ВОДНЫЕ ПОЛИУРЕТАНОВЫЕ ДИСПЕРСИИ, ПОЛУЧЕННЫЕ ИЗ ГИДРОКСИМЕТИЛСОДЕРЖАЩИХ ПОЛИЭФИРПОЛИОЛОВ НА ОСНОВЕ СЛОЖНОГО ЭФИРА, ПОЛУЧЕННЫХ ИЗ ЖИРНЫХ КИСЛОТ

Изобретение относится к дисперсии полимерных частиц в непрерывной водной фазе, к способу ее получения и композиции клея, герметика или покрытия, ее содержащей. Диспергированные частицы в такой дисперсии содержат полиуретановую смолу, которая представляет собой продукт реакции между полиизоцианатом, по меньшей мере, одним отвердителем и, по меньшей мере, одним материалом, имеющим эквивалентную массу от, по меньшей мере, 400 вплоть до 15000, и группы, реагирующие с изоцианатом, где указанный материал включает, по меньшей мере, один гидроксиметилсодержащий полиэфирполиол. При этом гидроксиметилсодержащий полиэфирполиол представляет собой продукт реакции между жирной кислотой, имеющей гидроксиметильную группу и содержащей от 12 до 26 атомов углерода, или сложным эфиром такой гидроксиметилированной жирной кислоты и соединением полиольного, гидроксиламинового или полиаминового инициатора, в среднем имеющим, по меньшей мере, 2,0 гидроксильные, первичные амино- и/или вторичные аминогруппы/молекула ...

ОТТАЛКИВАЮЩИЕ ЗЕМЛЮ И ГРЯЗЬ ПОКРЫТИЯ ИЗ ПОРОШКОВОГО МАТЕРИАЛА

Изобретение относится к вариантам отталкивающих землю и грязь покрытиям из порошкового материала, содержащим анионные фтористые поверхностно-активные вещества, и способу получения покрытий такого типа. Предложена отталкивающая грязь панель, содержащая подложку и нанесенное на эту подложку покрытие из порошкового материала, сформированное из смеси, содержащей связующее вещество, содержащее полимерную смолу, содержащую по меньшей мере две функциональные группы, которая по существу не содержит групп фторзамещенного углеводорода; сшивающее средство, которое реагирует с функциональными группами полимерной смолы; и состав поверхностно-активного вещества, который по существу не содержит растворителей и содержит анионное фтористое поверхностно-активное вещество. Анионное фтористое поверхностно-активное вещество присутствует в количестве от 0,05 до 4 мас.% от общей массы состава покрытия из порошкового материала. Технический результат – получение грязеотталкивающих покрытий без ухудшения прочности ...

БЫСТРОРЕАГИРУЮЩАЯ КОМПОЗИЦИЯ ДЛЯ ПРИГОТОВЛЕНИЯ ТВЕРДОЙ ПОЛИУРЕТАНОВОЙ ПЕНЫ НИЗКОЙ ПЛОТНОСТИ

Изобретение относится к быстрореагирующей композиции, используемой для получения жесткого пенополиуретана низкой плотности. Описана быстрореагирующая композиция, используемая для получения жесткого пенополиуретана низкой плотности, она получена путем смешивания следующих компонентов в соответствующей пропорции по массе: высокоактивный сложный материал:пенообразователь:изоцианат - 100:(8~28):(105~155); причем высокоактивный сложный материал получен путем смешивания следующих компонентов в соответствующей пропорции по массе: смешанный полиол:стабилизатор пены:катализатор:вода:дополнительный ингредиент - 100:(0,5~3,5):(1,0~10):(0,5~3,0):(0~5); причем пенообразователь относится к смеси циклопентана и HFC-365 mfc, или смеси циклопентана и HFC-245 fa, или смеси циклопентана, HFC-365 mfc и HFC-245 fa; причем смешанный полиол состоит из сложного полиэфирполиола с гидроксильным числом 100-450 мг КОН/г, полиола Манниха с гидроксильным числом 160-750 мг КОН/г и простого полиэфирполиола, где сложный ...

СЛОЖНЫЕ ПОЛИЭФИРПОЛИОЛЫ ДЛЯ ПОЛУЧЕНИЯ ЖЕСТКИХ ПЕНОПОЛИУРЕТАНОВ

Настоящее изобретение относится к получению сложных полиэфирполиолов, используемых для получения жестких пенополиуретанов или пенополиизоциануратов. Описан сложный полиэфирполиол, получаемый путем взаимодействия: b1) от 10 до 70% мол. по меньшей мере одного соединения, выбранного из группы, состоящей из терефталевой кислоты, диметилтерефталата, полиэтилентерефталата, фталевого ангидрида, фталевой кислоты и изофталевой кислоты, b2) от 0,8 до 3,2% мол. триглицерида жирной кислоты, b3) от 10 до 70% мол. диола, выбранного из группы, состоящей из этиленгликоля, диэтиленгликоля и полиэтиленгликоля, и b4) от 5 до 50% мол. простого полиэфирполиола с функциональностью более 2 и гидроксильным числом от 150 до 1250 мг КОН/г, полученного путем алкоксилирования этиленоксидом, причем используют по меньшей мере 200 ммолей компонента b4) на килограмм сложного полиэфирполиола, и причем сумма компонентов b1)-b4) составляет 100% мол. Также описан способ получения жестких пенополиуретанов или жестких пенополиизоциануратов ...

СПОСОБ ПОЛУЧЕНИЯ СЛОЖНЫХ ПОЛИЭФИРПОЛИОЛОВ С КОНЦЕВЫМИ ВТОРИЧНЫМИ ГИДРОКСИЛЬНЫМИ ГРУППАМИ

Изобретение относится к способу получения сложных полиэфирполиолов с концевыми вторичными гидроксильными группами, включающему стадию взаимодействия содержащего концевые карбоксильные группы сложного полиэфира с эпоксидом общей формулы (1), в которой R1 означает алкильный или арильный остаток, и взаимодействие осуществляют в присутствии катализатора по меньшей мере с одним атомом азота в молекуле, где содержащий концевые карбоксильные группы сложный полиэфир, который обладает кислотным числом от ≥ 25 до ≤ 400 мг КОН/г и гидроксильным числом ≤ 5 мг КОН/г, получают с использованием от ≥ 1,03 до ≤ 1,90 моль карбоксильных групп или эквивалентов карбоксильных групп кислотного компонента на моль гидроксильных групп спирта. Изобретение также относится к сложному полиэфирполиолу с концевыми вторичными гидроксильными группами и к композиции на основе сложного полиэфирполиола, предназначенной для получения полиуретанов, а также к полиуретановому полимеру, полученному путем превращения полиизоцианата ...

ЖЕСТКИЕ ПЕНОПОЛИУРЕТАНЫ

Настоящее изобретение относится к жестким пенополиуретанам, способу их получения, а также к полиольной смеси для их получения. Жесткий пенополиуретан получают путем превращения А) органических или модифицированных органических полиизоцианатов или их смесей, В) одного или нескольких простых полиэфиров сложных эфирполиолов, D) при необходимости простых полиэфиролполиолов, Е) при необходимости антипиренов, F) одного или нескольких вспенивающих агентов, G) катализаторов и Н) при необходимости других вспомогательных компонентов и/или добавок. Указанный компонент В) является продуктом превращения а1) от 15 до 40% масс. одного или нескольких полиолов со средней функциональностью от 2,5 до 8, а2) от 2 до 30% масс. одной или нескольких жирных кислот и/или одного или нескольких сложных моноэфиров жирных кислот и а3) от 35 до 70% масс. пропиленоксида. Полиольный компонент, используемый для получения жестких пенополиуретанов, отличается высокой растворимостью в нем физического вспенивающего агента, ...

НЕ СОДЕРЖАЩИЙ РАСТВОРИТЕЛЬ ДВУХКОМПОНЕНТНЫЙ ПОЛИУРЕТАНОВЫЙ КЛЕЙ С НИЗКИМ СОДЕРЖАНИЕМ СВОБОДНОГО МОНОМЕРА МДИ

Изобретение раскрывает способ приготовления не содержащего растворителя двухкомпонентного полиуретанового клея с низким содержанием свободного мономера МДИ (дифенилметандиизоцианата). Полиуретановый клей получают на основе полиэфир-полиольного компонента A и полиуретанового форполимера (компонент B) на основе МДИ. Компонент A получают реакцией эстерификации между двухосновным спиртом и бинарной кислотой. Компонент B получают реакцией между мономером МДИ и многоатомным спиртом при молярном отношении NCO/OH=3-5,5:1. Для получения компонента B сначала осуществляют обезвоживание многоатомного спирта до содержания воды (в % мас.) меньше 0,05%. Затем добавляют мономер МДИ и регулятор молекулярной массы. Нагревают до температуры 70-80°C до тех пор, пока гидроксил не прореагирует полностью. Добавляют тримерный катализатор для реакции тримеризации до завершения реакции. Изобретение отличается простотой, низкими производственными издержками, низким содержанием свободного мономера МДИ в полученном ...

СВЯЗУЮЩИЕ ВЕЩЕСТВА С ВЫСОКИМ ГИДРОКСИЛЬНЫМ ЧИСЛОМ И СОДЕРЖАЩИЕ ИХ КОМПОЗИЦИИ ПРОЗРАЧНОГО ЛАКА С ХОРОШИМИ ОПТИЧЕСКИМИ СВОЙСТВАМИ И ХОРОШЕЙ СТОЙКОСТЬЮ К ЦАРАПАНЬЮ И К ДЕЙСТВИЮ ХИМИЧЕСКИХ РЕАГЕНТОВ

Настоящее изобретение относится к гидроксифункциональному связующему веществу с гидроксильным числом ≥180, определенным согласно DIN 53240, и параметром растворимости SP ≤10. Также настоящее изобретение относится к способам получения указанного выше связующего вещества, к композиции прозрачного лака, его включающей, и к субстрату, покрытому такой композицией прозрачного лака. Технический результат - получение связующих веществ для композиций прозрачного лака с высокой долей твердых веществ, которые приводят к образованию покрытий с высокой стойкостью к царапанью, химической стойкостью и хорошими оптическими свойствами. 5 н. и 13 з.п. ф-лы, 1 табл., 4 пр.

РЕАКТИВНЫЕ ТЕРМОПЛАВКИЕ АДГЕЗИВЫ С УЛУЧШЕННОЙ АДГЕЗИЕЙ

Изобретение относится к влагоотверждаемым термоплавким клеевым композициям, содержащим от 50 до 95 масс. % продукта взаимодействия (i) полукристаллического полиола, (ii) полиизоцианата и (iii) первичного аминосилана; и от 5 до 50 масс. % силан-реактивного пластификатора, а также к способу их получения и к применению. Силан-реактивная термоплавкая композиция по изобретению характеризуется отсутствием изоцианатных мономеров, обеспечивает хорошую адгезию к различным субстратам, быстрое схватывание и высокую прочность в сшитом состоянии. 5 н. и 16 з.п. ф-лы, 10 табл.

ЖЕСТКИЙ ПЕНОПОЛИУРЕТАНОВЫЙ МАТЕРИАЛ И СПОСОБ ЕГО ИЗГОТОВЛЕНИЯ

Настоящее изобретение относится к жесткому пенополиуретановому материалу для изоляции в условиях сверхнизких температур, а также к способу его получения. Жесткий пенополиуретановый материал включает 30-50 мас.ч. многофункционального простого полиэфирного полиола, 30-50 мас.ч. многофункционального сложного полиэфирполиола, 50-80 мас.ч. толуолдиизоцианата, 50-80 мас.ч. полиметиленполифенилполиизоцианата, 15-30 мас.ч. композиции вспомогательной пенообразующей добавки и 5-20 мас.ч. непрерывного стекломата. Композиция вспомогательной пенообразующей добавки содержит 10-20 вес.ч. сополимера полиэфирполидиметилсилоксана, 30-40 вес.ч. пентафторпропана, 30-40 вес.ч. транс-1-хлор-3,3,3-трифторпропена, 1-3 вес.ч. низкомолекулярного аминного катализатора и 1-3 вес.ч. оловоорганического катализатора. Способ изготовления жесткого пенополиуретанового материала включает: (1) взвешивание сырья; (2) смешивание сырьевых материалов, за исключением цельного стекломата; (3) распределение смеси на ровной поверхности ...

Соединение с органической аминовой солью, имеющее анион в качестве донора CO, и его использование в качестве вспенивающего агента

Изобретение относится к вспенивающему агенту, содержащему соединение соли органического амина формулы (I) или смесь соединений солей органического амина формулы (I). Формула (I): A[B](I), где A- анион - источник CO, имеющий -n валентность, где n=1, 2 или 3, Bпредставляет собой или содержит ион аммония с валентностью +1 и/или один или более катионов органического амина (B), в котором каждый катион (B) имеет группу -NRRH и/или группу -NRH- в количестве m, где m=1-5, 00 мас.% до 40 мас.%. Также предложены способы ...

НЕВОДНАЯ ЖИДКАЯ КОМПОЗИЦИЯ ДЛЯ НАНЕСЕНИЯ ПОКРЫТИЯ

... 1. Неводная жидкая композиция для нанесения покрытия, содержащая:a) полиол,b) полиизоцианатный отвердитель,c) одно или несколько тиолсодержащих соединений,d) металлосодержащий катализатор отверждения для ускорения реакции присоединения изоцианатных групп и гидроксильных групп,e) основание, имеющее величину pKa по меньшей мере 7 и не взаимодействующее с изоцианатными группами со снижением основности, иf) одно или несколько содержащих кислотные группы соединений,где одно или несколько тиолсодержащих соединений содержится в количестве, обеспечивающем молярное отношение тиольных групп к атомам металла металлосодержащего катализатора отверждения, составляющее 1 или выше, и где основание содержится в молярном количестве, меньшем, чем молярное количество тиольных групп, и где молярное отношение кислотных групп и групп основания составляет 1:1 или выше.2. Композиция для нанесения покрытия по п. 1, где основание содержится в молярное количестве, равном или превышающем молярное количество атомов ...

ПРИМЕНЕНИЕ СОДЕРЖАЩИХ КАРБОДИИМИДЫ КОМПОЗИЦИЙ ДЛЯ РЕГУЛИРОВАНИЯ ДОЛГОВЕЧНОСТИ ПРИ ХРАНЕНИИ

... 1. Применение композиции, содержащей- по меньшей мере один полиол и- по меньшей мере один карбодиимид формулы (I)причем m=1-40,R представляет собой алкилен с 6-18 атомами углерода или циклоалкилен с 6-18 атомами углеродаи Rпредставляет собой алкил с 1-4 атомами углерода, а также остаток -(CH)-O-[(CH)-O]-R, причемh=1-3, k=1-3, g=5-20 и при этом Rпредставляет собой H или алкил с 1-4 атомами углерода, для регулирования долговечности при хранении (жизнеспособности).2. Применение по п. 1, отличающееся тем, что в карбодиимиде формулы (I) m=10-30,R представляет собой алкилен с 6-18 атомами углерода или циклоалкилен с 6-18 атомами углерода,Rпредставляет собой алкил с 1-4 атомами углерода или остаток -(CH)-O-[(CH)-O]-R,где h=1-3, k=1-3, g=10-12 и причем Rпредставляет собой H или алкил с 1-4 атомами углерода.3. Применение по п. 1, отличающееся тем, что эта композиция содержит смесь из нескольких карбодиимидов формулы (I).4. Применение по п. 1, отличающееся тем, что R в карбодиимидах формулы (I) обозначаетилиRпредставляет ...

УЛУЧШЕННЫЕ КОМПОЗИЦИИ КРАСОК, СОДЕРЖАЩИЕ ДОБАВКУ ДЛЯ СНИЖЕНИЯ ЭФФЕКТА ПОТЕРИ ВЯЗКОСТИ, ВЫЗЫВАЕМОЙ ДОБАВКОЙ ОКРАШИВАЮЩИХ ВЕЩЕСТВ

... 1. Композиция водорастворимой латексной краски, содержащая ! (а) основную краску, ! (b) по меньшей мере один ассоциативный загуститель, ! (с) окрашивающее соединение и ! (d) по меньшей мере 0,1% в расчете на сухую массу композиции блоксополимера ABLBA. ! 2. Композиция по п.1, где полимер ABLBA-типа включает компонент А, содержащий гидрофобную группу А; компонент В, содержащий гидрофильный полимер В; и компонент L, содержащий связывающую группу. ! 3. Композиция по п.1, где полимер ABLBA-типа включает компонент А, включающий мономерное звено, содержащее фрагмент, выбранный из группы, состоящей из алкильной группы, арильной группы или алкиларильной группы; компонент В, содержащий полиэтиленоксидный полимер или полиэтилен-полипропиленоксидный сополимер; и компонент L, выбранный из одного или более следующих связывающих звеньев: диангидридного звена и диизоцианатного звена. ! 4. Композиция по п.3, где компонент А включает одно или более из следующего: линейные С10-С22 спирты или разветвленные ...

ИЗОЦИАНАТНО-ЭПОКСИДНАЯ ВСПЕНИВАЕМАЯ СИСТЕМА

ТЕРМОПЛАСТИЧЕСКИЙ ПОЛИУРЕТАНОВЫЙ ТЕРМОПЛАВКИЙ КЛЕЙ

АДГЕЗИВНАЯ КОМПОЗИЦИЯ НА ОСНОВЕ РАСТВОРИТЕЛЯ C ВЫСОКИМ СОДЕРЖАНИЕМ ТВЁРДЫХ ВЕЩЕСТВ И СПОСОБ ЕЁ ИЗГОТОВЛЕНИЯ

НИЗКОЭМИССИОННЫЙ ИНГИБИТОР ПОДВУЛКАНИЗАЦИИ ДЛЯ ПОЛИУРЕТАНОВОЙ ПЕНЫ

ВЫБОРОЧНО СНИМАЕМЫЕ ПОКРЫТИЯ ДЛЯ МЕТАЛЛИЧЕСКИХ И ПЛАСТИКОВЫХ ПОДЛОЖЕК

БЛОКИРОВАННЫЙ ПОЛИИЗОЦИАНАТ, СОДЕРЖАЩИЙ БИУРЕТОВЫЕ ГРУППЫ, И ЕГО ПРИМЕНЕНИЕ В КОМПОЗИЦИИ ДЛЯ ПОКРЫТИЙ

... 1. Блокированный полиизоцианат, содержащий биуретовые группы, полученный способом, включающим A) взаимодействие аддукта полиизоцианата, который a) получен из алифатического и/или циклоалифатического диизоцианата, b) имеет изоцианатную функциональность по меньшей мере 2,5 и c) содержит изоциануратные группы, с агентом биуретизации для введения в указанный полиизоцианат биуретовых групп и B) взаимодействие биуретсодержащего полиизоцианата с блокирующим агентом, выбранным из группы, включающей ди-C1-С12-алкил- и/или алкоксиалкилмалонаты и С1-С12-алкил- и/или алкоксиалкиловые эфиры ацетоуксусной кислоты, причем полиизоцианат имеет функциональность блокированного изоцианата по меньшей мере 4. 2. Блокированный полиизоцианат, содержащий биуретовые группы, по п.1, где указанный аддукт имеет изоцианатную функциональность по меньшей мере 2,8. 3. Блокированный полиизоцианат, содержащий биуретовые группы, по п.2, где указанный аддукт имеет изоцианатную функциональность по меньшей мере 3,0 и не более ...

ПРЕПРЕГИ И ПОЛУЧАЕМЫЕ ИЗ НИХ ПРИ ПОНИЖЕННОЙ ТЕМПЕРАТУРЕ ФОРМОВАННЫЕ ИЗДЕЛИЯ

... 1. Препреги, в основном состоящие из:A) по меньшей мере одной волокнистой основы иB) в качестве матричного материала по меньшей мере одной содержащей уретдионовые группы порошкообразной полиуретановой композиции с высокой реакционной способностью, которая содержит в основном:a) по меньшей мере один содержащий уретдионовые группы отвердитель иb) при необходимости по меньшей мере один полимер с функциональными группами, реакционноспособными по отношению к NCO-группам,c) от 0,1 до 5% масс. по меньшей мере одного катализатора, выбранного из группы, включающей четвертичные соли аммония и/или четвертичные соли фосфония с анионами галогенов, гидроксидов, алкоголятов или органических или неорганических кислот в качестве противоионов,а такжеd) от 0,1 до 5% масс. по меньшей мере одного сокатализатора, выбранного из группы, включающей:d1) no меньшей мере один эпоксид и/илиd2) по меньшей мере один ацетилацетонат металла, и/или ацетилацетонат четвертичного соединения аммония, и/или ацетилацетонат четвертичного ...

ПОЛИУРЕТАНМОЧЕВИНА И СПОСОБ ЕЕ ПОЛУЧЕНИЯ

Настоящее изобретение относится к полиуретанмочевинам, которые могут применяться в качестве заменителей стекла, например в качестве прозрачных крыш, ветровых, задних или боковых стекол в автомобилях или самолете, в оптических областях, таких как линзы для офтальмологического применения и т.п., а также к способам их получения. В одном варианте полиуретанмочевина содержит продукт реакции: (А) по меньшей мере, одного (цикло)алифатического полиизоцианатного форполимера, имеющего содержание NCO групп от около 4 до около 50% и среднюю функциональность от около 2 до около 3, представляющего собой продукт реакции (1) по меньшей мере, одного (цикло)алифатического полиизоцианата и (2) по меньшей мере, одного органического соединения, которое содержит, по меньшей мере, около двух гидроксильных групп и имеет молекулярную массу от около 100 до около 4000; с (В) изоцианат-реактивным компонентом, содержащим: (1) одно или более соединений ароматического диамина, содержащих две первичные ароматические аминные ...

СПОСОБ СКЛЕИВАНИЯ С ФОЛЬГОЙ

ЖЕСТКИЕ ПОЛИУРЕТАНОВЫЕ ПЕНОМАТЕРИАЛЫ

... 1. Жесткий полиуретановый пеноматериал, который можно получить по реакцииa) полиизоцианатов сb) соединениями, содержащими по меньшей мере два атома водорода, которые являются реакционноспособными по отношению к изоцианатным группам, в присутствииc) вспенивающих средств иd) по меньшей мере одного огнезащитного средства,где соединения, содержащие по меньшей мере два атома водорода, которые являются реакционноспособными по отношению к изоцианатным группам b), содержат по меньшей мере один простой полиэфир полиола bi) и по меньшей мере один сложный полиэфир полиола bii), и огнезащитное средство d) содержит вспененный графит di).2. Жесткий полиуретановый пеноматериал по п. 1, в котором вспененный графит di) используют в количестве, составляющем от 2 до 25 мас.% в пересчете на массу компонентов b), c) и d).3. Жесткий полиуретановый пеноматериал по п. 1, в котором простой полиэфир полиола bi) используют в количестве, составляющем от 3 до 20 мас.% в пересчете на массу компонентов b), c) и d).4.

ПОЛИУРЕТАНОВЫЙ/ПОЛИИЗОЦИАНУРАТНЫЙ ЖЕСТКИЙ ПЕНОПЛАСТ, СПОСОБ ЕГО ПОЛУЧЕНИЯ И ЛАМИНАТ, СОДЕРЖАЩИЙ УКАЗАННЫЙ ПЕНОПЛАСТ

... 1. PUR-/PIR-Жесткий пенопласт, полученный взаимодействием органического полиизоцианатного компонента с полиольным компонентом, содержащем соединения с водородными атомами, реакционно-способными по отношению к изоцианатным группам, при индексе от 100 до 400, в присутствии подходящих вспомогательных веществ и добавок, а также порообразователя и сопорообразователя, при этом полиольный компонент содержит, по меньшей мере, один алифатический сложный полиэфирполиол, который, наряду с фрагментами, производными от адипиновой кислотой, содержит также фрагменты, производные от глутаровой кислоты, янтарной кислоты и/или себациновой кислоты. 2. PUR-/PIR-Жесткий пенопласт по п.1, при этом индекс лежит в области от 180 до 400. 3. Способ получения PUR-/PIR-жесткого пенопласта по п.1 или 2, при котором органический полиизоцианатный компонент распыляется с полиольным компонентом, содержащем соединение с водородными атомами, реакционноспособными по отношению к изоцианатным группам, при индексе от 100 до ...

ПОЛИУРЕТАНЫ, ПОЛУЧЕННЫЕ ИЗ ГИДРОКСИМЕТИЛСОДЕРЖАЩИХ ЖИРНЫХ КИСЛОТ ИЛИ АЛКИЛОВЫХ ЭФИРОВ ТАКИХ ЖИРНЫХ КИСЛОТ

... 1. Способ получения полиуретана, включающий образование реакционной смеси, содержащей по меньшей мере один полиизоцианат, жирную кислоту, имеющую в среднем по меньшей мере 0,8 гидроксиметилгруппы на молекулу, и по меньшей мере одно соединение полиола, полиамина или аминоспирта, и отверждение реакционной смеси с образованием полиуретанового полимера.2. Способ по п.1, в котором жирная кислота содержит 10-26 углеродных атомов.3. Способ по п.2, в котором жирная кислота представляет собой смесь материалов, выбранных из материалов, имеющих структуры А1, А2, А3, А4 и А5,где А1 соответствует формуле (I)в которой m представляет собой число >3; n≥0, (m+n) составляет от 8 до 22, особенно, от 11 до 19;А2 соответствует формуле (II)в которой v представляет собой число >3, r и s представляют собой каждый число ≥0, причем (v+r+s) составляет от 6 до 20, особенно от 10 до 18;А3 соответствует формуле (III)в которой v, каждый r и s являются такими, как определено выше, t представляет собой число ≥0, (v+r+s ...

Selbstvernetzendes Harz

Urethanisierungsreaktionsverfahren

Bioabbaubare Polyesterurethane, Verfahren zu ihrer Herstellung sowie ihre Verwendung

The invention relates to biodegradable linear polyester urethanes and to biodegradable cross-linked polyester urethanes obtained from linear polyester urethanes by virtue of the fact that they are cross-linked by diisocyanate bridges. By varying the degree of crosslinking, the physical, chemical and biological properties of the inventive cross-linked polyester urethane can be adjusted and the biodegradability thereof can also be varied considering that biological degradability occurs more slowly as the degree of crosslinking increases. The invention also relates to a method for producing the inventive polyester urethanes and to the use thereof as films, rubber bodies, containers, packaging materials and in galenical preparations, as adhesives, adhesive strips and the like. The invention also relates to polymer blends containing the inventive polyurethanes.

Bioabbaubare Polyesterurethane, Verfahren zu ihrer Herstellung sowie ihre Verwendung

REACTIVE POLYMERS FOR DERMAL AND TRANSDERMAL THERAPY

Lagerstabile Polyurethan-Prepregs und daraus hergestellte Formkörper aus Polyurethanzusammensetzung mit flüssigen Harzkomponenten

Die Erfindung betrifft lagerstabilen Polyurethan-Prepregs und daraus hergestellte Formkörper aus Polyurethanzusammensetzung mit flüssigen Harzkomponenten, bevorzugt flüssigen Polyolen.

NEW POLYESTER MANUFACTURING PROCESS

... 1282422 Polyesters IMPERIAL CHEMICAL INDUSTRIES Ltd 11 Feb 1970 [12 Dec 1968] 59088/68 Heading C3R Polyesters of low acid number are made by heating an aliphatic dicarboxylic acid, alone or in admixture with other carboxylic acids, with an aliphatic diol, in proportions to give an OH: COOH ratio of between 1À0:1 and 1À1:1, in the presence of a stannous salt of an aliphatic monocarboxylic acid in an amount to provide less than 55 p.p.m. of tin in the total reaction mixture. The reaction mixture may also include aromatic dicarboxylic acids, aliphatic diamines or aminoalcohols, monohydric alcohols, monobasic carboxylic acids and polyhydric alcohols. In examples, stannous octoate is used as a catalyst in the polycondensation of (1) adipic acid, propylene glycol and coconut oil fatty acid; (2) ethylene glycol, propylene glycol and adipic acid and (3) ethylene glycol, diethylene glycol and adipic acid.

METHOD OF INCREASING THE VELOCITY OF ESTERIFICATION IN THE PRODUCTION OF POLYHYDROXY POLYESTERS

... 1429735 Hydroxy polyesters BAYER AG 11 Jan 1974 [13 Jan 1973] 01389/74 Heading C3R A polyester having a hydroxyl number of 30 to 500 is derived from a polybasic carboxylic acid or anhydride and a polyhydric alcohol component comprising 2-methyl-propane-1,3- diol which may be mixed with up to 90 mol per cent, based on the total quantity of polyhydric alcohol component, of other polyols. The examples described polyesters prepared from, in addition to 2-methyl-propane-1,3-diol, one or more of the following: adipic acid, phthalic acid anhydride, maleic acid anhydride, hexahydrophthalic acid anhydride, trimethylolpropane, ethylene glycol, hexane-1,6-diol and propylene- 1,2-glycol.

VAPOUR-PERMEABLE SHEET MATERIAL

... 1327573 Microporous polyurethanes SANYO CHEMICAL INDUSTRIES Ltd 6 April 1971 8892/71 Heading C3R [Also in Division B2] A vapour-permeable sheet material is obtained by a process comprising (I) coating a substrate with a solution of a substantially linear polyurethane in a solvent which is a non-solvent for the substrate, (II) removing the solvent from the coated substrate by treating with a liquid which is miscible with the solvent but is a non-solvent for the polyurethane and the substrate, and (III) drying the coated substrate, the polyurethane containing unts of (A) a hydroxylterminated polyester having a molecular weight of at least 2,000, (B) diphenyl methane diisocyanate or a mixture thereof with a minor amount of at least one organic diisocyanate and (C) a glycol consisting mainly of ethylene glycol, the molar amount of the organic diisocyanate being substantially equivalent to or up to 10% in excess of the total molar amount of the polyester and the glycol, the molar ratio of the ...

Process for the production of synthetic plastics from vinyl or vinylidene polymers and polyurethanes

Homo- or co-polymers of vinyl chloride, vinyl acetate and/or vinylidene chloride are mixed with a preformed polyurethane based on aliphatic or araliphatic polyisocyanates and polyesters of M.W. 400 to 4000 at least 5 weight per cent thereof being a mixed polyester of a dicarboxylic acid and a mixture containing at least 3 mol per cent of each of two polyhydric alcohols. The polymethane may also contain structural components derived from other polyesters, polyesteramides, polyethers, polyacetals or polythioethers or may be used in admixture with other polyurethanes. Lists are given of suitable polyester components and polyisocyanates. Water or polyhydric alcohols, amines or aminoalcohols, which may contain ether, ester, amide, urethane, urea or acetal groupings, may be used as chain extenders in production of the polyurethane. The mixture may also include plasticizers or fillers. In the examples dibutyl tin mercaptide (stabilizer); dioctyl phthalate, diphenyl tolyl phosphate, adipic acid ...

Process for the production of modified polyester moulding materials

A microporous polyurethane sheet structure permeable to water vapour is prepared from a solution having a solids content of 5-30% by weight and a Ford viscosity of 10-180 seconds (4 mm. outflow nozzle at spray temperature) and comprising: (a) a reaction product free of-NCO groups, of an OH containing polyester or polyesterurethane of M.W. 500-10,000 and from 90-115% of the quantity equivalent to the total of reactive hydrogen atoms present in the polyester or polyurethane of an organic polyisocyanate, 0.05-0.35 gram equivalents of the organic polyisocyanate being used to make 100 grams of the reaction product, (b) 3-26% by weight of an organic polyisocyanate calculated on (a), and (c) an organic solvent of B.P. below 120 DEG C., by spraying the solution on to a substrate through a stream of gas at not more than 80 DEG C. below the B.P. of the solvent so that the sprayed solution is broken up into drops and 50-95% of the solvent is evaporated before reaching the substrate to form a non-melting ...

Pyridine derivatives

Metal-pyridines interaction products are prepared by the interaction of an alkali metal, Mg, Al or mixture thereof with pyridine or an alkyl pyridine or mixture thereof wherein the interacting mixture is maintained so that its specific conductivity is at least 200 microhmo. The interaction may be initiated, preferably rapidly, in known manner, during which initiation the specific conductivity varies considerably, and said initiation should be completed prior to control of the interaction by maintaining the specific conductivity at at least 200 microhmo. The conductivity is preferably measured by a pair of electrodes, preferably Pt. electrodes, inserted inside the interaction vessel and dipping into the bulk of the interaction mixture. Maintenance of the specified specific conductivity may be effected by regulation of temperature, rate of addition of further reactants as diluents or addition of initiator and agitation of the interaction to ensure a uniform mixture. The products of the invention ...

Improvements in or relating to the manufacture of polymeric materials

A process for the manufacture of expanded synthetic rubber-like materials by reacting polyesters with polyisocyanates and water in the presence of a tertiary amine catalyst is characterized in that the reactants used in preparing the polyester comprise from 1.92 to 18 molar percentage, based on the total dicarboxylic acid incorporated, of at least one compound containing more than two isocyanate-reactive groups. The polyester is preferably prepared from such dicarboxylic acids and glycols as to be liquid at normal temperature. Suitable compounds containing more than two isocyanate-reactive groups are polyhydric alcohols such as glycerol, pentaerythritol, sorbitol, mannitol, hexanetriol, polyallyl alcohol and triethanolamine, polycarboxylic acids such as tricarballylic acid and pyromellitic acid and compounds with mixed functional groups such as diethanolamine and dihydroxystearic acid. The reaction may be effected in the presence of emulsifying agents such as turkey red oil, oleic acid ...

Polyisocyanate alkyd resin compositions

Foams are produced by reacting a polyisocyanate, water and an alkyd resin derived from a dicarboxylic acid, a trihydric alcohol (with or without up to 40 mol. per cent of the total polyhydric alcohol of an alcohol having more than three hydroxy groups), and a dicarboxylic acid or hydroxy acid having from 15-20 carbon atoms or a dimer fat acid used in a proportion of 1-50 mol. per cent of total acid component. The hydroxy to carboxy group ratio in the alkyd components should be between 1.5 to 1 and 3.5 to 1 and the acid number of the resin 0.5 to 100. The quantity of water should be from 0.1 to 3.0 per cent by weight and the quantity of diisocyanate from 35 to 130 per cent by weight of the resin. The water may be that present in the resin. Long chain difunctional acids referred to are hydroxy palmitic, hydroxy stearic, ricinoleic and dilinoleic acid. Twenty-two examples are given of suitable alkyd resins using trimethylol propane, trimethylol ethane and pentaerythritol as alcohols, phthalic ...

FLUSSIGER EINBRENNLACK AUF DER BASIS VON OLFREIEN POLYESTERN

WASSERVERDUNNBARER, LUFTTROCKNENDER LACK

GEL COATS FROM PU ALSO UNITS ABSTENTION POLYESTER PU HYBRID RESIN FORM COMPOSITIONS DERIVED FROM ALIPHATIC ISOCYANATES

COMPOSITION, WHICH IS TO USE AS ADHESIVE WITH THE INSTALLATION OF VEHICLE WINDOWS USEFUL

COLÖSERFREIE, SELF-BRANCHED ONES POLYURETHANE DISPERSIONS

ABSPALTERFREIER PU POWDER COATING WITH LOW BURNING TEMPERATURE

ANTISTATIC PU

NICHTHALOGENES, FLAME RETARDING, THERMOPLASTIC PU

UVINTERLACE-CASH URETHANE (METH) ACRYLATE OF POLYMERS

ABSPALTERFREIE PULVERLACKVERNETZER

TWO-COMPONENT SYSTEMS FOR THE PRODUCTION OF FLEXIBLE COATINGS

REACTIVE PU COMPOSITION

FLUSSIGER BAKING ENAMEL ON THE BASIS OF OLFREIEN POLYESTERS

AQUEOUS BONDING AGENT COMBINATION, A PROCEDURE FOR YOUR PRODUCTION AND YOUR USE

WITH POLYESTERS VINYLÄTHER CHAIN-EXTENDED URETHANE OLIGOMERE ONES.

PROCEDURE FOR THE PRODUCTION OF SINGLE COMPONENT POLYURETHANE BAKING ENAMELS.

STRAHLENHAERTBARE MAKROMERE ON THE BASIS OF (METH) ACRYLIC-FUNCTIONAL POLYESTERS AND THEIR USE.

POWDERED COAT MEANS.

ON PU RESINS BASING WATER-DILUTE-CASH PRIMERS, THE SHORT EVAPORATION TIMES AND DRYING TIMES EXHIBITING.

POWDER COATING AND ITS USE

AMINE CATALYSTS WITH LOW SMELL FOR PU OF BLOCK SOFT FOAM MATERIALS BASED ON POLYESTER POLYOLE

DETENTION ADHESIVES ON THE BASIS OF RADIATIONHARDENABLE, (METH) ACRYLGRUPPENHALTIGEN POLYESTERS.

POLYACETALHARZZUSAMMENSETZUNG

TWO-COMPONENT COATING MEANS

WASSERVERDUNNBARER, AIR-DRYING LACQUER

SULFONATE GROUPS ABSTENTION POLYESTERPOLYOLE

PU CONTAINING a POLYESTER POLYOLE WITH 2,4-DIETHYL-1,5-PENTANDIOL UNITS

FOAM-STABILIZING ADDITIVE AND IN ITS PRESENCE MANUFACTURED POLYURETHAN-FOAM

Procedure for the controlling of the conversion of Pyridin or alkylpyridine with a metal reactive opposite Pyridin or alkylpyridine

LACQUERS, A PROCEDURE FOR YOUR PRODUCTION AND YOUR USE

BIOLOGICALLY DEGRADABLE ONES OF POLYMERS, PROCEDURES FOR THEIR PRODUCTION AS WELL AS THEIR USE FOR THE PRODUCTION OF BIODEGRADABLE MOLDED ARTICLES

CHEMICAL BONDING AGENT FOR FOUNDRY FORMS

BIOLOGICALLY DEGRADABLE ONES OF POLYMERS, PROCEDURES FOR THEIR PRODUCTION AS WELL AS THEIR USE FOR THE PRODUCTION OF BIODEGRADABLE MOLDED ARTICLES

Self-branched bonding agents for baking enamels

PRINTABLE FILM AND MARK-REJECTING COATING COMPOSITION

Procedure for the production of plastics from PU and Vinylpolymerisaten

Polyurethane comprising formulations with isocyanate functionality

A urethane group-containing reactive polyisocyanate composition is disclosed which contains not more than 1 wt% of monomeric starting di-isocyanate based on the total weight of said polyisocyanate composition, having an NCO value in the range 0.1-15%, and wherein said composition comprises urethane groups and allophanate groups and wherein the ratio of allophanate groups over urethane groups is between 0.05 and 100.

Composition for preparing a degradable polyol polyester, process for obtaining a polyol polyester, an elastomer, foams, paints and adhesives, and a degradable polyol polyester foam

Two-component systems for producing flexible coatings

The invention relates to two-component coating systems for producing flexible coatings. Said coating systems comprise polyurethane prepolymers having allophanate structures, in addition to amino-functional polyaspartic acid esters as hardeners.

Polyester polyol, polyurethane obtained therefrom, and rigid polyurethane foam

Antistatic or semi-conductive polyurethane elastomers

A polyurethane elastomer showing desirable conductivity properties comprises at least 0.3 percent by weight of an aggregated particulate carbon black, having a particle size of less than or equal to 100 nanometers, that forms a continuous conductive pathway within the polyurethane elastomer. The polyurethane elastomer may exhibit a surface resistivity ranging from 1 x 10 to 1 x 10 ohms. It may be made by first preparing an isocyanate-terminated prepolymer containing the carbon black, the prepolymer having a volume resistivity of from 1 x 10 to 1 x 10 ohms, and then reacting the isocyanate-terminated prepolymer with an isocyanate-reactive component. The proportion of the prepolymer ensures that it forms a continuous phase in the final elastomer.

Method for producing storage-stable polyurethane prepregs and moldings produced therefrom

The invention relates to a method for producing storage-stable polyurethane prepregs and moldings produced therefrom and moldings produced therefrom (composite components), which can be obtained by a direct melt impregnation method of woven fabrics and laid scrim using reactive polyurethane compositions.

Modified diphenylmethane diisocyanate-based adhesives

Adhesive compositions using modified diphenylmethane diisocyanate are disclosed along with methods and articles using the adhesive compositions. The adhesive compositions are especially suited for making flexible laminates for use in food packaging.

Improved agricultural soil heating processes using aromatic thermoplastic polyurethane films

Electromechanical transducer comprising a polyurethane polymer with polyester and/or polycarbonate units

The present invention relates to an electromechanical transducer comprising a dielectric elastomer with contact by a first electrode and a second electrode, wherein the dielectric elastomer comprises a polyurethane polymer. In this case, the polyurethane polymer comprises at least one polyester and/or polycarbonate unit. The invention also relates to a process for producing such an electromechanical transducer, to the use of the dielectric elastomer used and also to an electrical and/or electronic apparatus comprising an electromechanical transducer according to the invention.

Water-based two-layer coating systems based on urethane, the use thereof and substrates coated with them

Hydrophilic coating

A hydrophilic, lubricious coating for a substrate includes a first coating layer having a cross-linked polyurethane or polyurea complexed with poly(ethylene oxide) formed by reacting a mixture of an isocyanate, a polyol or polyamine, and a poly(ethylene oxide), and a second coating layer having a cross-linked polyurethane or polyurea complexed with polyvinylpyrrolidone formed by reacting a mixture of an isocyanate, a polyol or polyamine, and a polyvinylpyrrolidone. The first layer is substantially covered by the second layer and the second layer at least partially interpenetrates the first layer. The coating is provided by applying the first coating layer, curing to provide a cross-linked polyurethane or polyurea/poly(ethylene oxide) coating, applying the second layer, and curing to provide a cross-linked polyurethane or polyurea/polyvinylpyrrolidone coating.

PROCESS FOR PRODUCING SYNTHETIC RESIN FOAM, BLOWING AGENT, AND PREMIX

Polymer material

MODIFIED POLYHYDROXY COMPOUNDS USED FOR POLYURETHANE FOAMS

REACTIVE POLYMERS FOR DERMAL AND TRANSDERMAL THERAPY

THERMOSET DRAWABLE COATING COMPOSITIONS

TRANSPARENT COVERING COATING OF NON-RIGID POLYURETHANE WITH MISTING INHIBITING ACTION FOR TRANSPARENT GLASS OR PLASTIC SUBSTRATES

Items of clothing having shape memory

A method for making items of clothing having shape memory, the method comprising: synthesizing ( 31 ) a shape memory polyurethane; subjecting ( 34 ) the shape memory polyurethane to wet spinning, dry spinning, melt spinning or multi-component spinning in order to produce shape memory fibers; and knitting or weaving ( 36 ) the shape memory fibers to form the item of clothing.

Prepregs and molded bodies produced from same

The invention relates to prepregs and composite components produced therefrom (mouldings), obtainable by the use of powdery reactive polyurethane compositions.

Method for formulating a reactive polyurethane emulsion

A method for production of a reactive polyurethane emulsion for use in impregnating and coating a textile fabric includes reacting polyols alone or in combination with at least one of diols and triols with a substoichiometric amount of diisocyanates so as to form medium-viscosity, OH-terminated prepolymers. The prepolymers are mixed with an external emulsifier. At least one of a diisocyanate, a triisocyanate and a polyisocyanate are added so as to bring about a crosslinking of the prepolymers.

Method for preparing an allophanate, allophanate, and low-viscosity composition containing the allophanate

A process for the preparation of an allophanate of one or more identical or different isocyanates, compositions obtained by the process, and uses of the compositions are disclosed. The process comprises reacting an isocyanate with at least one monoalcohol comprising an ether or polyether functional group in the presence of a bismuth-comprising catalyst and a metal compound as co-catalyst.

Natural oil polyols in elastomers for tires

Prepolymers having active NCO groups are disclosed. The prepolymers are the reaction product of at least one polyisocyanate and a polyhydric component which comprises at least one dimer fatty derivative diol or diamine that is a natural oil based polyol or polyamine which includes the derivative of at least one dimer fatty acid. Polyurethane and polyurea elastomer obtained from the prepolymers are also disclosed. Also disclosed are methods of manufacturing polyurethane or polyurea treaded tires.

Aqueous coating systems based on physically drying urethane acrylates

The invention relates to radiation curable coating systems on the basis of aqueous polyurethane dispersions, to a method for the production thereof, to the use of the coating systems as paints and/or adhesives, and to objects and substrates provided with said paints and/or adhesives.

Curable composition with rubber-like properties

Low viscosity, radiation curable compositions have been developed that produce plastics with silicone rubber-like properties. These compositions have also been shown to give great adhesion to plastics. The combination of an ethylenically unsaturated oligomer with di- or polythiol compound, reactive diluents and a radical initiator will produce these properties. These materials can find use in many areas such as: Electronics packaging, displays, conformal coatings, seals, gaskets, fiber optics coatings, and golf ball coatings.

Biodisintegratable composite foils

The use of an aqueous polyurethane dispersion adhesive is described for producing biodisintegratable composite foils where at least two substrates are adhesive-bonded to one another with use of the polyurethane dispersion adhesive, where at least one of the substrates is a biodisintegrable polymer foil. At least 60% by weight of the polyurethane is composed of diisocyanates, polyesterdiols, and at least one bifunctional carboxylic acid selected from dihydroxycarboxylic acids and diaminocarboxylic acids.

Multiple-layer golf ball

Disclosed herein is a multi-layer golf ball having a soft outer cover. The golf ball has an inner cover layer with a Shore D hardness of 60 or more, and an outer cover with a Shore D hardness of 55 or less, and more preferably 50 or less. In a particularly preferred form of the invention, the outer cover comprises one or more polyurethane materials. The golf ball of the invention has exceptionally soft feel and high spin rates on short shots of 80 yards or less, and particularly, 40 yards or less, while maintaining good distance and average spin on full shots.

Improved coating composition for wind turbine blades

The present application discloses a wind turbine blade having on the outer surface thereof a polyurethane-based coating including a polyurethane binder prepared from polyol(s) having an average functionality of ≧2.0 and <8.0; at least 50% (w/w) of the polyols have aliphatic polyester segments included therein and have a Mw of 300-3,000 g/mol; and polyisocyanate(s) having an average functionality of <3.0; at least 50% (w/w) of the polyisocyanate(s) are selected from: (i) polyisocyanates having aliphatic polyester segments included therein, and having a molecular weight of 500-3,000 g/mol and a functionality of ≧2.0 and <3.0; (ii) polyisocyanates of the allophanate type having a Mw of 250-2,000 g/mol and a functionality of ≧2.0 and <3.0; and (iii) polyisocyanates of the uretdion type having a Mw of 250-2,000 g/mol and a functionality of ≧2.0 and <3.0. The application also discloses corresponding coating compositions and a method for coating a substrate.

Mixtures containing 1,1,1,3,3,3-hexafluorobutene and 1-chloro-3,3,3-trifluoropropene

The present invention relates to mixtures of 1,1,1,3,3,3-hexafluorobutene (1336mzzm) and 1-chloro-3,3,3-trifluoropropene (1233zd). The blends are useful as blowing agents for polymer foam, solvents, aerosol propellants and heat transfer media.

Polyurethane materials comprising carbon nanotubes

The invention relates to semicrystalline polyurethane (PU) compositions which have been filled with carbon nanotubes (CNTs) and have improved electrical properties, and which are obtainable on the basis of water-based polyurethane-CNT mixtures. The invention further relates to a process for producing the polyurethane compositions, in which water-based polyurethane latices are mixed with carbon nanotubes dispersed in water. The invention further relates to films produced by pressurized injection moulding processes or processing of casting solutions.

Two component polyurethane coating compositions comprising isocyanurate compositions from bis(isocyanatomethyl) cyclohexane and from aliphatic diisocyanates

The present invention provides two-component polyurethane compositions comprising, as one component, polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane or, preferably, a mixture of two or more of these, and of the isocyanurate of hexamethylene diisocyanate (HDI trimer), and, as the other component, a mix of a soft polyol having a hydroxyl functionality of from 2.5 to 5.0 and a molecular weight of from 500 to 3,000, and a hard polyol. Such compositions provide coatings, especially clear topcoats, which exhibit excellent scratch and mar and solvent resistance in addition to a good balance of hardness and flexibility without the need for increasing the volatile organic content (VOC) of the compositions. Also provided are compositions of a polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane with soft polyol which have lower VOCs.

Coating Compositions and Articles Coated Therewith

The present invention relates to a binder useful in coating end uses. The binder preferably includes an aqueous polymer dispersion and a vinyl polymer. The binder is useful in packaging coatings, including coatings for use on food or beverage cans, or a portion thereof.

Polylactic acid-based decorative body

A polylactic acid-based decorative body including a polylactic acid resin-containing substrate, a polylactic acid resin-containing adhesion layer provided on the substrate, and at least one functional layer that is formed on the adhesion layer by applying an acrylic urethane coating composition, wherein in the acrylic urethane coating composition, the molar ratio of OH groups in an acrylic resin to NCO groups in a polyfunctional isocyanate is 1:4 to 1:6.

Method for producing polyesters and co-polyesters from lactones

The invention relates to a method for producing polyesters and co-polyesters from lactones

Method for producing a foam composite element

The invention relates to a process for the production of a foam composite element, comprising the steps of providing a facing, applying adhesion promoter, and applying a foam layer comprising polyurethane and/or polyisocyanurate to the adhesion promoter, characterised in that the adhesion promoter consists of at least one compound selected from the group consisting of polyether polyol (B.1), polymer polyol (B.2), polyurea dispersion (B.3), polyester polyol (B.4) and PIPA polyol (B.5). The invention relates further to the use of at least one compound selected from the group consisting of polyether polyol, polymer polyol and polyurea dispersion as adhesion promoter in the production of foam composite elements, as well as to foam composite elements produced by the process according to the invention.

Branched poly(trimethylene ether) polyols

Disclosed is branched poly(trimethylene ether)polyols prepared from the acid catalyzed polycondensation reaction of 1,3-propanediol, and at least one triol comonomer selected from 1,1,1-tris(hydroxymethyl)ethane and 1,1,1-tris(hydroxymethyl)propane. Also disclosed is a branched poly(trimethylene ether)polyol with an equivalent hydroxyl functionality of about 2.1 to about 3.2 and a M n of about 200 to about 6000. The polyols are useful in the preparation of polyurethane rigid and flexible foams.

Photopolymer formulation having different writing comonomers

The invention relates to a photopolymer formulation comprising matrix polymers, writing monomers, and photo initiators, comprising a combination of at least two different writing monomers. The invention further relates to the use of the photopolymer formulation for producing optical elements, in particular for producing holographic elements and images, to a method for producing the photopolymer formulation and to a method for illuminating holographic media made of the photopolymer formulation.

Etch resistant clearcoat

A crosslinked coating composition formed from polyurethane polyols and blocked or unblocked polyisocyanates. The polyisocyanates, in particular, comprise at least bis(isocyanatomethyl) cyclohexane. The coating is substantially free from ester functionality that forms a contiguous part of the network backbone. A clearcoat formed from the described components and having a majority of urethane bonds is very resistant to environmental etch damage.

Polyurethane Dispersions and Methods of Making and Using Same

The presently disclosed and claimed inventive concept(s) relates generally to polyethylene terephthalate (“PET”) polymers, digested oligomeric derivatives of PET (“dPET”), functionalized oligomeric derivatives of dPET (“dfPET”), and polyurethane dispersions (“PUD”) made from or incorporating dfPET therein.

Composition containing specific carbamate type compounds suitable for producing polyurethane foams

Compositions suitable for producing polyurethane foams which include at least an isocyanate component, a polyol component, a catalyst catalyzing formation of a urethane or isocyanurate bond, and at least one compound containing at least one structural element of formula (I)

Silane-functional polyesters in moisture-curing compositions based on silane-functional polymers

A silane-functional polyester of formula (I): wherein Y is an n-valent residue of a polyester P which is solid at room temperature and terminated by hydroxy groups, after removal of n hydroxy groups; R 1 is a linear or branched, monovalent carbon residue having 1 to 12 carbon atoms, optionally having one or more C—C multiple bonds and/or having optionally cycloaliphatic and/or aromatic portions; R 2 is an acyl residue or a linear or branched, monovalent hydrocarbon residue having 1 to 12 carbon atoms, optionally having one or more C—C multiple bonds and/or having optionally cycloaliphatic and/or aromatic portions; R 3 is a linear or branched, divalent hydrocarbon residue having 1 to 12 carbon atoms, optionally having cyclic and/or aromatic portions, and optionally having one or more heteroatoms; the index a has a value of 0, 1 or 2; and the index n has a value of 1 to 3.

Composite Materials Comprising Aggregate And An Elastomeric Composition

A composite material comprises aggregate and an elastomeric composition. The elastomeric composition comprises the reaction product of an isocyanate component and an isocyanate-reactive component. The isocyanate component comprises a polymeric isocyanate, and optionally, an isocyanate-prepolymer. The isocyanate-reactive component comprises a hydrophobic polyol and a chain extender having at least two hydroxyl groups and a molecular weight of from about 62 to about 220. The chain extender is present in the isocyanate-reactive component in an amount of from about 1 to about 20 parts by weight based on 100 parts by weight of the isocyanate-reactive component. The aggregate may be rock, crumb rubber, and/or glass. The composite material has excellent physical properties and may be formed underwater, used in various locations, and used in various applications, such as for pavement, revetments, etc. Methods of forming and using the composite material and systems for forming the elastomeric composition are also disclosed.

Photochromic Polyurethane Laminate

A photochromic polyurethane laminate wherein the photochromic polyurethane layer of the laminate has been crosslinked with a isocyanate-active prepolymer using a crosslinking agent. The crosslinking agent is formulated to have at least three functional groups that are reactive with functional groups of the polyurethane or of the isocyanate-active prepolymer. A method of making the photochromic polyurethane laminate includes steps of causing the crosslinking.

Polishing pad

A polishing pad generates very few scratches on a surface of a polishing object, and is excellent in planarization property. The polishing pad has a high polishing rate and is excellent in planarization property. The polishing pad grooves become very little clogged with abrasive grains or polishing swarf during polishing and, even when continuously used for a long period of time, the polishing rate is scarcely reduced.

Polishing pad, manufacturing method therefor, and method for manufacturing a semiconductor device

A polishing pad having a polishing layer comprising a thermoset polyurethane foam, wherein the thermoset polyurethane foam contains, as raw material components, an isocyanate component, and active-hydrogen-containing compounds, and the active-hydrogen-containing compounds comprise one or more polyol compounds (each) having two or more functional groups, and a monool compound having one functional group.

Articles Comprising Reinforced Polyurethane Coating Agent

Articles, such as absorbent articles, are described, comprising a coating or film, for example applied to superabsorbent polymer particles, the coating or film containing a polyurethane polymer material, containing polyurethane polymers with covalently bonded modified silica-containing material.

PROCESS FOR PRODUCING POLYOL DISPERSIONS

The present invention relates to polyol dispersions comprising at least one polyol and at least one polymer particle mixture comprising at least one thermoplastic polymer (P) and at least one block copolymer (B), wherein the block copolymer (B) has at least one block which is compatible with the thermoplastic polymer (P) and at least one block which is compatible with the polyol, a process for producing such polyol dispersions, their use for producing polyurethanes and a process for producing polyurethanes. 1. A process for producing a polyol dispersion , comprising:(a) heating a composition (I) comprising at least one thermoplastic polymer (P) of polystyrene, substituted polystyrenes, polyacrylates, polymethacrylates, polyolefins, polyvinylchloride, polyacrylonitrile, polyesters, polyamides and copolymers of said polymers, at least one polyol selected from the group consisting of polyetherols and polyesterols, and at least one block copolymer (B) selected from the group consisting of polyester-polyether block copolymers, polyamide-polyether block copolymers, polystyrene-polyether block copolymers and polyethylene-polyether block copolymers, comprising at least one block which is compatible with the thermoplastic polymer (P) and at least one block which is compatible with the polyol and forming a composition (II) comprising said at least one block copolymer (B), and (b) cooling the composition (II).2. The process according to claim 1 , wherein said at least one thermoplastic polymer (P) is selected from the group consisting of polystyrene claim 1 , polyethylene and polyethylene terephthalate.3. The process according to claim 1 , wherein the at least one block copolymer (B) is used in an amount of from 0.1 to 10% by weight claim 1 , based on the total weight of the thermoplastic polymer (P) used.4. The process according to claim 1 , comprising stirring.5. A process for producing a polyurethane claim 1 , comprising reacting a polyol dispersion obtainable by a process ...

Polyurethane/Polyolefin Blends with Improved Strain and Scratch Whitening Performance

A composition, preferably a halogen-free, flame retardant composition, comprising in weight percent based on the weight of the composition: A. 1 to 90% TPU polymer, B. 1 to 90% polyolefin polymer, preferably a polar polyolefin polymer, C. 1 to 60% phosphorus-based, intumescent flame retardant, D. 0.5 to 25% liquid phosphate modifier, e.g., bis-phenol-A-polyphosphate, and E. Optional additives and/or fillers. The compositions exhibit excellent strain and scratch whitening performance in combination with excellent burn performance, good flexibility and tensile properties, and good fabrication extrusion characteristics including improved surface smoothness.

Biobased Polyester Diols And Polyols From High Molecular Weight Polyhydroxyalkanoates

Methods for producing biobased hydroxyl-terminated polyester polymers are described wherein molten-dispersed or hydrocarbonaceous fluid-dispersed phase polyhydroxyalkanoate polymers are reacted with a difunctional hydroxylated insertion compound at a sufficient temperature and time to depolymerize the starting polyester polymers to provide hydroxyl-terminated reaction products of reduced molecular weight. The difunctional hydroxylated insertion compound can be at least one of diol, aminoalcohol, and polyhydroxyalcohol. The use of catalyst may be required, reduced or eliminated. The hydroxyl-terminated reaction product is at least one of hydroxyl-terminated polyhydroxyalkanoate. A method for making polyurethanes further is described wherein the hydroxyl-terminated reaction product is reacted with polyfunctional isocyanate to form a polyurethane product. Products that include the hydroxyl-terminated reaction product or polyurethane also are described.

Seat support

A seat support and a method for obtaining same includes a support body made from polymeric materials derived from castor oil, a padding positioned on said body, and a coating that covers the padding. The padding includes at least one layer of foam made at least in part from a component derived from renewable sources and/or of natural origin like palm oil, castor oil, soybean oil, colza oil, or in general a vegetable oil, and it can include a layer and/or insert made from gel obtained by adding in dispersion with a polyolic and or isocyanic component, possible particles of cork and possible compatibilizing agents to maintain the continuity of the polymeric characteristics with the coating and promote sticking. The coating includes a polymer formed from castor oil. The seat support according to the present invention is therefore environmentally-friendly, biodegradable, easy to recycle and/or dispose of.

Microorganisms and methods for the production of caprolactone

The invention provides non-naturally occurring microbial organisms containing caprolactone pathways having at least one exogenous nucleic acid encoding a butadiene pathway enzyme expressed in a sufficient amount to produce caprolactone. The invention additionally provides methods of using such microbial organisms to produce caprolactone by culturing a non-naturally occurring microbial organism containing caprolactone pathways as described herein under conditions and for a sufficient period of time to produce caprolactone.

Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making The Same

The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.

SLIGHTLY MODIFIED PREPOLYMERS AND THEIR USES

An isocyanate-terminated prepolymer C having an NCO content of from ≧26% by mass to ≦31.0% by mass is obtainable from the reaction of an isocyanate composition A having a viscosity at 25° C. of from ≧60 mPas to ≦800 mPas, comprising from ≧25% by mass to ≦60% by mass MDI and from ≧40% by mass to 75% by mass pMDI, wherein the sum of the amounts of those components is ≦100% by mass, with a bifunctional polyester ether polyol B having an OH number of ≧200 mg(KOH)/g and ≦500 mg(KOH)/g, obtained from the reaction of a dicarboxylic acid/dicarboxylic acid derivative with at least one polyol and with an epoxide, wherein the polyester ether polyol B is used in amounts of from ≧1.5% by mass to ≦6.0% by mass, based on the sum of the masses of A and B. The invention further provides a PUR/PIR polymer produced from the prepolymer C, its use and composite elements based thereon. 1. Isocyanate-terminated prepolymer C having an NCO content of from ≧26.0% by mass to ≦31.0% by mass , based on the mass of the prepolymer C , obtainable from the reaction of from ≧25% by mass to ≦60% by mass monomeric diphenylmethane diisocyanate A1 and', 'from ≧40% by mass to ≦75% by mass polymeric diphenylmethane diisocyanate A2,', 'wherein the sum of the amounts of components A1 and A2 is ≦100% by mass, with, '(i) an isocyanate composition A having a viscosity at 25° C. of from ≧60 mPas to ≦800 mPas, comprising'} 'obtained from the reaction of a dicarboxylic acid and/or a dicarboxylic acid derivative B1 with at least one polyol B2 and with an epoxide B3, wherein the polyester ether polyol B is used in amounts of from ≧1.5% by mass to ≦6.0% by mass, based on the sum of the masses of A and B.', '(ii) a polyester ether polyol B having an average functionality of from ≧1.9 to ≦2.1 and an OH number of from ≧200 mg(KOH)/g to ≦500 mg(KOH)/g,'}2. Prepolymer according to having a viscosity at 25° C. of from ≧300 mPas to ≦1600 mPas.3. Prepolymer according to claim 1 , wherein component A has a viscosity at 25° C ...

HIGH FUNCTIONALITY AROMATIC POLYESTERS, POLYOL BLENDS COMPRISING THE SAME AND RESULTANT PRODUCTS THEREFROM

The present invention discloses aromatic polyester polyols suitable for blending with other polyols or other materials mutually compatible with the polyester polyols to achieve polyurethane and polyisocyanurate products. In particular the present invention discloses polyester polyols comprising the reaction of: A) an aromatic component comprising 80 mole percent or greater of terephthalic acid; B) a polyether polyol having a nominal functionality greater than 2 and less than or equal to 4, a molecular weight of 250 to 1000 and has a polyoxypropylene content of at least 70% by weight of the polyol; and C) a glycol other than B having a molecular weight from 60 to 250; wherein A, B, and C are present in the reaction on a percent weight bases of 20 to 60 weight percent A); 15 to 70 weight percent of B); and 10 to 50 weight percent of C). 2. The polyester polyol of wherein the aromatic content comprises 85 mole percent or greater of terephthalic acid.3. The polyester polyol of wherein the aromatic content comprises 95 mole percent or greater of terephthalic acid.4. The polyester polyol of wherein the functionality of the polyol is from 2.4 to 3.5. The polyester polyol of wherein the polyether polyol B) has a molecular weight of less than 800.6. The polyester polyol of wherein the glycol C) has a functionality of 2 to 3.8. The polyester polyol of wherein the glycol C) is a mixture of a two functional glycol and a three functional glycol.9. The polyester polyol of wherein the three functional glycol is glycerol claim 8 , trimethyolpropane or a combination thereof.10. A polyol mixture comprising: A) an aromatic component comprising 80 mole percent or greater of terephthalic acid;', 'B) at least one polyether polyol having a nominal functionality greater than 2 and less than or equal to 4, a molecular weight of 250 to 1000 and has a polyoxypropylene content of at least 70% by weight of the polyol; and', 'C) at least one glycol other than B) having a molecular weight from 60 ...

Polymer Having Polycyclic Groups and Coating Compositions Thereof

A polymer and coating composition containing the polymer are provided that are useful in coating applications such as, for example, food or beverage packaging containers. The polymer preferably includes a backbone having one or more polycyclic groups. In one embodiment, the polymer is a polyester and, more preferably, a polyester-urethane polymer. In one embodiment, the one or more polycyclic groups is a tricyclic or higher group.

REACTION SYSTEM FOR PREPARING POLYURETHANE MICROCELLULAR FOAM, A POLYURETHANE MICROCELLULAR FOAM AND THE USE THEREOF

The present invention relates to a reaction system for preparing polyurethane microcellular foam, a polyurethane microcellular foam and the use thereof. The reaction system for preparing polyurethane microcellular foam comprises isocyanate prepolymer, polyols, catalysts and chain extenders. The isocyanate prepolymer is a reaction product of polyisocyanates and polyester polyols, wherein the polyester polyols comprise 10-60 wt. % succinic acid units, based on 100 wt. % of the polyester polyols, the NCO content of the isocyanate prepolymer is 13-30 wt. %, based on 100 wt. % of isocyanate prepolymer. By using the reaction components provided in the present invention, the demould time for preparing the polyurethane microcellular foam can be reduced. The obtained polyurethane microcellular foam, which possesses good physical and mechanical properties, is particularly suitable to prepare shoes. 115-. (canceled)17. The reaction system as claimed in claim 16 , wherein component B further comprises one or more additives selected from the group consisting of:b4) one or more blowing agent; andb5) from 0.01 to 5 weight % of one or more surfactants, based on 100 weight % of polyurethane microcellular foam.18. The reaction system as claimed in claim 16 , wherein the polyester polyols comprise from 40 to 53 weight % of the succinic acid units claim 16 , based on 100 weight % of polyester polyols.19. The reaction system as claimed in claim 16 , wherein the NCO content of the isocyanate prepolymer is from 16 to 20 weight % claim 16 , based on 100 weight % of isocyanate prepolymer.21. The polyurethane microcellular foam as claimed in claim 20 , wherein component B further comprises one or more additives selected from the group consisting of:b4) one or more blowing agent; andb5) from 0.01 to 5 weight % of one or more surfactants, based on 100 weight % of polyurethane microcellular foam.22. The polyurethane microcellular foam as claimed in claim 20 , wherein the polyester polyols ...

Polyurethane hot-melt adhesive produced from polyacrylates and polyesters

A solvent-free moisture-curing polyurethane hot-melt adhesive composition, in which the adhesive comprises the following components: 20 to 85 wt % of a polyurethane prepolymer with free isocyanate groups produced from at least one polyol from the group of polyether polyols, polyester polyols, polyalkylene polyols and mixtures thereof with an excess of at least one polyisocyanate, the prepolymer having a monomeric diisocyanate content of below 1 wt %, 4 to 40 wt % of at least one acrylate copolymer with a molecular weight of below 60,000 g/mol, 3 to 35 wt % of a thermoplastic polyester with a number-average molecular weight (MN) of below 6000 g/mol, which comprises fewer than 1.4 NCO-reactive groups, and 0 to 25 wt % of at least one additive from the group of catalysts, resins, plasticizers, fillers, pigments, stabilizers or adhesion promoters, the sum of the constituents being equal to 100 wt %.

URETHANE-CROSSLINKED BIODEGRADABLE ELASTOMERS

Among other things, the present disclosure provides compositions and methods for an elastomeric cross-linked polyester material. Such an elastomeric cross-linked polyester material, in some embodiments, comprises a plurality of polymeric units of the general formula (-A-B—), wherein p is an integer greater than 1; and a plurality of urethane cross-links each of which covalently links two polymeric units to one another, which two linked polymeric unit each had at least one free hydroxyl or amino group prior to formation of the crosslink. 1. A precursor composition comprising{'sub': 'p', 'claim-text': A-B has a chemical structure that is achieved when a polyol component A′ is condensed with a polyacid component B′; and', 'at least two A-B units in the material each have at least one free hydroxyl or amino group;, 'a polyester material comprising a polymeric unit of the general formula (-A-B—), whereinand a polyisocyanate.2. The precursor composition of claim 1 , wherein the polyester material in non-linear.3. The precursor composition of claim 1 , wherein the polyester material has a molecular weight within the range of 5K-50K.4. The precursor composition of claim 1 , wherein the polyisocyanate is present at a level such that the precursor composition has a molar ratio of the free hydroxyl or amino of the pre-polymer to the polyisocyanate ranging from 1:0.3 to 1:1.5. The precursor composition of claim 1 , further comprising a catalyst.6. The precursor composition of claim 1 , further comprising a solvent.7. The precursor composition of claim 1 , further comprising a porogen.8. The precursor composition of claim 1 , wherein the polyester material further comprises a polyamide backbone when a polyamine component C′ is condensed with the polyacid component B′9. An elastomeric cross-linked polyester material comprising:{'sub': 'p', 'a plurality of polymeric units of the general formula (-A-B—), wherein p is an integer greater than 1; and'}a plurality of urethane cross- ...

Urethane resin particles

Provided is a slush molding material which exhibits excellent low-temperature meltability and heat resistance and which can yield a molded product having excellent tensile strength and elongation. The present invention is urethane resin particles (D 1 ) comprising a urethane or urethane-urea resin (U 1 ) that has residues (j) bonded thereto covalently, said residues (j) being residues derived from an at least trivalent aromatic polycarboxylic acid by removing hydroxyl groups, or urethane resin particles (D 2 ) comprising a urethane resin composition (S 2 ) which comprises both a urethane or urethane-urea resin (U 2 ) and a compound (E) that has a residue (j) derived from an at least trivalent aromatic polycarboxylic acid by removing hydroxyl groups, said compound (E) being represented by general formula (1), wherein the residues (j) are linked respectively to urethane or urea groups (u) of the resin (U 1 ) or (U 2 ) by hydrogen bonds.

Polyisocyanate-Based Binder

Aqueous binder composition comprising an organic emulsifiable polyisocyanate, an aromatic polyester polyol and a alkali metal salt of a carboxylic acid as trimerisation catalyst and its use for bonding mineral fibre or lignocellulosic material. 1. A binder composition comprising an organic polyisocyanate , an isocyanate-reactive compound and an isocyanate-trimerisation promoting catalyst.2. The binder composition according to wherein the solids content is 2 to 100 wt %.3. The binder composition according to also containing water.4. The binder composition according to in the form of an aqueous emulsion or dispersion.5. The binder composition according to wherein the polyisocyanate is modified to make it emulsifiable or dispersible.6. The binder composition according to wherein the modification involves reaction with cationic claim 5 , anionic and/or nonionic compounds containing isocyanate-reactive groups.7. The binder composition according to wherein the polyisocyanate is derived from diphenylmethane diisocyanates (MDI) and/or oligomers thereof.8. The binder composition according to wherein the isocyanate-reactive compound comprises an aromatic polyester polyol.9. The binder composition according to wherein the amount of isocyanate-reactive compound is sufficient to provide an equivalent ratio of isocyanate groups to hydroxyl groups (excluding water) of 2:1 to 30:1 claim 1 , preferably 5:1 to 20:1.10. The binder composition according to wherein the isocyanate-trimerisation promoting catalyst is an alkali metal salt of a carboxylic acid.11. The binder composition according to wherein the isocyanate-trimerisation promoting catalyst is used in an amount ranging from 0.1 to 5 wt % based on the binder solids.12. The binder composition according to further comprising a reaction retarder and/or a wetting agent and/or an adhesion promoter.13. The binder composition according to wherein the reaction retarder is lactic acid.14. A process for preparing the binder composition ...

Producing rigid polyurethane foams and rigid polyisocyanurate foams

The present invention relates to a process for producing rigid polyurethane foams or rigid polyisocyanurate foams by the reaction of at least one polyisocyanate A), polyetherester polyols B) based on aromatic dicarboxylic acids obtainable by esterification of b1) 10 to 70 mol % of a dicarboxylic acid composition comprising b11) 50 to 100 mol %, based on the dicarboxylic acid composition, of one or more aromatic dicarboxylic acids or derivatives thereof, b12) 0 to 50 mol %, based on said dicarboxylic acid composition b1), of one or more aliphatic dicarboxylic acids or derivatives thereof, b2) 2 to 30 mol % of one or more fatty acids and/or fatty acid derivatives, b3) 10 to 70 mol % of one or more aliphatic or cycloaliphatic diols having 2 to 18 carbon atoms or alkoxylates thereof, b4) 2 to 50 mol % of a polyether polyol having a functionality of not less than 2, prepared by alkoxylating a polyol having a functionality of not less than 2 in the presence of an amine as catalyst, optionally further polyester polyols C) other than those of component B), and at least one polyether polyol D), wherein the mass ratio of total components B) and optionally C) to component D) is at least 7. The present invention also relates to the rigid foams thus obtainable and also to their use for producing sandwich elements having rigid or flexible outer layers. The present invention further relates to the underlying polyol components.

Process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups

The present invention relates to a process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups. It furthermore relates to polyricinoleic acid ester polyols obtainable according to the invention and polyurethane polymers prepared using these polyols. The process comprises the steps: a) polycondensation of ricinoleic acid until a hydroxyl number of >0 mg of KOH/g to <60 mg of KOH/g is reached; and b) reaction of the product obtained in step a) or of a secondary product of the product obtained in step a) comprising carboxyl groups with an epoxide of the general formula (I), wherein R1 represents hydrogen, an alkyl radical or an aryl radical, with the proviso that >80% by weight to <100% by weight, based on the total amount of the epoxide (I) employed, is ethylene oxide and the reaction is carried out in the presence of an amine as the catalyst.

Elastomer Resins, Fibers And Fabrics Thereof, And Uses Thereof

The present invention relates to elastomeric resins, fibers made from said resins, fabrics made with said fibers, and applications and uses for the resins, fibers and fabrics. The elastomer resins of the invention provide high strength fibers and well balanced fabrics with good physical properties and chemical resistance, making them attractive for use in various applications that use elastic fibers and fabrics. 1. An elastomer resin prepared by reacting:(i) a hydroxyl terminated polyester intermediate derived from a dicarboxylic acid and a blend of at least two alkylene glycols wherein two of the alkylene glycols have a number average molecular weight that differs by at least 20 percent;(ii) a diisocyanate and(iii) a linear alkylene glycol chain extender;wherein the resulting resin has a weight average molecular weight of at least 600,000.2. The resin of wherein component (i) is derived from a carboxylic acid comprising adipic acid.3. The resin of wherein component (i) is derived from a 25:75 to 75:25 mixture claim 1 , on a molar basis claim 1 , of 1 claim 1 ,4-butanediol and 1 claim 1 ,6-hexanediol.4. The resin of wherein component (ii) comprises methylene diphenyl diisocyanate.5. The resin of wherein component (iii) comprises 1 claim 1 ,4-butanediol claim 1 , 1 claim 1 ,6-hexanediol claim 1 , or combinations thereof.6. A melt-spun fiber claim 1 , film claim 1 , or hose made from the resin of wherein the resin is further reacted with:(iv) an agent comprising the reaction product of a polyalkylene ether glycol and a diisocyanate;wherein said fiber, film, or hose has a weight average molecular weight of at least 700,000.7. The fiber claim 6 , film claim 6 , or hose of wherein component (iv) is derived from a polyalkylene ether glycol comprising polytetramethylene ether glycol.8. The fiber claim 6 , film claim 6 , or hose of to wherein component (iv) is derived from a diisocyanate comprising methylene diphenyl diisocyanate.9. A fabric made from the fiber of .10. An ...

Adhesive compositions and methods

The present invention encompasses polyurethane adhesive compositions comprising aliphatic polycarbonate chains. In one aspect, the present invention encompasses polyurethane adhesives derived from aliphatic polycarbonate polyols and polyisocyanates wherein the polyol chains contain a primary repeating unit having a structure: In another aspect, the invention provides articles comprising the inventive polyurethane compositions as well as methods of making such compositions.

Aromatic polyesters, polyol blends comprising the same and resultant products therefrom

The present invention discloses low viscosity aromatic polyester polyols suitable for blending with other polyols or other materials mutually compatible with the polyester polyols to achieve polyurethane and polyisocyanurate products. In particular the present invention discloses polyester polyols comprising the reaction of: A) an aromatic component comprising at 80 mole percent or greater of terephthalic acid; B) polyethylene glycol having a molecular weight from 150 to 1000; and C) a glycol different from the glycol of B); wherein A, B, and C are present in the reaction on a percent weight bases of 20 to 60 weight percent A); 40 to 75 weight percent of B); and 0 to 40 weight percent of C).

METHOD FOR PRODUCING ALIPHATIC POLYESTER HAVING INCREASED MOLECULAR WEIGHT

The present invention addresses the problem of providing a method for continuously and effectively producing an aliphatic polyester having an increased molecular weight by preventing evaporation of a diisocyanate when blending the diisocyanate with an aliphatic polyester prepolymer in a molten state at a temperature not lower than the melting point thereof so that the diisocyanate and the aliphatic polyester prepolymer are uniformly blended. 1. A method for producing an aliphatic polyester having an increased molecular weight comprising the steps of:(i) quantitatively injecting a diisocyanate into an aliphatic polyester prepolymer which has a number average molecular weight of 5000 or higher and has terminal hydroxyl groups and in which at least one acid component is a succinic acid compound, in a molten state at a temperature not lower than the melting point thereof, whereinthe diisocyanate comprises isocyanate groups in the amount equivalent to between one tenth and two times the amount of the hydroxyl groups in the aliphatic polyester prepolymer,(ii) quantitatively and continuously introducing the diisocyanate-containing aliphatic polyester prepolymer obtained at step (i) into a mixing tank, discharging same from the mixing tank under stirring, and supplying same to a coupling reaction tank, and(iii) reacting the aliphatic polyester prepolymer with the diisocyanate in the coupling reaction tank.2. The method for producing an aliphatic polyester having an increased molecular weight according to claim 1 ,wherein the mixing tank in (ii) has an inlet of the diisocyanate-containing aliphatic polyester prepolymer in its upper portion, an outlet for discharging a mixture of the aliphatic polyester prepolymer with the diisocyanate in its bottom portion, and at least one partitioning plate and stirring blade.3. The method for producing an aliphatic polyester having an increased molecular weight according to claim 2 ,wherein said at least one partitioning plate and ...

Aqueous autoxidisable coating composition

An aqueous coating composition comprising an autoxidisable polyester resin having ≧30 wt % of fatty acid residues; a Tg in the range of from −60° C. to +35° C.; an acid value greater than 15 mg KOH/g and less than 75 mg KOH/g; a Mw in the range of from 2,500 to 100,000 g/mol; said composition having a co-solvent content less that 15 wt % by weight of total composition; a solids content >30 wt %; and when a film, a telegraphing value of less than 20 gloss units.

Bonding agent composition

The present invention relates to an adhesive promoter composition, containing: at least one film-forming resin; at least one aromatic polyisocyanate; at least one solvent; as well as at least one specific isocyanurate containing silane groups. Adhesive promoter compositions according to the invention are suitable in particular for improving the adhesion of adhesives and sealants to glass and glass ceramics.

Thermosetting polyester coating compositions containing tetramethyl cyclobutanediol

Disclosed are polyester resins and solvent borne thermosetting coating compositions that include these resins in combination with at least one crosslinker. The polyester resins contain 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibit a combination of good solubility in organic solvents and high hardness with good flexibility in a coating composition.

GLYCEROL LEVULINATE KETALS AND THEIR USE IN THE MANUFACTURE OF POLYURETHANES, AND POLYURETHANES FORMED THEREFROM

The present disclosure relates to the preparation of ketal compounds from glycerol and levulinic acid and esters, and uses thereof, in particular the manufacture of polyurethanes. 2. The method of claim 1 , wherein the polyol polymer has an average molecular weight in excess of 500 Da.3. The method of claim 1 , wherein the polyol polymer has an average molecular weight in excess of 1000 Da.4. The method of claim 1 , wherein the polyol polymer is a linear polymer.5. The -linked claim 1 , or star-method of claim 1 , wherein the polyol polymer is a branched claim 1 , or star-shaped polymer.6. The method of claim 1 , wherein the polyol polymer is a cross-linked polymer.8. The method of claim 1 , wherein the reaction conditions comprise the use of a catalyst.9. The method of claim 8 , wherein the catalyst is dibutyl tin dilaurate claim 8 , 1 claim 8 ,4-diazabicyclo[2.2.2]octane claim 8 , or combinations thereof.10. The method of claim 1 , wherein the reaction conditions comprise a temperature between 30 and 160° C.11. The method of claim 1 , wherein the reaction conditions comprise substantially anhydrous conditions.12. The method of claim 1 , wherein the isocyanate is isophorone diisocyanate claim 1 , tolylene diisocyanate claim 1 , hexamethylene 1 claim 1 ,6-diisocyanate claim 1 , 4 claim 1 ,4′-methylenebis(phenyl isocyanate) claim 1 , or combinations thereof.14. The polyurethane polymer of claim 13 , wherein the polymer is a solid.15. The polyurethane polymer of claim 13 , wherein the polymer is a viscous liquid.16. The polyurethane polymer of claim 13 , wherein the polymer is rigid.17. The polyurethane polymer of claim 16 , wherein the polymer is a foam.18. The polyurethane polymer of claim 13 , wherein the polymer is flexible.19. The polyurethane polymer of claim 18 , wherein the polymer is a foam.20. The polyurethane polymer of claim 13 , wherein the polymer is a thermoset. This application is a continuation application of U.S. patent application Ser. No. 13/445, ...

Pentamethylenediisocyanate, method for producing pentamethylenediisocyanate, polyisocyanate composition, polyurethane resin, and polyurea resin

A Pentamethylene diisocyanate is obtained by phosgenating pentamethylenediamine or its salt obtained by a biochemical method, and contains 5 to 400 ppm of a compound represented by the general formula (1) below and a compound represented by the general formula (2) below in total:

Biodegradable Photoluminescent Polymers

The present invention describes a novel clastomeric biodegradable photoluminescent polymer (BPLP). The BPLPs of the present invention possess great processability and tunable fluorescence emission characteristics and are cell-compatible and biodegradable. The BPLPs of the present invention can serve as both implant materials and bioimaging probes. 158-. (canceled)60. The composition of claim 59 , wherein the diol is selected from 1 claim 59 ,8-octanediol claim 59 , ethylene glycol claim 59 , propylene glycol claim 59 , poly(ethylene glycol) claim 59 , poly(propylene glycol) claim 59 , 1 claim 59 ,3-propanediol claim 59 , ethanediol claim 59 , and cis-1 claim 59 ,2-cyclohexanediol.61. The composition of claim 59 , wherein the amino acid comprises alanine claim 59 , arginine claim 59 , asparagine claim 59 , aspartic acid claim 59 , cysteine claim 59 , glycine claim 59 , glutamine claim 59 , glutamic acid claim 59 , histidine claim 59 , isoleucine claim 59 , leucine claim 59 , lysine claim 59 , methionine claim 59 , proline claim 59 , phenylalanine claim 59 , serine claim 59 , threonine claim 59 , tyrosine claim 59 , tryptophan claim 59 , valine claim 59 , or a combination thereof.62. The composition of claim 59 , wherein the amino acid comprises an L-amino acid claim 59 , D-amino acid claim 59 , D claim 59 ,L-amino acid claim 59 , or a derivative thereof.63. The composition of claim 59 , wherein an acid anhydride or a multifunctional acid chloride is used in addition to the citric acid or triethyl citrate.64. The composition of claim 59 , wherein maleic acid claim 59 , maleic anhydride claim 59 , fumaric acid claim 59 , fumaryl chloride claim 59 , acryloylchloride claim 59 , itaconic acid claim 59 , or allylmalonic acid is used in addition to the citric acid or triethyl citrate.65. The composition of claim 59 , wherein the oligomer is crosslinked.66. A composition comprising:an oligomer synthesized from monomers comprising (i) a multifunctional monomer comprising ...

Polyurethane urea mixture for hair cosmetics

The invention relates to a specific polyurethane urea, which can be obtained by reacting a single polyisocyanate component, at least one polymeric polyol component, at least one hydrophilizing component and a single amino-functional chain extender component, wherein the polyisocyanate component comprises more than 75 mol % isophorone diisocyanate and the amino-functional chain extender component comprises more than 75 mol % isophorone diamine. Said polyurethane urea can be used in the field of hair cosmetics, in particular in the form of a mixture with conventional solvents. The invention further relates to the use of the polyurethane urea in cosmetics, to a cosmetic composition containing the polyurethane urea, to the use of the cosmetic composition in cosmetics, and to a method for forming hair styles using the cosmetic composition.

Belt

In the belt according to the present invention, the whole or a part of a belt body is formed from a thermoplastic resin composition (C) comprising a thermoplastic resin (A) and a modified ethylene copolymer (B) dispersed and contained therein. The modified ethylene copolymer (B) is preferably a copolymer, modified with an unsaturated carboxylic acid or a derivative thereof, of ethylene with at least one monomer component selected from (i) olefin components except for ethylene, (ii) diene components and (iii) ester components having an ethylenically unsaturated group. The belt according to the present invention hardly causes abrasion, damage, cracks, breakage and the like on the belt body and is remarkably excellent in durability, even if the belt is used at a high load for a long time.

Biocompatible, Biodegradable Polyurethane Materials With Controlled Hydrophobic to Hydrophilic Ratio

The biocompatible, biodegradable materials in the solid and/or liquid form are based on segmented linear polyurethanes and/or segmented crosslinked polyurethanes based on A) one or more biocompatible polyols susceptible to hydrolytic and/or enzymatic degradation having a molecular weight of 100 to 20,000 dalton and a number of active hydroxyl groups per molecule (functionality) of at least two or higher; B) one or more diisocyanates and/or triisocyanates; and C) one or more low molecular weight chain extenders having a molecular weight of 18 to 1000 dalton and the functionality of at least two or higher.

Antifouling composition

The present invention relates to the use of polyoxalates as binders for antifouling coating compositions and antifouling coating compositions comprising the polyoxalates.

Polymer in multicoat color and/or effect paint systems

Disclosed is a polymer which is prepared by reacting (a) dimer fatty acids with (b) at least one polyether of general structural formula (I) where R is a C 3 to C 6 alkylene radical and n is selected accordingly such that said polyether has a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting polymer has a number-average molecular weight of 1500 to 5000 g/mol and an acid number <10 mg KOH/g. Also disclosed is a pigmented aqueous basecoat material which comprises this polymer, and the use of said polymer in pigmented aqueous basecoat materials. It further relates to a method for producing multicoat paint systems, and also to the multicoat paint systems producible by means of said method. Moreover, the present invention relates to the refinish of defect areas on multicoat paint systems.

Implantable medical devices

A medical device includes a balloon catheter having an expandable member, e.g., an inflatable balloon, at its distal end and a stent or other endoprosthesis. The stent is, for example, an apertured tubular member formed of a polymer and is assembled about the balloon. The stent has an initial diameter for delivery into the body and can be expanded to a larger diameter by inflating the balloon.

POLYESTER POLYOLS IMPARTING IMPROVED FLAMMABILITY PROPERTIES

An aromatic polyester polyol having a nominal functionality of at least about 2 is produced from the esterification reaction of a phthalate-based composition containing less than 50 mol % of ortho-phthalic acid or phthalic anhydride, with a hydroxyl material containing at least 20 mol % of at least one branched aliphatic diol, and optionally transesterified with at least one hydrophobic material. The polyester polyol has improved shelf-life stability as demonstrated by the polyester polyol remaining clear and homogeneous for at least 6 months when stored at room temperature. The polyester polyol, when incorporated into a polyol foam-forming resin composition in an amount of at least 40 wt %, results in polyurethane and polyisocyanurate foams that exhibit low smoke and weight loss upon burning conditions. 1. A polyester polyol comprising:the esterification reaction product ofa. a phthalate-based composition comprising less than 50 mol % of ortho-phthalic acid or ortho-phthalic anhydride; and the esterification reaction product being optionally transesterified with at least one hydrophobic material,', 'wherein the polyester polyol remains clear and homogeneous for a period of at least 6 months when stored at 25° C., 'b. a hydroxyl-containing composition comprising at least 20 mol % of at least one branched aliphatic diol;'}2. The polyester polyol of claim 1 , wherein the phthalate-based composition comprises at least 50 mol % of one or more of terephthalic acid claim 1 , isophthalic acid claim 1 , polyalkylene terephthalate claim 1 , and dimethyl terephthalate.3. The polyester polyol of claim 1 , wherein the at least one branched aliphatic diol is selected from 2-methyl-1 claim 1 ,3-propanediol claim 1 , neopentyl glycol claim 1 , 2-methyl-2 claim 1 ,4-pentandiol claim 1 , 2-butyl-2-ethyl-1 claim 1 ,3-propandiol claim 1 , 2-ethyl-1 claim 1 ,3-hexandiol claim 1 , 2 claim 1 ,4-diethyl-1 claim 1 ,5-pentandiol claim 1 , 1 claim 1 ,2-propylene glycol claim 1 , and ...

A POLYOL BASED ON DIMER FATTY ACID RESIDUES AND THE CORRESPONDING POLYURETHANES

The present invention relates to a polyol comprising a) at least one dimer fatty residue selected from a dimer fatty diacid residue and a dimer fatty diol residue; and b) at least one residue of a linear or branched C17 to C32 dicarboxylic acid or diol; wherein the polyol comprises at least two hydroxyl end groups. The invention also relates to a a polyurethane comprising the polyol, the use of the polyol and a method of making the polyurethane. 1. A polyol comprising:a) at least one dimer fatty residue selected from a dimer fatty diacid residue and a dimer fatty diol residue; andb) at least one residue of a linear or branched C17 to C32 dicarboxylic acid or diol;wherein the polyol comprises at least two hydroxyl end groups.2. A polyol as claimed in wherein the C17 to C32 dicarboxylic acid or diol is a linear dicarboxylic acid or diol.3. A polyol as claimed in wherein the weight ratio of a) to b) in the polyol is in the range 90:10 to 30:70.4. A polyol as claimed in wherein the weight % of a) in the polyol is at least the weight % of b) in the polyol.5. A polyol as claimed in wherein the C17 to C32 dicarboxylic acid or diol is a C18 to C26 dicarboxylic acid or diol.6. A polyol as claimed in wherein the C17 to C32 dicarboxylic acid or diol is derived from a C17 to C32 diacid or dialkyl ester which is obtained by a metathesis reaction.7. A polyol as claimed in which further comprises:c) at least one residue of a C2 to C16 acid or alcohol which has at least 2 functional groups selected from a carboxylic acid group, a hydroxyl group and mixtures thereof.8. A polyol as claimed in wherein c) is at least one residue of a diol comprising from 2 to 10 carbon atoms.9. A polyol as claimed in wherein the weight % of a) in the polyol is greater than the weight % of c) in the polyol.10. A polyol as claimed in wherein the weight % of b) in the polyol is greater than the weight % of c) in the polyol.11. A polyurethane comprising a polyol as claimed in .12. A polyurethane as claimed ...

POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIALS, OPTICAL MATERIAL AND PLASTIC LENS OBTAINED FROM COMPOSITION

A polymerizable composition for optical materials of the present invention includes a polyisocyanate compound (A), a polyol compound (B) represented by the following General Formula (1) having a number average molecular weight of 100 or more, a di- or higher functional active hydrogen compound (C) (here, the compound (B) is excluded), and a photochromic compound (D). 2. The polymerizable composition for optical materials according to claim 1 ,wherein the polyisocyanate compound (A) is at least one kind selected from the group consisting of hexamethylene diisocyanate, pentamethylene diisocyanate, xylylene diisocyanate, isophorone diisocyanate, bis(isocyanatomethyl) cyclohexane, dicyclohexylmethane diisocyanate, 2,5-bis(isocyanatomethyl)bicyclo[2.2.1]-heptane, 2,6-bis(isocyanatomethyl)bicyclo-[2.2.1]-heptane, tolylene diisocyanate, phenylene diisocyanate, and diphenylmethane diisocyanate.4. The polymerizable composition for optical materials according to claim 3 ,wherein the polyol compound (B) is the compound represented by General Formula (I), (III), or (IV).5. The polymerizable composition for optical materials according to claim 3 ,wherein the compound represented by General Formula (I) is polyethylene glycol or polypropylene glycol.6. The polymerizable composition for optical materials according to claim 3 ,wherein the number average molecular weight of the compound represented by General Formula (I) is 200 to 4000.7. The polymerizable composition for optical materials according to claim 3 ,wherein the number average molecular weight of the compound represented by General Formula (I) is 300 to 3000.8. The polymerizable composition for optical materials according to claim 3 ,13. The polymerizable composition for optical materials according to claim 1 ,wherein the active hydrogen compound (C) is at least one kind selected from the group consisting of glycerin, pentaerythritol tetrakis(2-mercaptoacetate), pentaerythritol tetrakis(3-mercaptopropionate), 4- ...

POLYURETHANE HOT-MELT ADHESIVE HAVING A LOW CONTENT OF DIISOCYANATE MONOMERS AND GOOD CROSS-LINKING SPEED

A moisture-cured hot-melt adhesive can be formulated as a PUR-HM that is R-40 classification-free and stable during storage and processing, having a residual monomer content of less than 1 wt. % and having good cross-linking density and full-curing speed. The hot-melt adhesive is particularly suitable for vehicle construction in industrial manufacture, in particular of automobiles, in the textile or furniture industry or in the packaging industry. 1. A moisture-curing hotmelt adhesive obtainable by a process comprisingA) reacting one or more polyols as component a) with one or more monomeric polyisocyanates as component b), the stoichiometric ratio of isocyanate groups to hydroxyl groups being greater than 1, to give a reaction product comprising an isocyanate-functional polyurethane prepolymer, [{'br': None, 'sup': 3', '2, 'sub': (3-a)', 'a, 'HS—R—Si(X)(R)\u2003\u2003(I)'}, {'sup': 2', '3, 'in which Ris a linear or branched alkyl group having 1 to 10 C atoms, Ris a linear or branched alkylene group having 1 to 10 C atoms, X is a hydrolyzable radical, and a has a value of 0, 1 or 2,'}, 'to the reaction product and carrying out reaction to give a reaction product modified with the mercaptosilane, and, 'B) adding at least one mercaptosilane of the formula (I) as component c)'}C) adding an isocyanate-functional polyurethane prepolymer having a monomeric polyisocyanate content of below 1 wt % as component d) before, during and/or after the adding of the mercaptosilane to the reaction product or modified reaction product,the at least one mercaptosilane being added in an amount of 0.5 to 3.5 wt % and the isocyanate-functional polyurethane prepolymer as component d) being added in an amount of 10 to 50 wt %, based in each case on the total weight of the components a) to d).2. The moisture-curing hotmelt adhesive as claimed in claim 1 , wherein the isocyanate-functional polyurethane prepolymer as component d) is added in an amount of 10 to 45 wt % based on the total weight ...

Coating Composition Comprising a Polyisocyanate and a Polyol

The invention relates to a non-aqueous coating composition comprising 1. A non-aqueous coating composition comprisinga) a polyisocyanate,b) a polyol having an average functionality of more than 3 hydroxyl groups per molecule, and i) a metal based curing catalyst for the addition reaction of isocyanate groups and hydroxyl groups and', 'ii) a mercapto carboxylic acid,, 'c) the reaction product of'}wherein the coating composition does not contain a carboxylic acid wherein the carbonyl group of the carboxylic acid is in conjugation with a TT-electron system.2. The coating composition according to claim 1 , wherein the catalyst for the addition reaction of isocyanate groups and hydroxyl groups is based on a metal selected from the group consisting of tin claim 1 , bismuth claim 1 , zirconium claim 1 , and mixtures thereof.3. The coating composition according to claim 1 , wherein the catalyst for the addition reaction of isocyanate groups and hydroxyl groups is based on tin.4. The coating composition according to claim 1 , wherein the amount of metal based curing catalyst is in the range of 0.001 to 10 weight-% claim 1 , calculated on the non-volatile matter of the composition.5. The coating composition according to claim 1 , wherein the mercapto carboxylic acid is selected from the group consisting of 2-mercapto-carboxylic acids claim 1 , 3-mercapto-carboxylic acids claim 1 , and mixtures thereof.6. The coating composition according to claim 1 , wherein the amount of mercapto carboxylic acid is in the range of 0.1 to 18 weight-% claim 1 , calculated on the non-volatile matter of the composition.7. The coating composition according to claim 1 , wherein component b) comprises a polyester polyol and a polyacrylate polyol.8. The coating composition according to claim 1 , wherein the composition further comprises a volatile organic solvent.9. The coating composition according to claim 7 , wherein the amount of volatile organic solvent does not exceed 420 g/l of coating ...

FOAMED ISOCYANATE-BASED POLYMER

There is described a foamed isocyanate-based polymer derived from a reaction mixture comprising: an isocyanate; a polyol composition comprising a first prescribed amount of polymer particles dispersed in a base polyol; a second prescribed amount of biomass-based carbonaceous particulate material; and a blowing agent. In one embodiment, the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 15% as that of a reference foam produced by omitting the biomass-based carbonaceous particulate material from the reaction mixture and increasing the amount of polymer particles in the polymer polyol composition to equal the sum of the first prescribed amount and the second prescribed amount. In another embodiment, the foamed polymer has a cellular matrix comprising a plurality of interconnected struts, the biomass-based carbonaceous particulate material conferring to the cellular matrix a load efficiency of at least about 5 Newtons/weight % of biomass-based carbonaceous particulate material. A process to produce the foamed isocyanate-based polymer is also described. A polyol-based dispersion to produce the foamed isocyanate-based polymer is also described. It has been discovered that a relatively expensive petroleum-based copolymer polyol can be fully substituted by a relative inexpensive bio-based (amorphous carbon) dispersion with no significant compromise in important physical properties in the resulting polyurethane foam. 1. A foamed isocyanate-based polymer derived from a reaction mixture comprising:an isocyanate;a polyol composition comprising a first prescribed amount of polymer particles dispersed in a base polyol;a second prescribed amount of biomass-based carbonaceous particulate material; anda blowing agent;the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 15% as that of a reference foam produced by ...

CRYSTALLIZATION STABLE POLYESTER PREPOLYMERS

The invention relates to a crystallization stable polyester prepolymers for producing HDI- and PDI-based, solvent free two component (2K)-polyurethane- and/or polyurea coating agents. 2: The process according to claim 1 , wherein the polyol components A) and B) are reacted with the diisocyanate(s) as a mixture or successively in any sequence.5: A process for preparing prepolymers having isocyanate groups and having an NCO content of 2.8% to 18.0% by weight claim 1 , a mean isocyanate functionality of 1.9 to 3.0 and a viscosity claim 1 , measured to DIN EN ISO 3219 claim 1 , of max. 3000 mPas at 23° C. claim 1 , comprising reacting 1 claim 1 ,5-diisocyanatopentane and/or 1 claim 1 ,6-diisocyanatohexane in separate reactions with A) at least one polyester polyol of mean functionality from 1.9 to 2.3 and of number-average molecular weight from 300 to 3000 g/mol, prepared from aliphatic dicarboxylic acids and/or anhydrides thereof with excess amounts of polyfunctional alcohols, where the polyfunctional alcohols are branched aliphatic diols to an extent of at least 30% by weight, based on the total amount of polyfunctional alcohols, with', 'B) at least one polycaprolactone polyester of mean functionality from 2.0 to 3.0 and number-average molecular weight from 176 to 2000 g/mol,', 'and, 'i) a mixture/mixtures of'} 'and/or', 'ii) at least one polyester polyol according to A,'}iii) at least one polyester polymer according to B,at temperatures of 20 to 200° C., observing an equivalents ratio of isocyanate groups to hydroxyl groups of 4:1 to 200:1, and the prepolymers thus obtained are blended with one another such that the proportion of the polyester component A) in the total amount of the polyester components A) and B) converted is from 15% to 70% by weight.6: The process for preparing prepolymers having isocyanate groups according to claim 1 , wherein the proportion of the polyester component A) claim 1 , based on the total amount of the polyester components A) and B) ...

LIGHTWEIGHT TILE

The present disclosure provides a lightweight tile. The lightweight tile has a tile body and a lacquer layer overlaying on the tile body. The tile body is composed of a rigid foamed resin having a plurality of void cells. The density of the rigid foamed resin is 0.2 to 0.45 g/cm. The lightweight tile provided in the present disclosure is less dense than the conventional ceramic tiles. In addition, the heat insulation and sound insulation of the lightweight tile are excellent. 1. A lightweight tile , comprising:a tile body composed of a rigid foamed resin, wherein the tile body comprises a plurality of void cells; and{'sup': 3', '3, 'a lacquer layer overlaying at least one surface of the tile body, wherein the tile body has a density ranged from 0.2 g/cmto 0.45 g/cm.'}2. The lightweight tile of claim 1 , wherein the density of the tile body ranges from 0.25 g/cmto 0.4 g/cm.3. The lightweight tile of claim 1 , wherein the void cells in the tile body has an open cell content ranged from 5% to 20%.4. The lightweight tile of claim 3 , wherein the open cell content of the void cells in the tile body ranges from 10% to 15%.5. The lightweight tile of claim 1 , wherein the rigid foamed resin is obtained by foaming a mixture of an isocyanate compound and a polyol by adding a foaming agent and a catalyst into the mixture.6. The lightweight tile of claim 5 , wherein the isocyanate compound is a polyisocyanate.7. The lightweight tile of claim 5 , wherein the polyol is an aromatic polyester polyol.8. The lightweight tile of claim 5 , wherein the polyol is an aliphatic polyester polyol.9. The lightweight tile of claim 1 , wherein the rigid foamed resin further comprises a glass fiber in the rigid foamed resin.10. The lightweight tile of claim 1 , further comprising a protruding portion disposed on the tile body. This application claims priority to Taiwan Application Serial Number 107122666, filed Jun. 29, 2018, which is herein incorporated by reference.The present disclosure ...

SILICONE URETHANE UREA COPOLYMER AND PREPARATION AND USE THEREOF

A silicone urethane urea copolymer and methods for preparation and use of the copolymer are disclosed. The copolymer is crosslinkable. The copolymer is useful in various applications, including personal care compositions, such as hair care compositions and skin care compositions and in health care compositions such as skin contact adhesive compositions and transdermal drug delivery systems. 2. The copolymer of claim 1 , where subscript b is 0 to 1 claim 1 ,000 claim 1 ,000; subscript c is 0 to 200 claim 1 ,000; subscript i is 0 to 200 claim 1 ,000; subscript w1≥0; subscript w2 is 0 to 200 claim 1 ,000; subscript w3 is 0 to 200 claim 1 ,000; subscript w4 is 0 to 200 claim 1 ,000; subscript q has a value such that 2≤q≤3; subscript d is 0 to 1 claim 1 ,000 claim 1 ,000; subscript e is 0 to 1 claim 1 ,000 claim 1 ,000;subscript h is 0 to 1,000,000; subscript f is 1 to 1,500,000; subscript g is 0 to 500,000;subscript j is 0 to 500,000; subscript s is 0 to 200,000; subscript v is 0 to 200,000;subscript y1 is >0 to 1,000,000; and subscript y2 is >0 to 500,000.4. A method for preparing the copolymer of claim 1 , where the method comprises: a) an isocyanate compound, and', {'sup': U', 'S', 'P, 'sub': 'z3', 'b) an endblocker of formula (RR)ROH, where and subscript z3≥0; thereby preparing a precursor, and'}], 'i) combining starting materials comprising c) a catalyst selected from the group consisting of tertiary amines and metal salts,', 'd) a polyorganosiloxane, and', 'e) polymeric organic diol selected from the group consisting of polyalkylene oxide diols, polyester diols, polycarbonate oxide diols, or copolymer diols of these polymers; thereby preparing the copolymer., 'ii) combining the precursor prepared in step i) with a starting material comprising'}5. A method for preparing the copolymer of claim 1 , where the method comprises: a) an isocyanate compound,', {'sup': U', 'S', 'P, 'sub': 'z3', 'b) an endblocker of formula (RR)ROH, where subscript z3≥0, and'}, 'c) a ...

POLYMERIC DISPERSANTS CONTAINING ONE OR TWO QUATERNARY AMINE ANCHORING GROUPS WITH IMPROVED CHEMICAL AND THERMAL STABILITY

The present invention relates to a dispersant having a tertiary or quaternary amine anchoring group and a solubilizing polymer selected from Cfatty acid; a Cak(en)yl substituted succinic acid, anhydride or partial ester; a dimer or trimer fatty acid; and/or polymers from repeating units of polyesters, polyethers, polyacrylate, polyamides, polyurethanes or mixtures of said repeating units in a random or blocky copolymer. The dispersants are an improvement in that the alkylene connecting group between the tertiary or quaternized amine and the solubilizing polymer lacks abstractable hydrogen atoms at the geminal carbon atom from the nitrogen of the tertiary or quaternized amine over the prior art. The dispersants are useful as dispersants with improved thermal stability and low amounts yellow color after aging at elevated temperatures. 2. The dispersant composition of claim 1 , wherein D comprises be a polymer comprising repeating units from a polyester claim 1 , polyether claim 1 , polyamide claim 1 , polyamide claim 1 , polyacrylate claim 1 , polyurethane claim 1 , polyolefin repeating units and mixtures of said repeating units as random or blocky copolymers.3. The dispersant composition of claim 1 , wherein D comprises a Cfatty acid; a Cak(en)yl substituted succinic acid claim 1 , anhydride or partial ester; and/or a dimer or trimer fatty acid.5. The composition of claim 4 , wherein D comprises be a polymer comprising repeating units from a polyester claim 4 , polyether claim 4 , polyamide claim 4 , polyacrylate claim 4 , polyurethane claim 4 , polyolefin repeating units and mixtures of said repeating units as random or blocky copolymers claim 4 , such as a polyether/polyester or polyester/polyamide.6. The composition of claim 4 , wherein D comprises a Cfatty acid; a Calk(en)yl substituted succinic acid claim 4 , anhydride or partial ester; and/or a dimer or trimer fatty acid.7. The composition of claim 4 , wherein the continuous media is an aqueous media and D is a ...

INTUMESCENT COATING SYSTEM

An intumescent coating system contains: a polyol component; an isocyanate component; a latent crosslinker having two or more —NACHOR groups, where A is selected from a group consisting of H and —CHOR, and in each case R is independently selected from a group consisting of hydrocarbons having from one to four carbons, the latent crosslinker being present at a concentration of 30 weight-percent or more based on polyol weight; a boron component one weight-percent or more and 10 weight-percent or less based on total weight of the formulation; and expandable graphite at a concentration of 10 weight-percent or more and 50 weight-percent or less based on the total intumescent system weight; where the polyol and isocyanate are selected so that the reaction product at room temperature of the intumescent coating system components produces a coating having a tensile elongation of 40-percent or more as determined according to ISO 37. 2. The intumescent coating system of claim 1 , wherein the polyol component is present at a concentration of 60 weight-percent or more based on total weight of polyol and isocyanate-containing component.3. The intumescent coating system of claim 1 , wherein the isocyanate component is selected from a group consisting of methylene diphenyl diisocyanate claim 1 , polymeric methylene diphenyl diisocyanate claim 1 , toluene diisocyanate claim 1 , isophorone diisocyanate claim 1 , and xylene diisocyanate.5. The intumescent coating system of claim 4 , wherein each A is independently an R group.6. An intumescent coating comprising the reaction product of the intumescent coating system of .7. The intumescent coating of claim 6 , further characterized by the latent crosslinker being present at a concentration of 20 weight-percent or more based on polyurethane weight.8. An article comprising:a. a substrate; and{'claim-ref': {'@idref': 'CLM-00006', 'claim 6'}, 'b. the intumescent coating of covering at least a portion of the surface of the substrate.'}9. The ...

APPARATUS FOR DISPERSING A GAS, FOR EXAMPLE CARBON DIOXIDE, IN AT LEAST ONE REACTIVE RESIN

The invention concerns an apparatus () for the dispersion of an expansion gas even in supercritical conditions, e.g. carbon dioxide, in a reactive resin, of the kind in which a reaction chamber having an input () for gas and an input () for resin is provided. Advantageously, the chamber is a dispersion and containment chamber made into a casing () of predetermined high resistance susceptible to sustain high pressure and is divided into two sections () by a head () of a dispersion and mixing cylinder-piston group () in fluid communication between themselves by means of at least one pouring passage () provided with a static mixer (), motor means () being provided for piston () control of said mixing cylinder-piston group (). The invention also concerns a process for the formation of a polyurethane foam starting with the dispersion of carbon dioxide, even supercritical, in a reactive resin in which at least one initial dispersion and mixing controlled phase of the two components is provided in a dispersion and containment chamber under pressure divided into two sections () by a head () of a cylinder-piston mixing group () in fluid communication between themselves by means of at least one pouring passage () provided with a static mixer () and in which adduction, dispersion and mixing occurs under high pressure (at least greater than 75 bar). 1. Apparatus for the dispersion and mixing of an expansion gas , e.g. carbon dioxide , in a reactive resin , comprising:a mixing chamber having a supply input for the gas and a supply input for the resin is provided and comprising:said chamber being a dispersion and containment chamber made in a casing of predetermined high resistance susceptible to sustain high pressure;said chamber being divided into two sections by a head of a dispersion and mixing cylinder-piston group, said two sections being in fluid communication between themselves by means of at least one pouring passage;a static mixer in said pouring passage;a motor for ...

COMPOSITION, COMPOSITION FOR DOWNHOLE TOOLS, DEGRADABLE RUBBER MEMBER FOR DOWNHOLE, DOWNHOLE TOOL, AND METHOD FOR WELL DRILLING

A composition for downhill tool, a degradable rubber member for a downhole tool, a downhole tool, and a method for well drilling are provided which contribute to cost reduction and process shortening and can contribute to improvement of production efficiency. A degradable rubber and a degradation accelerator comprising at least one type of compounds represented by a general formula (I) below at the ratio from 0.1 to 20 parts by mass to 100 parts by mass of the degradable rubber, containing the composition for a down hole tool, i.e. degradable rubber member for a down hole tool, and a method for well drilling using them. 2. The composition according to claim 1 , wherein Rand Rare each individually selected from the group consisting of a methyl group claim 1 , ethyl group claim 1 , propyl group claim 1 , and butyl group.3. The composition according to claim 1 , wherein the melting point of the compound represented by Formula (I) is from −60 to 80° C.4. A composition for a downhole tool comprising the composition described in .5. A degradable rubber member for a downhole tool formed by using the composition for a downhole tool described in .6. The degradable rubber member for a downhole tool according to claim 5 , whereinsurface hardness of the degradable rubber member for a down hole tool is within the range from A60 to D80, andsurface hardness after immersion in water at 80° C. for 7 days is within the range from A0 to A60.7. The degradable rubber member for a downhole tool according to claim 5 , wherein the degradable rubber includes at least one type selected from the group consisting of urethane rubber claim 5 , natural rubber claim 5 , isoprene rubber claim 5 , ethylene propylene rubber claim 5 , butyl rubber claim 5 , styrene rubber claim 5 , acryl rubber claim 5 , aliphatic polyester rubber claim 5 , chloroprene rubber claim 5 , polyester thermoplastic elastomer claim 5 , and polyamide thermoplastic elastomer.8. The degradable rubber member for a downhole tool ...

AQUEOUS POLYURETHANE-POLYUREA DISPERSION AND AQUEOUS BASE PAINT CONTAINING SAID DISPERSION

The present invention relates to an aqueous polyurethane-polyurea dispersion (PD) having polyurethane-polyurea particles, present in the dispersion, having an average particle size of 40 to 2000 nm, and having a gel fraction of at least 50%, obtainable by 1. A process for preparing an aqueous polyurethane-polyurea dispersion , said process comprising , in the following order:dispersing, in an aqueous phase, a composition comprising, based in each case on the total amount of the composition 15 to 65 wt % of at least one intermediate comprising at least one isocyanate group and at least one blocked primary amino group, and 35 to 85 wt % of at least one organic solvent which has a solubility in water of not more than 38 wt % at a temperature of 20° C., thereby obtaining a dispersion, andat least partly removing the at least one organic solvent from the dispersion,thereby obtaining an aqueous polyurethane-polyurea dispersion comprising polyurethane-polyurea particles having an average particle size of 40 to 2000 nm and a gel fraction of at least 50%, at least one polyurethane prepolymer comprising isocyanate groups and comprising anionic groups and/or groups which can be converted into anionic groups, with', 'at least one polyamine comprising at least two blocked primary amino groups and at least one free secondary amino group,, 'wherein the at least one intermediate is prepared by a process comprising reaction of'}by addition reaction of isocyanate groups from the, at least one polyurethane prepolymer with free secondary amino groups from the at least one polyamine.2. A method for producing multicoat paint system , the method comprising:(1) applying a pigmented aqueous basecoat material to a substrate, thereby obtaining a coating material,(2) forming a polymer film the coating material, thereby obtaining a basecoat film,(3) applying a clearcoat material to the basecoat film, thereby obtaining a clearcoat film on the basecoat film, and then(4) curing the basecoat film ...

COATING COMPOSITION

The present invention relates to a coating composition and a method for preparing the same, a coating method and use thereof as well as a product coated with the coating composition. The coating composition comprises: A) a hydroxyl-containing component consisting of: a) a polyester-modified polycarbonate polyol having a number-average molecular weight of 500-6000 g/mol, the amount of which is greater than 50 wt. % based on that the weight of the hydroxyl-containing component is 100 wt. %, b) an optional polyester polyol having a hydroxyl content of not less than 10 wt. % as measured in accordance with DIN EN ISO 4629-2, and c) an optional polyacrylate polyol; and B) a polyisocyanate; wherein the equivalent ratio of isocyanate groups to hydroxyl groups of the composition is 0.5-1.2. A coating formed from the coating composition provided by the present invention has good appearance and adhesion as well as good reflowing, and especially can rapidly reflow at normal temperature. 120.-. (canceled)21. A coating composition comprising: a) a polyester-modified polycarbonate polyol having a number-average molecular weight (determined by gel permeation chromatography (GPC) in accordance with DIN 55672-1:2016-03 using polystyrene as standard and tetrahydrofuran as eluent) of 500-6000 g/mol, the amount of which is greater than 50 wt. % based on that the weight of the hydroxyl-containing component is 100 wt. %,', 'b) optionally a polyester polyol having a hydroxyl content of not less than 10 wt. % as measured in accordance with DIN EN ISO 4629-2, and', 'c) optionally a polyacrylate polyol; and, 'A) a hydroxyl-containing component consisting ofB) a polyisocyanate;the equivalent ratio of isocyanate groups to hydroxyl groups of the composition being 0.5-1.2.22. The composition according to claim 21 , wherein the polyester-modified polycarbonate polyol is a polyester-modified aliphatic polycarbonate polyol.23. The composition according to claim 21 , wherein the polyester-modified ...

ADHESIVE, LAMINATED FILM, AND PRODUCTION METHOD FOR LAMINATED FILM

Provided are an adhesive including a polyisocyanate composition (X) containing a polyisocyanate (A), and a polyol composition (Y) containing a tertiary amine compound (B) having plural hydroxyl groups, a polyol (C), and an aliphatic cyclic amide compound (D), as essential components, a laminated film using the adhesive, and a method for producing a laminated film including a step of separately applying two components, which includes bringing a polyisocyanate composition (X) containing a polyisocyanate (A) that is applied onto one base material into contact with a polyol composition (Y) containing a tertiary amine compound (B) having plural hydroxyl groups, a polyol (C), and an aliphatic cyclic amide compound (D) that is applied onto the other base material, and performing pressure-bonding. 1. An adhesive comprising:a polyisocyanate composition (X) containing a polyisocyanate (A); anda polyol composition (Y) containing a tertiary amine compound (B) having plural hydroxyl groups, a polyol (C), and an aliphatic cyclic amide compound (D), as essential components.2. The adhesive according to claim 1 ,wherein the polyol (C) is a polyester polyol, a polyester urethane polyol, a polyether urethane polyol, a polyether polyol, or a castor oil-based polyol.3. The adhesive according to claim 1 ,wherein an amine value of the adhesive is in a range of 0.5 to 40 mgKOH/g.4. The adhesive according to claim 1 ,wherein the aliphatic cyclic amide compound (D) is selected from the group consisting of δ-valerolactam, ε-caprolactam, ω-enanthollactam, η-capryllactam, and β-propiolactam.5. The adhesive according to claim 1 ,wherein a mass proportion of the polyol composition (Y) when a mass content of the polyisocyanate composition (X) is taken as 100 is in a range of 10 to 150.6. A laminated film comprising:an adhesive cured between a first base film and a second base film,{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'wherein the adhesive is the adhesive according to .'}7. A method ...

AQUEOUS PRIMER COATING

The present invention relates to novel coatings which are applied from an aqueous phase to substrates such as plastics, and which are overlaid with other coatings. These coatings are characterized by particularly good adhesive strength, in particular on plastics, and are thus particularly commercial. 1. A composition for coating substrates , comprising at least one optionally hydroxy-functional , anionic or nonionic polyurethane dispersion and at least one anionic styrene-butadiene copolymer dispersion.2. The composition as claimed in claim 1 , wherein a weight ratio of the at least one polyurethane dispersion to the anionic styrene-polybutadiene copolymer dispersion is in a range from 10:1 to 1:3 claim 1 , based on a nonvolatile proportion of the composition.3. The composition as claimed in claim 1 , wherein the composition comprises the at least one polyurethane dispersion in an amount of from 33 to 90% by weight claim 1 , based on a nonvolatile proportion of the composition.4. The composition as claimed in claim 1 , wherein the composition comprises the at least one anionic styrene-polybutadiene copolymer dispersion in an amount of from 9 to 67% by weight claim 1 , based on a nonvolatile proportion of the composition.5. The composition as claimed in claim 1 , wherein the composition comprises at least one reactive crosslinker component.6. The composition as claimed in claim 5 , wherein the at least one reactive crosslinker component comprises a polyisocyanate having a functionality in a range from 1.5 to 6.7. The composition as claimed in claim 1 , wherein the polyurethane dispersion comprises a polyurethane obtained from a reaction of reaction mixture comprising:(A) at least one diol and/or polyol component,(B) at least one polyisocyanate component,(C) at least one hydrophilizing component having at least one hydrophilizing group,(D) optionally mono-, di-, or tri-amino-functional compounds, or a combination thereof and/or hydroxyamino-functional compounds, and(E ...

Solventless Adhesive Composition Process and Laminate with Same

A process comprises (i) providing an isocyanate component A that is a reaction product of an aliphatic polyisocyanate, an aromatic polyisocyanate, an aliphatic polyester polyol, and a polyether polyol; (ii) providing a polyol component B comprising an aliphatic polyester polyol and a polyether polyol; (iii) mixing A and B to form a solventless adhesive (SLA) composition component A and component B each comprises an aliphatic polyester polyol having a viscosity from 800 to 6000 mPa·s at 25° C. and a hydroxyl number from 60 to 180 mg KOH/g; the SLA composition has (a) an initial viscosity at 40° C. from 500 to 1600 mPa·s, (b) an increasing viscosity ratio from 100% to 112% of the initial viscosity after the SLA composition stands at 40° C. for 10 min, and (c) an end viscosity at 40° C. from 120% to 210% of the initial viscosity at 40 min after forming the SLA composition. 1. A process comprising:(i) providing an isocyanate component A that is a reaction product of an aliphatic polyisocyanate, an aromatic polyisocyanate, an aliphatic polyester polyol, and a polyether polyol;(ii) providing a polyol component B comprising an aliphatic polyester polyol and a polyether polyol;component A and component B each comprising an aliphatic polyester polyol having a viscosity from 800 to 6000 mPa·s at 25° C. and a hydroxyl number from 60 to 180 mg KOH/g; (a) an initial viscosity at 40° C. from 500 to 1600 mPa·s,', '(b) an increasing viscosity ratio from 100% to 112% of the initial viscosity after the SLA composition stands at 40° C. for 10 min, and', '(c) an end viscosity at 40° C. from 120% to 210% of the initial viscosity at a time 40 min after forming the SLA composition., '(iii) mixing component A and component B to form a solventless adhesive (SLA) composition, the SLA composition having;'}2. The process according to claim 1 , comprising(iv) applying the SLA composition to a first film at a lamination speed from 80 m/min to 600 m/min to form an adhesive applied film;(v) ...

URETHANE (METH)ACRYLATE AND MOISTURE-PROOF INSULATING COATING MATERIAL

Provided is a photocurable moisture-proof insulating coating material which places little burden on the environment and has excellent surface curability with low irradiation. In addition, this photocurable moisture-proof insulating coating material is hydrophobic and exhibits high adhesion to a substrate material. Also provided is a novel urethane (meth)acrylate which is used for this moisture-proof insulating coating material. A urethane (meth)acrylate of the present invention is obtained by reacting (a) a polyester polyol that has a structural unit derived from a hydrogenated dimer acid and a structural unit derived from a hydrogenated dimer diol, (b) a polyisocyanate compound and (c) a hydroxyl group-containing (meth)acrylate. A moisture-proof insulating coating material of the present invention contains this urethane (meth)acrylate and a (meth)acryloyl group-containing compound that does not contain a silicon atom. 1. A urethane (meth)acrylate obtained by allowing(a) a polyester polyol having a structural unit derived from a hydrogenated dimer acid and a structural unit derived from a hydrogenated dimer diol;(b) a polyisocyanate compound; and(c) a hydroxyl group-containing (meth)acrylate to react.2. The urethane (meth)acrylate according to claim 1 , wherein the polyester polyol (a) comprises not less than 80% by weight of the structural unit derived from the hydrogenated dimer acid based on the total amount of a structural unit derived from a polycarboxylic acid claim 1 , and not less than 80% by weight of the structural unit derived from the hydrogenated dimer diol based on the total amount of a structural unit derived from a polyol.3. The urethane (meth)acrylate according to claim 1 , wherein the polyisocyanate compound (b) is at least one selected from the group consisting of norbornane diisocyanate claim 1 , isophorone diisocyanate claim 1 , and methylene bis(4-cyclohexylisocyanate).4. A moisture-proof insulating coating comprising:{'claim-ref': {'@idref': ' ...

ADHESIVE FOR SOLAR BATTERY BACK SHEETS

An adhesive for solar battery back sheets obtainable by mixing (A) a urethane prepolymer having an isocyanate group at the end with (B) a polyol, wherein the urethane prepolymer (A) is obtainable by a reaction of a hydroxyl group-containing compound with an isocyanate compound, and the hydroxyl group-containing compound comprises a polycaprolactone polyol. Also, cured reaction products of the adhesive. Also, a solar battery back sheet and a solar cell module comprising the adhesive. 1. An adhesive for solar battery back sheets prepared by mixing (A) a urethane prepolymer having an isocyanate group at the end with (B) a polyol , wherein the urethane prepolymer (A) is obtained by a reaction of a hydroxyl group-containing compound with an isocyanate compound , and the hydroxyl group-containing compound comprises a polycaprolactone polyol.2. The adhesive for solar battery back sheets according to claim 1 , wherein the urethane prepolymer (A) further comprises a trimer of an isocyanate compound.3. The adhesive for solar battery back sheets according to claim 1 , wherein the urethane prepolymer (A) has an isocyanate index of 2.0 to 4.0.4. The adhesive for solar battery back sheets according to claim 1 , wherein the hydroxyl group-containing compound further comprises trimethylolpropane.5. The adhesive for solar battery back sheets according to claim 1 , wherein the polyol (B) comprises a polyol having an ester bond.6. The adhesive for solar battery back sheets according to claim 1 , the adhesive further comprises an epoxy resin.7. The adhesive for solar battery back sheets according to claim 1 , wherein the polyol (B) has a glass transition temperature of 10° C. or lower.8. A solar battery back sheet comprising the adhesive for solar battery back sheets according to .9. A solar battery module comprising the solar battery back sheets according to .10. A solar battery back sheet comprising cured reaction products of the adhesive of .11. An adhesive for solar battery back ...

METHODS OF USING THERMOPLASTIC POLYURETHANES IN SELECTIVE LASER SINTERING AND SYSTEMS AND ARTICLES THEREOF

The present invention relates to systems and methods for solid freeform fabrication, especially selective laser sintering, as well as various articles made using the same, where the systems and methods utilize certain thermoplastic polyurethanes which are particularly suited for such processing. The useful thermoplastic polyurethanes are derived from (a) a polyisocyanate component, (b) a polyol component, and (c) an optional chain extender component; wherein the resulting thermoplastic polyurethane has a melting enthalpy of at least 5.5 J/g, a Tc (crystallization temperature) of more than 70° C., a Δ(Tm:Tc) of from 20 to 75 degrees, where Δ(Tm:Tc) is the difference between the Tm (melting temperature) and Tc. 1. A system for fabricating a three-dimensional object , comprising a solid freeform fabrication apparatus that selectively fuses layers of powder;wherein said powder comprises a thermoplastic polyurethane derived from (a) a polyisocyanate component, (b) a polyol component, and (c) an optional chain extender component;wherein said powder has an average particle diameter of less than 200 microns;wherein the resulting thermoplastic polyurethane has a melting enthalpy of at least 5.5 J/g;wherein the resulting thermoplastic polyurethane has a Tc of at least 70; andwherein the resulting thermoplastic polyurethane has a Δ(Tm:Tc) of between 20 and 75 degrees.2. A method of fabricating a three-dimensional object , comprising the step of: (I) operating a system for producing a three-dimensional object from a powder;wherein said system comprises a solid freeform fabrication apparatus that selectively fuses layers of powder; so as to form the three-dimensional object;wherein said powder comprises a thermoplastic polyurethane derived from (a) a polyisocyanate component, (b) a polyol component, and (c) an optional chain extender component;wherein said powder has an average particle diameter of less than 200 microns;wherein the resulting thermoplastic polyurethane has a ...

STABILIZED PLASTICIZERS FOR THERMOPLASTIC POLYURETHANE

The present invention relates to a process for producing a thermoplastic polyurethane, comprising the provision of a composition Z(W) comprising at least one carbodiimide selected from the group consisting of monomeric aliphatic carbodiimides, oligomeric aliphatic carbodiimides, polymeric aliphatic carbodiimides, monomeric aromatic carbodiimides, oligomeric aromatic carbodiimides and polymeric aromatic carbodiimides, and at least one ester selected from the group consisting of citric acid esters, acetyl citric acid esters, phthalic acid esters, benzoic acid esters, adipic acid esters, hydrogenated phthalic acid esters and phosphoric acid esters; and the subsequent addition of the composition Z(W) to a thermoplastic polyurethane or a reaction mixture for producing a thermoplastic polyurethane. Further, the present invention relates to a thermoplastic polyurethane obtainable or obtained by a process according to the invention and to the use of the composition Z(W) as plasticizer for thermoplastic polyurethanes. The present invention also relates to moldings comprising a thermoplastic polyurethane according to the invention. 1. A process for producing a thermoplastic polyurethane , the process comprising: (a) at least one carbodiimide selected from the group consisting of monomeric aliphatic carbodiimides, oligomeric aliphatic carbodiimides, polymeric aliphatic carbodiimides, monomeric aromatic carbodiimides, oligomeric aromatic carbodiimides and polymeric aromatic carbodiimides, and', '(b) at least one ester selected from the group consisting of citric acid esters, acetyl citric acid esters, phthalic acid esters, benzoic acid esters, adipic acid esters, hydrogenated phthalic acid esters and phosphoric acid esters; and, '(i) providing a composition Z(W) comprising'}(ii) adding the composition Z(W) to a thermoplastic polyurethane or a reaction mixture for producing a thermoplastic polyurethane.2. The process according to claim 1 , wherein the production of the ...

Cobalt and manganese based urethanized polymers for air drying polymer-based coatings, paints and inks

The present disclosure relates to polymer compounds for use as polymerization agents in coatings, paints or inks. In one embodiment, a polymer compound comprises at least one of a cobalt-bearing urethanized polymer having a cobalt content of no more than 6% by weight and a mean molecular weight of no more than 2500 Da, or a manganese-bearing urethanized polymer having a manganese content of 1% to 6% by weight and a mean molecular weight of no more than 2000 Da.

PUR-/PIR RIGID FOAMS CONTAINING POLYESTER POLYOLS WITH REDUCED FUNCTIONALITY

The invention relates to a method for preparing polyester polyols containing monools, and to their use, in particular for preparing polyurethane/polyisocyanurate rigid foams (also referred to hereafter as PUR/PIR rigid foams) with improved fire performance. 1. A multistage process for producing a polyester polyol PES-B comprising: {'sub': a', 'a, 'claim-text': {'br': None, 'i': n', '/n, 'sub': a', 'a, '(OH)(carboxy)>1, and'}, 'wherein in step a) the ratio of the molar amount of employed hydroxyl groups [n(OH)] to the molar amount of carboxyl-equivalent groups [n(carboxy)] is, 'a) completely reacting at least one carboxyl compound selected from the group consisting of i) polyfunctional carboxylic acids and ii) polyfunctional hydroxy-reactive carboxylic acid derivatives selected from the group consisting of carbonyl chlorides, alkyl carboxylates, hydroxy-functional carboxylic acids, lactones and carboxylic anhydrides with at least one polyol containing 2-8 hydroxy groups to afford a polyester polyol PES-A,'} {'sub': reactant', 'reactant, 'claim-text': {'br': None, 'i': n', '/n, 'sub': reactant', 'reactant, '(OH)(Carboxy)>1.'}, 'wherein the ratio of the molar sum of the hydroxy groups n(OH)of all reactant molecules employed in steps a) and b) to the molar sum of the employed carboxyl-equivalent groups n(carboxy)is, 'b) subsequently reacting the polyester polyol PES-A obtained in step a) with a monofunctional alcohol to afford the PES-B,'}2. The process as claimed in claim 1 , wherein the polyester polyol PES-B has a number-average OH functionality of >1.00 to <2.00.3. The process as claimed in claim 1 , wherein the carboxyl compound in step a) comprises glutaric acid claim 1 , succinic acid claim 1 , adipic acid claim 1 , terephthalic acid claim 1 , phthalic acid claim 1 , isophthalic acid claim 1 , a derivative of any thereof claim 1 , or a combinations of any thereof.4. The process as claimed in claim 1 , wherein the at least one polyol in step a) comprises a polyol ...

CHEMICAL RESISTANT POLYURETHANE ADHESIVE

A pressure sensitive adhesive composition includes a polyurethane polymer that includes the reaction product of a polyisocyanate component and a polyol component. The polyol component has a total solubility parameter ranging from 10 to 14 (cal/cm). 1. A pressure sensitive adhesive composition comprising a polyurethane polymer that comprises the reaction product of a polyisocyanate component and a polyol component; wherein the polyol component has a total solubility parameter ranging from 10 to 14 (cal/cm).2. The pressure sensitive adhesive composition of wherein the polyol component has hydrogen bonding solubility parameter ranging from 3.5 to 6.3. The pressure sensitive adhesive composition of wherein the polyol component comprises a polyester polyol claim 1 , a polycaprolactone polyol claim 1 , a polycarbonate polyol claim 1 , or a combination thereof.4. The pressure sensitive adhesive composition of wherein the polyol component claim 1 , isocyanate component claim 1 , or combination thereof comprises at least one six-membered ring structure.5. The pressure sensitive adhesive composition of wherein the polyol component claim 1 , isocyanate component claim 1 , or combination thereof comprises alkylene groups having at least 4 claim 1 , 5 claim 1 , or 6 carbon atoms.6. The pressure sensitive adhesive of wherein the polyisocyanate component comprises a polyisocyanate that is a liquid at 25° C.7. The pressure sensitive adhesive of wherein the polyol component comprises repeat units of an ortho- or meta-phthalate claim 1 , and an alkylene group comprising at least 4 claim 1 , 5 or 6 carbon atoms.8. The pressure sensitive adhesive of claim 1 , wherein the polyurethane polymer comprises the reaction product of the polyisocyanate component claim 1 , the polyol component claim 1 , and a functional acid containing compound.9. The pressure sensitive adhesive of claim 8 , wherein the functional acid containing compound is represented by the generic formula (HX)RA; wherein A ...

POLYURETHANE POWDER COATING MATERIAL

The invention relates to a polyurethane powder coating material, to the use of such a polyurethane powder coating material, to a method for producing a coating, and to coated substrates. 2. The powder coating material according to claim 1 , wherein component A) comprises at least one polyester which contains hydroxyl groups and has an OH number of 25 to 200 and a number-average molecular weight of 1000 to 5000.3. The powder coating material according to claim 1 , wherein component A) comprises at least one polyester which contains hydroxyl groups claim 1 , has a softening temperature (Tg) within the temperature range from 40 to 120° C. and/or is semicrystalline with a melting point in the range from 40 to 130° C.4. The powder coating material according to claim 1 , wherein component C) comprises at least one polyaddition compound which contains uretdione groups and optionally free isocyanate groups and which is based on one selected from the group consisting of pentamethylene 1 claim 1 ,5-diisocyanate (PDI) claim 1 , hexamethylene 1 claim 1 ,6-diisocyanate (HDI) claim 1 , 1-isocyanato-3 claim 1 ,3 claim 1 ,5-trimethyl-5-isocyanatomethylcyclohexane (isophorone diisocyanate claim 1 , IPDI) claim 1 , 4 claim 1 ,4′- and/or 4 claim 1 ,2′-diisocyanatodicyclohexylmethane (H-MDI) claim 1 , and mixtures of these diisocyanates.5. The powder coating material according to claim 1 , wherein component C) comprises at least one polyaddition compound which contains uretdione groups and optionally free isocyanate groups and which has a minimum carboxylic ester (calculated as CO; molecular weight=44) and/or carbonate (calculated as CO; molecular weight=60) group content of 1 wt %.6. The powder coating material according to claim 1 , wherein curing catalyst D) comprises salt-like compounds comprising a structural element of the general formulae (I) or (II) in which{'sup': 1', '2, 'Rand Rindependently of one another are identical or different radicals which denote saturated or ...

COATING COMPOSITION

The present invention relates to a coating composition and a method for preparing the same, a coating method and use thereof as well as a product coated with the coating composition. The coating composition comprises: A) a hydroxyl-containing component consisting of: a) a polycaprolactone polyol, b) a polyester polyol having a hydroxyl content of not less than 10 wt. % as measured in accordance with DIN EN ISO 4629-2, c) an optional polyacrylate polyol, and d) an optional polycarbonate polyol; and B) a polyisocyanate; wherein the equivalent ratio of isocyanate groups to hydroxyl groups of the composition is 0.5-1.2. A coating formed from the coating composition provided by the present invention has good reflowing, and especially can rapidly reflow at normal temperature. 120.-. (canceled)21. A coating composition comprising: a) a polycaprolactone polyol,', 'b) a polyester polyol having a hydroxyl content of not less than 10 wt. % as measured in accordance with DIN EN ISO 4629-2,', 'c) optionally a polyacrylate polyol, and', 'd) optionally a polycarbonate polyol; and, 'A) a hydroxyl-containing component consisting ofB) a polyisocyanate;the equivalent ratio of isocyanate groups to hydroxyl groups of the composition being 0.5-1.2.22. The composition according to claim 21 , wherein the polycaprolactone polyol has a hydroxyl functionality of 2-3 claim 21 , and a number-average molecular weight (determined by gel permeation chromatography (GPC) in accordance with DIN 55672-1:2016-03 using polystyrene as standard and tetrahydrofuran as eluent) of 500-5000 g/mol.23. The composition according to claim 21 , wherein the polycaprolactone polyol is in an amount of 10-90 wt. % claim 21 , based on that the weight of the hydroxyl-containing component is 100 wt. %.24. The composition according to claim 21 , wherein the polyester polyol has a hydroxyl content of 10-20 wt. % claim 21 , as measured in accordance with DIN EN ISO 4629-2.25. The composition according to claim 21 , wherein ...

Acrylic resin powder, resin composition, hot melt adhesive composition containing acrylic resin powder and method for producing same

An acrylic resin powder soluble in acetone, including a multi-stage polymer (M) that includes a polymer (B) obtained by polymerizing a monomer mixture (b) containing methyl methacrylate and an alkyl (meth)acrylate ester (mb) in the presence of a polymer dispersion that contains a polymer (A) obtained by polymerizing a monomer mixture (a) containing an alkyl (meth)acrylate ester (ma), in which an alkyl group in the alkyl (meth)acrylate ester (ma) has 4 to 8 carbon atoms, an alkyl group in the alkyl (meth)acrylate ester (mb) has 4 to 8 carbon atoms, a glass transition temperature of the polymer (A) is 20° C. or lower, a glass transition temperature of the polymer (B) obtained by polymerizing the monomer mixture (b) is 55° C. or higher, and a mass average molecular weight of the multi-stage polymer (M) is 10,000 or more and 300,000 or less.

AQUEOUS POLYURETHANE-UREA DISPERSION

The present invention relates to an aqueous dispersion based on polyurethane-urea, a composition comprising the same, and a use of the same in a coating agent, a sealant and an adhesive. The aqueous polyurethane-urea dispersion comprises a polyurethane-urea dispersed therein having sulfonate and/or carboxylate groups and lateral carboxyl groups, wherein the amount of said sulfonate and or carboxylate groups is 1.5 to 15 mmol/100 g; said lateral carboxyl is introduced by an aminocarboxylic acid having an amino functionality of greater than 1; the amount of said lateral carboxyl is 1.5 to 9.5 mmol/100 g, based on the polyurethane-urea solid components. Compared with the prior art, the composition of the polyurethane-urea based aqueous dispersion and a carboxyl reactive cross-linking agent provided by the present invention has a good cross-linking property and an excellent heat-resistance, which is not prone to come unglued when being exposed to heat. 115-. (canceled)16. An aqueous polyurethane-urea dispersion , comprising a polyurethane-urea dispersed therein having sulfonate and/or carboxylate groups and lateral carboxyl groups , wherein an amount of said sulfonate and/or carboxylate groups is 1.5 to 15 mmol/100 g; said lateral carboxyl groups are introduced by an aminocarboxylic acid having an amino functionality of greater than 1; an amount of said lateral carboxyl groups is 1.5 to 9.5 mmol/100 g , based on the polyurethane-urea solid components.17. The aqueous polyurethane-urea dispersion according to claim 16 , wherein said polyurethane-urea is prepared by comprising following components:A) at least one polyol component having a number-average molecular weight of 400 to 5000 Daltons and a hydroxyl functionality of not less than 1.9;B) optionally at least one polyol component having a number-average molecular weight of 62 to 399 Daltons;C) at least one diisocyanate or polyisocyanate component;D) at least one aminocarboxylic acid having an amino functionality of ...

TPU SHRINK MATERIAL

The present invention relates to a method for producing a molded body (MB) comprising the production of a thermoplastic polyurethane, the production of a molded body (MB*) from the thermoplastic polyurethane, heating the molded body (MB*) to a temperature below the temperature at which there is permanent deformability of the molded body (MB*), and above the switching temperature of the thermoplastic polyurethanes, elongating the heated molded body (MB*) with obtention of a molded body (MB), and cooling the molded body (MB) to a temperature below the switching temperature of the thermoplastic polyurethane, and the molded body obtained or obtainable by such a method. The present invention further relates to a thermoplastic polyurethane with shape memory and the use of a thermoplastic polyurethane for producing a molded body with shape memory effect in a temperature range from 0° C. to 130° C. 1. A method for producing a molded body MB , the method comprising: (i) at least one polyisocyanate composition,', '(ii) at least one chain extender, and', '(iii) at least one polyol composition,, '(a) producing a thermoplastic polyurethane by reacting'}wherein the polyol composition comprises at least one polyol P1 which contains at least one aromatic polyester block B1;(b) producing a molded body MB* from the thermoplastic polyurethane,(c) heating the molded body MB* to a temperature below a temperature at which there is permanent deformability of the molded body, MB* and above a switching temperature of the thermoplastic polyurethanes, to obtain a heated molded body MB*,(d) elongating the heated molded body MB* to obtain the molded body MB, and(e) cooling the molded body MB to a temperature below the switching temperature of the thermoplastic polyurethane,wherein a start of the permanent deformability corresponds to a start of melting of a hard phase of the thermoplastic polyurethane, and the switching temperature corresponds to a start of phase transition lying highest in the ...

INTEGRATED PROCESS FOR TREATING RECYCLED PET AND PTT MATERIALS

A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C-Cfatty acid units, saturated or unsaturated C-Cfatty acids, alkoxylated castor oil, saturated or unsaturated C-Cdicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C-Cfatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof. 129.-. (canceled)30. A process comprising:(a) reacting a recycle stream comprising recycled carpet selected from PTT carpet, PET carpet or mixtures thereof, with a glycol in a reactor, thereby forming a completely digested product stream comprising polyols, and at least one undigested stream;(b) separating the completely digested product stream from the undigested stream, thereby forming a separated digested product stream and a separated undigested product stream; and{'sub': 6', '36', '6', '36', '9', '18', '6', '36, '(b) reacting the separated digested product stream in the reactor with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C-Cfatty acid units, saturated or unsaturated C-Cfatty acids, alkoxylated castor oil, saturated or unsaturated C-Cdicarboxylic acids, cardanol- ...

TWO-COMPONENT CURABLE SOLVENTLESS-TYPE LAMINATE ADHESIVE AND RESIN CURED PRODUCT

A two-component curable solventless-type laminate adhesive contains a polyisocyanate component and a polyol component. The polyisocyanate component contains a derivative of a pentamethylene diisocyanate, the derivative of the pentamethylene diisocyanate contains an isocyanurate group and an allophanate group, and the content ratio of the isocyanurate group with respect to 100 moles of the total amount of the isocyanurate group and the allophanate group is 60 moles or more and 99 moles or less. 1. A two-component curable solventless-type laminate adhesive comprising:a polyisocyanate component and a polyol component, whereinthe polyisocyanate component containsa derivative of a pentamethylene diisocyanate,the derivative of the pentamethylene diisocyanate contains an isocyanurate group and an allophanate group, andthe content ratio of the isocyanurate group with respect to 100 moles of the total amount of the isocyanurate group and the allophanate group is 60 moles or more and 99 moles or less.2. The two-component curable solventless-type laminate adhesive according to claim 1 , whereinthe allophanate group is derived from the pentamethylene diisocyanate and a monohydric alcohol.3. The two-component curable solventless-type laminate adhesive according to claim 1 , whereinthe content ratio of the isocyanurate group with respect to 100 moles of the total amount of the isocyanurate group and the allophanate group is 90 moles or more and 98 moles or less.4. The two-component curable solventless-type laminate adhesive according to claim 1 , whereinthe polyisocyanate component contains a diisocyanate group-terminated prepolymer that is a reaction product of a diisocyanate containing an araliphatic diisocyanate and a diol containing a high molecular weight diol having a number average molecular weight of 300 or more and 2000 or less.5. The two-component curable solventless-type laminate adhesive according to claim 1 , whereinthe viscosity thereof at 70° C. in 2 minutes after ...

CRYSTALLINE THERMOPLASTIC POLYURETHANE ARTICLE

The disclosed technology relates to an article, such as a hose, tube, sheet, film, or filament made from a crystalline thermoplastic polyurethane composition, wherein the crystalline thermoplastic polyurethane composition comprises the reaction product of a polyisocyanate component, a polyester polyol component, optionally a chain extender component, and optionally a catalyst. The article is produced by melt or extrusion processes. 1. A filament comprising:a crystalline thermoplastic polyurethane composition comprising:the reaction product of (a) a polyisocyanate component, (b) a polyol component, comprising a polyester polyol (c) optionally, a catalyst; and (d) optionally, a chain extender component, wherein the crystalline thermoplastic polyurethane composition has a melt enthalpy measured by DSC of at least about 17 J/g and/or a cooling enthalpy measured by DSC of at least about 15 J/g, wherein the filament shrinks less than 15% after exposure to 80° C. for 90 seconds.2. The article of where the article is prepared by melt-extrusion.3. The article of wherein the polyester polyol comprises a polycaprolactone polyester polyol.4. The article of wherein the polyester polyol consists essentially of a polycaprolactone polyester polyol.5. The article of wherein the polyester polyol component comprises polybutanediol succinate.6. The article of wherein the polyester polyol component consists essentially of polybutanediol succinate.7. The article of wherein the polybutanediol succinate has a molecular weight of about 3000 to about 6000.8. The article of claim 7 , wherein the polybutanediol succinate has a molecular weight of about 4000 to about 6000.9. The article of wherein the thermoplastic polyurethane composition has a melt enthalpy measured by DSC of at least 40 J/g.10. The article of wherein the thermoplastic polyurethane composition has a cooling enthalpy measured by DSC of at least 40 J/g.11. The article of claim 1 , wherein the polyol component further comprises ...

SOLUTION FOR FORMING SURFACE PROTECTIVE RESIN MEMBER, SOLUTION SET FOR FORMING SURFACE PROTECTIVE RESIN MEMBER, AND SURFACE PROTECTIVE RESIN MEMBER

Provided is a solution for forming a surface protective resin member, containing: a fluorine-containing acrylic resin having a hydroxyl value of 40 to 280; a fluorine-free acrylic resin having a hydroxyl value of 40 to 280; and a polyether polyol or a polyester polyol. 1. A solution for forming a surface protective resin member , comprising:a fluorine-containing acrylic resin having a hydroxyl value of 40 to 280;a fluorine-free acrylic resin having a hydroxyl value of 40 to 280; anda polyether polyol or a polyester polyol.2. The solution for forming a surface protective resin member according to claim 1 , wherein a content of fluorine in the fluorine-containing acrylic resin is 1 mass % to 33 mass % with respect the fluorine-containing acrylic resin.3. The solution for forming a surface protective resin member according to claim 1 , wherein a proportion of the fluorine-containing acrylic resin is 10 mass % to 90 mass % with respect to a total amount of the fluorine-containing acrylic resin and the fluorine-free acrylic resin.4. The solution for forming a surface protective resin member according to claim 1 , wherein a ratio [OH]/[OH] of the hydroxyl value [OH] of the fluorine-containing acrylic resin to the hydroxyl value [OH] of the fluorine-free acrylic resin is ⅓ to 3.5. A solution set for forming a surface protective resin member claim 1 , the solution set comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a first solution containing the solution according to ; and a second solution containing a polyfunctional isocyanate.'}6. A surface protective resin member that is a cured product of: a fluorine-containing acrylic resin having a hydroxyl value of 40 to 280; a fluorine-free acrylic resin having a hydroxyl value of 40 to 280; a polyether polyol or a polyester polyol; and a multifunctional isocyanate. The surface protective resin member according to claim 6 , wherein a contact angle with respect to water is 95° to 140°.8. The solution for forming a ...

MIXING SYSTEM FOR PRODUCING AQUEOUS REPAIR COATING PRODUCTS, METHOD FOR THE PRODUCTION THEREOF, AND AQUEOUS REPAIR COATING PRODUCTS PRODUCED FROM THE MIXING SYSTEM

Provided herein is a mixer system for producing refinish compositions, more particularly for the sector of automotive finishing, including at least mutually different components (1), (2), and (3), namely component (1) as base varnish, component (2) as tinting base, and component (3) as rheology module, with at least one of components (1) to (3) including at least one aqueous dispersion including at least one polymer prepared by multistage emulsion polymerization, and at least one of components (1) to (3) including at least one aliphatic monoalcohol having 5 carbon atoms and/or at least one aliphatic monoalcohol having 6 carbon atoms. Further provided herein is an aqueous refinish composition that is produced by the mixing of components (1) to (3), and a method for producing aqueous refinish compositions. Further provided herein is a use of the mixer system for producing aqueous refinish compositions for automotive refinishing. 1. A mixer system for producing aqueous refinish compositions , the mixer system comprising:at least one component (1) as pigment-free base varnish, comprising at least one physically curing polyurethane or a self-crosslinking polyurethane or an externally crosslinking polyurethane;at least one component (2) as tinting base, comprising at least one physically drying polyurethane or a self-crosslinking polyurethane or an externally crosslinking polyurethane and at least one color-imparting and/or optical-effect-imparting pigment; andat least one component (3) as rheology module, comprising at least one inorganic and/or organic thickener,wherein at least one of the components, (1), (2), or (3), comprises an aqueous dispersion comprising at least one polymer SCS, and wherein at least one of the components, (1), (2), or (3), comprises at least one aliphatic monoalcohol having 5 carbon atoms and/or at least one aliphatic monoalcohol having 6 carbon atoms,the aqueous dispersion being prepared by the successive radical emulsion polymerization of ...

POLYASPARTIC COATING COMPOSITION, COATING FILM, AND COATED ARTICLE

The present invention provides a polyaspartic coating composition containing (A) an aspartic acid ester compound represented by the following formula (I) 2. The polyaspartic coating composition according to claim 1 , wherein the polyol further contains a polyoxyalkylene polyol.3. The polyaspartic coating composition according to claim 2 , wherein a ratio of the polyoxyalkylene polyol to a total amount of the polyoxyalkylene polyol and the polycaprolactone polyol is 80% by mass or less.4. The polyaspartic coating composition according to claim 1 , wherein an equivalent ratio between the amino group of (A) the aspartic acid ester compound and the isocyanate group of (B) the polyisocyanate component is amino group:isocyanate group=10:1 to 1:10.6. The polyaspartic coating composition according to claim 5 , wherein a number-average molecular weight of (B′) the polyisocyanate component is 700 to 3500.7. The polyaspartic coating composition according to claim 5 , wherein an equivalent ratio between the amino group of (A) the aspartic acid ester compound and the isocyanate group of (B′) the polyisocyanate component is amino group:isocyanate group=10:1 to 1:10.8. The polyaspartic coating composition according to claim 1 , wherein the diisocyanate monomer contains a hexamethylene diisocyanate.9. A coating film formed from the polyaspartic coating composition defined in .10. A coated article comprising the coating film defined in .11. Use of the polyaspartic coating composition defined in for heavy-duty anticorrosion coating.12. A method for preventing corrosion of a structure claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'coating a structure with the polyaspartic coating composition defined in .'} The present invention relates to a polyaspartic coating composition, a coating film and a coated article.Priority is claimed on Japanese Patent Application No. 2017-043141, filed Mar. 7, 2017 and Japanese Patent Application No. 2017-169741, filed Sep. 4, ...

CLEANING BLADE

A cleaning blade includes an elastic body that is a molded body of a rubber base material, and which has at least a surface treatment layer in a portion of the elastic body , the portion coming into contact with an object to be contacted. The surface treatment layer is formed by impregnating a surface portion of the elastic body with a surface treatment liquid, which contains an isocyanate compound and an organic solvent, and curing the surface treatment liquid; the surface treatment layer has an elastic modulus of 95 MPa or less; the elastic body has an elastic modulus of from 20 MPa to 60 MPa (inclusive); and the difference between the elastic modulus of the surface treatment layer and the elastic modulus of the elastic body is 1 MPa or more. 1. A cleaning blade , comprising:an elastic body formed of a rubber base material molded product, and a surface treatment layer on at least an area of the elastic body to be brought into contact with a cleaning object, wherein,the surface treatment layer is a hardened product containing an isocyanate compound with which a surface portion of the elastic body has been impregnated and which has been reacted with the elastic body;the surface treatment layer has an elastic modulus of 95 MPa or lower;the elastic body has an elastic modulus of 20 MPa to 60 MPa; andthe difference in elastic modulus between the surface treatment layer and the elastic body is 1 MPa or greater.2. The cleaning blade according to claim 1 , wherein the surface treatment layer has a thickness of 10 μm to 50 μm. The present invention relates to a cleaning blade employed in image-forming apparatuses including an electrophotographic copying machine or printer, and a toner-jet-type copying machine or printer.In a general electrophotographic process, an electrophotographic photoreceptor undergoes processes including at least cleaning, charging, light exposure, development, and image transfer. Each process employs a cleaning blade for removing a toner remaining ...

WATER-DISPERSIBLE POLYURETHANE-UREA RESIN COMPOSITION FOR SYNTHETIC LEATHER AND PREPARING METHOD THEREOF

The present disclosure relates to a polyurethane-urea resin composition for synthetic leather and a method of preparing the polyurethane-urea resin composition, the polyurethane-urea resin composition having excellent resin stability, heat resistance and aesthetic properties by including an ionic compound containing a sulfonic acid group, and by not including a neutralizer. In addition, the polyurethane-urea resin composition for synthetic leather may be applicable for various purposes by controlling a polyurethane-urea particle size to a desired size by controlling a content of the ionic compound containing a sulfonic acid group. 1. A water-dispersible polyurethane-urea resin composition for synthetic leather , comprising:a polyol comprising a polyester polyol, a polyether polyol or a mixture thereof;an isocyanate; andan ionic compound comprising a sulfonic acid group.2. The water-dispersible polyurethane-urea resin composition for synthetic leather of claim 1 , wherein the composition does not contain a neutralizer.3. The water-dispersible polyurethane-urea resin composition for synthetic leather of claim 1 , wherein a content of the ionic compound comprising the sulfonic acid group is in a range of 1 to 15 parts by weight with respect to the total weight of the polyol.4. The water-dispersible polyurethane-urea resin composition for synthetic leather of claim 1 , wherein the ionic compound comprising the sulfonic acid group comprises sodium-N-(2-aminoethyl)aminoethanesulfonate claim 1 , sodium-3-[(2-aminoethyl)amino]propanesulfone claim 1 , sodium-2-[(2-aminoethyl)amino]ethanesulfonate claim 1 , or a mixture thereof.5. The water-dispersible polyurethane-urea resin composition for synthetic leather of claim 1 , wherein a mixing ratio of the polyester polyol and the polyether polyol is in a range of 1:0.25 to 2 by weight.6. The water-dispersible polyurethane-urea resin composition for synthetic leather of claim 1 , wherein the polyol comprises one or more of ...

THERMOPLASTIC POLYURETHANE

A polyurethane, in particular a thermoplastic polyurethane, is obtainable or obtained by reacting at least a polyisocyanate composition and a polyol composition. The polyol composition contains at least one polyester diol or polyether diol, having a number-average molecular weight in the range from 500 to 3000 g/mol, and at least one polysiloxane having two terminal isocyanate-reactive functionalities selected from a thio group, a hydroxyl group, and an amino group. A process can be used for preparing this polyurethane, and a molded body containing the polyurethane is useful. Foam beads based on polyurethane can be obtained or obtainable from the polyurethane, and a process can be used for producing foam beads. Corresponding bead foams are useful. 131-. (canceled)32. A foam bead based on polyurethane , obtained from a polyurethane , wherein the polyurethane is obtained by reacting at least components (i) to (ii):(i) a polyisocyanate composition; and (ii.1) a polyester diol or polyether diol having a number-average molecular weight in a range from 500 to 3,000 g/mol, and', '(ii.2) a polysiloxane having two terminal isocyanate-reactive functionalities selected from the group consisting of a thio group, a hydroxyl group, and an amino group., '(ii) a polyol composition, comprising'}33. The foam bead based on polyurethane according to claim 32 , wherein the polyurethane is obtained by reacting at least components (i) to (iii):(i) a polyisocyanate composition; (ii.1) a polyester diol or polyether diol having a number-average molecular weight in a range from 500 to 3,000 g/mol, and', '(ii.2) a polysiloxane having two terminal isocyanate-reactive functionalities selected from the group consisting of a thio group, a hydroxyl group, and an amino group; and, '(ii) a polyol composition, comprising'}(iii) a chain extender composition.35. The foam bead based on polyurethane according to claim 34 , wherein n of the polysiloxane as per (ii.2) is an integer in a range from 3 to 50 ...

Composition

The present invention provides a stabilising composition, comprising:a) a first phenolic antioxidant comprising one or more phenolic compounds having the structure of formula (I): wherein R1 is a linear or branched alkyl group having from 12 to 20 carbon atoms; andb) one or more second phenolic antioxidants independently selected from: a mono-hydroxybenzene having lower steric hindrance than the first phenolic antioxidant; a di-hydroxybenzene; and/or a tri-hydroxybenzene.