ПОЛИМОЧЕВИНО/ПОЛИТИОМОЧЕВИНОВЫЕ ПОКРЫТИЯ

FIELD: chemistry. ^ SUBSTANCE: polyurea and polythiourea contained in the disclosed compositions are obtained from a reaction mixture containing: a first component which contains isocyanate and isocyanate-functional polythioether-polyurethane and/or polythiourethane; and a second component containing an amine; from a reaction mixture which contains: a first component containing isocyanate; a second component containing amine and amine/hydroxy-functional polythioether; and from a reaction mixture containing a first component which contains isocyanate and isocyanate-functional polythioether-polyurethane and/or polythiourethane; and a second component containing amine and amine/hydroxy-functional polythioether, respectively. ^ EFFECT: obtaining compositions whose coatings applied on a substrate have significant longevity, avoid tackiness of the layer and dampen explosion pressure or ballistic impact on the substrate. ^ 37 cl, 15 ex, 3 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 429 249 (13) C1 (51) МПК C08G C08G C08G C08G C08G C08G C09D ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ 18/10 18/12 18/32 18/38 18/48 18/52 175/02 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ИЗОБРЕТЕНИЯ К ПАТЕНТУ (24) Дата начала отсчета срока действия патента: 19.06.2008 Приоритет(ы): (30) Конвенционный приоритет: 03.07.2007 US 11/773,051 (45) Опубликовано: 20.09.2011 Бюл. № 26 (73) Патентообладатель(и): ППГ ИНДАСТРИЗ ОГАЙО, ИНК. (US) 2 4 2 9 2 4 9 R U (86) Заявка PCT: US 2008/067476 (19.06.2008) C 1 C 1 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 03.02.2010 (87) Публикация заявки РСТ: WO 2009/006034 (08.01.2009) Адрес для переписки: 109012, Москва, ул. Ильинка, 5/2, ООО "Союзпатент", О.И.Воль (54) ПОЛИМОЧЕВИНО/ПОЛИТИОМОЧЕВИНОВЫЕ ПОКРЫТИЯ (57) Реферат: Настоящее изобретение относится к композициям покрытия, содержащим полимочевину и политиомочевину, к способам их нанесения на подложку и к самой подложке, ...

VERWENDUNG VON ZWEIKOMPONENTEN-BINDEMITTELKOMBINATIONEN IN AUTOREPARATURLACKEN

SYNERGISTISCHE AMIN-KETTENVERLÄNGERUNGSMITTEL IN POLYURETHANSPRITZELASTOMEREN

Kapsel mit organisch-anorganischer Hybridwand

Die vorliegende Erfindung betrifft eine Kapsel, umfassend oder bestehend aus einem Kern und einer den Kern umschließenden Hülle, wobei die Hülle ein polymeres Material umfasst und daraus besteht, welches herstellbar ist durch Reaktion einer Komponente (A) mit einer Komponente (B), wobei Komponente (A) aus einem oder mehreren Aminogruppen tragenden Polysiloxanen besteht und Komponente (B) aus einem oder mehreren Polyisocyanaten besteht. The present invention relates to a capsule comprising or consisting of a core and a shell enclosing the core, the shell comprising and consisting of a polymeric material which is preparable by reacting a component (A) with a component (B), wherein component (A) consists of one or more amino-carrying polysiloxanes and component (B) consists of one or more polyisocyanates.

VERFAHREN ZUR HERSTELLUNG VON POLYURETHANSCHAUMSTOFFEN

HARDER FOR THE PU PRODUCTION.

DIAMINE CHAIN EXTENDER COMPOSITIONS

This invention provides chain extender compositions. These compositions c omprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphati c primary diamine; (c) an aliphatic secondary diamine and an aliphatic prima ry diamine; (d) a diimine; and (e) a combination of any two or more of (a) t hrough (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are sec ondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aroma tic diimine, each imino hydrocarbylidene group has at least two carbon atoms . Processes for producing polyurethanes, polyureas, and polyurea-urethanes a re also provided.

METHODS FOR REACTIVE THREE-DIMENSIONAL PRINTING BY EXTRUSION

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also enclosed.

ISOCYANATE-BASED PREPOLYMER

The invention relates to an isocyanate-containing prepolymer obtained from a stepwise mixing by reacting at least one isocyanate with at least one first compound selected from the group consisting of monohydric thiols, monohydric secondary amines, and monohydric alcohols, and subsequently with at least one second compound selected from the group consisting of monohydric thiols, monohydric secondary amines, and monohydric alcohols, wherein said at least one second compound is different from said at least one first compound, wherein the at least one isocyanate comprises polymeric methylene diphenyl diisocyanate and wherein the ratio of the NCO value of the isocyanate-containing prepolymer, to the weighted average of the monohydric alcohols, monohydric thiols and monohydric secondary amines value, of said first and second compounds ranges from 0.0005 to 1.0000. This prepolymer can be used as a one-component adhesive or as a component in a two-component adhesive.

TWO-COMPONENT COATING COMPOSITIONS FOR MOTOR VEHICLE REPAIR LACQUERS

Mo3614 LeA 27,837 TWO-COMPONENT COATING COMPOSITIONS FOR MOTOR VEHICLE REPAIR LACQUERS The present invention relates to an improved process for repairing a motor vehicle by applying a coating composition wherein improvement is the use of a binder containing a) a polyisocyanate component and b) a mixture of organic compounds having isocyanate-reactive groups containing b1) a secondary diamine corresponding to formula I (I) and b2) a polyhydroxyl component containing (i) a polyhydroxypolyacrylate or (ii) a mixture of such polyhydroxypolyacrylate with up to 95% by weight, based on the weight of (ii), of a polyester polyol, wherein components b1) and b2) are present in a weight ratio of 0.7:1 to 20:1 and components a) and b) are present in an amount which corresponds to an equivalent ratio of isocyanate groups of component a) to isocyanate-reactive groups of component b) of 0.8:1 to 1.5:1. Mo3614 ...

КОМПОЗИЦИЯ УДЛИНИТЕЛЯ ЦЕПИ НА ОСНОВЕ ДИАМИНА

Настоящее изобретение относится к композициям удлинителя цепи. Данные композиции включают: (i) ароматический первичный диамин и (ii) компонент, выбранный из группы, включающей (a) алифатический вторичный диамин; (b) алифатический первичный диамин; (c) алифатический вторичный диамин и алифатический первичный диамин; (d) диимин и (e) комбинацию любых двух или нескольких компонентов по пп. (a)-(d). Когда (ii) представляет собой (а), (а) содержит аминогидрокарбильные группы, которые являются вторичными или третичными гидрокарбильными группами; когда (ii) представляет собой (d), и (d) представляет собой ароматический диимин, каждая иминогидрокарбилиденовая группа содержит по меньшей мере два атома углерода. Также предложены способы получения полиуретанов, полимочевин и полимочевин-уретанов.

СМЕСИ ДИАМИНОВ, ИМЕЮЩИЕ ОСЛАБЛЕННЫЙ ЦВЕТ

Настоящее изобретение обеспечивает смесь, которая включает: (i) по меньшей мере один ароматический первичный диамин, с которым смешано минимизирующее цвет количество по меньшей мере одного N,N-дигидрокарбилгидроксиламина, в которой ароматический первичный диамин представлен в виде одного бензольного кольца, имеющего две первичные аминогруппы в ядре, в котором аминогруппы находятся в мета- или пара-положении друг к другу и в котором каждое орто-положение к первичной аминогруппе несет алкильную группу, и (ii), по меньшей мере один ароматический вторичный диамин, имеющий число цвета по шкале Гарднера не больше чем приблизительно 7, в котором указанный ароматический вторичный диамин либо представлен в виде одного бензольного кольца, имеющего две вторичные аминогруппы в ядре, либо представлен в виде двух бензольных колец, связанных алкиленовым мостиком и имеющих одну вторичную аминогруппу в каждом ядре, с которым по меньшей мере один N,N-дигидрокарбилгидроксиламин необязательно смешали с ароматическим ...

MICROCAPSULE COMPOSITIONS STABILIZED WITH VISCOSITY CONTROL AGENTS

BLENDS OF DIAMINES HAVING REDUCED COLOR

This invention provides a blend which comprises (i) at least one aromatic primary diamine, with which has been blended a color-minimizing amount of at least one N,N-dmydrocarbylhydroxylarnine, wherein the aromatic primary diamine is in the form of one benzene ring having two primary amino groups on the ling, which amino groups are meta or para relative to each other, and in which each position ortho to a primary amino group bears an alkyl group, and (ii) at least one aromatic secondary diamine having a Gardner color number no more than about 7, wherein said aromatic secondary diamine either is in the form of one benzene ring having two secondary amino groups on the ring, or is in the form of two benzene rings connected by an alkylene bridge and having one secondary amino group on each ring. Optionally, at least one N,N-dihydrocarbylhydroxylamine has been blended with the aromatic secondary diamine. © KIPO & WIPO 2008 ...

Diimines and secondary diamines

This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.

MULTI COMPONENT DISPERSANT

The invention relates to a composition comprising i) 10-90 wt. % of an ethylenically unsaturated component (A), ii) 10-90 wt. % of a component (B) having urethane and/or urea groups, iii) 0-4 wt. % of an organic component (C) which is different from components (A) and (B), and iv) 0-9 wt. % of other ingredients (D) wherein the wt. % are calculated on the total weight of the composition, wherein the sum of the wt. % of component (A) and the wt. % of component (B) is 91-100 wt. %, component (A) consists of compounds having 1-8 ethylenically unsaturated bonds and a molar mass of 100-1400 g/mol, component (A) contains no amino groups, component (B) contains no primary and no secondary amino groups, component (B) consists of compounds having 2-40 functional groups selected from urethane and urea groups, having 1-40 groups selected from tertiary amino groups, salts thereof, quaternary ammonium groups, and mixtures thereof, component (B) contains not more tertiary amino groups than the sum of urethane and urea groups, and component (B) has a nitrogen content in the range of 1.0 to 12.0 wt. %, component (C) consists of organic compounds having a molar mass of less than 1000 g/mol.

ПОЛИУРЕТАНЫ, ИЗДЕЛИЯ И ПОКРЫТИЯ, ИЗГОТОВЛЕННЫЕ ИЗ НИХ, И СПОСОБЫ ИХ ПРОИЗВОДСТВА

Изобретение относится к вариантам полиуретана, который характеризуется низкой полосчатостью или отсутствием видимой полосчатости, а также к изделию и ламинату, содержащим такой полиуретан. Полиуретан содержит продукт реакции следующих компонентов: (а) уретанового преполимера с изоцианатной функциональностью, (b) от 0,3 до 0,7 эквивалента триметилолпропана, (с) до 0,4 эквивалента бутандиола или пентандиола. Компонент (а) представляет собой продукт реакции, по меньшей мере, одного полиизоцианата в количестве 1 эквивалент и пентандиола в количестве от 0,35 до 0,4 эквивалента. Продукт реакции компонентов по существу не содержит сложный полиэфирполиол и простой полиэфирполиол. Изделие, содержащее вышеуказанный полиуретан, выбирают из группы, включающей прозрачные изделия, оптические изделия, фотохромные изделия, баллистические стойкие изделия. Ламинат, содержащий, по меньшей мере, один слой вышеуказанного полиуретана, содержит также, по меньшей мере, один слой основы, выбранной из группы, включающей ...

КОМПОЗИЦИЯ ДЛЯ СОКРАЩЕНИЯ КОЛИЧЕСТВА АЛЬДЕГИДОВ, ВЫДЕЛЯЮЩИХСЯ ИЗ ПОЛИУРЕТАНОВЫХ ПЕН

FIELD: chemistry.SUBSTANCE: present invention relates to a curable polyurethane composition having a reduced level of aldehydes release. Said composition contains at least one component which is reactive with respect to isocyanates, an auxiliary reagent, as well as one or more amine components. Auxiliary reagent is selected from group (i) a mixture of cyclic urea, substituted with at least one isocyanate-reactive group, and a free-radical scavenger which contains phosphite, and optionally a polymer acid or (ii) only a polymeric acid. Polymeric acid is any compound containing in its structure three or more identical repeating monomers based on unsaturated carboxylic acid or its anhydride. Cyclic urea is a compound of formula (I),where substituents R, R, R, R, R, R, independently selected from H, OH, ROH, Ris a C1-C4-alkyl group, and additionally provided that at least one of substitutes R' or Ris H, and provided that at least one of substituents R, R, R, R, Ris OH or ROH. One or more amine component has structure in accordance with structural formula,where Rcontains from 3 to 17 nitrogen atoms, as well as a plurality of substitutes selected from R, where Ris,wherein each of said substitutes R, R, Rand Rindependently of each other is -H or -CH.EFFECT: obtained composition reduces the amount of aldehydes released from polyurethane foams obtained using said composition.15 cl, 4 tbl, 2 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 712 184 C2 (51) МПК C08G 18/18 (2006.01) C08G 18/32 (2006.01) C08G 18/38 (2006.01) C08G 18/66 (2006.01) C08G 18/76 (2006.01) C08G 101/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C08G 18/18 (2019.08); C08G 18/32 (2019.08); C08G 18/38 (2019.08); C08G 18/66 (2019.08); C08G 18/76 (2019.08) (21)(22) Заявка: 2017104242, 09.07.2015 09.07.2015 Дата регистрации: Приоритет(ы): (30) Конвенционный приоритет: 10.07.2014 US 62/022,928; 24.07.2014 EP 14178274.8 (43) Дата публикации заявки: ...

СПОСОБЫ РЕАКТИВНОЙ ТРЕХМЕРНОЙ ПЕЧАТИ ПУТЕМ ЭКСТРУЗИИ

Группа изобретений относится к термореактивной композиции для трехмерной печати, используемой для способа печати трехмерного объекта с использованием совместно реагирующих компонентов, и к трехмерному объекту, полученному способом по изобретению. Композиция содержит первый компонент, содержащий первую функциональную группу, и второй компонент, содержащий вторую функциональную группу, вступающие в реакцию между собой. Формирование объекта осуществляется наращиванием последовательных слоев путем экструзии. При формировании объект имеет части, которые отличаются одна от другой по химическим, физическим или термическим свойствам. Технический результат, достигаемый при использовании группы изобретений, заключается в повышении надежности сцепления между слоями объекта при экструзии. 2 н. и 46 з.п. ф-лы, 2 ил., 1 пр., 3 табл.

ПРЕПОЛИМЕР НА ОСНОВЕ ИЗОЦИАНАТА

Настоящее изобретение относится к изоцианатсодержащему преполимеру, способу его получения, а также к клею и однокомпонентной самовыравнивающейся жидкой мембране, полученной с использованием данного изоцианатсодержащего преполимера. Указанный преполимер получен в результате взаимодействия по меньшей мере одного изоцианата с по меньшей мере одним первым соединением и по меньшей мере с одним вторым соединением. Указанные первое и второе соединения каждое независимо представляет собой одноатомный спирт, причем средневесовая молекулярная масса второго соединения ниже, чем первого. Изоцианат включает метилендифенилдиизоцианат. Полученный изоцианатсодержащий преполимер обладает уменьшенным содержанием свободного мономера при сохранении хорошей способности к переработке за счет низкой вязкости, и при этом также сохраняются хорошие механические характеристики преполимера. 6 н. и 7 з.п. ф-лы, 1 ил., 6 табл., 4 пр.

СОВМЕСТНО РЕАГИРУЮЩИЕ МАТЕРИАЛЫ И СПОСОБЫ ТРЕХМЕРНОЙ ПЕЧАТИ

Изобретение относится к способам трехмерной печати и совместно реагирующим композициям для печати, в частности к применению композиций для трехмерной печати, содержащих совместно реагирующие компоненты. Композиция для трехмерной печати включает первый компонент, содержащий первое соединение, имеющее по меньшей мере две первые функциональные группы, а также второй компонент, содержащий второе соединение, имеющее по меньшей мере две вторые функциональные группы, где вторые функциональные группы могут вступать в реакцию с первыми функциональными группами. При этом по меньшей мере одна из первой функциональной группы и второй функциональной группы включает насыщенную функциональную группу. А каждый из первого и второго компонентов имеет вязкость при 25°С и скорости сдвига, равной 0,1 с, от 5000 сантипуаз (сП) до 5000000 сП при измерении с использованием реометра Anton Paar MCR 301 или 302 с зазором от 1 мм до 2 мм. Техническим результатом изобретения является повышение качества изделий. 3 н ...

КОМПОЗИЦИЯ, СОДЕРЖАЩАЯ ЦИКЛИЧЕСКИЙ ВТОРИЧНЫЙ АМИН, И СПОСОБЫ ФОРМИРОВАНИЯ ПОКРЫТИЯ ТРУБОПРОВОДОВ ДЛЯ ПИТЬЕВОЙ ВОДЫ

... 1. Способ формирования покрытия на поверхности трубопровода, при этом способ включает стадии, на которых:a) обеспечивают композицию покрытия, содержащуюпервый компонент, содержащий, по меньшей мере, один полиизоцианат, ивторой компонент, содержащий, по меньшей мере, 20 мас.% алифатического циклического вторичного диамина, содержащего вторичные аминные заместители, не содержащие сложноэфирных групп, и от 20 мас.% до 75 мас.% неорганического наполнителя в виде частиц;b) объединяют первый компонент и второй компонент с образованием жидкой смеси;c) наносят жидкую смесь на внутренние поверхности трубопровода; иd) выдерживают смесь для схватывания с формированием отвержденного покрытия.2. Способ по п.1, отличающийся тем, что жидкую смесь наносят толщиной в диапазоне от приблизительно 1 до 15 мм.3. Способ по п.1, отличающийся тем, что второй компонент содержит алифатический циклический вторичный диамин, содержащий два гексильных кольца, связанных мостиковой группой.4. Способ по п.3, отличающийся ...

ПОЛИУРЕТАНЫ, ИЗДЕЛИЯ И ПОКРЫТИЯ, ИЗГОТОВЛЕННЫЕ ИЗ НИХ, И СПОСОБЫ ИХ ПРОИЗВОДСТВА

... 1. Полиуретан, содержащий продукт реакции компонентов, включающих:(а) уретановый преполимер с изоцианатной функциональностью, содержащий продукт реакции компонентов, включающих:(i) приблизительно 1 эквивалент, по меньшей мере, одного полиизоцианата; и(ii) приблизительно от 0,3 до приблизительно 0,4 эквивалента бутандиола или приблизительно от 0,35 до приблизительно 0,4 эквивалента пентандиола; и(b) приблизительно от 0,3 до приблизительно 0,7 эквивалента триметилолпропана; и(с) приблизительно до 0,4 эквивалента бутандиола или пентандиола;где продукт реакции компонентов по существу не содержит сложный полиэфирполиол и простой полиэфирполиол.2. Полиуретан по п.1, где полиизоцианат выбран из группы, включающей диизоцианаты, триизоцианаты, их димеры, тримеры и смеси.3. Полиуретан по п.2, где полиизоцианат представляет собой диизоцианат, выбранный из группы, включающей этилендиизоцианат,триметилендиизоцианат, 1,6-гексаметилендиизоцианат,тетраметилендиизоцианат, гексаметилендиизоцианат,октаметилендиизоцианат ...

ПРЕПОЛИМЕР НА ОСНОВЕ ИЗОЦИАНАТА

... 1. Изоцианат-содержащий преполимер, получаемый взаимодействием, по меньшей мере, одного изоцианата, по меньшей мере, с одним первым соединением и, по меньшей мере, с одним вторым соединением, отличным от указанного, по меньшей мере, одного первого соединения, причем оба соединения каждое независимо друг от друга выбирают из группы, включающей одноатомные спирты, тиолы и вторичные амины; и где, по меньшей мере, один изоцианат включает метилендифенилдиизоцианат.2. Преполимер по п.1, где указанное, по меньшей мере, одно второе соединение имеет более низкую средневесовую молекулярную массу, чем указанное, по меньшей мере, одно первое соединение.3. Преполимер по п.1 или 2, где указанное первое соединение представляет собой одноатомный спирт, выбранный из группы, включающей сложные полиэфиры с одной гидроксильной группой (монофункциональный), монофункциональный С1-20-гидроксиалкил и гетероциклил с одной гидроксильной группой (монофункциональный).4. Преполимер по любому из пп.1-3, где указанное ...

USE OF TWO-COMPONENT BONDING AGENT COMBINATIONS IN AUTOCREPAIR LACQUERS.

PROCEDURE FOR THE PRODUCTION OF POLYURETHAN-FOAM MATERIALS

Coreactive materials and methods for three-dimensional printing

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also disclosed.

Methods for reactive three-dimensional printing by extrusion

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also enclosed.

METHOD FOR FORMING MULTILAYER COATING FILM

Provided is a method for forming a multilayer coating film, which is capable of forming a multilayer coating film that exhibits excellent curability at low temperatures, while having excellent hardness and excellent finish appearance. A method for forming a multilayer coating film, which sequentially performs: (1) a step for forming an uncured first color coating film by applying a two-package type aqueous first color coating material (X) onto an object to be coated; (2) a step for forming an uncured second color coating film by applying a one-package type aqueous second color coating material (Y) onto the uncured first color coating film obtained in the step (1); (3) a step for forming an uncured clear coating film by applying a two-package type clear coating material (Z) onto the uncured second color coating film obtained in the step (2); and (4) a step for curing the uncured first color coating film, the uncured second color coating film and the uncured clear coating film, which are ...

TRANSPARENT HYDROPHOBIC COATING MATERIALS WITH IMPROVED DURABILITY AND METHODS OF MAKING SAME

Durable, transparent, inorganic-organic hybrid hydrophobic coating materials for glass, metal or plastic substrates are provided. The coating materials are generally an acid catalyzed condensation reaction product comprised of an organic polymeric silane (e.g., a polyol functionalized with a silane through a urethane linkage or a polyamine functionalized with a silane through a urea linkage, such as isocyanatopropyltrimethoxysilane or isocyanatopropyltriethoxysilane), an inorganic metal alkoxide (e.g., silicon alkoxides such as tetraethoxysilane or tetramethoxysilane) and a fluorinated silane (e.g., (3,3,3-trifluoropropyl)trimethoxysilane or nonafluorohexyltrimethoxysilane).

COMPOSITION COMPRISING CYCLIC SECONDARY AMINE AND METHODS OF COATING DRINKING WATER PIPELINES

Two-part coating compositions are described comprising an aliphatic cyclic secondary amine and methods of coating surfaces of a (e.g. drinking water) pipeline.

REACTION INJECTION MOLDING POLYUREA RESIN COMPOSITION

POLYAMINE COMPOSITIONS CONTAINING SECONDARY AMINE FUNCTIONS

Polyoxyalkylene polyamine or aromatic diamines or xylylenediamines are modified by subjecting to the Michael reaction with an ethylenically unsaturated monomer having an electron-withdrawing group to convert the primarary amino groups at least in part to a secondary amino group of the formula: -NH-CH2-CH(R)-Y wherein R is a hydrogen atom or methyl, and Y is an electron-withdrawing group. The modified amines find use in the manufacture of plastics such as polyurea elastomers or polyurea RIM.

КОМПОЗИЦИЯ УДЛИНИТЕЛЯ ЦЕПИ НА ОСНОВЕ ДИАМИНА, ПОЛИМЕР И СПОСОБ ЕГО ПОЛУЧЕНИЯ

Настоящее изобретение относится к композициям удлинителя цепи. Данные композиции включают (i) ароматический первичный диамин и (ii) компонент, выбранный из группы, включающей: (c) алифатический вторичный диамин и алифатический первичный диамин; (d) диимин и (e) комбинацию двух или нескольких компонентов (с)-(d). Когда компонент (ii) представляет собой (d) и (d) является ароматическим диимином, каждая иминогидрокарбилиденовая группа содержит от 2 до 20 атомов углерода; или когда (d) является алифатическим диимином, каждая иминогидрокарбилиденовая группа содержит от 1 до 20 атомов углерода. Также предложены способы получения полиуретанов, полимочевин и полимочевин-уретанов.

BLENDS OF DIAMINES HAVING REDUCED COLOR

This invention provides a blend which comprises (i) at least one aromatic primary diamine, with which has been blended a color-minimizing amount of at least one N,N- dmydrocarbylhydroxylarnine, wherein the aromatic primary diamine is in the form of one benzene ring having two primary amino groups on the ling, which amino groups are meta or para relative to each other, and in which each position ortho to a primary amino group bears an alkyl group, and (ii) at least one aromatic secondary diamine having a Gardner color number no more than about 7, wherein said aromatic secondary diamine either is in the form of one benzene ring having two secondary amino groups on the ring, or is in the form of two benzene rings connected by an alkylene bridge and having one secondary amino group on each ring. Optionally, at least one N,N-dihydrocarbylhydroxylamine has been blended with the aromatic secondary diamine.

Reaction injection molding polyurea resin composition

A polyurea resin molding composition for reaction injection molding use which comprises (a) a polyoxyalkylenepolyamine, (b) an aromatic polyamine and/or a xylylenediamine and (c) a polyisocyanate, wherein either one or both of components (a) and (b) have been modified by a Michael reaction with an unsaturated compound of the formula CH2 =C(R)--Y wherein R is H or CH3 and Y is an electron attracting group. The use of such modified polyamine(s) improves in-mold flow and green strength characteristics.

Polyurethane composition

The present technology provides a polyurethane composition including: a main agent; and a curing agent, wherein the main agent includes a urethane prepolymer having an isocyanate group, a morpholine compound having one morpholine ring, and an ether compound having two dimethylamino groups, and the curing agent includes an active hydrogen compound having two or more active hydrogen-containing groups in one molecule.

COREACTIVE MATERIALS AND METHODS FOR THREE-DIMENSIONAL PRINTING

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also disclosed. 1. A composition for three-dimensional printing , comprising:a first component comprising a first compound, wherein the first compound comprises at least one first functional group; anda second component comprising a second compound, wherein the second compound comprises at least one second functional group,wherein the at least one second functional group is reactive with the at least one first functional group;wherein at least one of the first functional group and the second functional group comprises a saturated functional group; andwherein each of the first functional group and the second functional group does not comprise an ethylenically unsaturated group.2. The composition of claim 1 , wherein the composition is characterized by: a viscosity less than 30 cP; a surface tension of 30 mN/m to 50 nM/m; a contact angle on glass of less than 20 degrees; and a contact angle on polyethylene terephthalate of less than 40 degrees.3. The composition of claim 1 , wherein each of the first component and the second component comprises less than 5 wt % solvent claim 1 , wherein wt % is based on the total weight of each of the respective coreactive components.4. The composition of claim 1 , wherein an equivalents ratio of the at least one first functional group to the at least one second functional group is from 2:1 to 1:2.5. The composition of claim 1 , wherein the first compound and the second compound are capable of coreacting at a temperature less than 30° C.6. The composition of claim 1 , wherein each of the first component and the second component independently comprises:a monomer having a molecular weight less than 600 Daltons;a prepolymer having a molecular weight with a range from 1,000 Daltons to 20,000 Daltons; ora combination thereof.7. The composition of claim 1 , wherein claim 1 ,the composition ...

КОМПОЗИЦИЯ, СОДЕРЖАЩАЯ ЦИКЛИЧЕСКИЙ ВТОРИЧНЫЙ АМИН, И СПОСОБЫ ФОРМИРОВАНИЯ ПОКРЫТИЯ ТРУБОПРОВОДОВ ДЛЯ ПИТЬЕВОЙ ВОДЫ

Изобретение относится к способу формирования покрытия на поверхности трубопровода, при этом способ включает стадии, на которых обеспечивают композицию покрытия, содержащую первый компонент, содержащий, по меньшей мере, один полиизоцианат, и второй компонент, содержащий, по меньшей мере, 20 мас. % алифатического циклического вторичного диамина, содержащего вторичные аминные заместители, не содержащие сложноэфирных групп, причем алифатический циклический вторичный диамин содержит два гексильных кольца, связанных мостиковой группой, или одно гексильное кольцо; и вся композиция содержит от приблизительно 15% до приблизительно 45% по объему неорганического наполнителя в виде частиц, объединяют первый компонент и второй компонент с образованием жидкой смеcи, наносят жидкую смесь на внутренние поверхности трубопровода и выдерживают смесь для схватывания с формированием отвержденного покрытия. Также изобретение относится к двухкомпонентным композициям покрытий, содержащим алифатический циклический ...

ДИИМИНЫ И ВТОРИЧНЫЕ ДИАМИНЫ

... 1. Ароматический диимин, где указанный диимин состоит либо из одного бензольного кольца, имеющего две иминогруппы в кольце, где иминогруппы находятся в положении мета или пара по отношению друг к другу, и в котором в каждом положении орто к иминогруппе находится гидрокарбильная группа, либо из двух бензольных колец, связанных алкиленовым мостиком и имеющих одну иминогруппу в каждом кольце, где в каждом положении орто к иминогруппе находится гидрокарбильная группа, и где каждая иминогидрокарбилиденовая группа содержит, по крайней мере, два атома углерода. ! 2. Диимин по п.1, где указанный диимин состоит из одного бензольного кольца, имеющего две иминогруппы в кольце, где указанные иминогруппы находятся в положении мета по отношению друг к другу. ! 3. Диимин по п.1, где указанный диимин состоит из двух бензольных колец, связанных алкиленовым мостиком и имеющих одну иминогруппу в каждом кольце, где указанный алкиленовый мостик содержит от одного до около трех атомов углерода, и где каждая ...

СОВМЕСТНО РЕАГИРУЮЩИЕ МАТЕРИАЛЫ И СПОСОБЫ ТРЕХМЕРНОЙ ПЕЧАТИ

КОМПОЗИЦИЯ ДЛЯ СОКРАЩЕНИЯ КОЛИЧЕСТВА АЛЬДЕГИДОВ, ВЫДЕЛЯЮЩИХСЯ ИЗ ПОЛИУРЕТАНОВЫХ ПЕН

АДДИТИВНОЕ ПРОИЗВОДСТВО С ИСПОЛЬЗОВАНИЕМ РЕАКТИВНЫХ КОМПОЗИЦИЙ

Изобретение относится к способу аддитивного производства с использованием реактивной композиции и трехмерному объекту. Способ включает подачу первого компонента, содержащего первое соединение, в первый насос и подачу второго компонента, содержащего второе соединение, во второй насос. При этом первое соединение способно реагировать со вторым соединением. Путем перекачивания первого компонента первым насосом и перекачивания второго компонента вторым насосом через смеситель получают сореактивную композицию. Затем сореактивную композицию осаждают. При этом первый компонент имеет первую вязкость, и второй компонент имеет вторую вязкость, где первая вязкость составляет ±50% от второй вязкости, и вязкость измеряют, используя реометр Anton Paar MCR 301 или 302 с зазором до 1 мм, шпинделем диаметром 25 мм с параллельными пластинами, при частоте колебаний 1 Гц и амплитуде 0,3%. Технический результат - расширение конструктивных возможностей трехмерной печати. 2 н. и 22 з.п. ф-лы, 6 ил., 7 табл., 6 ...

Полимерная защитная композиция и способ ее получения

VERFAHREN ZUR HERSTELLUNG VON POLYURETHANSCHAUMSTOFFEN

POLYHARNSTOFF UND FILM AUS MINDESTENS EINER MONOMOLEKULAREN SCHICHT EINES POLYHARNSTOFFS

PROCEDURE FOR THE PRODUCTION OF POLYURETHAN-FOAM MATERIALS

POLYUREA AND COATING COMPOSITION THEREOF

Polyamine compositions containing secondary amine functions

Additive manufacturing using reactive compositions

Methods of additive manufacture using coreactive components are disclosed. Thermosetting compositions for additive manufacturing are also disclosed.

METHODS FOR REACTIVE THREE-DIMENSIONAL PRINTING BY EXTRUSION

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also enclosed.

TWO-COMPONENT COATING COMPOSITIONS FOR MOTOR VEHICLE REPAIR LACQUERS

The present invention relates to an improved process for repairing a motor vehicle by applying a coating composition wherein improvement is the use of a binder containing a) a polyisocyanate component and b) a mixture of organic compounds having isocyanate-reactive groups containing b1) a secondary diamine corresponding to formula I and b2) a polyhydroxyl component containing (i) a polyhydroxypolyacrylate or (ii) a mixture of such polyhydroxypolyacrylate with up to 95% by weight, based on the weight of (ii), of a polyester polyol, wherein components b1) and b2) are present in a weight ratio of 0.7:1 to 20:1 and components a) and b) are present in an amount which corresponds to an equivalent ratio of isocyanate groups of component a) to isocyanate-reactive groups of component b) of 0.8:1 to 1.5:1.

포토크로믹 조성물

... [과제] 본 발명은 폴리카보네이트 수지 등으로 이루어지는 광학 시트 또는 필름을 접합하기 위한 접착층을 하여 기능하는 포토크로믹 조성물로서, 상기 포토크로믹 조성물을 이용하여 제조한 적층 시트가 뛰어난 접착성, 내열성, 포토크로믹성, 내한성을 나타내는 포토크로믹 조성물을 제공하는 것에 있다. [해결 수단] (A)분자 사슬 중에 우레아 결합을 가지며, 테트라하이드로퓨란 불용분이 20.0~90.0 질량%인 폴리우레탄-우레아 수지, 및 (B)포토크로믹 화합물을포함하는 것을 특징으로 하는 포토크로믹 조성물을 제공한다.

Additive manufacturing using reactive compositions

POLYUREAS MADE FROM AMINOCROTONATES AND ENAMINONES

A polymer made by reacting a polyisocyanate with a compound having the formula below. R1 is an organic group. R2 is an aliphatic group or oxyaliphatic group. R3 is an aliphatic group. The reaction forms urea groups from the isocyanate groups of the polyisocyanate and the NH groups of the compound.

Полимерная защитная композиция

Настоящее изобретение относится к полимерной защитной композиции для защиты изделий и конструкций из разных материалов, в том числе из резины. Полимерная защитная композиция, состоит из полимочевинной двухкомпонентной композиции, состоящей из форполимера на основе изоцианата и отвердителя полиаспартического типа, в которую дополнительно введена модифицирующая добавка, в качестве которой использован полидиметилфенилсилоксан (ПДМФС) в количестве 15-30 мас. %. Указанная композиция обеспечивает получение покрытия, обладающего хорошей адгезией к различным материалам, в том числе к резине, повышенной эластичностью, атмосферостойкостью и стойкостью к действию химических агентов, таких как минеральные кислоты, щелочи и углеводородные среды. 2 табл., 8 пр.

РАДИАЦИОННО-ОТВЕРЖДАЕМАЯ КОМПОЗИЦИЯ ПОКРЫТИЯ НА ОСНОВЕ СШИТЫХ ПОЛИУРЕТАНОВ С УДЛИНЕННОЙ ЦЕПЬЮ

SYNERGISTIC AMINE CHAIN EXTENSION MEANS IN PU SPRAYING ELASTOMERS

Polyurea/polythiourea coatings

Photochromic composition

... [Problem] To provide a photochromic composition which serves as an adhesive layer for bonding an optical sheet or film that is formed of a polycarbonate resin or the like, and which is characterized in that a laminated sheet produced using the photochromic composition exhibits excellent adhesiveness, heat resistance, photochromic properties and perspiration resistance. [Solution] Provided is a photochromic composition which is characterized by containing (A) a polyurethane-urea resin that has a urea bond in a molecular chain, while having a tetrahydrofuran-insoluble fraction of 20.0-90.0% by mass and (B) a photochromic compound.

DIIMINES AND SECONDARY DIAMINES

This invention provides aromatic diimines where the diimines have imino groups with at least two carbon atoms, and either are in the form of one benzene ring having two imino groups on the ring, which imino groups are meta or para relative to each other, and in which each position ortho to an imino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one imino group on each ring, and in which each position ortho to an imino group bears a hydrocarbyl group. This invention also provides aromatic secondary diamines where the diamines have amino hydrocarbyl groups with at least two carbon atoms, and either are in the form of one benzene ring having two amino groups on the ring, which amino groups are meta or para relative to each other, and in which each position ortho to an amino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one amino group on each ring, and ...

POLYUREA/POLYTHIOUREA COATINGS

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first component further comprises an isocyanate functional polythioether-polyurethane and/or polythiourethane, and/or the second component further comprises an amine/hydroxy functional polythioether, are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed.

POLYUREA COPOLYMER COATING COMPOSITIONS AND METHODS

Durable polyurea copolymer coatings can be applied to surfaces that come in contact with fluids, such as biological fluids, thereby passivating the surface. Polyurea copolymer coating compositions comprise a reaction product of (a) a diamine composition that includes a polyethylene glycol diamine, and optionally, a dipiperidyl alkane; and (b) a diisocyanate. Solutions containing polyurea copolymers, coated surfaces and methods are also described.

ADDITIVE MANUFACTURING USING REACTIVE COMPOSITIONS

Methods of additive manufacture using coreactive components are disclosed. Thermosetting compositions for additive manufacturing are also disclosed.

METHODS FOR REACTIVE THREE-DIMENSIONAL PRINTING BY INKJET PRINTING

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also disclosed.

POLYURETHANES, ARTICLES AND COATINGS PREPARED THEREFROM AND METHODS OF MAKING THE SAME

The present invention provides polyurethanes including a reaction product of components including: (a) an iso-cyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.3 to about 0.4 equivalents of butanediol or pentanediol; and (b) about 0.3 to about 0.7 equiva-lents of trimethylolpropane; and (c) up to about 0.4 equivalents of butanediol or pentanediol, wherein the reaction product compo-nents are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and meth-ods of making the same.

Photochromic composition

폴리우레탄 발포체로부터 방출되는 알데히드의 양을 감소시키기 위한 조성물

... 이소시아네이트 반응성 성분으로 이루어진 군으로부터 선택된 적어도 1종의 성분; 적어도 1개의 이소시아네이트 반응성 기로 치환된 시클릭 우레아, 자유 라디칼 스캐빈저, 또는 중합체 산, 또는 그의 혼합물로 이루어진 군으로부터 선택된 처리제; 각각 주어진 구조를 갖는 1종 이상의 아민 성분을 포함하는 이소시아네이트 반응성 조성물.

METHOD FOR PREPARING SOLVENT-FREE TYPE WATER-DISPERSED URETHANE RESIN AND WATER-SOLUBLE COATING COMPOSITION COMPRISING RESIN PREPARED THEREBY

The present invention relates to a method for preparing a solvent-free type water-dispersed urethane resin and a water-soluble coating composition comprising the resin prepared thereby. According to the present invention, an organic solvent is not used when manufacturing the resin so environmental problems caused by waste organic solvents are not generated. Also, a film having excellent water resistance, chipping resistance and appearance can be formed when being applied on an aqueous paint. COPYRIGHT KIPO 2017 ...

Chain extenders

This invention provides chain extender compositions. These compositions comprise either (i) N,N'-dicyclohexyl-1,6-hexanediamine or (ii) an aliphatic secondary , -diamine having a secondary amino straight chain. When said composition comprises (i), said composition is also comprised of a component selected from the group consisting of (a) an aliphatic secondary diamine, (b) an aliphatic secondary diamine and an aliphatic primary diamine, (c) an aliphatic diimine, (d) an aromatic primary diamine, and (e) a combination of any two or more of (a) through (d). When said composition comprises (ii), said composition is also comprised of a component selected from the group consisting of (a) an aliphatic secondary diamine, (d) an aromatic primary diamine, (f) an aliphatic secondary , -diamine having at least one internal secondary amino group, and (g) a combination of any two or more of (a), (d), and (f). Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.

DIAMINE CHAIN EXTENDER COMPOSITIONS

ポリ尿素/ポリチオ尿素コーティング

... イソシアネートを含む第1成分とアミンを含む第2成分との反応生成物であって、その第1成分が、イソシアネート官能性ポリチオエーテル-ポリウレタンおよび/またはポリチオウレタンをさらに含み、かつ/またはその第2成分が、アミン/ヒドロキシ官能性ポリチオエーテルをさらに含む該反応生成物を含むポリ尿素/ポリチオ尿素組成物が開示される。そのコーティングを使用する方法およびそれをコーティングした基材もまた開示される。 ...

СПОСОБЫ РЕАКТИВНОЙ ТРЕХМЕРНОЙ ПЕЧАТИ ПУТЕМ ЭКСТРУЗИИ

PROCESS FOR THE PRODUCTION OF POLYURETHANE FOAMS

... 1412818 Polyurethane foams BAYER AG 28 June 1973 [28 June 1972] 30784/73 Heading C3R [Also in Division C2] Flame proof, open-cell polyurethane foams are prepared by reacting a polyisocyanate with a compound which contains active hydrogen atoms and has a M.W. of from 400 to 16,000 in the presence of water and/or an organic expanding agent and in the presence of an asymmetrical aromatic diamine corresponding to any of the following general formulae wherein R and R11 each represents -CH 3 , -C 2 H 5 , -C 8 H 7 , -CH(CH 3 ) 2 , -C 4 H 9 or -CH 2 -CH 2 -OH, R1 represents -O-CH 3 , -O-C 2 H 5 , -O-(CH 2 ) 2 -OH, -O-(CH 2 ) 2 -O-CH 3 , -O-(CH 2 ) 2 -O-C 2 H 5 , -CH 3 , -C 2 H 5 , -C 3 H 7 , -CH(CH 3 ) 2 , C 4 H 9 , -CO-CH 3 , -CO-O-C 2 H 2 , -CO-O-C 3 H 7 , -CO-O-C 4 H 9 , -CO-O-(CH 2 ) 2 -OH, -CO-O-(CH 2 ) 2 -O-CH 3 or -CO-NH 2 and R111 represents -O-CH3, -O-C 2 H 5 , -O-(CH 2 ) 2 -OH, -O-(CH 2 ) 2 -O-CH 3 , -CH 3 , -C 2 H 5 , -C 3 H 7 , CH(CH 3 ) 2 , or -C 4 H 9 .

Photochromic composition

... [Problem] To provide a photochromic composition which serves as an adhesive layer for bonding an optical sheet or film that is formed of a polycarbonate resin or the like, and which is characterized in that a laminated sheet produced using the photochromic composition exhibits excellent adhesiveness, heat resistance, photochromic properties and perspiration resistance. [Solution] Provided is a photochromic composition which is characterized by containing (A) a polyurethane-urea resin that has a urea bond in a molecular chain, while having a tetrahydrofuran-insoluble fraction of 20.0-90.0% by mass and (B) a photochromic compound.

OXAZOLIDINEDIONE-TERMINATED PREPOLYMER

The present invention relates to a compound obtained by a process comprising the following steps: (i) Reacting at least one isocyanate containing compound, in stoichiometric excess, with at least one isocyanate-reactive compound having a number average molecular weight equal to or higher than 400, resulting in the formation of at least one prepolymer having soft blocks and hard blocks in its structure, which prepolymer contains unreacted isocyanate monomer, (ii) Reacting said at least one prepolymer with a hydroxyl-ester compound or a hydroxyl-acid compound with the formation of hydroxyl-ester terminated prepolymer or hydroxyl-acid terminated prepolymer, and Ring-closing said hydroxyl-ester terminated prepolymer or hydroxyl-acid terminated prepolymer; (iii) Formation of said compound made of oxazolidinedione-terminated prepolymer and oxazolidinedione-terminated monomer, which is soluble in said oxazolidinedione-terminated prepolymer.

COREACTIVE MATERIALS AND METHODS FOR THREE-DIMENSIONAL PRINTING

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also disclosed.

SYNERGISTIC AMINE CHAIN-EXTENDERS IN POLYUREA SPRAY ELASTOMERS

Disclosed are derivatives of isophorone diamine exhibiting a synergistic relationship with other commonly employed chain extenders offering enhanced efficacy with regard to slowing of the polyurea elastomer cure profile, and processes employing their use. According to the invention, extensions of the gel-free and tack-free times are more readily achieved at lower loading levels for these chain extender blends than are afforded through the sole use of the individual molecules.

CURING AGENTS IN POLYURETHANE MANUFACTURE

PROCESS FOR THE PRODUCTION OF POLYURETHANE FOAMS

LOW TEMPERATURE CURABLE EPOXY COMPOSITIONS CONTAINING UREA CURATIVES

LOW TEMPERATURE CURABLE EPOXY COMPOSITIONS CONTAINING EPOXY RESIN AND UREA HARDENERS

PURPOSE: A low temperature curable epoxy composition is provided to afford excellent activation temperature, good reaction heat, and high glass transition. CONSTITUTION: A urea compound is the reaction product of an isocyanate and an alkylated polyalkylenepolyamine having at least one primary or secondary amine and at least two tertiary amines of chemical formula 1, where R1, R2, R3, R4 and R5 independently represent hydrogen, methyl or ethyl; n and m independently are integers from 1 to 6 and; X is an integer from 1 to 10. COPYRIGHT KIPO 2011 ...

압출에 의한 반응성 3차원 프린팅 방법

... 본 발명은, 공-반응성 성분을 사용한 3차원 물체의 프린팅 방법에 관한 것이다. 또한, 본 발명은 3차원 프린팅용 열경화성 조성물에 관한 것이다.

USE OF A POLYURETHANE ADHESIVE COMPOSITION FOR CRYOGENIC APPLICATIONS

The present invention relates to the use of a bi-component polyurethane structural adhesive composition (PU2K) in cryogenic applications, in particular in tankers that transport liquefied gases. The present invention therefore relates to the use of an adhesive composition with a shear strength of more than 10 MPa measured according to the ISO 4587 standard across the entire temperature range of -170ºC to +40ºC. In particular, the adhesive composition acts as a bonding element between two substrates to form a multilayer structure capable of providing a seal with respect to gases and liquids across the entire temperature range of +40 ºC to -170 ºC.

Material forming supramolecular structures, process and uses

A novel material, forming supramolecular structures below its transition temperature, which contains at least one CO and/or CS group and at least one NH, OH and/or SH group and wherein the material has the structure A(-XB)n(1) wherein A, X, B and n are defined. Also a process for preparation of the material and uses thereof.

METHOD FOR PREPARING A POLYCARBAMIDE RESIN

CAPSULE WITH ORGANIC/INORGANIC HYBRID WALL

СПОСОБЫ РЕАКТИВНОЙ ТРЕХМЕРНОЙ ПЕЧАТИ ПУТЕМ ЭКСТРУЗИИ

Изобретение относится к способам печати трехмерного объекта с использованием совместно реагирующих компонентов. Способ включает экструзию первого компонента, содержащего первую функциональную группу. Затем осуществляется экструзия второго компонента, содержащего вторую функциональную группу. Вторая функциональная группа вступает в реакцию с первой. Формирование объекта осуществляется осаждением последовательных слоев путем экструзии. Техническим результатом изобретения является повышение конструктивных особенностей изделий. 14 н. и 9 з.п. ф-лы, 2 ил., 1 пр. 3 табл.

СПОСОБЫ РЕАКТИВНОЙ ТРЕХМЕРНОЙ ПЕЧАТИ ПУТЕМ ЭКСТРУЗИИ

СПОСОБЫ РЕАКТИВНОЙ ТРЕХМЕРНОЙ СТРУЙНОЙ ПЕЧАТИ

Methods for reactive three-dimensional printing by inkjet printing

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also disclosed.

Polyetheramine Macromonomers Comprising Two Neighboring Hydroxyl Groups And Their Use For Producing Polyurethanes

The object of the invention are compounds of the formula (2) wherein Ris H, methyl or ethyl, Ris C- to Calkyl, A is a C- to Calkylene group, m is number from 10 to 400, n is 1, 2, 3, 4, or 5, a method for their production and their use in the production of polyurethane prepolymers. 17.-. (canceled)13. (canceled)14. (canceled)15. The process as claimed in claim 8 , wherein the alkylene oxide is ethylene oxide.16. The process as claimed in claim 8 , wherein the dihydroxyalkylamino group is a dihydroxyethylamino group.17. A polyurethane prepolymer made in accordance with the process of .18. A polyurethane polymer made in accordance with the process of .19. A polyurethane prepolymer made in accordance with the process of .20. A polyurethane polymer made in accordance with the process if . The present invention relates to Ω-(alkoxy)-α-N,N-dihydroxyalkylaminopoly-alkylene glycols, and to their use for producing water-dispersible polyurethanes.On account of their high resistance and simple application, polyurethane systems have acquired a broad application field in the paint, (surface) coating and textile industry sector. For reasons of environmental protection and occupational protection, in the recent past primarily solvent-free, water-dispersed polyurethane systems have been developed.The production of aqueous polyurethane dispersions has been known for many years and is described in detail in a large number of publications (e.g. Houben-Weyl, Methoden der Organischen Chemie [Methods of organic chemistry], Volume E20, Part I, pp. 1659-1681; D. Dieterich, Prog. Org. Coat. 1981, 9, 281-330; J. W. Rosthauser, K. Nachtkamp, Journal of Coated Fabrics 1986, 16, 39-79; R. Arnoldus, Surf. Coat. 1990, 3 (Waterborne Coat.), 179-198).Aqueous polyurethane dispersions consist of polyurethane polymers or polyurethane-polyurea polymers which include both urethane groups and also urea groups and are accessible by polyaddition reactions of polyols, polyisocyanates and polyamines. Firstly ...

Airfoil leading edge coatings

A polyurethane or polyurea coating composition for use in protecting a leading edge substrate on an airfoil, such as aircraft wings, rotor blades and propeller blades, against liquid or solid particle erosion, the composition made from a polyisocyanate and curing agents, such as polyaspartic esters, aldimines and ketimines, polyamines and polyols or mixtures thereof with optional flatting agent for matte coatings.

SOLVENT-FREE POLYURETHANE LIQUID MEMBRANE

The present disclosure relates to a two-component composition containing a polymer polyol, a dial chain extender, an aldimine of formula (I), optionally additional polyols and diphenylmethandiisocyanates in the two components. The composition is particularly suitable as a manually applicable solvent-free liquid film for coating and/or sealing floors and roofs. It also has a long open time, cures quickly and without complications in a wide temperature and humidity range, has a high level of strength and is weather resistant. 2. The composition as claimed in claim 1 , wherein the aldimine of the formula (I) is selected from the group consisting of:N,N′-bis(2,2-dimethyl-3-lauroyloxypropylidene)hexamethylene-1,6-diamine, N,N′-bis(2,2-dimethyl-3-lauroyloxypropylidene)-3-aminomethyl-3, 5, 5-trimethylcyclohexylamine, N-2,2-dimethyl-3-lauroyloxypropylidene-2-(2-aminoethoxy)ethanol, N,N′-bis(2,2-dimethyl-3-lauroyloxypropylidene)polyoxypropylenediamine with average molecular weight in a range from 710 to 810 g/mol and N,N′,N″-tris(2,2-dimethyl-3-lauroyloxypropylidene)polyoxypropylenetriamine with average molecular weight in a range from 1190 to 1290 g/mol.3. The composition as claimed in claim 1 , wherein the solid polymer is a copolymer of acrylonitrile and styrene (SAN) or is a polyurea/polyhydrazodicarbonamide (PHD) or is a polyurethane.4. The composition as claimed in claim 1 , wherein the polyether polyol is an ethylene-oxide-terminated polyoxypropylenetriol with molecular weight in a range from 1000 to 6000 g/mol.5. The composition as claimed in claim 1 , wherein the diol chain extender is selected from the group consisting of:1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, 2-methyl-1,3-propanediol, 1,5-pentanediol, 1,2-pentanediol, 2,4-pentanediol, 2-methyl-1,4-pentanediol, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol, 1,2-hexanediol, 3-methyl-1,5-pentanediol, 1,8-octanediol, 1,2-octanediol, 3,6- ...

EROSION RESISTANT COATINGS

An erosion resistant article such as rotor blades for helicopters and wind turbines having the leading edge surface protected from damage from high speed impingement of rain or sand with a protective coating formed from specific polyurethane or polyurea coating having a defined set of minimum physical properties where the protective coating can be applied as a liquid coating and cured in place or as a preformed complementary shaped covering to protect the leading edge against erosion damage in service. 1. An erosion resistant article comprising an airfoil shaped substrate having a leading edge surface exposed in use to high speed impingement of liquid or solid particles , said leading edge surface covered with a protective coating comprising: a polyurethane or polyurea coating selected from the group consisting of an isocyanate-terminated prepolymer cured with a curing agent , a polyisocyanate cured with a curing agent , and a water dispersion of a pre-reacted polyurethane , said curing agent selected from a group consisting of an aldimine , a ketimine , a polyaspartic ester , a polyamine , one or more polyols and mixtures thereof having a tensile strength greater than 1000 psi (70 kg/cm) , an elongation at break greater than 350% , a tensile set of less than 150% , and a Shore A hardness of 44 A to 95 A as measured at 68° F. when tested without any filler.2. The erosion resistant article of wherein said polyurethane or polyurea coating is preformed into a cured form selected from the group consisting of boots claim 1 , films claim 1 , sheets claim 1 , and tapes.3. The erosion resistant article of further comprising an underlying layer of primer or an adhesive material bonding said preformed sheet to said airfoil shaped substrate.4. The erosion resistant article of wherein said polyurethane or polyurea coating is preformed into a cured sheet or tape.5. The erosion resistant article of wherein said cured form is a boot preformed to have the shape of the leading edge ...

CYCLIC DYNAMIC POLYUREAS FOR POLYMERIC UREA PROCESSING

The present invention relates to a one-component processing method and system for preparing polyurea materials. This method and system involves a polymerization process using cyclic oligomeric polyurea precursors. These cyclic oligomeric precursors have dynamic urea bonds such as hindered urea bonds (HUBs). These cyclic oligomeric precursors exhibit dynamic properties to reversibly dissociate yielding isocyanate and amine components which polymerize to yield the polyureas, such as linear, branched or cross-linked polyureas. This method and system has advantages over conventional methods that utilize two-component systems. Such two-component systems require the segregation of the isocyanate and amine components to prevent premature or too rapid polymerization. The resulting polyureas are useful for a variety of applications including coatings. 2. A cyclic oligomer or polymer according to corresponding to formula (Ia).3. A cyclic oligomer or polymer according to corresponding to formula (Ib).4. A cyclic oligomer or polymer according to any of to wherein R claim 1 , R claim 1 , and Rare each methyl.6. A cyclic oligomer or polymer according to any of to wherein x is an integer from about 2 to about 500.7. A cyclic oligomer or polymer according to any of to wherein x is an integer from about 2 to about 50.8. A cyclic oligomer or polymer according to any of to wherein x is an integer from about 2 to about 20.9. A cyclic oligomer or polymer according to any of to wherein x is an integer about 2 to about 8.11. A hyperbranched cyclic oligomer or polymer according to corresponding to formula (IIa).12. A hyperbranched cyclic oligomer or polymer according to corresponding to formula (IIb).13. A hyperbranched cyclic oligomer or polymer according to any of to wherein R claim 10 , R claim 10 , and Rare each methyl.14. A hyperbranched cyclic oligomer or polymer according to any of to wherein x is an integer from about 2 to about 500.15. A hyperbranched cyclic oligomer or polymer ...

Self-healing, self-cleaning omniphobic composition, related articles and related methods

The disclosure relates to a self-healing omniphobic composition including a self-healing omniphobic polymer with a crosslinked backbone. The crosslinked backbone includes a reaction product between a polyisocyanate, a functionalized omniphobic polymer reactive therewith, a reversible polyfunctional linker including a hindered secondary amino group and/or an aromatic hydroxy group, and one or more polymeric backbone components. The crosslinked backbone includes reversible urea or reversible urethane bonds between the reversible polyfunctional linker and the polyisocyanate, which in turn provide self-healing properties to the omni-phobic composition. The self-healing omniphobic composition has favorable omniphobic properties, for example as characterized by water and/or oil contact and/or sliding angles. The omniphobic composition can be used as a coating on any of a variety of substrates to provide self-healing omniphobic properties to a surface of the substrate. Such self-healing omniphobic coatings can be scratch resistant, ink/paint resistant, and optically clear.

ADDITIVE MANUFACTURING USING POLYUREA MATERIALS

Methods of additive manufacture using coreactive components are disclosed. Thermosetting compositions for additive manufacturing are also disclosed. 1. A method of reactive additive manufacturing , comprising:providing a first component comprising a first prepolymer into a first pump;providing a second component comprising a second prepolymer into a second pump, wherein the second prepolymer is reactive with the first prepolymer;pumping the first component from the first pump, and the second component from the second pump through a mixer to provide a reactive composition; anddepositing the reactive composition through a nozzle connected to the mixer.2. The method of claim 1 , wherein the first component comprises a polyisocyanate prepolymer; and the second component comprises a polyamine prepolymer.3. The method of claim 1 , wherein each of the first pump and the second pump independently comprise a syringe pump claim 1 , a peristaltic pump claim 1 , or a progressive cavity pump.4. The method of claim 1 , wherein each of the first pump and the second pump comprises a progressive cavity pump.5. The method of claim 1 , wherein the mixer comprises a static mixer claim 1 , a dynamic mixer claim 1 , or a combination thereof.6. The method of claim 1 , wherein the mixer comprises a static mixer.7. A reactive additive manufacturing composition claim 1 , comprising:a first component comprising a polyisocyanate prepolymer and a first viscosity; anda second component comprising a polyamine prepolymer and a second viscosity,wherein the first viscosity is within ±20% of the second viscosity,wherein viscosity is measured using an Anton Paar MCR 301 or 302 rheometer with a 25 mm-diameter parallel plate spindle, an oscillation frequency of 1 Hz and amplitude of 0.3%, and with a rheometer plate temperature of 25° C.8. The composition of claim 7 , wherein the first viscosity is within ±10% of the second viscosity.9. The composition of claim 7 , wherein the first component claim 7 , ...

POLYURETHANE INSULATION FOAM COMPOSITION COMPRISING HALOGENATED OLEFINS

A polyurethane insulation foam composition is disclosed herein. The polyurethane insulation foam comprises: (i) an isocyanate compound; (ii) an isocyanate reactive compound; (iii) water; (iv) a heterocyclic amine compound; (v) a hydrophilic carboxylic acid compound; (vi) a halogenated olefin compound; and (vii) optionally, other additives. 1. A polyurethane insulation foam composition comprising:(i) an isocyanate compound;(ii) an isocyanate reactive compound;(iii) water; [{'br': None, 'sub': 'z', 'R1-[CH2-CH2-X—]—CH2-CH2-R2\u2003\u2003(a)'}, R1 and R2 are independently a five or six membered heterocyclic amine consisting of carbon, nitrogen, or combinations thereof;', {'sub': 1', '4', '2', '4', '4', '12, 'X is oxygen or N—R3 and wherein R3 is a C-Calkyl or C-Calkanol or C-Cether group;'}, 'Z is an integer from 1 to 4;, 'wherein'}], '(iv) a heterocyclic amine compound having the structure of Formula (a) [{'br': None, 'sub': n', 'm, '(HO)—R′—(COOH)\u2003\u2003(b)'}, {'sub': 1', '10, 'R′ is a divalent C-Caliphatic hydrocarbon moiety, n and m are both integers and wherein when n=0 then m≥2 and wherein when n≥1 then m≥1;'}, 'wherein'}], '(v) a hydrophilic carboxylic acid having the structure of Formula (b)(vi) a halogenated olefin blowing agent; and(vii) optionally, other additives; and [{'br': None, 'sub': 45', '0', '0, 'CT REACTIVE SHIFT=100*[(CT−CT)/CT]\u2003\u2003Formula X, [ [{'sub': '45', "CTmeans a composition's CT as determined using the FOAM REACTIVITY TEST after the composition's B-Side comprising Components (ii) and (iii) has been aged at 40° C. in a closed, pressure-rated, glass container that was placed in an oven for 45 days."}, {'sub': '0', "CTmeans a composition's CT as determined using the FOAM REACTIVITY TEST after the composition's B-Side comprising Components (ii) and (iii) has been aged at 40° C. for 0 days."}], 'wherein'}, {'br': None, 'sub': 45', '0', '0, 'TFT REACTIVE SHIFT=100*[(TFT−TFT)/TFT]\u2003\u2003Formula Y, 'and'}, [{'sub': '45', "TFTmeans ...

AQUEOUS COATING COMPOSITION WITH SOFT TOUCH UPON DRYING

Aqueous coating compositions include dispersed polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane. The polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, and the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt. % of at least one active-hydrogen chain extending compound with a functionality of at least 2 other than water, (e) from 0 to 10 wt. % of at least one diol having a molecular weight below 500 g/mol. The isocyanate and hydroxy groups on the components used are present in a respective mole ratio (NCO to OH) in the range of from 0.8:1 to 5:1. 1. An aqueous coating composition comprising dispersed polymer particles , wherein(i) the dispersed polymer particles are polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane,(ii) the polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, preferably from 2:1 to 16:1, even more preferably from 3:1 to 12:1, even more preferably from 4:1 to 12:1 and even more preferably from 4:1 to 10:1, (a) from 5 to 40 wt. %, preferably from 10 to 35 wt. % of at least one organic difunctional isocyanate,', '(b) from 0.5 to 4 wt. %, preferably from 0.8 to 3.2 wt. % and even more preferably from 1 to 2.5 wt % of an isocyanate-reactive compound containing ionic or potentially ionic water- ...

PROCESS FOR PRODUCING 2,2-DIALKYL-3-ACYLOXYPROPANALS

A process for preparing an aldol ester of the formula (I), wherein at least one carboxylic anhydride of the formula (II) is reacted with at least one aldol of the formula (III) with heating in the presence of a basic catalyst with a pKa of the conjugate acid of at least 8, and the reaction product obtained from the process. The process provides a light-coloured and low-odour reaction product which has a high content of aldol ester content of the formula (I) and can be used, without elaborate purification steps, particularly without overhead distillation of the aldol ester, as a blocking agent for primary amines. The resultant blocked amines have a long storage life together with polymers containing isocyanate groups, and cure rapidly and reliably on contact with moisture to form mechanically high-grade and robust elastomers. 2. The method as claimed in claim 1 , wherein Rand Rare each methyl.3. The method as claimed claim 1 , wherein Ris an alkyl radical having 1 to 7 carbon atoms or is phenyl.4. The method as claimed in claim 1 , wherein the basic catalyst has a conjugate acid pKa of at least 9.5. The method as claimed in claim 1 , wherein the basic catalyst is triethylamine.6. The method as claimed in claim 1 , wherein it is executed at a temperature within a range from 80 to 150° C.7. The method as claimed in claim 1 , wherein it is executed without using an organic solvent or entraining agent.10. A reaction product obtained from the method as claimed in claim 1 , wherein it comprises 60% to 95% by weight of aldol ester of the formula (I) and 5% to 40% by weight of other esters claim 1 , aldehydes and/or acetals not corresponding to the formula (I).12. A blocked amine obtained from reacting the reaction product as claimed in with at least one amine that has a primary amino group and additionally at least one reactive group selected from primary amino group claim 10 , secondary amino group claim 10 , and hydroxyl group.13. The blocked amine as claimed in claim 12 ...

A Composition to Reduce the Amount of Aldehydes Emitted from Polyurethane Foams

An isocyanate reactive composition comprising 3. The composition according to claim 1 , wherein the cyclic urea substituted with at least one isocyanate reactive group is selected from the group consisting of 4 claim 1 ,5-dihydroxy-2-imidazolidinone claim 1 , 4 claim 1 ,5-dimethoxy-2-imidazolidinone claim 1 , 4-hydroxyethyl ethylene urea claim 1 , 4-hydroxy-5-methyl propylene urea claim 1 , 4-methoxy-5-methyl propylene urea claim 1 , 4-hydroxy-5 claim 1 ,5-dimethyl propylene urea claim 1 , 1-(2-hydroxyethyl)-2-imidazolidinone or a mixture thereof.5. The composition according to claim 1 , wherein the free radical scavenger is a phosphite.7. A composition according to claim 1 , wherein the average number of nitrogen atoms of said one or more amine components is in the range of 5 to 10 claim 1 , preferably in the range of 5 to 8.8. A composition according to claim 1 , wherein said one or more amine components comprise at least one component comprising at least two primary and at least one secondary amine group.9. A composition according to claim 1 , wherein all R- claim 1 , R- claim 1 , R- and R-groups are hydrogen.10. A composition according to claim 1 , wherein the polymer acid contains at least three of the same repeating monomers claim 1 , of either an unsaturated carboxylic acid or an anhydride; or wherein the polymer acid contains at least two repeating monomers claim 1 , wherein the first monomer is an unsaturated carboxylic acid or an anhydride claim 1 , and the second monomer is different from the first monomer.11. A composition according to claim 1 , wherein said one or more amine components is a mixture comprising triethyltetramines (TETA) claim 1 , tetraethyl pentamines (TEPA) claim 1 , pentaethylhexamines (PEHA) claim 1 , hexaethylheptamines (HEHA) claim 1 , heptaethyloctamines (HEOA) and/or octaethylenenonamines (OENO).12. A composition according to claim 1 , wherein the amount of the one or more amine components claim 1 , in the composition is between 0. ...

METHOD FOR PRODUCING A MULTICOAT PAINT SYSTEM ON PLASTICS SUBSTRATES

The present invention relates to a method for producing a multicoat paint system on a plastics substrate, in which a basecoat film or a plurality of directly successive basecoat films are produced on a plastics substrate, a clearcoat film is produced directly on the one basecoat film or on the topmost of the plurality of basecoat films, and subsequently the one or more basecoat films and the clearcoat film are jointly cured, this method being a method wherein at least one basecoat material used for the production of the basecoat films comprises at least one aqueous polyurethane-polyurea dispersion (PD) comprising polyurethane-polyurea particles, where the polyurethane-polyurea particles present in the dispersion (PD) comprise anionic groups and/or groups which can be converted into anionic groups, and have an average particle size of 40 to 2000 nm and also a gel fraction of at least 50%. 1. A method for producing a paint system on a plastics substrate , comprising(1) producing a basecoat film or a plurality of directly successive basecoat films on the plastics substrate by applying an aqueous basecoat material to the substrate or directly successively applying a plurality of basecoat materials to the substrate,(2) producing a clearcoat film directly on the basecoat film or a topmost basecoat film by applying a clearcoat material directly to the basecoat film or the topmost basecoat film,(3) jointly curing the basecoat film and the clearcoat film or the basecoat films and the clearcoat film,whereinthe basecoat material or at least one of the basecoat materials comprises at least one aqueous polyurethane-polyurea dispersion comprising polyurethane-polyurea particles, where the polyurethane-polyurea particles present in the dispersion comprise anionic groups and/or groups which can be converted into anionic groups, and have an average particle size of 40 to 2000 nm and also a gel fraction of at least 50%.2. The method of claim 1 , wherein the polyurethane-polyurea ...

Latent curing agent and curable polyurethane composition

A compound of formula (I) having advantageous properties when used as a latent curing agent for compositions containing isocyanate groups, and to compositions containing the compound of formula (I). The compound of formula (I) is odourless, is liquid and has comparatively low viscosity at room temperature and is stable in storage together with isocyanates. It makes possible odourless single-component polyurethane compositions which have good stability in storage, do not produce bubbles when cured in the presence of moisture, and cause no problematic odour emissions, giving a cured elastic material having good mechanical properties, good heat stability, a surprisingly non-adhesive surface and little tendency towards plasticizer migration.

METHOD FOR ELIMINATING RADIOACTIVE IODINE AND HYDROPHILIC RESIN FOR ELIMINATING RADIOACTIVE IODINE

The present invention is a method for eliminating radioactive iodine using a hydrophilic resin that adsorbs radioactive iodine, wherein the hydrophilic resin is at least one selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin and has a hydrophilic segment and, in the principal chain and/or a side chain in the structure thereof, has a tertiary amino group or has a tertiary amino group and polysiloxane segment. By means of the present invention, a novel method for eliminating radioactive iodine is provided that is simple and low-cost, furthermore does not require an energy source such as electricity, moreover can take in and stably immobilize the eliminated radioactive iodine within a solid, and is capable of reducing the volume of radioactive waste as necessary. 1. A method for eliminating radioactive iodine using a hydrophilic resin that adsorbs radioactive iodine in liquid and/or a solid body , comprising the steps of:providing a hydrophilic resin selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin, wherein the hydrophilic resin has a hydrophilic segment, wherein a structure of the hydrophilics resin has a principal chain and a side chain, and wherein a tertiary a amino group-containing segment is located in said principal chain and/or said side chain; andcontacting the liquid and/or solid body with the hydrophilic resin adsorb radioactive iodine from the liquid and/or solid body in the hydrophilic resin.2. The method for eliminating radioactive iodine according to claim 1 , wherein the hydrophilic segment is a polyethylene oxide segment.3. The method for eliminating radioactive iodine according to claim 1 , wherein the hydrophilic resin is a resin formed from claim 1 , as a part of a raw material claim 1 , a polyol having at least one tertiary amino group or a polyamine ...

ADDITIVE MANUFACTURING USING POLYUREA MATERIALS

Methods of additive manufacture using coreactive components are disclosed. Thermosetting compositions for additive manufacturing are also disclosed. 1. A reactive additive manufacturing composition , comprising:a first compound having a first functional group;a second compound having a second functional group, wherein the second functional group is reactive with the first functional group; anda third compound having a third functional group, wherein the third functional group is reactive with the first functional group or the second functional group.2. The composition of claim 1 , wherein the reaction rate between the third compound with the first compound or with the second compound is faster than the reaction rate between the first compound and the second compound.3. The composition of claim 1 , wherein the composition is a thermosetting composition.4. The composition of claim 1 , wherein the composition comprises a polymeric rheology modifier.5. The composition of claim 4 , wherein the polymeric rheology modifier comprises polyethylene or a propylene/ethylene copolymer.6. The composition of claim 4 , wherein the polymeric rheology modifier comprises a reactive polymeric rheology modifier.7. The composition of claim 1 , wherein each of the first compound claim 1 , the second compound claim 1 , and the third compound independently comprises a prepolymer claim 1 , a monomer claim 1 , or a combination thereof.8. The composition of claim 7 , wherein claim 7 ,each monomer independently has a molecular weight less than 600 Daltons; andeach prepolymer independently has a molecular weight from 1,000 Daltons to 20,000 Daltons.9. The composition of claim 1 , wherein the first compound comprises an polyisocyanate and the second compound comprises a polyamine or a polyol.10. The composition of claim 1 , wherein the first compound comprises a thiol and the second compound comprises a polyalkenyl claim 1 , a polyisocyanate claim 1 , a polythiol claim 1 , a polyfunctional ...

LIQUID-APPLIED WATERPROOFING MEMBRANE FOR ROOFS

A one-part moisture-curing liquid-applied waterproofing membrane as disclosed includes a polyurethane polymer obtained from at least one polyether polyol and at least one diisocyanate, and an aldimine of the formula (I). The membrane has a long shelf life stability with both aromatic and aliphatic isocyanates, a low viscosity at low solvent content, a sufficiently long open time to allow hand application and cures fast to a solid elastic material of high strength and high elongation. The released aldehyd is non-toxic and low flammable and evaporates quickly out of the membrane causing only minimal odour emission. The membrane has high crack-bridging qualities in a broad temperature range and is easily overcoatable without interlayer adhesion problems, which makes it particularly suitable for roofing applications. 2. The membrane according to claim 1 , wherein the diisocyanate to obtain the isocyanate-functional polyurethane polymer is MDI or TDI.3. The membrane according to claim 1 , wherein the polyether polyol is a polymerization product of ethylene oxide and/or propylene oxide.4. The membrane according to claim 1 , wherein the aldimine of the formula (I) is selected from the group consisting of N claim 1 ,N′-bis(3-acetoxy-2 claim 1 ,2-dimethylpropylidene)hexamethylene-1 claim 1 ,6-diamine claim 1 , N claim 1 ,N′-bis(3-acetoxy-2 claim 1 ,2-dimethylpropylidene)-3-aminomethyl-3 claim 1 ,5 claim 1 ,5-trimethylcyclohexylamine claim 1 , N claim 1 ,N′-bis(3-acetoxy-2 claim 1 ,2-dimethylpropylidene)polyoxypropylene diamines with an average molecular weight in a range of 450 to 750 g/mol and N claim 1 ,N′ claim 1 ,N″-tris(3-acetoxy-2 claim 1 ,2-dimethylpropylidene)polyoxypropylene triamines with an average molecular weight in a range of 750 to 900 g/mol.5. The membrane according to claim 4 , comprising:a combination of N,N′-bis(3-acetoxy-2,2-dimethylpropylidene)-3-aminomethyl-3,5,5-trimethylcyclohexylamine and N,N′,N″-tris(3-acetoxy-2,2-dimethylpropylidene) ...

TWO-COMPONENT COATING COMPOSITIONS FOR COATING FIBER-REINFORCED PLASTICS MATERIALS

The present disclosure relates to two-component coating material compositions including a paint base component A and a curing component B. The paint base component A includes one or more polyols A1 selected from the group of polyols containing ester groups and which possess a hydroxyl number of 300 to 500 mg KOH/g and have a hydroxyl group functionality of greater than 2. The curing component B includes one or more polyisocyanates B1 having on average 2.4 to 5 NCO groups. The two-component coating material composition possesses a solids content of at least 96 wt %, and the molar ratio of the NCO groups in the curing component B to the acidic hydrogen atoms in the paint base component A is from 1:1.15 to 1:0.95. The disclosure further relates to a method for coating fiber-reinforced plastics and to a method for producing coated fiber-reinforced plastics, and to coating fiber-reinforced plastics. 1. A two-component coating material composition which comprises a paint base component A and a curing component B , wherein the paint base component A comprises:i. one or more polyols A1 which are selected from the group of polyols containing ester groups and which possess a hydroxyl number of 300 to 500 mg KOH/g and have a hydroxyl group functionality of greater than 2; [{'br': None, 'sup': '1', 'sub': 'p', 'R—(OH)\u2003\u2003(I)'}, {'sup': 1', '1, 'in which Ris a p-valent branched, cyclic or linear, saturated or unsaturated, aliphatic hydrocarbon radical having 5 to 18 carbon atoms, the radical Roptionally comprising one or more tertiary amino groups, and p is 2 to 6;'}], 'ii. one or more aliphatic polyols A2 free from ether groups and ester groups, of the general formula (I)'} [{'br': None, 'sup': 2', '3, 'sub': r', 's, 'R—(C═O)—O-(AO)—R\u2003\u2003(II)'}, {'sup': 2', '3', '2, 'in which Ris a saturated or unsaturated, aliphatic hydrocarbon radical having 6 to 30 carbon atoms, Ris H, a radical PO(OH), or the optionally partially phosphated radical of a mono- or disaccharide ...

BLOCKING AGENT FOR AMINES, LATENT HARDENERS AND POLYURETHANE COMPOSITIONS

The use of an aldehyde mixture containing 70 to 95 wt % of aldehydes of formula (I) and 5 to 30 wt % of alkylbenzene compounds not corresponding to formula (I) as a blocking agent for amines results in odorless, especially economically blocked amines, which at room temperature are typically liquid and have a surprisingly low viscosity. Such blocked amines are particularly suitable as latent hardeners in isocyanate-group-containing compositions. Single-component moisture-curing polyurethane compositions formulated therewith are surprisingly stable in storage, can be used for low-emission applications without odor problems and do not trigger any problems with plasticizer migration. Surprisingly, said compositions even have advantages over corresponding compositions having latent hardeners based on purified aldehydes of formula (I), in particular with respect to viscosity, storage stability and especially strength. 2. The method of claim 1 , wherein the alkylbenzene compounds not corresponding to the formula (I) have a higher boiling point than the aldehydes of the formula (I).3. The method of claim 1 , wherein the alkyl groups R of the aldehydes of the formula (I) are predominantly branched.4. The method of claim 1 , wherein the formyl group of the formula (I) is in the para position relative to the R group.8. The method of claim 7 , wherein the formylation was carried out with carbon monoxide in the presence of hydrofluoric acid and boron trifluoride.9. The method of claim 1 , wherein the amine to be blocked hasat least one primary or secondary amino group and additionallyat least one reactive group selected from primary amino group, secondary amino group, hydroxyl group and silane group.10. The method of claim 1 , wherein the amine to be blocked is selected from the group consisting ofprimary aliphatic diamines,primary aromatic diamines,primary aliphatic triamines,aliphatic diamines having a primary and a secondary amino group,aliphatic polyamines having two primary ...

SUSTAINABLE CHEMISTRY SYSTEMS FOR RECYCLABLE DENTAL MODELS AND OTHER ADDITIVELY MANUFACTURED PRODUCTS

Provided herein are methods of recycling additively manufactured objects, which may include making a reactive particulate material by recycling preformed articles or recovered coating material. Methods of use of the reactive particulate material and material sets including the same are also provided. 1. A method of making a reactive particulate material by recycling a preformed article (e.g. , dental model) or recovered coating material , comprising:(a) providing a preformed article, or recovered coating material, produced by a process of light polymerizing a single-cure resin in an additive manufacturing (or coating) process, wherein said resin is solely polymerized by light polymerization in said process, the resin comprising more than 90 or 95% by weight of: (i) a reactive blocked polyurethane prepolymer, a reactive blocked polyurea prepolymer, a reactive blocked polyurethane-polyurea copolymer, or a combination thereof, and (ii) optionally a monofunctional reactive diluent; wherein said resin further comprises: (iii) a photo-initiator,wherein said reactive blocked polyurethane prepolymer, reactive blocked polyurea prepolymer, reactive blocked polyurethane-polyurea copolymer, or combination thereof is blocked with a tertiary amine-containing (meth)acrylate selected from t-butylaminoethyl methacrylate (TBAEMA), tertiary pentylaminoethyl methacrylate (TPAEMA), tertiary hexylaminoethyl methacrylate (THAEMA), tertiary-butylaminopropyl methacrylate (TBAPMA), acrylate analogs thereof, and mixtures thereof, andwherein said resin does not include a chain extender for heat and/or microwave polymerization of a thermally reactive component of the reactive blocked polyurethane prepolymer, reactive blocked polyurea prepolymer, or reactive blocked polyurethane-polyurea copolymer; and then(b) comminuting said preformed article or coating material into a reactive particulate material.2. The method of claim 1 , wherein said preformed article or coating material is comprised of a ...

REACTIVE PARTICULATE MATERIALS USEFUL FOR ADDITIVE MANUFACTURING

Provided herein are methods of making a reactive particulate material by free radically polymerizing a single-cure resin to produce a polymer, the resin comprising: a reactive blocked polyurethane prepolymer, a reactive blocked polyurea prepolymer, a reactive blocked polyurethane-polyurea copolymer, or a combination thereof, wherein said polymerizing is carried out by dispersive polymerization (e.g., an emulsion, suspension or dispersion polymerization process), to form said reactive particulate material. Methods of use of the reactive particulate material and material sets including the same are also provided. 1. A method of making a reactive particulate material , comprising:free radically polymerizing a single-cure resin (e.g., by exposure to light, heating, etc.) to produce a polymer, wherein said resin is solely polymerized by light polymerization, the resin comprising more than 90 or 95% by weight of: (i) a reactive blocked polyurethane prepolymer, a reactive blocked polyurea prepolymer, a reactive blocked polyurethane-polyurea copolymer, or a combination thereof, and (ii) optionally a monofunctional reactive diluent; wherein said resin optionally further comprises: (iii) a photo-initiator,wherein said reactive blocked polyurethane prepolymer, reactive blocked polyurea prepolymer, reactive blocked polyurethane-polyurea copolymer, or combination thereof is blocked with a tertiary amine-containing (meth)acrylate selected from t-butylaminoethyl methacrylate (TBAEMA), tertiary pentylaminoethyl methacrylate (TPAEMA), tertiary hexylaminoethyl methacrylate (THAEMA), tertiary-butylaminopropyl methacrylate (TBAPMA), acrylate analogs thereof, and mixtures thereof,wherein said resin does not include a chain extender for heat and/or microwave polymerization of a thermally reactive component of the reactive blocked polyurethane prepolymer, reactive blocked polyurea prepolymer, or reactive blocked polyurethane-polyurea copolymer, andwherein said polymerizing is carried out ...

Polyureas made from aminocrotonates

A compound having the formula below, where R is —H or —CH 2 —CH 3 ; n, x, y, and z are nonnegative integers; R 2 is an aliphatic group or oxyaliphatic group; and R 3 is an aliphatic group.

Polyurea systems, processes for preparing the same and use thereof for postoperative adhesion barriers

Polyurea systems comprising: (a) an amino-functional aspartic ester of the general formula (I) wherein X represents an n-valent organic radical derived from a corresponding n-functional primary amine X(NH 2 ) n , R 1 and R 2 each independently represent an organic radical having no Zerevitinov active hydrogens and n represents an integer of at least 2; and (b) an isocyanate functional prepolymer having a residual monomer content of less than 1% by weight, the prepolymer prepared by reacting: (b1) an aliphatic isocyante; and (b2) a polyol component having a number average molecular weight of ≥400 g/mol and an average OH functionality of 2 to 6, wherein the polyol component comprises one or more constituents selected from the group consisting of polyester polyols, polyester-polyether polyols and mixtures thereof; processes for making the same; postoperative adhesions barriers prepared therewith and dispensing systems for such polyurea systems.

INKJET INK COMPOSITIONS

An example inkjet ink composition includes a colorant, an acid, lithium, an organic solvent package, at least 50 wt % water with respect to the weight of the inkjet ink composition, and from about 0.25 wt % to about 2 wt %, with respect to the weight of the inkjet ink composition, of a polyurethane binder. The acid is selected from the group consisting of oleic acid, linoleic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, and combinations thereof. The organic solvent package includes from about 1 wt % to about 12 wt %, with respect to the weight of the inkjet ink composition, of a first solvent having 1 or 2 free hydroxyl groups and 0 to 3 glycol units and from about 0.5 wt % to about 25 wt %, with respect to the weight of the inkjet ink composition, of a second solvent selected from the group consisting of 1-(2-hydroxyethyl)-2-pyrrolidinone, 2-pyrrolidone, glycerol, and combinations thereof. 2. The inkjet ink composition as defined in wherein the first solvent having 1 or 2 free hydroxyl groups and 0 to 3 glycol units is selected from the group consisting of tripropylene glycol claim 1 , tripropylene glycol methyl ether claim 1 , tripropylene glycol monobutyl ether claim 1 , tripropylene glycol monoethyl ether claim 1 , triethylene glycol claim 1 , triethylene glycol monobutyl ether claim 1 , triethylene glycol monomethyl ether claim 1 , diethylene glycol claim 1 , diethylene glycol butyl ether claim 1 , ethylene glycol claim 1 , ethylene glycol butyl ether claim 1 , ethylene glycol phenyl ether claim 1 , 3-methyl-1 claim 1 ,3-butanediol claim 1 , 2-ethyl-2-hydroxymethyl-1 claim 1 ,3-propanediol claim 1 , 2-methyl-1 claim 1 ,3-propanediol claim 1 , 2-methyl-2 claim 1 ,4-pentanediol claim 1 , 3-methyl-1 claim 1 ,5-pentanediol claim 1 , 2-ethyl-1 claim 1 ,3-hexanediol claim 1 , and a combination thereof.3. The inkjet ink composition as defined in wherein the chain extender is a primary monoamino compound claim 1 , a secondary monoamino compound claim 1 , a ...

Methods for Reactive Three-Dimensional Printing by Extrusion

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also enclosed. 126.-. (canceled)27. A method of three-dimensional printing an object comprising: the coreactive composition comprises a first component comprising at least two first functional groups and a second component comprising at least two second functional groups,', 'the second functional group is reactive with the first functional group; and', 'at least one of the first functional group and the second functional group comprises a saturated functional group; and, '(a) extruding a coreactive composition, wherein,'}(b) building a three-dimensional printed object;wherein extruding comprises forming an extrusion wherein the extrusion is characterized by a cross-sectional profile having an inhomogeneous material composition.28. The method of claim 27 , wherein claim 27 ,the cross-sectional profile comprises a first proton and a second portion;the first portion comprises a molar ratio of the first component to the second component greater than 1; andthe second portion comprises a molar ratio of the first component to the second component less than 1.29. The method of claim 28 , wherein the first portion and the second portion are on opposite sides of the cross-sectional profile.30. The method of claim 28 , wherein claim 28 ,the first portion comprises an equivalent ratio of the first functional group to the second functional group greater than 1; andthe second portion comprises an equivalent ratio of the first functional group to the second functional group less than 1.31. The method of claim 27 , wherein an equivalents ratio of the first component to the second component is not homogeneous throughout the cross-sectional profile.32. The method of claim 27 , wherein an equivalents ratio of the first component to the second component is homogeneous throughout the cross-sectional profile.33. The method of claim 27 , ...

A coating composition

The present invention relates to a coating composition, a coating method and use of the composition, and a product coated with the coating composition. The coating composition comprises: (a) an isocyanate-reactive component comprising: (a1) at least one polyaspartic ester, and (a2) optionally a polyetheraspartic ester; (b) an isocyanate component comprising: (b1) at least one isocyanate prepolymer having an isocyanate group equivalent of 300 to 1100, and (b2) at least one isocyanate oligomer containing not less than two isocyanate groups, the weight ratio of the isocyanate prepolymer (b1) to the isocyanate oligomer (b2) being from 1:4 to 4:1; (c) a catalyst; and (d) optionally an additive; wherein the coating composition has a molar ratio of isocyanate groups to isocyanate-reactive groups of 1.5:1 to 8:1. The coating composition provided by the present invention has a long pot life, and the resulting coating has the advantages of fast drying and high hardness.

DYNAMIC UREA BONDS FOR POLYMERS

The present invention relates to polymers having dynamic urea bonds and more specifically to polymers having hindered urea bonds (HUBs). The present invention also relates to: (a) malleable, repairable, and reprogrammable shape memory polymers having HUBs, (b) reversible or degradable (e.g., via hydrolysis or aminolysis) linear, branched or network polymers having HUBs, and (c) to precursors for incorporation of HUBs into these polymers. The HUB technology can be applied to and integrated into a variety of polymers, such as polyureas, polyurethanes, polyesters, polyamides, polycarbonates, polyamines, and polysaccharides to make linear, branched, and cross-linked polymers. Polymers incorporating the HUBs can be used in a wide variety of applications including plastics, coatings, adhesives, biomedical applications, such as drug delivery systems and tissue engineering, environmentally compatible packaging materials, and 4D printing applications. 1. A hindered urea bond polymer comprising recurring units from:(a) an unsaturated monomer substituted by a hindered amine, and(b) a crosslinking agent comprising two or more isocyanate groups.2. The polymer according to wherein the unsaturated monomer substituted by a hindered amine is selected from the group consisting of acrylates claim 1 , butadienes claim 1 , ethylenes claim 1 , styrenes claim 1 , vinyl esters claim 1 , vinyl ethers claim 1 , and combinations thereof.4. The polymer according to wherein Ris H or methyl.5. The polymer according to wherein the unsaturated monomer substituted by a hindered amine is a compound of formula Al.6. The polymer according to wherein R claim 5 , R claim 5 , R claim 5 , are each methyl.7. The polymer according wherein the crosslinking agent is OCN—Y—NCO claim 1 , where Y is selected from (C-C)alkyl claim 1 , (C-C)cyclolalkyl claim 1 , (C-C)alkyl(C-C)cycloalkyl claim 1 , (C-C)alkyl(C-C)cycloalkyl(C-C)alkyl claim 1 , (C-C)alkyl(C-C)aryl(C-C)alkyl claim 1 , and (C-C)alkyl- ...

METHODS FOR REDUCING ALDEHYDE EMISSIONS IN POLYURETHANE FOAMS

Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant, at least one catalyst, and certain aldehyde-suppressing additives. Foams so produced emit low levels of formaldehyde, acetaldehyde and propionaldehyde. 3. The process of wherein R claim 1 , R claim 1 , Rand Rare each independently C1-C4 alkyl.4. The process of wherein m is 1 and A is hydrogen claim 3 , hydroxyl claim 3 , —NHor alkyl.5. The process of wherein m is 2 or more and A is —O— claim 3 , —NH— claim 3 , alkylene claim 3 , arylene claim 3 , aryl-substituted alkylene claim 3 , aryl-substituted alkylene claim 3 , —NH—C(O)—(CH)—C(O)—NH— where 0 is 1 to 20 claim 3 , or —O—C(O)—(CH)—C(O)—O— where o is 1 to 20.7. The process of wherein Ris C1-C4 alkyl and Ris hydrogen or C1-C4 alkyl.9. The method of wherein the compound represented by structure I is present in an amount of from 0.02 to 0.25 parts by weight per 100 parts by weight of the at least one isocyanate reactive compound having at least two isocyanate-reactive groups per molecule and an equivalent weight of at least 200 per isocyanate-reactive group.10. The method of wherein the compound represented by structure II is present in an amount of from 0.02 to 0.25 parts by weight per 100 parts by weight of the at least one isocyanate reactive compound having at least two isocyanate-reactive groups per molecule and an equivalent weight of at least 200 per isocyanate-reactive group.11. The method of wherein the reaction mixture is cured in the presence of an antioxidant.12. The method of wherein the antioxidant is a phenolic compound.13. The method of wherein the antioxidant is present in an amount of 0.2 to 1.5 parts by weight per 100 parts by weight of the at least one isocyanate reactive compound having at ...

POLYMERIC MATERIAL INCLUDING A URETDIONE-CONTAINING MATERIAL AND A THERMALLY ACTIVATABLE AMINE, TWO-PART COMPOSITIONS, AND METHODS

The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components, and a thermally activatable amine curative, and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; and an optional second hydroxyl-containing compound having a single OH group. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which a polymeric material is included in the first part and the second part includes at least one liquid amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of curing a two-part composition. Advantageously, two-part compositions according to the present disclosure can be used as coatings and adhesive systems having a two-step cure with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water. 1. A polymeric material comprising: (a) a uretdione-containing material comprising a reaction product of a diisocyanate reacted with itself;', '(b) a first hydroxyl-containing compound having more than one OH group; and', '(c) an optional second hydroxyl-containing compound having a single OH group,, 'a polymerized reaction product of a polymerizable composition comprising components, the components comprisingwherein the second hydroxyl-containing compound is a ...

Polymeric material including a uretdione-containing material and an epoxy component, two-part compositions, and methods

The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; an optional second hydroxyl-containing compound having a single OH group, wherein; and an epoxy component. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which the polymeric material is included in the first part and the second part includes at least one amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of making a two-part composition. Advantageously, two-part compositions according to the present disclosure can be used as coatings and adhesive systems with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.

Microcapsule compositions stabilized with viscosity control agent

Disclosed are microcapsule compositions each comprising a microcapsule suspended in an aqueous phase and a viscosity control agent, wherein the viscosity control agent is an acrylate copolymer, a cationic acrylamide copolymer, or a polysaccharide. Also disclosed are consumer products containing such a microcapsule composition.

Additive manufacturing using polyurea materials

Methods of additive manufacture using coreactive components are disclosed. Thermosetting compositions for additive manufacturing are also disclosed.

Polyurethane Composition

The present technology provides a polyurethane composition including: a main agent; and a curing agent, wherein the main agent includes a urethane prepolymer having an isocyanate group, a morpholine compound having one morpholine ring, and an ether compound having two dimethylamino groups, and the curing agent includes an active hydrogen compound having two or more active hydrogen-containing groups in one molecule. 1. A polyurethane composition , comprising:a main agent; anda curing agent,wherein a urethane prepolymer having an isocyanate group,', 'a morpholine compound having one morpholine ring, and', 'an ether compound having two dimethylamino groups, and, 'the main agent includes'}the curing agent includes an active hydrogen compound having two or more active hydrogen-containing groups in one molecule.2. The polyurethane composition according to claim 1 , whereina content of the morpholine compound is from 0.02 to 1.6 parts by mass with respect to 100 parts by mass of the urethane prepolymer, anda content of the ether compound is from 0.002 to 0.16 parts by mass with respect to 100 parts by mass of the urethane prepolymer.3. The polyurethane composition according to claim 1 , wherein the morpholine compound is dimethylaminoethyl morpholine.4. The polyurethane composition according to claim 1 , wherein the ether compound is bis(dimethylaminoethyl) ether.5. The polyurethane composition according to claim 1 , wherein the main agent further includes at least one organophosphorus compound selected from the group consisting of a phosphite compound claim 1 , a phosphonite compound claim 1 , a phosphinite compound claim 1 , and a phosphine compound.6. The polyurethane composition according to claim 5 , wherein a content of the organophosphorus compound is from 0.01 to 1.0 part by mass with respect to 100 parts by mass of the urethane prepolymer.7. The polyurethane composition according to claim 5 , wherein the organophosphorus compound is triphenylphosphine.8. The ...

POLYURETHANE DISPERSIONS BASED ON RENEWABLE RAW MATERIALS

A polyurethane dispersion PUD comprises at least one polyurethane P based on at least one polyisocyanate and at least one polyester polyol PES, wherein the polyester polyol PES is based on at least one polyhydric alcohol A and at least one dicarboxylic acid D, wherein at least one polyhydric alcohol A and/or at least one dicarboxylic acid D were at least partly derived from renewable raw materials. 1. A polyurethane dispersion PUD comprising at least one polyurethane P based on at least one polyisocyanate and at least one polyester polyol PES , wherein the polyester polyol PES is based on at least one polyhydric alcohol A and at least one dicarboxylic acid D , wherein at least one polyhydric alcohol A and/or at least one dicarboxylic acid D were at least partly derived from renewable raw materials.2. The polyurethane dispersion according to wherein the at least one dicarboxylic acid D is sebacic acid claim 1 , azelaic acid claim 1 , succinic acid claim 1 , furan dicarboxylic acid or tetrahydrofuran dicarboxylic acid.3. The polyurethane dispersion according to wherein the at least one dicarboxylic acid D comprises sebacic acid at least partly derived from renewable raw materials claim 1 , and adipic acid.4. The polyurethane dispersion according to wherein the at least one polyhydric alcohol A was at least partly derived from renewable raw materials.5. The polyurethane dispersion according to claim 1 , wherein the at least one polyhydric alcohol A is selected from the group consisting of aliphatic C2-C6 diols.6. The polyurethane dispersion according to wherein the at least one polyhydric is selected from the group consisting of 1 claim 1 ,3-propanediol and 1 claim 1 ,4-butanediol.7. The polyurethane dispersion according to claim 1 , wherein the polyurethane comprises at least one chain extender.8. The polyurethane dispersion according to claim 1 , wherein the polyurethane dispersion is aqueous.9. A process for producing a polyurethane dispersion claim 1 , which ...

Liquid-applied waterproofing membrane for roofs comprising two different aldimines

A one-part moisture-curing liquid-applied waterproofing membrane is disclosed as including a polyurethane polymer and two different aldimines as blocked amine hardeners in a specific ratio range. The membrane has a low odour, a long shelf life stability, a low viscosity at low solvent content, a sufficiently long open time to allow hand application and cures fast to a solid elastic material. The liquid-applied waterproofing membrane is particularly suitable for roofing applications, possessing high strength, high elongation and good durability under outdoor weathering conditions in a broad temperature range.

LOW-TEMPERATURE CURING COATING COMPOSITIONS

The present invention is directed towards a coating composition comprising a film-forming polymer comprising active hydrogen-containing functional groups; a blocked polyisocyanate curing agent comprising a blocking group derived from a blocking agent comprising an alpha-hydroxy amide, ester or thioester; and a curing catalyst that does not contain tin, lead, iron, zinc or manganese. Also disclosed are coatings, coated substrates, and methods of coating a substrate. 1. A coating composition comprising:a film-forming polymer comprising active hydrogen-containing functional groups;a blocked polyisocyanate curing agent comprising a blocking group derived from a blocking agent comprising an alpha-hydroxy amide, ester or thioester; anda curing catalyst that does not contain tin, lead, iron, zinc or manganese.2. The coating composition of claim 1 , wherein the film-forming polymer comprises an active hydrogen-containing claim 1 , cationic salt group-containing film-forming polymer.4. The coating composition of claim 1 , wherein the blocking agent comprises an alpha-hydroxy amide blocking agent.5. The coating composition of claim 4 , wherein the alpha-hydroxy amide blocking agent comprises an alkyl glycolamide and/or an alkyl lactamide.8. The coating composition of claim 5 , wherein the alkyl glycolamide comprises a Cto Cmono-alkyl glycolamide.9. The coating composition of claim 5 , wherein the alkyl lactamide comprises a Cto Cmono-alkyl lactamide.10. The coating composition of claim 5 , wherein the alkyl lactamide comprises a racemic lactamide.11. The coating composition of claim 5 , wherein the blocking group derived from the alpha-hydroxy amide claim 5 , ester or thioester blocking agent comprise at least 10% of the total blocked isocyanato groups of the blocked polyisocyanate.12. The coating composition of claim 1 , wherein the curing catalyst comprises a guanidine.13. The coating composition of claim 12 , wherein the guanidine comprises a bicyclic guanidine.14. The ...

ALDIMINE CONTAINING GLASS BONDING PRIMER

A novel primer composition contains aldimine and/or epoxy resins, a process of making such primer to be used in glass bonding adhesive kit. 1. A primer composition comprising , based on the total weight of the composition , an organic solvent; an aldimine; an alkoxysilane; a non-reactive film forming resin; a polyisocyanate prepolymer; a reactive modifier; a catalyst; and an isocyanate stabilizer.2. The primer composition of further comprising less than 10 wt. % of an epoxy resin.3. The primer composition of wherein the epoxy resin is a diglycidyl ether of bisphenol A.4. The primer composition of is substantially free of carbon black.5. The primer composition of is free of carbon black.6. The primer composition of wherein the organic solvent comprises one of acetone claim 1 , methyl ethyl ketone claim 1 , and a mixture thereof; and wherein the reactive modifier is an oxazolidine containing compound.7. The primer composition of wherein the isocyanate stabilizer comprises diethyl malonate.8. The primer composition of wherein the aldimine is a dialdimine.9. The primer composition of wherein the aldimine is a reaction product of polyetheramines and benzaldehyde.10. The primer composition of wherein alkoxysilane is a reaction product of gamma-mercaptopropyltrimethoxysilane and hexamethylene diisocyanate (HDI) biuret. The present invention relates to a new primer composition or “primer” having unique properties in automotive related applications, particularly in glass bonding applications.A typical, glass bonding adhesive kit contains a primer composition and a moisture cured urethane adhesive. The glass bonding primer typically contains organic solvents, organosilane intermediates, isocyanate prepolymers, film formers, carbon black, catalysts, and stabilizers. The primer modifies the surface of the glass to enable good bonding with the moisture cured urethane adhesive. The isocyanates within the primers undergo moisture curing to produce a crosslinked thermoset network ...

WATER-SWELLABLE MOISTURE CURING ONE-COMPONENT POLYURETHANE SEALANT

A one-component moisture curing composition and a method for sealing construction joints against penetration of water. The one-component moisture curing composition includes at least one isocyanate-functional polyurethane polymer, at least one inorganic swelling agent selected from the group including aluminum sulfate and magnesium sulfate, and at least one hydrophilic aldimine of formula (I). 2. The one-component moisture curing composition according to claim 1 , wherein the total amount of the at least one inorganic swelling agent is in the range of 1.0-35.0% by weight claim 1 , based on the total weight of the one-component composition.3. The one-component moisture curing composition according to claim 1 , wherein A is a divalent or a trivalent hydrocarbyl moiety having a content of ethylene oxide units of at least 50.0% by weight claim 1 , based on the weight of A.4. The one-component moisture curing composition according to claim 1 , wherein the hydrophilic aldimine of formula (I) has a content of ethylene oxide units of at least 30.0% by weight claim 1 , based on the weight of the hydrophilic aldimine.5. The one-component moisture curing composition according to claim 1 , wherein the at least one hydrophilic aldimine of formula (I) is present in an amount of 1.0-30.0% by weight claim 1 , based on the total weight of the one-component moisture curing composition.7. The one-component moisture curing composition according to claim 1 , wherein the hydrophilic aldimine of formula (I) is selected from the group consisting of N claim 1 ,N′-bis(2 claim 1 ,2-dimethyl-3-(N-morpholino)-propylidene)-polyoxyethylene-polyoxypropylenediamines with an average molecular weight in the range of 1 claim 1 ,000 to 3 claim 1 ,000 g/mol claim 1 , N claim 1 ,N′-bis(2 claim 1 ,2-dimethyl-3-acetoxypropylidene)-polyoxyethylene-polyoxypropylenediamines with an average molecular weight in the range of 1 claim 1 ,000 to 3 claim 1 ,000 g/mol claim 1 , and N claim 1 ,N′-bis(2 claim 1 ,2- ...

POLYUREA COPOLYMER COATING COMPOSITIONS AND METHODS

Durable polyurea copolymer coatings can be applied to surfaces that come in contact with fluids, such as biological fluids, thereby passivating the surface. Polyurea copolymer coating compositions comprise a reaction product of (a) a diamine composition that includes a polyethylene glycol diamine, and optionally, a dipiperidyl alkane; and (b) a diisocyanate. Solutions containing polyurea copolymers, coated surfaces and methods are also described. 2. The coating composition of wherein the polyethylene glycol diamine has a molecular weight of 500 to 2500.3. The coating composition of wherein the diamine composition of (a) further comprises a dipiperidyl alkane claim 1 , and wherein the diamine composition comprises 20 to 99.9 molar percent of the polyethylene glycol and 0.1 to 80 molar percent of the dipiperidyl alkane.5. The coating composition of wherein the dipiperidyl alkane comprises dipiperidyl propane.7. The coating composition of claim 6 , wherein the diisocyanate is selected from hexane diisocyanate and isophorone diisocyanate.8. The coating composition of wherein the copolymer comprises polyethylene glycol in amount of 25 to 95 weight percent claim 1 , based on total weight of the polyurea copolymer.9. The coating composition of having a Hardness Value of 30D or less.10. The coating composition of wherein the polyurea copolymer has an average molecular weight of 100 claim 1 ,000 or less.11. The coating composition of wherein the polyurea copolymer has a Young's modulus that is at least 1 claim 1 ,000 psi.12. The coating composition of claim 1 , wherein the surface is a surface that contacts biological fluids.1316.-. (canceled)17. The coating composition of further comprising one or more latent reactive groups selected from photoreactive groups claim 1 , thermally reactive groups claim 1 , chemically reactive groups claim 1 , or a combination of any two or more of these.1822.-. (canceled)23. The coating composition of wherein the copolymer does not include ...

Coreactive materials and methods for three-dimensional printing

Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also disclosed.

Post-operative adhesion barriers

Polyurea system comprises: (a) an amino functional aspartic acid (I); (b) an isocyanate functional prepolymer, with a residual monomer content of less than 1 wt.%, obtained by reacting (b1) aliphatic isocyanate with (b2) a polyol component with a number average molecular weight of greater than 400 g/mol and an average hydroxyl-functionality of 2-6 and comprises polyesterpolyol and/or polyester-polyether-polyol and optionally polyetherpolyol; and/or (c) optionally organic filler; and (d) optionally the reaction product of component (b) with component (a) and/or component (c). Polyurea-system comprises: (a) an amino functional aspartic acid of formula (X[-NH-CH(-CH 2-COOR 2)-COOR 1] n) (I); and (b) an isocyanate functional prepolymer, with residual monomer content of less than 1 wt.%, obtained by reacting (b1) aliphatic isocyanate with (b2) a polyol component with a number average molecular weight of greater than 400 g/mol and an average hydroxyl-functionality of 2-6 and comprises polyesterpolyol and/or polyester-polyether-polyol and optionally polyetherpolyol; and/or (c) optionally organic filler having viscosity, measured according to DIN 53019 at 23[deg] C, of 10-6000 mPas; and (d) optionally the reaction product of component (b) with component (a) and/or component (c). X : n-valenced organic residue, obtained by removing the primary amino group of n-valenced amine; R 1, R 2organic residue comprising no Zerewitinoff-active hydrogen; and n : whole number of at least 2. Independent claims are included for: (1) preparing the polyurea system, comprising mixing the components (a), (b), and optionally (c) and (d), where the ratio of free or blocked amino groups to free isocyanate groups is 1:1 and the weight ratio of the component (c) to component (a) is 0:1-20:1; and (2) a 2-chamber dosing system comprising the polyurea system, where one chamber comprises the component (a) and the other chamber comprises the harder component (b) and optional components (c) and (d).

Method for joinning substrates and objects

A method to join a substrate to an object is disclosed using a curable one or two part adhesive composition comprising an effective amount of a stabilized organoborane amine complex initiator and one or more monomers, oligomers, polymers or mixtures thereof having olefinic unsaturation which is capable of polymerization by free radical polymerization.

Method for joining substrates and objects

A method to join a substrate to an object is disclosed using a curable one or two part adhesive composition comprising an effective amount of a stabilized organoborane amine complex initiator and one or more monomers, oligomers, polymers or mixtures thereof having olefinic unsaturation which is capable of polymerization by free radical polymerization.

Abrasion resistant coatings

A method of protecting a substrate against damage comprising disposing on a substrate one or more coatings, wherein one coating comprises an isocyanate-terminated polyurethane prepolymer and a curing agent; wherein the curing agents comprise polyaspartic esters, ketimines, aldimines, or a combination comprising at least one of the foregoing curing agents; reacting the isocyanate-terminated polyurethane prepolymer with a curing agent; wherein the reacting can optionally be carried out in the presence of moisture or heat; and curing the isoycyanate-terminated polyurethane prepolymer to form the coating.

Polyurea/polythiourea coatings

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first component further comprises an isocyanate functional polythioether-polyurethane and/or polythiourethane, and/or the second component further comprises an amine/hydroxy functional polythioether, are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed.

secondary diamine, process for forming a secondary diamine, formulation, process for producing a polyurethane

diamina secundária, processo para formar uma diamina secundária, formulação, processo para produzir um poliuretano. esta invenção fornece ainda diaminas secundárias aromáticas onde as diaminas possuem grupos amino hidrocarbil com pelo menos dois átomos de carbono, e ambos estão na forma de um anel de benzeno com grupos amino em seu anel, estes grupos amino são meta ou para relativos uma ao outro, e nos quais cada posição orto de um grupo amino dá origem à um grupo hidrocarbil, ou estão na forma de dois anéis de benzeno ligados por uma ponte alcalina e possuem um grupo aminoem cada anel, e nos quais cada posição orto de um grupo amino dá origem à um grupo hidrocarbil. fomece ainda processos para formação de diaminas secundárias à partir de diaminas primárias, incluindo as diiminas aromáticas e diaminas scundárias aromáticas desta invenção. secondary diamine, process for forming a secondary diamine, formulation, process for producing a polyurethane. This invention further provides aromatic secondary diamines where the diamines have hydrocarbyl amino groups having at least two carbon atoms, and both are in the form of a benzene ring with amino groups on their ring, these amino groups are meta or para relative to each other. wherein each ortho position of an amino group gives rise to a hydrocarbyl group, or are in the form of two benzene rings linked by an alkaline bridge and have an amino group in each ring, and wherein each ortho position of an amino group gives rise to a hydrocarbyl group. further provides processes for forming secondary diamines from primary diamines, including the aromatic diimines and aromatic secondary diamines of this invention.

Chain extenders

This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.

Diimines and secondary diamines

Method of producing multilayer paint system on plastic bases

FIELD: chemistry. SUBSTANCE: invention relates to a method of producing a multilayer paint system based on a plastic base and can be used in the field of coating of a vehicle. Method of producing a paint system on a plastic base, in which a base coat film or several directly applied base coat films are obtained on a plastic base, wherein coating lacquer film is obtained directly on one film of base coating or on uppermost of several films of base coating, and then one or more base coat films and lacquer film are hardened together, wherein at least one base coating material contains at least one aqueous dispersion of polyurethane and polyurea, in which the polyurethane and polyurea particles have anionic groups and/or groups which can be converted to anionic groups, and an average particle size in range of 110–500 nm, as well as a gel fraction which is at least 50 wt. %. EFFECT: invention provides high adhesion on base material aqueous base materials plastic bases. 15 cl, 7 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 686 904 C1 (51) МПК B05D 7/00 (2006.01) C09D 175/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК B05D 7/532 (2019.02); C09D 175/00 (2019.02) (21) (22) Заявка: 2017142382, 31.03.2016 (24) Дата начала отсчета срока действия патента: 31.03.2016 06.05.2019 06.05.2015 EP 15166548.6 (73) Патентообладатель(и): БАСФ КОАТИНГС ГМБХ (DE) (45) Опубликовано: 06.05.2019 Бюл. № 13 (56) Список документов, цитированных в отчете о поиске: WO 2015029627 A1 (KANSAI (85) Дата начала рассмотрения заявки PCT на национальной фазе: 06.12.2017 (86) Заявка PCT: EP 2016/057007 (31.03.2016) R U 2 6 8 6 9 0 4 C 1 WO 2016/177515 (10.11.2016) Адрес для переписки: 105082, Москва, Спартаковский пер., 2, стр. 1, секция 1, этаж 3, ЕВРОМАРКПАТ (54) СПОСОБ ПОЛУЧЕНИЯ МНОГОСЛОЙНОЙ КРАСОЧНОЙ СИСТЕМЫ НА ПЛАСТМАССОВЫХ ОСНОВАХ (57) Реферат: Изобретение относится к способу получения покрытия и пленка покровного лака многослойной ...

Method of joining substrates and objects

FIELD: chemistry. SUBSTANCE: invention relates to the method of joining membrane roof coating, with a first surface, and an object, with a second surface, involving the following stages; (i) deposition of an effective amount of a hardening adhesive composition on the first surface of the membrane roof coating, second surface of the object or on both surfaces, where the adhesive contains (a) an effective amount of initiator based on a complex of organo borane and amine, with the structure (R 2 ) 3 -B←NH 2 (CH 2 ) b -(C(R 12 ) 2)a -Si-((R 11 ) q (Q) P )- or , where B is boron; R 2 in each separate case represents C 1-10 alkyl, C 3-10 cycloalkyl, or two or more R 2 can be combined, forming a cycloaliphatic ring; Q is a hydrolised link; R 11 in each case independently represents hydrogen, alkyl, alkoxy, alkenyl, alkylamino or has the formula ((CR 14 H) r O) n -(NR 4 )-(CH 2 ) 0 -NH 2 under the condition that, at least (R 11 ) is a primary amine, representing the above mentioned; R 12 in each case independently represents hydrogen, alkyl, aryl, alkoxy and can additionally contain one or several primary, secondary or tertiary amines; R in each separate case is hydrogen or alkyl; R 4 is hydrogen, C 1-10 alkyl, C 6-10 aryl or C 7-10 alkaryl; a assumes values from 1 to 10; b assumes values from 0 to 1; m in each separate case is an integer equal to or greater than 1; p in each separate case assumes values from 1 to 3; q in each separate case is an integer assuming values from 1 to 2, where the sum of p and q on each silicon atom equals 3; n in each separate case is an integer assuming values from approximately 4 to approximately 400; o in each separate case is an integer assuming values from approximately 1 to approximately 9; and r in each separate case is an integer equal to 2 or 4, and (b) one or several monomers, oligomers, polymers or their mixtures, with olefin-type unsaturation, which can take part in free-radical polymerisation and produced from acrylates and ...

聚氨酯潜固化剂及单组份聚氨酯防水涂料及制备方法

本发明公开了一种聚氨酯潜固化剂，其结构式为R 1 —CH══N—R 2 —N══CH—R 3 ，其中，R 1 、R 2 、R 3 为烷基或芳基或烷芳基，所述潜固化剂的分子量不高于300。本发明还公开了采用上述潜固化剂的单组份聚氨酯防水涂料及其制备方法。本发明提供了一种聚氨酯潜固化剂，稳定性好，采用其制得的单组份聚氨酯防水涂料更加耐储存，保质期更长；单位质量的聚氨酯潜固化剂能提供更多‑NH2基团，用量小，应用成本低。本发明公开的聚氨酯防水涂料对人体伤害小，对环境友好，具有优良的储存稳定性，同时所得到的涂层性能优异，具有优异的拉伸强度和撕裂强度，可直接采用现有的生产工艺及生产设备制备，生产成本低。

包含交联聚氨基甲酸酯基料和特定溶剂组合物的水性基底涂料

本发明涉及一种包含水性聚氨基甲酸酯‑聚脲分散液(PD)的经着色水性基底涂料，所述分散液具有存在于分散液中、具有40‑2000nm的平均粒度(体积平均粒度)、且具有至少50重量％的凝胶分率的聚氨基甲酸酯‑聚脲颗粒。呈经反应形式的聚氨基甲酸酯‑聚脲颗粒各自包含(Z.1.1)至少一种聚氨基甲酸酯预聚物，其含有异氰酸酯基且包含阴离子基团和/或可转化成阴离子基团的基团；以及(Z.1.2)至少一种多元胺，其包含两个伯氨基及一个或两个仲氨基，所述水性基底涂料包含特定溶剂组合物。本发明还涉及包含所述分散液(PD)的基底涂料的用途以及通过使用所述基底涂料产生的多层涂漆体系。

包含尿素固化剂的可低温固化的环氧组合物

本发明公开了包含尿素固化剂的低温固化环氧组合物。本发明公开了一种可热固化的环氧组合物，包含环氧树脂、环氧树脂固化剂和该环氧树脂固化剂的加速剂的接触产物，该固化剂或加速剂包含作为异氰酸酯和具有至少一个伯胺或仲胺和至少两个叔胺的烷基化的聚亚烷基多胺的反应产物的尿素化合物，该烷基化的聚亚烷基多胺如以下通式所示： 其中R 1 、R 2 、R 3 、R 4 和R 5 独立地代表氢、甲基或乙基；n和m独立地为1-6的整数；和X为1-10的整数。

Water-based paints which include cross-linking polyurethane binding substances and a defined solvent composition

FIELD: technological processes.SUBSTANCE: present invention relates to a pigmented aqueous primer, as well as to multilayer paint systems and a method for production thereof. Said primer material contains an aqueous polyurethane-polyurea dispersion having polyurethane-polyurea particles present in the dispersion, the average size of which is 40–2,000 nm, and having a gel fraction of at least 50 wt. % of polyurethane-polyurea particles, in each case in a reactive form and a defined composition of solvents. Said dispersion contains at least one polyurethane prepolymer (Z.1.1) containing isocyanate groups and containing anionic groups and / or groups, which can be converted to anionic groups, as well as at least one polyamine (Z.1.2), which includes two primary amino groups and one or two secondary amino groups. Total amount of solvents present in the primer material is less than 9 wt. % of solvents selected from the group comprising solvents having LGB between 5 and 15 and solubility in water greater than 1.5 wt. % at 20 °C.EFFECT: obtained pigmented aqueous primer material has storage stability, good applicability, as well as stability of point holes and blisters.15 cl, 6 tbl, 9 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) (19) RU (11) (13) 2 690 855 C1 (51) МПК C08G 18/08 (2006.01) C08G 18/42 (2006.01) C08G 18/32 (2006.01) C08G 18/10 (2006.01) C08G 18/66 (2006.01) C09D 175/02 (2006.01) C09D 175/04 (2006.01) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C08G 18/0823 (2019.02); C08G 18/0866 (2019.02); C08G 18/10 (2019.02); C08G 18/246 (2019.02); C08G 18/3256 (2019.02); C08G 18/348 (2019.02); C08G 18/4063 (2019.02); C08G 18/4288 (2019.02); C08G 18/4615 (2019.02); C08G 18/6659 (2019.02); C08G 18/765 (2019.02); C09D 175/02 (2019.02); C09D 175/04 (2019.02); C09D 175/06 (2019.02); C09D 7/65 (2019.02); C08L 2203/16 (2019.02); C08L 61/28 (2019.02); C09D 5/028 (2019.02) 2018119702, 31.10.2016 (24) Дата начала отсчета срока действия патента: 31. ...

含有羟基醛亚胺的聚氨酯组合物

本发明涉及具有式(I)的醛亚胺的组合物。这类组合物特别是双组分的聚氨酯组合物。其尤其特征在于长的晾置时间，虽然如此但迅速地建立起早期强度，并在固化的状态下具有高拉伸强度和高弹性模量。而且，这是一个重要的优势，使得组合物能够实现在固化之前、期间和之后无气味或者至少低气味。

low temperature curing adhesive composition

본 발명은 에폭시-함유 성분; 및 α-하이드록시 아마이드, 에스터, 티오에스터 또는 이들의 조합을 포함하는 차단제로부터 유래한 차단기를 포함하는 차단된 폴리이소시아네이트 경화제를 포함하는 접착 조성물에 관한 것이다. 본 발명은 또한 상기 접착 조성물에 의해 결합된 기재를 형성하는 방법에 관한 것이다. 본 발명은 또한 제1 및 제2 기재 및 상기 접착 조성물을 포함하는 제품에 관한 것이다. The present invention relates to an epoxy-containing component; and a blocked polyisocyanate curing agent comprising a blocking group derived from a blocking agent comprising an α-hydroxy amide, an ester, a thioester, or a combination thereof. The present invention also relates to a method of forming a substrate bonded by the adhesive composition. The present invention also relates to articles comprising first and second substrates and said adhesive composition.

Aldimines and aldimine-containing compositions

FIELD: chemistry. SUBSTANCE: in formula : A denotes either an amine residue after removing n primary n aliphatic amino groups and m HX- groups, or together with R 7 denotes a (n+2)-valent hydrocarbon residue with 3-20 carbon atoms, which optionally contains at least one heteroatom, particularly in form of oxygen an ether or tertiary amine nitrogen; n equals 1-4, m equals 0-4; under the condition that (m+n) equals 2-5; R 1 and R 2 either, independently of each other, each denote a univalent hydrocarbon residue with 1-12 carbon atoms, or together denote a divalent hydrocarbon residue with 4-12 carbon atoms, which is part of an optionally substituted carbocycle with 5-8, preferably 6, carbon atoms; R 3 denotes a hydrogen atom or an alkyl group or an arylalkyl group or an alkoxycarbonyl group, particularly with 1-12 carbon atoms; X denotes O or S, or N-R 6 , or N-R 7 , where values of radicals R 4 -R 6 are given in the claim. The invention also relates to a curable or cured composition containing said compound, use of the compound in adhesives, sealants, filling compounds, coatings and an article containing the curable composition. EFFECT: higher compound properties. 21 cl, 13 tbl, 48 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 489 421 (13) C2 (51) МПК C07C 251/08 (2006.01) C07C 249/02 (2006.01) C08L 75/04 (2006.01) C09J 5/04 (2006.01) C08G 18/48 (2006.01) C08G 18/32 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА C09J 175/04 (2006.01) ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ C09K 3/10 (2006.01) C08K 5/29 (2006.01) C09D 175/04 (2006.01) (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2010105241/04, 16.07.2008 (24) Дата начала отсчета срока действия патента: 16.07.2008 (73) Патентообладатель(и): ЗИКА ТЕКНОЛОДЖИ АГ (CH) R U Приоритет(ы): (30) Конвенционный приоритет: 16.07.2007 EP 07112503.3 (72) Автор(ы): БУРКХАРДТ Урс (CH) (43) Дата публикации заявки: 27.08.2011 Бюл. № 24 2 4 8 9 4 2 1 2 4 8 9 4 2 1 R U (56) Список документов, цитированных в отчете о поиске: ERIC С. BROWN et al. Modular ...

낮은 경화 온도 및 양호한 저장 안정성을 갖는 열경화성 에폭시 수지 조성물

본 발명은, 양호한 저장 안정성 및 낮은 경화 온도를 특징으로 하는, 특정 유레아 촉진제와 조합하여, 글루타르산 다이하이드라자이드, 아디프산 다이하이드라자이드 및 피멜산 다이하이드라자이드로 이루어진 군으로부터 선택된 다이하이드라자이드를 경화제로서 포함하는 열경화성 에폭시 수지 조성물에 관한 것이다. 에폭시 수지 조성물은 차체 접착제로서 사용하는데 특히 적합하다.

Diimines and secondary diamines

本发明提供了芳香族二亚胺，其中该二亚胺具有含至少两个碳原子的亚氨基，且具有下述两种形式之一：具有一个苯环，在环上具有两个亚氨基，其中该亚氨基位于彼此的间位或对位，其中位于亚氨基邻位的每个位置连有烃基；或者具有通过亚烷基桥相连的两个苯环，在每个环上具有一个亚氨基，其中位于亚氨基邻位的每个位置连有烃基。本发明还提供了芳香族仲二胺，其中该二胺具有含至少两个碳原子的氨基烃基基团，且具有下述两种形式之一：具有一个苯环，在环上具有两个仲氨基，其中该氨基位于彼此的间位或对位，其中位于仲氨基邻位的每个位置连有烃基；或者具有通过亚烷基桥相连的两个苯环，在每个环上具有一个仲氨基，其中位于仲氨基邻位的每个位置连有烃基。本发明还提供了由伯二胺制备二亚胺和仲二胺，包括本发明的芳香族二亚胺和芳香族仲二胺的方法。

Patent RU2019128021A3

РОССИЙСКАЯ ФЕДЕРАЦИЯ ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) (19) RU (51) МПК C08G 18/08 C08G 18/10 C08G 18/12 C08G 18/64 C08G 18/78 C08G 18/80 C09J 175/06 (11) (13) 2019 128 021 A (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2019128021, 07.02.2018 (71) Заявитель(и): ППГ ИНДАСТРИЗ ОГАЙО, ИНК. (US) Приоритет(ы): (30) Конвенционный приоритет: 07.02.2017 US 62/455,778 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 09.09.2019 R U (43) Дата публикации заявки: 09.03.2021 Бюл. № 7 (72) Автор(ы): ЧЖОУ, Хунин (US), НАКАДЗИМА, Масаюки (US), ТАНЬ, Кар Тин (US) (86) Заявка PCT: (87) Публикация заявки PCT: WO 2018/148323 (16.08.2018) R U (54) КОМПОЗИЦИИ НИЗКОТЕМПЕРАТУРНЫХ ОТВЕРЖДАЕМЫХ ПОКРЫТИЙ (57) Формула изобретения 1. Клеевая композиция, содержащая эпоксид-содержащий компонент; блокированный полиизоцианатный отверждающий агент, содержащий блокирующую группу, полученную из блокирующего агента, содержащего альфа-гидроксиамид, сложный эфир или тиоэфир или их комбинацию; и катализатор латентного отверждения. 2. Клеевая композиция по п. 1, отличающаяся тем, что эпоксид-содержащий компонент присутствует в количестве от 50 до 95 мас. % в расчете на общую массу композиции. 3. Клеевая композиция по п. 1, отличающаяся тем, что эпоксидсодержащий компонент содержит пластификатор с эпоксидным покрытием. 4. Клеевая композиция по п. 1, отличающаяся тем, что блокированный полиизоцианатный отверждающий агент присутствует в количестве от 5 до 50% в расчете на общую массу композиции. 5. Клеевая композиция по п. 1, отличающаяся тем, что блокированный полиизоцианат содержит вторую блокирующую группу, полученную из блокирующего агента, содержащего спирт, фенольное соединение, третичный гидроксиламин, оксим, амин или их комбинацию. 6. Клеевая композиция по п. 1, отличающаяся тем, что блокирующий агент, Стр.: 1 A 2 0 1 9 1 2 8 0 2 1 A Адрес для переписки: 101000, Москва, ул. Мясницкая, 13, стр. 5, ООО ...

Aldimines and compositions comprising aldamine

本发明的第一个方面涉及式(I)的醛亚胺。所述醛亚胺特别适合作为可固化组合物、特别是具有异氰酸酯基的单组分或双组分的组合物中的潜固化剂。由于所存在的反应性基团，其能够转化为含醛亚胺基的式(X)和(XII)的化合物，这是本发明的另一个方面。所述醛亚胺或含醛亚胺基的化合物能够首先用于粘合剂和密封剂中，但是也能用于涂层中，并且能够容易地由易获得的基础原料制得并具有良好的热稳定性。其叔氨基具有令人吃惊地低碱性并能在某些情况下在化学反应体系中发挥催化剂的作用。

Use of Schiff bases as cross-linking agents for high resilience polyurethane foam

Selected Schiff bases of aromatic and alkylsubstituted aromatic ortho diamines are employed as cross-linking agents in the preparation of high resilience polyurethane foam.

Benzylated polyalkylene polyamines and uses thereof

본 발명은 벤질화된 폴리알킬렌 폴리아민 화합물을 포함하는 경화제 조성물을 제공한다. 아민-에폭시 조성물 및 상기 아민-에폭시 조성물로부터 제조된 물품을 또한 개시한다. The present invention provides a curing agent composition comprising a benzylated polyalkylene polyamine compound. Also disclosed are amine-epoxy compositions and articles made from the amine-epoxy compositions.

A kind of asymmetric latency polyurethane curing agent and preparation method thereof

本发明公开了一种非对称潜伏性聚氨酯固化剂及其制备方法，其分子结构既有噁唑烷基团又具有亚胺基团，兼具噁唑烷和亚胺双重官能团作用，具有粘度低，操作方便，反应速度适中，解封后几乎无气味等特点。其合成特征为可在一反应釜中完成羟乙基胺的环化、伯氨基的醛（酮）亚氨基化以及羧基和羟基的酯化反应，无需对中间产物的提纯分离等工序，工艺条件温和，无废气废渣排放，催化剂可回收重复使用。所用主要原料为对氨基苯甲酸（或酯）、二乙醇胺以及1‑13个碳的醛或酮。反应温度40‑150℃。该品既可作为聚氨酯材料的潜固化剂又可作为活性稀释剂使用。

LOW TEMPERATURE CURING COATING COMPOSITIONS

РОССИЙСКАЯ ФЕДЕРАЦИЯ ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) (19) RU (51) МПК C08G 18/08 C08G 18/10 C08G 18/12 C08G 18/64 C08G 18/78 C08G 18/80 C09J 175/06 (11) (13) 2019 128 021 A (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2019128021, 07.02.2018 (71) Заявитель(и): ППГ ИНДАСТРИЗ ОГАЙО, ИНК. (US) Приоритет(ы): (30) Конвенционный приоритет: 07.02.2017 US 62/455,778 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 09.09.2019 R U (43) Дата публикации заявки: 09.03.2021 Бюл. № 7 (72) Автор(ы): ЧЖОУ, Хунин (US), НАКАДЗИМА, Масаюки (US), ТАНЬ, Кар Тин (US) (86) Заявка PCT: (87) Публикация заявки PCT: WO 2018/148323 (16.08.2018) R U (54) КОМПОЗИЦИИ НИЗКОТЕМПЕРАТУРНЫХ ОТВЕРЖДАЕМЫХ ПОКРЫТИЙ (57) Формула изобретения 1. Клеевая композиция, содержащая эпоксид-содержащий компонент; блокированный полиизоцианатный отверждающий агент, содержащий блокирующую группу, полученную из блокирующего агента, содержащего альфа-гидроксиамид, сложный эфир или тиоэфир или их комбинацию; и катализатор латентного отверждения. 2. Клеевая композиция по п. 1, отличающаяся тем, что эпоксид-содержащий компонент присутствует в количестве от 50 до 95 мас. % в расчете на общую массу композиции. 3. Клеевая композиция по п. 1, отличающаяся тем, что эпоксидсодержащий компонент содержит пластификатор с эпоксидным покрытием. 4. Клеевая композиция по п. 1, отличающаяся тем, что блокированный полиизоцианатный отверждающий агент присутствует в количестве от 5 до 50% в расчете на общую массу композиции. 5. Клеевая композиция по п. 1, отличающаяся тем, что блокированный полиизоцианат содержит вторую блокирующую группу, полученную из блокирующего агента, содержащего спирт, фенольное соединение, третичный гидроксиламин, оксим, амин или их комбинацию. 6. Клеевая композиция по п. 1, отличающаяся тем, что блокирующий агент, Стр.: 1 A 2 0 1 9 1 2 8 0 2 1 A Адрес для переписки: 101000, Москва, ул. Мясницкая, 13, стр. 5, ООО ...

Moisture curable polyurethane composition comprising polyaldimine

내용없음 No content

Humidity curing polyurethane composition being accelerated by influence of heat

Curable composition comprises (a) at least one isocyanate group containing polymer; (b) at least one blocked amine comprising a blocked, hydrolytically activatable amino group or at least one reactive group, which comprises hydroxyl-, mercapto- or secondary amino-groups; and (c) at least one finely divided water-producing substance that is solid at room temperature, when heated to a minimum temperature of 50-100[deg] C. An independent claim is included for bonding of a substrate-S1 with a substrate-S2 comprising either applying the composition on the substrate-S1 and contacting the applied composition with the substrate-S2 within the open time of the composition, or applying the composition on the substrates-S1 and -S2, contacting the applied composition together within the open time of the composition and processing the composition by heating at 50-100 (preferably 90-130)[deg] C, where the substrate-S1 is same or different from -S2.

Moisture-reactive polyurethane composition with accelerated curing achieved by the action of heat

Die vorliegende Erfindung betrifft Zusammensetzungen, welche mindestens ein Isocyanatgruppen aufweisendes Polymer, mindestens ein spezielles blockiertes Amin sowie feinteilige Borsäure umfassen. Es resultieren härtbare Polyurethanzusammensetzungen mit guten Verarbeitungseigenschaften, insbesondere einer langen Offenzeit, die einerseits nach der Applikation bei genügender Wärmezufuhr sehr rasch aushärten, und die andererseits bei ungenügender oder ausbleibender Wärmezufuhr trotzdem aus- bzw. nachhärten, wobei als Ergebnis der beiden Aushärtungsverfahren ein Material mit vergleichbar guten mechanischen Eigenschaften erhalten wird.

Hot curing or heat-activated composition containing a surface-deactivated polyisocyanate

The present invention relates to curable compositions comprising at least one specific blocked amine, at least one surface-deactivated polyisocyanate that is solid at ambient temperature and optionally water or a water-producing substance. Compositions of this type are characterized by an extremely high storage stability as long as they are not heated. Hot curing compositions that cure with the action of heat can thus be produced. Heat-activated compositions can also be produced. When heat is applied the latter compositions are not cured but are activated so that they are able to cure under the influence of moisture. The curable compositions are particularly suitable for use as adhesives.

Process for the preparation of stabilized polyamines, stabilized polyamines with retarded reactivity and their use in the preparation of polyurethane

Gegenstand der Erfindung ist ein Verfahren zur Herstellung von durch Polyadduktumhüllung stabilisierten, festen Polyaminen mit retardierter Reaktivität, gekennzeichnet durch Umsetzung fester, feinteiliger Polyamine mit wasserunlöslichen, zwei- und/oder mehrfunktionellen Polyisocyanaten in einer Menge von 0,1 bis 25 Äquivalent-% NCO pro Äquivalent Amin, in einem flüssigen Medium aus di- und/oder mehrfunktionellen Polyolen und/oder Weichmachern und/oder gegebenenfalls Wasser (gegebenenfalls in Gegenwart von unpolaren oder wenig polaren Lösungsmitteln), zu einer Suspension von Polyaddukt-umhüllten, stabilisierten Polyaminen retardierter Reaktivität in dem flüssigen Medium. Gegebenenfalls können die stabilisierten Polyamine aus dem flüssigen Medium, z.B. durch Filtration, isoliert werden und dann nachträglich in Polyolen und/oder Polyaminen suspendiert werden. Erfindungsgegenstand sind auch Polyaddukt-umhüllte Polyamine nach obigem Verfahren in feinteiliger Form, vorzugsweise suspendiert in flüssigen oder niedrigschmelzenden, höhermolekularen Polyhydroxylverbindungen und/oder höhermolekularen Polyaminoverbindungen. Weiterer Erfindungsgegenstand ist die Verwendung der stabilisierten, bevorzugt in Weichmachern und/oder höhermolekularen, niedrigschmelzenden Polyhydroxylverbindungen und/oder höhermolekularen Polyaminen suspendierten, Polyadduktumhüllten Polyamine als gegenüber Isocyanaten reaktive Wasserstoffe aufweisende Reaktionskomponente in polyurethanbildenen Systemenen, gegebenenfalls unter Mitverwendung von niedermolekularen aromatischen und/oder (cyclo)aliphatischen Polyaminen und/oder Polyolen, gegebenenfalls Katalysatoren, üblichen Hilfs- bzw. Zusatstoffen, zusammen mit (bevorzugt höhermolekularen) Polyisocyanat(prepolymer)en, zur Herstellung von Polyurethanen. The invention relates to a process for the preparation of solid polyamines stabilized by a polyadduct coating with retarded reactivity, characterized by reacting solid, finely divided polyamines with water- ...

Polyureas as coatings

The polyureas resulting from curing polyfunctional isocyanates having at least three isocyanate groups with a N,N'-dialkylmethylenedianiline are broadly useful as coatings on the surface of objects made of metal, wood, glass, or plastic. The diamine N,N'-di(2-butyl)4,4'-methylenedianiline is a particularly useful diamine. Biurets are an especially desirable class of polyisocyanates for the polyureas of this invention, particularly those arising from polymethylene diisocyanates and aromatic diisocyanates.

Aldimines and compositions comprising aldamine

The present invention relates in a first consideration to aldimines of formula (I). Said aldimines are particularly suitable as latent hardeners in curable compositions, particularly compositions comprising one or two-component isocyanate groups. Due to the presence of the reactive group, they can be converted to compounds of the formulas (X) and (XII) comprising aldimine groups, implementing a further consideration of the present invention. The aldimines, or the compounds comprising aldimine groups, can be used primarily in adhesive and sealant materials, but also in coatings, and can be produced easily from readily available source materials, and have good thermal stability. The tertiary amino group thereof has a surprisingly low alkalinity and can in some cases have a catalytic effect in chemical reaction systems.

Aldimines comprising hydroxyl groups, and compositions containing aldimine

Die vorliegende Erfindung betrifft Aldimine der Formel (I), welche mindestens eine Hydroxylgruppe aufweisen, sowie härtbare Zusammensetzungen enthaltend diese Aldimine. Die Aldimine lassen sich auf einfache Art und Weise herstellen und sind breit einsetzbar. Die bei der Hydrolyse entstehenden Aldehyde lassen sich über die Hydroxylgruppen in ein Polymer einbauen und weisen tertiäre Aminogruppen auf, welche katalytisch wirken können.

Hardening compounds with reduced gas emission

Hardenable composition (I) comprises (a) at least a polyisocyanate; (b) at least an aldehyde or ketone blocked amine; and (c) at least a hydrazide of a carboxylic acid or sulfonic acid having a melting point of at least 100[deg] C, preferably at least 150[deg] C; where the amount of (b) is 0.3-1.1 equivalent of hydrazide group/equivalent of aldehyde or keto group, by which the amine group is blocked. Independent claims are included for: (1) a process for adhering a substrate S1 with a substrate S2 comprising either applying (I) on a substrate (S1) at less than 40[deg] C, contacting the applied substrate (S1) with the substrate (S2) within the open time of (I) and hardening the applied composition at less than 40[deg] C, or applying (I) on the substrates (S1) and (S2) at less than 40[deg] C, contacting the applied composition together within the open time of the composition, and hardening the composition at less than 40[deg] C; (2) a process for sealing the substrates (S1) and (S2), comprising applying (I) between the substrates (S1) and (S2), such that (I) is contacted with (S1) and (S2), at less than 40[deg] C, and hardening the applied composition at less than 40[deg] C, where the substrates (S1) and (S2) are different; (3) a process for coating the substrate (S1), comprising applying (I) on the substrate (S1) at less than 40[deg] C within the open time, and hardening the applied composition at less than 40[deg] C; (4) a hardened composition obtained by hardening (I) at less than 40[deg] C using water, e.g. in the form of water vapor, and subsequently warming at >= 80[deg] C, where the hardened composition comprises at least an amide compound of formula (W 1>-(C(=O)-NH-N=C(Q 1>)(Q 2>)) p) (d1), ((Q 1>)(Q 2>)C=N-NH-(C(=O)) m-C(=O)-NH-N=C(Q 1>)(Q 2>) (d2) or (X-(S(=O) 2-NH-N=C(Q 1>)(Q 2>)) q) (d3); and (5) an aldazide compound (e) of formula (W 1>-(C(=O)-NH-N=CH-C(R 1>)(R 2>)-Z 1>) p1) (e1) or (Z 1>-C(R 1>)(R 2>)-CH ...

Polyurethane composition comprising hydroxyaldimines

Composition (A) comprises at least one aldimine compound (I) and at least one polyisocyanate (P). Composition (A) comprises at least one aldimine compound of formula ((HX-E-N=CH) n-Y1) (I) and at least one polyisocyanate (P). n : 2-4; X : O, S, N-R10 or N-R11; either E : divalent 3-20C hydrocarbyl; or E+R11 : trivalent 3-20C hydrocarbyl, where E optionally contains heteroatoms in the form of ethereal oxygen or tertiary amine nitrogen; Y1 : n-valent 6-30C organic radical, which optionally contains N and/or O atoms in the form of tertiary amino groups, ether, ester, carbonate, amide, comprising urethane or urea groups; and R10 : monovalent 1-20C hydrocarbyl optionally containing at least one carboxylic acid ester, nitrile, nitro, phosphonic, sulfonic acid or sulfonic acid ester group. Independent claims are included for: (1) an addition product obtained from the reaction of (I) with a polyisocyanate (P); (2) an aldimine compound of formula ((HX-E-N=CH-C(R1)(R2)) n-Y3) (III); (3) bonding a substrate (S1) with a substrate (S2) comprising: application of the composition to a substrate (S1), and contacting the applied composition to a substrate (S2) within the open time of the composition; or application of the composition to substrates (S1) and (S2) and contacting the applied composition with each other within the open time of the composition; and (4) a cured composition obtained by exposing (A) to moisture. Either R1, R2 : monovalent 1-12C hydrocarbyl; or R1R2 : divalent 4-12C hydrocarbyl with one part being optionally substituted 5-8C, preferably 6C carbocyclic ring; and Y3 : n-valent 1-24C organic radical optionally containing N and/or O in the form of tertiary amino groups, ether, ester, carbonate, amide exhibits, urethane or urea groups.

Polyurethane compound containing asymmetric dialdimine

Composition (A) comprise at least one aromatic isocyanate group-bearing polyisocyanate and at least one dialdimine compound (I). Composition (A) comprise at least one aromatic isocyanate group-bearing polyisocyanate and at least one dialdimine compound of formula (X-(N=CH-C(Y 1>)(Y 2>)(Y 3>)) 2) (I). X : a diamine with two primary amino group after the removal of these two amino group; either Y 1>, Y 2> : univalent 1-12C-hydrocarbon; or Y 1>Y 2> : 4-20C-bivalent hydrocarbon, whose one part is optionally substituted by 5-8, preferably 6C carbocyclic rings; and Y 3> : a univalent hydrocarbon optionally exhibiting at least a heteroatom, preferably O in the form of ether, carbonyl or ester. Provided that: at least one of both primary amino group of the diamine is an aliphatic amino group and the two primary amino group of the diamine is either in the amount of the hydrogen atoms at the alpha position of the alpha -carbon atoms of the respective amino group, or in the amount of the hydrogen atoms at beta position of the beta -carbon atoms of the respective amino group. Independent claims are included for: (1) a hardening composition, obtained by either reacting (A) with water, preferably in the form of humidity, or mixing two components K1 and K2 optionally with water; (2) a process for adhering a substrate (S1) with a substrate (S2) comprising either applying (A) on the substrate (S1) and contacting substrate (S1) having the applied composition with the substrate (S2) within the open time of (A), or either applying (A) on the substrate (S1) and substrate (S2) and contacting the applied composition within the open time of (A), where the substrate (S2) is from same or different material of substrate (S1); (3) a process for sealing comprising applying (A) between a substrate (S1) and a substrate (S2) such that the composition contacts with the substrates (S1) and (S2); and (4) coating a substrate (S1) comprising applying (A) on a substrate S1 within ...

Liquid-applied waterproofing membrane for roofs comprising a trialdimine

The present invention describes a one-part moisture-curing liquid-applied waterproofing membrane comprising a polyurethane polymer and both a trialdimine and a dialdimine as blocked amine hardeners in a specific ratio range. The membrane has a low odour, a long shelf life stability, a low viscosity at low solvent content, a sufficiently long open time to allow hand application and cures fast to a solid elastic material. The liquid-applied waterproofing membrane is particularly suitable for roofing applications, possessing high strength, high elongation and good durability under outdoor wheathering conditions in a broad temperature range.

Liquid-applied waterproofing membrane for roofs comprising a long-chain aldimine

Liquid-applied waterproofing membrane comprising oxazolidine and aldimine

본 발명은 특정한 비율 범위로 폴리우레탄 중합체 및 차단 아민 경화제로서의 알디민 및 옥사졸리딘 둘 다를 포함하는 1부분 수분 경화성 액체 도포 방수막을 기술한다. 막은 적은 냄새, 긴 저장 안정성, 낮은 용매 함량에서의 낮은 점도, 충분히 긴 오픈 타임을 가져 손에 의한 도포를 허용하고 고체 탄성 재료에 신속히 경화한다. 액체 도포 방수막은 지붕공사 분야에 특히 적합하고, 광범위한 온도 범위에서 실외 기후 조건 하에 높은 강도, 높은 신장 및 우수한 내구성을 보유한다. The present invention describes a one part moisture curable liquid coated waterproof membrane comprising both aldimine and oxazolidine as a polyurethane polymer and a barrier amine curing agent in a range of specific proportions. The membrane has low odor, long storage stability, low viscosity at low solvent content, long enough open time to allow application by hand and cure quickly on solid elastic materials. The liquid-coated waterproofing membrane is particularly suitable for roofing applications and possesses high strength, high elongation and good durability under outdoor climatic conditions over a wide temperature range.

Flame retardant adhesives and sealants with improved mechanical properties

本发明涉及一种具有阻燃性能的湿固化性的组合物和其作为粘合剂、密封剂或涂料的用途。根据本发明的组合物含有10‑50wt％比例的至少一种湿反应性聚合物，30‑60wt％比例的至少一种沉淀的、表面涂覆的三水合铝和在优选的实施方案中高达25wt％的至少一种含磷化合物和高达20wt％的至少一种碳添加剂。本发明的湿固化性的组合物具有优异的阻燃性能，并且在固化后在高热水平下长时间保持耐久性。所述组合物在固化后还表现出非常好的机械性能，特别是在拉伸强度、断裂伸长率和拉伸剪切强度方面。

Two component polyurethane adhesive with substantially temperature dependent mechanical properties and high strength

Die vorliegende Erfindung betrifft eine zweikomponentige Polyurethanzusammensetzung enthaltend mindestens 55 Gewichts-% Polybutadienpolyole bezogen auf die Gesamtmenge aller Polyole mit einem mittleren Molekulargewicht von mindestens 500 g/mol, und mindestens einen latenten Härter, wobei das Verhältnis der Anzahl Reaktivgruppen des latenten Härters zur Anzahl der vorhandenen OH-Gruppen im Bereich von 0.02 bis 0.4 liegt. Die Zusammensetzung verfügt über eine lange Offenzeit, eine blasenfreie Aushärtung, eine sehr tiefe Glasübergangstemperatur, eine hohe Elastizität und eine überraschend hohe Festigkeit, welche über einen weiten Temperaturbereich sehr konstant sind. Weiterhin haftet sie sehr gut auf metallischen und nichtmetallischen Substraten, wobei sie auf glasigen thermoplastischen Kunststoffen kaum Spannungsrisse verursacht. Sie ist somit hervorragend geeignet als struktureller elastischer Klebstoff für Verklebungen, welche in einem breiten Temperaturbereich beansprucht werden. The present invention relates to a two-component polyurethane composition containing at least 55% by weight of polybutadiene polyols based on the total amount of all polyols having an average molecular weight of at least 500 g / mol, and at least one latent curing agent, wherein the ratio of the number of reactive groups of the latent curing agent to the number of existing OH groups in the range of 0.02 to 0.4. The composition has a long open time, a bubble-free cure, a very low glass transition temperature, a high elasticity and a surprisingly high strength, which are very constant over a wide temperature range. Furthermore, it adheres very well to metallic and non-metallic substrates, where it hardly causes stress cracks on glassy thermoplastics. It is thus extremely suitable as a structural elastic adhesive for bonding, which are claimed in a wide temperature range.

Moisture curable polyurethane composition comprising polyaldimine

A moisture curable polyurethane composition comprising a polyaldimine represented by the formula (I): Y(̵N = CH - X) n wherein X is an aryl group having from 6 to 15 carbon atoms, Y is a divalent or trivalent hdyrocarbon group having from 2 to 15 carbon atoms or a divalent or trivalent polyoxyalkylene group having a molecular weight of from 70 to 6000, and n is an integer of 2 or 3, and a polyisocyanate and/or a polyurethane prepolymer having 2 or more isocyanate groups; and a water proof material, flooring material, sealing material, wall covering material and paint comprising said composition and various fillers, are disclosed. The polyurethane composition has excellent storage stability and quick rate of curing in application.

Polyurea compositions and the coating of substrates with such compositions

Polyaldimine derivatives

This invention relates to a novel polyaldimine, preparation process of the polyaldimine, moisture curable polyurethane composition containing the polyaldimine and use of the composition. Polyaldimine of this invention is represented by the formula (I): wherein R¹, R² and R³ are a halogen atom, hydrogen atom, alkoxy group having 4 or less carbon atoms or an alkyl group having 5 or less carbon atoms, and may be the same or different; R⁴ is a hydrogen atom or a methyl group; Y is -N=CH-C(R⁵ )₃ or -N=CH-C(CH₃ )₂-CH₂-O-CO-R⁶ wherein R⁵ is an alkyl group having 4 or less carbon atoms, R⁶ is an alkyl group, anilino group, benzylamino group or an alkylamino group having 16 or less carbon atoms; and ℓ is an integer of 1 or 2, m is an integer of 1 to 3, and n is an integer of 0 to 300. Polyaldimine is prepared by condensation of the corresponding aromatic polyamine and aldehyde. A moisture curable polyurethane composition is prepared from the above polyaldimine and organic polyisocyanates. Sealing materials, wall covering materials, water proof materials and flooring materials can be prepared by blending thixotropic agents or fillers with the polyurethane composition. These materials have very good storage stability and are rapidly cured by atmospheric moisture and cured polyurethane resin having excellent properties can be obtained.

Coating compositions containing polyisocyanates and aldimines which have improved storage stability

The present invention relates to a coating composition having an improved pot life without a corresponding increase in dry time when cured under ambient conditions which contains a) a polyisocyanate component, b) an aldimine based on the reaction product of a polyamine having 2 or more primary amino groups with an aldehyde corresponding to the formula: O=CHCH(R1)(R2) wherein R1 and R2 may be the same or different and represent optionally substituted hydrocarbon radicals, or R1 and R2 together with the .beta.-carbon atom form a cycloaliphatic or heterocyclic ring and c) 0.001 to 5 weight percent, based on the weight of components a) and b), of a tin(IV) compound which is a catalyst for the reaction between isocyanate groups and hydroxyl groups, wherein components a) and b) are present in an amount sufficient to provide an equivalent ratio of isocyanate groups to aldimine groups of 0.5:1 to 20:1.

Coating compositions containing aldimines and polyisocyanates

The present invention is directed to coating compositions which have long pot lives and may be rapidly cured under ambient conditions wherein the binder contains a) a polyisocyanate component containing i) 5 to 100% by weight of a monoallophanate and ii) 0 to 95% by weight of another polyisocyanate adduct, and b) an aldimine based on the reaction product of diamino dicyclohexyl methane with an aldehyde corresponding to the formula: O=CHCH(R.sub.1)(R.sub.2) wherein R 1 and R 2 may be the same or different and represent optionally substituted hydrocarbon radicals, or R 1 and R 2 together with the β-carbon atom form a cycloaliphatic or heterocyclic ring.

Coating compositions containing polyisocyanates and aldimines which have improved storage stability

The present invention relates to a coating composition having an improved pot life without a corresponding increase in dry time when cured under ambient conditions which contains a) a polyisocyanate component, b) an aldimine based on the reaction product of a polyamine having 2 or more primary amino groups with an aldehyde corresponding to the formula: O═CHCH(R.sub.1)(R.sub.2) wherein R 1 and R 2 may be the same or different and represent optionally substituted hydrocarbon radicals, or R 1 and R 2 together with the β-carbon atom form a cycloaliphatic or heterocyclic ring and c) 0.1 to 15 weight percent, based on the total weight of the coating composition, of a water-adsorbing zeolite, wherein components a) and b) are present in an amount sufficient to provide an equivalent ratio of isocyanate groups to aldimine groups of 0.5:1 to 20:1.

Coating compositions based on aldimines and polyisocyanates containing uretdione groups

The present invention is directed to coating compositions which have long pot lives and may be rapidly cured under ambient conditions to provide coatings with improved optical properties and resistance to yellowing, such coating compositions containing as binder a) a polyisocyanate component containing i) 5 to 100% by weight of a polyisocyanate adduct containing uretdione groups and ii) 0 to 95% by weight of a monomeric polyisocyanate, an NCO prepolymer or a polyisocyanate adduct other than i), and b) an aldimine based on the reaction product of a polyamine having 2 or more primary amino groups with an aldehyde corresponding to the formula: O═CHCH(R.sub.1)(R.sub.2) wherein R 1 and R 2 may be the same or different and represent optionally substituted hydrocarbon radicals, or R 1 and R 2 together with the β-carbon atom form a cycloaliphatic or heterocyclic ring, wherein components a) and b) are present in an amount sufficient to provide an equivalent ratio of isocyanate groups to aldimine groups of 0.5:1 to 20:1.

Polymeric imine functional compositions and their use in film-forming compositions

Novel imine functional copolymers are provided containing a plurality of groups of the structure: where R 1 is hydrogen or methyl; R 2 is hydrogen or an alkyl group having from about 1 to about 10 carbon atoms; R 3 is an alkyl or aryl group having from about 1 to about 10 carbon atoms, or R 3 is bonded to R 2 and forms part of a five- or six-membered ring; and Y is a divalent linking group having from about 3 to about 15 carbon atoms. The composition is useful in film-forming compositions curable at ambient temperature and above.

Aldimines and compositions comprising aldimine

Aldimines of formula (I) that are particularly suitable as latent hardeners in curable compositions, particularly compositions having one or two-component isocyanate groups. Due to the presence of the reactive group, they can be converted to compounds of formulas (X) and (XII) having aldimine groups. The aldimines, or the aldimine compounds, can be used primarily in adhesive and sealant materials, but also in coatings, and can be produced easily from readily available source materials, and have good thermal stability. The tertiary amino group thereof has a surprisingly low alkalinity and can in some cases have a catalytic effect in chemical reaction systems.

Aldimines and compositions comprising aldimine

Aldimino containing compounds obtained from a reaction of aldimines of formula (I) with a compound that bears at least one reactive group that can enter into addition reactions with an HX group of an aldimine of formula I. The compounds containing aldimine groups can be used primarily in adhesive and sealant materials, but also in coatings, and can be produced easily from readily available source materials, and have good thermal stability. The tertiary amino group thereof has a surprisingly low alkalinity and can in some cases have a catalytic effect in chemical reaction systems.

Aldimines comprising hydroxyl groups, and compositions containing aldimine

The present invention relates to aldimines of the formula (I) which have at least one hydroxyl group, and to curable compositions comprising these aldimines. The aldimines can be prepared in a simple manner and are widely usable. The aldehydes formed in the hydrolysis can be incorporated into a polymer via the hydroxyl groups and have tertiary amino groups which can act catalytically.

Curable compositions having less volatilization

The invention particularly relates to curable compositions comprising at least one polyisocyanate, at least one amine that is blocked by means of aldehyde or ketone, and at least one carboxylic acid hydrazide or sulfonic acid hydrazide which has a minimum melting point of 100°C, especially at least 150°C. Surprisingly, after being cured using moisture at room temperature and when being heated to increased temperatures, significantly fewer volatile components of such compositions volatilize than in the corresponding compositions that do not contain said hydrazide.

Hydroxyaldimine-containing polyurethane composition

A composition that includes aldimines of Formula (I). The composition can be a two-component polyurethane composition. The composition can have a long open time, but build up an early strength quickly, and in the cured state can have high tensile strength and a high modulus of elasticity. The composition can be odorless or at least low-odor before, during and after curing.

Polyurethane composition comprising hydroxyaldimines

The invention relates to compositions comprising aldimines of formula (I). Such compositions are, in particular, two-component polyurethane compositions, characterised, in particular, by a long open time, which however, have a rapid onset of early hardening and have a high tensile resistance and modulus of elasticity in the hardened state. An additional advantage is that the compositions can be easily produced, which are being non-odorous or at least low-odour during and after curing.

Polyurethane composition comprising hydroxyaldimines

本发明涉及具有式(I)的醛亚胺的组合物。这类组合物特别是双组分的聚氨酯组合物。其尤其特征在于长的晾置时间，虽然如此但迅速地建立起早期强度，并在固化的状态下具有高拉伸强度和高弹性模量。而且，这是一个重要的优势，使得组合物能够实现在固化之前、期间和之后无气味或者至少低气味。