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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 1111. Отображено 100.
30-05-2013 дата публикации

Microcapsules and production thereof

Номер: US20130137626A1
Автор: Daniel Mues, Klaus Last

The invention relates to microcapsules, the capsule walls of which comprise a resin that can be obtained by reacting a) at least one compound selected from the group consisting of a1) amines and a2) aromatic or heteroaromatic compounds which are unsubstituted or substituted with one or more substituents from the group consisting of C 1 -C 20 -alkyl, OH, OR, COOH, SH, SR, NHCOR, OCOR, halogen, or an aromatic compound, where R is a C 1 -C 10 -alkyl group, with b) at least one aldehydic component that contains at least two carbons atoms per molecule, in the presence of c) at least one copolymer which contains units of 2-acrylamido-2-methylpropane sulphonic acid or salts (AMPS) thereof and/or 2-acrylamido-2-methylpropane phosphonic acid or salts (AMPP) thereof and units of one or more (meth)acrylates.

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04-07-2013 дата публикации

Method for producing epoxy compound having cyanuric acid skeleton

Номер: US20130172525A1
Принадлежит: Nissan Chemical Corp

There is provided an epoxy compound that provides properties of cured products combining high transparency with high flexural strength by being thermally cured while maintaining advantageous handling properties in a liquid state thereof; and a method for producing a composition by using the epoxy compound. A method for producing an epoxy compound of Formula (1): (in Formula (1), n1, n2, and n3 are individually any one of integers of 2 to 6; n4, n5, and n6 are individually an integer of 2; n7, n8, and n9 are individually an integer of 1; and R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are independently a hydrogen atom or a C 1-10 alkyl group), including: reacting cyanuric chloride with a C 4-8 alkenol and reacting the obtained compound having an unsaturated bond with a peroxide.

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18-07-2013 дата публикации

SULPHUR-CONTAINING TRIAZINE MONOMER THAT CAN BE USED FOR THE SYNTHESIS OF A POLYMER MEMBRANE FOR A FUEL CELL

Номер: US20130184428A1
Автор: Fedurco Milan
Принадлежит:

A sulphur-containing triazine monomer is provided that can be used in the synthesis of a polymer membrane for a PEM-type fuel cell. The sulphur-containing triazine monomer has a structure corresponding to a formula (I): 110-. (canceled)12. The triazine monomer according to claim 11 , wherein Zand Z claim 11 , which are identical or different claim 11 , are selected from a group that includes halogens claim 11 , hydroxyl claim 11 , thiol claim 11 , and combinations thereof.14. The triazine monomer according to claim 12 , wherein Zand Z claim 12 , which are identical or different claim 12 , are halogens.17. The triazine monomer according to claim 11 , wherein the triazine monomer is a suphonated monomer that includes a sulphonic (—SOH) group or a sulphonate (—SOM) group claim 11 , in which M represents an alkali metal cation.18. The triazine monomer according to claim 17 , wherein the sulphonic (—SOH) group or the sulphonate (—SOM) group is carried by a phenyl group or a phenylene group or by at a substituent thereof. The present invention relates to the monomers which can be used for the synthesis of polymers intended in particular, in the sulphonated form, to constitute a solid electrolyte or membrane in a fuel cell.It relates more particularly to the above monomers of the aromatic type comprising a base structural unit with a triazine nucleus.The recent interest in fuel cells arises from their ability to convert chemical energy into electricity with a relatively high yield and a low emission of environmental pollutants. The use of such electrochemical devices extends today from the motor vehicle industry to portable computers, to mobile phones, to the stationary generation of electrical energy and to other applications comprising exploration of the sea and space.It should be remembered first of all that a fuel cell is an electrochemical energy generator in which a chemical reaction between hydrogen and oxygen is maintained under control, which reaction will produce ...

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22-08-2013 дата публикации

Triazine ring-containing polymer and membrane-forming composition containing the same

Номер: US20130214372A1
Принадлежит: Nissan Chemical Corp

Disclosed is a triazine ring-containing hyperbranched polymer containing a repeating unit structure represented by the expression (1). By this means, it is possible to achieve a triazine ring-containing polymer which, alone, has high heat resistance, high transparency, high refractive index, high light resistance, high solubility, low volume shrinkage without adding metal oxides; and also a membrane-forming composition containing the same. (In the formula, R and R′ represent independently a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, or an aralkyl group, and A represents an alkylene group optionally having a branched or alicyclic structure of 1 to 20 carbon atoms.)

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31-10-2013 дата публикации

Film-forming material

Номер: US20130284261A1
Автор: Kazuya Ebara
Принадлежит: Nissan Chemical Corp

There is provided a novel material used for solar cells that can contribute to the improvement in maximum output of solar cells without using the conventional MPPT system. A film-forming material for forming a light-collecting film on a transparent electrode of a solar cell, including an aromatic group-containing organic polymer compound (A) and a cross-linker (B), wherein the film-forming material exhibits an index of refraction of 1.5 to 2.0 at a wavelength of 633 nm and a transmittance of 95% or more with respect to light having a wavelength of 400 nm, and a solar cell obtained by coating a cured film made from the film-forming material on a surface of a transparent electrode.

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05-12-2013 дата публикации

PHOTOCURABLE FILM-FORMING COMPOSITION AND MANUFACTURING METHOD FOR CURED FILM

Номер: US20130324634A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

A composition comprising both a polymer which contains triazine-ring-containing repeating units represented by formula (17) and a crosslinking agent which consists of either a poly-functional epoxy compound or a polyfunctional (meth)acrylic compound can be photo-cured even without the addition of an initiator to yield a cured film having a high refractive index and high heat resistance. Thus, a photocurable film-forming composition that comprises a triazine-ring-containing polymer, which can achieve, even without the addition of a metal oxide by the polymer alone, high heat resistance, high transparency, a high refractive index, high solubility and low volume shrinkage, and that is curable even without the addition of an acid generator can be provided. 2. The photocurable film-forming composition according to claim 1 , wherein the crosslinking agent is a polyfunctional (meth)acrylate compound.3. The photocurable film-forming composition according to claim 1 , wherein the polyfunctional (meth)acrylate compound is a compound having an isocyanuric acid skeleton.4. The photocurable film-forming composition according to claim 1 , wherein the polyfunctional (meth)acrylate compound is a combination of a compound having an isocyanuric acid skeleton and a compound which at 25° C. is a liquid and has a viscosity of 5 claim 1 ,000 mPa·s or less.5. The photocurable film-forming composition according to claim 1 , wherein the polyfunctional (meth)acrylate compound is a compound which at 25° C. is a liquid and has a viscosity of 5 claim 1 ,000 mPa·s or less.6. The photocurable film-forming composition according to or claim 1 , wherein the compound having an isocyanuric acid skeleton is tris[2-(acryloyloxy)ethyl]isocyanurate.7. The photocurable film-forming composition according to which includes from 1 to 25 parts by weight of the crosslinking agent per 100 parts by weight of the triazine ring-containing polymer.8. The photocurable film-forming composition according to which ...

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05-01-2017 дата публикации

POLYHEMIAMINAL AND POLYHEXAHYDROTRIAZINE MATERIALS FROM 1,4 CONJUGATE ADDITION REACTIONS

Номер: US20170002145A1
Принадлежит:

Polyhemiaminal (PHA) and polyhexahydrotriazine (PHT) materials are modified by 1,4 conjugate addition chemical reactions to produce a variety of molecular architectures comprising pendant groups and bridging segments. The materials are formed by a method that includes heating a mixture comprising solvent(s), paraformaldehyde, aromatic amine groups, aliphatic amine Michael donors, and Michael acceptors, such as acrylates. The reaction mixtures may be used to prepare polymer pre-impregnated materials and composites containing PHT matrix resin. 2. The polymeric material of claim 1 , wherein A claim 1 , B claim 1 , D claim 1 , and E on each of the first claim 1 , second claim 1 , and third phenyl groups are hydrogens (H).4. The polymeric material of claim 3 , wherein R3 in each instance is:{'sub': 4', '11', '3, '—(CH)CH.'}5. The polymeric material of claim 3 , wherein R3 in each instance is:{'sub': 2', '3', '2', '3, 'sup': +', '−, '—(CH)N(CH)(HCCl).'}6. The polymeric material of claim 1 , wherein R1 in each instance is hydrogen (H).8. The polymeric material of claim 7 , wherein R4 is a polymeric moeity.9. The polymeric material of claim 8 , wherein R4 comprises a poly(ether) segment.10. The polymeric material of claim 8 , wherein R4 comprises a poly(butadiene) segment.11. The polymeric material of claim 8 , wherein R4 comprises a poly(amino ester) segment.13. The polymeric material of claim 12 , wherein R2 in each instance is hydrogen (H).14. The polymeric material of claim 13 , wherein R3 in each instance comprises a poly(butadiene) segment.15. The polymeric material of claim 13 , wherein R3 in each instance comprises a poly(amino ester) segment.16. The polymeric material of claim 1 , wherein at least one instance of R3 is:{'sub': 2', '11', '3, '—(CH)CH.'}17. The polymeric material of claim 1 , wherein at least one instance of R3 is:{'sub': 2', '3', '2', '3, 'sup': +', '−, '—(CH)N(CH)(HCCl).'}19. The polymeric material of claim 18 , wherein R3 in each instance is:{'sub ...

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20-01-2022 дата публикации

Composition of Phthalonitrile Resin Matrix for Polymer Composite Materials, Method for Fabrication Thereof, Method for Manufacturing of Polymer Composite Material, and Material Obtained by this Method

Номер: US20220017712A1
Принадлежит:

This invention is related to a resin matrix composition intended for production of a polymer composite material (PCM) or prepregs for PCM, to variants of methods for producing resin matrix compositions, to a method for curing the resin matrix composition, to a polymer composite material and method for its fabrication. The resin matrix composition includes: (1) polymerizable mixture containing one or more bis-phthalonitrile monomers with the general formula: 2. The composition of claim 1 , wherein the reactive diluent is selected from one or more compounds from the group consisting of 4-[3-(dipropargylamino)phenoxy]phthalonitrile claim 1 , 4-[4-(dipropargylamino)phenoxy]phthalonitrile claim 1 , 4-(4-cyanophenoxy)-benzene-1 claim 1 ,2-dicarbonitrile claim 1 , 4-(4-cyanophenoxy)-phthalonitrile claim 1 , 4-(3-cyanophenoxy)-phthalonitrile and 4-(4-aminophenoxy)-phthalonitrile claim 1 , the most preferably from one or more following compounds 4-(4-cyanophenoxy)-benzene-1 claim 1 ,2-dicarbonitrile claim 1 , 4-[3-(dipropargylamino)phenoxy]phthalonitrile claim 1 , 4-[4-(dipropargylamino)phenoxy]phthalonitrile.3. The composition of claim 1 , wherein the active diluent is present in an amount from 1 to 40 wt % of the total weight of the mixture or from 10 to 50 wt % of the total weight of the mixture claim 1 , or from 10 to 40 wt % of the total weight of the mixture claim 1 , or from 20 to 40 wt % of the total weight of the mixture claim 1 , or from 20 to 35 wt % of the total weight of the mixture claim 1 , or from 20 to 30 wt % of the total weight of the mixture claim 1 , preferably from 10 to 40% of the total weight of the mixture claim 1 , or in the amount of 10 to 30% of the total weight of the mixture.4. The composition of claim 1 , wherein said aryl is an optionally substituted aryl C-C claim 1 , preferably an aryl C-C claim 1 , more preferably an unsubstituted aryl C-Cor a substituted aryl C claim 1 , wherein the substituent may be methyl claim 1 , fluoro claim 1 , ...

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11-01-2018 дата публикации

POROUS/NANOPOROUS PHT

Номер: US20180009948A1
Принадлежит:

Methods of forming nanoporous materials are described herein that include forming a polymer network with a chemically removable portion. The chemically removable portion may be polycarbonate polymer that is removable on application of heat or exposure to a base, or a polyhexahydrotriazine (PHT) or polyhemiaminal (PHA) polymer that is removable on exposure to an acid. The method generally includes forming a reaction mixture comprising a formaldehyde, a solvent, a primary aromatic diamine, and a diamine having a primary amino group and a secondary amino group, the secondary amino group having a base-reactive substituent, and heating the reaction mixture to a temperature of between about 50 degC and about 150 degC to form a polymer. Removing any portion of the polymer results in formation of nanoscopic pores as polymer chains are decomposed, leaving pores in the polymer matrix. 1. An article comprising a porous polymer having a plurality of hexahydrotriazine units , hemiaminal units , or both , the polymer having an average pore size less than about 100 nm and density less than about 1.5 g/cm.2. The article of claim 1 , further comprising a plurality of carbon fibers disposed in the porous polymer.4. The article of claim 3 , wherein each bridging group is divalent or trivalent and is bonded to at least two hexahydrotriazine units or hemiaminal units.6. The article of claim 3 , wherein the porous polymer also has a plurality of monovalent sub stitutents.8. An article comprising a porous polymer having a plurality of hexahydrotriazine units claim 3 , hemiaminal units claim 3 , or both claim 3 , the polymer having an average pore size of 20-100 nm and bulk density of 1.0-1.5 g/cm.9. The article of claim 8 , further comprising a plurality of carbon fibers disposed in the porous polymer.11. The article of claim 10 , wherein each bridging group is divalent or trivalent and is bonded to at least two hexahydrotriazine units or hemiaminal units.13. The article of claim 10 , ...

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28-01-2016 дата публикации

THERMOPLASTIC TOUGHENING OF PHT'S

Номер: US20160024253A1
Принадлежит:

Polyhexahydrotriazine (PHT) and polyhemiaminal (PHA) materials chemically modified to include thermoplastic polymer bridging groups, and methods of making such materials, are disclosed. The materials are formed by a process that includes heating a mixture comprising i) a solvent, ii) paraformaldehyde, iii) a diamine monomer comprising two primary aromatic amine groups, and iv) a polymer diamine at a temperature of about 20° C. to less than 150° C. This heating step forms a stable PHA in solution, which can be isolated. The PHA includes covalently bonded thermoplastic polymer groups. The PHA is then heated at a temperature of 150° C. to about 280° C., thereby converting the PHA material to a PHT material that includes covalently bonded thermoplastic polymer groups. 2. The PHT of claim 1 , wherein each Q is independently a vinyl polymer chain claim 1 , a polyether chain claim 1 , a polyester chain claim 1 , a polyimide chain claim 1 , a polyamide chain claim 1 , a polyurea chain claim 1 , a polyurethane chain claim 1 , a polyaryl ether sulfone chain claim 1 , a polybenzoxazole chain claim 1 , a polybenimidazole chain claim 1 , an epoxy resin claim 1 , a polysiloxane chain claim 1 , a polybutadiene chain claim 1 , and butadiene copolymer claim 1 , or a combination thereof.3. The PHT of claim 1 , wherein L′ is a divalent linking group selected from the group consisting of *—O—* claim 1 , *—S—* claim 1 , *—N(R′)—* claim 1 , *—N(H)—* claim 1 , *—R″—* claim 1 , and combinations thereof claim 1 , wherein R′ comprises at least one carbon and R″ comprises at least one carbon claim 1 ,4. The PHT of claim 1 , wherein a ratio of number of L′ groups to number of Q groups is at least about 30.6. The PHT of claim 3 , wherein each Q is a polyaryl ether sulfone chain.719.-. (canceled) The present invention relates to methods of improving physical properties of polyhemiaminal and polyhexahydrotriazine polymers and networks, and more specifically to preparing polyhemiaminals and ...

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28-01-2016 дата публикации

THERMOPLASTIC TOUGHENING OF PHT'S

Номер: US20160024254A1
Принадлежит:

Polyhexahydrotriazine (PHT) and polyhemiaminal (PHA) materials chemically modified to include thermoplastic polymer bridging groups, and methods of making such materials, are disclosed. The materials are formed by a process that includes heating a mixture comprising i) a solvent, ii) paraformaldehyde, iii) a diamine monomer comprising two primary aromatic amine groups, and iv) a polymer diamine at a temperature of about 20° C. to less than 150° C. This heating step forms a stable PHA in solution, which can be isolated. The PHA includes covalently bonded thermoplastic polymer groups. The PHA is then heated at a temperature of 150° C. to about 280° C., thereby converting the PHA material to a PHT material that includes covalently bonded thermoplastic polymer groups. 1. A method , comprising:{'sub': '1', 'forming a polymer diamine mixture having Mof at least about 1000 g/mole;'}forming a reaction mixture comprising i) the polymer diamine mixture, ii) a solvent, iii) paraformaldehyde, and iv) a monomer comprising two primary aromatic amine groups; andheating the reaction mixture at a temperature of 150° C. to about 280° C., thereby forming a PHT.3. The method of claim 2 , wherein each Q is a polyaryl ether sulfone chain.4. The method of claim 3 , wherein L′ is *—O—*.5. The method of claim 3 , wherein L′ is *—R″—* and R″ comprises at least one carbon.6. A method claim 3 , comprising:forming a mixture comprising i) a solvent, ii) paraformaldehyde, iii) a polymer diamine mixture, and iv) a monomer comprising two primary aromatic amine groups; andheating the mixture at a temperature of about 20° C. or higher to form a polyhemiaminal (PHA).8. The method of claim 7 , wherein the solvent is selected from the group consisting of N-methylpyrollidone (NMP) claim 7 , propylene carbonate (PC) claim 7 , dimethylacetamide (DMA) claim 7 , dimethylsulfoxide (DMSO) claim 7 , propylen glycol methyl ether acetate (PGMEA) claim 7 , dimethylformamide (DMF) claim 7 , and combinations thereof ...

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11-02-2016 дата публикации

High-performance, filler-reinforced, recyclable composite materials

Номер: US20160039976A1
Принадлежит: International Business Machines Corp

Polyhexahydrotriazine (PHT) and polyhemiaminal (PHA) materials form highly cross-linked polymers which can be used as binder resins in composite materials. A filler element functionalized with a primary amine group can be covalently bonded to the PHA/PHT polymer resins. Example filler elements include, without limitation, carbon nanotubes, silica materials, carbon and glass fibers, and nanoparticles. Filler materials are incorporated into polymeric materials to improve the mechanical strength or other characteristics of the polymeric material for various applications. Typical composite materials use thermosetting materials that, once set, are intractable. PHT and PHA materials can be reverted to starting materials by exposure to acids. Thus, composite components formed using these materials are recyclable.

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07-02-2019 дата публикации

SYSTEMS CHEMISTRY APPROACH TO POLYHEXAHYDROTRIAZINE POLYMERIC STRUCTURES

Номер: US20190040200A1
Принадлежит:

In some embodiments, a product, such as a thermoset, has a polyhexahydrotriazine and a self-polymerized cross-linkable polymer. In some embodiments, a product is the reaction product of a diamine, an aldehyde, and a compound having an α,β-unsaturated electron withdrawing moiety. 1. A product that is the reaction product of:a diamine;an aldehyde;a compound having an α,β-unsaturated electron withdrawing moiety; anda cross-linkable polymer.2. The product of claim 1 , wherein the aldehyde is paraformaldehyde.3. The product of claim 1 , wherein the cross-linkable polymer is functionalized with at least one of cyanate claim 1 , alkyne claim 1 , epoxide claim 1 , maleimide claim 1 , and norbornene-2 claim 1 ,3-dicarboximide.8. The product of claim 1 , wherein the diamine is of the structure: NH—X—NH claim 1 , wherein X is selected from the group consisting of a phosphine derivative claim 1 , an ether claim 1 , and a lactone.10. The product of claim 1 , wherein the compound having an α claim 1 ,β-unsaturated electron withdrawing moiety is an acrylate that is 1 claim 1 ,4-butanediol diacrylate or trimethylolpropane triacrylate.11. The product of claim 1 , wherein the cross-linkable polymer is an epoxide that is a diglycidyl ether of a bisphenol.17. The composition of claim 15 , wherein n is a positive integer from between about 2 to about 500.20. The composition of claim 18 , wherein n is a positive integer from between about 2 to about 500. This application is a divisional application of U.S. application Ser. No. 15/460,785 filed Mar. 16, 2017, which is a divisional of U.S. application Ser. No. 14/951,186 filed Nov. 24, 2015, now U.S. Pat. No. 9,873,766. The above-mentioned applications are hereby incorporated by reference.Embodiments herein generally relate to polyhexahydrotriazines (PHTs) with tailored macromolecular architectures.Polyhexahydrotriazines (PHTs) are an emerging class of high strength engineering thermosetting polymers (thermosets) that have a unique ...

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07-02-2019 дата публикации

POST SPACER, LIQUID CRYSTAL DISPLAY PANEL INCLUDING THE SAME, AND METHOD FOR MANUFACTURING LIQUID CRYSTAL DISPLAY PANEL

Номер: US20190041679A1
Автор: YANG Yong

The present disclosure discloses a post spacer, which is applied to a liquid crystal display panel. The post spacer has a material having a structure as represented by Formula 1, wherein X includes at least one of groups represented by Formulae 2-1 to 2-5; Y includes at least one of groups represented by Formulae 3-1 and 3-2; at least one of the X and the Y has a molecular chain end having a group capable to chemically cross-link with materials of alignment layers; and at least one of the X and the Y has a side chains having a group capable to generate a hydrogen bond or intermolecular force with a material of liquid crystal molecules. The present disclosure also discloses a liquid crystal display panel having the post spacers described above and a method of manufacturing the same. 2. The post spacer of claim 1 , wherein the first group is at least one selected from an azo group claim 1 , an imide group and an amine group claim 1 , and the second group is at least one selected from a Cto Calkyl chain claim 1 , a cyano group claim 1 , a fluoro group claim 1 , a hydroxyl group and an ester group.3. The post spacer of claim 2 , wherein the material of the liquid crystal molecules has at least one group selected from a Cto Calkyl chain claim 2 , a cyano group claim 2 , a fluoro group claim 2 , a hydroxyl group and an ester group.4. The post spacer of claim 2 , wherein the material of the alignment layer has at least one group selected from an epoxy group claim 2 , a hydroxyl group and a carboxyl group.6. The post spacer of claim 5 , wherein the material of the post spacer has a net structure claim 5 , or a linear structure having a relative molecular weight of 50000˜100000.8. The liquid crystal display panel of claim 7 , wherein the first group is at least one selected from an azo group claim 7 , an imide group and an amine group claim 7 , and the second group is at least one selected from a Cto Calkyl chain claim 7 , a cyano group claim 7 , a fluoro group claim 7 , a ...

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15-02-2018 дата публикации

THERMOSET POLYMERS HAVING A TRIAZINE NETWORK OBTAINED BY REACTION OF CYANATE ESTERS WITH DICYANAMIDE ROOM TEMPERATURE IONIC LIQUIDS

Номер: US20180044473A1
Принадлежит: DREXEL UNIVERSITY

The invention relates to the use of dicyanamide-containing ionic liquids which decrease the cure temperature of cyanate esters to form unique thermoset polymers having a triazine network. These thermoset polymers having the triazine network have an ionic character allowing for use in varied applications. The thermoset polymers described herein are useful in high temperature performance composites, and their high Tg makes them useful as a substitute for epoxies in the microelectronics industry. The thermoset polymers have good fracture toughness, excellent substrate adhesion, low shrinkage, and low moisture uptake. 1. A curable composition for preparing a thermoset polymer having a triazine network , said curable composition comprising:(a) a cyanate ester monomer; and(b) at least one ionic liquid comprising a dicyanamide anion.2. The curable composition of claim 1 , wherein said ionic liquid comprises the dicyanamide anion and at least one cation selected from the group consisting of imidazolium claim 1 , phosphonium claim 1 , pyridinium and pyrrolidinium.3. The curable composition of claim 1 , wherein said cation is selected from the group consisting of 1-ethyl-3-methyl imidazolium claim 1 , 1-(3-cyanopropyl)-3-methyl imidazolium claim 1 , trihexyltetradecylphosphonium claim 1 , 1-(2-hydroxyethyl)-3-methylimidazolium claim 1 , 1-butyl-3-methyl pyridinium claim 1 , and 1-butyl-1-methyl-pyrrolidinium.4. The curable composition as claimed in claim 1 , wherein said cyanate ester monomer has two cyanate ester groups bonded to a core which is an optionally substituted aryl claim 1 , alkyl or aralkyl group.5. The curable composition as claimed in claim 1 , wherein said cyanate ester monomer has two cyanate ester groups bonded to a core which is an optionally substituted aralkyl group having 2 or more phenyl rings.6. The curable composition of claim 1 , wherein said cyanate ester monomer has two cyanate ester groups bonded to phenyl rings of an alkylenebisphenyl group.7. ...

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14-02-2019 дата публикации

IMPACT RESISTANT FLAME RETARDANT POLYHEXAHYDROTRIAZINE POLYMERS VIA GENERATION OF POLYHEXAHYDROTRIAZINE MONOMERS AND HEXAHYDRO-1,3,5-TRIAZINE SMALL MOLECULES

Номер: US20190048140A1
Принадлежит:

An impact resistant polyhexahydrotriazine polymer, a process for forming an impact resistant polyhexahydrotriazine polymer, and an article of manufacture comprising an impact resistant material containing an impact resistant polyhexahydrotriazine polymer are disclosed. The impact resistant polyhexahydrotriazine polymer includes at least one hexahydrotriazine group and at least one chain comprising an allylic portion and a styrenic portion. Variations in the chain control properties of the impact resistant polymer. The process of forming the impact resistant polyhexahydrotriazine polymer includes reactions between formaldehyde and at least two classes of monomer that form hexahydrotriazine groups and impact resistant chains. Adjusting relative monomer concentrations controls properties of the impact resistant polyhexahydrotriazine polymer. The article of manufacture contains a material that has an impact resistant polymer. Impact resistance of the impact resistant polyhexahydrotriazine polymer is dependent upon variation in relative amounts of monomers used in its synthesis. 1. An impact resistant polymer , comprising:at least one hexahydrotriazine group; andat least one chain comprising an allylic portion and a styrenic portion, wherein variation in the at least one chain controls impact resistance of the impact resistant polymer.2. The impact resistant polymer of claim 1 , wherein the variation is a difference in relative lengths of the allylic portion and the styrenic portion.3. The impact resistant polymer of claim 2 , wherein the difference in relative lengths of the allylic portion and the styrenic portion controls a degree of cross-linking in the impact resistant polymer.4. The impact resistant polymer of claim 3 , wherein the degree of cross-linking controls impact resistance of the impact resistant polymer.5. The impact resistant polymer of claim 1 , wherein the at least one chain further comprises a flame retardant portion.6. The impact resistant polymer of ...

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13-02-2020 дата публикации

Phosphazene-containing polyhexahydrotriazine elastomers

Номер: US20200048417A1
Принадлежит: International Business Machines Corp

An elastomer, a process for forming an elastomer, and an article of manufacture are disclosed. The elastomer comprises a phosphazene backbone and at least one polyhexahydrotriazine component. The process for forming the elastomer includes obtaining an amine-terminated cyclotriphosphazene, reacting it with a diamine to form a phosphazene-containing PHT polymer, and then reacting the phosphazene-containing PHT polymer with a side-chain modified cyclic phosphazene to form a PCPHT elastomer with halogen ligands. The PCPHT elastomer with halogen ligands is then reacted with an alkoxide to form a PCPHT elastomer with at least one ether-linked side chain. The article of manufacture comprises a material comprising an elastomer having a phosphazene backbone and at least one PHT component.

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10-03-2016 дата публикации

SYNTHETIC POLYMERS AND METHODS OF MAKING AND USING THE SAME

Номер: US20160068635A1
Принадлежит:

Monomer embodiments that can be used to make polymers, such as homopolymers, heteropolymers, and that can be used in particular embodiments to make sequence-defined polymers are described. Also described are methods of making polymers using such monomer embodiments. Methods of using the polymers also are described. 2. The polymer of claim 1 , wherein two or more Rgroups are different.3. The polymer of claim 1 , wherein two or more Wgroups claim 1 , Lgroups claim 1 , or Zgroups are different.4. The polymer of claim 1 , wherein T and Tindependently are selected from an amine claim 1 , an alkylene oxide claim 1 , an alkylene amino claim 1 , or an alkylene thio.5. The polymer of claim 1 , wherein T and Tindependently are or comprise a solid support.6. The polymer of claim 1 , wherein Rand each of Rindependently is selected from Calkyl claim 1 , Cheteroalkyl claim 1 , or Caryl.7. The polymer of claim 1 , wherein Rand each of Rindependently is selected from methyl claim 1 , ethyl claim 1 , propyl claim 1 , butyl claim 1 , pentyl claim 1 , hexyl claim 1 , septyl claim 1 , octyl claim 1 , nonyl claim 1 , decyl claim 1 , phenyl claim 1 , propyne claim 1 , —(CH)—CH—Cl claim 1 , —(CH)NH claim 1 , —(CH)NHBOC claim 1 , —(CH)COOH claim 1 , or —(CH)COOBu.8. The polymer of claim 1 , wherein each of W claim 1 , W claim 1 , Z claim 1 , and Zindependently are selected from NH claim 1 , S claim 1 , or O.9. The polymer of claim 1 , wherein each of Land Lindependently are selected from —(CH)— claim 1 , —(CH)— claim 1 , —C(Me)H—CH— claim 1 , —CH—C(Me)H— claim 1 , —C(Me)H—C(Me)H— claim 1 , —C(Naphthyl)H—C(Naphthyl)H— claim 1 , and —(CH)—O—(CH)—.11. The polymer of claim 10 , wherein the polymer comprises at least one Rgroup and Ris ethyl or naphthyl.14. The polymer of claim 1 , wherein:{'sup': 1', 'n', '1', 'p', '4', '4', '1', 'q, 'any one or more of Ror Ris not butyl if any one or more of Yor Yis NRwhere Ris butyl and any one or more of Lor Lis phenyl or —Ph—O—Ph;'}{'sup': 1', 'q', '1', 'a ...

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18-03-2021 дата публикации

POLYIMIDE PRECURSOR COMPOSITION, USE THEREOF AND POLYIMIDE MADE THEREFROM

Номер: US20210079161A1
Принадлежит: ETERNAL MATERIALS CO., LTD.

The present disclosure relates to a polyimide precursor composition comprising an antic acid ester oligomer of formula (I): 2. The method according to claim 1 , wherein r is an integer ranging from 5 to 150.5. The method according to claim 1 , wherein based on the total moles of the divalent organic groups P present in the composition claim 1 , about 1 mol % to about 15 mol % of the divalent organic group P is an divalent organic group that is capable of forming a coordinate bond with a metal ion.10. The method according to claim 1 , wherein the amic acid ester oligomer is in an amount of about 10 wt % to about 70 wt % claim 1 , based on the total weight of the polyimide precursor composition.11. The method according to claim 9 , wherein the cyclization promoter is in an amount of about 0.1 parts by weight to about 2 parts by weight claim 9 , based on 100 parts by weight of the amic acid ester oligomer of formula (I).13. The method according to claim 1 , wherein the polyimide is activated by plasma or laser.14. The method according to claim 1 , wherein the metal ion is copper ion.15. The method according to claim 1 , wherein the plated metal is copper.16. The method according to claim 1 , wherein in step (d) a patterned metal layer or circuit is formed. This application is a Divisional of U.S. patent application Ser. No. 15/941,052 filed Mar. 30, 2018, which claims the benefit of Taiwanese Application No.: 106111470 filed Mar. 31, 2017, the content of which is incorporated herein by reference.The present disclosure relates to a polyimide precursor composition and the applications thereof. In particular, the present disclosure relates to a polyimide precursor composition that can be used in a laser direct imaging process.A printed circuit board (PCB) is a product where a designed circuit pattern is transferred to a substrate by printing so that the substrate can be equipped with electronic devices and the connection to related circuit signals can be built.A most ...

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22-03-2018 дата публикации

POROUS MATERIALS AND METHOD OF MAKING POROUS MATERIALS

Номер: US20180079883A1
Принадлежит:

A porous material includes a resin material based on a trifunctional ethynyl monomer. Pores in the porous material can be of various sizes including nanoscale sizes. The porous material may be used in a variety of applications, such as those requiring materials with a high strength-to-weight ratio. The porous material can include a filler material dispersed therein. The filler material can be, for example, a particle, a fiber, a fabric, or the like. In some examples, the filler material can be a carbon fiber or a carbon nanotube. A method of making a porous material includes forming a resin including a trifunctional ethynyl monomer component and a polythioaminal component. The resin can be heated to promote segregation of the components into different phases with predominately one or the other component in each phase. Processing of the resin after phase segregation to decompose the polythioaminal component can form pores in the resin. 1. A method , comprising:forming a mixture comprising: i) trifunctional ethynyl monomer, ii) a polythioaminal, and iii) a solvent;heating the mixture to a first temperature at which the trifunctional ethynyl monomer polymerizes to a first resin and the polythioaminal is substantially stable; andheating the mixture to a second temperature at which the first resin further polymerizes to a second resin that is a crosslinked resin and the polythioaminal decomposes, the second temperature being higher than the first temperature.2. The method of claim 1 , wherein the trifunctional ethynyl monomer is 1 claim 1 ,3 claim 1 ,5 tris-(4-ethynyl phenyl)benzene.3. The method of claim 1 , wherein the mixture includes a filler material.4. The method of claim 3 , wherein the filler material is a carbon fiber.5. The method of claim 3 , wherein the filler material is a carbon nanotube.6. The method of claim 3 , wherein the filler material is a fiber.7. The method of claim 1 , wherein the mixture includes a filler material that is at least one of a ...

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24-03-2016 дата публикации

METHODS OF PREPARING POLYHEMIAMINALS AND POLYHEXAHYDROTRIAZINES

Номер: US20160083520A1
Принадлежит:

Polyhexahydrotriazine (PHT) film layers are formed by a process comprising heating a first mixture comprising i) a solvent, ii) paraformaldehyde, and iii) a diamine monomer comprising two primary aromatic amine groups at a temperature of about 20° C. to less than 150° C. This heating step forms a stable polyhemiaminal (PHA) in solution, which can be cast on a surface of a substrate, thereby forming an initial film layer comprising the PHA. The initial film layer is heated at a temperature of 180° C. to about 280° C., thereby converting the PHA film layer to a PHT film layer. Young's moduli of about 8 GPA to about 14 GPA have been observed for the PHT film layers. 2. The PHT of claim 1 , wherein the PHT has a number average molecular weight (Mn) of about 1000 to about 20000.3. The PHT of claim 1 , wherein L′ is *—O—*.4. The PHT of claim 1 , wherein L′ is *—S—*.5. The PHT of claim 1 , wherein L′ is *—N(R′)—* claim 1 , wherein R′ is selected from the group consisting of methyl claim 1 , ethyl claim 1 , propyl claim 1 , isopropyl claim 1 , phenyl claim 1 , and combinations thereof.6. The PHT of claim 1 , wherein L′ is *—CH—*.7. The PHT of claim 1 , wherein L′ is isopropylidenyl (*—C(Me)-*).11. The PHT of claim 1 , wherein the PHT is a product of a reaction of paraformaldehyde with a monomer comprising two primary aromatic amine groups at a temperature of 150° C. to about 280° C.12. The PHT of claim 11 , wherein the monomer is selected from the group consisting of 4 claim 11 ,4′-oxydianiline (ODA) claim 11 , 4 claim 11 ,4′-methylenedianiline (MDA) claim 11 , p-phenylenediamine (PD) claim 11 , 4 claim 11 ,4′-(9-fluorenylidenyl)dianiline (FDA) claim 11 , and combinations thereof.13. The PHT of claim 12 , wherein the reaction is conducted in a solvent selected from the group consisting of N-methylpyrolidone (NMP) claim 12 , propylene carbonate (PC) claim 12 , dimethylacetamide (DMA) claim 12 , dimethylsulfoxide (DMSO) claim 12 , propylene glycol methyl ether acetate (PGMEA) ...

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30-03-2017 дата публикации

SYNTHETIC POLYMERS AND METHODS OF MAKING AND USING THE SAME

Номер: US20170088671A1
Принадлежит: BATTELLE MEMORIAL INSTITUTE

Disclosed herein are monomer embodiments that can be used to make polymers, such as homopolymers, heteropolymers, and that can be used in particular embodiments to make sequence-defined polymers. Also disclosed herein are methods of making polymers using such monomer embodiments. Methods of using the polymers disclosed herein also are described. 2. The polymer of claim 1 , wherein at least one of Rand Ris hydrogen bound to Yor Y claim 1 , respectively claim 1 , with Yor Ybeing a bond that binds Ror Rto a triazine ring of the polymer.3. The polymer of claim 1 , wherein at least one of Rand Ris hydrogen bound to Yor Y claim 1 , respectively claim 1 , with Yor Ybeing oxygen claim 1 , sulfur claim 1 , or —NH.4. The polymer of claim 1 , wherein at least one of Rand Ris aliphatic bound to Yor Y claim 1 , respectively claim 1 , with Yor Ybeing oxygen claim 1 , sulfur claim 1 , or —NH.5. The polymer of claim 1 , wherein each Wand each Zindependently is selected from —NH claim 1 , S claim 1 , or O.6. The polymer of claim 1 , wherein each of Lindependently is aliphatic.7. The polymer of claim 1 , wherein T and Tindependently are selected from —NH; —NHR; —NRR—SH; —SR; —OH; or —OR; wherein each Rand Rindependently is selected from aliphatic or aryl.8. The polymer of claim 1 , wherein each Rand Rindependently is selected from phenyl claim 1 , benzyl claim 1 , halogen-substituted benzyl claim 1 , dimethoxy-substituted benzyl claim 1 , Cthiol claim 1 , Chydroxyl claim 1 , or Camine.10. The polymer of claim 1 , wherein the polymer is assembled in the form of a membrane claim 1 , an amorphous particle claim 1 , a crystal claim 1 , or a nanorod wherein a backbone of the polymer interacts to create a columnar structure and side chains of the polymer project outward from the column.11. A plurality of polymers comprising two or more polymers of claim 1 , wherein each of the two or more polymers of are the same or different and are assembled in the form of a nanorod wherein side chains ...

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12-05-2022 дата публикации

Triazine-based membranes for gas separation

Номер: US20220145008A1

A polymer composition comprising a covalent triazine framework having the following structure: wherein: each asterisk (*) in A units denotes a point of covalent bonding with an asterisk in B units, and each asterisk (*) in B units denotes a point of covalent bonding with an asterisk in A units; r is an integer of 1-3; R is a fluorinated hydrocarbon containing at least two aromatic rings and at least one ether linkage between aromatic rings; the composition includes a multiplicity of A units and multiplicity of B units; and a portion of the connection points are terminated by endcapping nitrile groups. Also described are methods for producing the polymer and a microporous carbon material produced by pyrolysis of the porous polymer membrane. Also described are methods for using the polymer and microporous carbon material for gas or liquid separation, filtration, or purification.

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21-04-2016 дата публикации

POROUS/NANOPOROUS PHT

Номер: US20160108176A1
Принадлежит:

Methods of forming nanoporous materials are described herein that include forming a polymer network with a chemically removable portion. The chemically removable portion may be polycarbonate polymer that is removable on application of heat or exposure to a base, or a polyhexahydrotriazine (PHT) or polyhemiaminal (PHA) polymer that is removable on exposure to an acid. The method generally includes forming a reaction mixture comprising a formaldehyde, a solvent, a primary aromatic diamine, and a diamine having a primary amino group and a secondary amino group, the secondary amino group having a base-reactive substituent, and heating the reaction mixture to a temperature of between about 50 deg C. and about 150 deg C. to form a polymer. Removing any portion of the polymer results in formation of nanoscopic pores as polymer chains are decomposed, leaving pores in the polymer matrix. 1. A thermally stable polymer material comprising a porous carbon-nitrogen polymer having average pore size less than about 100 nm and density less than about 1.5 g/cm.2. The thermally stable polymer material of claim 1 , further comprising carbon fibers.3. The thermally stable polymer material of claim 1 , wherein the carbon-nitrogen polymer is a polyhexahydrotriazine.6. A polymeric material comprising a plurality of hexahydrotriazine units claim 1 , hemiaminal units claim 1 , or both bonded together by a first linkage and a second linkage claim 1 , wherein the first linkage is thermally stable and resistant to bases and the second linkage is thermally degradable and degradable by a base.7. The polymeric material of claim 6 , wherein the second linkage is a polycarbonate or polyester linkage.8. The polymeric material of claim 7 , wherein the first linkage is a dianiline linkage.1017-. (canceled)18. An article comprising a porous polymer having a plurality of hexahydrotriazine units claim 7 , hemiaminal units claim 7 , or both.19. The article of claim 18 , further comprising a plurality of ...

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27-04-2017 дата публикации

POROUS/NANOPOROUS PHT

Номер: US20170114186A1
Принадлежит:

Methods of forming nanoporous materials are described herein that include forming a polymer network with a chemically removable portion. The chemically removable portion may be polycarbonate polymer that is removable on application of heat or exposure to a base, or a polyhexahydrotriazine (PHT) or polyhemiaminal (PHA) polymer that is removable on exposure to an acid. The method generally includes forming a reaction mixture comprising a formaldehyde, a solvent, a primary aromatic diamine, and a diamine having a primary amino group and a secondary amino group, the secondary amino group having a base-reactive substituent, and heating the reaction mixture to a temperature of between about 50 degC and about 150 degC to form a polymer. Removing any portion of the polymer results in formation of nanoscopic pores as polymer chains are decomposed, leaving pores in the polymer matrix. 1. A thermally stable polymer material comprising a porous polyhemiaminal having average pore size less than about 100 nm and density less than about 1.5 g/cm.2. The thermally stable polymer material of claim 1 , further comprising carbon fibers.3. The thermally stable polymer material of claim 1 , wherein the thermally stable polymer material further comprises a polyhexahydrotriazine.6. A polymeric material comprising a plurality of hemiaminal units bonded together by a first linkage and a second linkage claim 1 , wherein the first linkage is thermally stable and resistant to bases and the second linkage is thermally degradable and degradable by a base.7. The polymeric material of claim 6 , wherein the second linkage is a polycarbonate or polyester linkage.8. The polymeric material of claim 7 , wherein the first linkage is a dianiline linkage.10. A method of making a material claim 7 , comprising:forming a reaction mixture comprising a formaldehyde, a solvent, a primary aromatic diamine, and a diamine having a primary amino group and a secondary amino group, the secondary amino group having a ...

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27-04-2017 дата публикации

POROUS MATERIALS AND METHOD OF MAKING POROUS MATERIALS

Номер: US20170114204A1
Принадлежит:

A porous material includes a polyhexahydrotriazine material. Pores in the porous material can be of various sizes including nanoscale sizes. The porous material may be used in a variety of applications, such as those requiring materials with a high strength-to-weight ratio. The porous material can include a filler material dispersed therein. The filler material can be, for example, a particle, a fiber, a fabric, or the like. In some examples, the filler material can be a carbon fiber or a carbon nanotube. A method of making a porous material includes forming a resin including a polyhemiaminal or polyhexahydrotriazine component and a polythioaminal component. The resin can be heated to promote segregation of the components into different phases with predominately one or the other component in each phase. Processing of the resin after phase segregation to decompose the polythioaminal component can form pores in the resin. 1. A method , comprising:forming a reaction mixture comprising: i) paraformaldehyde, ii) a monomer including at least two primary aromatic amine groups, and iii) a polythioaminal including at least two primary aromatic amine groups; andheating the reaction mixture to form a resin including a polyhexahydrotriazine component and a polythioaminal component.2. The method of claim 1 , further comprising heating the resin to form a phase segregated resin including a first portion in which the polyhexahydrotriazine component is predominant and a second portion in which the polythioaminal component is predominant.3. The method of claim 2 , further comprising heating the phase segregated resin to a temperature at which the polythioaminal component decomposes and at which the polyhexahydrotriazine component is substantially stable.4. The method of claim 3 , wherein the heating of the phase segregated resin is performed at a pressure below 1 atm.5. The method of claim 3 , wherein the reaction mixture further comprises a filler material.6. The method of claim 5 ...

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13-05-2021 дата публикации

PERSONALIZED, ALLOGENEIC CELL THERAPY OF CANCER

Номер: US20210139418A1
Принадлежит:

The present invention describes methods of preparing a cell composition for treating cancer in a human being by obtaining lymphocytes from a partially or fully HLA-matched healthy donor, activating and expanding T cells reactive to neo-antigens (i.e. new epitopes resulting from somatic mutations in the cancer cell), and enriching for tumor-specific T cells that are not reactive against non-tumor tissue of the cancer patient. Provide herein are lymphocyte compositions comprising partially or fully HLA-matched healthy donor T cells reactive to neo-antigens. Also provided herein are methods of treating human cancer with such neo-antigen-specific, non-alloreactive T cells. 1. A method of making an allogeneic lymphocyte composition for treating cancer , the method comprising:a) providing a peripheral blood composition comprising a population of lymphocytes from a human donor allogeneic to the recipient, said composition comprising T cells, in which the T cells are enriched for T cells reactive to neo-antigens in the recipient andb) depleting of T cells reactive to antigens on non-cancerous tissues of the recipient,to thereby generate a population of non-alloreactive T cells depleted of alloreactive T cells.2. The method of claim 1 , wherein the T cell is CD3 T cell.3. The method of claim 1 , wherein neo-antigens are identified by whole exome sequencing and RNAseq of both cancerous and non-cancerous tissue of the same individual claim 1 , and HLA binding algorithms applied to determine which neo-antigens bind HLA molecules shared by the donor and recipient.4. The method of claim 1 , wherein the donor has been immunized against one or more neo-antigen of the recipient.5. The method of claim 4 , wherein the immunization consists of intramuscular injection of antigen emulsified in an adjuvant or DNA vaccination plus electroporation.6. The method of claim 1 , wherein the T cells from an unvaccinated donor are stimulated ex vivo with one or more neo-antigen claim 1 , with or ...

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04-05-2017 дата публикации

COATING COMPOSITIONS FOR USE WITH AN OVERCOATED PHOTORESIST

Номер: US20170123319A1
Принадлежит:

Organic coating compositions, particularly antireflective coating compositions for use with an overcoated photoresist, are provided that in a first aspect comprise a crosslinker component that comprises a structure of the following Formula (I): 1. A method for forming a photoresist relief image , comprising:a) applying on a substrate a layer of a coating composition comprising a resin that comprises one or more glycoluril groups that have a non-hydrogen substituent at the 1 and/or 5 glycoluril ring positions; andb) applying a layer of a photoresist composition above the coating composition layer.4. The method of wherein at least one of Rand Ris optionally substituted alkyl or optionally substituted heteroalkyl.5. The method of wherein the resin comprises 1) polyester linkages and/or 2) polymerized isocyanurate groups.6. The method of the photoresist composition is imaged with activating radiation and the imaged photoresist composition layer is developed to provide a photoresist relief image.9. A resin that comprises one or more glycoluril groups that have a non-hydrogen substituent at the 1 and/or 5 glycoluril ring positions. The present invention relates to compositions and, in particular, antireflective coating compositions for use in microelectronic application Compositions of the invention comprise a resin with covalently linked substituted glycoluril moieties. Preferred compositions of the invention are used with an overcoated photoresist composition and may be referred to as bottom antireflective compositions or “BARCs”.Photoresists are photosensitive films used for the transfer of images to a substrate. A coating layer of a photoresist is formed on a substrate and the photoresist layer is then exposed through a photomask to a source of activating radiation. Following exposure, the photoresist is developed to provide a relief image that permits selective processing of a substrate.Reflection of activating radiation used to expose a photoresist often poses ...

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10-05-2018 дата публикации

REVERSIBLE AMINAL GEL COMPOSITIONS, METHODS, AND USE

Номер: US20180127634A1
Принадлежит:

A well treatment composition for use in a hydrocarbon-bearing reservoir comprising a reversible aminal gel composition is disclosed. The reversible aminal gel composition includes a liquid precursor composition. The liquid precursor composition is operable to remain in a liquid state at about room temperature. The liquid precursor composition comprises an organic amine composition; an aldehyde composition; a polar aprotic organic solvent; and a metal salt composition with valence 3, 4, or 5. The liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature in the hydrocarbon-bearing reservoir. The gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, and the gel state is operable to return to the liquid state responsive to a change in the hydrocarbon-bearing reservoir selected from the group consisting of: a decrease in pH in the hydrocarbon-bearing reservoir and an addition of excess metal salt composition in the hydrocarbon-bearing reservoir. 1. A method for producing a reversible aminal gel composition , the method comprising the steps of: an organic amine composition;', 'an aldehyde composition;', 'a polar aprotic organic solvent; and', 'a metal salt composition with valence 3, 4, or 5;, 'preparing a liquid precursor composition, the liquid precursor composition operable to remain in a liquid state at about room temperature, where the liquid precursor composition comprisesallowing the liquid precursor composition to transition from the liquid state to a gel state responsive to an increase in temperature; andreturning the gel state to the liquid state by changing a property selected from the group consisting of: pH, an amount of the metal salt composition, and combinations thereof.2. The method according to claim 1 , further comprising the step of adding a gel time accelerating additive comprising sodium sulfite.3. The method ...

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19-05-2016 дата публикации

Copolymer of dcpd-containing benzoxazine (dcpdbz) and cyanate ester resin, and method of manufacturing the copolymer

Номер: US20160137786A1

A copolymer of DCPD-containing benzoxazine (DCPDBz) and cyanate ester resin forms a low-dielectric thermosetting polymeric material for making electronic components. A method of manufacturing the copolymer is also introduced. The method includes allowing DCPD-phenol oligomer, aniline, and paraformaldehyde to react at 110° C. for 6-12 hours before being extracted and baked to obtain DCPDBz; and mixing cyanate ester and the DCPDBz at 150° C.; heating the mixture up to 220° C.

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03-06-2021 дата публикации

TRIAZINE RING-CONTAINING POLYMER, AND THERMOPLASTIC ARTICLE AND OPTICAL PART INCLUDING SAME

Номер: US20210163682A1
Принадлежит:

Disclosed are a triazine ring-containing polymer having a repeating unit that comprises a structural unit derived from a triazinedithiol compound, the triazine ring-containing polymer having a yellowness index of less than 3 and comprising terminal SH groups, wherein at least a portion of the SH groups are capped with a hydrocarbon group, and a number of the SH groups in the triazine ring-containing polymer is less than about 1×10per gram of the polymer, and a thermoplastic article and optical part including the polymer. 1. A triazine ring-containing polymer having a repeating unit that comprises:a structural unit derived from a triazine dithiol compound,the triazine ring-containing polymer comprising terminal SH groups, wherein at least a portion of the SH groups are capped with a hydrocarbon group, and{'sup': '18', 'wherein a number of the SH groups in the triazine ring-containing polymer is less than about 1×10per gram of the polymer.'}2. The triazine ring-containing polymer of claim 1 , wherein the hydrocarbon group is represented by any one of Chemical Formulae (a-1) to (a-3):{'br': None, 'sub': m', 'm+1, '*—CH\u2003\u2003(a-1)'}{'br': None, 'sub': '1', '*—Ar\u2003\u2003(a-2)'}{'br': None, 'sub': n', '2n', '2, '*—CH—Ar\u2003\u2003(a-3)'}wherein in Chemical Formula (a-1), m indicates an integer ranging from 1 to 6;wherein in Chemical Formula (a-2), An indicates a substituted or unsubstituted aromatic hydrocarbon group;{'sub': '2', 'wherein in Chemical Formula (a-3), n indicates an integer ranging from 1 to 6, and Arindicates a substituted or unsubstituted aromatic hydrocarbon group; and'}* indicates a point linked to another structural unit or atom.5. The triazine ring-containing polymer of claim 4 , wherein when L of General Formula 2 is a linking group claim 4 , the linking group is a C1 to C6 alkylene group claim 4 , a divalent C6 to C30 aromatic hydrocarbon group claim 4 , or an aromatic hydrocarbon linking group in which two or more C6 to C30 aromatic ...

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21-05-2015 дата публикации

PROCESS FOR PRODUCING SUBSTITUTED METHYLAMINE COMPOUND AND TRIAZINE DERIVATIVE

Номер: US20150141653A1
Принадлежит:

The present invention provides a process that enables a substituted methylamine compound which is useful as an intermediate for the production of agricultural chemicals and medicines, to be produced easily, with good yield, and at low cost, and also provides a production intermediate thereof. The process comprises a step of reacting a hexamethylenetetraammonium salt compound represented by a formula (I) with a base to obtain an N-methylidene-substituted methylamine oligomer represented by a formula (II) or a mixture of two or more of the oligomers, and a step of hydrolyzing the N-methylidene-substituted methylamine oligomer represented by formula (II) or the mixture of two or more of the oligomers in the presence of an acid. 113-. (canceled)15. (canceled)17. The process for producing a substituted methylamine compound according to claim 16 , wherein said A is a 2-chloropyridin-5-yl group.18. The process for producing a substituted methylamine compound according to claim 16 , wherein hydrolyzing the N-methylidene-substituted methylamine oligomer represented by formula (II′) is conducted in at least one solvent selected from a group consisting of water claim 16 , alcohol-based solvents claim 16 , aliphatic hydrocarbon-based solvents claim 16 , alicyclic hydrocarbon-based solvents claim 16 , aromatic hydrocarbon-based solvents claim 16 , ketone-based solvents claim 16 , and ether-based solvents.19. The process for producing a substituted methylamine compound according to claim 16 , wherein hydrolyzing the N-methylidene-substituted methylamine oligomer represented by formula (II′) is conducted at an temperature of within a range from room temperature to 90° C. This application is a Continuation application of U.S. application Ser. No. 12/596,950, filed on Oct. 21, 2009, which is a national phase application of PCT/JP2007/058842, filed on Apr. 24, 2007, the contents of each are hereby incorporated by reference.The present invention relates to a process that enables a ...

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08-09-2022 дата публикации

Polymerized high-molecular-weight sterically hindered amine and preparation method thereof

Номер: US20220282044A1
Принадлежит: BEIJING TIANGANG AUXILIARY CO., LTD.

The present invention discloses a polymerized high-molecular-weight sterically hindered amine having a general formula I, the sterically hindered amine has the advantages of high molecular weight, difficult migration in polymer products, good thermal stability, etc., and can stabilize and/or be flame retardant to organic substances sensitive to light, heat or oxidation, and furthermore, can be made to have better compatibility with different types of polymer materials by changing substituents. 2. The polymerized high-molecular-weight sterically hindered amine according to claim 1 , characterized in that Gand Gare independently selected from C-Calkyl; the Ris selected from C-Calkyl; E is selected from —CO— or —CH—; the Qand Qare independently selected from —O— claim 1 , —CO—O— claim 1 , —CO—NR— or —NR—; the Rand Rare independently selected from hydrogen and C-Calkyl.4. The polymerized high-molecular-weight sterically hindered amine according to claim 3 , characterized in that the Rand Rare independently selected from hydrogen claim 3 , and C-Calkyl claim 3 , wherein the H atom in the alkyl can be substituted with —R claim 3 , —OR claim 3 , —COORor —COR; the Ris selected from C-Calkylene claim 3 , wherein the H atom in the alkylene can be substituted with —R claim 3 , —OR claim 3 , —COORor —COR; the total number of carbon atoms in the R claim 3 , Rand Ris 40 or less;{'sub': 7', '8', '1', '20', '1', '20', '21', '7', '8', '7', '8', '3', '12', '2', '12, 'the Rand Rare independently selected from hydrogen, unsubstituted C-Calkyl or C-Calkyl substituted with —R; or, R, Rand the N atom between Rand Rform unsubstituted C-Ccycloalkylene or C-Cheterocycloalkylene;'}{'sub': 3', '22', '22, 'the Qis selected from —O—, —CO—O—, —CO—NR— or —NR—; and'}{'sub': 4', '5', '1', '40', '21', '21', '21', '21', '6', '1', '40', '21', '21', '21', '21', '4', '5', '6, 'the Rand Rare independently selected from hydrogen, and C-Calkyl, wherein the H atom in the alkyl can be substituted with —R, —OR ...

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09-05-2019 дата публикации

POROUS/NANOPOROUS PHT

Номер: US20190135979A1
Принадлежит:

Methods of forming nanoporous materials are described herein that include forming a polymer network with a chemically removable portion. The chemically removable portion may be polycarbonate polymer that is removable on application of heat or exposure to a base, or a polyhexahydrotriazine (PHT) or polyhemiaminal (PHA) polymer that is removable on exposure to an acid. The method generally includes forming a reaction mixture comprising a formaldehyde, a solvent, a primary aromatic diamine, and a diamine having a primary amino group and a secondary amino group, the secondary amino group having a base-reactive substituent, and heating the reaction mixture to a temperature of between about 50 deg C. and about 150 deg C. to form a polymer. Removing any portion of the polymer results in formation of nanoscopic pores as polymer chains are decomposed, leaving pores in the polymer matrix. 2. The article of claim 1 , further comprising a plurality of carbon fibers disposed in the porous polymer.5. The article of claim 1 , wherein each divalent bridging group is selected from the group consisting of polycarbonates claim 1 , polyesters claim 1 , polyvinylethers claim 1 , polyacrylates claim 1 , polyacetals claim 1 , polyaminals claim 1 , polythioacetals claim 1 , polyphosphates claim 1 , and aliphatic polysulfones.6. The article of claim 1 , wherein the porous polymer also has a plurality of monovalent substituents.10. The article of claim 9 , further comprising a plurality of carbon fibers disposed in the porous polymer.13. The article of claim 9 , wherein each divalent bridging group is selected from the group consisting of polycarbonates claim 9 , polyesters claim 9 , polyvinylethers claim 9 , polyacrylates claim 9 , polyacetals claim 9 , polyaminals claim 9 , polythioacetals claim 9 , polyphosphates claim 9 , and aliphatic polysulfones.14. The article of claim 9 , wherein the porous polymer also has a plurality of monovalent substituents.17. An article comprising a porous ...

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10-06-2021 дата публикации

FR COMPOSITE COMPOSITION FOR LIGHT-BASED ADDITIVE MANUFACTURING

Номер: US20210171697A1
Принадлежит: The Boeing Company

A fire retardant (FR) composite composition, including a liquid polymer, wherein the liquid polymer includes a photopolymer including at least two of a first molecule, a second molecule, and a third molecule, a FR thermoset, and a photoinitiator. 1. A fire retardant (FR) composite composition , comprising:from about 15.0 weight % to about 99.9 weight % of a liquid polymer, based on a total weight of the FR composite composition, from about 10.0 weight % to about 90.0 weight % of a photopolymer comprising at least two of a first molecule, a second molecule, and a third molecule, based on a total weight of the liquid polymer,', 'from about 15.0 weight % to about 80.0 weight % of a FR thermoset, based on the total weight of the liquid polymer, and', 'from about 0.001 weight % to about 10 weight % of a photoinitiator, based on the total weight of the liquid polymer, and, 'wherein the liquid polymer compriseswherein the first molecule comprises one or more unsaturated carbon-carbon double bonds or triple bonds,wherein the second molecule comprises a terminal thiol group, andwherein the third molecule comprises one or more functional groups selected from the group consisting of an aliphatic ether, a cyclic ether, a vinyl ether, an epoxy, a cyclo aliphatic epoxy, an oxetane, an isocyanate, and a diisocyanate group.2. The FR composite composition of claim 1 , further comprising:from about 15.0 weight % to about 80.0 weight % of a solid filler,wherein the solid filler comprises at least one of an inert, a nonflammable, and a flame retarding material.3. The FR composite composition of claim 1 , wherein the photopolymer comprises from about 5.0 weight % to about 90 weight % of the first molecule claim 1 , based on a total weight of the photopolymer.4. The FR composite composition of claim 3 , wherein the first molecule comprises at least one of tris (2-hydroxyethyl) isocyanurate triacrylate claim 3 , 1 claim 3 ,3 claim 3 ,5-trivinyl-1 claim 3 ,3 claim 3 ,5- ...

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24-05-2018 дата публикации

TRIAZINE RING-CONTAINING POLYMER, AND COMPOSITION FOR FILM FORMATION USE CONTAINING SAME

Номер: US20180142064A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

A triazine ring-containing polymer which contains a repeating unit structure represented by, for example, formula [4] has a high refractive index and also has excellent solubility in various organic solvents including low-polarity solvents, hydrophobic solvents and low-boiling point solvents. A thin film having a high refractive index and excellent transparency can be formed using a composition for film formation use which contains the polymer. 2. The triazine ring-containing polymer of claim 1 , wherein Rto Rand Rto Rare each a hydrogen atom.5. The triazine ring-containing polymer of claim 3 , wherein Ris a perfluoroalkyl group having 1 to 10 carbons.7. A film-forming composition comprising{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the triazine ring-containing polymer of and an organic solvent.'}8. The film-forming composition of claim 7 , wherein the organic solvent is at least one selected from the group consisting of glycol ester solvents claim 7 , ketone solvents and ester solvents.9. The film-forming composition of or claim 7 , further comprisinga crosslinking agent.10. The film-forming composition of claim 9 , wherein the crosslinking agent is a polyfunctional (meth)acrylic compound.11. A thin film obtained from the film-forming composition of .12. An electronic device comprisinga substrate and{'claim-ref': {'@idref': 'CLM-00011', 'claim 11'}, 'the thin film of formed on the substrate.'}13. An optical member comprisinga substrate and{'claim-ref': {'@idref': 'CLM-00011', 'claim 11'}, 'the thin film of formed on the substrate.'} The present invention relates to a triazine ring-containing polymer and a film-forming composition containing same.In recent years, there is an increasing demand for highly-functional polymer materials upon development of electronic devices such as liquid-crystal displays, organic electroluminescence (EL) displays, touch panels, optical semiconductor (LED) devices, solid-state image sensors, organic thin-film solar cells, dye- ...

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25-05-2017 дата публикации

SYSTEMS CHEMISTRY APPROACH TO POLYHEXAHYDROTRIAZINE POLYMERIC STRUCTURES

Номер: US20170145161A1
Принадлежит:

In some embodiments, a product, such as a thermoset, has a polyhexahydrotriazine and a self-polymerized cross-linkable polymer. In some embodiments, a product is the reaction product of a diamine, an aldehyde, and a compound having an α,β-unsaturated electron withdrawing moiety. 234-. (cancelled)36. The composition of claim 1 , wherein the ether is arylether or alkylether.38. The composition of claim 1 , wherein the lactone is a phthalide.41. The composition of claim 40 , wherein n is a positive integer between about 2 and about 100.42. The composition of claim 41 , wherein n is a positive integer between about 10 and about 50. Embodiments herein generally relate to polyhexahydrotriazines (PHTs) with tailored macromolecular architectures.Polyhexahydrotriazines (PHTs) are an emerging class of high strength engineering thermosetting polymers (thermosets) that have a unique combination of properties. PHTs have high modulus, solvent resistance, and resistance to environmental stress cracking. The ability to tune both the thermal and mechanical properties of PHTs is critical to meet the increasingly stringent demands of structural materials. Addition of a second polymer to a PHT network is one method of tuning the thermal or mechanical properties of a PHT network, but such multicomponent PHT networks suffer from biphasic separation of the individual polymers and multistep syntheses are required in order to obtain each type of polymer for the PHT network.Therefore, there is a need in the art for PHT networks and multicomponent PHT networks with improved material properties, and improved syntheses of these networks.In some embodiments, a product has a polyhexahydrotriazine and a self-polymerized cross-linked polymer.In some embodiments, a product is the reaction product of a diamine, an aldehyde, and a compound having an α,β-unsaturated electron withdrawing moiety.Embodiments herein generally relate to polyhexahydrotriazines (PHTs) with tailored macromolecular ...

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17-06-2021 дата публикации

TRIAZINE-RING-CONTAINING POLYMER AND COMPOSITION INCLUDING SAME

Номер: US20210179779A1
Принадлежит: NISSAN CHEMICAL CORPORATION

A triazine-ring-containing polymer characterized by including a repeating unit structure represented by formula (1). 2. The triazine-ring-containing polymer according to claim 1 , wherein the Wand Weach independently represent CRR(Rand Reach independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms claim 1 , which may be substituted with a halogen atom) claim 1 , or O.7. A triazine-based polymer-containing composition comprising the triazine-ring-containing polymer according to and an organic solvent.8. The triazine-based polymer-containing composition according to claim 7 , further comprising a crosslinking agent.9. The triazine-based polymer-containing composition according to claim 8 , wherein the crosslinking agent is a polyfunctional (meth)acrylic compound.10. A film obtained from the triazine-based polymer-containing composition according to .11. A pattern prepared from the triazine-based polymer-containing composition according to .12. An electronic device comprising: a substrate; and the film according to claim 10 , formed on the substrate.13. An optical member comprising: a substrate; and the film according to claim 10 , formed on the substrate.14. An electronic device comprising: a substrate; and the pattern according to claim 11 , formed on the substrate. The present invention relates to a triazine-ring-containing polymer and a composition including the polymer.To date, it has already been found that hyperbranched polymers including a triazine ring as a repeating unit are capable of achieving high heat resistance, high transparency, high refractive index, high solubility, and low volume shrinkage ratio by the polymers alone, and suitable as materials for film formation in preparing electronic devices and optical members (Patent Document 1).Optical materials provided with thin films prepared from compositions including the polymers, however, may have the problem of thin film degradation due to light (sunlight or ultraviolet ...

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07-06-2018 дата публикации

Phthalonitrile compound

Номер: US20180155276A1
Принадлежит: LG Chem Ltd

The present application can provide a phthalonitrile compound and a use thereof. The present application can provide a phthalonitrile compound capable of forming a phthalonitrile resin by self-curing or of serving as a curing agent after being mixed with another phthalonitrile compound, and a use of the phthalonitrile compound. The phthalonitrile compound can form a phthalonitrile resin by rapid self-curing even at a low temperature and does not create any defects resulting from the use of a conventional curing agent. Also, the phthalonitrile compound can be applied as a curing agent after being mixed with another compound, in which case, even if the content of the compound applied as a curing agent increases, the total content of the phthalonitrile resin obtained does not decrease, and thus a resin exhibiting an excellent degree of cure can be provided.

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14-06-2018 дата публикации

SOLVENT-FREE LIGHT-CURABLE ADHESIVE COMPOSITION

Номер: US20180163097A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

A solvent-free light-curable adhesive composition includes: for example, a triazine ring-containing polymer including a repeating unit structure represented by formula [3] and having a weight-average molecular weight of 500-5000; and a reactive diluent such as N-vinylformamide, the composition not including a solvent. The solvent-free light-curable adhesive composition has good compatibility with acrylic materials and the like, which are adhesive components, even without including a solvent. 2. The solvent-free light-curable adhesive additive composition of claim 1 , wherein Rand Rin the formula (A) are each a hydrogen atom and Ris a polymerizable carbon-carbon double bond-containing group.3. The solvent-free light-curable adhesive additive composition of or claim 1 , wherein the reactive diluent includes one or more reactive diluent selected from the group consisting of N-vinylformamide claim 1 , 4-acryloylmorpholine claim 1 , N-dimethylacrylamide claim 1 , and N-diethylacrylamide.5. The solvent-free light-curable adhesive additive composition of claim 1 , which is for a solvent-free light-curable adhesive comprising an acrylic material as an adhesive ingredient.6. A solvent-free light-curable adhesive comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the solvent-free light-curable adhesive additive composition of ; and'}at least one selected from the group consisting of allyl monomers, (meth)acrylic monomers and (meth)acrylic oligomers.7. The solvent-free light-curable adhesive of claim 6 , wherein the (meth)acrylic monomers are one or more methyl (meth)acrylate claim 6 , ethyl (meth)acrylate claim 6 , butyl (meth)acrylate claim 6 , 2-(2-ethoxyethoxy)ethyl acrylate claim 6 , tetrahydrofurfuryl (meth)acrylate claim 6 , lauryl acrylate claim 6 , isooctyl acrylate claim 6 , isodecyl acrylate claim 6 , 2-phenoxyethyl acrylate claim 6 , 2-ethylhexyl (meth)acrylate claim 6 , isobornyl (meth)acrylate claim 6 , adamantly (meth)acrylate claim 6 , ...

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13-06-2019 дата публикации

POLYHEMIAMINAL AND POLYHEXAHYDROTRIAZINE MATERIALS FROM 1,4 CONJUGATE ADDITION REACTIONS

Номер: US20190177481A1
Принадлежит:

Polyhemiaminal (PHA) and polyhexahydrotriazine (PHT) materials are modified by 1,4 conjugate addition chemical reactions to produce a variety of molecular architectures comprising pendant groups and bridging segments. The materials are formed by a method that includes heating a mixture comprising solvent(s), paraformaldehyde, aromatic amine groups, aliphatic amine Michael donors, and Michael acceptors, such as acrylates. The reaction mixtures may be used to prepare polymer pre-impregnated materials and composites containing PHT matrix resin. 2. The polymeric material of claim 1 , wherein A claim 1 , B claim 1 , D claim 1 , and E on each of the first claim 1 , second claim 1 , and third phenyl groups are hydrogens (H).4. The polymeric material of claim 3 , wherein R3 in each instance is:{'sub': 2', '11', '3, '—(CH)CH.'}5. The polymeric material of claim 3 , wherein R3 in each instance is:{'sub': 2', '3', '2', '3, 'sup': +', '−, '—(CH)N(CH)(HCCl).'}6. The polymeric material of claim 1 , wherein R1 in each instance is hydrogen (H).8. The polymeric material of claim 7 , wherein R4 is a polymeric moeity.9. The polymeric material of claim 8 , wherein R4 comprises a poly(ether) segment.10. The polymeric material of claim 8 , wherein R4 comprises a poly(butadiene) segment.11. The polymeric material of claim 8 , wherein R4 comprises a poly(amino ester) segment.13. The polymeric material of claim 12 , wherein R2 in each instance is hydrogen (H).14. The polymeric material of claim 13 , wherein R3 in each instance comprises a poly(butadiene) segment.15. The polymeric material of claim 13 , wherein R3 in each instance comprises a poly(amino ester) segment.16. The polymeric material of claim 1 , wherein at least one instance of R3 is:{'sub': 2', '11', '3, '—(CH)CH.'}17. The polymeric material of claim 1 , wherein at least one instance of R3 is:{'sub': 2', '3', '2', '3, 'sup': +', '−, '—(CH)N(CH)(HCCl).'} This application is a divisional of co-pending U.S. patent application Ser. ...

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29-06-2017 дата публикации

Systems chemistry approach to polyhexahydrotriazine polymeric structures

Номер: US20170183451A1
Принадлежит: International Business Machines Corp

In some embodiments, a product, such as a thermoset, has a polyhexahydrotriazine and a self-polymerized cross-linkable polymer. In some embodiments, a product is the reaction product of a diamine, an aldehyde, and a compound having an α,β-unsaturated electron withdrawing moiety.

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07-07-2016 дата публикации

High-performance, filler-reinforced, recyclable composite materials

Номер: US20160194472A1
Принадлежит: International Business Machines Corp

Polyhexahydrotriazine (PHT) and polyhemiaminal (PHA) materials form highly cross-linked polymers which can be used as binder resins in composite materials. A filler element functionalized with a primary amine group can be covalently bonded to the PHA/PHT polymer resins. Example filler elements include, without limitation, carbon nanotubes, silica materials, carbon and glass fibers, and nanoparticles. Filler materials are incorporated into polymeric materials to improve the mechanical strength or other characteristics of the polymeric material for various applications. Typical composite materials use thermosetting materials that, once set, are intractable. PHT and PHA materials can be reverted to starting materials by exposure to acids. Thus, composite components formed using these materials are recyclable.

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23-07-2015 дата публикации

HIGH-MOLECULAR COMPOUND AND LIGHT-EMITTING ELEMENT USING SAME

Номер: US20150207077A1
Принадлежит:

A high-molecular compound including a group indicated by general formula (11) as a repeating unit. 10. The polymer compound according to claim 4 , wherein the content of the groups represented by said formula (3) is 50 mol % or less with respect to the total content of repeating units contained in the polymer compound and the groups represented by said formula (3) are not substantially adjacent.11. The polymer compound according to claim 4 , wherein the content of the group represented by said formula (2) is 50 mol % or more with respect to the total content of repeating units contained in the polymer compound and the groups represented by said formula (11) claim 4 , and the group represented by said formula (11) and the group represented by said formula (3) are not substantially adjacent.12. A composition comprising the polymer compound according to and at least one material selected from the group consisting of a hole transporting material claim 1 , an electron transporting material and a light emitting material.13. The composition according to claim 12 , wherein said light emitting material is a phosphorescent compound.14. A liquid composition comprising the polymer compound according to and a solvent.15. An organic film comprising the polymer compound according to .16. A light emitting device comprising an anode claim 1 , a cathode and an organic layer disposed between the anode and the cathode claim 1 , wherein the organic layer contains the polymer compound according to . The present invention relates to a polymer compound and a raw material monomer of the polymer compound, and a composition, an organic film and a light emitting device containing the polymer compound.As a light emitting material used in a light emitting layer of a light emitting device, a composition is known obtained by doping a host material with a phosphorescent compound showing light emission from the triplet excited state. Since light emission of the triplet excited state attains 4 times ...

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30-07-2015 дата публикации

TRIAZINE RING-CONTAINING POLYMER AND FILM-FORMING COMPOSITION CONTAINING SAME

Номер: US20150210808A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

A polymer containing a repeating unit structure having a triazine ring such as, for example, that which is represented by formula (25): can exhibit alone high heat resistance, high transparency, high refractive index, high solubility and low volume shrinkage; and can be used as a component in a film-forming composition as appropriate. 2. The triazine ring-containing polymer according to claim 1 , wherein the combination of Arand Aris two selected from the group consisting of formulas (5) to (11) claim 1 , (14) to (18) claim 1 , and (22).3. The triazine ring-containing polymer according to claim 1 , wherein the combination of Arand Aris two selected from the group consisting of formulas (7) claim 1 , (11) claim 1 , (14) claim 1 , (15) claim 1 , and (22).8. A film-forming composition comprising the triazine ring-containing polymer of .9. A film obtained from the film-forming composition of .10. A film comprising the triazine ring-containing polymer according to .11. An electronic device comprising a base material and the film of formed on the base material.12. An electronic device comprising a base material and the film of formed on the base material.13. An optical member comprising a base material and the film of formed on the base material.14. An optical member comprising a base material and the film of formed on the base material.15. A solid-state image sensor formed of a charge-coupled device or a complementary metal oxide semiconductor claim 9 , the sensor comprising at least one layer of the film of .16. A solid-state image sensor formed of a charge-coupled device or a complementary metal oxide semiconductor claim 10 , the sensor comprising at least one layer of the film of .17. A solid-state image sensor comprising claim 9 , as a planarization layer on a color filter claim 9 , the film of .18. A solid-state image sensor comprising claim 10 , as a planarization layer on a color filter claim 10 , the film of . This application is a 37 CFR 1.53(b) divisional of, ...

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25-06-2020 дата публикации

HYDROGELS FROM DYNAMIC COVALENT NETWORKS

Номер: US20200199298A1
Принадлежит:

In an embodiment is provided a polymer that includes a plurality of N-J-N or N—C—S repeating units, wherein each J is independently a carbon atom, an alkyl group, or an aryl group; a plurality of hydrophilic groups bonded with the repeating units; and a plurality of hydrophobic groups bonded with the hydrophilic groups and the repeating units. In another embodiment is provided hydrogels of such polymers. The hydrogels may be used as delivery vehicles for various payloads. In another embodiment is provided methods of forming such polymers. 2. The method of claim 1 , wherein at least one of the hydrophilic component or the hydrophobic component comprises a thioaminal.3. The method of claim 1 , wherein at least one of the hydrophilic component or the hydrophobic component comprises a polythioaminal.4. The method of claim 3 , wherein the hydrophilic component or the hydrophobic component comprises a polythioaminal having repeated S—C—N—C—S linkages.5. The method of claim 3 , wherein the hydrophilic component or the hydrophobic component comprises a polythioaminal having repeated S—C—N—R—N—C—S linkages.6. The method of claim 1 , wherein the hydrophobic component is a monothiol.7. The method of claim 6 , wherein the hydrophobic component is a theranostic agent.10. The method of claim 9 , wherein the hydrophilic component or the hydrophobic component comprises a polythioaminal claim 9 , the polythioaminal having repeated S—C—N—C—S linkages.11. The method of claim 9 , wherein the hydrophilic component or the hydrophobic component comprises a polythioaminal claim 9 , the polythioaminal having repeated S—C—N—R—N—C—S linkages.12. The method of claim 9 , wherein the hydrophobic component is a monothiol.13. The method of claim 12 , wherein the hydrophobic component is a theranostic agent.15. A hydrogel comprising:water; and a plurality of N-J-N or N—C—S repeating units, wherein each J is independently a carbon atom, an alkyl group, or an aryl group;', 'a plurality of hydrophilic ...

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03-08-2017 дата публикации

REVERSIBLE AMINAL GEL COMPOSITIONS, METHODS, AND USE

Номер: US20170218248A1
Принадлежит: Saudi Arabian Oil Company

A well treatment composition for use in a hydrocarbon-bearing reservoir comprising a reversible aminal gel composition is disclosed. The reversible aminal gel composition includes a liquid precursor composition. The liquid precursor composition is operable to remain in a liquid state at about room temperature. The liquid precursor composition comprises an organic amine composition; an aldehyde composition; a polar aprotic organic solvent; and a metal salt composition with valence 3, 4, or 5. The liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature in the hydrocarbon-bearing reservoir. The gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, and the gel state is operable to return to the liquid state responsive to a change in the hydrocarbon-bearing reservoir selected from the group consisting of: a decrease in pH in the hydrocarbon-bearing reservoir and an addition of excess metal salt composition in the hydrocarbon-bearing reservoir. 1. A well treatment composition for use in a hydrocarbon-bearing reservoir comprising a reversible aminal gel composition , the reversible aminal gel composition comprising: an organic amine composition;', 'an aldehyde composition;', 'a polar aprotic organic solvent; and', 'a metal salt composition with valence 3, 4, or 5,, 'a liquid precursor composition, the liquid precursor composition operable to remain in a liquid state at about room temperature, where the liquid precursor composition compriseswhere the liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature from the hydrocarbon-bearing reservoir,where the gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, andwhere the gel state is operable to return to the liquid state responsive to a ...

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02-08-2018 дата публикации

POLYMER CONTAINING TRIAZINE RING AND COMPOSITION CONTAINING SAME

Номер: US20180215870A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

It is possible to obtain a thin film that can form a minute pattern and that has a high index of refraction by using a polymer containing a triazine ring and containing a repeating unit structure represented for example by formula (22) or (26). 2. The triazine ring-containing polymer of claim 1 , wherein Aris an aryl group substituted with a carboxyl group.3. The triazine ring-containing polymer of claim 1 , wherein the moieties of formulas (2) to (13) all have therein at least one carboxyl group on at least one aromatic ring.4. The triazine ring-containing polymer of claim 3 , wherein Aris an aryl group substituted with an alkyl claim 3 , alkoxy claim 3 , aryl or aralkyl group.6. The triazine ring-containing polymer of claim 5 , wherein Arand Arare aryl groups having an alkyl group of 1 to 20 carbon atoms on at least one ortho position with respect to the NH group on Arand Ar.7. The triazine ring-containing polymer of claim 6 , wherein Arand Arare phenyl groups having an alkyl group of 1 to 5 carbon atoms at both ortho positions.13. The triazine ring-containing polymer of which has at least one diamine end claim 1 , wherein at least one such diamine end is capped with an acyl group claim 1 , an alkoxycarbonyl group claim 1 , an aralkyloxycarbonyl group or an aryloxycarbonyl group.14. A triazine polymer-containing composition comprising the triazine ring-containing polymer of and an organic solvent.15. The triazine polymer-containing composition of which further comprises a crosslinking agent.16. The triazine polymer-containing composition of claim 15 , wherein the crosslinking agent is a poly(meth)acrylic compound.17. The triazine polymer-containing composition of claim for use in forming a cured film or in patterning.18. A cured film obtained by curing the triazine polymer-containing composition of .19. A pattern produced from the triazine polymer-containing composition of .20. An electronic device comprising a substrate and the cured film of formed on the ...

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11-07-2019 дата публикации

POROUS/NANOPOROUS PHT

Номер: US20190211152A1
Принадлежит:

In an embodiment, a polymeric material includes a plurality of hemiaminal units bonded together by a first linkage and a second linkage, wherein the first linkage is thermally stable and resistant to bases and the second linkage is thermally degradable and degradable by a base. In another embodiment, a method of forming nanoporous materials includes forming a polymer network with a chemically removable portion. The chemically removable portion may be polycarbonate polymer that is removable on application of heat or exposure to a base, or a polyhexahydrotriazine (PHT) or polyhemiaminal (PHA) polymer that is removable on exposure to an acid. Removing any portion of the polymer results in formation of nanoscopic pores as polymer chains are decomposed, leaving pores in the polymer matrix. 1. A polymeric material comprising a plurality of hemiaminal units bonded together by a first linkage and a second linkage , wherein the first linkage is thermally stable and resistant to bases and the second linkage is thermally degradable and degradable by a base.2. The polymeric material of claim 1 , wherein the second linkage is a polycarbonate or polyester linkage.3. The polymeric material of claim 2 , wherein the first linkage is a dianiline linkage.5. The polymeric material of claim 4 , wherein R includes an aromatic diamine.6. The polymeric material of claim 5 , wherein the aromatic diamine is paraphenylenedianiline.12. The polymeric material of claim 11 , wherein the first linkage is a dianiline linkage.13. The polymeric material of claim 11 , wherein R includes an aromatic diamine.14. The polymeric material of claim 13 , wherein the aromatic diamine is paraphenylenedianiline.20. The polymeric material of claim 19 , wherein R includes an aromatic diamine. This is a divisional application of co-pending U.S. patent application Ser. No. 15/399,365 filed Jan. 5, 2017 which is a divisional application of co-pending U.S. patent application Ser. No. 14/516,117 filed Oct. 16, 2014, ...

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11-07-2019 дата публикации

PHOTOSENSITIVE ADHESIVE COMPOSITION

Номер: US20190211242A1
Принадлежит: NISSAN CHEMICAL CORPORATION

A novel photosensitive adhesive composition including the following components (A), (B), (C), and (D): Component (A): a polymer having a structural unit of the following formula (1) and a structure of the following formula (2) at a terminal, Component (B): a polymer having the structural unit of formula (1), and a carboxy group or hydroxy group at a terminal, Component (C): a radical photopolymerization initiator, and Component (D): a solvent, wherein the content by mass of the component (B) is larger than that of the component (A), 2. The photosensitive adhesive composition according to claim 1 , wherein the divalent hydrocarbon group of Q in formula (1) is a linear or branched alkylene group claim 1 , a group containing two carbon atoms bonded through a double bond claim 1 , or a group containing in a main chain an alicyclic hydrocarbon group or aromatic hydrocarbon group optionally having at least one substituent.3. The photosensitive adhesive composition according to claim 1 , wherein the divalent linking group of Z in formula (2) is a linear or branched alkylene group optionally having at least one hydroxy group as a substituent.4. The photosensitive adhesive composition according to claim 1 , wherein the mass ratio of the component (A) to the component (B) is 1:2 to 1:20.5. The photosensitive adhesive composition according to claim 1 , further comprising a bifunctional (meth)acrylate and/or a multifunctional thiol.6. An adhesion method comprising steps of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'applying the photosensitive adhesive composition according to to a first substrate;'}pre-baking the photosensitive adhesive composition applied to the first substrate at 50° C. to 160° C.;exposing the coating film on the first substrate after the pre-baking;developing the coating film after the exposure; andbonding a second substrate to the first substrate after the development and thermally curing the coating film by heating. The present invention relates to ...

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03-08-2017 дата публикации

CONDUCTIVE HYBRID MATERIAL INCLUDING COVALENT ORGANIC STRUCTURE

Номер: US20170222231A1
Принадлежит:

An electrically conductive hybrid material includes: a covalent organic framework having pores; and a conductor material, wherein the covalent organic framework is supported on the conductor material. The covalent organic framework that does not have electron conductivity is supported on the conductor material such as a carbon material, thereby can be given the electron conductivity, and becomes usable as such a catalyst material and such an electrode material, which involve the electron transfer, these materials including an electrode catalyst material of a fuel cell, and the like. 1. An electrically conductive hybrid material comprising:a covalent organic framework having meso-sized or micro-sized pores, the covalent organic framework being a polymer having a structure in which same or different plural aromatic cyclic groups form a cyclic repeating unit by a covalent bond; anda conductor material,wherein the covalent organic framework is supported on the conductor material.2. The electrically conductive hybrid material according to claim 1 , wherein the covalent organic framework is a polymer composed of repeating units having plural triazine rings in a molecule.3. The electrically conductive hybrid material according to claim 1 , wherein the covalent organic framework has a structure in which plural triazine rings are bonded to one another by the covalent bond through arylene claim 1 , hetero arylene or hetero atoms.4. The electrically conductive hybrid material according to claim 1 , wherein the covalent organic framework has a structure in which plural triazine rings are bonded to one another by the covalent bond through phenylene or pyridylene.5. The electrically conductive hybrid material according to claim 4 , wherein the covalent organic framework is a compound obtained by a condensation reaction of dicyanobenzene or dicyanopyridine.6. The electrically conductive hybrid material according to claim 1 , wherein the covalent organic framework is a compound ...

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10-08-2017 дата публикации

Photoresponsive hexahydrotriazine polymers

Номер: US20170226262A1
Принадлежит: International Business Machines Corp

This disclosure describes new compositions and methods related to photoresponsive poly(hexahydrotriazines) and related polymers.

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10-08-2017 дата публикации

PHOTORESPONSIVE HEXAHYDROTRIAZINE POLYMERS

Номер: US20170226290A1
Принадлежит:

This disclosure describes new compositions and methods related to photoresponsive poly(hexahydrotriazines) and related polymers. 2. The PHT of claim 1 , wherein at least one of A claim 1 , B claim 1 , C claim 1 , D claim 1 , and E absorbs ultraviolet radiation.3. The PHT of claim 2 , wherein at least one of A claim 2 , B claim 2 , C claim 2 , D claim 2 , and E comprises a reaction product of ultraviolet radiation absorption.4. The PHT of claim 3 , wherein the reaction product is a product of a photoreversible reaction.5. The PHT of claim 3 , wherein the reaction product comprises a cyclic carbon group.6. The PHT of claim 5 , wherein the reaction product comprises a cycloaliphatic carbon group.7. The PHT of claim 5 , wherein the cyclic carbon group is the reaction product of a [2π+2π] cycloaddition reaction.8. The PHT of claim 5 , wherein the cyclic carbon group is the reaction product of a [4π+4π] cycloaddition reaction.9. The PHT of claim 6 , wherein cycloaliphatic carbon group comprises a cyclobutane group.10. The PHT of claim 9 , wherein the cyclobutane group is a photoreaction product of at least two carbon-carbon double bonds.11. The PHT of claim 10 , wherein the carbon-carbon double bonds are resonance stabilized.12. The PHT of claim 3 , wherein at least one of A claim 3 , B claim 3 , C claim 3 , D claim 3 , and E comprises a carbon-carbon double bond.13. The PHT of claim 12 , wherein at least one carbon-carbon double bond is resonance stabilized.14. The PHT of claim 3 , wherein the reaction product includes at least one conjugated carbon-carbon double bond from a photo-cleavage reaction.15. The PHT of claim 14 , wherein the at least one conjugated carbon-carbon double bond is a reaction product of a cyclobutane photo-cleavage reaction.1620-. (canceled) The present disclosure relates to new compositions and methods related to polyhexahydrotriazines and related polymers. The compositions and methods described herein are useful for removable and recyclable ...

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18-07-2019 дата публикации

PHOTORESPONSIVE HEXAHYDROTRIAZINE POLYMERS

Номер: US20190218342A1
Принадлежит:

This disclosure describes new compositions and methods related to photoresponsive poly(hexahydrotriazines) and related polymers. In an embodiment, a method of patterning a substrate includes forming a liquid poly(hemiaminal) material by a process that includes forming a reaction mixture comprising a polar solvent, paraformaldehyde, and an aminobenzene compound having photoreactive groups, and heating the reaction mixture at a temperature up to 50° C. The method further includes applying the liquid poly(hemiaminal) material to a substrate; patterning the liquid poly(hemiaminal) material with UV light; and curing the liquid poly(hemiaminal) material to form a cured poly(hexahydrotriazine) polymer. 1. A method of patterning a substrate , comprising: forming a reaction mixture comprising a polar solvent, paraformaldehyde, and an aminobenzene compound comprising photoreactive groups; and', 'heating the reaction mixture at a temperature up to 50° C.;, 'forming a liquid poly(hemiaminal) material by a process, comprisingapplying the liquid poly(hemiaminal) material to a substrate;patterning the liquid poly(hemiaminal) material with UV light; andcuring the liquid poly(hemiaminal) material to form a cured poly(hexahydrotriazine) polymer.2. The method of claim 1 , wherein patterning the liquid poly(hemiaminal) material with UV light comprises exposing the liquid poly(hemiaminal) material to the UV light through a mask.3. The method of claim 2 , wherein curing the liquid poly(hemiaminal) material comprises heating the liquid poly(hemiaminal) material.4. The method of claim 3 , wherein the curing the liquid poly(hemiaminal) material to form a poly(hexahydrotriazine) polymer comprises heating the liquid poly(hemiaminal) material to a temperature of from about 50° C. to about 280° C. to form a cured poly(hexahydrotriazine) polymer.5. The method of claim 3 , wherein the curing the liquid poly(hemiaminal) material is performed following the patterning the liquid poly(hemiaminal) ...

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09-09-2021 дата публикации

Triazine-ring-containing polymer and composition in which same is used

Номер: US20210277184A1
Автор: Hirotoshi Ishii
Принадлежит: Idemitsu Kosan Co Ltd

A triazine ring-containing polymer, having a structural unit represented by the following formula (1), in which a peak top molecular weight obtained by gel permeation chromatography is 19,000 or less.

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08-09-2016 дата публикации

SYNTHETIC POLYMERS AND METHODS OF MAKING AND USING THE SAME

Номер: US20160257785A1
Принадлежит:

Disclosed herein are monomer embodiments that can be used to make polymers, such as homopolymers, heteropolymers, and that can be used in particular embodiments to make sequence-defined polymers. Also disclosed herein are methods of making polymers using such monomer embodiments. Methods of using the polymers disclosed herein also are described. 2. The polymer of claim 1 , wherein at least one of R claim 1 , R claim 1 , and Ris hydrogen bound to Y claim 1 , Y claim 1 , or Y claim 1 , respectively claim 1 , with Y claim 1 , Y claim 1 , or Ybeing a bond that binds R claim 1 , R claim 1 , and Rto a triazine ring of the polymer.3. The polymer of claim 1 , wherein at least one of R claim 1 , R claim 1 , and Ris hydrogen bound to Y claim 1 , Y claim 1 , or Y claim 1 , respectively claim 1 , with Y claim 1 , Y claim 1 , or Ybeing oxygen claim 1 , sulfur claim 1 , or —NH.4. The polymer of claim 1 , wherein at least one of R claim 1 , R claim 1 , and Ris methyl bound to Y claim 1 , Y claim 1 , or Y claim 1 , respectively claim 1 , with Y claim 1 , Y claim 1 , or Ybeing a bond that binds R claim 1 , R claim 1 , and Rto a triazine ring of the polymer.5. The polymer of claim 1 , wherein each of W claim 1 , W claim 1 , Z claim 1 , and Zindependently are selected from NH claim 1 , S claim 1 , or O.6. The polymer of claim 1 , wherein each of Land Lindependently are selected from a porphyrin claim 1 , a poly(ethylene)glycol claim 1 , a polyester claim 1 , a polyamide claim 1 , or a polyalkene.9. A polymer according to claim 1 , wherein the polymer is assembled in the form of a membrane claim 1 , an amorphous particle claim 1 , a crystal claim 1 , or a nanorod wherein a backbone of the polymer interacts to create a columnar structure and side chains of the polymer project outward from the column.10. A plurality of polymers according to claim 1 , wherein the polymers are assembled in the form of a nanorod wherein side chains of a polymer interacts with side chains of another polymer ...

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06-09-2018 дата публикации

HIGH-TEMPERATURE RESISTANT MODIFIED SILICON-CONTAINING CYANATE ESTER RESIN AS WELL AS PREPARATION METHOD AND APPLICATION THEREOF

Номер: US20180251604A1
Принадлежит:

The present invention relates to a high-temperature resistant modified silicon-containing cyanate ester resin as well as a preparation method and an application thereof. The preparation method comprises the following steps: adding a mixed solution of hydroxyl silicone oil, a silane coupling agent and an organic solvent into a mixed solution of a tetramethylammonium hydroxide aqueous solution and a polar solvent, performing hydrolytic polycondensation at a temperature of 5-40° C. for 4-8 h, and performing distillation to obtain an epoxy-containing silsesquioxane; performing pre-polymerization on the epoxy-containing silsesquioxane and a cyanate ester resin at a temperature of 50-100° C. for 1-8 h to obtain a modified cyanate ester resin; and uniformly mixing the modified cyanate ester resin and a modified anhydride, thereby obtaining the high-temperature resistant modified silicon-containing cyanate ester resin. 1. A preparation method of a high-temperature resistant modified silicon-containing cyanate ester resin , comprising the following steps:step (1), adding a mixed solution of hydroxyl silicone oil, a silane coupling agent and an organic solvent into a mixed solution of a tetramethylammonium hydroxide aqueous solution and a polar solvent, performing hydrolytic polycondensation at a temperature of 5-40° C. for 4-8 h, and then performing distillation to obtain an epoxy-containing silsesquioxane;step (2), performing pre-polymerization on the epoxy-containing silsesquioxane obtained in the step (1) and a cyanate ester resin at a temperature of 50-100° C. for 1-8 h to obtain a modified cyanate ester resin; andstep (3), uniformly mixing the modified cyanate ester resin obtained in the step (2) and a modified anhydride, thereby obtaining the high-temperature resistant modified silicon-containing cyanate ester resin.2. The preparation method of the high-temperature resistant modified silicon-containing cyanate ester resin according to claim 1 , wherein a mass fraction ...

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15-09-2016 дата публикации

Polyhemiaminal And Polyhexahydrotriazine Materials From 1,4 Conjugate Addition Reactions

Номер: US20160264734A1
Принадлежит:

Polyhemiaminal (PHA) and polyhexahydrotriazine (PHT) materials are modified by 1,4 conjugate addition chemical reactions to produce a variety of molecular architectures comprising pendant groups and bridging segments. The materials are formed by a method that includes heating a mixture comprising solvent(s), paraformaldehyde, aromatic amine groups, aliphatic amine Michael donors, and Michael acceptors, such as acrylates. The reaction mixtures may be used to prepare polymer pre-impregnated materials and composites containing PHT matrix resin. 2. The PHT of claim 1 , wherein at least one of A claim 1 , B claim 1 , C claim 1 , D claim 1 , and E is a Michael addition reaction product.3. The PHT of claim 2 , wherein at least one of A claim 2 , B claim 2 , C claim 2 , D claim 2 , and E is a chemical group containing a Michael addition donor reaction product.4. The PHT of claim 3 , wherein the Michael addition donor comprises a material selected from the group consisting of amines claim 3 , thiols claim 3 , sulphides claim 3 , phosphines claim 3 , phosphides carbanions claim 3 , and alkoxides.5. The PHT of claim 2 , wherein at least one of A claim 2 , B claim 2 , C claim 2 , D claim 2 , and E is a chemical group containing a Michael addition acceptor reaction product.6. The PHT of claim 5 , wherein the Michael addition acceptor is selected from the group consisting of alpha-beta unsaturated esters claim 5 , acrylates claim 5 , methacrylates claim 5 , alkyl methacrylates claim 5 , cyanoacrylates claim 5 , acrylonitrile claim 5 , acrylamides claim 5 , maleimides claim 5 , vinyl sulfones claim 5 , vinyl sulfoxides claim 5 , vinyl sulfones claim 5 , vinyl ketones claim 5 , nitro ethylenes claim 5 , vinyl phosphonates claim 5 , acrylonitrile claim 5 , vinyl pyridines claim 5 , azo compounds claim 5 , beta-keto acetylenes and acetylene esters.7. The PHT of claim 2 , wherein less than three Michael addition reaction products are covalently bound pendant groups.8. The PHT of claim ...

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01-10-2015 дата публикации

Triazine cationic polymers and methods of use thereof

Номер: US20150273073A1
Автор: Mingxing Wang, QI Lu
Принадлежит: Charlotte Mecklenburg Hospital

The present invention provides compounds of Formula I or Formula II: wherein: T, V, W, Y and Z are each independently selected from the group of substituents described herein, and X is a linker as further described herein. The present invention further provides compositions and conjugates including the compounds as well as methods of using these compounds including, but not limited to, methods of preventing, treating and/or diagnosing genetic disorders, such as muscular dystrophy, or non-genetic disorders as described herein.

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22-08-2019 дата публикации

HIGHLY SOLUBLE TRIS- (2, 3-EPOXYPROPYL)- ISOCYANURATE AND METHOD FOR PRODUCING SAME

Номер: US20190256657A1
Принадлежит: NISSAN CHEMICAL CORPORATION

There is provided an epoxy composition which has difficulty in precipitating a crystal during storage, is homogeneous and can be stored for a long period; and a cured product of the composition having excellent transparency, heat resistance, and light resistance can be obtained on curing. An α-type tris-(2,3-epoxypropyl)-isocyanurate crystal including β-type tris-(2,3-epoxypropyl)-isocyanurate in the crystal in a ratio of 2% by mass to 15% by mass. A method for producing the α-type tris-(2,3-epoxypropyl)-isocyanurate crystal including step (i) separating β-type tris-(2,3-epoxypropyl)-isocyanurate contained in a tris-(2,3-epoxypropyl)-isocyanurate solution from the solution as a solid to obtain a crystal with an increased content ratio of α-type tris-(2,3-epoxypropyl)-isocyanurate. 1. A curable composition comprising:an α-type tris-(2,3-epoxypropyl)-isocyanurate crystal comprising β-type tris-(2,3-epoxypropyl)-isocyanurate in the crystal in a ratio of 2% by mass to 15% by mass; andan amine, a phenol-based substance, an acid anhydride, a carboxylic acid, a mercaptan, an isocyanate, or a cationic curing agent,wherein a content ratio of residual component except for a solvent in the curable composition is 1% by mass to 99% by mass.2. A curable composition comprising:an α-type tris-(2,3-epoxypropyl)-isocyanurate crystal comprising β-type tris-(2,3-epoxypropyl)-isocyanurate in the crystal in a ratio of 2% by mass to 15% by mass; anda carboxylic acid anhydride in a ratio of 0.5 molar equivalent to 1.5 molar equivalent relative to 1 molar equivalent of the crystal, ora cationic curable compound in a ratio of 0.2 molar equivalent to 5 molar equivalent relative to 1 molar equivalent of the crystal,wherein a content ratio of residual component except for a solvent in the curable composition is 1% by mass to 99% by mass.3. A cured product formed by attaching the curable composition according to to a substrate and curing the curable composition by heating or light irradiation.4. ...

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20-09-2018 дата публикации

PERSONALIZED, ALLOGENEIC CELL THERAPY OF CANCER

Номер: US20180265456A1
Принадлежит: The John Hopkins University

Resins are provided including bisphenol M diphthalonitrile ether resin or bisphenol P diphthalonitrile either resin. Compositions are also provided, including a primary amine curative and the bisphenol M diphthalonitrile ether resin or the bisphenol P diphthalonitrile either resin. Further, polymerized products are provided of the bisphenol M diphthalonitrile ether resin or the bisphenol P diphthalonitrile either resin. In addition, a method of making a polymerized network is provided. A two component system is further provided, including a curative in one of the components and the bisphenol M diphthalonitrile ether resin or the bisphenol P diphthalonitrile either resin in the other component. In addition, a resin blend is provided, including a blend of at least two of bisphenol M diphthalonitrile ether resin, bisphenol P diphthalonitrile either resin, or bisphenol T diphthalonitrile ether resin. 2. A composition comprising a primary amine curative and a monomer of Formula I.3. The composition of claim 2 , wherein the primary amine curative comprises an aniline functional residue.4. The polymerized product of the monomer of Formula I.5. The polymerized product of the composition of or .7. A composition comprising a primary amine curative and a monomer of Formula II.8. The composition of claim 7 , wherein the primary amine curative comprises an aniline functional residue.9. The polymerized product of the monomer of Formula II.10. The polymerized product of the composition of or .11. A method of making a polymerized network claim 7 , the method comprising:obtaining a monomer of Formula I or Formula II;blending the monomer with a curative, a catalyst, or a combination thereof to form a monomer blend; andsubjecting the monomer blend to a temperature of no more than 300 degrees Celsius to form a fully polymerized network, wherein any optional postcuring of the polymerized network consists of subjecting the polymerized network to a temperature of no more than 300 degrees ...

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18-12-2014 дата публикации

TRIAZINE RING-CONTAINING POLYMER AND COMPOSITION FOR FILM FORMATION COMPRISING SAME

Номер: US20140371367A1
Принадлежит:

Provided is a triazine ring-containing hyperbranched polymer comprising the repeating unit structure represented by formula (1) and having one or more triazine ring terminals, said one or more triazine ring terminals being capped with a compound that differs from the diamine compound serving as the starting material for the polymer and has at least two active hydrogen groups. In addition to the polymer itself exhibiting high heat resistance, high transparency, a high refractive index, high light resistance, high solubility, and low volume shrinkage, it is also possible to use the polymer to provide a composition for film formation capable of yielding a thick film having high hardness. 2. The triazine ring-containing hyperbranched polymer according to claim 1 , wherein the compound having active hydrogen groups is at least one compound selected from among diamine compounds and amino alcohol compounds.3. The triazine ring-containing hyperbranched polymer according to claim 2 , wherein the compound having active hydrogen groups is an amino alcohol compound.5. The triazine ring-containing hyperbranched polymer according to claim 4 , wherein Ar has formula (12).8. A film-forming composition comprising the triazine ring-containing hyperbranched polymer of .9. The film-forming composition according to which includes a crosslinking agent.10. The film-forming composition according to claim 9 , wherein the crosslinking agent is at least one compound selected from among compounds containing a blocked isocyanate group and polyfunctional isocyanate compounds.11. The film-forming composition according to which includes a metal oxide.12. The film-forming composition according to claim 11 , wherein the metal oxide is ZrO.13. A film comprising the triazine ring-containing hyperbranched polymer according to .14. A film obtained from the film-forming composition of .15. An optical member comprising a base material and the film of or formed on the base material. The present invention ...

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06-10-2016 дата публикации

METHODS OF MANUFACTURING POLY(HEXAHYDROTRIAZINE)S VIA SUSPENSION OR EMULSION POLYMERIZATION

Номер: US20160289387A1
Принадлежит: BAKER HUGHES INCORPORATED

A method of manufacturing a hemiaminal dynamic covalent network (HDCN) comprises reacting a diamine and formaldehyde in the presence of a reaction medium comprising a polar solvent and a nonpolar solvent at a temperature of about 15° C. to about 100° C. to form the HDCN. A composition comprising the produced HDCN can be molded to form various articles comprising poly(hexahydrotriazine)s. 1. A method of manufacturing a hemiaminal dynamic covalent network , the method comprising:reacting a diamine and formaldehyde in the presence of a reaction medium comprising a first solvent and an immiscible second solvent at a temperature of about 15° C. to about 100° C. to form the hemiaminal dynamic covalent network.2. The method of claim 1 , wherein the first solvent is a polar solvent comprising one or more of the following: 1-methyl-2-pyrrolidone; N claim 1 ,N-dimethyl formamide; N claim 1 ,N-dimethyl acetamide; dimethyl sulfoxide;hexamethylphosphoramide; diphenyl sulfone; or tetramethylene sulfone.3. The method of claim 1 , wherein the immiscible second solvent is a nonpolar solvent comprising one or more of the following: benzene; toluene; xylenes; diethyl benzene; C5-C20 alkanes; or diethyl ether.4. The method of claim 3 , wherein the immiscible second solvent is a paraffinic hydrocarbon.5. The method of claim 1 , wherein the volume ratio of the first solvent relative to the immiscible second solvent is about 1:1 to about 1:5.6. The method of claim 1 , wherein the reaction medium further comprises water.7. The method of claim 1 , wherein the reaction medium further comprises one or more of a surfactant; or a stabilizer.8. The method of claim 7 , wherein the surfactant comprises sorbitan esters.9. The method of claim 7 , wherein the stabilizer comprises amphiphilic copolymers.10. The method of claim 1 , wherein the reaction is conducted in an emulsion or a suspension.11. The method of claim 1 , wherein the diamine is 4 claim 1 ,4′-oxydianiline claim 1 , 4 claim 1 ,4′- ...

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09-12-2021 дата публикации

ELECTROCHEMICAL OXYGEN REDUCTION CATALYST

Номер: US20210384524A1
Автор: Asahi Masafumi
Принадлежит:

An electrochemical oxygen reduction catalyst comprising platinum-containing nanoparticles and at least one member selected from the group consisting of a melamine compound, a thiocyanuric acid compound, and a polymer containing the melamine compound or the thiocyanuric acid compound as a monomer is an electrochemical oxygen reduction catalyst having a high oxygen reduction activity (small overvoltage). 1. An electrochemical oxygen reduction catalyst comprising platinum-containing nanoparticles and at least one member selected from the group consisting of a melamine compound , a thiocyanuric acid compound , and a polymer containing the melamine compound or the thiocyanuric acid compound as a monomer.2. The electrochemical oxygen reduction catalyst according to claim 1 , wherein the at least one member selected from the group consisting of a melamine compound claim 1 , a thiocyanuric acid compound claim 1 , and a polymer containing the melamine compound or the thiocyanuric acid compound as a monomer is supported on the platinum-containing nanoparticles.5. The electrochemical oxygen reduction catalyst according to claim 4 , wherein in formula (2) claim 4 , each of Rto Ris substituted or unsubstituted alkylene claim 4 , substituted or unsubstituted alkenylene claim 4 , or substituted or unsubstituted arylene.6. The electrochemical oxygen reduction catalyst according to claim 1 , which is supported on a conductive carrier.7. The electrochemical oxygen reduction catalyst according to claim 6 , wherein the conductive carrier is a carbonaceous material.8. The electrochemical oxygen reduction catalyst according to claim 1 , which is a cathode catalyst for fuel cells.9. An air electrode for fuel cells or metal-air batteries claim 1 , using the electrochemical oxygen reduction catalyst according to .10. A fuel cell using the air electrode according to as a cathode.11. A metal-air battery using the air electrode according to as a cathode. The present invention relates to an ...

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15-10-2015 дата публикации

Sealing resin, semiconductor device, and photocoupler

Номер: US20150295121A1
Принадлежит: Toshiba Corp

A semiconductor device includes: a sealing resin and a semiconductor element. The sealing resin includes a base resin and a curing agent. The base resin includes isocyanuric acid having an epoxy group. The curing agent includes an acid anhydride having an acid anhydride group. A mole ratio of the acid anhydride group to the epoxy group is not less than 0.67 and not more than 0.8. A semiconductor element is covered with the sealing resin.

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06-10-2016 дата публикации

Organic electroluminescent element

Номер: US20160293893A1
Принадлежит: Nissan Chemical Corp

This organic electroluminescent element, which is provided with a light scattering film obtained by curing a composition for light scattering film formation containing, for example, a triazine ring-containing polymer represented by formula (AA), a crosslinking agent and a light-diffusing agent, has excellent current efficiency.

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13-10-2016 дата публикации

Polyhexahydrotriazine dielectrics

Номер: US20160297931A1
Принадлежит: International Business Machines Corp

Low dielectric constant (low-k) polyhemiaminal (PHA) and polyhexahydrotriazine (PHT) materials with cyclic aliphatic ring structures are described. The materials are formed by a method that includes heating a mixture comprising amines and paraformaldehyde. The reaction mixtures may be used to form low-k PHT prepregs, composites and dielectrics used in integrated circuits.

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19-09-2019 дата публикации

Thermoset 3-oxo-isoindoline diphthalonitrile polymers, method of manufacture, and uses thereof

Номер: US20190284339A1
Принадлежит: SABIC Global Technologies BV

A thermoset polymer product comprising 4,4′-(((3-oxo-isoindoline-1,1-diyl)bis(4,1-arylene))bis(oxy))dibenzonitrile units of formula (2) wherein the units are derived from a 4,4′-(((3-oxo-isoindoline-1,1-diyl)bis(4,1-arylene))bis(oxy))diphthalonitrile monomer of formula (1) wherein R is a C 1-25 hydrocarbyl, preferably a C 1-6 alkyl, a phenyl, or a phenyl substituted with up to five C 1-6 alkyl groups, more preferably a C 1-3 alkyl or a phenyl; each occurrence of R 2 and R 3 is independently a hydrogen, a halogen, or a C 1-25 hydrocarbyl, preferably a hydrogen, a halogen, or a C 1-6 alkyl, more preferably a hydrogen or a C 1-3 alkyl; p and q are each independently 0 to 4, preferably 0 or 1, more preferably 0; and G is a residue of a cyano group, and is a C 1-25 hydrocarbyl linking group having a valence of at least 2.

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27-10-2016 дата публикации

Composition for film formation

Номер: US20160312062A1
Принадлежит: Nissan Chemical Corp

With a photocurable composition for film formation which comprises a polymer containing a repeating unit structure having a triazine ring, for example, one represented by the following formula (17), a crosslinking agent, an ultraviolet absorber, and a light stabilizer, it is possible to produce a cured film which has a high refractive index and satisfactory weatherability.

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03-11-2016 дата публикации

COMPOSITION FOR FORMING PROTECTIVE FILM FOR TRANSPARENT CONDUCTIVE FILM

Номер: US20160319132A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

Provided is a composition for forming a protective film for a transparent conductive film, said composition comprising a triazine ring-containing hyperbranched polymer comprising a repeating unit structure represented by formula (1) and a crosslinking agent having a molecular weight of 1,000 or greater. 2. The composition of claim 1 , wherein crosslinking agent A is a poly(meth)acrylic compound.3. The composition of or which includes from 0.1 to 30 parts by weight of crosslinking agent A per 100 parts by weight of the triazine ring-containing hyperbranched polymer.4. The composition of which further comprises a crosslinking agent B having a molecular weight of less than 1 claim 1 ,000.5. The composition of claim 4 , wherein crosslinking agent B is a poly(meth)acrylic compound.6. The composition of or which includes from 0.5 to 400 parts by weight of crosslinking agent B per 100 parts by weight of crosslinking agent A.7. The composition of which further comprises a solvent.8. A protective film for use on a transparent conductive film claim 1 , which protective film is obtained by curing the composition of .9. The protective film of claim 8 , wherein the transparent conductive film is a transparent conductive film having electrically conductive nanostructures.10. The protective film of claim 9 , wherein the electrically conductive nanostructures are made of silver nanowire.11. A transparent electrode comprising a transparent conductive film and the protective film of formed on the transparent conductive film.12. An electronic device comprising a transparent conductive film and the protective film of formed on the transparent conductive film.13. The electronic device of which is an organic electroluminescence display. This invention relates to a protective film-forming composition for use on a transparent conductive film.Transparent conductive film materials in use today are predominantly inorganic oxides such as indium tin oxide (ITO) and indium zinc oxide (IZO). ...

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01-10-2020 дата публикации

REVERSIBLE AMINAL GEL COMPOSITIONS, METHODS, AND USE

Номер: US20200308467A1
Принадлежит: Saudi Arabian Oil Company

A well treatment composition for use in a hydrocarbon-bearing reservoir comprising a reversible aminal gel composition is disclosed. The reversible aminal gel composition includes a liquid precursor composition. The liquid precursor composition is operable to remain in a liquid state at about room temperature. The liquid precursor composition comprises an organic amine composition; an aldehyde composition; and a polar aprotic organic solvent. The liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature in the hydrocarbon-bearing reservoir. The gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, and the gel state is operable to return to the liquid state responsive to a change in the hydrocarbon-bearing reservoir selected from the group consisting of: a decrease in pH in the hydrocarbon-bearing reservoir and an addition of excess metal salt composition in the hydrocarbon-bearing reservoir. 1. A method for introducing a reversible gel composition into a wellbore in a hydrocarbon-bearing reservoir , the method comprising the steps of: an organic amine composition;', 'an aldehyde composition; and', 'a polar aprotic organic solvent; and, 'a liquid precursor composition, the liquid precursor composition operable to remain in a liquid state at about room temperature, where the liquid precursor composition comprises, 'injecting the reversible gel composition into the hydrocarbon-bearing reservoir, the reversible gel composition comprisingallowing the liquid precursor composition to transition from the liquid state to a gel state responsive to an increase in temperature from the hydrocarbon-bearing reservoir.2. The method according to claim 1 , further comprising the step of diluting the liquid precursor composition with an aqueous composition comprising water to form a dilute liquid precursor composition claim 1 , the dilute ...

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16-11-2017 дата публикации

Organic Materials as Fire and Flame Retardant Synergists

Номер: US20170327665A1
Автор: KAUL Bansi Lal
Принадлежит:

Use of oligomeric or polymeric compounds according to the general formula I 2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. (canceled)7. (canceled)8. An electronic or electrical apparatus comprising a polymer composition according to .9. A cable comprising a polymer composition according to .10. An outdoor article or construction article comprising a polymer composition of .11. A polymer composition according to comprising ethyl vinyl acetate as the polymer.12. A polymer composition according to comprising a polyolefinic polymer or copolymer as the polymer.13. A polymer composition according to comprising polyamides or polyesters as the polymer.14. A polymer composition according to comprising 0.1 to 10% by weight of the compound of Formula I.15. A polymer composition according to comprising 0.5 to 7.5% by weight of the compound of Formula I.16. A polymer composition according to wherein the fire and flame retardants and compounds of Formula I and the at least one further flame retardant form a synergistic blend. Fire and flame retardants are widely used as plastic additives for the safer use-in-service of the resulting plastic materials. For many applications such as wire and cable and electric and electronic applications the use of fire and flame retardants as part of the non-conducting insulation materials is mandatory.There are many types of fire and flame retardants available. The most commonly used are the inorganic substances, the halogenated organic compounds, the organophosphorus compounds, or other organic substances.Halogen-containing fire retarding additives are no longer fulfilling the conditions which are now demanded by various industry and governmental regulations. For example the polymer resins for e.g. electric and electronic applications have to comply with the RoHS15 and WEEE16 directives: 152002/9516 2002/96The use of halogen-containing fire retardant additives or materials in plastics/polymers is also not allowed in the building and ...

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03-12-2015 дата публикации

SULFUR SCAVENGING MATERIALS FOR FILTERS AND COATINGS

Номер: US20150343352A1
Принадлежит:

Materials which react with (“scavenge”) sulfur compounds, such as hydrogen sulfide and mercaptans, are used to limit sulfur-induced corrosion. Filters and protective coatings including these materials, described broadly as polyhexahydrotriazines (PHT) and polyhemiaminals (PHA), are disclosed. Methods of using these materials to prevent corrosion are described. PHT and PHA materials have excellent thermal and mechanical properties for many applications as coatings and filtration media. Specifically, PHT and PHA materials react with sulfur compounds in such a manner as to incorporate sulfur atoms into the polymeric matrix, thus sequestering the sulfur atoms and allowing removal from fluids such as crude oil, natural gas, hydrocarbon combustion exhaust gases, sulfur polluted air and water. A coating PHT or PHA material on a component to be protected similarly reacts with sulfur compounds prior to sulfur being able to penetrate to the component. 2. The filter of claim 1 , wherein the filtration medium is a PHT material.3. The filter of claim 1 , wherein the filtration medium is a PHA material.4. The filter of claim 1 , wherein the filtration medium comprises a plurality of fibers.5. The filter of claim 4 , wherein the plurality of fibers comprise a fibrous mat.6. The filter of claim 4 , wherein the at least one of the PHT material and the PHA material is coated on to the plurality of fibers.7. The filter of claim 1 , wherein the plurality of fibers are the at least one of the PHT material and the PHA material.8. The filter of claim 1 , wherein filtration medium is in a fluidized bed.920.-. (canceled) The present disclosure relates to materials that react with sulfur and sulfur-containing compounds, and more specifically to filtration of and corrosion protection against sulfur and sulfur-containing compounds.Sulfur and sulfur containing compounds are often unwanted impurities in a variety of contexts. For example, sulfur is typically the most abundant element after ...

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23-11-2017 дата публикации

REVERSIBLE AMINAL GEL COMPOSITIONS, METHODS, AND USE

Номер: US20170335161A1
Принадлежит: Saudi Arabian Oil Company

A well treatment composition for use in a hydrocarbon-bearing reservoir comprising a reversible aminal gel composition. The reversible aminal gel composition includes a liquid precursor composition. The liquid precursor composition is operable to remain in a liquid state at about room temperature. The liquid precursor composition comprises an organic amine composition; an aldehyde composition; a polar aprotic organic solvent; and a metal salt composition with valence 3, 4, or 5. The liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature in the hydrocarbon-bearing reservoir. The gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, and the gel state is operable to return to the liquid state responsive to a change in the hydrocarbon-bearing reservoir selected from the group consisting of: a decrease in pH in the hydrocarbon-bearing reservoir and an addition of excess metal salt composition in the hydrocarbon-bearing reservoir. 1. A well treatment composition for use in a hydrocarbon-bearing reservoir comprising a reversible aminal gel composition , the reversible aminal gel composition comprising: an organic amine composition;', 'an aldehyde composition;', 'a polar aprotic organic solvent; and', 'a metal salt composition with valence 3, 4, or 5,, 'a liquid precursor composition, the liquid precursor composition operable to remain in a liquid state at about room temperature, where the liquid precursor composition compriseswhere the liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature from the hydrocarbon-bearing reservoir,where the gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, andwhere the gel state is operable to return to the liquid state responsive to a change in the ...

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10-12-2015 дата публикации

HIGHLY SOLUBLE TRIS- (2, 3-EPOXYPROPYL)- ISOCYANURATE AND METHOD FOR PRODUCING SAME

Номер: US20150353684A1
Принадлежит:

There is provided an epoxy composition which has difficulty in precipitating a crystal during storage, is homogeneous and can be stored for a long period; and a cured product of the composition having excellent transparency, heat resistance, and light resistance can be obtained on curing. An α-type tris-(2,3-epoxypropyl)-isocyanurate crystal including β-type tris-(2,3-epoxypropyl)-isocyanurate in the crystal in a ratio of 2% by mass to 15% by mass. A method for producing the α-type tris-(2,3-epoxypropyl)-isocyanurate crystal including step (i) separating β-type tris-(2,3-epoxypropyl)-isocyanurate contained in a tris-(2,3-epoxypropyl)-isocyanurate solution from the solution as a solid to obtain a crystal with an increased content ratio of α-type tris-(2,3-epoxypropyl)-isocyanurate. 1. An α-type tris-(2 ,3-epoxypropyl)-isocyanurate crystal comprising:β-type tris-(2,3-epoxypropyl)-isocyanurate in the crystal in a ratio of 2% by mass to 15% by mass.2. The α-type tris-(2 claim 1 ,3-epoxypropyl)-isocyanurate crystal according to claim 1 , wherein β-type tris-(2 claim 1 ,3-epoxypropyl)-isocyanurate is contained in the crystal in a ratio of 2% by mass to 10% by mass.3. The α-type tris-(2 claim 1 ,3-epoxypropyl)-isocyanurate crystal according to claim 1 , wherein the crystal has a particle diameter of 1 μm to 500 μm.4. A method for producing the α-type tris-(2 claim 1 ,3-epoxypropyl)-isocyanurate crystal according to claim 1 , the method comprising:(i) separating β-type tris-(2,3-epoxypropyl)-isocyanurate contained in a tris-(2,3-epoxypropyl)-isocyanurate solution from the solution as a solid to obtain a crystal with an increased content ratio of α-type tris-(2,3-epoxypropyl)-isocyanurate.5. A method for producing the α-type tris-(2 claim 1 ,3-epoxypropyl)-isocyanurate crystal according to claim 1 , the method comprising:(i) separating β-type tris-(2,3-epoxypropyl)-isocyanurate contained in a tris-(2,3-epoxypropyl)-isocyanurate solution from the solution as a solid to obtain ...

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17-12-2015 дата публикации

Sulfur scavenging materials for filters and coatings

Номер: US20150360173A1
Принадлежит: International Business Machines Corp

Materials which react with (“scavenge”) sulfur compounds, such as hydrogen sulfide and mercaptans, are used to limit sulfur-induced corrosion. Filters and protective coatings including these materials, described broadly as polyhexahydrotriazines (PHT) and polyhemiaminals (PHA), are disclosed. Methods of using these materials to prevent corrosion are described. PHT and PHA materials have excellent thermal and mechanical properties for many applications as coatings and filtration media. Specifically, PHT and PHA materials react with sulfur compounds in such a manner as to incorporate sulfur atoms into the polymeric matrix, thus sequestering the sulfur atoms and allowing removal from fluids such as crude oil, natural gas, hydrocarbon combustion exhaust gases, sulfur polluted air and water. A coating PHT or PHA material on a component to be protected similarly reacts with sulfur compounds prior to sulfur being able to penetrate to the component.

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24-12-2015 дата публикации

METHODS AND MATERIALS FOR THERAPEUTIC DELIVERY

Номер: US20150366972A1
Принадлежит:

Methods for preparing a supramolecular therapeutic agent delivery assembly are provided. A hydrophilic precursor, a hydrophibic precursor, and an aromatic diamine precursor may be combined to form an amphiphilic block co-polymer. The block co-polymer may undergo a cross-linking polymerization process and a therapeutic agent may be incorporated into the resulting supramolecular assembly. The supramolecular assembly may comprise HT, PHT, HA, and/or PHA materials. 1. A method of preparing a supramolecular therapeutic agent delivery assembly comprising:providing a first precursor, a second precursor, and a third precursor;performing a ring opening polymerization to form a block co-polymer;cross-linking the block co-polymer by performing a PHT or PHA polymerization process to form a supramolecular assembly; andincorporating a therapeutic agent into the supramolecular assembly.2. The method of claim 1 , wherein at least a portion of the supramolecular assembly is a reaction product of a formaldehyde and a primary diamine.3. The method of claim 2 , wherein reaction product is a PHT or PHA material.4. The method of claim 3 , wherein the PHT material comprises an aromatic or aliphatic bridging group.5. The method of claim 1 , wherein the first precursor is a cyclic carbonate-containing material.6. The method of claim 5 , wherein the therapeutic agent is covalently linked to a hydrophobic component of the supramolecular assembly.7. The method of claim 1 , wherein the second precursor is a functionalized aliphatic material.8. The method of claim 7 , wherein the functionalized aliphatic material is a PEG diamine.9. The method of claim 1 , wherein the third precursor is an aromatic diamine.10. The method of claim 1 , wherein the cross-linking of the block co-polymer is formed by a process comprising:{'sub': 2', '2, 'forming a mixture comprising one or more monomers comprising two aromatic primary amine groups having the general structure HN—Ar-L′-Ar—N—H, wherein Ar denotes a ...

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15-12-2016 дата публикации

FLAME RETARDANT PHT COMPOSITIONS

Номер: US20160362520A1
Принадлежит:

Hexahydrotriazine (HT) materials and hemiaminal (HA) materials derived from aromatic, aliphatic, and/or polyether diamines may be used as a platform for creating flame retardant materials. Various flame retardant material precursors may be incorporated into the HA and HT materials. Examples of flame retardant precursors may include organohalogen materials, organophosphorous materials, melamines, and dianiline compounds, among others. The flame retardant materials and precursors may be single molecule species, oligomers, and/or polymers (i.e., polyhexahydrotriazine, PHT, polyhemiaminal, PHA). The flame retardant materials may be made using an aromatic diamine, an aliphatic diamine, a polyether diamine, or a mixture thereof to react with an aldehyde (i.e. formaldehyde or paraformaldehyde). Such flame retardant material precursors will complex with the diamine monomers via a copolymerization reaction to form the flame retardant materials. 2. The method of claim 1 , wherein the diamine monomer is selected from the group consisting of 4 claim 1 ,4′-oxydianiline (ODA) claim 1 , 4 claim 1 ,4′-methylenedianiline (MDA) claim 1 , 4 claim 1 ,4′-(9-fluorenylidene)dianiline (FDA) claim 1 , p-phenylenediamine (PD) claim 1 , 1 claim 1 ,5-diaminonaphthalene (15DAN) claim 1 , 1 claim 1 ,4-diaminonaphthalene (14DAN) claim 1 , and benzidene.3. The method of claim 2 , wherein the diamine monomer is ODA.4. The method of claim 1 , wherein the phthalic anhydride monomer comprises biphthalic dianhydride.5. The method of claim 1 , wherein the brominated phthalic anhydride monomer comprises tetrabromophthalic anhydride.6. The method of claim 1 , wherein the brominated phthalic anhydride monomer comprises bis(tribromophthalic) anhydride.7. The method of claim 1 , further comprising:mixing the flame retardant material with a powder, a fiber aggregate, or a nanotube aggregate to form a composite material.8. The method of claim 7 , wherein the nanotube aggregate is a carbon nanotube material.9. ...

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21-12-2017 дата публикации

TRIAZINE-RING-CONTAINING POLYMER AND COMPOSITION CONTAINING SAME

Номер: US20170362382A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

For example, a thin film which has a high refractive index and which it is possible to form a fine pattern can be obtained by using a composition that contains a triazine-ring-containing polymer that includes a repeating unit structure represented by formula [5]. 6. The triazine ring-containing polymer of claim 1 , wherein the polymer has at least one triazine ring end claim 1 , and at least a portion of the triazine ring ends are capped with an arylamino group that may be substituted with an alkyl claim 1 , alkoxy claim 1 , aryl or aralkyl group.7. The triazine ring-containing polymer of claim 6 , wherein the arylamino group has the alkyl claim 6 , alkoxy claim 6 , aryl or aralkyl group at at least one ortho position to the amino group thereon.8. The triazine ring-containing polymer of claim 7 , wherein the arylamino group has the alkyl claim 7 , alkoxy claim 7 , aryl or aralkyl group at both ortho positions to the amino group thereon.10. A triazine polymer-containing composition comprising the triazine ring-containing polymer of and an organic solvent.11. The triazine polymer-containing composition of which further comprises a crosslinking agent.12. The triazine polymer-containing composition of claim 11 , wherein the crosslinking agent is a poly(meth)acrylic compound.13. The triazine polymer-containing composition of for use in forming a cured film or in patterning.14. A cured film obtained by curing the triazine polymer-containing composition of .15. A pattern produced from the triazine polymer-containing composition of .16. An electronic device comprising a substrate and the cured film of formed on the substrate.17. An optical member comprising a substrate and the cured film of formed on the substrate.18. An electronic device comprising a substrate and the pattern of formed on the substrate. The present invention relates to a triazine ring-containing polymer and a composition that includes the same.In recent years, a need has arisen for high-performance ...

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21-12-2017 дата публикации

POROUS/NANOPOROUS PHT

Номер: US20170362383A1
Принадлежит:

Methods of forming nanoporous materials are described herein that include forming a polymer network with a chemically removable portion. The chemically removable portion may be polycarbonate polymer that is removable on application of heat or exposure to a base, or a polyhexahydrotriazine (PHT) or polyhemiaminal (PHA) polymer that is removable on exposure to an acid. The method generally includes forming a reaction mixture comprising a formaldehyde, a solvent, a primary aromatic diamine, and a diamine having a primary amino group and a secondary amino group, the secondary amino group having a base-reactive substituent, and heating the reaction mixture to a temperature of between about 50 deg C. and about 150 deg C. to form a polymer. Removing any portion of the polymer results in formation of nanoscopic pores as polymer chains are decomposed, leaving pores in the polymer matrix. 1. A polymeric material comprising a plurality of hexahydrotriazine units , hemiaminal units , or both bonded together by a first linkage and a second linkage , wherein the first linkage is thermally stable and resistant to bases and the second linkage is thermally degradable and degradable by a base.2. The polymeric material of claim 1 , wherein the second linkage is a polycarbonate or polyester linkage.3. The polymeric material of claim 2 , wherein the first linkage is a dianiline linkage.6. The polymeric material of claim 1 , wherein the polymeric material has a bulk density between 1.0 and 1.5 g/cm.7. The polymeric material of claim 1 , wherein the polymeric material has pores 20-100 nm in dimension.8. A polymeric material comprising a plurality of hexahydrotriazine units claim 1 , hemiaminal units claim 1 , or both bonded together by a first linkage and a second linkage claim 1 , wherein the first linkage is a dianiline linkage that is thermally stable and resistant to bases and the second linkage is a polymer linkage that is thermally degradable and degradable by a base.14. The ...

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31-12-2015 дата публикации

POLYMER AND ORGANIC LIGHT-EMITTING DEVICE

Номер: US20150376495A1
Принадлежит:

A co-polymer comprising a repeat unit of formula (I): 2. A polymer according to wherein Aris phenylene.3. A polymer according to wherein Aris 1 claim 2 ,3-linked phenylene.4. A polymer according to wherein Ais phenyl.5. A polymer according to wherein Aris phenyl.7. A composition comprising a polymer according to and a light-emitting material.8. A composition according to wherein the light-emitting material is mixed with the polymer.9. A composition according to wherein the light-emitting material is covalently bound to the polymer.10. A composition according to wherein the light-emitting material is a phosphorescent material.11. A composition according to wherein the phosphorescent material has a photoluminescent spectrum with a peak in the range of 420-490 nm.12. A formulation comprising a polymer according to or a composition according to and at least one solvent.13. An organic light-emitting device comprising an anode claim 7 , a cathode and a light-emitting layer between the anode and cathode wherein the light-emitting layer comprises a composition according to .15. A method according to claim 14 , wherein each LG is independently selected from the group consisting of halogens; boronic acids; boronic esters; sulfonic acids; and sulfonic esters.16. A method according to wherein the halogens are selected from bromine or iodine.17. A method according to wherein the polymerisation is carried out in the presence of a metal catalyst. This application claims foreign priority benefits under 35 U.S.C. §119(a)-(d) or 35 U.S.C. §365(b) of British application number 1411485.4, filed Jun. 27, 2014, the entirety of which is herein incorporated by reference.Electronic devices containing active organic materials are attracting increasing attention for use in devices such as organic light emitting diodes (OLEDs), organic photoresponsive devices (in particular organic photovoltaic devices and organic photosensors), organic transistors and memory array devices. Devices containing ...

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21-11-2019 дата публикации

REVERSIBLE AMINAL GEL COMPOSITIONS, METHODS, AND USE

Номер: US20190352554A1
Принадлежит: Saudi Arabian Oil Company

A well treatment composition for use in a hydrocarbon-bearing reservoir comprising a reversible aminal gel composition is disclosed. The reversible aminal gel composition includes a liquid precursor composition. The liquid precursor composition is operable to remain in a liquid state at about room temperature. The liquid precursor composition comprises an organic amine composition; an aldehyde composition; a polar aprotic organic solvent; and a metal salt composition with valence 3, 4, or 5. The liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature in the hydrocarbon-bearing reservoir. The gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, and the gel state is operable to return to the liquid state responsive to a change in the hydrocarbon-bearing reservoir selected from the group consisting of: a decrease in pH in the hydrocarbon-bearing reservoir and an addition of excess metal salt composition in the hydrocarbon-bearing reservoir. 1. A method for introducing a reversible gel composition into a wellbore in a hydrocarbon-bearing reservoir , the method comprising the steps of: an organic amine composition;', 'an aldehyde composition; and', 'a polar aprotic organic solvent;, 'a liquid precursor composition, the liquid precursor composition operable to remain in a liquid state at about room temperature, where the liquid precursor composition comprises, 'injecting the reversible gel composition into the hydrocarbon-bearing reservoir, the reversible gel composition comprisingallowing the liquid precursor composition to transition from the liquid state to a gel state responsive to an increase in temperature from the hydrocarbon-bearing reservoir; andreturning the gel state to the liquid state by changing pH in the hydrocarbon-bearing reservoir.2. The method according to claim 1 , further comprising the step of adding a gel ...

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28-12-2017 дата публикации

POLYMERS OF INTRINSIC MICROPOROSITY

Номер: US20170369652A1
Принадлежит:

A polymer of intrinsic microporosity having a repeating subunit including both a spirobisindane imide moiety and an amido (lactam) moiety. 2. The polymer of wherein: n claim 1 , n′ and n″ are 1.3. The polymer of wherein Z claim 1 , Z′ claim 1 , Y and Y′ are hydrogen or hydroxyl.4. The polymer of wherein R claim 1 , R claim 1 , R claim 1 , and Rare independently selected from: methyl claim 1 , Rand Rcollectively form a ketone claim 1 , and Rand Rcollectively form a ketone group.5. The polymer of wherein L is a covalent bond.6. The polymer of wherein Rand Rare independently selected from a covalent bond and a methylene group.7. The polymer of wherein at least one X and X′ is a nitrile group.8. The polymer of wherein at least one of X and X′ is selected from a carboxylic acid and its corresponding salt or ester claim 1 , iminocarbamate or iminocarbonate.9. The polymer of wherein the polymer is crosslinked through at least one of X and X′.10. The polymer of wherein the polymer includes crosslinks comprising a triazine moiety.11. A membrane comprising the polymer of . The invention relates to polymers that possess intrinsic microporosity and which have particular utility as membranes.Polymers with intrinsic microporosity (PIMS) are characterized by having macromolecular structures that are both rigid and contorted so as to have extremely large fractional free volumes. Examples include poly(1-trimethylsilyl-1-propyne) (PTMSP), poly(4-methyl-2-pentyne) (PMP) and polybenzodioxane (PIM-1). Because of their exceptional free volume, all are extremely permeable. For illustrative purposes, the free volume and B.E.T. (Brunauer-Emmett-Teller method) surface area of PTMSP and PIM-1 are compared with a conventional glassy polymer, polysulfone. See: Baker, Membrane Technology and Applications, 3ed., (2012), and Polymers of Intrinsic Microporosity, Enc. Polymer Sci. & Tech., (2009)—both by John Wiley & Sons Ltd.See also: Pinnau, I. et al., Hydrocarbon/hydrogen mixed gas permeation in ...

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28-11-2019 дата публикации

REVERSIBLE AMINAL GEL COMPOSITIONS, METHODS, AND USE

Номер: US20190359877A1
Принадлежит: Saudi Arabian Oil Company

A well treatment composition for use in a hydrocarbon-bearing reservoir comprising a reversible aminal gel composition is disclosed. The reversible aminal gel composition includes a liquid precursor composition. The liquid precursor composition is operable to remain in a liquid state at about room temperature. The liquid precursor composition comprises an organic amine composition; an aldehyde composition; a polar aprotic organic solvent; and a metal salt composition with valence 3, 4, or 5. The liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature in the hydrocarbon-bearing reservoir. The gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, and the gel state is operable to return to the liquid state responsive to a change in the hydrocarbon-bearing reservoir selected from the group consisting of: a decrease in pH in the hydrocarbon-bearing reservoir and an addition of excess metal salt composition in the hydrocarbon-bearing reservoir. 1. A method for introducing an aminal gel composition into a wellbore in a hydrocarbon-bearing reservoir , the method comprising the steps of: an organic amine composition;', 'an aldehyde composition;', 'a polar aprotic organic solvent; and', 'a metal salt composition with valence 2; and, 'a liquid precursor composition, the liquid precursor composition operable to remain in a liquid state at about room temperature, where the liquid precursor composition comprises, 'injecting an aminal gel composition into the hydrocarbon-bearing reservoir, the aminal gel composition comprisingallowing the liquid precursor composition to transition from the liquid state to a gel state responsive to an increase in temperature from the hydrocarbon-bearing reservoir.2. The method according to claim 1 , further comprising the step of adding a gel time accelerating additive comprising sodium sulfite.3. The ...

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19-11-2020 дата публикации

TRIAZINE RING-CONTAINING POLYMER, AND THERMOPLASTIC ARTICLE AND OPTICAL PART INCLUDING SAME

Номер: US20200362112A1
Принадлежит:

A triazine ring-containing polymer including a structural unit represented by General Formula 1: 4. The triazine ring-containing polymer of claim 1 , wherein m1 and n1 of General Formula 3 are both 0.5. The triazine ring-containing polymer of claim 1 , wherein at least one of m1 and n1 of General Formula 3 is 1 claim 1 , and Rto Rare each independently a hydrogen atom claim 1 , a C1 to C30 alkyl group claim 1 , or a C6 to C30 aromatic hydrocarbon group.6. The triazine ring-containing polymer of claim 1 , wherein m1 and n1 of General Formula 3 are both 1 claim 1 , and Rto Rare each independently a hydrogen atom claim 1 , a C1 to C10 alkyl group claim 1 , or a C6 to C20 aromatic hydrocarbon group.7. The triazine ring-containing polymer of claim 1 , wherein when L of General Formula 2 is a linking group claim 1 , the linking group is a C1 to C6 alkylene group claim 1 , a divalent C6 to C30 aromatic hydrocarbon group claim 1 , or a an aromatic hydrocarbon linking group in which two or more C6 to C30 aromatic hydrocarbon groups are linked to each other by a single bond claim 1 , a C1 to C6 alkylene group claim 1 , or an atom of oxygen claim 1 , sulfur claim 1 , or selenium.8. The triazine ring-containing polymer of claim 1 , wherein L of General Formula 2 is a single bond claim 1 , a methylene group claim 1 , an ethylene group claim 1 , a phenylene group claim 1 , a biphenylene group claim 1 , or a naphthalene group.9. The triazine ring-containing polymer of claim 1 , wherein L of General Formula 2 is a single bond.11. The triazine ring-containing polymer of claim 1 , comprising a structural unit represented by General Formula (1-1) and a structural unit represented by General Formula (1-2):{'br': None, 'i': A', 'B, '*-[′--]-*\u2003\u2003(1-1)'}{'br': None, 'i': A', 'B, '*-[″--]-*\u2003\u2003(1-2)'}wherein, in General Formula (1-1) and General Formula (1-2),A and A′ are each independently represented by General Formula 2, wherein A and A′ are different from each other,B ...

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05-12-2019 дата публикации

TRIAZINE-RING-CONTAINING POLYMER AND COMPOSITION IN WHICH SAME IS USED

Номер: US20190367674A1
Автор: ISHII Hirotoshi
Принадлежит: IDEMITSU KOSAN CO., LTD.

A triazine ring-containing polymer, having a structural unit represented by the following formula (1), in which a peak top molecular weight obtained by gel permeation chromatography is 19,000 or less. 2: The triazine ring-containing polymer of claim 1 , wherein an end group comprises an amino group claim 1 , —NHRor —N(R) claim 1 ,{'sup': 1', 'a', '1, 'sub': 3', '3', '3', '2', '2, 'wherein Rindependently represents —Si(R″), —Si(OR″), a group which is a combination of —Si(OR″)and a divalent group, R—(C═O)—, an aliphatic hydrocarbon group, an aromatic hydrocarbon group, an aliphatic hydrocarbon group comprising a group which is a combination of an aromatic hydrocarbon group and one or more selected from the group consisting of a single bond, —S—, —S(═O)—, —O—, —NH—, —NR″—, —(C═O)—NH—, —O—(C═O)—O—, —(C═O)—O—, —(C═O)—, a silylene group and a siloxylene group, or an aromatic hydrocarbon group comprising a group which is a combination of an aliphatic hydrocarbon group and one or more selected from the group consisting of a single bond, —S—, —S(═O)—, —O—, —NH—, —NR″—, —(C═O)—NH—, —O—(C═O)—O—, —(C═O)—O—, —(C═O)—, a silylene group and a siloxylene group; and Rmay be further substituted with a substituent;'}{'sup': 'a', 'Rrepresents an aliphatic hydrocarbon group, an aromatic hydrocarbon group, or an aliphatic hydrocarbon group comprising an aromatic hydrocarbon group; and'}R″ represents an aliphatic hydrocarbon group, an aromatic hydrocarbon group, or a group which is a combination of one or more aliphatic hydrocarbon groups and one or more aromatic hydrocarbon groups.3: The triazine ring-containing polymer of claim 1 , wherein an extinction coefficient at a wavelength of 400 nm is 0.01 or less.5: The triazine ring-containing polymer of claim 1 , wherein R is a phenyl group claim 1 , a p-cyanophenyl group or a p-nitrophenyl group.6: A composition claim 1 , comprising the triazine ring-containing polymer of claim 1 , and an organic solvent.7: The composition of claim 6 , ...

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05-12-2019 дата публикации

Organic Materials as Fire and Flame Retardant Synergists

Номер: US20190367701A1
Автор: KAUL Bansi Lal
Принадлежит:

Use of oligomeric or polymeric compounds according to the general formula I 2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. (canceled)7. (canceled)8. An electronic or electrical apparatus comprising a polymer composition according to .9. A cable comprising a polymer composition according to .10. An outdoor article or construction article comprising a polymer composition of .11. A polymer composition according to comprising ethyl vinyl acetate as the polymer.12. A polymer composition according to comprising a polyolefinic polymer or copolymer as the polymer.13. A polymer composition according to comprising polyamides or polyesters as the polymer.14. A polymer composition according to comprising 0.1 to 10% by weight of the compound of Formula I.15. A polymer composition according to comprising 0.5 to 7.5% by weight of the compound of Formula I.16. A polymer composition according to wherein the fire and flame retardants and compounds of Formula I and the at least one further flame retardant form a synergistic blend. Fire and flame retardants are widely used as plastic additives for the safer use-in-service of the resulting plastic materials. For many applications such as wire and cable and electric and electronic applications the use of fire and flame retardants as part of the non-conducting insulation materials is mandatory.There are many types of fire and flame retardants available. The most commonly used are the inorganic substances, the halogenated organic compounds, the organophosphorus compounds, or other organic substances.Halogen-containing fire retarding additives are no longer fulfilling the conditions which are now demanded by various industry and governmental regulations. For example the polymer resins for e.g. electric and electronic applications have to comply with the RoHS15 and WEEE16 directives: 15: Directive 2002/95/EC on Restriction of certain hazardous Substances in Electric and Electronic Equipment 16 Directive 2002/96/EC on Waste of ...

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05-12-2019 дата публикации

REVERSIBLE AMINAL GEL COMPOSITIONS, METHODS, AND USE

Номер: US20190367794A1
Принадлежит: Saudi Arabian Oil Company

A well treatment composition for use in a hydrocarbon-bearing reservoir, optionally as a kill pill, and comprising a reversible aminal gel composition is disclosed. The reversible aminal gel composition includes a liquid precursor composition. The liquid precursor composition is operable to remain in a liquid state at about room temperature. The liquid precursor composition comprises an organic amine composition; an aldehyde composition; a polar aprotic organic solvent; and a metal salt composition. The liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature in the hydrocarbon-bearing reservoir. The gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, and the gel state is operable to return to the liquid state responsive to a change in the hydrocarbon-bearing reservoir selected from the group consisting of: a decrease in pH in the hydrocarbon-bearing reservoir and an addition of excess metal salt composition in the hydrocarbon-bearing reservoir. 1. A method for producing a reversible aminal gel composition for use as a kill pill , the method comprising the steps of: an organic amine composition;', 'an aldehyde composition;', 'a polar aprotic organic solvent; and', 'a metal salt composition; and, 'preparing a liquid precursor composition, the liquid precursor composition operable to remain in a liquid state at about room temperature, where the liquid precursor composition comprisesallowing the liquid precursor composition to transition from the liquid state to a gel state in situ proximate a hydrocarbon-bearing reservoir responsive to an increase in temperature.2. The method according to claim 1 , further comprising the step of returning the gel state to the liquid state in situ.3. The method according to claim 2 , where the step of returning the gel state to the liquid state comprises introducing a phosphine-containing ...

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19-12-2019 дата публикации

Impact resistant flame retardant polyhexahydrotriazine polymers via generation of polyhexahydrotriazine monomers and hexahydro-1,3,5-triazine small molecules

Номер: US20190382529A1
Принадлежит: International Business Machines Corp

An impact resistant polyhexahydrotriazine polymer, processes of forming an impact resistant polyhexahydrotriazine polymer, and an article of manufacture comprising an impact resistant polyhexahydrotriazine polymer are disclosed. The impact resistant polyhexahydrotriazine polymer includes at least one hexahydrotriazine group and at least one chain comprising an allylic portion and a styrenic portion. Variations in the chain control properties of the impact resistant polymer. The process of forming the impact resistant polyhexahydrotriazine polymer includes reactions between formaldehyde and at least two classes of monomer that form hexahydrotriazine groups and impact resistant chains. Adjusting relative monomer concentrations controls properties of the impact resistant polyhexahydrotriazine polymer. The article of manufacture contains a material that has an impact resistant polymer. Impact resistance of the impact resistant polyhexahydrotriazine polymer is dependent upon variation in relative amounts of monomers used in its synthesis.

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16-03-2002 дата публикации

Aryl sulfonamides and analogues thereof and their use in the treatment of neurodegenerative diseases

Номер: ES2165792A1

The present invention relates to novel aryl sulfonamides and analogues thereof, methods for producing same and their use in the treatment of neurodegenerative diseases, in particular the prophylaxis and treatment of neurodegenerative diseases, and notably for the treatment of cerebral stroke and craniocerebral trauma.

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11-12-2008 дата публикации

Highly-branched melamine polymers

Номер: WO2008148766A1
Принадлежит: BASF SE

The invention relates to a method for producing highly-branched melamine polymers, according to which melamine with 1.5 to 4 mol of one or several diamines or polyamines per mol of melamine, said diamines or polyamines having at least two primary amino groups, is reacted in the presence of an acidic catalyst. According to the invention, up to 25 mol % of the diamines or polyamines can have three or more primary amino groups and up to 50 mol % of the diamines or polyamines can be substituted by amines with only one primary amino group.

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14-06-2016 дата публикации

process for the preparation of amphiphilic functionalized highly branched polyamine polymers, functionalized highly branched polyamine melamine polymer, and use of polymers

Номер: BR112012014202A2
Принадлежит: BASF SE

processo para a preparação de polímeros de melamina-poliamina altamente ramificados funcionalizados anfifílicos, polímero de melamina-poliamina altamente ramificado funcionalizado, e, uso de polímeros. a presente invenção refere-se a um processo para produzir copolímeros de melamina-poliamina altamente ramificados funcionalizados anfifílicos por meio de condensação de melamina e opcionalmente um derivado de melamina apresentando pelo menos uma amina diferente apresentando pelo menos uma amina diferente apresentando pelo menos dois grupos amino primários e opcionalmente também com uréia e/ou pelo menos um derivado de uréia e/ou com pelo menos um poliisocianato ou diisocianato pelo menos difuncional e/ou pelo menos um ácido carbólico apresentando pelo menos dois grupos carboxila ou pelo menos um derivado dos mesmos, opcionalmente quaternizar uma porção dos grupos amino do polímero assim obtido, reagir o polímero assim obtido com pelo menos um composto capaz de sofrer uma condensação ou reação de adição com grupos aminos, e opcionalmente quaternizar pelo menos parte dos grupos amino do polímero obtido na primeira etapa. a invenção refere-se adicionalmente aos polímeros de melamina-poliamina altamente ramificados funcionalizados anfifílicos que podem ser obtidos de acordo com a invenção, e ao uso dos mesmos como agentes tensoativos. process for the preparation of amphiphilic functionalized highly branched polyamine polymers, functionalized highly branched polyamine melamine polymer, and use of polymers. The present invention relates to a process for producing amphiphilic functionalized highly branched melamine-polyamine copolymers by melamine condensation and optionally a melamine derivative having at least one different amine having at least one different amine having at least two amino groups primary and optionally also with urea and / or at least one urea derivative and / or at least one at least a difunctional polyisocyanate or diisocyanate and / or at least one ...

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11-12-2012 дата публикации

Antireflective coating compositions

Номер: US8329387B2
Принадлежит: AZ Electronic Materials USA Corp

The present invention relates to an antireflective coating composition comprising a novel polymer without an aromatic chromophore, where the polymer comprises a structural unit derived from an aminoplast and a structural unit derived from a diol, triol, dithiol, trithiol, other polyols, diacid, triacid, other polyacids, diimide or mixture thereof, where the diol, dithiol, triol, trithiol, diacid, triacid, diimide, diamide or imide-amide optionally contain one or more nitrogen and/or sulfur atoms or contain one or more alkene groups. The invention also relates to the novel polymer and a process for using the novel antireflective coating composition in a lithographic process.

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21-06-2015 дата публикации

光硬化與熱硬化樹脂組成物、以及防焊乾膜

Номер: TWI489206B
Принадлежит: Lg Chemical Ltd

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29-12-2022 дата публикации

LIQUID PROCESSABLE BISMALEIMIDE-TRIAZINE RESINS

Номер: US20220411583A1
Принадлежит: ROLLS-ROYCE PLC

A curable resin composition including a first bismaleimide compound, a second bismaleimide compound which is different from the first bismaleimide compound, and a cyanate ester monomer. A liquid processible bismaleimide-triazine resin is provided by curing the resin composition. A method of preparing the liquid processible bismaleimide-triazine resin is also disclosed. 1. A curable resin composition comprising:(a) a first bismaleimide compound;(b) a second bismaleimide compound, which is different from the first bismaleimide compound; and(c) a cyanate ester monomer.6. The curable resin composition of claim 1 , wherein the first bismaleimide compound and the second bismaleimide compound are present in a eutectic mixture.8. The curable resin composition of claim 7 , wherein Ris —C(H)(C-C-alkyl)-.9. The curable resin composition of claim 8 , wherein Ris —C(H)(CH)—.11. The curable resin composition of claim 1 , wherein the curable resin composition is free of any solvent.12. The curable resin composition of claim 1 , further comprising a catalyst.13. The curable resin composition of claim 10 , wherein the catalyst is bis(acetylacetonato)copper(II).14. A liquid processible bismaleimide-triazine resin comprising a cured curable resin composition of .15. A method of preparing a liquid processible bismaleimide-triazine resin of claim 14 , the method comprising the steps of:mixing a first bismaleimide compound, a second bismaleimide compound that is different from the first bismaleimide compound, and a cyanate ester monomer to form a curable resin composition; andcuring the curable resin composition to form a liquid processible bismaleimide-triazine resin.16. The method of claim 15 , wherein the curable resin composition is cured at about 150° C. to about 170° C.17. The method of claim 16 , wherein the curable resin composition is cured at about 160° C.18. The method of claim 15 , wherein the curable resin composition is cured at about 150° C. to about 170° C. for about 1 ...

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21-01-2021 дата публикации

Photosensitive adhesive composition

Номер: KR102205627B1
Принадлежит: 닛산 가가쿠 가부시키가이샤

[과제] 신규한 감광성 접착제 조성물을 제공한다. [해결수단] 하기 (A)성분, (B)성분, (C)성분 및 (D)성분을 포함하고, 상기 (B)성분을 상기 (A)성분보다 질량비로 보다 많이 함유하는, 감광성 접착제 조성물. (A)성분: 하기 식(1)로 표시되는 구조단위를 갖고, 말단에 하기 식(2)로 표시되는 구조를 갖는 폴리머, (B)성분: 상기 식(1)로 표시되는 구조단위를 갖고, 말단에 상기 카르복시기 또는 하이드록시기를 갖는 폴리머, (C)성분: 라디칼형 광중합개시제 및 (D)성분: 용제(이들 식 중, X는 탄소원자수 1 내지 6의 알킬기, 비닐기, 알릴기 또는 글리시딜기를 나타내고, m 및 n은 각각 독립적으로 0 또는 1을 나타내고, Q는 탄소원자수 1 내지 16의 2가의 탄화수소기를 나타내고, Z는 탄소원자수 1 내지 4의 2가의 연결기를 나타내고, 이 2가의 연결기는 상기 식(1)에 있어서의 -O-기와 결합하고, R 1 은 수소원자 또는 메틸기를 나타낸다.) [Task] To provide a novel photosensitive adhesive composition. [Solution means] A photosensitive adhesive composition comprising the following (A) component, (B) component, (C) component, and (D) component, and contains more of the (B) component in a mass ratio than the (A) component . (A) component: a polymer having a structural unit represented by the following formula (1), and having a structure represented by the following formula (2) at the terminal, (B) component: having a structural unit represented by the above formula (1) , Polymer having the carboxy group or hydroxy group at the terminal, (C) component: radical photopolymerization initiator and (D) component: solvent (in these formulas, X is an alkyl group having 1 to 6 carbon atoms, a vinyl group, an allyl group, or Represents a cidyl group, m and n each independently represents 0 or 1, Q represents a divalent hydrocarbon group having 1 to 16 carbon atoms, Z represents a divalent linking group having 1 to 4 carbon atoms, and this divalent linking group Is bonded to the -O- group in the above formula (1), and R 1 represents a hydrogen atom or a methyl group.)

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14-04-2010 дата публикации

Proton conducting compound and proton conducting polymer

Номер: EP2078715A4
Принадлежит: Nippon Steel Chemical Co Ltd

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04-04-2013 дата публикации

Stabilized moulding compounds consisting of polyamide and asa-copolymers

Номер: WO2013045205A1
Принадлежит: STYROLUTION GMBH

The invention relates to thermoplastic moulding compounds containing: a) between 3 and 91.8 wt.% of at least one polyamide as component A, b) between 3 and 91.8 wt. % of one or more styrene copolymers B having no units derived from maleic anhydride, c) between 3 and 91.8 wt. % of one or more impact-modifying graft rubbers C, d) between 0.2 and 1.5 wt. % of a compound of formula (I) as component D, e) between 0 and 0.9 wt. % of a blend of formula (II) as component E, f) between 0 and 0.9 wt. % of an additional stabilizer component F, g) between 1 and 25 wt. % of one or more styrene copolymers G, h) between 1 and 30 wt. % of one or more other rubbers. Said compounds have an improved weather-resistance.

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11-06-2021 дата публикации

Resist underlayer composition, and method of forming patterns using the composition

Номер: KR102264693B1
Принадлежит: 삼성에스디아이 주식회사

말단에 적어도 하나의 티올기(-SH)를 포함하는 이소시아누레이트 유도체로부터 유도되는 구조단위를 포함하는 중합체, 및 용매를 포함하는 레지스트 하층막용 조성물, 및 상기 레지스트 하층막용 조성물을 이용한 패턴형성방법을 제공한다. A composition for a resist underlayer film comprising a polymer comprising a structural unit derived from an isocyanurate derivative having at least one thiol group (-SH) at the terminal, and a solvent, and a pattern forming method using the composition for a resist underlayer film provides

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27-01-2014 дата публикации

Функционализованные высокоразветвленные полимеры на основе меламина и полиамина

Номер: RU2012129681A
Принадлежит: БАСФ СЕ

1. Способ получения амфифильных функционализованных высокоразветвленных полимеров на основе меламина и полиамина, который включает следующие стадии:(A-i) конденсацию(A-i.1) меламина и при необходимости по меньшей мере одного производного меламина(A-i.2) по меньшей мере с одним отличающимся от них амином по меньшей мере с двумя первичными аминогруппами,а также при необходимости(A-i.3) с мочевиной и/или по меньшей мере одним производным мочевины, и/или(A-i.4) по меньшей мере с одним по меньшей мере бифункциональным диизоцианатом или полиизоцианатом, и/или(A-i.5) по меньшей мере с одной карбоновой кислотой по меньшей мере с двумя карбоксильными группами или по меньшей мере с одним ее производным,(A-ii) при необходимости кватернизацию части аминогрупп полученного на стадии (A-i) полимерного фрагмента,(A-iii) взаимодействие полученного на стадии (A-i) или (A-ii) полимерного фрагмента по меньшей мере с одним соединением, которое может вступать с аминогруппами в реакцию конденсации или присоединения и приводит к образованию гидрофильного полимерного фрагмента, причем соединение выбрано из группы, включающей- алифатические монокарбоновые кислоты с 4-22 атомами углерода или их производные,- α,β-дикарбоновые кислоты по меньшей мере с шестью атомами углерода или их производные,- при необходимости блокированные алифатические, циклоалифатические или ароматические изоцианаты по меньшей мере с шестью атомами углерода,- алифатические моноамины по меньшей мере с шестью атомами углерода,- алифатические полиамины, в которых все аминогруппы линейно упорядочены относительно друг друга, причем отношение числа содержащихся в полиамине атомов углеро РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C08G 83/00 (13) 2012 129 681 A (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2012129681/04, 15.12.2010 (71) Заявитель(и): БАСФ СЕ (DE) Приоритет(ы): (30) Конвенционный приоритет: 16.12.2009 EP 09179490.9 (85) Дата начала рассмотрения заявки ...

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