14-11-2013 дата публикации
Номер: US20130303702A1
Принадлежит:
The present invention relates to a process for the modification of a polymer surface. The polymer surface is treated with 113-. (canceled)14. A process for the modification of a polymer surface comprising treating a polymer surface with(i) an organoborane-amine complex and subsequently with(ii) a radically polymerizable monomer compound and optionally a deblocking agent.15. The process according to claim 14 , wherein any excess polymerized material that is not grafted onto the surface is removed.16. The process according to claim 14 , wherein the polymer has a low surface energy.17. The process according to claim 14 , wherein the organoborane-amine complex has a structure of formula (1){'br': None, 'sub': 1', '2', '3', '4', '5', '6, 'RRRB—NRRR\u2003\u2003(1),'}{'sub': 1', '2', '3', '1', '2', '3, 'wherein R, Rand Rare independently alkyl, aryl, alkoxy or aryloxy groups, with the proviso that at least one of R, Rand Ris an alkyl or aryl group, and'}{'sub': 4', '5', '6', '4', '5', '6, 'R, Rand Rare independently hydrogen, alkyl, cycloalkyl, substituted alkyl, alkoxy, alkylamino, aryl or heteroaryl groups, with the proviso that not more than two of R, Rand Rare simultaneously hydrogen, or'}{'sub': 4', '5', '6, 'NRRRis a heterocyclic aliphatic or aromatic amine, optionally comprising further heteroatoms selected from the group, consisting of N, O, S and P.'}18. The process according to claim 17 , wherein the organoborane-amine complex is a trialkylborane-amine complex.19. The process according to claim 14 , wherein the radically polymerizable monomer compound has a structure of formula (2) comprising an olefinic double bond{'br': None, 'sub': 7', '8', '9', '10, 'RRC═CRR\u2003\u2003(2),'} [{'br': None, 'sub': 7', '8, 'RC≡CR\u2003\u2003(3),'}, {'br': None, 'or with a structure of formula (4) comprising a carbonyl group'}, {'br': None, 'sub': 7', '8, 'RRC═O \u2003\u2003(4),'}], 'or with a structure of formula (3) comprising an acetylenic triple bond'} {'br': None, 'sub': 7 ...
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