22-07-2021 дата публикации
Номер: US20210221931A1
Принадлежит:
PROMERUS, LLC
Embodiments in accordance with the present invention encompass compositions encompassing a latent organo-ruthenium compound, a pyridine compound, a photosensitizer and an ultra violet light blocking compound along with one or more monomers which undergo ring open metathesis polymerization (ROMP) when said composition is exposed to suitable actinic radiation to form a substantially transparent film or a three dimensional object. Surprisingly, the compositions are very stable at ambient conditions to temperatures up to 80° C. for several days and undergo mass polymerization only when subjected to actinic radiation under inert atmosphere such as for example a blanket of nitrogen. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as 3D printing materials, coatings, encapsulants, fillers, leveling agents, among others. 2. The composition according to claim 1 , wherein said composition comprises first and second monomer of formula (I) distinct from each other and one of said first and second monomers having a refractive index of at least 1.5 and viscosity below 100 centipoise claim 1 , and wherein said first monomer is completely miscible with said second monomer to form a clear solution.4. The composition according to claim 1 , wherein:{'sub': 3', '3', '3', '3, 'L is selected from the group consisting of P(iPr), P(tert-Bu), PCyand PPh;'}{'sub': 7', '8, 'Rand Rare the same or different and each independently selected from the group consisting of hydrogen, methyl, ethyl and isopropyl;'}{'sub': '9', 'Ris selected from the group consisting of hydrogen, methyl, ethyl and isopropyl;'}{'sub': 1', '2', '3, 'Ar, Arand Arare the same or different and each independently selected from the group consisting of phenyl, 2,6-dimethylphenyl, 2,6-diethylphenyl, 2,6-di(isopropyl)phenyl and 2,4,6-trimethylphenyl.'}6. The composition according to claim 1 , wherein:n is an integer from 0 to 2;{'sub': '10', 'each Ris independently selected ...
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