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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 9235. Отображено 100.
31-05-2012 дата публикации

Acrylamide-derived cationic copolymers, and uses thereof

Номер: US20120132382A1
Принадлежит: SPCM SA

Cationic or amphoteric (co)polymer obtained by Hofmann degradation reaction, in aqueous solution, in the presence of an alkaline-earth and/or alkali metal hydroxide and of an alkaline-earth and/or alkali metal hypohalide, on a base (co)polymer comprising at least one nonionic monomer chosen from the group comprising acrylamide (and/or methacrylamide) and N,N-dimethylacrylamide, is characterized in that the base (co)polymer is modified beforehand with at least one polyfunctional compound containing at least 3 heteroatoms chosen from N, S, O and P and each having at least one mobile hydrogen. Use as a flocculation, retention and/or drainage aid, and dry strength aid is contemplated.

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02-08-2012 дата публикации

Method for re-wetting surface post-cross-linked, water-absorbent polymer particles

Номер: US20120196987A1
Принадлежит: BASF SE

A process for producing water-absorbing polymer particles, wherein surface postcrosslinked water-absorbing polymer particles are remoisturized and classified, and wherein the time between remoisturization and classification is at least 15 minutes.

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30-08-2012 дата публикации

Process for producing hydrolyzable silyl group-containing fluoropolymer, and composition containing hydrolyzable silyl group-containing fluoropolymer

Номер: US20120220712A1
Принадлежит: Asahi Glass Co Ltd

The present invention has an object to provide a process for producing a hydrolyzable silyl group-containing fluoropolymer which is excellent in storage stability and has a sufficient pot life. At the time of producing a hydrolyzable silyl group-containing fluoropolymer by reacting an isocyanate group of an isocyanate group-containing alkoxysilane to a hydroxy group of a hydroxy group-containing fluoropolymer, the reaction is carried out in the presence a compound containing a specific metal atom at a certain concentration.

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14-03-2013 дата публикации

Epoxy resin composition for semiconductor encapsulant and semiconductor device using the same

Номер: US20130062748A1
Автор: Jun-Ichi Tabei
Принадлежит: Sumitomo Bakelite Co Ltd

According to the present invention, an epoxy resin composition for semiconductor encapsulant including (A) an epoxy resin, (B) a curing agent, (C) an inorganic filler, and (D) a compound in which a copolymer of a 1-alkene having 5 to 80 carbon atoms and maleic anhydride is esterified with an alcohol having 5 to 25 carbon atoms in the presence of a compound represented by General Formula (1), wherein R 1 in General Formula (1) is selected from the group consisting of an alkyl group having 1 to 5 carbon atoms, a halogenated alkyl group having 1 to 5 carbon atoms, and an aromatic group having 6 to 10 carbon atoms is provided.

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25-07-2013 дата публикации

Adhesive complex coacervates and method of making and using thereof

Номер: US20130189313A1

Described herein is the synthesis of adhesive complex coacervates and their use thereof. The adhesive complex coacervates are composed of a mixture of one or more polycations and one or more polyanions. The polycations and polyanions in the adhesive complex coacervate are crosslinked with one another by covalent bonds upon curing. The adhesive complex coacervates have several desirable features when compared to conventional bioadhesives, which are effective in water-based applications. The adhesive complex coacervates described herein exhibit good interfacial tension in water when applied to a substrate (i.e., they spread over the interface rather than being beaded up). Additionally, the ability of the complex coacervate to crosslink intermolecularly increases the cohesive strength of the adhesive complex coacervate. They have numerous biological applications as bioadhesives and drug delivery devices and are particularly useful in underwater applications and situations where water is present such as, for example, physiological conditions.

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24-10-2013 дата публикации

Fluoropolymer compositions and purification methods thereof

Номер: US20130281607A1
Принадлежит: 3M Innovative Properties Co

Described herein is a composition comprising an aqueous polymerization reaction product of fluorinated monomers and wherein the polymerization is initiated (i) in the absence of a fluorinated emulsifier and whereby no fluorinated emulsifier is added during polymerization or (ii) in the presence of an fluorinated emulsifier selected from: [R f —O-L-COO-] i X i+ (I) wherein L represents a linear or branched, non-fluorinated, partially fluorinated, or fully fluorinated alkylene group, R f represents a linear or branched partially or fully fluorinated aliphatic group or a linear or branched partially or fully fluorinated aliphatic group interrupted with at least one oxygen atom, X i+ represents a cation having the valence i and i is 1, 2 or 3; wherein the reaction product and/or the resulting aqueous phase are substantially free of di- and tri-alkylamines and substantially free of low molecular weight fluoroorganic compounds and methods thereof.

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07-01-2021 дата публикации

HOLLOW PARTICLES, METHOD FOR PRODUCING SAME, AND USAGE OF SAME

Номер: US20210001300A1
Принадлежит: SEKISUI KASEI CO., LTD.

This invention provides hollow particles having a shell containing at least one layer and having an average particle diameter of 10 to 150 nm, wherein a ratio β between absorbance at 908 cm(A908) and absorbance at 1722 cm(A1722) in an infrared absorption spectrum obtained by measuring the hollow particles by ATR-FTIR (absorbance ratio β: A908/A1722) is 0.1 or less. 1. A method for producing hollow particles having a shell containing at least one layer and having an average particle diameter of 10 to 150 nm , the method comprisingperforming a reaction of at least one epoxy group- or oxetane group-containing radical reactive monomer; andperforming a reaction with at least one water-soluble amine compound until the remaining unreacted epoxy group amount is 0.9 mmol/g or less.2. Hollow particles having a shell containing at least one layer and having an average particle diameter of 10 to 150 nm ,{'sup': −1', '−1, 'wherein a ratio β between absorbance at 908 cm(A908) and absorbance at 1722 cm(A1722) in an infrared absorption spectrum obtained by measuring the hollow particles by ATR-FTIR (absorbance ratio β: A908/A1722) is 0.1 or less.'}3. The hollow particles according to claim 2 , having a hollow ratio of 35 volume % or more.4. The hollow particles according to claim 2 , wherein the at least one layer contains nitrogen and carbon claim 2 , and wherein a nitrogen abundance ratio N and a carbon abundance ratio C obtained by measuring the hollow particles by XPS satisfy the relationship of 0.01≤N/C≤0.2.5. The hollow particles according to claim 2 , wherein the at least one layer contains a cross-linked copolymer derived from at least one epoxy group- or oxetane group-containing radical reactive monomer and at least one water-soluble amine compound.6. The hollow particles according to claim 2 , wherein the at least one layer contains a copolymer derived from at least one epoxy group- or oxetane group-containing radical reactive monomer and at least one silyl group- ...

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05-01-2017 дата публикации

ELECTRODE COMPOSITION FOR CAPACITIVE DEIONIZATION DEVICE, AND ELECTRODE FOR CAPACITIVE DEIONIZATION DEVICE CONTAINING THE SAME

Номер: US20170001188A1
Автор: Choi Yeong Suk, LIM Ju Wan
Принадлежит: SAMSUNG ELECTRONICS CO., LTD.

Provided are a binder composition for an electrode for a capacitive deionization device including a first polymer including a first structural unit including a zwitterionic functional group and a second structural unit including a cross-linkable functional group, a cross-linking agent, and ionic functional group, an electrode for a capacitive deionization device including the composition, a capacitive deionization device including the electrode, and a method of removing ions from a fluid using the device. 3. The electrode binder composition for a capacitive deionization device of claim 1 , wherein A of Chemical Formula 1 is a hydroxy group claim 1 , a carboxyl group claim 1 , a sulfonic acid group claim 1 , a phosphonic acid group claim 1 , an acrylate group claim 1 , a methacrylate group claim 1 , or a halogenated salt.4. The electrode binder composition for a capacitive deionization device of claim 1 , wherein Rto Rof Chemical Formula 1 are all hydrogen claim 1 , Lis a C1 to C10 alkylene group claim 1 , and A is a sulfonic acid group.5. The electrode binder composition for a capacitive deionization device of claim 1 , wherein Rof Chemical Formula 2 is methyl claim 1 , Rand Rare hydrogen claim 1 , Lis a C1 to C10 alkylene group claim 1 , and Ris a hydroxy group.6. The electrode binder composition for a capacitive deionization device of claim 2 , wherein Rof Chemical Formula 3 is hydrogen or methyl claim 2 , Rand Rare hydrogen claim 2 , Lis a single bond or —(C═O)O— claim 2 , and Ris a methyl claim 2 , phenyl claim 2 , or cyano group.8. The electrode binder composition for a capacitive deionization device of claim 1 , further comprising:at least one second hydrophilic polymer selected from polystyrene, polyacrylic acid-co-maleic acid, polyvinyl alcohol, carboxylmethyl cellulose, hydroxypropyl cellulose, polyvinylchloride, carboxylated polyvinylchloride, polyvinylfluoride, polyvinyl amine, chitosan, polyamide, polyurethane, polyacrylamide, polyacrylamide-co-acrylic ...

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05-01-2017 дата публикации

PHOTOCURABLE RESIN COMPOSITION FOR FORMING SUPPORT REGIONS

Номер: US20170001382A1
Принадлежит:

A photocurable resin composition for support regions for use in photochemical fabrication by an inkjet method, which has low viscosity and outstanding photocurability, and where the support regions, formed by the photocuring, have good supporting performance and, following the end of the photochemical fabrication, can readily be removed from the main body by dissolving in water and/or by a weak external force such as a water jet. The photocurable resin composition for support regions for use in photochemical 3D fabrication by the inkjet method contains, based on the total mass of photocurable resin composition, from 2 to 20 mass % of N-hydroxyalkyl (meth) acrylamide, from 2 to 20 mass % of (meth) acryloyl morpholine, from 3 to 30 mass % of (meth) acrylate compound having at least one (meth) acryloyloxy group, from 40 to 90 mass % of polyhydroxy compound containing two or more hydroxyl groups, and from 0.1 to 5 mass % of a photo-radical polymerization initiator. 18-. (canceled)10. The photocurable resin composition for forming the support regions according to claim 9 , wherein a combined content of said N-hydroxyalkyl (meth)acrylamide (I) and said (meth)acryloyl morpholine (II) is from 5 to 40 mass % claim 9 , based on the total mass of the photocurable resin composition for forming said support regions.11. The photocurable resin composition for forming the support regions according to claim 9 , wherein said component (C) is a (meth)acrylate compound having a (meth)acryloyloxy group and an aliphatic polyether structure.12. The photocurable resin composition for forming the support regions according to claim 9 , wherein said component (D) is a non-curable polyhydroxy compound of molecular weight no more than 2000.13. The photocurable resin composition for forming the support regions according to claim 9 , wherein the total mass of the photocurable resin composition for forming said support resin comprises as part of said component (D) from 2 to 10 mass % of diglycerol ...

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02-01-2020 дата публикации

A TIRE COMPRISING A RUBBER COMPOSITION

Номер: US20200001650A1
Принадлежит:

A tire comprises a rubber composition based on at least an elastomer matrix comprising 20 to 70 phr of a first diene elastomer bearing at least one SiOR function, R being a hydrogen atom or a hydrocarbon radical, the SiOR function not located at the chain ends of the first diene elastomer, 20 to 70 phr of a second diene elastomer which is a polyisoprene, and optionally, 0 to 20 phr of a third diene elastomer; and a reinforcing filler comprising a reinforcing inorganic filler. 117.-. (canceled)18. A tire comprising a rubber composition based on at least:an elastomer matrix comprising 20 to 70 phr of a first diene elastomer bearing at least one SiOR function, R being a hydrogen atom or a hydrocarbon radical, the SiOR function not located at the chain ends of the first diene elastomer, 20 to 70 phr of a second diene elastomer which is a polyisoprene, and optionally, 0 to 20 phr of a third diene elastomer; anda reinforcing filler predominantly comprising a reinforcing inorganic filler.19. The tire according to claim 18 , wherein the first diene elastomer is a styrene-butadiene copolymer.20. The tire according to claim 18 , wherein the first diene elastomer further bears at least one amine function.21. The tire according to claim 20 , wherein the SiOR function bears the amine function.22. The tire according to claim 18 , wherein R of the SiOR function is a hydrocarbon radical.23. The tire according to claim 18 , wherein the first diene elastomer has a glass transition temperature of lower than −40° C.24. The tire according to claim 18 , wherein the elastomer matrix comprises 30 to 60 phr of the first diene elastomer.25. The tire according to claim 18 , wherein the elastomer matrix comprises 30 to 60 phr of the second diene elastomer.26. The tire according to claim 18 , wherein the second diene elastomer comprises more than 50% by weight of natural rubber per 100% by weight of the second diene elastomer.27. The tire according to claim 18 , wherein the elastomer matrix ...

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05-01-2017 дата публикации

PROCESS FOR PRODUCING ETHYLENE/UNSATURATED CARBOXYLIC ACID COPOLYMER, AND SAID COPOLYMER

Номер: US20170002120A1
Принадлежит:

Provided is a process of effectively producing an ethylene/unsaturated carboxylic acid copolymer having excellent mechanical and thermal properties. A process for producing an ethylene/unsaturated carboxylic acid copolymer comprises: producing an ethylene/unsaturated carboxylic acid ester copolymer from ethylene and unsaturated carboxylic acid ester using a late-transition-metal complex catalyst; and heating the ethylene/unsaturated carboxylic acid ester copolymer at a temperature capable of converting the ester group into a carboxylic acid group, thereby converting into the ethylene/unsaturated carboxylic acid copolymer. 1. A process for producing an ethylene/unsaturated carboxylic acid copolymer comprising a structural unit derived from ethylene and a structural unit derived from unsaturated carboxylic acid , which have been copolymerized randomly and linearly , wherein the process comprises: producing an ethylene/unsaturated carboxylic acid ester copolymer from ethylene and unsaturated carboxylic acid ester using a late-transition-metal complex catalyst; and heating the ethylene/unsaturated carboxylic acid ester copolymer at a temperature capable of converting the ester group into a carboxylic acid group , thereby converting into the ethylene/unsaturated carboxylic acid copolymer2. The process for producing an ethylene/unsaturated carboxylic acid copolymer according to claim 1 , wherein the unsaturated carboxylic acid ester is (meth)acrylic acid ester and the unsaturated carboxylic acid is (meth)acrylic acid.3. The process for producing an ethylene/unsaturated carboxylic acid copolymer according to claim 1 , wherein a temperature of the heating is 150-350° C.5. The process for producing an ethylene/unsaturated carboxylic acid copolymer according to claim 1 , wherein the late-transition-metal complex is a phosphine-phenolate complex or a phosphine-sulfonate complex.6. The process for producing an ethylene/unsaturated carboxylic acid copolymer according to claim 1 ...

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02-01-2020 дата публикации

ULTRA-HIGH DK MATERIAL

Номер: US20200002452A1
Автор: Bonafini, JR. James A.
Принадлежит: Acuity Polymers, Inc.

A method of producing an ultra-high Dk material includes contacting and reacting a fluoroalkyl methacrylate; an alkyl glycol dimethacrylate; a hydrophilic agent, such as methacrylic acid; a hydroxyalkyl tris(trimethylsiloxy)silane; a hydroxyalkyl terminated polydimethylsiloxane; and styrylethyltris(trimethylsiloxy)silane. The reaction is conducted within an inert atmosphere at a pressure of at least 25 pounds per square inch (PSI) and for a period of time and at a temperature sufficient to produce the ultra-high Dk material. 2. The method of wherein the fluoroalkly methacrylate is hexafluoroisopropyl methacrylate; the alkyl glycol dimethacrylate is neopentyl glycol dimethacrylate; the hydroxyalkyl tris(trimethylsiloxy)silane is 3-methacryloyloxypropyl tris(trimethylsiloxy)silane; the hydroxyalkyl terminated polydimethylsiloxane is 4-methacryloxybutyl terminated polydimethylsiloxane; the hydrophilic agent is methacrylic acid.3. The method of wherein the styrylethyltris(trimethylsiloxy)silane comprises 14% of the material claim 2 , by weight.4. The method of wherein the styrylethyltris(trimethylsiloxy)silane comprises between 7% and 20% of the material claim 1 , by weight.5. The method of wherein the styrylethyltris(trimethylsiloxy)silane comprises 14% of the material claim 4 , by weight.6. The method of wherein the material has a Dk value greater than 175.7. The method of wherein the reaction is conducted under a nitrogen claim 1 , argon or helium atmosphere.8. The method of wherein the reaction is conducted between 25 psi and 1 claim 1 ,000 psi.9. The method of wherein the reaction is conducted within a vessel wherein the ultra-high Dk material is formed in the shape of the vessel.10. The method of wherein vessel is selected whereby the high Dk material is formed as a lens claim 9 , blank or rod.11. The method of wherein the vessel is constructed of a vessel material that is permeable to the inert gas comprising the inert atmosphere.12. The method of wherein the ...

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02-01-2020 дата публикации

Modified Conjugated Diene-Based Polymer and Rubber Composition Including the Same

Номер: US20200002454A1
Принадлежит: LG CHEM, LTD.

A modified conjugated diene-based polymer, and more particularly, a modified conjugated diene-based polymer having a unimodal molecular weight distribution curve measured by gel permeation chromatography (GPC), molecular weight distribution (PDI; MWD) of less than 1.7, and a Si content of 100 ppm or more based on weight, and a rubber composition including the same. 1. A modified conjugated diene-based polymer having:a unimodal molecular weight distribution curve measured by gel permeation chromatography (GPC),a molecular weight distribution (PDI; MWD) of 1.0 or more and less than 1.7, anda Si content of 100 ppm or more based on a total weight of the modified conjugated diene-based polymer.2. The modified conjugated diene-based polymer of further comprising claim 1 , a repeating unit derived from a conjugated diene-based monomer and a functional group derived from a modifier.3. The modified conjugated diene-based polymer of claim 2 , wherein the modifier is an alkoxysilane-based modifier.4. The modified conjugated diene-based polymer of claim 1 , wherein the modified conjugated diene-based polymer has a number average molecular weight (Mn) of 1 claim 1 ,000 g/mol to 2 claim 1 ,000 claim 1 ,000 g/mol claim 1 , and a weight average molecular weight (Mw) of 1 claim 1 ,000 g/mol to 3 claim 1 ,000 claim 1 ,000 g/mol.5. (canceled)6. The modified conjugated diene-based polymer of claim 1 , wherein Mooney viscosity is 30 or more at 100° C.7. A modified conjugated diene-based polymer having:a unimodal molecular weight distribution of a polymer component having a molecular weight of 100,000 g/mol or more measured by gel permeation chromatography (GPC) with polystyrene as a standard for calculating molecular weight,a molecular weight distribution (PDI; MWD) of 2.0 or less,a number average molecular weight (Mn) of 250,000 g/mol to 700,000 g/mol,a vinyl content of a butadiene unit of 20 mol % to 80 mol %,a Si content of 100 ppm or more based on a total weight of the modified ...

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07-01-2021 дата публикации

Method of producing multicomponent copolymer

Номер: US20210002398A1
Автор: Olivier Tardif
Принадлежит: Bridgestone Corp

Provided is a method of producing a multicomponent copolymer, in which ethylene, a non-conjugated olefin compound having 3 to 10 carbon atoms, and a conjugated diene compound are copolymerized to produce a multicomponent copolymer. The method of producing a multicomponent copolymer is a method in which ethylene, a non-conjugated olefin compound having 3 to 10 carbon atoms, and a conjugated diene compound are copolymerized to produce a multicomponent copolymer, including a step of copolymerizing the ethylene, the non-conjugated olefin compound, and the conjugated diene compound, in the presence of a polymerization catalyst composition containing a rare earth element compound (component (A)) represented by predetermined formula.

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07-01-2021 дата публикации

NITROGEN-CONTAINING MULTI-BLOCK COPOLYMERS AND METHOD OF MAKING

Номер: US20210002407A1
Принадлежит:

Described herein are nitrogen-containing multi-block copolymers, as well as methods for making such multi-block copolymers, and articles comprising such multi-block copolymers. The nitrogen-containing multi-block copolymers contains at least one A block comprising polyisoprene; and at least one B block comprising amino-functionalized polybutadiene, the amino-functionalized polybutadiene comprising nitrogen-containing pendant groups. 1. A nitrogen-containing multi-block copolymer comprising:at least one A block comprising polyisoprene having isoprene repeat units and wherein no more than 1 mole percent of the isoprene repeat units are aminated; and {'br': None, 'sub': 2', '2', '2, 'sup': 1', '2, '*—CHCHCH—NRR\u2003\u2003(I-A)'}, 'at least one B block comprising amino-functionalized polybutadiene, the amino-functionalized polybutadiene comprising pendant groups of Formula (I-A)'} [{'sup': 1', '2, 'Ris hydrogen, alkyl, or aryl and Ris an alkyl or aryl; or'}, {'sup': 1', '2, 'Rand Rtogether with the nitrogen to which they are both attached form a heterocyclic ring having 0 to 2 additional heteroatoms selected from nitrogen or oxygen; and'}, 'an asterisk (*) denotes the point of attachment of the pendant groups to a carbon atom in the polymeric backbone., 'wherein'}3. The nitrogen-containing multi-block copolymer of claim 2 , wherein the mole ratio of the pendant groups of Formula (I-A) to the pendant groups of Formula (I-B) is at least 15.4. The nitrogen-containing multi-block copolymer of claim 1 , wherein the nitrogen-containing multi-block copolymer comprises 5 to 95 mole percent A block and 5 to 90 mole percent B block based on total moles of repeat units in the nitrogen-containing multi-block.5. The nitrogen-containing multi-block copolymer of claim 4 , wherein the nitrogen-containing multi-block copolymer further comprises 0 to 70 mole percent C block based on total moles of repeat units in the nitrogen-containing multi-block copolymer claim 4 , wherein the C ...

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02-01-2020 дата публикации

RESIN COMPOSITION, AND MOLDING MATERIAL AND MULTILAYER STRUCTURE COMPRISING SAME

Номер: US20200002502A1
Принадлежит: MITSUBISHI CHEMICAL CORPORATION

The present invention provides a resin composition having a high level of processability, which is a resin composition including a saponified ethylene-vinyl ester-based copolymer (A), a layered inorganic compound (B), and a carbonic acid salt (C) (provided that the carbonic acid salt (C) excludes the layered inorganic compound (B)). 1. A resin composition comprising: a saponified ethylene-vinyl ester-based copolymer (A) , a layered inorganic compound (B) , and a carbonic acid salt (C) , provided that the carbonic acid salt (C) excludes the layered inorganic compound (B).2. The resin composition according to claim 1 , wherein the content of the carbonic acid salt (C) is claim 1 , in terms of metal of the carbonic acid salt (C) claim 1 , from 10 to 1 claim 1 ,000 ppm relative to the total amount of the saponified ethylene-vinyl ester-based copolymer (A) and the layered inorganic compound (B).3. The resin composition according to claim 1 , wherein the weight ratio of the carbonic acid salt (C) to the layered inorganic compound (B) is from 0.001 to 0.3 claim 1 , with respect to (C)/(B).4. A molding material comprising the resin composition according to .5. A multilayer structure comprising a layer comprising the resin composition according to . The present invention relates to a resin composition containing a saponified ethylene-vinyl ester-based copolymer (hereinafter, sometimes simply referred to as EVOH). The present invention also relates to a molding material composed of the resin composition and a multilayer structure having the resin composition layer.In general, EVOH is known as a melt-moldable resin excellent in transparency, gas barrier property, aroma retentivity, solvent resistance, oil resistance, etc. and, by taking advantages of these properties, is utilized by molding it into, for example, a film or sheet for a food packaging material, a pharmaceutical product packaging material, an industrial chemical packaging material, an agrochemical packaging ...

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02-01-2020 дата публикации

INK, METHOD OF MANUFACTURING ACRYLIC RESIN PARTICLE, PRINTING METHOD, INK ACCOMMODATING UNIT, AND INKJET PRINTING DEVICE

Номер: US20200002558A1
Принадлежит:

An ink includes a coloring material, an acrylic resin particle, an organic solvent, and water, wherein a solid dry film of the ink has a breaking elongation ratio of 50 percent or more, a storage elastic modulus G′ of 1.0×10Pa or more at 50 degrees C., and a swelling ratio of 40 percent or less to ethylacetate. 1. An ink comprising:a coloring material;an acrylic resin particle;an organic solvent; andwater,{'sup': '6', 'wherein a solid dry film of the ink has a breaking elongation ratio of 50 percent or more, a storage elastic modulus G′ of 1.0×10Pa or more at 50 degrees C., and a swelling ratio of 40 percent or less to ethylacetate.'}3. The ink according to claim 2 ,wherein the acrylic resin particle comprises the first structure unit A in an amount of from 40 to 60 percent by mass, the second structure unit B in an amount of 20 to 30 percent by mass, and the third structure unit C in an amount of from 10 to 40 percent by mass, wherein a mass ratio of the first structure unit A to the second structure unit B is from 2 to 3.4. The ink according to claim 1 , wherein the organic solvent comprises 1 claim 1 ,2-hexane diol or 1 claim 1 ,2-propane diol.5. The ink according to claim 1 , wherein the organic solvent comprises 1 claim 1 ,2-hexane diol and one member selected from the group consisting of 1 claim 1 ,2-propane diol claim 1 , 1 claim 1 ,3-butane diol claim 1 , and 1 claim 1 ,3-propane diol.6. A method of manufacturing the acrylic resin particle in the ink of claim 2 , comprising:reacting styrene as a monomer A forming the first structure unit A, (meth)acrylate as a monomer B forming the second structure unit B, and 2-ethylhexyl acrylate as a monomer C forming the third structure unit C.7. A printing method comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'attaching the ink of to a recording medium; and'}drying the recording medium to which the ink has been attached at 100 degrees C. or higher.8. The printing method according to claim 1 , wherein the ...

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02-01-2020 дата публикации

Dry Erase Article

Номер: US20200002564A1
Принадлежит:

Dry erase articles are described comprising a writable surface layer comprising a cured hardcoat composition comprising the reaction product of certain low surface energy compound(s). In one embodiment, the compound(s) comprise a C18-C36 hydrocarbon group and an ethylenically unsaturated group. In another embodiment, a mixture of compounds is utilized, the mixture comprising first compounds comprising a C18-C36 hydrocarbon group and an ethylenically unsaturated group and second compounds comprising a C8-C17 hydrocarbon group and an ethylenically unsaturated group, wherein the first and second compound are present at a weight ratio of 3:2 to 4:1. 1. A dry erase article comprising:a writable surface layer comprising a cured hardcoat composition comprising at least 2.8 wt.-% and less than 9.5 wt.-% ofi) the reaction product of a compound comprising a C18-C36 hydrocarbon group and an ethylenically unsaturated group; orii) the reaction product of a mixture of compounds comprising first compounds comprising a C18-C36 hydrocarbon group and an ethylenically unsaturated group and second compounds comprising a C8-C17 hydrocarbon group and an ethylenically unsaturated group wherein the first and second compound are present at a weight ratio of 3:2 to 4:1.2. The dry erase article of wherein the compound of i) or the first compounds of ii) have the formula{'br': None, 'sup': 1', '2, 'R-L-R'}{'sup': '1', 'wherein Ris a C18-36 hydrocarbon group;'}L is a covalent bond, a divalent atom, or a hydrophobic divalent liking group;{'sup': '2', 'Ris an ethylenically unsaturated group.'}3. The dry erase article of wherein the C18-36 hydrocarbon group is a linear alkylene group.4. The dry erase article of wherein the ethylenically unsaturated group is a (meth)acrylate group or a vinyl group.5. The dry erase article of wherein the compound(s) comprising the C18-C36 hydrocarbon group are solid at 25° C.6. The dry erase board of wherein the hardcoat comprises the reaction product of one or more ...

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03-01-2019 дата публикации

Process for preparing polymer compositions

Номер: US20190002610A1
Принадлежит: Borealis AG

The present invention relates to an olefin polymerization process, wherein propylene and a C4 to C10 α-olefin monomer, preferably 1-butene- and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst so as to obtain a polypropylene, wherein the polypropylene comprises C4 to C10 α-olefin, preferably 1-butene-derived comonomer units in an amount of from 0,5 to 15 wt % and ethylene-derived comonomer units in an amount of 0 to 3 wt %, and wherein the Ziegler-Natta catalyst comprises i) an external donor of the formula (I): (R3)z(R2O)ySi(R1)x, and ii) a solid catalyst component being free of external carrier material.

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03-01-2019 дата публикации

Ultra-High Molecular Weight Ethylene-Based Copolymer Powder, and Molded Article Using Ultra-High Molecular Weight Ethylene-Based Copolymer Powder

Номер: US20190002611A1
Автор: Yoshiaki Hamada
Принадлежит: Asahi Kasei Corp

An ultra-high molecular weight ethylene-based copolymer powder comprising: an ethylene unit and an α-olefin unit having 3 or more and 8 or less carbon atoms as structural units, wherein the ultra-high molecular weight ethylene-based copolymer powder has a viscosity-average molecular weight of 100,000 or more and 10,000,000 or less, a content of the α-olefin unit is 0.01 mol % or more and 0.10 mol % or less based on a total amount of the ethylene unit and the α-olefin unit, and in measurement with a differential scanning calorimeter under following conditions,an isothermal crystallization time is determined as a time from reaching 126° C. of Step A3 as a starting point (0 min) to giving an exothermic peak top due to crystallization and the isothermal crystallization time is 5 minutes or more. (Conditions for measurement of isothermal crystallization time) Step A1: holding at 50° C. for 1 minute and then an increase up to 180° C. at a temperature rise rate of 10° C./min, Step A2: holding at 180° C. for 30 minutes and then a decrease down to 126° C. at a temperature drop rate of 80° C./min, and Step A3: holding at 126° C.

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03-01-2019 дата публикации

ETHYLENE-VINYL ALCOHOL COPOLYMER COMPOSITION PELLETS, AND MULTILAYER STRUCTURE

Номер: US20190002612A1

An ethylene-vinyl alcohol copolymer composition is provided, which contains an ethylene-vinyl alcohol copolymer and an iron compound, wherein the ethylene-vinyl alcohol copolymer has an ethylene content of 20 to 60 mol %, wherein the iron compound is present in a proportion of 0.01 to 100 ppm on a metal basis based on the weight of the ethylene-vinyl alcohol copolymer composition. 1. A pellet of an ethylene-vinyl alcohol copolymer composition comprising:an ethylene-vinyl alcohol copolymer; andan iron compound;wherein the ethylene-vinyl alcohol copolymer has an ethylene content of 20 to 60 mol %; andwherein the iron compound is present in a proportion of 0.01 to 100 ppm on a metal basis based on weight of the ethylene-vinyl alcohol copolymer composition.2. A multilayer structure comprising at least one layer comprising an ethylene-vinyl alcohol copolymer composition ,wherein the ethylene-vinyl alcohol copolymer composition comprises an ethylene-vinyl alcohol copolymer and an iron compound,where the ethylene-vinyl alcohol copolymer has an ethylene content of 20 to 60 mol %; and wherein the iron compound is present in a proportion of 0.01 to 100 ppm on a metal basis based on weight of the ethylene-vinyl alcohol copolymer composition. The present disclosure relates to an ethylene-vinyl alcohol copolymer composition containing an ethylene-vinyl alcohol copolymer (hereinafter sometimes referred to simply as “EVOH resin”) as a main component and to a multilayer structure produced by using the same. More specifically, the present disclosure relates to an EVOH resin composition having a UV absorbing ability and to a multilayer structure having at least one layer containing the EVOH resin composition.EVOH resin is excellent in transparency, gas barrier property (e.g., oxygen barrier property), perfume retaining property, solvent resistance, oil resistance, mechanical strength, and the like, and is widely used for various packaging materials such as a food packaging material, ...

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03-01-2019 дата публикации

HYDROPHOBICALLY MODIFIED ALKALI-SWELLABLE EMULSION POLYMERS

Номер: US20190002613A1
Принадлежит:

The present technology relates to hydrophobically modified alkali-swellable emulsion polymers that are useful as rheology modifiers. More specifically the present technology relates to hydrophobically modified alkali-swellable emulsion polymers containing residues of a polyunsaturated amphiphilic macromonomer. In one aspect the disclosed polymers are useful for thickening aqueous surfactant containing compositions, while providing the compositions in which they are included excellent rheology properties, clarity, and the ability to stably suspend insoluble and particulate materials over long periods of time. 2. An emulsion polymer of wherein said amphiphilic macromonomer (D) contains at least two polymerizable unsaturated groups.3. An emulsion polymer of wherein said amphiphilic macromonomer (D) contains at least two allyl groups.7. An emulsion polymer of wherein said salt forming cation M is selected from Na claim 6 , K claim 6 , and NH claim 6 , or an alkanolamine.8. An emulsion polymer of wherein said monomer composition further comprises at least one polyunsaturated crosslinking monomer.9. An emulsion polymer of wherein said crosslinking monomer (F) is an acrylate ester of a polyol having at least two acrylate ester groups claim 8 , a methacrylate ester of a polyol having at least two methacrylate ester groups claim 8 , and mixtures thereof.10. An emulsion polymer of wherein said acidic vinyl monomer (A) is selected from acrylic acid claim 1 , methacrylic acid claim 1 , styrenesulfonic acid claim 1 , 2-acrylamido-2-methylpropane sulfonic acid; and salts thereof; and mixtures thereof.11. An emulsion polymer of wherein said salt is selected from an alkali metal salt claim 10 , an alkaline earth metal salt claim 10 , an ammonium salt claim 10 , an alkyl-substituted ammonium salt claim 10 , and mixtures thereof.12. An emulsion polymer of wherein said nonionic vinyl monomer (B) is selected from a C-Calkyl ester of (meth)acrylic acid claim 1 , a hydroxy-substituted C- ...

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03-01-2019 дата публикации

METHOD FOR PREPARING CONCRETE SUPERPLASTICIZER HAVING PHOSPHOROUS ACID GROUP AND USE THEREOF

Номер: US20190002614A1
Принадлежит:

The present invention discloses a method for preparing a concrete superplasticizer having a phosphorous acid group and a use of the concrete superplasticizer. The concrete superplasticizer having a phosphorous acid group according to the present invention is prepared by free radical copolymerization of a phosphorous-containing monomer A and a polyether macromonomer B. The concrete superplasticizer having a phosphorous acid group obtained in the present invention can effectively improve flowability of concrete and can retain good workability of concrete. The method is simple, economical and effective, and in particular, can be used for commercial mass production. 2. The method of claim 1 , wherein the concrete superplasticizer having a phosphorous acid group has a weight average molecular weight (M) of 20000 to 80000.3. The method of claim 1 , wherein wherein the chlorinated alkene is allyl chloride and/or methyl allyl chloride; and', 'the amine compound is ammonia, ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentaamine, pentaethylenehexamine, hexaethyleneheptaamine, or polyethylenepolyamine., 'the monomer A is prepared by reacting a chlorinated alkene and an amine compound in an aqueous phase;'}5. The method of claim 1 , wherein the monomer B is an etheric unsaturated polyether macromonomer claim 1 , selected from vinyl polyethylene glycol ether claim 1 , allyl polyethylene glycol ether claim 1 , 3-buten-1-ol polyethylene glycol ether claim 1 , methyl allyl polyethylene glycol ether claim 1 , and 3-methyl-3-buten-1-ol polyethylene glycol ether claim 1 , and a mixture thereof in any ratio.6. The method of claim 1 , specifically comprising the steps of:adding the monomer B and an oxidizing agent into a reaction container before beginning of the free radical copolymerization reaction,dropwise adding an aqueous solution of the monomer A, a chain transfer agent and a reducing agent to the reaction container after the beginning of the free ...

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02-01-2020 дата публикации

Adhesive composition, adhesive agent, adhesive tape, and airtight waterproof adhesive tape

Номер: US20200002579A1
Принадлежит: Mitsubishi Chemical Corp

An adhesive composition contains an acrylic resin (A) obtained by copolymerizing a copolymerization formulation (a), the copolymerization formulation (a) including predetermined proportions of: (a1) at least one selected from the group consisting of a (meth)acrylate having a C1 to C3 alkyl group, t-butyl (meth)acrylate, a cyclic structure-containing monomer, and a C3 to C10 vinyl ester monomer; (a2) a (meth)acrylate having a C4 to C24 alkyl group (excluding t-butyl (meth)acrylate); (a3) a terminal carboxyl-containing monomer having a specific structure; and (a4) (meth)acrylic acid. The adhesive composition provides firm adhesion to a higher-polarity adherend, a lower-polarity adherend, a poor-adhesion adherend such as of ethylene propylene diene rubber (EPDM), and a rough surface, and is excellent in holding force and adhesiveness in a high-temperature/high-humidity environment, with reduced susceptibility to deterioration in adhesiveness over time.

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07-01-2021 дата публикации

METHOD OF PREPARING GRAFT COPOLYMER, GRAFT COPOLYMER, AND THERMOPLASTIC RESIN MOLDED ARTICLE INCLUDING GRAFT COPOLYMER

Номер: US20210002472A1
Принадлежит: LG CHEM, LTD.

Provided are a method of preparing a graft copolymer, a graft copolymer, and a thermoplastic resin molded article including the graft copolymer, the method including: 1) preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer and performing polymerization; 2) in the presence of the seed, preparing a core by adding an alkyl (meth)acrylate-based monomer and performing polymerization; and 3) in the presence of the core, preparing a shell by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and performing polymerization, wherein the method further includes adding an alkyl acrylate-based polymer. When the alkyl acrylate-based polymer is included in a graft copolymer, a graft copolymer and a thermoplastic resin molded article excellent in weather resistance, fluidity, mechanical properties, and appearance quality can be provided. 1. A method of preparing a graft copolymer , comprising:1) preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer and performing polymerization;2) in the presence of the seed, preparing a core by adding an alkyl (meth)acrylate-based monomer and performing polymerization; and3) in the presence of the core, preparing a shell by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and performing polymerization,wherein the method further includes adding an alkyl acrylate-based polymer.2. The method of claim 1 , wherein the alkyl acrylate-based polymer has a weight-average molecular weight of 1 claim 1 ,000 to 2 claim 1 ,500 g/mol.3. The method of claim 1 , wherein the alkyl acrylate-based polymer has a viscosity of 20 to 1 claim 1 ,000 cps claim 1 , as measured at 25° C.4. The method of claim 1 , wherein the alkyl acrylate-based polymer is added in one or more steps of ...

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03-01-2019 дата публикации

ELASTOMER MATERIAL FOR MEDICAL DEVICES AND ELASTOMER MOLDED BODY FOR MEDICAL DEVICES

Номер: US20190002682A1
Автор: TOMIZUKA Kazuhito
Принадлежит: OLYMPUS CORPORATION

This elastomer material for medical devices contains: a first fluorine-based elastomer that is a ternary copolymer comprising three kinds of monomers A, B and C; and a second fluorine-based elastomer that is a ternary copolymer comprising the monomers A and B and a monomer D which is different from any one of the monomers A, B and C. The monomer C and the monomer D have side chains that have structures different from each other. 1. An elastomer material for medical devices comprising:a first fluorine-based elastomer which is a ternary copolymer having three kinds of monomers A, B and C; anda second fluorine-based elastomer which is a ternary copolymer having the monomers A and B and a monomer D different from any one of the monomers A, B and C,wherein the monomer A is vinylidene fluoride, the monomer B is tetrafluoroethylene, the monomer C is hexafluoropropylene, and the monomer D is perfluoroalkyl vinyl ether.2. The elastomer material for medical devices according to claim 1 , wherein claim 1 ,when total content of the first fluorine-based elastomer and the second fluorine-based elastomer is 100 parts by weight, a crosslinking aid is contained in an amount of not more than 15 parts by weight and not zero.3. The elastomer material for medical devices according to claim 1 , wherein claim 1 ,when total content of the first fluorine-based elastomer and the second fluorine-based elastomer is 100 parts by weight, a filler is contained in an amount of not more than 50 parts by weight and not zero.4. The elastomer material for medical devices according to claim 1 , wherein claim 1 ,when total content of the first fluorine-based elastomer and the second fluorine-based elastomer is 100 parts by weight, a third fluorine-based elastomer whose number average molecular weight is 5000 or less and having no crosslinking reactive group is contained in an amount of not more than 50 parts by weight and not zero.5. An elastomer molded body for medical devices comprising:a first ...

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03-01-2019 дата публикации

POLYAMIDE NANOPARTICLES AND USES THEREOF

Номер: US20190002706A1
Принадлежит:

Nanoparticles of N-halamine-derivatized crosslinked polyamide. Process of preparing the polymeric nanoparticles per se and incorporated in or on a substrate. Uses of the polymeric nanoparticles and of substrates incorporating same, particularly for reducing a formation of organic-based contaminants, e.g., load of a microorganism or of a biofilm. 2. The article of claim 1 , being selected from the group consisting of a medical device claim 1 , organic waste processing device claim 1 , fluidic device claim 1 , water system device claim 1 , tubing claim 1 , an agricultural device claim 1 , a package claim 1 , a sealing article claim 1 , a fuel container and a construction element.3. The article of claim 1 , wherein said halogen atom claim 1 , in one or more instances claim 1 , is bound to the nitrogen belonging to said Aand/or to said A.5. The method of claim 4 , wherein said load of organic-based contaminant is selected from a load of a microorganism claim 4 , or biofilm claim 4 , said microorganism being selected from the group consisting of: viruses claim 4 , fungi claim 4 , parasites claim 4 , yeast claim 4 , bacteria claim 4 , and protozoa.6. The method of claim 5 , wherein the bacterium is selected from the group consisting of: Gram positive bacteria claim 5 , and Gram negative bacteria.7. The method of claim 6 , wherein the bacterium is selected from the group consisting of Gram negative bacteria.8. The method of claim 4 , wherein said load of organic-based contaminant is maintained substantially reduced over a period of up to at least six months.9. The method of claim 4 , further comprising one or more dehalogenating-rehalogenating cycles with halogen atoms selected from the group consisting of Cl claim 4 , Br claim 4 , and I.10. The method of claim 9 , wherein said load of organic-based contaminant is maintained substantially reduced after at least one dehalogenating-rehalogenating cycle with said halogen atom.11. The method of claim 4 , wherein said Ais ...

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05-01-2017 дата публикации

COMPOUND CONTAINING MESOGENIC GROUP, AND MIXTURE, COMPOSITION, AND OPTICALLY ANISOTROPIC BODY USING SAID COMPOUND

Номер: US20170003418A1
Принадлежит: DIC CORPORATION

There is provided a compound containing a mesogenic group, which includes a silicon compound at a low concentration, a polymerizable compound containing the mesogenic group, a mixture and a composition using these compounds, a polymerizable mixture having the polymerizable compound, and a polymer, an optically anisotropic body, and a phase difference film using the polymerizable composition. It is possible to obtain the optically anisotropic body and the phase difference film having satisfactory scratch resistance and adhesion, by using the polymerizable composition composed of the compound containing a mesogenic group, which includes a silicon compound at a low concentration. 1. A compound containing a mesogenic group , which includes a silicon compound at a low concentration.2. The compound according to claim 1 ,wherein, with respect to a mixture only including two or more types of the compounds containing a mesogenic group, the content of the silicon compound is 1 ppm % by weight to 1,000 ppm % by weight with respect to the total amount of the mixture.3. A mixture comprising the compound according to .4. The mixture according to claim 3 , which has polymerization performance.5. A composition in which the mixture according to is dissolved in an organic solvent.6. A polymer obtained by polymerizing the mixture having polymerization performance according to .7. An optically anisotropic body obtained by polymerizing the mixture having polymerization performance according to .8. A phase difference film obtained by polymerizing the mixture having polymerization performance according to .9. A polymerizable composition having polymerization performance in which the mixture according to is dissolved in an organic solvent. The present invention relates to a compound containing a mesogenic group, which includes a silicon compound at a low concentration, a polymerizable compound containing the mesogenic group, a mixture and a composition using these compounds, a ...

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13-01-2022 дата публикации

RHEOLOGY MODIFICATION BY POROUS GEL PARTICLES

Номер: US20220010086A1
Принадлежит: Rhodia Operations

Modification of the rheology of a liquid medium, aqueous or nonaqueous, with polymers in the form of specific particles obtained by grinding (micronizing) a porous macrogel, itself prepared by a process comprising a radical polymerization step which comprises reacting in the presence of pore formers monomers containing monomers bearing at least two ethylenic unsaturations, typically in combination with monomers bearing a single ethylenic unsaturation; a polymerization initiator; and optionally a polymerization control agent. These polymer particles keep other particles in suspension within the liquid medium, and also the stabilized suspensions are obtained. 1. A method comprising adding crosslinked polymer particles (p) to a liquid medium , the crosslinked polymer particles (p) obtained by grinding a macrogel prepared by a process comprising a radical polymerization step (E) which comprises reacting , within a reaction medium M comprising pore formers: at least one radical polymerization initiator;', 'optionally at least one radical polymerization control agent, 'ethylenically unsaturated monomers, containing monomers m1 bearing at least two ethylenic unsaturations;'}to modify the rheology of said liquid medium.2. The method as claimed in claim 1 , wherein the monomers employed in step (E) comprise not only monomers m1 but also monomers m2 bearing a single ethylenic unsaturation claim 1 , preferably with a mass ratio m1/m2 of between 0.01 and 30.3. The method as claimed in claim 1 , wherein the liquid medium is an aqueous liquid medium.4. The method as claimed in claim 1 , wherein particles are kept in suspension within the liquid medium.5. The method as claimed in claim 1 , wherein the pore formers employed in step (E) are gas bubbles.6. The method as claimed in claim 1 , wherein step (E) first comprises a step (E1) in which only a part of the ethylenically unsaturated monomers are polymerized in the absence of pore formers claim 1 , then a step (E2) in which the ...

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05-01-2017 дата публикации

SEMICONDUCTOR ELEMENT AND INSULATING LAYER-FORMING COMPOSITION

Номер: US20170005266A1
Принадлежит: FUJIFILM Corporation

Provided is a semiconductor element having a semiconductor layer and an insulating layer adjacent to the semiconductor layer, in which the insulating layer is formed of a crosslinked product of a polymer compound having a repeating unit (IA) represented by the following General Formula (IA) and a repeating unit (IB) represented by the following General Formula (IB). 2. The semiconductor element according to claim 1 , wherein Lis represented by the following Formula (1a) claim 1 ,{'br': None, 'sup': 1a', '3a, '*-Ar-L** \u2003\u2003Formula (1a)'}{'sup': 3a', '1a', '1a', '2a, 'in Formula (1a), Lrepresents a single bond or a linking group, Arrepresents an aromatic ring, * indicates the bonding position of the carbon atom to which Rin the repeating unit (IA) is bonded, and ** indicates the bonding position of Lin the repeating unit (IA).'}3. The semiconductor element according to claim 2 , wherein Aris a benzene ring.6. The semiconductor element according to claim 1 , wherein the crosslinkable group X is an epoxy group claim 1 , an oxetanyl group claim 1 , a hydroxymethyl group claim 1 , an alkoxymethyl group claim 1 , a (meth)acryloyloxy group claim 1 , a styryl group claim 1 , or a vinyl group.7. The semiconductor element according to claim 1 , wherein the crosslinkable group X is a hydroxymethyl group or an alkoxymethyl group.8. The semiconductor element according to claim 1 , wherein the crosslinked product is a crosslinked product by a crosslinking reaction between the crosslinkable group X of the repeating unit (IA) and the repeating unit (IB).9. The semiconductor element according to claim 8 , wherein the crosslinked product has a crosslinked portion where a hydroxymethyl group or an alkoxymethyl group as a crosslinkable group is formed by a reaction.10. The semiconductor element according to claim 1 , wherein the semiconductor layer contains an organic semiconductor. This application is a Continuation of PCT International Application No. PCT/JP2015/058775 filed ...

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02-01-2020 дата публикации

ELECTRIC CABLE HAVING IMPROVED THERMAL CONDUCTIVITY

Номер: US20200005961A1
Принадлежит:

The invention relates to a cable comprising at least one electrically insulating layer obtained from a polymer composition comprising at least one polypropylene-based thermoplastic polymer material and at least one inorganic filler chosen from silicates, boron nitride, carbonates, and a mixture thereof, and to a process for preparing said cable. 1. Electric cable comprising:at least one elongated electrically conducting element; andat least one electrically insulating layer obtained from a polymer composition comprising at least one polypropylene-based thermoplastic polymer material and at least one inorganic filler,wherein the inorganic filler is chosen from silicates, boron nitride, carbonates, and a mixture thereof.2. Cable according to claim 1 , wherein the silicates are aluminum silicates chosen from kaolins and any other mineral or clay comprising predominantly kaolinite.3. Cable according to claim 1 , wherein the carbonates are chosen from chalk claim 1 , calcium carbonate claim 1 , magnesium carbonate claim 1 , limestone and any other material comprising predominantly calcium carbonate or magnesium carbonate.4. Cable according to claim 1 , wherein the inorganic filler represents from 2% to 40% by weight claim 1 , relative to the total weight of the polymer composition.5. Cable according to claim 1 , wherein the inorganic filler is chosen from kaolins claim 1 , chalk claim 1 , and a mixture thereof.6. Cable according to claim 1 , wherein the polypropylene-based thermoplastic polymer material comprises a Ppropylene homopolymer or copolymer.7. Cable according to claim 6 , wherein the Ppropylene copolymer is a random propylene copolymer or a heterophasic propylene copolymer.8. Cable according to claim 7 , wherein the heterophasic copolymer comprises a thermoplastic phase of propylene type and a thermoplastic elastomer phase of the type copolymer of ethylene and of an αolefin.9. Cable according to claim 6 , wherein the polypropylene-based thermoplastic polymer ...

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20-01-2022 дата публикации

PROCESS FOR PRODUCING CHLORINATED BUTYL RUBBER

Номер: US20220017651A1
Принадлежит:

The invention relates to an energy efficient, fast and environmentally favourable process for the preparation of chlorinated butyl rubbers, that uses hypochlorous acid (HOCl) and/or dichlorine monoxide (ClO) as halogenating agent. The process comprises reacting a copolymer with hypochlorous acid and/or dichlorine oxide. The copolymer comprises units derived from an isoolefin monomer and units derived from a multiolefin monomer. A preferred isoolefin is isobutene and a preferred multiolefin is isoprene. 1. A process for the preparation of a chlorinated copolymer comprising at least the step of reacting a copolymer comprisingi) structural units derived from at least one isoolefin monomer andii) structural units derived from at least one multiolefin monomerwith hypochloric acid and or dichlorine oxide.2. The process according to claim 1 , wherein the isoolefin monomer is selected from those having from 4 to 16 carbon atoms.3. The process according to or claim 1 , wherein the isoolefin monomer is isobutene.4. The process according to claim 1 , wherein the multiolefin is selected from the group consisting of isoprene claim 1 , butadiene claim 1 , 2-methylbutadiene claim 1 , 2 claim 1 ,4-dimethylbutadiene claim 1 , piperyline claim 1 , 3-methyl-1 claim 1 ,3-pentadiene claim 1 , 2 claim 1 ,4-hexadiene claim 1 , 2-neopentylbutadiene claim 1 , 2-methyl-1 claim 1 ,5-hexadiene claim 1 , 2 claim 1 ,5-dimethyl-2 claim 1 ,4-hexadiene claim 1 , 2-methyl-1 claim 1 ,4-pentadiene claim 1 , 4-butyl-1 claim 1 ,3-pentadiene claim 1 , 2 claim 1 ,3-dimethyl-1 claim 1 ,3-pentadiene claim 1 , 2 claim 1 ,3-dibutyl-1 claim 1 ,3-pentadiene claim 1 , 2-ethyl-1 claim 1 ,3-pentadiene claim 1 , 2-ethyl-1 claim 1 ,3-butadiene claim 1 , 2-methyl-1 claim 1 ,6-heptadiene claim 1 , cyclopentadiene claim 1 , methylcyclopentadiene claim 1 , cyclohexadiene and 1-vinyl-cyclohexadiene.5. The process according to claim 1 , wherein the multiolefin is isoprene.6. The process according to claim 1 , wherein the ...

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03-01-2019 дата публикации

Binder composition for non-aqueous secondary battery electrode, slurry composition for non-aqueous secondary battery electrode, non-aqueous secondary battery electrode, and non-aqueous secondary battery

Номер: US20190006677A1
Принадлежит: Zeon Corp

Disclosed is a binder composition for non-aqueous secondary battery electrode which comprises: a water-soluble polymer which comprises an acid group-containing monomer unit; and water, wherein the water-soluble polymer comprises the acid group-containing monomer unit in an amount of 5% to 70% by mass, and wherein the water-soluble polymer comprises water-soluble polymer particles having a radius of gyration of 200 nm or less in an amount of 95% to 100% by mass.

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20-01-2022 дата публикации

RESIN COMPOSITION, OPTICAL FIBER AND METHOD FOR PRODUCING OPTICAL FIBER

Номер: US20220017768A1
Принадлежит: Sumitomo Electric Industries, Ltd.

A resin composition for coating an optical fiber comprises: a base resin containing a photopolymerizable compound and a photopolymerization initiator; and hydrophobic inorganic oxide particles, wherein the photopolymerizable compound comprises urethane (meth)acrylate and aliphatic epoxy (meth)acrylate, and the content of the aliphatic epoxy (meth)acrylate is 1.0% by mass or more and 45% by mass or less based on the total amount of the photopolymerizable compound. 1: A resin composition for coating an optical fiber , comprising:a base resin comprising a photopolymerizable compound and a photopolymerization initiator; andhydrophobic inorganic oxide particles,wherein the photopolymerizable compound comprises urethane (meth)acrylate and aliphatic epoxy (meth)acrylate, and a content of the aliphatic epoxy (meth)acrylate is 1.0% by mass or more and 45% by mass or less based on a total amount of the photopolymerizable compound.2: The resin composition according to claim 1 , wherein the aliphatic epoxy (meth)acrylate has an ethylene oxide group or a propylene oxide group.3: The resin composition according to claim 1 , wherein the photopolymerizable compound further comprises an epoxy (meth)acrylate having an aromatic ring.4: The resin composition according to claim 1 , wherein the inorganic oxide particles are particles comprising at least one selected from the group consisting of silicon dioxide claim 1 , zirconium dioxide claim 1 , aluminum oxide claim 1 , magnesium oxide claim 1 , titanium oxide claim 1 , tin oxide claim 1 , and zinc oxide.5: An optical fiber comprising:a glass fiber comprising a core and a cladding;a primary resin layer being in contact with the glass fiber and coating the glass fiber; anda secondary resin layer coating the primary resin layer,{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'wherein the secondary resin layer comprises a cured product of the resin composition according to .'}6: A method for manufacturing an optical fiber claim 1 , ...

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12-01-2017 дата публикации

Binder for formation of ceramic or for use in conductive paste, and use of same

Номер: US20170008988A1
Принадлежит: Kuraray Co Ltd

There is provided a binder for ceramic formation or a conductive paste, comprising polyvinyl acetal having a degree of acetalization of from 50 to 85 mol %, a content of vinyl ester monomer unit of from 0.1 to 20 mol %, and having a viscosity-average degree of polymerization of from 200 to 5000, wherein a peak-top molecular weight (A) as measured by a differential refractive index detector and a peak-top molecular weight (B) as measured by an absorptiometer (measurement wavelength: 280 nm) in gel permeation chromatographic measurement of the polyvinyl acetal heated at 230° C. for 3 hours satisfy a formula (1) (A−B)/A<0.60 and the polyvinyl acetal has an absorbance in the peak-top molecular weight (B) of from 0.50×10 −3 to 1.00×10 −2 .

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12-01-2017 дата публикации

SUPER ABSORBENT POLYMER AND METHOD FOR PREPARING THE SAME

Номер: US20170009026A1
Принадлежит: LG CHEM, LTD.

The present invention relates to a super absorbent polymer and a method for preparing the same. The present invention has features that it is possible to prepare a super absorbent resin that can have an improved centrifuge retention capacity (CRC) and a high absorbency under load (AUL) by controlling the shape and size of the chopper die holes during coarse pulverization of a hydrous gel phase polymer. 1. A super absorbent polymer comprising a crosslinked polymer , the crosslinked polymer being obtained by surface-crosslinking a base polymer prepared by polymerizing a water-soluble ethylene-based unsaturated monomer including an acidic group in which at least a part of the acidic group is neutralized , wherein the super absorbent polymer hasa centrifuge retention capacity (CRC) of more than 20 g/g,an absorbency under 0.9 psi load (AUL) of more than 18 g/g, and {'br': None, 'ARUL=0.3AUL(5 min)/0.3AUL(60 min)\u2003\u2003[Equation 1]'}, 'ARUL shown in the following Equation 1 of 60% to 85%in Equation 1, {'br': None, 'i': Wb', 'Wa, '0.3AUL(g/g)=[(g)−(g)]/weight(g) of the absorbent polymer\u2003\u2003[Equation 2]'}, '0.3AUL (5 min) and 0.3AUL (60 min) are the values of absorbency under load (AUL) at 5 minutes and 60 minutes shown in the following Equation 2, respectively,'}in Equation 2,Wa(g) is the sum of the weight of the absorbent polymer and the weight of the device capable of providing a load for the absorbent polymer, andWb(g) is the sum of the weight of the absorbent polymer in which moisture is absorbed after supplying water for the absorbent polymer under a load (0.3 psi) for 5 minutes or 60 minutes, and the weight of the device capable of providing a load for the absorbent polymer.2. The super absorbent polymer according to wherein {'br': None, 'sub': '1', 'sup': '1', 'R-COOM\u2003\u2003[Chemical Formula 1]'}, 'the water-soluble ethylene-based unsaturated monomer is a compound represented by the following Chemical Formula 1in Chemical Formula 1,{'sub': 1', '1', ...

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12-01-2017 дата публикации

POLYAMIDE NANOPARTICLES AND USES THEREOF

Номер: US20170009084A1
Принадлежит:

Nanoparticles of N-halamine-derivatized crosslinked polyamide. Process of preparing the polymeric nanoparticles per se and incorporated in or on a substrate. Uses of the polymeric nanoparticles and of substrates incorporating same, particularly for reducing a formation of organic based contaminants, e.g., load of a microorganism or of a biofilm. 134.-. (canceled)36. The composition-of-matter of claim 35 , wherein said Ais methacrylamide.37. The composition-of-matter of wherein said Ais selected from the group consisting of: N claim 35 ,N′-methylene bisacrylamide claim 35 , N claim 35 ,N′-ethylene bisacrylamide claim 35 , and any derivative thereof.38. The composition-of-matter of claim 37 , wherein said Ais N claim 37 ,N′-methylene bisacrylamide.39. The composition-of-matter of claim 35 , wherein said n has a value such that n/(x+y) multiplied by 100 is at least 0.1.40. The composition-of-matter of claim 35 , being in the form of a dry powder.41. The composition-of-matter of claim 35 , wherein said plurality of crosslinked polymeric backbones is characterized by an average hydrodynamic diameter of less than 50 nm with a size distribution of that varies within a range of less than 20%.42. The composition-of-matter of claim 35 , further comprising a substrate claim 35 , wherein said plurality of crosslinked polymeric backbones is incorporated or coated in/on at least a portion of said substrate.43. The composition-of-matter of claim 42 , wherein said substrate is or forms a part of an article.44. The composition-of-matter of claim 42 , wherein said substrate comprises or is made of a polymer claim 42 , wood claim 42 , a metal claim 42 , glass claim 42 , carbon claim 42 , a biopolymer and/or silicon.45. An article comprising the composition-of-matter of .46. The article of claim 45 , being selected from the group consisting of a medical device claim 45 , organic waste processing device claim 45 , fluidic device claim 45 , water system device claim 45 , tubing claim 45 ...

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09-01-2020 дата публикации

Polymer Comprising Certain Level Of Bio-Based Carbon

Номер: US20200009041A1
Принадлежит: CLARIANT INTERNATIONAL LTD

The present invention relates to a polymer comprising: (a) from 9.49 mol-% to 98 mol-% repeating units according to Formula (1) wherein at least 10 wt.-% of the repeating units according to Formula (1) comprise from 28 wt.-% to 100 wt.-% bio-based carbon content, relative to the total mass of carbon in the repeating unit according to Formula (1), measured according to standard ASTM D6866-12, Method B; (b) from 0.01 mol-% to 5 mol-% crosslinking or branching units; (c) from 0.01 mol-% to 88.52 mol-% of repeating neutral structural units; (d) from 1.98 mol-% to 20 mol-% of repeating anionic structural units, wherein the repeating anionic structural units result from the incorporation of a monomer comprising at least one carboxylate anion, and wherein the repeating anionic structural units are different from units (a).

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27-01-2022 дата публикации

CYCLIC POLYOLEFINS DERIVED FROM HEXYNE, OCTYNE, NONYNE, PENTADECYNE AND THEIR COPOLYMERS WITH ACETYLENE

Номер: US20220025082A1
Автор: Veige Adam S.
Принадлежит:

Disclosed are saturated cyclic monopolymers derived from hexyne, octyne, nonyne, pentadecyne and saturated cyclic copolymers derived from acetylene and a second alkyne monomer that is hexyne, octyne, nonyne, or pentadecyne. 121.-. (canceled)23. The composition of claim 22 , wherein each R is n-butyl.24. The composition of claim 22 , wherein each R is n-hexyl.25. The composition of claim 22 , wherein each R is n-heptyl.26. The composition of claim 22 , wherein each R is n-tetradecyl.28. The composition of claim 27 , wherein each R is n-butyl.29. The composition of claim 27 , wherein each R is n-hexyl.30. The composition of claim 27 , wherein each R is n-heptyl.31. The composition of claim 27 , wherein each R is n-tetradecyl.33. The composition of claim 32 , where each R is n-butyl.34. The composition of claim 32 , where each R is n-tetradecyl. This application makes reference to the following patent applications and patents: International Patent Application No. PCT/US2015/034888, entitled “Metallacycloalkylene Complexes and Use for Alkyne Polymerization to Cyclic Polyacetylenes,” filed Jun. 9, 2015; which is a continuation-in-part of U.S. patent application Ser. No. 14/299,449, entitled “Tridentate Pincer Ligand Supported Metal-Alkylidyne and Metallacycloalkylene Complexes for Alkyne Polymerization,” filed Jun. 9, 2014, now U.S. Pat. No. 9,206,266, issued Dec. 8, 2015, which claims priority from U.S. Provisional Patent Application No. 61/845,764, filed Jul. 12, 2013, and is a continuation-in-part of PCT/US2012/065841, filed Nov. 19, 2012, which claims priority from U.S. Provisional Patent Application No. 61/567,909, filed Dec. 7, 2011.U.S. patent application Ser. No. 15/286,780, entitled “ONO Pincer Ligands and ONO Pincer Ligand Comprising Metal Complexes,” filed Oct. 6, 2016, which is a division of U.S. patent application Ser. No. 14/077,822, filed Nov. 12, 2013, now U.S. Pat. No. 9,464,104, issued Oct. 11, 2016, which is a continuation in part of PCT/US2012/037302, ...

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27-01-2022 дата публикации

CURABLE FLUOROPOLYMER COMPOSITIONS COMPRISING BIS PHTHALONITRILE-CONTAINING COMPOUND AND CURED ARTICLES THEREFROM

Номер: US20220025154A1
Принадлежит:

Described herein are fluoropolymer compositions comprising a bis phthalonitrile-containing compound. In one embodiment, the bis phthalonitrile-containing compound is used to crosslink a dehydrohalogenated polymer, and optionally with a polyhydroxy curative. In another embodiment, the bis phthalonitrile-containing compound is added to a composition comprising (i) a fluorinated elastomeric gum, wherein the fluorinated elastomeric gum comprises a fluoropolymer having a cure-site and (ii) a peroxide curing system. 2. The curable composition of claim 1 , wherein the curable composition further comprises a polyhydroxy curative.3. The curable composition of claim 2 , wherein the polyhydroxy curative is selected from at least one of 4 claim 2 ,4′-hexafluoroisopropylidenyl bisphenol claim 2 , 4 claim 2 ,4′-dihydroxydiphenyl sulfone claim 2 , 4 claim 2 ,4′-isopropylidenyl bisphenol claim 2 , 4 claim 2 ,4′(perfluoropropane-2 claim 2 ,2-diyl)diphenol claim 2 , dihydroxybenzophenone claim 2 , hydroquinone claim 2 , 2 claim 2 ,4 claim 2 ,6-trimercapto-S-triazine claim 2 , 4 claim 2 ,4′-thiodiphenol claim 2 , and a metal salt thereof.4. The curable composition of claim 1 , wherein the partially fluorinated polymer comprises (i) vinylidene fluoride claim 1 , tetrafluoroethylene claim 1 , and propylene; (iii) vinylidene fluoride with hexafluoropropylene; (iv) hexafluoropropylene claim 1 , tetrafluoroethylene claim 1 , and vinylidene fluoride; (v) hexafluoropropylene and vinylidene fluoride claim 1 , (ix) tetrafluoroethylene claim 1 , propylene claim 1 , and 3 claim 1 ,3 claim 1 ,3-trifluoropropene claim 1 , (x) tetrafluoroethylene claim 1 , and propylene; and (xvi) combinations thereof.5. The curable composition of claim 4 , wherein the fluorinated comonomer having an acidic hydrogen atom is selected from: trifluoroethylene; vinyl fluoride; 3 claim 4 ,3 claim 4 ,3-trifluoropropene-1; pentafluoropropene; and 2 claim 4 ,3 claim 4 ,3 claim 4 ,3-tetrafluoropropene.6. The curable ...

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11-01-2018 дата публикации

HIGH DIELECTRIC BREAKDOWN STRENGTH RESINS

Номер: US20180009934A1
Автор: LOMBARDI JOHN L.
Принадлежит:

A method to prepare an oligomer which includes a plurality of pendent alkenyl groups, where the method reacts a copolymer formed by copolymerizing styrene and allyl alcohol comprising a polyhydroxy oligomer wherein n is between about 3 and about 50, and having a structure: 2. The method of claim 1 , wherein said isocyanate comprises isocyanatomethylmethacrylate.3. The method of claim 1 , wherein said isocyanate comprises isocyanatoethylmethacrylate.3. The method of claim 1 , wherein said isocyanate comprises dimethyl meta-isopropenyl benzyl isocyanate (5).4. A formulation claim 1 , comprising:MONOMER (1) at about 31 weight percent;MONOMER (2) at about 26 weight percent;polystyrene-co-allyl alcohol (3) at about 25 weight percent about; anddimethyl meta-isopropenyl benzyl isocyanate (5) at about 18 weight percent.5. A formulation claim 1 , comprising:MONOMER (1) at about 21 weight percent;MONOMER (2) at about 18 weight percent;OLIGOMER (3) at about 17 weight percent;ISOCYANATE (5) at about 12 weight percent;MALEIMIDE (8), wherein R3=PHENYL at about 13 weight percent;MALEIMIDE (8) wherein R3=HYDROGEN at about 6 weight percent; andTris (2-hydroxyethyl) isocyanurate triacrylate (9) at about 12 weight percent.6. A resin formed by thermal cure of the formulation of .7. A resin formed by photocure of the formulation of .9. A resin formed by polymerization of the formulation of claim 8 , wherein:said resin comprises a dielectric constant of 2.7; andsaid resin further comprises a 10 GHz loss tangent of 0.00238.12. A formulation claim 8 , comprising:{'claim-ref': {'@idref': 'CLM-00011', 'claim 11'}, 'the polycarbonate diol comprising alkenyl end groups of at about 31 weight percent;'}MONOMER (1) at about 28 weight percent;MONOMER (2) at about 19 weight percent;MALEIMIDE (8), wherein R3=PHENYL at about 11 weight percent;MALEIMIDE (8) wherein R3=HYDROGEN at about 11 weight percent.13. A resin formed by polymerization of the formulation of claim 12 , wherein:said resin comprises ...

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11-01-2018 дата публикации

ANTI-BACTERIAL METALLO IONOMER POLYMER NANOCOMPOSITE POWDERS AND METHODS OF MAKING THE SAME

Номер: US20180009975A1
Принадлежит:

A composite powder includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite powders. 1. A composite powder comprising:a core particle comprising a styrene/acrylate polymer resin and optionally a first metal ion acrylate monomer; anda shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a second metal ion acrylate monomer;wherein the total amount of metal presented in the composite powder ranges in a concentration of from about 0.5 ppm to about 50,000 ppm; and further wherein the composite powder has a particle size of from about 10 microns to about 300 microns.2. The composite powder of claim 1 , wherein the first metal of the shell comprises a silver.3. The composite powder of claim 1 , wherein the styrene/acrylate ionomer resin of the shell comprises a silver monomer selected from a silver acrylate monomer claim 1 , a silver methacrylate monomer or combinations thereof.4. The composite powder of claim 3 , wherein the silver monomer is present in the shell resin from about 0.01% to about 10% by weight of the total monomers.5. The composite powder of claim 1 , wherein the styrene/acrylate ionomer resin of the shell comprises a co-monomer selected from methyl methacrylate claim 1 , butyl acrylate claim 1 , diacrylate claim 1 , cyclohexyl methacrylate claim 1 , styrene claim 1 , methacrylic acid claim 1 , dimethylaminoethyl methacrylate or combinations thereof.6. The composite powder of claim 1 , wherein the styrene/acrylate polymer resin of the core is selected from the group consisting of styrene acrylates claim 1 , styrene butadienes claim 1 , styrene methacrylates claim 1 , and combinations thereof.7. The composite powder of claim 6 , wherein the styrene/acrylate polymer resin ...

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14-01-2021 дата публикации

Method for fractionating liquid composition

Номер: US20210009733A1
Принадлежит: Asahi Glass Co Ltd

To provide a method for fractionating a liquid composition, which is excellent in separability of the liquid composition. This method for fractionating a liquid composition comprises discharging, from a discharge port of a filling nozzle, a liquid composition containing a solvent and a polymer having ion exchange groups, and fractionating a predetermined amount of the liquid composition, characterized in that the temperature of the liquid composition is controlled so that the average tan δ1 of the liquid composition when discharged from the discharge port of the filling nozzle becomes to be at most 1.00.

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10-01-2019 дата публикации

Ethylene based polymer composition suitable for use in extrusion coating

Номер: US20190010262A1
Принадлежит: SABIC Global Technologies BV

The present invention relates to an ethylene based polymer composition suitable for use in extrusion coating. The present invention also relates to an extrusion coating product comprising such composition and the use of such a composition.

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10-01-2019 дата публикации

PROCESS FOR PREPARING PROPYLENE COPOLYMER COMPOSITIONS

Номер: US20190010263A1
Принадлежит: Borealis AG

The present invention relates to an olefin polymerization process for producing propylene copolymer composition (P), wherein propylene, Cto Cα-olefin and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst in a multistage polymerization process comprising at least two polymerization reactors, wherein the copolymer composition is bimodal with respect to the content of Cto Cα-olefin and, if present, to ethylene. Further, the invention is directed to the propylene copolymer composition being bimodal with respect to the content of Cto Cα-olefin and optionally to ethylene, and use of said propylene copolymer compositions for producing articles. 1. An olefin polymerization process for producing a propylene copolymer composition (P) , wherein propylene , Cto Cα-olefin and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst in a multistage polymerization process comprising at least two slurry polymerization reactors , wherein the copolymer composition is bimodal with respect to the content of Cto Cα-olefin and , if present , to ethylene , and wherein the process comprises{'b': '1', 'feeding a fresh propylene monomer (C3) via a first line () into a monomer feed tank (A),'}{'b': '3', 'feeding circulated unreacted monomers from a product receiver (D) into the monomer feed tank (A) via a third line (),'}{'b': 4', '4', '4, 'dividing a monomer mixture from the monomer feed tank (A) in a fourth feed line () into a first divided fourth feed line (-C), which feeds the monomer mixture to a second reactor (C), and to a second divided fourth feed line (-B) which feeds to a first reactor (B),'}{'b': 4', '5', '6, 'feeding a fresh C4 to C10 α-olefin monomer and optionally ethylene into the second divided fourth feed line (-B) via a fifth line () forming a second combined monomer mixture feed in a sixth line (),'}{'b': '6', 'feeding the second combined monomer mixture via the sixth line () to the first reactor (B),'}{'b': '1', 'polymerizing ...

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10-01-2019 дата публикации

POLYMER AS THICKENER AND SUSPENDING AGENT

Номер: US20190010267A1
Принадлежит: COATEX

The present invention relates to a polymer obtained by radical polymerization of a mixture of monomers comprising: at least one anionic monomer (a) having a polymerizable vinyl function; at least one non-ionic hydrophobic monomer (b) having a polymerizable vinyl function; and one or more crosslinking monomer(s) (c) including at least one compound of formula (I) in which R is a hydrogen atom or a methyl group, n is zero or an integer from 1 to 30, and Ris a linear or branched C-Calkylene group. The present invention also relates to a process for the preparation thereof by radical polymerization, to an aqueous composition comprising same, to the use thereof as a thickener and suspending agent and also to the use of a monomer of formula (I) for synthesizing a polymer. 2. The polymer according to claim 1 , wherein:R is a hydrogen atom or a methyl group;{'sub': 1', '2', '2, 'Ris a —(CH)— group; and'}n is equal to 1.3. The polymer according to claim 1 , wherein:R is a hydrogen atom; andn is equal to 0.4. The polymer according to claim 1 , wherein the mixture of monomers further comprises:{'sub': '10', '(d) at least one monomer (d) having a polymerizable vinyl group and an at least Chydrophobic hydrocarbon chain, the monomer (d) being distinct from the monomer (b).'}5. The polymer according to claim 1 , wherein the mixture of monomers further comprises:(e) at least one additional monomer (e) that is optionally nonionic, the additional monomer (e) being distinct from the monomer (b).6. The polymer according to claim 1 , wherein the at least one anionic monomer (a) is selected from the group consisting of acrylic acid claim 1 , a salt of acrylic acid claim 1 , methacrylic acid claim 1 , a salt of methacrylic acid claim 1 , and mixtures thereof.7. The polymer according to claim 1 , wherein the at least one anionic monomer (a) represents more than 20% by weight claim 1 , based on a total weight of monomers forming the polymer.8. The polymer according to claim 1 , wherein the ...

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10-01-2019 дата публикации

PHOTOACTIVATABLE FOULING-RESISTANT COPOLYMERS

Номер: US20190010268A1
Принадлежит: Arrow International, Inc.

A photoactivatable fouling-resistant copolymer composed of a photoactivatable monomer and a hydrophilic monomer is disclosed. The photoactivatable monomer includes an aryl ketone derivative having one or more polar groups or alkyl groups. 156-. (canceled)57. A photoactivatable fouling-resistant copolymer comprising:(a) a photoactivatable monomer including an aryl ketone derivative having one or more polar groups or alkyl groups, and(b) a hydrophilic monomer.59. The copolymer of claim 57 , wherein the photoactivatable monomer is present in an amount of 0.1 to 70% by weight based on the total weight of the copolymer.60. The copolymer of claim 57 , wherein the hydrophilic monomer is present in an amount of 30 to 99.9% by weight based on the total weight of the copolymer.61. The copolymer of claim 57 , wherein the photoactivatable monomer comprises the one or more polar groups or alkyl groups.62. The copolymer of claim 57 , wherein the polar group of the photoactivatable monomer comprises at least one of carboxylic acid claim 57 , a sulfonate group claim 57 , a nitro group claim 57 , a hydroxyl claim 57 , carboxy claim 57 , amino claim 57 , amide claim 57 , phosphate or ether group.63. The copolymer of claim 57 , wherein the alkyl group of the photoactivatable monomer or the hydrophilic monomer comprises at least one of a methyl claim 57 , ethyl claim 57 , or propyl group.64. The copolymer of claim 57 , wherein the copolymer has a weight average molecular weight ranging from 5 claim 57 ,000 to 200 claim 57 ,000.65. The copolymer of claim 57 , wherein the photoactivatable monomer comprises at least one unsaturated group.66. The copolymer of claim 57 , wherein the hydrophilic monomer comprises at least one unsaturated group.67. The copolymer of claim 65 , wherein the unsaturated group is a methacrylate claim 65 , acrylate claim 65 , acrylamide claim 65 , vinyl group or mixtures thereof.69. The copolymer of claim 57 , wherein the hydrophilic monomer is a sulfobetaine ...

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10-01-2019 дата публикации

Resin composition and application thereof

Номер: US20190010321A1
Принадлежит: Chi Mei Corp

A resin composition and an application thereof are provided, wherein the resin composition includes a thermoplastic elastomer, a styrene-based resin, a processing oil, and a filler. Based on 100 wt % of the resin composition, the content of the thermoplastic elastomer is 20 wt % to 55 wt %, the content of the styrene-based resin is 25 wt % to 55 wt %, the content of the processing oil is 6 wt % to 18 wt %, and the content of the filler is 5 wt % to 20 wt %. A printing material made by the resin composition has good adhesion with a substrate.

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10-01-2019 дата публикации

Pressure-sensitive adhesive tape, pressure-sensitive adhesive tape for affixing component for electronic appliance, and transparent pressure-sensitive adhesive tape for optical use

Номер: US20190010366A1
Принадлежит: Sekisui Chemical Co Ltd

The present invention aims to provide an adhesive tape excellent in resistance against sebum to be able to maintain its adhesive force even when applied to a part frequently touched with human hands, and an adhesive tape for fixing electronic device component and a transparent adhesive tape for optical use each provided with the adhesive tape. The present invention relates to an adhesive tape including an adhesive layer containing an acrylic adhesive, the adhesive layer having a swelling ratio of 100% or more and 130% or less after immersion in oleic acid under the conditions of a temperature of 60° C. and a humidity of 90% for 24 hours.

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09-01-2020 дата публикации

Polar Functionalized Hydrocarbon Resin Via Post-Reactor Modification

Номер: US20200010595A1
Принадлежит:

This invention relates to a process for the preparation of a polar-functionalized resin composition comprising the steps of (A) contacting a polymer backbone with a reactive moiety to produce a polar-functionalized resin composition wherein the polymer backbone is derived from a feed comprising less than or equal to about 35 wt % components derived from piperylene; less than or equal to about 10 wt % components derived from amylene; less than or equal to about 10 wt % components derived from isoprene; less than or equal to about 55 wt % unreactive paraffins; and C9 homopolymer or copolymer resins, in the presence of a Friedel-Crafts or Lewis acid catalyst; and (B) recovering a polar-functionalized resin composition. 1. A process for the preparation of a polar-functionalized resin composition comprising the steps of: (i) less than or equal to about 35 wt % components derived from piperylene;', '(ii) less than or equal to about 10 wt % components derived from amylene;', '(iii) less than or equal to about 10 wt % components derived from isoprene;', '(iv) less than or equal to about 55 wt % unreactive paraffins; and', '(v) C9 homopolymer or copolymer resins in the presence of a Friedel-Crafts or Lewis acid catalyst; and, '(A) contacting a polymer backbone with a reactive moiety to produce a polar-functionalized resin composition, wherein the polymer backbone is derived from a feed comprising(B) recovering a polar-functionalized resin composition.2. The process of claim 1 , wherein the percent of polar units in the polar-functionalized resin composition is in the amount of about 10 to about 15 mol % based on the composition.3. The process of claim 1 , wherein the reactive moiety is selected from one or more pero-oxy acids claim 1 , hydroboration agents claim 1 , acetylation agents claim 1 , thiols claim 1 , and combinations thereof.4. The process of claim 1 , wherein the Friedel-Crafts catalyst is aluminum chloride.5. The process of claim 1 , wherein the Lewis acid ...

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09-01-2020 дата публикации

AQUEOUS DISPERSION AND METHOD FOR PRODUCING AQUEOUS DISPERSION

Номер: US20200010693A1
Принадлежит: AGC Inc.

An object of the present invention is to provide an aqueous dispersion capable of forming a coating film excellent in coloring stability, a method for producing the aqueous dispersion, an aqueous coating material and a coated article. This aqueous dispersion comprises water, a surfactant and a fluorinated polymer, wherein the fluorinated polymer is dispersed in the water, wherein the fluorinated polymer comprises units based a fluoroolefin and units based on a monomer having a hydrophilic group, and the surfactant is a compound of such a structure that to a benzene ring, 1 group represented by the formula —(OQ)OSOX and 2 to 4 phenyl alkyl groups are bonded (where Q represents a Calkylene group, n represents an integer of from 2 to 48, and X represents Na or NH). 2. The aqueous dispersion according to claim 1 , wherein the units based on a monomer having a hydrophilic group comprise at least one type selected from units based on a monomer having a hydroxy group and units based on a monomer having a carboxy group.3. The aqueous dispersion according to claim 1 , wherein the units based on a monomer having a hydrophilic group are units based on a monomer having a hydrophilic polyoxyalkylene chain.4. The aqueous dispersion according to claim 1 , wherein n is an integer from 2 to 30.5. The aqueous dispersion according to claim 1 , wherein in the surfactant claim 1 , each of two groups among the 2 to 4 phenylalkyl groups is bonded to a carbon atom at an ortho position to the carbon atom of the benzene ring to which the group represented by the formula —(OQ)OSOX is bonded.6. The aqueous dispersion according to claim 1 , wherein to the benzene ring in the surfactant claim 1 , at least one group of either an alkyl group or an alkoxy group is further bonded.7. The aqueous dispersion according to claim 1 , wherein to the benzene ring in the surfactant claim 1 , at least one methyl group is further bonded.8. The aqueous dispersion according to claim 1 , wherein the group ...

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09-01-2020 дата публикации

RESIN MOLDED PRODUCT, RESIN LAMINATE, CARTRIDGE, IMAGE-FORMING APPARATUS, METHOD FOR MANUFACTURING RESIN MOLDED PRODUCT, METHOD FOR MANUFACTURING RESIN LAMINATE, AND METHOD FOR MANUFACTURING CARTRIDGE

Номер: US20200012211A1
Принадлежит:

A resin molded product whose main component consists of an ethylene-vinyl acetate copolymer resin and carbon black. The ethylene-vinyl acetate copolymer resin has an MFR of 0.5 g/10 min or more and 20 g/10 min or less. The carbon black has an average primary particle diameter of 55 nm or more and 100 nm or less and a DBP oil absorption amount of 100 mL/100 g or more and 300 mL/100 g or less. The content of vinyl acetate is 2.9 parts by mass or more and 12.3 parts by mass or less based on 100 parts by mass of the main component. The resin molded product has a surface resistivity of 720 Ω/□ or less. 1. A resin molded product comprising a main component , the main component consisting of:an ethylene-vinyl acetate copolymer resin; andcarbon black,whereinthe ethylene-vinyl acetate copolymer resin has a melt flow rate of 0.5 g/10 min or more and 20 g/10 min or less;the carbon black has an average primary particle diameter of 55 nm or more and 100 nm or less and a dibutyl phthalate oil absorption amount of 100 mL/100 g or more and 300 mL/100 g or less;a content of the vinyl acetate is 2.9 parts by mass or more and 12.3 parts by mass or less based on 100 parts by mass of the main component; andthe resin molded product has a surface resistivity of 720 Ω/□ or less.2. The resin molded product according to claim 1 , whereinthe content of the vinyl acetate is 5 parts by mass or more and 20 parts by mass or less based on 100 parts by mass of the ethylene-vinyl acetate copolymer resin.3. The resin molded product according to claim 1 , whereinthe content of the carbon black is 35 parts by mass or more and 50 parts by mass or less based on 100 parts by mass of the main component.4. The resin molded product according to claim 1 , whereinthe resin molded product has a thickness of 30 μm or more and 200 μm or less.5. A resin laminate comprising:a base material made of a polystyrene resin; anda resin layer provided on the base material and including a main component consisting of an ...

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10-01-2019 дата публикации

BINDER COMPOSITION FOR NON-AQUEOUS SECONDARY BATTERY ELECTRODE, SLURRY COMPOSITION FOR NON-AQUEOUS SECONDARY BATTERY ELECTRODE, ELECTRODE FOR NON-AQUEOUS SECONDARY BATTERY, AND NON-AQUEOUS SECONDARY BATTERY

Номер: US20190013523A1
Автор: SHIBUYA Masanori
Принадлежит: ZEON CORPORATION

A binder composition for a non-aqueous secondary battery electrode contains a water-soluble polymer including a (meth)acrylamide monomer unit and an amine compound. Percentage content M0 of the (meth)acrylamide monomer unit is at least 40 mass % and not more than 100 mass % relative to 100 mass % of all monomer units of the water-soluble polymer. Content M1 of the amine compound is at least 0.01 parts by mass and not more than 0.5 parts by mass per 100 parts by mass of solid content of the water-soluble polymer. 1. A binder composition for a non-aqueous secondary battery electrode comprising:a water-soluble polymer including a (meth)acrylamide monomer unit; andan amine compound, whereinpercentage content M0 of the (meth)acrylamide monomer unit is at least 40 mass % and not more than 100 mass % relative to 100 mass % of all monomer units of the water-soluble polymer, andcontent M1 of the amine compound is at least 0.01 parts by mass and not more than 0.5 parts by mass per 100 parts by mass of solid content of the water-soluble polymer.2. The binder composition for a non-aqueous secondary battery electrode according to claim 1 , wherein{'sup': −3', '−3, 'a mass ratio M=M1/M0 calculated from the content M1 of the amine compound and the percentage content M0 of the (meth)acrylamide monomer unit is at least 0.10×10and not more than 12.5×10.'}3. The binder composition for a non-aqueous secondary battery electrode according to claim 1 , wherein the amine compound has a nitric oxide radical generating structure.4. The binder composition for a non-aqueous secondary battery electrode according to claim 1 , whereinthe amine compound is hydroxylamine sulfate or diethylhydroxylamine.5. The binder composition for a non-aqueous secondary battery electrode according to claim 1 , wherein{'sup': 6', '6, 'the water-soluble polymer has a weight average molecular weight of at least 0.01×10and not more than 20.0×10.'}6. A slurry composition for a non-aqueous secondary battery electrode ...

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10-01-2019 дата публикации

GEL ELECTROLYTE AND METHOD FOR PREPARING SAME

Номер: US20190013547A1
Автор: Watanabe Keisuke
Принадлежит:

Provided is a gel electrolyte that has a lower concentration of matrix polymer and that can maintain a gel state. The gel electrolyte contains a non-aqueous electrolyte solution in which a lithium-containing electrolyte is dissolved in a non-aqueous solvent and a matrix polymer, the matrix polymer being a copolymer containing a vinylidene fluoride unit and a fluorine atom-containing monomer unit as a repeating unit, and the crystallization temperature Tof the matrix polymer being within a range that satisfies the following Relationship (I) relative to the concentration C (mass %) of the matrix polymer included in the gel electrolyte: 1. A gel electrolyte comprising:a non-aqueous electrolyte solution in which a lithium-containing electrolyte is dissolved in a non-aqueous solvent; anda matrix polymer;the matrix polymer being a copolymer containing a vinylidene fluoride unit and a fluorine atom-containing monomer unit as a repeating unit; and{'sub': 'c', 'claim-text': {'br': None, 'i': Tc≥', 'C, '110−\u2003\u2003(I),'}, 'a crystallization temperature Tof the matrix polymer being within a range that satisfies Relationship (I) relative to a concentration C (mass %) of the matrix polymer included in the gel electrolytewhere 0.1≤C≤30.2. The gel electrolyte according to claim 1 , wherein the copolymer further contains at least one of a repeating unit derived from unsaturated dibasic acid and a repeating unit derived from unsaturated dibasic acid monoester.3. The gel electrolyte according to claim 2 , wherein the unsaturated dibasic acid is unsaturated dicarboxylic acid claim 2 , and the unsaturated dibasic acid monoester is unsaturated dicarboxylic acid monoester.4. The gel electrolyte according to claim 1 , wherein the fluorine atom-containing monomer unit is a repeating unit derived from hexafluoropropylene or a repeating unit derived from chlorotrifluoroethylene.5. The gel electrolyte according to claim 1 , wherein the non-aqueous solvent is ethylene carbonate claim 1 , ...

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03-02-2022 дата публикации

METHOD FOR PREPARING AN AQUEOUS POLYMER DISPERSION FROM A VINYL AROMATIC COMPOUND AND A CONJUGATED ALIPHATIC DIENE

Номер: US20220033534A1
Принадлежит:

The present invention relates to a process for producing an aqueous polymer dispersion by free-radically initiated aqueous emulsion polymerization, by polymerizing, in an aqueous medium, 1. A process for producing an aqueous polymer dispersion by free-radically initiated aqueous emulsion polymerization , which comprises polymerizing , in an aqueous medium ,(a) 40 to 75 parts by weight of at least one vinylaromatic compound and(b) 24.9 to 59.9 parts by weight of at least one conjugated aliphatic diene(c) 0.1 to 10 parts by weight of at least one monomer comprising acid groups and(d) 0 to 20 parts by weight of at least one other monoethylenically unsaturated monomer, the amounts of the monomers (a) to (d) adding up to 100 parts by weight, the continuous metering of the inorganic peroxide starts at the same time as the continuous metering of the vinylaromatic compound,', 'the metering of the organic peroxide is started at a time at which at least 5% and not more than 20% of the vinylaromatic compound has already been metered in in a continuous mass flow under polymerization conditions and', 'optionally a portion of inorganic peroxide is initially charged., 'in a monomer feed process in the presence of at least one inorganic peroxide and at least one organic peroxide, with the proviso that'}2. The process according to claim 1 , wherein the vinylaromatic compound is styrene and/or methylstyrene and the conjugated aliphatic diene is 1 claim 1 ,3-butadiene and/or isoprene.3. The process according to claim 1 , wherein during the monomer feed no reducing agent capable of forming a redox initiator system with the organic or inorganic peroxides is present.4. The process according to claim 1 , wherein the inorganic peroxide is selected from hydrogen peroxide and ammonium or alkali metal salts of peroxodisulfates and the organic peroxide is selected from alkyl hydroperoxides and aryl hydroperoxides.5. The process according to claim 1 , wherein the polymerization is initiated in ...

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03-02-2022 дата публикации

Polyolefin composition for carpet backing

Номер: US20220033543A1
Принадлежит: Basell Poliolefine Italia Srl

A filled polyolefin composition made from or containing butene-1 copolymers having high melt flow and an inorganic filler. The compositions are useful for carpet backing.

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03-02-2022 дата публикации

COPOLYMERS OF PERFLUOROCYCLOALIPHATIC METHYL VINYL ETHER

Номер: US20220033673A1
Принадлежит:

Described herein is a perfluoropolymer and compositions therefrom. The perfluoropolymer is derived from: (a) no more than 88 mol % tetrafluoroethylene monomer; and (b) a complementary amount of a perfluoro (cycloaliphatic methyl vinyl ether) monomer, and has substantially no melting point. 1. A perfluoropolymer , wherein the perfluoropolymer is derived from at least:(a) no more than 88 mol % tetrafluoroethylene monomer; and{'sub': 2', '3', '2', 'n', '2, 'claim-text': wherein Rf is a perfluorinated group comprising 6 carbon atoms and 11 fluorine atoms and a cycloaliphatic group, and n is 0, 1, or 2; and', 'wherein the perfluoropolymer has substantially no melting point., '(b) a complementary amount of a monomer according to Formula I Rf—CF—[OCF(CF)CF]O—CF═CF'}2. The perfluoropolymer according to claim 1 , wherein the monomer of Formula I comprises perfluoro(cyclohexyl methyl vinyl ether).3. The perfluoropolymer according to claim 1 , wherein the monomer of Formula I comprises at least one of perfluoro(cyclohexyl methyl vinyl ether) claim 1 , perfluoro(2-methyl cyclopentyl methyl vinyl ether) claim 1 , perfluoro(3-methyl cyclopentyl methyl vinyl ether) claim 1 , perfluoro(2-dimethyl cyclobutyl methyl vinyl ether) claim 1 , and perfluoro(3-dimethyl cyclobutyl methyl vinyl ether).4. The perfluoropolymer according to claim 1 , wherein the perfluoropolymer is further derived from at least one of hexafluoropropylene claim 1 , chlorotrifluoroethylene claim 1 , a perfluoroalkyl vinyl ether claim 1 , a perfluoroalkyl allyl ether claim 1 , and combinations thereof.5. The perfluoropolymer according to claim 4 , wherein the perfluoropolymer is further derived from at least 10 mol % of a perfluoroalkyl vinyl ether claim 4 , a perfluoroalkyl allyl ether claim 4 , or combinations thereof.6. The perfluoropolymer according to claim 1 , wherein the perfluoropolymer is derived from at least 15 mol % of the perfluoro(cycloaliphatic methyl vinyl ether) monomer.7. The perfluoropolymer ...

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03-02-2022 дата публикации

POLYMERISABLE LIQUID CRYSTAL MATERIAL AND POLYMERISED LIQUID CRYSTAL FILM

Номер: US20220033711A1
Принадлежит: Merck Patent GmBH

The invention relates to a polymerisable LC material comprising one or more di- or multireactive mesogenic compounds and one or more compounds of formula UVI, 2. Polymerisable LC material according to claim 1 , wherein at least one di- or multireactive mesogenic compound is selected of formula DRM{'br': None, 'sup': 1', '1', '2', '2, 'P-Sp-MG-Sp-P\u2003\u2003DRM'}wherein{'sup': 1', '2, 'Pand Pindependently of each other denote a polymerisable group,'}{'sup': 1', '2, 'Spand Spindependently of each other are a spacer group or a single bond, and'} {'br': None, 'sup': 1', '1', '2, 'sub': 'n', '-(A-Z)-A-\u2003\u2003MG'}, 'MG is a rod-shaped mesogenic group, which is preferably selected of formula MG'}wherein{'sup': 1', '2', '1, 'Aand Adenote, in case of multiple occurrence independently of one another, an aromatic or alicyclic group, which optionally contains one or more heteroatoms selected from N, O and S, and is optionally mono- or polysubstituted by L,'}{'sup': 1', '00', '000', '00', '00', '00', '000, 'sub': 2', '5, 'Lis P-Sp-, F, Cl, Br, I, —CN, —NO, —NCO, —NCS, —OCN, —SCN, —C(═O)NRR, —C(═O)OR, —C(═O)R, —NRR, —OH, —SF, optionally substituted silyl, aryl or heteroaryl with 1 to 12 C atoms, straight chain or branched alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy with 1 to 12, C atoms, wherein one or more H atoms are optionally replaced by F or Cl,'}{'sup': 00', '000, 'Rand Rindependently of each other denote H or alkyl with 1 to 12 C-atoms,'}{'sup': 1', '00', '00', '00', '000', '00', '00', '00', '1', '2, 'sub': 2', '2', '2', '2', '2', '2', '2', '2', '2', '2', '2', 'n1', '2', '2', '2', '2', '2', '2, 'Zdenotes, in case of multiple occurrence independently of one another, —O—, —S—, —CO—, —COO—, —OCO—, —S—CO—, —CO—S—, —O—OCO—, —CO—NR—, —NR—CO—, —NR—CO—NR, —NR—CO—O—, —O—CO—NR—, —OCH—, —CHO—, —SCH—, —CHS—, —CFO—, —OCF—, —CFS—, —SCF—, —CHCH—, —(CH), —CFCH—, —CHCF—, —CFCF—, —CH═N—, —N═CH—, —N═N—, —CH═CR—, —CY═CY—, —C≡C—, —CH═CH—COO—, —OCO ...

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17-01-2019 дата публикации

Dental Materials Based On Low-Viscosity Radically Polymerizable Monomers With A High Refractive Index

Номер: US20190015301A1
Принадлежит:

Radically polymerizable, difunctional phenylene sulfide according to Formula I 3. The dental material according to claim 1 , wherein the variables have the following meanings:{'sup': 1', '2, 'R, Rindependently of each other in each case are H or Br,'}{'sup': '3', 'sub': 2', '4, 'Ris dispensed with or is a C-Calkylene radical,'}{'sup': '4', 'sub': 1', '3, 'Ris dispensed with or is a C-Calkylene radical,'}{'sup': '5', 'Ris H,'}a, b, c, d in each case are 0, ande is 1.4. The dental material according to claim 1 , wherein the difunctional phenylene sulfide of Formula I has a viscosity of ≤3 Pa·s claim 1 , measured using a capillary viscometer at a temperature of 23° C.5. The dental material according to claim 4 , wherein the viscosity is in the range of 5 to 2 claim 4 ,000 mPas or 10 to 1 claim 4 ,000 mPa·s claim 4 , measured using a capillary viscometer at a temperature of 23° C.6. The dental material according to claim 1 , wherein the difunctional phenylene sulfide of Formula I has a refractive index of more than 1.57 claim 1 , measured at 20° C. with the light of the yellow Na D line (λ=589 nm).7. The dental material according to claim 6 , wherein the refractive index is in the range of from 1.575 to 1.75 or from 1.58 to 1.72 claim 6 , measured at 20° C. with the light of the yellow Na D line (λ=589 nm).8. The dental material according to claim 1 , which additionally contains at least one initiator for the radical polymerization claim 1 , wherein the initiator comprises a photoinitiator.9. The dental material according to claim 1 , which additionally contains at least one further radically polymerizable monomer claim 1 , wherein the at least one further radically polymerizable monomer comprises at least one mono- or multifunctional (meth)acrylate.10. The dental material according to claim 9 , wherein the at least one mono- or multifunctional (meth)acrylate comprises Bis-GMA claim 9 , UDMA claim 9 , TMX-UDMA claim 9 , DMA claim 9 , TEGDMA claim 9 , CMP-1E claim 9 , ...

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19-01-2017 дата публикации

Modified conjugated diene-based polymer, preparation method therefor, and rubber composition containing same

Номер: US20170015761A1
Принадлежит: LG Chem Ltd

Disclosed are a modified conjugated diene-based polymer represented by specific Chemical Formula, a method of preparing the same, and a rubber composition including the same.

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19-01-2017 дата публикации

CYANINE COLORING COMPOSITION

Номер: US20170015765A1
Принадлежит: WAKO PURE CHEMICAL INDUSTRIES, LTD.

It is an object of the present invention to provide a cyanine-based coloring composition having higher heat resistance, as compared with a conventional coloring composition. The present invention relates to a compound represented by the following general formula (1), a polymer having a monomer unit derived from the compound, along with a coloring composition, a coloring composition for a color filter, and a colored resin comprising the above-described compound or the above-described polymer. 2. The compound according to claim 1 , wherein the electron-withdrawing substituent in An is a halogen atom.3. The compound according to claim 1 , wherein the electron-withdrawing substituent in An is a fluorine atom.4. The compound according to claim 1 , wherein An is a quaternary boron anion.5. The compound according to claim 1 , wherein An is a tetrakis(perfluorophenyl)borate anion.7. The polymer according to claim 6 , wherein the electron-withdrawing substituent in An is a halogen atom.8. The polymer according to claim 6 , wherein the electron-withdrawing substituent An is a fluorine atom.9. The polymer according to claim 6 , wherein An is a quaternary boron anion.10. The polymer according to claim 6 , wherein An is a tetrakis(perfluorophenyl)borate anion.11. The polymer according to claim 6 , wherein the polymer is a copolymer.13. A coloring composition comprising the compound according to .14. A coloring composition for a color filter comprising the compound according to .15. A colored resin comprising the compound according to .16. A coloring composition comprising the polymer according to .17. A coloring composition for a color filter comprising the polymer according to .18. A colored resin comprising the polymer according to . The present invention relates to a cyanine-based coloring compound; a polymer having a monomer unit derived from the compound; and a coloring composition comprising the polymer.As a method for forming a color pixel in manufacturing a color filter ...

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19-01-2017 дата публикации

VINYLIDENE FLUORIDE COPOLYMER AND PREPARATION METHOD THEREFOR

Номер: US20170015771A1
Принадлежит:

Provided in the present invention is a vinylidene fluoride copolymer. Same is acquired via a polymerization reaction taking place at conditions of 30-100° C. and 2-7 MPa with vinylidene fluoride, tetrafluoroethylene, and perfluorinated dioxole or C1-4 alkoxy-substituted perfluorinated dioxole as raw materials, with an initiator added into an emulsion consisting of water, fluorinated emulsifier, a chain transfer agent, a pH regulator, and an antifouling agent, and then via steps of separation, purification, refinement, condensation, washing, drying, and granulation, where the molar ratio of vinylidene fluoride, tetrafluoroethylene, and perfluorinated dioxole or C1-4 alkoxy-substituted perfluorinated dioxole is 13-17:2-4:1-3. The vinylidene fluoride copolymer of the present invention provides excellent transparency, flexibility, and solubility, is widely applicable in optical apparatus such as lenses, and is for use in specialty films in the fields of solar panels and of capacitors as a fuel cell membrane, a transparent and tough coating, and a large-sized blown object. 1. A vinylidene fluoride copolymer , wherein the vinylidene fluoride copolymer is synthesized by polymerizing vinylidene fluoride , tetrafluoroethylene , and perfluorinated dioxole or C1-4 alkoxy-substituted perfluorinated dioxole in a molar ratio of 13-17:2-4:1-3.2. The vinylidene fluoride copolymer of claim 1 , wherein the C1-4 alkoxy-substituted perfluorinated dioxole is perfluorinated dimethyl dioxole.3. The vinylidene fluoride copolymer of claim 1 , wherein the vinylidene fluoride copolymer has a melt point in a range of 100-150° C. claim 1 , and has a melt flow index of 0-60 g/10 min claim 1 , preferably 2.1-10 g/10 min claim 1 , at a temperature of 230° C. and under a load of 5 kg.4. A preparation method of the vinylidene fluoride copolymer of claim 3 , wherein the vinylidene fluoride copolymer is prepared by performing a polymerization reaction by using vinylidene fluoride claim 3 , ...

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19-01-2017 дата публикации

ADHESIVE COMPOSITION

Номер: US20170015875A1
Принадлежит:

An adhesive composition includes0 an acryl copolymer having a carboxyl group, and a silane compound represented by Formula 1 or 2, thereby it is possible to exhibit excellent initial adhesiveness and adhesive durability under severe conditions, and prevent the substrate from being torn due to a decrease in adhesiveness by water applied thereto, and the adhesive from remaining on the substrate during peeling-off the adhesive layer, as well as after drying, the adhesive layer may exhibit favorable adhesiveness again, thus being used for re-bonding. 2. The adhesive composition according to claim 1 , wherein the acryl copolymer is prepared by polymerizing monomers including 1 wt. % or more of an ethylenically unsaturated monomer having a carboxyl group to a total weight of the monomers.3. The adhesive composition according to claim 1 , wherein the acryl copolymer is prepared by polymerizing monomers including 2.5 to 8 wt. % of an ethylenically unsaturated monomer having a carboxyl group to a total weight of the monomers.5. The adhesive composition according to claim 1 , wherein the silane compound is included in an amount of 0.01 to 5 wt. parts to 100 wt. parts of the acryl copolymer.6. The adhesive composition according to claim 1 , further comprising a cross-linking agent selected from a group consisting of isocyanate claim 1 , epoxy claim 1 , metal chelate claim 1 , oxazoline and poly-functional acrylate-based compounds.7. An adhesive sheet comprising an adhesive layer formed using the adhesive composition according to .8. A polarizing plate comprising an adhesive layer formed using the adhesive composition according to claim 1 , on at least one surface of the polarizing plate.9. An image display device comprising the polarizing plate according to . 1. Field of the InventionThe present invention relates to an adhesive composition.2. Description of the Related ArtA liquid crystal display device generally consists of liquid crystal cells and a polarizing plate, mostly ...

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19-01-2017 дата публикации

ULTRAVIOLET CURABLE RESIN COMPOSITION, SLIDING MEMBER, AND METHOD FOR PRODUCING SLIDING MEMBER

Номер: US20170015923A1
Принадлежит: MINEBEA CO., LTD.

There is provided a resin composition for a machinable liner of a sliding member. An ultraviolet curable resin composition for a self-lubricating liner contains a (meth)acrylate compound having an isocyanuric acid ring represented by the following formula and PTFE as a solid lubricant. In the formula (1), X is a group which contains an acryloyl group and is composed only of C, H, and O. Y and Z are groups each composed only of C, H, and O. PTFE is contained in an amount of 10 to 50% by weight with respect to a total amount of the ultraviolet curable resin composition. The ultraviolet curable resin composition is suitable for a self-lubricating liner of a spherical bearing having an outer race and an inner race . 2. The ultraviolet curable resin composition according to claim 1 , wherein the acrylate compound having the isocyanuric acid ring is selected from the group consisting of di-(2-acryloxyethyl) isocyanurate claim 1 , tris-(2-acryloxyethyl) isocyanurate claim 1 , ε-caprolactone modified tris-(2-acryloxyethyl) isocyanurate claim 1 , and a mixture of the di-(2-acryloxyethyl) isocyanurate and the tris-(2-acryloxyethyl) isocyanurate.3. The ultraviolet curable resin composition according to claim 1 , wherein the acrylate compound having the isocyanuric acid ring is a mixture of di-(2-acryloxyethyl) isocyanurate and tris-(2-acryloxyethyl) isocyanurate claim 1 , or ε-caprolactone modified tris-(2-acryloxyethyl) isocyanurate.4. The ultraviolet curable resin composition according to claim 1 , further comprising melamine cyanurate in an amount of 30% by weight or less with respect to the total amount of the ultraviolet curable resin composition.5. The ultraviolet curable resin composition according to claim 1 , wherein the polytetrafluoroethylene resin is in a powder form having an average particle diameter ranging from 75 μm to 180 μm.6. The ultraviolet curable resin composition according to claim 1 , wherein the polytetrafluoroethylene resin is a ...

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21-01-2021 дата публикации

Permeable Superabsorbent and Process for Production Thereof

Номер: US20210016247A1
Принадлежит:

A highly permeable superabsorbent is prepared by a process comprising 1. A process for producing a superabsorbent , comprisingpolymerizing an aqueous monomer solution comprisinga) at least one ethylenically unsaturated monomer which bears an acid group and optionally is at least partly in salt form,b) at least one crosslinker,c) at least one initiator,d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a), ande) optionally one or more water-soluble polymer;drying a resulting polymer,optionally grinding the dried polymer and sieving the ground polymer,optionally surface postcrosslinking the dried and optionally ground and sieved polymer,wherein, after drying, grinding, or sieving, and, if surface postcrosslinking is conducted, during or after the surface postcrosslinking, adding an x-ray-amorphous aluminum hydroxide powder.2. The process according to claim 1 , wherein 0.01% to 2% by weight claim 1 , based on the amount of polymer prior to the addition claim 1 , of x-ray-amorphous aluminum hydroxide is added.3. The process according to claim 2 , wherein 0.2% to 1% by weight claim 2 , based on the amount of polymer prior to the addition claim 2 , of x-ray-amorphous aluminum hydroxide is added.4. The process according to any of claim 1 , wherein the dried and optionally ground and sieved polymer is surface postcrosslinked with a postcrosslinker that forms covalent bonds with polar groups at a surface of the superabsorbent particles.5. The process according to any of claim 1 , wherein claim 1 , after the addition of x-ray-amorphous aluminum hydroxide powder claim 1 , 0.1% to 10% by weight claim 1 , based on the amount of polymer prior to the addition of the x-ray-amorphous aluminum hydroxide powder claim 1 , of water is added to the superabsorbent.6. A superabsorbent obtained by the process of any of .7. An article for absorption of fluids claim 6 , comprising the superabsorbent of .8. A process for producing ...

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17-01-2019 дата публикации

An Amphoteric Polymer and an Alkenyl Succinic Anhydride Emulsion Containing the Same

Номер: US20190016880A1
Принадлежит: ECOLAB USA INC.

The present invention is directed to an amphoteric polymer, a method for preparing an amphoteric polymer, use of the amphoteric polymer for emulsifying an alkenyl succinic anhydride. The present invention also provides an alkenyl succinic anhydride emulsion prepared using the amphoteric polymer, and a method for sizing paper using an alkenyl succinic anhydride emulsion prepared using the amphoteric polymer. The amphoteric polymer of the present invention is obtained by copolymerization of cationic monomers, non-ionic monomers, and anionic monomers. 1. (canceled)2. The alkenyl succinic anhydride emulsion of claim 16 , wherein the cationic monomer is selected from diallyl-N claim 16 ,N-dimethyl ammonium chloride claim 16 , methacryloyloxyethyltrimethylammonium chloride claim 16 , methacryloyloxyethyltrimethylammonium sulfate claim 16 , methacryloyloxyethyldimethylphenylammonium chloride claim 16 , acryloyloxyethyltrimethylammonium chloride claim 16 , acryloyloxyethyltrimethylammonium sulfate claim 16 , acryloyloxyethyldimethylphenylammonium chloride claim 16 , N claim 16 ,N claim 16 ,N-trimethyl-3-(2-methylacrylamino)-1-propyl ammonium chloride claim 16 , methacrylic N claim 16 ,N′-dimethylamino ethyl ester claim 16 , methacrylic N claim 16 ,N′-dimethylamino ethyl ester quaternary ammonium salt cation claim 16 , acrylic-(dimethylamino) ethyl ester claim 16 , acrylic-(dimethylamino) ethyl ester quaternary ammonium salt claim 16 , acrylic-(diethylamino) ethyl ester claim 16 , acrylic-(diethylamino) ethyl ester quaternary ammonium salt claim 16 , or a combination thereof.3. The alkenyl succinic anhydride emulsion of claim 16 , wherein the anionic monomer is selected from acrylic acid or a salt thereof claim 16 , methacrylic acid or a salt thereof claim 16 , or a combination thereof.4. The alkenyl succinic anhydride emulsion of claim 16 , wherein the non-ionic monomer is elected from acrylamide claim 16 , methacrylamide claim 16 , N claim 16 ,N-dimethylacrylamide claim 16 ...

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17-01-2019 дата публикации

POLY(METH)ACRYLATE COPOLYMERS WITH BRANCHED C17 ALKYL CHAINS AND THEIR USE IN LUBRICANT OIL COMPOSITIONS

Номер: US20190016987A1
Принадлежит:

The presently claimed invention is directed to poly(meth)acrylate copolymers containing alkyl(meth)acrylate comonomer with branched C17 alkyl group. The invention is further related to lubricating oil compositions comprising poly(meth)acrylate copolymers containing alkyl(meth) acrylate comonomer with branched C17 alkyl group as viscosity index improving component. 115.-. (canceled)16. A poly(meth)acrylate copolymer that is obtained by polymerizing a mixture comprising:(A) C17 alkyl (meth)acrylate, where C17 alkyl chain is branched with a mean degree of branching between 2.0 and 4.0,(B) methyl methacrylate and/or methyl acrylate, and(C) alkyl methacrylate and/or alkyl acrylate with a linear or branched C2 to C30 alkyl chain.17. The copolymer of claim 16 , wherein the C17 alkyl chain is branched with a mean degree of branching between 2.8 and 3.7.18. The copolymer of claim 16 , wherein the copolymer has a weight average molecular weight Mof from 10 claim 16 ,000 to 800 claim 16 ,000 determined by gel permeation chromatography according to DIN 55672-1.19. The copolymer of claim 16 , wherein the amount of comonomer (A) is from 5 to 80 wt.-% claim 16 , based on the total weight of the poly(meth)acrylate copolymer.20. The copolymer of claim 16 , wherein the amount of comonomer (B) is from 5 to 40 wt.-% claim 16 , based on the total weight of the poly(meth)acrylate copolymer.21. The copolymer of claim 16 , wherein the amount of comonomer (C) is from 15 to 80 wt.-% claim 16 , based on the total weight of the poly(meth)acrylate copolymer.22. The copolymer of claim 16 , wherein the linear or branched C2 to C30 alkyl chain is selected from the group consisting of ethyl claim 16 , n-propyl claim 16 , iso-propyl claim 16 , n-butyl claim 16 , iso-butyl claim 16 , sec-butyl claim 16 , tert-butyl claim 16 , pentyl claim 16 , hexyl claim 16 , heptyl claim 16 , octyl claim 16 , 2-ethylhexyl claim 16 , 2-propyl heptyl claim 16 , nonyl claim 16 , decyl claim 16 , stearyl claim 16 , ...

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21-01-2021 дата публикации

PROCESS FOR FUNCTIONALIZATION OF ORGANO-ZINC COMPOUNDS WITH HALOSILANES USING BASIC NITROGEN CONTAINING HETEROCYCLES AND SILYL-FUNCTIONALIZED COMPOUNDS PREPARED THEREBY

Номер: US20210017195A1
Принадлежит:

A process to functionalize organo-zinc compounds with halosilane electrophiles employs a basic additive. The process includes combining the organo-zinc compound, a halosilanes, and a nitrogen containing heterocycle as the basic additive. The presence of the basic additive facilitates successful substitution. Functionalized silanes and silyl-terminated polyolefins can be prepared using this process. The functionalized silanes may be useful as endblockers for polyorganosiloxanes having SiH and/or silicon bonded aliphatically unsaturated groups capable of undergoing hydrosilylation. 1. A process for preparing a silyl-terminated polyolefin comprising: A) a polymeryl-zinc;', 'B) a nitrogen containing heterocycle, and', 'C) a halosilane;, '1) combining starting materials comprising'}thereby forming a product comprising the silyl-terminated polyolefin.2. The process of claim 1 , further comprising: forming the polymeryl-metal before step 1) by a process comprising combining starting materials comprisingi) an olefin monomer,ii) a catalyst, andiii) a chain shuttling agent of formula R2Zn, where each R is independently a monovalent hydrocarbyl group of 2 to 12 carbon atoms.3. The process of claim 2 , where the starting materials further comprise one or more additional materials selected from: iv) a solvent claim 2 , vi) a scavenger claim 2 , vii) an adjuvant claim 2 , and viii) a polymerization aid.4. The process of claim 1 , further comprising purifying A) the polymeryl-zinc before step 1).5. The process of claim 1 , where A) the polymeryl-zinc comprises A1) di-polyethylene zinc claim 1 , A2) polyethylene/octene zinc claim 1 , and a mixture of A1) and A2).7. A process for preparing a hydrocarbyl functional silane comprising: A) a chain shuttling agent of formula R2Zn, where each R is independently a monovalent hydrocarbyl group of 2 to 12 carbon atoms;', 'B) a nitrogen containing heterocycle, and', 'C) a halosilane;, '1) combining starting materials comprising'}thereby ...

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16-01-2020 дата публикации

Catalysts for Olefin Polymerization

Номер: US20200017615A1
Принадлежит:

The present disclosure provides catalyst compounds having a tridentate ethylene bridged amine bis(phenolate) ligand. Catalysts of the present disclosure preferably provide catalyst activity values of 250 gP/mmolCat/hr or greater and polyolefins, such as polyethylene copolymers, having comonomer content of 8.5 wt % or greater, an Mn of 190,000 g/mol or greater, an Mw of 350,000 g/mol or greater, and a narrow Mw/Mn (such as about 2). Catalysts, catalyst systems, and processes of the present disclosure can provide polymers having a high comonomer content (e.g., 8.5 wt % or greater). 2. The catalyst compound of claim 1 , wherein Ris hydrogen or C-Chydrocarbyl.3. The catalyst compound of claim 2 , wherein RC-Chydrocarbyl.4. The catalyst compound of claim 2 , wherein Ris hydrogen.5. The catalyst compound of claim 1 , wherein n is 2.7. The catalyst compound of claim 6 , wherein each of R claim 6 , R claim 6 , R claim 6 , R claim 6 , and Ris independently selected from hydrogen and C-Chydrocarbyl.8. The catalyst compound of claim 7 , wherein each of R claim 7 , R claim 7 , R claim 7 , R claim 7 , and Ris hydrogen.9. The catalyst compound of claim 1 , wherein each of R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Ris independently hydrogen and C-Chydrocarbyl.10. The catalyst compound of claim 9 , wherein two or more of R claim 9 , R claim 9 , R claim 9 , and Rare hydrogen and two or more of R claim 9 , R claim 9 , R claim 9 , and Rare hydrogen.11. The catalyst compound of claim 10 , wherein each of R claim 10 , R claim 10 , R claim 10 , R claim 10 , R claim 10 , R claim 10 , R claim 10 , and Ris hydrogen.12. The catalyst compound of claim 1 , wherein M is Zr or Hf.13. The catalyst compound of claim 1 , wherein each X is methyl claim 1 , benzyl claim 1 , or chloro.16. A catalyst system comprising an activator and the catalyst compound of .17. The catalyst system of claim 16 , further comprising a support material.18. The catalyst ...

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21-01-2021 дата публикации

PRINTABLE RESINS AND USES OF SAME

Номер: US20210017302A1
Принадлежит:

Provided are resin compositions, which may be used for 3D printing. The resins may be colorless and/or transparent. The resins include a photoinitiator and one or more hard cross-linker. The resins may also include one or more of soft cross-linker(s), reactive diluent(s), filler(s), and additive(s). Also provided are articles of manufacture and methods of making articles of manufacture using one or more of the resins. The articles of manufacture may have one or more desirable mechanical and/or one or more desirable biocompatibility properties. The articles of manufacture may be colorless and/or transparent. The articles of manufacture may be produced using a method of the present disclosure. 1. A resin composition comprising:one or more photoinitiator;one or more hard cross-linker, wherein the one or more hard cross-linker has at least two reactive groups and is present at 20-75 wt % (based on the total weight of the composition); andone or more soft cross-linker and/or one or more reactive diluent, wherein the one or more soft cross-linker has at least two reactive groups is present at 2-70 wt % (based on the total weight of the composition) and/or the one or more reactive diluent has only one reactive group and is present at 2-70 wt % (based on the total weight of the composition).2. The resin composition of claim 1 , wherein the resin composition further comprises one or more soft cross-linker and one or more reactive diluent.3. The resin composition of claim 1 , wherein the resin composition further comprises:one or more filler; and/orone or more additive.4. The resin composition of claim 1 , wherein the one or more photoinitiator is diphenyl(2 claim 1 ,4 claim 1 ,6-trimethylbenzoyl)phosphine oxide (TPO) claim 1 , 1-phenyl-1 claim 1 ,2-propanedione/triame (PPD/TA) claim 1 , camphoroquinone claim 1 , Irgacure 819 claim 1 , henanthrenequinone claim 1 , or a combination thereof.5. The resin composition of claim 1 , wherein the hard cross-linker has a molecular ...

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16-01-2020 дата публикации

Graft Polymers for Dispersing Graphene and Graphite

Номер: US20200017664A1
Принадлежит:

Disclosed herein are graft polymers having a copolymer backbone and polycyclic aromatic hydrocarbon branches for use as a nanofiller dispersant and methods for making the same. Also disclosed are elastomeric nanocomposite compositions comprising a halobutyl rubber matrix, nanoparticles of graphite or grapheme, and the graft polymer. Such elastomeric nanocomposite compositions are suitable as tire innerliners or innertubes. 1. A polymer comprising:(a) a copolymer backbone comprising units derived from an isoolefin having from 4 to 7 carbons and an alkylstyrene; and 'wherein the one or more branches are directly bonded to an aromatic moiety of the copolymer backbone.', '(b) one or more branches comprising a polycyclic aromatic hydrocarbon,'}2. The polymer of claim 1 , wherein the polycyclic aromatic hydrocarbon is polynuclear.3. The polymer of claim 2 , wherein the polycyclic aromatic hydrocarbon is selected from the group consisting of naphthalenes claim 2 , anthracenes claim 2 , phenanthrenes claim 2 , pyrenes claim 2 , benzopyrenes claim 2 , coronenes claim 2 , ovalenes claim 2 , and combinations thereof.4. The polymer of claim 1 , wherein the copolymer backbone is poly(isobutylene-co-p-methylstyrene) (IMSM).5. The polymer of claim 1 , wherein the one or more branches are covalently bound to the aromatic moiety via a ketone group.6. The polymer of claim 5 , wherein the polymer comprises the reaction product of:(a) a copolymer comprising units derived from an isoolefin having from 4 to 7 carbons and an alkylstyrene; and(b) an acyl halide and/or acid anhydride functionalized polycyclic aromatic hydrocarbon.7. A method comprising:(a) contacting (i) a copolymer comprising units derived from an isoolefin having from 4 to 7 carbons and an alkylstyrene and (ii) an acyl halide and/or acid anhydride functionalized polycyclic aromatic hydrocarbon in the presence of a catalyst at a temperature of about 80° C. to about 200° C.; and(b) recovering a polymer product.8. The method ...

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16-01-2020 дата публикации

FLUORINATED POLYACRYLATE ANTIFOAM COMPONENTS FOR LUBRICATING COMPOSITIONS

Номер: US20200017794A1
Принадлежит:

There is disclosed an antifoam component for a mechanical device which includes a fluorinated poly(acrylate) copolymer. The antifoam component has improved foam performance and thermal stability in finished fluids, such as driveline fluids. 1. A lubricating composition , comprising:a) an oil of lubricating viscosity selected from the group consisting of a Group III oil, a Group IV oil, a Group V oil, or mixtures thereof; andb) an antifoam component comprising a poly(acrylate) copolymer including:{'sub': 4', '8, '(i) from about 50 wt % up to about 90 wt % of an acrylate monomer having Cto Calkyl esters of acrylic acid;'}{'sub': 2', '3, '(ii) from about 10 wt % up to about 35 wt % of an acrylate comonomer having Cto Calkyl esters of acrylic acid; and'}(iii) from about 1.0 wt % up to 20 wt % of a fluorinated acrylate monomer;{'sub': 'w', 'the antifoam component having a Mof at least 45,000 Daltons.'}2. The lubricating composition of claim 1 , wherein the acrylate monomer (i) is present in an amount of about 54 wt % claim 1 , or 72 wt % claim 1 , and the acrylate comonomer (ii) is present in an amount of about 31 wt % or 23 wt %.3. The lubricating composition of claim 1 , wherein the acrylate monomer (i) comprises 2-ethylhexyl acrylate.4. The lubricating composition of claim 1 , wherein the comonomer (ii) comprises ethyl acrylate or propyl acrylate.5. The lubricating composition of claim 1 , wherein the acrylate monomer (i) is 2-ethylhexyl acrylate and the acrylate comonomer (ii) is ethyl acrylate.6. The lubricating composition of claim 1 , wherein the fluorinated acrylate comonomer is branched or linear.7. The lubricating composition of claim 1 , wherein the fluorinated acrylate monomer is selected from the group consisting of 2 claim 1 ,2 claim 1 ,2-trifluoroethyl acrylate claim 1 , 1 claim 1 ,1 claim 1 ,1 claim 1 ,3 claim 1 ,3 claim 1 ,-hexafluoroisopropyl acrylate claim 1 , octafluoropentylmethacrylate claim 1 , heptadecafluoroundecyl acrylate and tridecafluorooctyl ...

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17-01-2019 дата публикации

RESIST COMPOSITION, METHOD OF FORMING RESIST PATTERN, AND POLYMER COMPOUND

Номер: US20190018319A1
Принадлежит:

A resist composition which generates an acid when exposed and whose solubility in a developer is changed by an action of an acid, the resist composition including a polymer compound (A1) which has a constitutional unit (a0) derived from a compound represented by Formula (a0-1) and a constitutional unit (a10) derived from a compound represented by Formula (a10-1) and does not have a constitutional unit represented by Formula (1). In the formulas, Raand Rarepresent a polymerizable group-containing group; Waand Warepresent an (n+1)-valent or (n+1)-valent aromatic hydrocarbon group; nand nrepresent an integer of 1 to 3; and Zrepresents Fe, Co, Ni, Cr, or Ru. 7. The resist composition according to claim 1 , wherein a proportion of the constitutional unit (a0) in the polymer compound (A1) is in a range of 5% to 95% by mole with respect to the total amount (100% by mole) of all constitutional units constituting the polymer compound (A1).8. The resist composition according to claim 1 , wherein a proportion of the constitutional unit (a10) in the polymer compound (A1) is in a range of 5% to 95% by mole with respect to the total amount (100% by mole) of all constitutional units constituting the polymer compound (A1).9. A method of forming a resist pattern claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'forming a resist film on a support using the resist composition according to ;'}exposing the resist film; anddeveloping the exposed resist film to form a resist pattern.16. The polymer compound according to claim 10 , wherein a proportion of the constitutional unit (a0) in the polymer compound is in a range of 5% to 95% by mole with respect to the total amount (100% by mole) of all constitutional units constituting the polymer compound.17. The polymer compound according to claim 10 , wherein a proportion of the constitutional unit (a10) in the polymer compound is in a range of 5% to 95% by mole with respect to the total amount (100% by mole) of all ...

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16-01-2020 дата публикации

RESIN COMPOSITION, SEPARATOR OF SECONDARY BATTERY, AND SECONDARY BATTERY

Номер: US20200020909A1
Принадлежит:

The present invention provides a resin composition having excellent electrolyte solution retention ability. The resin composition contains an electrolyte composition containing a solvent and an electrolyte and a vinylidene fluoride copolymer. The vinylidene fluoride copolymer is a copolymer of vinylidene fluoride and a comonomer represented by Formula (1) below, wherein Rand Rare each independently a hydrogen atom or a fluorine atom, Ris a hydrogen atom, a fluorine atom, or an alkyl group having from 1 to 5 carbons, and Ris a basic group that is capable of forming an intermolecular hydrogen bond. 2. The resin composition according to claim 1 , wherein a content of a structural unit derived from the comonomer represented by the Formula (1) in the vinylidene fluoride copolymer is from 0.1 mol % to 1 mol % relative to a total monomer amount of 100 mol %.3. The resin composition according to claim 1 , wherein Rin the Formula (1) is a nitrogen atom-containing functional group.4. The resin composition according to claim 3 , wherein the nitrogen atom-containing functional group is an amino group or an amide group.5. (canceled)6. A separator for a secondary battery comprising a resin layer formed from the resin composition described in on a surface.7. A secondary battery comprising the separator described in . The present invention relates to a resin composition, a separator for a secondary battery, and a secondary battery. The present invention particularly relates to a resin composition used in a resin layer provided on a separator surface of a secondary battery, a separator for secondary batteries that uses the resin composition, and a secondary battery using the separator.Non-aqueous electrolyte secondary batteries have high energy density, and thus are used not only in the power source of portable devices but also in various applications such as hybrid electric vehicles and electric vehicles. In addition, as fields of application have been expanded, a non-aqueous ...

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24-01-2019 дата публикации

POLYOLEFIN ELASTOMER COMPOSITIONS AND METHODS OF MAKING THE SAME

Номер: US20190021441A1
Принадлежит: COOPER-STANDARD AUTOMOTIVE INC.

An elastomeric article is provided that includes a composition having a silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm. The elastomeric article can exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.). The silane-crosslinked polyolefin elastomer can include a first polyolefin having a density less than 0.86 g/cm, a second polyolefin having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, and a condensation catalyst. 1. A silane-crosslinked polyolefin elastomer blend comprising:{'sup': '3', 'a first polyolefin having a density less than 0.86 g/cm;'}a second polyolefin having a percent crystallinity less than 40%;a silane crosslinker,{'sup': '3', 'wherein the silane-crosslinked polyolefin elastomer blend exhibits a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.) and wherein the silane-crosslinked polyolefin elastomer blend has a density less than 0.90 g/cm.'}2. The silane-crosslinked polyolefin elastomer blend of further comprising a microencapsulated foaming agent.3. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the density is less than 0.70 g/cm.4. The silane-crosslinked polyolefin elastomer blend of further comprising a foaming agent.5. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the density is less than 0.60 g/cm.6. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the compression set is from about 15.0% to about 35.0% claim 1 , as measured according to ASTM D 395 (22 hrs @ 70° C.).7. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the first polyolefin comprises an ethylene-octene copolymer from about 60 wt % to about 97 wt %.8. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the second polyolefin comprises a polypropylene homopolymer from about 10 wt % to about 35 wt % and/or ...

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26-01-2017 дата публикации

Propylene-Based Impact Copolymers

Номер: US20170022308A1
Принадлежит:

A propylene-based impact copolymer (ICP) and composition including the ICP, the ICP comprising a polypropylene homopolymer and within the range of from 10 wt % to 45 wt % of propylene copolymer based on the weight of the ICP, wherein the copolymer comprises from 20 wt % to 44 wt % ethylene, 1-butene, 1-hexene and/or 1-octene derived units and from 80 to 60 wt % propylene-derived units based on the weight of the propylene copolymer, the propylene-based impact copolymer having a Melt Flow Rate (230° C./2.16 kg) within the range of from 10 g/10 mm to 50 g/10 mm and an Elongation at Break of greater than 70%. 1. A propylene-based impact copolymer (ICP) comprising a polypropylene homopolymer and within the range of from 10 wt % to 45 wt % of propylene copolymer based on the weight of the ICP , wherein the propylene copolymer comprises from 20 wt % to 44 wt % ethylene , 1-butene , 1-hexene and/or 1-octene derived units and from 80 to 56 wt % propylene-derived units based on the weight of the propylene copolymer , the propylene-based impact copolymer having a Melt Flow Rate (230° C./2.16 kg) within the range of from 10 g/10 mm to 50 g/10 mm and an Elongation at Break of greater than 60%.2. The propylene-based impact copolymer of claim 1 , wherein the polypropylene homopolymer forms a continuous phase and the propylene copolymer forms rubber domains having an average size within the range of from 0.40 μm to 0.90 μm.3. The propylene-based impact copolymer of claim 1 , wherein the impact copolymer is reactor grade granules having an average particle size within the range of from 1200 μm to 2800 μm and produced at a rate greater than 30 claim 1 ,000 lbs/hr (13 claim 1 ,620 kg/hr).4. The propylene-based impact copolymer of claim 1 , having a Gloss (60°) within a range of from 40 to 90% (ASTM D523).5. The propylene-based impact copolymer of claim 1 , having a Heat Deflection Temperature within the range of from 70° C. to 125° C.6. The propylene-based impact copolymer of claim 1 ...

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26-01-2017 дата публикации

LACTAMIC POLYMER CONTAINING AN ACETOACETATE MOIETY

Номер: US20170022313A1
Принадлежит: ISP Investments LLC

The invention provides lactamic polymers comprising an acetoacetate moiety. The lactamic polymers may be readily functionalized and the functionalized lactamic polymers may be further derivatized to provide a wide variety of useful polymers having desirable chemical and physical properties. The lactamic polymers of the invention may be employed in a wide variety of compositions. (A); (B) wherein R-R, w, x, y, z, and n are described herein. 2. The polymer according to claim 1 , wherein each Ris independently hydrogen or methyl.3. The polymer according to claim 1 , wherein each Ris —C(O)OCHCH—.4. (canceled)5. The polymer according to claim 1 , wherein each Ris independently selected from the group consisting of C-Cfunctionalized and unfunctionalized alkyl and alkenyl groups claim 1 , wherein any of the before mentioned groups may be with or without heteroatoms claim 1 , and mixtures thereof.6. The polymer according to claim 1 , wherein w ranges from 1-97% claim 1 , x ranges from 1-97% claim 1 , and y ranges from 1-97%.7. The polymer according to claim 1 , wherein each n is an integer independently ranging from 1-3.916-. (canceled)17. A composition comprising a lactamic polymer containing an acetoacetate moiety having the following structure:{'sub': 1', '1', '30', '3', '1', '6', '5', '1', '12, 'wherein each Ris independently selected from the group consisting of hydrogen and C-Cfunctionalized and unfunctionalized alkyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof; each Ris independently selected from the group consisting of hydrogen and C-Cfunctionalized and unfunctionalized alkyl, amide, carbonyl, and carboxyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof; each Ris independently selected from the group consisting of C-Cfunctionalized and unfunctionalized alkyl and alkenyl groups, wherein any of the before mentioned groups may be with or without ...

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25-01-2018 дата публикации

HYDROPHILIZING AGENT, COMPOSITION CONTAINING HYDROPHILIZING AGENT, AND POROUS POLYMER FILM

Номер: US20180022846A1
Принадлежит: DAIKIN INDUSTRIES, LTD.

The invention provides a hydrophilizing agent which is to be added to a polymer having a large contact angle to produce a porous polymer film that has a small contact angle and that can maintain this small contact angle even after 168-hour contact with an aqueous sodium hypochlorite solution. The hydrophilizing agent contains a fluoropolymer having a contact angle of 50° or smaller and a weight reduction rate of 7% or lower. 1. A hydrophilizing agent comprising a fluoropolymer having a contact angle of 50° or smaller and a weight reduction rate of 7% or lower.2. The hydrophilizing agent according to claim 1 ,wherein the fluoropolymer has a softening point of 70° C. to 200° C.3. The hydrophilizing agent according to claim 1 ,wherein the fluoropolymer is a copolymer of a fluoromonomer and an amide bond-containing polymerizable vinyl compound.4. The hydrophilizing agent according to claim 1 ,wherein the fluoropolymer has a fluorine content of 5 mass % or more.5. The hydrophilizing agent according to claim 1 , which is a hydrophilizing agent for a polymer other than the hydrophilizing agent.6. The hydrophilizing agent according to claim 1 , which is a hydrophilizing agent for a porous polymer film.7. A composition comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the hydrophilizing agent according to ; and'}a polymer other than the hydrophilizing agent.8. The composition according to claim 7 ,wherein the polymer is polyvinylidene fluoride or a copolymer containing a vinylidene fluoride unit.9. A porous polymer film comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the hydrophilizing agent according to ; and'}a polymer other than the hydrophilizing agent.10. The porous polymer film according to claim 9 ,wherein the polymer is polyvinylidene fluoride or a copolymer containing a vinylidene fluoride unit.11. The porous polymer film according to claim 9 , which has a contact angle of 55° or smaller.12. A hydrophilizing agent comprising a copolymer of ...

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26-01-2017 дата публикации

POLYMERIZABLE COMPOSITION CONTAINING REACTIVE FLUORINE-CONTAINING SILICONE COMPOUND

Номер: US20170023704A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

A polymerizable composition suitable for producing a molding that maintains a high refractive index and a low Abbe's number, discoloration (thermal yellowing) resulting from high thermal hysteresis can be reduced, no Tg and a low CTE are exhibited, and has good mold release properties. A polymerizable composition having: 100 parts by mass of a reactive silicone compound (a) obtained by polycondensation, in the presence of an acid or a base, of a polycondensable compound containing at least a diarylsilicic acid compound A, an alkoxy silicon compound B having a phenyl group or a naphthyl group having at least one group having a polymerizable double bond, and an alkoxy silicon compound C containing a fluoro group; and 1 part by mass to 200 parts by mass of a (meth) acrylate compound (b), and a cured product and material for high refractive index resin lens which are obtained from the polymerizable composition. 3. The polymerizable composition according to claim 2 , comprising at least two compounds claim 2 , the fluorene compound D and the polyfunctional (meth)acrylate compound F as the (meth)acrylate compound (b).4. The polymerizable composition according to claim 2 , comprising at least three compounds claim 2 , the fluorene compound D claim 2 , the bisphenol compound E claim 2 , and the polyfunctional (meth)acrylate compound F claim 2 , as the (meth)acrylate compound (b).6. The polymerizable composition according to claim 1 , further comprising 0.01 parts by mass to 5 parts by mass of at least one sulfur compound (d) selected from the group consisting of thiol compounds I and disulfide compounds J.9. The polymerizable composition according to claim 1 , wherein the polycondensation molar ratio of the alkoxy silicon compound B to the alkoxy silicon compound C is in a range of from 99.9:0.1 to 90:10.10. A cured product obtained by polymerizing the polymerizable composition as claimed in .11. An optical lens obtained by polymerizing the polymerizable composition as ...

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10-02-2022 дата публикации

BIARYL PHENOXY GROUP IV TRANSITION METAL CATALYSTS FOR OLEFIN POLYMERIZATION

Номер: US20220041764A1
Принадлежит: Dow Global Technologies LLC

Catalyst systems that include a metal-ligand complex according to formula (I): 2. The catalyst system of claim 1 , wherein each zis sulfur.3. The catalyst system of claim 1 , wherein each zis sulfur.4. The catalyst system of claim 1 , wherein each Y is oxygen.5. The catalyst system of further comprising one or more cocatalysts.6. The catalyst system of claim 1 , wherein each Ris a radical having formula (III) claim 1 , in which at least one of Ris chosen from (C-C)hydrocarbyl claim 1 , (C-C)heterohydrocarbyl claim 1 , —Si(R) claim 1 , —OR claim 1 , —SR claim 1 , —NO claim 1 , —CN claim 1 , —CF claim 1 , or halogen.7. The catalyst system of claim 1 , wherein each Ris a radical having formula (III) claim 1 , in which:{'sup': 42', '47', 'C', '43', '46, 'sub': 1', '20', '3', '3, '(1) Rand Rare independently chosen from (C-C)alkyl, —Si(R), —CF, or halogen and Rand Rare —H; or'}{'sup': 43', '46', 'C', '42', '47, 'sub': 1', '20', '3', '3, '(2) Rand Rare independently chosen from (C-C)alkyl, —Si(R), —CF, or halogen and Rand Rare —H.'}8. The catalyst system of claim 1 , wherein each Ris a radical having formula (IV) claim 1 , in which at least one of Ris chosen from (C-C)hydrocarbyl claim 1 , (C-C)heterohydrocarbyl claim 1 , —Si(R) claim 1 , —OR claim 1 , —SR claim 1 , —NO claim 1 , —CN claim 1 , —CF claim 1 , or halogen9. The catalyst system of claim 1 , wherein each Ris a radical having formula (IV) claim 1 , in which and Rare —H.10. The catalyst system of claim 1 , wherein when Q is (C-C)alkylene claim 1 , at least two of R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare selected from the group consisting of (C-C)aryl claim 1 , (C-C)heteroaryl claim 1 , —Si(R) claim 1 , —Ge(R) claim 1 , —P(R) claim 1 , —N(R) claim 1 , —OR claim 1 , —SR claim 1 , —NO claim 1 , —CN claim 1 , —CF claim 1 , RS(O)— claim 1 , —P(O)(R) claim 1 , RS(O)— claim 1 , (R)C═N— claim 1 , RC(O)O— claim 1 , ROC(O)— claim 1 , RC(O)N(R)— claim 1 , (R)NC(O)— claim 1 ...

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10-02-2022 дата публикации

HIGHLY FLEXIBLE VDF POLYMER

Номер: US20220041772A1
Автор: ABUSLEME Julio A.
Принадлежит:

The present invention pertains to vinylidene fluoride copolymers comprising recurring units derived from chlorotrifluoroethylene and from a (meth)acrylic monomer having improved flexibility, to a process for their manufacture, and to their use in applications where outstanding flexibility is required. 116-. (canceled)18. The polymer (A) according to claim 17 , having an intrinsic viscosity claim 17 , measured at 25° C. in N claim 17 ,N-dimethylformamide of at most 0.50 l/g.19. The polymer (A) according to claim 17 , having an intrinsic viscosity claim 17 , measured at 25° C. in N claim 17 ,N-dimethylformamide of at least 0.05 l/g.21. The polymer (A) according to claim 17 , wherein the amount of monomer (MA) is from 0.1% to 3% by weight claim 17 , with respect to the total weight of recurring units of polymer (A).22. The polymer (A) according to claim 17 , wherein comonomers (F) is selected from the group consisting of:{'sub': 2', '8, '(a) C-Cfluoro- and/or perfluoroolefins;'}{'sub': 2', '8, '(b) C-Chydrogenated monofluoroolefins;'}{'sub': 2', 'f0', 'f0', '1', '6, '(c) perfluoroalkylethylenes of formula CH═CH—R, wherein Ris a C-Cperfluoroalkyl group;'}{'sub': 2', 'f1', 'f1', '3', '2', '5', '3', '7', '4', '9', '5', '11, '(d) (per)fluoroalkylvinylethers of formula CF═CFORwherein Ris a perfluorinated alkyl group —CF(perfluoromethylvinylether (PMVE)), —CF(perfluoroethylvinylether (PEVE)), —CF(perfluoropropylvinylether (PPVE)), —CFor —CFgroup, and'}{'sub': 2', '6, '(e) chloro- and/or bromo- and/or iodo-C-Cfluoroolefins.'}23. The polymer (A) according to claim 17 , wherein comonomers (F) is HFP or PMVE.24. The polymer (A) according to claim 17 , which comprises:from 8 to 20% by weight of recurring units deriving from the CTFE monomer,from 0.4 to 1.5% by weight of recurring units deriving from hydrophilic (meth)acrylic monomer (MA) of formula (I),—from 0.7 to 2.0% by weight of recurring units deriving from comonomers (F),the percentages by weight being with respect to the ...

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10-02-2022 дата публикации

Preparation of a cured polymer comprising urethane groups and silicon atoms

Номер: US20220041815A1
Принадлежит: BASF SE

A process prepares a cross-linked polymer containing urethane groups and silicon atoms. Starting materials of the process include a compound A) with a five-membered cyclic monothiocarbonate group, a compound B) with an amino group, selected from primary or secondary amino groups or blocked amino groups, and optionally, a compound C) with at least one functional group that reacts with a group —SH. One of the compounds contains a silicon-functional group. In one example of the process, compounds A) and B), and optionally C), are then reacted under exclusion of water to obtain a polymer with curable silicon-functional groups. The polymer is applied to a surface, gap, or a three-dimensional template. The silicon-functional groups are cured with ambient water. The polymer contains 0.001 to 0.3 mol of silicon per 100 g of the polymer.

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10-02-2022 дата публикации

POWDER ADHESIVE AND BONDED ARTICLE

Номер: US20220041906A1
Принадлежит:

The powder adhesive comprises a thermoplastic resin and particles of an aromatic compound, wherein the particles of an aromatic compound are particles of a compound that has an aromatic ring and an azo bond bonded to the aromatic ring, or are particles of a compound comprising a heteroaromatic ring comprising nitrogen atom; the thermoplastic resin comprises an ester group; and, designating Es (mmol/g) as an ester group concentration in the thermoplastic resin, M (mass %) as a content of the aromatic compound particles in the powder adhesive, and N (mmol/g) as a nitrogen atom concentration in the aromatic compound particles, Es is from 1.0 mmol/g to 4.5 mmol/g, M is from 1.0×10mass % to 1.0×10mass %, and N is from 5.0 mmol/g to 15.0 mmol/g. 2. The powder adhesive according to claim 1 , wherein Es claim 1 , M claim 1 , and D satisfy formula (1) below where D (nm) is a number-average particle diameter of the particle:{'br': None, 'sup': 3', '4, 'i': ≤Es', 'D/M, '1.0×10×()≤3.0×10\u2003\u2003(1).'}3. The powder adhesive according to claim 1 , wherein D is 30 to 200 nm where D (nm) is a number-average particle diameter of the particle.4. The powder adhesive according to claim 1 , wherein the aromatic compound is the compound comprising the aromatic ring and the azo bond bonded to the aromatic ring.6. The powder adhesive according to claim 5 , wherein the compound comprising the structure represented by the formula (4) is a pigment.7. The powder adhesive according to claim 1 , wherein the thermoplastic resin comprises a copolymer of monomers comprisinga styrenic polymerizable monomer, andat least one selected from the group consisting of acrylate esters and methacrylate esters.8. The powder adhesive according to claim 7 , wherein a content of the copolymer in the thermoplastic resin is 70 to 100 mass %.9. The powder adhesive according to claim 1 , wherein the aromatic compound is at least one selected from the group consisting of C. I. Pigment Yellow 74 claim 1 , C. I. ...

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10-02-2022 дата публикации

One-component sealant or adhesive composition

Номер: US20220041907A1
Принадлежит: BASF SE

A process prepares a prepolymer containing a urethane group and a curable silicon-functional group, or a prepolymer of formula (IV), 1: A process for preparing a prepolymer comprising a urethane group and a curable silicon-functional group , the process comprising:reacting a compound A) with a compound B), and optionally a compound C), under exclusion of water, to obtain the prepolymer comprising the urethane group and the curable silicon-functional group,wherein the compound A) comprises at least one five-membered cyclic monothiocarbonate group, andwherein the compound B) comprises at least one amino group, selected from the group consisting of primary amino groups, secondary amino groups, blocked primary amino groups, and blocked secondary amino groups, andwherein the compound C), if present, comprises at least one functional group that reacts with a group —SH,wherein at least one of the compounds A), B), and optionally C) comprises a silicon-functional group.3: The process according to claim 1 , wherein the compound B) comprises one to five amino groups.4: The process according to claim 1 , wherein the at least one functional group of compound C) that reacts with —SH is a non-aromatic claim 1 , ethylenically unsaturated group.5: The process according to claim 1 , wherein the compound B) or compound C) claim 1 , if present claim 1 , comprises the silicon-functional group.6: The process according to claim 1 , wherein the silicon-functional group is an alkoxysilane group of formula (III) claim 1 ,{'br': None, 'sup': 1s', '2s', '3s, '—SiRRR'}{'sup': 1s', '3s', '1s', '3s, 'wherein two or three of the groups Rto Rare an alkoxy group, and the remaining group Rto Ris an alkyl or alkylene-vinyl group.'}7: The process according to claim 1 , wherein at least one of the compounds A) claim 1 , B) claim 1 , or optionally C) comprises a segment selected from the group consisting of a polyether group and an organic polysulfide group.8: The process according to claim 1 , wherein ...

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10-02-2022 дата публикации

PLATED STEEL PLATE HAVING EXCELLENT GLOSSINESS AND SURFACE PROPERTY, AND METHOD FOR MANUFACTURING SAME

Номер: US20220042163A1
Принадлежит:

Provided is a plated steel plate used for interior materials and exterior materials such as home appliances, construction materials, vehicles, etc., and a method for manufacturing same. The plated sheet plate includes: base steel; a Zn—Mg plating layer formed on the base steel; and a UV-curable film layer formed on the Zn—Mg plating layer, wherein a hairline pattern is formed on a surface of the Zn—Mg plating layer, and the Zn—Mg plating layer includes 8 to 27 weight % of Mg and a balance of Zn and inevitable impurities. 1. A plated sheet plate having excellent glossiness and surface characteristics , the plated steel sheet including:base steel;a Zn—Mg plating layer formed on the base steel; anda UV-curable film layer formed on the Zn—Mg plating layer,wherein a hairline pattern is formed on a surface of the Zn—Mg plating layer, and the Zn—Mg plating layer includes 8 to 27 weight % of Mg and a balance of Zn and inevitable impurities.2. The plated steel sheet of claim 1 , wherein the UV-curable film layer is transparent.3. The plated steel sheet of claim 1 , wherein the Zn—Mg plating layer has a double-layer structure including a Zn layer on the base steel and a Zn—Mg layer on the Zn layer.4. The plated steel sheet of claim 1 , wherein the UV-curable film layer has a thickness of 0.8 to 1.2 μm.5. The plated steel sheet of claim 1 , wherein glossiness of the plated steel sheet has a relative value of 60 to 120 when reflectivity of glass is 100 during measurement of the glossiness using a glossmeter at a measurement angle of 60 degree.6. A method of manufacturing a plated steel sheet having excellent glossiness and surface characteristics claim 1 , the method comprising:preparing base steel;forming a Zn—Mg plating layer on the base steel by vacuum deposition, the Zn—Mg plating layer including 8 to 27 weight % of Mg and a balance of Zn and inevitable impurities;forming a hairline pattern on a surface of the Zn—Mg plating layer;coating a UV-curable paint on the Zn—Mg ...

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24-01-2019 дата публикации

MODIFIER, METHOD OF PREPARING THE SAME, AND MODIFIED CONJUGATED DIENE-BASED POLYMER INCLUDING THE SAME

Номер: US20190023725A1
Принадлежит: LG CHEM, LTD.

The present invention relates to a modifier, and more particularly, to a modifier including a compound represented by Formula 1, a method of preparing the same, and a modified conjugated diene-based polymer including the same. 2. The modifier of claim 1 , wherein claim 1 , in Formula 1 claim 1 , Ris a substituted or unsubstituted C-Calkyl group claim 1 , a substituted or unsubstituted C-Calkenyl group claim 1 , a substituted or unsubstituted C-Calkynyl group claim 1 , a substituted or unsubstituted C-Cheteroalkyl group claim 1 , a substituted or unsubstituted C-Ccycloalkyl group claim 1 , a substituted or unsubstituted C-Caryl group claim 1 , or a substituted or unsubstituted C-Cheterocyclic group claim 1 ,{'sup': '2', 'Ris the functional group of Formula 1a,'}{'sup': '3', 'Ris the functional group of Formula 1b,'}{'sup': '1', 'sub': 1', '30', '1', '30', '2', '30', '2', '30', '1', '30', '1', '30', '5', '30', '6', '30', '3', '30, 'wherein, when Ris the substituted alkyl group, the substituted alkenyl group, the substituted alkynyl group, the substituted heteroalkyl group, the substituted cycloalkyl group, the substituted aryl group, or the substituted heterocyclic group, a substituent of the substituted alkyl group, the substituted alkenyl group, the substituted alkynyl group, the substituted heteroalkyl group, the substituted cycloalkyl group, the substituted aryl group, or the substituted heterocyclic group comprises one or more selected from the group consisting of deuterium, a halogen, a hydroxyl group, a nitro group, a cyano group, a C-Calkyl group, a C-Calkylsilyl group, a C-Calkenyl group, a C-Calkynyl group, a C-Calkoxy group, a substituted or unsubstituted C-Cheteroalkyl group, a C-Ccycloalkyl group, a C-Caryl group, and a C-Cheterocyclic group, and'}X is one heteroatom selected from the group consisting of N, O, and S,{'sup': 2', '3, 'wherein, when X is O or S, only one of the Rand Rfunctional groups is present, and, in Formulae 1a and 1b,'}{'sup': 4', '7, ...

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24-01-2019 дата публикации

PARTICULATE POLYVINYL ALCOHOL, PROCESS FOR MAKING AND USES OF THE SAME

Номер: US20190023825A1
Принадлежит: KURARAY CO., LTD.

The present invention relates generally to a polyvinyl alcohol composition having higher amorphous polyvinyl alcohol polymer content and various end uses thereof. 1. A polyvinyl alcohol composition of particulate agglomerated polyvinyl alcohol particles , wherein:(1) the polyvinyl alcohol is a hydrolyzed polymer of a monomer component consisting essentially of vinyl acetate and, optionally, up to about 10 mol % of one or more acrylate monomers, with a degree polymerization of from about 400 to about 10000, and a degree of hydrolysis of about 93% or greater; and(2) the composition has a D(90) particle size of from about 1 μm to about 1000 μm, a bulk density of about 50 g/cm3 or greater, and a % warm-water (35° C.) solubles of about 5% or greater.2. The polyvinyl alcohol composition of claim 1 , wherein the polyvinyl alcohol composition is produced in a slurry alcoholysis process with a heat treatment step claim 1 , and the polyvinyl alcohol is produced at 50° C. or less in the heat treatment step and has a crystallinity reduced by about 2% to about 20% as compared to a polyvinyl alcohol produced under the same conditions except at 135° C. in the heat treatment step.3. The polyvinyl alcohol composition of claim 2 , wherein the polyvinyl alcohol is produced at 50° C. or less in the heat treatment step and has a crystallinity reduced by about 2% to about 20% as compared to a polyvinyl alcohol produced under the same conditions except at 110° C. in the heat treatment step.4. A composition comprising a solution of the polyvinyl alcohol composition of substantially dissolved in water.5. A paper inner sizing composition or a paper coating composition comprising the composition of . This application is a divisional application of prior U.S. application Ser. No. 15/440,718, filed Feb. 23, 2017, the disclosures of which are incorporated by reference herein for all purposes as if fully set forth. U.S. Ser. No. 15/440,718 claims priority under 35 U.S.C. § 119 from U.S. ...

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24-01-2019 дата публикации

Compositions of Isobutylene, Styrene and Styrene with Graft-On Pendant Double Bonds

Номер: US20190023827A1
Принадлежит:

A composition and methods for making the same. The composition includes an isoolefin having from 4 to 7 carbons, a first styrene, and a second styrene alkylated with a diene to have a pendant double bond. A copolymer having units derived from an isoolefin having from 4 to 7 carbons and an alkylstyrene can be reacted with a diene to provide the composition. The reaction of the copolymer with the diene can be reacted in the presence of a catalyst at a temperature of about 80° C. to about 200° C. 1. A composition comprising:an isoolefin having from 4 to 7 carbons;a first styrene; anda second styrene alkylated with a diene to have a pendant double bond.2. A composition comprising the reaction product of:a copolymer of an isoolefin having from 4 to 7 carbons and a first styrene; anda diene.3. A polymer comprising:a copolymer of an isoolefin having from 4 to 7 carbons and a first styrene grafted to a diene.4. The composition of claim 1 , wherein the diene is conjugated.5. The composition of claim 1 , wherein the diene is 2-methyl-1 claim 1 ,3-butadiene (isoprene) claim 1 , 1 claim 1 ,3-butadiene claim 1 , 1 claim 1 ,3-pentadiene (piperylene) claim 1 , or a combination thereof.6. The composition of claim 1 , wherein the diene is unconjugated and cyclic.7. The composition of claim 6 , wherein the diene is ethylidene norbornene claim 6 , vinyl norbornene claim 6 , dicyclopentadiene claim 6 , norbornadiene claim 6 , 1 claim 6 ,5 cyclooctadiene claim 6 , or a combination thereof.8. The composition of claim 1 , wherein the diene is unconjugated and non-cyclic.9. The composition of claim 8 , wherein the diene is 1 claim 8 ,4 hexadiene claim 8 , 1 claim 8 ,6 octadiene claim 8 , 1 claim 8 ,8 decadiene claim 8 , or a combination thereof.10. The composition of claim 1 , wherein the double bond is at one carbon away from the terminal carbon of the pendant double bond.11. The composition of claim 1 , wherein the first styrene is 0.5 mole % to 40 mole % of the composition based on the ...

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24-01-2019 дата публикации

GRAFT COPOLYMER AND ACRYLIC RESIN COMPOSITION CONTAINING SAME

Номер: US20190023828A1
Принадлежит: KANEKA CORPORATION

A graft copolymer includes: an inner layer made of a hard polymer (I) obtained by polymerizing a monomer mixture including 40 to 100 wt % of a methacrylate ester 0 to 15 wt % of an aromatic vinyl monomer, and 0 to 45 wt % of another copolymerizable monomer and 0.01 to 10 parts by weight of a polyfunctional monomer; an intermediate layer made of a soft polymer (II) obtained by polymerizing a monomer mixture including 60 to 100 wt % of an acrylate ester and 0 to 40 wt % of another copolymerizable monomer, 0.01 to 5 parts by weight of allyl (meth)acrylate, and a di(meth)acrylic compound; and an outer layer made of a hard polymer (III) obtained by polymerizing a monomer mixture including 40 to 100 wt % of a methacrylate ester and 60 to 0 wt % of another copolymerizable monomer and 0 to 10 parts by weight of a polyfunctional monomer. 2. The graft copolymer according to claim 1 , wherein the polymer obtained through polymerization up to the intermediate layer has an average particle diameter of 90 to 150 nm claim 1 ,3. The graft copolymer according to claim 1 , wherein the graft copolymer comprises 5 to 15 wt % of the inner layer claim 1 , 55 to 75 wt % of the intermediate layer claim 1 , and 20 to 30 wt % of the outer layer.4. The graft copolymer according to claim 1 , wherein the monomer mixture (a) comprises 40 to 99.9 wt % of the methacrylate ester claim 1 , 0.1 to 35 wt % of an acrylate ester claim 1 , 0 to 15 wt % of the aromatic vinyl monomer claim 1 , and 0 to 10 wt % of the another monomer having a copolymerizable double bond.5. The graft copolymer according to claim 1 , wherein the graft polymer has a 1% weight loss temperature of 260° C. or higher as measured by thermogravimetric analysis (TGA) and a 5% weight loss temperature of 310° C. or higher as measured by TGA.6. A resin composition comprising the graft copolymer according to and an acrylic resin.7. The resin composition according to claim 6 , comprising 60 to 2 wt % of the graft copolymer and 40 to 98 wt ...

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24-01-2019 дата публикации

THERMOPLASTIC COMPOSITIONS CONTAINING ACRYLIC COPOLYMERS AS MELT STRENGTH AND CLARITY PROCESS AIDS

Номер: US20190023889A1
Автор: PETR Michael T.
Принадлежит:

Provided are thermoplastic polymer composition comprising (a) a polyvinyl halide, and (b) an acrylic copolymer comprising 70 to 100 weight % of a first polymeric stage, based on the total weight of the acrylic copolymer, comprising polymerized units derived from at least 85 weight % of one or more C-Calkyl methacrylate monomers and C-Calkyl acrylate monomers, based on the total weight of monomers in the first polymeric stage, wherein the first polymeric stage has a calculated Tof 70° C. or less, and wherein the acrylic copolymer has a molecular weight of greater than 1.5×10g/mol. 1. A thermoplastic polymer composition comprising:(a) a polyvinyl halide; and{'sub': 1', '6', '1', '3', 'g, 'sup': '6', '(b) an acrylic copolymer comprising 70 to 100 weight % of a first polymeric stage, based on the total weight of the acrylic copolymer, comprising polymerized units derived from at least 85 weight % of one or more C-Calkyl methacrylate monomers and C-Calkyl acrylate monomers, based on the total weight of monomers in the first polymeric stage, wherein the first polymeric stage has a calculated Tof 70° C. or less, and wherein the acrylic copolymer has a molecular weight of 1.5×10g/mol or more.'}2. The thermoplastic polymer composition of claim 1 , wherein the first polymeric stage comprises (i) 35 to 75 weight % of methyl methacrylate monomers claim 1 , and (ii) 25 to 65 weight % of one or more C-Calkyl methacrylate monomers and C-Calkyl acrylate monomers claim 1 , based on the total weight of monomers in the first polymeric stage.3. The thermoplastic polymer composition of claim 2 , wherein the C-Calkyl methacrylate monomers and C-Calkyl acrylate monomers of the first polymeric stage comprise one or more of butyl methacrylate and ethyl acrylate.4. The thermoplastic polymer composition of claim 1 , wherein the acrylic copolymer further comprises a second polymeric stage comprising polymerized units derived from one or more C-Calkyl (meth)acrylate monomers.5. The ...

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24-01-2019 дата публикации

METHOD OF PREPARING ABS-BASED GRAFT COPOLYMER HAVING IMPROVED IMPACT STRENGTH AND METHOD OF MANUFACTURING ABS-BASED INJECTION-MOLDED ARTICLE INCLUDING THE SAME

Номер: US20190023894A1
Принадлежит:

The present invention relates to a method of preparing an ABS-based graft copolymer having improved impact strength and an ABS-based injection-molded article including the same. More particularly, the present invention provides an ABS-based copolymer resin having improved impact strength by optimizing structures of large-diameter diene-based rubber latex particles and a matrix structure between ABS-based copolymer particles and a SAN resin through introduction of a multimeric acid of an unsaturated fatty acid or a metal salt thereof as an emulsifier in a large-diameter diene-based rubber latex polymerization step and an ABS graft polymerization step. 1. A method of preparing an ABS-based graft copolymer having improved impact strength , the method comprising:a) a step of polymerizing 100 parts by weight of a conjugated diene-based monomer, 0.5 to 5 parts by weight of an emulsifier, and 0.01 to 6 parts by weight of a water-soluble polymerization initiator; b) a step of adding 0.01 to 5 parts by weight of an emulsifier thereto when a polymerization conversion rate is 60 to 85%, after step a); c) a step of terminating polymerization when a polymerization conversion rate is 90 to 99% to obtain a large-diameter diene-based rubber latex; and d) a step of graft-polymerizing 100 parts by weight of a monomer mixture comprising 40 to 70% by weight (based on solids) of the large-diameter diene-based rubber latex, 15 to 35% by weight of an aromatic vinyl monomer, and 5 to 25% by weight of a vinyl cyan monomer with 0.01 to 3 parts by weight of an emulsifier, 0.01 to 3 parts by weight of an initiator, and 0.001 to 1 part by weight of an oxidation-reduction catalyst,wherein the emulsifiers of steps a) and d) are a multimeric acid of an unsaturated fatty acid or a metal salt thereof.2. The method according to claim 1 , wherein the unsaturated fatty acid is a straight-chain claim 1 , branched-chain claim 1 , or cyclic unsaturated fatty acid having 8 to 22 carbon atoms.3. The method ...

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24-01-2019 дата публикации

POLY(METH)ACRYLAMIDE-BASED COPOLYMERS WITH CARBOXYL-TERMINATED PENDANT CHAINS

Номер: US20190023935A1
Принадлежит:

The invention is related to a class of hydrophilic poly(meth)acrylamide-based copolymers each comprising dangling (i.e., pendant) reactive chains each terminated with a carboxyl group groups and at least 50% by mole of (meth)acrylamide repeating units relative to all repeating units of the hydrophilic poly(meth)acrylamide-based copolymer. The hydrophilic copolymers have a relatively high affinity to a base coating of a polyanionic polymer on a medical device or contact lens and are highly reactive towards azetidinium groups of an azetidinium-containing polymer upon heating. They can find particular use in producing water-soluble highly-branched hydrophilic polymeric material and in producing water gradient contact lenses. 2. The hydrophilic polymer of claim 1 , wherein the poly(meth)acrylamide-based copolymer comprises at least about 50% by mole of the first repeating units and from about 0.01% to about 40% by mole by mole of the second repeating units claim 1 , relative to all repeating units of the poly(meth)acrylamide-based copolymer.3. The hydrophilic polymer of claim 2 , wherein the second repeating units comprises acrylic repeating units each of which is a repeating unit of formula (1).4. The hydrophilic polymer of claim 2 , wherein the second repeating units comprises acrylic repeating units each of which is a repeating unit of formula (2).5. The hydrophilic polymer of claim 2 , wherein the second repeating units comprises acrylic repeating units each of which is a repeating unit of formula (3).6. The hydrophilic polymer of claim 2 , wherein the second repeating units comprises acrylic repeating units each of which is a repeating unit of formula (4).7. The hydrophilic polymer of claim 2 , wherein the second repeating units comprises acrylic repeating units each of which is a repeating unit of formula (5).8. The hydrophilic polymer of claim 7 , wherein claim 7 , in formula (1) to (5) claim 7 , Xis —NR— in which Ris hydrogen or a C-Calkyl group.9. The ...

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23-01-2020 дата публикации

PREPARATION OF BIMODAL RUBBER, THERMOPLASTIC VULCANIZATES, AND ARTICLES MADE THEREFROM

Номер: US20200024436A1
Принадлежит:

Pellet-stable olefinic copolymer bimodal rubber is made using parallel reactors, with one reactor synthesizing higher molecular weight (MW) rubber with dual catalysts, with an improved molecular weight split ratio and an improved composition distribution of the moderate and ultra-high MW components, while another reactor synthesizes random isotactic polypropylene copolymer (RCP). The effluents are reactor-blended and result in pellet-stable bimodal rubber (P-SBR), which may be pelletized. When making thermoplastic vulcanizates (TPVs) with P-SBR, the need to granulate rubber bales and subsequently use talc, clay, or other anti-agglomeration agents to prevent granulated rubber crumbs from agglomerating are eliminated. TPVs made with P-SBR have vulcanized rubber particles that are smaller and more uniform in size, resulting in TPVs with higher particle counts and more thermoplastic “ligaments” between the particles, with such ligaments being made stronger by the added RCP. Such thus-produced TPVs have a lower hysteresis and flexural modulus, and better elastic properties. 1. A method of preparing a pellet-stable olefinic copolymer bimodal rubber , comprising:producing a high molecular weight olefinic copolymer rubber characterized by a bimodal molecular weight and a bimodal composition distribution (“bimodal rubber”) within a first reactor;concurrently producing isotactic polypropylene random copolymer (RCP) within a second reactor, wherein the first and second reactors are operated in parallel to each other;obtaining an effluent from the first reactor;obtaining an effluent from the second reactor;reactor-blending the effluents in situ to thereby produce a pellet-stable RCP-containing bimodal rubber (“pellet-stable bimodal rubber”), wherein about 80-97.5 wt % of the bimodal rubber is blended with about 2.5-20 wt % of the RCP, and optionally pelletizing the pellet-stable rubber.3. The method of claim 2 , wherein the catalyst compound further comprises one or more of:{' ...

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28-01-2021 дата публикации

FLUORORESIN MATERIAL, FLUORORESIN MATERIAL FOR HIGH FREQUENCY TRANSMISSION, AND COVERED ELECTRIC WIRE FOR HIGH-FREQUENCY TRANSMISSION

Номер: US20210024769A1
Принадлежит: DAIKIN INDUSTRIES, LTD.

A fluororesin material including a melt-fabricable fluororesin, the fluororesin material having a dielectric constant of 2.1 or less and a dielectric loss tangent of 0.00030 or less at 12 GHz. Also disclosed is a fluororesin material for high-frequency transmission including the fluororesin material and a coated electric wire for high-frequency transmission including a solid insulating coating layer made of the fluororesin material. 1. A fluororesin material comprising a melt-fabricable fluororesin and having a dielectric constant of 2.1 or less and a dielectric loss tangent of 0.00030 or less at 12 GHz ,wherein the number of functional groups per 106 main-chain carbon atoms of the fluororesin is 6 or less, andwherein the fluororesin is at least one copolymer selected from the group consisting of a tetrafluoroethylene/(per)fluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer.2. (canceled)3. (canceled)4. A fluororesin material for high-frequency transmission comprising the fluororesin material according to .5. A coated electric wire for high-frequency transmission comprising the fluororesin material according to as an insulating coating layer claim 1 , wherein the insulating coating layer is a solid insulating coating layer. The present disclosure relates to a fluororesin material, a fluororesin material for high-frequency transmission, and a coated electric wire for high-frequency transmission.The development of means of communication utilizing radio waves is remarkable. Along with an increase in the volume of information to be transmitted, radio waves in a high-frequency range have tended to be increasingly used. For example, 3 to 30 GHz microwaves are used for high-frequency wireless LANs, satellite communication, cellular phone base stations, and the like.As bulk materials for materials used for communication devices that utilize such high frequencies, the development of materials having electrical properties such as a ...

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28-01-2021 дата публикации

COPOLYMER AND ANTIFOULING COATING COMPOSITION CONTAINING THE SAME

Номер: US20210024770A1
Принадлежит: Nippon Paint Marine Coatings Co., Ltd.

Provided are a copolymer containing: a structural unit (A) derived from a polymerizable monomer (a) having a silicon atom-containing group represented by formula (1) [wherein R, R, and Reach independently represent a hydrocarbon group having a carbon number of 1 to 6]; and a structural unit (B) derived from a polymerizable monomer (b) copolymerizable with the polymerizable monomer (a) with the content of the structural unit (A) being from 40 mass % to 80 mass % in 100 mass % of the copolymer, the content of the structural unit (B) being from 20 mass % to 60 mass % in 100 mass % of the copolymer, and an acid value derived from free carboxy group being from 0.1 KOHmg/g to 60 KOHmg/g.; and an antifouling coating composition containing the copolymer. 2. The vehicle resin according to claim 1 , wherein the acid value is greater than or equal to 0.1 KOHmg/g and less than or equal to 30 KOHmg/g.3. The vehicle resin according to claim 1 , wherein the acid value is greater than or equal to 0.3 KOHmg/g and less than or equal to 20 KOHmg/g.4. The vehicle resin according to claim 1 , wherein the structural unit (B) includes a structural unit derived from (meth)acrylic acid claim 1 , anda content of the structural unit derived from (meth)acrylic acid is greater than or equal to 0.02 mass % and less than or equal to 8 mass % in 100 mass % of the copolymer.6. The vehicle resin according to claim 4 , wherein the content of the structural unit derived from (meth)acrylic acid is greater than or equal to 0.02 mass % and less than or equal to 5 mass % in 100 mass % of the copolymer.7. The vehicle resincopolymcr according to claim 4 , wherein the content of the structural unit derived from (meth)acrylic acid is greater than or equal to 0.05 mass % and less than or equal to 2.5 mass % in 100 mass % of the copolymer.9. (canceled)10. An antifouling coating composition comprising the vehicle resin according to .11. The antifouling coating composition according to claim 10 , further ...

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10-02-2022 дата публикации

SOLID ELECTROLYTE FOR ORGANIC BATTERIES

Номер: US20220045361A1
Принадлежит: EVONIK OPERATIONS GMBH

A process can be used to produce a charge storage unit, especially a secondary battery, the electrodes of which contain an organic redox-active polymer, and which includes a polymeric solid electrolyte. The solid electrolyte is obtained by polymerizing from mixtures of acrylates with methacrylates in the presence of at least one ionic liquid, which imparts advantageous properties to the charge storage unit. 2: The process according to claim 1 , wherein claim 1 , in (a) claim 1 , a molar ratio of all compounds of formula (I) included in the mixture M to all compounds of the formula (II) included in the mixture M is in the range of 99:1 to 1:99.4: The process according to claim 1 , wherein a total molar amount of all ionic liquids IL included in the mixture M in (a) claim 1 , based on a total molar amount of all compounds of the formulae (I) and (II) included in the mixture M claim 1 , is ≥0.1 molar equivalent.5: The process according to claim 1 , wherein (a) is conducted on a surface of at least one of the electrodes Eand E.11: The process according to claim 1 , wherein the conductivity additive L is selected from the group consisting of carbon materials claim 1 , electrically conductive polymers claim 1 , metals claim 1 , semimetals claim 1 , metal compounds claim 1 , and semimetal compounds.12: A charge storage unit obtainable by the process according to .14: The charge storage unit according to claim 13 , wherein a molar ratio of all compounds of formula (I) included in the mixture M to all compounds of the formula (II) included in the mixture M is in the range of 99:1 to 1:99.16: The charge storage unit according to claim 13 , wherein a total molar amount of all ionic liquids IL included in the mixture M claim 13 , based on g total molar amount of all compounds of the formulae (I) and (II) included in the mixture M claim 13 , is ≥0.1 molar equivalents.22: The charge storage unit according to claim 13 , wherein the conductivity additive L is selected from the ...

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28-01-2021 дата публикации

CONDUCTIVE RESIN COMPOSITION AND CONDUCTIVE STRUCTURE USING SAME

Номер: US20210027909A1

A conductive composition is provided and at least includes an acrylic resin and a conductive powder, wherein the acrylic resin at least contains a polymer unit (A) of a (meth)acrylate having an epoxy group and a polymer unit (B) of a (meth)acrylate having an isobornyl group, and an amount of the polymer unit (B) is 5.0 parts by mass or more and 50.0 parts by mass or less based on 100 parts by mass of the acrylic resin. 1. A conductive composition at least comprising an acrylic resin and a conductive powder ,wherein the acrylic resin contains a polymer unit (A) of a (meth)acrylate having an epoxy group and a polymer unit (B) of a (meth)acrylate having an isobornyl group, andan amount of the polymer unit (B) is 5.0 parts by mass or more and 50.0 parts by mass or less based on 100 parts by mass of the acrylic resin.2. The conductive composition according to claim 1 , wherein an epoxy equivalent of the polymer unit (A) based on a total amount of the acrylic resin is in a range of 400 to 10 claim 1 ,000 g/eq.3. The conductive composition according to claim 1 , wherein the acrylic resin further contains a polymer unit (C) of a (meth)acrylate having a nitrile group.4. The conductive composition according to claim 1 , comprising 5.0 parts by mass or more and 30.0 parts by mass or less of the polymer unit (C) based on 100 parts by mass of the acrylic resin.5. The conductive composition according to claim 1 , further comprising a curing agent (D).6. The conductive composition according to claim 1 , further comprising a curing accelerator (E).7. The conductive composition according to claim 1 , further comprising a dispersant (F).8. The conductive composition according to claim 1 , further comprising a non-conductive powder (G).9. The conductive composition according to claim 1 , wherein a mass ratio of the acrylic resin to the conductive powder is in a range of 30:70 to 5:95.10. A conductive structure comprising the conductive composition according to . The present invention ...

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02-02-2017 дата публикации

SILYL BIS(HEXAMETHYLINDENYL) COMPLEXES OF GROUP IVA METALS AS POLYMERIZATION CATALYSTS

Номер: US20170029537A1
Принадлежит:

Novel Si-bridged metallocene catalysts of formula I defined herein are disclosed, as well as their use in olefin polymerisation reactions. 2. The compound according to claim 1 , wherein R claim 1 , R claim 1 , Rand Rare each independently (1-2C)alkyl.3. The compound according to claim 1 , wherein R claim 1 , R claim 1 , Rand Rare all methyl.4. The compound according to claim 1 , wherein X is zirconium or hafnium.5. The compound according to claim 1 , wherein Rand Rare each independently (1-6C)alkyl or (2-6C)alkenyl.6. The compound according to claim 1 , wherein Rand Rare each independently (1-4C)alkyl.7. The compound according to claim 1 , wherein each Y is independently halo or (1-2C)alkyl group which is optionally substituted with halo claim 1 , phenyl claim 1 , or Si[(1-4C)alkyl].8. The compound according to claim 1 , wherein Y is halo.9. The compound according to claim 8 , wherein Rand Rare each independently selected from the group consisting of methyl claim 8 , propyl and allyl.10. The compound according to claim 9 , wherein X is zirconium.1314-. (canceled)15. A composition comprising a compound of formula I as defined in claim 1 , and a suitable activator.16. The composition of claim 15 , wherein the suitable activator is solid MAO and the compound of formula I is supported thereon.17. A process for forming a polyethylene which comprises reacting olefin monomers in the presence of (i) a compound of formula I as defined in claim 1 , and (ii) a suitable activator.18. The process according to claim 17 , wherein the activator comprises an aluminoxane claim 17 , tri(isobutyl)aluminium (TIBA) or triethylaluminium (TEA).19. The process according to claim 17 , wherein the activator is provided as an activated support.20. The process according to claim 19 , wherein the compound of formula I is supported on the activated support.21. The process according to claim 19 , wherein the activated support is methylaluminoxane activated silica or methylaluminoxane activated AMO ...

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31-01-2019 дата публикации

SHOE SOLES, COMPOSITIONS, AND METHODS OF MAKING THE SAME

Номер: US20190029361A1
Принадлежит: COOPER-STANDARD AUTOMOTIVE INC.

A shoe sole composition and method for making a shoe sole are provided. The shoe sole includes a composition comprising a foamed silane-crosslinked polyolefin elastomer having a density less than 0.50 g/cm. The shoe sole exhibits a compression set of from about 5.0% to about 20.0%, as measured according to ASTM D 395 (6 hrs @ 50° C.). The foamed silane-crosslinked polyolefin elastomer can be produced from a blend including a first polyolefin having a density less than 0.86 g/cm, a second polyolefin, having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, a condensation catalyst, and a foaming agent. 1. A shoe midsole comprising:{'sup': '3', 'claim-text': [{'sup': '3', 'a first polyolefin having a density less than 0.86 g/cm,'}, 'a second polyolefin having a crystallinity less than 40%,', 'a silane crosslinker,', 'a grafting initiator,', 'a condensation catalyst, and', 'a foaming agent,, 'a foamed silane-crosslinked polyolefin elastomer having a density less than 0.50 g/cm, the foamed silane-crosslinked polyolefin elastomer comprisingwherein the shoe midsole exhibits a compression set of from about 1.0% to about 50.0%, as measured according to ASTM D 395 (48 hrs @ 50° C.).2. The shoe midsole of claim 1 , wherein the first polyolefin is an ethylene/α-olefin copolymer from about 60 wt % to about 97 wt %.3. The shoe midsole of claim 1 , wherein the second polyolefin is a polypropylene homopolymer and/or a poly(ethylene-co-propylene) claim 1 , the second polyolefin from about 10 wt % to about 35 wt %.4. The shoe midsole of claim 1 , wherein the silane crosslinker comprises a vinyltrialkoxy silane from about 1 wt % to about 4 wt %.5. The shoe midsole of claim 1 , wherein the grafting initiator comprises one or more halogen molecules claim 1 , azo compounds claim 1 , carboxylic peroxyacids claim 1 , peroxyesters claim 1 , peroxyketals claim 1 , and peroxides claim 1 , the grafting initiator from greater than 0.15 wt % to about 2 wt %.6. The shoe ...

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28-01-2021 дата публикации

SILICON ELECTRODE BINDER

Номер: US20210028461A1
Принадлежит: LG CHEM, LTD.

The present application relates to a binder. The present application can provide a binder which can be applied to production of silicon series negative electrodes to cope well with shrinkage and expansion by repeated charge and discharge, and has excellent binding force between active materials and adhesive force to a current collector, and an active material composition, an electrode and a secondary battery, comprising the same. 1. A silicon electrode binder comprising:a copolymer comprising:a first monomer unit, wherein a homopolymer of said first monomer unit has a glass transition temperature of 80° C. or higher;a second monomer unit, wherein a homopolymer of said second monomer unit has a glass transition temperature of 70° C. or lower; anda third monomer unit, wherein said third monomer unit has an aqueous solubility at room temperature of less than 5%.2. The silicon electrode binder according to . wherein an aqueous solubility of the copolymer is 5% or more.3. The silicon electrode binder according to claim 1 , wherein the copolymer has a weight average molecular weight in a range of 100 claim 1 ,000 to 5 claim 1 ,000 claim 1 ,000.4. The silicon electrode binder according to claim 1 , wherein the first monomer is a carboxyl group-containing monomer.5. The silicon electrode binder according to claim 4 , wherein the carboxyl group-containing monomer is (meth)acrylic acid claim 4 , 2-(meth)acryloyloxyacetic acid claim 4 , 3-(meth)acryloyloxypropylic acid claim 4 , 4-(meth) acryloyloxybutyric acid claim 4 , acrylic acid dimer claim 4 , itaconic acid claim 4 , maleic acid or maleic anhydride.6. The silicon electrode binder according to claim 1 , wherein the ratio of the first monomer unit is in a range of 10 wt % to 40 wt % based on a total weight of the copolymer.7. The silicon electrode binder according to claim 1 , wherein the second monomer unit is a hydroxyl group-containing monomer unit claim 1 , a polyalkylene oxide unit-containing monomer unit claim 1 , a ...

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