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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 31017. Отображено 100.
05-01-2012 дата публикации

Process for producing alkylated aromatic compounds and process for producing phenols

Номер: US20120004471A1
Принадлежит: Mitsui Chemicals Inc

According to a process of the invention, a ketone, an aromatic compound and hydrogen as starting materials are reacted together in a single reaction step to produce an alkylaromatic compound in high yield. A process for producing phenols in the invention includes a step of performing the above alkylation process and does not increase the number of steps compared to the conventional cumene process. The process for producing alkylated aromatic compounds includes reacting an aromatic compound such as benzene, a ketone such as acetone and hydrogen in the presence of a solid acid substance, preferably a zeolite, and a silver-containing catalyst.

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05-01-2012 дата публикации

Catalyst for producing para-substituted aromatic hydrocarbon and method for producing para-substituted aromatic hydrocarbon using the same

Номер: US20120004487A1
Принадлежит: JX Nippon Oil and Energy Corp

This invention relates to a novel catalyst which enables an efficient production of a high-purity para-substituted aromatic hydrocarbon even without conducting isomerization step and/or adsorption separation step, and more particularly to a catalyst for producing a para-substituted aromatic hydrocarbon, which is formed by coating an MFI-type zeolite having an SiO 2 /Al 2 O 3 ratio (molar ratio) of 20 to 5000 and a primary particle size of not more than 1 μm with a crystalline silicate and is characterized by having a pKa value as measured by a Hammett indicator of not less than −8.

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12-01-2012 дата публикации

Olefin production process

Номер: US20120010453A1
Принадлежит: Mitsui Chemicals Inc

A novel olefin production process is provided which can be established as an industrial and practical process capable of producing olefins by directly reacting a ketone and hydrogen in a single reaction step. In particular, a novel olefin production process is provided in which propylene is obtained with high selectivity by directly reacting acetone and hydrogen. The olefin production process according to the present invention includes reacting a ketone and hydrogen in the presence of at least one dehydration catalyst and a silver-containing catalyst, and the at least one dehydration catalyst is selected from metal oxide catalysts containing a Group 6 element, zeolites, aluminas and heteropoly acid salts in which part or all the protons in heteropoly acids are exchanged with metal cations.

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26-01-2012 дата публикации

Process for preparing aromatics from methane

Номер: US20120022310A1
Принадлежит: BASF SE

The present invention relates to a process for carrying out endothermic, heterogeneously catalyzed reactions in which the reaction of the starting materials is carried out in the presence of a mixture of inert heat transfer particles and catalyst particles, where the catalyst particles are regenerated in a nonoxidative atmosphere at regular intervals and the heat of reaction required is introduced by separating off the inert heat transfer particles, heating the heat transfer particles in a heating zone and recirculating the heated heat transfer particles to the reaction zone. The process of the invention is particularly suitable for the nonoxidative dehydroaromatization of C 1 -C 4 -aliphatics in the presence of zeolite-comprising catalysts.

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23-02-2012 дата публикации

Process for preparing organic compounds by a transition metal-catalysed cross-coupling reaction of an aryl-x, heteroaryl-x, cycloalkenyl-x or alkenyl-x compound with an alkyl, alkenyl, cycloalkyl or cycloalkenyl halide

Номер: US20120046471A1
Принадлежит: Saltigo GmbH

This invention relates to a process for preparing functionalized aryl, heteroaryl, cycloalkenyl, or alkenyl compounds, by a transition-metal-catalyzed cross-coupling reaction of a substituted or unsubstituted aryl-X, heteroaryl-X, cycloalkenyl-X or alkenyl-X compound with an alkyl, alkenyl, cycloalkyl or cycloalkenyl halide, where X is a halide, diazonium, tosylate (p-toluenesulphonate), mesylate (methanesulphonate) or triflate (trifluoromethanesulphonate) leaving group.

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01-03-2012 дата публикации

Process for selectively making olefins from energy dense alcohols

Номер: US20120053384A1
Принадлежит: US Department of Army

A process to perform selective catalytic oxidation of four-carbon alcohols to produce four-carbon olefins with yields greater than 90%. The process includes providing a supply of oxygen gas and a butanol fuel, atomizing and evaporating the fuel to produce a vapor, mixing the vapor with the oxygen to form a fuel mixture, reacting the fuel mixture in the presence of a heated solid Rh/Al 2 O 3 or Al 2 O 3 catalysts.

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08-03-2012 дата публикации

Zeolite-palladium complex, method for producing the same, catalyst containing the complex, and method for producing a coupling compound by using the catalyst

Номер: US20120059191A1
Принадлежит: Individual

There is provided a substance having much higher catalytic activity for a Suzuki-Miyaura coupling reaction than conventional heterogenous catalysts. The present invention provides a zeolite-palladium complex including USY-zeolite and Pd supported on the USY-zeolite, the Pd having a Pd—Pd coordination number of 4 or less and an oxidation number of 0.5 or less.

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29-03-2012 дата публикации

Removal of Hydrogen From Dehydrogenation Processes

Номер: US20120078024A1
Принадлежит: Fina Technology Inc

A process and system for dehydrogenating certain hydrocarbons is disclosed. The process includes contacting a dehydrogenatable hydrocarbon with steam in the presence of a dehydrogenation catalyst to form hydrogen and a dehydrogenated hydrocarbon. Some of the hydrogen is then removed and some of the remaining dehydrogenatable hydrocarbon is dehydrogenated.

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03-05-2012 дата публикации

Process for preparing a phenylcyclohexane

Номер: US20120108874A1
Принадлежит: BASF SE

The present invention relates to an improved process for preparing a substituted or unsubstituted phenylcyclohexane by catalytic hydrogenation of a substituted or unsubstituted biphenyl.

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10-05-2012 дата публикации

Multiple zeolite catalyst

Номер: US20120116139A1

The multiple zeolite catalyst is a catalytic composition used to convert C 9+ alkylaromatic hydrocarbons to BTX, particularly commercially valuable xylenes. The catalyst is formed by mixing at least two zeolites selected from mordenite, beta zeolite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, MAPO-36, SAPO-5, SAPO-11, SAPO-34, and SAPO-41, and adding at least one metal component selected from Group VIB and Group VIII of the Periodic Table of the Elements. The two zeolites should have different physical and chemical characteristics, such as pore size and acidity. An exemplary catalyst includes mordenite, ZSM-5, and 3 wt. % molybdenum. The transalkylation reaction may be conducted in one or more reactors with a fixed bed, moving bed, or radial flow reactor at 200-540° C., a pressure of 1.0-5.0 MPa, and liquid hourly space velocity of 1.0-5.0 per hour.

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17-05-2012 дата публикации

Methane aromatization catalyst, method of making and method of using the catalyst

Номер: US20120123176A1
Принадлежит: Shell Oil Co

A catalyst for converting methane to aromatic hydrocarbons is described herein. The catalyst comprises an active metal or a compound thereof, and an inorganic oxide support wherein the active metal is added to the support in the form of metal oxalate. The metal oxalate-derived catalyst exhibits superior performance in the conversion of methane-rich feed to aromatics products relative to catalysts prepared from non-oxalate metal precursors. A method of making the catalyst and a method of using the catalyst are also described.

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31-05-2012 дата публикации

Methods for producing fuels and solvents

Номер: US20120136185A1
Автор: David Bressler
Принадлежит: University of Alberta

Described herein are methods for producing fuels and solvents from fatty acid resources. Also disclosed herein are fuels and solvents produced by the methods described herein.

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07-06-2012 дата публикации

Process for producing aromatic hydrocarbon and transition-metal-containing crystalline metallosilicate catalyst for use in the production process

Номер: US20120142986A1

Provided is a process for producing an aromatic hydrocarbon efficiently at high yield from a lower hydrocarbon containing methane as a major component, and such a process for producing an aromatic hydrocarbon includes the step of reacting a lower hydrocarbon containing methane as a major component in the presence of a transition-metal-containing crystalline metallosilicate catalyst which is obtainable by supporting 5 to 25 parts by weight of a transition metal (X) on 100 parts by weight of a modified crystalline metallosilicate obtainable by subjecting a crystalline metallosilicate to a series of treatment (A) including a step (i) of eliminating part of a metal from the crystalline metallosilicate and a silylation step (ii).

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21-06-2012 дата публикации

Methods for removing unsaturated aliphatic hydrocarbons from a hydrocarbon stream using an acidic molecular sieve

Номер: US20120157739A1
Принадлежит: UOP LLC

Disclosed is a method for removing unsaturated aliphatic compounds from a hydrocarbon feed stream by contacting the hydrocarbon feed stream with an acidic molecular sieve to produce a hydrocarbon effluent stream having a lower unsaturated aliphatic content relative to the hydrocarbon feed stream. The hydrocarbon feed stream comprises an aromatic compound, a nitrogen compound, and an unsaturated aliphatic compound.

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12-07-2012 дата публикации

Process For Producing Cyclohexylbenzene

Номер: US20120178969A1
Принадлежит: ExxonMobil Chemical Patents Inc

In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted under hydroalkylation conditions with a catalyst system comprising a MCM-22 family molecular sieve and at least one hydrogenation metal. The conditions comprise a temperature of about 140° C. to about 175° C., a pressure of about 135 psig to about 175 psig (931 kPag to 1207 kPag), a hydrogen to benzene molar ratio of about 0.30 to about 0.65 and a weight hourly space velocity of benzene of about 0.26 to about 1.05 hr −1 .

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26-07-2012 дата публикации

Molecular Sieve Of MFS Framework Type With Controllable Average Size, Its Method of Making And Use

Номер: US20120190896A1
Принадлежит: ExxonMobil Chemical Patents Inc

A method of making a crystalline molecular sieve of MFS framework type, preferably ZSM-57, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure-directing-agent (R) and water, said alkali metal (M) comprising potassium, and having the following mole composition (expressed in terms of oxide): YO 2 :( p )X 2 O 3 :( q )OH − :( r )R:( s )H 2 O, wherein (p) is in the range from 0.005 to 0.05, (q) is in the range from 0.01 to 3, (r) is in the range from 0.03 to 2 and (s) is in the range from 10 to 75 (based on total weight of said synthesis mixture); wherein the crystals of molecular sieve formed having an average diameter (D) of less than or equal to 1.5 micron and an average thickness (T) of less than or equal to 300 nanometers.

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09-08-2012 дата публикации

Method for manufacturing catalyst

Номер: US20120203048A1
Принадлежит: Mitsubishi Chemical Corp

A method for manufacturing a catalyst, which comprises regenerating a catalyst comprising a zeolite as an active ingredient and having an ethylene conversion lowered through reaction of producing propylene by bringing into contact with ethylene in a vapor phase, by bringing the catalyst into contact with a gas which does not comprise oxygen and comprises hydrogen having a hydrogen partial pressure of 0.01 MPa or more as an absolute pressure thereof.

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06-09-2012 дата публикации

Molecular Sieve Composition (EMM-10), Its Method of Making, and Use for Hydrocarbon Conversions

Номер: US20120226084A1
Принадлежит: ExxonMobil Chemical Patents Inc

This invention relates to a process for hydrocarbon conversion comprising contacting a hydrocarbon feedstock with a crystalline molecular sieve, in its ammonium exchanged form or in its calcined form, under conversion conditions to form a conversion product, said crystalline molecular sieve comprising unit cells with MWW topology and is characterized by diffraction streaking from the unit cell arrangement in the c direction as evidenced by the arced hk0 patterns of electron diffraction pattern.

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20-09-2012 дата публикации

Methanation Reaction Methods Utilizing Enhanced Catalyst Formulations and Methods of Preparing Enhanced Methanation Catalysts

Номер: US20120238647A1
Принадлежит: ConocoPhillips Co

Enhanced mixed metal catalysts are provided which allow high conversions of carbon dioxide to methane, in some cases up to about 100% conversion. Methods of preparing enhanced mixed metal catalysts comprise a series of steps involving combining nickel and chromium salts with a nucleation promoter in a base environment to form a gel, allowing the gel to digest to form a solid and a mother liquor, isolating the solid, washing the solid, drying the solid, and thermally treating the solid to form a nickel-chromium catalyst. Methanation processes using the catalysts are also provided. The enhanced mixed metal catalysts provide more efficient conversion and lower operating temperatures for carbon dioxide methanation when compared to conventional methanation catalysts. Additionally, these enhanced catalyst formulations allow realization of higher value product from captured carbon dioxide.

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27-09-2012 дата публикации

Process for the conversion of mixed lower alkanes to aromatic hydrocarbons

Номер: US20120240467A1
Принадлежит: Individual

A process for the conversion of mixed lower alkanes into aromatics which comprises first reacting a mixed lower alkane feed comprising at least propane and ethane in the presence of an aromatization catalyst under reaction conditions which maximize the conversion of propane into first stage aromatic reaction products, separating ethane from the first stage aromatic reaction products, reacting ethane in the presence of an aromatization catalyst under reaction conditions which maximize the conversion of ethane into second stage aromatic reaction products, and optionally separating ethane from the second stage aromatic reaction products.

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27-09-2012 дата публикации

Method for producing n-propyl acetate

Номер: US20120245376A1
Принадлежит: Showa Denko KK

One object of the present invention is to provide a method for producing n-propyl acetate by the hydrogenation reaction with a hydrogenation catalyst, using an allyl acetate containing solution as a raw material, wherein the method can prevent the conversion rate of the substrate (allyl acetate) from decreasing with time and the product quality from deteriorating, and the present invention provides a method for producing n-propyl acetate including a first hydrogenation step in which a raw material solution containing allyl acetate and a hydrogen containing gas are reacted under a pressure P 1 of 1.0 MPa G (gage pressure) or more in the presence of a hydrogenation catalyst, to hydrogenate the allyl acetate to produce a hydrogenation reaction product containing n-propyl acetate: a gas-liquid separation step in which the hydrogenation reaction product is gas-liquid separated into to produce a crude n-propyl acetate solution containing n-propyl acetate: and a second hydrogenation step in which non-reacted allyl acetate contained in the crude n-propyl acetate solution is hydrogenated using hydrogen dissolved in the crude n-propyl acetate solution in the presence of a hydrogenation catalyst.

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11-10-2012 дата публикации

Production of lower olefins from synthesis gas

Номер: US20120259026A1

Disclosed is a process for the production of lower olefins by the conversion of a feed stream comprising carbon monoxide and hydrogen, and catalysts as used therein, such as a Fischer-Tropsch process. By virtue of the invention, lower olefins can be formed from synthesis gas, with high selectivity, and low production of methane. The catalysts used herein comprise an α-alumina support, and a catalytically active component that comprises iron-containing particles dispersed onto the support in at least 1 wt. %. The majority of the iron-containing particles is in direct contact with the α-alumina and is well-distributed thereon. Preferably, the iron-containing particles have an average particle size below 30 nm, and most preferably below 10 nm. The supported catalysts not only show a high selectivity, but also a high catalyst activity and chemical and mechanical stability.

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25-10-2012 дата публикации

Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes

Номер: US20120271089A1
Автор: Michael E. Wright
Принадлежит: US Department of Navy

A method and apparatus for dehydrating bio-1-alcohols to bio-l-alkenes with high selectivity. The bio-1-alkenes are useful in preparing high flashpoint diesel and jet biofuels which are useful to civilian and military applications. Furthermore, the bio-1-alkenes may be converted to biolubricants useful in the transporation sector and other areas requiring high purity/thermally stable lubricants.

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01-11-2012 дата публикации

Double-component modified molecular sieve with improved hydrothermal stability and production method thereof

Номер: US20120275994A1
Принадлежит: Petrochina Co Ltd

A method for producing double-component modified molecular sieve comprises adding molecular sieve to an aqueous solution containing phosphorus to form a mixture, allowing the mixture to react at pH of 1-10, temperature of 70-200° C. and pressure of 0.2-1.2 MPa for 10-200 min, and then filtering, drying and baking the resultant to obtain phosphorus-modified molecular sieve, and then adding the phosphorus-modified molecular sieve to an aqueous solution containing silver ions, allowing the phosphorus-modified molecular sieve to react with silver ions at 0-100° C. in dark condition for 30-150 min, and then filtering, drying and baking. The obtained double-component modified molecular sieve contains 88-99 wt % molecular sieve with a ratio of silica to alumina between 15 and 60, 0.5-10 wt % phosphorus (based on oxides) and 0.01-2 wt % silver (based on oxides), all based on dry matter. A catalyst produced from the double-component modified molecular sieve has improved hydrothermal stability and microactivity.

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01-11-2012 дата публикации

Process for the regeneration of hydrocarbon conversion catalysts

Номер: US20120277089A1
Принадлежит: Individual

The present invention provides a process for hydrocarbon conversion, especially for producing aromatic hydrocarbons, which comprises: (a) alternately contacting a hydrocarbon feed, especially a lower alkane feed, with a hydrocarbon conversion catalyst, especially an aromatization catalyst, under hydrocarbon conversion, especially aromatization reaction conditions, in a reactor for a short period of time, preferably 30 minutes or less, to produce reaction products and then contacting the catalyst with hydrogen-containing gas at elevated temperature for a short period of time, preferably 10 minutes or less, (b) repeating the cycle of step (a) at least one time, (c) regenerating the catalyst by contacting it with an oxygen-containing gas at elevated temperature and (d) repeating steps (a) through (c) at least one time.

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01-11-2012 дата публикации

Processes for Transalkylating Aromatic Hydrocarbons

Номер: US20120277512A1
Автор: Edwin P. Boldingh
Принадлежит: UOP LLC

A process for transalkylating aromatic hydrocarbon compounds, the process comprising introducing an aromatic hydrocarbon feed stream and a sulfur source to a transalkylation zone. The feed stream contacts a catalyst in the transalkylation zone in the presence of sulfur, and produces a reaction product stream comprising benzene and xylene. The invention includes methods to control the transalkylation process.

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08-11-2012 дата публикации

Dehydrogenation Process

Номер: US20120283494A1
Принадлежит: ExxonMobil Chemical Patents Inc

In a dehydrogenation process a hydrocarbon stream comprising at least one non-aromatic six-membered ring compound and at least one five-membered ring compound is contacted with a first catalyst comprising at least one metal component and at least one support and a second catalyst. The first catalyst is utilized to convert at least a portion of the at least one non-aromatic six-membered ring compound in the hydrocarbon stream to at least one aromatic compound and the second catalyst is utilized to convert at least a portion of the at least one five-membered ring compound in the hydrocarbon stream to at least one paraffin.

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22-11-2012 дата публикации

Catalyst and process for hydrogenating aromatics

Номер: US20120296111A1
Принадлежит: BASF SE

The present invention relates to an eggshell catalyst comprising an active metal selected from the group consisting of ruthenium, rhodium, palladium, platinum and mixtures thereof, applied to a support material comprising silicon dioxide, wherein the pore volume of the support material is 0.6 to 1.0 ml/g, determined by Hg porosimetry, the BET surface area is 280 to 500 m 2 /g, and at least 90% of the pores present have a diameter of 6 to 12 nm, to a process for preparing this eggshell catalyst, to a process for hydrogenating an organic compound which comprises at least one hydrogenatable group using the eggshell catalyst, and to the use of the eggshell catalyst for hydrogenating an organic compound.

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22-11-2012 дата публикации

Process for alkylation of toluene to form styrene and ethylbenzene

Номер: US20120296136A1
Автор: Sivadinarayana Chinta
Принадлежит: Fina Technology Inc

A process is disclosed for making styrene and/or ethylbenzene by reacting toluene with a C 1 source over a catalyst in at least one radial reactor to form a product stream comprising styrene and/or ethylbenzene.

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29-11-2012 дата публикации

Process for preparing an alkene

Номер: US20120302810A1
Принадлежит: Individual

A process for the preparation of an alkene from an oxygenate comprising contacting a reactant feedstream comprising at least one oxygenate reactant and water with a supported heteropolyacid catalyst at a temperature of at least 170° C., wherein the process is initiated using a start-up procedure comprising the following steps: (i) heating the supported heteropolyacid catalyst to a temperature of at least 220° C.; (ii) maintaining the heat-treated supported heteropolyacid catalyst of step (i) at a temperature of at least 220° C. for a time sufficient to remove bound water from the heteropolyacid component of the supported heteropolyacid catalyst; and (iii) whilst maintaining the supported heteropolyacid catalyst of step (ii) at a temperature of at least 220° C., contacting the supported heteropolyacid catalyst with the reactant feedstream having a temperature of at least 220° C.

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27-12-2012 дата публикации

Catalyst composition for direct conversion of ethanol to propylene

Номер: US20120330080A1
Принадлежит: Dow Global Technologies LLC

A process to prepare propylene showing desirably increased selectivity comprises contacting, at an elevated temperature, ethanol and a rhenium oxide-modified ZSM-5 zeolite catalyst, under conditions suitable to form propylene. The rhenium oxide-modified ZSM-5 zeolite catalyst may be prepared by impregnating, in an aqueous or organic medium, a ZSM-5 zeolite with a rhenium source, under conditions suitable to form a catalyst precursor, and calcining the catalyst precursor under conditions suitable to form a rhenium oxide-modified ZSM-5 zeolite catalyst.

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21-02-2013 дата публикации

Process for the Production of Light Olefins from Synthesis Gas

Номер: US20130046033A1
Автор: Cristina Ferrini
Принадлежит: Casale Chemicals SA

A new process for light-olefins production is disclosed. The process comprises the step of contacting syngas with a iron-based catalyst at a temperature in the range from 250° C. to 350° C. and at a pressure in the range from 10 bar to 40 bar. By so doing a production of light olefins with a selectivity of at least 80% is obtained.

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14-03-2013 дата публикации

Hydroisomerization and selective hydrogenation of feedstock in ionic liquid-catalyzed alkylation

Номер: US20130066121A1
Принадлежит: Chevron USA Inc

A process for producing alkylate comprising contacting a first hydrocarbon stream comprising at least one olefin having from 2 to 6 carbon atoms which contains 1,3-butadiene and 1-butene with a hydroisomerization catalyst in the presence of hydrogen under conditions favoring the simultaneous selective hydrogenation of 1,3-butadiene to butenes and the isomerization of 1-butene to 2-butene and contacting the resulting stream and a second hydrocarbon stream comprising at least one isoparaffin having from 3 to 6 carbon atoms with an acidic ionic liquid catalyst under alkylation conditions to produce an alkylate is disclosed.

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14-03-2013 дата публикации

Pre-carburized molybdenum-modified zeolite catalyst and use thereof for the aromatization of lower alkanes

Номер: US20130066126A1
Автор: Suman Kumar Jana
Принадлежит: Saudi Basic Industries Corp

The present invention relates to a method for producing a zeolite catalyst useful for aromatization of a lower alkane, a zeolite catalyst useful for aromatization of a lower alkane obtainable by said method and a process for aromatization of a lower alkane using the zeolite catalyst of the present invention.

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28-03-2013 дата публикации

Conversion of methylamine to olefin or mixture of olefins

Номер: US20130079576A1
Принадлежит: Dow Global Technologies LLC

Convert a methylamine (e.g. monomethylamine, dimethylamine and trimethylamine) to a mixture of olefins (e.g. ethylene, propylene and butylene) by placing the methylamine, optionally in a mixture with at least one of ammonia and an inert diluent, in contact with a microporous acidic silicoaluminophosphate catalyst or a microporous aluminosilicate catalyst.

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18-04-2013 дата публикации

Heavy alkylbenzene transalkylation operating cost reduction

Номер: US20130096357A1
Принадлежит: UOP LLC

A process for increasing the production of monoalkylbenzenes is presented. The process includes utilizing a transalkylation process to convert dialkylbenzenes to monoalkylbenzenes. The transalkylation process recycles a portion of the effluent stream from the transalkylation reactor back to the feed of the transalkylation reactor. The recycled dialkylbenzenes and a portion of the recycled benzene are converted to monoalkylbenzenes.

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02-05-2013 дата публикации

Process for reprocessing spent catalysts

Номер: US20130109560A1
Принадлежит: BASF SE

The invention relates to a process for reprocessing spent catalysts comprising rare earth metals, and to a process for producing a new styrene catalyst from a spent styrene catalyst.

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09-05-2013 дата публикации

Preparation of Alkyl Aromatic Compounds

Номер: US20130116492A1

Provided is a process for preparing alkyl aromatic compounds. The process comprises contacting an alkane under dehydrogenation conditions in the presence of a dehydrogenation catalyst, e.g., a pincer iridium catalyst, to form olefins, and then contacting the olefins generated with an aromatic compound under alkylation conditions. Both reactions are conducted in a single reactor, and occur simultaneously.

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23-05-2013 дата публикации

Production of renewable aromatic compounds

Номер: US20130130345A1
Принадлежит: JNF BIOCHEMICALS LLC

The invention provides a process for producing a variety renewable aromatic compounds such as benzene, toluene, xylenes, and cumene, as well as compounds derived from these including, for example, aniline, benzoic acid, cresol, cyclohexane, cyclohexanone, phenol and bisphenol A, toluene di-isocyanate, isophthalic acid, phthalic anhydride, terephthalic acid and dimethyl terephthalate. The invention also provides for renewable forms of these aromatic compounds.

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27-06-2013 дата публикации

Uzm-39 aluminosilicate zeolite

Номер: US20130164213A1
Принадлежит: UOP LLC

A new family of coherently grown composites of TUN and IMF zeotypes have been synthesized. These zeolites are represented by the empirical formula. Na n M m k+ T t Al 1−x E x Si y O z where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to TNU-9 and IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations.

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27-06-2013 дата публикации

Catalytic refining of terpenes of pulp origin

Номер: US20130165721A1
Принадлежит: STORA ENSO OYJ

Biobased p-cymene and methods of producing same, which can further be converted to terephtalate. Further, a method is described for converting crude sulfate turpentine recovered from chemical wood pulping into p-cymene and eventually to terephtalic acid of biological origin, and and products thereof respectively. In said method, both conversion and desulfurization is realized in one reaction step. The disclosure is also related to use of zeolite catalysts in said method.

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04-07-2013 дата публикации

"process for producing cycloalkylaromatic compounds"

Номер: US20130172514A1
Автор: Teng Xu, Wenyih F. Lai
Принадлежит: ExxonMobil Chemical Patents Inc

In a process for producing a cycloalkylaromatic compound, an aromatic compound, hydrogen and at least one diluent are supplied to a hydroalkylation reaction zone, such that the weight ratio of the diluent to the aromatic compound supplied to the hydroalkylation reaction zone is at least 1:100. The aromatic compound, hydrogen and the at least one diluent are then contacted under hydroalkylation conditions with a hydroalkylation catalyst in the hydroalkylation reaction zone to produce an effluent comprising a cycloalkylaromatic compound.

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04-07-2013 дата публикации

Supported nano sized zeolite catalyst for alkylation reactions

Номер: US20130172649A1
Принадлежит: Fina Technology Inc

A catalyst containing nanosize zeolite particles supported on a support material for alkylation reactions, such as the alkylation of benzene to form ethylbenzene, and processes using such a catalyst is disclosed.

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18-07-2013 дата публикации

Hydrogenation Process Using Catalyst Comprising Ordered Intermetallic Compound

Номер: US20130184507A1

The present invention relates to a process for the hydrogenation, in particular the selective hydrogenation of unsaturated hydrocarbon compounds using a hydrogenation catalyst comprising an ordered intermetallic compound. The ordered intermetallic compound comprises at least one metal of type A capable of activating hydrogen, and at least one metal of type B not capable of activating hydrogen, and the structure of the ordered intermetallic compound is such that at least one king of type A metals is mainly surrounded by atoms of the metal of type B. According to another aspect, the present invention is concerned with a catalyst comprising a support and the above ordered intermetallic compound supported on the support. According to still another aspect, the invention pertains to the use of a binary Pd—Ga ordered intermetallic compound as a catalyst. The hydrogenation process and catalysts of the present invention achieve a selectivity to the target compounds, e.g. in the selective hydrogenation of acetylene to ethylene, which is superior to the prior art.

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01-08-2013 дата публикации

Process for the preparation of a catalyst support

Номер: US20130197290A1
Принадлежит: Individual

Process for preparing a catalyst support which process comprises a) mixing pentasil zeolite having a bulk silica to alumina molar ratio in the range of from 20 to 150 with water, a silica source and an alkali metal salt, b) extruding the mixture obtained in step (a), c) drying and calcining the extrudates obtained in step (b), d) subjecting the calcined extrudates obtained in step (c) to ion exchange to reduce the alkali metal content, and e) drying the extrudates obtained in step (d); process for preparing a catalyst by furthermore impregnating such support with platinum in an amount in the range of from 0.001 to 0.1 wt % and tin in an amount in the range of from 0.01 to 0.5 wt %, each on the basis of total catalyst; ethylbenzene dealkylation catalyst obtainable thereby and a process for dealkylation of ethylbenzene which process comprises contacting feedstock containing ethylbenzene with such catalyst.

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15-08-2013 дата публикации

Fischer-tropsch catalyst regeneration

Номер: US20130210939A1
Принадлежит: GTL F1 AG

A process for the regeneration of deactivated catalyst from a Fischer-Tropsch synthesis reactor, the catalyst being a supported cobalt catalyst. The process comprises the following steps: a withdrawal step, in which a portion of deactivated catalyst together with liquid hydrocarbon is withdrawn from the reactor; a concentration step, in which the concentration of the catalyst in the liquid hydrocarbon is increased; a calcination step, in which the deactivated catalyst composition is subjected to an oxidising gas to oxidise carbonaceous material contained in the deactivated catalyst in to gaseous oxides of the components of the carbonaceous material; and a reactivation step, in which the deactivated catalyst composition is reactivated to produced a regenerated catalyst.

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05-09-2013 дата публикации

Silica composite, method for producing the same, and method for producing propylene using the silica composite

Номер: US20130231515A1
Принадлежит: Asahi Kasei Chemicals Corp

The present invention provides a method for producing a silica composite by the steps of: preparing a raw material mixture containing silica and zeolite; drying the raw material mixture to obtain a dried product; and calcining the dried product, wherein the method comprising the step of allowing the raw material mixture to contain phosphoric acid and/or phosphate or bringing a solution of phosphoric acid and/or phosphate into contact with the zeolite and/or the dried product, or a combination thereof to thereby adjust a phosphorus content in the silica composite to 0.01 to 1.0% by mass based on the total mass of the silica composite.

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12-09-2013 дата публикации

Method for tiered production of biobased chemicals and biofuels from lignin

Номер: US20130232852A1
Принадлежит: Thesis Chemistry LLC

The present invention is directed generally to a method of production of value-added, biobased chemicals from lignin sources, including waste lignin. A method of using a depolymerization of lignin to create a tiered production of biobased aromatic chemicals and biofuels is also described herein. The method described herein may also allow for the selective production of the biobased aromatic chemicals and biofuels. Additionally, a reduction of waste products may also be provided from the present method.

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12-09-2013 дата публикации

Process for producing cumene

Номер: US20130237730A1

A process of producing isopropyl benzene which solves the problem of high amount of n-propyl benzene according to the prior art. The process separates the polyisopropyl benzene through a suitable rectification into two streams of relatively lighter and heavier components, wherein the content of diisopropylbenzene in the stream of relatively lighter components is controlled to be at least greater than 95 wt %, and the content of tri-isopropyl benzene in the stream of relatively heavier components is controlled to be at least greater than 0.5 wt %. Such a technical solution subjecting the two streams respectively to the transalkylation solves the problem raised from the prior art, and is useful for the industrial production of isopropyl benzene.

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19-09-2013 дата публикации

Catalyst for hydrocarbon steam cracking, method of preparing the same and method of preparing olefin by using the same

Номер: US20130244868A1
Принадлежит: LG Chem Ltd

The present invention relates to a catalyst for hydrocarbon steam cracking, a method of preparing the same, and a method of preparing olefin by the hydrocarbon steam cracking by using the catalyst, and more specifically, to a catalyst for hydrocarbon steam cracking for preparing light olefin including an oxide catalyst (0.5≦j≦120, 1≦k≦50, A is transition metal, and x is a number satisfying conditions according to valence of Cr, Zr, and A and values of j and k) represented by CrZr j A k O x , wherein the composite catalyst is a type that has an outer radius r 2 of 0.5 R to 0.96 R (where R is a radius of a cracking reaction tube), a thickness (t; r 2 −r 1 ) of 2 to 6 mm, and a length h of 0.5 r 2 to 10 r 2 , a method of preparing the same, and a method of preparing light olefin by using the same.

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19-09-2013 дата публикации

Production of propylene via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by metathesis

Номер: US20130245348A1
Принадлежит: Total Research and Technology Feluy SA

The present invention relates to a process for the production of propylene in which in a first step isobutanol is subjected to a simultaneous dehydration and skeletal isomerisation to make substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene and in a second step n-butenes are subjected to methathesis, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerase at least a portion of the isobutanol to make a mixture of n-butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, d) fractionating said mixture to produce a n-butenes stream (N) and to remove the essential part of isobutene optionally recycled with stream (A) to the dehydration/isomerization reactor of step b), e) sending the stream (N) to a methathesis reactor and contacting stream (N) with a catalyst in said methathesis reactor, optionally in the presence of ethylene, at conditions effective to produce propylene, f) recovering from said methathesis reactor a stream (P) comprising essentially propylene, unreacted n-butenes, heavies, optionally unreacted ethylene, g) fractionating stream (P) to recover propylene and optionally recycling unreacted n-butenes and unreacted ethylene to the methathesis reactor.

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03-10-2013 дата публикации

Dehydrogenation of alkanols to increase yield of aromatics

Номер: US20130261361A1
Принадлежит: Virent Inc

The present invention provides methods, reactor systems, and catalysts for increasing the yield of aromatic hydrocarbons produced while converting alkanols to hydrocarbons. The invention includes methods of using catalysts to increase the yield of benzene, toluene, and mixed xylenes in the hydrocarbon product.

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31-10-2013 дата публикации

Method of carrying out cc-coupling reactions

Номер: US20130289321A1
Принадлежит: Universite Catholique de Louvain UCL

The present invention is directed to a method of carrying out Suzuki-Miyaura CC-coupling reactions, including reacting an aryl halide with an aryl boronic acid in an organic solvent in the presence of a carbon supported palladium catalyst and a base, wherein the reactions are carried out at constant pH. The invention is also directed to a palladium on carbon catalyst suitable for catalyzing Suzuki-Miyaura CC-coupling reactions.

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31-10-2013 дата публикации

Catalyst for producing monocyclic aromatic hydrocarbon and production method of monocyclic aromatic hydrocarbon

Номер: US20130289325A1
Принадлежит: JX Nippon Oil and Energy Corp

The catalyst for producing aromatic hydrocarbon is for producing monocyclic aromatic hydrocarbon having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower and contains crystalline aluminosilicate and phosphorus. A molar ratio (P/Al ratio) between phosphorus contained in the crystalline aluminosilicate and aluminum of the crystalline aluminosilicate is from 0.1 to 1.0. The production method of monocyclic aromatic hydrocarbon is a method of bringing oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower into contact with the catalyst for producing monocyclic aromatic hydrocarbon.

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14-11-2013 дата публикации

Catalyst for the hydrogenation of unsaturated hydrocarbons and process for its preparation

Номер: US20130303812A1
Принадлежит: Shell Oil Co

The present invention relates to a catalyst for the hydrogenation of unsaturated hydrocarbons, in particular aromatics with a broad molecular weight range, a process for the production thereof and a process for hydrogenating unsaturated hydrocarbons.

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14-11-2013 дата публикации

Process for conversion of lower aliphatic ethers to aromatics and lower olefins

Номер: US20130303814A1
Принадлежит: Saudi Basic Industries Corp

The invention relates to a process for converting a feed stream consisting of reactive components and an optional feed diluent to a product stream comprising aromatic hydrocarbons and C2-C3 olefins, wherein the reactive components comprise at least 90 vol % of an aliphatic ether selected from the group consisting of methyl tertiary butyl ether and ethyl tertiary butyl ether, the process comprising the step of contacting the feed stream with a catalyst composition comprising a zeolite catalyst, wherein the zeolite catalyst is a zeolite modified by Ga and an element M1 selected from the group consisting of Zn, Cd and Cu.

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28-11-2013 дата публикации

Nickel-M-Alumina Xerogel Catalyst, Method for Preparing the Same, and Method for Preparing Methane Using the Catalyst

Номер: US20130317127A1
Принадлежит: Posco Co Ltd

A nickel-M-alumina hybrid xerogel catalyst for preparing methane, wherein the metal M is at least one element selected from the group consisting of Fe, Co, Ni, Ce, La, Mo, Cs, Y, and Mg, a method for preparing the catalyst and a method for preparing methane using the catalyst are provided. The catalyst has strong resistance against a high-temperature sintering reaction and deposition of carbon species, and can effectively improve a conversion ratio of carbon monoxide and selectivity to methane.

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28-11-2013 дата публикации

Methods for co-production of alkylbenzene and biofuel from natural oils using hydrocracking

Номер: US20130317267A1
Принадлежит: UOP LLC

Embodiments of methods for the production of linear alkylbenzene and optionally biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form paraffins. A first portion of the paraffins is hydrocracked to form a first stream of normal and lightly branched paraffins in the C 9 to C 14 range and a second stream of isoparaffins. The first stream is dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. Optionally a second portion of the paraffins and the isoparaffins are processed to form biofuel.

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28-11-2013 дата публикации

Manganese Oxides and Their Use in the Oxidation of Alkanes

Номер: US20130317272A1
Принадлежит: ExxonMobil Chemical Patents Inc

Catalytic structures are provided comprising octahedral tunnel lattice manganese oxides ion-exchanged with metal cations or mixtures thereof. The structures are useful as catalysts for the oxidation of alkanes and may be prepared by treating layered manganese oxide under highly acidic conditions, optionally drying the treated product, and subjecting it to ion exchange.

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28-11-2013 дата публикации

Process for non-oxidative dehydrogenation of alkane

Номер: US20130317273A1
Принадлежит: Saudi Basic Industries Corp

The invention relates to a process for producing an alkene by non-oxidative dehydrogenation of an alkane, comprising contacting a feed stream comprising the alkane with a catalyst composition comprising an unsupported catalyst comprising ZrV 2 O 7 at a temperature of 400 to 600° C.

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26-12-2013 дата публикации

Reduction of c-0 bonds by catalytic transfer hydrogenolysis

Номер: US20130345445A1
Принадлежит: KAT2BIZ AB

The present invention relates to a method of reducing a C—O bond to the corresponding C—H bond in a substrate which could be a benzylic alcohol, allylic alcohol, ester, or ether or an ether bond beta to a hydroxyl group or alpha to a carbonyl group.

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26-12-2013 дата публикации

Alkylation Process Using Phosphonium-Based Ionic Liquids

Номер: US20130345482A1
Принадлежит: UOP LLC

A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary phosphonium based ionic liquid, and the reaction is performed at or near ambient temperatures.

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26-12-2013 дата публикации

Alkylation Process Using Phosphonium-Based Ionic Liquids

Номер: US20130345483A1
Принадлежит: UOP LLC

A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary phosphonium based ionic liquid, and the reaction is performed at or near ambient temperatures.

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26-12-2013 дата публикации

Alkylation Process Using Phosphonium-Based Ionic Liquids

Номер: US20130345484A1
Принадлежит: UOP LLC

A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary chloroaluminate based ionic liquid, and the reaction is performed at or near ambient temperatures.

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02-01-2014 дата публикации

Metallophosphate molecular sieves, methods of preparation and use

Номер: US20140004024A1
Принадлежит: UOP LLC

A new family of crystalline microporous metallophosphates designated AlPO-57 has been synthesized. These metallophosphates are represented by the empirical formula R + r M m n+ EP x Si y O z where R is an organoammonium cation such as the DEDMA + , M is a divalent framework metal such as an alkaline earth or transition metal, and E is a framework element such as aluminum or gallium. The microporous AlPO-57 compositions are characterized by a new unique ABC-6 net structure and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

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02-01-2014 дата публикации

Process for making isooctenes from aqueous isobutanol

Номер: US20140005443A1
Принадлежит: EI Du Pont de Nemours and Co

The present invention relates to a catalytic process for making isooctenes using a reactant comprising isobutanol and water. The isooctenes so produced are useful for the production of fuel additives.

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23-01-2014 дата публикации

Process for treating an output from a hydrocarbon conversion with removal of hydrogen halides and subsequent wash

Номер: US20140024875A1
Принадлежит: BASF SE

The present invention relates to a process for treating an output from a hydrocarbon conversion, wherein the hydrocarbon conversion is performed in the presence of an acidic ionic liquid. The hydrocarbon conversion is preferably an isomerization. First of all, the hydrogen halide is drawn off in an apparatus from a mixture which originates from the hydrocarbon conversion and comprises at least one hydrocarbon and at least one hydrogen halide, and then the mixture depleted of hydrogen halide is subjected to a wash.

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13-02-2014 дата публикации

Isomerization of light alpha-olefins to light internal olefins

Номер: US20140046110A1
Принадлежит: BASF SE

The present invention relates to a process for isomerizing linear alpha-olefins having from 4 to 8 carbon atoms over a heterogeneous catalyst, wherein the catalyst comprises a hydrogenation metal and a selectivity promoter selected from among selenium and tellurium on a support, and also a process for preparing 1-olefins by a metathesis reaction of 2-olefins with ethene, wherein the 2-olefins are prepared by the above mentioned isomerization process.

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27-02-2014 дата публикации

3,3',4,4'-tetraalkyl cyclohexylbenzene and method for producing same

Номер: US20140058143A1
Принадлежит: UBE Industries Ltd

The present invention relates to a 3,3′,4,4′-tetraalkyl cyclohexylbenzene represented by the general formula (1): wherein R represents an alkyl group having 1 to 4 carbon atoms, which may be easily converted into a 3,3′,4,4′-biphenyltetracarboxylic acid and a 3,3′,4,4′-biphenyltetracarboxylic dianhydride thereof, which are a starting material for a polyimide, via a 3,3′,4,4′-tetraalkylbiphenyl; and a method for producing the same.

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06-03-2014 дата публикации

Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization

Номер: US20140066681A1
Принадлежит: Lummus Technology Inc

A process for the double-bond isomerization of olefins is disclosed. The process may include contacting a fluid stream comprising olefins with a fixed bed comprising an activated basic metal oxide isomerization catalyst to convert at least a portion of the olefin to its isomer. The isomerization catalysts disclosed herein may have a reduced cycle to cycle deactivation as compared to conventional catalysts, thus maintaining higher activity over the complete catalyst life cycle.

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20-03-2014 дата публикации

Even carbon number paraffin composition and method of manufacturing same

Номер: US20140081057A1
Принадлежит: Syntroleum Corp

Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.

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27-03-2014 дата публикации

Process for producing 1,3-butadiene by dimerizing ethylene and dehydrogenating the butenes obtained

Номер: US20140088331A1
Автор: Gildas Rolland
Принадлежит: Axens SA

The present invention describes a process for the production of 1,3-butadiene from ethylene by dimerizing ethylene into butenes using homogeneous catalysis and dehydrogenating the butenes obtained.

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10-04-2014 дата публикации

Low pressure transalkylation process

Номер: US20140100403A1
Принадлежит: UOP LLC

A process for transalkylation is described. The process operates at a lower pressure than a typical transalkylation processes, and provides higher benzene purity with comparable or lower ring loss compared to the typical transalkylation process. The xylene selectivity is comparable to or higher than the standard process, and the ethyl benzene selectivity is comparable to or lower than the standard process.

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06-01-2022 дата публикации

PROCESS AND CATALYST FOR LOW TEMPERATURE NON-OXIDATIVE DEHYDROGENATION OF PROPANE TO PROPYLENE

Номер: US20220001359A1
Принадлежит:

A process and catalyst are provided for the non-oxidative dehydrogenation of propane for the production of propylene as petrochemical building blocks. The process provides a direct single-step gas-phase dehydration of propane mixed with nitrogen in the presence and absence of steam/hydrogen over supported bimetallic alumina-silicates zeolites. The catalyst contains no precious metal entities and may contain one metal from group VIB in combination with another metal from group IIIA or IVA supported on FAU, MFI, KFI, BEA type alumina-silicates zeolites. The process provides a propane conversion of 18% to 52% with a propylene yield of 10% to 25%. 1. A catalyst composition comprising:(a) a porous alumina-silicates zeolite Faujasite (FAU), Zeolite Mobil type Five (MFI), Zeolite Kerr Five (KFI) and Zeolite Beta polymorph A (BEA) as catalyst support;(b) a first metal selected from transition metals of group VIB, wherein the amount of the first metal is from 1 wt % to 10 wt % based on the porous zeolite catalyst support;(c) a second metal selected from a metals of group IIIA or IVA, wherein the amount of the second metal is from 1 wt % to 8 wt % based on the porous zeolite catalyst support; and(d) an alkaline metal, wherein the amount of alkaline metal from 0.5 wt % to 2 wt % based on the porous zeolite catalyst support.2. The catalyst of claim 1 , wherein the transition metal is selected from the group consisting of molybdenum claim 1 , chromium claim 1 , and tungsten.3. The catalyst of claim 1 , wherein the second metal is selected from the group consisting of tin claim 1 , gallium claim 1 , and indium.4. The catalyst of claim 1 , wherein the alkaline metal is selected from the group consisting of sodium claim 1 , potassium claim 1 , and cesium.6. The process of claim 5 , wherein the first metal is selected from the group consisting of molybdenum claim 5 , chromium claim 5 , and tungsten.7. The process of claim 5 , wherein the second metal is selected from the group ...

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07-01-2021 дата публикации

Catalyst for Ethylbenzene Conversion in a Xylene Isomerization Process

Номер: US20210001312A1
Принадлежит: BP Amoco Chemicals Corp

The present invention relates to a method for converting a feed mixture comprising an aromatic C8 mixture of xylenes and ethylbenzene in which the para-xylene content of the xylene portion of the feed is less than equilibrium to produce a product mixture of reduced ethylbenzene content and a greater amount of para-xylene, which method comprises contacting the feed mixture at conversion conditions with a first catalyst having activity for the conversion of ethylbenzene, and with a second catalyst having activity for the isomerization of a xylene.

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07-01-2021 дата публикации

METHODS FOR PRODUCING MULTIFUNCTIONAL CATALYSTS FOR UPGRADING PYROLYSIS OIL

Номер: US20210001320A1
Автор: SUN Miao
Принадлежит: Saudi Arabian Oil Company

A method of making a multifunctional catalyst for upgrading pyrolysis oil includes contacting a zeolite support with a solution including at least a first metal catalyst precursor and a second metal catalyst precursor, the first metal catalyst precursor, the second metal catalyst precursor, or both, including a heteropolyacid. Contacting the zeolite support with the solution deposits or adsorbs the first metal catalyst precursor and the second catalyst precursor onto outer surfaces and pore surfaces of the zeolite support to produce a multifunctional catalyst precursor. The method further includes removing excess solution from the multifunctional catalyst precursor and calcining the multifunctional catalyst precursor to produce the multifunctional catalyst comprising at least a first metal catalyst and a second metal catalyst deposited on the outer surfaces and pore surfaces of the zeolite support. 110-. (canceled)11. A multifunctional catalyst produced by a method of making a multifunctional catalyst for upgrading pyrolysis oil , the method comprising:contacting a zeolite support with a solution comprising at least a first metal catalyst precursor and a second metal catalyst precursor, the first metal catalyst precursor, the second metal catalyst precursor, or both, comprising a heteropolyacid, where the contacting deposits the first metal catalyst precursor and the second metal catalyst precursor onto outer surfaces and pore surfaces of the zeolite support to produce a multifunctional catalyst precursor;removing excess solution from the multifunctional catalyst precursor; andcalcining the multifunctional catalyst precursor to produce the multifunctional catalyst comprising at least a first metal catalyst and a second metal catalyst deposited on the outer surfaces and pore surfaces of the zeolite support.12. The multifunctional catalyst of claim 11 , in which the first metal catalyst comprises molybdenum and the second metal catalyst comprises cobalt.13. The ...

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07-01-2021 дата публикации

METHODS FOR PRODUCING MULTIFUNCTIONAL CATALYSTS FOR UPGRADING PYROLYSIS OIL

Номер: US20210001321A1
Автор: SUN Miao
Принадлежит: Saudi Arabian Oil Company

A method of making a multifunctional catalyst for upgrading pyrolysis oil includes contacting a zeolite support with a solution including at least a first metal catalyst precursor and a second metal catalyst precursor, the first metal catalyst precursor, the second metal catalyst precursor, or both, including a heteropolyacid. Contacting the zeolite support with the solution deposits or adsorbs the first metal catalyst precursor and the second catalyst precursor onto outer surfaces and pore surfaces of the zeolite support to produce a multifunctional catalyst precursor. The method further includes removing excess solution from the multifunctional catalyst precursor and calcining the multifunctional catalyst precursor to produce the multifunctional catalyst comprising at least a first metal catalyst and a second metal catalyst deposited on the outer surfaces and pore surfaces of the zeolite support. 110-. (canceled)11. A multifunctional catalyst produced by a method of making a multifunctional catalyst for upgrading pyrolysis oil , the method comprising:contacting a zeolite support with a solution comprising at least a first metal catalyst precursor and a second metal catalyst precursor, the first metal catalyst precursor, the second metal catalyst precursor, or both, comprising a heteropolyacid, where the contacting deposits the first metal catalyst precursor and the second metal catalyst precursor onto outer surfaces and pore surfaces of the zeolite support to produce a multifunctional catalyst precursor;removing excess solution from the multifunctional catalyst precursor; andcalcining the multifunctional catalyst precursor to produce the multifunctional catalyst comprising at least a first metal catalyst and a second metal catalyst deposited on the outer surfaces and pore surfaces of the zeolite support.12. The multifunctional catalyst of claim 11 , in which the first metal catalyst comprises molybdenum and the second metal catalyst comprises cobalt.13. The ...

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07-01-2016 дата публикации

ALUMINA MATERIALS WITH INCREASED SURFACE ACIDITY, METHODS FOR MAKING, AND METHODS FOR USING THE SAME

Номер: US20160001265A1
Принадлежит:

Aluminas with increased surface acidity, methods of making the same, and methods for using the same are provided. In an exemplary embodiment, a method for increasing the surface acidity of an alumina material includes providing an alumina starting material, and processing the alumina starting material under hydrothermal conditions in the presence of one or more organic acids to generate a hydrothermally treated alumina. In this embodiment, the one or more organic acids includes a polyprotic organic acid with a pKa value of about 0 to about 10, and the resulting hydrothermally treated alumina has increased surface acidity relative to the alumina starting material. 1. A method for increasing surface acidity of an alumina material , the method comprising the steps of:providing an alumina starting material; andprocessing the alumina starting material under hydrothermal conditions in the presence of an organic acid to generate a hydrothermally treated alumina,wherein the organic acid comprises a polyprotic organic acid with a pKa value of about 0 to about 10, and the hydrothermally treated alumina has increased surface acidity relative to the alumina starting material.2. The method of claim 1 , wherein the organic acids comprises tartaric acid claim 1 , malic acid claim 1 , citric acid claim 1 , or a mixture thereof.3. The method of claim 1 , wherein the alumina starting material comprises a gamma alumina.4. The method of claim 1 , wherein the hydrothermally treated alumina comprises a boehmite alumina.5. The method of claim 4 , further comprising calcining the hydrothermally treated alumina to convert at least a portion of the boehmite alumina in the hydrothermally treated alumina into a gamma alumina.6. The method of claim 5 , wherein the gamma alumina has a Brunauer claim 5 , Emmett and Teller (BET) surface area that is ±25% of the alumina starting material.7. The method of claim 4 , wherein substantially all of the hydrothermally treated alumina is a boehmite alumina ...

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07-01-2016 дата публикации

PROCESSES USING MOLECULAR SIEVE SSZ-98

Номер: US20160001273A1
Принадлежит: Chevron U.S.A. Inc

Uses for a new crystalline molecular sieve designated SSZ-98 are disclosed. SSZ-98 has the ERI framework type and is synthesized using a N,N′-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent. 3. The process of claim 2 , wherein the light olefins are ethylene claim 2 , propylene claim 2 , butylene claim 2 , or mixtures thereof.4. The process of claim 2 , wherein the oxygenate is methanol claim 2 , dimethyl ether claim 2 , or a mixture thereof.7. The process of claim 6 , wherein the molecular sieve contains a metal or metal ions capable of catalyzing the reduction of the oxides of nitrogen.8. The process of claim 7 , wherein the metal is lanthanum claim 7 , chromium claim 7 , manganese claim 7 , iron claim 7 , cobalt claim 7 , rhodium claim 7 , nickel claim 7 , palladium claim 7 , platinum claim 7 , copper claim 7 , zinc claim 7 , or mixtures thereof.9. The process of claim 6 , wherein the gas stream is the exhaust stream of an internal combustion engine.11. The process of claim 10 , wherein the engine is an internal combustion engine.12. The process of claim 11 , wherein the internal combustion engine is an automobile engine.13. The process of claim 10 , wherein the engine is fueled by a hydrocarbon fuel.14. The process of claim 10 , wherein the molecular sieve has deposited on it a metal selected from the group consisting of ruthenium claim 10 , rhodium claim 10 , palladium claim 10 , platinum claim 10 , and mixtures thereof.15. The process of claim 14 , wherein the metal is palladium claim 14 , platinum claim 14 , or a mixture thereof. This application claims the priority benefit of U.S. Provisional Application No. 62/020,638, filed Jul. 3, 2014, which is incorporated herein by reference.This disclosure relates to new crystalline molecular sieve designated SSZ-98, a method for preparing SSZ-98 using a N,N′-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent (“SDA”), and uses for SSZ-98. These materials have ...

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07-01-2016 дата публикации

Process for Making Alkylated Aromatic Compound

Номер: US20160001276A1
Принадлежит: ExxonMobil Chemical Patents Inc

A process for producing an alkylated aromatic compound comprises contacting an aromatic starting material and hydrogen with a plurality of catalyst particles under hydroalkylation conditions to produce an effluent comprising the alkylated aromatic compound, the catalyst comprising a composite of a solid acid, an inorganic oxide different from the solid acid and a hydrogenation metal, wherein the distribution of the hydrogenation metal in at least 60 wt % of the catalyst particles is such that the average concentration of the hydrogenation metal in the rim portion of a given catalyst particle is Crim, the average concentration of the hydrogenation metal in the center portion of the given catalyst particle is Ccenter, where 0.2≦Crim/Ccenter<2.0. Also disclosed are hydroalkylation catalyst and process for making phenol and/or cyclohexanone using the catalyst.

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02-01-2020 дата публикации

Membrane process for olefin separation

Номер: US20200001242A1
Принадлежит: UOP LLC

A process is provided to separate a hydrocarbon stream comprising a mixture of light olefins and light paraffins, the process comprising sending the hydrocarbon stream through a pretreatment unit to remove impurities selected from the group consisting of sulfur compounds, arsine, phosphine, methyl acetylene, propadiene, and acetylene to produce a treated hydrocarbon stream; vaporizing the treated hydrocarbon stream to produce a gaseous treated hydrocarbon stream; adding liquid or vapor water to the gaseous treated hydrocarbon stream; then contacting the gaseous treated hydrocarbon stream to a membrane in a membrane system comprising one or more membrane units to produce a permeate stream comprising about 96 to 99.9 wt % light olefins and a retentate stream comprising light paraffins.

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02-01-2020 дата публикации

Catalytic oxidation method and method for producing conjugated diene

Номер: US20200001262A1
Принадлежит: Mitsubishi Chemical Corp

An object of the present invention is to suppress performance deterioration of a molybdenum composite oxide-based catalyst at the time of performing gas-phase catalytic partial oxidation with molecular oxygen by using a tubular reactor. The present invention relates to a catalytic oxidation method using a tubular reactor in which a Mo compound layer containing a Mo compound and a composite oxide catalyst layer containing a Mo composite oxide catalyst are arranged in this order from a reaction raw material supply port side and under a flow of a mixed gas containing 75 vol % of air and 25 vol % of water vapor at 440° C., a Mo sublimation amount of the Mo compound is larger than a Mo sublimation amount of the Mo composite oxide catalyst under the same conditions.

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02-01-2020 дата публикации

PROCESS FOR THE OLIGOMERIZATION OF ETHYLENE WITH STIRRED GAS/LIQUID REACTOR AND PLUG-FLOW REACTOR SEQUENCE

Номер: US20200001266A1
Принадлежит: IFP ENERGIES NOUVELLES

Reaction device which makes possible the oligomerization of olefins to give linear olefins and preferably linear α-olefins, comprising a gas/liquid reactor and a reactor of plug-flow type. The reaction device is also employed in an oligomerization process. 1. Device comprising:{'b': '1', 'a gas/liquid reactor (), of elongated shape along the vertical axis, comprising a liquid phase and a gas phase located above the said liquid phase,'}{'b': '3', 'a means for introduction of the olefin () into the gas/liquid reactor employing a means for injection of the olefin within the said liquid phase of the gas/liquid reactor,'}{'b': '14', 'a means for introduction of the catalytic system () into the gas/liquid reactor,'}{'b': 13', '1, 'a recirculation loop () comprising withdrawal means in the gas/liquid reactor for the withdrawal and the dispatch of a fraction of withdrawn liquid to a heat exchanger capable of cooling the said liquid fraction, and means for introduction of the said cooled liquid, exiting from the heat exchanger, into the upper part of the gas/liquid reactor (),'}{'b': '11', 'a reactor of plug-flow type () comprising withdrawal means in the gas/liquid reactor for the withdrawal and the dispatch of a fraction of withdrawn liquid to the reactor of plug-flow type and means for recovery of a reaction effluent, at the outlet of the reactor of plug-flow type.'}2. Device according to claim 1 , in which the reactor of plug-flow type is located outside the gas/liquid reactor.3. Device according to claim 1 , in which the reactor of plug-flow type comprises a heat exchanger.4. Olefin oligomerization process employing the device according to claim 1 , at a pressure between 1.0 and 10.0 MPa and at a temperature between 0° C. and 200° C. claim 1 , comprising the following stages:{'b': '1', 'a) a catalytic oligomerization system comprising at least one metal precursor and at least one activating agent is introduced into a gas/liquid reactor () comprising a liquid phase and a ...

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05-01-2017 дата публикации

Method For Producing Hydrocarbon Dehydrogenation Catalyst Using Sponge-Type Support

Номер: US20170001174A1
Принадлежит:

Disclosed are a catalyst for dehydrogenating a paraffinic hydrocarbon and a method of preparing the same, wherein the catalyst is configured such that a sponge-type alumina support having 3D meso/macro pores is directly impregnated with an active metal, thus decreasing the diffusion resistance of a material, realizing structural stability, and maximizing the distribution of the active metal in the support, thereby significantly increasing olefin conversion and selectivity. 1. A method of preparing a catalyst for dehydrogenating paraffin , comprising:providing a sponge-type alumina support having meso/macro pore sizes;thermally treating the support at 800 to 1200° C. for 2 to 10 hr in an air atmosphere;dispersing an active metal precursor in the support so as to be loaded into the support;drying the support having the loaded active metal at 80 to 150° C.; andfiring the dried catalyst at 500 to 900° C. for 2 to 10 hr in an air atmosphere.2. The method of claim 1 , further comprising reducing the fired catalyst at 400 to 700° C. in a hydrogen atmosphere claim 1 , after the firing the dried catalyst.3. The method of claim 1 , wherein the active metal comprises platinum claim 1 , tin claim 1 , or an alkali metal or alkaline earth metal.4. The method of claim 1 , wherein the sponge-type alumina support comprises two kinds of pores having a meso pore size and a macro pore size.5. The method of claim 1 , wherein the sponge-type alumina support is selected from the group consisting of alpha alumina claim 1 , theta alumina claim 1 , silicon carbide claim 1 , and mixtures thereof.6. The method of claim 1 , wherein the sponge-type alumina support has a specific surface area of 50 to 100 m/g claim 1 , a total pore volume of 0.1 to 0.7 cm/g claim 1 , and a pore size of 10 to 100 nm.7. A catalyst for dehydrogenating paraffin claim 1 , prepared by the method of any one of to .8. A method of producing an olefin claim 7 , comprising dehydrogenating a gas mixture comprising paraffin ...

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02-01-2020 дата публикации

Palladium Catalysts Supported on Carbon for Hydrogenation of Aromatic Hydrocarbons

Номер: US20200001274A1
Принадлежит:

Provided is a process for preparing partially or fully hydrogenated hydrocarbons through hydrogenation of aromatic hydrocarbons in the presence of a hydrogenation catalyst. The hydrogenation catalyst comprises palladium deposited on carbon with optional acid wash and calcination treatments and with optional additions of silver and/or alkali metals. 1. A chemical catalyst , comprising an acid-washed carbon base and palladium deposited on said carbon base.2. The chemical catalyst of claim 1 , wherein said carbon base is an activated carbon base.3. The chemical catalyst of claim 1 , wherein said carbon base is calcinated before said palladium is deposited thereon.4. The chemical catalyst of claim 1 , wherein said catalyst comprises from about 0.1 to about 5 weight percentage of palladium.5. The chemical catalyst of claim 1 , further comprising a metal additive deposited on said carbon base with said palladium.6. The chemical catalyst of claim 5 , wherein the molar ratio of said palladium to said metal additive is in a range of from 1:1 to 12:1.7. The chemical catalyst of claim 5 , wherein said metal additive comprises a metal selected from the group consisting of alkali metals and silver.8. A method of making a chemical catalyst claim 5 , comprising the steps of:(i) dissolving a first precursor in deionized water to form a solution;(ii) depositing said solution onto an acid-washed carbon base; and(iii) drying said carbon base in the presence of static air.9. The method of claim 8 , wherein step (ii) is conducted according to the incipient wetness method.10. The method of claim 8 , wherein said carbon base is an activated carbon base.11. The method of claim 8 , further comprising the step of calcining said carbon base prior to the performance of step (ii).12. The method of claim 11 , wherein no calcination treatment is applied to said carbon base following the performance of step (ii).13. The method of claim 11 , wherein said calcining step involves subjecting said ...

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05-01-2017 дата публикации

CATALYST COMPOSITION FOR ISOMERIZATION OF PARAFFINS

Номер: US20170001180A1
Принадлежит:

A catalyst composition for isomerization of paraffins includes at least one metal, at least one heteropoly acid and a support material. Further provided are a process for preparation of the catalyst composition and a process for isomerization of paraffins using the catalytic composition. 1. A catalyst composition comprising:at least one metal in an amount in the range of 0.1% to 10% w/w of the total weight of the composition;at least one heteropoly acid in an amount in the range of 14% to 50% w/w of the total weight of the composition; anda support material in an amount in the range of 60% to 85% w/w of the total weight of the composition.2. The catalyst composition as claimed in claim 1 , wherein the at least one metal in an amount in the range of 0.1% to 6% w/w of the total weight of the composition.3. The catalyst composition as claimed in claim 1 , wherein the at least one metal in an amount in the range of 1.5% to 6% w/w of the total weight of the composition.4. The catalyst composition as claimed in claim 1 , wherein the at least one metal is selected from the group consisting of alkali metal claim 1 , alkaline earth metal claim 1 , transitional metal claim 1 , lanthanides claim 1 , and combinations thereof.5. The catalyst composition as claimed in claim 1 , wherein the at least one metal is a alkali metal selected from the group consisting of Na claim 1 , K claim 1 , Rb claim 1 , Cs claim 1 , and combinations thereof.6. The catalyst composition as claimed in claim 1 , wherein the at least one metal is a transitional metal selected from the group consisting of Pt claim 1 , Ni claim 1 , Pd claim 1 , Re claim 1 , Ir claim 1 , Rh claim 1 , and combinations thereof.7. The catalyst composition as claimed in claim 1 , wherein the at least one metal is nickel in an amount in the range of 1.5% to 6% w/w of the total weight of the composition.8. The catalyst composition as claimed in claim 1 , wherein the at least one heteropoly acid in an amount in the range of 18% to ...

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03-01-2019 дата публикации

ZEOLITIC 3D SCAFFOLDS WITH TAILORED SURFACE TOPOGRAPHY FOR METHANOL CONVERSION WITH LIGHT OLEFINS SELECTIVITY

Номер: US20190001311A1

The present disclosure relates to 3D printed zeolite scaffolds. The zeolite scaffolds can be used as a catalyst for methanol to olefin (MTO) conversion and hydrocarbon cracking processes. 1. A zeolite coated monolith article comprising an uncoated monolithic support structure including walls having a honeycomb structure comprising ammonia-ZSM-5 powder (SiO/AlO) and bentonite clay; and a porous coating disposed directly upon the uncoated monolithic support structure.2. The zeolite coated monolith article of claim 1 , further comprises an additional component selected from the group consisting of amorphous silica claim 1 , a plasticizing binder claim 1 , a metal dopant claim 1 , and combinations thereof disposed within the uncoated monolithic support structure.3. The zeolite coated monolith article of claim 2 , wherein the metal dopant is selected from the group consisting of Zn claim 2 , Ce claim 2 , Cr claim 2 , Mg claim 2 , Cu claim 2 , La claim 2 , Ga claim 2 , Y claim 2 , and combinations thereof.4. The zeolite coated monolith article of claim 1 , wherein the porous coating comprises SAPO-34.5. The zeolite coated monolith article of claim 1 , wherein the zeolite coated monolith has a wall thickness of about 0.2 mm to about 0.9 mm.6. The zeolite coated monolith article of claim 1 , wherein the zeolite coated monolith has a square channel length of about 0.2 mm to about 1.6 mm.7. The zeolite coated monolith article of claim 1 , wherein the zeolite coated monolith has a total pore volume of about 0.2 cm/g to about 0.95 cm/g.8. The zeolite coated monolith article of claim 1 , wherein the zeolite coated monolith has a mesoporosity of about 0.1 cm/g to about 0.95 cm/g.9. A process for converting methanol to one or more light olefins (MTO) claim 1 , the process comprising contacting methanol claim 1 , under deoxygenation conditions claim 1 , with a catalyst comprising a zeolite monolith claim 1 ,{'sub': 2', '2', '3, 'wherein the zeolite monolith comprises an uncoated ...

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07-01-2021 дата публикации

MWW TYPE ZEOLITE, METHOD FOR PRODUCING SAME, AND CRACKING CATALYST

Номер: US20210002140A1
Принадлежит:

Provided are the following: an MWW type zeolite which has many Brønsted acid sites when in the form of a proton type and which is highly suitable as a cracking catalyst for cumene; a method for producing same; and an application of same. The present invention provides an MWW type zeolite in which the ratio (B/A) of the peak intensity (B) attributable to tetracoordinate aluminum relative to the peak intensity (A) attributable to hexacoordinate aluminum is 2 or more in Al MAS NMR, when measured as an ammonium type. The present invention also provides a method for producing an MWW type zeolite, the method having a step for carrying out a hydrothermal synthesis reaction in the presence of: a seed crystal of an MWW type zeolite containing no organic structure-directing agent; and a reaction mixture containing a silica source, an alumina source, an alkali source, an organic structure-directing agent, and water. The reaction mixture satisfies the following molar ratio: X/SiO<0.15 (here, X denotes the number of moles of the organic structure-directing agent). 1. An MWW-type zeolite wherein a ratio (B/A) of a peak intensity (B) attributable to tetracoordinate aluminum to a peak intensity (A) attributable to hexacoordinate aluminum is 2 or more in Al MAS NMR as measured in the form of an ammonium type.2. The MWW-type zeolite according to claim 1 , wherein an amount of Brønsted acid site with a adsorption heat of ammonia of 106 kJ/mol or more is 0.5 mmol/g or more.3. The MWW-type zeolite according to claim 1 , wherein a micropore volume is 0.07 cm/g or more and 0.2530 cm/g or less.4. The MWW-type zeolite according to claim 1 , wherein SiO/AlOmolar ratio is 17 or more and 37 or less.5. The MWW-type zeolite according to claim 1 , wherein when the MWW-type zeolite is subjected to X-ray diffraction measurement claim 1 , a peak is observed in at least one range below:2θ=6.4° to 7.4°, 13.5° to 14.5°, 24.1° to 25.1°, 24.7 to 25.7°, 27.1 to 28.1°, 28.0° to 29.0°, 28.6° to 29.6°, and ...

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05-01-2017 дата публикации

CIT-10: A TWO DIMENSIONAL LAYERED CRYSTALLINE MICROPOROUS SILICATE COMPOSITION AND COMPOSITIONS DERIVED THEREFROM

Номер: US20170001872A1
Принадлежит:

This disclosure relates to a new crystalline microporous silicate solid, designated CIT-10, comprising a two dimensional layered structure, having an organic interlayer sandwiched between individual crystalline silicate layers. This CIT-10 material can be converted to a pure-silicate of RTH topology, as well as two new of pillared silicate structures, designated CIT-11 and CIT-12. This disclosure characterizes new materials and provides methods of preparing and using these new crystalline microporous solids. 1. A crystalline microporous silicate , designated CIT-10 , which exhibits a powder X-ray diffraction (XRD) pattern exhibiting at least five of the characteristic peaks at 7.6±0.2° , 8.7±0.2° , 10.3±0.2° , 18.8±0.2° , 20.3±0.2° , 21.8±0.2° , 22.4±0.2° , 22.7±0.2° , 22.9±0.2° , and 23.6±0.2° 2-theta.2. The crystalline microporous silicate of claim 1 , wherein the crystalline microporous silicate comprises a two dimensional layered structure claim 1 , having an organic material sandwiched between individual crystalline silicate layers.3. The crystalline microporous silicate of claim 2 , having a structure which is ordered along its two dimensional crystalline silicate layers claim 2 , but which exhibits disorder between its crystalline silicate layers claim 2 , as evidenced by RED (rotating electron diffraction) structure analysis.4. The crystalline microporous silicate of claim 1 , which exhibits an Si-MAS NMR spectrum having resonances at chemical shifts of −113 ppm claim 1 , −107 ppm claim 1 , and −102 ppm claim 1 , relative to tetramethylsilane (TMS).5. The crystalline microporous silicate of claim 4 , wherein the resonances at chemical shifts of −113 ppm claim 4 , −107 ppm claim 4 , and −102 ppm have relative integrated intensities of 8 claim 4 , 5 claim 4 , and 3 claim 4 , respectively.7. A crystalline microporous silicate claim 4 , designated CIT-11 claim 4 , which exhibits a powder X-ray diffraction (XRD) pattern exhibiting at least five of the ...

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07-01-2021 дата публикации

CATALYST, AND METHOD FOR DIRECT CONVERSION OF SYNGAS TO PREPARE LIGHT OLEFINS

Номер: US20210002184A1
Принадлежит:

A process for direct synthesis of light olefins uses syngas as the feed raw material. This catalytic conversion process is conducted in a fixed bed or a moving bed using a composite catalyst containing components A and B (A+B). The active ingredient of catalyst A is metal oxide; and catalyst B is an oxide supported zeolite. A carrier is one or more of AlO, SiO, TiO, ZrO, CeO, MgO and GaOhaving hierarchical pores; the zeolite is one or more of CHA and AEI structures. The loading of the zeolite is 4%-45% wt. A weight ratio of the active ingredients in the catalyst A and the catalyst B is within a range of 0.1-20, and preferably 0.3-5. The total selectivity of the light olefins comprising ethylene, propylene and butylene can reach 50-90%, while the selectivity of a methane byproduct is less than 15%. 1. A catalyst , wherein the catalyst is a composite catalyst composed of A+B; the catalyst component A and the catalyst component B are compounded by mechanical mixing method; the active ingredients of the catalyst component A are active metal oxides; the catalyst component B are supported zeolites; the carrier is at least one of porous AlO , SiO , TiO , ZrO , CeO , MgO and GaO; the zeolite is at least one of CHA and AEI structures; the loading of the zeolite is 4%-45% wt; and the active metal oxide is at least one of MnO , MnCrO , MnAlO , MnZrO , ZnO , ZnCrO , ZnAlO , CoAlOand FeAlO.2. The catalyst according to claim 1 , wherein at least one of porous AlO claim 1 , SiO claim 1 , TiO claim 1 , ZrO claim 1 , CeO claim 1 , MgO and GaOin the catalyst component B is used as the carrier; specific surface area is 30-250 m/g; pore volume is 0.25-0.80 ml/g; through calculation according to the specific surface area claim 1 , mesoporous specific surface area occupies 30-75% and macroporous specific surface area occupies 25-70%; and the zeolite is used as an active component and dispersed on the carrier by in situ growth or physical mixing mode.3. The catalyst according to claim 1 , ...

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07-01-2021 дата публикации

METHOD OF PRODUCING A FUEL ADDITIVE

Номер: US20210002185A1
Принадлежит:

A method of producing a fuel additive includes producing a first product stream comprising butadiene by passing a feed stream comprising C4 hydrocarbons through a steam cracker; transforming greater than or equal to 90 weight % of the butadiene in the first product stream into a second product stream by passing the first product stream through a first hydrogenation unit, wherein the second product stream comprises 1-butene, 2-butene, n-butane, isobutylene, isobutane, or a combination thereof; and converting the second product stream into the fuel additive by passing the second product stream through a fuel additive synthesis unit with an acid catalyst. 1. A method of producing a fuel additive , comprising:producing a first product stream comprising butadiene by passing a feed stream comprising C4 hydrocarbons through a steam cracker;transforming greater than or equal to 90 weight % of the butadiene in the first product stream into a second product stream by passing the first product stream through a first hydrogenation unit, wherein the second product stream comprises 1-butene, 2-butene, n-butane, isobutylene, isobutane, or a combination thereof; andconverting the second product stream into the fuel additive by passing the second product stream through a fuel additive synthesis unit with an acid catalyst.2. The method of claim 1 , wherein the feed stream comprises a portion of an effluent from a fluid catalytic cracking process.3. The method of claim 1 , wherein the feed stream comprises at least one of methyl acetylene claim 1 , propylene claim 1 , 1 claim 1 ,3-butadiene claim 1 , 1 claim 1 ,2-butadiene claim 1 , isobutylene claim 1 , cis-2-butene claim 1 , trans-2-butene claim 1 , 1-butene claim 1 , propene claim 1 , isobutane claim 1 , or n-butane.4. The method of claim 1 , wherein greater than or equal to 95 weight % of the butadiene in the first product stream is transformed into the second product stream.5. The method of claim 1 , wherein the acid catalyst ...

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07-01-2016 дата публикации

Process to Make Olefins from Isobutanol

Номер: US20160002122A1
Принадлежит:

A process for the conversion of an alcohol mixture to make propylene may include introducing into a reactor a stream that includes the alcohol mixture. The alcohol mixture may include 20 to 100 weight percent isobutanol. The process may include contacting the stream with a single catalyst at a temperature above 450° C. in the reactor at conditions effective to dehydrate the isobutanol, forming C olefins, and to catalytically crack the C olefins. The single catalyst may be an acid catalyst adapted to cause both the dehydration and the catalytic cracking. The process may include recovering from the reactor an effluent that includes ethylene, propylene, water, and various hydrocarbons. The process may include fractionating the effluent to produce an ethylene stream, a propylene stream, a fraction of hydrocarbons having 4 carbon atoms or more, and water. 119-. (canceled)20. A process for the conversion of an alcohol mixture comprising about 20 to 100 weight percent isobutanol to make essentially propylene , comprising:a) introducing in a reactor a stream comprising the alcohol mixture, optionally water, optionally an inert component,{'sup': +', '+, 'b) contacting said stream with a single catalyst at a temperature above 450° C. in said reactor at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, forming C4 olefins, and to catalytically crack the C4 olefins, wherein the single catalyst is an acid catalyst adapted to cause both the dehydration and the catalytic cracking,'}c) recovering from said reactor an effluent comprising: ethylene, propylene, water, optionally unconverted alcohols of the alcohol mixture, various hydrocarbons, and the optional inert component of step a),d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ...

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07-01-2016 дата публикации

NOZZLE DESIGN FOR IONIC LIQUID CATALYZED ALKYLATION

Номер: US20160002125A1
Принадлежит: Chevron U.S.A. INC.

Systems for ionic liquid catalyzed hydrocarbon conversion comprise a reactor vessel, a mixing device in fluid communication with the reactor vessel, and at least one circulation loop in fluid communication with the reactor vessel and the mixing device. The mixing device may comprise an upper venturi, at least one feed injection component, and a lower venturi. Such systems may be used for ionic liquid catalyzed alkylation reactions. Processes for ionic liquid catalyzed hydrocarbon conversion are also disclosed. 1. A system for ionic liquid catalyzed hydrocarbon conversion , the system comprising:a reactor vessel having a top; anda mixing device disposed at the top of the reactor vessel, wherein the mixing device comprises:an upper venturi having an axial outlet at the upper venturi distal end, the upper venturi distal end disposed within the reactor vessel,at least one feed injection array disposed within the reactor vessel, each said feed injection array coaxial with the upper venturi, anda lower venturi having an axial inlet at the lower venturi proximal end, the lower venturi proximal end disposed within the reactor vessel, wherein:the lower venturi inlet is spaced radially outward from the upper venturi outlet to define an inter-venturi channel between the upper venturi distal end and the lower venturi proximal end,the lower venturi is coaxial with the upper venturi,the mixing device is configured for projecting a central jet of a first liquid downward from the upper venturi outlet into the lower venturi, andeach said feed injection array is configured for projecting a second liquid toward an axis of the upper venturi.2. (canceled)3. The system according to claim 1 , wherein the lower venturi inlet is disposed at the same elevation or about the same elevation as the upper venturi outlet.4. The system according to claim 1 , wherein:the lower venturi has a lower venturi constriction point,the at least one feed injection array comprises a single feed injection array ...

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07-01-2016 дата публикации

Oxidative Dehydrogenation Process With Hydrocarbon Moderator Gas and Reduced Nitrogen Feed

Номер: US20160002126A1
Принадлежит: TPC Group LLC

Oxidative dehydrogenation includes: (a) providing a gaseous feed stream to a catalytic reactor, the feed stream comprising a dehydrogenation reactant, oxygen, superheated steam, hydrocarbon moderator gas and optionally nitrogen, wherein the molar ratio of moderator gas to oxygen in feed stream is typically from 4:1 to 1:1 and the molar ratio of oxygen to nitrogen in the feed stream is at least 2; (b) oxidatively dehydrogenating the reactant in the reactor to provide a dehydrogenated product enriched effluent product stream; and (c) recovering dehydrogenated product from the effluent product stream. One preferred embodiment is a process for making butadiene including dimerizing ethylene to n-butene in a homogeneous reaction medium to provide a hydrocarbonaceous n-butene rich feed stream and oxidatively dehydrogenating the n-butene so formed. 1. A method of oxidatively dehydrogenating a dehydrogenation reactant comprising: 'wherein the molar ratio of hydrocarbon moderator gas to oxygen in the feed stream is from 50:1 to 0.5:1;', '(a) providing a gaseous feed steam to a catalytic reactor, the feed stream comprising a dehydrogenation reactant, oxygen, superheated steam and a hydrocarbon moderator gas,'}(b) oxidatively dehydrogenating the dehydrogenation reactant in the reactor to generate an effluent product stream enriched in a dehydrogenated product derived from said dehydrogenation reactant; and(c) recovering said dehydrogenated product from the effluent product stream.23-. (canceled)4. The method according to claim 1 , wherein the molar ratio of hydrocarbon moderator gas to oxygen in the feed stream is from 8:1 to 0.5:1.5. (canceled)6. The method according to claim 1 , wherein the molar ratio of hydrocarbon moderator gas to oxygen in the feed stream is from 3:1 to 1.5:1.7. The method according to claim 1 , wherein the feed stream optionally comprises nitrogen and the molar ratio of oxygen:nitrogen in the feed stream is at least 0.5.8. The method according to claim 4 ...

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05-01-2017 дата публикации

Catalyst composite and preparation thereof for isomerization of paraffins

Номер: US20170001924A1
Принадлежит: Hindustan Petroleum Corp Ltd

A catalyst composition is provided for isomerization of paraffins comprising of at least one heteropoly acid and reduced graphene oxide. Further provided are a process for preparation of the catalyst composition and a process for isomerization of paraffins using the catalytic composition.

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05-01-2017 дата публикации

PROPYLENE PRODUCTION USING A MESOPOROUS SILICA FOAM METATHESIS CATALYST

Номер: US20170001925A1
Принадлежит:

Embodiments of a metathesis process for producing propylene comprise providing a metathesis catalyst comprising an amorphous mesoporous silica foam impregnated with metal oxides, where the metathesis catalyst has a pore size distribution of at least 3 nm to 40 nm and a total pore volume of at least 0.700 cm/g. The process further involves producing a product stream comprising propylene by contacting a feed stream comprising butene with the metathesis catalyst. 1. A metathesis process for producing propylene comprising:{'sup': '3', 'providing a metathesis catalyst comprising an amorphous mesoporous silica foam impregnated with metal oxides, where the metathesis catalyst has a pore size distribution of at least 3 nm to 40 nm and a total pore volume of at least 0.700 cm/g; and'}producing a product stream comprising propylene by contacting a feed stream comprising butene with the metathesis catalyst.2. The process of further comprising tri-block copolymer structuring agent claim 1 , where the tri-block copolymer structuring agent is poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) structure.3. The process of where the metathesis catalyst catalyzes isomerization of 2-butene to 1-butene followed by cross-metathesis of 2-butene and 1-butene into a metathesis product stream comprising propylene4. The process of where at least 90% of the 2-butene is converted to 1-butene via isomerization.5. The process of where the pore size distribution is from at least 4 nm to 10 nm and the total pore volume is from at least 0.800 cm/g to 1.5 cm/g.6. The process of where the metathesis catalyst has a total acidity from 0.125 mmol/g to 0.500 mmol/g claim 1 , and a surface area of 400 to 500 m/g.7. The process of where the metal oxide is an oxide of molybdenum claim 1 , rhenium claim 1 , tungsten claim 1 , or combinations thereof.8. The process of where the metal oxide is tungsten oxide.9. The process of where the metathesis catalyst has a molar ratio for ...

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05-01-2017 дата публикации

SYSTEMS AND METHODS FOR PRODUCING PROPYLENE

Номер: US20170001926A1
Принадлежит: Saudi Arabian Oil Company

According to one embodiment described in this disclosure, a process for producing propylene may comprise at least partially metathesizing a first stream comprising at least about 10 wt. % butene to form a metathesis-reaction product, at least partially cracking the metathesis-reaction product to form a cracking-reaction product comprising propylene, and at least partially separating propylene from the cracking-reaction product to form a product stream comprising at least about 80 wt. % propylene. 1. A process for producing propylene , the process comprising:{'sup': '3', 'at least partially metathesizing a first composition comprising at least 10 wt. % butene to form a metathesis-reaction product, where the first composition is metathesized with a metathesis catalyst comprising a mesoporous silica catalyst impregnated with metal oxide, where the mesoporous silica catalyst includes a pore size distribution of about 2.5 nm to about 40 nm and a total pore volume of at least about 0.600 cm/g;'}at least partially cracking the metathesis-reaction product to form a cracking-reaction product comprising propylene, where the metathesis-reaction product is cracked with a cracking catalyst comprising a mordenite framework inverted (MFI) structured silica catalyst, where the MFI structured silica catalyst includes total acidity of 0.001 mmol/g to 0.1 mmol/g; andat least partially separating propylene from the cracking-reaction product to form a product composition comprising at least 80 wt. % propylene.2. The process of claim 1 , where the MFI structured silica catalyst has a pore size distribution of at least 1.5 nm to 3 nm.3. The process of claim 1 , where the MFI structured silica catalyst is free of acidity modifiers selected from the group consisting of rare earth modifiers claim 1 , phosphorus modifiers claim 1 , potassium modifiers claim 1 , and combinations thereof.4. The process of claim 1 , where the metathesis catalyst is positioned generally upstream of the cracking ...

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05-01-2017 дата публикации

DUAL CATALYST SYSTEM FOR PROPYLENE PRODUCTION

Номер: US20170001927A1
Принадлежит:

Embodiments of processes for producing propylene utilize a dual catalyst system comprising a mesoporous silica catalyst impregnated with metal oxide and a mordenite framework inverted (MFI) structured silica catalyst downstream of the mesoporous silica catalyst, where the mesoporous silica catalyst includes a pore size distribution of at least 2.5 nm to 40 nm and a total pore volume of at least 0.600 cm/g, and the MFI structured silica catalyst has a total acidity of 0.001 mmol/g to 0.1 mmol/g. The propylene is produced from the butene stream via metathesis by contacting the mesoporous silica catalyst and subsequent cracking by contacting the MFI structured silica catalyst. 1. A process for production of propylene comprising: [{'sup': '3', 'a mesoporous silica catalyst impregnated with metal oxide, where the mesoporous silica catalyst includes a pore size distribution of about 2.5 nm to about 40 nm and a total pore volume of at least about 0.600 cm/g, and'}, 'a mordenite framework inverted (MFI) structured silica catalyst downstream of the mesoporous silica catalyst, where the MFI structured silica catalyst includes a total acidity of 0.001 mmol/g to 0.1 mmol/g,, 'providing a dual catalyst system comprisingproducing propylene from a stream comprising butene via metathesis and cracking by contacting the stream comprising butene with the dual catalyst system, where the stream comprising butene contacts the mesoporous silica catalyst before contacting the MFI structured silica catalyst.2. The process of where the MFI structured silica catalyst has a pore size distribution of at least 1.5 nm to 3 nm.3. The process of where the MFI structured silica catalyst is free of acidity modifiers selected from the group consisting of rare earth modifiers claim 1 , phosphorus modifiers claim 1 , potassium modifiers claim 1 , and combinations thereof.4. The process of where the mesoporous silica catalyst catalyzes isomerization of 2-butene to 1-butene followed by cross-metathesis of ...

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05-01-2017 дата публикации

Systems and methods for producing propylene

Номер: US20170001928A1
Принадлежит: Saudi Arabian Oil Co

According to one or more embodiments described herein, a process for producing propylene, the process comprising at least partially metathesizing a first portion of a first stream to form a first metathesis-reaction product, at least partially cracking the first metathesis-reaction product to form a cracking-reaction product, the cracking reaction product comprising propylene and ethylene, at least partially separating ethylene from at least the cracking reaction product to form a first recycle stream, combining the first recycle stream with a second portion of the first stream to a form a mixed stream, and at least partially metathesizing the mixed stream to from a second metathesis-reaction product. In embodiments, the second metathesis-reaction product may comprise propylene, the first stream may comprise butene, and the first recycle stream may comprise ethylene.

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04-01-2018 дата публикации

PRODUCTION OF HYDROCARBON LIQUIDS

Номер: US20180002248A1
Принадлежит:

A process to efficiently convert organic feedstock material into liquid non-oxygenated hydrocarbons in the Cto Ccarbon skeleton range is disclosed. The process can utilize gaseous, liquid or solid organic feedstocks containing carbon, hydrogen and, optionally, oxygen. The feedstock may require preparation of the organic feedstock for the process and is converted first into a synthesis gas containing carbon monoxide and hydrogen. The synthesis gas is then cleaned and conditioned and extraneous components removed, leaving substantially only the carbon monoxide and hydrogen. It is then converted via a series of chemical reactions into the desired liquid hydrocarbons. The hydrocarbons are suitable for combustion in a vehicle engine and may be regarded a replacement for petrol made from fossil fuels in the Cto Ccarbon backbone range. The process also recycles gaseous by-products back through the various reactors of the process to maximize the liquid hydrocarbon in the Cto Ccarbon skeleton range yield. 1. A process for producing a Cto Chydrocarbon fuel from organic material , comprising:a) applying a heat source to heat an organic feedstock and oxygen at substoichiometric conditions to a temperature sufficient for partial combustion of said organic feedstock to occur and then ceasing application of said heat source once partial combustion has commenced;b) partially combusting said organic feedstock so as to produce a synthesis gas stream, said synthesis gas stream containing at least carbon monoxide, carbon dioxide and hydrogen;{'sub': '10', 'c) substantially removing unwanted solid and liquid matter comprising oxides, ash and hydrocarbons having a carbon skeleton of greater than Cfrom said synthesis gas stream to produce a first cleaned synthesis gas stream containing at least carbon monoxide, carbon dioxide and hydrogen;'}d) compressing said first cleaned synthesis gas stream and substantially removing water;e) conditioning and further cleaning the first cleaned ...

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