12-01-2017 дата публикации
Номер: US20170009060A1
Принадлежит:
Crosslinkable polymeric compositions comprising a thermoplastic, non-elastomer ethylene-based polymer, an organic peroxide, and a crosslinking coagent comprising N,N,N′,N′,N″,N″-hexaallyl-1,3,5-triazine-2,4,6-triamine. Such crosslinkable polymeric compositions and their crosslinked forms can be employed as polymeric layers in wire and cable applications, such as insulation in power cables. 1. A crosslinkable polymeric composition , comprising:(a) a thermoplastic, non-elastomer ethylene-based polymer;(b) an organic peroxide; and(c) a crosslinking coagent comprising N,N,N′,N′,N″,N″-hexaallyl-1,3,5-triazine-2,4,6-triamine2. The crosslinkable polymeric composition of claim 1 , wherein said ethylene-based polymer is non-polar.3. The crosslinkable polymeric composition of claim 2 , wherein said ethylene-based polymer has no fluoromonomers incorporated therein.4. The crosslinkable polymeric composition of claim 1 , wherein said N claim 1 ,N claim 1 ,N′ claim 1 ,N′ claim 1 ,N″ claim 1 ,N″-hexaallyl-1 claim 1 ,3 claim 1 ,5-triazine-2 claim 1 ,4 claim 1 ,6-triamine and said organic peroxide are present in a coagent-to-peroxide weight ratio of greater than 1:1.5. The crosslinkable polymeric composition of claim 1 , wherein said ethylene-based polymer comprises a high-pressure low-density polyethylene; wherein said organic peroxide comprises dicumyl peroxide; wherein said crosslinkable polymeric composition further comprises one or more antioxidants.6. The crosslinkable polymeric composition of claim 1 , wherein said ethylene-based polymer is present in an amount ranging from 50 to 99 weight percent claim 1 , based on the entire crosslinkable polymeric composition weight; wherein said organic peroxide is present in an amount of less than 1.2 weight percent claim 1 , based on the entire crosslinkable polymeric composition weight; wherein said crosslinking coagent is present in an amount ranging from 0.01 to 15 weight percent claim 1 , based on the entire crosslinkable polymeric ...
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