24-01-2019 дата публикации
Номер: US20190023948A1
Принадлежит:
Provided are curable precursor compositions for pressure-sensitive adhesives and related articles, assemblies and methods. The provided compositions contain an alkyl (meth)acrylate, a hollow non-porous particulate filler, and a surface-modifying agent comprising a hydrophobic alkoxy silane or hydrophobic organofunctional polysiloxane. These compositions and methods enable in situ functionalization of the filler particles during or after the time they are combined with the curable resin components, thereby allowing pressure-sensitive adhesive materials to be made faster and more efficiently than when using conventional manufacturing methods. 1. A curable precursor composition for a pressure-sensitive adhesive comprising:an alkyl (meth)acrylate;a hollow non-porous particulate filler; anda surface-modifying agent comprising a hydrophobic alkoxy silane or hydrophobic organofunctional polysiloxane.2. The curable precursor composition of claim 1 , wherein the hollow non-porous particulate filler consists of hollow glass microspheres.3. The curable precursor composition of claim 1 , wherein the surface-modifying agent has the following chemical structure:{'br': None, 'sup': 1', '2', '1', '2', '1', '2', 'r, 'sub': m', 'p', 'q', '2-q', 'x', 'm', '3-m, '(R—O)(R)Si—[(O—Si(OR)(R))—Si(O—R)(R)],'}{'sup': 1', '2', '1', '2, 'wherein Ris independently an alkyl, Ris independently a hydrophobic moiety, m is in a range of from 0 to 3, p is in a range of from 0 to 3, q is in a range of from 0 to 2, r is in a range of from 0 to 4, x is in a range of from 0 to 9, wherein the sum m+p+r equals 4 and wherein at least one Rand at least one Rare present.'}4. The curable precursor composition of claim 3 , wherein Rhas from 1 to 4 carbon atoms.5. The curable precursor composition of claim 4 , wherein Rhas 1 or 2 carbon atoms.6. The curable precursor composition of claim 3 , wherein the hydrophobic moiety has from 1 to 25 carbon atoms.7. The curable precursor composition of claim 3 , wherein Ris ...
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