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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 1466. Отображено 100.
27-02-2014 дата публикации

Preparation method of superabsorbent polymer

Номер: US20140058048A1
Принадлежит: LG Chem Ltd

The present invention relates to a method of preparing a superabsorbent polymer, including the steps of: preparing a hydrous gel phase polymer by thermal polymerizing or photo-polymerizing a monomer composition including a water-soluble ethylene-based unsaturated monomer and a polymerization initiator; drying the hydrous gel phase polymer; milling the dried polymer; adding a surface cross-linking agent to the milled polymer; and elevating the temperature of the polymer including the surface cross-linking agent at a speed of 3° C./min to 15° C./min, and carrying out a surface cross-linking reaction at 100° C. to 250° C.

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03-01-2019 дата публикации

ANTIFOULING FILM

Номер: US20190001612A1
Принадлежит:

The antifouling film includes a polymer layer that includes on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light. The polymer layer has a proportion of the number of fluorine atoms relative to the sum of the numbers of carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms of 33 atom % or more on the surface of the uneven structure. The polymer layer has at least one local maximum of the proportion of the number of nitrogen atoms relative to the sum of the numbers of carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms in a region 5 to 90 nm deep from the surface of the uneven structure. The local maximum is 0.3 atom % or more greater than the average value in a region 90 to 120 nm deep from the surface of the uneven structure. 1. An antifouling film comprisinga polymer layer that includes on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light,the polymer layer being a cured product of a resin containing an antifouling agent and a curable resin and containing carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms as constituent atoms,the antifouling agent containing fluorine atoms as constituent atoms,the curable resin containing nitrogen atoms as constituent atoms,fluorine atoms in the antifouling agent being distributed on the surface of the polymer layer,the polymer layer having a proportion of the number of the fluorine atoms relative to the sum of the numbers of the carbon atoms, the nitrogen atoms, the oxygen atoms, and the fluorine atoms measured by X-ray photoelectron spectroscopy of 33 atom % or more on the surface of the uneven structure,the polymer layer having at least one local maximum of the proportion of the number of the nitrogen atoms relative to the sum of the numbers of the carbon atoms, the nitrogen atoms, the oxygen atoms, and the fluorine atoms measured by X-ray ...

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02-01-2020 дата публикации

METHOD OF MANUFACTURING SILICON DIOXIDE NANOPARTICLES MODIFIED BY POLYMER CONTAINING PHOSPHORUS AND NITROGEN

Номер: US20200002503A1
Принадлежит:

The present disclosure discloses a method of manufacturing silicon dioxide nanoparticles modified by a polymer containing phosphorus and nitrogen, which relates to organic/inorganic hybrid nanoparticles, dispersing SiOin an organic solvent, then adding THPS, stirring, and finally adding p-phenylenediamine, reacting, centrifuging, washing, and drying to obtain silicon dioxide nanoparticles modified by a polymer containing phosphorus and nitrogen. The silicon dioxide nanoparticles modified by the polymer containing phosphorus and nitrogen have effects in flame retardancy, strengthening effect of polymer matrixes, and are expected to be widely used in the halogen-free synergistic flame retardancy of polymer materials. 1. A method for manufacturing silicon dioxide nanoparticles modified by a polymer containing phosphorus and nitrogen , the method comprising:{'sub': 2', '2', '2, 'sup': −5', '−3', '−4', '−2, '1) dispensing silicon dioxide nanoparticles in an organic solvent and ultrasonically dispersing for 10-60 minutes to obtain a SiO-organic solvent solution dispersion with a SiOconcentration of 8×10-6×10g/mL; diluting a tetrakis(hydroxymethyl)phosphonium sulfate (THPS) solution with distilled water to obtain a THPS diluent with a THPS concentration of 8×10-4×10g/mL; adding the THPS diluent drop by drop into the SiO-organic solvent solution dispersion while stirring; and continuing to stir for 5-45 minutes to obtain a mixed solution, wherein, a weight ratio of the silicon dioxide nanoparticles to THPS is in a range of 1:0.7-4; and'}{'sup': −4', '−3, '2) dissolving p-phenylenediamine in the organic solvent to obtain a p-phenylenediamine solution with a p-phenylenediamine concentration of 4×10-6×10g/mL; adding the p-phenylenediamine solution drop by drop into the mixed solution obtained in step 1; reacting for 20-70 minutes; ultrasonically treating for 20-70 minutes; centrifuging; washing; and drying in vacuum at 40-50° C. to obtain the silicon dioxide nanoparticles ...

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01-01-2015 дата публикации

CATALYST-FREE SURFACE FUNCTIONALIZATION AND POLYMER GRAFTING

Номер: US20150005447A1
Принадлежит:

Some embodiments described herein relate to a substrate with a surface comprising a silane or a silane derivative covalently attached to optionally substituted cycloalkene or optionally substituted heterocycloalkene for direct conjugation with a functionalized molecule of interest, such as a polymer, a hydrogel, an amino acid, a nucleoside, a nucleotide, a peptide, a polynucleotide, or a protein. In some embodiments, the silane or silane derivative contains optionally substituted norbornene or norbornene derivatives. Method for preparing a functionalized surface and the use in DNA sequencing and other diagnostic applications are also disclosed. 1. A substrate comprising a first surface comprising silane or a silane derivative covalently bound to a functionalized molecule through a first plurality of unsaturated moieties selected from cycloalkenes , cycloalkynes , heterocycloalkenes , heterocycloalkynes , or optionally substituted variants or combinations thereof covalently attached to silicon atoms of said silane or silane derivative.2. The substrate of claim 1 , wherein said first plurality of unsaturated moieties are selected from norbornene claim 1 , heteronorbornenes claim 1 , norbornene derivatives claim 1 , trans-cyclooctene claim 1 , trans-cyclooctene derivatives claim 1 , cyclooctyne claim 1 , bicycloalkynes claim 1 , or optionally substituted variants or combinations thereof.3. The substrate of claim 1 , wherein said first plurality of unsaturated moieties are selected from optionally substituted norbornene claim 1 , optionally substituted cyclooctyne claim 1 , optionally substituted bicyclononyne claim 1 , or optionally substituted bicyclo[6.1.0]non-4-yne.4. The substrate of claim 1 , further comprising linkers covalently attached between silicon atoms of said silane or silane derivative and the first plurality of unsaturated moieties.5. The substrate of claim 4 , wherein the linkers are selected from optionally substituted alkylenes claim 4 , optionally ...

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08-01-2015 дата публикации

Catalyst composition and method for preparing the same

Номер: US20150011702A1
Принадлежит: Saudi Basic Industries Corp

The invention relates to linear low density polyethylene having a density in the range from about 900 kg/m 3 to less than about 940 kg/m 3 as determined using IS01872-2, having a molecular weight distribution (M w /M n ) in the range from 2.5 to 3.5, having an area under the peak in the temperature range from 20 to 40° C. determined using an analytical temperature rising elution fractionation analysis using 1,2-dichlorobenzene and a heating rate of 1° C./min, wherein the area is in the range from 5 to 20% of the sum of the areas under all peaks determined with the analytical temperature rising elution fractionation analysis.

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09-01-2020 дата публикации

PHASE DIFFERENCE PLATE, MULTILAYER PHASE DIFFERENCE PLATE, POLARIZING PLATE, IMAGE DISPLAY DEVICE AND POLYMERIZABLE COMPOUND

Номер: US20200012026A1
Принадлежит: ZEON CORPORATION

A phase difference plate including a layer of a liquid crystal material oriented in an in-plane direction, wherein an in-plane retardation Re(λ) at a wavelength λ nm of the phase difference plate satisfes the following formulae (e1) and (e2): {Re(400)-Re(550)}/{Re(550)-Re(700)}<2.90 (e1), and Re(400)/Re(700) >1.13 (e2); as well as a multilayer phase difference plate including the same, a polarizing plate including the same, and an image display device including the same. 1. A phase difference plate comprising a layer of a liquid crystal material oriented in an in-plane direction , wherein [{'br': None, '{Re(400)-Re(550)}/{Re(550)-Re(700)}<2.90 \u2003\u2003(e1), and'}, {'br': None, 'Re(400)/Re(700) >1.13 \u2003\u2003(e2).'}], 'an in-plane retardation Re(λ) at a wavelength λ nm of the phase difference plate satisfies the following formulae (e1) and (e2)2. The phase difference plate according to claim 1 , wherein the in-plane retardation Re(λ)satisfies the following formula (e3):{'br': None, 'Re(400)/Re(700) 1.50 \u2003\u2003(e3).'}412. A multilayer phase difference plate comprising a phase difference plate P and a phase difference plate P claim 1 , wherein{'b': 1', '2, 'an in-plane slow axis of the phase difference plate P is orthogonal to an in-plane slow axis of the phase difference plate P,'}{'b': '2', 'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the phase difference plate P is the phase difference plate according to ,'}{'b': 1', '1', '2', '2, 'claim-text': [{'br': None, 'ReP1(550) >ReP2(550) \u2003\u2003(e4), and'}, {'br': None, 'ReP1(400)/ReP1(700) Подробнее

16-01-2020 дата публикации

HYDROGEL

Номер: US20200016300A1
Автор: IIZUKA Ryo, KATO Kazuki
Принадлежит: SEKISUI PLASTICS CO., LTD.

A hydrogel 1 having a laminate structure of layer A 10 and layer B 20, wherein layer A 10 contains a monomer-derived component, water, a humectant, a water-insoluble polymer having tackiness and an amphiphilic polymer, the water-insoluble polymer is contained in a proportion of 3 to 20 wt % based on a total amount of layer A, and the amphiphilic polymer is a polyvinyl alcohol having a saponification degree of 50 to 75% and is contained in a proportion of 0.05 to 5 wt % based on the total amount of layer A; layer B 20 contains a monomer-derived component, water and a humectant and is substantially free of a water-insoluble polymer having tackiness and a polyvinyl alcohol; and an amount of the water based on a total amount of layer B is the amount of water based on the total amount of layer A±10 wt %. 1. A hydrogel having a laminate structure of layer A and layer B , whereinlayer Acomprises a monomer-derived component, water, a humectant, a water-insoluble polymer having tackiness and an amphiphilic polymer,the water-insoluble polymer is comprised in a proportion of 3 to 20 wt % based on. a total amount of layer A, andthe amphiphilic polymer is a polyvinyl alcohol having a saponification degree of 50 to 75% and is comprised in a proportion of 0.05 to 5 wt % based on the total amount of layer A;layer Bcomprises a monomer-derived component, water and a humectant andis substantially free of a water-insoluble polymer having tackiness and a polyvinyl alcohol;an amount of the water based on a total amount of layer B is the amount of water based on the total amount of layer A±10 wt %; andan amount of the humectant based on the total amount of layer B is an amount of the humectant based on the total amount of layer A±10 wt %.2. The hydrogel according to claim 1 , wherein the monomer-derived component in layer A and the monomer-derived component in Layer B are identical as a compound.3. The hydrogel according to claim 1 , wherein the humectant is a polyhydric alcohol.4. The ...

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19-01-2017 дата публикации

Emulsions with improved stability

Номер: US20170018328A1
Принадлежит: Elantas PDG Inc

Disclosed are methods of lowering application viscosities of or of reducing or eliminating monomer content in electrical impregnating materials comprising or consisting of an emulsion of an unsaturated polyester or a mixture of unsaturated polyesters, water, at least one radical polymerisation initiator or radical polymerisation initiator/promoter mixture, at least one surfactant having an HLB-value of greater than 15, optionally at least one reactive diluent, and optionally further additives, a process for preparing zero or low VOC electrical impregnation materials, a method of impregnating electrical or electromechanical devices and a method of increasing the stability of aqueous emulsions of unsaturated polyesters.

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24-01-2019 дата публикации

DRUG DELIVERY DEVICE AND ITS METHOD OF MANUFACTURE

Номер: US20190022233A1
Принадлежит:

The invention relates to a drug delivery device adapted for carrying and delivering both hydrophilic and lipophilic drug molecules. The drug delivery device includes a porous body for adsorption of drug molecules, the body including a plurality of microspheres, and a hydrogel forming cross-links connecting the plurality of microspheres. 1. A drug delivery device adapted for carrying and delivering both hydrophilic and lipophilic drug molecules , comprising: a plurality of microspheres, and', 'a hydrogel forming cross-links connecting the plurality of microspheres., 'a porous body for adsorption of drug molecules, comprising2. The drug delivery device of claim 1 , wherein the microspheres each contains one or more acrylate groups.3. The drug delivery device of claim 2 , wherein the microspheres are formed by trimethylolpropane ethoxylate triacrylate claim 2 , trimethylolpropane triacrylate claim 2 , or their derivative.4. The drug delivery device of claim 2 , wherein the microspheres are poly(trimethylolpropane ethoxylate triacrylate) microspheres.5. The drug delivery device of claim 1 , wherein the hydrogel is formed by a starch-based derivative modified with a methacrylate source.7. The drug delivery device of claim 1 , wherein the drug delivery device is adapted for simultaneous delivery of at least one type of hydrophilic drug molecules and at least one type of lipophilic drug molecules.8. The drug delivery device of claim 1 , wherein the drug delivery device is adapted for simultaneous delivery of at least two different types of drugs molecules with different aqueous solubility.9. The drug delivery device of claim 1 , further comprising at least one type of hydrophilic drug molecules adsorbed on the body.10. The drug delivery device of claim 1 , further comprising at least one type of lipophilic drug molecules adsorbed on the body.11. The drug delivery device of claim 1 , further comprising at least one type of lipophilic drug molecules and at least one type of ...

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02-02-2017 дата публикации

Optical resin composition and film

Номер: US20170031058A1
Принадлежит: Kaneka Corp

Disclosed herein are an optical resin composition whose orientation birefringence and photoelastic birefringence are both very low and which has high transparency and which provides a film having few surface defects and excellent mechanical strength, and a film comprising the optical resin composition. Also disclosed herein is a film that has optical isotropy and excellent transparency even after stretching. The optical resin composition contains a thermoplastic resin and a multistep-polymerized graft copolymer obtained by polymerizing, in the presence of crosslinked polymer-containing particles formed by polymerizing a monomer mixture containing a monomer represented by the following formula (4) and a polyfunctional monomer, a monomer mixture containing a monomer represented by the following formula (4) and another monofunctional monomer copolymerizable therewith.

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31-01-2019 дата публикации

USE OF MULTI-FUNCTIONAL CROSS-LINKING AGENTS IN THE MANUFACTURE OF PULSE SHAPE DISCRIMINATING PLASTIC SCINTILLATORS, THE SCINTILLATOR, AND METHODS OF USING THE SAME

Номер: US20190033474A1
Принадлежит:

The present invention is directed to systems and methods for producing an improved pulse shape discriminating (PSD) scintillator by including a cross-linking agent, such as BPA-DM, in the polymer from which the scintillator is machined, and to PSD scintillators produced thereby. The cross-linking agent could also be used for plastic scintillators with significant incorporation of specialized dopants (boron, lead or bismuth) for thermal neutron, fast neutron and/or gamma radiation detection. 1. A method for producing a pulse shape discriminating scintillator , comprising:combining between about 20 wt. % and 40 wt. % of a first dopant, between about 0.01 wt. % and about 2 wt. % of a secondary dopant, at least 0.5 wt. % of at least one cross-linking agent, and a balance of at least one monomer, wherein the at least one monomer is a styrene-based monomer, methacrylate monomer, a benzyl acrylate, or a benzyl methacrylate, to form a mixture;purging the mixture with an inert gas; andcuring the mixture at a temperature between about 60° C. and about 110° C. to form the pulse shape discriminating capable scintillator.2. The method of claim 1 , wherein a molecular structure of the cross-linking agent provides aromatic π-electrons.3. The method of claim 1 , wherein the at least one cross-linking agent comprises at least one of a bisphenol A dimethacrylate claim 1 , a halogenated bisphenol A dimethacrylate claim 1 , or a di-functional aromatic acrylate.4. The method of claim 1 , wherein the mixture comprises less than or equal to about 10 wt. % of the cross-linking agent.5. The method of claim 1 , further comprising at least one initiator.6. The method of claim 5 , wherein the at least one initiator is azobisisobutyronitrile AIBN.7. The method of claim 6 , wherein between about 0.01 wt. % and about 0.1 wt. % of the initiator is combined with the monomer to form a premixture claim 6 , wherein the premixture is substituted for the monomer in the mixture.8. The method of claim 1 , ...

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09-02-2017 дата публикации

Curable Compositions and Membranes

Номер: US20170037206A1
Автор: Antheunis Harro
Принадлежит:

A method for preparing an ionically-charged membrane comprising the steps (1) applying a film of curable composition to a support; (2) curing the film of curable composition to give anionically-charged membrane; and (3) removing the ionically-charged membrane from the support; wherein the curable composition comprises a) 5 to 50 wt % of curable compound comprising one ethylenically unsaturated group and anionic group; b) 10 to 70 wt % of crosslinking agent comprising at least two ethylenically unsaturated groups and having a molecular weight of at least 500 dalton per ethylenically unsaturated group; and c) 5 to 60 wt % of inert solvent. 1. A method for preparing an ionically-charged membrane comprising the steps:(1) applying a film of curable composition to a support;(2) curing the film of curable composition to give an ionically-charged membrane; and(3) removing the ionically-charged membrane from the support;wherein the curable composition comprises:a) 5 to 50 wt % of curable compound comprising one ethylenically unsaturated group and an ionic group;b) 10 to 70 wt % of crosslinking agent comprising at least two ethylenically unsaturated groups and having a molecular weight of at least 500 dalton per ethylenically unsaturated group; andc) 5 to 60 wt % of inert solvent.2. The method according to wherein the crosslinking agent comprising at least two ethylenically unsaturated groups having a molecular weight of at least 700 dalton per ethylenically unsaturated group.3. The method according to wherein the crosslinking agent comprising at least two ethylenically unsaturated groups having a molecular weight below 10 claim 1 ,000 dalton.4. The method according to wherein the said crosslinking agent has a solubility in water of less than 0.01 mol/l claim 1 , when measured at 25° C.5. The method according to wherein the film is applied to the support by a method comprising curtain coating claim 1 , blade coating claim 1 , air-knife coating claim 1 , knife-over-roll ...

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08-02-2018 дата публикации

OPTICAL ISOMER

Номер: US20180037819A1
Принадлежит:

The problem that the present invention is to solve is to provide an optical film that has less alignment defects and is less liable to cause variation in the optical characteristics when placed in a high temperature state. The present invention provides an optical film containing a structural unit derived from a specific compound, that is, an optical film containing a structural unit derived from a compound represented by the general formula (I), which has less alignment defects and is less liable to cause variation in the optical characteristics when placed in a high temperature state, and also provides a display device including the optical film. 4. The optical film according to claim 3 , wherein in the general formula (I-A) claim 3 , n111 represents 0 claim 3 , n121 represents 1 claim 3 , Rrepresents a group represented by the formula (I-R2-A) claim 3 , n211 represents 1 claim 3 , and n221 represents 0.8. The optical film according to claim 1 , which further comprises a structural unit derived from a chiral compound.9. The optical film according to claim 1 , which has a cholesteric structure.11. A compound claim 1 , which is represented by the general formula (I) as set forth in .12. A compound claim 6 , which is represented by the general formula (I-A-111) claim 6 , the general formula (I-A-221) claim 6 , the general formula (I-A-121) claim 6 , or the general formula (I-A-211) as set forth in .13. A compound claim 7 , which is represented by the general formula (I-A-112) claim 7 , the general formula (I-A-222) claim 7 , the general formula (I-A-122) claim 7 , or the general formula (I-A-212) as set forth in .14. A laminate film claim 1 , comprising the optical film as set forth in .15. A display device claim 1 , comprising the optical film as set forth in .16. A display device claim 14 , comprising the laminate film as set forth in . The present invention relates to an optical film and a display device including the optical film.Compounds (polymerizable ...

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24-02-2022 дата публикации

Isocyanate Free Binder

Номер: US20220056171A1
Принадлежит:

The present invention relates to a resin composition that comprises an acetoacetate ester compound with at least two acetoacetate ester functional groups, an acrylate compound with at least two acrylate functional groups, and a tertiary amine curing catalyst. This resin composition acts as an isocyanate-free binder that is less toxic to the environment. The invention further discloses a method for preparation fiber reinforced parts comprising fibers and said resin composition as well as a method for the preparation of foundry molds for the casting industry, which is based on said binder. 1. A method of preparing a foundry shape comprising the steps ofi) mixing a foundry aggregate with a resin formulation to give a foundry mix, andii) curing said foundry mix with a tertiary amine curing catalyst that is provided in the form of a gas and/or in a stream of an inert gas,wherein said resin formulation comprisesa) one or more acetoacetate ester compounds each comprising at least two acetoacetate ester functional groups, andb) one or more acrylate compounds each comprising at least two acrylate functional groups.2. A method for preparation of fiber reinforced parts comprising the steps of(i) contacting a fiber with a resin composition to provide a fiber resin composition; and(ii) curing said fiber resin composition to provide the fiber reinforced part;wherein the resin composition comprisesa) one or more acetoacetate ester compounds comprising at least two acetoacetate ester functional groups,b) one or more acrylate compound comprising at least two acrylate functional groups, andc) a tertiary amine curing catalyst.3. The method according to claim 1 , wherein{'sup': ['2,6', '2,6'], '#text': 'the one or more acetoacetate ester compounds are independently selected from the group consisting of 1,4-butanediol diacetoacetate, 1,6-hexanediol diacetoacetate, neopentyl glycol diacetoacetate, the diacetoacetate of 4,8-bis(hydroxymethyl)tricyclo[5.2.1.0]decane, 2-methyl-1,3- ...

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06-02-2020 дата публикации

Dye-doped laser protective film

Номер: US20200041701A1

A dye-doped laser protective film is disclosed, comprising a polymer layer A and a polymer layer B. The polymer molecules in the polymer layer A are arranged in a left-handed helical structure which can reflect a left-handed polarized laser. The polymer molecules in the polymer layer B are arranged in a right-handed helical structure which can reflect a right-handed polarized laser. The combination of the polymer layer having the left-handed helical structure and the polymer layer having the right-handed helical structure can completely reflect circularly polarized light. In addition, the dye can absorb incident laser, so as to expand the protection angle of the laser protective film. The dye-doped laser protective film of the present disclosure has a simple manufacturing process, large protection angle and good flexibility, and can refit existing devices. Thus, the dye-doped laser protective film of the present disclosure has a good application prospect in many fields such as laser goggles, window films and the like.

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15-02-2018 дата публикации

GEL COMPOSITIONS, SHAPED GEL ARTICLES AND A METHOD OF MAKING A SINTERED ARTICLE

Номер: US20180044245A1
Принадлежит:

Reaction mixtures, gel compositions that are a polymerized product of the reaction mixtures, shaped gel articles that are formed within a mold cavity and that retain the size and shape of the mold cavity upon removal from the mold cavity, and sintered articles prepared from the shaped gel articles are provided. The sintered article has a shape identical to the mold cavity (except in regions where the mold cavity was overfilled) and to the shaped articles but reduced in size proportional to the amount of isotropic shrinkage. Methods of forming the sintered articles also are provided. 1. A gel composition comprising a polymerized product of a reaction mixture comprising:{'sub': '2', 'a. 20 to 60 weight percent zirconia-based particles based on a total weight of the reaction mixture, the zirconia-based particles having an average particle size no greater than 100 nanometers and comprising at least 70 mole percent ZrO;'}b. 30 to 75 weight percent of a solvent medium based on the total weight of the reaction mixture, the solvent medium comprising at least 60 percent of an organic solvent having a boiling point equal to at least 150° C.;c. 2 to 30 weight percent polymerizable material based on the total weight of the reaction mixture, the polymerizable material comprising (1) a first surface modification agent having a free radical polymerizable group; andd. a photoinitiator for a free radical polymerization reaction.2. The gel composition of claim 1 , wherein the solvent medium comprises at least 80 weight percent of the organic solvent having the boiling point equal to at least 150° C.4. The gel composition of claim 1 , wherein the zirconia-based particles are crystalline and wherein at least 80 weight percent of the zirconia-based particles have a cubic structure claim 1 , tetragonal structure claim 1 , or a combination thereof.5. The gel composition of claim 1 , wherein the first surface modification agent having a free radical polymerizable group further has a ...

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15-02-2018 дата публикации

METHOD FOR MAKING COLORED FILM, COLORED FILM, COLORED MATERIAL, AND OPHTHALMIC LENS

Номер: US20180044501A1
Автор: CHIEN HSIU-WEN
Принадлежит:

A method for making a colored film includes following steps of providing a mixture comprising a hydrophilic monomer, a functionalized vinylic monomer, a clay, a cross-linking agent, and an initiator; mixing a pigment and a solvent with the mixture to form a colored material; and placing the colored material into a mold, and exposing the colored material to ultraviolet radiation or heating the colored material, to cause the hydrophilic monomer, the functionalized vinylic monomer, the cross-linking agent, and the initiator in the colored material to undergo a polymerization reaction to form a cross-linking network, and the clay in the colored material to be dispersed in the cross-linking network, thereby forming the colored film. The disclosure also provides a colored film made by above method, a colored material making for the colored film, and an ophthalmic lens. 1. A method for making a colored film , comprising:providing a mixture comprising a hydrophilic monomer, a functionalized vinylic monomer, a clay, a cross-linking agent, and an initiator;mixing a pigment and a solvent with the mixture to form a colored material; andplacing the colored material into a mold, and exposing the colored material to ultraviolet radiation or heating the colored material, to cause the hydrophilic monomer, the functionalized vinylic monomer, the cross-linking agent, and the initiator in the colored material to undergo a polymerization reaction to form a cross-linking network, and the clay in the colored material to be dispersed in the cross-linking network, thereby forming the colored film.2. The method of claim 1 , wherein the hydrophilic monomer has a mass percentage of about 20% to about 50% of a total mass of the mixture claim 1 , the functionalized vinylic monomer has a mass percentage of about 25% to about 60% of the total mass of the mixture claim 1 , the clay has a mass percentage of about 0.5% to about 42% of the total mass of the mixture claim 1 , the cross-linking agent ...

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03-03-2022 дата публикации

BARRIER FILM

Номер: US20220064395A1
Принадлежит:

Provided is a barrier film, comprising:

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25-02-2016 дата публикации

ROBUST POLYMERIC MEMBRANE

Номер: US20160053064A1
Принадлежит:

Hydrophilic porous membranes comprising a random copolymer of: 4. The hydrophilic membrane of claim 1 , wherein the hydrophobic polymer is a sulfone polymer.5. A method of filtering a fluid claim 1 , the method comprising passing the fluid through the membrane of .6. The method of claim 5 , wherein the fluid is a protein-containing fluid.7. The hydrophilic membrane of claim 2 , wherein the hydrophobic polymer is a sulfone polymer.8. The hydrophilic membrane of claim 3 , wherein the hydrophobic polymer is a sulfone polymer.9. A method of filtering a fluid claim 2 , the method comprising passing the fluid through the membrane of .10. A method of filtering a fluid claim 3 , the method comprising passing the fluid through the membrane of .11. A method of filtering a fluid claim 4 , the method comprising passing the fluid through the membrane of .12. The method of claim 9 , wherein the fluid is a protein-containing fluid.13. The method of claim 10 , wherein the fluid is a protein-containing fluid.14. The method of claim 11 , wherein the fluid is a protein-containing fluid. Polymeric membranes are used to filter a variety of fluids. However, there is a need for membranes that provide robust performance.The present invention provides for ameliorating at least some of the disadvantages of the prior art. These and other advantages of the present invention will be apparent from the description as set forth below.An embodiment of the invention provides a hydrophilic porous membrane, comprising a random copolymer of:In accordance with another embodiment, a hydrophilic porous membrane is prepared by a process comprising polymerizing in a solvent:In accordance with other embodiments of the invention, filters and filter devices comprising the membranes, as well as methods of making and using the membranes, are provided.In accordance with an embodiment of the present invention, a hydrophilic porous membrane (preferably, a hydrophilic microporous membrane) is provided, the membrane ...

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25-02-2016 дата публикации

POROUS RESIN PARTICLES, METHOD OF MANUFACTURING POROUS RESIN PARTICLES, DISPERSION LIQUID, AND USE OF POROUS RESIN PARTICLES

Номер: US20160053067A1
Принадлежит: SEKISUI PLASTICS CO., LTD.

Disclosed are porous resin particles which contain a polymer of a monomer mixture of a mono(meth)acrylate-based monomer and a polyfunctional vinyl-based monomer. The mono(meth)acrylate-based monomer contains an ethylenic unsaturated group only in a (meth)acrylic acid residue, a hydroxyl group in an alcohol residue, and at least one of an ether group and an ester group in an alcohol residue. The polyfunctional vinyl-based monomer contains two or more ethylenic unsaturated groups. The porous resin particles have a water absorption value of from more than 400 ml to 700 ml per 100 g of the particles and an oil absorption value of from more than 400 ml to 700 ml per 100 g of the particles. 1. Porous resin particles which comprise a polymer of a monomer mixture which comprises:a mono(meth)acrylate-based monomer containing: an ethylenic unsaturated group only in a (meth)acrylic acid residue; a hydroxyl group in an alcohol residue; and at least one of an ether group and an ester group in an alcohol residue; anda polyfunctional vinyl-based monomer containing two or more ethylenic unsaturated groups,said particles having a water absorption value of from more than 400 ml to 700 ml per 100 g of said particles and an oil absorption value of from more than 400 ml to 700 ml per 100 g of said particles.2. The porous resin particles as set forth in claim 1 , wherein the mono(meth)acrylate-based monomer is a compound of either general formula (1) or general formula (2):{'br': None, 'sub': 2', '2', '4', 'l', '3', '6', 'm, 'CH═CR—COO[(CHO)(CHO)]—H\u2003\u2003(1)'}{'sub': '3', 'claim-text': {'br': None, 'sub': 2', '2', '2', '2', '5', 'p, 'CH═CR—COOCHCHO(CO(CH)O)—H\u2003\u2003(2)'}, 'where R is either H or CH, l is 0 to 50, m is 0 to 50, and l+m>1, and'}{'sub': '3', 'where R is either H or CH, and p is 1 to 50.'}3. The porous resin particles as set forth in claim 1 , wherein the monomer mixture further comprises another monofunctional vinyl-based monomer having one ethylenic unsaturated ...

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23-02-2017 дата публикации

METHOD TO GENERATE AND DISPERSE NANOSTRUCTURES IN A COMPOSITE MATERIAL

Номер: US20170050159A1
Автор: Agrawal Gaurav, Xu Zhiyue
Принадлежит: BAKER HUGHES INCORPORATED

A method of making a nanostructure-reinforced composite comprises providing matrix particles in a reactor; fluidizing the matrix particles; introducing a nanostructure material into the reactor; homogeneously dispersing the nanostructure material; uniformly depositing the nanostructure material on the matrix particles to form a composite powder; generating a nanostructure on the matrix particles from the nanostructure material; and processing the composite powder to form the nanostructure-reinforced composite having a matrix formed from the matrix particles. The nanostructures are evenly distributed in the matrix of the nanostructure-reinforced composite. 1. A method of making a composite powder comprising:providing matrix particles in a reactor, the matrix particles comprising a metal oxide, metal carbide, polymer, ceramic, plastic, glass, graphene, graphite, or a combination thereof;fluidizing the matrix particles;introducing a nanostructure material into the reactor;homogeneously dispersing the nanostructure material; anduniformly depositing the nanostructure material on the matrix particles to form the composite powder.2. The method of claim 1 , wherein the matrix particles are the polymer selected from polyphenylene claim 1 , polyacetylene claim 1 , polypyrrole claim 1 , polythiophene claim 1 , polyester claim 1 , polyethylene claim 1 , polyacrylate claim 1 , polypropylene claim 1 , polyamide claim 1 , polyimide claim 1 , polybenzoxazole claim 1 , poly(amino acid) claim 1 , epoxy claim 1 , polystyrene claim 1 , polybutadiene claim 1 , polycarbonate claim 1 , or a combination thereof.3. The method of claim 1 , wherein the matrix particles are the ceramic selected from an oxide-based ceramic claim 1 , nitride-based ceramic claim 1 , carbide-based ceramic claim 1 , boride-based ceramic claim 1 , silicide-based ceramic claim 1 , or a combination thereof.4. The method of claim 1 , wherein the matrix particles are about 0.5 μm to about 500 μm.5. The method of claim 1 ...

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25-02-2021 дата публикации

Recycling of Superabsorbent Polymer with an Extensional Flow Device

Номер: US20210054163A1
Принадлежит:

Poly(acrylic acid)-based superabsorbent polymer (SAP) in a feed stream is converted into poly(acrylic acid) (PAA) in an extensional flow device. The total energy used to degrade the SAP into PAA is less than about 50 MJ/kg SAP. 1. A method for degrading a superabsorbent polymer (SAP) to poly(acrylic acid) (PAA) comprising flowing a feed stream comprising said SAP into an inlet of an extensional flow device and producing a product stream comprising said PAA at an outlet of said extensional flow device; wherein said feed stream comprises said SAP at a concentration greater than about 1 wt %; wherein said feed stream has a residence time in said extensional flow device of less than about 120 s; and wherein said degradation of said SAP to said PAA requires a total energy of less than about 50 MJ/kg SAP.2. The method of claim 1 , wherein said residence time is less than about 60 s.3. The method of claim 1 , wherein said total energy is less than about 16 MJ/kg SAP.4. The method of claim 1 , wherein said feed stream comprises SAP and water.5. The method of claim 1 , wherein said feed stream comprises SAP and hydrogen peroxide.6. The method of claim 1 , wherein said SAP has degree of neutralization (DN) greater than about 50%.7. The method of claim 1 , wherein said SAP has DN between about 65% and about 75%.8. The method of claim 1 , wherein said feed stream has a viscosity; wherein said product stream has a viscosity; wherein the ratio of the viscosity of the product stream to the viscosity of the feed stream is the viscosity ratio; and wherein the negative logarithm of said viscosity ratio is less than about 6.9. The method of claim 1 , wherein said feed stream has a viscosity; wherein said product stream has a viscosity; wherein the ratio of the viscosity of the product stream to the viscosity of the feed stream is the viscosity ratio; and wherein the negative logarithm of said viscosity ratio is less than about 4.10. The method of claim 1 , wherein said feed stream has ...

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22-02-2018 дата публикации

Cellulose Cyanoacrylate and Method of Employment

Номер: US20180051146A1
Автор: Carlisle Richard S.
Принадлежит:

Cellulose cyanoacrylate is employed either to bond two surfaces or to duplicate the shape of a three-dimensional object. The method is carried out by applying a release material to the object to be duplicated, applying a sheet of cellulosic material formed of wood fibers onto the three dimensional object, then saturating the sheet of cellulosic material with a cyanoacrylate glue and permitting the saturated sheet to cure. The resulting product duplicates the shape of the object. Two surfaces may be bonded by placing a sheet of cellulosic material between the two surfaces and applying the cyanoacrylate glue to edges of the sheet until saturated and allowing it to cure. Paper toweling may favorably be employed as the cellulosic material. This material may also be employed in bone or tooth repair. A break or fracture in an article can be repaired by positioning a sheet of cellulosic material over the break, saturating it with cyanoacrylate glue, and holding the saturated sheet in place with a releasable film. Irritating fumes may be suppressed by covering the saturated cellulosic material with a release film. 120-. (canceled)21. (canceled)22. (canceled)23. (canceled)24. A cellulose cyanoacrylate compound , comprising a waterproof composition of matter formed by saturating fibrous cellulosic material selected from the group consisting of cotton and sheets of paper toweling comprising wood fibers , with liquid cyanoacrylate glue.25. compound of wherein the glue is selected from the group consisting of one or more of cyano-methyl claim 24 , cyano-ethyl and cyano-octyl acrylates.26. compound of having properties of high rigidity and high abrasion resistance.27. compound of shaped while curing with pressure applied through a layer of flexible material that is releasable from the cured surface.28. compound of applied as a support system for repair of a bone fracture. An invention is provided for repairing a wide variety of broken items made of plastic, wood or metal and is ...

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01-03-2018 дата публикации

POLYMERIC COMPOSITE PARTICLES

Номер: US20180057770A1
Принадлежит:

Compositions are provided that include a matrix and a polymeric composite particles disposed in the matrix. The polymeric composite particles include a porous polymeric core and a fragrance positioned within the porous polymeric core. Polymeric composite particles are also provided including a porous polymeric core, a fragrance positioned within the porous polymeric core, and a coating layer around the porous polymeric core. Further, a method of determining a minimum temperature of a composition is provided including providing a composition including polymeric composite particles disposed in a matrix, heating the composition, releasing at least a portion of the fragrance as a vapor from the porous polymeric core of the polymeric composite particles at or above the minimum temperature, and detecting at least a portion of the fragrance vapor in a location outside of the matrix. 1. A composition comprising a matrix and a plurality of polymeric composite particles disposed in the matrix , wherein the polymeric composite particles comprise a porous polymeric core and a fragrance positioned within the porous polymeric core , wherein the matrix comprises a film , a nonwoven matrix , a woven matrix , a foam , a multilayer construction , or a combination thereof.2. The composition of claim 1 , wherein the matrix comprises a film claim 1 , a multilayer construction claim 1 , or a combination thereof.3. The composition of claim 1 , wherein the matrix comprises an adhesive.4. The composition of claim 1 , wherein the polymeric composite particles are not visible from an exterior of the composition.5. The composition of claim 1 , wherein the fragrance has a vapor pressure at 25 degrees Celsius of at least 0.05 mmHg.6. The composition of claim 1 , wherein the polymeric composite particles further comprise a coating layer around the porous polymer core claim 1 , the coating layer comprising a thermoplastic polymer claim 1 , a wax claim 1 , or a mixture thereof.7. The composition of ...

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02-03-2017 дата публикации

METHOD FOR PRODUCING FIBER-REINFORCED RESIN COMPOSITE MATERIAL

Номер: US20170058087A1
Принадлежит:

A method for producing a fiber-reinforced resin composite material includes a step of curing a composition for producing a fiber-reinforced resin composite material, which includes a reinforcing fiber material and a resin composition including a radical reactive resin having at least one polymerizable unsaturated double bond, by irradiating the composition with ionizing radiation. 1. A method for producing a fiber-reinforced resin composite material , the method comprising a step of curing a composition for producing a fiber-reinforced resin composite material , which includes a reinforcing fiber material and a resin composition including a radical reactive resin having at least one polymerizable unsaturated double bond , by irradiating the composition with ionizing radiation.2. The method for producing a fiber-reinforced resin composite material according to claim 1 , wherein the total absorbed dose of the ionizing radiation for the composition for producing a fiber-reinforced resin composite material is 10 kGy to 500 kGy. The present invention relates to a method for producing a fiber-reinforced resin composite material.Fiber-reinforced resin composite materials, in which resin materials have been reinforced with reinforcing fiber materials such as carbon fibers or glass fibers, are generally characterized by having excellent strength and rigidity. Such fiber-reinforced, resin composite materials are widely used in various applications ranging from, for example, structural materials for aircrafts to automotive parts and sports applications such as rackets and golf shafts, by utilizing lightweightness of the materials.As a fiber-reinforced resin composite material, for example, Patent Literature 1 described below suggests a carbon fiber-reinforced resin composite material produced by curing a composition that includes an epoxy group-containing vinyl ester resin having epoxy groups and ethylenically unsaturated groups at predetermined proportions in one molecule, a ...

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10-03-2016 дата публикации

REACTION MIXTURE, POROUS PARTICLES AND METHODS OF MAKING

Номер: US20160068651A1
Принадлежит:

Porous polymeric particles are provided that can be hydrophilic or hydrophobic. The porous polymeric particles can be used for the storage and delivery of various active agents or for moisture management. Reaction mixtures for forming the porous polymeric particles, methods of making the porous polymeric particles, and articles containing the porous polymeric particles are also provided. 1. A reaction mixture comprising: [ {'br': None, 'sub': 2', '2', 'n, 'HO[—CH—CH(OH)—CH—O]—H\u2003\u2003(I)'}, 'i) a compound of Formula (I)'}, 'wherein n is an integer equal to at least 1; and', 'ii) a nonionic surfactant; and, 'a) a first phase comprising'} [ {'br': None, 'sub': 2', '2', '2', 'p', '2, 'sup': 1', '1, 'CH═C(R)—(CO)—O[—CH—CH—O]—(CO)—C(R)═CH\u2003\u2003(II)'}, 'i) a monomer composition comprising a monomer of Formula (II)'}, p is an integer equal to at least 1;', {'sup': '1', 'Ris hydrogen or alkyl; and'}], 'wherein'}, 'ii) a polypropylene glycol) having a weight average molecular weight of at least 500 grams/mole., 'b) a second phase dispersed in the first phase, wherein a volume of the first phase is greater than a volume of the second phase and wherein the second phase comprises'}2. The reaction mixture of claim 1 , wherein the monomer composition further comprises a second monomer having one (meth)acryloyl group.3. The reaction mixture of claim 2 , wherein the second monomer comprises a hydroxyl-containing monomer.4. The reaction mixture of claim 2 , wherein the second monomer comprises a sulfonyl-containing monomer.5. The reaction mixture of claim 2 , wherein the second monomer is of Formula (III){'br': None, 'sub': '2', 'sup': 1', '2, 'CH═CR—(CO)—O—Y—R\u2003\u2003(III)'} [{'sup': '1', 'Ris hydrogen or methyl;'}, 'Y is a single bond, alkylene, oxyalkylene, or poly(oxyalkylene); and', {'sup': '2', 'Ris a carbocyclic group or heterocyclic group.'}], 'wherein'}6. A method of making a polymeric particle claim 2 , the method comprising: [ {'br': None, 'sub': 2', '2', ' ...

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07-03-2019 дата публикации

Fine and Uniform Methyl Vinyl Ether-Maleic Acid Inorganic Salt Copolymers and Their Use in Oral Care and Pharmaceutical Applications

Номер: US20190071521A1
Принадлежит:

The invention relates to fine and uniform copolymer powders of partial mixed metal salts of lower alkyl vinyl ether-maleic acid copolymers having a defined particle size distribution. In particular; it relates to powders that are suitably used in the areas of oral care and pharmaceuticals and to methods for preparing the powders. Provided is a composition of powders of partial mixed metal salts of lower alkyl vinyl ether-maleic acid copolymers having: (i) a Dv50 of less than or equal to 25 microns; a Dv90 of less than or equal to 50 microns; and (ii) a particle uniformity reflected by a Dv90/Dv10 ratio of less than or equal to 10. 1. A composition of powders of partial mixed metal salts of lower alkyl vinyl ether-maleic acid copolymers having:(i) a median particle size by volume (Dv50) of less than or equal to 25 microns; a maximum particle diameter below which 90% of the sample volume exists (Dv90) of less than or equal to 50 microns; and(ii) a particle uniformity reflected by a ratio between the maximum particle diameter below which 90% of the sample volume exists and the maximum particle diameter below which 10% of the sample volume exists (Dv90/Dv10 ratio) of less than or equal to 10, preferably wherein the Dv90/Dv10 ratio is less than or equal to 6.2. The composition of claim 1 , having a Dv50 of less than 15 microns claim 1 , a Dv90 of less than 25 microns and a Dv90/Dv10 ratio of less than 6.3. The composition of claim 1 , in which the oversize fraction equal to or less than 1% by volume is not greater than 75 microns.4. The composition of claim 1 , wherein from about 10 to about 90 mole % of the carboxylic units in the polymer are converted to a mixture of metal salts.5. The composition of wherein the metal salt is selected from the group consisting of sodium claim 4 , calcium claim 4 , strontium claim 4 , zinc claim 4 , magnesium claim 4 , iron and potassium.6. The composition of claim 5 , wherein the partial mixed metal salts are sodium and calcium salts.7 ...

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07-03-2019 дата публикации

RESIN COMPOSITION, AND PRE-PREG, METAL-CLAD LAMINATE AND PRINTED CIRCUIT BOARD PREPARED USING THE SAME

Номер: US20190071548A1
Принадлежит:

A resin composition is provided. The resin composition comprises the following components: 3. The resin composition of claim 1 , wherein the epoxy resin is selected from the group consisting of novolac epoxy resins claim 1 , dicyclopentadiene (DCPD) epoxy resins claim 1 , bisphenol epoxy resins claim 1 , diphenylethylene epoxy resins claim 1 , triazine skeleton-containing epoxy resins claim 1 , fluorene skeleton-containing epoxy resins claim 1 , triphenol methane epoxy resins claim 1 , biphenyl epoxy resins claim 1 , xylylene epoxy resins claim 1 , biphenyl aralkyl epoxy resins claim 1 , naphthalene epoxy resins claim 1 , alicyclic epoxy resins claim 1 , and combinations thereof.4. The resin composition of claim 1 , wherein the cross-linking agent is selected from the group consisting of styrene maleic anhydride (SMA) resins claim 1 , cyanate ester resins claim 1 , benzoxazine resins claim 1 , phenolic novolac (PN) resins claim 1 , dicyandiamide (Dicy) claim 1 , diaminodiphenyl sulfone (DDS) claim 1 , amino triazine novolac (ATN) resins claim 1 , diaminodiphenylmethane claim 1 , styrene-vinyl phenol copolymers claim 1 , and combinations thereof.5. The resin composition of claim 1 , wherein the weight ratio of the bismaleimide resin represented by formula (I) to the resin represented by formula (II) is about 3:1 to about 1:3.6. The resin composition of claim 5 , wherein the weight ratio of the bismaleimide resin represented by formula (I) to the resin represented by formula (II) is about 2:1 to about 1:2.7. The resin composition of claim 1 , wherein based on the dry weight of the resin composition claim 1 , the amount of the bismaleimide resin represented by formula (I) is about 5 wt % to about 35 wt % claim 1 , and the amount of the resin represented by formula (II) is about 5 wt % to about 35 wt %.8. The resin composition of claim 1 , wherein based on the dry weight of the resin composition claim 1 , the amount of the epoxy resin is about 1 wt % to about 20 wt %.9. ...

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16-03-2017 дата публикации

Monoliths

Номер: US20170073492A1

The present invention relates to a monolith for processing fluid samples, and methods of making and using the monolith. The monolith can contain certain monomers or combinations of monomers that can be polymerized to give a polymeric monolith that can efficiently self-wick fluid. The self-wicking polymeric monolith can be used as a convenient tool for point of care/on site diagnostics and analytics. The monolith is easily stored and transported, comparatively cost-efficient to make, permits good detection of analyte molecules and is readily functionalizable by impregnation of and/or covalently grafting additional chemical moieties to either the whole monolith or in zones.

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16-03-2017 дата публикации

METHODS OF SELECTIVE CELL ATTACHMENT/DETACHMENT, CELL PATTERNIZATION AND CELL HARVESTING BY MEANS OF NEAR INFRARED RAYS

Номер: US20170073627A1
Принадлежит:

The present invention relates to a method for selective cell attachment/detachment, cell patternization and cell harvesting by means of near infrared rays. More particularly, conducting polymers or metal oxides having exothermic characteristics upon irradiation of near infrared light is used as a cell culture scaffold, thus selectively attaching/detaching cells without an enzyme treatment. The scaffold has an effect of promoting proliferation or differentiation of stem cells, and therefore, can be used as a stem cell culture scaffold. The scaffold enables cell attachment/detachment without temporal or spatial restrictions, thus enabling cell patternization. 2. The method of detaching cultured cells according to claim 1 , wherein the cell culture region is formed of any one of polycarbonate claim 1 , polypropylene claim 1 , polyethylene claim 1 , polystyrene claim 1 , polyurethane claim 1 , polyethylene terephthalate claim 1 , polyester claim 1 , polyimide claim 1 , polyethylene glycol claim 1 , polydimethylsiloxane claim 1 , and a copolymer or composite thereof; Nylon; paper; cotton; and glass.3. The method of detaching cultured cells according to claim 1 , wherein the polymer or copolymer has a weight average molecular weight of 1 claim 1 ,000 to 1 claim 1 ,000 claim 1 ,000 Da.4. The method of detaching cultured cells according to claim 1 , wherein the polymer or copolymer film has a thickness of 10 nm to 1 mm.5. The method of detaching cultured cells according to claim 1 , wherein the cells include adult stem cells derived from breasts claim 1 , bone marrow claim 1 , cord blood claim 1 , blood claim 1 , liver claim 1 , skin claim 1 , gastrointestine claim 1 , placenta claim 1 , or womb. This application is a continuation-in-part of co-pending U.S. application Ser. No. 14/342,451, filed Mar. 3, 2014.1. Field of the InventionThe present invention relates to methods for selectively detaching, patterning, and harvesting cells using near-infrared capable of being used ...

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05-03-2020 дата публикации

POLYMERISABLE LIQUID CRYSTAL MATERIAL AND POLYMERISED LIQUID CRYSTAL FILM

Номер: US20200071618A1
Принадлежит: Merck Patent GmBH

The invention relates to a polymerisable LC material comprising one or more direactive mesogenic compounds selected from the group of compounds of formula I, 5. Polymerisable LC material according to wherein the proportion of polymerizable mesogenic compounds of formula I is in the range from 5 to 40% by weight.6. Polymerisable LC material according to wherein the proportion of polymerizable mesogenic compounds of formula II is in the range from 5 to 30% by weight.7. Polymerisable LC material according to comprising one or more surfactants.8. Polymerisable LC material according to comprising one or more antioxidants.9. Polymerisable LC material according to comprising one or more photoinitiators.10. Polymerisable LC material according to comprising optionally one or more additives selected from the group consisting of , further stabilisers , catalysts , sensitizers , inhibitors , chain-transfer agents , co-reacting monomers , reactive thinners , surface-active compounds , lubricating agents , wetting agents , dispersing agents , hydrophobing agents , adhesive agents , flow improvers , degassing or defoaming agents , deaerators , diluents , reactive diluents , auxiliaries , colourants , dyes , pigments and nanoparticles.11. Process for the preparation of the polymerisable LC material according to comprising the step of mixing at least one direactive mesogenic compound of formula I , with at least one monoreactive mesogenic compound of formula II.12. Process for the preparation of the of a polymer film byproviding a layer of a polymerisable LC material according to onto a substrate,polymerising the polymerisable LC material, andoptionally removing the polymerised LC material from the substrateand/or optionally providing it onto another substrate.13. Polymer film obtainable from a polymerisable LC material according to by a process comprising the stepsproviding a layer of the polymerisable LC material onto a substrate,polymerising the LC material, andoptionally, ...

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24-03-2016 дата публикации

COMPOSITION FOR FIBER-REINFORCED COMPOSITE MATERIAL, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL

Номер: US20160083544A1
Принадлежит: Daicel Corporation

An object of the present invention is to provide a composition for a fiber-reinforced composite material, the composition being capable of forming the fiber-reinforced composite material excellent in work stability, high in curing speed and high in heat resistance, and particularly suitable for production of a continuous fiber-reinforced composite material by a pultrusion method. 1. A composition for a fiber-reinforced composite material , comprising: a radically polymerizable compound (A); a cationically polymerizable compound (B); a compound (C) having a radically polymerizable group and a cationically polymerizable group in one molecule thereof; a radical polymerization initiator (D); an acid generator (E); and a release agent (F) ,wherein the radically polymerizable compound (A) is a compound having not less than two radically polymerizable groups in one molecule thereof, and having a functional group equivalent weight of the radically polymerizable group of 50 to 300.2. The composition for a fiber-reinforced composite material according to claim 1 , wherein the cationically polymerizable compound (B) is at least one compound selected from the group consisting of epoxy compounds claim 1 , oxetane compounds and vinyl ether compounds.3. The composition for a fiber-reinforced composite material according to claim 1 , wherein the cationically polymerizable compound (B) is an alicyclic epoxy compound.4. The composition for a fiber-reinforced composite material according to claim 1 , wherein the cationically polymerizable compound (B) is a compound having not less than two cationically polymerizable groups in one molecule thereof claim 1 , and having a functional group equivalent weight of the cationically polymerizable groups of 50 to 300.5. The composition for a fiber-reinforced composite material according to claim 1 , wherein a proportion (weight ratio) [(A)/(B)] of the radically polymerizable compound (A) to the cationically polymerizable compound (B) is 30/70 to ...

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26-03-2015 дата публикации

PHOTOCURED PRODUCT

Номер: US20150086755A1
Принадлежит:

To provide a photocured product having small mold releasing force. A photocured product obtained by curing with light and containing a surface active agent, wherein a peak area of the ether bond derived peak is 3.0 times or more as large as a peak area of the ester bond derived peak, wherein the peak areas are obtained by peak separation processing by curve fitting of an X-ray photoelectron spectroscopy spectrum obtained as an analytical result on a chemical state of carbon at topmost surface of the photocured product, the analytical result being among analytical results on the topmost surface of the photocured product obtained by surface analysis of the photocured product with angle resolved X-ray photoelectron spectroscopy. 1. A photocured product obtained by curing with light , comprising a surface active agent ,wherein a peak area of an ether bond derived peak is at least 3.0 times large as a peak area of an ester bond derived peak, wherein the peak areas are obtained by peak separation processing by curve fitting of an X-ray photoelectron spectroscopy spectrum obtained as an analytical result of a chemical state of carbon at a topmost surface of the photocured product, the analytical result being among analytical results on the topmost surface of the photocured product obtained by a surface analysis of the photocured product with angle resolved X-ray photoelectron spectroscopy.2. The photocured product according to claim 1 , wherein the peak area of the ether bond derived peak is at least 4 times large as the peak area of the ester bond derived peak.3. The photocured product according to claim 1 , wherein the peak area of the ether bond derived peak is from 4 times to 20 times as large as the peak area of the ester bond derived peak.4. The photocured product according to claim 1 , wherein the surface active agent is a nonionic surface active agent.5. The photocured product according to claim 1 , wherein the surface active agent is a cationic surface active ...

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31-03-2022 дата публикации

BLACK RESIN COMPOSITION, CURED FILM, AND BLACK FILTER

Номер: US20220098398A1
Принадлежит: eChem Solutions Corp.

A black resin composition, a cured film, and a black filter are provided. The black resin composition includes: a black coloring agent (A), an ethylenically-unsaturated monomer (B), a solvent (C), a resin (D), a photoinitiator (E), a UV absorber (F), and a surfactant (G). The resin (D) includes a first resin having a weight-average molecular weight of 2,000 to 20,000. The first resin includes a structural unit having a fluorene ring and two or more ethylenically-polymerizable groups. The UV absorber (F) includes a benzylidene-based derivative. 1. A black resin composition , comprising:a black coloring agent (A);an ethylenically-unsaturated monomer (B);a solvent (C);a resin (D);a photoinitiator (E);a UV absorber (F); anda surfactant (G),wherein the resin (D) comprises a first resin having a weight-average molecular weight of 2,000 to 20,000, and the first resin comprises a structural unit having a fluorene ring and two or more ethylenically-polymerizable groups,the UV absorber (F) comprises a benzylidene-based derivative.3. The black resin composition of claim 1 , wherein the black coloring agent (A) comprises a carbon black (A-1) and a titanium black (A-2) claim 1 , and a particle size of the carbon black (A-1) and the titanium black (A-2) is less than 80 nm.4. The black resin composition of claim 1 , wherein the ethylenically-unsaturated monomer (B) is a monomer having four or more (meth)acryloyl groups.5. The black resin composition of claim 1 , wherein the solvent (C) comprises a propylene glycol-based ether solvent (C-1) claim 1 , and the propylene glycol-based ether solvent (C-1) is at least one selected from a group consisting of propylene glycol monomethyl ether claim 1 , propylene glycol monomethyl ether acetate claim 1 , dipropylene glycol monomethyl ether acetate claim 1 , propylene glycol monoethyl ether claim 1 , and propylene glycol monopropyl ether.6. The black resin composition of claim 1 , wherein the photoinitiator (E) comprises an oxime ester-based ...

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29-03-2018 дата публикации

3D PRINTING OF COMPOSITION-CONTROLLED COPOLYMERS

Номер: US20180086002A1
Автор: Lee Young, Sun Jirun
Принадлежит: ADA Foundation

A computer-controlled method for forming a composition-controlled product using 3D printing includes disposing two or more liquid reactant compositions in respective two or more reservoirs; and mixing the two or more liquid reactant compositions, which in turn includes controlling by the computer a mass ratio of the mixed two or more liquid reactant compositions. The computer-controlled method further includes scanning, under control of the computer, a mixed liquid reactants nozzle over a substrate; depositing the mixed liquid reactant compositions onto the substrate; and operating, under control of the computer, a light source to polymerize the deposited mixed liquid reactant compositions. 1. A computer-controlled method for forming a composition-controlled product using 3D printing , comprising:disposing two or more liquid reactant compositions in respective two or more reservoirs;mixing the two or more liquid reactant compositions, comprising controlling by the computer a mass ratio of the mixed two or more liquid reactant compositions;scanning, under control of the computer, a mixed liquid reactants nozzle over a substrate;depositing the mixed liquid reactant compositions onto the substrate; andoperating, under control of the computer, a light source to polymerize the deposited mixed liquid reactant compositions.2. The method of claim 1 , wherein the liquid reactant compositions in the reservoirs comprise reactant(s) claim 1 , initiators claim 1 , porogenic particles claim 1 , reinforcing particles claim 1 , solvent(s) claim 1 , and combinations thereof.3. The composition of matter in claim 2 , wherein the reactants are chosen from a group consisting of monomers or monomer mixtures that form composition controlled copolymers at different degrees of monomer to polymer conversion.4. The composition of matter in claim 2 , wherein the initiators are chosen from a group consisting of initiators for free-radical polymerization claim 2 , cationic polymerization or ...

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28-03-2019 дата публикации

SYNTHETIC POLYMER FILM WHOSE SURFACE HAS MICROBICIDAL ACTIVITY, PHOTOCURABLE RESIN COMPOSITION, MANUFACTURING METHOD OF SYNTHETIC POLYMER FILM, AND STERILIZATION METHOD WITH USE OF SURFACE OF SYNTHETIC POLYMER FILM

Номер: US20190092883A1
Принадлежит:

A synthetic polymer film is a synthetic polymer film whose surface has a plurality of raised or recessed portions. The synthetic polymer film has a crosslink structure, and the crosslink structure does not contain any nitrogen element that is a constituent of a urethane bond. The synthetic polymer film contains an organic carboxylic acid, and an amount of water required for dissolving 1 g of the organic carboxylic acid is equal to or greater than 10 mL and less than 10000 mL. At the lapse of 5 minutes since placing a 200 μL drop of water on the surface of the synthetic polymer film, a pH of an aqueous solution is not more than 5, and an area equivalent circle diameter of the aqueous solution is not less than 20 mm. A synthetic polymer film whose surface has a microbicidal activity can be produced using a photocurable resin composition which contains an organic carboxylic acid or a photoacid generator which generates the organic carboxylic acid. 1. A synthetic polymer film whose surface has a plurality of raised or recessed portions ,wherein the synthetic polymer film has a crosslink structure, and the crosslink structure does not contain any nitrogen element that is a constituent of a urethane bond,the synthetic polymer film contains an organic carboxylic acid, and an amount of water required for dissolving 1 g of the organic carboxylic acid is equal to or greater than 10 mL and less than 10000 mL, andat the lapse of 5 minutes since placing a 200 μL drop of water on the surface of the synthetic polymer film, a pH of an aqueous solution is not more than 5, and an area equivalent circle diameter of the aqueous solution is not less than 20 mm.2. The synthetic polymer film of claim 1 , wherein when viewed in a normal direction of the synthetic polymer film claim 1 , a two-dimensional size of the plurality of raised or recessed portions is in the range of more than 20 nm and not more than 1 μm.3. The synthetic polymer film of claim 2 , wherein when viewed in the normal ...

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13-04-2017 дата публикации

Optical film having excellent water resistance and solvent resistance, and polarization plate comprising same

Номер: US20170101517A1
Принадлежит: LG Chem Ltd

Disclosed are an optical film, including: a transparent film, and a coating layer on at least one surface of the transparent film, in which the coating layer is formed using a composition including a polymer resin, a dihydrazide-based crosslinking agent, and water-dispersible fine particles, and a polarizing plate including the same.

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02-06-2022 дата публикации

ANTI-CURLING FILM

Номер: US20220169808A1

An anti-curling film is provided. The anti-curling film includes a first portion and a second portion covering the first portion. The first portion includes polylactic acid (PLA), polycaprolactone (PCL), polyethylene glycol dimethacrylate (PEGDMA) and a photoinitiator. The second portion includes polycaprolactone (PCL), gelatin, hyaluronic acid (HA), alginate (AA), polyvinyl alcohol (PVA) or a combination thereof. 1. An anti-curling film , comprising:a first portion comprising polylactic acid (PLA), polycaprolactone (PCL), polyethylene glycol dimethacrylate (PEGDMA) and a photoinitiator; anda second portion covering the first portion, wherein the second portion comprises polycaprolactone (PCL), gelatin, hyaluronic acid (HA), alginate (AA), polyvinyl alcohol (PVA) or a combination thereof.2. The anti-curling film as claimed in claim 1 , wherein polyethylene glycol dimethacrylate (PEGDMA) has a grafting rate which is between 65% and 72%.3. The anti-curling film as claimed in claim 1 , wherein polylactic acid (PLA) claim 1 , polycaprolactone (PCL) and polyethylene glycol dimethacrylate (PEGDMA) have a weight ratio which is between 0.5:1:1 and 0.5:1:6.4. The anti-curling film as claimed in claim 1 , wherein the first portion comprises a first layer and a second layer.5. The anti-curling film as claimed in claim 4 , wherein the first layer comprises polycaprolactone (PCL) and polyethylene glycol dimethacrylate (PEGDMA) claim 4 , and polycaprolactone (PCL) and polyethylene glycol dimethacrylate (PEGDMA) have a weight ratio which is between 1:6 and 1:12.6. The anti-curling film as claimed in claim 4 , wherein the second layer comprises polyethylene glycol dimethacrylate (PEGDMA) and polylactic acid (PLA) claim 4 , and polyethylene glycol dimethacrylate (PEGDMA) and polylactic acid (PLA) have a weight ratio which is between 1:1 and 3:1.7. The anti-curling film as claimed in claim 1 , wherein polyethylene glycol dimethacrylate (PEGDMA) claim 1 , polylactic acid (PLA) and the ...

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02-06-2022 дата публикации

LIQUID COMPOSITION SET, POROUS RESIN MANUFACTURING APPARATUS, AND POROUS RESIN MANUFACTURING METHOD

Номер: US20220169821A1
Принадлежит: RICOH COMPANY, LTD.

A liquid composition set is provided. The liquid composition set comprises: a liquid composition X comprising a polymerizable compound X and a solvent X; and a liquid composition Y comprising a solvent Y. The liquid composition X is to form a porous resin, and has a smaller surface tension than the liquid composition Y. 1. A liquid composition set comprising:a liquid composition X comprising a polymerizable compound X and a solvent X; anda liquid composition Y comprising a solvent Y,wherein the liquid composition X is to form a porous resin, andwherein the liquid composition X has a smaller surface tension than the liquid composition Y.2. The liquid composition set according to claim 1 ,wherein the liquid composition X has a light transmittance of 30% or more at a wavelength of 550 nm, the light transmittance measured while the liquid composition X is being stirred, andwherein a haze measuring element produced from the liquid composition X has a haze increasing rate of 1.0% or more.3. The liquid composition set according to claim 1 , wherein the polymerizable compound X has two or more unsaturated hydrocarbon groups.4. The liquid composition set according to claim 1 , wherein the polymerizable compound X has a (meth)acryloyl group or a vinyl group.5. The liquid composition set according to claim 1 , wherein the solvent X and the solvent Y each independently have a boiling point of from 50° C. to 250° C.6. The liquid composition set according to claim 1 , wherein the polymerizable compound X accounts for 10.0% to 50.0% by mass of the liquid composition X claim 1 , and the solvent X accounts for 50.0% to 90.0% by mass of the liquid composition X.7. The liquid composition set according to claim 1 , wherein the liquid composition X and the liquid composition Y each independently have a viscosity of from 1.0 to 150.0 mPa·s at 25° C.8. The liquid composition set according to claim 1 , wherein the liquid composition Y is substantially free of polymerizable compound.9. The ...

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21-04-2016 дата публикации

TRIPHENYL MONOMERS SUITABLE FOR MICROSTRUCTURED OPTICAL FILMS

Номер: US20160109618A1
Принадлежит:

Optical films are described having a polymerized microstructured surface that comprises the reaction product of a polymerizable resin composition comprising at least one polymerizable ethylenically unsaturated triphenyl monomer. Also described are certain triphenyl (meth)acrylate monomers and polymerizable resin compositions. 2. The optical film of wherein p is 0.4. The optical film of wherein Q is O.5. The optical film of wherein L is Cor Cand n is 1.6. The optical film of wherein the triphenyl monomer is a di(meth)acrylate.7. The optical film of to wherein the triphenyl monomer is a tri(meth)acrylate.8. The optical film of wherein the polymerizable resin composition comprises up to 50 wt-% of one or more triphenyl (meth)acrylate monomers; and25 wt-% to 75 wt-% of one or more multi(meth)acrylate monomers or oligomers having at least two polymerizable (meth)acrylate groups.9. The optical film of wherein the multi(meth)acrylate monomer comprises one or more bisphenol A (meth)acrylates claim 1 , aromatic epoxy (meth)acrylates claim 1 , and mixtures thereof.10. The optical film of wherein the polymerizable resin composition comprises less than 1 wt-% total of chlorine claim 1 , bromine claim 1 , or mixtures thereof.11. The optical film of wherein the polymerizable resin composition comprises less than 1 wt-% total of chlorine claim 1 , bromine claim 1 , fluorine and iodine.12. The optical film of wherein the polymerizable resin is free of inorganic nanoparticles.13. The optical film of wherein the polymerizable resin comprises at least 10 wt-% of surface modified inorganic nanoparticles.14. The optical film of wherein the inorganic nanoparticles have a refractive index of at least 1.68.15. The optical film of wherein the inorganic nanoparticles comprise zirconia.16. The optical film of wherein the optical film is a brightness enhancing film having a single sheet gain of at least 1.59. Certain microstructured optical products, such as described in U.S. Pat. Nos. 5,175, ...

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09-06-2022 дата публикации

Multilayer phase difference plate, polarizing plate, and image display device

Номер: US20220177419A1
Принадлежит: Zeon Corp

A phase difference plate includes a phase difference plate P1 and a phase difference plate P2. An in-plane slow axis of the phase difference plate P1 is orthogonal to an in-plane slow axis of the phase difference plate P2. The phase difference plate P2 includes a layer of a liquid crystal material oriented in an in-plane direction. An in-plane retardation ReP2(λ) at a wavelength λ nm of the phase difference plate P2 satisfies the following formulae (e1) and (e2): {Re2(400)−Re2(550)}/{Re2(550)−Re2(700)}<2.90 (e1), and Re2(400)/Re2(700)>1.13 (e2). An in-plane retardation ReP1(λ) of the phase difference plate P1 at a wavelength λ nm and the in-plane retardation ReP2(λ) of the phase difference plate P2 at the wavelength λ nm satisfy the following formulae (e4) and (e5): ReP1(550)>ReP2(550) (e4), and ReP1(400)/ReP1(700)<ReP2(400)/ReP2(700) (e5).

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09-04-2020 дата публикации

COMPOSITION, CURED PRODUCT AND LAMINATE

Номер: US20200109276A1
Принадлежит:

An object of the invention is to provide a composition having excellent heat resistance and excellent adhesiveness. Moreover, another object is to provide a cured product obtained by curing the composition and a laminate containing the cured product. Furthermore, another object is to provide a heat-resistant material, a heat-resistant member, an electronic material and an electronic member each containing the composition. The objects are achieved by providing a composition including: a (meth)allyl group-containing maleimide compound having a structure having one or more benzene rings, one or more groups having a (meth)allyl group and one or more groups having a maleimide group; and a hydroxy group-containing maleimide compound having a structure having one or more benzene rings, one or more groups having a hydroxy group and one or more maleimide groups. 3. The composition according to claim 1 , wherein in general formula (4) above claim 1 , Ais a benzene ring structure claim 1 , and nand mare both 1.4. The composition according to claim 1 , further comprising an epoxy compound.5. The composition according to claim 1 , further comprising a filler.6. The composition according to claim 1 , further comprising a fibrous substrate.7. A cured product comprising a product obtained by curing the composition according to .817-. (canceled)19. A method for producing a composition comprising a (meth)allyl group-containing compound and a hydroxy group-containing maleimide compound claim 1 , the method comprising:a step of producing a mixture solution by mixing a (meth)allyl group-containing maleimide compound represented by formula (1) above, a hydroxy group-containing maleimide compound represented by formula (4) above and a solvent, and a step of removing the solvent from the obtained mixture solution.20. A cured product comprising a product obtained by curing the composition according to .21. A cured product comprising a product obtained by curing the composition according to ...

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07-05-2015 дата публикации

HYDROPHILIC MODIFIED ACRYLIC RESIN FILM

Номер: US20150126682A1
Автор: OKAZAKI Koju
Принадлежит:

[Problem] 1. A modified acrylic resin film obtained by treating a surface of an acrylic resin film having anionic hydrophilic groups with a compound (A) , the acrylic resin film being such that the concentration of the anionic hydrophilic groups on the surface is higher than the concentration of the anionic hydrophilic groups at a depth half the film thickness from the surface of the acrylic resin film , the compound (A) having in the molecule thereof one or more anionic hydrophilic groups and one or more groups selected from groups having a polymerizable carbon-carbon double bond , amino groups , mercapto groups and hydroxyl groups.2. The modified acrylic resin film according to claim 1 , wherein the treatment is graft treatment.5. A stack comprising a substrate and the modified acrylic resin film described in .6. A method for producing modified acrylic resin films claim 1 , comprising treating a surface of an acrylic resin film having anionic hydrophilic groups with a compound (A) claim 1 , the acrylic resin film being such that the concentration of the anionic hydrophilic groups on the surface is higher than the concentration of the anionic hydrophilic groups at a depth half the film thickness from the surface of the acrylic resin film claim 1 , the compound (A) having in the molecule thereof one or more anionic hydrophilic groups and one or more groups selected from groups having a polymerizable carbon-carbon double bond claim 1 , amino groups claim 1 , mercapto groups and hydroxyl groups.7. The method for producing modified acrylic resin films according to claim 6 , comprising a step of forming the acrylic resin film on a substrate.8. The method for producing modified acrylic resin films according to claim 7 , wherein the acrylic resin film is such that the concentration of the anionic hydrophilic groups on the side of the surface opposite to the side adjacent to the substrate is higher than the concentration of the anionic hydrophilic groups at a depth half ...

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16-04-2020 дата публикации

LIQUID CRYSTAL ELASTOMERS

Номер: US20200115483A1

Shape-programmable liquid crystal elastomers. The shape-programmable liquid crystal elastomers being synthesized by filling an alignment cell with liquid crystal monomers. The liquid crystal monomers align to a surface of the alignment cell and then are polymerized with a dithiol chain transfer agent. The alignment cell is configured to impose a director orientation on a portion of the shape-programmable liquid crystal elastomer. For some embodiments, liquid crystal elastomer laminates are prepared by arranging a plurality of liquid crystal elastomers such that a director orientation of each liquid crystal elastomer of the plurality is in registered alignment with an adjacent liquid crystal elastomer of the plurality. The arrangement is secured and the plurality of liquid crystal elastomers cured. 1. A method of synthesizing a shape-programmable liquid crystal elastomer , the method comprising:filling an alignment cell with liquid crystal monomers, wherein the liquid crystal monomers align to a surface of the alignment cell; andpolymerizing the liquid crystal monomers with a dithiol chain transfer agent,wherein the alignment cell is configured to impose a director orientation on a portion of the shape-programmable liquid crystal elastomer.2. The method of claim 1 , wherein the liquid crystal monomers are mesogenic diacrylates.3. The method of claim 2 , wherein the mesogenic diacrylate is selected from C3M claim 2 , C6M claim 2 , and C11M.4. The method of claim 1 , wherein the dithiol chain transfer agent is a C2-C6 alkyl-dithiol.5. The method of claim 4 , wherein the dithiol chain transfer agent is selected from ethane dithiol claim 4 , propane dithiol claim 4 , hexane dithiol claim 4 , and 1 claim 4 ,4-benezenedimethanethiol.6. The method of claim 1 , wherein an amount of thiol incorporated into the liquid crystal elastomer ranges from about 30% to about 50%.7. The method of claim 1 , wherein the liquid crystal monomers comprise a mixture of a first mesogenic ...

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14-05-2015 дата публикации

AQUEOUS GEL

Номер: US20150133566A1
Принадлежит:

An aqueous gel that is prepared by gelling a polymer components, the polymer components containing polymer A, which is obtained by polymerizing a monomer component containing a betaine monomer represented by the formula (I): 2. The aqueous gel according to claim 1 , wherein the betaine monomer represented by the formula (I) claim 1 , Ris hydrogen atom or an alkyl group having 1 to 6 carbon atoms which may have hydroxyl group or a halogen atom; Ris —COO-group or —CONH-group; each of Rand Ris methyl group claim 1 , respectively; and Ris methylene group.3. The aqueous gel according to claim 1 , wherein the molar ratio of the functional group of the polymer A to the functional group of the polymer B is 0.5/1 to 1.5/1.4. A medical material in which the aqueous gel according to is used.5. A cosmetic composition in which the aqueous gel according to is used.6. A toiletry article in which the aqueous gel according to is used.7. A coating material in which the aqueous gel according to is used.8. An electric or electronic material in which the aqueous gel according to is used.9. A process for producing an aqueous gel claim 1 , which comprises carrying out a solution polymerization of an aqueous solution of a monomer composition comprising an acidic monomer to give polymer B claim 1 , mixing the resulting polymer B with an aqueous solution of a monomer composition comprising a betaine monomer to form a homogeneous mixture claim 1 , and carrying out a solution polymerization of the resulting mixture to prepare a polymer A; or carrying out a solution-polymerization of an aqueous solution of a monomer composition comprising a betaine monomer to give a polymer A claim 1 , mixing the resulting polymer A with a monomer composition comprising an acidic monomer to form a homogeneous mixture claim 1 , and carrying out the solution-polymerization of the resulting mixture to prepare a polymer B. The present invention relates to an aqueous gel. More specifically, the present invention ...

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10-05-2018 дата публикации

WATER-BASED SEALING COMPOSITIONS WITH AMINOSILANE CROSSLINKERS

Номер: US20180127557A1
Принадлежит:

Treating a subterranean formation with a composition including a maleic anhydride copolymer and an aminosilane crosslinker. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV: 3. The composition of claim 1 , wherein the aminosilane crosslinker is an aminoalkoxysilane.4. The composition of claim 3 , wherein the aminoalkoxysilane is an aminotrialkoxysilane.5. The composition of claim 3 , wherein the aminosilane crosslinker has 0 claim 3 , 1 claim 3 , or 2 secondary amine groups.6. The composition of claim 3 , wherein the aminosilane crosslinker is 3-aminopropyl-triethoxysilane.7. The composition of claim 3 , wherein the aminosilane crosslinker is 2-aminoethyl-3-aminopropyltrimethoxysilane.8. The composition of claim 3 , wherein the aminosilane crosslinker is N-(3-trimethoxysilylpropyl)diethylenetriamine.9. The composition of claim 1 , wherein the aminosilane crosslinker is 0.5% to 10% by weight of the composition.10. The composition of claim 1 , comprising a polyamine crosslinker claim 1 , wherein the polyamine crosslinker has at least two primary amine groups.11. The composition of claim 1 , comprising a gelling agent claim 1 , wherein the gelling agent comprises at least one of:a calcium chelating agent;a calcium precipitating agent;a pH buffer;an agent reactive with hydroxide; andan acid generating agent,wherein the gelling agent promotes formation of a gel comprising the maleic anhydride copolymer and the aminosilane crosslinker in contact with set cement.12. The composition of claim 1 , comprising a gel time control agent claim 1 , wherein the gel time control agent comprises at least one of:a salt that yields a basic solution when dissolved in water;a salt that yields an acidic solution when dissolved in water;an uncharged organic molecule that yields a basic solution when dissolved in water;an uncharged organic molecule that yields an acidic solution when dissolved in water; anda pH buffer, ...

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01-09-2022 дата публикации

Transparent resin multilayer body, and transparent substrate material and transparent protective material each using same

Номер: US20220274384A1
Автор: Masaki Hirabayashi

A resin layered body includes a polycarbonate-based resin (A); a thermoplastic resin (B) on at least one surface of the polycarbonate-based resin (A); and a hard coating layer on a surface of the thermoplastic resin (B) on at least one side, wherein the polycarbonate-based resin (A) has a glass-transition temperature from 115° C.-140° C., the thermoplastic resin (B) includes a methacrylic resin (C) and a styrene copolymer (D), a content of the methacrylic resin (C) is from 5-70 parts by mass and a content of the styrene copolymer (D) is from 95-30 parts by mass based on 100 parts by mass of a total content of the methacrylic resin (C) and the styrene copolymer (D), and the styrene copolymer (D) includes a vinyl aromatic monomer unit (d1) in an amount of from 68-84 mass % and a cyclic acid anhydride monomer unit (d2) in an amount of from 16-32 mass %.

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02-05-2019 дата публикации

SYNTHESIS OF SUPERHYDROPHOBIC MICROPOROUS SURFACES VIA LIGHT-DIRECTED PHTOPOLYMERIZATION AND PHASE SEPARATION

Номер: US20190127548A1
Автор: Hosein Ian D.
Принадлежит: SYRACUSE UNIVERSITY

The formation of microporous surfaces through polymer induced phase separation in a photopolymer solvent mixture using photopolymerization via light self-focusing and self-trapping. The self-trapping of light sets fixed regions of brightness and darkness, sustained by the polymerization of light, and then wave guiding within the substrate. Phase separation occurs with the solvent phase separating in the regions of darkness and crosslinking in the regions of brightness. Upon removal of the solvent, precise and uniformly dispersed pores are created in the surface. The pore size and spacing may be tuned by adjusting the weight fraction of the photopolymer solvent mixture as well as through changes in the mask pattern. 1. A method of fabricating a porous surface , comprising the steps of:providing a mixture including a monomer and a solvent;positioning a mask having a predetermined series of chrome regions over the mixture to define a series of dark regions that correspond to the series of chrome regions in the mask and an irradiated region;irradiating the mixture through the mask so that the monomer is polymerized into a polymer in the irradiated portions and the solvent phase separates out of the irradiated region of the mixture into the series of dark regions; andremoving the monomer and the solvent in the dark regions to define a polymer substrate having a surface defining a series of pores.2. The method of claim 1 , further comprising the step of spray coating the polymer surface with a plurality of nanoparticles.3. The method of claim 2 , wherein the nanoparticles comprise polytetrafluoroethylene (PTFE).4. The method of claim 1 , wherein the step of irradiating the mixture comprises irradiating with light having a wavelength of 470 nm.5. The method of claim 4 , wherein the step of irradiating the mixture comprises irradiating with light at an exposure intensity between 2 and 20 mW/cm2.6. The method of claim 1 , wherein the monomer comprises trimethylolpropane ...

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03-06-2021 дата публикации

GEL COMPOSITIONS, SHAPED GEL ARTICLES AND A METHOD OF MAKING A SINTERED ARTICLE

Номер: US20210163362A1
Принадлежит:

Reaction mixtures, gel compositions that are a polymerized product of the reaction mixtures, shaped gel articles that are formed within a mold cavity and that retain the size and shape of the mold cavity upon removal from the mold cavity, and sintered articles prepared from the shaped gel articles are provided. The sintered article has a shape identical to the mold cavity (except in regions where the mold cavity was overfilled) and to the shaped articles but reduced in size proportional to the amount of isotropic shrinkage. Methods of forming the sintered articles also are provided. 1. A method of making a sintered article , the method comprising:providing a mold having a mold cavity;positioning a reaction mixture within the mold cavity, the reaction mixture comprising:{'sub': '2', 'a. 20 to 60 weight percent zirconia-based particles based on a total weight of the reaction mixture, the zirconia-based particles having an average particle size no greater than 100 nanometers and comprising at least 70 mole percent ZrO;'}b. 30 to 75 weight percent of a solvent medium based on the total weight of the reaction mixture, the solvent medium comprising at least 60 percent of an organic solvent having a boiling point equal to at least 150° C.;c. 2 to 30 weight percent polymerizable material based on a total weight of the reaction mixture, the polymerizable material comprising (1) a first surface modification agent having a free radical polymerizable group and a surface modifying group, the first surface modification agent being a first monomer; andd. a photoinitiator for a free radical polymerization reaction;polymerizing the reaction mixture to form a shaped gel article that is in contact with the mold cavity;removing the shaped gel article from the mold cavity, wherein the shaped gel article retains a size and shape identical to the mold cavity (except in regions where the mold cavity was overfilled);forming a dried shaped gel article by removing the solvent medium; ...

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18-05-2017 дата публикации

Particulate water-absorbing agent and method for producing the same

Номер: US20170136441A1
Принадлежит: NIPPON SHOKUBAI CO LTD

It is an object to provide a particulate water-absorbing agent having a high fluid retention capacity under pressure and reduced moisture absorption blocking properties, and a method for producing the same. A particulate water-absorbing agent including a water-insoluble metal phosphate including an anion of a phosphoric acid compound and a divalent or trivalent metal cation, the water-insoluble metal phosphate having a crystallite size of less than 0.15 mm, wherein the particulate water-absorbing agent has a fluid retention capacity under pressure of 2.06 kpa of 20 g/g or more.

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18-05-2017 дата публикации

FLEXIBLE TO RIGID NANOPOROUS POLYURETHANE-ACRYLATE (PUAC) TYPE MATERIALS FOR STRUCTURAL AND THERMAL INSULATION APPLICATIONS

Номер: US20170137376A1
Принадлежит:

Novel urethane-acrylate (UAC) Star monomers and polyurethane-acrylate (PUAC) aerogel polymers derived therefrom are described herein, along with other novel, related monomers and polymers. Also described herein are processes for preparing the UAC Star monomers, the PUAC aerogel polymers, and the other related monomers and polymers. The PUAC and related polymers herein are useful in various applications including in structural and thermal insulation. 132.-. (canceled)35. The process of claim 34 , wherein the organic solvent is selected from the group consisting of benzene claim 34 , toluene claim 34 , and xylene claim 34 , and combinations thereof.37. A process for preparing the norbornene-containing star monomer of claim 36 , the process comprising the step of mixing a tris(isocyanatophenyl)methane of formula (III) with three molar equivalents of the norbornene-containing hydroxyl compound of formula (IX) in an organic solvent.38. The process of claim 37 , further comprising the addition of a catalyst.39. The process of claim 38 , wherein the catalyst is an organotin compound.40. The process of claim 39 , wherein the organotin compound is dibutyltin dilaurate.41. The process of wherein the organic solvent is selected from the group consisting of a ketone solvent claim 37 , an ester solvent claim 37 , and a combination thereof.42. The process of claim 41 , wherein the organic solvent is acetone claim 41 , ethyl acetate claim 41 , or a combination thereof.46. The polynorbornene-polyurethane polymer of or claim 41 , wherein the polymerization is ring-opening metathesis polymerization.4748.-. (canceled)49. The norbornene-containing hydroxyl compound of claim 33 , wherein R1=R2=R3=H claim 33 , W=CHCH claim 33 , and m=1.50. The norbornene-containing star monomer of claim 36 , wherein claim 36 , in the norbornene-containing hydroxyl compound of formula (IX) claim 36 , R1=R2=R3=H claim 36 , W=CHCH claim 36 , and m=1; and claim 36 , wherein claim 36 , in the tris( ...

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26-05-2016 дата публикации

Monoliths

Номер: US20160146714A1

Described herein are monoliths for processing fluid samples, and methods of making and using such monoliths.

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25-05-2017 дата публикации

Methods of Generating Microparticles and Porous Hydrogels Using Microfluidics

Номер: US20170145169A1
Принадлежит:

Provided herein are methods utilizing microfluidics for the oxygen-controlled generation of microparticles and hydrogels having controlled microparticle sizes and size distributions and products from provided methods. The included methods provide the generation of microparticles by polymerizing an aqueous solution dispersed in a non-aqueous continuous phase in an oxygen-controlled environment. The process allows for control of size of the size of the aqueous droplets and, thus, control of the size of the generated microparticles which may be used in biological applications. 1. A method of preparing a plurality of microparticles in a microfluidics device in an oxygen-controlled environment comprising the steps of:(a) providing a continuous phase comprising a non-aqueous liquid and a dispersed phase comprising an aqueous solution comprising a monomer or a macromer, and an initiator;(b) forming a composition comprising microdroplets of said aqueous phase and said non-aqueous liquid;(c) purging said composition comprising said microdroplets and the non-aqueous liquid with an oxygen-free gas; and(d) polymerizing said monomer or said macromer in said microdroplets to form microparticles.2. The method of claim 1 , wherein said oxygen-free gas is nitrogen.3. The method of claim 1 , wherein said oxygen-free gas is provided at a pressure selected from the range of 0.1 atm to 10 atm.45-. (canceled)65. The method of claim claim 1 , where said initiator is a photoinitiator and said step of polymerizing said monomer or macromer is carried out in the presence of ultraviolet light.7. The method of claim 6 , wherein said photoinitiator is lithium phenyl-2 claim 6 ,4 claim 6 ,6-trimethylbenzoylphosphinate (LAP) or Irgacure 1173.8. (canceled)9. The method of claim 1 , wherein said non-aqueous liquid comprises a fluorocarbon oil.10. The method of claim 9 , wherein said fluorocarbon oil is a segregated hydrofluoroether.11. (canceled)12. The method of claim 1 , wherein said non-aqueous ...

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31-05-2018 дата публикации

Transparent Laminate

Номер: US20180148578A1
Принадлежит:

A transparent laminate including a transparent substrate and structure layer, wherein the structure layer contains protrusion portions, depression portions, or both on a surface thereof, and an average distance between the adjacent protrusion portions or between the adjacent depression portions is equal to or less than a visible light wavelength, the structure layer includes a polymerized product of an active energy ray curable resin composition, the resin composition includes a composition of a (meth)acryloyl group-containing polymerizable compound, the compound composition includes one or more from each of (A), (B), and (C): 1. A transparent laminate comprising:a transparent substrate; anda structure layer,wherein the structure layer contains protrusion portions, depression portions, or both on a surface of the structure layer, and an average distance between the adjacent protrusion portions or an average distance between the adjacent depression portions is equal to or less than a wavelength of visible light,the structure layer includes a polymerized product of an active energy ray curable resin composition,the active energy ray curable resin composition includes a composition of a (meth)acryloyl group-containing polymerizable compound, (A) a monofunctional (meth)acryloyl group-containing polymerizable compound;', '(B) alkylene glycol di(meth)acrylate; and', '(C) trifunctional or higher (meth)acrylate,, 'the composition of a (meth)acryloyl group-containing polymerizable compound includes one or more of (A) below, one or more of (B) below, and one or more of (C) below (A-1) a nitrogen-containing monofunctional (meth)acryloyl group-containing polymerizable compound that includes nitrogen in a structure thereof is included but a nitrogen-free monofunetional (meth)acryloyl group-containing polymerizable compound that does not include nitrogen in a structure thereof is not included, and an amount of the nitrogen-containing monofunctional (meth)acryloyl group-containing ...

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11-06-2015 дата публикации

Polyesters and articles made therefrom

Номер: US20150158973A9
Принадлежит: EI Du Pont de Nemours and Co

Disclosed herein are polyesters and articles made therefrom. The article comprising a substrate comprising a first surface and a second surface, the second surface in contact with an outside environment, wherein the substrate comprises a polymer comprising poly(trimethylene furandicarboxylate) (PTF), and wherein the polymer provides an improvement in gas barrier properties of the substrate as compared to a substrate comprising nascent polyethylene terephthalate) (PET).

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01-06-2017 дата публикации

FUNCTIONAL POLYMER MEMBRANE, PRODUCTION METHOD THEREOF, AND STACK OR DEVICE PROVIDED WITH FUNCTIONAL POLYMER MEMBRANE

Номер: US20170152361A1
Принадлежит: FUJIFILM Corporation

Provided are a functional polymer membrane including: a surface layer; and an anion exchange membrane or a cation exchange membrane, in which the surface layer contains a polymer which includes a cross-linked structure having, in a cross-linking unit, an ionic group with a charge opposite to a charge of an ionic group included in at least one of the anion exchange membrane or the cation exchange membrane; a production method thereof, and a stack or a device provided with a polymer functional membrane. 2. The functional polymer membrane according to claim 1 ,wherein the surface layer is formed by photopolymerization.3. The functional polymer membrane according to claim 1 ,wherein the thickness of the surface layer is 50% or less of the thickness of the anion exchange membrane or the cation exchange membrane.4. The functional polymer membrane according to claim 3 ,wherein the thickness of the surface layer is 20% or less of the thickness of the anion exchange membrane or the cation exchange membrane.5. The functional polymer membrane according to claim 4 ,wherein the thickness of the surface layer is 10% or less of the thickness of the anion exchange membrane or the cation exchange membrane.6. A stack comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the functional polymer membrane according to .'}7. A device comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the functional polymer membrane according to .'} This application is a Continuation of PCT International Application No. PCT/JP2015/070807 filed on Jul. 22, 2015, which claims priority under 35 U.S.C. §119(a) to Japanese Patent Application No. 2014-165309, filed on Aug. 14, 2014, and Japanese Patent Application No. 2015-119497, filed on Jun. 12, 2015. Each of the above applications is hereby expressly incorporated by reference, in its entirety, into the present application.1. Field of the InventionThe present invention relates to a functional polymer membrane, a production method thereof, ...

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07-05-2020 дата публикации

BIOCHEMICAL CARRIERS CAPABLE OF STORAGE, PRESERVATION AND INDEXING AND METHOD FOR FABRICATING THE SAME

Номер: US20200143909A1
Принадлежит:

Biochemical carriers are provided. Each of the biochemical carriers includes: biochemical molecules having a sequence into which digital data information is encoded; a carrier particle composed of a polymer matrix and in which the biochemical molecules are connected to the surface or inside of the polymer matrix; and an index code introduced into the carrier particle. Also provided is a method for fabricating biochemical carriers. The fabrication method includes: encoding digital data into a sequence of biochemical molecules; synthesizing the biochemical molecules based on the encoded sequence; mixing the biochemical molecules with a photocurable material; curing the mixture to obtain carrier particles including a polymer matrix; and introducing an index code into the carrier particles simultaneously with or separately from the curing. Also provided is a method for restoring digital data from the biochemical carrier. The restoration method includes: analyzing the index code of the biochemical carrier; reacquiring the biochemical molecules from the biochemical carrier based on the analytical results of the index code; sequencing the biochemical molecules; and decoding the sequencing results to restore digital data. 1. A biochemical carrier comprising: biochemical molecules having a sequence into which digital data information is encoded; a carrier particle composed of a polymer matrix and in which the biochemical molecules are connected to the surface or inside of the polymer matrix; and an index code introduced into the carrier particle.2. The biochemical carrier according to claim 1 , wherein the polymer matrix is composed of a photocurable polymer.3. The biochemical carrier according to claim 1 , wherein the polymer matrix is porous.4. The biochemical carrier according to claim 1 , wherein the biochemical molecules have functional groups that are chemically connected to the chains of the polymer matrix.5. The biochemical carrier according to claim 1 , further ...

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07-05-2020 дата публикации

POLYMER SOLID ELECTROLYTES, METHODS OF MAKING, AND ELECTROCHEMICAL CELLS COMPRISING THE SAME

Номер: US20200144667A1
Принадлежит: Lionano SE Inc.

The present invention generally relates to various polymer solid electrolyte materials suitable for various electrochemical devices and methods for making or using the same. Certain embodiments of the invention are generally directed to solid electrolytes having relatively high ionic conductivity and/or other mechanical or electrical properties, e.g., tensile strength or decomposition potential. Certain aspects include a polymer, a plasticizer, and an electrolyte salt. In some cases, the polymer may exhibit certain structures such as: 2. The article of claim 1 , wherein the product is the product of a crosslinking reaction including the polymer and a second polymer.4. The article of claim 1 , wherein the polymer is crosslinked via urea and/or carbamate functional groups.57-. (canceled)8. The article of claim 1 , wherein the article further comprises a plasticizer and an electrolyte salt.926-. (canceled)27. The article of claim 8 , wherein the article further comprises an initiator.28. (canceled)29. The article of claim 27 , wherein initiator has a mole fraction between 0.001 and 0.01.30. The article of claim 8 , wherein the polymer has a mole fraction between 0.027 and 0.200 claim 8 , the plasticizer has a mole fraction between 0.287 and 0.916 claim 8 , and the electrolyte salt have a mole fraction between 0.04 and 0.617.3134-. (canceled)35. The article of claim 1 , wherein the inorganic additive comprises AlO claim 1 , SiO claim 1 , SiO claim 1 , TiO claim 1 , LiPS claim 1 , LiGePS claim 1 , LiLaZrO claim 1 , LiLaZrTaO claim 1 , LiLaTiO claim 1 , LiAlTi(PO) claim 1 , and/or LiAlGe(PO) claim 1 , ZrO claim 1 , BaTiO claim 1 , LiTiO.36. (canceled)37. The article of claim 1 , wherein the article comprises a network-type microphase-separated structure.38. The article of claim 1 , wherein the polymer has a tensile strength of between 5 and 500 MPa.39. The article of claim 1 , wherein the polymer has an ionic conductivity between 1×10and 10S/cm.40. The article of claim 1 ...

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07-06-2018 дата публикации

COMPOSITION AND METHOD TO FORM A COMPOSITE CORE MATERIAL

Номер: US20180155521A1
Автор: Gleason, SR. Stephen
Принадлежит:

A composite core material and methods for making same are disclosed herein. The composite core material comprises mineral filler discontinuous portions disposed in a continuous encapsulating resin. Further, the method for forming a composite core material comprises the steps of forming a mixture comprising mineral filler, an encapsulating prepolymer, and a polymerization catalyst; disposing the mixture onto a moving belt; and polymerizing said encapsulating prepolymer to form a composite core material comprising mineral filler discontinuous portions disposed in a continuous encapsulating resin. 1. A composite core material , comprising mineral filler discontinuous portions disposed in a continuous encapsulating resin.2. The composite core material of claim 1 , wherein said mineral filler is selected from the group consisting of calcium sulfate claim 1 , calcium carbonate claim 1 , aluminum trihydrate claim 1 , talc claim 1 , gypsum claim 1 , magnesium hydroxide claim 1 , and dolomite.3. The composite core material of claim 2 , wherein said calcium sulfate comprises hydrates thereof claim 2 , wherein the hydrate is selected from the group consisting of calcium sulfate hemihydrate having a formula of CaSO.(nHO) claim 2 , wherein n is equal to or greater than 0.5 and equal to or less than 0.8; and calcium sulfate dihydrate having a formula of CaSO.2HO.4. The composite core material of claim 1 , wherein the encapsulating resin is selected from the group consisting of polyester resins claim 1 , vinyl ester resins claim 1 , fire retardant resins and any combinations thereof.5. The composite core material of claim 4 , wherein the encapsulating resin is polyester resins.6. The composite core material of claim 4 , wherein the encapsulating resin is vinyl ester resins.7. The composite core material of claim 4 , wherein the encapsulating resin is fire retardant resins.8. A method to form a composite core material claim 4 , comprising:forming a mixture comprising mineral filler ...

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08-06-2017 дата публикации

ORDERED MACROPOROUS HYDROGELS FOR BIORESPONSIVE PROCESSES

Номер: US20170158836A1
Принадлежит:

A three-dimensionally ordered macroporous hydrogel for immobilizing a selected bioresponsive molecule and method of making are disclosed. The three-dimensionally ordered macroporous hydrogel comprises a crosslinked polymer that has a system of interconnected pores. The interconnected pores have a uniform pore size in the range of 50 to 5000 nm, and a plurality of first pore functional groups. The plurality of first pore functional groups is selected to immobilize a selected bioresponsive molecule. Examples of bioresponsive molecules include an enzyme; a molecule for: a protein scaffold, solid phase synthesis, nucleic acid synthesis, polypeptide synthesis, analyte detection, adsorption of analytes and measuring analyte concentrations, organic synthesis, and degradation of biologically active agents in wastewater. A method includes forming a colloidal crystal template, polymerizing a hydrogel within the pores of the colloidal crystal template, and selectively removing the colloidal crystal template. The hydrogel can be polymerized using CRP, ATRP and FRP polymerization processes. 1. A three-dimensionally ordered macroporous hydrogel , comprising:a polymer comprising at least one hydrophilic monomer, and at least one crosslinker; 'wherein the plurality of first pore functional groups is selected to covalently bond with a selected bioresponsive molecule.', 'a plurality of first pore functional groups;'}, 'wherein the polymer comprises a system of interconnected pores, the interconnected pores comprising a uniform pore size in the range of 50 to 5000 nm; and'}2. The three-dimensionally ordered macroporous hydrogel of claim 1 , wherein the at least one hydrophilic monomer is selected from the group consisting of (ethylene glycol) (meth)acrylate claim 1 , hydroxylated-(ethylene glycol) (meth)acrylate claim 1 , quaternized 2-(dimethylamino)ethyl (meth)acrylate claim 1 , hydroxyalkyl (meth)acrylates claim 1 , n-vinyl pyrrolidone claim 1 , and acrylamides.3. The three- ...

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14-05-2020 дата публикации

ISOCYANATE-FREE FOAM USING CARBON MICHAEL ADDITION CHEMISTRY

Номер: US20200148850A1
Принадлежит:

A seating device has a seating platform and at least one leg supporting it in its elevated position. 1. (canceled)2. The method of claim 23 , wherein the formulation has a ratio of at least one multifunctional carbon Michael acceptor to at least one multifunctional carbon Michael donor of 0.9 to 1.6.3. (canceled)4. The method of claim 25 , wherein the aprotic polar solvent is triethyl phosphate and the protic polar solvent is water.5. (canceled)6. The method of claim 23 , wherein the at least one multifunctional carbon Michael acceptor is at least one multifunctional acrylate.7. The method of claim 6 , wherein the at least one multifunctional acrylate comprises at least one member selected from the group consisting of polypropylene glycol diacrylate claim 6 , dipropylene glycol diacrylate claim 6 , dipentaerythritol pentaacrylate claim 6 , dipentaerythritol hexaacrylate claim 6 , polyethylene glycol diacrylate claim 6 , PEG 400 diacrylate claim 6 , PEG 600 diacrylate claim 6 , trimethylolpropane triacrylate claim 6 , ethoxylated trimethylolpropane triacrylate claim 6 , tripropylene glycol diacrylate claim 6 , di(trimethylolpropane) tetraacrylate claim 6 , pentaerythritol tetraacrylate claim 6 , pentaerythritol triacrylate claim 6 , bisphenol A glycolate diacrylate claim 6 , ethoxylated bisphenol A diacrylate claim 6 , polyethylene glycol dimethacrylate claim 6 , ethoxylated neopentyl glycol diacrylate claim 6 , epoxy acrylates claim 6 , polyester acrylate.8. The method of claim 23 , wherein the at least one multifunctional carbon Michael donor comprises at least one member selected from the group consisting of acetoacetate esters and acetoacetamides.9. The method of claim 23 , wherein the at least one multifunctional carbon Michael donor is propane-1 claim 23 ,1 claim 23 ,1-triyltrimethyl tris(acetoacetate).10. The method of claim 23 , wherein the second part further comprises a physical blowing agent comprising at least one member selected from the group consisting ...

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24-06-2021 дата публикации

CATALYST-FREE SURFACE FUNCTIONALIZATION AND POLYMER GRAFTING

Номер: US20210189082A1
Принадлежит:

Some embodiments described herein relate to a substrate with a surface comprising a silane or a silane derivative covalently attached to optionally substituted cycloalkene or optionally substituted heterocycloalkene for direct conjugation with a functionalized molecule of interest, such as a polymer, a hydrogel, an amino acid, a nucleoside, a nucleotide, a peptide, a polynucleotide, or a protein. In some embodiments, the silane or silane derivative contains optionally substituted norbornene or norbornene derivatives. Method for preparing a functionalized surface and the use in DNA sequencing and other diagnostic applications are also disclosed. 1. A substrate comprising a first surface comprising silane or a silane derivative covalently bound to a functionalized molecule through a first plurality of unsaturated moieties selected from cycloalkenes , cycloalkynes , heterocycloalkenes , heterocycloalkynes , or optionally substituted variants or combinations thereof covalently attached to silicon atoms of said silane or silane derivative.2. The substrate of claim 1 , wherein said first plurality of unsaturated moieties are selected from norbornene claim 1 , heteronorbornenes claim 1 , norbornene derivatives claim 1 , trans-cyclooctene claim 1 , trans-cyclooctene derivatives claim 1 , cyclooctyne claim 1 , bicycloalkynes claim 1 , or optionally substituted variants or combinations thereof.3. The substrate of claim 1 , wherein said first plurality of unsaturated moieties are selected from optionally substituted norbornene claim 1 , optionally substituted cyclooctyne claim 1 , optionally substituted bicyclononyne claim 1 , or optionally substituted bicyclo[6.1.0]non-4-yne.4. The substrate of claim 1 , further comprising linkers covalently attached between silicon atoms of said silane or silane derivative and the first plurality of unsaturated moieties.5. The substrate of claim 4 , wherein the linkers are selected from optionally substituted alkylenes claim 4 , optionally ...

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22-09-2022 дата публикации

POLYMER SOLID ELECTROLYTES, METHODS OF MAKING, AND ELECTROCHEMICAL CELLS COMPRISING THE SAME

Номер: US20220302499A1
Принадлежит:

The present invention generally relates to various polymer solid electrolyte materials suitable for various electrochemical devices and methods for making or using the same. Certain embodiments of the invention are generally directed to solid electrolytes having relatively high ionic conductivity and/or other mechanical or electrical properties, e.g., tensile strength or decomposition potential. Certain aspects include a polymer, a plasticizer, and an electrolyte salt. In some cases, the polymer may exhibit certain structures such as: 161-. (canceled)63. The electrochemical cell of claim 62 , wherein the one or more monomers are crosslinked in the presence of an initiator or crosslinking agent claim 62 , at an elevated temperature claim 62 , under UV light claim 62 , or a combination thereof.64. The electrochemical cell of claim 63 , wherein the initiator or crosslinking agent has a mole fraction ranging from 0.001 and 0.01.65. The electrochemical cell of claim 62 , wherein the electrolyte comprises a plasticizer and an electrolyte salt.66. The electrochemical cell of claim 65 , wherein the one or more monomers have a mole fraction ranging from 0.027 to 0.200 in the electrolyte prior to the crosslinking claim 65 , the plasticizer has a mole fraction ranging from 0.287 to 0.916 claim 65 , and the electrolyte salt has a mole fraction ranging from 0.04 to 0.617.67. The electrochemical cell of claim 65 , wherein the plasticizer comprises ethylene carbonate claim 65 , cyclic carbonate claim 65 , oligoether claim 65 , succinonitrile claim 65 , polyethylene oxide claim 65 , polycarbonate claim 65 , polyacrylonitrile claim 65 , polyactic acid claim 65 , ionic liquid claim 65 , nitrile or a combination thereof.68. The electrochemical cell of claim 65 , wherein the electrolyte salt comprises a lithium salt claim 65 , a quaternary ammonium salt claim 65 , a quaternary phosphonium salt claim 65 , a transition metal salt claim 65 , or a salt of protonic acid.69. The ...

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14-06-2018 дата публикации

Aflatoxin templates, molecularly imprinted polymers, and methods of making and using the same

Номер: US20180163011A1
Принадлежит: Alltech Corp

Molecularly imprinted polymers (MIPs) are materials exhibiting molecular recognition of a target molecule. MIPs are synthesized in the presence of an aflatoxin template, a mimic to the targeted molecule, used as an imprint that is further washed away with suitable solvent after completion of the polymerization process, leaving a cavity in the polymer of the same stereochemistry, functionality and morphology to the template. When the MIP encounters an aflatoxin, the molecule is bound in the cavity with a receptor-like affinity.

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21-06-2018 дата публикации

POLYMERIZABLE LIQUID CRYSTAL COMPOUND, POLYMERIZABLE COMPOSITION, AND FILM

Номер: US20180171232A1
Принадлежит: FUJIFILM Corporation

The present invention is to provide a polymerizable liquid crystal compound represented by Formula (I); 2. The polymerizable liquid crystal compound according to claim 1 ,{'sub': '1', 'sup': 3', '3', '3, 'wherein Ris a group represented by —C(═O)—X-Sp-Q.'}3. The polymerizable liquid crystal compound according to claim 2 ,{'sup': 3', '3', '3, 'wherein Xis —O—, Spis a linear or branched alkylene group having 1 to 20 carbon atoms, and Qis a hydrogen atom.'}4. The polymerizable liquid crystal compound according claim 1 ,{'sub': '10', 'wherein Ris an alkyl group having 1 to 5 carbon atoms.'}6. The polymerizable liquid crystal compound according to claim 5 ,{'sub': '1', 'sup': 3', '3', '3, 'wherein Ris a group represented by —C(O)—X-Sp-Q.'}7. The polymerizable liquid crystal compound according to claim 6 ,{'sup': 3', '3', '3, 'wherein Xis —O—, Spis a linear or branched alkylene group having 1 to 20 carbon atoms, and Qis a hydrogen atom.'}8. The polymerizable liquid crystal compound according to claim 6 ,{'sub': '2', 'sup': 3', '3', '3, 'wherein Ris a group represented by —C(═O)—X-Sp-Q.'}9. The polymerizable liquid crystal compound according to claim 6 ,{'sub': 1', '2, 'wherein Rand Rare identical to each other and r1 and r2 are identical to each other.'}10. The polymerizable liquid crystal compound according to claim 5 ,{'sub': '10', 'wherein Ris an alkyl group having 1 to 5 carbon atoms.'}11. The polymerizable liquid crystal compound according to claim 9 ,{'sub': '10', 'wherein Ris methyl group or ethyl group.'}12. The polymerizable liquid crystal compound according to claim 11 ,wherein r10 represents 0 or 1.13. The polymerizable liquid crystal compound according to claim 1 ,{'sup': 3', '3', '3', '3', '4', '4', '3', '3', '3', '4', '3', '4, 'sub': 2', '3', '2', '3, "wherein, in Formula (I), substituents that may be included in the phenylene group and the trans-1,4-cyclohexylene group are selected from the group consisting of an alkyl group, an alkoxy group, and a group ...

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22-06-2017 дата публикации

STYRENE-FREE THERMOSET RESINS

Номер: US20170174806A1
Автор: Li Kaichang, Wu Yili
Принадлежит: Oregon State University

A reaction product of: 1. A reaction product of:(a) at least one cinnamyl alcohol or ester of cinnamic acid;(b) at least one unsaturated polyester resin, or at least one vinyl ester resin, or a mixture of an unsaturated polyester resin and a vinyl ester resin;(c) at least one (meth)acrylated vegetable oil; and(d) a free radical initiator system.2. A reaction product of:(a) at least one (meth)acrylated vegetable oil;(b) at least one unsaturated polyester resin, or at least one vinyl ester resin, or a mixture of an unsaturated polyester resin and a vinyl ester resin; and(c) a free radical initiator system.3. A reaction product of:(a) at least one cinnamyl alcohol or ester of cinnamic acid;(b) at least one unsaturated polyester resin, or at least one vinyl ester resin, or a mixture of an unsaturated polyester resin and a vinyl ester resin; and(c) a free radical initiator system.4. The product of claim 1 , wherein the (meth)acrylated vegetable oil comprises (meth)acrylated soybean oil.5. The product of claim 1 , wherein the (meth)acrylated vegetable oil comprises acrylated epoxidized soybean oil.6. The product of claim 1 , wherein the unsaturated polyester resin comprises a reaction product of (a) at least one saturated dibasic acid claim 1 , (b) at least one diol claim 1 , and (c) at least one unsaturated dibasic acid.7. The product of claim 1 , wherein the vinyl ester resin comprises a reaction product of (a) at least one epoxy resin claim 1 , and (b) at least one unsaturated carboxylic acid.8. The product of claim 1 , wherein the free radical initiator system includes peroxide and azo functional groups claim 1 , and optionally at least one promoter or accelerator.9. The product of claim 1 , wherein the unsaturated polyester resin or vinyl ester resin is styrene-free.10. The product of claim 1 , wherein the product is styrene-free.11. The product of claim 1 , wherein the product is hazardous air pollutant (HAP)-free.12. The product of claim 2 , wherein the (meth) ...

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21-06-2018 дата публикации

COMPOSITION FOR ELECTRODE PROTECTIVE FILM OF ELECTROSTATIC CAPACITANCE-TYPE INPUT DEVICE, ELECTRODE PROTECTIVE FILM OF ELECTROSTATIC CAPACITANCE-TYPE INPUT DEVICE, TRANSFER FILM, LAMINATE, ELECTROSTATIC CAPACITANCE-TYPE INPUT DEVICE, AND IMAGE DISPLAY DEVICE

Номер: US20180173095A1
Автор: KANNA Shinichi
Принадлежит: FUJIFILM Corporation

A composition for an electrode protective film of an electrostatic capacitance-type input device including (a) a binder polymer, (b) a photopolymerizable compound having an ethylenic unsaturated group, (c) a photopolymerization initiator, and (d) a compound capable of reacting with acidic groups or alcoholic hydroxy groups by heating, in which (b) the photopolymerizable compound having an ethylenic unsaturated group includes (b1) a photopolymerizable compound in which a value obtained by dividing a weight-average molecular weight by an average number of polymerizable groups is 270 or more can be used to form electrode protective films of electrostatic capacitance-type input devices having favorable bending resistance; an electrode protective film of an electrostatic capacitance-type input device; a transfer film; a laminate; an electrostatic capacitance-type input device; and an image display device. 1. A composition for an electrode protective film of an electrostatic capacitance-type input device comprising:(a) a binder polymer;(b) a photopolymerizable compound having an ethylenic unsaturated group;(c) a photopolymerization initiator; and(d) a compound capable of reacting with acidic groups or alcoholic hydroxy groups by heating,wherein (b) the photopolymerizable compound having an ethylenic unsaturated group includes (b1) a photopolymerizable compound in which a value obtained by dividing a weight-average molecular weight by an average number of polymerizable groups is 270 or more.2. The composition for an electrode protective film of an electrostatic capacitance-type input device according to claim 1 ,wherein, in an electrode protective film of an electrostatic capacitance-type input device obtained by curing the composition for an electrode protective film of an electrostatic capacitance-type input device, a breaking elongation is 5% or more in a tensile test under an environment of 23° C. and a relative humidity of 50%.3. The composition for an electrode ...

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08-07-2021 дата публикации

HARD COATING FILM AND IMAGE DISPLAY DEVICE COMPRISING SAME

Номер: US20210206934A1
Принадлежит:

A hard coating film may include a substrate and a hard coating layer provided on at least one surface of the substrate, in which, when the hard coating film is folded and unfolded 200,000 times with a bending radius of 1 mm in the direction in which the hard coating layer is oriented inwards under 60° C. and 90% relative humidity (RH), breakage does not occur, and the amount of change in transmission b* (chromaticity) of the film after UV irradiation for 100 hr using a 15 W UV-B lamp is 1.5 or less. The hard coating film may exhibit superior anti-curling properties, superior bending resistance under high-temperature and high-humidity conditions, and high light resistance, and can thus be applied not only to an image display device but also to a window for a flexible display device. 1. A hard coating film , comprising:a substrate; anda hard coating layer provided on at least one surface of the substrate,wherein, when the hard coating film is folded and unfolded 200,000 times with a bending radius of 1 mm in a direction in which the hard coating layer is oriented inwards under 60° C. and 90% relative humidity (RH), breakage does not occur, and an amount of change in transmission b* (chromaticity) of the film after UV irradiation for 100 hr using a 15 W UV-B lamp is 1.5 or less.2. The hard coating film of claim 1 , wherein the hard coating layer comprises a cured product of a hard coating composition comprising a first photopolymerization initiator having a maximum absorption wavelength of 250 nm or less and a second photopolymerization initiator having a maximum absorption wavelength of 300 nm or less but exceeding 250 nm.3. The hard coating film of claim 2 , wherein the hard coating composition further comprises at least one selected from the group consisting of a light-transmissive resin claim 2 , a solvent claim 2 , and an additive.4. The hard coating film of claim 3 , wherein the light-transmissive resin comprises dendritic acrylate.5. The hard coating film of ...

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13-06-2019 дата публикации

Highly Stable Quantum DOT-Containing Polymer Films

Номер: US20190177609A1
Принадлежит:

Highly stable films containing semiconductor nanoparticles (“quantum dots”) are prepared from resins containing a fast-curing inner phase having a high glass transition temperature (T) and certain inner phase/outer phase combinations. The resins may comprise an inner phase and outer phase (but may appear to be a single phase due to their homogeneous appearance when viewed using an optical microscope). The method provides a highly scalable and cost-effective procedure for preparing films that are resistant to light, elevated temperatures, moisture, and oxygen. 1. A two-phase resin system , the system comprising: an acrylate resin having a glass transition temperature of greater than 35° C.; and', 'a plurality of semiconductor nanoparticles dispersed throughout the acrylate resin; and, 'an inner phase comprisingan outer phase.2. The system of claim 1 , wherein acrylate resin having a glass transition temperature of greater than 90° C.3. The system of claim 1 , wherein the acrylate resin is made from acrylate monomers.4. The system of claim 3 , wherein the acrylate monomers are selected from the group consisting of isobornyl acrylate claim 3 , lauryl acrylate claim 3 , behenyl acrylate claim 3 , tert-butyl acrylate claim 3 , dihydrodicyclo-pentadienyl acrylate claim 3 , stearyl acrylate claim 3 , trimethylolpropane triacrylate claim 3 , PEG 30 dipolyhydroxystearate and any combination thereof.5. The system of claim 1 , wherein the acrylate resin is made from methacrylate monomers.6. The system of claim 5 , wherein the methacrylate monomers are selected from the group consisting of lauryl methacrylate claim 5 , behenyl methacrylate claim 5 , tert-butyl methacrylate claim 5 , cyclohexyl methacrylate claim 5 , methyl methacrylate claim 5 , trimethylolpropane trimethacrylate claim 5 , and any combination thereof.7. The system of claim 1 , wherein the acrylate resin is made from monomers selected from the group consisting of isobornyl acrylate claim 1 , lauryl acrylate ...

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05-07-2018 дата публикации

Colored metallic pigment and colored article

Номер: US20180186945A1
Принадлежит: Toyo Aluminum KK

A colored metallic pigment of the present invention contains a metallic pigment, a coloring pigment, a first compound and a second compound. The coloring pigment adheres to the surface of the metallic pigment in the coexistence of the first compound and the second compound, the first compound is a compound having two or more carboxyl groups, and the second compound is a compound having one or more amino groups.

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04-06-2020 дата публикации

FIBER COMPOSITE LAMINATE INCLUDING SELF-ASSEMBLED CONDUCTIVE PASTE AND METHOD OF MANUFACTURING SAME

Номер: US20200178388A1

Disclosed are a fiber composite laminate including a self-assembled conductive paste and a method of manufacturing the same. The fiber composite laminate includes a fiber-based circuit unit including a fiber substrate and a circuit electrode positioned on the fiber substrate, a composite binder unit positioned on the fiber-based circuit unit, and a connection unit including a connection electrode positioned on the composite binder unit and a flexible substrate positioned on the composite binder unit and the connection electrode. The fiber composite laminate can thus be applied to wearable devices having increased conductivity and durability of joints thereof, a minimized foreign-body sensation, and an improved wearing sensation. Moreover, productivity can be increased owing to a simple manufacturing process, and mass production becomes possible. 1. A fiber composite laminate , comprising:a fiber-based circuit unit including a fiber substrate and a circuit electrode positioned on the fiber substrate;a composite binder unit positioned on the fiber-based circuit unit; anda connection unit including a connection electrode positioned on the composite binder unit and a flexible substrate positioned on the composite binder unit and the connection electrode.2. The fiber composite laminate of claim 1 , wherein the fiber-based circuit unit is adhered to the connection unit by the composite binder unit.3. The fiber composite laminate of claim 1 , wherein the composite binder unit includes a binder portion and a conductor portion claim 1 ,the binder portion is positioned between the fiber substrate and the flexible substrate, andthe conductor portion is positioned between the circuit electrode and the connection electrode.4. The fiber composite laminate of claim 3 , wherein the conductor portion includes a conductor and serves to electrically connect the circuit electrode and the connection electrode.5. The fiber composite laminate of claim 4 , wherein the conductor includes at ...

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06-07-2017 дата публикации

ACTIVE ENERGY RAY-CURABLE COMPOSITION AND ANTISTATIC FILM

Номер: US20170190825A1
Автор: YAMASHITA Masako
Принадлежит: FUJIFILM Corporation

Provided are an active energy ray-curable composition that has good antistatic properties, scratch resistance, and transparency after curing, and an antistatic film using the same. The active energy ray-curable composition of the present invention is an active energy ray-curable composition, including a photopolymerization initiator A represented by the following Formula (I), an antistatic polymer B, and a polymerizable compound C containing an ethylenically unsaturated group, 3. The active energy ray-curable composition according to claim 2 , wherein the antistatic polymer B is a cationic polymer having a repeating unit represented by Formula (1).6. The active energy ray-curable composition according to claim 2 , wherein the antistatic polymer B contains a repeating unit represented by Formula (1) and a repeating unit represented by Formula (3) or (4).8. The active energy ray-curable composition according to claim 2 , wherein the antistatic polymer B contains at least one repeating unit selected from the group consisting of repeating units represented by Formulae (1) to (5) and a repeating unit derived from a monomer having a CLogP value of 0.3 to 5.9. The active energy ray-curable composition according to claim 2 , wherein the antistatic polymer B is a copolymer containing 40 to 80 mass % of repeating units represented by Formulae (1) to (5).10. The active energy ray-curable composition according to claim 9 , wherein the antistatic polymer B contains 40 to 80 mass % of repeating units represented by Formulae (1) to (5) claim 9 , and 20 to 60 mass % of a repeating unit represented by Formula (7).11. The active energy ray-curable composition according to claim 9 , wherein the antistatic polymer B contains 39.5 to 70 mass % of a repeating unit represented by Formula (1) claim 9 , 20 to 60 mass % of a repeating unit represented by Formula (7) claim 9 , and 0.5 to 10 mass % of a repeating unit represented by Formula (3) or (4).12. The active energy ray-curable ...

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20-06-2019 дата публикации

METHODS AND COMPOSITIONS RELATING TO TUNABLE NANOPOROUS COATINGS

Номер: US20190185630A1
Принадлежит:

Described herein are methods and compositions relating to tunable nanoporous coatings. In certain aspects, described herein are methods and compositions wherein a tunable nanoporous coating comprises a tunable nanoporous membrane which transitions from opaque to transparent upon the application of force, and from transparent to opaque after washing with a solvent. 1. A method for fabricating a tunable polymer membrane , comprising:forming at least one silica layer with silica nanoparticles;transferring the at least one silica layer onto at least one first surface of one or more substrates;creating a volume between the first surface and at least one opposing second surface of a second substrate;adding a monomer composition into the volume between the opposing first and second surfaces;polymerizing the monomer composition with a polymerization method to form a tunable polymer membrane; andremoving the at least one silica layer on the one or more substrates with the first solvent.2. The method of claim 1 , further comprising:washing the tunable polymer membrane with a second solvent after removing the silica layers.3. The method of claim 1 , wherein the silica nanoparticles are SiOnanoparticles with a diameter of about 100 nm to about 10 claim 1 ,000 nm.4. The method of claim 1 , wherein the silica layer is a monolayer of colloidal silica crystals.5. The method of claim 1 , wherein the one or more substrates comprise glass.6. The method of claim 1 , further comprising transferring the at least one silica layer onto at least one second surface of the second substrate.7. The method of claim 1 , wherein the monomer composition comprises polymerized polyethylene glycol diacrylate (PEGDA) claim 1 , polyethylene glycol (600) diacrylate (PEGDA 600) claim 1 , ethoxylated trimethylolpropane triacrylate (ETPTA) claim 1 , ethoxylated (20) trimethylolpropane triacrylate (ETPTA 20) claim 1 , or a combination thereof.8. The method of claim 1 , wherein the first solvent is 2% ...

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20-06-2019 дата публикации

PORE INDUCER AND POROUS ABRASIVE FORM MADE USING THE SAME

Номер: US20190185636A1
Принадлежит:

Various embodiments disclosed relate to pore inducers and porous abrasive forms made using the same. In various embodiments, the present invention provides a method of forming a porous abrasive form including heating an abrasive composition including pore inducers to form the porous abrasive form. During the heating the pore inducers in the porous abrasive form reduce in volume to form induced pores in the porous abrasive form. 1. A method of forming a porous abrasive form , the method comprising:heating an abrasive composition comprising pore inducers, to form the porous abrasive form, wherein during the heating the pore inducers in the porous abrasive form reduce in volume to form induced pores in the porous abrasive form.210-. (canceled)11. The method of claim 1 , wherein the induced pores substantially correspond in shape and location to that of the pore inducers in the abrasive composition prior to the heating.12. The method of claim 1 , wherein the induced pores approximately correspond in size to that of the pore inducers in the abrasive composition prior to the heating.13. The method of claim 12 , wherein the induced pores have a volume that is about 50% to about 100% of the volume of the pore inducers in the abrasive composition prior to the heating.14. The method of claim 12 , wherein the induced pores have a volume that is about 70% to about 95% of the volume of the pore inducers in the abrasive composition prior to the heating.15. The method of claim 1 , wherein during the heating one or more components of the pore inducers melt or become flowable.1619-. (canceled)20. The method of claim 1 , wherein the heating comprising vitrifying claim 1 , wherein the porous abrasive form comprises a porous vitrified abrasive form.2124-. (canceled)25. The method of claim 1 , wherein the pore inducers are shaped pore inducers.26. The method of claim 1 , wherein the pore inducers are three dimensional geometric shapes.27. The method of claim 1 , wherein the pore ...

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27-06-2019 дата публикации

Curable composition and film

Номер: US20190194478A1
Автор: Kiyotaka Fukagawa
Принадлежит: Fujifilm Corp

A curable composition contains at least one polyfunctional compound selected from the group consisting of a compound represented by General Formula (I) and a compound represented by General Formula (II), and an ionic polymer including a repeating unit indicated by General Formula (IV).

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25-06-2020 дата публикации

HIGHLY SENSITIVE OXIME ESTER PHOTOPOLYMERIZATION INITIATOR AND PHOTOPOLYMERIZABLE COMPOSITION INCLUDING THE SAME

Номер: US20200199261A1
Принадлежит:

Provided is an oxime ester phenylcarbazole compound useful as a photoinitiator for photocrosslinking. Specifically, the carbon atom forming a double bond with the nitrogen atom in the oxime ester moiety of the oxime ester phenylcarbazole compound is bonded to the phenylcarbazole group and is directly bonded to a (C-C)alkyl or (C-C)aryl group. Also provided is a photopolymerizable composition including the oxime ester phenylcarbazole compound. The oxime ester phenylcarbazole compound and the photopolymerizable composition have improved solubilities, are highly photosensitive, and exhibit excellent physical properties in terms of residual film ratio, pattern stability, resist adhesiveness. Due to these advantages, the oxime ester phenylcarbazole compound and the photopolymerizable composition are suitable for use in black resists, color resists, overcoats, column spacers, and organic insulating films of LCDs. 1. An oxime ester phenylcarbazole compound as a photoinitiator for use in photocrosslinking wherein the carbon atom forming a double bond with the nitrogen atom in the oxime ester moiety is bonded to the phenylcarbazole group and is directly bonded to a (C-C)alkyl or (C-C)aryl group and wherein the phenylcarbazole group is substituted with one or more nitro groups.2. The oxime ester phenylcarbazole compound according to claim 1 , wherein the phenylcarbazole group is substituted with one or two nitro groups.4. The oxime ester phenylcarbazole compound according to claim 3 , wherein Rand Rin Formula 1 are each independently hydrogen claim 3 , nitro claim 3 , cyano claim 3 , alkoxy or halogen claim 3 , with the proviso that one of Rand Ris nitro.5. The oxime ester phenylcarbazole compound according to claim 3 , wherein Rin Formula 1 is (C-C)alkyl or (C-C)aryl.6. The oxime ester phenylcarbazole compound according to claim 3 , wherein Rin Formula 1 is (C-C)alkyl or (C-C)aryl.7. The oxime ester phenylcarbazole compound according to claim 3 , wherein Rand Rin Formula 1 ...

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05-08-2021 дата публикации

SYNTHESIS OF SUPERHYDROPHOBIC MICROPOROUS SURFACES VIA LIGHT-DIRECTED PHTOPOLYMERIZATION AND PHASE SEPARATION

Номер: US20210240084A1
Автор: Hosein Ian D.
Принадлежит: SYRACUSE UNIVERSITY

The formation of microporous surfaces through polymer induced phase separation in a photopolymer solvent mixture using photopolymerization via light self-focusing and self-trapping. The self-trapping of light sets fixed regions of brightness and darkness, sustained by the polymerization of light, and then wave guiding within the substrate. Phase separation occurs with the solvent phase separating in the regions of darkness and crosslinking in the regions of brightness. Upon removal of the solvent, precise and uniformly dispersed pores are created in the surface. The pore size and spacing may be tuned by adjusting the weight fraction of the photopolymer solvent mixture as well as through changes in the mask pattern. 1. A microporous structure , comprising a polymerized monomer having a surface defining a series of pores that have a diameter ranging from 10 to 40 micrometers and that are spaced apart from each other by a distance ranging from 50 to 100 micrometers.2. The structure of claim 1 , wherein the microporous structure has a thickness between 100 and 400 micrometers.3. The structure of claim 1 , wherein the monomer comprises trimethylolpropane triacrylate (TMPTA).4. The structure of claim 1 , wherein the surface is coated with a plurality of nanoparticles.5. The structure of claim 4 , wherein the nanoparticles comprise polytetrafluoroethylene (PTFE).6. The structure of claim 5 , wherein the coated surface is characterized by a static water contact angle at or above 150°. The present application is a divisional of U.S. application Ser. No. 16/164,910, filed on Oct. 19, 2018, which claims priority to U.S. Provisional App. No. 62/579,964, filed on Nov. 1, 2017.The present invention relates to microporous surfaces and, more particularly, to the combination of photopolymerization induced phase separation and light self-trapping in photopolymer-solvent mixtures to control the formation of pores.Living systems abound with surface anatomies possessing inherent porous, ...

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13-08-2015 дата публикации

Process For Curing Thermoset Resins

Номер: US20150225515A1
Принадлежит:

Process for curing a thermoset resin comprising the step of contacting said resin with (i) an imine of the structure C(R)(R)═N—Rwherein Ris selected from hydrogen, hydroxyl, linear or branched alkyl having 1-22 carbon atoms, cycloalkyl having 3-22 carbon atoms, aryl having 6 to 15 carbon atoms, and aralkyl having 7 to 22 carbon atoms, which alkyl, cycloalkyl, aryl, and aralkyl groups may be optionally substituted with one or more groups containing heteroatoms selected from S, O, P, and/or Si. Ris selected from C(R)(R)—C(═O)—R, —C(R)(R)—C(═S)—R, and —C(R)(R)—C(═N)—R, wherein R, R, and Rare selected from hydrogen, linear or branched alkyl having 1-6 carbon atoms, cycloalkyl having 3-12 carbon atoms, aryl, aralkyl, alkoxy having 1-6 carbon atoms, and aryloxy. Ris selected from linear or branched alkyl having 1-22 carbon atoms, 1 cycloalkyl having 3-22 carbon atoms, aryl having 6 to 15 carbon atoms, and aralkyl having 7 to 22 carbon atoms, and (ii) methyl isopropyl ketone peroxide. 1. Process for curing a thermoset resin comprising the step of contacting said resin with{'sup': 2', '3', '1, 'claim-text': [{'sup': '1', 'Ris selected from the group consisting of hydrogen, hydroxyl, linear or branched alkyl having 1-22 carbon atoms, cycloalkyl having 3-22 carbon atoms, aryl having 6 to 15 carbon atoms, and aralkyl having 7 to 22 carbon atoms, which said alkyl, cycloalkyl, aryl, and aralkyl groups may be optionally substituted with one or more groups containing heteroatoms selected from the group consisting of S, O, P, and Si.'}, {'sup': 2', '6', '5', '4', '6', '5', '4', '6', '5', '4', '5', '6, 'Ris selected from C(R)(R)—C(═O)—R, —C(R)(R)—C(═S)—R, and —C(R)(R)—C(═N)—R4, wherein R, R, and Rare selected from the grow consisting of hydrogen, linear or branched alkyl having 1-6 carbon atoms, cycloalkyl having 3-12 carbon atoms, aryl, aralkyl, alkoxy having 1-6 carbon atoms, and aryloxy.'}, {'sup': '3', 'Ris selected from the group consisting of linear or branched alkyl having 1- ...

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11-08-2016 дата публикации

METHODS OF ALTERING THE REFRACTIVE INDEX OF MATERIALS

Номер: US20160228238A1
Принадлежит:

Methods and devices for altering the power of a lens, such as an intraocular lens, are disclosed. In one method, the lens comprises a single polymer matrix containing crosslinkable pendant groups, wherein the polymer matrix increases in volume when crosslinked. The lens does not contain free monomer. Upon exposure to ultraviolet radiation, crosslinking causes the exposed portion of the lens to increase in volume, causing an increase in the refractive index. In another method, the lens comprises a polymer matrix containing photobleachable chromophores. Upon exposure to ultraviolet radiation, photobleaching causes a decrease in refractive index in the exposed portion without any change in lens thickness. These methods avoid the need to wait for diffusion to occur to change the lens shape and avoid the need for a second exposure to radiation to lock in the changes to the lens. 18-. (canceled)9. A method of altering the optical power of a lens , comprising:providing a lens comprising a polymer matrix having photobleachable chromophores; andexposing a portion of the lens to electromagnetic or charged particle radiation, causing photobleaching to occur in the exposed portion of the lens and increasing the refractive index of the exposed portion of the lens, thereby altering the optical power of the lens.10. The method of claim 9 , wherein the charged particle radiation is provided by an electron beam.11. A method of altering the optical power of a lens claim 9 , comprising: a single polymer matrix having crosslinkable pendant groups;', 'wherein the polymer matrix does not change significantly in volume when crosslinked; and, 'providing a lens comprisingexposing a portion of the lens to electromagnetic or charged particle radiation, causing crosslinking to occur in the exposed portion of the lens and increasing the refractive index of the exposed portion of the lens, thereby altering the optical power of the lens.12. The method of claim 11 , wherein the lens is devoid of ...

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11-08-2016 дата публикации

Structural handling film

Номер: US20160229965A1
Принадлежит: Zephyros Inc

A handling film to be applied to an adhesive, wherein the handling film comprises a polyhydroxyamino ether thermoplastic, a monofunctional epoxy, and a carboxylated nitrile butadiene elastomer.

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09-08-2018 дата публикации

POROUS PARTICLE, METHOD FOR PRODUCING POROUS PARTICLE, AND BLOCK COPOLYMER

Номер: US20180223067A1
Принадлежит:

The present invention provides porous particles uniform in shape and having through holes that are not closed. The porous particles according to the present invention are porous particles having a substantially spherical shape. Each of the porous particles has an interconnected pore structure in which through holes provided inside the porous particle communicate with each other, and ends of the through holes are open toward an outside of the porous particle. 1. Porous particles having a substantially spherical shape , whereineach of the porous particles has an interconnected pore structure in which through holes provided inside the porous particle communicate with each other,the through holes are formed by spinodal decomposition, andends of the through holes are open toward an outside of the porous particle.2. (canceled)3. The porous particles according to claim 1 , whereineach of the porous particle is shaped so that the longest diameter is not more than 1.6 times the shortest diameter.4. The porous particles according to or claim 1 , having a mean particle size in a range from 0.5 to 30 claim 1 ,000 μm.5. A method for producing the porous particles according to claim 1 , claim 1 , or claim 1 , the method comprising:a dispersion preparation step of preparing a dispersion by dispersing a porous particle raw material comprising a monomer and/or a prepolymer in a dispersion medium; anda polymerization step of polymerizing the porous particle raw material in the dispersion,wherein, in the polymerization step, the through holes are formed by spinodal decomposition.6. The method according to claim 5 , whereinin the dispersion preparation step, the porous particle raw material is dispersed in the dispersion medium together with a dispersant.7. The method according to claim 6 , whereinthe dispersant is a block copolymer comprising a hydrophobic polymer block and a hydrophilic polymer block.8. The method according to claim 7 , further comprising a dispersant production step ...

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18-08-2016 дата публикации

POLYESTERS AND ARTICLES MADE THEREFROM

Номер: US20160237206A1
Принадлежит:

Disclosed herein are polyesters and articles made therefrom. The article comprising a substrate comprising a first surface and a second surface, the second surface in contact with an outside environment, wherein the substrate comprises a polymer comprising poly(trimethylene furandicarboxylate) (PTF), and wherein the polymer provides an improvement in gas barrier properties of the substrate as compared to a substrate comprising nascent poly(ethylene terephthalate) (PET). 150-. (canceled)52. The use of the polymer composition of claim 51 , wherein the polymer is:(a) poly(trimethylene furandicarboxylate) derived from 2,5-furan dicarboxylic acid or a derivative thereof and 1,3-propanediol;{'sub': 2', '12, '(b) a polymer blend comprising 0.1-99.9% by weight of poly(trimethylene furandicarboxylate) and 99.9-0.1% by weight of a poly(alkylene terephthalate), based on the total weight of the polymer blend, wherein the poly(alkylene terephthalate) comprises monomeric units derived from terephthalic acid and a C-Caliphatic diol; or'}(c) a poly(trimethylene furandicarboxylate) copolymer derived from 2,5-furan dicarboxylic acid or a derivative thereof, at least one of a diol or a polyol monomer, and at least one of a polyfunctional aromatic acid or a hydroxyl acid, wherein the molar ratio of 2,5-furan dicarboxylic acid to at least one of a polyfunctional aromatic acid or a hydroxy acid is in the range of 1:100 to 100:1, and wherein the molar ratio of diol to total acid content is in the range of 1.2:1 to 3:1.53. The use of the polymer composition of claim 51 , wherein the polymer composition provides an improved barrier to at least one of oxygen claim 51 , carbon dioxide or moisture as compared to a 100% poly(ethylene terephthalate) substrate claim 51 , wherein the oxygen permeability is measured according to ASTM D-3985 claim 51 , the carbon dioxide permeability is measured according to ASTM F-2476-05 claim 51 , and the moisture permeability is measured according to ASTM F-1249 ...

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16-08-2018 дата публикации

Porous particle made of organic polymer, method for producing porous particle made of organic polymer, and block copolymer

Номер: US20180230284A1

The present invention provides porous particles made of an organic polymer, uniform in shape, and having through holes that are not closed. The porous particles according to the present invention are porous particles having a substantially spherical shape. The porous particles are made of an organic polymer. Each of the porous particles has an interconnected pore structure in which through holes provided inside the porous particle communicate with each other, and ends of the through holes are open toward an outside of the porous particle.

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17-08-2017 дата публикации

Highly Stable Quantum Dot-Containing Polymer Films

Номер: US20170233644A1
Принадлежит:

Highly stable films containing semiconductor nanoparticles (“quantum dots”) are prepared from resins containing a fast-curing inner phase having a high glass transition temperature (T) and certain inner phase/outer phase combinations. The resins may comprise an inner phase and outer phase (but may appear to be a single phase due to their homogeneous appearance when viewed using an optical microscope). The method provides a highly scalable and cost-effective procedure for preparing films that are resistant to light, elevated temperatures, moisture, and oxygen. 1. A film comprising:a plurality of semiconductor nanoparticles dispersed in an uncured inner phase that comprises isopropyl myristate; and,an outer phase that comprises a bisphenol A epoxy diacrylate oligomer.2. The film recited in wherein the inner phase additionally comprises fumed silica.3. The film recited in additionally comprising:an oxygen-barrier film.4. A film comprising:a plurality of semiconductor nanoparticles dispersed in a cured inner phase that comprises lauryl methacrylate and trimethylolpropane trimethacrylate; and,an outer phase that comprises an acrylate-functionalized silica nanoparticle resin.5. The film recited in additionally comprising:an oxygen-barrier film.6. A film comprising:a plurality of semiconductor nanoparticles dispersed in a cured inner phase that comprises lauryl methacrylate and trimethylolpropane trimethacrylate; and,an outer phase that comprises a monofunctional adhesion-promoting acrylic oligomer and a tricyclodecane dimethanol diacrylate.7. The film recited in wherein the outer phase comprises substantially equal amounts of the monofunctional adhesion-promoting acrylic oligomer and the tricyclodecane dimethanol diacrylate.8. The film recited in additionally comprising:an oxygen-barrier film.9. The film recited in wherein the semiconductor nanoparticles comprise red-emitting quantum dots.10. The film recited in wherein the semiconductor nanoparticles comprise red- ...

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16-07-2020 дата публикации

CURABLE COMPOSITION, FILM, CURED PRODUCT, AND MEDICAL MEMBER

Номер: US20200223967A1
Принадлежит: FUJIFILM Corporation

A curable composition contains a betaine monomer having a predetermined structure and a polyfunctional (meth)acrylamide compound having a predetermined structure. 2. The curable composition according to claim 1 ,{'sup': '1', 'wherein Ain Formula (1) represents S═O, and'}{'sup': '2', 'Ain Formula (2) represents S═O.'}4. A cured product formed by curing the curable composition according to .5. The cured product according to that is in the form of a film.6. The cured product according to that is used as a biomaterial.7. A medical member comprising:a substrate; and{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, 'the cured product according to disposed on the substrate.'} This application is a Continuation of PCT International Application No. PCT/JP2018/037662 filed on Oct. 10, 2018, which claims priority under 35 U.S.C § 119(a) to Japanese Patent Application No. 2017-201962 filed on Oct. 18, 2017. Each of the above application(s) is hereby expressly incorporated by reference, in its entirety, into the present application.The present invention relates to a curable composition, a film, a cured product, and a medical member.Originally, it is desired that artificial organs, medical instruments, and the like are made of a material which is compatible with a substance constituting a living body and is hardly contaminated. For example, it is desired that artificial blood vessels, catheters, stents, artificial bones, and dentures that are introduced into a human body for a long period of time do not cause an inflammatory response and rejection. In addition, the replacement of those artificial organs or medical instruments caused by contamination imposes a burden on the patient. Therefore, it is desired that artificial organs, medical instruments, and the like are formed of a material which hardly interacts with biological materials such as proteins, blood cells, and cells. That is, it is desired that artificial organs, medical instruments, and the like are formed of a ...

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26-08-2021 дата публикации

USE OF BORON NITRIDE NANOSHEETS TO INCREASE COMPOSITE MODULUS AND DECREASE VISCOSITY AND PHASE SEPARATION IN COMPOSITES WITH HYDROPHOBIC MONOMERS

Номер: US20210261750A1
Принадлежит:

A composite includes a filler comprising boron nitride nanosheets (BNN) and a resin. The resin includes a multifunctional oxirane epoxy phenol novolac resin (EP8370), a multifunctional acrylate dipenta erythritol hexaacrylate (DPHA), 2-(perfluorooctyl)ethyl acrylate (PFOEA), urethane dimethacrylate (UDMA), and tetryhydrofuran (THF). Additional resins for use with the composite include bisphenol A glycidyl dimethacrylate (BisGMA), urethane dimethacrylate (UDMA), and/or triethylene glycol dimethacrylate (TEGDMA) in any combination thereof. 1. A composite comprising:a filler comprising boron nitride nanosheets (BNN); and a multifunctional oxirane epoxy phenol novolac resin (EP8370);', 'a multifunctional acrylate dipenta erythritol hexaacrylate (DPHA);', '2-(perfluorooctyl)ethyl acrylate (PFOEA);', 'urethane dimethacrylate (UDMA); and', 'tetryhydrofuran (THF)., 'a resin comprising2. The composite of claim 1 , wherein the boron nitride nanosheets comprise approximately 0.5 wt % of the composite.3. The composite of claim 1 , wherein the filler comprises approximately 69.5 wt % of the composite.4. The composite of claim 1 , wherein the resin comprises approximately 30 wt % of the composite.5. The composite of claim 4 , wherein the EP8370 comprises approximately 22.5 wt % of the resin.6. The composite of claim 4 , wherein the DPHA comprises approximately 22.5 wt % of the resin.7. The composite of claim 4 , wherein the PFOEA comprises approximately 17 wt % of the resin.8. The composite of claim 4 , wherein the UDMA comprises approximately 26.875 wt % of the resin.9. The composite of claim 4 , wherein the THF comprises approximately 1.25 wt % of the resin.10. The composite of claim 1 , further comprising a photoinitiator system.11. The composite of claim 10 , wherein the photoinitiator system comprises camphorquinone (CQ) claim 10 , borate claim 10 , and ethyl-4-dimethylamino benzoate (EDMAB).12. The composite of claim 11 , wherein the CQ comprises approximately 0.125 wt % of ...

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23-08-2018 дата публикации

PREPARATION METHOD OF SUPERABSORBENT POLYMER AND SUPERABSORBENT POLYMER PREPARED THEREBY

Номер: US20180237594A1
Принадлежит: LG CHEM, LTD.

A preparation method of a superabsorbent polymer, and a superabsorbent polymer prepared thereby are provided. The preparation method of the superabsorbent polymer according to the present disclosure prevents polymer particles from being broken or the surface thereof from being damaged during preparation and handling of the superabsorbent polymer, thereby providing a superabsorbent polymer having excellent absorption properties and permeability. 2. The preparation method of the superabsorbent polymer of claim 1 , wherein the polycarboxylic acid-based copolymer is mixed in an amount of 0.001 parts by weight to 5 parts by weight claim 1 , based on 100 parts by weight of the surface-crosslinked polymer.3. The preparation method of the superabsorbent polymer of claim 1 , wherein the polycarboxylic acid-based copolymer has a weight average molecular weight of 500 to 1 claim 1 ,000 claim 1 ,000.4. The preparation method of the superabsorbent polymer of claim 1 , wherein the drying of the water-containing gel polymer is performed at a temperature of 120° C. to 250° C.5. The preparation method of the superabsorbent polymer of claim 1 , further comprising pulverizing the water-containing gel polymer to have a particle size of 1 mm to 10 mm claim 1 , before drying the water-containing gel polymer.6. The preparation method of the superabsorbent polymer of claim 1 , wherein the pulverizing of the dried polymer is performed such that the pulverized polymer has a particle size of 150 μm to 850 μm.7. The preparation method of the superabsorbent polymer of claim 1 , wherein the surface crosslinking of the pulverized polymer is performed at a temperature of 100° C. to 250° C.8. The preparation method of the superabsorbent polymer of claim 1 , wherein the surface crosslinking is performed by reacting one or more surface crosslinking agents selected from the group consisting of ethylene glycol diglycidyl ether claim 1 , polyethylene glycol diglycidyl ether claim 1 , glycerol ...

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10-09-2015 дата публикации

COLORED METALLIC PIGMENT AND COLORED ARTICLE

Номер: US20150252153A1
Принадлежит: TOYO ALUMINIUM KABUSHIKI KAISHA

A colored metallic pigment of the present invention contains a metallic pigment, a coloring pigment, a first compound and a second compound. The coloring pigment adheres to the surface of the metallic pigment in the coexistence of the first compound and the second compound, the first compound is a compound having two or more carboxyl groups, and the second compound is a compound having one or more amino groups. 16.-. (canceled)7. A colored metallic pigment comprising a metallic pigment , a coloring pigment , a first compound , and a second compound , whereinsaid coloring pigment adheres to a surface of said metallic pigment in coexistence of said first compound and said second compound in a state where said first compound and/or said second compound does not adhere to said metallic pigment in advance,said first compound is a polymer of an unsaturated carboxylic acid having two or more carboxyl groups, andsaid second compound is an amine having one or more amino groups.8. A colored metallic pigment comprising a metallic pigment , a coloring pigment , a first compound , and a second compound , whereinsaid coloring pigment adheres to a surface of said metallic pigment in coexistence of said first compound and said second compound,said first compound is a compound having two or more carboxyl groups, andsaid second compound is an amine having two or more amino groups (excluding a case where said second compound is a polymer).9. A colored metallic pigment comprising a metallic pigment , a coloring pigment , a first compound , and a second compound , whereinsaid coloring pigment adheres to a surface of said metallic pigment in coexistence of said first compound and said second compound,said first compound is a compound having two or more carboxyl groups, andsaid second compound is an amine that is a monomer having two or more amino groups.10. The colored metallic pigment according to claim 7 , whereinsaid first compound is a polymerized carboxylic acid obtained by ...

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24-08-2017 дата публикации

RESIN COMPOSITION AND OPTICAL COMPENSATION FILM USING SAME

Номер: US20170242174A1
Принадлежит: TOSOH CORPORATION

A resin composition suitable for an optical compensation film, an optical compensation film using the same, which is excellent in the retardation characteristics and wavelength dispersion characteristics, and a production method of an optical compensation film. A resin composition containing, as resin components, from 30 to 99 wt % of a cellulose-based resin represented by the following formula (1) and from 1 to 70 wt % of a cinnamic acid ester copolymer: 12: The resin composition according to claim 10 , wherein the fumaric acid monoester residue unit is a fumaric acid monoester residue unit selected from the group consisting of a monomethyl fumarate residue unit claim 10 , a monoethyl fumarate residue unit claim 10 , a monoisopropyl fumarate residue unit claim 10 , a mono-n-propyl fumarate residue unit claim 10 , a mono-n-butyl fumarate residue unit claim 10 , a mono-s-butyl fumarate residue unit claim 10 , a mono-tert-butyl fumarate residue unit claim 10 , and a mono-2-ethylhexyl fumarate residue unit.14: The resin composition according to claim 9 , wherein the p-position-substituted cinnamic acid ester residue unit is selected from the group consisting of a methyl 4-nitrocinnamate residue unit claim 9 , an ethyl 4-nitrocinnamate residue unit claim 9 , an isopropyl 4-nitrocinnamate residue unit claim 9 , an n-propyl 4-nitrocinnamate residue unit claim 9 , an n-butyl 4-nitrocinnamate residue unit claim 9 , a sec-butyl 4-nitrocinnamate residue unit claim 9 , a tert-butyl 4-nitrocinnamate residue unit claim 9 , a 2-ethylhexyl 4-nitrocinnamate residue unit claim 9 , a methyl 4-fluorocinnamate residue unit claim 9 , an ethyl 4-fluorocinnamate residue unit claim 9 , an isopropyl 4-fluorocinnamate residue unit claim 9 , an n-propyl 4-fluorocinnamate residue unit claim 9 , an n-butyl 4-fluorocinnamate residue unit claim 9 , a sec-butyl 4-fluorocinnamate residue unit claim 9 , a tert-butyl 4-fluorocinnamate residue unit claim 9 , a 2-ethylhexyl 4-fluorocinnamate residue ...

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17-09-2015 дата публикации

FUNCTIONAL POLYMER MEMBRANE AND METHOD OF PRODUCING THE SAME

Номер: US20150259488A1
Принадлежит: FUJIFILM Corporation

A functional polymer membrane, prepared by curing a composition comprising a polymerizable compound (A) represented by Formula (1) and a monofunctional polymerizable compound (B): 4. The functional polymer membrane according to claim 3 , wherein Z in Formula (3) represents a polyol residue formed by removing n hydrogen atoms from hydroxyl groups of glycerin claim 3 , erythritol claim 3 , xylitol claim 3 , mannitol claim 3 , sorbitol claim 3 , pentaerythritol or dipentaerythritol.5. The functional polymer membrane according to claim 1 ,wherein the copolymerizable monomer (B) has a dissociative group.6. The functional polymer membrane according to claim 5 , wherein the dissociative group is selected from the group consisting of a sulfo group or a salt thereof claim 5 , a carboxy group or a salt thereof claim 5 , an ammonio group and a pyridinio group.7. The functional polymer membrane according to claim 1 ,wherein the copolymerizable monomer (B) is a (meth)acrylate compound or a (meth)acrylamide compound.8. The functional polymer membrane according to claim 3 , wherein a content of the polymerizable compound (A) represented by Formula (3) in the composition is 1 to 40% by mass.9. The functional polymer membrane according to claim 2 , wherein a content of the polymerizable compound (A) represented by Formula (2) is 1 to 45 parts by mass based on 100 parts by mass of the monofunctional polymerizable compound (B).10. The functional polymer membrane according to claim 3 , wherein a content of the polymerizable compound (A) represented by Formula (3) is 10 to 200 parts by mass based on 100 parts by mass of the monofunctional polymerizable compound (B).11. The functional polymer membrane according to claim 1 , wherein the composition contains a solvent (E).12. The functional polymer membrane according to claim 11 , wherein the solvent (E) is selected from water and a water-soluble solvent.13. The functional polymer membrane according to claim 11 , wherein a content of the ...

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17-09-2015 дата публикации

POLYACRYLIC ACID-TYPE WATER ABSORBENT RESIN AND METHOD FOR PRODUCING SAME

Номер: US20150259494A1
Принадлежит:

Provided is a method for producing a water absorbent resin, which promotes the formation of interconnected voids (continuous gas bubbles) in a foamed polymer (foam-like water absorbent resin) by a more convenient method, and produces with high efficiency a water absorbent resin which exhibits a high water absorption rate even when stepped into a sheet form or a powder form in hygiene articles and the like. Disclosed is a method for producing a polyacrylic acid-type water absorbent resin, comprising (A) a step of obtaining an aqueous solution of acrylic acid-type monomers containing gas bubbles dispersed therein; (B) a step of polymerizing the aqueous monomer solution and thereby obtaining a foamed polymer; and (C) a step of heating and drying the foamed polymer, 1. A polyacrylic acid-type water absorbent resin having an open gas bubble ratio of 5% or greater and the content of p-methoxyphenol is 60 ppm or less.2. The water absorbent resin according to claim 1 , wherein the independent gas bubble ratio is 5% or greater.3. The water absorbent resin according to claim 1 , comprising at least any one of a metal chelating agent and a reducing agent.4. The water absorbent resin according to claim 1 , wherein the water absorption rate (FSR) is 0.25 [g/g/s] or greater.5. The water absorbent resin according to claim 1 , wherein the water absorbent resin is surface-crosslinked by using a covalently bondable crosslinking agent and/or an ionically bondable crosslinking agent.6. The water absorbent resin according to claim 1 , which is in a sheet form.7. The water absorbent resin according to claim 1 , wherein the water absorbent resin is in the form of a powder having a weight average particle diameter (D50) of greater than or equal to 300 μm and less than 600 μm.8. A water absorbing article comprising the water absorbent resin according to . The present application is a divisional of commonly assigned copending patent application Ser. No. 13/807,530, filed on Dec. 28, 2012, ...

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24-09-2015 дата публикации

Multifunctional Hyperbranched Polymers

Номер: US20150266986A1
Принадлежит: NATIONAL UNIVERSITY OF IRELAND, GALWAY

A hyperbranched copolymer comprising PEG-based monomers is described wherein the hyperbranched copolymer comprises a double bond content in the range 5 mol % to 50 mol %. RAFT (Reverse Addition-Fragmentation chain Transfer) polymerisation is used to synthesise the PEG-based hyperbranched copolymer described herein. The hyperbranched copolymer can be used for the preparation of antibacterial hydrogels. 1. A hyperbranched copolymer comprising PEG-based monomers wherein the hyperbranched copolymer comprises a double bond content in the range 5 mol % to 50 mol %.2. A hyperbranched copolymer according to claim 1 , wherein the copolymer comprises a double bond content in the range 10 mol % to 25 mol % claim 1 , preferably at least 24 mol %.3. A hyperbranched copolymer according to claim 1 , wherein the copolymer comprises a degree of branching in the range 5 mol % to 30 mol % claim 1 , preferably at least 27 mol %.4. A hyperbranched copolymer according to claim 1 , wherein use of the copolymer is selected from the group consisting of a drug delivery vehicle claim 1 , a diagnostic tool claim 1 , a cross-linking agent claim 1 , a cross-linking agent in the preparation of a 3 dimensional printable material claim 1 , and an additive.5. A hyperbranched copolymer according to claim 1 , wherein the PEG-based monomers have molecular weights in the range 1000 Da to 500 kDa.6. A hyperbranched copolymer according to claim 1 , wherein the PEG based monomers comprise end functional groups selected from the group consisting of acrylate claim 1 , methacrylate claim 1 , hydroxyl claim 1 , carboxyl claim 1 , amine claim 1 , thiol claim 1 , aldehyde claim 1 , azide and sulphone and wherein the PEG-based monomers are selected from the group consisting of PEGDA ((poly)ethylene glycol)diacrylate) claim 1 , PEGAcryate ((poly)ethylene glycol)acrylate) claim 1 , PEGMEMA (poly(ethylene glycol)methyl ether methacrylate) claim 1 , PEGDMA (poly(ethylene glycol)dimethacrylate) and PEG methacrylate ( ...

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07-10-2021 дата публикации

POLYESTERS AND ARTICLES MADE THEREFROM

Номер: US20210309795A1
Принадлежит:

Disclosed herein are polyesters and articles made therefrom. The article comprising a substrate comprising a first surface and a second surface, the second surface in contact with an outside environment, wherein the substrate comprises a polymer comprising poly(trimethylene furandicarboxylate) (PTF), and wherein the polymer provides an improvement in gas barrier properties of the substrate as compared to a substrate comprising nascent poly(ethylene terephthalate) (PET).

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15-09-2016 дата публикации

FLUORINE-CONTAINING HIGHLY BRANCHED POLYMER AND RESIN COMPOSITION CONTAINING THE SAME

Номер: US20160264739A1
Принадлежит:

It is an object to provide a compound that can provide a molded article and a coating film excellent not only in solubility in an organic solvent, but also in miscibility with/dispersibility in a matrix resin, causing no aggregation in a matrix resin, excellent in surface modification property, and having high transparency. A fluorine-containing highly branched polymer obtained by polymerizing a monomer A having two or more radical polymerizable double bonds in the molecule thereof with a monomer B having a fluoroalkyl group and at least one radical polymerizable double bond in the molecule thereof in the presence of a polymerization initiator C in a content of 5% by mol or more and 200% by mol or less, based on the total molar amount of the monomer A and the monomer B; and a resin composition comprising the polymer. 1. A photopolymerizable composition comprising: 'any one of at least a part of the monomer and the polymerization initiator has a fluoroalkyl group in the molecule thereof;', 'a fluorine-containing highly branched polymer (a) obtained by polymerizing a monomer A having two or more radical polymerizable double bonds in the molecule thereof in the presence of a polymerization initiator C in a content of 5% by mol or more and 200% by mol or less, relative to 1 mol of the monomer A, wherein'}a photopolymerizable compound (b); anda photopolymerization initiator (c).2. The photopolymerizable composition according to claim 1 , wherein the photopolymerizable compound (b) is a multifunctional (meth)acrylate compound.3. The photopolymerizable composition according to claim 2 , wherein the photopolymerizable compound (b) is tricyclodecanedimethanol di(meth)acrylate.4. The photopolymerizable composition according to claim 1 , wherein the content of the fluorine-containing highly branched polymer (a) is 0.01% by mass to 20% by mass claim 1 , based on the total mass of the photopolymerizable compound (b).5. A resin-molded article produced by photopolymerizing the ...

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15-08-2019 дата публикации

POLYESTERS AND ARTICLES MADE THEREFROM

Номер: US20190248954A1
Принадлежит:

Disclosed herein are polyesters and articles made therefrom. The article comprising a substrate comprising a first surface and a second surface, the second surface in contact with an outside environment, wherein the substrate comprises a polymer comprising poly(trimethylene furandicarboxylate) (PTF), and wherein the polymer provides an improvement in gas barrier properties of the substrate as compared to a substrate comprising nascent poly(ethylene terephthalate) (PET). 1. An article comprising:a substrate comprising a first surface and a second surface, the second surface in contact with an outside environment.wherein the substrate comprises a polymer comprising poly(trimethylene furandicarboxylate) (PTF), andwherein the polymer provides an improvement in gas barrier properties of the substrate as compared to a substrate consisting of nascent poly(ethylene terephthalate) (PET),wherein the improvement for oxygen is in the range of 2-99%, an improvement for carbon dioxide is in the range of 11-99%, and an improvement for moisture is in the range of 3-99%.2. The article of claim 1 , wherein polymer provides an improvement in the range of 50-98% in oxygen barrier properties of the substrate.3. The article of claim 1 , wherein polymer provides an improvement in the range of 50-98% in carbon dioxide barrier properties of the substrate.4. The article of claim 1 , wherein polymer provides an improvement in the range of 25-75% in moisture barrier properties of the substrate.5. The article of claim 1 , wherein the polymer has a crystallinity of less than 100 J/g claim 1 , as measured by differential scanning calorimetry with heating rates of 10° C./min.6. The article of claim 1 , wherein the polymer is a polymer blend comprising poly(trimethylene furandicarboxylate) (PTF) and poly(alkylene furandicarboxylate) claim 1 , andwherein the polymer comprises 0.1-99.9% by weight of PTF based on the total weight of the polymer blend.7. The article of claim 1 , wherein the polymer is ...

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14-10-2021 дата публикации

PORE INDUCER AND POROUS ABRASIVE FORM MADE USING THE SAME

Номер: US20210317282A1
Принадлежит:

Various embodiments disclosed relate to pore inducers and porous abrasive forms made using the same. In various embodiments, the present invention provides a method of forming a porous abrasive form including heating an abrasive composition including pore inducers to form the porous abrasive form. During the heating the pore inducers in the porous abrasive form reduce in volume to form induced pores in the porous abrasive form. 1. A method of forming a porous abrasive form , the method comprising:heating an abrasive composition to form the porous abrasive form, the abrasive composition comprising a plurality of pore inducers, the plurality of pore inducers having a pore inducer composition that comprises a cured component; andwherein during the heating the pore inducers in the porous abrasive form reduce in volume to form induced pores in the porous abrasive form, wherein the induced pores substantially correspond in shape and location to that of the pore inducers in the abrasive composition prior to the heating.2. The method of claim 1 , further comprising forming the abrasive composition.3. The method of claim 1 , further comprising forming the plurality of pore inducers.4. The method of claim 1 , wherein forming the pore inducers further comprises placing the pore inducer starting material composition in a mold prior to the curing claim 1 , wherein the curing is performed while the pore inducer starting material composition is in the mold claim 1 , further comprising removing the pore inducers from the mold after the curing.5. The method of claim 1 , wherein the induced pores approximately correspond in size to that of the pore inducers in the abrasive composition prior to the heating.6. The method of claim 1 , wherein during the heating one or more components of the pore inducers melt or become flowable.7. The method of claim 1 , wherein during the heating one or more components of the pore inducers vaporize claim 1 , sublime claim 1 , decompose claim 1 , ...

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14-09-2017 дата публикации

FIBER-REINFORCED RESIN MOLDING MATERIAL AND PRODUCTION METHOD THEREOF

Номер: US20170260345A1
Принадлежит:

A fiber-reinforced resin molding material includes at least bundled discontinuous reinforcing fiber aggregates and matrix resin, wherein said bundled reinforcing fiber aggregates include both reinforcing fiber aggregates (A) which are formed by cutting continuous reinforcing fiber strands after fiber splitting, in which said strands are completely split into multiple bundles, and reinforcing fiber aggregates (B) having at least unsplit strand sections in which fiber splitting is incomplete, an incision substantially originating from fiber splitting is present at least at one of both end portions of said reinforcing fiber aggregates (B), and a ratio of the weight of said reinforcing fiber aggregates (B) to the total weight of reinforcing fibers in said material is 5-50%. 15-. (canceled)6. A fiber-reinforced resin molding material comprising at least bundled discontinuous reinforcing fiber aggregates and matrix resin , wherein said bundled reinforcing fiber aggregates comprise both reinforcing fiber aggregates (A) which are formed by cutting continuous reinforcing fiber strands after fiber splitting , in which said strands are completely split into multiple bundles , and reinforcing fiber aggregates (B) having at least unsplit strand sections in which fiber splitting is incomplete , an incision substantially originating from fiber splitting is present at least at one of both end portions of said reinforcing fiber aggregates (B) , and a ratio of the weight of said reinforcing fiber aggregates (B) to the total weight of reinforcing fibers in said material is 5-50%.7. The fiber-reinforced resin molding material according to claim 6 , wherein an average fiber length of said reinforcing fiber aggregates (A) and said reinforcing fiber aggregates (B) is 5-100 mm.8. The fiber-reinforced resin molding material according to claim 6 , wherein a number of single fibers of said reinforcing fiber aggregates (A) is 800-10 claim 6 ,000.9. The fiber-reinforced resin molding material ...

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14-09-2017 дата публикации

RESIN COMPOSITION AND USES OF THE SAME

Номер: US20170260365A1
Принадлежит:

A resin composition, comprising the following components: 2. The resin composition of claim 1 , wherein the amount of the metal hypophosphite (b) is 10 wt % to 22 wt % based on the total weight of the resin system (a) and the metal hypophosphite (b).3. The resin composition of claim 1 , wherein a is an integer from 1 to 3 claim 1 , and M is an ion of a metal selected from the group consisting of lithium claim 1 , sodium claim 1 , potassium claim 1 , magnesium claim 1 , calcium claim 1 , strontium claim 1 , barium claim 1 , and aluminum.4. The resin composition of claim 3 , wherein a is 3 claim 3 , and M is Al.5. The resin composition of claim 1 , wherein the resin system (a) comprises thermal-curable resin(s) selected from the group consisting of polyphenylene ether resins claim 1 , bismaleimide resins claim 1 , isocyanurates containing vinyl and/or allyl claim 1 , elastomers containing butadiene and/or styrene claim 1 , and epoxy resins.6. The resin composition of claim 2 , wherein the resin system (a) comprises thermal-curable resin(s) selected from the group consisting of polyphenylene ether resins claim 2 , bismaleimide resins claim 2 , isocyanurates containing vinyl and/or allyl claim 2 , elastomers containing butadiene and/or styrene claim 2 , and epoxy resins.7. The resin composition of claim 3 , wherein the resin system (a) comprises thermal-curable resin(s) selected from the group consisting of polyphenylene ether resins claim 3 , bismaleimide resins claim 3 , isocyanurates containing vinyl and/or allyl claim 3 , elastomers containing butadiene and/or styrene claim 3 , and epoxy resins.8. The resin composition of claim 4 , wherein the resin system (a) comprises thermal-curable resin(s) selected from the group consisting of polyphenylene ether resins claim 4 , bismaleimide resins claim 4 , isocyanurates containing vinyl and/or allyl claim 4 , elastomers containing butadiene and/or styrene claim 4 , and epoxy resins.11. The resin composition of claim 5 , ...

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21-09-2017 дата публикации

POLYMER-ENCAPSULATED PIGMENT PARTICLE

Номер: US20170267792A1
Автор: Ness Jason
Принадлежит: Valspar Sourcing, Inc.

A polymer-encapsulated pigment dispersion is prepared from a mixture of (a) a carrier; (b) pigment particles; and (c) a polymeric dispersing agent having a polymer backbone, and an alkali-swellable copolymer component. The dispersing agent may provide efficient pigment wetting and dispersion using relatively low and thus economical dispersant amounts, and subsequently enable formation of polymer-encapsulating pigment dispersions that, when used in coatings, provide good opacity and good hiding characteristics, especially in titanium dioxide-containing coating compositions.

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20-09-2018 дата публикации

CATALYST-FREE SURFACE FUNCTIONALIZATION AND POLYMER GRAFTING

Номер: US20180265660A1
Принадлежит:

Some embodiments described herein relate to a substrate with a surface comprising a silane or a silane derivative covalently attached to optionally substituted cycloalkene or optionally substituted heterocycloalkene for direct conjugation with a functionalized molecule of interest, such as a polymer, a hydrogel, an amino acid, a nucleoside, a nucleotide, a peptide, a polynucleotide, or a protein. In some embodiments, the silane or silane derivative contains optionally substituted norbornene or norbornene derivatives. Method for preparing a functionalized surface and the use in DNA sequencing and other diagnostic applications are also disclosed. 1. A method of grafting primers on a first surface of a substrate , the method comprising:providing pre-conjugated primers comprising oligonucleotides covalently bonded to a functionalized molecule, wherein the functionalized molecule comprises functional groups; andcontacting the pre-conjugated primers with a substrate having a first surface comprising a silane or a silane derivative, wherein the silane or silane derivative comprises a first plurality of unsaturated moieties selected from the group consisting of cycloalkenes, cycloalkynes, heterocycloalkenes, heterocycloalkynes, and optionally substituted variants and combination thereof covalently attached thereto, and wherein the pre-conjugated primers are covalently bound to the first surface of the substrate through the reaction of the functional groups of the functionalized molecule with the first plurality of unsaturated moieties of the silane or silane derivative.2. The method of claim 1 , wherein the pre-conjugated primers are prepared by reacting the functional groups of the functionalized molecule with a second plurality of unsaturated moieties of the oligonucleotides to form covalent bonding claim 1 , and wherein the second plurality of unsaturated moieties of the oligonucleotide are selected from the group consisting of alkynes claim 1 , cycloalkenes claim 1 , ...

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