08-05-2014 дата публикации
Номер: US20140128538A1
The present invention relates to the field of the vulcanization of unsaturated polymers, in particular unsaturated halogenated polymers and more particularly unsaturated chlorinated polymers, such as, for example, polychloroprene, by using, as vulcanization agent, a mixture of bis(2,5-dimercapto-1,3,4-thiadiazole) and at least one organic base. The present invention relates to the process for the vulcanization of the said polymers with the said vulcanization mixture. 18-. (canceled)9. A composition for the vulcanization of unsaturated polymers , comprising a mixture of bis(2 ,5-dimercapto-1 ,3 ,4-thiadiazole) and at least one organic base.10. The composition according to claim 9 , wherein the at least one organic base is chosen from nitrogenous organic bases.11. The composition according to claim 10 , wherein the at least one organic base comprises a guanidine.12. The composition according to claim 10 , wherein the at least one organic base comprises a substituted guanidine.13. The composition according to claim 12 , wherein the at least one organic base is a guanidine substituted by one or more aryl groups.14. The composition according to claim 12 , wherein the at least one organic base comprises diphenylguanidine.15. The composition according to claim 9 , wherein the bis(2 claim 9 ,5-dimercapto-1 claim 9 ,3 claim 9 ,4-thiadiazole) to organic base molar ratio is between 1:99 and 99:1.16. The composition according to claim 15 , wherein the bis(2 claim 15 ,5-dimercapto-1 claim 15 ,3 claim 15 ,4-thiadiazole) to organic base molar ratio is between 25:75 and 75:25.17. The composition according to claim 15 , wherein the bis(2 claim 15 ,5-dimercapto-1 claim 15 ,3 claim 15 ,4-thiadiazole) to organic base molar ratio is approximately 50:50.18. A process for the vulcanization of an unsaturated polymer claim 15 , comprising:mixing the unsaturated polymer with a mixture of bis(2,5-dimercapto-1,3,4-thiadiazole) and at least one organic base, andvulcanizing the unsaturated ...
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