ФОТОЛАТЕНТНЫЕ КАТАЛИЗАТОРЫ НА ОСНОВЕ ТИТАН-ОКСО-ХЕЛАТОВ

Изобретение относится к композиции катализатора реакций полиприсоединения или поликонденсации на основе титан-оксо-хелата. Композиция содержит (i) по меньшей мере, одно вещество формулы Iгде Rи Rи Rвместе с С-атомом, к которому они присоединены, образуют фенильную группу, которая может быть незамещенной или замещенной одним, двумя либо тремя С-Салкилами, ORили NRR; Rи Rи Rвместе с С-атомом, к которому они присоединены, образуют фенильную группу, которая может быть незамещенной или замещенной одним, двумя либо тремя С-Салкилами, ORили NRR; R, R, R, R, R, R, независимо друг от друга представляют собой водород, галоген либо С-Салкил; при условии что только один из R, Rи Rв группеи только один из R, Rи Rв группеможет быть водородом;или R, Rи Rи R, Rи Rвместе с С-атомом, к которому они присоединены, образуют фенильную группу; или Rи Rи Rи Rвместе с С-атомом, к которому они присоединены, образуют циклогексильное кольцо; Rи Rнезависимо друг от друга представляют собой С-Салкил; (ii) по меньшей ...

СПОСОБ ПОЛУЧЕНИЯ ГИБКОГО ПЕНОПОЛИУРЕТАНА

Изобретение относится к способу получения гибкого пенополиуретана. Способ включает проведение реакции между полиизоцианатом и полиольной композицией при изоцианатном индексе 95-125, в присутствии воды, реакционноспособного катализатора на основе третичного амина, содержащего по меньшей мере один атом водорода, реакционноспособный по отношении к изоционату, и катализатора на основе карбоксилата цинка. При этом полиольная композиция содержит полиоксиэтиленполиоксипропиленполиол (a1), характеризующийся уровнем содержания оксиэтилена 50-95 масс. % в расчете на массу (a1), и полиоксипропиленполиол (a2), при массовом соотношении между полиолами (a1) и (a2) в диапазоне от 90:10 до 50:50. Использование в способе карбоксилатов цинка в комбинации с реакционноспособными катализаторами на основе третичного амина позволяет значительно снизить уровень летучих органических соединений (ЛОС) в полученном гибком пенополиуретане, а также достичь желательную комбинацию механических свойств и характеристик ...

КОМПОЗИЦИЯ ДЛЯ ПОКРЫТИЯ ДЛЯ ПОЛУЧЕНИЯ ЛЕГКООТСЛАИВАЮЩИХСЯ И ХИМИЧЕСКИ СТОЙКИХ ПОКРЫТИЙ

Настоящее изобретение относится к композиции для легкоотслаивающихся и химически стойких покрытий для металлических и пластмассовых основ, а также к способу получения легкоотслаивающегося лакового слоя, способу химического фрезерования металлических основ и основе. Указанная композиция содержит по меньшей мере один связующий компонент А и по меньшей мере один отверждающий компонент В. Связующий компонент А содержит по меньшей мере один простой полиэфирполиольный компонент на основе полиоксиалкиленгликоля (А1), по меньшей мере один ароматический диамин (А2), частицы силиконового эластомера (А3) и по меньшей мере одну полиуретанмочевину (А4). Отверждающий компонент В содержит по меньшей мере один содержащий уретановые группы компонент, содержащий неблокированные изоцианатные группы (В1), и по меньшей мере один ароматический диизоцианат на основе метилендифенилизоцианата (В2). Компонент В1 получают путем реакции содержащего гидроксильные группы компонента В1.1 с изоцианатным компонентом В1.2 ...

СПОСОБ УЛУЧШЕНИЯ ПРОЧНОСТИ ПОЛИИЗОЦИАНАТНЫХ ПРОДУКТОВ РЕАКЦИИ ПОЛИПРИСОЕДИНЕНИЯ

Настоящее изобретение относится к способу улучшения прочности полиизоцианатных продуктов реакции полиприсоединения. Способ включает взаимодействие при изоцианатном индексе не менее 100 изоцианатов и реакционноспособных в отношении изоцианатов соединений и необязательно каталитических соединений и пенообразующих веществ. Указанные реакционноспособные в отношении изоцианатов соединения включают 1-20 мас.ч. соединений, выбираемых из полиолов, являющихся производными димерных жирных кислот. Содержание жестких блоков полиизоцианатных продуктов реакции полиприсоединения составляет не менее 40%. Полиизоцианатные продукты, полученные указанным способом, обладают улучшенной прочностью, имеют содержание жестких блоков больше 40% и температуру стеклования больше 80°С. 2 н. и 13 з.п. ф-лы, 2 табл., 6 пр.

ПОЛИУРЕТАНОВЫЕ КОМПОЗИЦИИ МАТЕРИАЛОВ ПОКРЫТИЙ И ИХ ПРИМЕНЕНИЕ ДЛЯ ПРОИЗВОДСТВА МНОГОСЛОЙНЫХ КРАСОЧНЫХ СИСТЕМ

Изобретение относится к композициям материалов покрытий. Предложена композиция материала покрытия, включающая а) как минимум один содержащий полигидроксильную группу компонент (А), выбранный из сложного полиэфирполиола, олиакрилатполиола и/или полиметакрилатполиола и их сополимеров, б) как минимум один компонент (В), имеющий в среднем как минимум одну изоцианатную группу и как минимум одну гидролизируемую силановую группу формулы (I) и/или как минимум одну гидролизируемую силановую группу формулы (II); в) как минимум один фосфор- или азотсодержащий катализатор (D) для сшивания силановых групп и г) как минимум один катализатор (Z) для реакции гидроксильных групп с изоцианатными группами, выбранный из группы, к которой относятся карбоксилаты цинка и висмута, хелаты алюминия, циркония, титана и/или бора и/или неорганические, оловосодержащие катализаторы и их смеси, причем композиция материала покрытия включает как минимум один ускоритель реакции (R), который выбирают из группы, к которой относятся ...

ОДНОКОМПОНЕНТНЫЕ ПОЛИУРЕТАНОВЫЕ СИСТЕМЫ ДЛЯ НАНЕСЕНИЯ ПОКРЫТИЙ, СОДЕРЖАЩИЕ ЧЕТЫРЕХВАЛЕНТНЫЙ ВАНАДИЙ

... 1. Однокомпонентная система горячей сушки на полиуретановой основе, отличающаяся тем, что она содержит одно или несколько органических и/или неорганических соединений ванадия, в которых ванадий имеет степень окисления, по меньшей мере, +4. 2. Система согласно п.1, отличающаяся тем, что в случае соединений ванадия речь идет о соединениях, выбранных из группы, состоящей из аммоний-, литий-, натрий-, калий-ванадата, литий-, натрий-, калий-ортованадата, магний-ванадата, кальций-ванадата, ванадил-(IV)-ацетилацетоната (VO(C5H7O5)2), ванадил-бис-тетраметилгептадионата VO(TMHD)2 и ванадиевой кислоты. 3. Система согласно п.1, отличающаяся тем, что в случае соединений ванадия речь идет о соединениях, выбранных из группы, состоящей из литий-ванадата Li3VO4, натрий-ванадата Na3VO4, калий ванадата К3VO4, литий-метаванадата LiVO3, натрий-метаванадата NaVO3 или калий-метаванадата KVO3. 4. Система согласно п.1, отличающаяся тем, что в случае соединений ванадия речь идет о литий- или натрий-ванадате. 5.

СОСТАВ, СОДЕРЖАЩИЙ СОЛИ ОЛОВА И/ИЛИ СОЛИ ЦИНКА С РИЦИНОЛЕВОЙ КИСЛОТОЙ, СПОСОБ ПОЛУЧЕНИЯ ПОЛИУРЕТАНОВОЙ СИСТЕМЫ, ПРИМЕНЕНИЕ СОСТАВА ДЛЯ ПОЛУЧЕНИЯ ПОЛИУРЕТАНОВЫХ СИСТЕМ, ПОЛИУРЕТАНОВАЯ СИСТЕМА И ЕЕ ПРИМЕНЕНИЕ

... 1. Состав, особенно для получения полиуретановой системы, предпочтительно пенополиуретана, содержащая рицинолеат(-ы) олова и/или рицинолеат(-ы) цинка, а также при необходимости другой(-ие) карбоксилат(-ы) олова, смесь, содержащую мочевину, сахарный спирт и полиэтиленгликоль, при необходимости органический растворитель, один или несколько органических изоцианатов с двумя или более изоцианатными функциональными группами, один или несколько полиолов с двумя или более реакционноспособными по отношению к изоцианату группами, при необходимости другие катализаторы взаимодействия изоцианата с полиолом, взаимодействия изоцианата с водой и/или тримеризации изоцианата, воду, необязательно физический порообразователь, необязательно антипирен и при необходимости другие добавки.2. Состав по п.1, отличающийся тем, что массовое отношение мочевины к сахарному спирту составляет от 1:1 до 1:10.3. Состав по п.1, отличающийся тем, что массовое отношение мочевины к полиэтиленгликолю составляет от 1:0,5 до 1: ...

МЕТАЛЛООРГАНИЧЕСКИЕ КОМПОЗИЦИИ

... 1. Металлорганическая композиция, содержащая комплекс, по меньшей мере, одного ортоэфира металла, имеющего формулу M(ROAcAc)x(OR')у, в которой (a) М выбран из группы, состоящей из титана, циркония и гафния, (b) ROAcAc означает сложный эфир спирта ROH, в котором R означает необязательно замещенную C1-30 циклическую, разветвленную или линейную алкильную, алкенильную, арильную или алкиларильную группу или их смесь, с ацетоуксусной кислотой, (c) OR' означает остаток спирта R'OH, в котором R' означает необязательно замещенную С7-зо циклическую, разветвленную или линейную алкильную, алкенильную, арильную или алкиларильную группу или их смесь, и (d) каждый из х и у находится в интервале 1-3 и х+у=4. 2. Металлорганическая композиция по п.1, где R означает необязательно замещенную С7-30 циклическую, разветвленную или линейную алкильную, алкенильную, арильную или алкиларильную группу или их смесь. 3. Металлорганическая композиция по п.1, где R означает необязательно замещенную C1-C6 циклическую, ...

СИНТАКТИЧЕСКИЙ ПОЛИУРЕТАНОВЫЙ ЭЛАСТОМЕР НА ОСНОВЕ ПРЕПОЛИМЕРА С МЯГКИМИ СЕГМЕНТАМИ И КАТАЛИЗАТОРА, НЕ СОДЕРЖАЩЕГО РТУТИ, ДЛЯ ИСПОЛЬЗОВАНИЯ ПРИ ИЗОЛЯЦИИ ПОДВОДНЫХ ТРУБОПРОВОДОВ

Настоящее изобретение относится к способу получения синтактического полиуретанового эластомера, применяемого в качестве изоляции для подводных труб и конструкций. Указанный способ включает (а) формирование реакционной смеси, содержащей удлинитель цепи на основе алкиленгликоля, от 5 до 50 мас.% микросфер, преполимер с изоцианатными концевыми группами, имеющий содержание изоцианата от 3 до 12 мас.%, и не содержащий ртути катализатор, и (b) отверждение реакционной смеси. Преполимер представляет собой продукт реакции по меньшей мере одного простого полиэфирполиола с избытком ароматического полиизоцианата. Не содержащий ртути катализатор представляет собой смесь от 98 до 99,99 мас.% одного или нескольких карбоксилатов цинка и от 0,01 до 2 мас.% одного или нескольких карбоксилатов циркония. Полученный эластомер хорошо склеивается сам с собой, что делает его очень полезным в качестве термоизоляции для трубопроводов и других структур, которые имеют сложную геометрию, а также обладает физическими ...

СПОСОБ УЛУЧШЕНИЯ ПРОЧНОСТИ ПОЛИИЗОЦИАНАТНЫХ ПРОДУКТОВ РЕАКЦИИ ПОЛИПРИСОЕДИНЕНИЯ

СИНТЕЗ И ПРИМЕНЕНИЕ КОМПОЗИЦИЙ МЕТАЛЛОСОДЕРЖАЩИХ ПОЛИЭДРИЧЕСКИХ ОЛИГОМЕРНЫХ СИЛСЕСКВИОКСАНОВЫХ КАТАЛИЗАТОРОВ

КОМПОЗИЦИЯ ДЛЯ ДОСТАВКИ ЛЕКАРСТВ, СОДЕРЖАЩАЯ СИЛИЛЬНЫЕ ПОЛИМЕРЫ

СПОСОБ ПОЛУЧЕНИЯ УРЕТАН(МЕТ)АКРИЛАТОВ

Verfahren zur Herstellung von Polyurethanelastomeren aus hoehermolekularen Polyhydroxylverbindungen

PHOTOAKTIVIERBARE BESCHICHTUNGSZUSAMMENSETZUNG

IMPROVEMENTS IN AND RELATING TO POLYURETHANES

... 1,217,950. Polyurethanes. E. I. DU PONT DE NEMOURS & CO. 17 Oct., 1968 [18 Oct., 1967], No. 49293/68. Headings C3C and C3R. Polyurethanes are prepared by reacting an isocyanate terminated prepolymer with monoethanolamine in the presence of an organic salt of Ca, Zn and/or Pb, e.g. a naphthenate or octoate; from 0À01 to 1 part by weight of catalyst may be used per 100 parts of prepolymer. Up to 50% by wt. of the monoethanolamine may be replaced by triethanolamine. Examples relate to the preparation of foams from a polyether polyol using conventional blowing and wetting agents.

Impact resistant garment

In a first aspect, a method of manufacturing an impact resistant textile is provided in which a heat curable composition for forming a polyurethane is vacuum moulded and heated until partially cured before being pressed onto the fabric such that it joins before being fully cured. Preferably the curable composition comprises polyols and isocyanates. In a second aspect, an impact resistant garment or portion thereof comprises a fabric layer and at least 5 non-interconnected impact resistant polyurethane segments, at least two of which have a depth of at least 3mm and dimensions as per the specification. In a third aspect the segments have a depth of at least 3mm and have a hollow defining a perimeter and an uncovered area of fabric therein (figures 10-11). In a fourth aspect a chemical composition for forming the polyurethane comprises a (polyether) polyol composition as defined in the specification for reacting with an isocyanate and an appropriate catalyst such as zinc neodecanoate, bismuth ...

An improved process for preparing foamed polymeric materials

Cellular polyurethanes are prepared by reacting an organic compound having 2 or more reactive hydrogen groups with an organic polyfunctional isocyanate and water, in the presence of a gelation catalyst of formula Sn(OCOR)2 or R1aSnXb where R and R1 are hydrocarbon residues, the sum of a and b is 4 and X chlorine, carboxylate, mercaptide, alkoxy, or mercaptoacid ester, and a blowing catalyst constituted by a carboxylic acid salt of Mn, Fe, Ni or Co. Specified acids from which the salts may be derived are: benzoic, naphthoic, phenylacetic, cinnamic, toluic, methyl toluic, naphthenic, acetic, propionic, butyric, caproic, caprylic, cupric, stearic, oleic, linoleic and tall oil fatty acids. The reaction may be in a single stage in which all the reactants are mixed at room or elevated temperature. Alternatively the catalyst and water may be added to the reaction product after the other reactants. A trimethyl end-blocked dimethyl polysiloxane may also be present. The reactive hydrogen containing ...

Cellular foamed plastics and process of producing same

In the production of foamed bodies by reacting with a polyisocyanate in the presence of water and a basic reaction accelerator, a polymer containing hydroxy and/or carboxylic acid groups, the reaction is conducted in the presence also of a non-basic metal compound, resulting in foams free from cracks and having a closed pore structure. Metal compounds specified are lead phenolate, iron and nickel carbonyls, ferric and zinc acetyl acetonates, ferric acetoacetate, iron, zinc, nickel and cobalt cyclopentanone carboxylic acid alkyl esters and ferric chloride. In a modification the polymer and polyisocyanate are reacted in the presence of the metal compound and the product reacted with water in the presence of the accelerator. Specified polymers are polyesters, polyesteramides, polyglycol ethers and polymers obtained by the polymerization of olefines and carbon monoxide with subsequent hydrogenation of the primary product. In examples (1) a polyester from adipic acid, diethylene glycol and trimethylol ...

IMPROVED METHOD AND COMPOSITIONS FOR CABLE-BLOCKING

... 1284740 Method and compositions for cable blocking MINNESOTA MINING & MFG CO 4 Nov 1969 [5 Nov 1968] 54077/69 Heading H2C Cable blocks are formed in sheathed multiconductor pressurized cables by filling a short length of the cable with a liquid composition that self cures to form a solid polyurethane and allowing the curing to take place within the cable, the mixture exhibiting a controlled expansion. Reaction between isocyanate groups and active hydrogens is induced preferentially to reaction with a small amount of water in the mixture by means of a catalyst, for example a mono-organic-mercuric compound. When the mixture attains a viscosity of at least 50,000 centipoises, its composition is so chosen that reaction between the water and the isocyanate groups now takes place aided by a further catalyst, producing carbon dioxide sufficient to expand the mixture to 105-125% of its original size, so that the cable is firmly blocked. Materials used to form the block are disclosed.

POLYURETHANE FROTH

... 1376531 Coated products TEXTILE RUBBER & CHEMICAL CO 1 Feb 1972 [3 Nov 1971] 4666/72 Heading B2E [Also in Division C3] Carpets may be backed with a heat-curable flexible polyurethane-forming froth mixture which comprises a transformed diphenylmethane diisocyanate obtained by heating a diphenylmethane diisocyanate with from 0.1% to 3% by weight of a trihydrocarbyl phosphate wherein the hydrocarbyl radical contains from 1 to 12 carbon atoms, at a temperature of 160‹C to 250‹C, a polymeric hydroxy compound, a silicone surfactant, a catalyst selected from nickel acetylacetonate, diacetonitrilediacetylacetonato nickel, diphenylnitrilediacetylacetonato nickel and bis (triphenylphosphine)-diacetylacetonato nickel and an inert gas uniformly dispersed throughout the mixture. The froth is most suitably cured to a tack-free foam condition by raising the temperature thereof to at least 70‹C. In an Example the diisocyanate is prepared by heating diphenylmethane diisocyanate with triethyl phosphate.

Polyurethane foam

Organometallic compositions and polyisocyanate compostitions containing them

Improvements in or relating to the manufacture of foamed polyurethanes

Foamed polyurethanes are made by reacting together an organic polyisocyanate and a hydroxyl-ended polymer in the presence of a co-ordination compound of titanium, zirconium, hafnium, thorium or manganese with a b -diketone, b -ketoester or b -hydroxyaldehyde, to give a reaction product containing free isocyanate groups which is then reacted with water. Specified co-ordinating compounds are acetylacetone, benzoylacetone, 3-cyanoacetylacetone, dibenzoylacetone, propionylacetone, trifluoroacetylacetone, methyl acetoacetate, ethyl acetoacetate, propyl acetoacetate and salicylaldehyde. Specified polyisocyanates include hexamethylene diisocyanate, tolylene diisocyanates, diphenyl methane-4:41-diisocyanate, 3-methyl diphenyl methane-4:41-diisocyanate, m- and p-phenylene diisocyanates, chlorophenylene-2:4-diisocyanate, dicyclohexyl methane diisocyanate, 2:4:6-triisocyanato toluene and 2:4:4-triisocyanatodiphenyl ether. Specified hydroxyl-ended polymers are polyesters, polyesteramides and polyethers ...

REACTIVE PU PREPOLYMERE ONE WITH A SMALL CONTENT OF MONOMERS DIISOCYANATEN

REACTIVE PU COMPOSITION

PROCEDURE FOR THE POLYCONDENSATION OF ISOCYANATES

PU RESIN FOR WHITE INK

ORGANOMETALLI COMPOSITIONS

PU RESIN FOR COLOR INK

BONDING AGENT FOR THE ELECTRICAL DIPPING LACQUER FINISH

WATER-DISPERSE-CASH POLYETHER MODIFYING OF POLYISOCYANATE MIXTURES

Procedure for the production of preferably not foamed PU

Polyurethane comprising formulations with isocyanate functionality

A urethane group-containing reactive polyisocyanate composition is disclosed which contains not more than 1 wt% of monomeric starting di-isocyanate based on the total weight of said polyisocyanate composition, having an NCO value in the range 0.1-15%, and wherein said composition comprises urethane groups and allophanate groups and wherein the ratio of allophanate groups over urethane groups is between 0.05 and 100.

Polyurethane coating material composition, multistage coating methods using these coating material compositions, and also the use of the coating material composition as clearcoat material and pigmented coating material, and application of the coating method for automotive refinish and/or for the coating of plastics substrates and/or of utility vehicles

The present invention relates to coating material compositions comprising at least one polyhydroxyl group-containing compound (A), at least one polyisocyanate group-containing compound (B) having free and/or blocked isocyanate groups, and at least one catalyst (D) based on a zinc-amidine complex which is preparable by reaction of 1.0 moles of at least one zinc(II) biscarboxylate with less than 2.0 moles of at least one amidine where R ...

MICRO-CELLULAR OR NON-CELLULAR LIGHT-STABLE POLYURETHANE MATERIAL AND METHOD FOR THE PRODUCTION THEREOF

Zinc (1-methylimidazole)bis(2-ethylhexanoate) complex catalyzed coating material composition

The invention relates to coating material compositions comprising an isocyanate group-containing component, a hydroxyl group-containing component, and a zinc (1-methylimidazole)bis(2-ethylhexanoate) complex, and also to the use of a zinc (1-methylimidazole)bis(2-ethylhexanoate) complex as a catalyst system for the urethane reaction in coating material compositions.

Curable composition based on polymers containing silane groups and on a zinc catalyst

The invention relates to a composition, comprising at least one polymer that contains silane groups and comprising at least one zinc(II) complex compound of the formula Zn ...

Drug delivery composition containing silyl polymers

The invention relates to a silyl-containing polymer that is used, together with a tackifying resin to form an adhesive composition capable of storing and delivering drugs to the skin of a user. Typically the composition is formed into a patch which shows excellent adhesion to the skin even when drugs and other additives are dissolved into the composition.

Catalyst for the reaction between a compound that can react with isocyanate groups and an aliphatic diisocyanate with one isocyanate group bound to a primary carbon atom and one isocyanate group bound to a tertiary carbon atom

POLYURETHANE/UREAS USEFUL FOR THE PRODUCTION OF SPANDEX AND A PROCESS FOR THEIR PRODUCTION

Segmented polyurethane/ureas useful in the production of spandex are produced by chain extending an isocyanate-terminated prepolymer in the presence of a solvent. The isocyanate-terminated prepolymer is formed by reacting a stoichiometric excess of an isocyanate with an isocyanate-reactive component that includes more than 50 equivalent percent of a high molecular weight polyoxyalkylene diol having an unsaturation level no greater than about 0.015 meq/g and up to about 50 equivalent percent of a polytetramethylene ether glycol.

A POLYURETHANE RESIN FOR WHITE INKS

The present invention is related to a Polyurethane resin obtainable by a) reacting an excess of one or more aliphatic diisocyanates with a group of isocyanate-reactive components consisting of one or more polyether polyols each having an average molecular weight in the range of not more than 1500 g/mol, and at least one diamine so as to obtain a prepolymer; and b) adding a mixture of isophorone diamine and a second diamine selected from the group consisting of ethylenediamine, 1,2-diaminocyclohexane and 2,2,4- or 2,4,4- trimethyldiiaminohexane (TMDA) in excess to the free NCO groups of the prepolymer obtained in step a).

HIGH PERFORMANCE POLYURETHANE PREPOLYMER AND CURING COMPOSITIONS

Compositions comprising isocyanate capped polyurethane prepolymers and select mono-benzyl phthalate plasticizers, e.g., 7-(2,6,6,8-tetramethyl-4-oxa-3-oxo-nonyl) benzylphthalate, exhibit better isocyanate stability than prepolymer compositions comprising other plasticizers common in polyurethane systems. Curing compositions comprising these prepolymers, the select mono-benzyl phthalate plasticizers, and methylenedianiline coordination complex curing agents exhibit improved processing characteristics and yield elastomeric polyurethanes with lower compression set, higher break strength and lower color than similar composition comprising plasticizers such as benzoate plasticizers.

ORGANOMETALLIC COMPOSITIONS

An organometallic composition is described which comprises a complex of at least one orthoester of a metal having a formula M(ROAcAc)x(OR')y in which M is selected from the group consisting of titanium, zirconium and hafnium; ROAcAc denotes an ester of an alcohol ROH, in which R comprises an (optionally substituted) C1-30 cyclic, branched or linear, alkyl, alkenyl, aryl or alkyl- aryl group or a mixture thereof, with acetoacetic acid; OR' is the residue of an alcohol R'OH in which R' comprises an (optionally substituted) C7-30 cyclic, branched or linear, alkyl, alkenyl, aryl or alkyl-aryl group or a mixture thereof, and x and y are each in the range 1 - 3. The composition is useful as a curing agent for polyurethanes used in various applications.

POLYISOCYANATE COMPOSITIONS

A polyisocyanate composition comprising an iron and/or aluminum composition, which is a complex of at least one metal selected from the group consisting of iron or aluminum and a .beta.-dicarbonyl compound in which the molar ratio of Fe or Al to .beta.-dicarbonyl compound is in the range 1:3.5 to 1:10.

POLYISOCYANATES CONTAINING ALLOPHANATE AND SILANE GROUPS

The invention relates to polyisocyanates containing allophanate groups and silane groups, to a process for preparing them and to their use as a starting component in the production of polyurethane polymers, more particularly as a crosslinker component in polyurethane paints and coatings.

SYNTHESIS AND USE OF METALLIZED POLYHEDRAL OLIGOMERIC SILSEQUIOXANE CATALYST COMPOSITIONS

The present invention relates to a method to form a polyurethane material. The method includes blending at least one isocyanate, at least one isocyanate reactive component and a catalyst composition to form a blend and reacting said blend to provide said polyurethane material. The catalyst composition includes metallized polyhedral oligomeric silsesquioxanes (POMS) compounds wherein said POMS compounds are reaction products of metallic alkoxides and silsesquioxane silanols, wherein the silsesquioxane silanols comprises structure [2] the number of equivalents of silsesquioxane silanols used is higher than the number of equivalents of metallic alkoxides used to react with said silsesquioxane silanols, R is an alkyl group, and the metal in the metallic alkoxide is selected from Ti.

SYNTACTIC POLYURETHANE ELASTOMERS HAVING DISTINCT MORPHOLOGY FOR USE IN SUBSEA PIPELINE INSULATION

Syntactic polyurethane elastomers are made using a non-mercury catalyst. The elastomer is made from a reaction mixture containing a polyether polyol, a chain extender, a polyisocyanate and microspheres. The elastomer is characterized morphologically by the presence of small discrete morphological domains 0.1 to 3 µm in diameter, and the substantial absence of discrete morphological domains 5 to 30 µm in diameter. The elastomer adheres well to itself, which makes it very useful as thermal insulation for pipelines and other structures that have a complex geometry.

SYNTHESIS AND USE OF METALLIZED POLYHEDRAL OLIGOMERIC SILSEQUIOXANE CATALYST COMPOSITIONS

The present invention relates to a method to form a polyurethane material, a catalyst composition comprising metalized polyhedral oligomeric silsesquioxanes (POMS) compounds in combination with reactive compounds suitable to be used to provide a polyurethane material and the polyurethane material obtained using the catalyst composition.

COATING MATERIAL SYSTEM BASED ON POLYOLS OF LOW ACID NUMBER

The invention relates to a coating agent system comprising the components (A) to (C) and, if necessary, further components, wherein in a first option all the components (A) to (C) and, if necessary, also the further optional components are provided separately from each other, i.e. the individual components are not mixed together. In a second option of the coating agent system according to the invention, the aforementioned components can, by contrast, also be completely or at least in part mixed together. If the components are at mixed together at least in part, this means that, for example, component (C) is mixed with component (A), while component (B) is provided separately from this mixture of (A) and (C). If necessary however, component (B) can also be mixed with a partial quantity of component part (C). Furthermore, the mixtures of (A) and (C) and of (B) and (C) additionally contain at least one optional component, such as a solvent, for example. Component (A) comprises at least one ...

POLYURETHANE FOAM PREMIXES CONTAINING HALOGENATED OLEFIN BLOWING AGENTS AND FOAMS MADE FROM SAME

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a precipitation-resistant metal-based catalyst used alone or in combination with an amine catalyst.

POLYURETHANE MOLDING COMPOSITION METHOD AND ARTICLE

A high pressure method of molding polyurethane articles is described. A polyurethane material is formed from a cross-linkable polymer comprising the reaction product of a polyol and polyisocyanate, said polymer containing a high activation temperature catalyst and a high surface area filler. The material is processed to a gum state suitable for high pressure molding. The material and process are particularly suitable for forming small, intricately shaped articles. Such articles are also described. DCl-9654 ...

POLYURETHANE COMPOSITIONS AND METHOD

A two-component polyurethane sealant composition comprising a diisocyanate-based prepolymer as a first component and a polyol composition as a second component reactable with said first component, when said two components are admixed, to form a thermoset curable polyurethane, said polyol composition comprising a polyol capable of reacting with said diisocyanate-based prepolymer to form a polyurethane catalyst, comprising a mixture of cobalt and vanadium alkanoates and a ketimine, and the method of making an architectural seal utilizing the same.

BINDERS FOR ELECTROCOATING

... - 15 - O.Z. 0062/02118 Binder systems suitable for electrocoating and consisting of a base resin A which carries groups which can be protonated with acids or cationic quaternary groups and, if desired, hydroxyl or thiol groups, a crosslinking component B which carries at least two blocked isocyanate groups per molecule and an organic iron compound C which is partially or completely soluble in water, as a catalyst for the thermal crosslinking of components A and B, and if desired, an additive D which increases the catalytic activity of C, are used to prepare dispersions which are used for electrocoating.

COATING COMPOSITIONS HAVING EXTENDED POT LIFE AND SHORTENED CURE TIME AND COMBINATION OF CHEMICALS USED THEREIN

A combination of chemicals suitable for extending pot life and shortening cure time of a pot mix of a thermosetting composition is disclose d. The combination of chemicals includes a catalyst, such as, dibutyl tin dilau rate; carboxylic or sulfonic acid; and an extender compound, such as 2,4 pentanedi one.The combination is generally included in a polymeric component of the urethane composition. The extended pot life provides the user with longer open time during which to efficiently apply a coating of the pot mix over a wide varie ty of substrate surfaces while still producing coatings that cure quickly upon application.

Verfahren zur Herstellung kautschukartiger Produkte

Verfahren zur Herstellung von kautschukartigen Produkten sowie Anwendung dieses Verfahrens

Verfahren zur Herstellung kautschukartiger Produkte

Verfahren zur Herstellung kautschukartiger Produkte

Verfahren zur Herstellung kautschukartiger Produkte

Verfahren zur Herstellung von Polyurethan-Kunstharzen

Verfahren zur Herstellung eines Polyurethanschaumstoffes

Verfahren zur Herstellung von festen, nicht zelligen, vernetzten Polyurethanen

VERFAHREN ZUR HERSTELLUNG VON NICHT GESCHAEUMTEN POLYURETHAN-FORMKOERPERN.

Verfahren zur Herstellung elastischer hochmolekularer Kunststoffe

Polyalkylenätherpolyol und Füllstoff enthaltende Masse, sowie ihre Verwendung zur Herstellung von elastomeren Polyurethanen

Verfahren zum Veredeln, insbesondere zum Ölabweisendmachen, von aus Cellulosefasern bestehenden Textilien

Verfahren zur Herstellung von Polyurethanen

Verfahren zur Herstellung von Polyurethanen

Verfahren zur Herstellung von Polyurethanen

[...] A BASE DE [...] ET tITANATES.

Jewelry piece for e.g. cuff-link, has slide comprising mechanical support with tongues forming spring piece that is welded on collet, where spring piece and collet are sandblasted and annealed in furnace for one hour at preset temperature

The piece has a support (4) on which a slide supporting a decorative object is fixed in a removable manner by interlocking. The slide has a mechanical support (1) with two tongues in the form of U and forming a spring piece (2). The piece is welded and set on an oval shaped collet, where the collet and the piece are sandblasted after welding, and are annealed in a furnace for 60 minutes at a temperature of 280[deg] Celsius.

ЭЛАСТИЧНЫЕ, ДИСПЕРГИРУЕМЫЕ В ВОДЕ ПОЛИУРЕТАНОВЫЕ ПЕНЫ И СОДЕРЖАЩИЕ ИХ ИЗДЕЛИЯ

Предложена мягкая и эластичная, диспергируемая в холодной воде полиуретановая пена, приемлемая для одноразовых изделий личной гигиены, которую получают путем объединения кукурузного сиропа, глицерина, простого полиэфирдиамина, ПЭГ, диизоцианата, воды и катализатора. Рецептура и реакционные условия для получения заявляемой пены разумно выбраны и тщательно контролируются, чтобы получить диспергируемость в воде и желаемые механические свойства. Характеристическая эластичность или процент упругого восстановления пен обычно превышает 75%, и пены легко производятся в виде мягких пен, проявляющих значение относительного сжатия от 20 до 150% от относительного сжатия промышленных полиуретановых пен в косметических прокладках, которые не диспергируются в воде. Пена может быть введена в полотна и складываемые в пачку изделия или складываемые трехмерные изделия.

A method for improving toughness of polyisocyanate polyaddition reaction products

SPRAYABLE POLYURETHANE COATING

Reactive polyurethane prepolymers with low monomeric diisocyanate content

TWO-COMPONENT POLYURETHANE ADHESIVE HAVING SUBSTANTIALLY TEMPERATURE-INDEPENDENT MECHANICAL PROPERTIES AND HIGH STRENGTH

Thermoplastic polyurethane elastomer as well as preparation method, application and product thereof

Improvements in the process for preparation of polyurethanes and in particular of polyurethane foams

POLYURETHANES

MANUFACTORING PROCESS OF POLYURETHANE USING a CATALYTIC SYSTEM ACETYLACETONATE METALLIQUE/ACETYLACETONE AND PRODUCT OBTAINED CONSTITUTES

Organic compositions containing of polyols, method of preparation of polyurethans starting from these compositions and polyurethans obtained

Polyisocyanates Containing Acylurea Groups, a Process for Their Production and Their Use

COATING COMPOSITION FOR CHROMIUM THIN FILM COATING

... 다양한 조건하에 있어서의 크롬 박막에 대한 부착성이 양호하고, 또한 충분한 내흠집성을 구비한 피복 도막을 형성할 수 있는 도료 조성물을 제공하는 것을 목적으로 하고, 기재 위에 형성되는 크롬 박막을 피복하는 피복용 도료 조성물로서, 인산기와 당해 인산기에 포함되는 수산기 이외의 수산기를 갖는 아크릴계 공중합체(A)와, 이소시아네이트(B)와, 금속 킬레이트(C)를 포함하는 것을 특징으로 하는 크롬 박막 피복용 도료 조성물을 제공한다.

스크래치-내성 수성 2K PU 코팅

... 본 발명은 바람직하게는 히드록시-관능성 및/또는 아미노-관능성 수성 중합체 분산물 및 가교제로서의 실란 기를 함유하는 티오알로파네이트를 기재로 하는 수성 2-성분 코팅 조성물, 그것의 제조 방법, 및 코팅의 제조에서의 이들 코팅 조성물의 용도에 관한 것이다.

이소시아네이트 링커 및 단쇄 및 장쇄 알킬 폴리에테르의 혼합으로 개질된 과분지형 중합체

... 본 발명은 하기를 포함하는 과분지형 중합체에 관한 것이다: a) 하기와 축합된 히드록실 및/또는 아미노 말단 기를 갖는 과분지형 중축합물 b) 하기에 연결된 하나 이상의 연결 기 c1) 하나 이상의 폴리에틸렌 글리콜 모노메틸 에테르 및 c2) 하나 이상의 폴리(C2-C3)알킬렌 글리콜 모노-(C8-C22)-알킬 에테르, 이때, 성분 c1) : c2) 의 중량 비는 9 : 1 내지 1 : 9 임. 이는 추가로 중합체의 제조 방법, 중합체 및 활성 성분을 포함하는 조성물, 및 식물병원성 진균 또는 목적하지 않은 식생 또는 곤충 또는 진드기 침입의 방제 방법 또는 식물의 생장의 조절 방법에 관한 것이다.

FINE PARTICLE, HIGH CONCENTRATION, POLYISOCYANATE POLYADDITION/POLYURETHANE-UREA POLYOLS

NOVEL THERMOPLASTIC POLYURETHANES, USE OF THESE MATERIAL FOR THE PREPARATION OF T-FRAMES FOR INTRAUTERINE SYSTEMS AND T-FRAMES MADE OUT OF THIS MATERIAL

Poliuretano / uréias úteis para a produção de spandex e um processo para sua produção

TITANORGANISK FORENING FOR BEHANDLING AV PARTIKELFORMIGA FYLLMEDEL

TIN FREE POLYMER POLYOLS

Embodiments include polymer polyol dispersions which include a polyol liquid phase and solid particle phase. Embodiments include methods of making the polymer polyol dispersions. The polymer polyol dispersions are essentially free of tin, have a solid content of between about 20 and 50 wt% based on the total weight of the polymer polyol dispersion, and have a viscosity at 20C of less than 9000 mPas. The solid particle phase has more than 90% by weight of particles in the solid particle phase having a particle diameter of less than 5 µm.

POLYMERIZABLE COMPOSITION FOR POLYTHIOURETHANE OPTICAL MATERIAL

A polymerizable composition for polythiourethane optical material comprising any of compounds of the general formula (1): M(L)n (1) (wherein M is Al, Fe, Cu, Zn, Zr or Bi; L is a dithiocarbamic acid group, a sulfonic acid group, a mono- or dialkyl phosphoric ester group, a substituted acetylacetonato group or a halogen; and n is an integer of 1 to 5); one or two or more isocyanates selected from the group consisting of isocyanate compounds and isothiocyanate compounds; and one or two or more active hydrogen compounds each having a mercapto group. The compounds of the general formula (1) exhibit a catalytic activity equal to or superior to that had by organotin catalysts having been employed as catalysts for the production of polythiourethane optical materials, and have high safety. Further, the thus obtained polythiourethane resins satisfactorily meet the property requirements for optical materials, in particular, excelling in weather resistance. Therefore, the proposed catalysts are available ...

POLYURETHANE COMPOSITIONS COMPRISING URETDIONE GROUPS WHICH MAY HARDEN AT LOW TEMPERATURES AND COMPRISE (PARTLY-)CRYSTALLINE RESINS

The invention relates to polyurethane compositions, comprising uretdione groups which may harden at low temperatures and comprise (partly-)crystalline resins, in particular, for polyurethane powder paints and adhesive compositions which may harden at low temperatures and method for production and use thereof.

Polyurethane coating systems

Novel one-component polyurethane systems, to their preparation and use for preparing paints, inks and adhesives. The one-component polyurethane systems include one or more organic and/or inorganic compounds of molybdenum and/or of tungsten in which the molybdenum and/or tungsten has an oxidation state of at least +4.

Ceric hydrocarbyl silyloxides and process for their preparation

Ceric hydrocarbyl silyloxides are provided, as well as a process for preparing them, which comprises reacting ceric ammonium nitrate with a hydrocarbyl silanol, including a lower aliphatic silanol, under anhydrous conditions in the presence of an anhydrous base at a temperature within the range from about -30° C. to about 200° C. but preferably from 0° to about 150° C. until ceric hydrocarbyl silyloxide and the nitrate salt of the base are formed; the nitrates formed during the reaction can be separated from the reaction mixture and the ceric hydrocarbyl silyloxides isolated pure or as complexes with the solvent, or in some cases the ceric hydrocarbyl silyloxides can be used without separation from the reaction mixture in the presence of the nitrates.

Process for producing hydrolyzable silyl group-containing fluoropolymer, and composition containing hydrolyzable silyl group-containing fluoropolymer

The present invention has an object to provide a process for producing a hydrolyzable silyl group-containing fluoropolymer which is excellent in storage stability and has a sufficient pot life. At the time of producing a hydrolyzable silyl group-containing fluoropolymer by reacting an isocyanate group of an isocyanate group-containing alkoxysilane to a hydroxy group of a hydroxy group-containing fluoropolymer, the reaction is carried out in the presence a compound containing a specific metal atom at a certain concentration.

Method to form a polyurethane material

A method to form a urethane material, the method comprises blending and reacting at least one isocyanate, at least one isocyanate reactive compound and a metallized polyhedral oligomeric silsesquioxane to provide said urethane material, the metallized polyhedral oligomeric silsesquioxane is a dimeric structure with general formula wherein M represents a metal providing a 6-coordinated metal center, x and y being 1, R 1 O and R 2 O represent an alkoxide bridging the 6-coordinated metal centers, R 3 OH and R 4 OH represent an alcohol ligand and each of R 5 , to R 18 is selected from the group consisting of alkyl-, polyether- and polyester ligands.

Composition containing specific carbamate type compounds suitable for producing polyurethane foams

Compositions suitable for producing polyurethane foams which include at least an isocyanate component, a polyol component, a catalyst catalyzing formation of a urethane or isocyanurate bond, and at least one compound containing at least one structural element of formula (I)

Formulation containing tin and/or zinc salts of ricinoleic acid, urea, polyethylene glycol and sugar alcohol and use of the formulation in the production of polyurethane systems

A formulation for the production of a polyurethane system, in particular a polyurethane foam, containing or consisting of tin and/or zinc ricinoleate(s), optionally tin carboxylate(s), a mixture containing or consisting of urea, sugar alcohol and polyethylene glycol, optionally organic solvent, one or more organic isocyanates having two or more isocyanate functions, one or more polyols having two or more groups which are reactive towards isocyanate, optionally further catalysts for the isocyanate-polyol and/or isocyanate-water reactions and/or isocyanate trimerization, water, optionally physical blowing agents, optionally flame retardants and optionally further additives, a process for the production of polyurethane systems, these polyurethane systems and their use.

Method of preparing a polymer and compositions therefor

The invention provides a method of making a polymer in the presence of a catalyst composition having an empirical formula M(glycerol) a (X) b , where M represents a metal atom selected from titanium, zirconium, hafnium or aluminium, X is a ligand derived from acetylacetone or a peroxo ion; a is a number between 1 and 2.5; b is a number in the range from 1 to 2. Reactive compositions containing the catalyst composition are also described.

TIN FREE SILYL-TERMINATED POLYMERS

Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer. 1. A method of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule , the method comprising:providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule and having a number average molecular weight of between about 100 and about 10000;{'sup': '1', 'adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, wherein the hydrosilylation reaction has a hydrosilylation efficiency of at least about 70% as determined by H-NMR;'}reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate at an isocyanate index of between about 80 and about 250 and in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymers; ...

Polyurethanes Made with Copper Catalysts

Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a copper catalyst that contains at least one copper atom associated with a polydentate ligand that contains at least one nitrogen-containing complexing site. 27-. (canceled)911-. (canceled)1316-. (canceled)2224-. (canceled)2627-. (canceled)28. The process of wherein the polyisocyanate-based polymer is a polyurethane claim 1 , polyurea claim 1 , or polyurethane-urea.29. The process of claim 1 , wherein the reaction mixture further contains a blowing agent and a surfactant claim 1 , and the polyisocyanate-based polymer is a foam.30. The process of claim 1 , wherein the isocyanate-reactive compound includes a polyol having a molecular weight of from 800 to 12 claim 1 ,000 and an average of from 1.8 to 2.5 hydroxyl groups per molecule claim 1 , and the polyisocyanate-based polymer is a cast elastomer.31. The process of wherein the reaction mixture contains at least one additional catalyst. This application claims priority from U.S. Provisional Application No. 61/362,553, filed 8 Jul. 2010.This invention relates to processes for making polymers from polyisocyanates and isocyanate reactive materials. The invention is particularly applicable to making cast polyurethane elastomers.Many solid or microcellular polyurethane elastomers are manufactured using cast elastomer methods. These elastomers are made by reacting a high equivalent weight polyol and a chain extender material with a polyisocyanate compound. Because it is usually intended to form a highly flexible, rubbery product, the amount of chain extender in the formulation is usually somewhat small. The elastomer is produced by mixing the starting materials and transferring the mixture into a mold where it is cured, usually with application of heat. Some or all of the high equivalent weight polyol may ...

POLYURETHANE ELASTOMERS MADE USING MIXTURES OF ALIPHATIC DIOL CHAIN EXTENDER AND SECONDARY AMINE

Polyurethane elastomers are formed by curing a reaction mixture containing at least one polyisocyanate at least one polyol, an aliphatic diol chain extender and a small amount of a secondary amino compound that may have none or one or more hydroxyl groups. The reaction is catalyzed with a metal catalyst. In certain embodiments, the catalyst is an organozirconium, organotitanium or tertiary amine-based catalyst. The presence of the secondary amine compound in those cases provides for a good surface appearance and good physical properties. 2. (canceled)3. The process of wherein component b) is a dialkyl amine claim 1 , a substituted dialkyl amine claim 1 , a di(aryl)amine claim 1 , an alicyclic compound containing one or more secondary nitrogen atoms in the ring structure claim 1 , a dialkanolamine claim 1 , a monoalkylmonoalkanolamine claim 1 , or a mixture of any two or more of the foregoing.4. The process of wherein component b) is dimethyl amine claim 3 , diethyl amine claim 3 , diisopropylamine claim 3 , methylethyl amine claim 3 , dibenzyl amine or a mixture of any two or more thereof.5. (canceled)6. The process of wherein component b) is 2-(methylamino)ethanol claim 3 , 2-(ethylamino)ethanol claim 3 , 2-(propylamino)ethanol claim 3 , 1-methyl-2-(methylamino)ethanol claim 3 , 1-methyl-2-(ethylamino)ethanol claim 3 , 1-methyl-2-(propylamino)ethanol claim 3 , 1-ethyl-2-(methylamino)ethanol claim 3 , 1-ethyl-2-(ethylamino)ethanol claim 3 , 1-ethyl-2-(propylamino) ethanol claim 3 , N-hydroxyethylbenzylamine claim 3 , N-hydroxypropylbenzylamine claim 3 , or a mixture of two or more of the foregoing.7. The process of claim 1 , wherein component a) constitutes from 6 to 15% of the weight of the reactive materials in the reaction mixture.8. The process of claim 1 , wherein components a) and b) are present in a weight ratio of from 80:20 to 95:5.9. The process of claim 1 , wherein the reaction mixture contains no mercury-containing catalyst.10. The process of claim 1 , ...

PHOTO-LATENT TITANIUM-OXO-CHELATE CATALYSTS

A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R, R, R, R, R, R, R, R, R, R, Rand Rindependently of each other are for example hydrogen, halogen, C-Calkyl, C-Caryl which is unsubstituted or substituted; or R, Rand Rand/or R, Rand Rand/or R, Rand Rand/or R, Rand Rtogether with the C-atom to which they are attached each form a C-Caryl group which is unsubstituted or substituted; or Rand Rand/or Rand Rand/or Rand Rand/or Rand Rtogether with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (IIa), (IIb) or (IIc), wherein R, R, R, R, Rand Rare defined as above for formula (I), is suitable as photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid. 2. Titanium-oxo-chelate catalyst formulation according to claim 1 , comprising{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(i) 50-99% by weight of at least one compound of the formula I as defined in , and'}{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(ii) 1-50% by weight of at least one chelate ligand compound of the formula IIa, IIb or IIc as defined in .'}46-. (canceled)7. A polymerizable composition comprising(a) at least one component which is capable of a polyaddition or polycondensation reaction in the presence of a Lewis-acid type reactants; and{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(b) at least one titanium-oxo-chelate catalyst compound of the formula I as defined in .'}8. A polymerizable composition according to comprising as component (a)(a1) at least one blocked or unblocked isocyanate or isothiocyanate component, and(a2) at least one polyol.9. A polymerizable composition according to claim 7 , comprising in addition to components (a) and (b) a further additive (d) claim 7 , in particular a photosensitizer compound.10. A polymerizable composition according to claim 7 , which ...

Biocompatible, Biodegradable Polyurethane Materials With Controlled Hydrophobic to Hydrophilic Ratio

The biocompatible, biodegradable materials in the solid and/or liquid form are based on segmented linear polyurethanes and/or segmented crosslinked polyurethanes based on A) one or more biocompatible polyols susceptible to hydrolytic and/or enzymatic degradation having a molecular weight of 100 to 20,000 dalton and a number of active hydroxyl groups per molecule (functionality) of at least two or higher; B) one or more diisocyanates and/or triisocyanates; and C) one or more low molecular weight chain extenders having a molecular weight of 18 to 1000 dalton and the functionality of at least two or higher.

FINE PARTICLE, HIGH CONCENTRATION, POLYISOCYANATE POLYADDITION/POLYURETHANE-UREA POLYOLS

Embodiments of the invention include a method of producing polymer polyol dispersions is. The method includes providing at least one reaction system, and the reaction system includes: a) at least one polyol, b) at least one seed population, c) at least one catalyst, d) at least one co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom, and e) at least one polyisocyanate. The at least one seed population includes less than about 5% by weight of the total weight of the at least one reaction system and includes seed particles having diameters of less than 5 μm. The at least one reaction mixture reacts to form at least one of a polyurea and polyurethane-urea particle population in the at least one polyol without the addition of any catalysts comprising tin. The polymer polyol dispersion has a solids content of at least 15% of the weight of the polymer polyol dispersion. 1. A method of producing a polymer polyol dispersion , the method comprising:providing at least one reaction system, the reaction system comprising:a) at least one polyol:b) at least one seed population:c) at least one catalyst;d) at least one of a co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom; ande) at least one polyisocyanate;wherein the at least one seed population comprises less than about 5% by weight of the at least one polyol and comprises suspended seed particles having maximum particle diameters of less than 5 μm;wherein to the at least one reaction mixture reacts to form at least one of a polyurea, polyurethane, and polyurethane-urea particle population in the at least one polyol without the addition of any catalysts comprising tin; andwherein the polymer polyol dispersion has a solids content of at least 15% of the weight of the polymer polyol dispersion.2. A polymer polyol dispersion comprising a reaction product of a reaction system , the ...

METHOD FOR PRODUCING POLYURETHANE SOFT FOAMS WITH HIGH BULK DENSITY

The invention relates to a method for producing polyurethane soft foams having a volumetric weight according to DIN EIN ISO 845: 2009-10 from 50.0 to 80.0 kg/m, in particular open-cell polyurethane soft foams based on polyether polyol and toluylene diisocyanate, having a high bulk density, wherein the resulting polyurethane foams have similar properties to the already known polyurethane soft foams, these being simpler and more sustainable in terms of their production. 2. The process as claimed in claim 1 , wherein in the formula (I){'sup': '1', 'Ris an aromatic hydrocarbon radical having at least 6 carbon atoms or is a linear, branched, substituted or unsubstituted aliphatic hydrocarbon radical having at least 3 carbon atoms;'}{'sup': '2', 'Ris a linear, branched, substituted or unsubstituted aliphatic hydrocarbon radical having at least 3 carbon atoms; and'}n is 1 to 3.3. The process as claimed in claim 1 , wherein component A comprises:A1 40 to 100 parts by weight of one or more polyether polyols having a hydroxyl value in accordance with DIN 53240-1:2013-06 from 20 mg KOH/g to 250 mg KOH/g and an ethylene oxide content of 0.10% to 59.0% by weight,A2 0 to 60 parts by weight of one or more polyether carbonate polyols having a hydroxyl value in accordance with DIN 53240-1:2013-06 from 20 mg KOH/g to 120 mg KOH/g,A3 0 to 60 parts by weight, based on a sum of the parts by weight of components A1 and A2, of one or more polyether polyols having a hydroxyl value in accordance with DIN 53240-1:2013-06 from 20 mg KOH/g to 250 mg KOH/g and an ethylene oxide content of at least 60% by weight,A4 0 to 40 parts by weight, based on the sum of the parts by weight of components A1 and A2, of one or more polymer polyols, PUD polyols, PIPA polyols, or a combination thereof, andA5 0 to 40 parts by weight, based on the sum of the parts by weight of components A1 and A2, of polyols that are different from components A1 to A4, wherein all stated parts by weight of components A1, A2, A3, ...

MOISTURE-CURABLE SILYLATED POLYMER RESIN COMPOSITION WITH REDUCED MOISTURE SENSITIVITY

There is provided herein a silylated polyurethane composition, a process of preparing a silylated polyurethane polymer, and an adhesive, sealant or coating containing a silylated polyurethane made therewith. 4. The silylated polyurethane composition of where in formula (IIA) Rpossesses 1 to 4 carbon atoms claim 3 , each Ris the same or different group selected from the group consisting of methyl claim 3 , ethyl claim 3 , propyl or isopropyl group and a is 0.5. The silylated polyurethane composition of claim 1 , comprising the reaction product of:a polyol;an isocyanatosilane silylating agent; and,an yttrium-containing catalyst.6. The silylated polyurethane composition of claim 1 , comprising the reaction product of:a polyisocyanate;an active hydrogen-containing silane; and,an yttrium-containing catalyst.7. The silylated polyurethane composition of claim 1 , wherein the yttrium-containing catalyst is selected from the group consisting of an yttrium salt claim 1 , a hydrate of an yttrium salt claim 1 , an yttrium complex claim 1 , an yttrium alkoxide claim 1 , an organic yttrium compound claim 1 , an inorganic yttrium compound claim 1 , and combinations thereof.8. The silylated polyurethane composition of claim 1 , wherein the yttrium-containing catalyst is an yttrium salt selected from the group consisting of yttrium halide claim 1 , yttrium nitrate claim 1 , yttrium sulfate claim 1 , yttrium trifluoromethanesulfonate claim 1 , yttrium acetate claim 1 , yttrium trifluoroacetate claim 1 , yttrium malonate claim 1 , octylic acid (ethyl hexanoic acid) salt of yttrium claim 1 , yttrium naphthenate claim 1 , versatic acid salt of yttrium claim 1 , yttrium neodecanoate claim 1 , yttrium carbonate claim 1 , yttrium hydrogen carbonate claim 1 , and combinations thereof.9. The silylated polyurethane composition of claim 1 , wherein the yttrium-containing catalyst is an yttrium alkoxide selected from the group consisting of yttrium trimethoxide claim 1 , yttrium triethoxide ...

Cobalt and manganese based urethanized polymers for air drying polymer-based coatings, paints and inks

The present disclosure relates to polymer compounds for use as polymerization agents in coatings, paints or inks. In one embodiment, a polymer compound comprises at least one of a cobalt-bearing urethanized polymer having a cobalt content of no more than 6% by weight and a mean molecular weight of no more than 2500 Da, or a manganese-bearing urethanized polymer having a manganese content of 1% to 6% by weight and a mean molecular weight of no more than 2000 Da.

Tin free silyl-terminated polymers

Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer.

Zinc (1-Methylimidazole)bis(2-Ethylhexanoate) Complex Catalyzed Coating Material Composition

Described are coating material compositions comprising an isocyanate group-containing component, a hydroxyl group-containing component, and a zinc (1-methylimidazole)bis(2-ethylhexanoate) complex. Also described is the use of a zinc (1-methylimidazole)bis(2-ethylhexanoate) complex as a catalyst system for the urethane reaction in coating material compositions.

TWO-COMPONENT POLYURETHANE COMPOSITION

A two-component polyurethane composition made of a polyol component and a polyisocyanate component, wherein the polyol component includes at least one reaction product of castor oil with ketone resins A1, at least one aliphatic triol A2, an aliphatic diol A3, and a polybutadiene polyol A4. The polyurethane composition has high strength and only a minor dependence of mechanical properties, especially of strength, on temperature, especially in the range from −60° C. to +60° C. Moreover, the composition is capable of curing without blistering under ambient conditions, even in the presence of substrates that typically promote foaming reactions owing to the presence of residual moisture, for example glass fiber weave. 2. The two-component polyurethane composition as claimed in claim 1 , wherein the at least one aliphatic diol A3 is selected from the list consisting of butane-1 claim 1 ,4-diol claim 1 , 2-ethylhexane-1 claim 1 ,3-diol claim 1 , 3-methylpentane-1 claim 1 ,5-diol and pentane-1 claim 1 ,5-diol.3. The two-component polyurethane composition as claimed in claim 1 , wherein the ratio of the percentages by weight of ((A1+A2)/(A3+A4)) is 1.6-3.2.4. The two-component polyurethane composition as claimed in claim 1 , wherein the ratio of the percentages by weight of (A4/A3) is 0.8-7.5.5. The two-component polyurethane composition as claimed in claim 1 , wherein the sum total of all OH groups of (A1+A2+A3+A4) is ≥95% of the sum total of all OH groups of the two-component polyurethane composition.6. The two-component polyurethane composition as claimed in claim 1 , wherein the aromatic polyisocyanate B1 comprises oligomers claim 1 , polymers and derivatives derived from MDI.7. The two-component polyurethane composition as claimed in claim 1 , wherein the sum total of the NCO groups that do not originate from B1 is ≤5% claim 1 , based on the sum total of all NCO groups of the two-component polyurethane composition.8. A method of bonding a first substrate to a second ...

METHOD FOR THE PRODUCTION OF THERMOPLASTIC POLYOXAZOLIDINONE POLYMERS

A process for producing thermoplastic polyoxazolidinone, comprising the following steps: (i) Reaction of a diisocyanate compound (A) with a bisepoxide compound (B) in the presence of a catalyst (C) and a compound (D) in a solvent (E) forming an intermediate compound (F) and (ii) Reaction of a compound (G) with the intermediate (F) formed in step (i), wherein the bisepoxide compound (B) comprises isosorbide diglycidylether, wherein compound (D) is one or more compounds selected from the group consisting of monofunctional isocyanate and monofunctional epoxide, and wherein compound (G) is an alkylene oxide. The invention is also related to the resulting thermoplastic polyoxazolidinone. 2. The process according to claim 1 , wherein step (i) comprises:(i-1) placing the solvent and the catalyst in a reactor to provide a mixture,(i-2) placing the diisocyanate compound, the bisepoxide compound and the chain regulator in a vessel to provide a mixture and(i-3) adding the mixture resulting from step (i-2) to the mixture resulting from step (i-1).3. The process according to claim 2 , wherein the mixture resulting from step (i-2) is added in a continuous manner or step-wise manner with two or more individual addition steps to the mixture of step (i-1).4. The process according to claim 2 , wherein the alkylene oxide is added in a step-wise manner with two or more individual addition steps or in continuous manner in step (ii) to the intermediate compound.6. The process according to claim 1 , wherein the catalyst comprises LiCl claim 1 , LiBr claim 1 , LiI claim 1 , MgCl2 claim 1 , MgBr2 claim 1 , MgI2 claim 1 , SmI3 claim 1 , Ph4SbBr claim 1 , Ph4SbCl claim 1 , Ph4PBr claim 1 , Ph4PCl claim 1 , Ph3PBr claim 1 , Ph3PCl claim 1 , Ph3PCl claim 1 , and Ph3(C3H4F)PBr claim 1 , or a mixture of any two or more thereof.7. The process according to claim 1 , wherein the chain regulator comprises phenyl glycidyl ether claim 1 , o-kresyl glycidyl ether claim 1 , m-kresyl glycidyl ether claim ...

ORIENTED BIODEGRADABLE POLYURETHANES

Provided are oriented biodegradable thermoplastic polyurethane films. The films may be prepared by extruding and drawing biodegradable polyurethane films. The polyurethanes may be prepared from biodegradable polyols and/or biodegradable chain extenders. The films possess high tensile strength yet are degradable under biological conditions. The films may be utilized in the fabrication of devices, particularly implantable medical devices. 141-. (canceled)42. An oriented biodegradable thermoplastic polyurethane film , said film being the extruded and drawn product of a biodegradable thermoplastic polyurethane.43. An oriented biodegradable thermoplastic polyurethane film according to claim 42 , wherein the film is biaxially oriented.44. An oriented biodegradable thermoplastic polyurethane film according to claim 42 , wherein the polyurethane is derived from one or more polyols claim 42 , one or more isocyanates and one or more chain extenders.45. An oriented biodegradable thermoplastic polyurethane film according to claim 42 , wherein the polyurethane is derived from one or more aliphatic polyester polyols.46. An oriented biodegradable thermoplastic polyurethane film according to claim 45 , wherein the polyester polyol is derived from one or more diol initiators and one or more hydroxy acids claim 45 , diacids or cyclic esters and combinations thereof.47. An oriented biodegradable thermoplastic polyurethane film according to claim 45 , wherein one or more of the following applies:the polyols have a molecular weight between about 200 and about 2,000 Daltons, or between about 200 and about 1,500 Daltons, or between about 200 and about 1,300 Daltons;the polyols have a molecular weight of less than or equal to about 10,000 Daltons, or less than or equal to about 8,000 Daltons, or less than or equal to about 6,000 Daltons, or less than or equal to about 4,000 Daltons, or less than or equal to about 2,000 Daltons, or less than or equal to about 1,500 Daltons, or less than or ...

ADHESIVE FOR LAMINATE OF METAL FOIL AND RESIN FILM, LAMINATED BODY, BATTERY EXTERIOR PACKAGING MATERIAL, AND BATTERY CASE AND MANUFACTURING METHOD THEREFOR

An adhesive for laminating a metal foil to a resin film, the adhesive including: a polyol (A); a multimer of a polyisocyanate (B); and a metal compound (C) being a compound of at least one metal of Groups 7 and 12, wherein the multimer of a polyisocyanate (B) contains a multimer of a saturated aliphatic polyisocyanate and a multimer of a saturated alicyclic polyisocyanate. Also disclosed is a laminate having a metal foil and a resin film laminated through an adhesive layer obtained from the adhesive for laminating of the invention. Yet further disclosed is a packaging material for a battery casing obtained by using the laminate. Yet further disclosed is a battery case obtained by using the packaging material for a battery casing. Also disclosed is a method for producing a battery case which includes deep drawing or bulging the packaging material for a battery casing. 1. An adhesive for laminating a metal foil to a resin film , the adhesive comprising: a carboxyl group-containing polyolefin resin (A); a polyfunctional isocyanate compound (B); and a metal compound (C) being a compound of at least one metal of Groups 7 and 12.2. The adhesive for laminating a metal foil to a resin film according to claim 1 , wherein the carboxyl group-containing polyolefin resin (A) comprises a modified polyolefin resin comprising claim 1 , as a monomer unit claim 1 , propylene or propylene and ethylene and an ethylenically unsaturated carboxylic acid or an anhydride thereof.3. The adhesive for laminating a metal foil to a resin film according to claim 1 , wherein the carboxyl group-containing polyolefin resin (A) comprises a carboxyl group-containing polyolefin resin having an MFR of 5 g/10 min to 42 g/10 min as measured at 130° C.4. The adhesive for laminating a metal foil to a resin film according to claim 1 , wherein the polyfunctional isocyanate compound (B) comprises a multimer of a polyisocyanate.5. The adhesive for laminating a metal foil to a resin film according to claim 1 , ...

SILANE-TERMINATED ADHESIVE FOR JOINING JOINTS IN THE NAVAL FIELD

An adhesive which includes at least one silane-functional polymer P; at least one catalyst for crosslinking silane-functional polymers, the catalyst being selected from the group including organo-titanate, organo-zirconate, and organo-aluminate; at least one base; and at least one adhesive selected from alkoxy mercaptosilane and amino alkoxysilane, for filling wood joints. The adhesive filled into the joints is preferably sanded after the curing process. The adhesive exhibits a high UV stability and a stability against warm humid climates. The adhesive is therefore suitable for naval applications in particular, such as in the construction of boats and ships. The adhesive can be formulated so as to be black, white, or gray for example. 1. An adhesive comprisingat least one silane-functional polymer P;at least one catalyst for the crosslinking of silane-functional polymers, selected from the group consisting of organotitanate, organozirconate, and organoaluminate;at least one base; andat least one adhesion promoter selected from alkoxymercaptosilane and aminoalkoxysilanefor filling wood joints, the wood being natural or synthetic wood.2. An adhesive as claimed in claim 1 , wherein the adhesive is sanded after having cured.3. An adhesive as claimed in claim 1 , wherein the cured and sanded adhesive claim 1 , after 3000 hours in the QUV tester claim 1 , with 8-fold magnification claim 1 , shows no cracks claim 1 , wherein claim 1 , if the adhesive is white claim 1 , beige or gray claim 1 , the color difference delta E between the cured and sanded adhesive before weathering in the QUV tester and after the 3000 hours in the QUV tester is less than 2.4. An adhesive as claimed in claim 1 , wherein the silane-functional polymer P contains no methoxysilane groups.5. An adhesive as claimed in claim 1 , wherein the adhesive is phthalate-free and/or comprises no Sn catalyst.6. An adhesive as claimed in claim 1 , wherein the adhesion promoter is an ethoxymercaptosilane.7. An ...

Thermo-mechanical processing of nickel-base alloys

A thermo-mechanical treatment process is disclosed. A nickel-base alloy workpiece is heated in a first heating step to a temperature greater than the M 23 C 6 carbide solvus temperature of the nickel-base alloy. The nickel-base alloy workpiece is worked in a first working step to a reduction in area of 20% to 70%. The nickel-base alloy workpiece is at a temperature greater than the M 23 C 6 carbide solvus temperature when the first working step begins. The nickel-base alloy workpiece is heated in a second working step to a temperature greater than 1700° F. (926° C.) and less than the M 23 C 6 carbide solvus temperature of the nickel-base alloy. The nickel-base alloy workpiece is not permitted to cool to ambient temperature between completion of the first working step and the beginning of the second heating step. The nickel-base alloy workpiece is worked to a second reduction in area of 20% to 70%. The nickel-base alloy workpiece is at a temperature greater than 1700° F. (926° C.) and less than the M 23 C 6 carbide solvus temperature of the nickel-base alloy when the second working step begins.

Adhesive film for polarizing plate, polarizing plate comprising the same and optical display apparatus comprising the same

An adhesive film for polarizing plates, a polarizing plate including the same, and an optical display apparatus including the same are provided. An adhesive film for polarizing plates is formed of an adhesive composition including a (meth)acrylic copolymer, an isocyanate curing agent, a metal chelate curing agent, and an antistatic agent, and has a surface resistance difference ΔSR of 1.0 (log(Ω/□)) or less, as calculated by Equation 1 and, in Equation 1, SR1 is 10 (log(Ω/□)) or less.

POLYMERIZABLE COMPOSITION AND COMPOSITE MATERIAL

The present invention relates to polymerizable composition containing a cycloolefin monomer, a metathesis polymerization catalyst, a radical generator, a diisocyanate compound, and a polyfunctional (meth)acrylate compound. The composite material produced by using a polymerizable composition of the present invention has excellent mechanical strength and does not cause odor. 1. A polymerizable composition comprising a cycloolefin monomer , a metathesis polymerization catalyst , a radical generator , a diisocyanate compound , and a polyfunctional (meth)acrylate compound.3. A composite material wherein a polymerizable composition as defined in which is impregnated with a fibrous filler is cured.4. The composite material according to claim 3 , wherein the fibrous filler is a unidirectional material claim 3 , and wherein the flexural strength in a substantially perpendicular direction of said composite material against a direction of filling of the fibrous filler is 60 MPa or more.5. The composite material according to claim 3 , wherein the fibrous filler is one or more members selected from the group consisting of carbon fibers and glass fibers.6. A method for producing a composite material as defined in claim 3 , comprising the steps of:(1) placing a fibrous filler in a mold;(2) impregnating the fibrous filler with the polymerizable composition;(3) subjecting the polymerizable composition which is impregnated with a fibrous filler to a bulk polymerization to cure the polymerizable composition whereby to provide a composite material; and(4) demolding the composite material.7. The method according to claim 6 , wherein the highest temperature during the bulk polymerization is 90° C. or higher and 300° C. or lower. The present invention relates to a polymerizable composition and a composite material in which the polymerizable composition impregnated with a fibrous filler is cured. Further, the present invention relates to a method for producing the composite material.So far ...

POLYURETHANE FOAM PREMIXES CONTAINING HALOGENATED OLEFIN BLOWING AGENTS AND FOAMS MADE FROM SAME

Disclosed are polyol premix compositions, and foams formed therefrom, which comprise a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a catalyst system that includes a bismuth-based metal catalyst. Such catalysts may be used alone or in combination with an amine catalyst and/or other non-amine catalysts. 1. A method of forming a thermoset foam comprising:forming a polyol premix comprising: (a) from about 60 wt % to about 95 wt % of polyol; (b) from about 1 wt % to about 30 wt % of blowing agent, said blowing agent comprising from about 7 wt % to about 98 wt % by of 1-chloro-3,3,3-trifluoropropene; (c) at least one surfactant; and (d) a catalyst system comprising metal-based catalyst, wherein said metal based-catalyst consists essentially of at least one bismuth-based metal catalyst;using said polyol premix after a storage period of at least one month to form a foamable composition,forming a foam from said foamable composition, provided that said polyol premix is sufficiently free of non-bismuth-based catalyst such that said foam has a cream time of not greater than 10 seconds.2. The method of wherein said foam formed from said polyol premix has a cream time of not greater than 10 seconds when aged for 3 months at room temperature.3. The method of wherein said bismuth-metal catalyst comprises a catalyst represented by the formula Bi—(R) claim 1 , wherein each R is independently selected from the group consisting of a hydrogen claim 1 , a halide claim 1 , a hydroxide claim 1 , a sulfate claim 1 , a carbonate claim 1 , a cyanate claim 1 , a thiocyanate claim 1 , an isocyanate claim 1 , a isothiocyanate claim 1 , a carboxylate claim 1 , an oxalate claim 1 , a C-Calkane claim 1 , a C-Calkene claim 1 , a C-Calkyne claim 1 , a heteroalkyl group claim 1 , an aryl group claim 1 , a ketone claim 1 , an aldehyde claim 1 , an esters claim 1 , an ether claim 1 , an alcohol claim 1 , an alcoholate claim 1 , a phenolate claim 1 , a glycolates ...

TIN FREE POLYMER POLYOLS

Embodiments include polymer polyol dispersions which include a polyol liquid phase and solid particle phase. Embodiments include methods of making the polymer polyol dispersions. The polymer polyol dispersions are essentially free of tin, have a solid content of between about 20 and 50 wt % based on the total weight of the polymer polyol dispersion, and have a viscosity at 20C of less than 9000 mPas. The solid particle phase has more than 90% by weight of particles in the solid particle phase having a particle diameter of less than 5 μm. 1. A method of producing a polymer polyol dispersion , the method comprising:1) in a first step, a) combining at least one of a tin-free catalyst, at least one of a polyol, and at least one of a co-reactant, wherein the co-reactant has an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom, and b) introducing at least one polyisocyanate to create a polymer polyol having a first solid content; and2) in a second step, a) introducing at least one of a co-reactant to the polymer polyol, wherein the co-reactant has an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom, b) introducing at least one polyisocyanate to create a polymer polyol having a second solid content.2. The method of claim 1 , further comprising repeating the second step at least 1 time until a final polymer polyol having a final solid content is obtained.3. The method of any claim 1 , wherein in step 1 claim 1 , the at least one of a tin-free catalyst is combined with the at least one of a co-reactant before being combined with the at least one of a polyol.4. The method of claim 1 , wherein the first solid content is between 1 and 15 wt % based on the total weight of the polymer polyol having a first solid content.5. The method of claim 4 , wherein the second solid content is between 2 and 25 wt % based on the total weight of the polymer polyol having a second solid ...

POLYBUTADIENOLS FOR PRODUCING GLASSY POLYURETHANES

The invention relates to a process for the production of polybutadienols from polybutadienes with number-average molar mass from 300 to 2000 g/mol comprising from 20 to 50% of 1,4 double bonds and from 50 to 80% of 1,2 vinylic and 1,2 cyclovinylic double bonds, based on the quantity of all of the double bonds, comprising the steps of 1. A process for the production of polybutadienols having a hydroxy equivalent mass from 250 to 750 g from polybutadienes with number-average molar mass from 300 to 2000 g/mol comprising from 20 to 50% of 1 ,4 double bonds and from 50 to 80% of 1 ,2 vinylic and 1 ,2 cyclovinylic double bonds , based on [[the]] a quantity of all of the double bonds , comprising the steps ofi) epoxidation of at least one of the 1,4 double bonds with an epoxidizing reagent which selectively epoxidizes 1,4 double bonds, andii) reaction of the epoxidized polybutadiene with a monoalcohol or water to give a polybutadienol.2. The process according to claim 1 , wherein the epoxidizing reagent is performic acid.3. The process according to claim 1 , wherein the monoalcohol is a primary alcohol.4. The process according to claim 3 , wherein the monoalcohol is selected from the group consisting of ethanol claim 3 , 1-propanol claim 3 , and 1-butanol.5. A polybutadienol obtainable by the process according to .6. The polybutadienol according to claim 5 , which comprises>90% of secondary OH groups claim 5 , based on a quantity of all of the OH groups.7. A polyurethane with glass transition temperature at least 15° C. claim 5 , obtainable via reaction of;a) polyisocyanates A with{'claim-ref': {'@idref': 'CLM-00005', 'claim 5'}, 'b) polybutadienols B according to .'}8. (canceled)9. The polyurethane according to claim 7 , obtainable via reaction of:a) polyisocyanates A with{'claim-ref': {'@idref': 'CLM-00005', 'claim 5'}, 'b) polybutadienols B according to , and'}c) other compounds C having at least 2 hydrogen atoms reactive toward isocyanates.10. The polyurethane ...

POLYISOCYANATE CURED PRODUCT, AND METHOD FOR PRODUCING POLYISOCYANATE CURED PRODUCT

The polyisocyanate cured product according to the present invention has an isocyanurate structure, which comprises at least one diisocyanate selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate, as a unit structure, the polyisocyanate cured product having an allophanate group, and the molar ratio of the isocyanurate group to the allophanate group (isocyanurate group/allophanate group) is 99/1 to 20/80. 1. A polyisocyanate cured product comprising an isocyanurate structure , which comprises at least one diisocyanate selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate , as a unit structure , the polyisocyanate cured product having an allophanate group ,wherein a molar ratio of an isocyanurate group to the allophanate group (isocyanurate group/allophanate group) is 99/1 to 20/80.2. The polyisocyanate cured product according to claim 1 , wherein the molar ratio of the isocyanurate group to the allophanate group (isocyanurate group/allophanate group) is 99/1 to 50/50.3. The polyisocyanate cured product according to claim 1 , wherein a yellowness index (YI) in a case of 1 mm thickness is 10 or smaller claim 1 , and a change in a yellowness index (YI) in a thermal yellowing resistance test under conditions of 150° C.×144 hours is 10 or smaller.5. The method for producing the polyisocyanate cured product according to claim 4 , wherein a molar ratio of the isocyanurate group to the allophanate group (isocyanurate group/allophanate group) in the polyisocyanates in the polyisocyanate composition is 99/1 to 30/70.6. The method for producing the polyisocyanate cured product according to claim 5 , wherein the polyisocyanate composition is a polyisocyanate composition obtained by using a monoalcohol having 3 to 9 carbon atoms as one of the starting materials.7. The method for producing the polyisocyanate cured product according to claim 4 , wherein an isocyanate group (NCO group) content of the ...

Two-Component Solvent-Based Adhesive Composition

The present disclosure provides a two-component adhesive composition. The two-component solvent-based adhesive composition contains the reaction product of (A) an isocyanate component; (B) a dimer acid polyester polyol component containing the reaction product of a reaction mixture including (i) from 20 wt % to 60 wt % dimer acid, based on the total weight of the dimer acid polyester polyol component, (ii) a dicarboxylic acid, and (iii) a polyol; and (C) a solvent. 1. A two-component solvent-based adhesive composition comprising the reaction product of:(A) an isocyanate component;{'claim-text': ['(i) from 20 wt % to 60 wt % dimer acid, based on the total weight of the dimer acid polyester polyol component;', '(ii) a dicarboxylic acid;', '(iii) a polyol; and'], '#text': '(B) a dimer acid polyester polyol component comprising the reaction product of a reaction mixture comprising'}(C) a solvent.2. The two-component solvent-based adhesive composition of claim 1 ,wherein the dicarboxylic acid is selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, azelaic acid, sebacic acid, adipic acid, and combinations thereof.3. The two-component solvent-based adhesive composition of claim 1 , wherein the polyol is selected from the group consisting of 2-methyl-1 claim 1 , 3-propanediol claim 1 , trimethylolpropane claim 1 , 1 claim 1 , 4-butanediol claim 1 , 1 claim 1 , 6-hexanediol claim 1 , and neopentyl glycol (NPG) claim 1 , and combinations thereof.4. The two-component solvent-based adhesive composition of claim 1 , wherein the isocyanate is a multifunctional isocyanate.5. The two-component solvent-based adhesive composition of claim 1 , wherein the isocyanate component has an average NCO functionality from 2.2 to 5.0.6. The two-component solvent-based adhesive composition of claim 1 , wherein the two-component solvent-based adhesive composition has a Polyol:Isocyanate Weight Ratio from 100:5 to 100:35.7. A laminate comprisinga first ...

Urethane acrylate hybrid structure adhesives

A polymerizable adhesive composition comprising a two-part hybrid polymerizable adhesive composition is disclosed. In particular, the polymerizable adhesive composition comprises an organoborane monoamine complex, a free polyol comprising a dimer fatty polyol and a polyether polyol, at least one free radically polymerizable component, an isocyanate-terminated urethane pre-polymer, a free isocyanate and a low molecular weight chain extending compound. Also disclosed is methods of making and using a hybrid adhesive obtained from polymerization of the polymerizable adhesive composition

Polyurethane Elastomers for Use in Subsea Pipeline Insulation

Polyurethane systems that cure similarly to systems based on mercury catalysts contain 1,4-butanediol and a zinc carboxylate catalyst. These systems cure and develop green strength similarly to systems based on mercury catalysts. These systems are especially useful in making insulated pipe joints for subsea pipeline installations. 1. A cured polyurethane elastomer which is a reaction product of a reaction mixture comprising at least one polyether polyol having a hydroxyl equivalent weight of at least 1000 , 1 to 20 parts by weight of 1 ,4-butanediol per 100 parts by weight of the polyether polyol(s) , an aromatic polyisocyanate in amount to provide an isocyanate index of 80 to 130 and a zinc carboxylate catalyst.2. The cured polyurethane elastomer of wherein the reaction mixture further contains an epoxy resin in an amount up to 20 parts by weight per 100 parts by weight of the polyether polyol(s) claim 1 , the reaction mixture is essentially devoid of a catalyst for the reaction of epoxy group with an isocyanate group to form an oxazolidinone and essentially devoid of an amine curing agent or sulfide curing agent claim 1 , and the cured elastomer contains epoxy groups from the epoxy resin.3. The cured elastomer of wherein the amount of metal carboxylate catalyst is 0.01 to 0.5 parts by weight per 100 parts by weight of the polyether polyol(s) that have an equivalent weight of at least 1000.4. The cured elastomer of wherein the reaction mixture contains no more than 2 parts by weight claim 3 , per 100 parts by weight of the polyether polyol(s) that have an equivalent weight of at least 1000 claim 3 , of one or more isocyanate-reactive materials other than the polyether polyol and the 1 claim 3 ,4-butanediol.5. The cured elastomer of which is non-cellular.6. The cured elastomer of which is non-cellular.7. The cured elastomer of wherein the reaction mixture contains no more than 0.25 weight percent water claim 6 , based on the entire weight of the reaction mixture.8. ...

A Method For Improving Toughness of Polyisocyanate Polyaddition Reaction Products

Use of compounds selected from polyols derived from dimer fatty acids and/or dimer fatty alcohols as toughening agent in a process for making polyisocyanate polyaddition reaction products, in particular for polyisocyanate polyaddition reaction products having a hardblock >40% and a process for making said products. 1. A method for improving the toughness of polyisocyanate polyaddition reaction products having a glass transition temperature of at least 80° C. said method comprising at least reacting at an isocyanate index of at least 100:(a) isocyanates, and(b) isocyanate-reactive compounds, and optional(c) catalyst compounds, and optional(d) blowing agents and/or other auxiliary compoundscharacterized in that the isocyanate-reactive compounds (b) comprise 1-20 pbw of compounds selected from polyols derived from dimer fatty acids and/or dimer fatty alcohols (calculated on the total weight of ingredients (a)-(d)) and wherein the hardblock content of the polyisocyanate polyaddition reaction products is at least 40%.2. The method according to claim 1 , wherein the polyols derived from dimer fatty acids and/or dimer fatty alcohols are selected from polyester polyols derived from dimer fatty acids.3. The method according to claim 1 , wherein the dimer fatty acids are selected from dimer fatty acids wherein the fatty acid is selected from C10-C30.4. The method according to claim 1 , wherein the dimer fatty acids includes dimerisation products of oleic acid claim 1 , linoleic acid claim 1 , linolenic acid claim 1 , palmitoleic acid and/or elaidic acid.5. The method according to claim 1 , wherein the isocyanate-reactive compounds (b) comprise preferably 2.5 up to 7 pbw of compounds selected from polyols derived from dimer fatty acids and/or dimer fatty alcohols (calculated on the total weight of ingredients (a)-(d)).6. The method according to claim 1 , wherein the isocyanate-reactive compounds (b) comprise polyamines and/or polyetherpolyols and/or polyesterpolyols having an ...

NON-TIN CATALYST FOR CURING ALKOXYSILYL-CONTAINING POLYMER

A non-tin catalyst for accerating the curing of alkoxysilyl-containing polymer contains a mixture and/or complex of organotitanium compound and a compound containing at least one (-)N—C═N— linkage. 1. A moisture-curable composition comprising:a) at least one alkoxysilyl-containing polymer;{'sub': '2', 'b) at least one non-tin cure catalyst comprising a mixture and/or complex of an organotitanium compound and compound containing at least one (-)N—C═N— linkage.'}2. The moisture-curable composition of wherein the alkoxysilyl-containing polymer (a) has 2 or 3 alkoxy groups.3. The moisture-curable composition of wherein of the alkoxysilyl-containing polymer (a) has at least one alkoxy group containing at least 2 carbon atoms.4. The moisture-curable composition of wherein alkoxysilyl-containing polymer (a) has 2 or 3 alkoxy groups claim 1 , each such group containing at least 2 carbon atoms.5. The moisture-curable composition of wherein alkoxysilyl-containing polymer (a) is an alkoxysilyl-containing silicone resin.6. The moisture-curable composition of wherein the alkoxysilyl-containing silicone resin comprises divalent units of the formula RSiO in the backbone wherein each R group independently is C-C-alkyl; C-Calkyl substituted with one or more of Cl claim 5 , F claim 5 , N claim 5 , O or S; phenyl; C-Calkylaryl; C-Carylalkyl; or C-Cpolyoxyalkylene ether or a combination of two or more such groups.9. The moisture-curable composition of wherein alkoxysilyl-containing polymer (a) is a non-silicone resin.11. The moisture-curable composition of wherein polymer residue P is chosen from one of polyether claim 10 , polyester claim 10 , polyether-co-polyester claim 10 , polyester-co-polyether claim 10 , polythioether claim 10 , polyamine claim 10 , polyamide claim 10 , polyester-co-polyamide claim 10 , polyacrylate claim 10 , polyacetal claim 10 , polycarbonate claim 10 , polybutadiene claim 10 , polyolefin claim 10 , polyurethane claim 10 , polyurea claim 10 , polyacrylate ...

Compounds for Coordinating with a Metal, Compositions Containing Such Compounds, and Methods of Catalyzing Reactions

A compound capable of coordinating with a metal includes a chemical structure as shown in claim , in which: EPD represents a group having an electron pair donor atom; B and B′ are each independently an aryl group, a heteroaryl group, an alkenyl group, or alkynyl group, or B and B′ form a spirocyclic group; and R, R, and Rare selected from various substituents. 2. (canceled)3. The compound of claim 1 , wherein the EPD of Formula (II)-B comprises a nitrogen atom claim 1 , an oxygen atom claim 1 , a phosphorus atom claim 1 , a carbene or a cyclic ring comprising at least one of a nitrogen atom claim 1 , an oxygen atom claim 1 , and/or a phosphorus atom.4. The compound of claim 1 , wherein a substituent of each carbon atom located at positions 5-7 independently comprises a hydroxyl group claim 1 , an alkyl group claim 1 , an aryl group claim 1 , a haloalkyl group claim 1 , an alkoxy group claim 1 , an amino group claim 1 , a nitrogen-containing heterocycle group claim 1 , an alkylthio group claim 1 , an arylthio group claim 1 , an aryloxy group claim 1 , an aralkyl claim 1 , a nitrile group claim 1 , a nitro group claim 1 , a formyl group claim 1 , a carboxylic acid group claim 1 , a ketone group claim 1 , an ester group claim 1 , a carboxylate group claim 1 , a halo group claim 1 , a group comprising a siloxane claim 1 , an alkenyl group claim 1 , an alkynyl group claim 1 , or any combination thereof or where a substituent of a carbon atom at one of positions 5-7 forms a fused ring with a substituent of an adjacent carbon atom.5. (canceled)7. The compound of claim 6 , wherein Rcomprises an alkenyl group substituted with two substituents that are the same as B and B′ and n is 1.8. (canceled)10. (canceled)11. The composition of claim 9 , wherein the reactive material comprises the active hydrogen functional first component and the second component reactive with the active hydrogen groups of the first component.12. The composition of claim 11 , wherein the active hydrogen ...

AROMATIC POLYISOCYANATES WITH A HIGH SOLIDS CONTENT

The invention relates to an aromatic allophanate polyisocyanate based on aromatic diisocyanates, containing a) ≥15 mol-% of allophanate groups, based on the sum of urethane, allophanate and isocyanurate groups, b) ≤50 mol-% of isocyanurate groups, based on the sum of urethane, allophanate and isocyanurate groups and c) ≤1.5% by weight of monomeric diisocyanates, based on the total weight of the aromatic allophanate polyisocyanate. Furthermore, the invention relates to a process for producing aromatic allophanate polyisocyanates and their use in polyisocyanate compositions or two-component systems. 1: An aromatic allophanate polyisocyanate based on aromatic diisocyanates , containinga) ≥15 mol-% of allophanate groups, based on the sum of urethane, allophanate and isocyanurate groups,b) ≤50 mol-% of isocyanurate groups, based on the sum of urethane, allophanate and isocyanurate groups andc) ≤1.5% by weight of monomeric diisocyanates, based on the total weight of the aromatic allophanate polyisocyanate.2: The aromatic allophanate polyisocyanate according to claim 1 , containing ≥20 mol-% of allophanate groups claim 1 , based on the sum of urethane claim 1 , allophanate and isocyanurate groups.3: The aromatic allophanate polyisocyanate according to claim 1 , containing ≤40 mol-% of isocyanurate groups claim 1 , based on the sum of urethane claim 1 , allophanate and isocyanurate groups.4: The aromatic allophanate polyisocyanate according to claim 1 , containing ≤1.0% by weight of monomeric diisocyanates claim 1 , based on the total weight of the aromatic allophanate polyisocyanate.5: The aromatic allophanate polyisocyanate according to claim 1 , wherein the aromatic diisocyanate is selected from the group consisting of toluene 2 claim 1 ,4-diisocyanate claim 1 , toluene 2 claim 1 ,6-diisocyanate claim 1 , and a mixture of toluene 2 claim 1 ,4- and 2 claim 1 ,6-diisocyanate.6: The aromatic allophanate polyisocyanate according to claim 1 , wherein the aromatic diisocyanate ...

Zinc-imidazole-carboxylate-complex-catalysed coating agent composition

The invention relates to coating material compositions comprising an isocyanate group-containing component, a hydroxyl group-containing component, a zinc-imidazole-carboxylate complex and a monomeric aromatic carboxylic acid, and also to the use of a zinc-imidazole-carboxylate complex in the presence of a monomeric aromatic carboxylic acid as a catalyst system for the urethane reaction in coating material compositions.

POLYURETHANE COATING COMPOSITION

Methods of making a two-component composition that can be applied to a substrate and cured to provide a coating that demonstrates minimal solvent pop at the dry film thickness limit of the coating are provided. A cured coating made from the two-component composition demonstrates minimal solvent pop, minimal air entrapment, and optimal dry spray and overspray acceptance. Coated articles made using the methods described herein are also provided 2. A method , comprising: two or more solvents; and', 'a catalyst;, 'providing a first component of a coating composition, including a reaction mixture comprisingproviding a second component of the coating composition, wherein the second component is capable of reacting with the first component;combining the first and second components to obtain the coating composition; andapplying the composition to a substrate and drying at temperatures of 25° C. up to about 160° C. to form a cured coating,wherein the cured coating demonstrates minimal solvent pop at the dry film thickness limit of the cured coating.3. The method of claim 1 , wherein the first component includes at least one polyol.4. The method of claim 1 , wherein the second component includes at least one polyisocyanate.5. The method of claim 1 , wherein the mixture of one or more solvents includes water.6. The method of claim 1 , wherein the mixture of one or more solvents includes at least one compound with at least one alpha-hydrogen.7. The method of claim 1 , wherein the mixture of one or more solvents includes at least one compound that is a bidentate ligand capable of chelation with a metal catalyst or metal-containing species.8. The method of claim 1 , wherein the mixture of one or more solvents includes at least one compound selected from beta-dicarbonyl compounds claim 1 , alpha-hydroxy ketones claim 1 , fused aromatic beta-hydroxy ketones claim 1 , beta-hydroxy nitrogen-heterocyclic fused aromatics claim 1 , and mixtures or combinations thereof.9. The method of ...

AQUEOUS COATING COMPOSITION WITH SOFT TOUCH UPON DRYING

Aqueous coating compositions include dispersed polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane. The polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, and the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt. % of at least one active-hydrogen chain extending compound with a functionality of at least 2 other than water, (e) from 0 to 10 wt. % of at least one diol having a molecular weight below 500 g/mol. The isocyanate and hydroxy groups on the components used are present in a respective mole ratio (NCO to OH) in the range of from 0.8:1 to 5:1. 1. An aqueous coating composition comprising dispersed polymer particles , wherein(i) the dispersed polymer particles are polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane,(ii) the polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, preferably from 2:1 to 16:1, even more preferably from 3:1 to 12:1, even more preferably from 4:1 to 12:1 and even more preferably from 4:1 to 10:1, (a) from 5 to 40 wt. %, preferably from 10 to 35 wt. % of at least one organic difunctional isocyanate,', '(b) from 0.5 to 4 wt. %, preferably from 0.8 to 3.2 wt. % and even more preferably from 1 to 2.5 wt % of an isocyanate-reactive compound containing ionic or potentially ionic water- ...

CURABLE COMPOSITION, AND CURED SYNTHETIC RESIN USING SAME

[Problem] To provide a curable composition having high stability and excellent curing properties. [Solution] The present invention relates to a curable composition, and a cured synthetic resin using same, that functions as a curing catalyst for a synthetic resin. The curable composition contains (A) a titanium alkoxide, (B) a bidentate organic chelating agent that stabilizes the titanium alkoxide and (C) a guanidine compound. The molar ratio of the titanium alkoxide (A), the bidentate organic chelating agent (B), and the guanidine compound (C) is 1:0.5-3:0.5-2. 1. A curable composition serving as a curing catalyst for a synthetic resin , comprising(A) a titanium alkoxide,(B) a bidentate organic chelating agent for stabilizing the titanium alkoxide, and(C) a guanidine compound,wherein the composition comprises the titanium alkoxide (A), the bidentate organic chelating agent (B) and the guanidine compound (C) in a molar ratio of 1:0.5 to 3:0.5 to 2.2. The curable composition according to claim 1 , whereinthe bidentate organic chelating agent (B) is at least one of ethyl acetoacetate and acetylacetone, andthe guanidine compound (C) is at least one of 1-phenylguanidine and 1,1,3,3-tetramethylguanidine.3. A synthetic resin cured by using the curable composition according to to produce silanol condensation of polydimethylsiloxane having a reactive silanol group.4. A synthetic resin cured by using the curable composition according to and an alkoxysilane as a crosslinking agent to produce a siloxane bond of polydimethylsiloxane having a reactive silanol group.5. A synthetic resin cured by using the curable composition according to to produce a siloxane bond of a crosslinkable silyl group-containing polymer having a polyether or an acrylic polymer as a main chain.6. A synthetic resin cured by using the curable composition according to to produce a urethane bond due to a reaction of a polyol and a polyisocyanate. The present application claims the priority based on Japanese ...

URETHANE EXCHANGE CATALYSTS AND METHODS FOR REPROCESSING CROSS-LINKED POLYURETHANES

Disclosed herein are polyurethane compositions and methods for reprocessing cross-linked polyurethane compositions. The polyurethane composition comprises a network polymer and a poluyurethane exchange catalyst permeated within the network polymer. The network polymer comprises a dynamic network formed from an isocyanate constitutional unit and a second constitution unit having a hydroxyl group capable of reacting with an isocyanate group of the isocyanate constitutional unit to form a urethane bond. The catalyst comprises a metal atom and a ligand coordinated to the metal atom. 1. A polyurethane composition comprising a network polymer and a polyurethane exchange catalyst permeated within the network polymer ,wherein the network polymer comprises a dynamic network formed from an isocyanate constitutional unit and a second constitution unit having a hydroxyl group capable of reacting with an isocyanate group of the isocyanate constitutional unit to form a urethane bond;wherein the polyurethane exchange catalyst comprises a metal selected from Bi, Fe, Zr, Ti, Hf, Al, Zn, Cu, Ni, Co, Mn, V, Sc, Y, Ce, or Mo and a ligand coordinated with the metal atom; andwherein a mol % of the polyurethane exchange catalyst to total isocyanate functionality is less or equal to 5 mol %.2. The composition of claim 1 , wherein the catalyst comprises Bi(neo) claim 1 , Fe(acac) claim 1 , Ti(OiPr)(acac) claim 1 , Hf(acac) claim 1 , Zr(acac) claim 1 , Mn(acac) claim 1 , Bi(oct) claim 1 , Zn(tmhd) claim 1 , Zr(tmhd) claim 1 , or any combination thereof.3. The composition of claim 2 , wherein the catalyst is Bi(neo).4. The composition of claim 2 , wherein the catalyst is Fe(acac).5. The composition of claim 1 , wherein the second constitutional unit is a prepolymer molecule comprising a polyether claim 1 , a polyester claim 1 , a polycarbonate claim 1 , a polyacrylate claim 1 , a polyolefin claim 1 , a polybutadiene claim 1 , a polysulfide claim 1 , or a polysiloxane.6. The composition of ...

FOAM INSULATION WITH ENHANCED FIRE AND SMOKE PERFORMANCE

A polyisocyanurate foam insulation product includes polyisocyanurate foam produced from reacting an isocyanate and a polyol blend having a functionality of at least 2.2. The isocyanate and the polyol blend are reacted so that the polyisocyanurate foam has an isocyanate index equivalent with or greater than 300. The polyisocyanurate foam includes a fire retardant and includes between 0.02 and 0.45 weight percent of a zinc salt compound. The foam insulation board exhibits a flame spread of no greater than 25 and a smoke index of no greater than 50 when exposed to flame conditions in accordance with an ASTM E-84 test. 1. A method of producing a foam insulation board comprising:reacting an isocyanate with a polyol blend to form a polyisocyanurate foam, the polyol blend having a functionality of at least 2.2 and the isocyanate and the polyol blend being reacted so that the polyisocyanurate foam has an isocyanate index equal to or greater than 300;adding a blowing agent to the polyisocyanurate foam;adding a fire retardant to the polyisocyanurate foam; andadding between 0.02 and 0.45 weight percent of a zinc salt compound to the polyisocyanurate foam;wherein the foam insulation board exhibits a flame spread of no greater than 25 and a smoke index of no greater than 50 when exposed to flame conditions in accordance with an ASTM E-84 test.2. The method of claim 1 , wherein the zinc salt compound comprises a zinc carboxylate.3. The method of claim 2 , wherein adding the zinc salt compound to the polyisocyanurate foam comprises adding between 0.045 and 0.23 weight percent of the zinc carboxylate to the polyisocyanurate foam.4. The method of claim 2 , wherein adding the zinc salt compound to the polyisocyanurate foam comprises adding between 0.045 and 0.14 weight percent of the zinc carboxylate to the polyisocyanurate foam.5. The method of claim 1 , wherein the fire retardant is non-halogenated.6. The method of claim 5 , wherein the fire retardant comprises diethyl ...

SYSTEMS AND METHODS FOR FORMING POLYURETHANES

A reaction system for forming a thermoset urethane or polyurethane comprising at least one polyol, at least one isocyanate, and a zinc-containing catalyst. In some aspects, the polyol may be a monomeric polyol comprising secondary hydroxyl groups or it may be a polymeric polyol comprising residues of the monomeric polyol. The zinc-containing catalyst may be effective for catalyzing the reaction of the polyol and isocyanate, particularly when at least a portion of the secondary hydroxyl groups in the monomeric or polymeric polyol are hindered secondary hydroxyl groups. Urethanes and polyurethanes formed as described herein may be used in coating compositions, including powder coating compositions, solvent-based coating compositions, and waterborne coating compositions, as well as in many other applications. 1. A reaction system for forming a urethane and/or polyurethane , said reaction system comprising:(a) at least one of a monomeric polyol having hindered secondary hydroxyl groups and a polymeric polyol comprising residues of said monomeric polyol;(b) an isocyanate; and(c) a zinc-containing catalyst.2. The system of claim 1 , wherein component (a) comprises said polymeric polyol claim 1 , wherein said polymeric polyol comprises a plurality of primary hydroxyl groups and a plurality of secondary hydroxyl groups claim 1 , wherein at least 5 weight percent of the total amount of said primary hydroxyl groups and said secondary hydroxyl groups of said polymeric polyol are secondary hydroxyl groups.3. The system of claim 2 , wherein said polymeric polyol is a polyester polyol and wherein said polyester polyol comprises about 5 to about 65 weight percent of said residues of said monomeric polyol.4. The system of claim 3 , wherein at least 15 weight percent of the total amount of said primary hydroxyl groups and said secondary hydroxyl groups of said polymeric polyol are secondary hydroxyl groups claim 3 , wherein said isocyanate is an aliphatic isocyanate claim 3 , and ...

Photo-latent titanium oxo-chelate catalysts

A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 independently of each other are for example hydrogen, halogen, C 1 -C 20 alkyl, C 6 -C 14 aryl which is unsubstituted or substituted; or R 1 , R 2 and R 3 and/or R 4 , R 5 and R 6 and/or R 7 , R 8 and R 9 and/or R 10 , R 11 and R 12 together with the C-atom to which they are attached each form a C 6 -C 14 aryl group which is unsubstituted or substituted; or R 1 and R 2 and/or R 4 and R 5 and/or R 7 and R 8 and/or R 10 and R 11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (IIa), (IIb) or (IIc), wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are defined as above for formula (I), is suitable as a photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.

Polyisocyanates having thioallophanate structure

The invention relates to polyisocyanates that have aliphatically, cycloaliphatically, araliphatically and/or aromatically bonded isocyanate groups and contain thioallophanate structures of formula (I), to a method for producing them, and to their use as starting components in the production of polyurethane plastics.

SULFONATED FLUORINATED, NON-FLUORINATED OR PARTIALLY FLUORINATED URETHANES

The invention relates to a compound prepared by (i) reacting (a) at least one compound selected from diisocyanate, polyisocyanate, or mixture thereof; (b) at least one isocyanate-reactive compound selected from a fluorinated alcohol; a cyclic or acyclic sugar alcohol which is substituted with at least one —R, —C(O)R, —(CHCHO)(CH(CH)CHO)R, —(CHCHO)(CH(CH)CHO)C(0)R, or mixtures thereof; or mixtures of a fluorinated alcohol and a substituted cyclic or acyclic sugar alcohol; and (c) at least one isocyanate-reactive ethylenically unsaturated compound; wherein each n is independently 0 to 20; each m is independently 0 to 20; m+n is greater than 0; each Ris independently a linear or branched alkyl group having 5 to 29 carbons optionally comprising at least 1 unsaturated bond; each Ris independently —H, or a linear or branched alkyl group having 6 to 30 carbons optionally comprising at least 1 unsaturated bond, or mixtures thereof; and (ii) reacting the reaction product of step (i) with a bisulfate source. 1. (canceled)2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. (canceled)7. (canceled)8. (canceled)9. (canceled)10. A method of preparing a compound comprising:{'sup': 1', '1', '2', '1', '1', '1', '2', '1, 'sub': 2', '2', 'n', '3', '2', 'm', '2', '2', 'n', '3', '2', 'm', '2', '2', 'n', '3', '2', 'm', '2', '2', 'n', '3', '2', 'm, '(i) reacting (a) at least one isocyanate group-containing compound selected from diisocyanate, polyisocyanate, or mixture thereof; (b) at least one isocyanate-reactive compound selected from the group consisting of a fluorinated alcohol; a cyclic or acyclic sugar alcohol which is substituted with at least one —R, —C(O)R, —(CHCHO)(CH(CH)CHO)R, —(CHCHO)(CH(CH)CHO)C(O)R, or mixtures thereof; and mixtures of a fluorinated alcohol and a cyclic or acyclic sugar alcohol which is substituted with at least one —R, —C(O)R, —(CHCHO)(CH(CH)CHO)R, —(CHCHO)(CH(CH)CHO)C(O)R, or mixtures thereof; and (c) at least one isocyanate-reactive ethylenically ...

WATERBORNE AZIDO-ALKYNE CLICK COMPOSITIONS

A waterborne poly(alkynyl carbamate) prepolymer is provided which comprises a reaction product of a polyisocyanate comprising a first portion and a second portion of isocyanate groups; an isocyanate-reactive component comprising 0.1 mol % to 6 mol % of a C-Cglycol ether; and 99.9 mol % to 94 mol % of an alkynol, wherein the mol % is based on the moles of isocyanate in the polyisocyanate, wherein the first portion of isocyanate groups reacts with the C-Cglycol ether, wherein the second portion of isocyanate groups reacts with the alkynol, and wherein reaction occurs optionally in the presence of a catalyst. The reaction of long chain glycol ethers with the polyisocyanate at a level of from 0.1 mol % to 6 mol % imparts water dispersibility to the prepolymer, and when the prepolymer is dispersed in water, the performance of waterborne alternative polyurethane compositions made therefrom, such as coatings, adhesives, sealants, films, elastomers, castings, foams, and composites, are not compromised. The invention allows for the use of water as a carrier, thus eliminating the need for organic solvents. 1. A waterborne poly(alkynyl carbamate) prepolymer comprising a reaction product of:a polyisocyanate comprising a first portion and a second portion of isocyanate groups;{'sub': 10', '50, 'an isocyanate reactive component comprising 0.1 mol % to 6 mol % of a C-Cglycol ether and 99.9 mol % to 94 mol % of an alkynol;'}wherein the mol % is based on the moles of isocyanate in the polyisocyanate;{'sub': 10', '50, 'wherein the first portion of isocyanate groups reacts with the C-Cglycol ether;'}wherein the second portion of isocyanate groups reacts with the alkynol, and wherein reaction occurs optionally in the presence of a catalyst.2. The waterborne poly(alkynyl carbamate) prepolymer according to claim 1 , wherein the polyisocyanate is selected from the group consisting of 1 claim 1 ,4-tetramethylene diisocyanate claim 1 , 1 claim 1 ,6-hexamethylene diisocyanate claim 1 , 2 ...

Azido-alkyne click and oxysilane hybrid compositions

The present invention provides alternative polyurethane composition comprising the reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer, wherein the poly(alkynyl carbamate) prepolymer comprises the reaction product of a polyisocyanate, an alkynol, and an oxysilane. The reaction of the polyol and the prepolymer may occur in the presence of a catalyst or at a temperature of from 20° C. to 120° C. The inventive oxysilane and azido-alkyne hybrid click formulations provide comparable performance, and in some cases better performance, to/than urethane and azido-alkyne control click formulations in terms of pencil hardness, MEK double rubs, and glass transition temperature. The inventive alternative polyurethane compositions may be used to provide coatings, adhesives, sealants, films, elastomers, castings, and composites.

ALLOPHANATE CARBAMATE AZIDO-ALKYNE CLICK COMPOSITIONS

An alternative polyurethane composition is provided comprising a reaction product of an azidated polyol and a poly(alkynyl carbamate) allophanate prepolymer, wherein the poly(alkynyl carbamate) allophanate prepolymer comprises a reaction product of a first alkynol and a poly(alkynyl carbamate) prepolymer, in the presence of a metallo-organic compound of the formula: M(acac), wherein, M=a metal, acac=an acetylacetonate residue, and n=2 or 3, wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate and a stoichiometric equivalent of a second alkynol, and wherein the polyisocyanate comprises isocyanate groups and uretdione groups. The inventive alternative polyurethane compositions may be used to provide solventborne or waterborne coatings, adhesives, sealants, films, elastomers, castings, foams, and composites. 1. A poly(alkynyl carbamate) allophanate prepolymer comprising a reaction product of a first alkynol and a poly(alkynyl carbamate) prepolymer , in the presence of a metallo-organic compound of the formula:{'br': None, 'sub': 'n', 'M(acac),'} M=a metal,', 'acac=an acetylacetonate residue,', 'n=2 or 3,, 'wherein,'}wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate and a stoichiometric equivalent of a second alkynol, and wherein the polyisocyanate comprises isocyanate groups and uretdione groups.2. The poly(alkynyl carbamate) allophanate prepolymer according to claim 1 , wherein the first alkynol and the second alkynol each independently contain from 3 to 10 carbon atoms.3. The poly(alkynyl carbamate) allophanate prepolymer according to claim 1 , wherein the first alkynol and the second alkynol are identical or different.4. The poly(alkynyl carbamate) allophanate prepolymer according to claim 1 , wherein the first alkynol and the second alkynol are selected from the group consisting of propargyl alcohol claim 1 , 2-hydroxyethylpropiolate claim 1 , and isomers of any of these; or ...

POLYURETHANE POLYMERS CURED VIA AZIDO-ALKYNE CYCLOADDITION

An alternative polyurethane composition is provided which comprises the reaction product of a poly(alkynyl carbamate) prepolymer and an azidated polyol, wherein reaction occurs without a catalyst at a temperature of from 100° C. to 200° C., or occurs in the presence of a Cu-containing catalyst at a temperature of from 20° C. to 140° C. The inventive alternative polyurethane compositions may be used to provide solventborne or waterborne coatings, adhesives, sealants, films, elastomers, castings, foams, and composites. 1. An alternative polyurethane composition comprising a reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer at a temperature of from 100° C. to 200° C. ,wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate and a stoichiometric equivalent of an alkynol.2. The alternative polyurethane composition according to claim 1 , wherein the alkynol contains from 3 to 10 carbon atoms.3. The alternative polyurethane composition according to claim 1 , wherein the alkynol is propargyl alcohol.4. The alternative polyurethane composition according to claim 1 , wherein the polyisocyanate is selected from the group consisting of 1 claim 1 ,4-tetramethylene diisocyanate claim 1 , 1 claim 1 ,6-hexamethylene diisocyanate claim 1 , 2 claim 1 ,2 claim 1 ,4-trimethyl-1 claim 1 ,6-hexamethylene diisocyanate claim 1 , 1 claim 1 ,12-dodecamethylene diisocyanate claim 1 , cyclohexane-1 claim 1 ,3-diisocyanate claim 1 , cyclohexane-1 claim 1 ,4-diisocyanate claim 1 , 1-isocyanato-2-isocyanato-methyl cyclopentane claim 1 , 1-isocyanato-3-isocyanatomethyl-3 claim 1 ,5 claim 1 ,5-trimethyl cyclohexane (isophorone diisocyanate or IPDI) claim 1 , bis-(4-isocyanatocyclohexyl)methane claim 1 , 1 claim 1 ,3-bis(isocyanatomethyl)-cyclohexane claim 1 , 1 claim 1 ,4-bis(isocyanatomethyl)-cyclohexane claim 1 , bis-(4-isocyanato-3-methyl-cyclohexyl)-methane claim 1 , α claim 1 ,α claim 1 ,α′ claim 1 ,α′-tetramethyl-1 claim 1 , ...

LOW VISCOSITY POLY(ALKYNYL CARBAMATE) POLYMERS

An alternative polyurethane composition is provided which comprises a reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer, wherein reaction occurs at a temperature of from 20° C. to 200° C., optionally in the presence of a Cu-containing catalyst and wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate, an alkynol, and a glycol ether, wherein from 1 mol % to 33 mol % of isocyanate groups are reacted with glycol ether and the remaining isocyanate groups are reacted with the alkynol. The inclusion of glycol ethers into the polyisocyanate chain of the poly(alkynyl carbamate) prepolymer at a level of from 1 mol % to 33 mol %, is efficient in reducing the viscosity of the composition without compromising its performance in coatings, adhesives, sealants, films, elastomers, castings, foams, and composites made with the inventive alternative polyurethane compositions. 1. A poly(alkynyl carbamate) prepolymer comprising a reaction product of:a polyisocyanate;an alkynol; anda glycol ether,wherein from 1 mol % to 33 mol % of isocyanate groups are reacted with glycol ether and the remaining isocyanate groups are reacted with the alkynol.2. The poly(alkynyl carbamate) prepolymer according to claim 1 , wherein the polyisocyanate is selected from the group consisting of 1 claim 1 ,4-tetramethylene diisocyanate claim 1 , 1 claim 1 ,6-hexamethylene diisocyanate claim 1 , 2 claim 1 ,2 claim 1 ,4-trimethyl-1 claim 1 ,6-hexamethylene diisocyanate claim 1 , 1 claim 1 ,12-dodecamethylene diisocyanate claim 1 , cyclohexane-1 claim 1 ,3-diisocyanate claim 1 , cyclohexane-1 claim 1 ,4-diisocyanate claim 1 , 1-isocyanato-2-isocyanato-methyl cyclopentane claim 1 , 1-isocyanato-3-isocyanatomethyl-3 claim 1 ,5 claim 1 ,5-trimethyl cyclohexane (isophorone diisocyanate or IPDI) claim 1 , bis-(4-isocyanatocyclohexyl)methane claim 1 , 1 claim 1 ,3-bis(isocyanatomethyl)-cyclohexane claim 1 , 1 claim 1 ,4-bis(isocyanatomethyl)- ...

LOW VISCOSITY POLY(ALKYNYL CARBAMATE) PREPOLYMERS

An alternative polyurethane composition is provided which comprises a reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer, wherein reaction occurs at a temperature of from 20° C. to 200° C., optionally in the presence of a catalyst, wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of stoichiometric equivalents of a polyisocyanate and a component comprising 1-100% of an alkynol-ether of the formula (I): HC≡C—R—OH (I), wherein R is a linear or branched ether chain having from 1 to 15 atoms, and wherein the remainder of the hydroxyl-functional component comprises a first alkynol. The inclusion of an alkynol-ether reduces the viscosity of the composition without compromising its performance. The inventive alternative polyurethane compositions may find use in providing coatings, adhesives, sealants, films, elastomers, castings, foams, and composites. 2. The alternative polyurethane composition according to claim 1 , wherein the alkynol-ether is a reaction product of a second alkynol and a toluenesulfonyl-trialkene glycol ether.3. The alternative polyurethane composition according to claim 2 , wherein the toluenesulfonyl-trialkene glycol ether is a hydrogenation product of a trityl-oxygen-trialkene glycol ether-toluenesulfonylate.4. The alternative polyurethane composition according to claim 3 , wherein the trityl-oxygen-trialkene glycol ether-toluenesulfonylate is a reaction product of a trityl-oxygen-trialkene glycol ether trialkene glycol ether and tosyl chloride.5. The alternative polyurethane composition according to claim 4 , wherein the trityl-oxygen-trialkene glycol ether is a reaction product of a trialkene glycol ether and trityl chloride.6. The alternative polyurethane composition according to claim 1 , wherein the trialkene glycol ether is selected from the group consisting of propargyl triethylene glycol claim 1 , propargyl tripropylene glycol claim 1 , and propargyl tributylene glycol.7. The alternative ...

Polyurethane polymers cured via azido-alkyne cycloaddition at ambient or mild curing conditions

and wherein R1 is an electron-withdrawing group selected from the group consisting of carbonyl, ester, amide, and urethane and R2 is a linear or branched alkyl chain having from 1 to 15 carbon atoms. The inventive alternative polyurethane composition position may be used to provide adhesives, sealants, films, elastomers, castings, foams, and composites.

WATERBORNE AZIDO-ALKYNE CLICK COMPOSITIONS

A waterborne alternative polyurethane composition is provided which comprises a reaction product of: an azidated polyol; and a waterborne poly(alkynyl carbamate) prepolymer comprising a reaction product of a polyisocyanate and from 1 wt. % to 20 wt. % of an alkynol-polyether having a formula (I), 2. The waterborne alternative polyurethane composition according to claim 1 , wherein the alkynol-polyether is a reaction product of an alkynol and a mono-toluenesulfonyl ester of a polyether diol (TsO-POE).3. The waterborne alternative polyurethane composition according to claim 2 , wherein the mono-toluenesulfonyl ester of a polyether diol (TsO-POE) is a hydrogenation product of a mono-trityl ether of a polyether diol claim 2 , toluenesulfonyl ester (TrtO-POE-OTs).4. The waterborne alternative polyurethane composition according to claim 3 , wherein the mono-trityl ether of a polyether diol claim 3 , toluenesulfonyl ester (TrtO-POE-OTs) is a reaction product of a mono-trityl ether of a polyether diol (TrtO-POE) and tosyl chloride (TOSYL-CL).5. The waterborne alternative polyurethane composition according to claim 4 , wherein the mono-trityl ether of a polyether diol (TrtO-POE) is a reaction product of a polyether diol (POE) and trityl chloride (TRTCl).6. The waterborne alternative polyurethane composition according to claim 1 , wherein the alkynol is selected from the group consisting of propargyl alcohol claim 1 , 2-hydroxyethylpropiolate claim 1 , and isomers of any of these; or mixtures of any of these.7. The waterborne alternative polyurethane composition according to claim 1 , wherein the alkynol-polyether comprises 5 wt. % to 15 wt. % of the prepolymer.8. The waterborne alternative polyurethane composition according to claim 1 , wherein the polyisocyanate is selected from the group consisting of 1 claim 1 ,4-tetramethylene diisocyanate claim 1 , 1 claim 1 ,6-hexamethylene diisocyanate claim 1 , 2 claim 1 ,2 claim 1 ,4-trimethyl-1 claim 1 ,6-hexamethylene diisocyanate ...

ORTHODONTIC ARTICLES PREPARED USING A POLYCARBONATE DIOL, AND METHODS OF MAKING SAME

The present disclosure provides an orthodontic article including the reaction product of the photopolymerizable composition. The photopolymerizable composition includes i) a monofunctional (meth)acrylate monomer whose cured homopolymer has a glass transition temperature of 90 degrees Celsius or greater; ii) a photoinitiator; and iii) a polymerization reaction product of components. The components include 1) an isocyanate; 2) a (meth)acrylate mono-ol; 3) a polycarbonate diol; and 4) a catalyst. Further, the present disclosure provides a method of making an orthodontic article. The method includes obtaining a photopolymerizable composition and selectively curing the photopolymerizable composition to form an orthodontic article. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an orthodontic article; and generating, with the manufacturing device by an additive manufacturing process, the orthodontic article based on the digital object. A system is also provided, including a display that displays a 3D model of an orthodontic article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an orthodontic article. 4. The orthodontic article of claim 3 , wherein the compound of Formula (III) is added to the photopolymerizable composition.5. The orthodontic article of claim 3 , wherein the compound of Formula (III) is present in an amount of 5 to 20 wt. % claim 3 , based on the weight of the polymerizable composition.7. The orthodontic article of claim 1 , wherein the monofunctional (meth)acrylate monomer is selected from the group consisting of dicyclopentadienyl acrylate claim 1 , isobornyl acrylate claim 1 , dicyclopentanyl acrylate claim 1 , dimethyl-1-adamantyl acrylate claim 1 , cyclohexyl methacrylate claim 1 , tert-butyl methacrylate claim 1 , 3 claim 1 ,3 claim 1 ,5-trimethylcyclohexyl ...

COMPOSITION BASED ON SILANE-TERMINATED POLYMERS THAT DOES NOT SPLIT OFF METHANOL DURING CURING

The invention relates to a composition including a) at least one silane-functional polymer P having alkoxy end groups, which are not methoxy groups; b) at least one catalyst for the cross-linking of silane-functional polymers, selected from the group comprising an organotitanate, organozirconate and organoaluminate; c) at least one compound having at least one amidino group. Such compositions are suitable as adhesives, sealants and coatings and have the advantage that the compositions are substantially free from tin or organic tin compounds and do not split off methanol during curing. 1. Composition comprisinga) at least one silane-functional polymer P with alkoxy end groups that are not methoxy groups;b) at least one catalyst for the cross-linking of silane-functional polymers, selected from the group consisting of an organotitanate, organozirconate and organoaluminate;c) at least one compound containing at least one amidino group.3. Composition according to claim 1 , wherein the alkoxy end groups of the silane-functional polymer P are ethoxy groups.4. Composition according to claim 1 , wherein the catalyst for the cross-linking of silane-functional polymers has at least one multidentate ligand.5. Composition according to claim 1 , wherein the catalyst for the cross-linking of silane-functional polymers is an organotitanate.8. Composition according to claim 1 , wherein the compound which has at least one amidino group is a guanidine claim 1 , an imidazole claim 1 , an imidazoline claim 1 , a bicyclic amidine or a derivative of these compounds.9. Composition according to claim 1 , wherein the composition is substantially free from tin or organic tin compounds.10. Composition according to claim 1 , wherein the composition contains no constituents that split off methanol when curing.11. Composition according to claim 1 , wherein the fraction of the catalyst amounts to 0.1 to 10 wt % of the total composition.12. Composition according to claim 1 , wherein the fraction ...

HIGH PERFORMANCE POLYURETHANE PREPOLYMER AND CURING COMPOSITIONS

Compositions comprising isocyanate capped polyurethane prepolymers and select mono-benzyl phthalate plasticizers, e.g., 7-(2,6,6,8-tetramethyl-4-oxa-3-oxo-nonyl) benzylphthalate, exhibit better isocyanate stability than prepolymer compositions comprising other plasticizers common in polyurethane systems. Curing compositions comprising these prepolymers, the select mono-benzyl phthalate plasticizers, and methylenedianiline coordination complex curing agents exhibit improved processing characteristics and yield elastomeric polyurethanes with lower compression set, higher break strength and lower color than similar composition comprising plasticizers such as benzoate plasticizers. 4. The prepolymer composition according to wherein in formula (IV) Ris Calkyl.5. The composition according to wherein each Ris methyl claim 4 , and Ris Calkyl.6. The composition according to wherein the isocyanate capped prepolymer comprises less than 5 wt % free isocyanate monomer.7. The composition according to wherein the isocyanate capped prepolymer is prepared from diphenylmethane diisocyanate and a polyol.8. The composition according to further comprising a curing agent.9. The composition according to further comprising a curing agent.10. The composition according to wherein the curing agent is a metal salt coordination complex of methylene dianiline.11. The composition according to wherein the curing agent is a metal salt coordination complex of methylene dianiline.12. An elastomeric polyurethane obtained by curing the composition of .13. An elastomeric polyurethane obtained by curing the composition of .14. An elastomeric polyurethane obtained by curing the composition of .15. An elastomeric polyurethane obtained by curing the composition of .16. The elastomeric polyurethane according to having a Shore hardness of from 50 A to 85 A.17. The elastomeric polyurethane according to having a Shore hardness of from 50 A to 85 A.18. A method of preparing a polyurethane elastomer claim 10 , ...

Metal polyols for use in a polyurethane polymer

The present disclosure provides for a metal chelated polyol liquid and/or a metal chelated polyether polyol liquid that can be used in an isocyanate-reactive composition and a reaction mixture for forming a polyurethane polymer. The metal chelated polyester polyol liquid is a reaction product of a chelating polyester polyol having a chelating moiety and a metal compound having a metal ion. The metal chelated polyether polyol liquid is a reaction product of a chelating polyether polyol having a chelating moiety and a metal compound having a metal ion. The chelating moiety of the chelating polyester polyol or the chelating polyether polyol chelates the metal ion to form the metal chelated polyester polyol liquid or the metal chelated polyether polyol liquid, respectively, having a mole ratio of the metal ion to the chelating moiety of 0.05:1 to 2:1.

SHELF-STABLE RIGID FOAM FORMULATIONS

The shelf life of B-side compositions comprising a polyol, a surfactant, a blowing agent, an organometallic or metal salt catalyst wherein the metal of the catalyst comprises Zn or Bi, and from 1 to 10 weight percent water is improved by the addition of a thiol compound. 1. A B-side composition useful for preparing a rigid foam , the composition comprising a polyol , a surfactant , a blowing agent , a thiol compound , from 1 to 10 weight percent water , based on the weight of the composition , and an organometallic or metal salt catalyst wherein the metal of the catalyst comprises Zn or Bi.2. The composition of wherein the composition has a shelf life of at least 4 months.3. The composition of wherein the amount of water is from 2 to 5 wt. %.4. The composition of wherein the amount of water is from 3 to 5 wt. %.5. The composition of wherein the thiol is a saturated or unsaturated alkyl thiol claim 1 , including alky thiols with aromatic substitutions (e.g. benzyl thiol) claim 1 , mercaptoacetates claim 1 , mercaptopropionates claim 1 , poly(ethylene glycol) methyl ether thiols claim 1 , dithiols claim 1 , bis-PEG-thiols claim 1 , trithiols claim 1 , thioglycerol claim 1 , HSCHCH(OH)CHOH claim 1 , thiol-PEG-alcohols claim 1 , cysteine and derivatives and mixtures thereof.6. The composition of wherein the blowing agent comprises at least one of trans-1 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene (1234ze) and 1-chloro-3 claim 1 ,3 claim 1 ,3-trifluoropropene (1233 zd).7. The composition of wherein a stoichiometric excess of the thiol is employed8. The composition of wherein the composition comprises from 60 to 95 wt. % polyol claim 1 , from 0.5 to 6.0 wt. % surfactant claim 1 , from 1 to 30 wt. % blowing agent claim 1 , not counting water claim 1 , from 0.0001 to 10 wt. % thiol compound claim 1 , from 0.001 wt. % to 5.0 wt. % catalyst and from 1 to 10 wt. % water claim 1 , based on 100 weight percent of the composition.9. A rigid foam prepared from an admixture ...

POLYURETHANE FOAM PREMIXES CONTAINING HALOGENATED OLEFIN BLOWING AGENTS AND FOAMS MADE FROM SAME

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst. 1. A foamable composition comprising:a. a hydrohaloolefin blowing agent,b. one or more polyols,c. one or more surfactants, andd. a catalyst system comprising at least a first metal and at least a second metal, and at least one amine catalyst selected from the group of amine catalysts having a pKa of not less than about 10.2. The foamable composition of wherein said first and second metal catalyst is selected from the group consisting of bismuth nitrate claim 1 , lead 2-ethylhexoate claim 1 , lead benzoate claim 1 , lead naphthanate claim 1 , ferric chloride claim 1 , antimony trichloride claim 1 , antimony glycolate claim 1 , tin salts of carboxylic acids claim 1 , dialkyl tin salts of carboxylic acids claim 1 , potassium acetate claim 1 , potassium octoate claim 1 , potassium 2-ethylhexoate claim 1 , potassium salts of carboxylic acids claim 1 , zinc salts of carboxylic acids claim 1 , zinc 2-ethylhexanoate claim 1 , glycine salts claim 1 , alkali metal carboxylic acid salts claim 1 , and sodium N-(2-hydroxy-5-nonylphenol)methyl-N-methylglycinate claim 1 , tin (II) 2-ethylhexanoate claim 1 , dibutyltin dilaurate claim 1 , and combinations thereof.3. The foamable composition of wherein said first and second metal catalyst is each present in an amount of about 0.001 wt. % to about 5.0 wt. % claim 2 , by weight of the composition.4. The foamable composition of further comprising a quaternary ammonium carboxylate.5. ...

Water-based coating composition and production method of the same

A water-based coating composition including: a polyol; a polyisocyanate; a hydrophobic curing catalyst which is made of an organometallic compound containing at least one metal atom selected from the group consisting of Sn, Bi, Zr, Ti, and Al and of which solubility in water under conditions of atmospheric pressure at 20° C. is 1 g/100 ml or less; and a nonionic surfactant of which an HLB value determined by a Griffin method is 10 to 15.

Process for producing polyol

A process for preparing polyol, wherein, in a first process stage, a diol is prepared by a process comprising: (1-i) adding alkylene oxide and carbon dioxide onto an H-functional starter substance in the presence of a catalyst to obtain polyethercarbonate polyol and a cyclic carbonate, (1-ii) separating the cyclic carbonate from the resulting reaction mixture from step (1-i), (1-iii) hydrolyzing the cyclic carbonate separated from step (1-ii) to carbon dioxide and diol, and (1-iv) optionally purifying the diol resulting from step (1-iii) by distillation.

SOLVENT-BASED PRIMER HAVING A LONG OPEN TIME AND IMPROVED ADHESION

Adhesion promoter compositions, containing: a) between 40 and 80 parts by weight of a binder composition, including i) 20-40 wt % of at least one silane-terminated polyurethane polymer STP, which can be obtained from at least one polyol P, aliphatic polyisocyanate I and organosilane OS1, ii) 4-20 wt % of at least one organosilane OS2 and/or organotitanate OT, iii) 0-3 wt % of at least one desiccant, iv) 40-80 wt % of solvent L1; b) between 0-30 parts by weight of industrial carbon black; c) between 0-1 parts by weight of UV marker; d) so much of solvent L2 that sum of a)-d) is 100 parts by weight; OS1 having secondary amino, mercapto or hydroxyl group on organic moiety and the at least one STP having been produced in absence of OS2, and the at least one P having an average OH functionality of at least 2 and equivalent weight of at most 500. 1. An adhesion promoter composition containing i) 20% to 40% by weight based on the binder composition of at least one silane-terminated polyurethane polymer STP obtainable from at least one polyol P, at least one aliphatic polyisocyanate I and at least one organosilane OS1 in the presence of a catalyst K,', 'ii) 4% to 20% by weight based on the binder composition of at least one organosilane OS2 and/or organotitanate OT,', 'iii) 0% to 3% by weight based on the binder composition of at least one drying agent,', 'iv) 40% to 80% by weight based on the binder composition of a solvent L1;, 'a) between 40 and 80 parts by weight of a binder composition comprising'}b) between 0 and 30 parts by weight of carbon black;c) between 0 and 1 parts by weight of UV marker;d) sufficient of a solvent L2 for a) to d) to sum to 100 parts by weight; whereinthe organosilane OS1 comprises a secondary amino group, a mercapto group or a hydroxyl group on the organic radical andthe at least one silane-terminated polyurethane polymer STP was produced in the absence of the organosilane OS2 andthe at least one polyol P has an average OH functionality of at ...

ORTHODONTIC ARTICLES PREPARED USING A POLYCARBONATE DIOL, POLYMERIZABLE COMPOSITIONS, AND METHODS OF MAKING THE ARTICLES

The present disclosure provides an orthodontic article including the reaction product of the polymerizable composition. Further, the present disclosure provides polymerizable compositions and methods of making an orthodontic article. The method includes obtaining a polymerizable composition and selectively curing the polymerizable composition to form an orthodontic article. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an orthodontic article; and generating, with the manufacturing device by an additive manufacturing process, the orthodontic article based on the digital object. A system is also provided, including a display that displays a 3D model of an orthodontic article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an orthodontic article. 1. An orthodontic article comprising the reaction product of a polymerizable composition comprising:{'sub': 'g', '30-65 parts by weight of monofunctional (meth)acrylate monomer(s) per 100 parts of the total polymerizable composition, wherein a cured homopolymer of at least one monofunctional (meth)acrylate monomer has a Tof 30 degrees Celsius (° C.) or greater, at least 40, 50, 60, 70, 80, or 90° C.; and'}at least one urethane (meth)acrylate comprising polymerized units of an aliphatic polycarbonate diol.2. The orthodontic article of claim 1 , wherein the monofunctional (meth)acrylate monomer(s) having a Tof at least 30° C. has a log P value of greater than 1 claim 1 , 1.5 claim 1 , 2 claim 1 , 2.5 claim 1 , or 3.3. (canceled)4. The orthodontic article of claim 1 , wherein the at least one urethane (meth)acrylate comprises a reaction product of an aliphatic polycarbonate diol claim 1 , a diisocyanate claim 1 , and a hydroxy functional (meth)acrylate.5. The orthodontic article of claim 4 , wherein the hydroxy functional (meth)acrylate is of ...

RETROREFLECTIVE ARTICLES WITH WASH DURABLE BEAD BOND LAYERS

Retroreflective articles include a layer of optical elements, and a polyurethane bead bond layer. The optical elements include transparent microspheres, and at least one reflective layer. The polyurethane bead bond layer is the reaction product of a reaction mixture of at least one aliphatic polycarbonate polyol and at least one polyisocyanate, and the reaction mixture is free of polyols containing unsaturated groups. The retroreflective articles have improved wash durability. 1. A retroreflective article comprising:a polyurethane bead bond layer; and 'transparent microspheres, and at least one reflective layer;', 'a layer of optical elements partially embedded in the bead bond layer, the optical elements comprisingwherein the polyurethane bead bond layer comprises the reaction product of a reaction mixture comprising at least one aliphatic polycarbonate polyol and at least one polyisocyanate, and wherein the reaction mixture is free of polyols containing unsaturated groups.2. The retroreflective article of claim 1 , wherein the reaction mixture further comprises at least one additional polyol.3. The retroreflective article of claim 1 , wherein the reaction mixture further comprises at least two additional polyols.4. The retroreflective article of claim 3 , wherein at least one of the two additional polyols comprises a polyol with a functionality greater than 2 claim 3 , and wherein at least one of the two additional polyols is not a polyester polyol.5. The retroreflective article of claim 1 , wherein the at least one polyisocyanate comprises an aliphatic polyisocyanate.6. The retroreflective article of claim 1 , wherein the at least one polyisocyanate comprises an aromatic polyisocyanate.7. The retroreflective article of claim 1 , wherein the amount of polyisocyanate present in the reaction mixture comprises a stoichiometric excess of polyisocyanate relative to amount of polyol.8. The retroreflective article of claim 1 , wherein the reaction mixture further ...

Curable composition based on polymers containing silane groups and on a zinc catalyst

Composition including at least one polymer containing silane groups and at least one zinc(II) complex compound of Zn k (L) x (Y) 2k-nx , where k is an integer from 1-10, x is 1, 2, 3, or 4, n corresponds to of ligand L, Y is ligand having −1 charge, and L is ligand of where n is 1, 2, or 3, A is R 4 or polyoxyalkylene group or group of polyoxyalkylated compound optionally having one or two terminal 1,3-ketoamide groups, R 1 and R 2 are hydrogen residue or monovalent saturated or unsaturated hydrocarbon group having 1-10 carbon atoms independently of each other or jointly bivalent alkylene group having 3-6 carbon atoms; R 3 and R 4 are hydrogen residue or monovalent saturated hydrocarbon group having 1-12 carbon atoms independently of each other, hydrocarbon group optionally contains one or more heteroatoms, or jointly bivalent alkylene group having 3-6 carbon atoms, which alkylene group optionally contains one or more heteroatoms. The invention further relates to the use of the zinc(II) complex compound of the formula Zn k (L) x (Y) 2k-nx as a catalyst for the cross-linking of polymers containing silane groups by means of moisture.

SHELF STABLE, LOW TIN CONCENTRATION, DUAL CURE ADDITIVE MANUFACTURING RESINS

Provided herein are methods of making (meth)acrylate blocked polyurethanes with zirconium catalysts, dual cure resins containing (meth)acrylate blocked polyurethanes and zirconium catalysts, methods of using the same in additive manufacturing, and products made therefrom. 1. A method of making a precursor resin useful for additive manufacturing , comprising the steps of:(a) reacting a polyisocyanate with a polyol in the presence of a zirconium catalyst to produce a first reaction product;(b) reacting said first reaction product with an amine(meth)acrylate monomer blocking agent to produce a second reaction product comprising a (meth)acrylate blocked polyurethane (ABPU); and then(c) combining said second reaction product with (i) a free radical photoinitiator and (ii) optionally a comonomer, to produce said precursor resin.2. The method of claim 1 , wherein said method further comprises adding a radical polymerization inhibitor before claim 1 , during or after any one of steps (a) claim 1 , (b) and (c).3. The method of claim 1 , wherein said method further comprises adding a reactive diluent or non-reactive diluent before claim 1 , during or after any one of steps (a) claim 1 , (b) and (c).4. The method of claim 1 , wherein said reacting step (a) is carried out in the absence of a tin catalyst under nonaqueous conditions.5. The method of claim 1 , wherein said polyisocyanate comprises 1 claim 1 ,6-diisocyanatohexane (HDI) claim 1 , methylene diphenyl diisocyanate (MDI) claim 1 , toluene diisocyanate (TDI)) claim 1 , para-phenyl diisocyanate (PPDI) claim 1 , 4 claim 1 ,4′-dicyclohexylmethane-diisocyanate (HMDI) claim 1 , isophorone diisocyanate (IPDI) claim 1 , triphenylmethane-4 claim 1 ,4′4″-triisocyanate claim 1 , tolune-2 claim 1 ,4 claim 1 ,6-triyl triisocyanate claim 1 , 1 claim 1 ,3 claim 1 ,5-triazine-2 claim 1 ,4 claim 1 ,6-triisocyanate claim 1 , or ethyl ester L-lysine triisocyanate.6. The method of claim 1 , wherein said polyol comprises a polyether claim ...

PROCESS FOR THE PREPARATION OF SILYLATED POLYURETHANE POLYMERS USING TITANIUM-CONTAINING AND ZIRCONIUM-CONTAINING CATALYSTS

The present invention relates to a process for preparing silylated polyurethane polymers which have increased stability under ambient condition or storage toward atmospheric moisture, in the presence of at least one of titanium-containing catalyst or zirconium-containing catalyst and to silylated polyurethane polymer compositions comprising these catalysts. 1. A process for the preparation of silylated polyurethane polymer (i) from the reaction of polyol (ii) and/or hydroxyl-terminated polyurethane (iii) with isocyanatosilane silylating agent (iv) , or the reaction of isocyanate-terminated polyurethane (v) with amino-functional silane silylating agent (vi) and/or mercapto-functional silane silylating agent (vii) , the process comprising employing at least one urethane-forming reaction catalyst (viii) for the preparation of hydroxyl-terminated polyurethane (iii) , isocyanate-terminated polyurethane (v) and/or silylated polyurethane polymer (i) , urethane-forming reaction catalyst (viii) being selected from the group consisting of titanium-containing catalyst and zirconium-containing catalyst.2. The process of wherein hydroxyl-terminated polyurethane (iii) is obtained by reacting a molar excess of the hydroxyl equivalents of polyol (ii) with respect to the isocyanate equivalents of polyisocyanate (ix) in the presence of urethane-forming reaction catalyst (viii).3. The process of wherein isocyanate-terminated polyurethane (v) is obtained by reacting a molar excess of the isocyanate equivalents of polyisocyanate (ix) with respect to the hydroxyl equivalents of polyol (ii) in the presence of urethane-forming reaction catalyst (viii).4. The process of wherein polyol (ii) is at least one member selected from the group consisting of polyether polyols claim 1 , polyester polyols and polybutadienediols.5. The process of wherein polyisocyanate (ix) is at least one member selected from the group consisting of 2 claim 2 ,4-toluene diisocyanate claim 2 , 2 claim 2 ,6-toluene ...

Conductive Paste

Provided is a solderable conductive paste that cures at low temperature, that is excellent in adhesiveness with an ITO layer, and that is inexpensive. The conductive paste of the present invention includes: flaky silver-coated copper powder; a phenoxy resin; a hexamethylene diisocyanate-based polyisocyanate compound and/or a blocked isocyanate compound; a phosphorus-containing organic titanate; and an alkanolamine, in which a content of the flaky silver-coated copper powder is from 88 parts by weight to 92 parts by weight with respect to 100 parts by weight of a total amount of the flaky silver-coated copper powder, the phenoxy resin, and the hexamethylene diisocyanate-based polyisocyanate compound and the blocked isocyanate compound. 1. A conductive paste , comprising:flaky silver-coated copper powder;a phenoxy resin;a hexamethylene diisocyanate-based polyisocyanate compound and/or a blocked isocyanate compound;a phosphorus-containing organic titanate; andan alkanolamine,wherein a content of the flaky silver-coated copper powder is from 88 parts by weight to 92 parts by weight with respect to 100 parts by weight of a total amount of the flaky silver-coated copper powder, the phenoxy resin, and the hexamethylene diisocyanate-based polyisocyanate compound and the blocked isocyanate compound.2. The conductive paste according to claim 1 , wherein the flaky silver-coated copper powder has an average particle diameter of from 5 μm to 25 μm.3. The conductive paste according to claim 1 , wherein:the flaky silver-coated copper powder includes copper particles each serving as a core and silver coating layers configured to coat the copper particles; anda weight ratio of the silver coating layers is from 5 wt % to 20 wt % with respect to the copper particles.4. The conductive paste according to claim 1 , wherein a content of the phenoxy resin is from 40 parts by weight to 65 parts by weight with respect to 100 parts by weight of a total amount of the phenoxy resin claim 1 , ...

Polyurethane based gel composition

A polyurethane gel for comfort applications includes a reaction product of a composition that includes (1) from 5 wt % to 35 wt % of a prepolymer component, based on a total weight of the composition, the prepolymer component including a reac tion product of an isocyanate component that includes diphenylemethane diisocyanate (MDI) and a polyol component that includes a polyoxyethylene-polyoxypropylene polyol that has an polyoxyethylene content greater than 65 wt %, based on a total weight of the polyoxyethylene polyoxypropylene polyol, and (2) a remainder of a prepolymer-reactive component that includes an amine-terminated polyol and a propylene oxide-ethylene oxide based monol or polyol. The composition excludes any plasticizers.

COATING MATERIAL SYSTEM COMPRISING A MERCAPTO GROUP-CONTAINING COMPOUND

Described herein is a coating material system which includes components (A) to (C) and (K) and also, optionally, further components, where all components (A) to (C) and (K) and also, where present, the further optional components are present separately from one another or are mixed wholly or at least partly with one another. 1. A coating material system comprising components (A) to (C) and (K):(A) at least one polyhydroxy group-containing compound, wherein the polyhydroxy group-containing compound of component (A) has an acid number of between 0 and 30 mg KOH/g,(B) at least one polyisocyanate-containing compound,(C) at least one catalyst which comprises bismuth (Bi) as metal component and at least one further metal component selected from the group consisting of zinc (Zn), lithium (Li), zirconium (Zr) and aluminum (Al), and(K) at least one mercapto group-containing compound,whereini) components (A), (B), (C), and (K) are present separately from one another orii) are mixed wholly or at least partly with one another.2. The coating material system as claimed in claim 1 , wherein the catalyst of component (C) comprises bismuth (Bi) and lithium (Li) as metal components.3. The coating material system as claimed in claim 1 , whereini) the polyhydroxy group-containing compound of component (A) is selected from the group consisting of the polyacrylate polyols, the polymethacrylate polyols, the polyester polyols, the polyurethane polyols and/or the polysiloxane polyols, and/orii) the polyisocyanate-containing compound of component (B) is selected from the group consisting of 1,6-hexamethylene diisocyanate, isophorone diisocyanate, 4,4′-methylene dicyclohexyl diisocyanate, the biuret dimers of the aforesaid diisocyanates, the iminooxadiazinediones of the aforesaid diisocyanates and/or the asymmetrical trimers of the aforesaid diisocyanates, and/oriii) the mercapto group-containing compound (K) is selected from the group consisting of 2-mercapto propionic acid, 3-mercapto ...

POLYURETHANES WITH GOOD PERMEABILITY TO ELECTROMAGNETIC RADIATION

The invention provides articles made of thermoplastic polyurethane based on polycarbonate diol which are a constituent of a device that receives or transmits electromagnetic radiation, are a cover for a device, or are used in proximity to such a device. The invention further provides for the use of thermoplastic polyurethane based on polycarbonate diol for these articles. 114-. (canceled)15. An article , made of a thermoplastic polyurethane , and which is a constituent of a device or a cover for the device or which is used in proximity to the device , wherein the device receives or transmits electromagnetic radiation and the thermoplastic polyurethane is produced from at least one diisocyanate and at least one isocyanate-reactive substance having a number-average molecular weight of more than 0.500×10g/mol , wherein the at least one isocyanate-reactive substance comprises at least one polycarbonate having at least two hydroxyl groups , and wherein the frequency of the electromagnetic radiation is between 10Hz and 10Hz.16. The article of claim 15 , wherein the at least one polycarbonate is an aliphatic polycarbonate.17. The article of claim 15 , wherein the at least one polycarbonate is based on diols selected from the group consisting of butanediol claim 15 , pentanediol and hexanediol.18. The article of claim 15 , wherein the at least one diisocyanate is selected from the group consisting of 4 claim 15 ,4′- claim 15 , 2 claim 15 ,4′- and 2 claim 15 ,2′-dicyclohexylmethane diisocyanate (H12 MDI) claim 15 , 1 claim 15 ,6-hexamethylene diisocyanate (HDI) claim 15 , 1 claim 15 ,4-cyclohexane diisocyanate claim 15 , 1-methyl-2 claim 15 ,4- and/or -2 claim 15 ,6-cyclohexane diisocyanate claim 15 , 2 claim 15 ,2′- claim 15 , 2 claim 15 ,4′- and/or 4 claim 15 ,4′-diphenylmethane diisocyanate (MDI) claim 15 , and 2 claim 15 ,4- and/or 2 claim 15 ,6-tolylene diisocyanate (TDI).19. The article of claim 15 , wherein the at least one diisocyanate is selected from the group ...

POROUS MEMBRANES

The present invention relates to a porous membrane, process for the manufacture thereof and uses thereof. 1. A porous membrane comprising at least one layer obtained from a composition (C) , said composition (C) comprising: optionally, at least one monomer (a), wherein monomer (a) is a diol selected from the group consisting of poly-ether type diols, poly-ester type diols, polybutadien-diols and polycarbonate-diols;', 'at least one monomer (b), wherein monomer (b) is a hydroxy-terminated (per)fluoropolyether polymer;', 'at least one monomer (c), wherein monomer (c) is an aromatic, aliphatic or cycloaliphatic diisocyanate; and', 'at least one monomer (d), wherein monomer (d) is an aliphatic, cycloaliphatic or aromatic diol having from 1 to 14 carbon atoms; and, 'at least one F-TPU polymer, wherein said F-TPU polymer is a fluorinated polyurethane, polymer comprising recurring units derived fromoptionally at least one further ingredient.2. The porous membrane according to claim 1 , wherein said membrane has an average pore diameter of at least 0.001 μm and of at most 50 μm.3. The porous membrane according to claim 1 , wherein said optional at least one monomer (a) is selected from the group consisting of poly(ethylene)glycol claim 1 , poly(propylene)glycol claim 1 , poly(tetramethylen)glycol (PTMG) claim 1 , poly(1 claim 1 ,4-butanediol) adipate claim 1 , poly(ethandiol-1 claim 1 ,4-butanedio) adipate claim 1 , poly(1 claim 1 ,6-hexandiol-neopentyl) glycol adipate claim 1 , poly-caprolactone-diol (PCL) and polycarbonate-diol.4. The porous membrane according to claim 1 , wherein said at least one monomer (b) is a hydroxy-terminated (per)fluoropolyether polymer comprising a (per)fluoropolyoxyalkylene chain (R) having two chain ends claim 1 , wherein one or both chain ends terminates with at least one —OH group.5. The porous membrane according to claim 1 , wherein said at least one monomer (c) is selected from the group consisting of 4 claim 1 ,4′-methylene-diphenylene- ...

PROCESS FOR THE SYNTHESIS OF SILYLATED POLYURETHANES AND SILYLATED POLYURETHANE COMPOSITION

The present invention provides a process for the synthesis of silylated polyurethanes, comprising three sequential steps, a step (i) of preparing NCO-terminated polyurethane, a step (ii) of partial grafting of the NCO functions with silane functions and a step (iii) of total grafting of the residual NCO functions with functions that react with the NCO functions by means of polyfunctional compounds. The present invention also provides a silylated polyurethane composition that can be obtained by means of the process according to the invention, an adhesive composition comprising said silylated polyurethane composition and a self-adhesive item obtained from the adhesive composition according to the invention. 115-. (canceled)16. A process for the synthesis of a composition of silylated polyurethanes (A) , said process comprising the following sequential stages:{'sub': '2', 'i. polyaddition of at least one polyol (B) with at least one diisocyanate (C), in which the ratio (r1) of the number of NCO functional groups to the total number of OH functional groups, and of NH and NHfunctional groups optionally present, is strictly greater than 1;'}ii. reacting the composition obtained in stage (i) with at least one silane (E) selected from the group consisting of aminosilanes (E1) and mercaptosilanes (E2), in which the ratio (r2) of the number of NCO functional groups to the number of amine and/or thiol functional groups is strictly greater than 1;iii. reacting the composition resulting from stage (ii) with at least one compound (G) comprising at least two identical or different functional groups selected from the group consisting of alcohol, primary amine, secondary amine and thiol functional groups, in which the ratio (r3) of the number of NCO functional groups to the number of alcohol, primary amine, secondary amine and thiol functional groups is less than or equal to 1.17. The synthesis process as claimed in claim 16 , wherein claim 16 , during stage (ii) claim 16 , the ...

Coating Agent Composition for Producing Peelable and Chemically-Resistant Coatings

The invention relates to peelable and chemically resistant coatings for metal and plastic substrates, and to the coating agent compositions required to produce same. The invention also relates to a process for producing such coatings and to the use of the coating agent compositions to protectively coat metal and plastic substrates in the field of aircraft construction. 1. A coating agent composition containing at least one binder component A andat least one curing agent component B,the binder component A containingA1 at least one polyether polyol component of poly(oxyalkylene) glycol,A2 at least one aromatic diamine,A3 silicone elastomer particles andA4 at least one polyurethane urea,the curing agent component B containingB1 at least one urethane-group-containing component containing unblocked isocyanate groups andB2 at least one aromatic diisocyanate of methylene di(phenyl isocyanate),wherein the curing agent component B has a content of unblocked isocyanate groups of from 10 to 30% by weight andwherein the solids content of the coating agent composition is greater than 95% by weight.2. The coating agent composition according to claim 1 , whereincomponent A1 is present in an amount of from 8 to 76% by weight,component A2 is present in an amount of from 1 to 8% by weight,component A3 is present in an amount of from 0.2 to 9% by weight,component A4 is present in an amount of from 0.5 to 11% by weight, andthe curing agent component B is present in an amount of from 20 to 40% by weight,in each case based on the total weight of the coating agent composition.3. The coating agent composition according to claim 1 , wherein the polyether polyol component A1 of poly(oxyalkylene glycol) contains at least one poly(oxyalkylene) glycol of ethylene oxide and/or propylene oxide.4. The coating agent composition according to claim 3 , wherein the polyether polyol component A1 comprises at least one propoxylated polyethylene glycol A1.1 claim 3 , at least one polypropylene glycol A1. ...

POLYURETHANE FOAM PREMIXES CONTAINING HALOGENATED OLEFIN BLOWING AGENTS AND FOAMS MADE FROM SAME

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a precipitation-resistant metal-based catalyst used alone or in combination with an amine catalyst. 1. A foamable composition comprising:a. a blowing agent comprising a tetrafluoropropene, a chlorotrifluoropropene, and/or a hexafluorobutene;b. one or more polyols,c. one or more surfactants,d. water, ande. at least one precipitant resistant metal catalyst selected from the group consisting of a precipitant resistant cobalt-based metal catalyst, a precipitant resistant zinc-based metal catalyst, a precipitant resistant tin-based metal catalyst, a precipitant resistant zirconate-based metal catalyst, a precipitant resistant manganese-based metal catalyst, a precipitant resistant titanium-based metal catalyst and combinations thereof.2. The foamable composition of wherein said precipitant resistant metal catalyst comprises a precipitant resistant cobalt-based metal catalyst.3. (canceled)4. The foamable composition of wherein said precipitant resistant cobalt-based metal catalyst is selected from the group consisting of cobalt octoate claim 2 , cobalt hexanoate claim 2 , cobalt ethylhexanoate claim 2 , cobalt acetylacetonate claim 2 , cobalt ethoxide claim 2 , cobalt propoxide claim 2 , cobalt butoxide claim 2 , cobalt isopropoxide claim 2 , cobalt butoxide claim 2 , derivatives thereof claim 2 , and combinations thereof.5. The foamable composition of wherein said precipitant resistant metal catalyst comprises a precipitant resistant zinc-based metal catalyst.6. (canceled)7. The foamable ...

Anchorage connector for a safety system

An anchorage connector for use in a height safety system is provided. The anchorage connector comprises an energy absorbing, deformable, corrugated enclosed chamber having a first end and a second end, and at least one anchorage attachment point, at one end or both ends.

Thixotropic polyol compositions containing dispersed urethane-modified polyisocyanurates

Thixotropic polyol dispersions are described. The dispersions contain a dispersed phase of polyurethane-isocyanurate particles. They can be made by reacting a low equivalent weight polyol with a polyisocyanate in the presence of an isocyanate trimerization catalyst while dispersed in a base polyol. These polyol dispersions are useful as the resin component of curable systems such as formulated coatings, sealants or adhesives.

IMPACT-RESISTANT THERMOPLASTIC POLYURETHANES, PRODUCTION AND USE THEREOF

The present invention relates to polyester-based hard thermoplastic polyurethane systems which are impact-resistant at low temperatures, and to the production and use thereof. 110-. (canceled)11. A thermoplastically processable polyurethane elastomer (TPU) having a hardness of 56 to 85 Shore D (according to ISO 7619-1: 2012-02) obtained from the reaction of the componentsa) one or more substantially linear polyester polyols having a number-average functionality of 1.8 to 2.2 and a number-average molecular weight of 500 to 4000 g/mol based on dicarboxylic acids selected from the group consisting of adipic acid, succinic acid, terephthalic acid and derivatives thereof, and based on dialcohols selected from the group consisting of ethanediol, 1,4-butanediol, 1,3-propanediol, 1,6-hexanediol and neopentyl glycol, and optionally 0% to 60% by weight of polycarbonate diol based on 1,6-hexanediol,b) one or more substantially linear polyether polyols having a number-average functionality of 1.9 to 2.1 and a number-average molecular weight of 4000 to 20 000 g/mol based on propylene oxide or propylene oxide/ethylene oxide mixtures,c) one or more linear organic diisocyanates,d) one or more dials having a number-average molecular weight of 60 to 250 g/mol, in the presence ofe) optionally catalysts,f) optionally auxiliary and/or additive substances,g) optionally monofunctional chain terminators,wherein the molar ratio of NCO groups to OH groups is from 0.9:1 to 1.1:1 and the weight ratio of the polyether polyols (b) to the polyester polyols (a) is from 5:95 to 30:70.12. The thermoplastically processable polyurethane elastomer as claimed in claim 11 , wherein the component (a) is a linear polyester polyol having a number-average molecular weight of 900 to 2500 g/mol and/or a polycarbonate diol having a number-average molecular weight of 1000 to 4000 g/mol.15. The thermoplastically processable polyurethane elastomer as claimed in claim 11 , wherein component (b) is a linear ...

ZINC(II) COMPLEX COMPOUNDS AS CATALYSTS FOR POLYURETHANE COMPOSITIONS

The present invention relates to zinc(II) complex compounds of the formula Zn(L)(Y), wherein the ligand L has the formula (I). Such complex compounds are particularly suitable as catalysts for two-component polyurethane compositions. The invention also relates to two-component polyurethane compositions including at least one polyisocyanate as a first component, at least one polyol as a second component and at least one such zinc(II) complex compound as a catalyst. In addition, the invention relates to various uses of these two-component polyurethane compositions. 2. A zinc(II) complex compound according to claim 1 , where Rstands for an alkyl residue having 1 to 4 carbons claim 1 , for a phenyl residue claim 1 , or together with Rstands for a bivalent alkylene residue having 3 to 4 carbon atoms.3. A zinc(II) complex compound according to claim 1 , where Rstands for a hydrogen residue.5. A zinc(II) complex compound according to claim 1 , where Rstands for a hydrogen residue claim 1 , an alkyl residue having 1 to 8 carbon atoms claim 1 , a cycloalkyl residue having 5 to 6 carbon atoms claim 1 , a hydroxyalkyl residue having 1 to 4 carbon atoms or an alkyl ether residue having 1 to 4 carbon atoms.6. A zinc(II) complex compound according to claim 1 , where x stands for 2.8. A method according to claim 7 , wherein the ratio between the zinc(II) salt or the zinc(II) complex and the 1 claim 7 ,3-ketoamide is in the range from 1:2 to 1:6.9. A method according to claim 7 , wherein zinc(II) bis(acetylacetonate) is used as zinc(II) complex.10. A zinc(II) complex compound according to as catalyst for curable compositions.11. A two-component polyurethane compositions claim 1 , comprising at least one polyol as first component claim 1 , at least one polyisocyanate as second component claim 1 , and at least one zinc(II) complex compound according to .12. A two-component polyurethane composition according to claim 11 , wherein the polyol is a polyether polyol and the polyisocyanate ...

POLYURETHANE RESIN-FORMABLE COMPOSITION FOR MEMBRANE SEAL MATERIAL, AND MEMBRANE SEAL MATERIAL AND MEMBRANE MODULE USING SAID COMPOSITION

Provided are a composition for forming a polyurethane resin used for a membrane sealing material, the composition having low viscosity and contributing to the formation of a membrane sealing material having reduced elution of low-molecular weight reaction products; and a membrane sealing material and a membrane module using this composition. Disclosed is a composition for forming a polyurethane resin used for a membrane sealing material, the composition including a base agent (A) and a curing agent (B), wherein the base agent (A) comprises an isocyanate group-terminated prepolymer (A1), the isocyanate group-terminated prepolymer (A1) is a reaction product between an isocyanate group-containing compound (a1) and an active hydrogen-containing compound (a2), the base agent (A) comprises diphenylmethane diisocyanate, the monomer content of the diphenylmethane diisocyanate is 35% by mass or less, and the curing agent (B) comprises a compound (b1) represented by Formula (1). In Formula (1), R represents an alkyl group having 2 or more carbon atoms. 110.-. (canceled)12. The composition for forming a polyurethane resin used for a membrane sealing material according to claim 11 , wherein the isocyanate group-terminated prepolymer (A1) is an allophanate group-containing polyisocyanate.14. The composition for forming a polyurethane resin used for a membrane sealing material according to claim 11 , wherein R in Formula (1) is an alkyl group having 6 to 24 carbon atoms.15. The composition for forming a polyurethane resin used for a membrane sealing material according to claim 13 , wherein R in Formula (1) is an alkyl group having 6 to 24 carbon atoms.16. The composition for forming a polyurethane resin used for a membrane sealing material according to claim 11 , wherein a hydrophilic-lipophilic balance (HLB) of the curing agent (B) is 9.0 or less.17. The composition for forming a polyurethane resin used for a membrane sealing material according to claim 13 , wherein a ...

METAL COMPLEX COMPOUNDS AS CATALYSTS FOR POLYURETHANE COMPOSITIONS

The invention relates to metal complex compounds of the formula M(L)(Y), where the ligand L has the formula (I), and to metal complex compounds which include the reaction product of at least one salt or a complex of a transition metal or a main group metal element of the groups 13 to 15 and at least one 1,3-ketoamide. Such complex compounds are suitable in particular as catalysts for polyurethane compositions. The invention also relates to two-component polyurethane compositions including at least one polyisocyanate as the first component, at least one polyol as the second component, and at least one such metal complex compound as the catalyst. The invention additionally relates to different uses of the two-component polyurethane compositions. 2. Metal complex compound according to claim 1 , wherein the metal cation is a metal cation or oxometal cation of scandium claim 1 , yttrium claim 1 , lanthanum claim 1 , titanium claim 1 , zirconium claim 1 , hafnium claim 1 , vanadium claim 1 , niobium claim 1 , tantalum claim 1 , chromium claim 1 , molybdenum claim 1 , tungsten claim 1 , manganese claim 1 , iron claim 1 , cobalt claim 1 , nickel claim 1 , copper claim 1 , zinc claim 1 , aluminum claim 1 , gallium claim 1 , indium claim 1 , germanium claim 1 , tin claim 1 , lead claim 1 , antimony and bismuth.3. Metal complex compound according to claim 1 , wherein the metal cation or oxometal cation is a dioxomolybdenum (VI) claim 1 , iron (III) claim 1 , zinc (II) claim 1 , bismuth (III) or zirconium (IV) cation.4. Metal complex compound according to claim 1 , wherein Rstands for an alkyl residue with 1 to 4 carbon.5. Metal complex compound according to claim 1 , wherein Rstands for a hydrogen residue.6. Metal complex compound according to claim 1 , wherein Rstands for a hydrogen residue claim 1 , an alkyl residue with 1 to 8 carbon atoms.7. Metal complex compound according to claim 1 , wherein A stands for a polyoxyalkylene residue or a residue of a polyoxyalkylated ...

POLYURETHANE COATING MATERIAL COMPOSITION, MULTISTAGE COATING METHODS USING THESE COATING MATERIAL COMPOSITIONS, AND ALSO THE USE OF THE COATING MATERIAL COMPOSITION AS CLEARCOAT MATERIAL AND PIGMENTED COATING MATERIAL, AND APPLICATION OF THE COATING METHOD FOR AUTOMOTIVE REFINISH AND/OR FOR THE COATING OF PLASTICS SUBSTRATES AND/OR OF UTILITY VEHICLES

The present invention relates to coating material compositions comprising at least one polyhydroxyl group-containing compound (A), at least one polyisocyanate group-containing compound (B) having free and/or blocked isocyanate groups, and at least one catalyst (D) based on a zinc-amidine complex which is prepared by reaction of 1.0 moles of at least one zinc(II) biscarboxylate with less than 2.0 moles of at least one amidine 2. The coating material composition of claim 1 , wherein the radicals Rand Rare identical or different radicals selected from the group consisting of acyclic alkyl radicals claim 1 , straight-chain alkyl radicals claim 1 , branched alkyl radicals claim 1 , aryl radicals claim 1 , and mixtures of two or more of the foregoing claim 1 , and wherein the radicals Rand Rare identical or different members selected from the group consisting of hydrogen claim 1 , acyclic alkyl radicals claim 1 , straight-chain alkyl radicals claim 1 , branched alkyl radicals claim 1 , aryl radicals claim 1 , and mixtures of two or more of the foregoing.3. The coating material composition of claim 1 , wherein the zinc-amidine complex is selected from the group consisting of the reaction product of 1.0 moles of one or more zinc(II) biscarboxylates with 0.1 to 1.8 moles of an amidine of the formula (I) claim 1 , the reaction product of 1.0 moles of one or more zinc(II) biscarboxylates with 0.1 to 1.8 moles of a mixture of two or more amidines of the formula (I).4. The coating material composition of claim 1 , wherein the carboxylate radical of the zinc-amidine complex (D) is selected from the group consisting of carboxylate radicals of aliphatic linear and/or branched claim 1 , optionally substituted monocarboxylic acids having 1 to 12 C atoms in the alkyl radical claim 1 , aromatic claim 1 , optionally substituted monocarboxylic acids having 6 to 12 C atoms in the aryl radical and mixtures of two or more of the foregoing.5. The coating material composition of claim 1 , ...

DUAL CURE RESINS FOR ADDITIVE MANUFACTURING

Provided herein is a resin product useful for the production of three-dimensional objects by additive manufacturing, and methods using the same. The resin may include a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups; a polyol; a photoinitiator; and at least one organometallic catalyst. A packaged product useful for the production of three-dimensional objects by additive manufacturing, the product comprising a single container having a single chamber and a resin in the chamber with all components mixed together, is also provided. 1. A resin product useful for the production of three-dimensional objects by additive manufacturing , comprising:(a) a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups (e.g., in an amount of from 5 to 90 percent by weight);(b) a polyol (e.g., a diol or triol) (e.g., in an amount of from 5 to 30 or 40 percent by weight);(c) a photoinitiator (e.g., a free radical photoinitiator) (e.g., in an amount of from 0.1 to 4 percent by weight);(d) at least one non-tin organometallic catalyst (e.g., in a total amount of from 0.01, 0.05, 0.1, 0.2, or 0.3 percent by weight to 1, 2 or 3 percent by weight), said at least one non-tin organometallic catalyst comprising a metal carboxylate;(e) optionally, but in some embodiments preferably, a reactive diluent (e.g., in an amount of from 1 or 5 percent by weight to 40 or 50 percent by weight);(f) optionally, but in some embodiments preferably, a filler (e.g., in an amount of from 1, 2, 5 or 10 percent by weight to 50 percent by weight); and(g) optionally, but in some embodiments preferably, a pigment or dye (e.g., in an amount of from 0.05, 0.1 or 0.5 percent by weight to 2, 4 or 6 percent by weight).2. The resin of claim 1 , wherein said prepolymer comprises a polyurethane prepolymer claim 1 , a polyurea prepolymer claim 1 , a polyurethane-polyurea copolymer claim 1 , or a combination thereof.3. The resin of claim 1 , said ...

Dispersion

The present invention relates to a dispersion comprising (A) a carrier fluid in an amount from 35 to 95 wt. %, the carrier fluid comprising: (A1) water, and (A2) at least one compound selected from the group consisting of ethanol, 1-propanol, 2-propanol, ethyl acetate, n-propyl acetate, isopropyl acetate, acetone, methyl ethyl ketone and any mixture of at least two of these compounds, whereby the amount of water (A1) relative to the carrier fluid (A) is less than 85 wt. % and the amount of water relative to the dispersion is from 1 to 30 wt. %; and (B) polymer(s) in an amount from 5 to 65 wt. %, the polymer(s) comprising: (B1) polymeric particles having a volume average particle size from 1 μm to 20 μm, whereby the polymer of the polymeric particles (B1) has a weight average molecular weight of at least 100 kDaltons and whereby the polymer of the polymeric particles (B1) is selected from the group consisting of polyurethane, polyurethane-polyacrylate hybrid and any mixture thereof; and whereby the amounts of (A) and (B) are given relative to the total amount of (A) and (B).

Biocompatible, Biodegradable Polyurethane Materials With Controlled Hydrophobic to Hydrophilic Ratio

The biocompatible, biodegradable materials in the solid and/or liquid form are based on segmented linear polyurethanes and/or segmented crosslinked polyurethanes based on A) one or more biocompatible polyols susceptible to hydrolytic and/or enzymatic degradation having a molecular weight of 100 to 20,000 dalton and a number of active hydroxyl groups per molecule (functionality) of at least two or higher: B) one or more diisocyanates and/or triisocyanates; and C) one or more low molecular weight chain extenders having a molecular weight of 18 to 1000 dalton and the functionality of at least two or higher.

SYNTACTIC POLYURETHANE ELASTOMER BASED ON SOFT SEGMENT PREPOLYMER AND NON-MERCURY CATALYST FOR USE IN SUBSEA PIPELINE INSULATION

Syntactic polyurethane elastomers are made using a non-mercury catalyst. The elastomer is made from a reaction mixture containing a prepolymer made from a polyether polyol and a polyisocyanate, a chain extender, a polyisocyanate and microspheres. The elastomer adheres well to itself, which makes it very useful as thermal insulation for pipelines and other structures that have a complex geometry. 1. A method for making a syntactic polyurethane elastomer , comprisinga) forming a reaction mixture containing an alkylene glycol chain extender, 5 to 50 weight percent, based on the weight of the reaction mixture, of microspheres, an isocyanate-terminated prepolymer having an isocyanate content of 3 to 12% by weight, and a non-mercury catalyst, wherein (i) the prepolymer is the reaction product of at least one polyether polyol having a number average hydroxyl equivalent weight of at least 800 with an excess of an aromatic polyisocyanate, (ii) the amount of prepolymer provided to the reaction mixture is sufficient to provide an isocyanate index of 80 to 130, (iii) wherein the non-mercury catalyst is a zinc carboxylate or a mixture of 98-99.99 weight percent of one or more zinc carboxylates and 0.01 to 2 weight percent of one or more zirconium carboxylates and (iv) the reaction mixture is essentially devoid of mercury compounds, andb) curing the reaction mixture to form the syntactic polyurethane elastomer.2. The process of wherein in step b) is performed on the surface of a substrate to form a coating of the syntactic polyurethane elastomer on the substrate.3. A process for producing a substrate having an applied syntactic polyurethane elastomer claim 1 , comprisinga) forming a section of a syntactic polyurethane elastomer on at least a portion of the substrate by (1) applying a first reaction mixture containing an alkylene glycol chain extender, 5 to 35 weight percent, based on the weight of the reaction mixture, of microspheres, an isocyanate-terminated prepolymer having ...

LATENT CATALYST FOR THE PRODUCTION OF POLYURETHANE FOAM

The present technology provides a foam-forming composition comprising at least one polyol, at least one isocyanate, at least one copper catalyst composition, and at least one surfactant. The copper catalyst composition may comprise a copper (II) compound dissolved in a solvent. In one embodiment, the copper catalyst composition comprises (Cu(II)(acac)) dissolved in DMSO. 1. A foam-forming composition comprising:a) at least one polyol;b) at least one isocyanate;c) a catalyst composition comprising a copper (II) compound dissolved in a solvent; andd) at least one surfactant.2. The foam-forming composition of claim 1 , where the copper (II) compound comprises copper (II) coordinated to a ligand chosen from a carboxylate claim 1 , a diketonate claim 1 , a salicylate claim 1 , an organic salt claim 1 , a halide claim 1 , or a combination of two or more thereof.3. The foam-forming composition of claim 1 , where the catalyst composition comprises (Cu(II)(acac)).4. The foam-forming composition of claim 3 , where the solvent comprises DMSO.5. The foam-forming composition of claim 4 , where the catalyst composition comprises a co-diluent chosen from a fatty acid claim 4 , a vegetable oil claim 4 , or a combination thereof.6. The foam-forming composition of claim 1 , wherein the catalyst composition comprises two or more Cu(II) salts.7. The foam-forming composition of claim 6 , wherein the catalyst composition comprises Cu(II)(acac)and Cu(II)acetate.8. The foam-forming composition of claim 1 , where the catalyst composition comprises a copper concentration of about 0.04 to about 10% by weight of the catalyst composition.9. The foam-forming composition of claim 1 , comprising an optional component (e) chosen from a blowing agent claim 1 , a chain extender claim 1 , a crosslinker claim 1 , a filler claim 1 , a reinforcement claim 1 , a pigment claim 1 , a tint claim 1 , a dye claim 1 , a colorant claim 1 , a flame retardant claim 1 , an antioxidant claim 1 , an antiozonant claim ...

Flame-resistant polymer polyol dispersion

The invention relates to a process for preparing a flame-resistant polymer-modified polyol having a solids content of 1 to 65 wt. % wherein (i) at least one polyisocyanate and (ii) an olamine are reacted in (iii) a base polyol having at least two active hydrogen containing groups of which more than 50% are primary active hydrogen containing groups and wherein the olamine has at least one phosphonic ester group attached to a tertiary nitrogen atom and contains at least two hydroxyl groups. The invention further relates to a flame-resistant polymer-modified polyol obtainable with the process of the invention, to a process for preparing optionally foamed plastics using the polymer- modified polyol of the invention, and to the use of a polymer-modified polyol for the preparation of flexible polyurethane foams.

ZINC KETOIMINATE COMPLEXES AS CATALYSTS FOR THE PRODUCTION OF POLYURETHANES

The use of zinc ketoiminate complexes in the production of polyurethanes is described, wherein the zinc ketoiminate complexes are obtainable by reacting a zinc compound with certain ketimines. 3. The process according to claim 1 , wherein the zinc compound (A) is an organozinc compound.4. The process according to claim 3 , wherein an organozinc compound is used claim 3 , and the alcohol is added after (A) has been reacted with (B).5. The process according to claim 3 , wherein the zinc ketoiminate complex are obtained by reaction of zinc salt with previously deprotonated ketimines (B) and alkoxide claim 3 , which have been converted into the anionic form by exposure to a suitable base.6. The process according to claim 3 , wherein the zinc ketoiminate complex are obtained by reacting a zinc salt claim 3 , with alkoxide or polyether ion previously deprotonated by exposure to suitable basic substances claim 3 , such that a zinc dialkoxide is formed claim 3 , which is reacted with previously deprotonated ketimines (B).7. The process according to claim 1 , wherein the zinc ketoiminate complex is used as catalyst in the production of polyurethanes.8. The process according to claim 1 , wherein a PU coating claim 1 , PU adhesive claim 1 , PU sealant or PU elastomer is produced.9. The process according to claim 1 , wherein in the production of the polyurethane a composition is prepared which comprises at least one zinc ketoiminate complex claim 1 , at least one polyol component and at least one isocyanate component claim 1 , and this composition is reacted.11. A composition comprising at least one polyol component claim 1 , wherein the composition comprises at least one zinc ketoiminate complex as defined in .12. The composition according to claim 11 , wherein the composition comprises at least one isocyanate component.13. A polyurethane system claim 1 , wherein the polyurethane system is obtained by the process according to .14. The polyurethane system according to claim 13 ...

THERMOPLASTIC POLYURETHANES MADE WITH TIN-FREE CATALYSTS

Thermoplastic polyurethanes, including those based on aliphatic isocyanates, are of great interest for industrial applications that require UV-stability. To overcome the low reactivity of some diisocyanates a catalyst is usually added to accelerate urethane formation. In most applications, organotin-based compounds are used, however, due to growing concerns about the toxicity of some of these organotin compounds, their use is being restricted and the need for alternative catalysts is growing. The thermoplastic polyurethanes described herein are made using tin-free catalysts while retaining the UV-stability and other properties required for many industrial applications. 1. A thermoplastic polyurethane composition comprising the reaction product of:a) a polyisocyanate;b) a polyol component; andc) a chain extender component;wherein the reaction is carried out in the presence of a catalyst;wherein said catalyst comprises one or more iron compounds.2. The thermoplastic polyurethane composition of wherein the catalyst is free of tin.3. The thermoplastic polyurethane composition of wherein the catalyst comprises a compound having the general structure (X)-M-(Y)where m is 2 or 3 claim 1 , M is iron; each X is independently a ligand with a −1 charge claim 1 , obtained by deprotonation of a β-diketone compound claim 1 , a β-ketoester compound claim 1 , a β-ketoamide compound or any other β-dicarbonyl compound claim 1 , chloride claim 1 , bromide claim 1 , iodide claim 1 , fluoride claim 1 , perchlorate claim 1 , alkoxide claim 1 , alkylsulfonate claim 1 , arylsulfonate claim 1 , alkylsulfate claim 1 , arylsulfate claim 1 , hydroxide claim 1 , or a combination of these ligands; each Y is a neutral ligand; and n is an integer between 0 and 6.4. The thermoplastic polyurethane composition of wherein the catalyst comprises a compound of Fe(III) or Fe(II) containing three or two anionic ligands claim 1 , each formed by deprotonation of a β-diketone claim 1 , a β-ketoester claim 1 , ...

Polyurethanes Made with Copper Catalysts

Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a copper catalyst that contains at least one copper atom associated with a polydentate ligand that contains at least one nitrogen-containing complexing site. 1. A process for preparing a polyisocyanate-based polymer , comprising forming a reaction mixture containing at least one polyisocyanate , at least one isocyanate-reactive compound having at least two isocyanate-reactive groups and at least one copper catalyst , and then curing the reaction mixture to form a polymer , wherein the copper catalyst contains at least one copper atom associated with a polydentate organic ligand that contains at least two complexing sites , of which at least one is nitrogen-containing , wherein the ligand isa) a β-amino alcohol or enol;b) a β-imino alcohol or enol;c) a β-enamino alcohol;d) a β-amino keto or β-enamino keto or ester compound;e) a β-diketiminate compound; orf) a β-diamine compound.27-. (canceled)9. (canceled)10. The process of wherein each R claim 8 , R claim 8 , Rand Ris independently hydrogen or a hydrocarbyl group that is unsubstituted claim 8 , inertly substituted claim 8 , or substituted with one or more complexing sites.11. (canceled)1316-. (canceled)1820-. (canceled)2224-. (canceled)2627-. (canceled)28. The process of wherein the polyisocyanate-based polymer is a polyurethane claim 1 , polyurea claim 1 , or polyurethane-urea.29. The process of claim 1 , wherein the reaction mixture further contains a blowing agent and a surfactant claim 1 , and the polyisocyanate-based polymer is a foam.30. The process of claim 1 , wherein the isocyanate-reactive compound includes a polyol having a molecular weight of from 800 to 12 claim 1 ,000 and an average of from 1.8 to 2.5 hydroxyl groups per molecule claim 1 , and the polyisocyanate-based polymer is a cast ...

DIOXOMOLYBDENUM (VI) COMPLEX COMPOUNDS AS CATALYSTS FOR POLYURETHANE COMPOSITIONS

The invention relates to dioxomolybdenum (VI) complex compounds of the formula MoO(L)(Y), where the ligand L has the formula (I). Such complex compounds are suitable in particular as catalysts for one- and two-component polyurethane compositions. The invention also relates to two-component polyurethane compositions including at least one polyisocyanate as the first component, at least one polyol as the second component, and at least one such dioxomolybdenum (VI) complex compound as the catalyst. The invention further relates to one-component polyurethane compositions comprising at least one polyurethane prepolymer with isocyanate groups, which are made from at least one polyisocyanate with at least one polyol, and comprising such a dioxomolybdenum (VI) complex compound as the catalyst. The invention additionally relates to different uses of said polyurethane compositions. 2. Dioxomolybdenum(VI) complex compound according to claim 1 , where Rstands for an alkyl residue having 1 to 4 carbon atoms claim 1 , for a phenyl residue claim 1 , or together with Rstands for a bivalent alkylene residue having 3 to 4 carbon atoms.3. Dioxomolybdenum(VI) complex compound according to claim 1 , where Rstands for a hydrogen residue.4. Dioxomolybdenum(VI) complex compound according to claim 1 , where Rstands for a hydrogen residue claim 1 , an alkyl residue having 1 to 8 carbon atoms claim 1 , a cycloalkyl residue having 5 to 6 carbon atoms claim 1 , a hydroxyalkyl residue having 1 to 4 carbon atoms claim 1 , an alkyl ether residue having 1 to 4 carbon atoms claim 1 , or together with Rstands for a bivalent alkylene residue of formula —(CH)—X—(CH)— with X=O claim 1 , NR claim 1 , where R is a monovalent alkyl residue having 1 to 4 carbon atoms claim 1 , or S claim 1 , and n=2 to 6.5. Dioxomolybdenum(VI) complex compound according to claim 1 , where Rstands for a hydrogen residue claim 1 , an alkyl residue having 1 to 8 carbon atoms claim 1 , a cycloalkyl residue having 5 to 6 carbon ...

FINE POWDER-COATED AMINE AND COMPOSITION CONTAINING SAME

This invention relates to a fine powder-coated amine comprising a solid amine having a melting point equal to or higher than 50° C. and a mean particle size equal to or smaller than 20 μm. The fine powder-coated amine has an amount of heat in the second absorption peak measured by a differential scanning calorimeter equal to or less than 220 J/g, and the surface of the solid amine is coated with fine powder having a mean particle size equal to or smaller than 2 μm. 1. A fine powder-coated amine comprising a solid amine having a melting point equal to or higher than 50° C. and a mean particle size equal to or smaller than 20 μm , wherein the fine powder-coated amine has an amount of heat in the second absorption peak measured by a differential scanning calorimeter equal to or less than 220 J/g , and the surface of the solid amine is coated with fine particles having a mean particle size equal to or smaller than 2 μm.2. The fine powder-coated amine according to claim 1 , wherein the solid amine is an aromatic or aliphatic amine compound.3. The fine powder-coated amine according to claim 1 , wherein the solid amine has a mean particle size of 1 μm to 20 μm.4. The fine powder-coated amine according to claim 1 , wherein a weight ratio of the solid amine to the fine particles is from 1/0.001 to 1/0.5.5. The fine powder-coated amine according to claim 1 , wherein the fine particles are at least one selected from the group consisting of a polyvinyl chloride claim 1 , titanium oxide claim 1 , calcium carbonate claim 1 , clay claim 1 , carbon claim 1 , alumina claim 1 , talc claim 1 , zinc oxide and silica.6. A one-pack type heat curable composition comprising the fine powder-coated amine according to .7. The one-pack type heat curable composition according to claim 6 , comprising an isocyanate component. The present application claims the Paris Convention priority based on Japanese Patent Application No. 2015-217842 filed on Nov. 5, 2015, the entire content of which is ...

High temperature-resistant polyisocyanurate foams

The present invention relates to a polyisocyanurate foam obtainable by reacting a mixture in the presence of a catalyst and optionally an initiator, comprising or consisting of: A) a polyisocyanate component comprising at least one aliphatic polyisocyanate; B) a component reactive to isocyanate comprising at least one polyol and/or an alcohol and also optionally an amine; C) at least one blowing agent; D) at least one foam stabilizer and E) optionally at least one additive, characterized in that the mixture, upon accompanying use of an isocyanate-reactive component (polyol, alcohol, amine), has an index of at least 200. The invention further relates to a process for producing such a foam and use thereof as an insulating material, as a construction element, as facade insulation, as reactor insulation, as battery insulation, as superheated steam insulation, as insulation for a still, or as weather-resistant insulating material.

Polyether-polysiloxane block copolymer composition, surfactant and foam stabilizer including same, polyurethane foam-forming composition, cosmetic, and preparation method thereof

A polyether-polysiloxane block copolymer composition is disclosed. The copolymer composition comprises (A) a polyether-polysiloxane block copolymer having in a molecule structural units as expressed by General Formula (1) below: where a terminal group thereof is an alkenyl group or the like bonded to a polyether portion. The copolymer composition further comprises (B) a liquid monool organic compound, which is (B1) a glycol ether compound having a low degree of polymerization, a terminal hydrogen substituted with a hydrocarbon group, and a secondary alcoholic hydroxyl group provided on another terminal, or (B2) a higher alcohol compound having a branched alkyl group with 12 or more carbon atoms. The copolymer composition generally does not contain a dimethyl polysiloxane at more than the mass of component (A). A manufacturing method, foam stabilizer or the like containing the copolymer composition, and a polyurethane foam are also disclosed.

Method of reducing odors of lipid-based polyols

A method of reducing odors in lipid-based polyol. At least one lipid-based polyol is provided, and mixed with ricinoleic acid and/or a metal salt of ricinoleic acid. Isocyanate may be added, preferably toluene diisocyanate (TDI). The polyol, and the isocyanate when present, are reacted in the presence of the ricinoleic acid and/or a metal salt of ricinoleic acid which reduces or removes odors in the lipid-based polyol. When isocyanate is used, low, limiting levels are preferred, well below the level required to fully react with all of the polyol. Tin, zinc, sodium, and calcium ricinoleic acid metal salts are particularly preferred. Preferably the reaction takes place without added heat, at room temperature. The reaction may be performed in a chamber which is under at least a partial vacuum.

MOISTURE CURABLE SYSTEMS BASED ON POLYSILYLATED POLYETHERS AND TITANIUM (IV) CATALYSTS AND/OR ZINC/CYCLIC AMIDINE CATALYST MIXTURES

Moisture-curable polysilylated polyether compositions contain titanium (IV) catalysts and/or zinc/amidine catalyst mixtures and are devoid of or nearly devoid of tin compounds. The titanium catalysts and zinc/amide catalyst mixtures are surprisingly found to be highly effective, even when the moisture-curable silane groups of the compositions are dialkoxysilyl groups. The moisture-cured compositions are surprisingly stable when aged at high temperatures. In addition, the compositions are surprisingly storage-stable in the uncured state, particularly when the polysilylated polyethers contain aliphatic urethane groups. The polyether compositions are also preferably devoid of aminosilane adhesion promoters. 1. A moisture-curable polysilylated polyether composition comprisinga) at least one urethane group-containing polysilylated polyether free of urea groups, having two or more dialkoxysilyl and/or trialkoxysilyl groups per molecule and a number average molecular weight of 4,000 to 20,000; andb) a catalytically effective amount of a catalyst selected from a titanium (IV) catalyst and a mixture of a zinc catalyst and a cyclic amidine catalyst;the polysilylated polyether composition containing no more than 1000 parts by weight tin per million parts by weight of the polysilylated polyether.2. The moisture-curable polysilylated polyether composition of claim 1 , wherein the polysilylated polyether contains two or more dialkoxysilyl groups per molecule.3. The moisture-curable polysilylated polyether composition of claim 2 , wherein the dialkoxysilyl groups are alkyldimethoxylsilyl or alkyldiethyoxysilyl groups.4. The moisture-curable polysilylated polyether composition of claim 3 , wherein the urethane groups of the polysilylated polyether are aliphatic urethane groups.5. The moisture-curable polysilylated polyether composition of claim 4 , which is devoid of aminosilane compounds.6. The moisture-curable polysilylated polyether composition of claim 4 , which contains an ...

POLYMER-MODIFIED POLYOL DISPERSION

The invention relates to a method of making a polymer-modified polyol having a solid content from 13 to 55 wt. % wherein an olamine is reacted with an organic polyisocyanate in the presence of a base polyol and at least one catalyst, wherein said at least one catalyst is a zinc carboxylate, and wherein the base polyol has hydroxyl functions wherein more than 20% of said hydroxyl functions are primary hydroxyl functions. The invention further relates to a polymer-modified polyol obtainable with the method of the invention, the use of the polymer-modified polyol for the preparation of optionally foamed plastics, and to a method for the preparation of optionally foamed plastics using the polymer-modified polyol of the invention. 125-. (canceled)26. A method of making a polymer-modified polyol dispersion having a solid content from about 13 to about 55 wt % based on the total weight of the dispersion comprising:reacting an olamine with an organic polyisocyanate in the presence of a base polyol, one or more catalysts, and a cross-linking agent,wherein the catalysts comprises a zinc carboxylate, the base polyol has hydroxyl functions where more than about 20% of said hydroxyl functions are primary hydroxyl functions, and the cross-linking agent has a weight average molecular weight of from about 200 to about 1000 g/mol.27. The method according to claim 26 , wherein the polymer-modified polyol dispersion has a solid content from about 15 to about 50 wt % based on the total weight of the dispersion.28. The method according to claim 26 , wherein the ratio of active hydrogen containing groups of the olamine to isocyanate groups of the polyisocyanate is from about 1 to about 2:1.29. The method according to claim 26 , wherein the catalyst is used in an amount of greater than about 0.01 claim 26 , greater than about 0.03 or greater than about 0.04 or greater than about 0.1 mmol/100 g polymer-modified polyol or in an amount of from about 0.105 to about 0.25 mmol/100 g polymer- ...

AQUEOUS POLYMER COMPOSITIONS COMPRISING POLYURETHANE (METH)ACRYLATES

Aqueous polymer compositions and their use as coatings are disclosed. A composition includes at least one polyurethane (meth)acrylate A and at least one compound B having a molecular weight of below 1000 g/mol and having at least two ethylenically unsaturated double bonds per molecule. The polyurethane (meth)acrylates A include the following components: component A1 includes at least one polyisocyanate A1a and at least one diisocyanate A1b; component A2 includes at least one compound having at least one ethylenically unsaturated double bond, and at least one functional group F; component A3 includes at least one neutral polyol including at least one aliphatic, polymeric polyol A3a and at least one low molecular weight diol A3b; component A4 includes at least one compound having at least one ionic or ionizable group I′ and at least one functional group F′; and component A5 includes at least one poly-C-Calkylene ether. 120-. (canceled)22. The composition according to claim 21 , the polyisocyanate A1a being selected from isocyanurates of a diisocyanate which has at least one saturated alicyclic structural unit claim 21 , and the diisocyanate A1b being selected from saturated alicyclic diisocyanates.23. The composition according to claim 21 , the polyisocyanate A1a making up 40 to 95 wt % claim 21 , based on a total weight of the isocyanate component A1.24. The composition according to claim 21 , a total amount of polyisocyanate A1a and diisocyanate A1b making up at least 50 wt % claim 21 , based on a total weight of the isocyanate component A1.25. The composition according to claim 21 , the isocyanate component A1 further comprising at least one polyisocyanate A1c having an average isocyanate functionality of at least 2.5 and obtainable by oligomerization of a C-Calkylene diisocyanate claim 21 , and selected from an isocyanurate of hexamethylene diisocyanate.26. The composition according to claim 21 , component A2 being selected from hydroxy-C-Calkyl esters of acrylic ...

SCRATCH-RESISTANT TWO-COMPONENT POLYURETHANE COATINGS

The invention relates to coating agents that contain thioallophanates, containing silane groups, as cross-linking agents and to the use of said coating agents to produce coatings, in particular clear coats for automobile painting. 115.-. (canceled)17. The coating composition as claimed in claim 16 , characterized in that the polyisocyanate component A) comprises at least one thioallophanate containing silane groups claim 16 , of the formula (I) claim 16 , in which{'sup': 1', '2', '3, 'R, Rand Rare identical or different radicals and are each a saturated, linear or branched, aliphatic or cycloaliphatic radical having up to 6 carbon atoms, and optionally contain up to 3 oxygen atoms, and'}X is a linear or branched alkylene radical having 2 to 10 carbon atoms, and{'claim-ref': {'@idref': 'CLM-00016', 'claim 16'}, 'Y and n have the definition stated in .'}18. The coating composition as claimed in claim 16 , characterized in that the polyisocyanate component A) comprises at least one thioallophanate containing silane groups claim 16 , of the formula (I) claim 16 , in which{'sup': 1', '2', '3', '1', '2', '3, 'R, Rand Rare each alkyl radicals having up to 6 carbon atoms and/or alkoxy radicals which contain up to 3 oxygen atoms, with the proviso that at least one of the radicals R, Rand Ris such an alkoxy radical, and'}{'sub': 2', '2', '2, 'X is a propylene radical (—CH—CH—CH—),'}{'claim-ref': {'@idref': 'CLM-00016', 'claim 16'}, 'Y and n have the definition stated in .'}19. The coating composition as claimed in claim 16 , characterized in that the polyisocyanate component A) comprises at least one thioallophanate containing silane groups claim 16 , of the formula (I) claim 16 , in which{'sup': 1', '2', '3', '1', '2', '3, 'R, Rand Rare identical or different radicals and are each methyl, methoxy or ethoxy, with the proviso that at least one of the radicals R, Rand Ris a methoxy or ethoxy radical,'}{'sub': 2', '2', '2, 'X is a propylene radical (—CH—CH—CH—), and'}{'claim-ref ...