Hydrogenation reaction catalyst and preparation method therefor

Provided are a hydrogenation reaction catalyst and a preparation method therefor, and more particularly, to a hydrogenation reaction catalyst including sulfur as a promoter, thereby selectively hydrogenating an olefin by changing a relative hydrogenation rate of the olefin and an aromatic group during a hydrogenation reaction of an unsaturated hydrocarbon compound containing an aromatic group, and a preparation method therefor.

METHOD FOR DEODORIZING HYDROGENATED PETROLEUM RESIN, AND METHOD FOR PRODUCING HYDROGENATED PETROLEUM RESIN

Provided is a new method that effectively reduces odor components that are present in a hydrogenated petroleum resin, and adjusts a softening point to an appropriate range for exhibiting an adhesive performance. 1. A method for deodorizing a hydrogenated petroleum resin , comprising: stripping a hydrogenated petroleum resin at a gas flow rate of 1 to 45 VVM.2. The method for deodorizing a hydrogenated petroleum resin according to claim 1 , wherein the stripping is performed at 150 to 250° C.3. The method for deodorizing a hydrogenated petroleum resin according to claim 1 , wherein the stripping is performed at 160 to 240° C.4. A method for producing a hydrogenated petroleum resin claim 1 , comprising: thermally polymerizing dicyclopentadiene and a vinyl aromatic compound claim 1 , hydrogenating the obtained polymerization reaction product claim 1 , and then stripping the obtained hydrogenated petroleum resin at a gas flow rate of 1 to 45 VVM.5. The method for deodorizing a hydrogenated petroleum resin according to claim 1 , wherein the hydrogenated petroleum resin is a dicyclopentadiene/vinyl aromatic compound hydrogenated petroleum resin. The present invention relates to a method for deodorizing a hydrogenated petroleum resin and a method for producing a hydrogenated petroleum resin. More specifically, the present invention relates to a method for deodorizing and a method for producing a dicyclopentadiene/vinyl aromatic compound hydrogenated petroleum resin obtained by hydrogenating a thermal polymerization reaction product of dicyclopentadiene and a vinyl aromatic compound.A hot melt adhesive is excellent in, for example, high-speed coating properties, fast setting properties, solvent-free properties, barrier properties, energy saving properties, and economic efficiency, and thus is increasingly used as an adhesive for, for example, sanitary materials, packaging materials, automobiles in various fields.A dicyclopentadiene/vinyl aromatic compound hydrogenated ...

METHOD FOR PRODUCING HYDROGENATED PETROLEUM RESIN

Provided is a method for producing a hydrogenated petroleum resin having good compatibility with a base polymer and a good hue under a hydrogen pressure of 4 MPaG or less. 1. A method for producing a hydrogenated petroleum resin , the method comprising hydrogenating a polymerization product of dicyclopentadiene and a vinyl aromatic compound in the presence of a catalyst ,wherein the hydrogenating is performed under the following conditions (A) to (C):(A) an amount of the catalyst employed is 0.125 to 0.4 parts by mass relative to 100 parts by mass of a resin in the polymerization product;(B) a reaction pressure is 4 MPaG or less; and(C) a reaction temperature is 240° C. or higher.2. The method of claim 1 , wherein the catalyst is a palladium catalyst or a nickel catalyst.3. The method of claim 1 , wherein the polymerization product is obtained by thermally polymerizing the dicyclopentadiene and the vinyl aromatic compound.4. The method of claim 1 , further comprising thermally polymerizing the dicyclopentadiene and the vinyl aromatic compound claim 1 , to obtain a polymerization product that is employed in the hydrogenating as the polymerization product of the dicyclopentadiene and the vinyl aromatic compound.6. The method of claim 1 , wherein the catalyst is a nickel catalyst claim 1 , a palladium catalyst claim 1 , a cobalt catalyst claim 1 , a platinum catalyst or a rhodium catalyst.7. The method of claim 1 , wherein the reaction pressure is normal pressure to 4 MPaG.8. The method of claim 1 , wherein the reaction temperature is 240 to 300° C. The present invention relates to a method for producing a hydrogenated petroleum resin. More specifically, the present invention relates to a method for producing a dicyclopentadiene/vinyl aromatic compound-based hydrogenated petroleum resin, including hydrogenating a polymerization product of dicyclopentadiene and a vinyl aromatic compound.A hot melt adhesive is widely used in the fields of, for example, bookbinding, ...

Hot-melt pressure sensitive adhesive composition having improved rheological properties

An adhesive compositions containing at least one first styrene-isoprene-styrene block copolymer having a diblock content of not less than 45%, at least one second styrene-isoprene-styrene block copolymer having a styrene content of not more than 30 wt.-%, at least one first tackifying resin having a softening point of equal to or higher than 100° C., and at least one second tackifying resin having a softening point of equal to or higher than 120° C. Further, a method for bonding substrates together using the adhesive composition.

Rosin-Derived Cationic Compounds and Polymers

Methods for forming rosin-derived cationic compounds are provided. The method can include attaching a cationic group to a conjugated diene on a hydrophenathrene-based ring of a resin acid (e.g., levopimaric acid, abietic acid, dehydroabietic acid, or a mixture thereof) to form a rosin-derived cationic compound. Attaching the cationic group to the conjugated diene on the hydrophenathrene-based ring of the resin acid can be achieved via a Diels-Alder reaction of a dienophile with the hydrophenathrene-based ring of the resin acid. Rosin-derived cationic compounds are also provided. The rosin-derived cationic compound can include a cationic group attached to a conjugated diene on a hydrophenathrene-based ring of a resin acid, wherein the rosin-derived cationic compound further comprises a carboxylic acid group.

Laser metal deposition welding process, parts formed therefrom and uses in oil, gas and petrochemical applications

Provided is an oil, gas and/or petrochemical ferrous or non-ferrous material component including two or more segments of ferrous or non-ferrous components for joining, wherein the two or more segments are of the same or different materials, and laser metal deposition weldments bonding adjacent segments of said components together. Also provided are methods of making laser metal deposition weldments and their uses in the oil, gas and petrochemical industry.

Silane-Functionalized Hydrocarbon Polymer Modifiers For Elastomeric Compositions

An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane-functionalized hydrocarbon polymer modifier (Si-HPM) made in a pre-reaction adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof.

HOT-MELT ADHESIVE COMPOSITION, PREPARATION METHOD THEREOF AND VEHICLE HEADLAMP

A hot-melt adhesive composition comprises 35 wt % to 40 wt % of petroleum resin, 10 wt % to 14 wt % of polyester elastomer resin, 10 wt % to 14 wt % of ethylene vinyl acetate resin, 14 wt % to 19 wt % of polyether polyol, 15 wt % to 21 wt % of polyester polyol, 8 wt % to 10 wt % of methylene diphenyl diisocyanate, and 0.1 wt % to 0.5 wt % of an amine catalyst, wherein the hot-melt adhesive composition has a melt viscosity of 20,000 cps to 50,000 cps as measured at 150° C. 1. A hot-melt adhesive composition comprising:35 wt % to 40 wt % of petroleum resin;10 wt % to 14 wt % of polyester elastomer resin;10 wt % to 14 wt % of ethylene vinyl acetate resin;14 wt % to 19 wt % of polyether polyol;15 wt % to 21 wt % of polyester polyol;8 wt % to 10 wt % of methylene diphenyl diisocyanate; and0.1 wt % to 0.5 wt % of an amine catalyst,wherein the hot-melt adhesive composition has a melt viscosity of 20,000 cps to 50,000 cps as measured at 150° C.2. The hot-melt adhesive composition of claim 1 , wherein the hot-melt adhesive composition has an adhesive strength (S) of 55 kg/20 mm to 60 kg/20 mm as measured at 20° C. claim 1 , an adhesive strength (S) of 20 kg/20 mm to 25 kg/20 mm as measured at 80° C. claim 1 , and an adhesive strength ratio of 35% to 45% as calculated using an Equation 1:{'br': None, 'i': S', '/S, 'sub': 80', '20, 'Adhesive strength ratio (%)=()×100\u2003\u2003(Equation 1)'}{'sub': 20', '80, 'wherein Sis the adhesive strength of the hot-melt adhesive composition and is measured at 20° C., and Sis the adhesive strength of the hot-melt adhesive composition and is measured at 80° C.'}3. The hot-melt adhesive composition of claim 1 , wherein a ratio of a total weight of the petroleum resin claim 1 , the polyester elastomer resin and the ethylene vinyl acetate resin to a total weight of the polyether polyol claim 1 , the polyester polyol and the methylene diphenyl diisocyanate is 1:0.4 to 1:1.4. The hot-melt adhesive composition of claim 1 , wherein a weight ratio ...

Curable petroleum resin and method for preparing same

This invention provides a method of manufacturing a curable petroleum resin and a curable petroleum resin obtained therefrom. The method includes (a) a process of thermally polymerizing a composition for polymerization which includes silanes and monomers, including cyclic olefins having at least one ethylenically unsaturated group selected from among C5 fractions, C9 fractions, and dicyclopentadiene of naphtha cracking, thereby enabling petroleum resins, which are thermoplastic resins, to be applied as reactive adhesives, and ultimately being capable of providing eco-friendly reactive adhesives.

COMPOSITION COMPRISING ESTERS

The present invention relates to a composition for use as a plasticizer composition in a formulation for a tire or a technical rubber good or for use as an extender oil for decreasing the mooney-viscosity and/or the glass transition temperature (T) of a polymer composition and its corresponding use. The invention also relates to the use of one or more than one ester as well as a process of preparing a formulation for making a tire or a technical rubber good or making a tire or a technical rubber good or preparing a polymer composition having a decreased mooney-viscosity. Moreover, the invention also relates to a formulation for making a tire or a technical rubber good and a corresponding tire or to technical rubber good. 2. Composition according to claim 1 , wherein the total amount of said esters selected from the group consisting of fatty acid alkyl esters and fatty acid aryl esters claim 1 , and said resins is above 90% by weight claim 1 , preferably above 95% by weight claim 1 , based on the total amount of the composition.3. Composition according to claim 1 , wherein the proportion of the total amount of said esters selected from the group consisting of fatty acid alkyl esters and fatty acid aryl esters is 40% by weight or lower claim 1 , based on the total amount of said esters and said resins claim 1 , preferably 30% by weight or lower claim 1 , more preferably in the range of from 10 to 25% by weight.6. Composition according to claim 1 , wherein said one or at least one of said more than one fatty acid alkyl esters is selected from the group consisting ofalkyl arachidonate,alkyl linoleate,alkyl linolenate,alkyl laurate,alkyl myristate,alkyl oleate,alkyl caprate,alkyl oleate,alkyl stearate,alkyl palmitate,alkyl caprylatealkyl caproate,alkyl butyrate,andalkyl behenate,preferably the one or at least one of said more than one fatty acid alkyl esters is 2-ethylhexyl oleate.7. Composition according to claim 1 , obtainable by mixing with the other ingredient(s) of ...

HYDROGENATED PETROLEUM RESIN, AND PRODUCTION METHOD AND USE THEREFOR

A hydrogenated petroleum resin, and a manufacturing method and use thereof, are provided. More specifically, a hydrogenated petroleum resin manufactured by subjecting dicyclopentadiene and an olefinic monomer to thermal polymerization and then carrying out a hydrogenation reaction, and a manufacturing method and use therefor are provided. The hydrogenated petroleum resin has the advantage of being useful in practical applications, since the petroleum resin is manufactured via thermal polymerization using inexpensive raw materials and on the contrary to conventional catalytic polymerization, a catalyst elimination process can be excluded. The hydrogenated petroleum resin produced in this way can be applied to, for example, an adhesive agent used in environmentally friendly sanitary goods, because the petroleum resin has excellent compatibility, adhesiveness and heat resistance, and has no bad odor. 1. A method for manufacturing a hydrogenated petroleum resin comprising the following steps of:{'sub': 3', '20, 'thermally polymerizing dicyclopentadiene and a Cto Colefinic monomer to prepare a petroleum resin; and'}subjecting the petroleum resin to a hydrogenation reaction with a hydrogenation catalyst.2. The method for manufacturing a hydrogenated petroleum resin of claim 1 , wherein the olefinic monomer is a linear or branched alpha olefinic monomer.3. The method for manufacturing a hydrogenated petroleum resin of claim 2 , wherein the linear alpha olefinic monomer is one selected from the group consisting of propene claim 2 , 1-butene claim 2 , 1-pentene claim 2 , 1-hexene claim 2 , 1-heptene claim 2 , 1-octene claim 2 , 1-decene claim 2 , 1-undecene claim 2 , 1-dodecene claim 2 , 1-tetradecene claim 2 , 1-hexadecene claim 2 , 1-eicosene and a combination thereof.4. The method for manufacturing a hydrogenated petroleum resin of claim 2 , wherein the branched alpha olefinic monomer is one selected from the group consisting of isobutylene claim 2 , 3-methyl-1-butene ...

A METHOD FOR SELECTIVE HYDROGENATION

The invention relates to a method for selective hydrogenation. More specifically, it relates to a method for selective hydrogenation capable of improving selectivity and reaction efficiency in the hydrogenation process of petroleum resin. 1. A method for selective hydrogenation comprising the steps of:dispersing two or more kinds of hydrogenation catalysts in a solvent to prepare a catalyst slurry; andmixing the catalyst slurry, a hydrogenation subject, and hydrogen gas to conduct a hydrogenation process.2. The method for selective hydrogenation according to claim 1 , wherein the hydrogenation subject is petroleum resin.3. The method for selective hydrogenation according to claim 1 , wherein the hydrogenation catalysts comprise a selective hydrogenation catalyst and a non-selective hydrogenation catalyst.4. The method for selective hydrogenation according to claim 3 , wherein the weight ratio of the non-selective hydrogenation catalyst and selective hydrogenation catalyst is 1:0.01 to 1:100.5. The method for selective hydrogenation according to claim 3 , wherein the selective hydrogenation catalyst includes one or more noble metals selected from the group consisting of palladium(Pd) claim 3 , platinum(Pt) claim 3 , ruthenium(Ru) claim 3 , and rhodium(Rh).6. The method for selective hydrogenation according to claim 3 , wherein the selective hydrogenation catalyst is one in which nickel and a cocatalyst are supported on a carrier claim 3 , and the cocatalyst comprises sulfur and copper.7. The method for selective hydrogenation according to claim 3 , wherein the non-selective hydrogenation catalyst comprises nickel(Ni).8. The method for selective hydrogenation according to claim 1 , wherein the solvent includes one or more selected from the group consisting of pentane claim 1 , hexane claim 1 , heptane claim 1 , nonane claim 1 , decane claim 1 , cyclohexane claim 1 , methylcyclohexane claim 1 , benzene claim 1 , toluene and xylene.9. The method for selective ...

Synthetic resins derived from petroleum

1360389 Petroleum resins IMPERIAL CHEMICAL INDUSTRIES Ltd 23 Aug 1971 [7 Sept 1970] 42768/70 Heading C3P [Also in Division C5] A synthetic resin is produced from a cracked naphtha or gas oil by first distilling to separate a C 5 stream, which may contain some C 4 and C 6 hydrocarbons, heating this stream to a temperature of at least 160‹ C., but preferably below 200‹ C., and then polymerizing it by treatment with a Friedel-Crafts catalyst. The heat treatment results in a finished synthetic resin that is more readily soluble in hydrocarbon solvents, possibly by dimerizing conjugated diolefines. Isoprene if present may be separated before the heat treatment. The preferred catalyst for the polymerization comprises aluminium chloride complexed with hydrogen chloride in an aromatic solvent and may be removed from the product by treatment with alcoholic ammonia or aqueous alkali.

Flourinated solid acids as catalysts for the preparation of hydrocarbon resins

Fluorinated solid acids and supported fluorinated solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer, C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the fluorinated solid acid catalyst and/or supported fluorinated solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5° C. to 170° C. can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerization catalysts since the acid sites are an integral part of the solid. The fluorinated solid acid catalysts and supported fluorinated solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.

Process for preparing petroleum resins ii

Preparation of olefinc-aromatic feeds for solvent extraction

Petroleum resins and their production with supported catalyst

Petroleum resins are produced by using a supported halide based Lewis acid polymerization catalyst wherein the Lewis acid is chemically bound to the support and free hydrogen halide and/or alkane formed by the reaction of the Lewis acid with the support has been removed. The more active catalysts are useful with both pure monomer and mixed feeds.

Petroleum resins and their production with BF3 catalyst

Petroleum resins are produced using a supported BF 3 cocatalyst complex. Preferably the cocatalyst is organic such as an alcohol or a carboxylic acid. Use of the catalyst in supported form together with the cocatalyst enables control over both Bronsted and Lewis acidity leading to better control of resin properties. Waste disposal and catalyst handling problems are also overcome.

Petroleum resins and their production with BF3 catalyst

Petroleum resins are produced using a supported BF 3 cocatalyst complex. Preferably the cocatalyst is organic such as an alcohol or a carboxylic acid. Use of the catalyst in supported form together with the cocatalyst enables control over both Bronsted and Lewis acidity leading to better control of resin properties. Waste disposal and catalyst handling problems are also overcome.

Petroleum resins and their production with BF3 catalyst

Petroleum resins are produced using a supported BF 3 cocatalyst complex. Preferably the cocatalyst is organic such as an alcohol or a carboxylic acid. Use of the catalyst in supported form together with the cocatalyst enables control over both Bronsted and Lewis acidity leading to better control of resin properties. Waste disposal and catalyst handling problems are also overcome.

用于制备烃树脂的金属氧化物固体酸催化剂

金属氧化物固体酸用作催化剂,用于含有纯单体(例如苯乙烯基单体),C5单体,和C9单体中至少之一的原料聚合制备烃树脂。在使用前,可以从固体酸催化剂上除去自由缔合水。制备的树脂的软化点(环球法)为约5～170℃。这些催化剂比传统的Friedel－Crafts聚合催化剂好,因为酸性位点是固体的组成部分。固体酸催化剂是相对安全的、可重复使用的催化剂,它消除或至少减少了残余酸或副产物对得到的树脂产品的污染。

Metal oxide solid acids as catalysts for the preparation of hydrocarbon resins

Metal oxide solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer (e.g., styrene based monomers), C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5° C. to 170° C. can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerization catalysts since the acid sites are an integral part of the solid. The solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.

Solid acids as catalysts for the preparation of hydrocarbon resins

Solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer, C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5° C. to 170° C. can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerization catalysts since the acid sites are an integral part of the solid. The solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.

Metal halide solid acids and supported metal halides as catalysts for the preparation of hydrocarbon resins

Supported metal halides and metal halide solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer, C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5° C. to 170° C. can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerization catalysts since the acid sites are an integral part of the solid. The solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.

Liquid, aliphatic hydrocarbon resin.

Petroleum resins

In a process in which a C5 fraction from a cracked naphtha or gas oil is polymerized with the help of a Friedel Crafts catalyst to produce a petroleum resin, the resin properties are improved and polymerization time reduced by heating the C5 fraction to a temperature of at least 160*C for a period of up to 5 hours before the polymerization.

Petroleum resins

Petroleum resins

Resin use for tackification

"Process for preparing petroleum resins having low softening points and narrow molecular weight ranges"

Low softening point resins are prepared by a process which comprises polymerising using a Friedel Crafts catalyst: (1) a petroleum resin feed comprising C 5 olefins and C 5 diolefins or a mixture of C 5 and C 6 olefins and diolefins, said feed being obtained from the cracking of petroleum feedstock and being subjected to thermal soaking at a temperature of 100° C to 150° C, and (2) a branched chain reactive aliphatic olefin or an oxygenated transfer agent. Preferred additives are diisobutene or U.O.P. olefins. The polymerization may take place in the presence of a C 8 to C 10 unsaturated aromatic compound.

Petroleum resins and their production

Hot melt adhesives comprising ethylene/vinyl acetate copolymer, wax, and a resin containing 5 to 80 wt. % of units derived from olefinically unsaturated aromatic compounds, 5 to 80 wt. % of units derived from C 5 or C 6 olefines or diolefines or a mixture thereof, and from 7 to 45% of units derived from a terpene. The hot melt adhesive composition has improved color and compatibility over ethylene/vinyl acetate copolymer and wax blends containing resins of significant portions of cyclopentadiene or dicyclopentadiene. The hot melt adhesive of the invention also show improved adhesive properties on substrate such as glass and aluminum.

Resin use for tackification

The invention concerns formulations for hot melt pressure sensitive adhesives. The formulation includes an adhesive formulation for hot melt pressure sensitive adhesives including a styrene-butadiene block copolymer and a petroleum resin produced by copolymerising using a Friedel Craft catalyst, a mixture of (1) from 40 to 90 wt % of a feed comprising C5 olefins and/or diolefins, and/or C6 olefins and/or diolefins; (2) from 10 to 50 wt % of a feed comprising C8-C10 aromatic compounds the wt % being calculated on the basis of the total weight of polymerisable feed components. The resin should possess (a) a level of aromaticity of from 13 to 45 wt % as determined by proton NMR, (b) a softening point of from 50 to 100 °C, (c) an Mn of from 400 to 900 and an Mz of below 2200 and Mw below 1300 and a ratio of Mw/Mn of from 1.2 to 1.7

一种改善石油树脂产品性能的方法

本发明公开了一种改善石油树脂产品性能的方法，以戊烷为溶剂、三氯化铝为催化剂，以单烯烃、间戊二烯为原料，进行阳离子聚合，得到聚合液；经过减洗和水洗，使催化剂失活、除去催化剂和其它杂质；然后经过常、减压汽提除去戊烷溶剂和低聚物；再进入造粒包装前加入改性剂，所述改性剂为聚异丁烯马来酸酐。本发明提供的改善石油树脂产品性能的方法，加入改性剂马来酸酐得到的产品在做热熔路标涂料过程中，其耐候性、抗污性、流平性、附着力等均好过未加改性剂的路标涂料。

Curable modified petroleum resin, preparation method thereof, and the use comprising the same

본 발명은 석유수지 단량체, 실란 단량체 및 C3 내지 C20의 알파 올레핀 단량체가 공중합된 것으로, 반응형 폴리올레핀계 접착제 조성물의 첨가제로서 사용하여 각종 부품으로 사용되는 폴리올레핀계 기재에 대한 접착력을 높일 수 있는 경화 가능한 경화형 석유수지, 이의 제조방법 및 이의 용도에 관한 것이다. The present invention is a copolymer of a petroleum resin monomer, a silane monomer and a C3 to C20 alpha olefin monomer, which can be used as an additive in a reactive polyolefin-based adhesive composition to increase adhesion to a polyolefin-based substrate used as various parts. It relates to a curable petroleum resin, a method for manufacturing the same, and a use thereof.

Curable petroleum resin, preparation method thereof, and the use comprising of the same

본 발명은 석유수지 단량체로부터 유래된 반복단위, 실란 단량체로부터 유래된 반복단위 및 스티렌계 단량체로부터 유래된 반복단위를 포함하는 것으로, 반응형 폴리올레핀계 접착제 조성물의 첨가제로서 사용하여 각종 부품으로 사용되는 폴리올레핀계 기재에 대한 접착력을 높일 수 있는 경화 가능한 경화형 석유수지, 이의 제조방법 및 이의 용도에 관한 것이다. The present invention includes a repeating unit derived from a petroleum resin monomer, a repeating unit derived from a silane monomer, and a repeating unit derived from a styrenic monomer. It relates to a curable curable petroleum resin capable of increasing adhesion to a base material, a method for manufacturing the same, and a use thereof.

Silane-functionalized hydrocarbon polymer modifiers for elastomeric compositions

An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane-functionalized hydrocarbon polymer modifier (Si-HPM) made in a pre-reaction adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof.

Process for the preparation of aromatic modified aliphatic hydrocarbon resins giving an excellent balance between tack and shear properties

Process for the production of petroleum resins

Petroleum resins

Patent FR2107326A5

Werkwijze voor het bereiden van een aardoliehars.

Patent JPS5534167B1

Resines de petrole

Werkwijze voor het bereiden van een aardoliehars.

Werkwijze voor de bereiding van een grondstof voor kunstharsen op aardoliebasis, werkwijze voor de bereiding van kunstharsen op aardoliebasis daaruit en gevormde voortbrengselen, vervaardigd onder toepassing van de aldus bereide kunstharsen.

Resines de

Petroleum resins

In the production of a petroleum resin an unsaturated hydrocarbon feedstock is continuously polymerised by means of a Friedel-Crafts catalyst in a plurality of alternating polymerisation and cooling zones in which catalyst is added to each polymerisation zone.

Patent JPS5617364B2

Process for the continuous production of indene resins

A process for the continuous production of indene resins comprising the steps of continuously pre-heating an indene-containing hydrocarbon mixture, continuously adding a boron trifluoride-adduct catalyst and the pre-heated indene-containing mixture to a reaction tube, continuously isothermally reacting the indene-containing mixture with the catalyst at the temperature of the pre-heated mixture to form an indene-containing resin, continuously decomposing the catalyst, and continuously separating the indene-containing resin from the decomposed catalyst and unreacted substances.

Synthetic resins derived from petroleum

1499005 Modifying hydrocarbon oils IMPERIAL CHEMICAL INDUSTRIES Ltd 24 March 1976 [16 April 1975] 15642/75 Addition to 1360389 Heading C5E [Also in Division C3] The process of parent Specification is modified in that the C5 stream which is preheated at at least 160‹ C. for not more than 5 hours is a stream which contains at least 0À5% by weight of butadiene. The preparation of the stream may be modified so that it contains the required amount of butadiene or butadiene may be added to a C5 stream.

Preparation of petroleum resin

Steam or

Petroleum resins

Verfahren zur Herstellung von Erdölharzen

8 Process for the production of petroleum resins

Synthetic resins derived from petroleum

1404580 Petroleum resins IMPERIAL CHEMICAL INDUSTRIES Ltd 29 Nov 1972 [15 Dec 1971] 58225/71 Addition to 1360389 Heading C3P [Also in Division C5] The process of the parent Specification 1,360,389 is modified by holding the C 5 stream at. a temperature between 100‹ and 160‹ C. for not more than five hours but long enough to dimerize the cyclopentadiene contained in the mixture, after the heat soak above 160‹ C. but before the polymerization.

Process for the preparation of hydrocarbon polymers

Process for producing hydrocarbon resin and pressure-sensitive adhesives containing same

Process for producing a hydrocarbon resin, characterized in that it comprises copolymerizing 100 parts by weight of vinylaromatic hydrocarbons (A) that contain more than 80% by weight of isopropenyl toluene and about 5 to 100 parts by weight of a fraction (B) which is the by-product of cracking or petroleum refining and comprising mainly unsaturated hydrocarbons having a boiling point of about -15ºC to + 45ºC and having 4 to 5 carbon atoms, in the presence of a Friedel-Crafts catalyst. (Machine-translation by Google Translate, not legally binding)

Synthetic rubber composition

1343515 Tackifiers for synthetic rubber NIPPON OIL CO Ltd 19 Oct 1971 [20 Oct 1970] 48532/71 Heading C3P Synthetic rubber compositions contain, as a tackifier, 3-30 phr of a phenol-modified resin obtained by polymerizing 100 parts by weight of a hydrocarbon mixture boiling in the range 140-180‹ C., containing unsaturated hydrocarbons and produced by cracking of petroleum, and 3-15 parts of a phenolic compound in the presence of 0À05-5 parts of a catalyst selected from BF 3 , complexes thereof, and AlCl 3 . In examples the rubber is alfin-type SBR, conventional SBR or SBR/polybutadiene rubber blend, and the compositions also contain carbon black, processing oil and conventional vulcanizing ingredients.

Process for preparing petroleum resin

Procedure to prepare a petroleum resin, which comprises polymerizing a hydrocarbon fraction by-product of refining, cracking, etc., of petroleum, which contains 5 carbon atoms, and which boils at temperatures between 30 and 45ºC, mainly composed of saturated hydrocarbons having 5 carbon atoms in the molecule, in the presence of an aluminum chloride catalyst. (Machine-translation by Google Translate, not legally binding)

基于二环戊二烯的树脂组合物以及由其制造的制品

本发明涉及基于二环戊二烯的树脂组合物以及由其制造的制品。该组合物包括至少一种弹性体、和烃聚合物添加剂，所述烃聚合物添加剂具有占所述烃聚合物添加剂总重量约40wt％‑约80wt％的得自二环戊二烯、环戊二烯、和甲基环戊二烯的含量，约100g/摩尔‑约800g/摩尔的重均分子量，和根据ASTM D6090测定的约110℃‑约150℃的软化点。

POLYMERIZATION OF LIQUID C LOW 1-8 REFINING GAS MIXTURE

Isomerization and polymerization of hydrocarbon resins

Hydrocarbon resins having an increased softening point are obtained by a process featuring the sequential steps of: isomerizing the 2-methylbutene-1 component of a branched olefin modifier stream whereby its 2-methylbutene-2 content is enriched; polymerizing a feedstock consisting of the mixture of said enriched modifier stream and a piperylene rich feed stream; and, recovering said hydrocarbon resin with properties enhancing its utility for adhesive applications.

Procedes de polymerisation a l'aide de catalyseurs de friedel-crafts perfectionnes

一种碳五共聚石油树脂的制备方法

本发明涉及有机合成技术领域，具体涉及一种碳五共聚石油树脂的制备方法。具体包括如下步骤：C5原料预处理、聚合、洗涤、常压蒸馏、减压蒸馏和造粒。采用本发明的步骤制备碳五共聚石油树脂，工艺简单、节能、反应可控，具有较高的经济效益，适合工业化生产；所得产品色泽较浅、软化点较高、相容性能更好。

Welding method with laser application of metal, parts obtained by this method, and application in oil, gas and petrochemical industries

FIELD: oil, gas and petrochemical industries.SUBSTANCE: invention relates to a component for use in the oil, gas and / or petrochemical industries. The component includes at least two adjacent segments, laser welded joints connecting the adjacent segments and possibly a heat affected zone (HAZ) adjacent to the welds, where the HAZ, if present, has a thickness of 0, 0025 cm (0.001 in.) or less. Segments include common grade carbon steel, cast iron, low alloy steel, high carbon steel having a carbon equivalent (CE) greater than or equal to 0.48, titanium alloy, nickel-based alloy, cobalt-based alloy, iron-nickel alloy, duplex stainless steel or their combinations.EFFECT: invention is aimed at increasing reliability of the welded joint by eliminating or practically eliminating the heat-affected zone and, accordingly, increasing the strength and toughness of the component.13 cl, 8 dwg, 1 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 746 510 C2 (51) МПК B23K 26/211 (2014.01) B23K 26/144 (2014.01) B23P 6/00 (2006.01) B23K 101/10 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК B23K 26/211 (2021.02); B23K 26/144 (2021.02); B23P 6/00 (2021.02) (21)(22) Заявка: 2019112703, 22.09.2017 (24) Дата начала отсчета срока действия патента: (73) Патентообладатель(и): ЭКССОНМОБИЛ РИСЕРЧ ЭНД ЭНДЖИНИРИНГ КОМПАНИ (US) Дата регистрации: 14.04.2021 17.10.2016 US 62/408,977 (43) Дата публикации заявки: 17.11.2020 Бюл. № 32 (45) Опубликовано: 14.04.2021 Бюл. № 11 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 17.05.2019 (56) Список документов, цитированных в отчете о поиске: David Locke ET AL : "Laser metal deposition defined- Industrial Laser Solutions", 11.01.2010, retrieved from Internet: https://www.industrial-lasers.com/articles/print/ volume-250/issue-6/features/laser-metaldeposition.html (найдено в Интернет 28.12.2020). CN 2838759 Y, 22.11.2006. JP 2006068819 A, 16.03.2006. JP 7060466 A, 07.03.1995. RU 2166421 ( ...

Hydrogenated petroleum resins and their use in adhesives

내용 없음. No content.

Liquid-phase resin composition and process of preparing the same

The present invention relates to a rubber composition comprising a polymer of C_9 monomers modified with a molecular weight modifier and a viscosity modifier, and a method for preparing the same. The rubber composition according to the present invention has improved processability and thus can replace process oils, and at the same time, can significantly improve air impermeability.

Method of manufacturing petroleum resin

본 발명은 석유수지의 제조 방법에 관한 것이다. 이 제조 방법은 나프타등 석유류의 열분해 과정에서 생성되는 비점범위 20 ~ 60℃, 탄소수 4 ~ 6인 불포화탄화수소를 포함하는 혼합 유분을 가열하여 상기 혼합 유분내에 포함되어 있는 환상 공액 디엔류 화합물을 이량화하는 단계; 얻어진 생성물을 증류하여 상기 이량화된 환상 공액 디엔류를 제거하는 단계; 얻어진 환상 공액 디엔류가 제거된 혼합 유분을 프리델-크라프트형 촉매를 사용하여 양이온 중합하는 단계를 포함하는 석유수지의 제조 방법에 있어서, 환상 공액 디엔류를 제거하는 단계 후에, 상기 환상 공액 디엔류가 제거된 혼합유분을 분별증류에 의해, 1,3-펜타디엔에 대한 이소프렌의 중량비가 1/3 이하인 유분(유분 B)와 나머지 이소프렌을 포함하는 유분(유분 A)로 분리하는 단계; 상기 유분 A중의 이소프렌의 90중량% 이상을 부분수소첨가에 의해 메틸부텐류 화합물로 전환시켜 유분 C를 제조하는 단계; 및 상기 유분 C를 상기 유분 B와 혼합하는 단계를 더욱 실시한 후, 이 혼합 유분을 프리델-크라프트형 촉매를 사용하여 양이온 중합하는 단계를 실시하는 것을 특징으로 하는 석유 수지의 제조 방법으로서, 이 석유 수지는 70 ~ 120℃의 연화점을 갖는 석유 수지의 제조 방법을 제공한다. The present invention relates to a method for producing a petroleum resin. This manufacturing method heats a mixed fraction containing unsaturated hydrocarbons having a boiling point of 20 to 60 ° C. and a carbon number of 4 to 6 generated during pyrolysis of petroleum such as naphtha and dimerizing the cyclic conjugated diene compound contained in the mixed fraction. Doing; Distilling the obtained product to remove the dimerized cyclic conjugated dienes; In the method for producing a petroleum resin comprising a step of cationic polymerization of the mixed fraction from which the obtained cyclic conjugated dienes have been removed using a Friedel-Craft catalyst, after the step of removing the cyclic conjugated dienes, Separating the removed mixed fraction into fractions (oil B) having fractions of 1/3 of isoprene to 1,3-pentadiene by weight distillation (oil B) and the remaining isoprene (oil A); Converting at least 90% by weight of isoprene in fraction A to methylbutene compounds by partial hydrogenation to prepare fraction C; And further carrying out the step of mixing the fraction C with the fraction B, followed by cationic polymerization of the mixed fraction using a Friedel-Craft catalyst. Provides a method for producing a petroleum resin having a softening point of 70 ~ 120 ℃. 이 제조 방법은 고품질의 석유수지를 경제적으로 제조할 수 있다. This manufacturing ...

Petroleum resins of improved color and process for making the same

An petroleum resin of improved color and process for making the same are provided. The improvement in color is the result of a "dry" quench process, in which the polymerizate of an olefinic, diolefinic, aromatic or mixed hydrocarbon feedstock polymerized in the presence of a Friedel-Crafts catalyst is quenched by admixing the polyemrizate with a phosphite instead of the familiar water wash quenching procedure.

Method of producing light petroleum polymer resins

FIELD: paint industry.SUBSTANCE: invention relates to a method of producing petroleum polymer resins used to produce paintwork materials. Described is a method of producing petroleum polymer resins by polymerization of unsaturated compounds of a fraction of liquid pyrolysis products of straight-run gasolines in the presence of a catalyst system with subsequent deactivation of the catalyst system with 1,2-epoxypropane. Catalyst system contains zeolite H-ZSM-5/20 % AlO, impregnated with CoClin amount of 2.0–3.0 % of the weight of the fraction, and Al (CH)Cl, taken in molar ratio of 1–1.2:1 with respect to CoCl. Process is carried out at temperature 65–95°C for 120 minutes.EFFECT: reduction of process duration, reduction of process temperature, as well as reduction of catalyst consumption due to possibility of its secondary use.1 cl, 1 tbl, 11 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 691 756 C1 (51) МПК C08F 240/00 (2006.01) C08F 6/02 (2006.01) C08F 6/08 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C08F 240/00 (2019.02); C08F 6/02 (2019.02); C08F 6/08 (2019.02) (21)(22) Заявка: 2018125610, 11.07.2018 (24) Дата начала отсчета срока действия патента: Дата регистрации: 18.06.2019 (45) Опубликовано: 18.06.2019 Бюл. № 17 Адрес для переписки: 634055, г. Томск, пр-кт Академический, 4, Федеральное государственное бюджетное учреждение науки Институт химии нефти Сибирского отделения Российской академии наук (ИХН СО РАН) 2 6 9 1 7 5 6 C 1 (56) Список документов, цитированных в отчете о поиске: МАНАНКОВА А.А. и др. Известия Самарского научного центра РАН. Специальный выпуск "Безопасность. Технологии. Управление", т.1, 2007, с.68-70. RU 2326896 C1, 20.06.2008. RU 2218358 C1, 10.12.2003. ДУМСКИЙ Ю.В., Нефтеполимерные смолы, Москва, Химия, 1988, с.7-14. JP 0062064811 А, 23.03.1987. (54) СПОСОБ ПОЛУЧЕНИЯ СВЕТЛЫХ НЕФТЕПОЛИМЕРНЫХ СМОЛ (57) Реферат: Изобретение относится к способу получения пропитанный СоСl2 в количестве 2 ...

Hydrogenated petroleum resin, preparation method thereof, and the use of the same

본 발명은 수소첨가 석유수지, 이의 제조방법 및 용도에 관한 것으로, 보다 상세하게는 디사이클로펜타디엔과 올레핀계 단량체를 열중합 후 수소첨가 반응을 통해 제조한 수소첨가 석유수지 및 이의 제조방법 및 용도에 관한 것이다. 상기 수소첨가 석유수지는 저렴한 원료를 이용하여 열중합을 통해 제조되어 종래 촉매 중합과는 달리 촉매 제거 공정을 배제할 수 있어 실용화에 유리한 이점이 있다. 이렇게 제조된 수소첨가 석유수지는 상용성이 우수하면서, 접착능 및 내열성이 우수하고 취기가 없어 친환경 위생용품에 사용하는 접착제 등으로 적용될 수 있다. The present invention relates to a hydrogenated petroleum resin, a process for producing the hydrogenated petroleum resin, and a use thereof, and more particularly, to a hydrogenated petroleum resin prepared by thermally polymerizing dicyclopentadiene and an olefin monomer through hydrogenation, . The hydrogenated petroleum resin can be produced through thermal polymerization using an inexpensive raw material and can be excluded from the catalyst removal process unlike the conventional catalyst polymerization, which is advantageous for practical use. The hydrogenated petroleum resin thus prepared is excellent in compatibility and excellent in adhesiveness and heat resistance, and can be applied as an adhesive for use in environmentally friendly hygiene products since it is not odor-free.

Process for producing hydrogenated petroleum resin

수소화 용매 제거 공정에서 수소화 용매를 분리한 후의 용융 수지인 수소화 화합물(수소 첨가 석유 수지)의 근적외 흡수 스펙트럼을 측정하고, 검량선 데이터에 기초하여 수소화 화합물의 물성값인 방향족 함유율과 브롬가와 연화점을 산출한다. 근적외 분석으로 측정한 방향족 함유율과 브롬가와, 제조 목적의 수소 첨가 석유 수지 펠릿의 방향족 함유율과 브롬가의 차이분이 작아지도록, 수소화 반응부(3)에 있어서의 온도와, 압력과, 반응 시간과, 수소량 중 적어도 어느 하나의 운전 조건을 제어한다. 근적외 분석으로 측정한 연화점과, 제조 목적의 수소 첨가 석유 수지 펠릿의 연화점의 차이분이 작아지도록, 박막 증발기(42)의 온도와 압력 중 적어도 어느 한쪽을 제어한다. The near infrared absorption spectrum of the hydrogenated compound (hydrogenated petroleum resin) as the molten resin after the hydrogenation solvent is separated in the hydrogenation solvent removal step is measured and the aromatic content, the aromatic content, the bromine value and the softening point are calculated based on the calibration curve data . The temperature, the pressure, the reaction time, and the temperature in the hydrogenation reaction section 3 are controlled so that the aromatic content and the bromine value measured by the near infrared analysis, the aromatic content of the hydrogenated petroleum resin pellets for production, And an amount of hydrogen. At least one of the temperature and the pressure of the thin film evaporator 42 is controlled so that the difference between the softening point measured by the near infrared analysis and the softening point of the hydrogenated petroleum resin pellet for production is reduced.

수소화된 수지, 접착제 재형 및 수지의 제조방법

내용 없음

수소첨가 석유수지 및 이를 포함하는 고무 조성물

본 발명은 수소첨가 석유수지 및 이를 포함하는 고무 조성물에 관한 것으로, 본 발명에 따른 수소첨가 석유수지는 이를 포함하는 고무의 점탄성 특성을 향상시킬 뿐만 아니라 고무와의 상용성이 우수하여 고무의 전반적인 물성을 개선시킬 수 있다. 이에 상기 수소첨가 석유수지를 포함하는 고무 조성물로부터 제조된 고무 성형품, 예컨대 타이어는 그립력(wet/dry)이 향상되고, 그립력 향상에 따른 회전 저항의 상승폭을 낮춰 타이어로서 요구되는 그립력과 회전 저항의 두 가지 물성을 동시에 만족시킴으로써 저연비 고성능 타이어를 제조할 수 있다.

수소첨가 석유수지 및 이를 포함하는 고무 조성물

본 발명은 수소첨가 석유수지 및 이를 포함하는 고무 조성물에 관한 것으로, 본 발명에 따른 수소첨가 석유수지는 이를 포함하는 고무의 점탄성 특성을 향상시킬 뿐만 아니라 고무와의 상용성이 우수하여 고무의 전반적인 물성을 개선시킬 수 있다. 이에 상기 수소첨가 석유수지를 포함하는 고무 조성물로부터 제조된 고무 성형품, 예컨대 타이어는 그립력(wet/dry)이 향상되고, 그립력 향상에 따른 회전 저항의 상승폭을 낮춰 타이어로서 요구되는 그립력과 회전 저항의 두 가지 물성을 동시에 만족시킴으로써 저연비 고성능 타이어를 제조할 수 있다.

一种浅色低软化点改性石油树脂的制备方法

本发明属于石油树脂技术领域，具体涉及一种浅色低软化点改性石油树脂的制备方法。一种制备浅色低软化点改性石油树脂的方法，以石油裂解制乙烯的副产品C5馏分经过两次预处理脱除环戊二烯和双环戊二烯后得到环戊二烯含量极低的含有多种二烯烃、单烯烃和烷烃的混合物为原料，选取芳香族乙烯基单体的一种或几种作为聚合改性剂，选取复配催化剂，在一定的聚合条件下，使C5中的烯烃与芳香族乙烯基单体进行聚合反应，并对聚合反应热进行有效控制，使反应平缓，而制得质量稳定、性能优良、分子量适中的浅色低软化点的改性石油树脂。

Production of polybutene with static mixer

Fresh feed of C 1 -C 5 refinery gases containing predominantly polymerizable butenes are rapidly mixed and diluted with Friedel-Crafts catalyst and recycle reaction mixture in a static mixer before passing to the polymerization reaction column whereby the temperature is more readily controlled to a constant value to produce polybutene of more constant quality in higher yield and with less catalyst loss.

Способ сварки с лазерным нанесением металла, детали, полученные этим способом, и применение в нефтяной, газовой и нефтехимической промышленности

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2019 112 703 A (51) МПК B23K 26/00 (2014.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2019112703, 22.09.2017 (71) Заявитель(и): ЭКССОНМОБИЛ РИСЕРЧ ЭНД ЭНДЖИНИРИНГ КОМПАНИ (US) Приоритет(ы): (30) Конвенционный приоритет: 17.10.2016 US 62/408,977 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 17.05.2019 R U (43) Дата публикации заявки: 17.11.2020 Бюл. № 32 (72) Автор(ы): МА Нинг (US) (86) Заявка PCT: (87) Публикация заявки PCT: WO 2018/075195 (26.04.2018) R U (54) СПОСОБ СВАРКИ С ЛАЗЕРНЫМ НАНЕСЕНИЕМ МЕТАЛЛА, ДЕТАЛИ, ПОЛУЧЕННЫЕ ЭТИМ СПОСОБОМ, И ПРИМЕНЕНИЕ В НЕФТЯНОЙ, ГАЗОВОЙ И НЕФТЕХИМИЧЕСКОЙ ПРОМЫШЛЕННОСТИ (57) Формула изобретения 1. Компонент из черного или цветного металла для нефтяной, газовой и/или нефтехимической промышленности, включающий: два или более предназначенных для соединения сегментов компонентов из черного или цветного металла, при этом эти два или более сегментов изготовлены из одного и того же или из различных материалов, и полученные посредством лазерного нанесения металла сварные узлы, связывающие соседние сегменты указанных компонентов. 2. Компонент по п. 1, где указанный компонент из черного или цветного металла представляет собой обычную углеродистую сталь, чугун, низколегированную сталь, высокоуглеродистую сталь, имеющую углеродный эквивалент (СЕ) больший или равный 0,48, титановый сплав, сплав на основе никеля, сплав на основе кобальта, железоникелевый сплав, дуплексную нержавеющую сталь или их сочетания. 3. Компонент по любому из пп. 1, 2, где условия лазерного нанесения металла включают тип лазера, тип металлического порошка, тип защитного газа, расход защитного газа, мощность лазера, размер лазерного пятна и скорость нанесения, и где тип металлического порошка выбран из группы, состоящей из нержавеющих сталей, инструментальных сталей, никелевых сплавов, кобальтовых сплавов, титановых сплавов, наплавляемых твердых сплавов или ...

用于制备烃树脂的金属卤化物固体酸和在载体上的金属卤化物催化剂

在载体上的金属卤化物和金属卤化物固体酸用作催化剂,用于使含有纯单体、C5单体、和C9单体中至少之一的原料聚合制备烃树脂。在使用前,可以从固体酸催化剂上除去自由缔合水。制备的树脂的软化点(环球法)为约5～170℃。这些催化剂比传统的Friedel－Crafts聚合催化剂好,因为酸性位点是固体的组成部分。固体酸催化剂是相对安全的、可重复使用的催化剂,它消除或至少减少了残余酸或副产物对得到的树脂产品的污染。

Metal oxide solid acids as catalysts for the preparation of hydrocarbon resins

Metal halide solid acids and supported metal halides as catalysts for the preparation of hydrocarbon resins

Supported metal halides and metal halide solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer, C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5 ~C to 170 ~C can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerization catalysts since the acid sites are an integral part of the solid. The solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.

FLUORINATED SOLID ACID AS CATALYSTS FOR THE PRODUCTION OF HYDROCARBON RESINS

Metal oxide solid acids as catalysts for the preparation of hydrocarbon resins

Metal oxide solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer (e.g., styrene based monomers), C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5 °C to 170 °C can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerization catalysts since the acid sites are an integral part of the solid. The solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.

Verfahren zur Herstellung eines Kohlenwasserstoffharzes

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung eines Kohlenwasserstoffharzes durch Polymerisation einer Monomerzusammensetzung enthaltend mindestens ein Monomer ausgewählt aus der Gruppe bestehend aus Vinyltoluol, Styrol, alpha-Methylstyrol, beta-Methylstyrol, Inden, Dicyclopentadien und deren alkylierte Derivate. Dabei wird ein Kohlenwasserstoffgemisch enthaltend die Monomerzusammensetzung und mindestens 30 Gew.% eines organischen Lösungsmittels mit einer sauren ionischen Flüssigkeit in Kontakt gebracht, wodurch das Kohlenwasserstoffharz erhalten wird.

一种以c9馏分为原料制备石油树脂的方法

本发明公开了一种以C9馏分为原料制备石油树脂的方法旨在提供一种提高石油树脂产率、缩短反应时间和提高产品质量，改进后处理工艺，减少后处理产生环境污染的石油树脂的制备方法；其技术要点：该方法：1)以原料体积15‑25％的正庚烷作为溶剂，将原料和溶剂加入到带有搅拌装置的反应器中，再加入Al‑MCM‑41分子筛负载的磷钨酸为催化剂，催化剂用量为原料质量的1％‑3％；2)加入氮气进行置换，启动搅拌，釜中压力设定为0.4‑0.9MPa，加热到60‑100℃，并在此温度下持续搅拌5‑10h，反应完毕，用氮气压出粗石油树脂，常温减压蒸馏，回收溶剂，便C9石油树脂。

石油树脂的改性方法

本发明公开一种石油树脂的改性方法，属于树脂加工技术领域。本发明按重量份计，将100份原料石油烃类裂解的C5馏分和C9馏分经过预处理后放入反应釜内，加入1份～2份聚合催化剂和50份～80份溶剂，以及同时以200L/h～1000L/h的流速通入纯度为99.9%的氢气，然后在三相点以下压力和波长为100nm～200nm的紫外线照射下，加热至80℃～105℃反应2小时～3小时，最后精制而得。本发明是通过在石油树脂生产过程的聚合反应中通入高纯度的氢气，并在特定压力、特定波长的紫外线照射下，使石油烃类裂解的C5馏分和C9馏分发生聚合反应的同时发生改性，从而使产物石油树脂的综合性能提到提高。

一种液态改性芳烃石油树脂的制备方法

本发明涉及一种液态改性芳烃石油树脂的制备方法，包括：将茚、苯乙烯及C5烯烃饱和溶剂混合后得到的聚合原料经泡沫陶瓷负载固体酸催化剂催化聚合获得聚合树脂液，再经吸附过滤、精馏脱除溶剂即得。本发明的制备方法工艺简便、聚合条件温和，减少了“三废”产生，所得的液态改性树脂具有良好相容性，适用于橡胶混炼、塑料改性等领域。

Polymers from piperylene concentrates

Resins from selected distillates

Controlled isobutylene polymerization

수첨 석유수지의 연속적 제조 방법

본 발명은 수첨 석유수지의 연속적 제조 방법에 관한 것이다. 보다 상세하게는, 연속적 수소화 반응을 통해 수첨 석유수지의 용도에 따라 APHA 값과 수첨화도를 용이하게 조절할 수 있는, 수첨 석유수지의 연속적 제조 방법에 관한 것이다.

Polymerizing C5 and C6 olefins and diolefins with 3° hydrocarbyl halide to produce narrow molecular weight petroleum resins having low softening points

A petroleum resin is prepared by a process which comprises polymerizing using a Friedel-Crafts catalyst: A. a petroleum resin feed comprising C 5 and C 5 diolefins, C 6 olefins and C 6 diolefins or a mixture of C 5 and C 6 olefins and diolefins, said feed being obtained from the cracking of petroleum feedstock and B. at least 0.5 wt.% based on the petroleum resin feed of a tertiary hydrocarbyl halide. The resulting resin usually has a softening point of 20° to 125° C. These resins have an extremely narrow molecular weight distribution and hence have good wax compatibility, viscosity, flexibility and tackifying properties for rubber.

Process for producing hydrocarbon resins having improved color and thermal stability by heat treatment with an α,βunsaturated anhydride

A hydrocarbon resin having improved color and thermal stability is prepared from a petroleum cracking or reforming fraction containing cationically polymerizable hydrocarbons and having a boiling range of 140° to 280° C. The petroleum fraction is first heat-treated with an α, β-unsaturated dicarboxylic acid anhydride at 50° to 250° C., and then polymerized in the presence of a catalyst. The hydrocarbon resin is useful as a binder component in hot-melt adhesives, pressure-sensitive adhesives and thermofusible traffic paints.

Petroleum resins containing vinyl norbornene or tetrahydroindene

A resin suitable as a tackifier is prepared by polymerizing using a Friedel Crafts catalyst: (1) a petroleum resin feed comprising C 5 olefins and diolefins, C 6 olefins and diolefins or a mixture of C 5 and C 6 olefins and diolefins, said feed being obtained from the cracking of petroleum feedstock, and (2) an additive comprising vinyl norbornene or tetrahydroindene. The resin thus prepared may be mixed with a natural or synthetic rubber.

Hydrocarbon resin prepared from antimony pentafluoride or ferric chloride

There is disclosed a hydrocarbon derived resin having a structure characterized by a softening point in the range of about 0° C. to about 45° C. and comprising from about 40 to about 80 weight percent units derived from piperylene and correspondingly from about 60 to about 20 weight percent units derived from 2-methyl-2-butene prepared by the method which comprises polymerizng a mixture comprising from about 20 to about 75 weight percent piperylene and correspondingly from about 80 to about 25 weight percent 2-methyl-2-butene in the presence of a catalyst selected from antimony pentafluoride and ferric chloride. The resin has particular utility when combined with rubber as a tackifier to form pressure sensitive adhesives.

Process for producing hydrocarbon resins having improved color and thermal stability

A process for producing a hydrocarbon resin having improved color and thermal stability, which comprises treating a petroleum cracking or reforming fraction containing cationically polymerizable hydrocarbons and not more than 0.7% by weight, based on the fraction, of cyclopentadienes and having a boiling range of from 140° C. to 280° C., with 0.8 to 3.0 moles, per mole of the cyclopentadienes, of a dienophile compound having a carbon-to-carbon double bond and a carbonyl or cyano group adjacent to the double bond; and then polymerizing the treated petroleum fraction in the presence of a polymerization catalyst.

Carene modified petroleum resins

Producing modified petroleum resins by the Friedel Crafts copolymerization of a C 5 olefines and diolefines, C 6 olefines or diolefines or a mixture of C 5 and C 6 olefines and diolefines feed and carene optionally together with a branched chain olefine.

Low color, high softening point aromatic resin and method for its production

Petroleum resins of lightened color while retaining satisfactory melting point and compatibility are provided by a process which comprises catalytically polymerizing an aromatic petroleum cracked or reformed fraction, e.g. an aromatic stream boiling between 80° C. and 260° C., sequentially treated with sulfuric Acid followed by distillation to provide an aromatic feedstock portion which is blended with an aliphatic petroleum cracking or reforming fraction feedstock portion containing cationically polymerizable hydrocarbons, less than 0.5 weight percent of cyclodienes and a pentadiene-1,3 to cyclodiene weight ratio of greater than 50, preferably at least 200 in the presence of a Friedel-Craft catalyst into a petroleum resin of lightened color and softening point in the range of 90° C. to 115° C.

Petroleum resins and their production

Resins having an improved combination of softening point and tackifying properties together with good color and heat stability are obtained by Freidel-Crafts copolymerization of 4 to 80 wt. % of a C 5 /C 6 unsaturated feed; 5 to 55 wt. % of a terpene and 3 to 55 wt. % of an unsaturated aromatic compound.