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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Применить Всего найдено 4578. Отображено 200.
25-12-2018 дата публикации

СПОСОБ ПОЛУЧЕНИЯ СТЕКЛА С ИСПОЛЬЗОВАНИЕМ ЭЛЕКТРОВАРКИ

Номер: RU2675817C2
Принадлежит: СЭН-ГОБЭН ИЗОВЕР (FR)

Изобретение относится к области плавки стекла, предназначенного для преобразования в минеральную вату путем волокнообразования. Способ получения стекла включает стадию электроварки с использованием электродов, погруженных в стекломассу из способной к стеклованию смеси материала шихты. В состав шихты входит по меньшей мере один поставщик марганца, в котором марганец находится в степени окисления выше чем +2, выбранный из MnO, MnO, MnO, MnO, перманганатов и минералов, выбранных из пиролюзита, гаусманита, биксбиита и бернессита. Общее количество поставщика марганца, входящего в состав способной к стеклованию смеси материала шихты, таково, что одна тонна указанной сухой смеси содержит между 1 и 20 кг марганца в степени окисления выше чем +2, в пересчете на MnO. Химический состав стекла включает следующие составляющие в пределах, приводимых ниже, выраженные в % вес.: SiO35-55%; AlO14-27%; CaO 3-18 %; MgO 0-15%; NaO+KO 1-17%; FeO3-15%; BO0-8%; PO0-1%; TiO0-2%. Общее содержание CaO и MgO составляет ...

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27-01-2013 дата публикации

ПРЕДМЕТ КУХОННОЙ УТВАРИ С АНТИПРИГАРНЫМ ПОКРЫТИЕМ, СТОЙКИЙ К КОРРОЗИИ И ЦАРАПИНАМ

Номер: RU2473297C2
Принадлежит: СЕБ СА (FR)

Изобретение относится к кухонной утвари. Предмет содержит металлический корпус (2), который содержит вогнутую внутреннюю поверхность (21), предназначенную для расположения со стороны продуктов питания, выгнутую внешнюю поверхность (22), предназначенную для расположения ближе к источнику тепла. Причем на упомянутую внутреннюю поверхность последовательно, начиная от упомянутого корпуса (2), наносятся покрытая эмалью твердая основа (3), которая является шероховатой и не содержит свинца и кадмия, а затем антипригарное покрытие (4), покрывающее упомянутый твердый слой (3). Настоящее изобретение также относится к способу изготовления такого предмета (1). Заявленная группа изобретений позволяет получить антипригарное покрытие, обладающее хорошими свойствами сцепления с корпусом и свойствами стойкости к коррозии. 2 н. и 19 з.п. ф-лы, 2 ил., 3 табл., 9 пр.

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05-08-2019 дата публикации

УСТРОЙСТВО ДЛЯ ПЛАВЛЕНИЯ СТЕКЛА, ВКЛЮЧАЮЩЕЕ ПЕЧЬ, КАНАЛ И ПЕРЕГОРОДКУ

Номер: RU2696731C2
Принадлежит: СЭН-ГОБЭН ИЗОВЕР (FR)

Группа изобретений относится к устройству для плавления стекла, способу получения стекла. Техническим результатом является повышение качества стекла. Устройство для плавления стекла включает печь, оснащенную электродами в контакте с массой остекловываемых материалов. Печь включает боковое отверстие, соединенное с каналом фидера для расплавленного стекла, удаляемую перегородку, погруженную в стекло в отверстии или перед ним так, что вертикальная плоскость, проходящая через обращенную в сторону выше по потоку поверхность перегородки, касается наибольшей горизонтальной окружности, которая может быть вписана в самую дальнюю ниже по потоку сторону печи, не включая перегородку. Наибольшая окружность находится на уровне самой высокой стороны днища канала. Перегородка является охлаждаемой внутренним потоком охлаждающей текучей среды. 2 н. и 18 з.п. ф-лы, 4 ил.

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16-02-2021 дата публикации

Номер: RU2017145338A3
Автор:
Принадлежит:

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09-03-2017 дата публикации

Стекло

Номер: RU2612380C1

Изобретение относится к производству стекол, которые могут быть использованы, например, для изготовления плафонов люстр. Стекло содержит, мас. %: SiO30,0-35,0; AlO1,0-2,0; CdO 37,0-40,0; SnO2,0-2,8; один оксид из группы LiO, NaO, KO 24,2-26,0. Технический результат – снижение температуры варки стекла. 1 табл.

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27-12-2017 дата публикации

ФЕРРОМАГНИТНОЕ СТЕКЛО

Номер: RU2640222C1

Изобретение относится к составам ферромагнитных стекол, которые могут быть использованы в приборостроении. Ферромагнитное стекло содержит, мас. %: SiO30,0-40,0; СаО 20,0-250,0; FeO15,0-20,0; PbO 5,0-10,0; окисел щелочного металла 15,0-20,0. Технический результат - снижение температуры варки стекла. 1 табл.

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20-03-1995 дата публикации

ФТОРФОСФАТНОЕ ОПТИЧЕСКОЕ СТЕКЛО

Номер: RU2031090C1

Использование: для оптической промышленности. Сущность изобретения: фторфосфатное оптическое стекло содержит, мас.% фосфат алюминия 30 - 45, фосфат бария 0,5 - 5, фторид магния 5 - 10, фторид стронция 0,5 - 12, фторид бария 0,5 - 15, оксид бария 32 - 50, оксид алюминия 0,5 - 2 БФ, оксид кремния 0,2 - 1,75. Стекло может содержать оксид тантала 0,5 - 5 мас.% Кристаллизационная способность за 3 ч при 300 - 800°С 1, nl 1,59548 - 1,61553. 1 з.п. ф-лы, 1 табл.

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10-04-2016 дата публикации

ЛИТИЙСОДЕРЖАЩЕЕ СТЕКЛО С ВЫСОКИМ СОДЕРЖАНИЕМ ОКИСЛИТЕЛЬНОГО ЖЕЛЕЗА И СПОСОБ ЕГО ИЗГОТОВЛЕНИЯ

Номер: RU2580857C1

Изобретение относится к литийсодержщим стеклам с высоким содержанием окисленного железа. Технический результат изобретения заключается в сокращении времени перехода от производственного цикла изготовления стекла с высоким поглощением в ИК-области к производственному цикла изготовления стекла с низким поглощением в ИК-области или наоборот. Стекло содержит следующие компоненты, % масс.: SiO60-63; NaO 10-12; LiO 4-5,5; AlO17-19; ZrO3,5-5; AlO+ZrO21,5-24; FeO 0,0005-0,015; FeO(общее железо) 50-1200 ч./млн и окислитель, выбранный из группы, включающей оксид церия в количестве более 0-0,50% масс., оксид марганца в количестве более 0-0,75% масс. и их смеси. Способ замены процесса изготовления стекла процесса изготовления литиевого стекла с высоким поглощением в инфракрасной области с содержанием FeO в количестве 0,02-0,04% масс. и редокс отношением в диапазоне 0,2-0,4 на процесс изготовления литиевого стекла с низким поглощением в инфракрасной области добавлением дополнительных окислителей - CeOи ...

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14-02-2018 дата публикации

Стекло

Номер: RU2644782C1

Изобретение относится к технологии силикатов, а именно к производству стекол, которые могут быть использованы для изготовления изделий декоративно-художественного назначения. Стекло содержит, мас. %: SiO30,0-32,0; ВO42,0-44,0; СаO 2,0-3,0; KO 7,0-10,0; СеO14,0-16,0. Технический результат- снижение температуры варки стекла. 1 табл.

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23-07-2018 дата публикации

МАТЕРИАЛЫ ФРИТТЫ НА ОСНОВЕ ВАНАДИЯ И СПОСОБЫ ИХ ИЗГОТОВЛЕНИЯ

Номер: RU2661968C1

Изобретение относится к вакуумному стеклопакету и способу его изготовления. Стеклопакет включает первую и вторую стеклянные подложки, расположенные параллельно друг другу и на некотором расстоянии друг от друга. По периметру подложек наносят краевую изоляцию на основе фритты. Фритта содержит, вес.%: оксид ванадия 50-60, оксид бария 27-33, оксид цинка 9-12, NbO1-8. Герметизацию осуществляют путем плавления фритты при температуре, не превышающей 375С. 2 н. и 2 з.п. ф-лы, 6 табл., 20 ил.

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04-09-2018 дата публикации

Стекло

Номер: RU2665725C1

Изобретение относится к технологии силикатов, в частности к производству стекол, которые могут быть использованы в производстве изделий декоративно-художественного назначения. Стекло содержит, мас.%: SiO13,2-19,2; AlO1,0-3,0; MgO 4,0-6,0; KO 17,0-19,0; NaO 0,5-1,5; AsO22,0-24,0; FeO2,5-3,0; ВО19,0-21,0; один компонент из группы СоО, NiO, MnO10,8-12,8. Технический результат - снижение температуры варки стекла. 1 табл.

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10-06-2015 дата публикации

РЕГУЛИРОВКА ДЛИНЫ ВОЛНЫ ИЗЛУЧЕНИЯ РЕДКОЗЕМЕЛЬНОГО ИОНА В СТЕКЛЕ НА ОСНОВЕ ФОСФАТА С ИСПОЛЬЗОВАНИЕМ ОКСИДА ЦЕРИЯ

Номер: RU2013152714A
Принадлежит:

... 1. Композиция фосфатного стекла, допированного Nd, или Yb, или Er, включающая, мол.%:где МО является суммой MgO, CaO, SrO, BaO и ZnO,M′O является суммой LiO, NaO, KO и CsO,сумма МО и М′О составляет 0,00-30,00 мол.%,сумма PO, BO, SiOи AlOсоставляет, по меньшей мере, 46 мол.%весь или часть СеОможет быть заменен эквивалентным количеством СеО, в котором эквивалентное количество CeOозначает количество, содержащее такое же количество молей Се, что и в CeO,сумма LaO, СеО, СеО, NdO, YbOи ErOсоставляет не более 35,00 мол.%предел растворимости относится к концентрации, которая является пределом растворимости YbOв композиции стекла, истекло включает, по меньшей мере, 0,25 мол.% NdOи/или, по меньшей мере, 0,50%мол. YbOи/или, по меньшей мере, 0,05 мол.% ErO.2. Композиция фосфатного стекла по п.1, в которой указанная композиция стекла содержит менее 0,01 CrO.3. Композиция фосфатного стекла по п.1, в которой указанная композиция стекла содержит 1,00-15,00 мол.% SiO.4. Композиция фосфатного стекла по п ...

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27-07-2005 дата публикации

ПЛАЗМЕННОЕ НАПЫЛЕНИЕ

Номер: RU2005102394A
Принадлежит:

... 1. Способ получения аморфного материала, включающий: ввод в плазму частиц для образования расплава, причем частицы содержат по меньшей мере 35 вес.% Al2O3, основываясь на общем весе частиц, и оксид металла, иной, чем Al2O3, где частицы содержат в общей сложности не более чем 10 вес.% As2O3, B2О3, GeO2, P2O5, SiO2, TeO2 и V2O5, основываясь на общем весе частиц, с оговоркой, что если оксидом металла, иным, чем Al2O3, является ZrO2, тогда частицы дополнительно содержат оксид металла, иной, чем Al2O3 и ZrO2; и напыление и охлаждение расплава с целью получения аморфного материала, причем аморфный материал содержит по меньшей мере 35 вес.% Al2O3, основываясь на общем весе аморфного материала, и оксид металла, иной, чем Al2O3, где аморфный материал содержит в общей сложности не более чем 10 вес.% As2 O3, B2O3, GeO2, P2O5, SiO2, TeO2 и V2O5, основываясь на общем весе аморфного материала, где аморфный материал имеет размерения x, y и z, каждое из которых перпендикулярно каждому другому, и где каждое ...

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23-07-1983 дата публикации

Стекло

Номер: SU1030329A1
Принадлежит:

СТЕКЛО, включающее SiO, , CdO, отличающееся тем, что, с целью увеличения коэффициента линейного термического расширения и снижения температуры варки, оно содержит ZnO при следующем соотношении компонентов, мае. %: SiOa.- 15-52 AljO 10-32 CdO 32-7 ZnO0,5-2,0 ...

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13-11-2014 дата публикации

Zusatzstoff für elektrochemische Energiespeicher und elektrochemischer Energiespeicher

Номер: DE102012215824A1
Принадлежит:

Die Erfindung betrifft einen Zusatzstoff für elektrochemische Energiespeicher, wobei der Zusatzstoff wenigstens ein siliciumhaltiges Material enthält, das in Kontakt mit einer fluorhaltigen Verbindung V1 im Energiespeicher wenigstens eine Verbindung V2 bildet, wobei die Verbindung V2 ausgewählt ist aus der Gruppe der silicium- und fluorhaltigen, lithiumfreien Verbindungen V2a, oder fluorhaltigen, lithiumfreien Erdalkaliverbindungen V2b, oder Kombinationen davon. Weiterhin betrifft die Erfindung einen elektrochemischen Energiespeicher, der den erfindungsgemäßen Zusatzstoff enthält.

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23-05-2019 дата публикации

Beschichtetes Glas- oder Glaskeramik-Substrat, Beschichtung umfassend geschlossene Poren sowie Verfahren zur Beschichtung eines Substrats

Номер: DE102017127624A1
Принадлежит:

Die Erfindung betrifft allgemein beschichtete Glas- oder Glaskeramik- Substrate mit hoher Temperaturbeständigkeit, hoher Festigkeit und einem niedrigen thermischen Ausdehnungskoeffizienten. Weitere Aspekte der Erfindung betreffen eine Beschichtung, welche Poren umfasst und fluiddicht ausgebildet ist und geeignet ist für die Beschichtung eines temperaturbeständigen, hochfesten Glas- oder Glaskeramik-Substrats mit niedrigem thermischen Ausdehnungskoeffizienten sowie ein Verfahren zur eines solchen Substrats.

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27-04-2005 дата публикации

Lead-free optical heavy flint glasses

Номер: GB0002377435B
Принадлежит: ZEISS STIFTUNG, * CARL-ZEISS-STIFTUNG

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12-10-1983 дата публикации

THALLIUM-CONTAINING OPTICAL GLASS COMPOSITION

Номер: GB0008324139D0
Автор:
Принадлежит:

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28-05-1981 дата публикации

Fluoride glass

Номер: GB0002062613A
Автор: Nozawa, Nobuhiro
Принадлежит:

A fluoride glass basically containing ingredients of a P-Si-Al-alkaline-earth metals-alkali metals-F system within specific content ranges has extremely high anomalous partial dispersion and low dispersion properties and is stable without tendency to devitrification.

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28-11-1984 дата публикации

THALLIUM-CONTAINING OPTICAL GLASS

Номер: GB0002100247B
Автор:
Принадлежит: NIPPON SHEET GLASS CO LTD

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18-03-1981 дата публикации

BIOCIDAL GLASS ADDITIVE FOR MARINE PAINTS

Номер: GB0001586395A
Автор:
Принадлежит:

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10-11-1982 дата публикации

HIGH REFRACTIVE INDEX GLASS OF LIMITED SPECIFIC GRAVITY FOR DISTANCE AND NEAR VISION SPECTACLE LENSES

Номер: GB0002022572B
Автор:
Принадлежит: ZEISS STIFTUNG, CARL ZEISS STIFTUNG

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19-12-1979 дата публикации

High refractive index glass of limited specific gravity for distance and near vision spectacle lenses

Номер: GB0002022572A
Принадлежит:

Optical glasses having high refractive indexes and low specific gravities are provided for use as both distant and near vision spectacle lenses. The glasses consist essentially of low molecular weight cationic oxides, alkali metal oxides and divalent oxides to promote the crystallization stability of the glass. They have good chemical resistance, chemical hardenability and a thermal expansion coefficient between 93 and 99x10-7/ DEG C. in the range of 20 DEG -300 DEG C. Optical lenses can be continuously produced due to the high crystallization stability of the glasses and the resultant spectacle lenses have high dioptric values even with thinner edge or center thicknesses.

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30-04-2016 дата публикации

A METHOD AND COMPOSTION FOR SEQUESTRATION OF ARSENIC

Номер: AP2016009144A0
Принадлежит:

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30-04-2016 дата публикации

A METHOD AND COMPOSTION FOR SEQUESTRATION OF ARSENIC

Номер: AP0201609144A0
Принадлежит:

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07-08-1968 дата публикации

Objects out of ceramic glass and their manufactoring process.

Номер: OA0000001081A
Автор:
Принадлежит:

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30-04-2016 дата публикации

A METHOD AND COMPOSTION FOR SEQUESTRATION OF ARSENIC

Номер: AP0201609144D0
Принадлежит:

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15-06-2005 дата публикации

OPTICAL GLASS

Номер: AT0000296269T
Принадлежит:

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12-10-2017 дата публикации

Inorganic fibre compositions

Номер: AU2014294819B2
Принадлежит: Spruson & Ferguson

Inorganic fibres having the composition:- 10≤A1 ...

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08-07-1980 дата публикации

GLASS COMPOSITIONS

Номер: CA0001081263A1
Принадлежит:

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18-05-2006 дата публикации

DENTAL GLASS COMPOSITION

Номер: CA0002587400A1
Автор: BLACKWELL, GORDON
Принадлежит:

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14-10-1980 дата публикации

BORON FREE ALUMINO-PHOSPHATE PHOTOCHROMIC GLASS COMPOSITION CONTAINING DISPERSED SILVER HALIDE CRYSTALS

Номер: CA1087436A

Fast-response photochromic boron-free alumino-phosphate glasses which have silver halide crystals dispersed throughout the glass comprise, in weight percentages: SiO2 10 to 17% Al2O3 20 to 29% P2O5 30 to 40% R2O 8.5 to 17% R'O 4 to 18% where R2O is taken from the group consisting of Na2O, K2O, and combinations thereof; R'O is taken from the group consisting of CaO, BaO and combinations thereof provided that when in combination, CaO is present up to 7%; the total of SiO2 + Al2O3 + P2O5 amounting to not less than 69% by weight of the glass. Preferably the total of SiO2 + P2O5 + Al2O3 is not less than 72% by weight of the glass. The silver content of the glass, expressed as Ag2O, is preferably not less than 0.05%. Refractive index nD can be corrected to the standard ophthalmic value of 1.523 by additions of TiO2, ZrO2 and/or PbO.

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26-06-1979 дата публикации

PHOTOTROPIC OPHTHALMIC GLASS

Номер: CA1057107A

A phototropic glass containing P2O5 as the principal component and, as agents imparting phototropy, silver and halogen in non-crystalline form.

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22-05-1990 дата публикации

THICK FILM CONDUCTOR COMPOSITION

Номер: CA0001269238A1
Автор: TAYLOR BARRY E
Принадлежит:

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21-08-1984 дата публикации

ALCOHOL-FREE ALKOXIDE PROCESS FOR CONTAINING NUCLEAR WASTE

Номер: CA0001172843A1
Принадлежит:

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31-01-2008 дата публикации

GLASSES HAVING A REDUCED STRESS-OPTIC COEFFICIENT

Номер: CA0002658823A1
Принадлежит:

The present invention provides novel glasses, methods of formulating glas ses having a reduced stress-optic coefficient at visible wavelengths under a nisotropic stress, and novel optical systems comprising a such glass. ...

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23-12-2016 дата публикации

A METHOD AND COMPOSITION FOR SEQUESTRATION OF ARSENIC

Номер: CA0002926123A1
Принадлежит:

There is provided a method and composition for sequestration of arsenic, the method comprising melting an arsenic-containing material in the presence of iron oxide and glass, and yielding a resulting glass incorporating arsenic. The resulting glass has an arsenic content comprised in a range between 1 and 25% w/w and an iron content comprised in a range between 8 and 20% w/w.

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15-06-2021 дата публикации

MAN-MADE VITREOUS FIBRES

Номер: CA2926033C
Принадлежит: ROCKWOOL INT A/S, ROCKWOOL INTERNATIONAL A/S

The invention provides a method of manufacture of man-made vitreous fibres (MMVF) comprising: providing a fiberising apparatus, wherein the fiberising apparatus comprises: a set of at least three rotors each mounted for rotation about a different substantially horizontal axis; wherein each rotor has a driving means; rotating the rotors; wherein the first rotor rotates to give an acceleration field of from 25 to 60 km/s2 and the second and third rotors each rotate to give an acceleration field of at least 125 km/s2, providing a mineral melt, wherein the melt has a composition comprising the following, expressed by wt of oxides: SiO2 in an amount of from 33 to 45 wt%, Al2O3 in an amount of from 16 to 24 wt%, an amount of K2O and/or Na2O, an amount of CaO and/or MgO, wherein the ratio of the amount of Al2O3 to the amount of SiO2 is in the range 0.34-0.73, wherein the ratio of the total amount of K2O and Na2O, to the total amount of CaO and MgO, is less than 1; pouring the melt on to the periphery ...

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28-04-2011 дата публикации

CONDUCTIVE PASTE FOR FORMING A SOLAR CELL ELECTRODE

Номер: CA0002718204A1
Принадлежит:

A conductive paste for forming a solar cell electrode, including: a conductive powder comprising silver as a main component; glass frit; and an organic vehicle, wherein the glass frit contains tellurium glass frit having tellurium oxide as a network-forming component. The conductive paste of the present invention makes it possible to form a solar cell electrode having a low dependence on firing temperature without causing problems due to fire-through into the substrate, and to thereby obtain a solar cell having good solar cell characteristics.

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27-10-1999 дата публикации

HIGH-DURABILITY LOW-TEMPERATURE LEAD-FREE GLASS AND ENAMEL COMPOSITIONS WITH LOW BORON CONTENT

Номер: CA0002269882A1
Принадлежит:

Low-temperature melting lead-free glass compositions are provided which have a bismuth oxide content of 40-70 wt.%, a SiO2 content of 24-40 wt.% and a low boron content or are free of boron. Enamel compositions made therewith possess high durability properties. Enamel pastes containing frits of the glass compositions are particularly useful in forming colored borders in automotive glass.

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31-08-1939 дата публикации

Optisches Glas und Verfahren zur Erzeugung desselben.

Номер: CH0000206664A
Принадлежит: KODAK SA, KODAK SOCIETE ANONYME

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15-09-1948 дата публикации

Glassatz zur Herstellung optischer Gläser.

Номер: CH0000256801A
Принадлежит: KODAK SA, KODAK SOCIETE ANONYME

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31-07-1966 дата публикации

Glas

Номер: CH0000417865A
Принадлежит: CATAPHOTE CORP, CATAPHOTE CORPORATION

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12-04-1979 дата публикации

Номер: CH0000610286A5

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31-07-1979 дата публикации

Glass electrode

Номер: CH0000612509A5

This is used to measure the oxidation potential of liquid media. The sensor element (2) arranged in a hermetically tight manner on a tube (1) made of high-resistance glass no longer consists of a noble metal but of an electron-conductive glass. Situated in the interior of the electrode there is the current tap (3) which passes to the outside via the lead (5). The sensor element (2) consists of the following composition in parts by weight: SiO2 from 32 to 45; Me2O from 7.0 to 26.0, Me being at least two of the elements Li, Na and K; TiO2 from 16.0 to 40; Ti2O3 from 0.8 to 4.2; Nb2O5 and/or Ta2O5 from 2.0 to 32.0. By virtue of this design of the sensor element (2), chemical stability is considerably enhanced, so that the electrode can now be employed for measurements in strongly acidic media having a pH of less than 3, and temperatures of more than 60 DEG C in the presence of dissolved oxygen, hydrogen and catalytic poisons. ...

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14-03-1980 дата публикации

Aluminium silicate glass powder for polycarboxylate cements

Номер: CH0000616131A5

Aluminium silicate glass powder for polycarboxylate cements used for dental or surgical purposes or as binder for other applications (NL270476) ...

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30-06-1978 дата публикации

Номер: CH0000601123A5

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28-02-1986 дата публикации

SCINTILLATION GLASS.

Номер: CH0000654562A5
Принадлежит: SCHOTT GLASWERKE

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29-09-2017 дата публикации

Lighting device with extended useful spectrum.

Номер: CH0000708055B1
Принадлежит: SCHOTT AG, Schott AG

Die Erfindung betrifft eine Beleuchtungseinrichtung (1) zum Bestrahlen von Objekten mit elektromagnetischer Strahlung (4), umfassend zumindest einen Lichtleiter (2) und eine Strahlungsquelle (10), die elektromagnetische Strahlung (4) insbes. im Spektralbereich von 320 nm bis 420 nm in den Lichtleiter (2) emittiert. Der Lichtleiter (2) wird aus einem Glas gebildet, das einen spektralen Transmissionsgrad bei 350 nm von mindestens 70% aufweist und ausgewählt ist aus dem System der bleifreien Silikat-Zinn-Gläser. Die Erfindung betrifft ebenfalls die Verwendung der erfindungsgemässen Beleuchtungseinrichtung (1), insbesondere in der Zahnheilkunde, bei der Krebsdiagnose und in Endoskopen.

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14-11-2014 дата публикации

Illumination device with extended utilizable spectrum.

Номер: CH0000708055A2
Принадлежит:

Die Erfindung betrifft eine Beleuchtungseinrichtung (1) zum Bestrahlen von Objekten mit elektromagnetischer Strahlung (4), umfassend zumindest einen Lichtleiter (2) und eine Strahlungsquelle (10), die elektromagnetische Strahlung (4), insbesondere im Spektralbereich von 320 nm bis 420 nm, in den Lichtleiter (2) emittiert. Der Lichtleiter (2) wird aus einem Glas gebildet, das einen spektralen Transmissionsgrad bei 350 nm von mindestens 70% aufweist und ausgewählt ist aus dem System der bleifreien Silikat-Zinn-Gläser. Die Erfindung betrifft ebenfalls die Verwendung der Erfindungsgemässen Beleuchtungseinrichtung (1), insbesondere in der Zahnheilkunde, bei der Krebsdiagnose und in Endoskopen.

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29-04-2016 дата публикации

Method for preparing a glass-ceramic article and [...]green glass component and green glass component ceramisable.

Номер: CH0000710312A2
Принадлежит:

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von keramisierbaren Grünglaskomponenten, eine Vorrichtung zur Durchführung eines solchen Verfahrens sowie eine durch das Verfahren herstellbare keramisierbare Grünglaskomponente. Das Verfahren ist ein Wiederziehverfahren, bei dem in einer Verformungszone eine Vorform auf eine Temperatur erhitzt wird, die ein Wiederziehen des Glases erlaubt. Das Verfahren zeichnet sich dadurch aus, dass die Verformungszone besonders klein ist. Dadurch wird erreicht, dass keramisierbare Grünglaskörper wiedergezogen werden können, ohne dass eine Keramisierung bereits während des Wiederziehen einsetzt. Mit dem Verfahren sind platten- oder scheibenförmige Grünglaskomponenten erhältlich, die sich unter anderem durch eine besonders glatte Oberfläche auszeichnen.

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31-01-2020 дата публикации

A process for preparing a green glass component and ceramicizable green glass and glass ceramic component ceramisable article.

Номер: CH0000710312B1
Принадлежит: SCHOTT AG, Schott AG

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung einer keramisierbaren Grünglaskomponente sowie eine durch das Verfahren hergestellte keramisierbare Grünglaskomponente und ein daraus hergestellter Glaskeramikgegenstand. Das Verfahren umfasst die folgenden Schritte: Erzeugen einer Glasschmelze aus keramisierbarem Glas, Erzeugen eines keramisierbaren Grünglaskörpers als Vorform (1) zum Wiederziehen, Bereitstellen der Vorform (1) in einer Wiederziehvorrichtung, Erwärmen zumindest eines Teilabschnitts der Vorform, Wiederziehen der Vorform (1) zu einer keramisierbaren Grünglaskomponente. Die keramisierbare Grünglaskomponente weist einen kristallinen Anteil von weniger als 20 Vol.-%, bevorzugt weniger als 10 Vol.-% und besonders bevorzugt weniger als 5 Vol.-% auf.

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29-07-2016 дата публикации

Method for preparing a glass-ceramic article and [...]green glass component and green glass component ceramisable.

Номер: CH0000710312A8
Принадлежит:

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von keramisierbaren Grünglaskomponenten, eine Vorrichtung zur Durchführung eines solchen Verfahrens sowie eine durch das Verfahren herstellbare keramisierbare Grünglaskomponente. Das Verfahren ist ein Wiederziehverfahren, bei dem in einer Verformungszone eine Vorform auf eine Temperatur erhitzt wird, die ein Wiederziehen des Glases erlaubt. Das Verfahren zeichnet sich dadurch aus, dass die Verformungszone besonders klein ist. Dadurch wird erreicht, dass keramisierbare Grünglaskörper wiedergezogen werden können, ohne dass eine Keramisierung bereits während des Wiederziehen einsetzt. Mit dem Verfahren sind platten- oder scheibenförmige Grünglaskomponenten erhältlich, die sich unter anderem durch eine besonders glatte Oberfläche auszeichnen.

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28-04-2017 дата публикации

A process for preparing a green glass component and ceramicizable green glass and glass ceramic component ceramisable article.

Номер: CH0000711704A2
Принадлежит:

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von keramisierbaren Grünglaskomponenten, eine Vorrichtung zur Durchführung eines solchen Verfahrens sowie eine durch das Verfahren herstellbare keramisierbare Grünglaskomponente. Das Verfahren ist ein Wiederziehverfahren, bei dem in einer Verformungszone eine Vorform auf eine Temperatur erhitzt wird, die ein Wiederziehen des Glases erlaubt. Das Verfahren zeichnet sich dadurch aus, dass die Verformungszone besonders klein ist. Dadurch wird erreicht, dass keramisierbare Grünglaskörper wiedergezogen werden können, ohne dass eine Keramisierung bereits während des Wiederziehens einsetzt. Mit dem Verfahren sind platten- oder scheibenförmige Grünglaskomponenten erhältlich, die sich unter anderem durch eine besonders glatte Oberfläche auszeichnen.

Подробнее
15-10-2020 дата публикации

Method of making a ceramisable green glass component and ceramic green glass component and glass-ceramic article.

Номер: CH0000711704B1
Принадлежит: SCHOTT AG, Schott AG

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von keramisierbaren Grünglaskomponenten, eine durch das Verfahren herstellbare keramisierbare Grünglaskomponente und ein Glaskeramikgegenstand. Das Verfahren ist ein Wiederziehverfahren, bei dem in einer Verformungszone eine Vorform auf eine Temperatur erhitzt wird, die ein Wiederziehen des Glases erlaubt. Das Verfahren zeichnet sich dadurch aus, dass die Verformungszone besonders klein ist. Dadurch wird erreicht, dass keramisierbare Grünglaskörper wiedergezogen werden können, ohne dass eine Keramisierung bereits während des Wiederziehen einsetzt. Mit dem Verfahren sind platten- oder scheibenförmige Grünglaskomponenten erhältlich, die sich unter anderem durch eine besonders glatte Oberfläche auszeichnen.

Подробнее
28-02-2019 дата публикации

RICH LITHIUM METALLURGICAL SLAG

Номер: EA0201891454A1
Автор:
Принадлежит:

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31-03-2014 дата публикации

METHOD OF PRODUCING ARTIFICIAL VITREOUS FIBERS

Номер: EA0201391520A1
Автор:
Принадлежит:

Подробнее
17-09-2003 дата публикации

Glass-ceramics, process for their preparation and use

Номер: CN0001443144A
Принадлежит:

Подробнее
31-08-2018 дата публикации

Lithium-rich metallurgical slag

Номер: CN0108474061A
Принадлежит:

Подробнее
01-09-2004 дата публикации

一类矿化水、杀菌用磷酸盐玻璃

Номер: CN0001164514C
Принадлежит:

... 本发明提供了一类矿化水、杀菌用磷酸盐玻璃。磷酸盐玻璃矿化水和杀菌功能的结合可以通过调整玻璃组成来达到的。玻璃中引入了一定比例的碱金属氧化物和碱土金属氧化物用于调节玻璃的溶解速率,以达到使玻璃能以恒定速率整体性溶解在水中。微量银或亚铜离子的引入使玻璃具有很好的杀菌作用。该玻璃不仅能在水中以恒定速率溶解释放出对人体有益的矿物元素补充人体所需,还具有良好的杀菌效率,使其完全适用于矿化水和杀菌用途。本发明的磷酸盐玻璃在国内外尚属首创,具有广泛的市场发展前景。 ...

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31-10-1964 дата публикации

Manufactoring process of objects out of glass with great mechanical resistance

Номер: FR0001377201A
Автор:
Принадлежит:

Подробнее
18-01-1985 дата публикации

PROCEDE POUR LES PERFECTIONNEMENTS APPORTES AUX CONDUCTEURS METALLIQUES ELECTRIQUES, ISOLES OU RELATIFS A CES CONDUCTEURS APPLIQUES AUX REACTEURS NUCLEAIRES REFROIDIS PAR UN METAL LIQUIDE

Номер: FR0002549276A
Автор: DOUGLAS MILTON MATTOX
Принадлежит:

A.PROCEDE POUR LES PERFECTIONNEMENTS APPORTES AUX CONDUCTEURS METALLIQUES ELECTRIQUES, ISOLES OU RELATIFS A CES CONDUCTEURS APPLIQUES AUX REACTEURS NUCLEAIRES REFROIDIS PAR UN METAL LIQUIDE. B.PROCEDE POUR L'APPLICATION D'UN REVETEMENT ISOLANT, CARACTERISE EN CE QUE LA COMPOSITION EST LA SUIVANTE:COMPOSANTSSIOMGOA1OCAOBAOYOPROPORTION EN EN POIDS30-405-80-65-1035-500-8 C.L'INVENTION CONCERNE UN ISOLANT EFFICACE DES BOBINAGES DES ELECTRO-AIMANTS COMMANDANT LES BARRES DE SECURITE SITUEES AU-DESSUS DU COEUR D'UN REACTEUR NUCLEAIRE A METAL LIQUIDE, NOTAMMENT A SODIUM LIQUIDE.

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02-02-1950 дата публикации

High dispersion fluosilicate glasses

Номер: FR0000956500A
Автор:
Принадлежит:

Подробнее
24-10-1980 дата публикации

PHOSPHATE GLASS OF SYSTEM AL2O3-SIO2-P2O5, PROCESS AND MIXTURE FOR SA PREPARATION AND USE OF GLASS AND THE MIXTURE

Номер: FR0002411164B1
Автор:
Принадлежит:

Подробнее
16-01-1976 дата публикации

OPTICAL GLASS

Номер: FR0002038401B1
Автор:
Принадлежит:

Подробнее
24-02-1967 дата публикации

Transparent glasses with the infra-reds

Номер: FR0001471011A
Автор:
Принадлежит:

Подробнее
29-05-1981 дата публикации

VERRE OPTIQUE CONTENANT DU CESIUM

Номер: FR0002470101A
Принадлежит:

CE VERRE COMPREND, EN POIDS, 30-65 DE SIO, 5-35 DE KO, 5-50 DE CSO, 0-32 DE BAO, 0-10 DE MGO, 2-36 DE ZNO, 0,4 DE ZRO ET 0-6 DE SNO, AVEC LA CONDITION QUE LA PROPORTION TOTALE DE BAO, MGO ET ZNO SOIT DE 8 A 42 ET QUE LA PROPORTION TOTALE DE ZRO ET SNO SOIT DE 0,2 A 8. EN TRAITANT CE VERRE DANS UN BAIN DE NITRATE DE POTASSIUM FONDU, L'ION CESIUM DU VERRE S'ECHANGE FACILEMENT CONTRE L'ION POTASSIUM DU BAIN, ET AINSI LA CONCENTRATION DE L'ION CESIUM DIMINUE PROGRESSIVEMENT DANS LA DIRECTION RADIALE, DEPUIS L'AXE CENTRAL VERS L'EXTERIEUR, TANDIS QUE LA CONCENTRATION DE L'ION POTASSIUM S'ELEVE PROGRESSIVEMENT DANS CETTE MEME DIRECTION. UTILISATION POUR LA FABRICATION DE FIBRES OPTIQUES AUTOFOCALISATRICES (A GRADIENT D'INDICE DE REFRACTION) DANS LESQUELLES L'INDICE DE REFRACTION DIMINUE PROGRESSIVEMENT DANS LA DIRECTION INDIQUEE.

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16-03-1984 дата публикации

COMPOSITION DE VERRE OPTIQUE CONTENANT DU THALLIUM

Номер: FR0002532931A
Принадлежит:

LA PRESENTE INVENTION SE RAPPORTE A UNE COMPOSITION DE VERRE OPTIQUE CONTENANT DU THALLIUM. LADITE COMPOSITION EST CARACTERISEE EN CE QU'ELLE CONTIENT EN DES PROPORTIONS DEFINIES LES OXYDES SUIVANTS: SIO, TLO, RO (OU R EST UN METAL ALCALIN), ZNO, ET EVENTUELLEMENT LES OXYDES SUIVANTS: ZRO, ALO, SNO ETOU SNO ET BO. LE VERRE REALISE A PARTIR DE CETTE COMPOSITION PRESENTE EN PARTICULIER UNE HAUTE RESISTANCE AUX SELS FONDUS DE METAUX ALCALINS. APPLICATION A LA FABRICATION DE LENTILLES A GRADIENT D'INDICE DE REFRACTION.

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29-11-1968 дата публикации

Target for camera tubes in television

Номер: FR0001547909A
Автор:
Принадлежит:

Подробнее
22-12-1978 дата публикации

VERRE PRESENTANT DES PROPRIETES ANTI-HALO, ET SON UTILISATION POUR LA FABRICATION DE VERRES DE LUNETTES

Номер: FR0002391965A
Автор:
Принадлежит:

L'invention concerne un verre qui comprend : a. 100 parties en moles d'un verre de base consistant en 47 à 65 moles % de P2 O5 , 0 à 12 moles % de SiO2 , 0 à 10 moles % de B2 O3 , la proportion totale SiO2 + B2 O3 étant de 6 à 15 %, 0 à 30 % d'au moms un oxyde de métal alcalino-terreux choisi parmi MgO, CaO, SrO et BaO, la porportion totale dudit oxyde de métal alcalin et dudit oxyde de métal alcalino-terreux étant de 20 à 45 %, 0 à 5 % de Al 2 O3 , 0 à 10 % de ZnO et 0 à 5 % de PbO; b. 0,1 à 2 parties en moles de CeO2 ; et c. 0 à 1,5 partie en moles de Nd2 o3 ou 0 à 1 partie en moles de Er2 O3 , ou un mélange de ces composés. Verre pour lunettes, anti-halo.

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27-06-2014 дата публикации

METHOD OF MANUFACTURING GLASS ELECTRIC FUSION

Номер: FR0003000056A1
Принадлежит:

L'invention a pour objet un procédé de fabrication d'un verre dont la composition chimique comprend au moins 3% en poids d'oxyde de fer, exprimé sous la forme Fe2O3, comprenant une étape de fusion électrique au moyen d'électrodes immergées dans le verre fondu d'un mélange de matières premières vitrifiable contenant au moins un porteur de manganèse dans lequel le manganèse est dans un état d'oxydation supérieur à +2.

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07-05-1982 дата публикации

COMPOSITIONS OF GLASSES FOR GLASSES OF SPECTACLE INDUSTRY

Номер: FR0002313328B1
Автор:
Принадлежит:

Подробнее
23-12-2016 дата публикации

GLASS COMPOSITION FOR CEMENTITIOUS PRODUCTS ACCELERATOR AND ACTIVATOR

Номер: FR0002995889B1
Принадлежит: SAINT-GOBAIN WEBER

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07-06-2013 дата публикации

GLASSES, VITROCERAMICS AND CERAMICS Of TRANSPARENT ALUMINATES

Номер: FR0002983473A1

La présente invention concerne de nouvelles compositions de verres transparents, de vitrocéramiques et de céramiques transparentes ou translucides comprenant au moins 85% massique, par rapport à la composition totale du verre, de la vitrocéramique ou de la céramique, d'une composition de formule I suivante : (M1O)x(M2O)y((M3)2O3)z(Al2O3)100-x-y-z (I) où M1 représente un élément choisi parmi Ba et/ou Sr, et M2 représente un élément choisi parmi Mg ou Ca, et x et y représentent des nombres tels que 30≤ x+y ≤80, et y est compris entre 0 et 10% de x, et M3 représente un élément choisi parmi B, Ga ou In, et z représente un nombre compris entre 0 et 10% de (100-x-y), leur procédé de fabrication et leurs utilisations dans le domaine de l'optique.

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03-05-2012 дата публикации

Abnormality detection system, abnormality detection method, and recording medium

Номер: US20120109582A1
Принадлежит: Tokyo Electron Ltd

Disclosed is an abnormality detection system that accurately detects abnormalities that arise in a device. The abnormality detection system 100, which detects abnormalities that arise in a plasma processing device 2, is provided with: a plurality of ultrasonic sensors 41, which detects acoustic emissions (AE), which cause abnormalities to arise; a distributor 65, which distributes each output signal from the ultrasonic sensors 41 into a first signal and a second signal; a trigger 52, which samples the first signal at, for example, 10 kHz, and generates a trigger signal when predetermined characteristics are detected; a trigger generation time counter 54, which receives trigger signals and determines the time of trigger generation; a data logger board 55, which creates sampling data from sampling the second signal at, for example, 1 MHz; and a PC 50, which analyzes abnormalities arising in the plasma processing device 2 by means of performing a waveform analysis of data from the sampling data, said data corresponding to a set time period using the time of trigger generation determined by the trigger generation time counter 54 as a benchmark.

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24-05-2012 дата публикации

Aluminum-boron solar cell contacts

Номер: US20120125428A1
Принадлежит: Ferro Corp

Formulations and methods of making solar cells are disclosed. In general, the invention provides a solar cell comprising a contact made from a mixture wherein, prior to firing, the mixture comprises at least one aluminum source, at least one boron source, and about 0.1 to about 10 wt % of a glass component. Within the mixture, the overall content of aluminum is about 50 wt % to about 85 wt % of the mixture, and the overall content of boron is about 0.05 to about 20 wt % of the mixture.

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07-06-2012 дата публикации

Green luminescent glass for ultraviolet led and preparation method thereof

Номер: US20120138854A1
Принадлежит: Mingjie Zhou, Wenbo Ma, Zhaopu Shi

A green luminescent glass for ultraviolet LED and a preparation method for glass are disclosed. The preparation method includes: weighing raw materials of CaCO 3 , Al 2 O 3 , SiO 2 , CeO 2 and Tb 4 O 7 respectively and mixing the raw materials evenly; melting the raw materials at 1500˜1700 for 0.5˜3 hours and then molding to form a glass; annealing the formed glass in reducing atmosphere with temperature of 650˜1050 for 3˜20 hours; and cooling the glass to room temperature to obtain the green luminescent glass for ultraviolet LED. The green luminescent glass for ultraviolet LED prepared according to the preparation method of the disclosure has advantages of high luminous intensity, uniformity and stability.

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20-12-2012 дата публикации

Glass composition and optical device

Номер: US20120319015A1
Принадлежит: Canon Inc

There is provided a glass composition containing an oxide containing Lu, Si, and Al, in which the composition of the glass composition lies within a compositional region of a ternary composition diagram of Lu, Si, and Al in terms of cation percent, the compositional region being defined by the following six points: (32.3% Lu0 3/2 , 30.0% SiO 2 , 37.7% AlO 3/2 ), (32.3% Lu0 3/2 , 37.7% SiO 2 , 30.0% AlO 3/2 ), (20.8% Lu0 3/2 , 55.0% SiO 2 , 24.2% AlO 3/2 ), (10.0% Lu0 3/2 , 45.0% SiO 2 , 45.0% AlO 3/2 ), (20.8% Lu0 3/2 , 24.2% SiO 2 , 55.0% AlO 3/2 ), and (30.0% Lu0 3/2 , 25.0% SiO 2 , 45.0% AlO 3/2 ). For the glass composition, a glassy state having low or no intrinsic birefringence in the ultraviolet region is stably obtained.

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16-05-2013 дата публикации

ION EXCHANGEABLE GLASS WITH HIGH CRACK INITIATION THRESHOLD

Номер: US20130122284A1
Автор: Gross Timothy Michael
Принадлежит:

Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % POand, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf. 2. The alkali aluminosilicate glass of claim 1 , wherein the glass satisfies:{'br': None, 'sub': 2', '3', 'x, '[MO(mol%)/RO(mol%)]<1.4.'}3. The alkali aluminosilicate glass of claim 2 , wherein the glass satisfies:{'br': None, 'sub': 2', '3', 'x, '[MO(mol%)/RO(mol%)]<1.'}4. The alkali aluminosilicate glass of claim 1 , wherein the glass satisfies:{'br': None, 'sub': 2', '5', '2', '2', '3, '1.3<[(PO+RO)/MO]≦2.3.'}5. The alkali aluminosilicate glass of claim 4 , wherein the glass satisfies:{'br': None, 'sub': 2', '5', '2', '2', '3, '1.5<[(PO+RO)/MO]≦2.0.'}6. The alkali aluminosilicate glass of claim 1 , further comprising less than 1 mol % KO.7. The alkali aluminosilicate glass of claim 6 , wherein the alkali aluminosilicate glass comprises 0 mol % KO.8. The alkali aluminosilicate glass of claim 1 , further comprising less than 1 mol % BO.9. The alkali aluminosilicate glass of claim 8 , wherein the alkali aluminosilicate glass comprises 0 mol % BO.10. The alkali aluminosilicate glass of claim 1 , wherein the glass is ion exchanged to a depth of layer of at least about 10 μm.11. The alkali aluminosilicate glass of claim 10 , wherein the glass is ion exchanged to a depth of layer of at least about 30 μm.12. The alkali aluminosilicate glass of claim 10 , wherein the alkali aluminosilicate glass has a compressive layer extending from a surface of the glass to the depth of layer claim 10 , and wherein the compressive layer is under a compressive stress of at least about 300 MPa.13. The alkali aluminosilicate glass of claim 12 , wherein the compressive stress is at least about 500 MPa.14. The alkali aluminosilicate glass of claim 10 , wherein the ion exchanged alkali aluminosilicate glass has a Vickers ...

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20-06-2013 дата публикации

IONICALLY CONDUCTIVE MATERIAL AND PROCESS FOR PRODUCING SAME

Номер: US20130157172A1
Принадлежит:

Provided is an ion-conducting material, comprising, as a composition in terms of mol o, 15 to 80% of PO, 0 to 70% of SiO, and 5 to 35% of RO, which represents the total content of LiO, NaO, KO, RbO, CsO, and AgO. 1. An ion-conducting material , comprising , as a composition in terms of mol % , 15 to 80% of PO , 0 to 70% of SiO , and 5 to 35% of RO , which represents a total content of LiO , NaO , KO , RbO , CsO , and AgO.2. The ion-conducting material according to claim 1 , wherein RO comprises at least two or more kinds of components among LiO claim 1 , NaO claim 1 , KO claim 1 , RbO claim 1 , CsO claim 1 , and AgO.3. The ion-conducting material according to claim 1 , wherein a content of POis 15 to 60% and a content of SiOis 10 to 60%.4. The ion-conducting material according to claim 1 , wherein the ion-conducting material has a molar ratio of (NaO+KO)/RO of 0.2 to 1.0.5. The ion-conducting material according to claim 1 , wherein the ion-conducting material has a molar ratio of NaO/RO of 0.2 to 0.8.6. The ion-conducting material according to claim 1 , wherein the ion-conducting material has a molar ratio of KO/RO of 0.2 to 0.8.7. The ion-conducting material according to claim 1 , further comprising 0.1 mol % or more of AlOin the composition.8. The ion-conducting material according to claim 1 , wherein the ion-conducting material has an ionic conductivity logσ (S/cm) at 500° C. of −5.5 or more and has a transport number of a proton at 500° C. of 0.7 or more.9. The ion-conducting material according to claim 1 , wherein the ion-conducting material has an areal resistance value (Ω.cm) at 500° C. of 30 or less.10. The ion-conducting material according to claim 1 , wherein the ion-conducting material is an amorphous material with a crystallinity of 50% or less.11. The ion-conducting material according to claim 1 , wherein the ion-conducting material has a thin-sheet shape and has a thickness of 1 to 500 μm.12. The ion-conducting material according to claim 1 , wherein ...

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04-07-2013 дата публикации

OPTICAL GLASS

Номер: US20130172168A1
Автор: Sato Fumio
Принадлежит: NIPPON ELECTRIC GLASS CO., LTD.

Provided is an optical glass that has desired optical properties, superior resistance to devitrification, and superior mass productivity. An optical glass is made of a SiO—NbO—TiO-based glass having a refractive index (nd) of 1.75 to 1.95 and an Abbe's number (νd) of 15 to 35 and has an operation temperature range (ΔT=(temperature at 10poise)−(liquidus temperature)) of 20° C. or more. The optical glass preferably contains, in percent by mass, 15% to 45% SiO, 15% to 40% (but excluding 40%) NbOand % to 30% TiOas glass components. 1. An optical glass made of a SiO—NbO—TiO-based glass having a refractive index (nd) of 1.75 to 1.95 and an Abbe's number (νd) of 15 to 35 , the optical glass having an operation temperature range (ΔT=(temperature at 100.5 poise)−(liquidus temperature)) of 20° C. or more.2. The optical glass according to claim 1 , containing claim 1 , in percent by mass claim 1 , 15% to 45% SiO claim 1 , 15% to 40% (but excluding 40%) NbOand 1% to 30% TiOas glass components.3. The optical glass according to claim 2 , further containing claim 2 , in percent by mass claim 2 , 0% to 15% LiO and 0% to 20% NaO as glass components.4. The optical glass according to claim 2 , further containing claim 2 , in percent by mass claim 2 , 0% to 2% KO claim 2 , 0% to 20% (but excluding 20%) RO (where R represents Li claim 2 , Na or K) claim 2 , and 0% to 2% R′O (where R′ represents Mg claim 2 , Ca claim 2 , Sr or Ba) as glass components and being substantially free of PbO claim 2 , AsO claim 2 , CsO claim 2 , GeO claim 2 , and BiO.5. An optical glass containing claim 2 , in percent by mass claim 2 , 15% to 45% SiO claim 2 , 15% to 40% (but excluding 40%) NbO claim 2 , 1% to 30% TiO claim 2 , 0% to 15% LiO claim 2 , 0% to 20% NaO claim 2 , 0% to 2% KO claim 2 , 0% to 20% (but excluding 20%) RO (where R represents Li claim 2 , Na or K) claim 2 , and 0% to 2% R′O (where R′ represents Mg claim 2 , Ca claim 2 , Sr or Ba) as glass components and being substantially free of PbO ...

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05-09-2013 дата публикации

HIGH-REFRACTIVE-INDEX GLASS

Номер: US20130230692A1
Принадлежит:

Provided is a high refractive index glass, comprising, as a glass composition in terms of mass %, 0.1 to 60% of SiO+AlO+BO, having a mass ratio (BaO+LaO+NbO+TiO+ZrO)/(SiO+AlO+BO) of 0.1 to 50, amass ratio (MgO+CaO+SrO+BaO)/(BaO+LaO+NbO+TiO+ZrO) of 0 to 10, and a mass ratio (TiO+ZrO)/(BaO+LaO+NbO) of 0.001 to 40, and having a refractive index nd of 1.55 to 2.3. 1. A high refractive index glass , comprising , as a glass composition in terms of mass % , 0.1 to 60% of SiO+AlO+BO , having a mass ratio (BaO+LaO+NbO+TiO+ZrO)/(SiO+AlO+BO) of 0.1 to 50 , a mass ratio (MgO+CaO+SrO+BaO)/(BaO+LaO+NbO+TiO+ZrO) of 0 to 10 , and a mass ratio (TiO+ZrO)/(BaO+LaO+NbO) of 0.001 to 40 , and having a refractive index nd of 1.55 to 2.3.2. The high refractive index glass according to claim 1 , wherein the high refractive index glass has a liquidus viscosity of 10dPa·s or more.3. The high refractive index glass according to claim 1 , wherein the high refractive index glass has a sheet shape.4. The high refractive index glass according to claim 3 , wherein the high refractive index glass is formed by one of an overflow down-draw method and a slot down-draw method.5. The high refractive index glass according to claim 3 , wherein the high refractive index glass comprises at least one unpolished surface claim 3 , the unpolished surface having a surface roughness Ra of 10 Å or less.611-. (canceled)12. A high refractive index glass claim 3 , comprising claim 3 , as a glass composition in terms of mass % claim 3 , 10 to 60% of SiO claim 3 , 0 to 5% of BO claim 3 , 0.1 to 60% of BaO claim 3 , 0.1 to 40% of LaO+NbO claim 3 , and 0 to 10% of LiO+NaO+KO claim 3 , having a value for a mass ratio (MgO+CaO)/(SrO+BaO) of 0 to 0.5 claim 3 , and having a strain point of 600° C. or more and a refractive index nd of 1.55 to 2.3.13. The high refractive index glass according to claim 12 , wherein the high refractive index glass has a liquidus viscosity of 10dPa·s or more.14. The high refractive index glass ...

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19-12-2013 дата публикации

OPTICAL GLASS, GLASS MATERIAL FOR PRESS MOLDING, OPTICAL ELEMENT, AND METHOD OF MANUFACTURING SAME

Номер: US20130337992A1
Принадлежит:

A method of making a press-moldable glass, including melting starting materials, forming a melt, and annealing a formed glass, wherein the melt has a composition such that, (1) when rapidly cooled to room temperature, it becomes glass that has a scattering coefficient of less than 0.005 cm-1 at wavelengths of from 400 to 2,500 nm or comprises crystals with a volumetric ratio of less than 10-6, and (2) when maintained for three hours at a temperature 10° C. higher than the glass transition temperature, maintained for 10 min at a temperature yielding a viscosity of 104.5 to 103.5 dPa·s, and then rapidly cooled to room temperature, (3) the resulting glass has (a) a scattering coefficient of at least one wavelength from 400 to 2,500 nm of greater than 0.01 cm-1 or (b) crystals with a volumetric ratio of greater than 10-5. A temperature for annealing is lower than for glass transition. 1. An optical glass , which comprises essential components in the form of SiO , BaO , and TiO; and exhibits a refractive index (nd) greater than or equal to 1.80 and an Abbé number (vd) less than or equal to 30 , wherein the number density of the crystal particles precipitating out after being maintained for five hours at a temperature 20° C. higher than the glass transition temperature and then for five minutes at 900° C. is less than or equal to 12/mm.2. The optical glass according to claim 1 , which comprises claim 1 , expressed as weight percentages claim 1 , greater than or equal to 24 percent and less than 30 percent of SiO claim 1 , greater than or equal to 12 percent and less than 23 percent of BaO claim 1 , and 22 to 37 percent of TiO.3. The optical glass according to claim 1 , wherein the weight ratio SiO/TiOof SiOto TiOexceeds 0.86.4. The optical glass according to claim 1 , which comprises claim 1 , expressed as weight percentages claim 1 , 10.50 to 20 percent of NaO.5. The optical glass according to claim 1 , which comprises claim 1 , expressed as weight percentages claim 1 , ...

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02-01-2014 дата публикации

Glass-ceramic substrates for semiconductor processing

Номер: US20140001485A1
Принадлежит: Corning Inc

Embodiments are directed to glass-ceramic substrates with a III-V semiconductor layer, for example, a GaN layer that can be used in LED lighting devices. The glass-ceramics material is in the anorthite-rutile (CaAl 2 Si 2 O 8 +TiO 2 ) family or in the cordierite-enstatite (SiO 2 —Al 2 O 3 —MgO—TiO 2 ) family.

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10-01-2019 дата публикации

Fluorinated Tin-Based Glass Frit And Method For Manufacturing Same

Номер: US20190010080A1
Принадлежит:

Provided is a super low melting SnO—SnF2—P2O5-based glass frit for which the firing temperature can be set to 200° C. or less and which has high water resistance and transparency. The fluorinated tin-based glass frit includes, in mol %, 30 to 70% of SnF2, 10 to 30% of P2O5, 10 to 40% of SnO, 0.1 to 10% of SnO2, 0 to 5% of In2O3, 0 to 5% of B2O3, and 0 to 5% of SiO2, and has a glass transition point of 160° C. or lower, a softening point of 180° C. or lower, and a maximum particle size of 100 μm or less. The fluorinated tin-based glass frit has a visible light transmission rate of 80% or more at 200° C. and a thickness of 0.6 mm of a fired product thereof, and a rate of volume reduction of the fired product due to soaking in hot water at 85° C. for 24 hours is 2 vol. % or less. 1. A fluorinated tin-based glass frit including , in mol % , 30 to 70% of SnF2 , 10 to 30% of P2O5 , 10 to 40% of SnO , 0.1 to 10% of SnO2 , 0 to 5% of In2O3 , 0 to 5% of B2O3 , and 0 to 5% of SiO2 , and having a glass transition point of 160° C. or lower , a softening point of 180° C. or lower , and a maximum particle size of 100 μm or less , and with which a visible light transmission rate of a fired product obtained at 200° C. is 80% or more at a thickness of 0.6 mm and a rate of volume reduction of the fired product due to soaking in hot water at 85° C. for 24 hours is 2 vol. % or less.2. The fluorinated tin-based glass frit according to claim 1 , including claim 1 , in mol % claim 1 , 40 to 65% of SnF2 claim 1 , 15 to 30% of P2O5 claim 1 , 15 to 40% of SnO claim 1 , 0.1 to 2% of SnO2 claim 1 , 0 to 5% of In2O3 claim 1 , 0 to 5% of B2O3 claim 1 , and 0 to 5% of SiO2.3. A method for manufacturing a fluorinated tin-based glass frit comprising the steps of mixing a glass raw material powder claim 1 , which includes claim 1 , in mol % claim 1 , 30 to 70% of SnF2 claim 1 , 10 to 30% of P2O5 claim 1 , 10 to 40% of SnO claim 1 , 0.1 to 10% of SnO2 claim 1 , 0 to 5% of In2O3 claim 1 , 0 to 5% of ...

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09-01-2020 дата публикации

Highly stable and chemically temperable glasses

Номер: US20200010354A1
Принадлежит: SCHOTT AG

Glasses and glass products which combine the chemical temperability with very good alkali and acid resistance, hydrolytic resistance, as well as a desired coefficient of thermal expansion are provided. The glass has a composition characterized by the following constituent phases: a composition characterized by the following constituent phases: 20-60 mol % albite; 0-40 mol % silicon dioxide; 0-20 mol % orthoclase; 0-10 mol % wollastonite; 0-20 mol % enstatite; 0-20 mol % parakeldyshite; 0-20 mol % narsarsukite; 0-40 mol % disodium zinc silicate; 0-20 mol % cordierite; 0-10 mol % strontium silicate; and 0-10 mol % barium silicate.

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12-01-2017 дата публикации

METHOD OF PREPARING SOLID ELECTROLYTE COMPOSITION FOR LITHIUM SECONDARY BATTERY

Номер: US20170012318A1
Принадлежит:

Disclosed is a method of preparing a solid electrolyte composition for a lithium secondary battery which includes: (a) mixing materials including LiO, SiO, TiO, PO, BaO, CsO and VO; (b) melting the mixed materials; (c) rapidly cooling the molten materials at room temperature and compressing the molten materials using a preheated plate to form electrolyte glass having a predetermined thickness; (d) heating the electrolyte glass to eliminate stress at a predetermined temperature range; (e) heating the electrolyte glass to a higher temperature range higher than in the step of heating the electrolyte glass to eliminate stress to be crystallized; and (f) precisely adjusting a thickness of the electrolyte glass by lapping the electrolyte glass. 1. A method of preparing a solid electrolyte composition for a lithium secondary battery , comprising:{'sub': 2', '2', '2', '2', '5', '2', '2', '5, '(a) mixing materials including LiO, SiO, TiO, PO, BaO, CsO and VO;'}(b) melting the mixed materials;(c) rapidly cooling the molten materials at room temperature and compressing the molten materials using a preheated plate to form electrolyte glass;(d) heating the electrolyte glass to eliminate stress at 500 to 600° C.;(e) heating the electrolyte glass to a temperature range higher than in the step of heating the electrolyte glass to eliminate stress to be crystallized; and(f) precisely adjusting a thickness of the electrolyte glass by lapping the electrolyte glass.2. The method of claim 1 , wherein 5 to 8 wt % of LiO claim 1 , 2 to 5 wt % of SiO claim 1 , 30 to 35 wt % of TiO claim 1 , 56 to 60 wt % of PO claim 1 , 0.1 to 2 wt % of BaO claim 1 , 0.1 to 2 wt % of CsO and 0.5 to 2 wt % of VOare mixed in the step (a).3. The method of claim 1 , wherein the mixed materials are introduced into a platinum crucible and are heated at a rate of 10° C./min to become molten in an air atmosphere at a temperature of 1300 to 1450° C. in the step (b).4. The method of claim 1 , wherein the molten ...

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17-04-2014 дата публикации

OPTICAL GLASS, PRESS-MOLDING GLASS MATERIAL, OPTICAL ELEMENT AND METHOD OF MANUFACTURING THE SAME, AND BONDED OPTICAL ELEMENT

Номер: US20140106174A1
Принадлежит: HOYA CORPORATION

An aspect of the present invention relates to an optical glass, which comprises, denoted as weight percent, 2 to 37 percent of SiO, 0 to 25 percent of BO, 0 to 10 percent of GeO, 18 to 55 percent of a combined content of LiO, NaO, KO, CaO, SrO, and BaO, and 27 to 55 percent of a combined content of TiO, NbO, and WO, wherein the weight ratio of SiOcontent relative to a combined content of SiOand BOranges from 0.1 to 1, a weight ratio of the LiO content to a combined content of LiO, NaO, KO, CaO, SrO, and BaO ranges from 0 to 0.4, and a weight ratio of TiOcontent relative to a combined content of TiO, NbO, and WOranges from 0.35 to 1, with a refractive index nd of 1.860 to 1.990 and an Abbé number νd of 21 to 29. 1. An optical glass , which comprises , denoted as weight percent ,{'sub': '2', '2 to 37 percent of SiO,'}{'sub': 2', '3, '0 to 25 percent of BO,'}{'sub': '2', '0 to 10 percent of GeO,'}{'sub': 2', '2', '2, '18 to 55 percent of a combined content of LiO, NaO, KO, CaO, SrO, and BaO,'}{'sub': 2', '2', '5', '3, '33.78 to 55 percent of a combined content of TiO, NbO, and WO, and'}{'sub': 2', '3, '0 to 15 percent of LaO;'}{'sub': 2', '2', '2', '3', '2', '2', '2', '3, 'wherein the weight ratio of SiOcontent relative to a combined content of SiOand BO(SiO/(SiO+BO) ranges from 0.1 to 1;'}{'sub': 2', '2', '2', '2', '2', '2', '2', '2, 'a weight ratio of the LiO content to a combined content of LiO, NaO, KO, CaO, SrO, and BaO (LiO/(LiO+NaO+KO+CaO+SrO+BaO) ranges from 0 to 0.4; and'}{'sub': 2', '2', '2', '5', '3', '2', '2', '2', '5', '3, 'a weight ratio of TiOcontent relative to a combined content of TiO, NbO, and WO(TiO/(TiO+NbO+WO) ranges from 0.35 to 1; and'}which has a refractive index nd ranging from 1.860 to 1.990 and an Abbé number νd ranging from 21 to 29.2. The optical glass according to claim 1 , wherein a difference (Tx−Tg) between a peak crystallization temperature Tx and a glass transition temperature Tg is equal to or greater than 120° C.3. The optical ...

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25-01-2018 дата публикации

Ion exchangeable glass with high crack initiation threshold

Номер: US20180022637A1
Автор: Timothy Michael Gross
Принадлежит: Corning Inc

Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P 2 O 5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.

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25-01-2018 дата публикации

Vanadium-based frit materials, and/or methods of making the same

Номер: US20180022639A1
Автор: Timothy A. Dennis
Принадлежит: Guardian Glass LLC

Certain example embodiments relate to improved seals for glass articles. Certain example embodiments relate to a composition used for sealing an insulted glass unit. In certain example embodiments the composition includes vanadium oxide, barium oxide, zinc oxide, and at least one additional additive. For instance, another additive that is a different metal oxide or different metal chloride may be provided. In certain example embodiments, a vacuum insulated glass unit includes first and second glass substrates that are sealed together with a seal that includes the above-described composition.

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10-02-2022 дата публикации

MINERAL FIBER COMPOSITIONS HAVING ENHANCED BIOPERSISTENT PROPERTIES AND METHODS FOR MAKING AND USING THE SAME

Номер: US20220041494A1
Принадлежит:

Described herein are mineral fiber compositions having enhanced characteristics, such as biopersistence and resistance to heat induced shrinkage. Also described are methods for making and using the same. Such compositions may comprise manganese oxide and aluminum oxide. 1. A composition comprising mineral fibers wherein: manganese oxide; and', 'aluminum oxide;, 'the mineral fibers comprise;'}wherein the manganese oxide is present in an amount from about 7 to about 10%, based on the total weight of the mineral fiber.2. The composition according to claim 1 , wherein the aluminum oxide is present in an amount greater than about 17% claim 1 , based on the total weight of the mineral fiber.3. The composition according to claim 1 , wherein the aluminum oxide is present in an amount between 17.5% to 21.0% claim 1 , based on the total weight of the mineral fiber.4. The composition according to claim 1 , wherein the mineral fiber comprises SiOpresent in an amount between 35.0% to 41.0% claim 1 , based on the total weight of the mineral fiber.5. The composition according to claim 1 , wherein the mineral fiber comprises FeOT present in an amount between 0.20% to 2.00% claim 1 , based on the total weight of the mineral fiber.6. The composition according to claim 1 , wherein the mineral fiber comprises MgO present in an amount between 5% to 9% claim 1 , based on the total weight of the mineral fiber.7. The composition according to claim 1 , wherein the mineral fiber comprises CaO present in an amount between 18% to 25% claim 1 , based on the total weight of the mineral fiber.8. The composition according to claim 1 , wherein the mineral fiber comprises KO present in an amount between 1.0% to 2.0% claim 1 , based on the total weight of the mineral fiber.9. The composition according to claim 1 , wherein the mineral fiber comprises about 40 wt. % of SiOand about 18.9 wt. % of AlO.10. The composition according to claim 9 , wherein the mineral fiber further comprises about 8.65 wt. % ...

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31-01-2019 дата публикации

LITHIUM-RICH METALLURGICAL SLAG

Номер: US20190032171A1
Принадлежит:

The present invention concerns a slag composition having a high lithium content, suitable as additive in the manufacture of end-user products, or for the economic recovery of the contained lithium. 17-. (canceled)8. A LiO bearing metallurgical slag comprising AlO , SiO , CaO , and MnO , wherein the by-weight composition is as follows:{'sub': '2', '3% Подробнее

31-01-2019 дата публикации

VANADIUM-BASED FRIT MATERIALS, BINDERS, AND/OR SOLVENTS AND/OR METHODS OF MAKING THE SAME

Номер: US20190032394A1
Автор: Dennis Timothy A.
Принадлежит:

Certain example embodiments relate to seals for glass articles. Certain example embodiments relate to a composition used for sealing an insulted glass unit. In certain example embodiments the composition includes vanadium oxide, barium oxide, zinc oxide, and at least one additional additive. For instance, another additive that is a different metal oxide or different metal chloride may be provided. In certain example embodiments, a composition may be combined with a binder solution that substantially or completely burns out by the time the composition is melted. In certain example embodiments, a vacuum insulated glass unit includes first and second glass substrates that are sealed together with a seal that included the above-described composition. 130-. (canceled)32. The method of claim 31 , further comprising evacuating the gap between the first and second glass substrates to a pressure less than atmospheric pressure after a seal has been formed via at least said frit material. This application is a continuation-in-part of U.S. application Ser. No. 13/238,358, filed Sep. 21, 2011, which is a continuation-in-part of U.S. application Ser. No. 12/929,875, filed Feb. 22, 2011, the entire contents of which are each hereby incorporated by reference.Certain example embodiments of this invention relate to improved frit materials for glass articles (e.g., for use in vacuum insulted glass or VIG units), and/or methods of making the same, as well as articles including such improved frit materials and/or methods of making the same. More particularly, certain example embodiments relate to binders used in vanadium-based frit materials. In certain example embodiments, improved insulted seals created with the frit materials are used in connection with vacuum insulted glass (VIG) units, and/or a method is provided for sealing VIG units with the improved seals.Vacuum IG units are known in the art. For example, see U.S. Pat. Nos. 5,664,395, 5,657,607, and 5,902,652, the disclosures of ...

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04-02-2021 дата публикации

GLASS COMPOSITION AND GLASS POWDER, IN PARTICULAR FOR THE USE IN THE DENTAL FIELD

Номер: US20210032154A1
Принадлежит:

The present disclosure relates to a glass composition as well as a glass powder. The disclosure also relates to the use in the dental field, e.g. as dental material such as dental filling or dental restauration material, in particular as or for the production of a glass ionomer cement, for example for the treatment and/or for the filling of cavities in human and/or animal teeth and/or for tooth restoration. 5. The glass according to claim 1 , wherein the component 1 comprises SiOand POand wherein the component 2 comprises AlO.7. The glass according to claim 1 , wherein the ratio of the proportion by weight of AlOto the proportion by weight of SiOis in a range of 0.9:1 to 1.15:1.8. The glass according to claim 1 , wherein the glass contains at least one X-ray absorbing component selected from the group consisting of YO claim 1 , YbO claim 1 , LaO claim 1 , SrO claim 1 , BaO and CsO in a proportion of in total at least 0.1% by weight.9. The glass according to claim 1 , wherein the ratio of the proportion by weight of the component 2 to the proportion by weight of the component 1 is in a range of 1.0:1 to 1.6:1.10. The glass according to claim 1 , wherein the ratio of the proportion by weight of the component 2 to the proportion by weight of the component 3 is in a range of 1.0:1 to 6.5:1.11. The glass according to claim 1 , wherein the ratio of the proportion by weight of the component 1 to the proportion by weight of the component 3 is in a range of 0.8:1 to 4.5:1.12. The glass according to claim 1 , wherein the glass has a refractive index of from 1.43 to 1.55.13. A glass powder comprising particles of glass powder claim 1 , wherein the particles of glass powder comprise the glass according to claim 1 , and wherein the particle size of the glass powder claim 1 , when specified as d50 value claim 1 , is in a range of 0.2 μm to 20 μm.14. A method of making a glass ionomer cement claim 1 , comprising the step of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'mixing ...

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04-02-2016 дата публикации

FEEDTHROUGH

Номер: US20160036016A1
Принадлежит: SCHOTT AG

A feed-through includes at least one main body which has at least one opening through which at least one conductor in an electrically insulating material comprising or consisting of a sealing glass is fed, wherein the main body comprises or consists of a light metal and/or a light metal alloy, with an integral bond being formed between the light metal and/or the conductor and the sealing glass, wherein the sealing glass comprises or consists of a titanate glass and has only a small phosphate proportion. 1. A feedthrough for a storage device , comprising:at least one base body, wherein the base body has at least one opening, said base body one of including and consisting of at least one of a light metal and a light metal alloy;at least one conductor in an electrically insulated material one of comprising and consisting of a sealing glass fed through said at least one opening, said sealing glass being material bonded with at least one of said base body and said conductor, wherein said sealing glass one of includes and consists of titanium glass.2. The feedthrough according to claim 1 , wherein said conductor is a substantially pin-shaped conductor claim 1 , said light metal is one of aluminum claim 1 , magnesium claim 1 , and titanium claim 1 , and said light metal alloy is one of an aluminum alloy claim 1 , a magnesium alloy claim 1 , a titanium alloy claim 1 , and AlSiC.3. The feedthrough according to claim 2 , wherein said substantially pin-shaped conductor one of includes and consists of a light metal claim 2 , a light metal alloy claim 2 , aluminum claim 2 , an aluminum alloy claim 2 , copper claim 2 , CuSiC claim 2 , a copper alloy claim 2 , gold claim 2 , a gold alloy claim 2 , silver claim 2 , a silver alloy claim 2 , NiFe claim 2 , an NiFe-casing having a copper core claim 2 , and a cobalt-iron alloy.4. The feedthrough according to claim 1 , wherein said sealing glass is a titanate glass one of including and consisting of the following components in weight-% ...

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05-02-2015 дата публикации

Direct Smelting Process

Номер: US20150038317A1
Принадлежит:

A molten bath-based direct smilting process comprises controlling the process conditions in a direct smelting vessel so that molten slag in a molten bath of metal and slag in the vessel has a viscosity in a range of 0.5-5 poise when the slag temperature is in the range of 1400-1550° C. in the molten bath in the vessel. 1. A molten iron product of a direct smelter , the molten iron product comprising molten iron and vanadium and wherein the vanadium comprises at least 50% of the vanadium output from the direct smelter.2. The molten iron product defined in claim 1 , wherein the vanadium in the molten iron product comprises at least 65% of the vanadium output from the direct smelter.3. The molten iron product defined in claim 1 , wherein the vanadium in the molten iron product comprises at least 80% of the total vanadium supplied to the smelter as part of a metalliferous feed material.4. A slag product of a direct smelter claim 1 , the slag product comprising molten slag that includes:{'sub': '2', 'TiO: at least 15 wt. %,'}{'sub': '2', 'SiO: at least 15 to 20 wt. %,'}CaO: at least 15 to 30 wt. %,{'sub': 2', '3, 'AlO: at least 10 to 20 wt. %,'}FeO: at least 3 to 10 wt. %, andvanadium oxide comprising up to 50% of the vanadium output from the direct smelter.5. The slag product defined in claim 4 , wherein the vanadium in the slag product comprises up to 35% of the vanadium output from the direct smelter.6. The slag product defined in claim 4 , wherein the vanadium in the slag product comprises up to 20% of the vanadium output from the direct smelter as part of a metalliferous feed material.7. The slag product defined in claim 4 , wherein the molten slag further comprises a carbon content of 3 to 5 wt. %.8. The slag product defined in claim 4 , wherein the molten slag comprises at least 20 wt. % TiO.9. The slag product defined in claim 4 , wherein the molten slag comprises at least 50 wt. % TiO.10. The slag product defined in claim 4 , wherein the molten slag further ...

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18-02-2021 дата публикации

ANTIBACTERIAL GLASS COMPOSITION AND METHOD FOR PREPARING SAME

Номер: US20210047232A1
Принадлежит:

The present invention relates to: an antibacterial glass composition which has antibacterial properties not only in an acidic environment but also in a non-acidic environment, by controlling water resistance; and a method for preparing same. The antibacterial glass composition according to the present invention includes: at least one of PO, SiO, and BO; and MoO, wherein 30 to 80 wt % of the at least one of PO, SiO, and BOis included to control water resistance, thereby providing the antibacterial glass composition which has antibacterial properties not only in an acidic environment but also in a non-acidic environment, and a method for preparing same. 1. An antibacterial glass composition , comprising:{'sub': 2', '5', '2', '2', '3, 'at least one of PO, SiO, or BO; and'}{'sub': '3', 'MoO,'}{'sub': 2', '5', '2', '2', '3, 'wherein the at least one of PO, SiO, or BOcomprises 30 to 80% by weight.'}2. The antibacterial glass composition of claim 1 , comprising:{'sub': 2', '5, '30 to 50% by weight of the PO; and'}{'sub': '3', '3 to 40% by weight of the MoO.'}3. The antibacterial glass composition of claim 2 , comprising 20 to 40% by weight of the MoO.4. The antibacterial glass composition of claim 1 , further comprising at least one of ZnO or CuO.5. The antibacterial glass composition of claim 4 , comprising 1 to 30% by weight of the at least one of ZnO or CuO.6. The antibacterial glass composition of claim 1 , further comprising 1 to 40% by weight of at least one of LiO claim 1 , NaO claim 1 , or KO.7. The antibacterial glass composition of claim 1 , further comprising 1 to 10% by weight of AlO.8. The antibacterial glass composition of claim 3 , comprising:{'sub': 2', '5, '30 to 40% by weight of the PO;'}{'sub': '2', '20 to 30% by weight of the SiO; and'}{'sub': '3', '30 to 40% by weight of the MoO.'}9. A method for preparing an antibacterial glass composition claim 3 , comprising:{'sub': 2', '5', '2', '2', '3', '3, 'preparing materials for antibacterial glass composition ...

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18-02-2016 дата публикации

NANOSTRUCTURED GLASSES AND VITROCERAMICS THAT ARE TRANSPARENT IN VISIBLE AND INFRA-RED RANGES

Номер: US20160046520A1

The present invention relates to novel vitroceramic or lens compositions that are nanostructured and transparent or translucent, including at least 97%, such as 97% to 100%, preferably 99% to 100%, by weight, relative to the total weight of the material, of a composition having the following formula I: (GeO)(SiO)(BO)(GaO)(Oxy)(Oxy)(I) where Oxyis an oxide selected from ZnO, MgO, NbO, WO, NiO, SnO, TiO, BiO, AgO, CaO, MnO, or a mixture thereof, selected preferably from ZnO, MgO, NbO, WO, NiO, SnO, AgO, CaO, MnO, or a mixture thereof, selected more preferably from ZnO, MgO, AgO, BiO, NbO, Or a mixture thereof, selected most preferably from ZnO, MgO, AgO, NbO, or a mixture thereof, and Oxyis an oxide selected from NaO, KO or a mixture thereof, Oxyis preferably NaO, and x, y, z, a, b and k are as defined in claim , to the manufacturing method thereof and to the uses thereof in the field of optics. 160-. (canceled)61. A nanostructured vitroceramic , either transparent or translucent , with essentially zero LiO content , containing 97% to 100% by weight in relation to the overall weight of the material , of a composition of the following formula I:{'br': None, 'sub': 2', 'x', '2', 'y', '2', '3', 'z', '2', '3', 'a', '1', 'b', '2', 'k, '(GeO)(SiO)(BO)(GaO)(Oxy)(Oxy)\u2003\u2003(I)'}where{'sub': 1', '2.5', '3', '2', '1.5, 'Oxyis an oxide selected from among ZnO, MgO, NbO, WO, NiO, SnO, TiO, BiO, AgO, CaO, MnO, or a mixture thereof, and'}{'sub': 2', '2', '2, 'Oxyis an oxide selected from NaO, KO, or a mixture thereof, and'}x is within the range between 0 and 98, andy is within the range between 0 and 60, andx and y are not simultaneously zero, andz is within the range between 0 and 20,x, y, z are such that x+y+z lie within the range between 40 and 98,a is within the range between 0.1 and 50,b is within the range between 0 and 35, andk is within the range between 0 and 7, andx, y, z, a, b and k are such that x+y+z+a+b+k=100.62. Nanostructured glass , either transparent or ...

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16-02-2017 дата публикации

LASER WELDING OF HIGH THERMAL EXPANSION GLASSES AND GLASS-CERAMICS

Номер: US20170047542A1
Принадлежит: CORNING INCORPORATED

Disclosed herein are methods for welding a first substrate and a second substrate, the method comprising bringing the first and second substrates into contact to form a substrate interface, and directing a laser beam operating at a predetermined wavelength through the second substrate onto the substrate interface, wherein the first substrate absorbs light from the laser beam in an amount sufficient to form a weld between the first substrate and the second substrate. The disclosure also relates to glass and/or glass-ceramic packaging and OLED display produced according to the methods disclosed herein. 1. A method for welding a first and second substrate comprising:(a) bringing the first and second substrates into contact to form a substrate interface;(b) directing a laser beam operating at a predetermined wavelength through the second substrate onto the substrate interface;wherein the first substrate absorbs light from the laser beam in an amount sufficient to form a weld between the first substrate and the second substrate;{'sup': −1', '−1, 'wherein the first substrate has an absorption at the predetermined wavelength of greater than about 10 cmand the second substrate has an absorption at the predetermined wavelength of less than about 1 cm; and'}wherein at least one of the first and second substrates has a coefficient of thermal expansion greater than about 5 ppm/° C.2. The method of claim 1 , wherein the first and/or second substrates are chosen from glasses claim 1 , ceramics claim 1 , and glass-ceramics.3. The method of claim 2 , wherein the first and/or second substrates are chosen from soda-lime silicate claim 2 , aluminosilicate claim 2 , alkali-aluminosilicate claim 2 , borosilicate claim 2 , alkali-borosilicate claim 2 , aluminoborosilicate claim 2 , and alkali-aluminoborosilicate glasses and glass-ceramics.4. The method of claim 1 , wherein the first and/or second substrates are chosen from pre-stressed laminates and chemically strengthened and/or ...

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25-02-2016 дата публикации

CHLORINE-CONTAINING SILICATE GLASSES AND GLASS CERAMICS

Номер: US20160051457A1
Принадлежит:

A chlorine-containing silicate glass comprising SiO, at least 0.5 mole percent metal chloride and at least 10 mole percent of MgO, SrO, BaO, and CaO combined. 1. A chlorine-containing silicate glass comprising SiO , at least 0.5 mole percent metal chloride and at least 10 mole percent of MgO , SrO , BaO , and CaO combined.2. A glass according to claim 1 , wherein the glass comprises less than 1 mole percent AlO claim 1 , and the ratio of non-bridging oxygens to bridging oxygens is between 0.7 and 1.5.3. A glass according to claim 1 , wherein the glass comprises less than 1 mole percent AlO claim 1 , the glass having a network connectivity (NC) which is in the range 2 to 3.4. A glass according to claim 1 , wherein the glass comprises at least 1 mole percent metal chloride.5. A glass according to claim 1 , wherein the glass comprises up to 50 mole percent metal chloride.6. A glass according to claim 1 , wherein the glass comprises up to 60 mole percent of MgO claim 1 , SrO claim 1 , BaO claim 1 , and CaO combined.7. A glass according to claim 1 , wherein the glass comprises either CaO claim 1 , SrO or BaO and a source of phosphate.8. A glass according to claim 7 , wherein the glass comprises at least 20 mole percent combined of CaO and SrO.9. A glass according to claim 1 , wherein the glass comprises a fluoride.10. A glass according to claim 1 , wherein the glass comprises at least 20 mole percent SiO.11. A glass according to claim 1 , wherein the glass comprises up to 60 mole percent SiO.12. A glass according to claim 1 , wherein the glass comprises at least 2 mole percent PO.13. A glass according to claim 1 , wherein the glass comprises up to 20 mole percent PO.14. A glass according to claim 1 , wherein the glass comprises at least 1 mole percent AlO claim 1 , and 8 to 60 mole percent of alkaline earth oxide and alkaline earth chloride or fluoride combined claim 1 , the glass comprising at least 2 mole percent metal chloride and metal fluoride combined.15. A glass ...

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25-02-2016 дата публикации

Glass frit

Номер: US20160052820A1
Принадлежит: Namics Corp

A glass frit having a low melting point containing (A) Ag 2 O, (B) V 2 O 5 , and (C) at least one first oxide selected from the group consisting of MoO 3 , ZnO, CuO, TiO 2 , Bi 2 O 3 , MnO 2 , MgO, Nb 2 O 5 , BaO and P 2 O 5 . The glass frit preferably contains 40 to 70% by mass of (A), 10 to 40% by mass of (B), and 0.5 to 30% by mass of (C) with respect to the total mass in terms of oxides. Furthermore, the glass frit preferably has a mass ratio (Ag 2 O/V 2 O 5 ) of (A) to (B) of 1.8 to 3.2.

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25-02-2021 дата публикации

Infrared transmitting glass

Номер: US20210053866A1
Принадлежит: Nippon Electric Glass Co Ltd

Provided is a glass having an excellent infrared transmittance and suitable for use in infrared sensors. An infrared transmitting glass containing, in terms of % by mole, over 0 to 50% Ge, over 0 to 50% Ga, over 0 to 50% Si, 20 to 90% Te, 0 to 40% Ag+Al+Ti+Cu+In+Sn+Bi+Cr+Sb+Zn+Mn, and 0 to 40% F+Cl+Br+I.

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25-02-2021 дата публикации

CONSTRUCTION OF ELASTOMERIC BIOCOMPOSITE INTENDED FOR INSULATING LAYERS AND PADS WITH REGARD TO FLEXIBLE ANTENNA

Номер: US20210054175A1

The disclosure relates to a composition of biocomposite based on natural rubber containing sol-bioglass, which is used and intended for insulating layers and pads in flexible antennas which can be worn in close vicinity with regard to the human body without adversely affecting it. According to the invention, the composition of the biocomposite intended and designed for insulating layers and pads in flexible antennas based on natural rubber is filled with sol-gel derived bioglass amounting to a quantitative range starting from 8 to 50 parts by weight with regard to 100 parts by weight rubber and having following list of remaining ingredients: zinc oxide from 2.5 to 3.5, stearic acid from 1 to 2.5, bis (triethoxysilylpropyl) tetrasulfide from 4 to 6, tertiary butyl-benzothiazolyl sulfenamide from 1 to 2.5, sulfur from 1 to 3 and isopropyl-phenyl-β-phenylene diamine from 0.5 to 1.5. 1. A composition of an elastomeric biocomposite designed for insulating layers and pads with regard to flexible antennas containing rubber , zinc oxide , stearic acid , isopropyl-phenyl-p-phenylenediamine , wherein the rubber comprises natural rubber , the filler is sol-gel derived and the ingredients of 100 weight parts natural rubber parts constitute: sol-gel derived glass from 8 to 50 , zinc oxide from 2.5 to 3.5 , stearic acid from 1 to 2.5 , bis (triethoxysilylpropyl) tetrasulfide from 4 to 6 , tertiary butyl-benzothiazolyl sulfenamide from 1 to 2.5 , sulfur from 1 to 3 and isopropyl-phenyl-β-phenylene diamine from 0.5 to 1.5.2. The composition according to data revealed within claim 1 , wherein the sol-gel glass contains CaO—49-51% claim 1 , SiO—39-41% claim 1 , PO—8% claim 1 , AgO—0.1-4%. The present invention relates to a biocomposite structure based on natural rubber containing sol-gel-derived Bioglass which is applicable with regard to insulating layers and pads in flexible antennas that can be worn and operated in close vicinity to the human body without causing adverse effects ...

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21-02-2019 дата публикации

Passivation Glasses For Semiconductor Devices

Номер: US20190055155A1
Принадлежит: Ferro Corp

A passivation glass coating composition is provided for forming a fired passivation glass layer on a semiconductor substrate having p-n junction. The passivation glass coating composition includes a glass component that is lead free, cadmium free, alkali metal oxides free, and colored transition metal oxides (i.e. metal oxides of V, Fe, Co, Ni, Cr, Cu, Mn) free. The glass component includes bismuth based glasses, and provides a firing temperature range of 500° C. to 900° C., and controlled devitrification. Once fired to a semiconductor device, the fired passivation glass layer provides exceptional device performance including no cracking of the fired passivation glass layer, excellent thermal expansion matching to silicon, good chemical resistance to acid and base, and improved device performance.

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20-02-2020 дата публикации

THERAPEUTIC MATERIAL

Номер: US20200054784A1
Автор: Martin Richard
Принадлежит: Aston University

A bioactive glass composition for use in treating bone cancer includes 0.5-10 mol % gallium oxide or 1.0-20 mol % gallium nitrate/halide; 25 to 75 mol % silicon dioxide; 10 to 30 mol % calcium oxide and/or strontium oxide; up to 30 mol % sodium oxide; and up to 15 mol % phosphorous pentoxide. It may further comprise magnesium and/or potassium oxide. The bioactive glass composition may be positioned within a patient's bone post-surgery to promote apatite formation and to release gallium ions having a toxic effect on any remaining cancerous cells. 149-. (canceled)50. A bioactive glass composition comprising:0.5-10 mol % gallium oxide or 1.0-20 mol % gallium nitrate/halide;35 to 55 mol % silicon dioxide;10 to 30 mol % calcium oxide and/or strontium oxide;up to 30 mol % sodium oxide; andup to 15 mol % phosphorous pentoxide.51. A bioactive glass composition according to comprising:1 to 30 mol % sodium oxide; and1 to 15 mol % phosphorous pentoxide.52. A bioactive glass composition according to comprising between 39.0 and 40.0 mol % silicon dioxide.53. A bioactive glass composition according to comprising between 28.0 and 29.0 mol % CaO.54. A bioactive glass composition according to comprising between 24.9 and 26.0 mol % sodium oxide.55. A bioactive glass composition according to comprising around 25.9 mol % sodium oxide.56. A bioactive glass composition according to comprising0.5-10 mol % gallium oxide or 1-20 mol % gallium nitrate/halide;{'sub': '2', '35.5-45.0 mol % SiO;'}27.0-30.0 mol % CaO;{'sub': '2', '24.5-27.0 mol % NaO; and'}{'sub': 2', '5, '2.7-2.8 mol % PO.'}57. A bioactive glass composition according to comprising1-5 mol % gallium oxide or 2-10 mol % gallium nitrate/halide;{'sub': '2', '38.0-42.0 mol % SiO;'}28.0-29.0 mol % CaO;{'sub': '2', '24.9-26.0 mol % NaO; and'}{'sub': 2', '5, '2.7-2.8 mol % PO.'}58. A bioactive glass composition according to further comprising magnesium oxide and/or potassium oxide.59. A bioactive glass composition according to ...

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05-03-2015 дата публикации

Lithium orthophosphate glasses, corresponding glass-ceramics and lithium ion-conducting nzp glass ceramics

Номер: US20150064576A1
Принадлежит: Corning Inc

A lithium-ion conductive glass-ceramic article has a crystalline component characterized by the formula MA 2 (XO 4 ) 3 , where M represents one or more monovalent or divalent cations selected from Li, Na and Zn, A represents one or more trivalent, tetravalent or pentavalent cations selected from Al, Cr, Fe, Ga, Si, Ti, Ge, V and Nb, and X represents P cations which may be partially substituted by B cations.

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28-02-2019 дата публикации

YOSHIOKAITE GLASS-CERAMICS OBTAINED FROM GLASS FRITS

Номер: US20190062218A1
Принадлежит:

A glass ceramic material is disclosed that includes a residual glass, and a crystalline phase that includes a yoshiokaite phase. The yoshiokaite phase constitutes a main crystalline phase of the glass ceramic material. A method for making a glass ceramic material is also disclosed that includes heat treating frit glass to form the glass ceramic material, wherein the frit glass comprises: SiOfrom 15 mol % to 37 mol %; AlOfrom 40 mol % to 47 mol %; and CaO from 20 mol % to 30 mol %; 1. A glass ceramic material , comprising:an amorphous glass phase; anda crystalline phase comprising a yoshiokaite phase,wherein the yoshiokaite phase constitutes a main crystalline phase of the glass ceramic material.2. The glass ceramic material of claim 1 , wherein the crystalline phase comprises one or more of an anorthite phase claim 1 , a gehlenite phase claim 1 , a nepheline phase claim 1 , and a cubic zirconia phase.3. The glass ceramic material of claim 1 , wherein the yoshiokaite phase comprises greater than or equal to 55 wt. % of the crystalline phase.4. The glass ceramic material of claim 1 , wherein the yoshiokaite phase comprises greater than or equal to 80 wt. % of the crystalline phase.5. The glass ceramic material of claim 1 , wherein the yoshiokaite phase comprises greater than or equal to 90 wt. % of the crystalline phase.6. The glass ceramic material of claim 1 , wherein the yoshiokaite phase comprises yoshiokaite crystals having an average crystal size from greater than or equal to 100 nm to less than or equal to 160 nm.7. The glass ceramic material of claim 1 , wherein the yoshiokaite phase comprises yoshiokaite crystals having an average crystal size from greater than or equal to 130 nm to less than or equal to 160 nm.8. The glass ceramic material of claim 1 , wherein the glass ceramic material is comprised of greater than or equal to 80 wt. % of the crystalline phase.9. The glass ceramic material of claim 1 , wherein the glass ceramic material is comprised of ...

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08-03-2018 дата публикации

OPTICAL GLASS AND OPTICAL ELEMENT

Номер: US20180065880A1
Автор: Yuan Wei
Принадлежит: CDGM GLASS CO., LTD.

The present invention provides a high refractivity and high dispersion optical glass and optical element with small relative partial dispersion (Pg,F), high transmittance and good chemical stability. For optical glass, with anion as O, wherein a cation thereof contains the following components by weight percentage: 12-25% of Si; 58-75% of Nb+W+Zr; 8-25% of Li+Na+K; 10% of Ba or less. Based on the reasonable component design, the refractive index of the optical glass is 1.81-1.89, the Abbe number is 20-29, Pg,F is 0.5956-0.6199, and the corresponding wave length λis below 450 nm when the transmittance reaches up to 70%. Therefore, the optical glass provided by the present invention is applicable to high-quality optical elements. 1. An optical glass , with anion as O , wherein a cation thereof contains the following components by weight percentage: 12-25% of Si; 58-75% of Nb+W+Zr; 8-25% of Li+Na+K; 10% of Ba or less.2. The optical glass according to claim 1 , further containing: 0-5% of B; 0-0.2% of Sb; 0-10% of Zn+Sr+Ca.3. The optical glass according to claim 1 , wherein (Ba/Nb) is 0.5 or less.4. The optical glass according to claim 1 , wherein Ti is excluded.5. The optical glass according to claim 1 , further containing: 12-23% of Si; and/or 60-72% of Nb+W+Zr; and/or 8-23% of Li+Na+K; and/or 0.5-8% of Ba; and/or 0-3% of B; and/or 0-0.1% of Sb; and/or 0.3 of (Ba/Nb) or less; and/or 0-8% of Zn+Sr+Ca.6. The optical glass according to claim 1 , further containing: 12-20% of Si; and/or 62-70% of Nb+W+Zr; and/or 10-20% of Li+Na+K; and/or 0-5% of Zn+Sr+Ca; and/or 0.01-0.2 of (Ba/Nb).7. An optical glass claim 1 , with anion as O claim 1 , wherein a cation contains the following components by weight percentage: 12-25% of Si; 49.5-65% of Nb; 0-8% of Zr; 0-10% of W; 8-25% of Li+Na+K; 10% of Ba or less.8. The optical glass according to claim 7 , further containing: 0-5% of B; 0-0.2% of Sb; 0-10% of Zn+Sr+Ca.9. An optical glass claim 7 , with anion as O claim 7 , wherein a ...

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05-03-2020 дата публикации

Glass Ionomer Compositions and Methods Including Water-Miscible, Silane-Treated, Nano-Sized Silica Particles

Номер: US20200069535A1
Принадлежит:

Disclosed herein are curable glass ionomer compositions that include a first paste and a second paste, and methods for using the disclosed compositions. The first paste includes water, a polyacid, and a non acid-reactive filler. The second paste includes water, an acid-reactive filler; and non-aggregated, water-miscible, nano-sized silica particles having at least 25% surface coverage of the particles with a silane. The composition is essentially free of a resin. In some embodiments, the water content of the first paste and the second paste of the paste/paste GI composition disclosed herein is less than 20% by weight, based on the total weight of the composition. 1. A curable glass ionomer composition comprising: water,', 'a polyacid, and', 'a non acid-reactive filler; and, 'a first paste comprising water,', 'an acid-reactive filler; and', 'non-aggregated, water-miscible, nano-sized silica particles having at least 25% surface coverage of the particles with a silane;, 'a second paste comprisingwherein the composition is essentially free of a resin.2. (canceled)3. The composition of claim 1 , wherein the silane is essentially free of unsaturated polymerizable groups.4. The composition of claim 1 , wherein the silane is represented by the formula:{'br': None, 'sup': 1', '2', '3, 'sub': 3', '2', 'n', 'x, '(RO)—Si—(CH)—(O—R)—OR,'} [{'sup': '1', 'Ris a C1-C3 alkyl group;'}, {'sup': '2', 'Ris a C2-C3 alkylene group;'}, {'sup': '3', 'Ris a C1-C10 alkyl group or 2,3-epoxypropyl;'}, 'n=2 to 6; and', 'x=0 to 200., 'wherein5. (canceled)6. The composition of claim 4 , wherein Rrepresents —CHCH—.7. The composition of claim 4 , wherein n=3.810.-. (canceled)11. The composition of claim 1 , wherein the non-aggregated claim 1 , water-miscible claim 1 , nano-sized silica particles are substantially free of fumed silica.12. The composition of claim 1 , wherein at least one of the first paste and the second paste further comprises pyrogenic silica particles.13. The composition of claim ...

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16-03-2017 дата публикации

MULTILAYER ELECTRONIC COMPONENT

Номер: US20170076868A1
Принадлежит: TDK Corporation

A multilayer electronic component includes an element body having an internal electrode layer and a dielectric layer. These are substantially parallel to a plane including a first axis and a second axis and are alternately laminated along a third axis direction. Side surfaces facing each other in the first axis direction are respectively equipped with an insulating layer. End surfaces facing each other in the second axis direction are respectively equipped with an external electrode. The insulating layer includes a glass component. A formula (1) of 0.25<α/β<1 is satisfied, where α denotes a thermal expansion coefficient of the insulating layer, and β denotes a thermal expansion coefficient of one of the internal electrode layer and the dielectric layer that is larger than a thermal expansion coefficient of the other layer. 1. A multilayer electronic component comprising an element body having an internal electrode layer and a dielectric layer , both of which are substantially parallel to a plane including a first axis and a second axis and are alternately laminated along a third axis direction , whereina pair of side surfaces facing each other in the first axis direction of the element body is respectively equipped with an insulating layer,a pair of end surfaces facing each other in the second axis direction of the element body is respectively equipped with an external electrode electrically connected to the internal electrode layer,the insulating layer comprises a glass component, anda formula (1) of 0.25<α/β<1 is satisfied, whereα denotes a thermal expansion coefficient of the insulating layer andβ denotes a thermal expansion coefficient of one of the internal electrode layer and the dielectric layer that is larger than a thermal expansion coefficient of the other layer.2. The multilayer electronic component according to claim 1 , whereina reaction phase where at least one of constituents of the insulating layer is diffused in the dielectric layer is formed at an ...

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21-03-2019 дата публикации

Dental glass powder

Номер: US20190083364A1
Принадлежит: GC Corp

In one aspect of the present invention, a dental glass powder contains zinc, silicon, and fluorine and does not substantially contain aluminum.

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21-03-2019 дата публикации

TRANSPARENT ION-EXCHANGEABLE SILICATE GLASSES WITH HIGH FRACTURE TOUGHNESS

Номер: US20190084869A1
Принадлежит:

Provided herein are glass based articles comprising SiOin a range from about 20 mol % to about 80 mol %; AlOin a range from about 2 mol % to about 60 mol %; MgO; LiO; LaOin an amount greater than or equal to about 3 mol %; a sum of alkali metal oxides (RO) is greater than or equal to about 6 mol %; and a sum of MgO and AlOis greater than or equal to about 28 mol %, wherein the glass based article is free of BeO. 1. A glass based article comprising:{'sub': '2', 'SiOin a range from about 20 mol % to about 80 mol %;'}{'sub': 2', '3, 'AlOin a range from about 2 mol % to about 60 mol %;'}MgO;{'sub': '2', 'LiO;'}{'sub': 2', '3, 'LaOin an amount greater than or equal to about 3 mol %;'}a sum of alkali metal oxides (R20) is greater than or equal to about 6 mol %; and{'sub': 2', '3, 'a sum of MgO and AlOis greater than or equal to about 28 mol %,'}wherein the glass based article is free of BeO.2. The glass based article of claim 1 , wherein (i) a fracture toughness is at least 0.8 MPa*m; (ii) a Young's modulus value is at least 90 GPa; and/or (iii) a stress optical coefficient (SOC) is not more than 3 Brewster.3. The glass based article of claim 1 , wherein LaOis in a range from about 3 mol % to about 18 mol %.4. The glass based article of claim 1 , wherein LaOis in a range from about 5 mol % to about 15 mol %.5. The glass based article of claim 1 , wherein MgO is in a range from about 1 mol % to about 42 mol %.6. The glass based article of claim 3 , wherein MgO is in a range from about 2 mol % to about 37 mol %.7. The glass based article of claim 4 , wherein MgO is in a range from about 3 mol % to about 32 mol %.8. The glass based article of claim 1 , wherein the sum of RO is in a range from about 6 mol % to about 15 mol %.9. The glass based article of claim 1 , comprising:MgO in the range of about 1 mol % to about 42 mol %;{'sub': 2', '3, 'LaOin the range of about 3 mol % to about 18 mol %; and'}{'sub': '2', 'the sum of RO is in a range from about 6 mol % to about 15 mol ...

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04-04-2019 дата публикации

DENTAL CEMENT

Номер: US20190099332A1
Принадлежит:

In one aspect of the present invention, a dental cement contains a glass powder, wherein the glass powder contains zinc, silicon, and fluorine and does not substantially contain aluminum. 1a glass powder,wherein the glass powder contains zinc, silicon, and fluorine and does not substantially contain aluminum.. A dental cement comprising: The present invention relates to a dental cement.As a dental glass powder, an aluminosilicate glass powder is well known. The aluminosilicate glass powder is a glass powder containing oxides of Al (III) and Si (IV) as a main component. In particular, a fluoroaluminosilicate glass powder is widely used for a dental material because it is expected to have a tooth strengthening effect by fluorine and an effect of preventing tooth decay (see, for example, Patent Documents 1 and 2).The fluoroaluminosilicate glass powder is known to be used for a dental glass ionomer cement.Dental glass ionomer cement is generally composed of a fluoroaluminosilicate glass powder and a liquid containing a polycarboxylic acid-based polymer and water, and a hardened substance is obtained by an acid-base reaction of aluminum (ions) in the fluoroaluminosilicate glass powder with the polycarboxylic acid-based polymer included in the liquid.However, it is desired to enhance the effect of suppressing tooth demineralization.Hence, an object in one aspect of the present invention is to provide a dental cement that can enhance an effect of suppressing tooth demineralization.According to one aspect of the present invention, a dental cement contains a glass powder, wherein the glass powder zinc, silicon, and fluorine and does not substantially contain aluminum.According to one aspect of the present invention it is possible to provide a dental cement that can enhance an effect of suppressing tooth demineralization.In the following, an embodiment for carrying out the present invention will be described.A dental cement contains a glass powder.Examples of ...

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02-06-2022 дата публикации

DECORATIVE GLASS ARTICLE

Номер: US20220169558A1
Принадлежит: NIPPON ELECTRIC GLASS CO., LTD.

A decorative glass article is substantially free of lead oxide, and has a refractive index of 1.9 or more and an Abbe number of 42 or less. 1. A decorative glass article , which is substantially free of lead oxide , and has a refractive index of 1.9 or more and an Abbe number of 42 or less.2. The decorative glass article according to claim 1 , which has a degree of coloring λof 395 or less.3. The decorative glass article according to claim 1 , wherein a content of bismuth oxide is 30% or less in mol %.4. The decorative glass article according to claim 1 , comprising: in mol % claim 1 , 0% to 63% of LaO claim 1 , 0% to 40% of BO claim 1 , 0% to 50% of AlO claim 1 , 0% to 40% of ZrO claim 1 , 0% to 80% of NbO claim 1 , 0% to 60% of GdO claim 1 , 0% to 60% of TaO claim 1 , and 0.1% to 100% of LaO+NbO+TaO+GdO.5. The decorative glass article according to claim 4 , further comprising: in mol % claim 4 , 0% to 85% of TiO.6. The decorative glass article according to claim 1 , which is subjected to chamfering.7. The decorative glass article according to claim 1 , which is an artificial jewel.8. A decoration comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the decorative glass article according to .'} The present invention relates to a decorative glass article suitable for decorative purposes, such as a ring, a pendant, an earring, or a bracelet.According to GLASS MANUFACTURERS' ASSOCIATION OF JAPAN, a crystal glass is defined as “a glass containing lead oxide as a main component and a glass containing potassium oxide, barium oxide, titanium oxide, etc. as a main component, which is characterized by having high transparency, a refractive index nd of 1.52 or more, a beautiful brilliance and a clear tone”. The crystal glass is excellent in brilliance, transparency, reverberation, profound feeling, processability, etc., and is used for decoration (jewelry, works of art, tableware, etc.).However, since the lead-containing crystal glass is harmful to a human body and ...

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02-06-2022 дата публикации

Thermal Barrier Material Formed Of Inorganic Material, Material Set For Producing Same, Material For Base Layers And Method For Producing Same

Номер: US20220169576A1
Принадлежит:

A novel heat shielding material made of an inorganic material is proposed. 1. A heat shielding material made of an inorganic material , comprising:a base material;a underlayer layered on the base material and having a total solar reflectance (TSR) greater than a TSR of the base material; anda top layer layered on the underlayer, whereinthe top layer has a thickness such that the underlayer is not visually recognizable, and transmits infrared rays, andthe underlayer includes a reaction region between a material of the underlayer and a material of the top layer, and a main reflection region where the material of the top layer is not present.2. The heat shielding material according to claim 1 , wherein the main reflection region has a thickness of 10 m or more.3. The heat shielding material according to claim 1 , wherein a halo intensity of the main reflection region determined by an X-ray diffraction method is 230 cps or less.4. The heat shielding material according to claim 1 , wherein the material of the underlayer is represented by a Seger formula: RO: 0.1 to 0.5 claim 1 , RO: 0.5 to 0.9 claim 1 , BO: 0.0 to 1.0 claim 1 , AlO: 2.2 to 10.2 claim 1 , SiO: 7.2 to 29.2 claim 1 , TiO: 0.0 to 0.5 claim 1 , ZrSiO: 0.0 to 5.5 claim 1 , SiO/AlO: 0.7 to 23.8 claim 1 , where RO is MgO claim 1 , CaO claim 1 , or BaO claim 1 , and RO is LiO claim 1 , NaO claim 1 , or KHO.6. A heat shielding material comprising:a base material;a underlayer having a TSR of 80% or more; and{'sub': 2', '3, 'a top layer containing a (Cr,Fe)Osolid solution having a ratio (molar ratio) of Cr to Fe of 93 to 97:7 to 3 or a ratio (molar ratio) of Cr to Fe of 80 to 97:20 to 3 and having a non-spinel structure, and having an L* value of 30 or less, wherein'}the top layer has a thickness such that the underlayer is not visually recognizable, and transmits infrared rays, andthe underlayer includes a reaction region between a material of the underlayer and a material of the top layer, and a main reflection ...

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19-04-2018 дата публикации

TRANSPARENT GLASS-CERAMIC ARTICLES, GLASS-CERAMIC PRECURSOR GLASSES AND METHODS FOR FORMING THE SAME

Номер: US20180105453A1
Принадлежит:

Embodiments of glass ceramic articles and precursor glasses are disclosed. In one or more embodiments, the glass-ceramic articles are transparent and include a nepheline phase and a phosphate phase. The glass-ceramic articles are colorless and exhibit a transmittance of about 70% or greater across the visible spectrum. The glass-ceramic articles may optionally include a lithium aluminosilicate phase. The crystals of the glass-ceramic articles may have a major cross-section of about 100 nm or less. 1. A glass comprising a composition , in mol % , comprising:SiO2 in the range from about 35% to about 60%,Al2O3 in the range from about 10% to about 30%,Na2O in the range from about 7% to about 31%,K2O in the range from 0% to about 20%,Li2O in the range from 0% to about 20%,P2O5 in the range from about 1.5% to about 8%, anda rare earth oxide in the range from 0% to about 6%.2. The glass of claim 1 , wherein the composition further comprises at least one oxide in an amount in the range from 0 mol % to about 8 mol % claim 1 , wherein the at least one oxide comprises one of B2O3 claim 1 , MgO claim 1 , CaO claim 1 , SrO claim 1 , BaO claim 1 , and ZrO2.3. The glass of claim 1 , wherein the composition further comprises claim 1 , in mol %:SiO2 in the range from about 40% to about 55%,Al2O3 in the range from about 14% to about 21%,Na2O in the range from about 13% to about 29%,K2O in the range from about 2% to about 14%,Li2O in the range from 0% to about 10%,P2O5 in the range from about 2.5% to about 5%, and{'sub': 2', '3', '2', '3, 'at least one of ZrO2, YOand LaOin an amount in the range from 0% to about 4%,'}wherein the composition comprises less than about 1% TiO2.4. The glass of claim 1 , further comprising a compressive stress layer having a surface compressive stress in the range from about 200 MPa to about 600 MPa and a depth of layer in the range from about 50 μm to about 150 μm.5. The glass of claim 1 , wherein the glass is a glass sheet having a thickness of less than ...

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30-04-2015 дата публикации

Conductive Paste for Solar Cell and the Method Thereof

Номер: US20150115207A1
Принадлежит: Giga Solar Materials Corp

The present invention discloses a conductive paste for solar cell, including the following composition: silver particle and two glass frits. A glass frit (I) comprises bismuth oxide, tellurium oxide, tungsten oxide, silicon oxide, and zinc oxide; and a glass frit (II) comprises lead oxide, tellurium oxide, and zinc oxide. The conductive paste is utilized to form the electrode of the substrate for solar cell to enhance the performance of Ohmic contact, fill factor and conversion efficiency of the solar cell, after sintering.

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11-04-2019 дата публикации

OPTICAL GLASS, PREFORM MATERIAL AND OPTICAL ELEMENT

Номер: US20190106352A1
Принадлежит: OHARA INC.

Provided is glass having a predetermined index of refraction (n) and Abbe number (ν), high chemical resistance (acid resistance) and a small degree of abrasion. The optical glass contains, in wt %, 10.0-40.0% of a SiOcomponent, 15.0-50.0% of a LaOcomponent and 5.0% to less than 25.0% of a TiOcomponent, has a mass ratio BO/SiOless than or equal to 1.00, an index of refraction (n) of 1.78-1.95 and an Abbe number (ν) of 25-45, and chemical resistance (acid resistance) via a powder method that is class 1-3. The optical glass has a degree of abrasion of less than or equal to 200. 1. An optical glass comprising , by mass %:{'sub': '2', '10.0% to 40.0% of an SiOcomponent;'}{'sub': 2', '3, '15.0% to 50.0% of an LaOcomponent; and'}{'sub': '2', '5.0% to less than 25.0% of a TiOcomponent,'}wherein the optical glass has{'sub': 2', '3', '2, 'a BO/SiOmass ratio of not more than 1.00,'}{'sub': d', 'd, 'a refractive index (n) of 1.78 to 1.95, and an Abbe number (ν) of 25 to 45, and'}chemical durability (acid resistance) of Class 1 to Class 3 when measured by a powder method.2. The optical glass according to comprising claim 1 , by mass %:0 to 30.0% of a ZnO component;{'sub': '2', '0 to 20.0% of a ZrOcomponent;'}{'sub': 2', '3, '0 to 20.0% of an AlOcomponent;'}{'sub': 2', '3, '0 to 25.0% of a YOcomponent; and'}{'sub': 2', '3, '0 to 20.0% of a BOcomponent.'}3. The optical glass according to claim 1 , wherein a total mass of BO+NbOis less than 20.0% claim 1 , and a total mass of ZrO+NbO+WO+ZnO is less than 25.0%.4. The optical glass according to claim 1 , wherein a total mass of TiO+ZrOis less than 35.0%.5. An optical glass comprising claim 1 , by mass %:{'sub': '2', '10.0% to 50.0% of an SiOcomponent;'}{'sub': 2', '3, '15.0% to 60.0% of an LaOcomponent; and'}{'sub': '2', '0 to less than 15.0% of a TiOcomponent,'}wherein the optical glass has{'sub': 2', '3', '2, 'a BO/SiOmass ratio of not more than 1.00,'}{'sub': d', 'd, 'a refractive index (n) of 1.60 to 1.85, and an Abbe number (ν) ...

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11-04-2019 дата публикации

X-ray induced coloration in glass or glass-ceramic articles

Номер: US20190106356A1
Принадлежит: Corning Inc

Embodiments of the present disclosure are directed to methods for inducing color change in glass and glass-ceramic articles. According to one embodiment, color change may be x-ray induced in glass or glass-ceramic articles. The method for x-ray inducing color change may include exposing the glass or glass-ceramic article to x-rays at a temperature of up to 200° C. to induce a colored area in the glass or glass-ceramic article. The glass or glass-ceramic article may comprise: 50-85 mole % SiO 2 ; 5-25 mole % Al 2 O 3 ; 0-15 mole % P 2 O 5 ; 0-15 mole % B 2 O 3 ; 5-25 mole % R 2 O, wherein R 2 O=Li 2 O+Na 2 O+K 2 O.

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28-04-2016 дата публикации

Laminated glass article with scratch resistant surface

Номер: US20160114564A1
Принадлежит: Corning Inc

Disclosed herein are laminated glass articles having a hard scratch resistant outer surface. In some embodiments, the laminated glass article includes a glass core layer and a glass clad layer. In some embodiments, the laminated glass article includes a glass core layer sandwiched between two glass clad layers. In some embodiments, the clad glass is selected from the group of consisting of: aluminate glasses; oxynitride glasses; rare earth/transition metal glasses; beryl glasses; and glasses containing lithium, zirconium, or both lithium and zirconium. Such glass compositions can thus be used in forming the clad layer.

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07-05-2015 дата публикации

DENTAL COMPOSITIONS WITH CALCIUM PHOSPHORUS RELEASING GLASS

Номер: US20150125823A1
Принадлежит:

The present application provides a glass composition comprising 10-50% by weight CaO, at least 15% and less than 50% by weight PO, less than 3% by weight AlO, less than 10% by weight LiO, NaO, and KO combined, and 0-60% by weight of SrO, MgO, BaO, ZnO, or combinations thereof; dental compositions comprising the glass composition, and methods of making and using such dental compositions. 1. A glass composition comprising 10-50% by weight CaO , at least 15% and less than 50% by weight PO , less than 3% by weight AlO , less than 10% by weight LiO , NaO , and KO combined , and 0-60% by weight of SrO , MgO , BaO , ZnO , or combinations thereof.2. The glass composition of claim 1 , wherein the glass is amorphous.3. The glass composition of claim 1 , wherein the glass is at least partially crystalline.4. The glass composition of claim 1 , wherein the glass is in a finely divided form of particles claim 1 , fibers claim 1 , or platelets.65. The glass composition of claim claim 1 , wherein the particles claim 1 , fibers claim 1 , or platelets are surface-treated.7. The glass composition of claim 6 , wherein the surface treatment comprises a silane.8. The glass composition of claim 1 , further comprising fluoride in an amount less than 25% by weight of the glass composition.9. The glass composition of claim 1 , further comprising BOin an amount less than 30% by weight of the glass composition.10. The glass composition of claim 1 , further comprising SiOin an amount less than 20% by weight of the glass composition.11. The glass composition of claim 10 , wherein the amount is less than 1% by weight of the glass composition.12. The glass composition of claim 1 , further comprising up to 40% by weight of a rare earth oxide.13. The glass composition of claim 1 , further comprising ZrOin an amount less than 15% by weight of the glass composition.14. A dental composition comprising the glass composition of .15. The dental composition of claim 14 , wherein the dental composition ...

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07-05-2015 дата публикации

GERMANIUM-BASED GLASS POLYALKENOATE CEMENT

Номер: US20150126640A1
Принадлежит:

Disclosed herein are compositions and methods for making germanium-based glass polyalkenoate cements. Also disclosed are methods for their use as bone cements for bone augmentation procedures. 1. A composition comprising: [{'sub': '2', '0.1-0.75 mole fraction GeO;'}, '0.11-0.53 mole fraction ZnO; and', '0.01-0.2 mole fraction CaO., 'a glass powder comprising2. The composition of further comprising 0.025-0.12 mole fraction SrO.3. The composition of further comprising 0.005-0.08 mole fraction each of ZrOand NaO.4. The composition of comprising 0.1-0.75 mole fraction GeOand 0.005-0.04 mole fraction each of ZrOand NaO.5. The composition of further comprising 0.02-0.48 mole fraction SiO.6. The composition of comprising 0.1-0.75 claim 1 , 0.1-0.6 claim 1 , 0.2-0.5 or 0.35-0.50 mole fraction GeO.7. The composition of comprising about 0.36 mole fraction ZnO.8. The composition of comprising 0.2-0.48 claim 1 , 0.02-0.25 or 0.02-0.2 mole fraction SiO.9. The composition of comprising about 0.04 mole fraction SrO.10. The composition of comprising 0.01-0.35 claim 1 , 0.02-0.16 claim 1 , 0.02-0.12 claim 1 , 0.05-0.15 claim 1 , or 0.07-0.13 mole fraction CaO.11. The composition of comprising 0.005-0.06 claim 1 , 0.01-0.055 or 0.02-0.04 mole fraction each of ZrOand NaO.12. The composition of comprising no more than 0.01 mole fraction aluminosilicates.13. The composition of that is substantially free of aluminosilicates.14. The composition of wherein the composition comprises an acid degradable powder.15. The composition of wherein the composition is radio opaque.16. The composition of wherein the composition comprises a polyalkenoate cement having a glass phase made from the glass powder.17. A method of preparing a bone cement comprising mixing the glass powder of with an aqueous solution of about 40%-60% by weight polyalkenoic acid in a ratio of about 2:1 to 1:1 claim 1 , and wherein the polyalkenoic acid has a weight average molecular weight (M) of about 1 claim 1 ,150 to 1 claim ...

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23-04-2020 дата публикации

DENTAL TREATMENT MATERIAL AND DENTAL TREATMENT MATERIAL KIT

Номер: US20200121563A1
Принадлежит:

A dental treatment material includes: a liquid dispersion of a glass powder; and an inorganic phosphoric acid aqueous solution, wherein the glass powder contains zinc, silicon, and fluorine and does not substantially contain aluminum. 1. A dental treatment material comprising:a liquid dispersion of a glass powder; andan inorganic phosphoric acid aqueous solution,wherein the glass powder contains zinc, silicon, and fluorine and does not substantially contain aluminum.2. The dental treatment material according to is used as a dentinal tubules sealing material.3. A dental treatment material kit comprising:a container in which a liquid dispersion of a glass powder that contains zinc, silicon, and fluorine and does not substantially contain aluminum is contained; anda container in which an inorganic phosphoric acid aqueous solution is contained. The present invention relates to a dental Treatment material and a dental treatment material kit.Conventionally, in dental treatment, a dental treatment material that is applied to an affected part for alleviating symptoms of hyperesthesia or the like is known. In particular, a treatment material that seals dentinal tubules of dentine exposed at an affected part to block external stimuli to alleviate pain is well known.For example, Patent Document 1 describes a dental treatment material containing two liquids that promptly causes precipitation hardly soluble in water when being mixed.[Patent Document 1] Japanese Laid-open Patent Publication No. H4-217904However, conventional dental treatment materials have room for improvement with respect to suppression of tooth demineralization.Hence, an object in one aspect of the present invention is to provide a dental treatment material having an enhanced effect of suppressing tooth demineralization.According to one aspect of the present invention, a dental treatment material includes: a liquid dispersion of a glass powder; and an inorganic phosphoric acid aqueous solution, wherein the ...

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02-05-2019 дата публикации

SCINTILLATOR PANEL AND PRODUCTION METHOD FOR SAME, AND RADIATION DETECTION APPARATUS

Номер: US20190131027A1
Принадлежит: Toray Industries, Inc.

A scintillator panel has a barrier rib structure, whereby opposing light-receiving substrates can be aligned with high precision and bonded with a photoelectric conversion element. In the scintillator panel, cells demarcated by lattice shaped barrier ribs formed on a sheet-shaped base member are filled with a phosphor for receiving radiation and emitting light, thereby configuring a pixel structure. The scintillator panel has portions in which the lattice-shaped barrier ribs are exposed on both a front surface and a back surface in a portion of a non-display region of the panel external periphery. The exposed parts are optically transparent. 1. A scintillator panel comprising a pixel structure in which cells divided by a barrier rib of a lattice shape formed on a base member of a sheet shape are loaded with a fluorescent that , when receiving a radiation ray , emits light , the scintillator panel further comprising , in at least a portion of a non-display region in an outer perimeter portion of the panel , a portion in which the barrier rib of the lattice shape is exposed on both obverse and reverse sides , wherein the exposed portion has a light-transmitting property.2. The scintillator panel according to claim 1 , wherein the barrier rib of the lattice shape is made of a material whose main component is a low melting point glass that contains 2 to 20 mass % of an alkali metal oxide.3. The scintillator panel according to claim 1 , wherein a surface of the barrier rib is provided with a reflective layer.4. A method for producing the scintillator panel according to claim 1 , the production method for the scintillator panel comprising a step of coating on a base member A a photosensitive paste that contains a low melting point glass and a photosensitive organic component and forming a photosensitive paste coat film claim 1 , an optical exposure step of optically exposing the photosensitive paste coat film to a predetermined pattern claim 1 , a development step of ...

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18-05-2017 дата публикации

VACUUM INSULATING GLASS (VIG) UNIT WITH LEAD-FREE DUAL-FRIT SEALS AND/OR METHODS OF MAKING THE SAME

Номер: US20170138115A1
Принадлежит:

Certain example embodiments of this invention relate to vacuum insulating glass (VIG) units having improved seals made using two different frit-based edge seal materials, and/or methods of making the same. In certain example embodiments, a first frit material is applied around peripheral edges of first and second glass substrates. The first frit material, which may be bismuth-based in certain example embodiments, is fired with a heat treatment (e.g., thermal tempering) process. A second frit material, which may be VBZ-based in certain example embodiments, is applied and at least partially overlaps with the fired first frit material. The first frit material acts as a primer, and the second frit material helps seal together the VIG unit. The second frit material is fired at a significantly lower temperature that enables the glass to retain the temper or other strength imparted by the heat treatment. 125-. (canceled)26. A vacuum insulating glass (VIG) window unit , comprising:first and second substantially parallel, spaced apart glass substrates, wherein at least one of the first and second substrates is heat treated;a plurality of spacers disposed between the first and second substrates; andan edge seal provided around the periphery of the first and/or second substrates, the first and second substrates, together with the edge seal, defining a cavity therebetween, the cavity being evacuated to a pressure less than atmospheric,wherein the edge seal is an hermetic seal formed by heating via a low temperature process for a short duration a second lead-free frit material that is sandwiched between bands of first frit materials fused with the first and second substrates during a high temperature process, the low temperature process being performed in connection with a second peak temperature of no more than 400 degrees C. and a time of no more than 15 minutes at the second peak temperature, and the high temperature being performed at a first peak temperature that is at ...

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30-04-2020 дата публикации

Optical material for light guide plates and light guide plate

Номер: US20200131077A1
Принадлежит: Asahi Glass Co Ltd

An optical material for a light guide plate has a refractive index of 1.70 or more, a thickness of 1.1 mm or less, and a waviness of a surface of less than 50×10 −4 degrees. The optical material may have the waviness of from 1.0×10 −4 to 10×10 −4 degrees. The optical material may contain glass.

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30-04-2020 дата публикации

GLASS BALL

Номер: US20200131086A1
Принадлежит: AGC Inc.

A glass ball has a density of 2.3 to 3.2 g/cm, a Young's modulus of 60 to 150 GPa, and an average coefficient of thermal expansion at 50 to 350° C. being 40×10to 120×10/° C. The glass ball is formed of a glass material including, as represented by mole percentage based on oxides, 30 to 75 mol % of SiO, 2 to 30 mol % of AlO, and 5 to 25 mol % of RO, where R is at least one kind selected from Li, Na and K. The glass ball includes a compressive stress layer in a surface thereof. 1. A glass ball , having:{'sup': '3', 'a density of 2.3 to 3.2 g/cm;'}a Young's modulus of 60 to 150 GPa; and{'sup': −7', '−7, 'an average coefficient of thermal expansion at 50 to 350° C. being 40×10to 120×10/° C.,'}{'sub': 2', '2', '3', '2, 'the glass ball being formed of a glass material comprising, as represented by mole percentage based on oxides, 30 to 75 mol % of SiO, 2 to 30 mol % of AlO, and 5 to 25 mol % of RO, wherein R is at least one kind selected from Li, Na and K, and'}the glass ball comprising a compressive stress layer in a surface thereof.2. The glass ball according to claim 1 , wherein the compressive stress layer has a depth (DOL) of 8 to 500 μm.3. The glass ball according to claim 1 , wherein the glass material is a Li-based glass comprising claim 1 , as represented by mole percentage based on oxides claim 1 , 50 to 75 mol % of SiO claim 1 , 4 to 20 mol % of AlO claim 1 , 1 to 15 mol % of LiO claim 1 , 5 to 25 mol % of RO claim 1 , and 0 to 15 mol % of MgO claim 1 , wherein R is at least one kind selected from Li claim 1 , Na and K claim 1 , and SiO+AlO+RO+MgO is 92 mol % or higher.4. The glass ball according to claim 1 , wherein the glass material is a YO-based glass comprising claim 1 , as represented by mole percentage based on oxides claim 1 , 30 to 70 mol % of SiO claim 1 , 4 to 30 mol % of AlO claim 1 , 5 to 20 mol % of LiO claim 1 , 5 to 25 mol % of RO claim 1 , 1 to 25 mol % of MgO claim 1 , and 1 to 20 mol % of YO claim 1 , wherein R is at least one kind selected ...

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24-05-2018 дата публикации

OPTICAL GLASS AND OPTICAL COMPONENT

Номер: US20180141851A1
Принадлежит: Asahi Glass Company, Limited

Provided is an optical glass having a high refractive index, a low density, and good manufacturing properties. An optical glass having: a refractive index (n) of 1.68 to 1.85; a density (d) of 4.0 g/cmor less; and a temperature where a viscosity of glass becomes log η=2 of 950 to 1200° C., and an optical component using the optical glass are provided. This optical glass has the high refractive index, the low density, and the good manufacturing properties, and is suitable as the optical glass of wearable equipment, for a vehicle mounting, for a robot mounting, and so on. 1. An optical glass , having:{'sub': 'd', 'a refractive index (n) of 1.68 to 1.85;'}{'sup': '3', 'a density (d) of 4.0 g/cmor less; and'}{'sub': '2', 'a temperature Twhere a viscosity of glass becomes log η=2 of 950° C. to 1200° C.'}2. The optical glass according to claim 1 , containing claim 1 , in percentage by mass based on oxides:{'sub': 2', '5, 'NbO: 5% to 55%;'}{'sub': 2', '2', '3', '2', '3, '0% to 30% of at least one kind selected from a group consisting of BaO, TiO, ZrO, WO, and LnO, where Ln is at least one kind selected from a group consisting of Y, La, Gd, Yb and Lu;'}{'sub': '2', 'SiO: 29% to 50%; and'}{'sub': 2', '2', '2, '2% to 20% of LiO+NaO+KO,'}{'sub': 2', '2', '2', '2, 'wherein LiO/(LiO+NaO+KO) is 0.45 or less.'}3. The optical glass according to claim 2 , containing claim 2 , in percentage by mass based on oxides:{'sub': 2', '3, 'BO: 0% to 10%;'}MgO: 0% to 10%;CaO: 0% to 15%;SrO: 0% to 15%;BaO: 0% to 15%;{'sub': '2', 'LiO: 0% to 9%;'}{'sub': '2', 'NaO: 0% to 10%;'}{'sub': '2', 'KO: 0% to 10%;'}{'sub': 2', '3, 'AlO: 0% to 5%;'}{'sub': '2', 'TiO: 0% to 15%;'}{'sub': '3', 'WO: 0% to 15%;'}{'sub': '2', 'ZrO: 0% to 15%;'}ZnO: 0% to 15%; and{'sub': 2', '3, 'LaO: 0% to 12%.'}4. The optical glass according to claim 1 ,wherein a devitrification temperature of the optical glass is 1200° C. or less.5. The optical glass according to claim 1 ,{'sub': '360', 'wherein transmittance of light with a ...

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15-09-2022 дата публикации

GLASSES AND GLASS-CERAMICS AND METHODS OF MAKING THEM

Номер: US20220289617A1
Принадлежит:

Phosphate glasses and glass-ceramics exhibit a positive percent kill as measured by United States EPA Test Method for Efficacy of Copper Alloy Surfaces as a Sanitizer and/or have a CIELAB L* value below 35, CIELAB a* and b* values within 5 of zero. 1. A method of making a material , the method comprising: [{'sub': 2', '5, '30 mol %≤PO≤65 mol %, and'}, '25 mol %≤CuO≤55 mol %;, 'melting a batch mixture comprisingmixing the melt;cooling the mixture to form a glass, andannealing the glass without growing crystals in the glass such that the annealed glass is amorphous, single-phase.2. The method of claim 1 , further comprising machining the glass in open air at atmospheric pressure and at temperature within 50 degrees of 0° C.3. The method of claim 1 , wherein the batch mixture further comprises 5 mol %≤FeO≤15 mol.4. The method of claim 1 , wherein the batch mixture comprises 40 mol %≤CuO≤55 mol %.5. The method of claim 1 , wherein the batch mixture further comprises 0 Подробнее

17-06-2021 дата публикации

OPTICAL GLASS AND OPTICAL COMPONENT

Номер: US20210179479A1
Принадлежит: AGC Inc.

An optical glass has: a refractive index (n) of 1.81 to 2.15; a density (d) of 6.0 g/cmor less; a temperature T, at which a viscosity of the glass is 10dPa·s, of 900° C. to 1,200° C.; a devitrification temperature of 1,300° C. or lower; and a content of SiOof 5% to 44% in mol % based on oxides. 1. An optical glass , having:{'sub': 'd', 'a refractive index (n) of 1.81 to 2.15;'}{'sup': '3', 'a density (d) of 6.0 g/cmor less;'}{'sub': '1', 'sup': '1', 'a temperature T, at which a viscosity of the glass is 10dPa·s, of 900° C. to 1,200° C.;'}a devitrification temperature of 1,300° C. or lower; and{'sub': '2', 'a content of SiOof 5% to 44% in mol % based on oxides.'}2. The optical glass according to claim 1 , having a glass transition point (Tg) of 600° C. or higher.3. The optical glass according to claim 1 , comprising claim 1 , in mol % based on oxides claim 1 , at least one oxide selected from the group consisting of TiO claim 1 , TaO claim 1 , WO claim 1 , NbO claim 1 , ZrO claim 1 , and LnO(Ln is at least one element selected from the group consisting of Y claim 1 , La claim 1 , Gd claim 1 , Yb claim 1 , and Lu) in an amount of 30% to 80% claim 1 ,{'sub': 2', '2', '3, 'wherein a total content of SiOand BOis 20% to 70% in mol % based on oxides, and'}wherein in a case where the glass comprises one or more alkaline-earth metal components (MgO, CaO, SrO, and BaO), a proportion of BaO in the alkaline-earth metal components is 0.5 or less.4. The optical glass according to claim 1 , having a viscosity at the devitrification temperature (devitrification viscosity) satisfying log η=0.4 or higher when the viscosity of the glass claim 1 , η claim 1 , is expressed in unit of dPa·s.5. The optical glass according to claim 1 , having a Young's modulus (E) of 60 GPa or higher.6. The optical glass according to claim 1 , having an Abbe number (v) of 60 or less and a coefficient of thermal expansion α within a range of 50° C. to 350° C. of 50×10/K to 150×10/K.7. The optical glass ...

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22-09-2022 дата публикации

PHOSPHATE GLASS AND LIGHT-EMITTING DEVICE USING SAME

Номер: US20220298060A1
Принадлежит:

Provided is a phosphate glass that has a low melting point and has excellent water resistance while maintaining a glass structure. This phosphate glass PGS has a glass transition temperature Tg lower than 490° C. and contains, in oxide-based mol %, 55-65 [mol %] of PO, 10-27 [mol %] of ZnO, 0.5-7 [mol %] of RO((ROis at least one of AlO, GaO, and YO), 0.5-3.5 [mol %] of a lanthanoid oxide LO(LOis at least one of LaO, CeO, PrO, NdO, PmO, SmO, EuO, GdO, TbO, DyO, HoO, ErO, TmO, YbO, and LuO), and 4-15 [mol %] of XO (XO is at least one of LiO, NaO, KO, RbO, CsO, and FrO). 1. Phosphate glass comprising , in terms of mole percentage based on oxides:{'sub': 2', '5, '55 to 65 [mol %] of PO;'}10 to 27 [mol %] of ZnO;{'sub': 2', '3', '2', '3', '2', '3', '2', '3, '0.5 to 7 [mol %] of RObeing at least one of AlO, GaO, or YO;'}{'sub': 2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3', '2', '3, '0.5 to 3.5 [mol %] of a lanthanoid oxide LObeing at least one of LaO, CeO, PrO, NdO, PmO, SmO, EuO, GdO, TbO, DyO, HoO, ErO, TmO, YbO, or LuO; and'}{'sub': 2', '2', '2', '2', '2', '2', '2, '4 to 15 [mol %] of XO being at least one of LiO, NaO, KO, RbO, CsO, or FrO, the phosphate glass having a glass transition temperature of lower than 490° C.'}2. The phosphate glass according to claim 1 , wherein{'sub': 2', '5, 'a total content of the POand the ZnO is 68 to 85 [mol %], and'}{'sub': 2', '3', '2', '3, 'a total content of the ROand the LOis 1 to 10 [mol %].'}3. The phosphate glass according to claim 1 , wherein the glass transition temperature is 240° C. or lower.4. The phosphate glass according to claim 3 , wherein a content of the AlOis 1 to 5 [mol %].5. The phosphate glass according to claim 3 , further comprising 0.001 to 10.0 [mol %] of SnO.6. The phosphate glass according to claim 1 , wherein the glass transition temperature is higher than 240° C.7. The phosphate glass according to claim ...

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09-06-2016 дата публикации

Conductive paste containing lead-free glass frit

Номер: US20160163893A1
Принадлежит: Giga Solar Materials Corp

The present invention discloses a conductive paste comprising a conductive metal or a derivative thereof, and a lead-free glass frit dispersed in an organic vehicle, wherein said lead-free glass frit comprises tellurium-bismuth-lithium-oxide. The conductive paste of the present invention can be used in the preparation of an electrode of a solar cell with excellent energy conversion efficiency.

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24-06-2021 дата публикации

Tube-drawable glass, method for the production and use

Номер: US20210188696A1
Принадлежит: SCHOTT AG

A glass has a maximum crystallization rate (KGmax) of at most 0.20 μm/min in a temperature range of 700° C. to 1250° C. and a hydrolytic stability according to a hydrolytic class 1 HGA1 according to ISO 720:1985. In the case of a sample thickness of 2 mm of the glass, a ratio of a minimum transmittance in a wavelength range of 850 nm to 950 nm to a maximum transmittance in a wavelength range of 250 nm to 700 nm is in a range of 1.9:1 to 15:1.

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24-06-2021 дата публикации

Metal anticorrosive coating, preparation method therefor, and use therefor

Номер: US20210188699A1
Принадлежит: Zhejiang University ZJU

The invention discloses a metal anticorrosive coating. The coating is an inorganic coating used for metal anticorrosion. This coating has a double-layer structure, including an outer enamel coating and an inner base oxide coating. Meanwhile, the content of the base metal oxide decreases from the inner layer to the outer layer, which causes the thermal expansion coefficient of the coating to increase from the inner layer to the outer layer, ensures that the overall thermal expansion coefficient of the coating is coordinate with various base metals. The composition of the outer layer enamel coating includes: by weight, 1-40 parts of silicon, 1-30 parts of sodium, 1-20 parts of potassium, 2-20 parts of calcium, 0.5-15 parts of fluorine, 0.3-10 parts of cobalt, 0.2-10 parts of nickel, 1-18 parts of boron, 0.5-10 parts of phosphorus, 0.1-8 parts of magnesium, and the rest is oxygen; the composition of the base oxide coating of the inner layer includes the base metal and oxygen. A preparation process of a double-layer dense metal anticorrosive coating formed by low-temperature sintering is also disclosed, including the following steps: 1) grinding; 2) preparation of mixture; 3) grinding; 4) high temperature reaction; 5) grinding; 6) coating; 7) sintering. The coating of the invention has the advantages of improving the corrosion resistance by more than 14 times, has a high ductility which can be coordinated with the reinforcing steel bar in tensile deformation, has a thermal expansion coefficient gradient which can be applied to different metals and different types of the same metal.

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16-06-2016 дата публикации

INORGANIC FIBRE COMPOSITIONS

Номер: US20160168019A1
Принадлежит: Morgan Advanced Materials plc.

Inorganic fibres having the composition: 10≦AlO≦50 mol %; 2≦KO≦40 mol %; 30≦SiO≦70 mol %; and in which SiO+AlO+KO>=80 mol % can be protected against surface crystallisation of kalsilite by: including an amount of a nucleation promoting component effective to promote bulk crystallisation in the glass; and/or providing on at least part of their surface, potassium scavenging materials. 2. Inorganic fibres claim 1 , as claimed in in which{'sub': 2', '3, '20≦AlO≦35 mol %.'}3. Inorganic fibres claim 2 , as claimed in in which{'sub': 2', '3, '23≦AlO≦33 mol %.'}4. Inorganic fibres claim 3 , as claimed in in which{'sub': 2', '3, '25≦AlO≦31 mol %.'}5. Inorganic fibres claim 1 , as claimed in in which{'sub': '2', '15≦KO≦30 mol %.'}6. Inorganic fibres claim 5 , as claimed in claim 5 , in which{'sub': '2', '17≦KO≦25 mol %.'}7. Inorganic fibres claim 6 , as claimed in claim 6 , in which{'sub': '2', '20≦KO≦24 mol %.'}8. Inorganic fibres claim 1 , as claimed in claim 1 , in which{'sub': '2', '35≦SiO≦60 mol %.'}9. Inorganic fibres claim 8 , as claimed in in which{'sub': '2', '40≦SiO≦50 mol %.'}10. Inorganic fibres claim 9 , as claimed in in which{'sub': '2', '40≦SiO≦45 mol %.'}11. Inorganic fibres claim 1 , as claimed in claim 1 , in which the component capable of promoting bulk crystallisation is or includes zirconia claim 1 , ceria claim 1 , titania claim 1 , phosphate claim 1 , or mixtures thereof.12. Inorganic fibres claim 11 , as claimed in claim 11 , in which the component capable of promoting bulk crystallisation is or includes zirconia.13. Inorganic fibres claim 12 , as claimed in claim 12 , in which:{'sub': '2', '3≦ZrO≦10 mol %.'}14. Inorganic fibres claim 13 , as claimed in claim 13 , in which:{'sub': '2', '3.5 mol %≦ZrO≦10 mol %.'}15. Inorganic fibres claim 13 , as claimed in claim 13 , in which:{'sub': '2', 'ZrO≦9 mol % or ≦7 mol % or ≦5 mol %.'}16. Inorganic fibres claim 1 , as claimed in claim 1 , in which the composition further comprises magnesia.17. Inorganic fibres ...

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16-06-2016 дата публикации

X-ray induced coloration in glass or glass-ceramic articles

Номер: US20160168023A1
Принадлежит: Corning Inc

Embodiments of the present disclosure are directed to methods for inducing color change in glass and glass-ceramic articles. According to one embodiment, color change may be x-ray induced in glass or glass-ceramic articles. The method for x-ray inducing color change may include exposing the glass or glass-ceramic article to x-rays at a temperature of up to 200° C. to induce a colored area in the glass or glass-ceramic article. The glass or glass-ceramic article may comprise: 50-85 mole % SiO 2 ; 5-25 mole % Al 2 O 3 ; 0-15 mole % P 2 O 5 ; 0-15 mole % B 2 O 3 ; 5-25 mole % R 2 O, wherein R 2 O=Li 2 O+Na 2 O+K 2 O.

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08-06-2017 дата публикации

METHOD OF FORMING ELECTRODE, ELECTRODE MANUFACTURED THEREFROM AND SOLAR CELL

Номер: US20170162727A1
Принадлежит:

A method of forming an electrode, an electrode for a solar cell manufactured, and a solar cell, the method including forming a pattern of a finger electrode by: coating a composition for forming a first electrode that includes a conductive powder, an organic vehicle, and a first glass frit that is free of silver and phosphorus, and drying the coated composition for forming a first electrode; forming a pattern of a bus electrode by: coating a composition for forming a second electrode that includes a conductive powder, an organic vehicle, and a second glass frit that includes silver and phosphorus, and drying the coated composition for forming a second electrode; and firing the resultant patterns. 1. A method of forming an electrode , the method comprising: coating a composition for forming a first electrode that includes a conductive powder, an organic vehicle, and a first glass frit that is free of silver and phosphorus, and', 'drying the coated composition for forming a first electrode;, 'forming a pattern of a finger electrode by coating a composition for forming a second electrode that includes a conductive powder, an organic vehicle, and a second glass frit that includes silver and phosphorus, and', 'drying the coated composition for forming a second electrode; and, 'forming a pattern of a bus electrode byfiring the resultant patterns.2. The method of forming an electrode as claimed in claim 1 , wherein the composition for forming the first electrode includes:about 60 wt % to about 95 wt % of the conductive powder,about 0.5 wt % to about 20 wt % of the first glass frit, anda balance amount of the organic vehicle.3. The method of forming an electrode as claimed in claim 1 , wherein the composition for forming the second electrode includes:about 60 wt % to about 95 wt % of the conductive powder,about 0.5 wt % to about 20 wt % of the second glass frit, anda balance amount of the organic vehicle.4. The method of forming an electrode as claimed in claim 1 , wherein ...

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21-05-2020 дата публикации

RADIOACTIVE MICROSPHERE, PREPARATION METHOD THEREOF AND RADIOACTIVE FILLER COMPOSITION

Номер: US20200155715A1
Принадлежит:

Provided is a radioactive microsphere including glass having a structure represented by a formula CaSiOand yttrium oxide contained in the glass. The radioactive microsphere has sphericity of from 0.71 to 1, and is radioactive after being activated by neutron irradiation. A method for preparing a radioactive microsphere and a radioactive filler composition is further provided. The present disclosure can be used to treat tumor by delivering radioactive microspheres to the target tissue, and then radioactive microspheres are activated by neutrons to generate radiation. The radioactivity of microspheres disappears over time, and the microspheres were dissolved and absorbed by the bone tissue in the end. 1. A radioactive microsphere , comprising glass represented by a chemical formula of CaSiOand yttrium oxide contained in the glass , and having sphericity from 0.71 to 1 , wherein the radioactive microsphere is radioactive after being activated by neutron irradiation.2. The radioactive microsphere of claim 1 , further comprising an imaging nuclide oxide.3. The radioactive microsphere of claim 2 , wherein the imaging nuclide oxide has an imaging nuclide that is at least one selected from the group consisting of phosphorus claim 2 , calcium claim 2 , sodium claim 2 , rhenium claim 2 , scandium claim 2 , lanthanum claim 2 , cerium claim 2 , praseodymium claim 2 , neodymium claim 2 , promethium claim 2 , samarium claim 2 , europium claim 2 , gadolinium claim 2 , terbium claim 2 , dysprosium claim 2 , holmium claim 2 , erbium claim 2 , thulium claim 2 , ytterbium claim 2 , lutetium claim 2 , actinium-225 claim 2 , antimony-127 claim 2 , arsenic-74 claim 2 , barium-140 claim 2 , bismuth-210 claim 2 , californium-246 claim 2 , calcium-46 claim 2 , calcium-47 claim 2 , carbon-11 claim 2 , carbon-14 claim 2 , cesium-131 claim 2 , cesium-137 claim 2 , chromium-51 claim 2 , cobalt-57 claim 2 , cobalt-58 claim 2 , cobalt-60 claim 2 , dysprosium-165 claim 2 , erbium-169 claim 2 , ...

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22-06-2017 дата публикации

ANTIMICROBIAL GLASS COMPOSITIONS, GLASSES AND POLYMERIC ARTICLES INCORPORATING THE SAME

Номер: US20170172151A1
Принадлежит:

Embodiments of the present invention pertain to antimicrobial glass compositions, glasses and articles. The articles include a glass, which may include a glass phase and a cuprite phase. In other embodiments, the glasses include as plurality of Cuions, a degradable phase including BO, POand KO and a durable phase including SiO. Other embodiments include glasses having a plurality of Cuions disposed on the surface of the glass and in the glass network and/or the glass matrix. The article may also include a polymer. The glasses and articles disclosed herein exhibit a 2 log reduction or greater in a concentration of at least one of bacteria, Methicillin Resistant , and , under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing conditions and under Modified JIS Z 2801 for Bacteria testing conditions. In some embodiments, the glass and articles exhibit a 2 log reduction or greater in a concentration of Murine Norovirus under Modified JIS Z 2801 Test for Viruses testing conditions. 1. An article comprising:a carrier; and{'sub': 2', '2', '3', '2', '5', '2, 'sup': '1+', 'a glass comprising, in mole percent, SiOin the range from about 40 to about 70, at least one of BO, PO, alkaline earth oxides, and RO, and a plurality of Cuions,'}{'sup': '1+', 'wherein a portion of the plurality of Cuions leach from the glass when the glass is exposed to or in contact with a leachate.'}2. The article of claim 1 , wherein the carrier comprises a polymer claim 1 , a monomer claim 1 , a binder or a solvent.3. The article of claim 2 , wherein the polymer comprises one of polycarbonate claim 2 , nylon claim 2 , polycarbonate and poly(acrylonitrile-butadiene-styrene) blends claim 2 , poly(acrylonitrile-butadiene-styrene) claim 2 , polybutyleneterephthlate claim 2 , polyethyleneterephthalate claim 2 , polyethyleneterephthalate copolymers claim 2 , polyphenylene oxide claim 2 , polyvinylchloride claim 2 , and acrylic polymers.4. The article of claim 2 , wherein the polymer ...

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21-06-2018 дата публикации

KANOITE GLASS-CERAMICS

Номер: US20180170798A1
Автор: Aitken Bruce Gardiner
Принадлежит:

A compositional range of manganese aluminosilicate glass-ceramics with high durability, and methods for making the same, are described herein. The glass-ceramics can be used in conjunction with electronic devices, such as in protective exteriors for such devices. The glass-ceramics can be characterized as having ring-on-ring strengths of at least 300 MPa and fracture toughnesses of at least 1.5 MPa·m. 2. The glass composition of claim 1 , comprising 0.1-5 mol % LiO.3. The glass composition of claim 1 , comprising 0.1-6 mol % NaO.4. The glass composition of claim 1 , comprising and 0.1-6 mol % YO.5. The glass composition of claim 1 , wherein the glass composition further comprises 0.1-15 mol % MgO.6. The glass composition of claim 1 , wherein the glass composition further comprises less than 5 mol % TiO.8. The glass ceramic of claim 7 , comprising 0.1-5 mol % LiO.9. The glass ceramic of claim 7 , comprising 0.1-6 mol % NaO.10. The glass ceramic of claim 7 , comprising and 0.1-6 mol % YO.11. The glass ceramic of claim 7 , wherein the glass ceramic further comprises 0.1-15 mol % MgO.12. The glass ceramic of claim 7 , wherein the glass ceramic further comprises less than 5 mol % TiO.13. The composition of claim 7 , wherein the glass-ceramic composition comprises at least 50 to 100% by volume grains having a kanoite crystal structure.14. The composition of claim 13 , wherein the grains have a grain size of up to 50 μm.15. The composition of claim 7 , wherein the glass-ceramic composition has a ring-on-ring strength of at least 300 MPa.16. The composition of claim 7 , wherein the glass-ceramic composition has a fracture toughness of at least 1.5 MPa·m.18. The method of claim 17 , wherein the heat treating comprises: a nucleation temperature in the range 700-775° C. for 0.5 to 6 hours, and', 'a crystallization temperature in the range 850-950° C. for 0.5 to 6 hours., 'subjecting the glass precursor, in order, to19. The method of claim 17 , wherein the heat treatment is ...

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21-06-2018 дата публикации

High-K LTCC Dielectric Compositions And Devices

Номер: US20180170813A1
Автор: Walter J. Symes, Jr.
Принадлежит: Ferro Corp

Electronic devices are produced from dielectric compositions comprising a mixture of precursor materials that, upon firing forms a dielectric material comprising a barium-titanium-tungsten-silicon oxide.

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08-07-2021 дата публикации

ARTICLES COMPRISING CRYSTALLINE MATERIALS AND METHOD OF MAKING THE SAME

Номер: US20210206683A1
Принадлежит:

Methods for making articles comprising crystalline material. Exemplary articles made by a method described herein include electronics enclosure (e.g., a watch case, cellular phone case, or a tablet case). 1. A method of forming an article comprising:providing a preform having a volume and a first shape, the preform comprising nanocrystalline glass-ceramic;providing a mold comprising a cavity having a void volume in the range of 70 to 130 percent of the volume of the preform;placing at least a portion of the preform within the void volume of the mold; andheating the preform at sufficient temperature and under sufficient pressure to form an article comprising crystalline material and having a second, different shape,{'sub': 'g', 'wherein at least 90 percent by weight of the nanocrystalline glass-ceramic, based on the total weight of the nanocrystalline glass-ceramic, does not have a T.'}2. A method of forming an article comprising:providing a preform having a volume and a first shape, the preform comprising nanocrystalline glass-ceramic;providing a major surface;placing at least a portion of the preform in contact with the major surface; andheating the preform at sufficient temperature and sufficient pressure to form an article comprising crystalline material and having a second, different shape,{'sub': 'g', 'wherein at least 90 percent by weight of the nanocrystalline glass-ceramic, based on the total weight of the nanocrystalline glass-ceramic, does not have a T.'}31. The method of , wherein the mold further comprises at least one cavity port in fluid connection with the cavity.4. The method of claim 1 , wherein the nanocrystalline glass-ceramic collectively contains claim 1 , on a theoretical oxides basis claim 1 , less than 40 percent by weight SiO claim 1 , BO claim 1 , and PO claim 1 , based on the total weight of the nanocrystalline glass-ceramic.5. The method of claim 1 , wherein the heating is conducted in a range from 1000° C. to 1300° C. for a time of at ...

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08-07-2021 дата публикации

Method for manufacturing crystallized glass member having curved shape

Номер: US20210206684A1
Принадлежит: Ohara Inc

A method for manufacturing a crystallized glass member having a curved shape includes a deforming step of deforming at least a portion of a glass plate into a curved shape by an external force that acts on the glass plate while maintaining the temperature of the glass plate within a first temperature range and precipitating crystals from the glass plate. In the method for manufacturing a crystallized glass member having a curved shape according to Claim 1, the first temperature range is from [At −40]° C. to [At +40]° C., wherein At (° C.) is a yield point of the glass plate.

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04-06-2020 дата публикации

High index low density glass

Номер: US20200172425A1
Принадлежит: Corning Inc

A glass comprising greater or equal to 30.0 mol % SiO2, the glass being free of iron, lead, antimony ant tantalum oxides, and having a refractive index nd greater than or equal to 1.75 and a linear thermal expansion coefficient α20-300, in the temperature range 20-300° C., that is less than or equal to about 65×10−7 K−1.

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04-06-2020 дата публикации

High index glasses

Номер: US20200172426A1
Принадлежит: Corning Inc

A glass composition comprising: Al 2 O 3 , ZnO, and SiO 2 ; TiO 2 , in the amount of at least 10 mol % and not greater than 20 mol %; and alkaline metal oxide selected from the group consisting of MgO, CaO, SrO, BaO, or any combination thereof, such that the molar sum of MgO, CaO, SrO, BaO, and ZnO, in the amount in the glass composition is least 20 mol % and not greater than 35 mol %, and such that: the amount of BaO is 0 to 10 mol %; the amount of MgO is 0 to 10 mol % the amount of CaO is 0 to 10 mol %, and the molar sum of CaO and MgO in the glass composition is less than 12.5 mol %; and rare earth metal oxides (ΣRE m O n ), in the amount of at least 1.5 mol % and not greater than 10 mol %; alkali metal oxides (ΣAlk 2 O), in the amount of greater than or equal to 0 mol % and less than or equal to 5 mol %; and not greater than 5 mol % of other components; and wherein −5 mol %≤Al 2 O 3 (mol %)−1.5 ΣRE m O n (mol %)−ΣAlk 2 O (mol %)≤+5 mol %.

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04-06-2020 дата публикации

PROCESS FOR THE MANUFACTURE OF AN INSULATING PRODUCT BASED ON MINERAL FIBRES

Номер: US20200172435A1
Принадлежит:

A process for the manufacture of an insulating product based on mineral fibres bonded by an organic binder, includes applying a sizing composition to the mineral fibres, forming an assembly of the mineral fibres, heating the assembly of mineral fibres until the sizing composition has cured, wherein the sizing composition includes the following constituents within the limits defined below, expressed as fractions by weight with respect to the total weight of the composition: from 80% to 98% of water, from 2% to 20% of water-soluble poly(furfuryl alcohol) and less than 0.5% of furfuryl alcohol, and the mineral fibres are fibres of aluminosilicate glass including aluminum oxide, AlO, in a fraction by weight of between 14% and 28%. 1. A process for the manufacture of an insulating product based on mineral fibres bonded by an organic binder , comprising:a. applying a sizing composition to the mineral fibres,b. forming an assembly of the mineral fibres, 'wherein:', 'c. heating said assembly of mineral fibres until the said-sizing composition has cured,'} from 80% to 98% of water,', 'from 2% to 20% of water-soluble poly(furfuryl alcohol) and', 'less than 0.5% of furfuryl alcohol, and, 'the sizing composition comprises the following constituents within the limits defined below, expressed as fractions by weight with respect to the total weight of the composition{'sub': 2', '3, 'the mineral fibres are fibres of aluminosilicate glass comprising aluminium oxide, AlO, in a fraction by weight of between 14% and 28%.'}2. The process according to claim 1 , wherein the mineral fibres have a fraction by weight of SiOof between 32% and 50%.3. The process according to claim 1 , wherein a sum of the AlOand SiOfractions by weight of the mineral fibres is between 46% and 78%.4. The process according to claim 1 , wherein the mineral fibres have an Al/(Al+Si) molar ratio of greater than 0.25.5. The process according to claim 1 , wherein the mineral fibres additionally comprise the oxides CaO ...

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30-06-2016 дата публикации

GLASS COMPOSITIONS FOR ELECTROCONDUCTIVE PASTE COMPOSITIONS

Номер: US20160190361A1
Принадлежит:

This invention relates to glass compositions for use in forming an electroconductive paste composition. In one aspect of the invention, an electroconductive paste composition utilized in solar panel technology includes conductive metallic particles, an organic vehicle, and a glass composition comprising tellurium oxide (TeO), zinc oxide (ZnO), and lithium oxide (LiO).

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20-06-2019 дата публикации

Optical glass, optical element including optical glass, and optical apparatus

Номер: US20190185369A1
Принадлежит: Nikon Corp, University of Tokyo NUC

Provided is optical glass containing, in terms of mol % of cations: 10 to 60% of a La 3+ component; more than 0% and up to 75% of a Ga 3+ component; and 5 to 75% of a Nb 5+ component, in which a total amount of the La 3+ component, Ga 3+ component, and Nb 5+ component is 60 to 100%.

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11-06-2020 дата публикации

Ion exchangeable glass with high crack initiation threshold

Номер: US20200180999A1
Автор: Timothy Michael Gross
Принадлежит: Corning Inc

Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P 2 O 5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.

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14-07-2016 дата публикации

METHOD AND APPARATUS FOR ADDING THERMAL ENERGY TO A GLASS MELT

Номер: US20160200618A1
Принадлежит:

Disclosed herein are methods and apparatuses for adding thermal energy to a glass melt. Apparatuses for generating a thermal plasma disclosed herein comprise an electrode, a grounded electrode, a dielectric plasma confinement vessel extending between the two electrodes, and a magnetic field generator extending around the dielectric plasma confinement vessel. Also disclosed herein are methods for fining molten glass comprising generating a thermal plasma using the apparatuses disclosed herein and contacting the molten glass with the thermal plasma. Glass structures produced according to these methods are also disclosed herein. 1. An apparatus for generating a thermal plasma , comprising:an electrode,a grounded electrode,a dielectric plasma confinement vessel extending between the electrode and the grounded electrode,a magnetic field generator extending around the dielectric plasma confinement vessel,an inlet for delivering a gas into the dielectric plasma confinement vessel,an RF current source coupled to the electrode and the grounded electrode for converting the gas into a thermal plasma, andan outlet for delivering the thermal plasma.2. The apparatus of claim 1 , wherein the electrode and the grounded electrode comprise metal rings.3. The apparatus of claim 1 , wherein the inlet comprises a central jet and a peripheral annulus comprising a plurality of jets.4. The apparatus of claim 1 , wherein the RF current generates electric field lines parallel to a direction of gas flow in the dielectric plasma confinement tube and magnetic field lines orthogonal to the direction of gas flow.5. The apparatus of claim 1 , wherein the magnetic field generator generates magnetic field lines parallel to a direction of gas flow in the dielectric plasma confinement tube.6. The apparatus of claim 1 , wherein the thermal plasma comprises a core region having a first temperature ranging from about 9000K to about 11000K and a peripheral region having a second temperature ranging from ...

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25-09-2014 дата публикации

HIGHLY REFRACTIVE THIN GLASSES

Номер: US20140284577A1
Принадлежит: SCHOTT AG

Thin glasses having high refractive index (n), a layer composite assembly made from these thin glasses, a method for the production of the thin glasses, and the uses of the thin glasses are provided. The thin glasses are processed in an in line manufacturing process and have the optical properties of a classical optical glass. The thin glasses are highly transparent, crystallization-resistant, chemically resistant and highly refractive. The viscosity/temperature behavior of the thin glasses is adjusted to the manufacturing process via in line flat glass methods. 2. The thin glass according to claim 1 , wherein BOis present at a content of at least 6% by mol.4. The thin glass according to claim 3 , wherein BOis present at a content of at least 6% by mol.5. The thin glass according to claim 3 , further comprising a sum of the contents of BaO claim 3 , SrO claim 3 , CaO claim 3 , MgO claim 3 , and ZnO that is at least 30 and at most 50% by mol.6. The thin glass according to claim 3 , further comprising a sum of the contents of TiO claim 3 , ZrO claim 3 , YO claim 3 , LaO claim 3 , and NbOthat is at least 2.5 and at most 12% by mol.8. The thin glass according to claim 1 , further comprising at least one fire-polished surface.9. A layer composite assembly claim 1 , comprising the thin glass according to and at least one semiconductor layer.10. An OLED claim 1 , comprising the thin glass according to and at least one semiconductor layer.11. A substrate or superstrate claim 1 , comprising the thin glass according to .13. The method according to claim 12 , wherein BOis present in the glass mixture at a content of at least 6% by mol.15. The method according to claim 14 , wherein BOis present at a content of at least 6% by mol.16. The method according to claim 14 , further comprising a sum of the contents of BaO claim 14 , SrO claim 14 , CaO claim 14 , MgO claim 14 , and ZnO that is at least 30 and at most 50% by mol.17. The method according to claim 14 , further comprising a ...

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12-07-2018 дата публикации

OPTICAL GLASS AND OPTICAL COMPONENT

Номер: US20180194671A1
Принадлежит: Asahi Glass Company, Limited

Provided is an optical glass having a high refractive index, a low density, and good manufacturing properties. An optical glass having: a refractive index (n) of 1.68 to 1.85; a density (d) of 4.0 g/cmor less; and a temperature where a viscosity of glass becomes log η=2 of 950 to 1200° C., and an optical component using the optical glass are provided. This optical glass has the high refractive index, the low density, and the good manufacturing properties, and is suitable as the optical glass of wearable equipment, for a vehicle mounting, for a robot mounting, and so on. 115-. (canceled)16. An optical glass , comprising , in percentage by mass based on oxides:{'sub': 2', '5, 'NbO: 5% to 55%;'}{'sub': '2', 'SiO: 29% to 50%;'}{'sub': '2', 'TiO: 0% to 15%; and'}{'sub': 2', '2', '2, '2% to 20% of LiO+NaO+KO,'}{'sub': 2', '2', '2', '2, 'wherein LiO/(LiO+NaO+KO) is 0.45 or less, and'}wherein the optical glass has:{'sub': 'd', 'a refractive index (n) of 1.68 to 1.85;'}{'sup': '3', 'a density (d) of 4.0 g/cmor less;'}a devitrification temperature of 1200° C. or less; and{'sub': '2', 'a temperature Twhere a viscosity of glass becomes log η=2 of 950° C. to 1200° C.'}17. The optical glass according to claim 16 , containing claim 16 , in percentage by mass based on oxides:{'sub': 2', '2', '3', '2', '3, '0% to 30% of at least one kind selected from a group consisting of BaO, TiO, ZrO, WO, and LnO, where Ln is at least one kind selected from a group consisting of Y, La, Gd, Yb and Lu.'}18. The optical glass according to claim 17 , containing claim 17 , in percentage by mass based on oxides:{'sub': 2', '3, 'BO: 0% to 10%;'}MgO: 0% to 10%;CaO: 0% to 15%;SrO: 0% to 15%;BaO: 0% to 15%;{'sub': '2', 'LiO: 0% to 9%;'}{'sub': '2', 'NaO: 0% to 10%;'}{'sub': '2', 'KO: 0% to 10%;'}{'sub': 2', '3, 'AlO: 0% to 5%;'}{'sub': '3', 'WO: 0% to 15%;'}{'sub': '2', 'ZrO: 0% to 15%;'}ZnO: 0% to 15%; and{'sub': 2', '3, 'LaO: 0% to 12%.'}19. The optical glass according to claim 16 ,{'sub': '360', ' ...

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13-07-2017 дата публикации

Device for melting glass comprising a furnace, a channel and a barrier

Номер: US20170197859A1
Принадлежит: Saint Gobain Isover SA France

A device for melting glass includes a furnace equipped with electrodes in contact with the mass of vitrifiable materials. The furnace includes a side opening connected to a feeder channel for the molten glass, a removable barrier dipping into the glass in or before the opening so that a vertical plane passing through the upstream face of the barrier touches the biggest horizontal circle which can be inscribed the furthest downstream in the furnace, barrier excluded, the biggest circle being at the height of the highest side of the bottom of the channel. The device delivers a glass of good quality which can feed a fiberizing device.

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11-06-2020 дата публикации

CONDUCTIVE PASTE AND SOLAR CELL

Номер: US20200185548A1
Принадлежит: NAMICS CORPORATION

Provided is a conductive paste for forming bus bar electrodes having high adhesive strength with respect to a passivation film in a crystalline silicon solar cell without having a detrimental effect on the passivation film so as to affect solar cell properties. 1. A conductive paste for forming an electrode on a passivation film of a solar cell , the conductive paste comprising:(A) silver particles,(B) an organic vehicle, and{'sub': 2', '2', '3, '(C) a glass frit comprising TeOat 1.0 mol % to 20 mol % and BiOat 10 mol % to 30 mol %.'}2. The conductive paste according to claim 1 , wherein the specific surface area of the silver particles (A) is 0.4 m/g to 1.5 m/g.3. The conductive paste according to claim 1 , wherein the organic vehicle (B) comprises at least one of ethyl cellulose claim 1 , rosin ester claim 1 , butyral claim 1 , acrylic and organic solvent.4. The conductive paste according to claim 1 , wherein the glass frit (C) further comprises SiOat 5 mol % to 30 mol %.5. The conductive paste according to claim 1 , wherein the glass frit (C) further comprises ZnO at 10 mol % to 30 mol %.6. The conductive paste according to claim 1 , wherein the glass frit (C) further comprises AlOat 1 mol % to 10 mol %.7. The conductive paste according to claim 1 , wherein the glass frit (C) further comprises TiOat 1 mol % to 20 mol %.8. The conductive paste according to claim 1 , comprising at least one additive selected from titanium resinate claim 1 , titanium oxide claim 1 , cobalt oxide claim 1 , cerium oxide claim 1 , silicon nitride claim 1 , copper-manganese-tin claim 1 , aluminosilicate and aluminum silicate.9. The conductive paste according to claim 1 , wherein the conductive paste is a conductive paste for forming back side TAB electrodes.10. A solar cell in which electrodes are formed using the conductive paste according to .11. The solar cell according to claim 10 , wherein the specific surface area of the silver particles (A) in the conductive paste is 0.4 m/g to 1 ...

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29-07-2021 дата публикации

WAVELENGTH CONVERSION MEMBER, AND LIGHT EMITTING DEVICE USING SAME

Номер: US20210230047A1
Принадлежит:

Provided is a wavelength conversion member that is less decreased in luminescence intensity with time by irradiation with light of an LED or LD and a light emitting device using the wavelength conversion member. A wavelength conversion member is formed of an inorganic phosphor dispersed in a glass matrix, wherein the glass matrix contains, in % by mole, 30 to 85% SiO, 0 to 20% BO, 0 to 25% AlO, 0 to 3% LiO, 0 to 3% NaO, 0 to 3% KO, 0 to 3% LiO+NaO+KO, 0 to 35% MgO, 0 to 35% CaO, 0 to 35% SrO, 0 to 35% BaO, 0.1 to 45% MgO+CaO+SrO+BaO, and 0 to 4% ZnO, and the inorganic phosphor is at least one selected from the group consisting of an oxide phosphor, a nitride phosphor, an oxynitride phosphor, a chloride phosphor, an oxychloride phosphor, a halide phosphor, an aluminate phosphor, and a halophosphate phosphor. 1. A wavelength conversion member formed of an inorganic phosphor dispersed in a glass matrix , wherein{'sub': 2', '2', '3', '2', '3', '2', '2', '2', '2', '2', '2, 'the glass matrix contains, in % by mole, 30 to 85% SiO, 0 to 20% BO, 0 to 25% AlO, 0 to 3% LiO, 0 to 3% NaO, 0 to 3% KO, 0 to 3% LiO+NaO+KO, 0 to 35% MgO, 9.5 to 35% CaO, 0 to 35% SrO, 0 to 5% BaO, 9.5 to 45% MgO+CaO+SrO+BaO, and 0 to 4% ZnO, and'}the inorganic phosphor is at least one selected from the group consisting of an oxide phosphor, a nitride phosphor, an oxynitride phosphor, a chloride phosphor, an oxychloride phosphor, a halide phosphor, an aluminate phosphor, and a halophosphate phosphor.2. The wavelength conversion member according to claim 1 , wherein the glass matrix contains claim 1 , in % by mole claim 1 , 30 to 85% SiO claim 1 , 0 to 20% BO claim 1 , 0 to 25% AlO claim 1 , 0 to 3% LiO claim 1 , 0 to 3% NaO claim 1 , 0 to 3% KO claim 1 , 0 to 3% LiO+NaO+KO claim 1 , 0 to 35% MgO claim 1 , 9.5 to 35% CaO claim 1 , 0 to 35% SrO claim 1 , 0 to 5% BaO claim 1 , 9.5 to 45% MgO+CaO+SrO+BaO claim 1 , and 0 to below 1.8% ZnO.3. The wavelength conversion member according to claim 1 , ...

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06-08-2015 дата публикации

Glass and optical element production method

Номер: US20150218041A1
Принадлежит: Hoya Corp

[Problem] The transmittance of glass can be dramatically improved as a result of this glass production method. In addition, the amount of rare metal, such as platinum, that melts into glass can be greatly reduced. [Solution] A glass production method whereby the water content in molten glass is increased, in a melting step (i) in which a glass raw material including at least one type of component among TiO 2 , Nb 2 O 5 , WO 3 , and Bi 2 O 3 is heated inside a melting container and melted, and a molten glass is obtained.

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09-10-2014 дата публикации

Enamel And Ground Coat Compositions

Номер: US20140302331A1
Принадлежит: Ferro Corp

A composition that upon firing, forms a non-stick enamel layer is disclosed. The composition can be applied to a metal substrate to provide a non-stick, durable coating for cooking surfaces. Also disclosed are methods of forming enamel layers and corresponding coated substrates. Various ground coats and related methods are also described. Furthermore, various multilayer coatings and structures are disclosed that include an enamel layer and a ground coat layer.

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05-08-2021 дата публикации

COATED GLASS SUBSTRATE OR GLASS CERAMIC SUBSTRATE WITH RESISTANT MULTIFUNCTIONAL SURFACE PROPERTIES, METHOD FOR PRODUCTION THEREOF, AND USE OF THEREOF

Номер: US20210238085A1
Принадлежит: SCHOTT AG

The invention relates to a coated glass substrate or glass ceramic substrate with resistant, multi-functional surface properties, including a combination of anti-microbial, anti-reflective and anti-fingerprint properties, or a combination of anti-microbial, anti-reflective and anti-fingerprint properties where the substrate is chemically pre-stressed, or a combination of anti-microbial and anti-reflective properties where the substrate is chemically pre-stressed. The coated glass substrate or glass ceramic substrate exhibits a unique combination of functions which are permanently present and do not exert a negative effect on each other. 1. A thin glass ceramic substrate with a thickness that is less than 1 mm.2. The thin glass ceramic substrate according to claim 1 , wherein the thin glass ceramic substrate comprises at least one of a silicate glass claim 1 , an aluminosilicate glass claim 1 , a fluorosilicate glass claim 1 , a lithium aluminosilicate glass ceramic claim 1 , or a ceramized aluminosilicate glass.6. The thin glass ceramic substrate according to claim 1 , wherein the thin glass ceramic substrate comprises a glass which is totally or partially crystallized.7. The thin glass ceramic substrate according to claim 1 , wherein the thin glass ceramic substrate comprises an amorphous phase and one or several crystalline phases that are produced through crystallization control.8. The thin glass ceramic substrate according to claim 1 , wherein the thin glass ceramic substrate has a crystalline phase of at least 30 vol-%.9. The thin glass ceramic substrate according to claim 1 , wherein a glass ceramic of the thin glass ceramic substrate is obtained through conversion of a glass by utilizing a thermal treatment.10. The thin glass ceramic substrate according to claim 9 , wherein a crystal phase in the glass ceramic is selected from the group consisting of: lithium silicate claim 9 , enstatite claim 9 , wollastonite claim 9 , filled ß-quartz claim 9 , ß-spodumene ...

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03-08-2017 дата публикации

Aluminophosphate glass composition

Номер: US20170217828A1
Принадлежит: Schott Corp

The invention relates to phosphate-based glasses suitable for use as a solid laser medium, doped with Er3+ and sensitized with Yb, in “eye-safe” applications. In particular, the invention relates to improving the physical properties of such phosphate-based laser glass composition, particularly with regards to strength of the glass structure and improved thermal shock resistance.

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02-08-2018 дата публикации

LIGHT GUIDING PANEL AND LAMINATED LIGHT GUIDING PANEL USING SAME

Номер: US20180217317A1
Принадлежит:

A technical object of the present invention is to devise a light-guiding plate, which allows increase in resolution of a display image and reduction in weight of a device. In order to achieve the technical object, the light-guiding plate of the present invention includes a glass sheet having a refractive index nd of 1.56 or more, and having a thickness of 1.0 mm or less. 1. A light-guiding plate , comprising a glass sheet having a refractive index nd of 1.56 or more , and having a thickness of 1.0 mm or less.2. The light-guiding plate according to claim 1 , wherein an end surface of the glass sheet has an arithmetic surface roughness Ra of 1 μm or less.3. The light-guiding plate according to claim 1 , wherein an intersection angle formed by each of both surfaces of the glass sheet and an end surface of the glass sheet falls within a range of 90°±3°.4. The light-guiding plate according to claim 1 , wherein the glass sheet has an internal transmittance of 80% or more at an optical path length of 10 mm and a wavelength of 550 nm.5. The light-guiding plate according to claim 1 , wherein the glass sheet comprises as a glass composition claim 1 , in terms of mass % claim 1 , 10% to 60% of SiO claim 1 , 0% to 8% of AlO claim 1 , 10% to 40% of BaO claim 1 , and 3% to 30% of TiO+LaO claim 1 , and has a liquidus viscosity of 10dPa·s or more.6. The light-guiding plate according to claim 1 , wherein the glass sheet has a content of FeOof 0.05 mass % or less.7. The light-guiding plate according to claim 1 , wherein the glass sheet has a content of CrOof 0.0005 mass % or less.8. The light-guiding plate according to claim 1 , wherein the glass sheet has a waviness of 0.1 μm or less.9. The light-guiding plate according to claim 1 , wherein at least one surface of the glass sheet has an arithmetic surface roughness Ra of less than 0.5 nm.10. The light-guiding plate according to claim 1 , wherein at least one surface of the glass sheet has a pencil hardness of 3H or more.11. The ...

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11-08-2016 дата публикации

ION EXCHANGEABLE GLASS WITH HIGH CRACK INITIATION THRESHOLD

Номер: US20160229736A1
Автор: Gross Timothy Michael
Принадлежит:

Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % POand, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf. 155.-. (canceled)56. An alkali aluminosilicate glass comprising from about 40 mol % to about 70 mol % SiO; from about 11 mol % to about 25 mol % AlO; from about 4 mol % to about 15 mol % PO; and from about 13 mol % to about 20 mol % NaO , wherein:i. the alkali aluminosilicate glass is lithium-free; and{'sub': 2', '5', '2', '2', '3', '2', '3', '2', '3', '2', '3', '2, 'ii. 1.3<[(PO+RO)/MO]≦2.3, where MO=AlO+BOand RO is the sum of monovalent cation oxides present in the alkali aluminosilicate glass.'}57. The alkali aluminosilicate glass of claim 56 , wherein the alkali aluminosilicate glass comprises from about 50 mol % to about 65 mol % SiO; from about 14 mol % to about 20 mol % AlO; from about 4 mol % to about 10 mol % PO; and from about 14 mol % to about 20 mol % NaO.58. The alkali aluminosilicate glass of claim 56 , wherein the glass satisfies:{'br': None, 'sub': 2', '5', '2', '2', '3, '1.5<[(PO+RO)/MO]≦2.0.'}59. The alkali aluminosilicate glass of claim 56 , further comprising less than 1 mol % KO.60. The alkali aluminosilicate glass of claim 59 , wherein the alkali aluminosilicate glass comprises 0 mol % KO.61. The alkali aluminosilicate glass of claim 56 , wherein the alkali aluminosilicate glass further comprises less than 4 mol % BO.62. The alkali aluminosilicate glass of claim 61 , further comprising less than 1 mol % BO.63. The alkali aluminosilicate glass of claim 61 , wherein the alkali aluminosilicate glass comprises 0 mol % BO.64. The alkali aluminosilicate glass of claim 56 , wherein the monovalent cation oxides are selected from the group consisting of NaO claim 56 , KO claim 56 , RbO claim 56 , and CsO.65. The alkali aluminosilicate glass of claim 57 , wherein the alkali aluminosilicate ...

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18-08-2016 дата публикации

GLASS COMPOSITION FOR SEALING

Номер: US20160236967A1
Принадлежит:

Disclosed is a sealing glass composition substantially not containing BOor AlO, which is a high-strength, high-expansive crystallizing glass composition that can be used at high temperatures of not less than 950° C. The composition substantially not containing boron oxide, alkali metal oxides or aluminum oxide, but containing, in mol %, SiO: 40-55, BaO: 18-35, TiO+ZrO: 0.1-10, ZnO: 0-15, CaO: 0-20, MgO: 0-9, SrO: 0-5, and LaO: 0-2, wherein the total content of RO (R: Mg, Ca, Sr, Ba and Zn) is at least 44 mol %, and wherein the glass composition, when fired in the form of glass powder at a temperature of 850-1050° C., turns into a crystallized glass that exhibits a thermal expansion coefficient of 90-150×10/° C. in the range of 50-850° C. 7. The sealing glass composition of comprising one or more chemical species selected from CeO claim 1 , YbOand YOat 0-2 mol % in total.8. A glass powder consisting of the sealing glass composition of .9. The glass powder of claim 8 , wherein the mean particle size thereof is 2-25 μm.108. The glass powder of further containing a ceramic filler.11. A solid oxide fuel cell sealed with the fired body formed by firing the powder of . The present invention relates to a glass composition for use in providing a seal between metals, or a metal and a ceramic, and more specifically to such a sealing glass composition that is used as a sealant for sealing between each of solid oxide fuel cells (SOFC) and a metal to which it is fixed or between metals, as well as for exhaust gas sensors, and the like, as a sealant.While there are needs for a sealant used in solid oxide fuel cells (SOFC), it is prerequisite that such a sealant would neither degrade nor melt when exposed to high temperatures for an extended length of time, for it is a material which is to be exposed to temperatures as high as 600-800° C. for a long time. Crystallized glass has been proposed as a type of material meeting this requirement. It is also required for such a sealant to ...

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18-08-2016 дата публикации

TRANSPARENT GLASS-CERAMIC ARTICLES, GLASS-CERAMIC PRECURSOR GLASSES AND METHODS FOR FORMING THE SAME

Номер: US20160236970A1
Принадлежит:

Embodiments of glass ceramic articles and precursor glasses are disclosed. In one or more embodiments, the glass-ceramic articles are transparent and include a nepheline phase and a phosphate phase. The glass-ceramic articles are colorless and exhibit a transmittance of about 70% or greater across the visible spectrum. The glass-ceramic articles may optionally include a lithium aluminosilicate phase. The crystals of the glass-ceramic articles may have a major cross-section of about 100 nm or less. 1. A device comprising: a major nepheline phase; and', 'a minor phosphate phase,, 'a glass-ceramic article comprisingwherein the glass-ceramic article is colorless and has transmission or reflection color coordinates under the CIE L*, a*, b* colorimetry system of L* in the range from about 80 to about 100, a* in the range from about −5 to about 5, and b* in the range from about b* in the range from about −5 to about 5, and exhibits a transmittance of about 70% or greater across the visible spectrum, in the range from about 390 nm to about 700 nm,wherein the device comprises any one of an electronic device, an automotive application, an architectural applications and an energy production application.2. The device of claim 1 , wherein the device comprises an electronic device selected from the group comprising claim 1 , a mouse claim 1 , a keyboard claim 1 , a monitor claim 1 , a tablet claim 1 , a whiteboard claim 1 , a personal digital assistant claim 1 , a navigation device an inventory device claim 1 , a media player claim 1 , an electronic reader claim 1 , a mobile phone and a smart phone.3. The device of claim 2 , wherein the glass-ceramic article further comprises a lithium aluminosilicate phase.4. The device of claim 2 , wherein at least one of the nepheline phase and the phosphate phase comprises a plurality of nanocrystals having a major cross-sectional dimension of about 100 nm or less.5. The device of claim 4 , wherein the plurality of nanocrystals form at least ...

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17-08-2017 дата публикации

COATED GLASS SUBSTRATE OR GLASS CERAMIC SUBSTRATE WITH RESISTANT MULTIFUNCTIONAL SURFACE PROPERTIES, METHOD FOR PRODUCTION THEREOF, AND USE OF THEREOF

Номер: US20170233287A1
Принадлежит: SCHOTT AG

The invention relates to a coated glass substrate or glass ceramic substrate with resistant, multi-functional surface properties, including a combination of anti-microbial, anti-reflective and anti-fingerprint properties, or a combination of anti-microbial, anti-reflective and anti-fingerprint properties where the substrate is chemically pre-stressed, or a combination of anti-microbial and anti-reflective properties where the substrate is chemically pre-stressed. The coated glass substrate or glass ceramic substrate exhibits a unique combination of functions which are permanently present and do not exert a negative effect on each other. 1. A coated glass or glass ceramic substrate with resistant multifunctional surface properties , comprising:a glass or glass ceramic substrate; and displays a combination of antimicrobial, antireflective, and anti-fingerprint properties;', 'displays a combination of antimicrobial, antireflective, and anti-fingerprint properties, wherein said coated glass or glass ceramic substrate is chemically prestressed; and', 'displays a combination of antimicrobial and antireflective properties, wherein said coated glass or glass ceramic substrate is chemically prestressed., 'a coating including at least one layer applied to said substrate, wherein said coated glass or glass ceramic substrate one of2. The coated substrate according to claim 1 , wherein said coated glass or glass ceramic substrate incorporates at least one antimicrobially effective metal ion therein claim 1 , said chemical prestressing is produced through an ion exchange claim 1 , and said coating includes an antireflective coating including at least one antireflective layer applied to said glass or glass ceramic substrate and an anti-fingerprint coating including at least one anti-fingerprint layer applied to said at least one antireflective layer.3. The coated substrate according to claim 1 , wherein said coated glass or glass ceramic substrate also displays antiglare ...

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16-08-2018 дата публикации

SENSOR ELEMENT FOR DETECTING AT LEAST ONE PROPERTY OF A MEASURING GAS IN A MEASURING GAS CHAMBER INCLUDING A GLASS CERAMIC SEAL

Номер: US20180231495A1
Принадлежит:

A sensor element for detecting at least one property of a measuring gas in a measuring gas chamber, in particular for detecting a portion of a gas component in the measuring gas or a temperature of the measuring gas. The sensor element includes a first substrate, a second substrate, and a sensor chip. The sensor chip includes at least one solid electrolyte diaphragm, a first electrode, and a second electrode. The first substrate and the second substrate are connected to each other via at least one glass ceramic. The glass ceramic is manufactured from a material which includes at least SiO, MgO, AlO, as well as ZnO and/or BO. 110-. (canceled)11. A sensor element for detecting at least one property of a measuring gas in a measuring gas chamber , the sensor element being for one of detecting a portion of a gas component in the measuring gas or detecting a temperature of the measuring gas , the sensor element comprising:a first substrate;a second substrate; anda sensor chip including at least one solid electrolyte diaphragm, a first electrode, and a second electrode;{'sub': 2', '2', '3', '2', '3, 'wherein the first substrate and the second substrate are connected to each other with the aid of at least one glass ceramic, the glass ceramic being manufactured from a material which includes at least SiO, MgO, and AlO, and further includes at least one of ZnO and BO.'}12. The sensor element as recited in claim 11 , wherein a portion of the ZnO in the material is from 0 weight percent to 65 weight percent and a portion of the BOin the material is from 0 weight percent to 40 weight percent.13. The sensor element as recited in claim 11 , wherein the first substrate and the second substrate are bonded to each other in a hermetically sealed manner claim 11 , and are integrally joined.14. The sensor element as recited in claim 11 , wherein the glass ceramic is designed as a seal between the first substrate and the second substrate.15. The sensor element as recited in claim 11 , ...

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16-07-2020 дата публикации

GERMANOSILICATE GLASSES CONTAINING ZINC OXIDE

Номер: US20200223738A1
Принадлежит:

A glass composition comprises a germanosilicate glass containing 5-35 mol % ZnO. The glass composition has a relatively high refractive index, good glass-forming ability, and UV-shielding properties. 1. A composition comprising:a germanosilicate glass containing 5-35 mol % ZnO.2. The composition of claim 1 , wherein the glass contains 10-30 mol % ZnO.3. The composition of claim 1 , wherein the glass contains 15-25 mol % ZnO.4. The composition of claim 1 , wherein:{'sub': 2', '2', '2, 'the glass has a molar composition of aKO-bZnO-cGeO-dSiO;'}a, b, c, and d are mole percents;the sum of a, b, c, and d is between 95 and 100;a is between 5 and 35;b is between 5 and 35;c is between 25 and 55; andd is between 5 and 35.5. The composition of claim 4 , wherein:a is between 10 and 30;b is between 10 and 30;c is between 30 and 50; andd is between 10 and 30.6. The composition of claim 4 , wherein:a is between 15 and 25;b is between 15 and 25;c is between 35 and 45; andd is between 15 and 25.7. The composition of claim 1 , wherein the glass is free of a lanthanide or lanthanide compound.8. The composition of claim 7 , wherein the glass is free of holmium or thulium.9. The composition of claim 1 , wherein the glass has a density of 3.1 to 3.5 g/cm.10. The composition of claim 1 , wherein the glass has a refractive index of 1.5 to 1.7.11. The composition of claim 1 , wherein the glass has a UV cut-off edge greater than 300 nm.12. The composition of claim 11 , wherein the UV cut-off edge is between 300 and 350 nm.13. The composition of claim 1 , wherein the glass has a thermal expansion coefficient of 100×10to 150×10/° C.14. The composition of claim 1 , wherein the glass has an average optical transmittance from 390 to 700 nm of at least 75% at a thickness of 2 mm.15. The composition of claim 14 , wherein the glass has an average optical transmittance from 390 to 700 nm of 80 to 90% at a thickness of 2 mm.16. The composition of claim 1 , wherein the glass has an optical reflectance ...

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16-07-2020 дата публикации

TRANSPARENT GLASS-CERAMIC ARTICLES, GLASS-CERAMIC PRECURSOR GLASSES AND METHODS FOR FORMING THE SAME

Номер: US20200223744A1
Принадлежит:

Embodiments of glass ceramic articles and precursor glasses are disclosed. In one or more embodiments, the glass-ceramic articles are transparent and include a nepheline phase and a phosphate phase. The glass-ceramic articles are colorless and exhibit a transmittance of about 70% or greater across the visible spectrum. The glass-ceramic articles may optionally include a lithium aluminosilicate phase. The crystals of the glass-ceramic articles may have a major cross-section of about 100 nm or less.

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01-08-2019 дата публикации

GLASSES, CEMENTS AND USES THEREOF

Номер: US20190233322A1
Принадлежит:

Various embodiments of tantalum- and/or niobium-containing glasses and cements as well as uses thereof are described herein. For example, in an embodiment, the glasses comprise a transition metal pentoxide such as tantalum pentoxide and/or niobium pentoxide present in the glass in an amount of less than 2.0 mol %, based on the total composition of the glass, glass polyalkenoate cements prepared from such glasses and uses of such cements, for example, for sternal closure or fixation, stabilization and/or repair of a fracture in a bone in the wrist, elbow, knee, shoulder, spine and/or hip. 1. A glass comprising silicon dioxide (SiO) , zinc oxide (ZnO) , calcium oxide (CaO) , strontium oxide (SrO) , phosphorous pentoxide (PO) and a transition metal pentoxide selected from tantalum pentoxide (TaO) , niobium pentoxide (NbO) and mixtures thereof , wherein the transition metal pentoxide is present in the glass in an amount of less than 2.0 mol %.2. The glass of claim 1 , wherein{'sub': '2', 'the SiOis present in an amount of from about 35.0 mol % to about 60.0 mol %;'}the ZnO is present in an amount of from about 25.0 mol % to about 40.0 mol %;the CaO is present in an amount of from about 2.0 mol % to about 12.0 mol %;the SrO is present in an amount of from about 5.0 mol % to about 15.0 mol %; and{'sub': 2', '5, 'the POis present in an amount of from about 1.0 mol % to about 5.0 mol %.'}3. (canceled)4. The glass of claim 2 , wherein the transition metal pentoxide is present in an amount of from about 0.2 mol % to about 0.5 mol %.5. The glass of claim 4 , whereinthe ZnO is present in an amount of about 35.5 mol %; andthe transition metal pentoxide is present in an amount of about 0.5 mol %.6. The glass of claim 4 , whereinthe ZnO is present in an amount of about 35.8 mol %; andthe transition metal pentoxide is present in an amount of about 0.2 mol %.7. The glass of claim 4 , wherein the transition metal pentoxide is tantalum pentoxide (TaO).813-. (canceled)14. A glass ...

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13-11-2014 дата публикации

TRANSPARENT ALUMINATE GLASSES, VITROCERAMICS, AND CERAMICS

Номер: US20140336032A1
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The invention relates to novel transparent glasses, vitroceramics, and transparent or translucent ceramics containing, in relation to the total composition of the glass, vitroceramic, or ceramic, at least 60 wt% of a composition having the following formula (I): (M1O)x(M2O)y(M3)2O3)z(Al2O3)100−x−y−z (I), where M1 is an element selected from among Ba and/or Sr, M2 is an element selected from among Mg or Ca, x and y are numbers such that 30≦x+y≦80, y is between 0% and 10% of x, M3 is an element selected from among B, Ga, or In, and z is a number between 0% and 10% of (100−x−y). The invention also relates to the method for manufacturing said compositions and to the uses of said compositions in the field of optics. 5. The ceramic , glassceramic or glass according to one of the foregoing claims characterised in that x and y represent numbers such that 30 Подробнее

30-08-2018 дата публикации

OPTICAL GLASS

Номер: US20180244559A1
Принадлежит: Asahi Glass Company, Limited

Provided is an optical glass suitable for an imaging lens or the like used for a vehicle-mounted camera exposed to harsh environment, having a high refractive index and high strength, excellent crack resistance, and a sufficiently low glass transition point and devitrification temperature. In the optical glass, nd is 1.70 or more and 2.10 or less, Tg is 500° C. or more and 630° C. or less, the devitrification temperature is 1300° C. or less, a specific gravity is 4.0 g/cmor less, a crack initiation load (CIL) is 20 gf or more, and a fracture toughness value (Kc) is 0.60 MPa·mor more. 1. An optical glass , having:a refractive index (nd) of 1.70 to 2.10;a glass transition point (Tg) of 500° C. to 630° C.;a devitrification temperature of 1300° C. or less;{'sup': '3', 'a specific gravity of 4.0 g/cmor less;'}a crack initiation load (CIL) of 20 gf or more; and{'sup': '1/2', 'a fracture toughness value (Kc) measured by an indentation fracture method based on JIS R1607 of 0.60 MPa·mor more.'}2. The optical glass according to claim 1 , containing claim 1 , in mass % based on oxides:{'sub': 2', '5, 'NbO: 20% to 75%;'}{'sub': '2', 'SiO: 22% to 50%;'}{'sub': '2', 'TiO: 0% to 7%;'}{'sub': '2', 'ZrO: 0% to 20%;'}{'sub': '2', 'LiO: 1% to 20%;'}{'sub': '2', 'NaO: 1% to 18%;'}{'sub': '2', 'KO: 0.1% to 10%;'}ZnO: 0% to 15%;{'sub': 2', '5, 'PO: 0% to 5%;'}{'sub': 2', '3, 'BO: 0% to 6%; and'}F: 0% to 5%, wherein{'sub': 2', '2', 'z, 'LiO+NaO+KO is 5% to 30%, and'}{'sub': 2', '2', '2', '2, 'LiO/(LiO+NaO+KO) is 0.4 or more.'}3. The optical glass according to claim 2 , wherein{'sub': 2', '2', '2', '2, 'ZnO is 0% to 10%, and LiO/(LiO+NaO+KO) is 0.45 or more.'}4. The optical glass according to claim 2 , further containing claim 2 , in mass % based on oxides:{'sub': 2', '3, 'LaO: 0% to 15%;'}BaO: 0% to 4%, wherein{'sub': 2', '5', '2', '3, 'NbO—(LaO+BaO) is 10% to 75%.'}5. The optical glass according to claim 4 , wherein in mass % based on oxides claim 4 ,{'sub': 2', '5', '2', '3, 'NbO—(LaO+ ...

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30-08-2018 дата публикации

Frits for use in vacuum insulating glass (vig) units, and/or associated methods

Номер: US20180244562A1
Принадлежит: Guardian Glass LLC

Certain example embodiments of this invention relate to vacuum insulating glass (VIG) units having improved seals made using two different frit-based edge seal materials, and/or methods of making the same. In certain example embodiments, a first frit material is applied around peripheral edges of first and second glass substrates. The first frit material, which may be bismuth-based in certain example embodiments, is fired with a heat treatment (e.g., thermal tempering) process. A second frit material, which may be VBZ-based in certain example embodiments, is applied and at least partially overlaps with the fired first frit material. The first frit material acts as a primer, and the second frit material helps seal together the VIG unit. The second frit material is fired at a significantly lower temperature that enables the glass to retain the temper or other strength imparted by the heat treatment.

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20-11-2014 дата публикации

Glass Substrate

Номер: US20140342146A1
Принадлежит:

A glass substrate chemically strengthened, includes a primary surface that has a compressive stress layer formed in an uppermost surface layer thereof. The compressive stress layer is configured to enhance strength of the glass substrate due to a compressive stress generated in the compressive stress layer. The compressive layer consists of a layer of a potassium ion concentration equal to or less than 5000 parts per million (ppm). 1. A glass substrate usable for a cover glass of a mobile terminal device , comprising:a primary surface that comprises a compressive stress layer formed by chemically strengthening, the compressive stress layer containing potassium ions;wherein the compressive stress layer consists of a layer of a concentration of ion-exchanged) potassium ions equal to or less than 5000 parts per million (ppm); andwherein a thickness of the glass substrate is equal to or less than 0.7 mm.2. The glass substrate according to ;wherein the primary surface is a surface formed by etching.3. The substrate according to ;wherein the primary surface is formed with an ion exchange layer of a potassium ion concentration more than 5000 ppm being removed therefrom.4. The glass substrate according to ;wherein the chemically strengthening is low-temperature chemically strengthening.5. The glass substrate according to claim 1 , formed from molten glass by a down-draw method.6. The glass substrate according to claim 1 , configured with aluminosilicate glass that comprises at least one selected from the group consisting of SiO claim 1 , AlO claim 1 , LiO claim 1 , and NaO.7. The glass substrate according to claim 2 , comprising substantially no potassium oxide as glass ingredients. The present application is a continuation of U.S. patent application Ser. No. 12/647,098 filed on Dec. 24, 2009, which claims priority from JP 2008-333215 filed on Dec. 26, 2008, the disclosures of which are hereby incorporated by reference in their entirety.The following description relates to ...

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06-09-2018 дата публикации

OPTICAL GLASS

Номер: US20180251395A1
Принадлежит: Asahi Glass Company, Limited

Provided is an optical glass suitable for an imaging lens or the like used for a vehicle-mounted camera exposed to harsh environment, having a high refractive index and high strength. The optical glass has a strengthened layer at a surface layer, and a depth of the strengthened layer is 1 μm or more from a surface of the optical glass, and a refractive index (nd) of the optical glass is 1.73 to 2.10. 1. An optical glass , comprising:a strengthened layer at a surface layer, whereina depth of the strengthened layer is 1 μm or more from a surface of the optical glass, anda refractive index (nd) of the optical glass is 1.73 to 2.10.2. The optical glass according to claim 1 , whereina scratch resistance of the optical glass is 200 gf or more.3. The optical glass according to claim 1 , wherein claim 1 , in mass % based on oxides in a glass inside of the optical glass claim 1 ,{'sub': 2', '2, 'LiO+NaO is 5% or more,'}{'sub': 2', '2', '2, 'LiO+NaO+KO is 5% to 20%, and'}{'sub': 2', '2', '2', '2', '2', '2', '2', '2, 'LiO/(LiO+NaO+KO) or NaO/(LiO+NaO+KO) is 0.20 or more.'}4. The optical glass according to claim 1 , whereina glass transition point (Tg) is 520° C. to 600° C., and a devitrification temperature is 1300° C. or less.5. The optical glass according to claim 3 , wherein the glass inside of the optical glass contains claim 3 , in mass % based on oxides:{'sub': 2', '5, 'NbO: 20% to 75%;'}{'sub': '2', 'SiO: 10% to 50%;'}{'sub': '2', 'TiO: 0% to 20%;'}{'sub': '2', 'ZrO: 0% to 20%;'}{'sub': '2', 'LiO: 0% to 20%;'}{'sub': '2', 'NaO: 0% to 20%;'}{'sub': '2', 'KO: 0% to 10%;'}BaO: 0% to 20%;ZnO: 0% to 15%;{'sub': 2', '3, 'LnO: 0% to 50%;'}{'sub': 2', '3, 'LaO: 0% to 50%;'}{'sub': 2', '3, 'YO: 0% to 20%;'}{'sub': 2', '5, 'PO: 0% to 20%; and'}{'sub': 2', '3, 'BO: 0% to 20%, and'}a crack initiation load (CIL) of the optical glass is 100 gf or more.6. The optical glass according to claim 5 , whereinthe ZnO content is 0% to 10%.7. The optical glass according to claim 5 , wherein{' ...

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30-09-2021 дата публикации

PARTICLE MIXTURE, KIT, INK, METHODS AND ARTICLE

Номер: US20210300815A1
Принадлежит:

A particle mixture for forming an enamel comprising particles of a first glass frit and particles of a second glass frit; wherein the first glass frit comprises greater than 5 wt % silicon oxide (SiO) and less than 5 wt % boron oxide (BO); wherein the second glass frit comprises boron oxide (BO) and less than 5 wt % of silicon oxide (SiO); and wherein both the particles of the first glass frit and the particles of the second glass frit have a D90 particle size of less than 5 microns. Also described is an ink comprising the particle mixture, methods of preparing the ink, an article formed using the ink, and a kit comprising particles of the first and second glass frit. 1. A particle mixture for forming an enamel comprising particles of a first glass frit and particles of a second glass frit; wherein the first glass frit comprises greater than 5 wt % silicon oxide (SiO) and less than 5 wt % boron oxide (BO); wherein the second glass frit comprises boron oxide (BO) and less than 5 wt % of silicon oxide (SiO); and wherein both the particles of the first glass frit and the particles of the second glass frit have a D90 particle size of less than 5 microns , and wherein the particle mixture further comprises particles of a pigment.2. A particle mixture as claimed in wherein the first glass frit comprises:{'sub': '2', '>5 to ≤65 wt % SiO;'}≥0 to ≤50 wt % ZnO;{'sub': 2', '3, '≥10 to ≤80 wt % BiO; and'}{'sub': 2', '3, '≥0 to <5 wt % BO.'}3. A particle mixture as claimed in wherein the first glass frit comprises ≥10 to ≤65 wt % SiO claim 1 , preferably ≥15 to ≤50 wt % SiO.4. A particle mixture as claimed in wherein the second glass frit comprises:{'sub': 2', '3, '>1 to ≤25 wt % BO;'}≥5 to ≤30 wt % ZnO;{'sub': 2', '3, '≥40 to ≤70 wt % BiO;'}{'sub': '2', '≥0 to ≤30 wt % SnO;'}{'sub': 2', '3, '≥0 to ≤20 wt % AlO;'}{'sub': '2', '≥0 to <5 SiOwt %; and'}≥0 to ≤18 wt % alkali metal oxide.5. A particle mixture as claimed in wherein the second glass frit comprises ≥5 to ≤25 wt % BO ...

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