybdenum or tungsten surfaces, particularly of electric leading-in wires for evacuated devices, are protected against oxidation by applying thereto powdered glass (e.g. in a suspension) having a compatible coefficient of expansion, and firing in a neutral atmosphere to fuse the glass thereto as a protective enamel coating. A glass member (e.g. a glass bead for sealing in) is subsequently fused, in air, on to an intermediate portion only of the protective enamel coating, or an intermediate portion of the coating itself may be used for the sealing in.

Improvements in and relating to quartz-to-metal seals

... 696,360. Quartz-metal seals. BRITISH THOMSON-HOUSTON CO., Ltd. June 12, 1952 [June 19, 1951], No. 14844/52. Class 36. In sealing a refractory metal conductor 2 through a quartz tube, the conductor is hermetically united to a refractory metal sealing disc 4, on either side of which is placed one of a pair of annular vitreous wafers 8 having a lower softening temperature than quartz and a coefficient of expansion between that of quartz and that of the metal of disc 4, the ends of the conductor are mounted in quartz tubes 14, 15 having flared inner ends 16, 17 so that the peripheries of the flares, the wafers and the disc are juxtaposed, the peripheries of the flares are softened by heat while a non-oxidizing atmosphere is maintained about the disc, and the flares are moved together so that they are united to each other and to the wafers, while the wafers are united to the disc. The conductor 2, which may be of tungsten, may be enclosed in molybdenum foil 3. The disc 4, which may be cupshaped ...

Improvements in or relating to a method of sealing glass to enamelled iron, more particularly a window to a cone of a cathode-ray tube

... 740,331. Glass-metal seals. PHILIPS ELECTRICAL INDUSTRIES, Ltd. April 22, 1954 [April 25, 1953], No. 11690/54. Class 36. In sealing a glass member to an enamelled iron surface, the latter is previously coated in the sealing zone with a layer of glass powder having substantially the same composition as the glass member. A hard glass window having a sealing temperature of more than 1000‹ C. may be sealed to the enamelled iron cone of a cathode-ray tube in this manner. The glass powder may be applied as a suspension which is dried and cooled prior to the sealing operation, when it forms a protective layer over the enamel.

Improvements in and relating to Hermetic Seals for the Leading-in Wires of Electric Lamps and like Apparatus.

... 130,212. British Thomson - Houston Co., (General Electric Co.). Sept. 26, 1918. Drawings to Specification. Coating-machines.-A wire is coated with paste by holding it against a sharp-edged rotating wheel, partially immersed in the paste.

Improvements in and relating to apparatus for and method of making silica glass

... 188,451. British Thomson-Houston Co., Ltd., (General Electric Co.). Sept. 14, 1921. Resistance furnaces.-A vacuum furnace for use in making silica glass comprises a tank 1 which is provided with a pipe 15 for evacuation of the air and may be fitted with a water jacket 7. The silica is contained in a cylindrical graphite crucible 8 supported within a helical resistance 9 that is provided with terminals 10, 11 supported by water cooled tubes 12, 13. The resistance is surrounded by a heat screen 14 consisting of a shell of carbon containing a refractory material. The furnace may be fitted at its upper part with a removable column 4 through which a shaft 5 carrying at its end a piston 6 may be introduced for compressing the plastic silica. Alternatively, the silica may be compressed by gas introduced into the furnace through the pipe 15.

Reflector Type Lamp

Procedure for the attachment of a schraubenlinienförmig wound leader at isolating supporting staffs

METAL-TO-GLASS-TO-CERAMIC SEAL

Procédé de réalisation d'une soudure étanche entre une pièce de verre et une pièce creuse en métal et soudure obtenue suivant ce procédé.

Verfahren zur Herstellung von als Elektronenschalter zu verwendenden Braunschen Röhren.

Glasgefäss.

Elektrische Entladungsröhre.

Procédé pour sceller l'un à l'autre des matériaux dont le coefficient de dilatation est compris entre 45.10-7 et 60.10-7.

Anschmelzung zwischen einem Metallteil und einem Glasteil.

Verfahren zur Herstellung einer Elektronenstrahlröhre mit einem Metallhohlkegel und einem den Fluoreszenzschirm tragenden Glasfenster.

Verre de borosilicate de plomb

Verfahren zum Giessen von spanlos aufteilbaren Gusssträngen.

Elektrodeneinschmelzung für Hochdruckentladungslampen

Verfahren zum vakuumdichten Einschmelzen eines Leiters in die Wand eines Entladungsgefässes und nach diesem Verfahren eingeschmolzener Leiter

Künstlich gekühlte Quecksilberdampfentladungsröhre.

Verfahren zum Herstellen zusammengesetzter, mindestens eine Verbindung zwischen Metall und einem glasartigen Teil enthaltender Körper

Verfahren zum Einschmelzen von wenigstens oberflächlich aus Nickel bestehenden Kontaktstiften für eine elektrische Entladungsröhre in Glas

Verfahren zum Zuschmelzen von in ein gläsernes Material eingeschlossenen Halbleiter-Schaltelementen und Vorrichtung zur Durchführung dieses Verfahrens

Verfahren zur Herstellung eines durch isolierende Stützstäbe gehaltenen Wendelleiters, insbesondere für eine Wanderfeldröhre

Verfahren zum vakuumdichten Verschliessen einer Öffnung in einem Körper mit mindestens einem Hohlraum und Anwendung des Verfahrens zum Verschliessen einer Öffnung des Hohlraumresonators eines Reflexklystrons

Paroi de verre comprenant une traversée et procédé de réalisation de cette paroi

Halbleiterelement und Verfahren zu dessen Herstellung

Dispositif d'entrée de courant à travers une paroi de verre

Korrosionsbeständiges Verbundrohr

Process for sealing seals with the vacuum of a driver in the wall of a container with discharge in gases

Sophisticated compositions of glasses resisting the alkaline vapors

Process of sealing of glass to enamelled iron

Sealing of leads of electric lamps

Methods and apparatuses for manufacture of silica glass

Methods and apparatuses for manufacture of silica glass

Methods and apparatuses for manufacture of silica glass

CRYSTALLIZING GLASS SOLDER AND USE THEREOF

ELECTRIC LAMP

NOVEL GLASS COMPOSITIONS AND METHOD FOR PRODUCING A GLASS/METAL JOIN

Novel glass compositions and method for producing a glass/metal join, in which the novel glass comprises: depending on the necessary requirements, highlighting, owing to the significance thereof, the thermal expansion coefficient such that said thermal expansion coefficient is adjusted to match that of the metallic or alloy part with which the glass/metal weld is to be achieved, which makes it possible to satisfactorily produce said weld, which results in a strong glass/metal join that is free from tensile stresses and that is durable over time and may be used, inter alia, to obtain parts that form part of solar collectors.

SEALING LIGHTING DEVICE COMPONENT ASSEMBLY WITH SOLDER GLASS PREFORM BY USING INDUCTION HEATING

Disclosed is a process for sealing component assembly to an electrical lighting device using induction heating. The assembly comprises the component, such as an electrode lead wire, and a solder glass preform. The process is useful, for example, in hermetically sealing and affixing lamp components, such as electrical lead wires and exhaust tubulation, to a low-pressure fluorescent discharge lamp envelope having phosphor coating already applied thereto. The present invention is particularly suitable for lamp envelopes made of borosilicate glass having a CTE from 0 to 300°C in the range of 30-45x10-7 °C-1.

GLASS ENAMELLING

The invention concerns glass enamelling. The application of an enamel layer brings about a substantial modification in surface stresses of the glass sheet. Said modifications embrittle the sheet. In order to avoid such effects or at least to minimise them, the invention provides a treatment which consists in limiting the enamel composition curing. The inventive treatment is applicable to all uses wherein the enamelled part is subjected to mechanical loads, which is the case, for example, of enamelled zones whereon accessories are bonded.

Glass ceramic composites

A method for joining glass ceramic surfaces to each other and/or other types of surfaces using a silicate liquid is disclosed. The products are suitable for use as, e.g. mirror blanks or microlithography stages, at low temperatures. Component pieces are polished then joined at low temperature using a silicate-containing joining liquid. Assembly is then performed in such a way that the joining liquid forms an interface between each component. After a period of low or slightly elevated temperature curing, rigid joints are formed throughout and the composite is dimensionally, vibrationally, and temperature stable and can withstand tensile stresses >4000 psi. The room-temperature cured composite can be heat treated using a slow, systematic temperature increase to dehydrate the joints. A sealing coating may optionally be provided to prevent excess dried joining liquid from flaking off the formed joint.

PETALITE-SPODUMENE-POTASSIUM SILICATE CEMENT FOR BONDING METAL TO GLASS

METAL-TO-GLASS-TO-CERAMIC SEAL

A method of making a seal comprising a metal member bonded to a glass member, said glass member in turn bonded to a ceramic member, said glass member and said ceramic member being resistant to corrosive materials in the device being sealed, said metal member, glass member and ceramic member having compatible coefficients of thermal expansion.

Hermetic glass-to-metal seal and method for making same

This invention relates to a manufacturing method and a hermetic glass-to-metal seal suitable for a component in an electric circuit such as a liquid tantalum electrolytic capacitor. The method comprises the steps of fusing a raw material glass in order to form a glass tube; setting a bead, obtained by cutting the glass tube across the axis, in the opening to be sealed, for example, the opening of a member which forms a circuit component; and heating the assembly of the members which composes the circuit component including the bead, above the melting temperature of the bead, with a longitudinal conductor piercing through the bead. This simplified method of manufacturing a hermetic glass-to-metal seal accomplishes a perfect sealing since the sealing glass includes no undesirable impurities such as binder, and since the thermal expansion coefficient of the sealing glass is close to that of the metals used to construct the circuit components, and the sealing glass is stable to electrolyte.

Glass ceramic composite of mirror blank

A method for fabricating composite light-weighted glass ceramics, suitable for use as, e.g. mirror blanks or microlithography stages, at low temperatures is disclosed. Component pieces are polished then joined at low temperature using a silicate-containing joining liquid. Assembly is then performed in such a way that the joining liquid forms an interface between each component. After a period of low or slightly elevated temperature curing, rigid joints are formed throughout and the composite is dimensionally, vibrationally, and temperature stable and can withstand tensile stresses >4000 psi. The room-temperature cured composite can be heat treated using a slow, systematic temperature increase to dehydrate the joints. A sealing coating may optionally be provided to prevent excess dried joining liquid from flaking off the formed joint.

Verfahren zum Herstellen einer Glas-Titan-Dichtung und Glas-Titan-Dichtung

Joining optical glass to metal - using crystallising glass solder

Optically ground glass windows are joined to metal frames at temps. below or at the most within the transformation range of the glass window material by employing a glass solder which crystallises. The solder should pref. have a m.pt. of 425-450 degrees C. The method ensures that the optical glass windows do not distort. The windows are used for viewing in vacuum equipment, etc.

Bei Temperaturen von mindestens 500°C arbeitende Halogen-Glühlampe

LAMP SEAL GLASS

Manufacture of butyraldehyde and a catalyst therefor

Butyraldehyde is prepared by the catalytic hydrogenation of crotonaldehyde at temperatures between 160 DEG and 250 DEG C. using as catalyst a material obtained by the application to a catalyst support of nickel oxide and copper sulphate, the latter in a proportion of 0.5-5% based on the combined weight of nickel oxide and support, followed by partial reduction at a temperature in the range 160-250 DEG C. Preferably equimolar proportions of hydrogen and crotonaldehyde are used and the hydrogen is diluted by nitrogen, methane or other hydrocarbons. Suitable catalyst supports are, for example, pumice grains, ceramic materials, kieselguhr, silica gel and pumice powder.ALSO:A catalyst for use in the hydrogenation of crotonaldehyde to butyraldehyde is obtained by applying to a support nickel oxide and copper sulphate, the latter in a proportion of 0.5-5% calculated on the combined weight of nickel oxide and support, and partially reducing at a temperature in the range 160-250 DEG C. Suitable ...

Improvements relating to the manufacture of cathode ray tubes

... 670,430. Cathode-ray tubes. ELECTRIC & MUSICAL INDUSTRIES, Ltd. May 1, 1947 [June 20, 1946], No. 4747/49. Divided out of 670,411. Class 39 (i). A cathode-ray tube has at least a substantial part of its envelope formed of borosilicate glass having a coefficient of expansion of 33- 35 x 10-7 approximately, and metal leads having a coefficient of expansion of the order of 49Î10-7connected to electrodes sealed in a disc-like glass seal formed of glass having a coefficient of expansion of approximately 47 x 10-7 or higher, the seal being sealed in the first glass-part by means of at least one additional part of glass having an intermediate coefficient of expansion. In an example the metal and glasses used are identical with those used in the example described in Specification 670,411 which is referred to. Reference has been directed by the Comptroller to Specification 420,634 and to the document " Technical Data on Chance Sealing Glasses (Chance Bros., Ltd., Smethwick ...

BONDING AGENT ON BASIS OF AQUEOUS ALKALIMETALLSILICATLÖSUNGEN AND THEIR USE.

Procedure for the production of glass window melting downs

Procedure for manufacturing a compound, at least one metallic glass connection of containing body

Crystallizing glass solder and use thereof

The present invention relates to crystallizing glass solders and composites, which are suited in particular for high-temperature applications, and to applications thereof, such as in fuel cells. The crystallizing glass solder contains 25% to 40% by weight of SiO, 45% to 60% of BaO, 5% to 15% of BO, 0 to <2% of AIO and at least one alkaline earth oxide, selected from the group consisting of MgO, CaO and SrO, wherein CaO is 0% to 5% and is characterized by a thermal expansion coefficient of 8.010 K to 13.010 K in the temperature range of 20°C to 300°C.

A VACUUM INSULATING GLAZING, A SEALING, AND A METHOD OF PRODUCING VACUUM INSULATING GLAZING

A vacuum multilayer glass configured by layering a first and second glass substrate with a gap therebetween, the gap being in a low pressure state less than the atmospheric pressure, characterized in that: said gap is sealed with a sealing member; said sealing member comprises a metal member and a vitrification layer for joining the metal member and the glass substrates; and said metal member is selected from among materials that satisfy the requirement Y=0.10X [wherein X represents tensile strength (N/mm2) and Y represents breaking elongation (%)], when being maintained in the atmosphere at 490°C for 40 minutes and then subjected to a room temperature tensile test at a tensile speed of 1 mm/min.

Tube composite corrosion resistant

Improvements in and relating to apparatus for and method of making silica glass

Process of fixing of a helical driver rolled up on insulating stems supports, and travelling wave tube equipped with such a driver

Methods and apparatuses for manufacture of silica glass

Semiconductor device encapsulated in glass and manufactoring process of this device

Improvements with the joints quartz-metal

FLASHLIGHT

PETALITE?SPODUMENE?POTASSIUM SILICATE CEMENT FOR BONDING METAL TO GLASS

Mode of tungsten wire sealing in quartz

GLASS COMPOSITION FOR SEALING CONNECTOR MICRO-D

La présente invention concerne une composition de verre à base d'oxyde de tellure pour le scellement verre-métal d'alliage ou de métaux ayant un coefficient de dilatation thermique supérieur à 16ppm/°C, ladite composition comprenant du TeO2, du ZnO, un oxyde choisi parmi TiO2, K2O et leurs mélanges et éventuellement du CsCl et étant essentiellement exempte d'oxyde de plomb, d'oxyde de sodium et d'oxyde de vanadium. Elle concerne de plus l'utilisation de la composition de verre selon l'invention pour le scellement verre-métal du cuivre ou d'un alliage de cuivre avec un alliage ou un métal ayant un coefficient de dilatation thermique supérieur à 16ppm/°C. Elle concerne en outre un connecteur comprenant un contact en cuivre ou en alliage de cuivre, un insert et/ou boîtier en métal ou alliage ayant un coefficient de dilatation thermique supérieur à 16ppm/°C et en tant que matériau de scellement verre-métal entre le contact et l'insert et/ou boîtier un verre à base d'oxyde de tellure ayant la ...

LEAD-FREE GLASS MATERIAL FOR USE IN SEALING AND, SEALED ARTICLE AND METHOD FOR SEALING USING THE SAME

METHOD FOR THE PERMANENT CONNECTION OF TWO COMPONENTS BY MEANS OF GLASS OR METAL SOLDER

The invention relates to a method for the permanent connection of two components by soldering using a glass or metal solder as the solder material, in which a layer system providing adhesion is applied to each of the two components, between which the solder material is applied that has been heated to a soldering temperature characteristic of said solder material and, after cooling, causes a permanent connection between the two components. The invention is characterized in that the layer system providing adhesion comprises an adhesive layer applicable directly to the components and a solderable layer, wherein, if a glass solder is used, the adhesive layer contains oxide, carbide, or nitride components or mixed compounds thereof and, if a metal solder is used, said adhesive layer contains carbide or nitride components or mixed compounds thereof.

Hermetic seals for lithium-ion batteries

Advanced implanted medical devices require long-lived, reliable power supplies. Lithium-ion batteries can be used to meet this need if they can be assured of maintaining a hermetic seal while implanted. The invention is a hermetic seal for a lithium-ion battery where the battery header is made of aluminum and the pin is a conventional metal, such as platinum. The glass-to-metal seal utilizes low-temperature processable ALSG-32 glass, which has been demonstrated to bond to aluminum at temperature below the melting point of aluminum and which has been demonstrated to exhibit excellent resistance to lithium battery electrolyte. ALSG-32 is a high phosphate glass having about 6.0% B2O3, 40.0% P2O5, 15.0% Na2O, 18.0% K2O, 9.0% PbO, and 12.0% Al2O3, expressed in mole percent.

Lead-free glass material for use in sealing and, sealed article and method for sealing using the same

Provided with a glass composition including a network-former oxide composed of any one of or both of B 2 O 3 and V 2 O 5 of 20-80% by weight, ZnO of 0-60% by weight and BaO of 0-80% by weight, wherein at least one of ZnO and BaO is included as an essential ingredient. The present invention is a glass material for use in sealing, which is of lead-free series, can be used for sealing at a low processing temperature and within a wide temperature range, has a low thermal expansion coefficient, superior adhesion, superior sealing processability, superior adherence, superior chemical stability, superior strength and the like and comprises sufficient practical performance to substitute for lead glass.

Crystallizing glass solders and uses thereof

A crystallizing glass solder for high-temperature applications, which is free of PbO and contains, in % by weight on an oxide basis: 45% to 60% of BaO; 25% to 40% of SiO2; 5% to 15% of B2O3; 0 to <2% of Al2O3; 2 to 7.0, preferably 4.4 to 7.0%, of MgO; and at least one alkaline earth metal oxide from the group consisting of MgO, CaO and SrO, wherein CaO is 0% to 5% and the sum of the alkaline earth metal oxides MgO, CaO and SrO is 2% to 15%. Preferred embodiments of the glass solder contain from 3 to 15 wt. % of Y2O3 and have low porosity and high stability with respect to a moist fuel gas environment.

Стекло для спаивания с металлами

СТЕКЛО ДЛЯ СПАИВАНИЯ С МЕТАЛЛАМИ, включающее SiO, , NaiO . KiO, LijO, ZnO, CdO, CaO, тличающесс  тем, что. с целью повышени  электроизол ционных свойств стекла и обеспечени  получени  спаев методами керамической технологии, оно дополнительно содержит FejOj при следующем соотношении компонентов, мас.%: SiOj23-26 13,0-13,5 BjO, 11-15 . NajO 14-17 KjO 2-3 Li. ZnO15-18 CdO3-4 CaO7-8 SnOi2,0-2,5 1,3-2,0 Fe.Oj GLASS FOR SALVING WITH METALS, including SiO,, NaiO. KiO, LijO, ZnO, CdO, CaO, similar to that. in order to improve the electrical insulating properties of glass and to ensure the fabrication of junctions using the methods of ceramic technology, it additionally contains FejOj in the following ratio of components, wt%: SiOj23-26 13.0-13.5 BjO, 11-15. NajO 14-17 KjO 2-3 Li. ZnO15-18 CdO3-4 CaO7-8 SnOi2-2-2.5 1.3-2.0 Fe.Oj

Einschmelzung von aus Wolfram oder Molybdaen bestehenden Stromzufuehrungsdraehten inQuarzglasgefaesse

GASENTLADUNGSLAMPE, INSBESONDERE BLITZROEHRE

Vakuumdichte Stromleitereinschmelzung in Quarzglas

Verfahren zum Verbinden von Glasteilen und durch dieses Verfahren hergestellter Gegenstand, insbesondere Elektronenstrahlroehre

Improvements in articles consisting partly of quartz and partly of metal

... 224,870. British Thomson-Houston Co., Ltd., (Assignees of Berry, E. R.). Nov. 17, 1923, [Convention date]. Forming silica-glass articles. -A method of joining a metal body, such as a wire 4, to an article 1 of quartz consists in forming a cavity in the quartz, coating the metal with glass 6 which has a coefficient of expansion between that of the quartz and that of the metal, inserting the coated metal body into the cavity and then heating to a temperature sufficiently high to fuse the metal, glass, and quartz to each other. The wires 4 in the article shown are of tungsten or molybdenum and are coated with a sodiummagnesium borosilicate glass.

Improvements in or relating to methods of closing in a vacuum-tight manner and opening in a hollow body

... 1,134,914. Jointing; soldering. PHILIPS ELECTRONIC & ASSOCIATED INDUSTRIES Ltd. 6 April, 1967 [9 April, 1966], No. 15894/67. Headings B3R and B3V. [Also in Division H1] A method of sealing an opening 3 in a hollow body 1 by means of a plate 4 secured in a grooved ring 5 by sealing material 6 comprises placing the sealing material in pulverulent state along the edge of the plate, subjecting the hollow body to the action of a vacuum pump 13, heating the body to a temperature exceeding the softening temperature of the sealing material until the vacuum in the hollow body reaches a maximum, and ensuring that the sealing material solidifies before it can be sucked into the hollow body. Cavities in conductive or insulating bodies may be sealed, and the sealing material may be a vitreous material, a thermohardening or thermoplastic synthetic resin, or a solder, e.g. Ti-Ni, Cu-Au or Cu-Sn. An alloy solder may be used in which one of the constitutents is in excess of the eutectic ratio. The edge ...

Glass and articles comprising the same

... 791,969. Glass. PITTSBURG PLATE GLASS CO. Oct. 7, 1955 [Oct. 14, 1954], No. 28625/55. Drawings to Specification. Class 56. A lead borosilicate glass for adhering to a nickel-iron alloy containing approximately equal parts by weight of iron and nickel, or to a metal oxide coating on said alloy, and for sealing to a lime-soda-silica glass comprises 67 to 75 per cent by weight PbO, 12-16 B 2 O 3 , 10-15 SiO 2 and about 4 per cent by weight Al 2 O 3 . The invention also includes the composite article for sealing to a lime-soda-silica glass and comprising a nickel-iron alloy containing approximately equal parts by weight of iron and nickel adhered to a lead borosilicate glass comprising 67-75 per cent by weight PbO, 12-16 Bz O 3 , 10-15 SiO 2 and 0-5 Al 2 O 3 . The invention is described with special reference to spacer elements and pore-sealing eyelets in multiple glazing units. Specification 734,922 is referred to.

Improvements in or relating to artificially cooled mercury vapour discharge tubes

... 431,923. Glass manufacture. NAAMLOOZE VENNOOTSCHAP PHILIPS' GLOEILAMPENFABRIEKEN, Emmasingel, Eindhoven, Holland. Feb. 26, 1935, No. 6183. Convention date, Nov. 5, 1934. Drawings to Specification. [Class 56] [See also Groups XL and XI] Tungsten leading-in wires are covered with insulating material and are sealed into a quartz high-pressure discharge tube by intermediate members consisting of 88À3 per cent of SiO2, 8À4 per cent of B2O3, 2À9 per cent of Al2O3, and 0À4 per cent of CaO.

Process for connecting glass and metal pieces having tubular ends

... 223,933. Compagnie GÚnÚrale de TÚlÚ- graphie sans Fil. Oct. 27, 1923, [Convention date]. Joints formed by molten glass. - To make an air-tight joint between a metal and a glass tube of the same diameter, for example in electric lighting and wireless signalling apparatus, a ring 4 of fusible glass is placed on the glass tube 3 at a short distance from the end, and while heated sufficiently to make the ring plastic the glass tube is pushed into the internally-enamelled flared end 2 of the metal tube 1.

Improvements in or relating to glass to metal seals

... 583,207. Metal-to-glass seals. M-O VALVE CO., Ltd., MANNERS, M., and PARTRIDGE, J. H. July 16, 1945, No. 18134. [Class 36] A metal surface is prepared for sealing to glass, for use in the construction of thermionic valves, by applying a thin coating of alkali-free boro-silicate glass by an enamelling process, the enamel being fired in a non-oxidizing, or reducing, atmosphere. The enamel slip may be applied by dipping, painting or spraying. The coating is stated to be particularly advantageous for seals used under tropical conditions, and the following are given as suitable compositions :- ...

Improvements in or relating to sealing of metal to vitrified materials such as glass, silica, porcelain and the like

... 584,935. Sealing metal to vitreous material. CROSSLEY, P. B., and ENFIELD ROLLING MILLS, Ltd. May 4,1944, No. 8472. [Class 36] A water-insoluble basic flux for sealing metal to glass or other vitrified material is compounded of lead oxide and a hydrated lead borate. The lead oxide may be replaced in part by one or more other metal oxides of the general formula RO or R2O3, e.g. oxides of barium, magnesium, manganese and bismuth. One or more alkali metal oxides, e.g. sodium, potassium or lithium, may also be embodied in the flux. The hydrated lead borate may be prepared by precipitation from a solution of lead acetate by means of borax, warmed with ammonia, and then boiled with a solution of boric acid. The flux may be used dry, or in water suspension. The stability of the suspension may be enhanced by the addition of a hydrogel, sodium silicate or ammonium nitrate. When the metal and vitrefied materials have widely different expansion coefficients, a flux having a coefficient more suitably ...

Improvements in and relating to Electric Conductors.

... 4235. British Thomson-Houston Co., [General-Electric Co.]. Feb. 18. Leading-in wires for incandescent lamps, mercury rectifiers, &c. are coated with a film of a borate, which is fused so as to form a continuous covering for the conducting core. The core may consist of an iron-nickel alloy coated with copper, and the process may be carried out by passing the conductor 1 through a saturated solution of a borate, for instance borax, in a tank 3 heated by the hot plate 4 and then leading it through an electric resistance furnace 7, wherein the water is driven off from the borax and the dried borax is finally fused. To provide a supply of saturated solution, hot water is allowed to drip from the tank 11 into the funnel 9 which is packed with the borate used, and steam is led through the pipo 12, round the jacketed funnel, through the guide 6 and the pipe 14, to the coil 15 in the hot-water tank.

Improvements in or relating to glass to metal seals

... 597,293. Glass. M-O VALVE CO., Ltd., MANNERS, M., and PARTRIDGE, J. H. Aug. 13, 1945, No. 20755. [Class 56] [Also in Group XXXVI] The invention relates to sealing tungsten, molybdenum and like metal rods &c. to glass pinches in the manufacture of thermionic valves. The following are given as examples of alkali-free boro-silicate glasses which may be used for pre-coating the rods &c. : ...

Glass compositions

... 675,594. Glass. BRITISH THOMSON-HOUSTON CO., Ltd., STANWORTH, J. E., and DALE, A. E. Sept. 15, 1950 [Nov. 11, 1949], No. 28962/49. Class 56. A glass composition comprises the following constituents in the respective percentage ranges by weight, P,O, 10-33, B 2 O 3 26-49, Al 2 O 3 15- 38, CaO, MgO, BaO together 15-25 and optionally SiO 2 less than 10, and alkali metal oxides less than 3. The preferred range is P 2 O 5 13- 20, B,O, 35-46, Al 2 O 3 20-29, CaO and/or MgO and/or BaO 15-25, SiO 2 less than 10, and Na 2 O and K 2 O less than 3, and an example contains P 2 O 5 16, B 2 O 3 39, Al 2 O 3 23, CaO 5, MgO 12, and SiO 2 5. The glass is resistant to alkali metal vapour and is used as a coating on boro-silicate glasses, e.g. SiO, 66, Al 2 O 3 2, B 2 O 3 24, alkali 8, to form composite glass envelopes for electric discharge lamps, the glass also being used to coat the exterior of the stem. The composite glass of the example given has a coefficient of expansion of the order of 50Î10-7 ...

Improvements in the manufacture of electric discharge devices

... 455,101. Glass manufacture. GENERAL ELECTRIC CO., Ltd., Magnet House, Kingsway, London.-(Patent - Treuhand Ges. f³r Elektrische Gliihlampen; 11, Ehrenbergstrasse, Berlin) May 28, 1935, No. 15557. [Class 56] [See also Group XL] In a high-pressure discharge lamp, the final closing of the envelope is effected by sealing a body 7, carrying a lead-in wire, into the quartz envelope end. The body 7 has a composition consisting of SiO2, 84À15 per cent; B2O3, 8À92 per cent ; Al2O3, 4À95 per cent ; and MgO, 1À98 percent. This body is given a thin quartz coating to allow ready sealing to the envelopes. Specification 452,854, [Group XI], is referred to.

Improvements in and relating to crystal valves or rectifiers

... 691,708. Point-contact rectifiers. BRITISH THOMSON-HOUSTON CO., Ltd. Feb. 14, 1952 [April 3, 1951], No. 7706/51. Class 37. A germanium or other pointcontact rectifier 5/7 is housed in an all-glass hermetically-sealed container comprising as shown a glass tube 1 fused to soft or low melting- point glass washers or end caps .2 whose projections 3 enter the tube bore. The connecting leads are fused or sealed to the washers 2 and the crystal 5 is mounted on and fused to one of the projections 3.

Improvements in or relating to electric lamps

... 1,102,526. Quartz glass to metal seals. PHILIPS ELECTRONIC & ASSOCIATED INDUSTRIES Ltd. 18 Jan., 1966 [21 Jan., 1965], No. 2310/66. Heading C1M. [Also in Division H2] An electric lamp of quartz glass having a current supply wire of molybdenum in a pinch seal, has the seal protected by an outer coating of silver-enamel with a covering layer of metal such as nickel or chromium. The molybdenum supply wire which may be rolled to thin tape, may be platinum coated. The metal coated pinch may be used as a contact member.

Improvements in electric discharge tubes

... 451,474. Uniting metal to glass by heat. NAAMLOOZE VENNOOTSCHAP PHILIPS' GLOEILAMPENFABRIEKEN, Emmasingel, Eindhoven, Holland. Nov. 14, 1935, No. 31574. Convention date, Feb. 11. [Class 39 (ii)] One or more of the current supply wires 2, 3 of an electric discharge tube is, or are, sealed into the pinch 1 with the interposition of an intermediate layer 4 consisting of a kind of glass different from that of the pinch. The pinch, which is preferably of the normal rectangular type, may consist of lead glass, whereas the intermediate layer consists of calcium glass, and may be provided in the form of a tube which is slipped on to the wire and sealed into the pinch during the sealing-in operation.

Electrical lamp

PROCEDURE FOR WELDING SURFACES OF MATERIALS

SEALS EXECUTION FOR LITHIUM BATTERY, PROCEDURE FOR THEIR PRODUCTION AND THEIR EMPLOYMENT IN A LITHIUM BATTERY AND LITHIUM BATTERY, WITH WHICH SUCH AN EXECUTION IS USED

Crystallizing glass solder and use thereof

The present invention relates to crystallizing glass solders and composites, which are suited in particular for high-temperature applications, and to applications thereof, such as in fuel cells. The crystallizing glass solder contains 25% to 40% by weight of SiO ...

HERMETIC SEALS FOR LITHIUM-ION BATTERIES

Use of a glass composition for making a solar collector with a glass-metal joint

A glass composition for a tubular glass body used to form a glass-metal joint in a tubular solar collector. Includes a borosilicate glass having a dilatometric chart with a hard segment and a soft- segment hysteresis. The soft segment glass transition temperature is less than the hard-segment glass transition temperature for a temperature difference ΔT higher than 20° C. The composition comprises: 5% to 8% Na 2 O, O, 1% to 3% K 2 0, O, 1% to 1.5% CaO, 5% to 7.5% Al 2 0 3 , 70% to 75% Si0 2 , 11.6% to 13.7% B 2 0 3 , Owing and owing to the choice of the B 2 0 3 in the range indicated, in combination with the other components, there is a glass transition temperature lower than other borosilicate glasses. The remarkable difference between the soft and hard segments glass transition temperatures make it possible to obtain a tubular glass body particularly suitable for a solar collector.

Hermetic Sealing of Glass Plates

Durable hermetic seals between two inorganic substrates are produced using a high-intensity electromagnetic energy source, such as laser, to heat and seal enamel layers with controlled absorption of high-intensity energy source. Durable hermetic seals incorporating electrical feedthroughs are also produced. 160-. (canceled)61. A process of hermetically sealing a conductive feed through comprising:a. applying to a first substrate a first enamel trace parallel to the substrate edge.b. applying a second enamel trace which contains a conductor across the first enamel trace such that it contacts the first substrate in the area adjacent both edges of the first enamel.c. applying a third enamel trace parallel to the substrate edge substantially over the first enamel trace, andd. heating the respective enamels.62. A process of sealing two inorganic substrates together using a high-intensity electromagnetic energy source comprising:a. providing first and second inorganic substrates;b. providing an enamel layer having graduated electromagnetic (EM) absorption situated between the first and second substrates such that at least 40% of EM energy incident on the enamel layer is absorbed by a portion of the layer not immediately adjacent to the substrates.63. The process of claim 62 , wherein the enamel layer comprises at least one first sublayer and at least one second sublayer claim 62 , wherein the at least one first sublayer has a higher EM absorbance than the at least one second sublayer claim 62 , wherein the at least one second sublayer is adjacent to a substrate and the at least one first sublayer is not adjacent to a substrate claim 62 , and wherein at least 40% of EM energy incident on the sublayers is absorbed by the at least one first sublayer.64. The process of claim 62 , wherein the at least one second sublayer does not substantially (that is not greater than 20%) absorb EM energy claim 62 , and wherein the absorption of incident EM energy occurs predominantly in the ...

Flexible Glass/Metal Foil Composite Articles and Production Process Thereof

A flexible article made of glass and metal foil, as well as the production thereof, are provided. The flexible article is a multilayered structure having at least one glass layer and one metal foil layer, and the shear strength between glass and metal foil is above 1 MPa/mm. The glass layer of said flexible article has high electrical resistivity at ambient temperature, low roughness, low thickness, good adherence to metal foil, and the glass in the glass layer has high temperature stability and low flowing temperature, and the thermal expansion coefficient (20 to 300° C.) is 1×10/K to 25×10/K. The whole article is flexible and can be bent, and the curvature radius of the bent flexible article is above 1 mm. 1. A flexible article suitable for producing substrates of flexible devices , comprising:{'sup': '10', 'a multilayered structure having a layer of glass and a layer of metal foil, the glass being produced by high temperature melting and cooling in the absence of any precursor, wherein the glass has an electrical resistivity of above 5×10Ω·m at ambient temperature, a surface roughness of below 300 nm, a porosity of below 0.1% on the surface, a thickness of below 350 μm, a flowing temperature of below 1200° C., and a softening temperature of above 350° C., and wherein the metal foil has a thickness below 1 mm; and'}{'sup': '2', 'a shear strength between the glass and the metal foil is above 1 MPa/mm, the multilayered structure being curvable to a curvature radius of above 1 mm.'}2. The flexible article according to claim 1 , wherein the layer of glass comprises one of a top layer or a bottom layer of the multilayered structure claim 1 , and wherein the multilayered structure further comprises another layer of glass that comprises another of the top layer or the bottom layer.3. The flexible article according to claim 2 , wherein the multilayered structure further comprises a layer formed from glass powder or glass slurry between the layer of glass and the layer of ...

BOND PRODUCED WITH AN AT LEAST PARTIALLY CRYSTALLIZED GLASS, SUCH AS A METAL-TO-GLASS BOND, IN PARTICULAR A METAL-TO-GLASS BOND IN A FEED-THROUGH ELEMENT OR CONNECTING ELEMENT, AND METHOD FOR PRODUCING SUCH A BOND, IN PARTICULAR IN A FEED-THROUGH ELEMENT OR CONNECTING ELEMENT

The disclosure relates to a bond produced with an at least partially crystallized glass, such as a metal-to-glass bond, in particular a metal-to-glass bond in a feed-through element or connecting element, and to a method for producing such a bond, in particular in a feed-through element or connecting element. The at least partially crystallized glass includes at least one crystal phase and pores which are distributed in the at least partially crystallized glass in a structured manner. 1. A bond , comprising:at least one joining partner;an at least partially crystallized glass joined with the at least one joining partner; andan interface between the at least partially crystallized glass and the at least one joining partner, the at least partially crystallized glass having a porosity that decreases towards the interface between the at least partially crystallized glass and the at least one joining partner.2. The bond of claim 1 , wherein the at least partially crystallized glass comprises at least one crystal phase and pores which are distributed in the at least partially crystallized glass in a structured manner.3. The bond of claim 1 , wherein said porosity has a gradient claim 1 , and wherein said porosity is less than 10% at a distance of less than 20 μm from the interface of the at least partially crystallized glass.4. The bond of claim 1 , wherein a number of pores is smaller or no pores are existent at the interface between the at least partially crystallized glass and the at least one joining partner claim 1 , wherein the porosity drops to a value of less than 5% at a distance of less than 2 μm in the at least partially crystallized glass from the interface.5. The bond of claim 1 , wherein said porosity has a gradient and increases from at least one of the interface or a surface of the at least partially crystallized glass towards an interior thereof to a maximum value of at least 20%.6. The bond claim 1 , wherein the at least partially crystallized glass has ...

Complex Stress-Engineered Frangible Structures

A stress-engineered frangible structure includes multiple discrete glass members interconnected by inter-structure bonds to form a complex structural shape. Each glass member includes strengthened (i.e., by way of stress-engineering) glass material portions that are configured to transmit propagating fracture forces throughout the glass member. Each inter-structure bond includes a bonding member (e.g., glass-frit or adhesive) connected to weaker (e.g., untreated, unstrengthened, etched, or thinner) glass member region(s) disposed on one or both interconnected glass members that function to reliably transfer propagating fracture forces from one glass member to other glass member. An optional trigger mechanism generates an initial fracture force in a first (most-upstream) glass member, and the resulting propagating fracture forces are transferred by way of inter-structure bonds to all downstream glass members. One-way crack propagation is achieved by providing a weaker member region only on the downstream side of each inter-structure bond. 120-. (canceled)21. A stress-engineered frangible structure , comprising:a plurality of interconnected discrete glass members comprising a first glass member and a second glass member each including at least one strengthened glass portion comprising a stress-engineered glass material, at least the second glass member comprising at least one weakened glass portion; anda bonding member connected between the first and second glass members, the bonding member configured to transmit a fracture force propagating from the first glass member to the second glass member with energy sufficient to cause the at least one weakened glass portion of the second glass member to fracture;wherein fracture of the at least one weakened glass portion of the second glass member changes functionality of the frangible structure.22. The stress-engineered frangible structure of claim 21 , wherein fracture of the at least one weakened glass portion of the ...

ELECTRONIC DEVICE THAT CAN BE WORN ON THE BODY AND METHOD FOR PRODUCING SAME

An electronic device that can be worn on the body or introduced into the body includes: a casing having a top and a bottom and an inorganic support including an opening and composed of a plurality of components; and at least one window made of at least one of glass or glass ceramic provided on the bottom. The window is secured in the inorganic support and seals the opening in the inorganic support. 1. An electronic device that can be worn on the body or introduced into the body , comprising:a casing having a top and a bottom and an inorganic support comprising an opening and composed of a plurality of components; andat least one window made of at least one of glass or glass ceramic provided on the bottom, wherein the window is secured in the inorganic support and seals the opening in the inorganic support.2. The electronic device of claim 1 , wherein the opening with the at least one window is provided in one of the components and at least one further component of the components surrounds the component which has the opening.3. The electronic device of claim 1 , wherein the inorganic support consists of two components comprising an outer component surrounding like a ring an inner component.4. The electronic device of claim 1 , wherein the inorganic support consists of two components comprising an outer metallic component surrounding like a ring an inner component made of ceramic or opaque glass claim 1 , wherein the inner component comprises the opening which is sealed by the at least one window.5. The electronic device of claim 1 , wherein the inorganic support has a multilayer structure claim 1 , wherein at least two components of the plurality of components define layers of the inorganic support.6. The electronic device of claim 1 , wherein the at least one window is fused into the inorganic support.7. The electronic device of claim 6 , wherein the at least one window is implemented as a compression glass seal or is bonded to the inorganic support by a glass ...

Laser welded glass packages and methods of making

An apparatus including a first substrate, a second substrate, an inorganic film provided between the first substrate and the second substrate and in contact with both the first substrate and the second substrate, a laser welded zone formed between the first and second substrate by the inorganic film, where the laser welded zone has a heat affected zone (HAZ), where the HAZ is defined as a region in which σHAZ is at least 1 MPa higher than average stress in the first substrate and the second substrate, wherein σHAZ is compressive stress in the HAZ, and wherein the laser welded zone is characterized by its σinterface laser weld>σHAZ, wherein σinterface laser weld is peak value of compressive stress in the laser welded zone.

SEALED DEVICES AND METHODS FOR MAKING THE SAME

Disclosed herein are sealed devices comprising at least one cavity containing at least one quantum dot or at least one laser diode are also disclosed herein. The sealed devices can comprise a glass substrate sealed to an inorganic substrate, optionally via a sealing layer, the seal extending around the at least one cavity. Display and optical devices comprising such sealed devices are also disclosed herein, as well as methods for making such sealed devices. 155-. (canceled)56. A sealed device comprising:a glass substrate comprising a first surface;an inorganic substrate comprising a second surface;a sealing layer in contact with at least a portion of the first surface and at least a portion of the second surface;at least one seal bonding the glass substrate to the inorganic substrate via the sealing layer;wherein the inorganic substrate has a thermal conductivity of greater than about 2.5 W/m-K,wherein at least one of the first or second surfaces comprises at least one cavity containing at least one quantum dot and at least one LED component or wherein at least one of the first or second surfaces comprises at least one cavity containing at least one laser diode, andwherein the at least one seal extends around the at least one cavity.57. The sealed device of claim 56 , wherein the glass substrate comprises a glass chosen from aluminosilicate claim 56 , alkali-aluminosilicate claim 56 , borosilicate claim 56 , alkali-borosilicate claim 56 , aluminoborosilicate claim 56 , and alkali-aluminoborosilicate glasses.58. The sealed device of claim 56 , wherein the inorganic substrate comprises aluminum nitride claim 56 , aluminum oxide claim 56 , beryllium oxide claim 56 , boron nitride claim 56 , or silicon carbide.59. The sealed device of claim 56 , wherein the sealing layer comprises a glass chosen from tin fluorophosphate glasses claim 56 , tungsten-doped tin fluorophosphate glasses claim 56 , chalcogenide glasses claim 56 , tellurite glasses claim 56 , borate glasses ...

JOINS HAVING AT LEAST PARTIALLY CRYSTALLIZED GLASS

A join is provided that has an electrically insulating component and two joining partners secured to one another and electrically insulated from one another by the electrically insulating component. The electrically insulating component has a surface that extends between the two joining partners. The surface defines a structure selected from a group consisting of an elevation, a depression, and any combinations thereof. The structure elongates a direct path along the surface. The structure completely surrounds at least one of the two joining partners. The electrically insulating component and/or the structure includes a glass that is at least partially crystallized. 1. A join comprising:an electrically insulating component; andtwo joining partners secured to one another and electrically insulated from one another by the electrically insulating component,the electrically insulating component comprises a surface that extends between the two joining partners, the surface defining a structure selected from a group consisting of an elevation, a depression, and any combinations thereofwherein the structure elongates a direct path along the surface,wherein the structure completely surrounds at least one of the two joining partners, andwherein the electrically insulating component and/or the structure comprises a glass that is at least partially crystallized.2. The join of claim 1 , wherein the insulating component is bonded or glass-fused to each of the two joining partners.3. The join of claim 1 , wherein the structure is integral with the insulating component and is made of the glass.4. The join of claim 3 , wherein the electrically insulating component further comprises a predominantly amorphous glass layer between the electrically insulating component and the two joining partners claim 3 , wherein the predominantly amorphous glass layer comprises a property selected from a group consisting of less than 10 pores per cm claim 3 , a thickness of 5 μm or less claim 3 , a ...

RARE EARTH SILICATE COATINGS SOLVOTHERMALLY GROWN OVER HIGH TEMPERATURE CERAMIC COMPONENTS

Methods are provided for forming high temperature coating over ceramic components, such as ceramic turbomachine components. In various embodiments, the method includes the step or process of at least partially filling a reactor vessel with a reaction solution containing a solution-borne rare earth cation source. A silicon-containing surface region of a ceramic component is submerged in the reaction solution, and a solvothermal growth process is carried-out. During the solvothermal growth process, the reaction solution is subject to elevated temperature and pressure conditions within the reactor vessel in the presence of a silicate anion source, which reacts with the solution-borne rare earth cation source to grow a rare earth silicate layer over the silicon-containing surface region of the ceramic component. 1. A method for producing a high temperature coating over a ceramic component , the method comprising:at least partially filling a reactor vessel with a reaction solution containing a solution-borne rare earth cation source;submerging a silicon-containing surface region of a ceramic component in the reaction solution; andcarrying-out a solvothermal growth process during which the reaction solution is subject to elevated temperature and pressure conditions within the reactor vessel in the presence of a silicate anion source, which reacts with the solution-borne rare earth cation source to grow at least one rare earth silicate layer over the silicon-containing surface region of the ceramic component.2. The method of wherein the silicon-containing surface region comprises a native surface oxide; andwherein the method further comprises utilizing the native surface oxide as the silicate anion source during the solvothermal growth process.3. The method of further comprising:approximating an amount of native surface oxide present on the silicon-containing surface region; andselecting an amount of the solution-borne rare earth cation source within the reaction solution ...

Complex Stress-Engineered Frangible Structures

A stress-engineered frangible structure includes multiple discrete glass members interconnected by inter-structure bonds to form a complex structural shape. Each glass member includes strengthened (i.e., by way of stress-engineering) glass material portions that are configured to transmit propagating fracture forces throughout the glass member. Each inter-structure bond includes a bonding member (e.g., glass-frit or adhesive) connected to weaker (e.g., untreated, unstrengthened, etched, or thinner) glass member region(s) disposed on one or both interconnected glass members that function to reliably transfer propagating fracture forces from one glass member to other glass member. An optional trigger mechanism generates an initial fracture force in a first (most-upstream) glass member, and the resulting propagating fracture forces are transferred by way of inter-structure bonds to all downstream glass members. One-way crack propagation is achieved by providing a weaker member region only on the downstream side of each inter-structure bond.

Complex Stress-Engineered Frangible Structures

A stress-engineered frangible structure includes multiple discrete glass members interconnected by inter-structure bonds to form a complex structural shape. Each glass member includes strengthened (i.e., by way of stress-engineering) glass material portions that are configured to transmit propagating fracture forces throughout the glass member. Each inter-structure bond includes a bonding member (e.g., glass-frit or adhesive) connected to weaker (e.g., untreated, unstrengthened, etched, or thinner) glass member region(s) disposed on one or both interconnected glass members that function to reliably transfer propagating fracture forces from one glass member to other glass member. An optional trigger mechanism generates an initial fracture force in a first (most-upstream) glass member, and the resulting propagating fracture forces are transferred by way of inter-structure bonds to all downstream glass members. One-way crack propagation is achieved by providing a weaker member region only on the downstream side of each inter-structure bond.

LASER WELDED GLASS PACKAGES AND METHODS OF MAKING

A method of forming a sealed device comprising providing a first substrate having a first surface, providing a second substrate adjacent the first substrate, and forming a weld between an interface of the first substrate and the adjacent second substrate, wherein the weld is characterized by ((σ)/(σ))<<1 or <1 and σ>10 MPa or >1 MPa where σis the stress present in the first substrate and σis the stress present at the interface. This method may be used to manufacture a variety of different sealed packages. 134-. (canceled)37. The apparatus of or further comprising:an inorganic film formed over the first surface of the first substrate; anda device protected between the first substrate and the second substrate wherein the inorganic film is in contact with the second substrate.38. The apparatus of claim 37 , wherein each of the inorganic film claim 37 , first substrate and second substrate are transmissive at approximately 420 nm to approximately 750 nm.39. The apparatus of claim 37 , wherein absorption of the inorganic film is more than 10% at a predetermined laser wavelength.40. The apparatus of claim 37 , wherein the composition of the inorganic film is selected from the group consisting of SnO claim 37 , ZnO claim 37 , TiO claim 37 , ITO claim 37 , Zn claim 37 , Ti claim 37 , Ce claim 37 , Pb claim 37 , Fe claim 37 , Va claim 37 , Cr claim 37 , Mn claim 37 , Mg claim 37 , Ge claim 37 , SnF claim 37 , ZnFand combinations thereof.41. The apparatus of claim 37 , wherein the composition of the inorganic film is selected to lower the activation energy for inducing creep flow of the first substrate claim 37 , the second substrate claim 37 , or both the first and second substrates.42. The apparatus of claim 37 , wherein the composition of the inorganic film is a laser absorbing low liquidus temperature material with a liquidus temperature less than or equal to about 1000° C.43. The apparatus of claim 37 , wherein the composition of the inorganic film comprises:20-100 mol % ...

Glass composition for micro-d connector sealing

Lastly, it relates to a process for forming a glass-to-metal seal between a contact made of copper or of copper alloy and an insert and/or shell made of metal or alloy having a coefficient of thermal expansion higher than 16 ppm/° C.

METHODS OF FORMING STRENGTHENED SINTERED GLASS STRUCTURES

A strengthened layered glass structure includes a first substrate layer comprising a flexible glass sheet having a thickness of less than or equal to 300 μm, a second substrate layer, and a sintered glass frit material layer coupled to a first surface of the first substrate layer and a second surface of the second substrate layer, the sintered glass frit material layer comprising a sintered glass frit coupled to the first and second surfaces providing the flexible glass sheet with a compressive stress of at least about 100 MPa across a thickness of the flexible glass sheet. 1. A strengthened layered glass structure comprising:a first substrate layer comprising a flexible glass sheet having a thickness of ≦300 μm;a second substrate layer; anda sintered glass frit material layer coupled to a first surface of the first substrate layer and a second surface of the second substrate layer, the sintered glass frit material layer comprising a sintered glass frit coupled to the first and second surfaces providing the flexible glass sheet with a compressive stress of at least about 100 MPa across a thickness of the flexible glass sheet.2. The strengthened layered glass structure of claim 1 , wherein the flexible glass sheet has a thickness of ≦200 μm.3. The strengthened layered glass structure of claim 1 , wherein flexible glass sheet has a thickness of ≦100 μm.4. The strengthened layered glass structure of claim 1 , wherein the second substrate layer comprises metal claim 1 , glass claim 1 , or a metal alloy.5. The strengthened layered glass structure of claim 1 , wherein a thickness of the sintered glass frit material layer is from 25 μm to 125 μm.6. The strengthened layered glass structure of claim 1 , wherein the flexible glass sheet is a chemically strengthened glass sheet.7. The strengthened layered glass structure of claim 1 , wherein a total thickness of strengthened layered glass structure is ≦300 μm.8. The strengthened layered glass structure of comprising multiple ...

Flexible Glass/Metal Foil Composite Articles and Production Process Thereof

A flexible article made of glass and metal foil, as well as the production thereof, are provided. The flexible article is a multilayered structure having at least one glass layer and one metal foil layer, and the shear strength between glass and metal foil is above 1 MPa/mm 2 . The glass layer of said flexible article has high electrical resistivity at ambient temperature, low roughness, low thickness, good adherence to metal foil, and the glass in the glass layer has high temperature stability and low flowing temperature, and the thermal expansion coefficient (20 to 300° C.) is 1×10 −6 /K to 25×10 −6 /K. The whole article is flexible and can be bent, and the curvature radius of the bent flexible article is above 1 mm.

Crystallizing glass solder and use thereof

본 발명은 특히 고온 용도에 적합한 결정성 유리 솔더 및 복합체, 및 이의, 연료 전지에서와 같은 용도에 관한 것이다. 상기 결정성 유리 솔더는 SiO 2 25∼40 중량%, BaO 45∼60 중량%, B 2 O 3 5∼15 중량%, Al 2 O 3 0 ∼ < 2 중량%, 및 MgO, CaO 및 SrO으로 구성된 군으로부터 선택된 1 이상의 알칼리 토류 산화물을 함유하며, 여기서 CaO는 0∼5 중량%이며, 20∼300℃의 온도 범위에서 8.0·10 -6 K -1 ∼ 13.0·10 -6 K -1 의 열팽창 계수를 특징으로 한다. The present invention relates to crystalline glass solder and composites particularly suitable for high temperature applications, and applications thereof such as in fuel cells. Wherein the crystalline glass solder comprises 25 to 40 wt% of SiO 2 , 45 to 60 wt% of BaO, 5 to 15 wt% of B 2 O 3 , 0 to 2 wt% of Al 2 O 3 , and MgO, CaO and SrO Wherein the CaO is 0 to 5% by weight and has a coefficient of thermal expansion of 8.0 · 10 -6 K -1 to 13.0 · 10 -6 K -1 in the temperature range of 20 to 300 ° C. .

Crystallized glass solder and use thereof

Sealing material and sealing paste

Crystallizing glass solder and use thereof

本发明涉及结晶化玻璃焊料和复合物，其特别适合用于高温应用，本发明还涉及其应用，例如在燃料电池中的应用。所述结晶化玻璃焊料包含25wt％至40wt％的SiO 2 、45wt％至60wt％的BaO、5wt％至15wt％的B 2 O 3 、0至＜2％的Al 2 O 3 和至少一种选自MgO、CaO和SrO的碱土金属氧化物，其中CaO是0wt％至5wt％，且其特征在于在20℃至300℃的温度范围内的热膨胀系数为8.0·10 -6 K -1 至13.0·10 -6 K -1 。

High-temperature sealing glass and preparation method and application thereof

本发明涉及一种高温封接玻璃及其制备方法和应用，该方法包括以下步骤：按设定高温封接玻璃的各组分含量取相应的原料并混合均匀，得到配合料；以氧化物为基准的重量百分比计，所述原料包括：SiO 2 40％‑70％，B 2 O 3 5％‑15％，ZnO5％‑20％，BaO1％‑20％，Al 2 O 3 1％～10％，Na 2 O3％～15％，K 2 O3％～15％，Sb 2 O 3 0.5％～2％；将得到的配合料、5wt％以下的粘结剂、30wt％以下的溶剂通过高速搅拌制成粘度为2000‑4000Pa·s的浆料；将得到的浆料通过丝网印刷涂敷在第一基体的表面，之后将其放入加热炉中，加热至260‑400℃，保温1‑2h，得到厚度为100‑500μm的预制膜层；将第一基体与第二基体紧密贴合；之后用激光对预制膜层进行加热熔融处理，得到所述高温封接玻璃。本发明大大缩短了高温封接玻璃的工艺过程环节，提高了生产效率，操作简单。

VACUUM INSULATING GLASS PACKAGE, SEALING AND METHOD FOR PRODUCING A VACUUM INSULATING GLASS PACKAGE

1. Вакуумный изолирующий стеклопакет, содержащийпервую и вторую подложки, которые пакетированы с оставлением зазора, причем зазор приведен в состояние с давлением менее чем атмосферное давление; иуплотнение, герметизирующее зазор,при этом уплотнение заключает в себе металлический элемент и стеклянный слой, который связывает металлический элемент и стеклянные подложки;при этом материал в качестве металлического элемента выбирают из материалов, чьи прочность при растяжении X (Н/мм) и относительное удлинение при разрыве Y (%) удовлетворяют соотношению Y≥0,10X по испытанию на растяжение при комнатной температуре, скорость растяжения: 1 мм/мин, которое осуществляют после того, как материалы выдерживают при 490˚C в течение 40 мин в атмосфере.2. Вакуумный изолирующий стеклопакет по п. 1, в котором металлический элемент имеет толщину между 0,03 и 0,5 мм.3. Вакуумный изолирующий стеклопакет по п. 1 или 2, в котором материал для металлического элемента выбирают из материалов, чьи прочность при растяжении X (Н/мм) и относительное удлинение при разрыве Y (%) не удовлетворяют соотношению Y≥0,10X по испытанию на растяжение при комнатной температуре, скорость растяжения: 1 мм/мин, которое осуществляют после того, как материалы выдерживают при 490˚C в течение 40 мин в атмосфере.4. Вакуумный изолирующий стеклопакет по п. 1 или 2, вкотором металлический элемент заключает в себе, по меньшей мере, один элемент, выбранный из группы, состоящей из чистого алюминия, алюминиевого сплава, чистого титана, а также титанового сплава.5. Вакуумный изолирующий стеклопакет по п. 1 или 2, в котором стеклянный слой заключает в себе стеклянный элемент, чей термический коэффициент расширения при температуре между 50 и 250˚C больше РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C03C 27/06 (13) 2014 145 553 A (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2014145553, 12.04.2013 (71) Заявитель(и): АСАХИ ГЛАСС КОМПАНИ, ЛИМИТЕД (JP) Приоритет(ы): (30) ...

NEW GLASS COMPOSITIONS AND PROCEDURE TO MAKE A GLASS-METAL UNION.

Nuevas composiciones de vidrio y procedimiento para realizar una unión vidrio-metal, donde el nuevo vidrio comprende: New glass and process compositions to make a glass-metal joint, where the new glass comprises: \vskip1.000000\baselineskip \ vskip1.000000 \ baselineskip Óxido Oxide (%) (%) B_{2}O_{3} B 2 O 3 8-13.5 8-13.5 Al_{2}O_{3} Al_ {2} O_ {3} 5-9 5-9 Na_{2}O Na 2 O 3-9 3-9 K_{2}O K_ {O} 0-5 0-5 CaO CaO 2-4 2-4 MgO MgO 0-4 0-4 ZnO ZnO 0-4 0-4 SiO_{2} SiO_ {2} Hasta 100 Until 100 \vskip1.000000\baselineskip \ vskip1.000000 \ baselineskip en función de los requerimientos necesarios, destacando por su importancia el coeficiente de dilatación térmica, de manera que este coeficiente de dilatación térmica es ajustado para que coincida con el de la parte metálica o aleación con la que se quiere llevar a cabo la soldadura vidrio-metal, lo que permite poder llevar a cabo de manera satisfactoria dicha soldadura obteniéndose una unión vidrio-metal fuerte, libre de tensiones y duradera en el tiempo que pueda ser empleada entre otras para la obtención de partes que forman parte de colectores solares. depending on the necessary requirements, Noting for its importance the coefficient of thermal expansion, so that this coefficient of thermal expansion is adjusted to match that of the metal or alloy part with which you want to carry out glass-metal welding, which allows to satisfactorily carry out said welding obtaining a glass-metal joint strong, stress free and durable as long as it can be used among others to obtain parts that are part of solar collectors

Machine arrangement

本发明涉及一种机械装置(1)，其包括或者是至少一个轴承环，其中玻璃纤维(2)与所述机械装置(1)连接。为了允许甚至在所述机械装置的弯曲表面上的应力的正确测量，因为这在轴承环的情况中是典型的，本发明提出，所述玻璃纤维(2)与所述机械装置(1)之间的连接通过玻璃材抓3)建立，其中所述玻璃材抓3)与所述机械装置(1)以及所述玻璃纤维(2)通过材料接合连接。

Method for performing a frit firing cycle in the manufacture of vacuum solar panels

Lead-free glass material for use in sealing and, sealed article and method for sealing using the same

본 발명은, 20∼35중량%의 B 2 O 3 와 10∼35중량%의 ZnO와 40∼60중량%의 BaO로 이루어지는 유리조성을 구성하는 산화물의 합량 100중량%에 대하여, TeO 2 및 Bi 2 O 3 가 어느 한쪽의 단독 사용 또는 양쪽의 병용으로 50∼500중량부 배합되어 이루어지는 유리조성을 갖는 봉착가공용 무연 유리재에 관한 것이다. 본 발명은, 봉착가공용 유리재로서, 무연계이고, 낮은 가공온도, 넓은 온도범위에서 봉착가공을 행할 수 있고, 저열팽창율이고, 접착성, 밀봉가공성, 밀착성, 화학적 안정성, 강도 등이 우수하고, 납계 유리에 대체할 수 있는 충분한 실용적 성능을 갖는다. The present invention relates to TeO 2 and Bi 2 based on 100% by weight of the oxide constituting the glass composition consisting of 20 to 35% by weight of B 2 O 3 , 10 to 35% by weight of ZnO and 40 to 60% by weight of BaO. It relates to a lead-free glass material for sealing processing having a glass composition in which O 3 is blended in an amount of 50 to 500 parts by weight either alone or in combination. The present invention is a glass material for sealing processing, is lead-free, can be sealed at a low processing temperature, a wide temperature range, has a low thermal expansion rate, excellent adhesion, sealing workability, adhesion, chemical stability, strength, etc., It has sufficient practical performance to replace lead-based glass. 망목형성 산화물, 유리조성, 봉착가공, 무연 유리재 Mesh forming oxide, glass composition, sealing processing, lead-free glass

Precess for producting vacuum glass panel and vacuum glass panet produced thereby

상부 판유리과 하부 판유리를 마련하고, 상기 하부 판유리의 가장자리를 따라 씰런트를 도포하여 씰링재를 형성한 후 상기 하부 판유리 상부에 상부 판유리를 배치하여 상기 상부 및 하부 판유리를 대향 합착하여 진공유리 패널을 제조하는 단계; 상기 진공유리 패널을 가열하여 상부 또는 하부 판유리에 형성되는 배기부로 상부 및 하부 판유리 사이의 공기를 배기하는 단계; 및 상기 진공유리 패널을 가열하여 상기 배기부를 밀봉하는 단계;를 포함하는 진공유리 패널 제조방법을 제공한다. 또한, 상기 진공유리 패널 제조방법에 의해 제조된 진공유리 패널을 제공한다. And a sealing glass is formed on the edge of the lower plate glass to form a sealing material and then an upper plate glass is disposed on the upper plate glass so that the upper and lower plate glasses are coupled to each other to produce a vacuum glass panel step; Heating the vacuum glass panel to exhaust air between the upper and lower plate glasses by an exhaust unit formed on the upper or lower plate glass; And sealing the exhaust part by heating the vacuum glass panel. Also, a vacuum glass panel manufactured by the vacuum glass panel manufacturing method is provided.

Double-pane glass, and manufacturing method for double-pane glass

复层玻璃，其为在相互相向的第1玻璃基板的第1表面和第2玻璃基板的第2表面之间具备间隙部的复层玻璃，其特征在于，上述间隙部由密封构件密闭，上述密封构件包含具有第3表面和第4表面的画框状的金属构件、第1接合层以及第2接合层，上述第1接合层以画框状配置在上述第1玻璃基板的第1表面，上述第2接合层以画框状配置在上述第2玻璃基板的第2表面，从该复层玻璃的厚度方向观察时，与上述第1接合层的位置错开，上述第1接合层与上述金属构件的第3表面的一部分结合，上述第2接合层与上述金属构件的第4表面的一部分结合。

Glass and articles made from it

Method for the permanent connection of two components by means of glass or metal solder

Method for manufacturing laminated glass plates

Electric lamp

MATERIALS FOR VITREOUS OR VITROCERAMIC JOINTS WITHOUT BARYUM OR STRONTIUM, JOINT CONNECTIONS COMPRISING SUCH MATERIALS, AND USE THEREOF

L'invention concerne un matériau de joint vitreux ou vitrocéramique qui présente un coefficient de dilatation thermique alpha d'au moins 7.10 K , qui ne contient ni oxyde de baryum ni oxyde de strontium, si ce n'est au plus au titre d'impuretés, et qui est approprié pour la production de liaisons par joints, en particulier entre des pièces en alliages à base de chrome ou en aciers au chrome. L'invention concerne aussi des liaisons par joints comprenant de tels matériaux de joints, ainsi que l'utilisation de ces matériaux.

LITHIUM BATTERY-BASED DRYWAY, ITS MANUFACTURING METHOD AND ITS USE IN A LITHIUM BATTERY, AND LITHIUM BATTERY USING SUCH A TRAVERSEE

Electrically conductive welding glass

GLASS COMPOSITION FOR SEALING MICRO-D CONNECTOR

La présente invention concerne une composition de verre à base d'oxyde de tellure pour le scellement verre-métal d'alliage ou de métaux ayant un coefficient de dilatation thermique supérieur à 16ppm/°C, ladite composition comprenant du TeO2, du ZnO, un oxyde choisi parmi TiO2, K2O et leurs mélanges et éventuellement du CsCl et étant essentiellement exempte d'oxyde de plomb, d'oxyde de sodium et d'oxyde de vanadium. Elle concerne de plus l'utilisation de la composition de verre selon l'invention pour le scellement verre-métal du cuivre ou d'un alliage de cuivre avec un alliage ou un métal ayant un coefficient de dilatation thermique supérieur à 16ppm/°C. Elle concerne en outre un connecteur comprenant un contact en cuivre ou en alliage de cuivre, un insert et/ou boîtier en métal ou alliage ayant un coefficient de dilatation thermique supérieur à 16ppm/°C et en tant que matériau de scellement verre-métal entre le contact et l'insert et/ou boîtier un verre à base d'oxyde de tellure ayant la composition selon l'invention. Enfin elle concerne un procédé de scellement verre-métal d'un contact en cuivre ou en alliage de cuivre dans un insert et/ou boîtier en métal ou alliage ayant un coefficient de dilatation thermique supérieur à 16ppm/°C. The present invention relates to a glass composition based on tellurium oxide for the glass-to-metal sealing of alloy or metals having a coefficient of thermal expansion greater than 16 ppm / ° C., said composition comprising TeO2, ZnO, a oxide chosen from TiO2, K2O and their mixtures and optionally CsCl and being essentially free of lead oxide, sodium oxide and vanadium oxide. It further relates to the use of the glass composition according to the invention for the glass-metal sealing of copper or a copper alloy with an alloy or a metal having a coefficient of thermal expansion greater than 16 ppm / ° C. It further relates to a connector comprising a contact made of copper or a copper ...

MATERIALS FOR VITREOUS OR VITROCERAMIC GASKETS WITHOUT BARIUM OR STRONTIUM, JOINTS BY GASKETS COMPRISING SUCH MATERIALS, AND THEIR USE

L'invention concerne un matériau de joint vitreux ou vitrocéramique qui présente un coefficient de dilatation thermique alpha d'au moins 7.10 K , qui ne contient ni oxyde de baryum ni oxyde de strontium, si ce n'est au plus au titre d'impuretés, et qui est approprié pour la production de liaisons par joints, en particulier entre des pièces en alliages à base de chrome ou en aciers au chrome. L'invention concerne aussi des liaisons par joints comprenant de tels matériaux de joints, ainsi que l'utilisation de ces matériaux. The invention relates to a vitreous or glass-ceramic gasket material which has a coefficient of thermal expansion alpha of at least 7.10 K , which does not contain barium oxide or strontium oxide, except at most as impurities , and which is suitable for the production of joints by joints, in particular between parts made of chromium-based alloys or chromium steels. The invention also relates to connections by joints comprising such joint materials, as well as the use of these materials.

Glass-plating metal articles

Articles are receivers, bars, tubes, joints etc. The process comprises (a) application of a base coating to each surface (b) assembly of one or pair of tube(s) of glass having softening point is not > that of base coating, juxtaposed to the base coatings(s) but with a cavity between tube and coating (c) heating the assembly to soften the tubes to extract air and other gases, to force the tube(s) to contact the coating(s) and bind. Spec. base coating is a kaolin/NaNO3 mixture.

Patent FR2189339A1

At least partially crystallized glass, a compound produced with this glass, for example a metal-glass compound, in particular a metal-glass compound in a feedthrough element and a method for producing such a compound, in particular in a feedthrough element

Die Erfindung betrifft ein zumindest teilweise kristallisiertes Glas, welches zumindest eine Kristallphase sowie Poren umfasst. Die Poren sind in dem zumindest teilweise kristallisierten Glas strukturiert verteilt angeordnet. Weiterhin betrifft die Erfindung ein Verfahren zur Herstellung eines solchen Glases sowie ein Durchführungs- und Verbindungselement, welches ein solches zumindest teilweise kristallisiertes Glas umfasst. The invention relates to an at least partially crystallized glass which comprises at least one crystal phase and pores. The pores are arranged in a structured manner distributed in the at least partially crystallized glass. Furthermore, the invention relates to a method for producing such a glass and a feedthrough and connecting element, which comprises such an at least partially crystallized glass.

Patent FR2141256A6

High strength insulating joints for solid oxide fuel cells and other high temperature applications and method of making

A seal formed between two parts that will remain gas tight in high temperature operating environments which experience frequent thermal cycling, which is particularly useful as an insulating joint in solid oxide fuel cells. A first metal part is attached to a reinforcing material. A glass forming material in the positioned in between the first metal part and the second part, and a seal is formed between the first metal part and the second part by heating the glass to a temperature suitable to melt the glass forming materials. The glass encapsulates and bonds at least a portion of the reinforcing material, thereby adding tremendous strength to the overall seal. A ceramic material may be added to the glass forming materials, to assist in forming an insulating barrier between the first metal part and the second part and to regulating the viscosity of the glass during the heating step.

Glass-to-metal seal

Soft glass, its manufacturing process and its applications

Solder chip, method for manufacturing glass substrate with terminal using solder chip

Rare earth silicate coatings solvothermally grown over high temperature ceramic components

Methods are provided for forming high temperature coating over ceramic components, such as ceramic turbomachine components. In various embodiments, the method includes the step or process of at least partially filling a reactor vessel with a reaction solution containing a solution-borne rare earth cation source. A silicon-containing surface region of a ceramic component is submerged in the reaction solution, and a solvothermal growth process is carried-out. During the solvothermal growth process, the reaction solution is subject to elevated temperature and pressure conditions within the reactor vessel in the presence of a silicate anion source, which reacts with the solution-borne rare earth cation source to grow a rare earth silicate layer over the silicon-containing surface region of the ceramic component.

Patent FR2075440A5

Glass bonding method

A structure for packaging semiconductor integrated circuits including a ceramic housing consisting of a base and cap having opposed mating surfaces for subsequent mating during a cap-to-base sealing operation that encapsulates an integrated circuit within the ceramic housing. Each of the base and cap mating surfaces having at least one thin sintered layer consisting of at least two sealing glass paste compositions sequentially printed onto each of the opposed mating surfaces before being sintered. The sealing glass paste compositions containing a mixture of glass powder and a liquid vehicle. A first of the compositions is characterized by having a glass-to-vehicle ratio range of 9:1 to 15:1 which is facilitated by having a liquid vehicle containing a mixture consisting of 93 wt % isotridecyl alcohol, 5 wt % diacetone acetate and 2 wt % acrylic resin and a glass powder selected from the group of LS0113, LS2001B, XS1175M, and T187 industry type glass powders. A second of the compositions being characterized by having a glass-to-vehicle ratio range of 8:1 to 12:1, which is facilitated by having a liquid vehicle containing a mixture consisting of 93 wt % isotridecyl alcohol, 0 to 5 wt % acrylic resin with diacetone acetate being the remainder and a glass powder selected from the group of LS0113, LS2001B, XS1175M, and T187 industry type glass powders.

Bonding an Insulator to an Insulator

1,179,535. Ceramic seals. P. R. MALLORY & CO. Inc. 3 May, 1968 [3 May, 1967 (2)], No. 21098/68. Heading B3V. [Also in Division C1] To bond insulating inorganic material to insulating inorganic material, the materials placed in close contact are heated to below their softening points to increase their electrical conductivity and an electric potential is then applied across the materials to produce an electrostatic force causing the materials to be attracted into intimate contact. Glasses, quartz, ceramics are joined to themselves or each other by this method and they may also be joined to metals by first forming a layer of the inorganic material on the metal substrate.

Lead-free glass material for use in sealing and, sealed article and method for sealing using the same

Provided with a glass composition including a network-former oxide composed of any one of or both of B 2 O 3 and V 2 O 5 of 20-80% by weight, ZnO of 0-60% by weight and BaO of 0-80% by weight, wherein at least one of ZnO and BaO is included as an essential ingredient. The present invention is a glass material for use in sealing, which is of lead-free series, can be used for sealing at a low processing temperature and within a wide temperature range, has a low thermal expansion coefficient, superior adhesion, superior sealing processability, superior adherence, superior chemical stability, superior strength and the like and comprises sufficient practical performance to substitute for lead glass.

Methods and apparatus for the manufacture of silica glass

STRAIN GAUGE

Novel glass compositions and method for producing a glass/metal join

Novel glass compositions and method for producing a glass/metal join, in which the novel glass comprises: depending on the necessary requirements, owing to the significance thereof the thermal expansion coefficient, such that this thermal expansion coefficient is adjusted to match that of the metal part or alloy with which the glass/metal weld is to be achieved, which makes it possible to satisfactorily produce said weld which results in a strong glass/metal join, that is free from tensile stresses and that is durable over time and may be used, inter alia, to obtain parts that form part of solar collectors.

Barium- and strontium-free vitreous or glass-ceramic jointing material and its use

本发明涉及一种不含钡和锶的玻璃质或玻璃陶瓷接合材料及其用途。具体而言，本发明涉及热膨胀系数α (20-750) ≥7×10 -6 K -1 的玻璃质或玻璃陶瓷接合材料，所述接合材料除了最多由于杂质之外不含BaO和SrO，并且适合产生含铬合金或含铬钢之间的节点连接。

Sight glass and low temperature method of manufacturing the same

An improved lower cost sight glass and a method for producing the same is disclosed, whereby the sight glass is made by placing a transparent component in secure contact with a metallic ring. The contact may optionally be effectuated by temporarily altering the relative dimensions of the metallic ring and the transparent component, placing the transparent component into the inner space of the metallic ring, and then reversing the altered relative dimensions of the metallic ring and the transparent component. A hermetic seal is formed between the transparent component and the metallic ring is by the application of an inorganic sealing compound.

Glass for metal seal

A composite metallic article for effecting a seal with glass, said article comprising a nickel-iron alloy core portion, a low carbon steel alloy sheath portion bonded to the core, and a uniformly thick shell portion of a glass-wetting material bonded about the sheath. A method for making the article is also disclosed.

Improvements in or relating to multiple glass-to-metal seals for electron discharge devices

696,987. Glass-to-metal seals. SHEPHERD, G. R. (Westinghouse Electric International Co.). Oct. 5, 1951, No. 23231/51. Class 36. A multi-seal envelope 11 for an electron discharge device is made by preparing a plurality of annular metal discs 13 for the application of vitreous material thereto, assembling a plurality of hollow vitreous envelope sections 12 alternately with the discs 13, vitreous material 15, having a lower softening temperature than the sections 12 and a coefficient of expansion matching that of the discs 13, being placed therebetween, then heating the assembly to soften the vitreous material 15 but not the sections 12, cooling to cause the vitreous material to seal the parts together simultaneously, and finally annealing the completed envelope. The members 13 may be prepared by pre-oxidization, sand-blasting or etching, and may be enamelled by firing on a layer 14 of powder glass, after which the welding glass 15 is applied and the coated discs assembled for sealing with the sections 12. The welding glass may be applied directly to the metal discs, and may be fired to form an enamel coating before the sealing process.

Glass-to-metal seal and process for its manufacture

Display device and method of fabricating the same

A display device includes a display panel including a display area and a non-display area surrounding the display area, and a metal wiring layer disposed on at least a portion of the non-display area, an encapsulation substrate disposed on the display panel, a sealing member which is disposed between the display panel and the encapsulation substrate and bonds the display panel to the encapsulation substrate and a first fusion region provided in at least a partial region between the sealing member and the encapsulation substrate, where the first fusion region has no physical boundary, and where at least a portion of the sealing member is disposed on the metal wiring layer in the non-display area, and the first fusion region is separated from the metal wiring layer while overlapping the metal wiring layer in a thickness direction.

Sealed devices and methods for making the same

Disclosed herein are sealed devices comprising at least one cavity containing at least one quantum dot or at least one laser diode are also disclosed herein. The sealed devices can comprise a glass substrate sealed to an inorganic substrate, optionally via a sealing layer, the seal extending around the at least one cavity. Display and optical devices comprising such sealed devices are also disclosed herein, as well as methods for making such sealed devices.

Barium- and strontium-free glassy or glass-ceramic joining material and its use

Glasiges oder glaskeramisches Fügematerial mit einem thermischen Ausdehnungskoeffizienten α(20-750) ≥ 7·10–6 K–1, das bis auf höchstens Verunreinigungen frei ist von BaO und SrO und zum Herstellen von Fügeverbindungen mit chromhaltigen Legierungen oder chromhaltigen Stählen geeignet ist. Glassy or glass-ceramic joining material with a coefficient of thermal expansion α (20-750) ≥ 7 · 10-6 K-1, which is free of impurities of BaO and SrO except for at most impurities and is suitable for producing joints with chromium-containing alloys or chromium-containing steels.

Barium - and strontium-free vitreous or glass-ceramic jointing material and its use

Hermetic seal and method

An annular metal flange portion of a member is concentrically arranged with respect to a glass cylindrical member and is reliably sealed to a side wall surface of the glass member by a hermetic sealing glass formed within an accumulation cavity between the metal and glass member. A compressive member is provided within the cavity for applying a compressive force during assembly against glass sealant material, and sealing glass formed therefrom, disposed within the cavity. A compressive force is applied to the compressive member during a heating operation of the sealing method for removal of liquid carriers of the glass sealant material and for hermetically sealing glass particles of that material. Compensation for shrinkage of the glass sealant material, and the sealing glass formed therefrom, during that heating operation is thereby provided. Also, the formation of bubbles and voids within the glass sealant material, and the sealing glass formed therefrom, is substantially avoided.

Patent JPS4952208A

SEALING GLASS COMPOSITION

Lead-free glass material for use in sealing and, sealed article and method for sealing using the same

Provided with a glass composition including a network-former oxide composed of any one of or both of B 2 O 3 and V 2 O 5 of 20-80% by weight, ZnO of 0-60% by weight and BaO of 0-80% by weight, wherein at least one of ZnO and BaO is included as an essential ingredient. The present invention is a glass material for use in sealing, which is of lead-free series, can be used for sealing at a low processing temperature and within a wide temperature range, has a low thermal expansion coefficient, superior adhesion, superior sealing processability, superior adherence, superior chemical stability, superior strength and the like and comprises sufficient practical performance to substitute for lead glass.

PROCEDURES FOR AA CONNECTING A METAL PIECE WITH A GLASS PLATE

Improved glass compositions and seals for sodium vapour electric discharge lamps made therewith

543,441. Glass manufacture. BRITISH THOMSON-HOUSTON CO., Ltd., and STANWORTH, J. E. Jan. 9, 1941, No. 315. [Class 56] [Also in Group XXXVI] Relates to glass suitable for sheathing a copper coated lead-in wire that is to be sealed into the glass envelope of a sodium vapour electric discharge lamp. According to the invention, the glass comprises 60-65 per cent. of silica plus boric oxide plus alumina (the boric oxide and alumina both being less than 5 per cent.), 21-25 percent, of barium oxide plus calcium oxide (the calcium oxide being less than 7 per cent.), and 12.5-14 per cent. of soda plus potash (the potash being less than 5 per cent.). A preferred composition consists of 59.7 per cent. of silica, 22.8 per cent. of barium oxide, 13.1 per cent. of soda, and 4.4 per cent. of alumina. A lead-in sheathed with this glass may be sealed into a glass envelope which is coated on the inside with a sodium-resistant glass composed of 27.0 per cent. of alumina, 36.0 per cent. of barium oxide, 30.4 per cent. of boric oxide, 2.2 per cent. of potassium oxide, and 4.4 per cent. of sodium oxide.

Crystal valve or rectifier

Glass-to-metal seal

Process for producing glass coatings for anodic bonding purposes

The invention relates to a process for anodic bonding and a method of producing glass coatings for anodic bonding purposes and colloidal solutions suitable therefor. The process is particularly suitable for anodic bonding with glass coatings of a thickness from over 100 nm to 10 νm used to bond two semiconductor layers. To produce the desired glass coating, an SiO2 sol is dissolved in at least one or a mixture of n-alkanols (n = 1 to 5). Tetraethyl orthosilicate (TEOS), methyl triethoxysilane (MTEOS) and water are then added to this organosol. In addition, a small quantity of acid and the desired quantity of alkaline salts are added and the colloidal solution is at least partly polymerised. The colloidal solution thus obtained is suitable for coating conductive material by economical processes like immersion, spin-on deposition or spraying followed by tempering. With a single coating, a layer of glass up to 2 νm thick is obtained. Coating thickness of up to more than 10 νm can be obtained by repeating the process several times.

Method of producing layered glass metal composites

FIELD: technological processes.SUBSTANCE: invention relates to a method of producing a layered glass metal composite. Method involves formation of glass-metal package by laying alternating plates of aluminum or its alloy, pre-aged for 5–10 minutes in glass melt with glass transition temperature of 450–550 °C obtained in system BO-NaO-SbO, and cooled to room temperature, and sheet silicate glass. Then, the formed glass metal package is compacted and thermally treated at a glass transition temperature of silicate glass for 2–3 hours, followed by reducing the temperature to room temperature at rate of 4–6 °C/min.EFFECT: increased resistance of glass-metal composite to destruction at dynamic loads due to increased adhesion between its layers at simultaneous reduction of total weight.1 cl, 1 dwg

Anodic bonding method

PCT No. PCT/DE96/00103 Sec. 371 Date Jul. 18, 1997 Sec. 102(e) Date Jul. 18, 1997 PCT Filed Jan. 17, 1996 PCT Pub. No. WO96/22256 PCT Pub. Date Jul. 25, 1996The invention relates to a method of anodic bonding and a method for producing glass coatings for purposes of anodic bonding and colloidal solutions suitable for this purpose. The method is particularly suitable for anodic bonding with glass coatings with a thickness of greater than 100 nm up to 10 mu m, which are used for connecting two semiconductor layers. In order to produce the required glass coating, an SiO2-sol is dissolved in at least one or in a mixture of n-alkanols (n=1 to 5). Then tetraethyl orthosilicate (TEOS), methyl triethoxysilane (MTEOS) and water are added to this organosol. Furthermore, a small quantity of acid is added to the desired quantity of alkali salts, and the colloidal solution is at least partly polymerized. The colloidal solution thus obtained is suitable for coating conductive materials by cost-effective methods such as immersion, spin-on deposition or spraying and subsequent tempering. After one coating there results a glass coating with a thickness of up to 2 mu m. When the method is repeated a plurality of times, coating thicknesses of over 10 mu m can be obtained.

Cap for semiconductor device

In a cap (10) for a semiconductor device in which a light transmissive window (14) is fixed to a cap body (12) provided with a light transmissive opening (12a) using low-melting glass as a fixing material (16) so that the light transmissive window (14) covers the light transmissive opening (12a), the low-melting glass is leadless vanadate-series low-melting glass, and the light transmissive window (14) is fixed to the cap body (12) through an eutectic alloy layer formed by an eutectic reaction of vanadium contained in the low-melting glass and metal applied on the surface of the cap body (12).

Airtight member and manufacturing method thereof

電磁波による局所加熱を適用してガラス基板と高熱伝導性基板との間を気密封止するにあたって、封着層の高熱伝導性基板に対する接着性やその信頼性を高めることを可能にした気密部材の製造方法を提供する。封止領域に電磁波吸収能を有する封着材料層９を設けたガラス基板２と、封止領域にガラス層７を形成した高熱伝導性基板３とを、封着材料層９とガラス層７とを接触させつつ積層する。ガラス基板２を通して封着材料層９に電磁波を照射し、封着材料層を加熱、溶融してガラス層７に固着させることにより、ガラス基板２と熱伝導性基板３との間の間隙を気密に封止する封着層８を形成する。 A hermetic member that can improve the adhesion and reliability of the sealing layer to the high thermal conductivity substrate when applying a local heating by electromagnetic waves to hermetically seal between the glass substrate and the high thermal conductivity substrate. A manufacturing method is provided. A glass substrate 2 provided with a sealing material layer 9 having electromagnetic wave absorbing ability in a sealing region, and a high thermal conductive substrate 3 formed with a glass layer 7 in the sealing region, a sealing material layer 9 and a glass layer 7 Laminate while contacting. The sealing material layer 9 is irradiated with electromagnetic waves through the glass substrate 2, and the sealing material layer is heated and melted to be fixed to the glass layer 7, whereby the gap between the glass substrate 2 and the heat conductive substrate 3 is hermetically sealed. The sealing layer 8 to be sealed is formed.

Seal-penetrating structure for lithium battery, manufacturing method and use thereof in lithium battery, and lithium battery using the same

Electronic discharge lamp and its manufacturing process

Glass winding sealed fitment

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

METHOD FOR MANUFACTURING A VACUUM SOLAR THERMAL PANEL

MÉTODO PARA A FABRICAÇÃO DE UM PAINEL TÉRMICO SOLAR A VÁCUO. O presente pedido refere-se a um método para a fabricação de um painel térmico solar a vácuo que compreende pelo menos uma placa de vidro temperado e uma moldura de metal presa à dita placa, sendo que o método compreende um ciclo de queima de frita para formar uma vedação vidro-metal, sendo que o ciclo de queima de frita compreende uma primeira fase de aquecimento da placa de vidro temperado até uma temperatura máxima (Tm), sendo que a temperatura mantém um nível de pré-tensão adequado da placa de vidro temperado. De modo vantajoso, de acordo com a invenção, o método adicionalmente compreende uma segunda fase de aquecimento (através de iluminação por radiação óptica) que é uma fase de aquecimento seletivo de uma área de fusão da placa de vidro temperado realizada a uma segunda temperatura (Th) que está acima da temperatura máxima (Tm). METHOD FOR MANUFACTURING A VACUUM SOLAR THERMAL PANEL. The present application relates to a method for the manufacture of a vacuum solar thermal panel comprising at least one tempered glass plate and a metal frame attached to said plate, the method comprising a frit burning cycle for form a glass-to-metal seal, and the fry-burning cycle comprises a first stage of heating the tempered glass plate to a maximum temperature (Tm), the temperature maintaining an adequate pre-tension level of the glass plate seasoned. Advantageously, according to the invention, the method additionally comprises a second heating phase (through optical radiation illumination) which is a selective heating phase of a melting area of the tempered glass plate carried out at a second temperature ( Th) that is above the maximum temperature (Tm).

Preparation and use method of low-temperature glass ring for sealing aluminum-based composite material and glass insulation terminal

一种用于封接铝基复合材料与玻璃绝缘端子的低温玻璃环的制备及其使用方法，本发明涉及一种用于封接铝基复合材料与玻璃绝缘端子的低温玻璃环的制备及其使用方法。本发明是要解决现有铝基复合材料与玻璃绝缘端子封接过程中采用含铅玻璃粉生产成本高、能耗大、效率低、复合玻璃低温层致密性差、气密性达标率低的问题。本发明采用非匹配封接方式，不需对低温玻璃粉进行造粒，采用相应模具烧结得到低温玻璃环；然后将玻璃绝缘端子、低温玻璃环置于待封装器件铝基复合材料壳体端孔内，一次烧结，完成封接。本发明用于航空、航天、舰船或地面的相控阵雷达T/R管壳的封装，以及其他领域的精密元器件的金属壳体与玻璃件的封接。

Conductor melting for vessels made of quartz glass or similar high-melting glasses, especially for high-load electrical mercury overpressure vapor lamps

Method for welding surfaces of materials

PROCEDURES FOR AA CONNECTING A METAL PIECE WITH A GLASS PLATE

LITHIUM BATTERY WATERPROOF TRACK, ITS MANUFACTURING METHOD AND USE THEREOF IN A LITHIUM BATTERY, AND LITHIUM BATTERY USING SUCH A TRAVERSEE

Cette traversée verre-métal est constituée de verre (1), d'un pion métallique (2) et d'un corps (3).Le verre est de type TA23 et le pion est réalisé à l'aide de platine iridié (90/10) massif. This glass-to-metal crossing consists of glass (1), a metal pin (2) and a body (3). The glass is of TA23 type and the pin is made using platinum iridium (90 / 10) massive.

Melting electrodes for high pressure discharge lamps and processes for their manufacture

Use of a glass composition for making a solar collector with a glass-metal joint

Use of a glass composition to make a tubular glass body that is adapted to form a glass-metal joint in a tubular solar collector. The composition is a borosilicate glass having a dilatometric chart with a hard segment and a soft- segment hysteresis where the soft segment glass transition temperature is less than the hard-segment glass transition temperature for a temperature difference (ΔΤ) higher than 20°C, in particular higher than 30°C, preferably higher than 40°C. In particular, the composition comprises: - 5% to 8% Na 2 O, - 0, 1% to 3% K 2 O, - 0, 1% to 1, 5% CaO, - 5% to 7,5% Al 2 O 3 , - 70% to 75% SiO 2 , - 11,6% to 13,7% Β 2 O 3 , and owing to the choice of the B 2 O 3 in the range indicated, in combination with the other components, there is a glass transition temperature lower than other borosilicate glasses, and the remarkable difference between the soft and hard segments glass transition temperatures make it possible to obtain a tubular glass body for a solar collector with minimum thermal stress in the working temperature ranges. To the above described composition an oxide can be added selected from the group consisting of: from 0,01% to 1,0% MgO; from 0,01 % to 1% Li 2 O; from 0,01% to 2% BaO; or a combination thereof.

Methods and apparatus for the manufacture of silica glass

The not glassiness or glass-ceramic grafting material and uses thereof of baric and strontium

本发明涉及一种不含钡和锶的玻璃质或玻璃陶瓷接合材料及其用途。具体而言，本发明涉及热膨胀系数α (20-750) ≥7×10 -6 K -1 的玻璃质或玻璃陶瓷接合材料，所述接合材料除了最多由于杂质之外不含BaO和SrO，并且适合产生含铬合金或含铬钢之间的节点连接。

Methods of forming strengthened sintered glass structures

Glass compositions

Method and apparatus for manufacturing semiconductor elements

Electronic device housing, electronic device, and combined body