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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Применить Всего найдено 43463. Отображено 100.

12-01-2012 дата публикации

Tetrazine monomers and copolymers for use in organic electronic devices

Номер: US20120007026A1

Автор: Jianfu Ding, Naiheng Song, Zhao Li

Принадлежит: NATIONAL RESEARCH COUNCIL OF CANADA

Copolymers of formula (I): where each A is S, Se or C═C; each x is an integer from 1 to 4; each R1 is independently H, F, CN or a C 1 -C 20 linear or branched aliphatic group; Ar is one or more substituted or unsubstituted aromatic units; and, n is an integer 5 or greater, can be formed into films or membranes that are useful as active layers in organic electronic device, such as PV solar cells, providing high power conversion efficiencies and good thermal stability. Such copolymers may be synthesized from monomers of formula (II): by Stille or Suzuki coupling reactions. Such monomers may be synthesized by a variation of the Pinner synthesis.

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Номер записи: 1

19-01-2012 дата публикации

Low temperature curable polyimide resin and method of preparing the same

Номер: US20120016076A1

Автор: Dong Hyun Oh, Kyung Jun Kim, Sang Woo Kim, Se Jin Shin

Принадлежит: LG Chem Ltd

In a method for preparing a polyimide resin by reacting diamine and dianhydride, the polyimide resin is polymerized under the presence of a solvent having a boiling point ranging from 130° C. to 180° C. so as to be curable at a low temperature ranging from 150° C. to 250° C. Because the polyimide is curable even at a low temperature, when the polyimide resin is used as an electronic material, damage to equipment due to an otherwise high temperature process can be minimized, and in addition, the polyimide resin can be extensively used as an electronic material such as for a plastic substrate, or the like.

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Номер записи: 2

09-02-2012 дата публикации

Carboxylic polybenzimidazole

Номер: US20120035333A1

Автор: Hsiao-Chien Chen, Lee-Yih Wang, Mu-Yi Hua, Rung-Ywan Tsai

Принадлежит: Chang Gung University CGU

A carboxylic polybenzimidazole includes at least one of the following functional group of formula (I): wherein G is a group containing a carboxylic acid end group or a carboxylated end group.

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Номер записи: 3

08-03-2012 дата публикации

Stable Solution of the Polymer Prepared from N,O-Heterocycles and its Preparation Method and Use

Номер: US20120059096A1

Автор: Chih-Wei Liao, Hsien-Te Chen, Hsuan-Hao HSU, Shih-Hao Liao, Tsung-Hsien Lin

Принадлежит: Taiwan Union Technology Corp

A stable solution of the polymer prepared from N,O-heterocyclic compound and its preparing method are provided, wherein the stable solution is prepared by making the N,O-heterocyclic compound of formulae I or II carry out a ring-opening polymerization: wherein R1 to R3, W1, W2, m, n, p and q are as defined in the specification. The stable solution can be used as a hardener for curing epoxy resin.

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Номер записи: 4

15-03-2012 дата публикации

Porous polymeric materials for hydrogen storage

Номер: US20120065289A1

Автор: Di-Jia Liu, Junbing Yang, Luping Yu, Shengwen Yuan

Принадлежит: UChicago Argonne LLC

A porous polymer, poly-9,9′-spirobifluorene and its derivatives for storage of H 2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO 2 /steam oxidation and supercritical water treatment.

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Номер записи: 5

15-03-2012 дата публикации

Composition, coated film formed of the composition, layered product containing the coated film, and electronic device incorporating the layered product

Номер: US20120065310A1

Автор: Eiji Honda, Enhai Sun, Hiroaki Adachi, Syuzou Waki, Toshiyuki Goshima, Yoro Sasaki, Yoshikazu Nishikawa

Принадлежит: Individual

An object is to provide a composition that has good viscosity stability and flowability at the time of processing, good shape retention after the processing, and good drying property in a temperature range of not degrading the conductor layer at the time of drying and that enables a coated film excellent in strength of adhesion with metal•polyimide, flame resistance, heat resistance, flexibility, mechanical properties, and chemical resistance to obtained after being dried. To meet this object, a composition is prepared containing (A) polyimide and (B) mixed solvent of two kinds or more, and the solubility parameter of the mixed solvent of two kinds or more ranges from 9 to 14.

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Номер записи: 6

15-03-2012 дата публикации

Electroactive materials

Номер: US20120065432A1

Автор: Adam Fennimore, Daniel David Lecloux, Eric Maurice Smith, Frederick P. Gentry, Gary A. Johansson, Gene M. Rossi, Kyung-ho Park, Michael Henry Howard, Jr., Nora Sabina Radu, Reid John Chesterfield, Troy C. Gehret

Принадлежит: EI Du Pont de Nemours and Co

A compound having Formula I, Formula II, or Formula III: Ar 1 may independently be phenylene, substituted phenylene, naphthylene, or substituted naphthylene. Ar 2 is the same or different at each occurrence and is an aryl group. M is the same or different at each occurrence and is a conjugated moiety. T 1 and T 2 are independently the same or different at each occurrence and are conjugated moieties which are connected in a non-planar configuration; a and e are the same or different at each occurrence and are an integer from 1 to 6; b, c, and d are mole fractions such that b+c+d=1.0, with the proviso that c is not zero, and at least one of b and d is not zero, and when b is zero, M has at least two triarylamine units; and n is an integer greater than 1.

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Номер записи: 7

12-04-2012 дата публикации

Alignment film, composition for forming alignment film and liquid crystal display device

Номер: US20120088040A1

Автор: Masaki Matsumori, Noboru Kunimatsu, Yasuo Imanishi, Yasushi Tomioka

Принадлежит: Japan Display East Inc

Disclosed is a liquid crystal display device including: a first substrate and a second substrate, one of which is transparent; a liquid crystal layer disposed between the first substrate and the second substrate; a group of electrodes for applying an electric field to the liquid crystal layer, which is formed on one of the first substrate and the second substrate; a plurality of active elements connected to the group of electrodes; and an alignment film disposed on one of the first substrate and the second substrate, wherein the alignment film contains a polyimide and a precursor of the polyimide, each of which is formed from a diamine and an acid anhydride, and the diamine contains a first diamine having an acidic group and a second diamine having a nitrogen atom-containing functional group other than two amino groups.

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Номер записи: 8

12-04-2012 дата публикации

Electrode for lithium secondary battery and lithium secondary battery including the same

Номер: US20120088150A1

Автор: Cheol-Hee Hwang

Принадлежит: Samsung SDI Co Ltd

An electrode for a lithium secondary battery and a lithium secondary battery including the same, the electrode including a polyamide imide (PAI)-based binder, wherein a 1,3-benzenediamine peak is not observed when a composition including components extracted from the electrode by a solvent capable of dissolving the polyamideimide (PAI)-based binder is analyzed with pyrolysis-gas chromatography (Py-GC) under conditions of a pyrolysis temperature of about 750 to about 780° C., a pyrolysis time of about 5 seconds to about 15 seconds, and increasing a gas chromatography oven temperature from about 40° C. to about 300° C. at a rate of about 10° C./min.

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Номер записи: 9

26-04-2012 дата публикации

Polyimide polyphenylsulfone blends with improved flame resistance

Номер: US20120100324A1

Автор: Mark Sanner, Rajendra K. Singh, Robert Russell Gallucci

Принадлежит: Robert Russell Gallucci, SANNER Mark, Singh Rajendra K

The present disclosure relates to a composition with improved flame resistance, to articles made from the composition, and to methods that include processing the composition. The composition can include from 15 to 85 percent by weight of a polyetherimide (PEI), from 15 to 85 percent by weight of a polyphenylsulfone (PPSU), a polyetherimide-siloxane copolymer in an amount up to 12 percent by weight, and from 0 to 0.30 percent by weight of a stabilizer.

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Номер записи: 10

03-05-2012 дата публикации

Composition for Solid Electrolyte and Solar Cell Using the Same

Номер: US20120104308A1

Автор: Fumiaki Kobayashi, Syuji Okamoto

Принадлежит: Soken Chemical and Engineering Co Ltd

A composition for a solid electrolyte includes a polymer compound (A) and a charge transfer material. The polymer compound (A) is obtained by polymerizing a monomer (a) comprising a monomer (a-2) having chelating ability. The charge transfer material is preferably a carbon material and/or a π-conjugated polymer (β). When a polymer electrolyte layer of a dye-sensitized solar cell is formed from the above solid electrolyte, efficient charge transfer and sufficient charge life can be reconciled with each other.

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Номер записи: 11

03-05-2012 дата публикации

Polyimide precursor solution composition containing filler, and polyimide film using same

Номер: US20120104310A1

Автор: Seiichirou Takabayashi, Takeshige Nakayama, Tomonori Nakayama

Принадлежит: UBE Industries Ltd

There is provided a filler-containing dispersion solution exhibiting very improved filler dispersion stability by dispersing a filler in a solvent using a polyimide precursor solution composition. Furthermore, in the filler-containing dispersion solution, a tetracarboxylic dianhydride and/or its derivative is reacted with a diamine compound to prepare a filler-containing polyimide precursor solution composition, which is then used to provide a polyimide in which a filler is dispersed.

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Номер записи: 12

17-05-2012 дата публикации

Liquid crystal polyimide, liquid crystal resin composition containing same, and resin film for semiconductor elements

Номер: US20120123050A1

Автор: Fumikazu Mizutani, Mitsuru Ueda, Tomohide Murase, Yu Shoji

Принадлежит: Mitsubishi Chemical Corp

A liquid crystal polyimide, containing: repeating units of formula (I) and having liquid crystallinity, wherein A 1 and A 2 are each independently a tetravalent residue of a tetracarboxylic acid, B 1 is a residue of a bis(amino)polysiloxane of formula (II), and C 1 is a residue of an organic diamine, wherein R 1 to R 6 are each independently a lower alkyl group, x is from 0 to 10, D 1 is an alkylene group, y is 0 or 1, and Z 1 is selected from the group consisting of —H, —CH 3 , CF 3 , —F, —CN and —NO 2 . In addition, a liquid crystal resin composition and a resin film for a semiconductor element containing the liquid crystal polyimide.

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Номер записи: 13

17-05-2012 дата публикации

Multifunctional Forms of Polyoxazoline Copolymers and Drug Compositions Comprising the Same

Номер: US20120123055A1

Автор: J. Milton Harris, Kunsang Yoon, Michael David Bentley, Tacey Viegas, Zhihao Fang

Принадлежит: Serina Therapeutics Inc

The present disclosure provides copolymers of 2-substituted-2-oxazolines possessing two or three reactive functional groups which are also chemically orthogonal. The copolymers described may be random copolymers, block copolymers or a mixture of random and block copolymer configurations. Furthermore, the present disclosure provides novel methods for synthesizing the above polymers and for conjugating to molecules such as targeting, diagnostic and therapeutic agents.

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Номер записи: 14

24-05-2012 дата публикации

Resin composition, multilayer body containing the same, semiconductor device, and film

Номер: US20120126393A1

Автор: Kenji Iida

Принадлежит: Mitsui Chemicals Inc

Disclosed is a resin composition which has high heat dissipation properties and high electrical insulation properties at the same time, while having low-temperature bondability to a conductor circuit or the like. The resin composition contains (A) a thermoplastic polyimide resin having a glass transition temperature of 160 DEG C or less and (B) an inorganic filler. The aspect ratio, that is the value of length/thickness, of the inorganic filler (B) is 9 or more, and the content of the inorganic filler (B) is 40-70 weight % relative to the total weight of the resin composition. The resin composition has a melt viscoelasticity of 10-300 MPa (inclusive) at 170 DEG C.

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Номер записи: 15

24-05-2012 дата публикации

Binder for lithium secondary battery, negative electrode for lithium secondary battery, lithium secondary battery, binder precursor solution for lithium secondary battery, and method for manufacturing negative electrode for lithium secondary battery

Номер: US20120129048A1

Автор: Atsushi Fukui, Maruo Kamino, Taizo Sunano, Yoshinori Yoneda

Принадлежит: Sanyo Electric Co Ltd, Shin Etsu Chemical Co Ltd

Provided is a binder capable of realizing a lithium secondary battery that includes a negative electrode including a negative-electrode active material layer containing at least one of silicon and a silicon alloy as a negative-electrode active material and also containing a binder and has an excellent charge-discharge cycle characteristic. The binder for the lithium secondary battery contains a polyimide resin that is formed by imidizing either a tetracarboxylic acid or a tetracarboxylic anhydride and a diamine, the polyimide resin having a hydrolyzable silyl group.

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Номер записи: 16

31-05-2012 дата публикации

Conductive polymer-carbon nanotube composite and manufacturing method thereof

Номер: US20120132863A1

Автор: Johannes Steinmetz, Yung-Woo Park

Принадлежит: SNU R&DB FOUNDATION

Provided are a conductive polymer-carbon nanotube composite including a carbon nanotube and a conductive polymer filled therein, and a method of manufacturing the same. The conductive polymer-carbon nanotube composite where a conductive polymer is filled in a carbon nanotube is manufactured by introducing a monomer of the conductive polymer into the carbon nanotube using a supercritical fluid technique and polymerizing the monomer. The conductive polymer-carbon nanotube composite is a novel nano-structure material which can overcome limitations that conventional materials may have, and thus can be applied to various applications such as sensors, electrode materials, nanoelectronic materials, etc.

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Номер записи: 17

31-05-2012 дата публикации

Pi-conjugated polymer composition

Номер: US20120135255A1

Автор: Norihiro Kuroda, Shingo Onodera

Принадлежит: Idemitsu Kosan Co Ltd

A π-conjugated polymer composition including: (a) a solvent; (b) a π-conjugated polymer which is dissolved in the solvent and doped with a dopant; (c) at least one of an acidic substance and a salt of an acidic substance; and (d) a phenolic compound; wherein when only the acidic substance is contained as the component (c), the acidic substance is different from the phenolic compound, when only the salt of an acidic substance is contained, the salt of an acidic substance is different from the phenolic compound, and when both the acidic substance and the salt of an acidic substance are contained, at least one of the acidic substance and the salt of an acidic substance is different from the phenolic compound.

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Номер записи: 18

21-06-2012 дата публикации

Method for high density data storage and imaging

Номер: US20120155242A1

Автор: Armin W. Knoll, Bernd Walter Gotsmann, Charles Gordon Wade, Erik Christopher Hagberg, James Lupton Hedrick, Jane Elizabeth Frommer, Johannes Windeln, Robert Dennis Miller, Russell Clayton Pratt, Teddie Peregrino Magbitang, Urs T. Duerig, Victor Yee-Way Lee

Принадлежит: International Business Machines Corp

An approach is presented for designing a polymeric layer for nanometer scale thermo-mechanical storage devices. Cross-linked polyimide oligomers are used as the recording layers in atomic force data storage device, giving significantly improved performance when compared to previously reported cross-linked and linear polymers. The cross-linking of the polyimide oligomers may be tuned to match thermal and force parameters required in read-write-erase cycles. Additionally, the cross-linked polyimide oligomers are suitable for use in nano-scale imaging.

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Номер записи: 19

12-07-2012 дата публикации

Solventless one liquid type cyanate ester-epoxy composite resin composition

Номер: US20120178853A1

Автор: Ryo Ogawa, Shinsuke Yamada

Принадлежит: Adeka Corp

The present invention is a solventless one liquid type cyanate ester-epoxy resin composition having high thermal resistance as well as excellent storage stability and curing properties, which contains (A) cyanate ester, (B) epoxy resin, (C) guanidine compounds and (D) at least one kind of phenol compounds selected from a group consisting of phenol compounds represented by the following general formulae. In the general formulae, 1 is an integer selected from 0 to 4, R 1 represents an unsubstituted or fluorine-substituted monovalent hydrocarbon group. General formula:

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Номер записи: 20

19-07-2012 дата публикации

Binder Compositions and Methods for Making and Using Same

Номер: US20120183723A1

Автор: Benjamin D. Gapud, Kelly A. Shoemake, Ramji Srinivasan

Принадлежит: Georgia Pacific Chemicals LLC

Binder compositions and methods for making and using same are provided. The binder composition can include at least one polyamidoamine prepolymer and at least one copolymer. The copolymer can include one or more vinyl aromatic derived units, and one or more unsaturated carboxylic acids, one or more unsaturated carboxylic anhydrides, or a combination thereof. The copolymer can be modified by reaction with one or more base compounds.

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Номер записи: 21

19-07-2012 дата публикации

Optical member and method of producing the same

Номер: US20120183730A1

Автор: Kenji Makino, Tomonari Nakayama

Принадлежит: Canon Inc

Provided is an optical member where at least a layer having polyimide as a main component and a layer having a textured structure arising from a crystal containing aluminum oxide as a main component are stacked in this order. The polyimide includes a silane group in a side chain via an amide bond.

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Номер записи: 22

26-07-2012 дата публикации

Liquid Crystal Alignment Agent, Liquid Crystal Alignment Film Manufactured Using the Same, and Liquid Crystal Display Device Including the Liquid Crystal Alignment Film

Номер: US20120190801A1

Автор: Eun-Ha Kim, Guk-Pyo JO, Jae-Deuk YANG, Jung-Gon CHOI, Myoung-Youp Shin, Yong-Sik Yoo

Принадлежит: Cheil Industries Inc

A liquid crystal alignment agent is provided that includes a polymer including polyamic acid including a repeating unit represented by the following Chemical Formula 1, polyimide including a repeating unit represented by the following Chemical Formula 2, or a combination thereof. In Chemical Formulae 1 and 2, each X 1 , X 2 , Y 1 and Y 2 is the same as in the detailed description.

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Номер записи: 23

02-08-2012 дата публикации

Aromatic polymer ion exchange membranes, its composite membrance, and its application in acidic electrolyte flow battery

Номер: US20120196188A1

Автор: Cheng Bi, Hua Dai, Huamin Zhang, Xianfeng Li

Принадлежит: Dalian Institute of Chemical Physics of CAS, Dalian Rongke Power Co Ltd

A polymer ion exchange membrane for acidic electrolyte flow battery. The membrane is nitrogen heterocycles aromatic polymer, especially polybenzimidazole type polymer. A nitrogen heterocycles in the membrane interact with acid in the electrolyte to form donor-receptor proton transport network, so as to keep the proton transport performance of the membrane. The preparation condition for the membrane is mild, and the process is simplicity. The preparation method is suitable for mass production. The membrane is used in acidic electrolyte flow battery, especially in vanadium flow energy storage battery. The membrane has excellent mechanical stability and thermostability. In vanadium redox flow battery, the membrane has excellent proton conduct performance and excellent resistance to the permeation of vanadium ions.

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Номер записи: 24

30-08-2012 дата публикации

Naphthoxazine benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the polymer, electrolyte membrane for fuel cell including the polymer, and fuel cell using the electrode

Номер: US20120219876A1

Автор: Jungock Park, Seongwoo CHOI

Принадлежит: SAMSUNG ELECTRONICS CO LTD

A naphthoxazine benzoxazine-based monomer is represented by Formula 1 below: In Formula 1, R 2 and R 3 or R 3 and R 4 are linked to each other to form a group represented by Formula 2 below, and R 5 and R 6 or R 6 and R 7 are linked to each other to form a group represented by Formula 2 below, In Formula 2, * represents the bonding position of R 2 and R 3 , R 3 and R 4 , R 5 and R 6 , or R 6 and R 7 of Formula 1. A polymer is formed by polymerizing the naphthoxazine benzoxazine-based monomer, an electrode for a fuel cell includes the polymer, an electrolyte membrane for a fuel cell includes the polymer, and a fuel cell uses the electrode.

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Номер записи: 25

13-09-2012 дата публикации

Semiconductor device

Номер: US20120228784A1

Автор: Tatsu Suzuki

Принадлежит: Sumitomo Bakelite Co Ltd

Disclosed is a semiconductor device configured by encapsulating a semiconductor element, partially or entirely covered with a polyimide, using an epoxy resin composition for encapsulating semiconductor device which contains an epoxy resin (A), a phenol resin (B), a curing accelerator (C), an inorganic filler (D), and a silane coupling agent (E) represented by the formula (1): (in the formula (1), each of R 1 , R 2 and R 3 represents a C 1-4 hydrocarbon group, all of them may be the same or different from each other, and n represents an integer from 0 to 2), and/or a hydrolytic condensate thereof.

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Номер записи: 26

13-09-2012 дата публикации

Thermally and dimensionally stable polyimide films and methods relating thereto

Номер: US20120231257A1

Автор: Brian C. Auman, Kostantinos Kourtakis, Meredith L. Dunbar, Tao He

Принадлежит: EI Du Pont de Nemours and Co

The present disclosure is directed to a polyimide film. The film is composed of a polyimide and a sub-micron filler. The polyimide is derived from at least one aromatic dianhydride component selected from rigid rod dianhydride, non-rigid rod dianhydride and combinations thereof, and at least one aromatic diamine component selected from rigid rod diamine, non-rigid rod diamine and combinations thereof. The mole ratio of dianhydride to diamine is 48-52:52-48 and the ratio of X:Y is 20-80:80-20 where X is the mole percent of rigid rod dianhydride and rigid rod diamine, and Y is the mole percent of non-rigid rod dianhydride and non-rigid rod diamine. The sub-micron filler is less than 550 nanometers in at least one dimension; has an aspect ratio greater than 3:1; is less than the thickness of the film in all dimensions.

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Номер записи: 27

13-09-2012 дата публикации

Coverlay compositions and methods relating thereto

Номер: US20120231263A1

Автор: Brian C. Auman, Kostantinos Kourtakis, Meredith L. Dunbar, Tao He

Принадлежит: EI Du Pont de Nemours and Co

The present disclosure is directed to a coverlay comprising a polyimide film and an adhesive layer. The polyimide film is composed of a polyimide and a sub-micron filler. The polyimide is derived from at least one aromatic dianhydride component selected from rigid rod dianhydride, non-rigid rod dianhydride and combinations thereof, and at least one aromatic diamine component selected from rigid rod diamine, non-rigid rod diamine and combinations thereof. The mole ratio of dianhydride to diamine is 48-52:52-48 and the ratio of X:Y is 20-80:80-20 where X is the mole percent of rigid rod dianhydride and rigid rod diamine, and Y is the mole percent of non-rigid rod dianhydride and non-rigid rod diamine. The sub-micron filler is less than 550 nanometers in at least one dimension; has an aspect ratio greater than 3:1; is less than the thickness of the film in all dimensions.

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Номер записи: 28

27-09-2012 дата публикации

Multilayer resin sheet and method for producing the same, method for producing cured multilayer resin sheet, and highly thermally conductive resin sheet laminate and method for producing the same

Номер: US20120244351A1

Автор: Hideyuki Katagi, Hiroyuki Takahashi, Hiroyuki Tanaka, Kensuke Yoshihara, Masayoshi Joumen, Naoki Hara, Tomoo Nishiyama, Yoshitaka Takezawa

Принадлежит: Hitachi Chemical Co Ltd

A multilayer resin sheet is constituted by including a resin layer containing an epoxy resin having a mesogenic skeleton, a curing agent and an inorganic filler, and an insulating adhesive layer formed on at least either of the surfaces of the resin layer. A cured multilayer resin sheet originated from the multilayer resin sheet has high thermal conductivity, good insulation and adhesive strength, and, further, superior thermal shock resistance, and is suitable as an electric insulating material to be used for an electric or electronic device.

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Номер записи: 29

04-10-2012 дата публикации

Polyamine Polyamidoamine Epihaloohydrin Compositions and Processes for Preparing and Using the Same

Номер: US20120247697A1

Автор: Chen Lu, Danny Nguyen, Scott Rosencrance, Vladimir Grigoriev

Принадлежит: KEMIRA OYJ

Compositions of and processes for preparing a polyamine-polyamidoamine-epihalohydrin resin generally include reacting a first polyamine, a polyamidoamine, and an epihalohydrin to form the polyamine-polyamidoamine-epihalohydrin (PPAE) resin, wherein the polyamidoamine is prepared by reacting a polycarboxylic acid or a polycarboxylic acid derivative with a second polyamine to form the polyamidoamine, wherein a molar ratio of the polyamine to the polycarboxylic acid is 1.05 to 2.0. The PPAE resin can be used in an adhesive formulation for use in creping applications for forming paper products such as tissue products.

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Номер записи: 30

04-10-2012 дата публикации

Positive type photosensitive resin composition

Номер: US20120251949A1

Автор: Tomotsugu MIYABE, Yoji Fujita

Принадлежит: TORAY INDUSTRIES INC

Disclosed is a positive-type photosensitive resin composition which has excellent storage stability, particularly excellent sensitivity stability, and can be formed into a cured film having excellent adhesion onto a substrate when heated at 350° C. or higher or heated in the air. The positive-type photosensitive resin composition comprises (a) a polymer having, as the main component, at least one structure selected from the group consisting of a polyimide precursor structure, a polybenzoxazole precursor structure, and a polyimide structure, (b) a quinonediazide compound, (c) a silane coupling agent having a styryl group, (d) a silane coupling agent having an epoxy group, an oxetanyl group, a methacryloxy group, an acryloxy group, an amino group, an amide group or mercapto group and an alkoxysilyl group, and (e) a solvent.

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Номер записи: 31

25-10-2012 дата публикации

Conformations of divergent peptides with mineral binding affinity

Номер: US20120270811A1

Автор: Cherng-Chyi Tzeng, Gwo-Jaw Wang, Hui-Ting Chen, Je-Ken Chang, Kuang-Chan Hsieh, Mei-Ling Ho, Yin-Chih Fu

Принадлежит: KAOHSIUNG MEDICAL UNIVERSITY

A series of peptides with divergent confirmations including structures of formula (1A), (1B), (2) and (3) are provided. In the formula, wherein U, G, A, B, R1, R2 and T are as defined in the specification. The divergent peptides disclosed in the present invention are characterized in a mineral binding affinity function.

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Номер записи: 32

01-11-2012 дата публикации

Polyimide resins for high temperature wear applications

Номер: US20120273731A1

Автор: Jesus G. Moralez, Lloyd Abrams, Robert Ray Burch, Timothy D. Krizan

Принадлежит: EI Du Pont de Nemours and Co

Polyimide resin compositions that contain an end-capped rigid aromatic polyimide, graphite and, optionally, a filler selected from sepiolite, attapulgite, kaolinite, or a mixture thereof, are found to exhibit low wear at high temperatures. Such compositions are especially useful in molded articles that are exposed to wear conditions at high temperatures such as aircraft engine parts.

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Номер записи: 33

22-11-2012 дата публикации

Polymide resin composition, adhesive agent and laminate each comprising same, and device

Номер: US20120295085A1

Автор: Kenji Iida, Kiyomi Imagawa, Yusuke Tomita

Принадлежит: Mitsui Chemicals Inc

Provided are a polyimide resin composition containing a polyimide obtained by the condensation of: a diamine component containing an aromatic diamine (A) represented by the general formula (1-1) or the like, a silicone diamine (B) represented by the general formula (2) and an aliphatic diamine (C) represented by the general formula (3); and an acid anhydride component containing a specific aromatic tetracarboxylic dianhydride (D); and a laminate and a device using the polyimide resin composition.

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Номер записи: 34

29-11-2012 дата публикации

heat sealable substrate and a process for making the same

Номер: US20120302660A1

Автор: Dirk Stanssens, Eric Jonsson

Принадлежит: TOPCHIM NV

A process for applying a heat sealable layer to a substrate in which the substrate is provided with a coating composition containing a cyclic imide, which can be a maleimide, an itaconimide, a citraconimide or a 2,3 dialkyl maleimide. Preferably the coating composition is brought on the substrate from a water borne formulation in which the coating composition containing a cyclic imide is dispersed in the water phase and the coating composition containing a cyclic imide is a copolymer of cyclic imides and vinylic co-monomers, preferably a co-polymer of cyclic imides and styrene. The dispersed product in the water phase has a particle size between 20 and 500 nm, preferably between 30 and 200 nm, and the particles have a core-shell structure.

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Номер записи: 35

29-11-2012 дата публикации

Novel Polyazomethine

Номер: US20120302720A1

Автор: Hikaru Meguro, Syuji Okamoto

Принадлежит: Soken Chemical and Engineering Co Ltd

Provided is a novel polyazomethine which is soluble in relatively versatile organic solvents including hydrophobic solvents such as toluene, alcohol solvents such as methanol and ethanol, glycol solvents such as propylene glycol monomethyl ether, and ester solvents such as methyl lactate, while securing carrier mobility sufficient for a semiconductor material. The polyazomethine is a repeating unit that contains a divalent aromatic ring-containing conjugated group wherein an azomethine group and a divalent aromatic group which may have a substituent are alternately bonded and conjugated and a divalent hydrocarbon group which may have a group that is not conjugated with the azomethine group and has an oxygen atom, a sulfur atom or a cycloalkylene group, with the aromatic ring-containing conjugated group and the hydrocarbon group being bonded with each other via the azomethine group.

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Номер записи: 36

06-12-2012 дата публикации

Polymers for reversing heparin-based anticoagulation

Номер: US20120308546A1

Автор: Cedric J. Carter, Donald E. Brooks, Jayachandran N. Kizhakkedathu, Rajesh A. Shenoi

Принадлежит: University of British Columbia

Embodiments presented herein relate to various polymers. Some of the polymer embodiments are heparin binding polymers. Some embodiments of the heparin binding polymers can be employed to bind to heparin for methods such as separating, purifying, removing, and/or isolating heparin and heparin like molecules.

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Номер записи: 37

13-12-2012 дата публикации

Laminate structure, method for manufactuing laminate structure, electronic element array, image displaying medium, image displaying apparatus, diamine, polyamic acid, and polyimide

Номер: US20120315498A1

Автор: Koei Suzuki, Takanori Tano, Yusuke Tsuda

Принадлежит: Ricoh Co Ltd

Disclosed is a laminate structure including a substrate, a wettability changing layer, and an electrical conductor layer, wherein the wettability changing layer and the electrical conductor layer are laminated on the substrate in order, wherein the wettability changing layer contains a polyimide, wherein the polyimide is obtainable by dehydrating and ring-opening a polyamic acid, wherein the polyamic acid is obtainable by ring-opening and addition-polymerizing a diamine and a tetracarboxylic acid dianhydride, wherein the diamine includes a compound represented by a general formula of: or a compound represented by a general formula of: wherein each of R 1 and R 2 in formula ( 1 ) is defined in the specification, and wherein R 1 in formula ( 2 ) is defined in the specification.

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Номер записи: 38

13-12-2012 дата публикации

Method for Producing Curing Agent Having Acidic Substituent and Unsaturated Maleimide Group, Thermosetting Resin Composition, Prepreg, and Laminate

Номер: US20120316263A1

Автор: Hikari Murai, Masanori Akiyama, Shinji Tsuchikawa

Принадлежит: Individual

A method for producing a curing agent having an acidic substituent and an unsaturated maleimido group, including reacting, in an organic solvent, a maleimide compound (a) having at least two N-substituted maleimido groups in a molecule thereof with an amine compound (b) having an acidic substituent (represented by formula (I) below); a thermosetting resin composition containing the curing agent (A) produced through the method and a compound (B) which is cured with the curing agent, wherein a cured product of the composition has a glass transition temperature of 200° C. or higher; and a prepreg and a laminated sheet produced therefrom. The thermosetting resin composition can produce a prepreg or laminated sheet exhibiting excellent performance suitable for a printed wiring board for electronic devices and similar devices.

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Номер записи: 39

13-12-2012 дата публикации

Photoaligning material with lateral substitution

Номер: US20120316317A1

Автор: Andreas Schuster, Jean-François ECKERT, Satish Palika

Принадлежит: ROLIC AG

The present invention relates to photoaligning material with lateral substitution, compositions thereof, and its use for optical and electro optical devices, especially liquid crystal devices (LCDs).

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Номер записи: 40

03-01-2013 дата публикации

Polymer compound and polymer light emitting device using the same

Номер: US20130002989A1

Автор: Hidenobu Kakimoto, Takanobu Noguchi, Tomoyuki Suzuki

Принадлежит: Sumitomo Chemical Co Ltd

A polymer compound containing a structure of the following formula (B): —Ar— (A) (wherein, Ar represents an arylene group, divalent heterocyclic group, divalent aromatic amine group or divalent group having a metal complex structure.) (wherein, A ring and B ring represent each independently an aromatic ring optionally having a substituent. X 1 represents —C(═O)—, —S(═O)—, —S(═O) 2 —, —P(═O)(R 1 )—, —C(R 1 )(R 2 )—, —C(R 2 )(R 2 )—, —B(R 1 )—, —N(R 1 )— or —Si(R 1 )(R 1 )—. R* represents a hydrogen atom or monovalent or divalent group, R 1 represents a hydrogen atom or monovalent group, and R 2 represents a monovalent group having a hetero atom. When R 1 and R 2 are present each in plural number, they may be the same or different.).

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Номер записи: 41

03-01-2013 дата публикации

Polyetherimide resins with very low levels of residual contamination

Номер: US20130003227A1

Автор: Aaron ROYER, Daniel Francis Lowery, Jamuna Chakravarti

Принадлежит: SABIC INNOVATIVE PLASTICS IP BV

Compositions and methods for producing compositions comprising a monoamine-endcapped polyimide component. Based on a gas chromatography mass spectroscopy analysis of a surface rinse of the composition performed at room temperature, the composition can have at least one surface with less than or equal to 5 ppb releasable phosphorous residuals, and less than or equal to 5 ppb releasable volatile organic compound residuals. The composition can also comprise less than or equal to 10 ppb combined releasable residuals. Because of the very low levels of residual contamination, the compositions can be used to produce a variety of articles, including a disk drive.

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Номер записи: 42

10-01-2013 дата публикации

2,4,5-triaminophenols and related compounds

Номер: US20130012679A1

Автор: David J. Rodini, Frederick K. Mallon, Joachim C. Ritter, Rajiv Dhawan, Roger K. Siamionko, Steven R. Allen

Принадлежит: EI Du Pont de Nemours and Co

New triaminophenol compositions and related compounds are disclosed, as are processes for their preparation and for the preparation of novel salts and diacid complexes from such compounds. Polymers prepared from these compositions can be made into high strength fiber, film, and tape and are useful in applications such as protective apparel, aircraft, automotive components, personal electronics, and sports equipment.

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Номер записи: 43

10-01-2013 дата публикации

2,4,5-triaminophenols and related compounds

Номер: US20130012681A1

Автор: Joachim C. Ritter, Rajiv Dhawan

Принадлежит: EI Du Pont de Nemours and Co

New triaminophenol compositions and related compounds are disclosed, as are processes for their preparation and for the preparation of novel salts and diacid complexes from such compounds. Polymers prepared from these compositions can be made into high strength fiber, film, and tape and are useful in applications such as protective apparel, aircraft, automotive components, personal electronics, and sports equipment.

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Номер записи: 44

24-01-2013 дата публикации

Composition, composite membrane prepared from composition, fuel cell including the composite membrane, and method of manufacturing the composite membrane

Номер: US20130022893A1

Автор: Pil-Won Heo, Takashi Hibino, Yong-Cheng Jin

Принадлежит: SAMSUNG ELECTRONICS CO LTD

A composite membrane containing a composite material including an azole-based polymer and a compound represented by Formula 3 below, a method of preparing the composite membrane, and a fuel cell including the composite membrane: M 1 1-a M 2 a P x O y <Formula 3> wherein, in Formula 3, M 1 is a tetravalent metallic element; M 2 is at least one metal selected from the group consisting of a monovalent metallic element, a divalent metallic element, and a trivalent metallic element; a satisfies 0≦a<1; x is a number from 1.5 to 3.5; and y is a number from 5 to 13.

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Номер записи: 45

07-02-2013 дата публикации

Thermal expansion control employing platelet fillers

Номер: US20130035411A1

Автор: Gareth G. Hougham, Xiao H. Liu

Принадлежит: International Business Machines Corp

Bilayer platelet fillers are employed to compensate for a positive coefficient of thermal expansion (CTE) of an embedding polymeric material, or even to provide a composite structure having a negative CTE to eliminate or alleviate thermomechanical stress and/or delamination during thermal cycling. A bilayer platelet includes two joined layers having different CTEs. The CTE mismatch induces bending of the bilayer platelets, thereby causing cavities at temperatures lower than the joining temperature at which the bilayers are joined. The decrease in the volume of the polymeric material and the bilayer platelets at low temperatures is compensated by an accompanying increase in the volume of the cavities so that the composite structure has a temperature independent volume, a low net CTE, or even a negative CTE.

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Номер записи: 46

14-02-2013 дата публикации

Synthesis and application reactive antimicrobial copolymers for textile fibers

Номер: US20130036558A1

Автор: Jason J. Locklin

Принадлежит: Individual

Embodiments of the present disclosure provide polymer compositions, methods of making polymer compositions, structures (e.g., textile articles) having the polymer composition covalently bonded to the structure, methods of attaching the polymer to the surface of the structure, methods of decreasing the amount of microorganisms formed on a structure, and the like.

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Номер записи: 47

14-02-2013 дата публикации

Poly (sulfoaminoanthraquinone) materials and methods for their preparation and use

Номер: US20130037487A1

Автор: Mei-rong Huang, Shao-jun Huang, Xin-Gui Li

Принадлежит: TONGJI UNIVERSITY

Poly(sulfoaminoanthraquinone) polymer compositions and methods of making these compositions are disclosed herein. The polymer compositions can, for example, be used for removing metal ions from a sample.

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Номер записи: 48

14-02-2013 дата публикации

Cytostatic drug composition

Номер: US20130040388A1

Автор: Oskar Schmidt

Принадлежит: Individual

A drug composition containing as a drug substance a polymeric guanidine derivative based on a diamine containing oxyalkylene chains between two amino groups, with the guanidine derivative representing a product of polycondensation between a guanidine acid addition salt and a diamine containing polyalkylene chains between two amino groups, as well as the pharmaceutically acceptable salts thereof.

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Номер записи: 49

14-02-2013 дата публикации

Methods for preparing polyethylene glycol maleimide using n-(2-hydroxyethyl) maleimide as a starting material

Номер: US20130041134A1

Автор: John R. Handley, Jonathon B. McKannan

Принадлежит: Sangart Inc

The present invention relates generally to methods for preparing polyethylene glycol maleimide (“PEG-Mal”). More specifically, the present invention relates to methods for synthesizing desired molecular weight PEG-Mal by direct ethoxylation of N-(2-hydroxyethyl)maleimide under specific reaction conditions.

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Номер записи: 50

28-02-2013 дата публикации

Porous abpbi [poly (2, 5-benzimidazole)] membrane and process of preparing the same

Номер: US20130053467A1

Автор: Harshada Lohokare, Ulhas Kharul

Принадлежит: Council of Scientific and Industrial Research CSIR

The present invention relates to a porous ABPBI (phosphoric acid doped poly(2,5-benzimidazole)) membrane and process of preparing the same. A stable porous ABPBI (Phosphoric Acid Doped Poly(2,5-benzimidazole)) membrane stable to acids, bases, solvents and autoclaving is disclosed. The membrane finds use for separation of solutes in solution in acids, bases and solvents

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Номер записи: 51

28-02-2013 дата публикации

Polyetherimide compositions and methods for the manufacture and use thereof

Номер: US20130053489A1

Автор: James A. Mahood, Robert R. Gallucci, Roy R. Odle, Steve Dimond

Принадлежит: SABIC INNOVATIVE PLASTICS IP BV

This disclosure relates to polyetherimide compositions whose residual phenolic monomers exhibit little or no estradiol binding activity. Also disclosed are methods for making the disclosed polyetherimides and articles of manufacture comprising the disclosed polyetherimides.

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Номер записи: 52

07-03-2013 дата публикации

Copolymer, organic solar cell using the same and manufacturing method thereof

Номер: US20130056073A1

Автор: Gang-Young LEE, Hangken LEE, Jaechol LEE, Jaesoon BAE, Jinseok Kim, Minjeong IM, Seulki SONG, Taiho Park

Принадлежит: Academy Industry Foundation of POSTECH, LG Chem Ltd

Disclosed herein are a 3,6-carbazole-containing copolymer, an organic solar cell comprising the copolymer in an organic material layer including a photoactive layer, and a method for fabricating the organic solar cell.

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Номер записи: 53

21-03-2013 дата публикации

Aliphatic-aromatic copolyesters and their mixtures

Номер: US20130071588A1

Автор: Catia Bastioli, Giampietro Borsotti, Luigi Capuzzi, Roberto Vallero, Tiziana Milizia

Принадлежит: Novamont SpA

This invention relates to an aliphatic-aromatic copolyester characterised in that it has appreciable workability properties even when mixed with other polymers, appreciable toughness and high values for ultimate tensile strength and elastic modulus. This invention also relates to mixtures of the said copolyester with other polymers.

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Номер записи: 54

28-03-2013 дата публикации

WATER-SOLUBLE POLYMER AND WATER-SOLUBLE NANOPARTICLE COMPOSITE

Номер: US20130075665A1

Автор: Higasa Masashi, Park Joonsik, Sogame Asako

Принадлежит: Toray Industries, Inc.

A water-soluble nanoparticle complex has a plurality of accumulated nanoparticles and has excellent uniformity and stability by forming a complex of nanoparticles using a water-soluble polymer and which allows for use of nanoparticles in biochemical applications. 2. The water-soluble polymer according to claim 1 , wherein x claim 1 , y claim 1 , and z satisfy x+y+z=10 to 350.3. The water-soluble polymer according to claim 1 , wherein at least one end of a polymer main chain composed of the repeating units of Formulas (1) claim 1 , (2) claim 1 , and (3) comprises at least one functional group selected from the group consisting of —NH claim 1 , —COOH claim 1 , —OH claim 1 , —SH claim 1 , —CHO claim 1 , and biotinyl.4. The water-soluble polymer according to claim 3 , comprising —(OCHCH)— (wherein p is an integer from 1 to 120) as a spacer between said polymer main chain and said functional group.5. A water-soluble nanoparticle complex claim 1 , comprising the water-soluble polymer according to and nanoparticles.6. The water-soluble nanoparticle complex according to claim 5 , wherein said water-soluble nanoparticle complex has an average particle size of 10 to 300 nm.7. The water-soluble nanoparticle complex according to claim 5 , wherein said nanoparticles have luminescence properties claim 5 , plasmon absorption properties claim 5 , or magnetic properties.8. The water-soluble nanoparticle complex according to claim 5 , wherein said nanoparticles are semiconductor nanoparticles.9. The water-soluble nanoparticle complex according to claim 8 , wherein said semiconductor nanoparticles are semiconductor nanoparticles comprising at least a Group 12 element of the periodic table and a Group 16 element of the periodic table claim 8 , semiconductor nanoparticles comprising a Group 11 element of the periodic table claim 8 , a Group 13 element of the periodic table claim 8 , and a Group 16 element of the periodic table claim 8 , or semiconductor nanoparticles comprising a Group ...

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Номер записи: 55

28-03-2013 дата публикации

AMINOBENZENE COMPOSITIONS AND RELATED DEVICES AND METHODS

Номер: US20130075670A1

Автор: Brown Christopher T., Seshadri Venkataramanan, Wang Jing

Принадлежит: Plextronics, Inc.

Oligomers and/or polymers comprising a backbone comprising arylamine and fluorinated alkyleneoxy moieties which may be crosslinked. Ink formulations and devices can be formed from the oligomers or polymers, or corresponding monomers. Doped compositions can be formed. Charge injection and transport layers can be formed. Improved stability can be achieved in organic electronic devices such as OLEDs and OPVs. 1. A composition comprising a polymeric or oligomeric backbone comprising at least one repeat moiety comprising at least one O-arylamine , and at least one repeat moiety comprising at least one fluorinated alkyleneoxy.2. The composition of claim 1 , wherein the repeat moiety comprising O-arylamine and the repeat moiety comprising fluorinated alkyleneoxy are alternating moieties.3. The composition of claim 1 , wherein the O-arylamine comprises triarylamine.4. The composition of claim 1 , wherein the O-arylamine moiety comprises at least two nitrogen atoms.5. The composition of claim 1 , wherein the fluorinated alkyleneoxy comprises a C-Calkylene ether.6. The composition of claim 1 , wherein the fluorinated alkyleneoxy comprises a fluorinated C-Cvinyl ether.7. The composition of claim 1 , wherein the fluorinated alkyleneoxy comprises a trifluoroalkyleneoxy moiety.8. The composition of claim 1 , wherein the composition comprises a soluble claim 1 , linear polymer comprising the O-arylamine and the fluorinated alkyleneoxy.9. The composition of claim 1 , wherein the composition is crosslinked.10. An oligomer or polymer comprising repeat units represented by{'br': None, 'sup': '1', '\ue8a0O—Ar\ue8a0 and\u2003\u2003(I)'}{'br': None, 'sup': 1', '2', '2, '\ue8a0O—R—O—Ar—O—R\ue8a0\u2003\u2003(II)'}wherein,{'sup': '1', 'Arcomprises arylamine,'}{'sup': '2', 'Arcomprises an aryl, and'}{'sup': 1', '2, 'sub': 1', '10, 'Rand Rare independently selected from C-Cfluorinated alkylenes.'}11. The oligomer or polymer of claim 10 , wherein the repeat units (I) and (II) are alternating. ...

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Номер записи: 56

28-03-2013 дата публикации

Compound, Composition, and Method for Protecting Skin from High Energy Visible Light

Номер: US20130078205A1

Автор: Dayan Nava, Gallas James M.

Принадлежит:

A compound, composition, and method for the protection of skin from the harmful effects of radiation, and particularly the harmful effects of high energy visible (HEV) radiation, are disclosed. The compound is a melanin derivative that can be formulated into compositions containing the melanin derivative and a suitable carrier. The composition is topically applied to the skin to reduce the risk of photoaging and improve skin repair due to damage from radiation. 1. A melanin derivative having a high HEV absorption and a low absorption of red light , a ratio of optical density at 440 nm to optical density at 600 nm of 10 or greater , and a molecular weight of 500 to about 10 ,000 Daltons.2. The melanin derivative of wherein the melanin derivative is produced by oxidative bleaching of melanin.3. The melanin derivative of wherein the melanin derivative is produced by fractionation of melanin.4. The melanin derivative of wherein the melanin derivative is produced by oxidative bleaching and fractionation of melanin.5. The melanin derivative of prepared from a melanin treated with enzymes and/or from a melanin and a co-polymerizing agent that reduces electronic delocalization of melanin oligomers.6. The melanin derivative of wherein the melanin is a synthetic melanin.7. The melanin derivative of wherein the co-polymerizing agent comprises a sulfur-containing amino acid.8. The melanin derivative of wherein the enzyme is selected from the group consisting of tyrosinase claim 5 , TRP1 (5 claim 5 ,6-dihydroxyindole-5-carboxylic acid oxidase) claim 5 , TRP2 (dopachrome tautomerase) claim 5 , and mixtures thereof.9. A composition comprising{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(a) a melanin derivative of ; and'}(b) a cosmetically acceptable carrier for applying the composition topically to skin.10. The composition of comprising about 0.001% to about 15% of the melanin derivative claim 9 , by weight of the composition.11. The composition of further comprising at ...

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Номер записи: 57

28-03-2013 дата публикации

Catalysis of cross-linking

Номер: US20130079479A1

Автор: Daniel RÖME, David Persson, Erik Lager, Jan-Erik Rosenberg

Принадлежит: NEXAM CHEMICAL AB

Disclosed is use of catalysts for chain extension and/or cross-linking of oligomers or polymers comprising carbon-carbon triple bonds.

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Номер записи: 58

28-03-2013 дата публикации

NORBORNANE-2-SPIRO-alpha-CYCLOALKANONE-alpha'-SPIRO-2''-NORBORNANE-5,5'',6,6''-TETRACARBOXYLIC DIANHYDRIDE, NORBORNANE-2-SPIRO-alpha-CYCLOALKANONE-alpha'-SPIRO-2''-NORBORNANE-5,5'',6,6''-TETRACARBOXYLIC ACID AND ESTER THEREOF, METHOD FOR PRODUCING NORBORNANE-2-SPIRO-alpha-CYCLOALKANONE-alpha'-SPIRO-2''-NORBORNANE-5,5'',6,6''-TETRACARBOXYLIC DIANHYDRIDE, POLYIMIDE OBTAINED BY USING THE SAME, AND METHOD FOR PRODUCING POLYIMIDE

Номер: US20130079490A1

Автор: Shinichi Komatsu, Toshihiko Matsumoto

Принадлежит: JX Nippon Oil and Energy Corp

A norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic dianhydride represented by the following general formula (1): [in the formula (1), n represents an integer of 0 to 12, and R 1 s, R 2 , R 3 each independently represents a hydrogen atom or the like].

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Номер записи: 59

04-04-2013 дата публикации

MODIFIED POLYMER SUBSTRATE AND METHOD FOR PRODUCING THE SAME, AND SURFACE TREATMENT AGENT

Номер: US20130084428A1

Автор: EGAWA Shuichi, HAYASHI Yousuke

Принадлежит: TOKAI RUBBER INDUSTRIES, LTD.

To provide a modified polymer substrate that has both excellent releasability from an accretion adhering to a surface of the substrate and functions for intended use other than releasability, and to provide a method for producing the modified polymer substrate. A modified polymer substrate (1) includes a polymer substrate (2) containing an organic component having unsaturated carbon-to-carbon double bonds, and an organic group having a functional group (R) arranged to provide functions to a surface of the polymer substrate, wherein the organic group is bonded to the surface of the polymer substrate via an isocyanuraic acid backbone by bringing a treatment solvent (3) that contains (a) a trichloroisocyanuric acid and (b) a compound having an unsaturated carbon-to-carbon double bond and an organic group having a functional group (R) arranged to provide functions to the surface of the polymer substrate into contact with the surface of the polymer substrate. 1. A modified polymer substrate , the substrate comprising:a polymer substrate; andan organic group having a functional group arranged to provide functions to a surface of the polymer substrate,wherein the organic group is bonded to the surface of the polymer substrate via an isocyanuric acid backbone.2. The modified polymer substrate according to claim 1 , wherein the functional group comprises one or more than one kind of functional group selected from the group consisting of a silicone group claim 1 , a fluorine-containing group claim 1 , a perfluoroalkyl group claim 1 , an ester group claim 1 , an amide group claim 1 , an imide group claim 1 , an ether group claim 1 , an aryl group claim 1 , an azo group claim 1 , a diazo group claim 1 , a nitro group claim 1 , an epoxy group claim 1 , a carbonyl group claim 1 , a heterocyclic group claim 1 , a mesoionic group claim 1 , a halogen group claim 1 , an amino group claim 1 , an imino group claim 1 , an alkyl group claim 1 , a sulfonic acid group claim 1 , a hydroxyl ...

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Номер записи: 60

04-04-2013 дата публикации

Polyimide porous web, method for manufacturing the same, and electrolyte membrane comprising the same

Номер: US20130084515A1

Автор: Heung Ryul Oh, Yun Kyung Kang

Принадлежит: Kolon Fashion Material Inc

Disclosed is a polyimide porous web with good porosity, good dimensional stability, and uniform pore; a method for manufacturing the same; and an electrolyte membrane with improved ion conductivity and good dimensional stability owing to ion conductors uniformly impregnated in the porous web, the polyimide porous web having a porosity of 60% to 90%, wherein not less than 80% of entire pores of the porous web have a pore diameter which differs from an average pore diameter of the porous web by not more than 1.5 μm.

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Номер записи: 61

04-04-2013 дата публикации

Porous polymer supported polyoxometalates

Номер: US20130085191A1

Автор: Matthew Laskoski

Принадлежит: US Department of Navy

A composition for the destruction of chemical warfare agents and toxic industrial chemicals having a polyoxometalate (POM) attached to an amine, carboxylic acid, or ammonium substituted porous polymer. Also disclosed is a method for attaching a POM to an amine, carboxylic acid, or ammonium substituted porous polymer by (1) dissolving the POM in water or an organic solvent, adding the functionalized porous polymer, whereby the POM ionically attaches to the amine, carboxylic acid or ammonium group, or (2) heating the POM and functionalized polymer in the presence of a dehydrating agent whereby an imide bond is produced between the POM and the functionality on the porous polymer.

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Номер записи: 62

04-04-2013 дата публикации

Fluorinated Diamine and Polymer Formed Therefrom

Номер: US20130085237A1

Автор: Hagiwara Yuji, Narizuka Satoru, YAMANAKA Kazuhiro

Принадлежит:

Polymer compounds derived from fluorine-containing diamine compounds represented by formula (1). 2. A polymer compound obtained by subjecting a polymer compound according to to dehydration and ring closure. This application is a division of co-pending application Ser. No. 12/519,428, which was the US national stage of international application no. PCT/JP2007/071980, filed Nov. 13, 2007. Priority is claimed based on Japanese patent application no. JP 2006-341834, filed Dec. 19, 2006.The present invention relates to a novel, fluorine-containing, rigid diamine and novel polymer compounds using the same.Polyamide and polyimide have been developed as representatives of organic polymers having high-degree heat resistance. They form a large market in electronic device field, engineering plastic field such as automotive and aerospace uses, fuel cell field, medical material field, optical material field, etc. At their center, many various polymers are put into practical use, such as polyamide represented by nylon, KEVLAR, etc.; polyamide acid and polyimide, which can be representative heat-resistant polymers; polyamide imide, which is a composite of them; and polybenzoxazole, polybenzthiazole, polybenzimidazole, etc. In particular, polyimide is again recently attracting attention as a material that is resistant to a lead-free solder step.Polymerization of many of these heat-resistant polymers is conducted by successively generating a reaction, such as polyaddition or polycondensation, using plural types of monomers having a bifunctional or trifunctional reactive group in the molecule.Regarding combinations of monomers in polymerization, there are known, in the case of polyamide, a method in which a diamine-type monomer is condensed with dicarboxylic acid or a dicarboxylic acid derivative, such as acid chloride or ester, and, in the case of polyamide acid or polyimide, a method by a polyaddition of diamine and acid dianhydride. As diamines that are generally used, aliphatic ...

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Номер записи: 63

04-04-2013 дата публикации

CROSSLINKABLE ARYLAMINE COMPOUNDS AND CONJUGATED OLIGOMERS OR POLYMERS BASED THEREON

Номер: US20130085258A1

Автор: "OBrien James J.", GAYNOR Scott, INBASEKARAN Michael, Welsh Dean M.

Принадлежит: Sumitomo Chemical Company, Limited

Crosslinkable arylamine compounds, oligomers and polymers prepared from such crosslinkable arylamine compounds, films and coatings, and multilayer electronic devices comprising such films are disclosed. 1. An oligomer or polymer having one or more repeating groups of the formula:{'br': None, 'sub': n', 'n′, 'Z′—(Ar—NX′)—Ar—(NX′—Ar)—Z′,\u2003\u2003(Ia)'}where X′ is X or a divalent crosslinked remnant formed by addition polymerization of a crosslinkable X group;Z′ is Z, a covalent bond, or a terminal group formed by replacement or reaction of a leaving group;Ar independently each occurrence is a divalent aromatic group, and optionally two Ar groups separated by a single NX group may be joined together by a second covalent bond or by a bridging group, thereby forming a fused multiple ring system;X is an inert substituent or a crosslinkable group, with the proviso that in at least one occurrence in said compound, X is a crosslinkable group;Z independently each occurrence is hydrogen or a leaving group,n is 1 or 2; andn′ is 0, 1 or 2.2. An oligomer or polymer according to wherein X in at least one occurrence is 1-benzo-3 claim 1 ,4-cyclobutane or 4-phenyl-1-(benzo-3 claim 1 ,4-cyclobutane).5. A crosslinked polymer according to wherein X′ in at least one occurrence is a divalent crosslinked remnant formed by addition polymerization of a crosslinkable X group.6. A crosslinked polymer according to claim 5 , wherein X′ comprises conjugated unsaturation.7. A process for preparing oligomers or polymers according to claim 10 , which comprises heating a composition comprising {'br': None, 'sub': n', 'n′, 'Z—(Ar—NX)—Ar—(NX—Ar)—Z,\u2003\u2003(I)'}, 'An arylamine compound of the formulawherein,Ar independently each occurrence is a group comprising one or more divalent aromatic groups, and optionally two Ar groups separated by a single NX group may be joined together by a second covalent bond or by a bridging group, thereby forming a fused multiple ring system;X is an inert ...

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Номер записи: 64

11-04-2013 дата публикации

Hydrophilic gels from polyurethane-based photoinitiators

Номер: US20130089582A1

Автор: Christian B. Nielsen, Niels Joergen Madsen

Принадлежит: Coloplast AS

The present invention relates to the use of polymeric photoinitiators based on polyalkyletherurethane backbones in the production of hydrophilic gels, in particular hydrogels. The invention relates to methods for manufacturing hydrophilic gels using said polymeric photoinitiators, and the hydrophilic gels thus obtained.

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Номер записи: 65

11-04-2013 дата публикации

SYNTHESIS SYSTEM, RUBBER CHEMICAL SUBSTANCE FOR TIRES, SYNTHETIC RUBBER FOR TIRES, AND PNEUMATIC TIRE

Номер: US20130090445A1

Автор: Fujikura Keitaro, HATTORI Takayuki, Matsuo Toshiro, WADA Takao, YOKOYAMA Yuka

Принадлежит: SUMITOMO RUBBER INDUSTRIES, LTD.

The present invention provides a synthesis system that can synthesize aniline and/or styrene efficiently, a synthesis system that can synthesize butadiene (1,3-butadiene) efficiently, a rubber chemical for a tire which is synthesized from the aniline obtained by the synthesis system, a synthetic rubber for a tire which is synthesized from the styrene and/or butadiene obtained by the synthesis systems, and a pneumatic tire produced using the rubber chemical for a tire and/or the synthetic rubber for a tire. The present invention relates to a synthesis system for synthesizing aniline and/or styrene from an alcohol having two or more carbon atoms via an aromatic compound. 1. A synthesis system for synthesizing at least one of aniline and styrene from an alcohol having two or more carbon atoms via an aromatic compound.2. The synthesis system according to claim 1 ,wherein the alcohol is ethanol.3. The synthesis system according to claim 2 ,wherein the ethanol is bioethanol.4. The synthesis system according to claim 1 ,wherein the aromatic compound is benzene.5. The synthesis system according to claim 4 ,wherein the benzene is synthesized via at least one of toluene and xylene.6. The synthesis system according to claim 1 ,wherein the aromatic compound is synthesized via an alkene.7. The synthesis system according to claim 1 ,wherein the synthesis system is adapted to subject the alcohol to catalysis by a solid acid catalyst.8. The synthesis system according to claim 7 ,wherein the solid acid catalyst is at least one selected from the group consisting of zeolites, alumina, and titanium compounds.9. The synthesis system according to claim 7 ,wherein the solid acid catalyst is an MFI-type zeolite.10. The synthesis system according to claim 1 ,wherein the synthesis system is adapted to subject the alcohol to catalysis by a solid acid catalyst to give a reaction product, andcirculate the reaction product so that it is further subjected to catalysis by the solid acid catalyst. ...

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Номер записи: 66

18-04-2013 дата публикации

PHOTOSENSITIVE POLYMIDES

Номер: US20130095426A1

Автор: CHOU Meng-Yen, LEE Chuan-Zong

Принадлежит: ETERNAL CHEMICAL CO., LTD.

The invention pertains to an isocyanate-modified photosensitive polyimide. The photosensitive polyimide of the invention possesses excellent heat resistance, chemical resistance and flexibility, and can be used in a liquid photo resist composition or dry film photo resist composition, or used in a solder resist, coverlay film, or printed wiring board. 12. A photosensitive composition claim 1 , which comprises claim 1 , based on the total weight of the composition claim 1 , at least 1% by weight of the photosensitive polyimide according to and at least one photoinitiator.13. The photosensitive composition according to claim 12 , further comprising a reactive monomer or oligomer.14. The photosensitive composition according to or claim 12 , which is a liquid photo resist composition or a solid dry film photo resist composition. The invention relates to an isocyanate-modified photosensitive polyimide. The photosensitive polyimide of the invention possesses excellent heat resistance, chemical resistance and flexibility, and can be used in a liquid photo resist composition or dry film photo resist composition, or used in a solder resist, coverlay film, or printed wiring board.Electronic products recently have more and more miniaturized and lighter in weight. In accordance with this, various electronic parts are required to be downsized. Based on the ground that flexible printed wiring boards have the advantage of flexibility and light weight, their demand greatly increases.With respect to the materials used, coverlay films can be divided into the following three types: photosensitive coverlay film (first type), non-photosensitive coverlay film (second type) and thermal plastic coverlay film (third type). The photosensitive coverlay film (first type) also can be divided into polyimide based coverlay film (PT based coverlay film) and non-polyimide based coverlay film (non-PI based coverlay film). Since the non-PI based coverlay film has poor heat resistance, higher ...

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Номер записи: 67

18-04-2013 дата публикации

Reagents and methods for phosphorylation/dephosphorylation analyses

Номер: US20130095502A1

Автор: Anton B. Iliuk, Weiguo A. Tao

Принадлежит: PURDUE RESEARCH FOUNDATION

Disclosed herein are reagents that include a moiety that includes a metal such as titanium and that readily binds to phosphorylated molecules the reagents also include at least one moiety that produces a signal or that binds to a molecule that produces a signal. The reagent may also include a moiety that binds to a larger molecule or to a surface. Some forms of the reagent include a dendrimer that can simultaneously bind to multiple metal moieties that include a metal such as titanium and multiple moieties that can be used to detected bound molecules. These reagents can be used in detection and/or measurement and/or at least partial purification of phosphorylated molecules. These reagents and methods using them are used to analyze proteins, polypeptides, nucleic acids, phospholipids and the like. They are readily adapted for use in gels, blots, plate based high through put assays and for mass spectrometry.

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Номер записи: 68

18-04-2013 дата публикации

POLYMERS FOR DELIVERING MOLECULES OF INTEREST

Номер: US20130096177A1

Автор: Creusat Gaelle, Frisch Benoit, Thomann Jean-Sébastien, Zuber Guy

Принадлежит:

The present invention relates to a new class of cationic polymers that self-assemble with a pH-sensitive dissolution switch, and their uses to deliver molecules of interest to a cell. The present invention also relates to compositions comprising said cationic polymers non-covalently associated with a molecule of interest, in particular with a siRNA. 134-. (canceled)36. The polyethylenimine of claim 35 , wherein the polyethylenimine is branched.37. The polyethylenimine of claim 35 , wherein the polyethylenimine has a molecular weight of at least 400 Da or between 500 Da to 200 claim 35 ,000 Da.38. The polyethylenimine of claim 35 , wherein the amine functions are modified or substituted by a radical X at a ratio of p from 0.1 to 0.9 claim 35 , or a ratio of p from 0.15 to 0.5 claim 35 , or a ratio of p from 0.2 to 0.4 claim 35 , or a ratio of p of about 0.30.39. The polyethylenimine of claim 35 , wherein R is independently selected from the group consisting of H claim 35 , OH claim 35 , OCH claim 35 , and NH.40. The polyethylenimine of claim 35 , wherein r is 0 or 1.42. The polyethylenimine of claim 41 , wherein Z is S.46. The polyethylenimine of claim 35 , wherein at least 3 or 4 of the 5 R are H and the other R is selected from the group consisting of H claim 35 , OH claim 35 , NH claim 35 , and OCH.47. The polyethylenimine of claim 44 , wherein at least 3 or 4 of the 5 R are H and the other R is selected from the group consisting of H claim 44 , OH claim 44 , NH claim 44 , and OCH.48. The polyethylenimine of claim 45 , wherein at least 3 or 4 of the 5 R are H and the other R is selected from the group consisting of H claim 45 , OH claim 45 , NH claim 45 , and OCH.50. The polyethylenimine of claim 49 , wherein Z is O.52. The polyethylenimine of claim 51 , wherein Z is S and r is O.54. The polyethylenimine of claim 53 , wherein Z is O.56. A composition comprising a polyethylenimine according to and a molecule of interest non-covalently associated with the ...

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Номер записи: 69

18-04-2013 дата публикации

NOVEL CROSS-LINKER

Номер: US20130096256A1

Автор: Knutsson Malin, Lager Erik, Momcilovic Dane, Persson David, Rome Daniel, Rosenberg Jan-Erik

Принадлежит: NEXAM CHEMICAL AB

Disclosed are novel cross-linkable end-cappers for oligo-and polyimides. End-capped oligo-and polyimides comprising such an end-capper may be cured at a lower temperature compared to oligo-and polyimides end-capped with PEPA. 2. The compound according to claim 1 , wherein “Ar” is phenyl claim 1 , naphtyl claim 1 , thiophenyl or furanyl.3. The compound according to claim 1 , wherein “Ar” is phenyl.4. The compound according to claim 1 , wherein the integer “n” is 0; or wherein “n” is 1 or more claim 1 , and R3 is claim 1 , independently if “n” is 2 or more claim 1 , selected from the group consisting of methyl claim 1 , methoxy claim 1 , nitro claim 1 , and trifluoromethyl.5. (canceled)6. The compound according to claim 1 , wherein said compound is a compound according to formula (II) and “X” is O (oxygen); or wherein said compound is a compound according to formula (I) and R1 and R2 are selected from OH claim 1 , chloro claim 1 , and OC1-C8 alkyl.8. (canceled)10. (canceled)11. The oligo- or polyimide according to claim 9 , wherein said oligo- or polyimide comprisesat least one residue of an aromatic dianhydride selected from the group consisting of pyromellitic dianhydride, 4,4′-oxydiphthalic anhydride, 2,2-bis-[4-(3,4-dicarboxyphenoxy)phenyl]-propane dianhydride, 3,3′,4,4′-benzophenonetetracarboxylic acid dianhydride, 3,3′,4,4′-tetracarboxybiphenyl dianhydride, 4,4′,5,5′-sulfonyldiphthalic anhydride, and 5,5′-(perfluoropropane-2,2-diyl)bis(isobenzofuran-1,3-dione); andat least one residue of an aromatic diamineselected from the group consisting of 4,4′-oxydianiline, 1,4-diaminobenzene, 1,3-diaminobenzene, 1,3-bis-(4-aminophenoxy)benzene, 1,3-bis-(3-aminophenoxy)benzene, methylenedianiline, and 3,4′-oxydianiline.12. The oligo- or polyimide according to claim 9 , having a number average molecular weight of about 1 claim 9 ,000 to 20 claim 9 ,000; or having a weight average molecular weight of about 1 claim 9 ,000 to 200 claim 9 ,000.1316-. (canceled)17. A composition ...

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Номер записи: 70

25-04-2013 дата публикации

Filmy Graphite and Process for Producing the Same

Номер: US20130101498A1

Автор: Kiyokazu Akahori, Mutsuaki Murakami, Yasushi Nishikawa

Принадлежит: Kaneka Corp

A process for producing a filmy graphite includes the steps of forming a polyimide film having a birefringence of 0.12 or more and heat-treating the polyimide film at 2,400° C. or higher.

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Номер записи: 71

02-05-2013 дата публикации

Polysiloxane-grafted polyimide resin composition and applications thereof

Номер: US20130109803A1

Автор: Huai-Pin Hsueh, Li-Tao Hsu, Yu-Hao LIANG

Принадлежит: Chi Mei Corp

A polysiloxane-grafted polyimide resin composition includes a polysiloxane-grafted polyimide resin, and a solvent. The polysiloxane-grafted polyimide resin is represented by formula (I): wherein W represents a tetravalent organic group, R represents a trivalent organic group, and X represents a polysiloxane-containing group.

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Номер записи: 72

09-05-2013 дата публикации

Liquid crystal display and method of manufacturing the same

Номер: US20130114030A1

Автор: Dong Gi Seong, Jin-Lak KIM, Jinhyeong LEE, Joon-Hyung Park, Kangsub JUNG, Keunchan Oh, Kyungseon TAK

Принадлежит: SAMSUNG ELECTRONICS CO LTD

A liquid crystal display includes a first substrate, a second substrate, and a liquid crystal layer disposed between the first substrate and the second substrate. The first substrate includes a first base substrate, a pixel electrode disposed on the first base substrate and including a plurality of branch portions, and a first alignment layer disposed on the pixel electrode. The second substrate includes a second base substrate, a common electrode disposed on the second base substrate, and a second alignment layer disposed on the common electrode.

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Номер записи: 73

16-05-2013 дата публикации

High Capacity Oxoanion Chelating Media From Hyperbranched Macromolecules

Номер: US20130118986A1

Автор: Diallo Mamadou S., Mishra Himanshu, Yu Changjun

Принадлежит:

A resin is provided for selectively binding to certain anions in aqueous solution. The beads are prepared by cross-linking macromolecules such as hyperbranched PEI, and functionalizing with groups containing vicinal diol moieties. 1. An oxoanion-selective microparticle comprising a hyperbranched macromolecular structure (A) comprising a plurality of branches , a plurality of terminal functional groups , and a plurality of cross-linking moieties within the same molecular structure;wherein each of said plurality of branches comprises an N-substituted or N,N-substituted n-aminoalkyl moiety (B) comprising one or two substituent moieties; (a) another of said plurality of branches;', '(b) one of the plurality of terminal functional groups; or', '(c) one of the cross-linking moieties attached at a first cross-linking end, wherein the cross-linking moiety further comprises a second cross-linking end, by which the moiety is also one of said substituent moieties of one of said plurality of branches at a different location within the hyperbranched macromolecular structure A;, 'wherein each of said substituent moieties comprises one of the followingwherein A has a molecular weight of at least 1500 grams per mole;wherein A comprises essentially no primary amine moieties; andwherein each of the plurality of terminal functional groups comprises a vicinal diol moiety.2. The microparticle of claim 1 , wherein the cross-linking moieties consist of a carbon backbone of at least three carbon atoms claim 1 , each carbon atom optionally substituted with one or more functional groups.3. The microparticle of claim 2 , wherein the cross-linking moieties are selected from the group consisting of —CH—CHOH—CH— and —CH—CH—CH—4. The microparticle of claim 1 , wherein the terminal functional groups are 2 claim 1 ,3-dihydroxypropyl.5. The microparticle of claim 1 , wherein the terminal functional groups are (2R claim 1 ,3S claim 1 ,4R claim 1 ,5R)-2 claim 1 ,3 claim 1 ,4 claim 1 ,5 claim 1 ,6- ...

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Номер записи: 74

16-05-2013 дата публикации

Fuser member

Номер: US20130122286A1

Автор: JIN Wu

Принадлежит: Xerox Corp

The present teachings provide a fuser member. The fuser member includes a substrate layer comprising a thermoplastic polyimide/polybenzimidazole blend. A method of making the fuser member is provided.

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Номер записи: 75

16-05-2013 дата публикации

Catalytic polymerization of polymers containing electrophiic linkages using nucleophilic reagents

Номер: US20130123458A1

Автор: James L. Hedrick, Robert M. Waymouth, Russell C. Pratt

Принадлежит: International Business Machines Corp, Leland Stanford Junior University

The disclosure relates to methods and materials useful for polymerizing a monomer. In one embodiment, for example, the disclosure provides a method for polymerizing a monomer containing a plurality of electrophilic groups, wherein the method comprises contacting the monomer with a nucleophilic reagent in the presence of a guanidine-containing catalyst. The methods and materials of the disclosure find utility, for example, in the field of materials science.

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Номер записи: 76

16-05-2013 дата публикации

POLYAMINE AND METHOD FOR PRODUCING THEREOF

Номер: US20130123542A1

Автор: Kitayama Hiroyuki, Monguchi Yasunari, Sajiki Hironao

Принадлежит: Rhodia Operations

A method for producing a polyamine is described that provides excellent safety, a lot of flexibility regarding a variety of its productions, and that can produce a polyamine of high-molecular weight easily and inexpensively. 1. A polyamine comprising a combination of units of formula (1) or (2):{'br': None, 'sub': 2', 'm', '2', 'n, '—(NH—(CH)—NH—(CH))—\u2003\u2003(1)'} {'br': None, '—(NH—Y—NH—Z)—\u2003\u2003(2)'}, '(in the formula (1), independently in every unit, “m” indicates an integral number of 0 or more and “n” indicates an integral number of 3 or more.)'}(in the formula (2), independently in every unit, “Y” and “Z” are the same as or different from each other, and they indicate substituted or unsubstituted groups comprising unsaturated aliphatic, cyclic aliphatic or aromatic hydrocarbon radicals that can include hetero atoms.)2. The polyamine according to claim 1 , wherein the m and/or n of the formula (1) are the same as each other among the combined units.3. The polyamine as defined by claim 1 , wherein the Y and/or Z of the formula (2) are the same as each other among combined units.4. The polyamine as defined by claim 1 , wherein the polyamine comprises a polymer with a molecular weight of 1 claim 1 ,000 or more as it is measured by a mass spectrum.5. A polyamine obtained by a reductive polycondensation polymerization of diamine and dinitrile claim 1 , the diamine is at least one member selected from the group consisting of a substituted diamine claim 1 , an unsubstituted diamine claim 1 , an aliphatic diamine claim 1 , an aromatic diamine and an aliphatic-aromatic combined diamine.6. The polyamine according to claim 5 , whereinthe aliphatic diamine is at least one member selected from the group consisting of ethylenediamine, 1,2-propylenediamine, 1,3-propylenediamine, 1,2-butylenediamine, 1,3-butylenediamine, 1,4-butylenediamine, 2,3-butylenediamine, 1,2-cyclohexanediamine, 1,3-cyclohexanediamine, 1,4-cyclohexanediamine, hydrazine, pentamethylenediamine, ...

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Номер записи: 77

23-05-2013 дата публикации

METAL SCAVENGING POLYMERS AND USES THEREOF

Номер: US20130131253A1

Автор: Mlambo Darlington, Stiles Rebecca L., Su Winston, Zinn Paul J.

Принадлежит:

A polymer, a composition, and uses for either are disclosed. The polymer is derived from at least two monomers: acrylic-x and an alkylamine, and has attached to the polymer backbone a functional group capable of scavenging at least one metal. The polymer has a polymer backbone with a fluorescing quantity of conjugated double bonds, thereby providing a method for controlling metal scavenging via fluorescence. These polymers have many uses in various media, including wastewater systems. 2. The method of claim 1 , wherein the functional group comprises at least one sulfide compound.3. The method of claim 1 , wherein the functional group is a dithiocarbamate salt group and wherein the polymer is between 5 to 100 percent functionalized with the dithiocarbamate salt group based upon the total possible functionalization of the polymer backbone.4. The method of claim 1 , wherein the at least one metal is selected from the group consisting of: copper claim 1 , nickel claim 1 , zinc claim 1 , lead claim 1 , mercury claim 1 , cadmium claim 1 , silver claim 1 , iron claim 1 , manganese claim 1 , palladium claim 1 , platinum claim 1 , strontium claim 1 , selenium claim 1 , arsenic claim 1 , cobalt claim 1 , gold claim 1 , and any combination thereof5. The method of claim 1 , further comprising a second treating of the process stream with a complexing amount of a water soluble ethylene dichloride ammonia polymer having a molecular weight of from 500 to 100 claim 1 ,000 Daltons and functionalized from 5 to 50% with dithiocarbamate salt groups.6. The method of claim 1 , further comprising: applying an oxidizing agent to a heat generating system flue gas; optionally wherein the oxidizing agent oxidizes a target species at a temperature of at least 500° C.; optionally wherein the target species is elemental mercury or derivatives thereof; and optionally wherein the oxidizing agent is at least one of the following: a thermolabile molecular halogen claim 1 , calcium bromide claim 1 , ...

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Номер записи: 78

30-05-2013 дата публикации

POLYIMIDE FILM

Номер: US20130133929A1

Автор: JUNG Hak Gee

Принадлежит: KOLON INDUSTRIES, INC.

Disclosed is a polyimide film for insulating material prepared by reacting an acid anhydride and diamine compounds comprising p-phenylenediamine. The polyimide film has excellent electric properties such as a coefficient of thermal expansion, an elongation, a intensity, a dielectric strength and a bulk resistance, and suitable for use in a TAB tape employing a polyimide film, and a flexible printed wiring board. 1. A polyimide film produced from a polyamic acid , said polyamic acid being prepared by reacting monomer components consisting of:(i) an acid anhydride, and(ii) diamine compounds,wherein the acid anhydride is selected from the group of pyromellitic dianhydride, a mixture of pyromellitic dianhydride and 3,3′,4,4′-benzophenone tetracarboxylic dianhydride, and a mixture of pyromellitic dianhydride and 3,3′,4,4′-biphenyltetracarboxylic dianhydride,{'sub': 2', '2', '2', '2', '2', '2, 'wherein the diamine compounds comprise p-phenylenediamine, and at least one diamine compound selected from the group consisting a diamine compound including an ether linkage between an HN—C bond and another HN—C bond in the molecule, a diamine compound including a methylene linkage between an HN—C bond and another HN—C bond in the molecule, and a diamine compound having a structure wherein an HN—C bond and another HN—C bond are not linearly arranged; and'}wherein the polyimide film has an average coefficient of linear expansion in the range of 50° C. to 300° C. of 6 to 30 ppm, a tensile modulus of 2.0 GPa or more, and a coefficient of hygroscopic expansion of 13 ppm or less.2. The polyimide film according to claim 1 , wherein the diamine compounds comprise p-phenylenediamine and 4 claim 1 ,4′-diaminodiphenylmethane claim 1 ,3. The polyimide film according to claim 1 , wherein the diamine compounds comprise p-phenylenediamine and 4 claim 1 ,4′-oxydianiline.4. The polyimide film according to claim 1 , wherein the amount of p-phenylenediamine is 10 mol % to 70 mol % based on the total ...

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Номер записи: 79

30-05-2013 дата публикации

Injectable dendrimer hydrogel nanoparticles

Номер: US20130136697A1

Автор: Anupa Menjoge, Raghavendra Navath, Rangaramanujam M. Kannan, Roberto Romero, Sujatha Kannan

Принадлежит: National Institutes of Health NIH, WAYNE STATE UNIVERSITY

The invention discloses injectable hydrogels which are in the form of crosslinked nano beads or particle in the size range 5 nm to 10 μm, comprising PAMAM dendrimer with asymmetrical peripheral end groups such that one of the terminal groups is involved in formation of hydrogel and the other in involved in the conjugation of drugs or imaging agents and their methods of preparation. The said gel is formed by reaction of the PAMAM dendrimer with asymmetrical end groups with other polymer wherein the other polymer is selected from the group of linear, branched, hyperbranched or star shaped polymers with functionalized terminal groups. The PAMAM dendrimer with asymmetrical terminal groups consists of a Generation 2 and above PAMAM dendrimer with symmetrical end groups modified using the amino acids or their modified forms. The gel disclosed in the present invention is formed as small crosslinked particles in the size range 25 nm to 10 μm and is suitable for injectable delivery of hydrogel to any of the body orifices, tissues by intramuscular or subcutaneous route and ocular delivery for the purpose of therapeutic treatment and imaging.

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Номер записи: 80

30-05-2013 дата публикации

Microcapsules and production thereof

Номер: US20130137626A1

Автор: Daniel Mues, Klaus Last

Принадлежит: Follmann and Co Gesellschaft fur Chemie Werkstoffe und Verfahrenstechnik mbH and Co KG

The invention relates to microcapsules, the capsule walls of which comprise a resin that can be obtained by reacting a) at least one compound selected from the group consisting of a1) amines and a2) aromatic or heteroaromatic compounds which are unsubstituted or substituted with one or more substituents from the group consisting of C 1 -C 20 -alkyl, OH, OR, COOH, SH, SR, NHCOR, OCOR, halogen, or an aromatic compound, where R is a C 1 -C 10 -alkyl group, with b) at least one aldehydic component that contains at least two carbons atoms per molecule, in the presence of c) at least one copolymer which contains units of 2-acrylamido-2-methylpropane sulphonic acid or salts (AMPS) thereof and/or 2-acrylamido-2-methylpropane phosphonic acid or salts (AMPP) thereof and units of one or more (meth)acrylates.

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Номер записи: 81

30-05-2013 дата публикации

Polymers having carbazole structural units

Номер: US20130137818A1

Автор: Anna Hayer, Aurélie LUDEMANN, Niels Schulte

Принадлежит: Merck Patent GmBH

The present invention relates to polymers which contain at least one carbazole structural unit of the general formula (I) where Ar1, Ar2, Ar3 is each, independently of one another, an aryl or heteroaryl group, which may be substituted by one or more radicals R of any desired type; m, o is, independently of one another, 0 or 1; n is 1, 2 or 3 and the dashed lines represent the linking in the polymer; and at least one arylamine structural unit of the general formula (II) and/or (III) where Ar4, Ar5, Ar7, Ar8 is each, inde pendently of one another, an aryl or heteroaryl group, which may be substituted by one or more radicals R of any desired type; Ar6 is an aryl or heteroaryl group, which may be substituted by one or more radicals R of any desired type, or represents a group of the formula Ar9-Y—Ar9, where Ar9 is in each case, independently, an aryl or heteroaryl group, which is substituted by one or more radi

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Номер записи: 82

30-05-2013 дата публикации

POLYIMIDE FIBER WITH HIGH STRENGTH AND HIGH MODULUS AND ITS PREPARATION METHOD

Номер: US20130137846A1

Автор: HAN ENLIN, NIU HONGQING, QI SHENGLI, TIAN GUOFENG, Wang Xiaodong, WU DEZHEN, WU ZHANPENG, YAN XIAONA

Принадлежит: Beijing University of Chemical Technology

A high-strength high-modulus polyimide fiber and its preparation method pertain to the technical field of high-performance organic fiber. This fiber includes the polyimide (PI) fiber made from 3,3′,4,4′-biphenyl tetracarboxylic diandhydride (BPDA), p-phenylenediamine (pPDA) and 2-(4-aminophenyl)-1H-benzimidazol-5-amine (BIA), wherein the molar ratio between PPDA and BIA is 1:10˜3:1. During the synthesis, other diamine and diandhydride monomers may also be added. In the preparation process, the gradient temperature reaction method and one-step continuous preparation method are adopted, the synthesis and processing difficulty caused by the increase of the content of BIA is overcome, the problem of poor uniformity and stability of fiber is solved and PI fiber with high strength and high modulus is obtained. Its strength may reach 4.5 GPa and modulus may reach 201 GPa. Moreover, the sources of the raw materials are extensive, the spinning process is continuous, the cost is low, the efficiency is high and industrial production may be realized. 144. A high-strength high-modulus polyimide fiber , comprising polyimide fiber obtained from random copolymerization of 3 , 3′ , , ′-benzophenone tetracarboxylic dianhydride (BPDA) , p-phenylenediamine (pPDA) and 2-(4-aminophenyl)-1H-benzimidazol-5-amine (BIA) , wherein molar ratio between pPDA and BIA is 1:10˜3:1.2. The high-strength high-modulus polyimide fiber according to claim 1 , wherein the polyimide fiber comprises copolymerization of BPDA claim 1 , pPDA and BIA with other diamine or/and dianhydride claim 1 , wherein molar ratio between said other diamine and the total addition amount of pPDA and BIA is 1:10˜1:4 claim 1 , molar ratio between said other dianhydride and BPDA is 1:10˜3:7.3. A method for preparing the high-strength high-modulus polyimide fiber according to claim 1 , comprising the following steps:A: providing pPDA, BIA and BPDA at a molar ratio of 1:0.95˜1:1.05 between pPDA and BPDA And at a molar ratio of 1:10 ...

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Номер записи: 83

30-05-2013 дата публикации

SYNTHESIS OF POLYALKYLENEPOLYAMINES HAVING A LOW COLOR INDEX BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION IN THE PRESENCE OF HYDROGEN

Номер: US20130137901A1

Автор: HUEFFER Stephan, MAAS Steffen, Paciello Rocco, Schaub Thomas, Strautmann Julia

Принадлежит:

Process for the preparation of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, in which aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst and in the presence of hydrogen gas. Polyalkylenepolyamines obtainable by such processes and polyalkylenepolyamines comprising hydroxy groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes. 1. A process for the preparation of polyalkylenepolyamines by homogeneously catalyzed alcohol amination , in which(i) aliphatic amino alcohols are reacted with one another or(ii) aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst and in the presence of hydrogen gas.2. The process according to claim 1 , wherein the reaction is carried out at a partial pressure of the hydrogen gas of from 0.1 to 25 MPa.3. The process according to or claim 1 , wherein the hydrogen gas engages chemically in the catalyzed alcohol amination claim 1 , thereby reducing the formation of coloring components.4. The process according to to claim 1 , wherein the catalyst is a transition metal complex catalyst.5. The process according to to claim 1 , wherein the catalyst comprises ruthenium or iridium.6. The process according to to claim 1 , wherein the catalyst comprises a nitrogen-heterocyclic carbene ligand.7. The process according to claim 6 , wherein the catalyst comprises a carbene ligand from the group ...

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Номер записи: 84

06-06-2013 дата публикации

Formulated Benzoxazine Based System for Transportation Applications

Номер: US20130143457A1

Автор: Hoge James

Принадлежит: Huntsman Advanced Materials Americas LLC

The present disclosure provides a halogen-free thermosetting composition including a benzoxazine compound, a monobenzoxazine monomer, and a naphthalene epoxy. The halogen-free thermosetting composition is especially suited for use in aerospace, automobile, rail and marine applications. 2. The halogen-free thermosetting composition according to wherein R is phenyl.3. The halogen-free thermosetting composition according to wherein X is phenyl.5. The halogen-free thermosetting composition according to further comprising at least one of a solvent claim 1 , a catalyst claim 1 , a flame retardant and fillers.6. The halogen-free thermosetting composition according to wherein the solvent is selected from the group consisting of methylethylketone claim 5 , acetone claim 5 , N-methyl-2-pyrrolidone claim 5 , N claim 5 ,N-dimethyl formamide claim 5 , pentanol claim 5 , butanol claim 5 , dioxolane claim 5 , isopropanol claim 5 , methoxy propanol claim 5 , methoxy propanol acetate claim 5 , dimethylformamide claim 5 , glycol claim 5 , glycol acetate claim 5 , toluene claim 5 , xylene and mixtures thereof.8. The halogen-free thermosetting composition according to claim 7 , wherein the glass transition temperature is greater than 180° C.10. A halogen-free thermosetting composition produced according to the method of .11. A method for producing a flame retarded composite article including the steps of: (i) providing a layer or bundle of reinforcement fibers; and (ii) providing the halogen-free thermosetting composition; (iii) contacting the reinforcement fibers with the halogen-free thermosetting composition to coat and/or impregnate the reinforcement fibers; and (iv) curing the coated and/or impregnated reinforcement fibers at a temperature of least about 80° C.12. A flame retarded article produced according to the method of .13. A process for producing a flame retarded composite article comprising the steps of: a) introducing a fiber preform comprising reinforcement fibers into a ...

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Номер записи: 85

06-06-2013 дата публикации

CARBODIIMIDATON METHOD

Номер: US20130143458A1

Автор: Achten Dirk, Avtomonov Evgeny, Büchner Jörg, Dörr Sebastian, Kraus Harald

Принадлежит:

The present invention relates to aqueous dispersions containing hydrophilized polycarbodiimides, methods for producing the aqueous dispersions according to the invention, their use as a constituent of binders in adhesives, lacquers, paints, paper coating compounds or in fibre nonwovens and articles made of wood, metal, textile, leather or plastic, which are treated with the aqueous dispersion according to the invention. 114.-. (canceled)15. A method for producing polycarbodiimide wherein , in at least one step , at least one aliphatic or cycloaliphatic polyisocyanate is converted at a temperature in the range of from 160 to 230° C. in the presence of from 50 to 3000 ppm of carbodiimidation catalyst , expressed in terms of the molar amount of polyisocyanate , into a polycarbodiimide having an average functionality of from 1 to 10 carbodiimide units , characterised in that the reaction gases are periodically or continuously removed.16. The method according to claim 15 , comprising the stepsa) converting at least one aliphatic or cycloaliphatic polyisocyanate at a temperature in the range of from 160 to 230° C. in the presence of from 50 to 3000 ppm of carbodiimidation catalyst, expressed in terms of the molar amount of polyisocyanate, into a polycarbodiimide having an average functionality of from 1 to 10 carbodiimide units, the reaction gases being periodically or continuously removed andb) reacting the polycarbodiimide obtained in step a) with at least one compound selected from the group consisting of polyethoxy monools, polyethoxy diols, polyethoxypolypropoxy monools, polyethoxypolypropoxy diols, polyethoxy monoamines, polyethoxy diamines, polyethoxypolypropoxy monoamines, polyethoxypolypropoxy diamines, hydroxyalkyl sulfonates, aminoalkyl sulfonates, polyethoxy mono- and dithiols, polyethoxymono- and dicarboxylic acids.17. The method according to claim 15 , characterised in that the conversion of aliphatic or cycloaliphatic polyisocyanate into polycarbodiimide is ...

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Номер записи: 86

13-06-2013 дата публикации

POLYMER AND ORGANIC LIGHT-EMITTING DIODE INCLUDING THE SAME

Номер: US20130146849A1

Автор: CHOI Hyeon-ho, HONG Seok-Hwan, JOO Won-Jae, Jung Yong-Sik, KANG Ho-suk, KIM Mi-Jeong, Kim Tae-Gon, SON Jhun-mo, YANG Hye-yeon

Принадлежит: SAMSUNG ELECTRONICS CO., LTD.

A polymer having a repeating unit represented by Formula 1, wherein Rthrough R, X, and Arare the same as defined in the detailed description, and an organic light-emitting diode including the polymer are described. 2. The polymer of claim 1 , wherein X is —[C(R)(R)]— claim 1 , Rand Rare each independently hydrogen claim 1 , deuterium claim 1 , a halogen atom claim 1 , a hydroxyl group claim 1 , a cyano group claim 1 , a nitro group claim 1 , an amino group claim 1 , an amidino group claim 1 , a hydrazine group claim 1 , a hydrazone group claim 1 , a carboxyl group or a salt thereof claim 1 , an ester group claim 1 , a sulfonic acid group or a salt thereof claim 1 , a phosphoric acid or a salt thereof claim 1 , a C-Calkyl group claim 1 , or a C-Calkoxy group claim 1 , and a is 1 claim 1 , 2 or 3.3. The polymer of claim 1 , wherein Rand Rare each independently hydrogen; deuterium; a halogen atom; a hydroxyl group; a cyano group; a nitro group; an amino group; an amidino group; a hydrazine group; a hydrazone group; a carboxyl group or a salt thereof; an ester group; a sulfonic acid group or a salt thereof; a phosphoric acid or a salt thereof; a C-Calkyl group; a C-Calkoxy group; a C-Calkyl group and a C-Calkoxy group that are substituted with a deuterium atom claim 1 , a halogen atom claim 1 , a hydroxyl group claim 1 , a cyano group claim 1 , a nitro group claim 1 , an amino group claim 1 , an amidino group claim 1 , a hydrazine group claim 1 , a hydrazone group claim 1 , a carboxyl group or a salt thereof claim 1 , an ester group claim 1 , a sulfonic acid group or a salt thereof claim 1 , and a phosphoric acid or a salt thereof; a phenyl group; a naphthyl group; an anthryl group; a phenanthrenyl group; a pyrenyl group; a chrysenyl group; a pyridinyl group; a pyrimidinyl group; a pyrazinyl group; an imidazolyl group; an indolyl group; or a phenyl group claim 1 , a naphthyl group claim 1 , an anthryl group claim 1 , a phenanthrenyl group claim 1 , a pyrenyl group claim ...

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Номер записи: 87

13-06-2013 дата публикации

POLYMERS WITH CARBAZOLE STRUCTURAL UNITS

Номер: US20130150527A1

Автор: Hayer Anna, Kim Heeyeon, Kwak Yoonhyun, Lee Jaeyong, Ludemann Aurélie, Schulte Niels, Yang Seunggak, Yi Jeongin

Принадлежит:

The present invention relates to polymers containing at least one carbazole structural unit of the general formula (I) where Ar1, Ar2, Ar3 is each, independently of one another, denote an aryl or heteroarylgroup, which may be substituted by one or more radicals R of any desired type; m, o is, independently of one another, 0 or 1; n is 1, 2 or 3 and the dashed lines represent the linking in the polymer; and at least one arylamine structural unit of the general formula (II) and/or (III) where Ar4, Ar5, Ar7, Ar8 is each, independently of one another, an aryl or heteroaryl group, which may be substituted by one or more radicals R of any desired type; Ar6 is an aryl or heteroaryl group, which may be substituted by one or more radicals R of any desired type, or represents a group of the formula Ar9-Ar9, where Ar9 is in each case, independently, an aryl or heteroaryl group, which may be substituted by one or more radicals R of any desired type or linked to one another; p is 1, 2 or 3; q is 0 or 1 and the dashed lines represent the linking in the polymer. Furthermore, the present invention relates to processes for the preparation of these polymers and to formulations and electronic devices which comprise these polymers. 112-. (canceled)18. The polymer according to claim 13 , wherein the polymer R is selected on each occurrence claim 13 , independently of one another claim 13 , from F claim 13 , Cl claim 13 , Br claim 13 , I claim 13 , N(Ar) claim 13 , N(R′) claim 13 , CN claim 13 , NO claim 13 , Si(R′) claim 13 , B(OR′) claim 13 , C(═O)Ar claim 13 , C(═O)R′ claim 13 , P(═O)(Ar) claim 13 , P(═O)(R′) claim 13 , S(═O)Ar claim 13 , S(═O)R′ claim 13 , S(═O)Ar claim 13 , S(═O)R′ claim 13 , —CR′═CR′Ar claim 13 , OSOR′ claim 13 , a straight-chain alkyl claim 13 , alkoxy or thioalkoxy group having 1 to 40 C atoms or a branched or cyclic alkyl claim 13 , alkoxy or thioalkoxy group having 3 to 40 C atoms claim 13 , each of which is optionally substituted by one or more radicals R′ ...

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Номер записи: 88

13-06-2013 дата публикации

Benzoxazine-thiol adducts

Номер: US20130150545A1

Автор: Ilya Gorodisher, Robert J. DeVoe, Robert J. Webb

Принадлежит: 3M Innovative Properties Co

Novel benzoxazine-thiol adducts are described, which may be may be cured to produce compositions useful in coating, sealants, adhesive and many other applications.

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Номер записи: 89

20-06-2013 дата публикации

NOVEL SILICON-CONTAINING ALICYCLIC POLYIMIDE RESIN, POLYAMIC ACID RESIN, AND MANUFACTURING METHOD FOR SAME

Номер: US20130158225A1

Автор: Kikuchi Tooru, Masuda Katsuyuki, Takasaki Toshihiko

Принадлежит:

A polyimide resin including repeating units represented by formula (1): The present invention relates to novel silicon-containing alicyclic polyimide resins and polyamic acid resins, and processes for producing these resins.In the application field of optoelectronics, such as optical devices, displays and optical information transmission, intensive research and development of transparent materials have been made and the utilization of the transparent materials has been studied. In the above application field, a wavelength ranging from 350 to 500 nm tends to be positively utilized from the viewpoints of high energy density and efficiency.As high-performance polymers for electronic equipments, polyimide resins are generally known. In particular, from the viewpoint of good heat resistance, aromatic polyimide resins have been conventionally used. However, the aromatic polyimide resins absorb light in the above wavelength range and their use as a transparent material is limited. Therefore, the development of non-aromatic polyimide resins having high heat resistance comes to be demanded. In addition, heat-resistant transparent materials to be applied to the field of optoelectronics are required to be good not only in mechanical properties, such as tensile strength and elongation at break, but also in properties, such as adhesion to silicon substrates or glass substrates and solubility in general-purpose solvents.To obtain polyimide resins having the above-mentioned properties, it has been studied to use a silicon-containing alicyclic tetracarboxylic dianhydride as a constituting unit of the polyimide resins.For example, Patent Document 1 discloses a polyimide resin produced using a tetracarboxylic dianhydride represented by formula (4):which is synthesized from 5-norbornene-2,3-dicarboxylic anhydride and a dimethylsiloxane terminated at each end with a hydrosilyl group.Non-Patent Document 1 discloses a polyimide resin produced using a tetracarboxylic dianhydride ...

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Номер записи: 90

27-06-2013 дата публикации

Substrate structure and method for making the same

Номер: US20130161864A1

Автор: Huai-Pin Hsueh, Jen-Hao Hsueh, Yu-Hao LIANG

Принадлежит: Chi Mei Corp

A substrate structure includes a support, a release layer releasably disposed on the support, and a flexible substrate disposed on the release layer. The release layer is made from a polymer composition including a polymer component obtained by subjecting a diamine component (A) and a tetracarboxylic dianhydride component (B) to a polymerization reaction.

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Номер записи: 91

27-06-2013 дата публикации

POLYMIDE BLEND NANOFIBER AND ITS USE IN BATTERY SEPARATOR

Номер: US20130164629A1

Автор: Chen Shuiliang, Cheng Chuyun, He Ping, Hou Haoqing, Kuang Xiaoming, Lv Xiaoyi, REN Jinsheng, ZHOU XIAOPING

Принадлежит: JIANGXI ADVANCE NANOFIBER S&T CO., LTD.

A polyimide blend nanofiber and its use in battery separator are disclosed. The polyimide blend nanofiber is made of two kinds of polyimide precursors by high pressure electrostatic spinning and then high temperature imidization processing, wherein one of the polyimide precursor does not melt under high temperature ,and the other is meltable at a temperature of 300-400° C. The polyimide blend nanofiber of present invention has high temperature-resistance, high chemical stability, high porosity, good mechanical strength and good permeability, and can be applied as battery separator. 1. A polyimide blend nanofibre , manufactured by subjecting a precursor of two polyimides to high-voltage electrostatic spinning and a high-temperature imidization treatment , characterized in that , said polyimide blend precursor is composed of a bicomponent of a precursor of polyimide nonmeltable at a high temperature and a precursor of polyimide meltable at 300-400° C.6. The polyimide blend nanofibre according to claim 1 , characterized in that claim 1 , the diameter of said fibre is 50-1000 nm.7. The polyimide blend nanofibre according to claim 1 , characterized in that claim 1 , the decomposition temperature of said fibre is higher than 500° C. and the melt temperature thereof is higher than 300° C.8. The polyimide blend nanofibre according to claim 1 , characterized in that claim 1 , the porosity of the porous membrane or nonwoven fabric composed of said fibre is higher than 75%.9. The polyimide blend nanofibre according to claim 1 , characterized in that claim 1 , the mechanical strength of the porous membrane or the nonwoven fabric composed of the fibre is 10-50 MPa and the electrical breakdown strength thereof is higher than 10 V/μm.10. Use of the porous membrane or the nonwoven fabric composed of the polyimide blend nanofibre according to in battery separators. The present invention relates to an electrostatic ally spun polyimide nanofibre and uses thereof, and in particular, a ...

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Номер записи: 92

04-07-2013 дата публикации

Conductive polymer, synthesis method thereof, and electroactive electrode covered with said conductive polymer

Номер: US20130171338A1

Автор: Dongyuan Zhai, Hao Qiu, Lijia Pan, Yi Shi

Принадлежит: NANJING UNIVERSITY

The present invention provides a conducting polymer, a synthesis method thereof, and an electroactive electrode covered with the said conducting polymer. The conducting polymer is synthesized as follows: use the polybasic acid as dopant and crosslinking agent, and polymerize monomers into conducting polymer hydrogel. The monomers are selected one or more from pyrrole or its derivatives, thiophene or its derivatives, aniline or its derivatives. The acid group of the polybasic acid contains phosphate or polybasic acid which contains at least two substituents per molecule selected from sulfate, nitrate or carboxylic in which the molecular weight of at least one acid group is no more than 800. The mole ratio of the acid group in polybasic acid to monomers of the conducting polymer is 1:12-12:1. The preparation applied in the invention is simple, and need not to import any impurity. The conducting polymer hydrogel has high ionic conductivity, super hydrophilicity, and good biocompatibility.

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Номер записи: 93

04-07-2013 дата публикации

Photosensitive Novolac Resin, Positive Photosensitive Resin Composition Including Same, Photosensitive Resin Film Prepared by Using the Same, and Semiconductor Device Including the Photosensitive Resin Film

Номер: US20130171563A1

Автор: Hyun-Yong Cho, Ji-young Jeong, Jong-Hwa Lee, Min-Kook CHUNG, Myoung-Hwan Cha

Принадлежит: Cheil Industries Inc

Disclosed is a photosensitive novolac resin including a structural unit represented by the following Chemical Formula 1 and structural unit represented by the following Chemical Formula 2, wherein R 11 , R 12 , R 13 , and R 14 in Chemical Formulae 1 and 2 are the same as defined in the detailed description, a positive photosensitive resin composition including the same, a photosensitive resin film fabricated using the same, and a semiconductor device including the photosensitive resin composition.

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Номер записи: 94

04-07-2013 дата публикации

Polymers, Their Method of Manufacture and Use Thereof

Номер: US20130172433A1

Автор: Carta Mariolino, McKeown Neil Bruce

Принадлежит: UNIVERSITY COLLEGE CARDIFF CONSULTANTS LIMITED

A method for the manufacture of a polymer is provided, the method comprising: Providing a first monomer, the first monomer comprising a bicyclic diamine moiety, a first nucleophilic group provided on a carbon atom of an aromatic moiety, and a second nucleophilic group provided on a carbon atom of an aromatic moiety; Providing a bridging compound comprising at least two sites vulnerable to nucleophilic attack; and Contacting the first monomer with the bridging compound. Polymers made by said method and uses of such polymers are also disclosed. 1. A method for the manufacture of a polymer , the method comprising:Providing a first monomer, the first monomer comprising a bicyclic diamine moiety, a first nucleophilic group provided on a carbon atom of an aromatic moiety, and a second nucleophilic group provided on a carbon atom of an aromatic moiety;Providing a bridging compound comprising at least two sites vulnerable to nucleophilic attack; andContacting the first monomer with the bridging compound.2. A method according to wherein the first and second nucleophilic groups are the same claim 1 , or wherein the first and second nucleophilic groups are different.3. (canceled)4. A method according to wherein the first and second nucleophilic groups are individually selected from the list consisting of —OH claim 1 , —SH and —NHor anions made from these groups by deprotonation.5. A method according to claim 1 , wherein the first monomer is provided with no further nucleophilic groups capable of forming bonds with the sites of the bridging compounds which are vulnerable to nucleophilic attack claim 1 , and wherein the bridging compound comprises only two sites vulnerable to nucleophilic attack by the first and second nucleophilic groups provided on the first monomer.6. (canceled)7. A method according to claim 1 , the first monomer being provided with a third nucleophilic group provided on a carbon atom of an aromatic moiety claim 1 , and a fourth nucleophilic group provided on ...

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Номер записи: 95

04-07-2013 дата публикации

POLYIMIDE PRECURSOR COMPOSITION AND PREPARATION METHOD AND USE THEREOF

Номер: US20130172494A1

Автор: Cheng Pi-Jen, CHOU Meng-Yen, Lee Chuan Zong, Wu Chung-Jen

Принадлежит: ETERNAL CHEMICAL CO., LTD.

The present invention provides a polyimide precursor composition comprising a polyimide precursor and a thermal base generator having the structure of formula (1): 2. The precursor composition according to claim 1 , wherein a weight ratio of component (a) to component (b) ranges from 2000:1 to 5:1.3. The precursor composition according to claim 2 , wherein a weight ratio of component (a) to component (b) ranges from 200:1 to 10:1.7. The precursor composition according to claim 1 , wherein R claim 1 , Rand Rare the same or different and are each independently H claim 1 , methyl claim 1 , ethyl claim 1 , n-propyl claim 1 , isopropyl claim 1 , n-butyl claim 1 , isobutyl claim 1 , tert-butyl claim 1 , pentyl claim 1 , hexyl claim 1 , hydroxymethyl claim 1 , hydroxyethyl claim 1 , hydroxypropyl claim 1 , hydroxybutyl claim 1 , hydroxypentyl claim 1 , hydroxyhexyl claim 1 , cyanomethyl claim 1 , cyanoethyl claim 1 , cyanopropyl claim 1 , cyanobutyl claim 1 , cyanopentyl claim 1 , cyanohexyl claim 1 , phenyl claim 1 , benzyl or diphenylmethyl.8. The precursor composition according to claim 1 , wherein R claim 1 , Rand Rare the same or different and are each independently H claim 1 , methyl claim 1 , ethyl claim 1 , n-propyl or isopropyl.9. The precursor composition according to claim 1 , wherein the anionic group is selected from a group consisting of halide ion claim 1 , sulfate claim 1 , nitrate claim 1 , phosphate claim 1 , sulfonate claim 1 , carbonate claim 1 , tetrafluoborate claim 1 , borate claim 1 , chlorate claim 1 , iodate claim 1 , hexafluorophosphate claim 1 , perchlorate claim 1 , trifluoromethanesulfonate claim 1 , trifluoroacetate claim 1 , acetate claim 1 , tert-butylcarbonate claim 1 , (CFSO)N and tert-butyloxy.10. The precursor composition according to claim 1 , wherein the anionic group is a halide ion or tetrafluoroborate.20. The precursor composition according to further comprising a polar aprotic solvent selected from a group consisting of N- ...

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Номер записи: 96

04-07-2013 дата публикации

Method for producing epoxy compound having cyanuric acid skeleton

Номер: US20130172525A1

Автор: Sayoko Yanagisawa, Toshiaki Takeyama, Yuki Endo

Принадлежит: Nissan Chemical Corp

There is provided an epoxy compound that provides properties of cured products combining high transparency with high flexural strength by being thermally cured while maintaining advantageous handling properties in a liquid state thereof; and a method for producing a composition by using the epoxy compound. A method for producing an epoxy compound of Formula (1): (in Formula (1), n1, n2, and n3 are individually any one of integers of 2 to 6; n4, n5, and n6 are individually an integer of 2; n7, n8, and n9 are individually an integer of 1; and R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are independently a hydrogen atom or a C 1-10 alkyl group), including: reacting cyanuric chloride with a C 4-8 alkenol and reacting the obtained compound having an unsaturated bond with a peroxide.

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Номер записи: 97

11-07-2013 дата публикации

Polyamine brightening agent

Номер: US20130175179A1

Автор: William E. Eckles

Принадлежит: Coventya Inc

A zinc electroplating bath includes zinc ions and a brightening agent. The brightening agent is a polyamine or a mixture of polyamines that include a quaternary ammonium group.

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Номер записи: 98

11-07-2013 дата публикации

Solid-state assembly of layers and an electric device comprising such assembly

Номер: US20130175513A1

Автор: Deqing Gao, Florian Von Wrochem, Garbiele Nelles, William Ford

Принадлежит: Sony Corp

The present invention relates to a solid-state assembly of layers and to an electric solid-state device comprising such assembly. In one aspect, such electric device is a field effect transistor. In another aspect, such device is a memory device. In yet a further aspect, the device is a sensor device.

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Номер записи: 99

11-07-2013 дата публикации

POLYIMIDE PRECURSOR, POLYIMIDE, AND MATERIALS TO BE USED IN PRODUCING SAME

Номер: US20130178597A1

Автор: HISANO Nobuharu, Kohama Yukinori, Kohda Masafumi, Nakagawa Miharu, Nakayama Takeshige, Nakayama Tomonori, Oka Takuya, Takasawa Ryoichi

Принадлежит: UBE INDUSTRIES, LTD.

Disclosed is a novel co-polyimide precursor for producing a polyimide having high transparency. The co-polyimide precursor comprises a unit structure represented by general Formula (A1) and a unit structure represented by general Formula (A2): 2. The co-polyimide precursor according to claim 1 , wherein the number ratio of the unit structures represented by general Formula (A1) to the unit structures represented by general Formula (A2) [the number of unit structures represented by general Formula (A1)/the number of unit structures represented by general Formula (A2)] is 50/50 to 99.5/0.5.4. The co-polyimide precursor according to claim 1 , having a logarithmic viscosity of 0.2 dL/g or more as a 0.5 g/dL solution in N claim 1 ,N-dimethylacetamide at 30° C.5. A method of producing a co-polyimide precursor according to claim 1 , comprising reacting a diamine component and a tetracarboxylic acid component in a solvent at temperature of 100° C. or less.6. The method of producing a co-polyimide precursor according to claim 5 , wherein the solvent has a purity claim 5 , as determined by GC analysis claim 5 , of 99.8% or more.7. A method of producing a solution composition of the co-polyimide precursor according to claim 5 , comprising reacting a tetracarboxylic acid component and a diamine component at a molar ratio such that the diamine component is in excess to obtain a polyimide precursor; and further adding a carboxylic acid derivative in an amount approximately corresponding to the number of excess moles of the diamine to the resulting polyimide precursor such that the total molar proportion of the tetracarboxylic acid and the carboxylic acid derivative component is approximately equivalent to the molar proportion of the diamine component.9. The co-polyimide according to claim 8 , wherein the number ratio of the unit structures represented by general Formula (A5) to the unit structures represented by general Formula (A6) [the number of unit structures represented by ...

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Номер записи: 100