01-04-2021 дата публикации
Номер: US20210094017A1
Принадлежит:
LG CHEM, LTD.
Provided is a method of preparing a superabsorbent polymer. More particularly, provided is a method of preparing a superabsorbent polymer having a rapid absorption rate and an improved water retention capacity by additional heat treatment while using a thermally degradable internal crosslinking agent and an encapsulated foaming agent at the same time during polymerization. 2. The method of preparing a superabsorbent polymer of claim 1 ,{'sup': '1', 'sub': -diyl,', '-diyl., 'wherein the internal crosslinking agent includes the compound of Chemical Formula 1, in which Ris methane-1,1-diyl, propane-1,3-diyl, propane-1,2-diyl, propane-1,1-diyl, n-butane-1,4-diyl, n-butane-1,3-diyl, n-butane-1,2-diyl, n-butane-1,1-diyl, 2-methylpropane-1,3-diyl, 2-methylpropane-1,2-diyl, 2-methylpropane-1,12-methylbutane-1,4-diyl, 2-methylbutane-2,4-diyl, 2-methylbutane-3,4-diyl, 2-methylbutane-4,4-diyl, 2-methylbutane-1,3-diyl, 2-methylbutane-1,2-diyl, 2-methylbutane-1,1-diyl, 2-methylbutane-2,3-diyl, 3-methylbutane-1,2-diyl, or 3-methylbutane-1,3'}3. The method of preparing a superabsorbent polymer of claim 1 ,wherein the internal crosslinking agent includes the compound represented by Chemical Formula 1 in an amount of 1% by weight to 100% by weight with respect to the a total weight of the internal crosslinking agent.4. The method of preparing a superabsorbent polymer of claim 1 ,wherein the internal crosslinking agent is used in an amount of 0.1 part by weight to 0.6 parts by weight with respect to 100 parts by weight of the water-soluble ethylenically unsaturated monomer.5. The method of preparing a superabsorbent polymer of claim 1 ,wherein the encapsulated foaming agent has a mean diameter of 5 μm to 50 μm before expansion.6. The method of preparing a superabsorbent polymer of claim 1 ,wherein the encapsulated foaming agent has a core-shell structure, in which a core contains a hydrocarbon and a shell composed of a thermoplastic resin is formed on the core.7. The method of ...
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