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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 13293. Отображено 100.
05-01-2012 дата публикации

Adhesive and adhesive sheet

Номер: US20120000599A1
Принадлежит: Denki Kagaku Kogyo KK

Provided is a adhesive and an adhesive sheet which exhibit excellent chip-holding properties during dicing and from which chips can be easily stripped during pick up, even when considering changes over time. It is a adhesive composition which contains both (A) a (meth)acrylic acid ester copolymer component that has functional-group containing monomer units and a weight average molecular weight of less than 350,000 and (B) a (meth)acrylic ester copolymer component that has functional-group containing monomer units and a weight average molecular weight of 350,000 to 2,000,000 at a weight ratio of 10:90 to 90:10, and further contains 0.5 to 20 parts by mass of a crosslinking agent per 100 parts by mass of components (A) and (B) in total, the crosslinking agent being a crosslinking agent that reacts with both the functional groups of the component (A) and the functional groups of the component (B).

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02-02-2012 дата публикации

Sequentially cross-linked polyethylene

Номер: US20120029160A1
Принадлежит: Howmedica Osteonics Corp

A method of producing an improved polyethylene, especially an ultra-high molecular weight polyethylene utilizes a sequential irradiation and annealing process to form a highly cross-linked polyethylene material. The use of sequential irradiation followed by sequential annealing after each irradiation allows each dose of irradiation in the series of doses to be relatively low while achieving a total dose which is sufficiently high to cross-link the material. The process may either be applied to a preformed material such as a rod or bar or sheet made from polyethylene resin or may be applied to a finished polyethylene part.

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16-02-2012 дата публикации

Energy-ray-curable elastomer composition, material for gasket, gasket, and hard disk device

Номер: US20120041096A1
Принадлежит: Bridgestone Corp

Provided is an energy ray-curable elastomer composition which can increase the inter-crosslinking point molecular weight without changing the kind of an energy ray-curable compound before cured and which provides an oligomer-cured substance having a braking elongation compatible with a processability, to be specific, an energy ray-curable elastomer composition containing (A) an energy ray-curable compound having a (meth)acryloyl group and (B) a polythiol compound having 2 to 6 mercapto groups in a molecule, wherein a functional group number ratio of the (meth)acryloyl group in the above composition to the mercapto group in the component (B) is 100:0.1 to 100:5n (n is the number of the mercapto group in a molecule of the polythiol compound). Further, provided are a material for a gasket containing the energy ray-curable elastomer composition described above which provides a gasket enhancing a braking elongation without damaging a processability and other necessary physical properties and making it possible to inhibit cracking, breaking and the like from being caused, a gasket comprising a substance obtained by curing the above material for a gasket by an energy ray and a hard disk device prepared by using the above gasket.

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15-03-2012 дата публикации

Curable adhesive system, method of assembly of distinct components therewith

Номер: US20120064274A1
Принадлежит: Teknor Apex Co

An adhesive system including a synergistic combination of a light curable silicone-containing adhesive composition and an amine-containing primer composition that provides desirable bond strength between two articles preferably one of the articles including a polyolefin or polyolefin-based thermoplastic elastomer. Methods of connecting articles, preferably those utilized in fluid transfer applications, utilizing the adhesive system and the resulting adhered assemblies are disclosed.

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29-03-2012 дата публикации

Crosslinked Polyolefin Polymer Blends

Номер: US20120077898A1
Автор: Sunny Jacob
Принадлежит: ExxonMobil Chemical Patents Inc

Crosslinked polyolefin blends, methods for their production, and articles made of the same are provided. In at least one specific embodiment, the polyolefin blends comprise a first polymer formed in a first reactor and a second polymer formed in a second reactor. The first and second polymers, as well as the resulting blend, may comprise units derived from propylene, ethylene, and a diene. The blended composition can then be compounded with one or more coagents, antioxidants, UV sensitizers, and/or other additives and crosslinked, preferably by exposure to UV radiation and/or energetic photons. The crosslinked polymers are particularly useful for making fibers, films, and nonwovens.

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24-05-2012 дата публикации

Crosslinked Flame Retardant Thermoplastic Elastomer Gels

Номер: US20120129962A1
Принадлежит: Tyco Electronics Corp

Crosslinked flame retardant thermoplastic elastomer gels are provided. The crosslinked flame retardant thermoplastic elastomer gels comprise a char catalyst, a char former, a maleic anhydride-modified styrene ethylene/butylene styrene polymer, and a softener oil. Methods are provided of making crosslinked flame retardant thermoplastic elastomer gels.

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09-08-2012 дата публикации

Organic-inorganic composite resin composition, organic-inorganic composite resin material, optical element, and stacked diffraction optical element

Номер: US20120200925A1
Принадлежит: Canon Inc

Provided are an organic-inorganic composite resin composition and an organic-inorganic composite resin material made of a cured product thereof, containing at least an organic compound having a polymerizable functional group, metal oxide fine particles, and a polymerization initiator. The cured product obtained by curing the organic-inorganic composite resin composition through application of an active energy has a refractive index nd of 1.61 or more and 1.65 or less, Abbe's number νd of 13 or more and 20 or less, and an anomalous dispersion characteristic θg,F of 0.42 or more and 0.54 or less. Further provided is an optical element comprising a transparent substrate and the organic-inorganic composite resin material formed on the transparent substrate.

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23-08-2012 дата публикации

Process for producing thermoplastic elastomer composition

Номер: US20120214943A1
Принадлежит: Yokohama Rubber Co Ltd

Disclosed is a process for producing a thermoplastic elastomer composition having a matrix phase comprising a polyamide and an ethylene/vinyl alcohol copolymer and a disperse phase comprising a rubber composition, by which gelation by a reaction between a polyamide and an ethylene/vinyl alcohol copolymer can be inhibited and the dispersion of the rubber composition can be good. In the process, the polyamide resin and the rubber composition are melt-blended to the extent necessary for the rubber composition to form a disperse phase, and then the ethylene/vinyl alcohol copolymer is added and further melt-blended together.

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30-08-2012 дата публикации

Environmentally Friendly, Polymer Dispersion-Based Coating Formulations and Methods of Preparing and Using Same

Номер: US20120220705A1
Принадлежит: BASF SE

Environmentally friendly, high performance coating formulations and methods for their preparation are described. The coating formulations can be prepared as aqueous dispersions. The aqueous dispersions include a plurality of multiphase polymer particles and a C8-C18 alkyl alcohol alkoxylated phosphate ester surfactant. The multiphase particles include an acrylic-based copolymer derived from one or more (meth)acrylate monomers and at least one copolymerizable surfactant. Optionally, the acrylic-based copolymer is further derived from one or more acid monomers, one or more amide monomers, and/or one or more molecular weight regulators. Further described herein are products prepared from the aqueous dispersions, such as for high gloss and satin paint compositions, that can have a low VOC content.

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01-11-2012 дата публикации

Surface covering materials and products

Номер: US20120277365A1
Принадлежит: American Biltrite Canada Ltd

In various embodiments, the present inventions provide a heat and color stable flooring materials/product comprising between about 1 wt % to about 50 wt % a polyolefin-based elastomer material; between about 2 wt % to about 50 wt % a polyolefin-based thermoplastic material; between about 20 wt % to about 75 wt % a filler; and between about 0.25 wt % to about 5 wt % a curing system containing a peroxide. Also provided in various embodiments are method of making and using such a flooring material/product.

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08-11-2012 дата публикации

Rubber Composition Including an Expoxide Resin

Номер: US20120283360A1
Принадлежит: Individual

A rubber composition which can be used in particular in tires, based on at least one diene elastomer, one reinforcing filler, one crosslinking system, between 1 and 20 phr of an epoxide resin and between 1 and 15 phr of an amine-comprising curing agent. The pair formed of epoxide resin with an amine-comprising curing agent advantageously replaces the pair formed of phenol/formaldehyde resin, which is a methylene acceptor, with the curing agent(s) HMT or H3M, which are conventional methylene donors. The use of this pair of reactants, epoxide resin and amine-comprising curing agent, makes it possible to obtain rubber compositions exhibiting a greater low-strain stiffness in comparison with conventional rubber compositions, without significantly damaging the hysteresis. Moreover, the combination of a phenolic resin, which is a methylene acceptor, with HMT or H3M, which is a methylene donor, produces formaldehyde during the vulcanization of the rubber composition. In point of fact, it is desirable to reduce, indeed even in the long run to eliminate, the formaldehyde of rubber compositions due to the environmental impact of this compound.

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21-02-2013 дата публикации

Sequentially cross-linked polyethylene

Номер: US20130046042A1
Принадлежит: Howmedica Osteonics Corp

A method of producing an improved polyethylene, especially an ultra-high molecular weight polyethylene utilizes a sequential irradiation and annealing process to form a highly cross-linked polyethylene material. The use of sequential irradiation followed by sequential annealing after each irradiation allows each dose of irradiation in the series of doses to be relatively low while achieving a total dose which is sufficiently high to cross-link the material. The process may either be applied to a preformed material such as a rod or bar or sheet made from polyethylene resin or may be applied to a finished polyethylene part.

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25-04-2013 дата публикации

Cross-Linked Polyolefin Composition

Номер: US20130102735A1
Принадлежит: Basell Poliolefine Italia Srl

A cross-linked composition obtained by cross-linking a polyolefin composition (I) comprising, all percentages being by weight: A) from 5 to 38% of a polypropylene; B) from 35 to 85% of a copolymer of ethylene with propylene, containing from 42 to 70% of ethylene and having solubility in xylene at room temperature greater than 50%; C) from 5 to 40% of a butene-1 homopolymer or copolymer having: a content of butene-1 derived units of 75% or more; a flexural modulus of 100 MPa or less; and optionally, D) from 5 to 35% of one or more polymers different from B) in composition, having a Shore A hardness value equal to or lower than 90 points, wherein the content of butene-1, if present, is of less than 50%; in which composition (I) the amounts of A), B), C) and D) are referred to the total weight of A)+B)+C) and optionally D), and when D) is present, the total weight of C)+D) is of 50% or less, referred to the total weight of A)+B)+C)+D).

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16-05-2013 дата публикации

Z-axis conductive article and method of making the same

Номер: US20130118773A1
Принадлежит: 3M Innovative Properties Co

A Z-axis conductive article includes an adhesive layer having a first major surface and a second major surface opposite the first major surface. The adhesive layer includes a dielectric pressure-sensitive adhesive and conductive magnetic particles aligned in mutually isolated conductive pathways extending from the first major surface to the second major surface of the adhesive layer. A method of making the same is also disclosed.

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06-06-2013 дата публикации

Liquid resin composition and semiconductor device

Номер: US20130143983A1
Принадлежит: Sumitomo Bakelite Co Ltd

According to the invention, a liquid resin composition which has favorable wet spreadability after mounting of a chip and exhibits excellent solder cracking resistance even in a high-temperature solder reflow process at about 260° C., i.e., even when being used in lead-free solder, and a semiconductor package using the liquid resin composition are provided. In the liquid resin composition of the invention, an acrylic copolymer having a radical polymerizable functional group contains alkyl(meth)acrylate as a constituent monomer having a linear or branched alkyl group having 6 to 9 carbon atoms in an amount of 10 wt % to 40 wt % of the entire constituent monomers.

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27-06-2013 дата публикации

Laminate of an acrylic resin composition layer containing triazine based ultra-violet compounds and an organosiloxane resin composition layer

Номер: US20130165570A1
Принадлежит: Teijin Chemicals Ltd

A laminate having excellent weatherability and abrasion resistance as well as adhesion. The laminate comprises a base, a first layer formed by thermally curing an acrylic resin composition and a second layer formed by thermally curing an organosiloxane resin composition, all of which are formed in the mentioned order, wherein the acrylic resin composition comprises: (A) an acrylic copolymer which contains at least 70 mol % of a recurring unit represented by the following formula (A): wherein X is a hydrogen atom or methyl group, and Y is a methyl group, ethyl group, cycloalkyl group, hydroxyalkyl group having 2 to 5 carbon atoms or triazine-based ultraviolet absorber residue; (B) a blocked polyisocyanate compound; (C) a curing catalyst; and (D) a triazine-based ultraviolet absorber, and the organosiloxane resin composition comprises: (E) colloidal silica and (F) a hydrolysis condensate of an alkoxysilane.

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04-07-2013 дата публикации

Analyte sensor

Номер: US20130168609A1
Автор: Eric Lee, Mark Micklatcher
Принадлежит: SENOVA SYSTEMS Inc

Matrix materials, such as sol-gels and polymers derivatives to contain a redox active material can be used to form electrodes and probes suitable for use in pH meters and other analyte sensing devices.

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31-10-2013 дата публикации

Radiation curable coating composition containing low molecular weight polytrimethylene ether glycol

Номер: US20130289129A1
Принадлежит: US COATINGS IP CO LLC

The present disclosure is directed to a radiation curable coating composition comprising low molecular weight polytrimethylene ether glycol. This disclosure is further directed to an antimicrobial coating layer formed from the coating composition comprising low molecular weight polytrimethylene ether glycol. The coating compositions can be used as interior and exterior top coats, basecoats, primers, primer surfacers and primer fillers. The disclosure is particularly directed to a coating composition comprising components derived from renewable resources.

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31-10-2013 дата публикации

Cross-linked polymer particle for epoxy resin, epoxy resin composition, and epoxy cured material

Номер: US20130289211A1
Принадлежит: Mitsubishi Rayon Co Ltd

The invention discloses a cross-linked polymer particle for an epoxy resin, an epoxy resin composition containing the cross-linked polymer particle, the epoxy resin and a curing agent, and an epoxy cured material having qualities of colorless transparency and crack resistance as a result of curing the resin composition. The cross-linked polymer particle for the epoxy resin contains a (meth)acrylate monomer unit and a crosslinking monomer unit, wherein a volume average primary particle diameter is 0.5 to 10 μm, and a glass transition temperature of the monomer components excluding the crosslinking monomer is 30° C. or more by FOX formula calculation, and the refractivity at 23° C. is 1.490 to 1.510.

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13-02-2014 дата публикации

Medical rubber

Номер: US20140045999A1
Принадлежит: Sumitomo Rubber Industries Ltd

The present invention provides a medical rubber having high cleanliness and excellent compression set resistance. The present invention relates to a medical rubber including an ethylene-propylene-diene rubber crosslinked by an organic peroxide having no aromatic ring structure.

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06-03-2014 дата публикации

Pressure-sensitive adhesive composition

Номер: US20140065324A1
Принадлежит: LG Chem Ltd

The present invention relates to a pressure sensitive adhesive composition, a polarizer and a liquid crystal display device. The present invention may provide a pressure sensitive adhesive which can have excellent stress relaxation characteristic to effectively inhibit light leakage by dimension change of optical films such as polarizing plates. In addition, a pressure sensitive adhesive having excellent physical properties such as adhesion durability and workability may be provided.

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13-03-2014 дата публикации

Crosslinked polymer nanoparticles containing composition, method for preparing a copolymer using the composition, and vinyl chloride resin with improved foam molding properties

Номер: US20140073713A1
Принадлежит: LG Chem Ltd

Disclosed is a crosslinked polymer nanoparticle containing composition, a method for preparing a copolymer using the composition, and a vinyl chloride resin with improved foam molding properties. Processing aid in according with the present invention, provides the effects of improved foam molding properties and processibility of a vinyl chloride resin, during a foam molding process upon being added to the vinyl chloride resin.

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07-01-2021 дата публикации

BIOELECTRODE AND METHOD FOR PRODUCING BIOELECTRODE

Номер: US20210000371A1
Принадлежит:

A bioelectrode and a method for producing the bioelectrode are provided. The bioelectrode has a non-complicated structure, satisfactory elasticity, and is capable of preventing an increase of contact impedance due to an increase of the number of times of usage. The bioelectrode includes a support member, which is an electrically conductive member, and at least one electrode member, which is a member projecting from the support member. At least the electrode member is molded from an electrically conductive rubber containing a silicone rubber and treated metal particles containing a crosslinkable functional group on a surface thereof. 1. A bioelectrode comprising:a support member, which is an electrically conductive member; andat least one electrode member, which is a member projecting from the support member,wherein at least the electrode member is molded from an electrically conductive rubber, the electrically conductive rubber containing a silicone rubber and metal particles containing a crosslinkable functional group on a surface thereof.2. The bioelectrode according to claim 1 , wherein the crosslinkable functional group is at least one group selected from the group consisting of a hydrolyzable silyl group claim 1 , a silanol group claim 1 , a (meth)acryloyl group claim 1 , an amino group claim 1 , a ureide group claim 1 , an isocyanurate group claim 1 , an isocyanate group claim 1 , and an epoxy group.3. The bioelectrode according to claim 1 , wherein the metal particles are silver particles.4. The bioelectrode according to claim 1 , wherein the silicone rubber is a room temperature-curable liquid silicone rubber.5. The bioelectrode according to claim 1 , wherein the electrode member has a tip end part in a pointed shape.6. The bioelectrode according to claim 5 , wherein the electrode member has an inclined face claim 5 , which is a face formed by removal in the tip end part inclinedly to an extending direction.7. A method for producing a bioelectrode comprising ...

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06-01-2022 дата публикации

POLYBUTADIENE COMPOSITION AND METHOD FOR PRODUCING SAME

Номер: US20220002524A1
Принадлежит: JSR Corporation

A polybutadiene composition which enables the achievement of a rubber material that has excellent crack propagation resistance and a method for producing this polybutadiene composition are provided. A polybutadiene composition is produced by a method that comprises a step Y wherein 1,3-butadiene is polymerized in the presence of 1,2-polybutadiene and a lanthanoid catalyst. A polybutadiene composition which contains 1,2-polybutadiene and 1,4-polybutadiene, and which is obtained by polymerizing 1,3-butadiene in the presence of 1,2-polybutadiene and a lanthanoid catalyst. 1. A method for producing a polybutadiene composition , the method comprising:polymerizing 1,3-butadiene in the presence of 1,2-polybutadiene and a lanthanoid-containing catalyst.2. The method according to claim 1 , further comprising:preparing 1,2-polybutadiene by polymerizing 1,3-butadiene in the presence of a cobalt-containing catalyst.3. The method according to claim 2 , further comprising:adding an organoaluminum compound to a reaction mixture in the preparing to terminate a polymerizing reaction.4. The method according to claim 2 , wherein the polymerizing is polymerizing 1 claim 2 ,3-butadiene by adding the lanthanoid-containing catalyst to a reaction mixture prepared in the preparing.5. The method according to claim 2 , wherein the cobalt-containing catalyst comprises a cobalt compound claim 2 , a phosphine compound claim 2 , and an organoaluminum compound.6. The method according to claim 1 , wherein the 1 claim 1 ,2-polybutadiene is 1 claim 1 ,2-syndiotactic polybutadiene.7. The method according to claim 1 , wherein the lanthanoid-containing catalyst comprises a lanthanoid compound claim 1 , an organoaluminum compound claim 1 , and a halogen compound.8. The method according to claim 1 , whereinthe preparing comprises producing 1,4-polybutadiene having active ends; andthe method further comprises reacting the active ends of 1,4-polybutadiene with an alkoxysilane compound.9. The method ...

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03-01-2019 дата публикации

TIRE TREAD COMPRISING AT LEAST ONE METAL CHELATE AND/OR A PIGMENT

Номер: US20190001748A1
Принадлежит:

A tire tread is based on one or more diene elastomers, on one or more reinforcing fillers, on a crosslinking system, and on at least one compound (A) selected from a metal chelate comprising at least one ligand and at least one metal, a pigment and their mixture. 115.-. (canceled)16. A tire tread based on:one or more diene elastomers;one or more reinforcing fillers;a crosslinking system; andat least one compound A selected from the group consisting of a metal chelate comprising at least one ligand and at least one metal, a pigment and the mixture thereof.17. The tread according to claim 16 , wherein the at least one ligand is selected from cyclic tetrapyrrole derivatives selected from the group consisting of chlorins claim 16 , bacteriochlorins claim 16 , porphyrins claim 16 , hemins and phthalocyanines.18. The tread according to claim 17 , wherein the at least one ligand is selected from the group consisting of porphyrins and phthalocyanines.19. The tread according to claim 16 , wherein the at least one metal is selected from the group consisting of copper claim 16 , cobalt and iron.20. The tread according to claim 19 , wherein the at least one metal is iron.21. The tread according to claim 16 , wherein the metal chelate is selected from the group consisting of iron porphyrins claim 16 , iron hemiporphyrazine claim 16 , iron hemin claim 16 , iron phthalocyanines and copper phthalocyanines.22. The tread according to claim 21 , wherein the metal chelate is iron porphines.24. The tread according to claim 16 , wherein the pigment is selected from the group consisting of diketopyrrolopyrroles claim 16 , anthraquinones claim 16 , quinacridones claim 16 , perylenes and pyrazolo-quinazolones.25. The tread according to claim 24 , wherein the pigment is a diketopyrrolopyrrole.26. The tread according to claim 16 , wherein the pigment is selected from the group consisting of Red 254 claim 16 , Red 255 claim 16 , Red 257 and Red 264.27. The tread according to claim 26 , wherein ...

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04-01-2018 дата публикации

FOOD PACKAGING FILMS FROM LIGNIN AND METHODS OF MAKING THE SAME

Номер: US20180002085A1
Автор: RAGHU Sivaraman
Принадлежит: EMPIRE TECHNOLOGY DEVELOPMENT LLC

Provided herein are materials comprising a crosslinked polymer and a hydrophobic starch, wherein the crosslinked polymer comprises a first polymer and a second polymer and the first polymer comprises a lignin polymer or a salt thereof, and methods of use and preparation thereof. 1. A material comprising a hydrophobic starch and a crosslinked polymer , wherein the crosslinked polymer comprises a first polymer and a second polymer; the first polymer comprises a lignin polymer or a salt thereof; and', 'the second polymer comprises polyvinyl alcohol or comprises one or more polymerized monomers selected from the group consisting of vinyl acetate, styrene, acrylonitrile, butadiene, hydroxyethyl acrylate, butyl acrylate, propylene, ethylene oxide, and propylene oxide., 'wherein2. The material of claim 1 , wherein the ratio of the first polymer and the second polymer is about 1:20 to 20:1 by weight.3. The material of claim 1 , wherein the ratio of the first polymer and the hydrophobic starch is about 1:20 to 20:1 by weight.4. The material of claim 1 , wherein the ratio of the first polymer claim 1 , the second polymer claim 1 , and the hydrophobic starch is about 1:4:1.5. The material of claim 1 , further comprising an antioxidant claim 1 , wherein the antioxidant is selected from the group consisting of tocopherol claim 1 , carotene claim 1 , lycopene claim 1 , lutein claim 1 , astaxanthin claim 1 , polyphenol claim 1 , and combinations thereof.6. The material of claim 5 , wherein the antioxidant comprises from about 1% to 20% by weight of the first polymer or about 0.1% to 10% of the total weight of the material.7. The material of claim 1 , further comprising an ethylene absorber claim 1 , wherein the ethylene absorber comprises aluminosilicate claim 1 , and wherein the aluminosilicate comprises a zeolite.8. The material of claim 7 , wherein the ethylene absorber comprises from about 1% to 30% by weight of the first polymer or about 0.1% to 10% of the total weight of the ...

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02-01-2020 дата публикации

RUBBER COMPOSITION AND PAPER FEEDING ROLLER FORMED OF THE SAME

Номер: US20200002109A1
Принадлежит: SUMITOMO RUBBER INDUSTRIES, LTD.

Provided are a rubber composition capable of imparting a high tensile strength to a roller main body so as to be able to be used for equipment that allows paper to pass through at high speed, while maintaining high abrasion resistance of the roller main body and a favorable paper feeding performance of the paper feeding roller; and a paper feeding roller. There is provided a rubber composition contains: a rubber that includes a non-oil extended EPDM having an ethylene content of 55 to 72%; and more than 20 parts by mass and 30 parts by mass or less of a filler, and 2.5 parts by mass or more of a peroxide crosslinking agent per 100 parts by mass of the rubber, in which the filler contains 15 to 30 parts by mass of an amorphous silica per 100 parts by mass of the rubber. 1. A rubber composition for forming a roller main body of a paper feeding roller , the rubber composition containing:a rubber that comprises at least an ethylene propylene diene rubber;more than 20 parts by mass and 30 parts by mass or less of a filler per 100 parts by mass of a total amount of the rubber; and2.5 parts by mass or more of a peroxide crosslinking agent per 100 parts by mass of the total amount of the rubber,wherein the ethylene propylene diene rubber contains at least a non-oil extended ethylene propylene diene rubber having an ethylene content of 55% or more and 72% or less, andthe filler contains at least 15 parts by mass or more and 30 parts by mass less of an amorphous silica per 100 parts by mass of the total amount of the rubber.2. The rubber composition according to claim 1 , wherein a proportion of the non-oil extended ethylene propylene diene rubber having an ethylene content of 55% or more and 72% or less is 20 parts by mass or more and 80 parts by mass or less with respect to 100 parts by mass of the total amount of the rubber.3. The rubber composition according to claim 1 , wherein the ethylene propylene diene rubber is a non-oil extended ethylene propylene diene rubber ...

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03-01-2019 дата публикации

ACID-RESISTANT BASE AND/OR RADICAL GENERATOR, AND CURABLE RESIN COMPOSITION CONTAINING SAID BASE AND/OR RADICAL GENERATOR

Номер: US20190002403A1
Принадлежит:

The present invention relates to a compound represented by the general formula (A), a base- and/or radical-generating agent comprising the compound, and so on. 2. The compound according to claim 1 , wherein claim 1 , in the general formula (A) claim 1 , two of the eight groups Rto Rare each a hydrogen atom claim 1 , and four to six of the remaining groups are each an alkyl group having 1 to 12 carbon atoms.3. The compound according to claim 1 , wherein claim 1 , in the general formula (A) claim 1 , Rto Rare each an alkyl group having 1 to 6 carbon atoms.5. The compound according to claim 1 , wherein claim 1 , in the general formula (A) claim 1 , the four pieces of Rare each a hydrogen atom or each a fluorine atom claim 1 , and the four pieces of Rare each a fluorine atom.6. The compound according to claim 1 , wherein claim 1 , in the general formula (A) claim 1 , the four pieces of Rare each a hydrogen atom claim 1 , and the four pieces of Rare each a trifluoromethyl group.8. A base- and/or radical-generating agent comprising the compound according to .9. A base-generating agent comprising the compound according to .10. The base- and/or radical-generating agent according to claim 8 , wherein the base- and/or radical-generating agent generates a base and/or a radical through irradiation with an active energy ray.11. The base-generating agent according to claim 9 , wherein the base-generating agent generates a base through irradiation with an active energy ray.12. A base- and/or radical-curable resin composition comprising the compound according to claim 1 , and a base-curable resin raw material and/or a radical-reactive compound.13. A base-curable resin composition comprising the compound according to claim 1 , and a base-curable resin raw material.14. The composition according to claim 12 , wherein the base-curable resin raw material is a mixture of an epoxy compound and a multivalent carboxylic acid.15. The composition according to claim 12 , wherein the base- ...

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05-01-2017 дата публикации

FLUORINE RUBBER COMPOSITION, CROSSLINKED RUBBER MOLDED BODY AND METHOD FOR PRODUCING SAME

Номер: US20170002153A1
Автор: Osumi Naoki, Toda Sayaka
Принадлежит: NIPPON VALQUA INDUSTRIES, LTD.

Provided are: a fluorine rubber composition which contains a hydrogen atom-containing fluorine rubber and a hydrogen atom-containing fluororesin; a crosslinked rubber molded body which uses this fluorine rubber composition; and a method for producing this crosslinked rubber molded body. It is preferable that the hydrogen atom-containing fluororesin is composed of at least one compound that is selected from the group consisting of polyvinylidene fluorides, vinylidene fluoride-hexafluoropropylene copolymers, tetrafluoroethylene-ethylene copolymers and vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene copolymers. 1. A fluorine rubber composition comprising a hydrogen atom-containing fluorine rubber and a hydrogen atom-containing fluororesin.2. The fluorine rubber composition according to claim 1 , wherein a content of said hydrogen atom-containing fluororesin is 1 to 50 parts by weight relative to 100 parts by weight of said hydrogen atom-containing fluorine rubber.3. The fluorine rubber composition according to claim 1 , wherein the fluorine rubber composition further comprises an organic peroxide and a co-crosslinking agent.4. The fluorine rubber composition according to claim 1 , wherein said hydrogen atom-containing fluororesin is at least one compound selected from the group consisting of polyvinylidene fluoride claim 1 , a vinylidene fluoride-hexafluoropropylene copolymer claim 1 , a tetrafluoroethylene-ethylene copolymer and a vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene copolymer.5. The fluorine rubber composition according to claim 1 , wherein the fluorine rubber composition contains no inorganic filler.6. A crosslinked rubber molded body comprising a crosslinked product of the fluorine rubber composition according to .7. The crosslinked rubber molded body according to claim 6 , wherein the crosslinked rubber molded body is a sealing material for semiconductor manufacturing devices.8. A method for producing a crosslinked rubber molded ...

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04-01-2018 дата публикации

Polymer Compositions with Improved Rheological Properties

Номер: US20180002517A1
Принадлежит:

Provided herein are metallocene-catalyzed polymer compositions that exhibit advantageous rheological properties, at least some of which are consistent with long-chain branching, as well as polymerization processes suitable for forming such polymer compositions. The polymer compositions may have both LCB index measured at 125° C. of less than 5; and phase angle δ at complex shear modulus G*=100,000 Pa of less than about 54.5°, as determined at 125° C. The polymer compositions of particular embodiments are reactor blends, preferably of ethylene copolymers (e.g., ethylene-propylene (EP) copolymers and/or ethylene-propylene-diene (EPDM) terpolymers). The reactor blend may include first and second copolymer components, which may differ in monomer content and weight-average molecular weight (Mw). 1. An olefinic polymer composition having both of the following properties:LCB index measured at 125° C. of less than 5; and(ii) phase angle δ at complex shear modulus G*=100,000 Pa of less than about 54.5°, as determined at 125° C.2. The olefinic polymer composition of claim 1 , further having one or both of the following properties:(iii) corrected Mooney Large Relaxation Area (cMLRA) at Mooney Large Viscosity (ML)=80 Mooney Units (mu), such that cMLRA is from about 240 to about 2000 mu*sec, where ML is determined at (1+4@125° C.); and(iv) MLRA/ML ratio greater than R, where R is given as R=9.57(ML)−40.83, where ML is the Mooney Large Viscosity of the polymer composition determined at (1+4@125° C.).3. The olefinic polymer composition of claim 1 , further having one or more of the following properties:(v) shear thinning index (STI) measured at 125° C. greater than 0.950;(vi) relaxation time T (determined at 125° C. using the Cross equation) of greater than 1.4 sec; and(vii) MWD greater than 4.4. The olefinic polymer composition of claim 1 , wherein the olefinic polymer composition comprises units derived from ethylene claim 1 , units derived from a C-Cα-olefin claim 1 , and units ...

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02-01-2020 дата публикации

HNBR ELASTOMERIC COMPOSITIONS

Номер: US20200002515A1
Автор: Stripe Dana
Принадлежит:

An elastomeric composition comprising hydrogentated nitrile butadiene rubber (HNBR), maleinized polybutadiene, and metal oxide. In addition, they optionally comprise a cure system, fillers, and other additives. In some embodiments, the metal oxide comprises one or more compounds selected from magnesium oxide, zinc oxide, and hydrotalcite. The elastomeric composition has improved swell resistance when exposed to water. 1. An elastomeric composition comprising hydrogentated nitrile butadiene rubber (HNBR) , maleinized polybutadiene , and metal oxide.2. The elastomeric composition of claim 1 , wherein the metal oxide comprises one or more compounds selected from magnesium oxide claim 1 , zinc oxide claim 1 , and hydrotalcite.3. The elastomeric composition of claim 2 , wherein the metal oxide comprises hydrotalcite.4. The elastomeric composition of claim 2 , wherein the metal oxide comprises magnesium oxide.5. The elastomeric composition of claim 2 , wherein the metal oxide comprises magnesium oxide and hydrotalcite.6. The elastomeric composition of claim 1 , wherein the amount of maleinized polybutadiene ranges from greater than 0 phr to about 20 phr.7. The elastomeric composition of claim 1 , wherein the amount of metal oxide ranges from greater than 0 phr to about 50 phr.8. The elastomeric composition of claim 6 , wherein the amount of metal oxide ranges from greater than 0 phr to about 50 phr.9. The elastomeric composition of claim 8 , wherein the metal oxide comprises hydrotalcite.10. The elastomeric composition of claim 9 , wherein the amount of metal oxide ranges from greater than 0 phr to about 26 phr.11. The elastomeric composition of claim 1 , further comprising a peroxide cure system.12. The elastomeric composition of claim 1 , further comprising one or more filler.13. The elastomeric composition of claim 12 , wherein the filler comprises a mineral filler.14. The elastomeric composition of claim 1 , further comprising an antioxidant. The present application ...

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07-01-2021 дата публикации

CURABLE ADHESIVE COMPOSITIONS AND USE THEREOF

Номер: US20210002418A1
Автор: LI Chunzhao, LU Victor X.
Принадлежит:

A solvent-less hybrid curable composition is prepared from grafting polyesters or polyamides onto a (meth)acrylic copolymer backbone. Besides the many benefits of a solvent-less system, the hybrid curable composition forms strong adhesion to polar substrates, widens the use temperatures, and enables faster processing speeds than conventional hybrid curable compositions. The solvent-less hybrid curable composition forms an optically clear single phase that is suitable as tapes and labels, or in electronic, optoelectronic, OLED and photovoltaic devices, and the like. 1. A solvent-less , curable composition comprising , a hybrid copolymer having a random copolymer of meth(acrylic copolymer) backbone A and a plurality of oligomeric arms of polyesters B grafted onto the meth(acrylic copolymer) backbone , (A1) a (meth)acrylic monomer,', '(A2) a copolymerizable hydroxyl group containing monomer; and, 'wherein the meth(acrylic copolymer) backbone is a reaction product ofwherein the polyester B is grafted at the hydroxyl group onto the meth(acrylic copolymer) backbone.2. The solvent-less claim 1 , curable composition of claim 1 , wherein the (meth)acrylate monomer is a linear or branched aliphatic alkyl(meth)acrylate having from 3 to 20 carbon atoms in the alkyl group.3. The solvent-less claim 2 , curable composition of claim 2 , wherein the (meth)acrylate monomer is selected form the group consisting of a methyl methacrylate claim 2 , n-butylacrylate claim 2 , iso-butylacrylate claim 2 , 2-ethyl hexylacrylate claim 2 , isobutyl methacrylate claim 2 , and methoxy polyethylene glycol acrylate.4. The solvent-less claim 1 , curable composition of claim 1 , wherein the copolymerizable hydroxyl group containing monomer is a hydroxyalkyl(meth)acrylate having from 1 to 20 carbon atoms in the alkyl group with lactone adduct claim 1 , or adducts with lactone in the ethoxylated or propoxylated derivative of hydroxyethyl(meth)acrylate claim 1 , hydroxypropyl(meth)acrylate claim 1 , ...

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02-01-2020 дата публикации

RUBBER COMPOSITION AND PAPER FEEDING ROLLER FORMED OF THE SAME

Номер: US20200002519A1
Принадлежит: SUMITOMO RUBBER INDUSTRIES, LTD.

Provided are a rubber composition which is a base of a roller main body and capable of imparting favorable flexibility to the roller main body while maintaining high abrasion resistance to form, for example, a paper feeding roller that has a favorable paper feeding performance and can be used as a paper supply roller or the like; and a paper feeding roller in which the roller main body is formed using the rubber composition. There is provided a rubber composition contains a rubber that includes 20 to 80 parts by mass of a non-oil extended EPDM having an ethylene content of 55% to 72%, and an oil extended EPDM; and 20 parts by mass or less of a filler and 2.5 parts by mass or more of a peroxide crosslinking agent per 100 parts by mass of the rubber. 1. A rubber composition for forming a roller main body of a paper feeding roller , the rubber composition containing:a rubber that comprises at least an ethylene propylene diene rubber;20 parts by mass or less of a filler per 100 parts by mass of a total amount of the rubber; and2.5 parts by mass or more of a peroxide crosslinking agent per 100 parts by mass of the total amount of the rubber,wherein the ethylene propylene diene rubber is a non-oil extended ethylene propylene diene rubber having an ethylene content of 55% or more and 72% or less, and an oil extended ethylene propylene diene rubber, anda proportion of the non-oil extended ethylene propylene diene rubber is 20 parts by mass or more and 80 parts by mass or less with respect to 100 parts by mass of the total amount of the rubber.2. The rubber composition according to claim 1 , wherein a proportion of the filler is 1 part by mass or more and 16 parts by mass or less per 100 parts by mass of the total amount of the rubber.3. The rubber composition according to claim 1 , wherein a proportion of the peroxide crosslinking agent is 2.8 parts by mass or more and 5 parts by mass or less per 100 parts by mass of the total amount of the rubber.4. The rubber composition ...

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02-01-2020 дата публикации

MATERIAL MIXTURE FOR A SEALING PART

Номер: US20200002520A1
Принадлежит:

Gasket profile made of a materials mixture which includes from 5 to 60% by volume of elastomer, from 8 to 50% by volume of copolymer, from 5 to 70% by volume of filler, from 0 to 40% by volume of plasticizer, from 0.1 to 5% by volume of accelerator/sulfur donor, from 0 to 5% by volume of sulfur, from 0 to 5% by volume of peroxide, and from 0 to 3% by volume of zinc oxide, where the copolymer is a thermoplastic or a thermoplastic elastomer. 112.-. (canceled)13. A gasket profile for window gasket profiles and door gasket profiles , comprising a materials mixture that comprises:from 5 to 60% by volume of EPDM;from 8 to 50% by volume of copolymer;from 5 to 70% by volume of filler;from 0 to 40% by volume of plasticizer;from 0.1 to 5% by volume of accelerator/sulfur donor;from 0 to 5% by volume of sulfur;from 0.05 to 5% by volume of peroxide; andfrom 0.05 to 3% by volume of zinc oxide;where the copolymer is a thermoplastic or a thermoplastic elastomer.14. The gasket profile as claimed in claim 13 , where a ratio of EPDM to copolymer in the materials mixture is 2:1.15. The gasket profile as claimed in claim 14 , where the EPDM is crosslinkable both by sulfur and/or accelerator/sulfur donor and by peroxide.16. The gasket profile as claimed in claim 15 , where the copolymer is not sulfur-crosslinkable.17. The gasket profile as claimed in claim 16 , where the copolymer is crosslinkable by peroxides.18. The gasket profile as claimed in claim 17 , where the copolymer is a propylene-ethylene copolymer claim 17 , an ethylene-butene copolymer claim 17 , an ethylene-octene copolymer or an ethylene-propylene copolymer.19. The gasket profile as claimed in claim 18 , where the proportion of peroxide of the sulfur/peroxide ratio is between 1% and 95%.20. The gasket profile as claims in claim 19 , wherein the proportion of the sulfur/peroxide ratio is between 2% and 50%.21. The gasket profile as claims in claim 20 , wherein the proportion of the sulfur/peroxide ratio is between 5% and ...

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02-01-2020 дата публикации

WATER-SWELLABLE POLYMER PARTICLES

Номер: US20200002522A1
Автор: GUBBELS Erik
Принадлежит: BASF SE

The present invention is related to water-swellable polymer particles which contain a hydrophilic base polymer (B) and a hydrophobic polymer (P). It is also related to a process for producing the water-swellable polymer particles, an article containing the water-swellable polymer particles and the use of the water-swellable polymer particles. 2. The water-swellable polymer particles according to claim 1 , wherein the hydrophilic base polymer (B) comprises carboxyl groups claim 1 , sulfonic acid groups and/or salts thereof and mixtures thereof.3. The water-swellable polymer particles according to claim 1 , which have a particle size dequal to or below 250 μm.5. The water-swellable polymer particles according to claim 1 , wherein the hydrophilic base polymer (B) comprisesa) 10.0 to 70.0 mol-% of the at least one acid-containing monomer,b) 0.0 to 90.0 mol-% of the at least one (meth)acrylamido-containing monomer of formula (III), andc) 0.0 to 30.0 mol-% of the cross-linker.6. The water-swellable polymer particles according to claim 4 , wherein the at least one acid-containing monomer is selected from the group consisting of acrylic acid claim 4 , methacrylic acid claim 4 , ethacrylic acid claim 4 , α-chloroacrylic acid claim 4 , α-cyanoacrylic acid claim 4 , β-methylacrylic acid (crotonic acid) claim 4 , α-phenylacrylic acid claim 4 , β-acryloxypropionic acid claim 4 , sorbic acid claim 4 , α-chloro sorbic acid claim 4 , 2′-methylisocrotonic acid claim 4 , cinnamic acid claim 4 , p-chlorocinnamic acid claim 4 , itaconic acid claim 4 , citraconic acid claim 4 , mesacronic acid claim 4 , glutaconic acid claim 4 , aconitic acid claim 4 , maleic acid claim 4 , fumaric acid claim 4 , maleic anhydride claim 4 , 2-acrylamido-2-methylpropane sulfonic acid (AMPS) claim 4 , styrenesulfonic acid claim 4 , vinyl sulfonic acid claim 4 , allyl sulfonic acid claim 4 , 2-methylacrylamido-2-methylpropane sulfonic acid claim 4 , 2-acrylamidobutane sulfonic acid claim 4 , 3-acrylamido-3 ...

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02-01-2020 дата публикации

DISPERSANT ATTACHED POLYTETRAFLUOROETHYLENE PARTICLE, COMPOSITION, LAYERED MATERIAL, ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS

Номер: US20200002525A1
Принадлежит: FUJI XEROX CO., LTD.

A dispersant attached polytetrafluoroethylene particle on whose surface a dispersant having a fluorine atom is attached has a content of perfluorooctanoic acid of from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle, and a composition contains a polytetrafluoroethylene particle and a dispersant having a fluorine atom in which a content of perfluorooctanoic acid is from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle. 1. A dispersant attached polytetrafluoroethylene particle on whose surface a dispersant having a fluorine atom is attached , wherein a content of perfluorooctanoic acid is from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle.2. The dispersant attached polytetrafluoroethylene particle as claimed in claim 1 , which has an average particle diameter of from 0.2 μm to 4.5 μm.3. The dispersant attached polytetrafluoroethylene particle as claimed in claim 1 , wherein the dispersant having a fluorine atom is a polymer obtained by homopolymerization or copolymerization of a polymerizable compound having a fluorinated alkyl group.5. The dispersant attached polytetrafluoroethylene particle as claimed in claim 1 , wherein a content of the dispersant having a fluorine atom is from 0.5% by weight to 10% by weight with respect to the polytetrafluomethylene particle.6. The dispersant attached polytetrafluomethylene particle as claimed in claim 5 , wherein the content of the dispersant having a fluorine atom is from 1% by weight to 7% by weight with respect to the polytetrafluoroethylene particle.7. A composition comprising a polytetrafluoroethylene particle and a dispersant having a fluorine atom claim 5 , wherein a content of perfluorooctanoic acid is from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle.8. The composition as claimed in claim 7 , wherein an average particle diameter of the polytetrafluoroethylene particle is from 0.2 μm to 4.5 μm.9. The composition as claimed in claim 7 ...

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02-01-2020 дата публикации

Shock-absorbing Nanostructured Polymer Alloy

Номер: US20200002536A1
Принадлежит:

The present invention relates to a shock-absorbing nanostructured polymer alloy, comprising: 1. A shock-absorbing nanostructured polymer alloy comprising:a (meth)acrylic polymer matrix comprising one or more (meth)acrylic polymer(s), said (meth)acrylic polymer matrix forming a (meth)acrylic network, and,at least one polyborodimethylsiloxane (PBDMS) distributed in the (meth)acrylic polymer matrix, the polyborodimethylsiloxane forming a network,the polyborodimethylsiloxane network and the (meth)acrylic network being intertwined.2. The alloy of claim 1 , wherein the (meth)acrylic polymer matrix forms a cross-linked (meth)acrylic network.3. The alloy of claim 1 , wherein the (meth)acrylic polymer is a poly(alkyl acrylate) or a poly(alkyl methacrylate) selected from: poly(methyl methacrylate) claim 1 , poly(ethyl methacrylate) claim 1 , poly(methyl acrylate) claim 1 , poly(ethyl acrylate) claim 1 , poly(butyl acrylate) claim 1 , poly(butyl methacrylate) claim 1 , and mixtures thereof.4. A chemical composition for the manufacture of the shock-absorbing nanostructured polymer alloy of claim 1 , said chemical composition comprising:a (meth)acrylic monomer mixture comprising one or more (meth)acrylic monomer(s),at least one polyborodimethylsiloxane (PBDMS),at least one polymerization initiator, for initiating the polymerization of the (meth)acrylic monomer mixture to form a (meth)acrylic polymer matrix.5. The chemical composition of claim 4 , further comprising at least one cross-linking agent for forming chemical bonds between the polymer chains of the (meth)acrylic polymer matrix so that said (meth)acrylic polymer matrix forms a cross-linked (meth)acrylic network.6. The chemical composition of claim 4 , wherein the mass ratio of the mass of (meth)acrylic monomer to the sum of the masses of (meth)acrylic monomer and polyborodimethylsiloxane (PBDMS) is comprised between 30% and 70%.7. The chemical composition of claim 4 , wherein the mass ratio of the mass of ...

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07-01-2021 дата публикации

Crosslinked rubber composition

Номер: US20210002466A1
Принадлежит: Bando Chemical Industries Ltd

A crosslinked rubber composition contains a rubber component and para-aramid short fibers having a filament fineness of 2.5 dtex or more and dispersed in the rubber component.

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03-01-2019 дата публикации

TIRE TREAD WITH LOW TG RUBBER

Номер: US20190002653A1
Принадлежит:

Rubber compositions and articles made such rubber compositions having at least 80 phr of a styrene-butadiene elastomer modified with a functional group that is capable of interacting with a silica reinforcing filler and having a glass transition temperature of between −60° C. and less than −40° C. The rubber compositions may also include an effective amount of a plasticizing system having a plasticizing resin and a plasticizing liquid, wherein the effective amount of the plasticizing system provides the rubber composition with a shear modulus G* measured at 60° C. of between 0.9 MPa and 1.5 MPa and a Tg of between −35° C. and −15°. The filler for the rubber compositions is silica and there is further a curing system. 1. A tread for a tire , the tread comprising a rubber composition that is based upon a cross-linkable elastomer composition , the cross-linkable elastomer composition comprising , per 100 parts by weight of rubber (phr):greater than 85 phr of a styrene-butadiene elastomer modified with a functional group that is capable of interacting with a silica reinforcing filler and having a glass transition temperature of between −60° C. and less than −40° C.;between 0 phr and less than 15 phr of an additional highly unsaturated diene elastomer;an effective amount of a plasticizing system that includes 3 phr and 40 phr of a plasticizing resin having a glass transition temperature (Tg) of at least 25° C. and a plasticizing liquid, wherein the effective amount of the plasticizing system provides the rubber composition with a shear modulus G* measured at 60° C. of between 0.9 MPa and 1.5 MPa and a Tg of between −35° C. and −15°;between 45 phr and 95 phr of a silica reinforcing filler; anda curing system.2. The tread of claim 1 , wherein the cross-linkable elastomer composition comprises 100 phr of the styrene-butadiene elastomer.3. The tread of claim 1 , wherein the butadiene portion of the styrene-butadiene elastomer has a vinyl-1 claim 1 ,2 content of less than 35 ...

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03-01-2019 дата публикации

PARTIALLY-CROSSLINKED POLYETHYLENE FORMULATIONS AND METHODS OF MAKING SAME

Номер: US20190002673A1
Принадлежит:

Embodiments of polyethylene formulations comprise a partially cross-linked multimodal polyethylene composition having a the first molecular weight ethylene-based polymer component and a second molecular weight ethylene-based polymer component, wherein the partially cross-linked multimodal polyethylene composition comprises a density from 0.930 g/cc to 0.943 g/cc measured according to ASTM D792, a melt index (I) from 0.01 g/10 min to 5 g/10 min, when measured according to ASTM D1238 at 190° C. and a 2.16 kg load, a molecular weight distribution (MWD) from 5 to 10, wherein MWD is defined as Mw/Mn with Mw being a weight average molecular weight and Mn being a number average molecular weight, and a complex viscosity ratio from 250 to 450, wherein the complex viscosity ratio is defined as the complex viscosity at a shear rate of 0.01 rad/s divided by the complex viscosity at a shear rate of at a shear rate of 100 rad/s. 1. A polyethylene formulation comprising a partially cross-linked multimodal polyethylene composition having a first molecular weight ethylene-based polymer component and a second molecular weight ethylene-based polymer component , wherein the partially cross-linked multimodal polyethylene composition comprises:a density from 0.930 g/cc to 0.943 g/cc measured according to ASTM D792;{'sub': '2', 'a melt index (I) from 0.01 g/10 min to 5 g/10 min, when measured according to ASTM D1238 at 190° C. and a 2.16 kg load;'}{'sub': w', 'n', 'w', 'n, 'a molecular weight distribution (MWD) from 5 to 10, wherein MWD is defined as M/Mwith Mbeing a weight average molecular weight and Mbeing a number average molecular weight; and'}a complex viscosity ratio from 250 to 450, wherein the complex viscosity ratio is defined as the complex viscosity at a shear rate of 0.01 rad/s divided by the complex viscosity at a shear rate of at a shear rate of 100 rad/s.2. The polyethylene formulation of claim 1 , wherein the partially cross-linked multimodal polyethylene composition has ...

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03-01-2019 дата публикации

POLYPHENYL ETHER RESIN COMPOSITION AND PREPREG, LAMINATED BOARD AND PRINTED CIRCUIT BOARD CONTAINING SAME

Номер: US20190002689A1
Принадлежит:

Provided are a polyphenyl ether resin composition and a prepreg and a laminated board containing same. The polyphenyl ether resin composition comprises the following components: (1) a tetrafunctional or higher multifunctional acrylate-modified thermosetting polyphenyl ether resin; and (2) a vinyl eresin cross-linking agent, the weight of the vinyl resin cross-linking agent being 40-100 parts by weight based on 100 parts by weight of the tetrafunctional or higher multifunctional acrylate-modified thermosetting polyphenyl ether resin. The modified thermosetting polyphenyl ether resin, due to containing a tetrafunctional or higher multifunctional acrylate active group, can cross-link more vinyl resin cross-linking agents. Not only the prepared high-speed electronic circuit substrate has low dielectric constant and dielectric loss, but also double bonds in side chains of the vinyl resin cross-linking agent are reacted completely in a resin curing system, so that the high-speed electronic circuit substrate has a better thermo-oxidative aging resistance. 12. The polyphenyl ether resin composition according to claim 11 , wherein b is an integer from 4 to 6.13. The polyphenyl ether resin composition according to claim 11 , wherein the weight of the vinyl resin crosslinking agent is 50 to 80 parts by weight claim 11 , based on 100 parts by weight of the tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin.14. The polyphenyl ether resin composition according to claim 11 , wherein the number average molecular weight of the tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin is 500 to 10000 g/mol.15. The polyphenyl ether resin composition according to claim 14 , the vinyl resin crosslinking agent is at least one member selected from a group consisting of a styrene-butadiene copolymer claim 14 , a polybutadiene and a styrene-butadiene-divinylbenzene copolymer.16. The polyphenyl ...

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03-01-2019 дата публикации

TYPE II PHOTOINITIATOR SYSTEM AND METHOD FOR CROSSLINKING SILICONE COMPOSITIONS

Номер: US20190002695A1
Принадлежит:

The present invention relates to a silicone composition C that is crosslinkable by exposure to radiation with a wavelength between 200 nm and 450 nm, comprising: 1. A silicone composition C that is crosslinkable by exposure to radiation with a wavelength between 200 nm and 450 nm , comprises:at least one radical photoinitiator A;at least one co-initiator B chosen from compounds comprising at least one hydrogen atom bonded to a silicon atom; andat least one organopolysiloxane D comprising at least one (meth)acrylate group;wherein the co-initiator B comprises at least 0.05 mole of functions Si—H per 100 g of co-initiator B.2. The composition C according to claim 1 , wherein the co-initiator B comprises at least one siloxane bond and at least one hydrogen atom bonded to a silicon atom.3. The composition according to claim 1 , wherein the co-initiator B is chosen from organohydrogenpolysiloxanes.4. The composition C according to claim 1 , wherein the co-initiator B comprises at least 0.08 moles of Si—H functions per 100 g of co-initiator B.5. The composition C according to claim 1 , wherein the radical photoinitiator A is selected from the group consisting of benzophenone and its derivatives claim 1 , thioxanthone and its derivatives claim 1 , anthraquinone and its derivatives claim 1 , the esters of benzoyl formate claim 1 , camphorquinone claim 1 , benzil claim 1 , phenanthrenequinone claim 1 , coumarins and cetocoumarins claim 1 , and mixtures thereof.6. The composition C according to claim 1 , wherein the radical photoinitiator A is benzophenone.7. The composition C according to claim 1 , wherein the organopolysiloxane D comprises: {'br': None, 'sub': a', 'b', '(4−a−b)/2, 'RZSiO\u2003\u2003(I)'}, 'a1) at least one unit of formula (I) below [{'sub': 1', '18', '6', '12, 'sup': 4', '4, 'the symbols R, which are identical or different, each represent a linear or branched C-Calkyl group, a C-Caryl or aralkyl group, optionally substituted, preferably with halogen atoms, ...

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03-01-2019 дата публикации

SILICONE COMPOSITION CROSSLINKABLE TO GIVE SILICONE GEL

Номер: US20190002696A1
Принадлежит: Wacker Chemie AG

Highly adhesive, soft silicone gels are prepared from an aliphatically unsaturated organopolysiloxanes and an organosilicon compound crosslinker of high molecular weight and a very low silicon-bonded hydrogen content. 110.-. (canceled)15. The silicone composition of claim 11 , wherein a portion of polyorganosiloxane (A) is an organosiloxane resin (A1) comprising units of formulae I claim 11 , II claim 11 , III and IV{'br': None, 'sub': 3', '1/2, 'RSiO\u2003\u2003(I),'}{'br': None, 'sub': 2', '2/2, 'RSiO\u2003\u2003(II),'}{'br': None, 'sub': '3/2', 'RSiO\u2003\u2003(III),'}{'br': None, 'sub': '4/2', 'SiO\u2003\u2003(IV),'}in which{'sup': 1', '2, 'R is R, Ror OH,'}wherein{'sup': '1', 'sub': 1', '10, 'Ris a monovalent, unsubstituted or halogen- or cyano-substituted, C-C-hydrocarbon radical optionally bonded to silicon via an organic divalent group and containing at least one aliphatic carbon-carbon multiple bond,'}{'sup': '2', 'sub': 1', '10, 'Ris a monovalent, unsubstituted or halogen- or cyano-substituted, SiC-bonded C-C-hydrocarbon radical free from aliphatic carbon-carbon multiple bonds,'}with the proviso thatat least 20 mol % of the units are units of formulae III and IV,{'sup': '1', 'at least 2 of the radicals R are radicals R, and not more than 2% by weight of the radicals R are radicals OH.'}16. The silicone composition of claim 12 , wherein a portion of polyorganosiloxane (A) is an organosiloxane resin (A1) comprising units of formulae I claim 12 , II claim 12 , III and IV{'br': None, 'sub': 3', '1/2, 'RSiO\u2003\u2003(I),'}{'br': None, 'sub': 2', '2/2, 'RSiO\u2003\u2003(II),'}{'br': None, 'sub': '3/2', 'RSiO\u2003\u2003(III),'}{'br': None, 'sub': '4/2', 'SiO\u2003\u2003(IV),'}in which{'sup': 1', '2, 'R is R, Ror OH,'}wherein{'sup': '1', 'sub': 1', '10, 'Ris a monovalent, unsubstituted or halogen- or cyano-substituted, C-C-hydrocarbon radical optionally bonded to silicon via an organic divalent group and containing at least one aliphatic carbon-carbon multiple ...

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02-01-2020 дата публикации

CROSSLINKED CELLULOSE AS PRECURSOR IN PRODUCTION OF HIGH-GRADE CELLULOSE DERIVATIVES AND RELATED TECHNOLOGY

Номер: US20200002891A1
Автор: Luo Mengkui
Принадлежит: INTERNATIONAL PAPER COMPANY

A pulp in accordance with a particular embodiment includes crosslinked cellulose fibers. The pulp can have high brightness, reactivity, and intrinsic viscosity. The pulp, therefore, can be well suited for use as a precursor in the production of low-color, high-viscosity cellulose derivatives. A method in accordance with a particular embodiment of the present technology includes forming a pulp from a cellulosic feedstock, bleaching the pulp, crosslinking cellulose fibers within the pulp while the pulp has a high consistency, and drying the pulp. The bleaching process can reduce a lignin content of the pulp to less than or equal to 0.09% by oven-dried weight of the crosslinked cellulose fibers. Crosslinking the cellulose fibers can include exposing the cellulose fibers to a glycidyl ether crosslinker having two or more glycidyl groups and a molecular weight per epoxide within a range from 140 to 175. 1. A method , comprising:crosslinking bleached cellulose fibers within a pulp while the pulp has a consistency greater than or equal to 12%; and a resultant carboxymethyl cellulose (CMC) viscosity greater than or equal to 60 centipoise (cP),', 'a brightness greater than or equal to 75%, and', 'a water retention value (WRV) greater than or equal to 1.1 g/g., 'drying the pulp after said crosslinking, wherein the dried pulp has2. The method of claim 1 , wherein crosslinking the bleached cellulose fibers includes crosslinking the bleached cellulose fibers while the pulp has a consistency greater than or equal to 15%.3. The method of claim 1 , wherein crosslinking the bleached cellulose fibers increases a WRV of the dried pulp.4. The method of claim 1 , wherein crosslinking the bleached cellulose fibers includes exposing the bleached cellulose fibers to a glycidyl ether crosslinker having two or more glycidyl groups.5. The method of claim 1 , wherein crosslinking the bleached cellulose fibers includes exposing the bleached cellulose fibers to a crosslinker claim 1 , and ...

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13-01-2022 дата публикации

FOAMS AND METHOD OF FORMING FOAMS OF IONOMERS OF COPOLYMERS OF VINYLIDENE AROMATIC MONOMER AND UNSATURATED COMPOUNDS WITH ACID GROUPS

Номер: US20220010087A1
Принадлежит:

A foaming composition useful to make an extruded foam is comprised of comprising a plurality of chains of a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated acids, the copolymer having about 0.01 to about 15.0 percent by weight of the one or more unsaturated acids wherein the acid groups are pendant from the copolymer a metal salt, metal oxide or combination thereof, the metal having a valence of at least 2; and one or more blowing agents. The foaming composition may be made into a foam by heating the foaming composition to a temperature sufficient to melt and ionically crosslink said copolymer which is then extruded through a die forming a foam. The foam is comprised of an ionically crosslinked aforementioned copolymer, wherein the copolymer is crosslinked through ionic bonds between the unsaturated acids and the metal of the metal salt or metal oxide. 1. A foaming composition comprising:(a) a plurality of chains of a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated acids, the copolymer having about 0.01 to about 15.0 percent by weight of the one or more unsaturated acids wherein the acid groups are pendant from the copolymer;(b) a metal salt, metal oxide or combination thereof, the metal having a valence of at least 2; and,(c) one or more blowing agents.2. The foaming composition of wherein the foaming composition is an admixture of each of (a) claim 1 , (b) and (c).3. The foaming composition of claim 1 , wherein the foaming composition are separate parts that are brought into contact when forming a foam.4. The foaming composition according to claim 1 , wherein the metal is one or more of transition metals claim 1 , post transition metals claim 1 , metalloids or an alkaline earth metals.5. The foaming composition according to claim 1 , wherein the metal is one or more of zinc claim 1 , zirconium claim 1 , aluminum claim 1 , magnesium and calcium.6. The foaming composition according to claim 1 , ...

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02-01-2020 дата публикации

RADIATION-SENSITIVE RESIN COMPOSITION AND ELECTRONIC COMPONENT

Номер: US20200004145A1
Автор: Fujimura Makoto
Принадлежит: ZEON CORPORATION

Provided is a radiation-sensitive resin composition capable of forming a resin film for which development residue formation is sufficiently inhibited and that has excellent extensibility. The radiation-sensitive resin composition contains: a cycloolefin polymer (A-1) including a protonic polar group; a cycloolefin polymer (A-2) including a protonic polar group; a difunctional epoxy compound (B); and a radiation-sensitive compound (C). The cycloolefin polymer (A-1) has a weight-average molecular weight of not less than 1,000 and less than 10,000, and the cycloolefin polymer (A-2) has a weight-average molecular weight of not less than 10,000 and not more than 100,000. Content of the cycloolefin polymer (A-2) is not less than 5 mass % and not more than 55 mass % of total content of the cycloolefin polymer (A-1) and the cycloolefin polymer (A-2). 1. A radiation-sensitive resin composition comprising:a cycloolefin polymer (A-1) including a protonic polar group;a cycloolefin polymer (A-2) including a protonic polar group;a difunctional epoxy compound (B); anda radiation-sensitive compound (C), whereinthe cycloolefin polymer (A-1) has a weight-average molecular weight of not less than 1,000 and less than 10,000, and the cycloolefin polymer (A-2) has a weight-average molecular weight of not less than 10,000 and not more than 100,000, andcontent of the cycloolefin polymer (A-2) is not less than 5 mass % and not more than 55 mass % of total content of the cycloolefin polymer (A-1) and the cycloolefin polymer (A-2).3. The radiation-sensitive resin composition according to claim 1 , wherein content of the difunctional epoxy compound (B) is 150 parts by mass or more per 100 parts by mass of the cycloolefin polymer (A-2).4. The radiation-sensitive resin composition according to claim 1 , further comprising either or both of a compound including at least two alkoxymethyl groups and a compound including at least two methylol groups.5. The radiation-sensitive resin composition ...

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01-01-2015 дата публикации

Resin particle aggregate, method for manufacturing same and application of same

Номер: US20150005437A1
Автор: Kenzo TERAMOTO
Принадлежит: Sekisui Plastics Co Ltd

A resin particle aggregate is the resin particle aggregate formed by aggregating a plurality of resin particles including a polymer of a vinyl monomer, includes 100 parts by mass of the resin particles and 1 to 5 parts by mass of a surfactant. The resin particles are cross-linked by a cross-linkable monomer in an amount of 10 to 50% by mass relative to the total mass of the resin particles, the resin particle aggregate contains an inorganic component in an amount of 0.5% by mass or less, the resin particles have a volume average particle diameter D1, particles contained in a dispersion liquid of the resin particle aggregate in water have a volume average particle diameter D2, and the ratio of D2/D1 is 15 or less.

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07-01-2021 дата публикации

COMPOSITE OF NON-POLAR ORGANIC POLYMER, POLAR ORGANIC POLYMER, AND ULTRA-LOW-WETTABILITY CARBON BLACK

Номер: US20210005344A1
Принадлежит:

A semiconductive composite material comprising a non-polar organic polymer, a polar organic copolymer, and an electrical conducting effective amount of an ultra-low-wettability carbon black. Also a method of making the composite material; a crosslinked polyethylene product made by curing the composite material; manufactured articles comprising a shaped form of the inventive composite material or product; and methods of using the inventive composite material, product, or articles. 1. A semiconductive composite material comprising (A) a non-polar polyolefin polymer in a first phase , (AA) a polar ethylene-based copolymer in a second phase , which is at least partially immiscible in the first phase , and an electrical conducting effective amount of (B) an ultra-low-wettability carbon black (ULW-CB) , which has a Brunauer-Emmett-Teller (BET) nitrogen surface area of from 35 to 190 square meters per gram (m/g) , measured by BET Nitrogen Surface Area Test Method; and an oil absorption number (OAN) from 115 to 180 milliliters of oil per 100 grams (mL/100 g) , measured by Oil Absorption Number Test Method; and a water uptake of from 400 to 2400 parts per million (ppm , weight) , measured by Moisture Uptake Test Method.2. The semiconductive composite material of wherein the (B) ULW-CB is characterized by any one of limitations (i) to (iii): (i) the (B) ULW-CB has a BET nitrogen surface area from 40 to 63 m/g claim 1 , measured by the BET Nitrogen Surface Area Test Method; and an OAN from 120 to 150 mL/100 g claim 1 , measured by the Oil Absorption Number Test Method; (ii) the (B) ULW-CB has a BET nitrogen surface area from 120 to 180 m/g claim 1 , measured by the BET Nitrogen Surface Area Test Method; and an OAN from 150 to 175 mL/100 g claim 1 , measured by the Oil Absorption Number Test Method; and (iii) the (B) ULW-CB is a blend of the ULW-CBs of (i) and (ii).3. A semiconductive composite material comprising (A) a non-polar polyolefin polymer in a first phase claim 1 , ( ...

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14-01-2021 дата публикации

POLYESTER BIOMATERIALS HAVING ANTIBACTERIAL AND IMMUNOREGULATORY ACTIVITIES

Номер: US20210008100A1
Принадлежит:

A method of treating infection and/or inflammation in a subject includes steps of providing a polyester biomaterial comprising diol monomers and at least first carboxylate monomers, wherein the first carboxylate monomers are itaconate; and administering the polyester biomaterial to the subject. The polyester biomaterial can be in the form of a biomimetic, and characterized by hydrolytic degradability. The polyester biomaterial may further include second carboxylate monomers. The biomaterial can be poly(itaconate-co-citrate-co-octanediol). 1. A method of treating infection and/or inflammation in a subject , said method comprises steps of:providing a polyester biomaterial comprising diol monomers and at least first carboxylate monomers, wherein the first carboxylate monomers are itaconate; andadministering the polyester biomaterial to the subject.2. The method of claim 1 , wherein the polyester biomaterial is in the form of a biomimetic.3. The method of claim 1 , wherein the polyester biomaterial is characterized by hydrolytic degradability.4. The method of claim 1 , wherein the polyester biomaterial is formed by polycondensation of the diol monomers with the itaconate monomers in the presence of a radical inhibitor.5. The method of claim 1 , wherein the polyester biomaterial is formed by polycondensation in temperature range from ab out 120° C. to about 130° C. at atmospheric pressure.6. The method of claim 1 , wherein the polyester biomaterial is formed by additional polycondensation at vacuum pressure.7. The method of claim 1 , wherein the itaconate monomers comprise methylated itaconate.8. The method of claim 1 , wherein the diol monomers are any one or a combination of 1 claim 1 ,6-hexanediol claim 1 , 1 claim 1 ,8-octanediol and 1 claim 1 ,10-decanediol.9. The method of claim 1 , wherein the administering step comprises intraperitoneal injection.10. The method of claim 1 , wherein the polyester biomaterial further comprises second carboxylate monomers.11. The ...

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12-01-2017 дата публикации

Crosslinked zwitterionic hydrogels

Номер: US20170009069A1

Zwitterionic crosslinking agents, crosslinked zwitterionic hydrogels prepared from copolymerization of zwitterionic monomers with the zwitterionic crosslinking agent, methods for making crosslinked zwitterionic hydrogels, and devices that include and methods that use the crosslinked zwitterionic hydrogels.

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14-01-2016 дата публикации

GRAFTING FUNCTIONAL SPECIES TO RUBBER

Номер: US20160009874A1
Автор: BOHN, JR. Clayton C
Принадлежит:

A method for producing a functionalized rubber that includes adding a diene rubber selected from natural rubber, a synthetic polyisoprene rubber or combinations thereof and an organic peroxide to a mixer, the organic peroxide may be represented by the formula R—O—O—R, wherein Ris selected from hydrogen or an organic moiety of between 4 and 15 carbon atoms and Rcomprises a functional moiety. The mix composition may be mixed until the mix composition reaches a target temperature of between 120° C. and 190° C. and decomposing the organic peroxide to provide a decomposition product comprising the functional moiety and reacting at least a portion of the decomposition product with at least a portion of the diene rubber to produce the functionalized rubber. 1. A method for producing a functionalized rubber , the method comprising:{'sub': 1', '2', '1', '2, 'adding a diene rubber selected from natural rubber, a synthetic polyisoprene rubber or combinations thereof and an organic peroxide to a mixer, the organic peroxide represented by the formula R—O—O—R, wherein Ris selected from hydrogen or an organic moiety of between 4 and 15 carbon atoms and Rcomprises a functional moiety selected from an amino, an amide, a hydroxyl, a sulfide, an epoxy, a tin-containing, an alkoxysilyl, a silanol, a carbonyl, a carboxyl, a thiocarbonyl, an ammonium, a nitrile, an imine functional moiety or combinations thereof;'}mixing a mix composition comprising the diene rubber and the organic peroxide until the mix composition reaches a target temperature of between 120° C. and 190° C.;decomposing the organic peroxide to provide a decomposition product comprising the carboxyl functional moiety;reacting at least a portion of the decomposition product with at least a portion of the diene rubber to produce the functionalized rubber;dropping the mix composition from the internal mixer; andcooling the mix composition.2. The method of claim 1 , wherein Ris the carboxyl functional moiety.3. The method of ...

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27-01-2022 дата публикации

METHOD FOR PRODUCING THERMOPLASTIC RESIN COMPOSITION AND THERMOPLASTIC RESIN COMPOSITION

Номер: US20220025170A1
Принадлежит: INOAC CORPORATION

It becomes possible to produce a thermoplastic resin composition having a sea-island structure by a kneading step of kneading a thermoplastic elastomer and/or rubber material having an alkoxysilyl group, in which the alkoxysilyl group is grafted to the thermoplastic elastomer and/or rubber material, and a thermoplastic resin in a melt state in a kneading machine and a dynamic crosslinking step of adding a water component into the kneading machine, forming a silanol group by a hydrolysis reaction of the alkoxysilyl group in the thermoplastic elastomer and/or rubber material having an alkoxysilyl group and the water component in the kneading machine, and subsequently forming a siloxane bond by a condensation reaction between the silanol groups. 1. A thermoplastic resin composition comprising a sea-island structure ,wherein an island structure part of the sea-island structure contains a thermoplastic elastomer and/or rubber material cross-linked by a siloxane bond and a sea structure part of the sea-island structure contains a thermoplastic resin,wherein a gel fraction (in accordance with JIS K 6769: 2004/1SO-15875-2: 2003) of the island structure part is 90% or more, andwherein the blending amount of the thermoplastic resin is 30 to 70 parts by weight relative to 100 parts by weight of the thermoplastic elastomer and rubber material.2. The thermoplastic resin composition according to claim 1 ,wherein the thermoplastic elastomer and/or rubber material is a thermoplastic elastomer in which the main chain and the side chains are formed of saturated bonds, andwherein the thermoplastic resin is a thermoplastic resin in which the main chain and the side chains are formed of saturated bonds.3. The thermoplastic resin composition according to claim 1 ,wherein a viscosity of the thermoplastic elastomer and/or rubber material cross-linked by the siloxane bond is larger than a viscosity of the thermoplastic resin.4. The thermoplastic resin composition according to claim 1 , ...

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27-01-2022 дата публикации

UV AND/OR HEAT CURABLE SILICONE BASED MATERIALS AND FORMULATIONS

Номер: US20220025180A1
Принадлежит:

The present disclosure is directed to a process for the preparation of curable, (meth)acrylate functionalized polysiloxanes. In addition, the present disclosure is directed to a curable, (meth)acrylate-functionalized polysiloxane obtained thereby and curable compositions comprising these curable, (meth)acrylate-functionalized polysiloxanes. 2. The polysiloxane polymer of wherein:a) each X is O; orb) each R is a bivalent moiety independently selected from alkylene, heteroalkylene, amine; urethane; urea; ether and combinations thereof; orc) each Y is independently selected from alkyl and aryl; ord) at least one Z is aryl; ore) any combination of a), b), c) and d).3. The polysiloxane polymer of claim 1 , wherein each R is independently selected from Calkylene claim 1 , -alkylene-urethane-ether- claim 1 , -amine-alkylene- and alkylene-urea-alkylene-.4. The polysiloxane polymer of claim 1 , wherein R comprises a urethane group claim 1 , an ether group claim 1 , an amine group and combinations thereof.5. The polysiloxane polymer of claim 1 , wherein m is 0.6. The polysiloxane polymer of claim 1 , wherein m is an integer from 1 to about 2300 and each Si atom in the m block has one phenyl Z moiety and one Calkyl Z moiety.7. The polysiloxane polymer of claim 1 , wherein R comprises one or more heteroatoms.8. The polysiloxane polymer of claim 1 , wherein R has a length of 2 to 20 atoms.9. The polysiloxane polymer of claim 1 , having a) a molecular weight of 300 to 200 claim 1 ,000 or b) a viscosity of 1 to 15 claim 1 ,000 Cps or both a) and b).10. Cured reaction products of the radiation curable polysiloxane polymer of .11. A curable composition comprising the radiation curable claim 1 , (meth)acrylate terminated polysiloxane polymer of .12. A process for preparation of a radiation curable claim 1 , organo-polysiloxane material claim 1 , comprising:providing a first material selected from one or more of diamino silicone polymer and carbinol silicone polymer;providing a second ...

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14-01-2016 дата публикации

Transparent And Tough Rubber Composition And Manufacturing Process For The Same

Номер: US20160009907A1
Принадлежит: KRATON POLYMERS US LLC

In order to provide a rubber composition having high transparency and toughness, the present invention can provide a crosslinked rubber composition, being substantially free of silica, comprising a first olefin polymer having refractive index of between 1.500 to 1.525 at 23 degree C.; and a second olefin polymer which is different from the first olefin polymer, wherein the composition has haze of 20% or less on 2 mm thick sheet, measured according to JIS K7136, and wherein the composition has Type A Durometer hardness (0 sec) of 35 or more, measured according to JIS K6253.

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09-01-2020 дата публикации

THIN FILM COMPOSITE MEMBRANE INCLUDING CROSSLINKED TROGER'S BASE POLYMER

Номер: US20200009511A1
Принадлежит:

A composite membrane including a porous support and a thin film layer comprising a reaction product of: i) a polymer comprising a sub-unit including a Troger's base moiety represented by Formula I: 2. The membrane of wherein L comprises a fused ring structure including from 1 to 4 rings including at least one aromatic ring.3. The membrane of wherein L is selected from: phenylene claim 1 , biphenylene claim 1 , naphthalene and spirobisindane. The invention generally relates to thin film composite membranes (“TFC” membranes). Such membranes include a thin discriminating layer located upon a porous support. The invention specifically relates to the use of a polymer having intrinsic microporosity (“PIMs”) as the thin film layer. The subject membranes are generally useful in performing fluid separations and particularly useful in separations involving organic solvents or wide ranges of pH conditions.Polymers with intrinsic microporosity (PIMs) are characterized by having macro-molecular structures that are both rigid and contorted so as to have extremely large fractional free volumes. Examples include poly(1-trimethylsilyl-1-propyne) (PTMSP), poly(4-methyl-2-pentyne) (PMP) and polybenzodioxane (PIM-1). Because of their exceptional free volume, all are extremely permeable. See: Baker, Membrane Technology and Applications, 3ed., (2012), and Polymers of Intrinsic Microporosity, Enc. Polymer Sci. & Tech., (2009)—both by John Wiley & Sons Ltd. See also: WO2016/206008, WO2016/195977, WO2016/148869, WO2005/113121, US2004/01985587, US2013/0146538, US2013/0172433, US2013/0267616, US2014/0251897, U.S. Pat. Nos. 9,018,270, 8,623,928, 8,575,414, 8,056,732, 7,943,543, 7,690,514 and 7,410,525 which are incorporated herein in their entirety. By way of example, US2014/025 1897 describes a thin film composite membrane including a thin selective layer of a networked microporous polymer having intrinsic microporosity formed via an interfacial polymerization of monomers having concavity (e. ...

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11-01-2018 дата публикации

Vulcanized Polymer Blends

Номер: US20180009976A1
Принадлежит: ExxonMobil Chemical Patents Inc

A heterogeneous vulcanized polymer blend comprising a continuous phase comprising a thermoplastic polypropylene having a crystallinity of at least 30% and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron. The elastomeric copolymer has a crystallinity of less than 20% and is at least partially cross-linked such that no more than about 80 wt % of the elastomeric copolymer is extractable in cyclohexane at 23° C.

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09-01-2020 дата публикации

MULTILAYER ELEMENT COMPRISING AN INTERLAYER COMPRISING A COPOLYMER OF ETHYLENE WITH A COMONOMER CONTAINING SILANE GROUP(S)

Номер: US20200009839A1
Принадлежит:

The present invention relates to a multilayer element (LE), the use of the multilayer element (LE) for producing an article, an article comprising multilayer element (LE), a layer element of at least two layers, the use of the polymer composition of the invention to produce a multilayer element, as well as to a process for producing the multilayer element (LE) and an article thereof. 1. A multilayer element (LE) comprising a first layer element , an interlayer element and a second layer element , whereinthe first layer element comprises a glass layer or a polymeric layer; (a1) a copolymer of ethylene with silane group(s) containing comonomer; or', '(a2) a copolymer of ethylene with one or more polar comonomer(s) selected from (C1-C6)-alkyl acrylate or (C1-C6)-alkyl (C1-C6)-alkylacrylate comonomer(s), which copolymer (a2) bears silane group(s) containing units and which copolymer (a2) is different from the copolymer (a1); and, 'the interlayer element comprises a polymer composition comprising a copolymer of ethylene (a) which is selected from'}the second layer element comprises a glass layer element or a polymeric layer element;and wherein the interlayer element is in adhering contact with said first and second layer element.2. The multilayer element (LE) according to claim 1 , wherein the copolymer of ethylene (a) is selected from(a1) a copolymer of ethylene with silane group(s) containing comonomer; or(a2) a copolymer of ethylene with one or more polar comonomer(s) selected from (C1-C6)-alkyl acrylate or (C1-C6)-alkyl (C1-C6)-alkylacrylate comonomer(s) and with silane group(s) containing comonomer.3. The multilayer element (LE) according to claim 1 , wherein the polar comonomer is present in the copolymer of ethylene (a2) in an amount of 0.5 to 30.0 mol %.5. The multilayer element (LE) according to claim 1 , wherein the polar comonomer is present in the copolymer of ethylene (a2) in an amount of 2.5 to 18 mol %.6. The multilayer element (LE) according to claim 1 , ...

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10-01-2019 дата публикации

COMPOUND, RESIN, COMPOSITION, RESIST PATTERN FORMATION METHOD, AND CIRCUIT PATTERN FORMATION METHOD

Номер: US20190010108A1
Принадлежит:

The present invention employs a compound represented by the following formula (0): 7. A resin obtained with the compound according to as a monomer.10. A composition comprising one or more selected from the group consisting of the compound according to .11. The composition according to claim 10 , further comprising a solvent.12. The composition according to claim 10 , further comprising an acid generating agent.13. The composition according to claim 10 , further comprising an acid crosslinking agent.14. The composition according to claim 10 , wherein the composition is used in film formation for lithography.15. The composition according to claim 10 , wherein the composition is used in optical component formation.16. A method for forming a resist pattern claim 14 , comprising the steps of: forming a photoresist layer on a substrate using the composition according to ; and then irradiating a predetermined region of the photoresist layer with radiation for development.17. A method for forming a resist pattern claim 14 , comprising the steps of: forming an underlayer film on a substrate using the composition according to ; forming at least one photoresist layer on the underlayer film; and then irradiating a predetermined region of the photoresist layer with radiation for development.18. A method for forming a circuit pattern claim 14 , comprising the steps of: forming an underlayer film on a substrate using the composition according to ; forming an intermediate layer film on the underlayer film using a resist intermediate layer film material; forming at least one photoresist layer on the intermediate layer film; then irradiating a predetermined region of the photoresist layer with radiation for development claim 14 , thereby forming a resist pattern; and then etching the intermediate layer film with the resist pattern as a mask claim 14 , etching the underlayer film with the obtained intermediate layer film pattern as an etching mask claim 14 , and etching the substrate ...

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14-01-2021 дата публикации

ACRYLIC RUBBER, ACRYLIC RUBBER COMPOSITION, CROSSLINKED ACRYLIC RUBBER, SEAL MATERIAL, AND HOSE MATERIAL

Номер: US20210009735A1
Автор: BANDO Fumiaki, Sato Susumu
Принадлежит: ZEON CORPORATION

An acrylic rubber containing acrylate monomer units, methacrylate monomer units, and crosslinkable monomer units, wherein a glass transition temperature is −20° C. or less, a change ratio in volume after a crosslinked rubber of the acrylic rubber is immersed in IRM903 oil at 150±2° C. for 72 hours is 0 to 100%, and a change ratio in weight after a crosslinked rubber of the acrylic rubber is immersed in hot water at 150±2° C. for 96 hours and dried is −5.0 to 0%. 1. An acrylic rubber comprising:acrylate monomer units;methacrylate monomer units; andcrosslinkable monomer units;wherein a glass transition temperature is −20° C. or less, a change ratio in volume after a crosslinked rubber of the acrylic rubber is immersed in IRM903 oil at 150±2° C. for 72 hours is 0 to 100%, and a change ratio in weight after the crosslinked rubber of the acrylic rubber is immersed in hot water at 150±2° C. for 96 hours and dried is −5.0 to 0%.2. The acrylic rubber according to claim 1 , wherein an acrylate constituting the acrylate monomer units is at least one selected from methyl acrylate claim 1 , ethyl acrylate claim 1 , n-butyl acrylate claim 1 , 2-ethylhexyl acrylate claim 1 , n-octyl acrylate claim 1 , and 2-methoxyethyl acrylate.3. The acrylic rubber according to claim 1 , wherein a methacrylate constituting the methacrylate monomer units is at least one selected from alkyl methacrylate claim 1 , alkoxyalkyl methacrylate claim 1 , polyalkylene glycol methacrylate claim 1 , and alkoxy polyalkylene glycol methacrylate.4. The acrylic rubber according to claim 1 , wherein a methacrylate constituting the methacrylate monomer units is at least one selected from methyl methacrylate claim 1 , ethyl methacrylate claim 1 , n-propyl methacrylate claim 1 , n-butyl methacrylate claim 1 , 2-methoxyethyl methacrylate claim 1 , 2-ethoxyethyl methacrylate claim 1 , 1-methyl-2-methoxyethyl methacrylate claim 1 , diethylene glycol methacrylate claim 1 , ethylene glycol methacrylate claim 1 , ...

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14-01-2021 дата публикации

RESIN COMPOSITION AND ARTICLE MADE THEREFROM

Номер: US20210009759A1
Принадлежит:

A resin composition comprises a prepolymer of crosslinking agent and benzoxazine resin and a maleimide resin. The resin composition may be used to make various articles, such as a prepreg, a resin film, a resin-coated copper, a laminate or a printed circuit board, and achieves improvements in at least one, more or all of the properties including laminate reflow shrinkage, T288 thermal resistance, ten-layer board T300 thermal resistance, dissipation factor, copper foil peeling strength, and resin filling property in open area. 1. A resin composition , comprising:(A) 10 parts by weight to 45 parts by weight of a prepolymer of crosslinking agent and benzoxazine resin; and(B) 30 parts by weight to 70 parts by weight of a maleimide resin.2. The resin composition of claim 1 , wherein the prepolymer of crosslinking agent and benzoxazine resin comprises a prepolymer of olefin and benzoxazine resin claim 1 , a prepolymer of acrylate and benzoxazine resin claim 1 , a prepolymer of unsaturated bond-containing acyl chloride and benzoxazine resin claim 1 , or a combination thereof3. The resin composition of claim 2 , wherein the olefin comprises styrene-butadiene-divinylbenzene terpolymer claim 2 , styrene-butadiene-maleic anhydride terpolymer claim 2 , vinyl-polybutadiene-urethane oligomer claim 2 , styrene-butadiene copolymer claim 2 , styrene-isoprene copolymer claim 2 , maleic anhydride-butadiene copolymer claim 2 , polybutadiene claim 2 , polyisoprene claim 2 , butadiene claim 2 , dicyclopentadiene claim 2 , bis(vinylbenzyl)ether claim 2 , 1 claim 2 ,2-bis(vinylphenyl) ethane claim 2 , divinylbenzene claim 2 , triallyl isocyanurate claim 2 , triallyl cyanurate claim 2 , 1 claim 2 ,2 claim 2 ,4-trivinyl cyclohexane claim 2 , or a combination thereof.4. The resin composition of claim 2 , wherein the acrylate comprises cyclohexane dimethanol di(meth)acrylate claim 2 , ethylene glycol di(meth)acrylate claim 2 , 1 claim 2 ,4-butylene glycol di(meth)acrylate claim 2 , ethoxylated ...

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14-01-2021 дата публикации

BUILD MATERIALS FOR 3D PRINTING

Номер: US20210009800A1
Принадлежит:

Polymerizable liquids are described herein which, in some embodiments, can produce 3D printed articles of high resolution and desirable mechanical properties. In one aspect, a polymerizable liquid comprises an acrylate component, a polymeric additive, and a monomeric curing agent, wherein the acrylate component and monomeric curing agent are copolymerizable upon exposure to light. In being copolymerizable, the acrylate component and monomeric curing agent can form a copolymer. As described father herein, the monomeric curing agent can enable further reaction of the copolymer with one or more crosslinking species to link the copolymer with one more polymeric networks. 1. A polymerizable liquid comprising:an acrylate component;a polymeric additive; anda monomeric curing agent, wherein the acrylate component and monomeric curing agent are copolymerizable upon exposure to light.2. The polymerizable liquid of claim 1 , wherein the polymeric additive comprises one or more thermoplastics.3. The polymerizable liquid of claim 2 , wherein the thermoplastic comprises multiblock copolymer.4. The polymerizable liquid of claim 3 , wherein the multiblock copolymer comprises polyurethane.5. The polymerizable liquid of claim 4 , wherein the monomeric curing agent includes an N-vinyl moiety.6. The polymerizable liquid of claim 1 , wherein the monomeric curing agent comprises one or more imidazoles.7. The polymerizable liquid of claim 1 , wherein the monomeric curing agent is present in an amount of 2-20 weight percent.8. The polymerizable liquid of claim 1 , wherein the monomeric curing agent is a solvent for the polymeric additive.9. The polymerizable liquid of further comprising a crosslinking component.10. The polymerizable liquid of claim 9 , wherein the crosslinking component comprises epoxy resin claim 9 , an isocyanate component claim 9 , a polyol component claim 9 , or mixtures thereof.11. The polymerizable liquid of claim 10 , wherein the crosslinking component is coated on ...

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10-01-2019 дата публикации

Ethylene based polymer composition suitable for use in extrusion coating

Номер: US20190010262A1
Принадлежит: SABIC Global Technologies BV

The present invention relates to an ethylene based polymer composition suitable for use in extrusion coating. The present invention also relates to an extrusion coating product comprising such composition and the use of such a composition.

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09-01-2020 дата публикации

CROSSLINKABLE RUBBER COMPOSITION AND CROSSLINKED RUBBER

Номер: US20200010597A1
Автор: MOSAKI Shiho
Принадлежит: ZEON CORPORATION

A crosslinkable rubber composition includes a carboxyl group-containing nitrile rubber (A); a carboxyl group-containing acrylic rubber (B); and a polyamine-based crosslinking agent (C), where a ratio of a weight of the carboxyl group-containing nitrile rubber (A) to a weight of the carboxyl group-containing acrylic rubber (B) is from 5:95 to 95:5. The carboxyl group-containing nitrile rubber (A) includes 5 to 60% by weight of α,β-ethylenically unsaturated nitrile monomer units, and α,β-ethylenically unsaturated monocarboxylic acid ester monomer units. The carboxyl group-containing nitrile rubber (A) has an iodine value of 120 or less. 1. A crosslinkable rubber composition comprising:a carboxyl group-containing nitrile rubber (A);a carboxyl group-containing acrylic rubber (B); anda polyamine-based crosslinking agent (C),wherein a ratio of a weight of the carboxyl group-containing nitrile rubber (A) to a weight of the carboxyl group-containing acrylic rubber (B) is from 5:95 to 95:5, 5 to 60% by weight of α,β-ethylenically unsaturated nitrile monomer units, and', 'α,β-ethylenically unsaturated monocarboxylic acid ester monomer units, and, 'wherein the carboxyl group-containing nitrile rubber (A) includes'}wherein the carboxyl group-containing nitrile rubber (A) has an iodine value of 120 or less.2. The crosslinkable rubber composition according to claim 1 , wherein a content of the α claim 1 ,β-ethylenically unsaturated monocarboxylic acid ester monomer units in the carboxyl group-containing nitrile rubber (A) is 5 to 60% by weight.3. The crosslinkable rubber composition according to claim 1 , wherein the α claim 1 ,β-ethylenically unsaturated monocarboxylic acid ester monomer units in the carboxyl group-containing nitrile rubber (A) are (meth)acrylic acid alkyl ester units.4. The crosslinkable rubber composition according to claim 1 , wherein the carboxyl group-containing nitrile rubber (A) includes α claim 1 ,β-ethylenically unsaturated dicarboxylic acid monoester ...

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09-01-2020 дата публикации

POLYMERIZABLE COMPOSITION AND MOLDED PRODUCT

Номер: US20200010665A1
Принадлежит: Mitsui Chemicals, Inc.

A polymerizable composition of the present invention includes a polymerization reactive compound (A), and an internal release agent (B) including a polyether-modified silicone compound (b1) represented by General Formula (1) and a polyether-modified silicone compound (b2) represented by General Formula (2), in which the polymerization reactive compound (A) is one or more compounds selected from a polyiso(thio) cyanate compound, a poly(thio) epoxy compound, a polyoxetanyl compound, a polythietanyl compound, an alkyne compound, a poly(thi)ol compound, a polyamine compound, an acid anhydride, or a polycarboxylic acid compound. 2. The polymerizable composition according to claim 1 ,wherein the polymerization reactive compound (A) is a combination of two compounds selected from a poly(thio)epoxy compound, an acid anhydride, a polyiso(thio)cyanate compound, and a poly(thi)ol compound.3. The polymerizable composition according to claim 1 ,{'sup': −1', '4, 'wherein the internal release agent (B) is included in the amount of 1×10to 5×10ppm with respect to the polymerization reactive compound (A).'}4. A molded product formed by curing the polymerizable composition according to .5. An optical material comprising:{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, 'the molded product according to .'}6. A plastic lens comprising:{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, 'the molded product according to .'}7. A process for producing a plastic lens claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a step of cast-polymerizing the polymerizable composition according to .'} The present invention relates to a polymerizable composition including an internal release agent and a molded product.From the viewpoint that a plastic lens is lightweight and hardly broken as compared with an inorganic lens, it has been rapidly distributed as an optical element for an eyeglass lens, a camera lens, or the like. Various resin materials for a lens have hitherto been ...

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09-01-2020 дата публикации

CONDUCTIVE POLYAMIDE RESIN COMPOSITION

Номер: US20200010678A1
Принадлежит: TOYOBO CO., LTD.

Disclosed is a conductive polyamide resin composition that excels not only in electroconductivity, but also in fuel resistance, particularly resistance against alcohol-containing fuel, and further excels in fluidity and moldability, and is capable of yielding a molded article with high impact resistance, the conductive polyamide resin composition including: 84 to 40% by mass of a polyamide resin (A); 5 to 30% by mass of conductive carbon black (B); 3 to 30% by mass of an ethylene-α-olefin copolymer (C) that has a reactive functional group capable of reacting with a terminal group of polyamide resin and/or an amido group on a principal chain of polyamide resin; and 1 to 20% by mass of a conductive polyethylene resin (D). 1. A conductive polyamide resin composition comprising:84 to 40% by mass of a polyamide resin (A);5 to 30% by mass of conductive carbon black (B);3 to 30% by mass of an ethylene-α-olefin copolymer (C) that has a reactive functional group capable of reacting with a terminal group of polyamide resin and/or an amido group on a principal chain of polyamide resin; and1 to 20% by mass of a conductive polyethylene resin (D),the conductive polyamide resin composition satisfying characteristics (i) and (ii) below:{'sup': 5', '7, '(i) a flat plate (100 mm×100 mm×2 mm (thickness)) obtained by injection molding of the conductive polyamide resin composition shows an initial volume resistivity less than or equal to 1×10Ω·cm, and the flat plate after exposed to CM15 fuel for 168 hours shows a volume resistivity less than or equal to 1×10Ω·cm; and'}{'sup': '2', '(ii) a test piece obtained by injection molding of the conductive polyamide resin composition shows a Charpy impact strength at −40° C. greater than or equal to 2.0 KJ/m.'}2. The conductive polyamide resin composition according to claim 1 , wherein the conductive polyamide resin composition satisfies characteristic (iii) below:(iii) showing a melt index, measured at 250° C. under 10 kgf load, greater than or ...

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09-01-2020 дата публикации

Rheological Methods For High Block, Tack and Scrub Resistant Coating Composition

Номер: US20200010712A9
Принадлежит: Valspar Sourcing, Inc.

The present invention is directed to a coating composition or paint comprising a multistage latex with at least first and second stages, wherein the composition or paint is substantially free of volatile organic compounds (VOC) and capable of film formation even in the absence of coalescent agents. The base paint formulation is capable of being tinted at a point-of-sale (i.e. in-store) using a colorant composition of a type and quantity required to produce a paint of desired color and finish. The paints, show improved block resistance, scrub resistance and tack resistance. Rheological techniques as described herein may be used to determine tack resistance, print resistance, and other performance characteristics. 1. A coating composition , comprising:a latex polymer having a Tg of about −35 to 120° C.;optionally, about 0.5 wt % fluorosurfactant; andoptionally, about 0 to 15 wt % of one or more colorant compositions havingvolatile organic content (VOC) of less than about 5 wt %,{'sup': 6', '7, 'wherein the coating composition has scrub resistance of at least 1000, storage modulus (E′) of about 1.0×10to 1.0 to 10Pa at 60° C. and 0.1 rad/s and tan (δ) of less than about 0.2 at 60° C. and 0.1 rad/s.'}2. The composition of claim 1 , wherein the latex polymer is a multistage composition comprising:at least a first stage with Tg of about 0 to 120° C.; andat least a second stage with Tg of about −35 to 10° C.3. The composition of claim 1 , wherein the latex polymer is derived from a mixture of monomers for the first stage or second stage claim 1 , wherein the mixture of monomers comprise one or more ethylenically unsaturated monomers selected from acrylic acid claim 1 , C1-C8 esters of acrylic acid claim 1 , substituted C1-C8 esters of acrylic acid claim 1 , methacrylic acid claim 1 , C1-C8 ester of methacrylic acid claim 1 , substituted C1-C8 esters of methacrylic acid claim 1 , styrene claim 1 , a-methyl styrene claim 1 , vinyl toluene claim 1 , vinyl acetate claim 1 , ...

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09-01-2020 дата публикации

SILICONE MEMBRANES

Номер: US20200011061A1
Принадлежит:

A method for covering a roof, the method comprising (i) providing first and second silicone membranes, where the membranes are in the form of rolls; (ii) unrolling the first and second silicone membranes over a roof surface; (iii) positioning first and second membranes adjacent to one another and overlapping and edge of the second over an adjacent edge of the first membrane to thereby form a lap; (iv) securing the first and second membranes to the roof surface; and (v) seaming the first membrane to the second membrane in the lap. 1. A method for covering a roof , the method comprising:(i) providing first and second silicone membranes, where the membranes are in the form of rolls;(ii) unrolling the first and second silicone membranes over a roof surface;(iii) positioning first and second membranes adjacent to one another and overlapping and edge of the second over an adjacent edge of the first membrane to thereby form a lap;(iv) securing the first and second membranes to the roof surface; and(v) seaming the first membrane to the second membrane in the lap.2. The method of claim 1 , where said step of securing includes mechanically fastening the membranes to the roof surface.3. The method of claim 1 , where said step of securing includes adhesively securing the membranes to the roof surface.4. The method of claim 1 , where said step of seaming the first membrane to the second membrane includes adhesively seaming the membranes.5. The method of claim 1 , where the first and second silicone membranes are characterized by tensile strength of 100 psi to 2 claim 1 ,000 psi as measured according to ASTM D412.6. The method of claim 5 , where the first and second silicone membranes are characterized by elongation at break of 50% to 400% as measured according to ASTM D412.7. The method of claim 6 , where the first and second silicone membranes are characterized by a reflectivity of 13% or greater wherein the reflectivity is measured after 3 months of exterior exposure and where ...

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15-01-2015 дата публикации

Encapsulating material for solar cell and solar cell module

Номер: US20150013755A1
Принадлежит: Mitsui Chemicals Tohcello Inc

An encapsulating material for solar cell of the invention contains an ethylene/α-olefin copolymer, an organic peroxide, at least one crosslinking aid selected from a group consisting of divinyl aromatic compounds, cyanurates, diallyl compounds, triallyl compounds, oximes and maleimides, and a (meth)acrylate-based monomer. The content of the (meth)acrylate-based monomer in the encapsulating material for solar cell is in a range of 0.1 parts by weight to 5.0 parts by weight with respect to 100 parts by weight of the ethylene/α-olefin copolymer, and the content of the crosslinking aid in the encapsulating material for solar cell is in a range of 0.1 parts by weight to 3 parts by weight with respect to 100 parts by weight of the ethylene/α-olefin copolymer.

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09-01-2020 дата публикации

PREPARATION METHOD OF CROSSLINKING-TYPE AQUEOUS BINDER FOR LITHIUM-ION BATTERIES INCORPORATING SLURRY COATING AND DRYING PROCESS

Номер: US20200014029A1
Автор: Su Jing, Zhang Lingzhi

A preparation method of a crosslinking-type aqueous binder for lithium-ion batteries. An organic carboxylic group-, amino group- or hydroxyl group-containing hydrophilic polymer, and a hydroxyl group-, amine group- or carboxyl group-containing water-soluble small-molecule crosslinker, both serve as starting materials of the aqueous binder, and can be crosslinked by esterification or amidation under coating and drying conditions of lithium-ion battery electrode slurry. The preparation method of the crosslinking-type aqueous binder is simple, without the need of modifying the current process or conditions for lithium-ion battery manufacture. The obtained electrodes have excellent binding capacity, flexibility, and elasticity. 1. A crosslinking-type aqueous binder for lithium-ion batteries , comprising , an organic carboxylic group- , amino group- or hydroxyl group-containing hydrophilic polymer , and a hydroxyl group- , amine group- or carboxyl group-containing water-soluble small-molecule crosslinker , wherein the organic carboxylic group- , amino group- or hydroxyl group-containing hydrophilic polymer has a molecular weight of 70000-1000000; the organic carboxylic group-containing hydrophilic polymer is prepared through a free radical graft copolymerization or a Michael addition reaction of an acrylic monomer and the hydroxyl group-containing hydrophilic polymer; the hydroxyl group-containing hydrophilic polymer is one or more selected from the group consisting of arabic gum , cyclodextrin , cellulose derivatives , xanthan gum , pectin , gelatin , starch , sesbania gum , polyvinyl alcohol , polyethylene glycol and polyhydroxy polybutadiene; the amino group-containing hydrophilic polymer is one or more selected from the group consisting of arabic gum , chitosan and its derivatives , linear polyethyleneimine and branched polyethyleneimine; a method of preparing the crosslinking-type aqueous binder comprises the following steps:(1) dissolving the organic carboxylic ...

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03-02-2022 дата публикации

RESIN COMPOSITION AND MOLDED PRODUCT THEREOF

Номер: US20220033628A1
Принадлежит: ZEON CORPORATION

Provided is a resin composition configured to show a small change in the void ratio of hollow resin particles during mold processing and configured to stably mold a lightweight molded product having a small variation in specific gravity. The resin composition is a resin composition comprising 50 parts by mass to 95 parts by mass of a thermoplastic elastomer and 5 parts by mass to 50 parts by mass of hollow resin particles, wherein the hollow resin particles have a void ratio of from 50% to 85%; wherein the hollow resin particles have a shell containing a resin; and wherein, with respect to 100 parts by mass of repeating units constituting the resin, 30 parts by mass to 100 parts by mass of a crosslinkable monomer unit and 0 part by mass to 70 parts by mass of a non-crosslinkable monomer unit are contained as a polymerizable monomer unit. 1. A resin composition comprising 50 parts by mass to 95 parts by mass of a thermoplastic elastomer and 5 parts by mass to 50 parts by mass of hollow resin particles ,wherein the hollow resin particles have a void ratio of from 50% to 85%;wherein the hollow resin particles have a shell containing a resin; andwherein, with respect to 100 parts by mass of repeating units constituting the resin, 30 parts by mass to 100 parts by mass of a crosslinkable monomer unit and 0 part by mass to 70 parts by mass of a non-crosslinkable monomer unit are contained as a polymerizable monomer unit.2. The resin composition according to claim 1 , wherein the hollow resin particles do not exhibit a glass transition temperature in a range of from 0° C. to 250° C.3. The resin composition according to claim 1 , wherein the hollow resin particles have a volume-based average particle diameter of from 1.0 μm to 20.0 μm.4. A molded product comprising the resin composition defined by .5. The resin composition according to claim 1 , wherein the hollow resin particles have a particle size distribution (the volume average particle diameter (Dv)/the number average ...

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03-02-2022 дата публикации

THERMOPLASTIC ELASTOMER COMPOSITION

Номер: US20220033632A1
Автор: Konishi Takahiro
Принадлежит:

Provided is a thermoplastic elastomer composition capable of producing a molded article having a good appearance such as surface smoothness and excellent bondability to another member, the thermoplastic elastomer composition comprising: an ethylene-based polymer (A); and a propylene-based polymer (B), wherein a melt viscosity of the thermoplastic elastomer composition measured at a temperature of 220° C. and a shear rate of 12 secis 2,500 Pa·sec or less; the thermoplastic elastomer composition has a sea-island structure; and an island portion has a volume average particle diameter of 2.1 μm or more and a particle diameter dispersion D of 7.0 or less. 1. A thermoplastic elastomer composition comprising:an ethylene-based polymer (A); anda propylene-based polymer (B), whereina melt viscosity of the thermoplastic elastomer composition measured at a temperature of 220° C. and a shear rate of 12 sec-1 is 2,500 Pa·sec or less;the thermoplastic elastomer composition has a sea-island structure; andan island portion has a volume average particle diameter of 2.1 μm or more and a particle diameter dispersion D of 7.0 or less.2. The thermoplastic elastomer composition according to claim 1 , further comprising a mineral oil (D) claim 1 , wherein the ethylene-based polymer (A) is oil-extended with the mineral oil (D).3. The thermoplastic elastomer composition according to claim 1 , wherein the ethylene-based polymer (A) has a Mooney viscosity (ML100° C.) of 40 or more.4. The thermoplastic elastomer composition according to claim 2 , wherein an oil-extended polymer comprising the ethylene-based polymer (A) and the mineral oil (D) has a Mooney viscosity (ML100° C.) of 40 or more.5. A method for producing a thermoplastic elastomer composition claim 2 , comprising a step of melt-kneading an ethylene-based polymer (A) and a propylene-based polymer (B) in the presence of a crosslinking agent (C) claim 2 , wherein{'sub': '1+4', 'the ethylene-based polymer (A) has a Mooney viscosity ( ...

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03-02-2022 дата публикации

CURABLE FLUORINE-BASED ELASTOMER COMPOSITE AND CURED PRODUCT THEREOF

Номер: US20220033634A1
Автор: Aoki Tamon, Suzuki Yuta
Принадлежит:

A curable fluorine-based elastomer composite containing a curable fluorine-based polymer including a curable fluorine-based elastomer including a copolymerization unit having a curing site; a crosslinking agent that reacts with a curing site to form a crosslinking unit in the elastomer; and a crosslinking aid including an organic onium salt, in which the total content of the crosslinking agent and the crosslinking aid is about 0.5 parts by mass or more and about 3 parts by mass or less with reference to 100 parts by mass of the curable fluorine-based polymer, and the ratio between the crosslinking agent and the crosslinking aid is from about 2:8 to about 7:3. 1. A curable fluorine-based elastomer composite , comprising:a curable fluorine-based polymer comprising a curable fluorine-based elastomer including a copolymerization unit having a curing site;a crosslinking agent that reacts with the curing site of the elastomer to form a crosslinking unit in the elastomer; anda crosslinking aid including an organic onium salt, wherein the organic onium salt is a salt of (trifluoromethyl)benzyl alcohol and tetramethyl ammonium or tetrabutyl phosphonium, and wherein the total content of the crosslinking agent and the crosslinking aid is about 0.5 parts by mass or more and about 3 parts by mass or less with reference to 100 parts by mass of the curable fluorine-based polymer, and the ratio between the crosslinking agent and the crosslinking aid is from about 2:8 to about 7:3.2. The composite of claim 1 , wherein the curable fluorine-based elastomer composite further comprises a curable fluorine-based plastic including a copolymerization unit having a curing site claim 1 , the curing site of the curable fluorine-based plastic is a site that reacts with the crosslinking agent to form a crosslinked unit in the plastic.3. The composite of claim 1 , wherein the curing site of the elastomer is a cyano group.4. The composite of claim 1 , wherein the curable fluorine-based elastomer ...

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03-02-2022 дата публикации

RESIN COMPOSITION AND MOLDED PRODUCT THEREOF

Номер: US20220033652A1
Принадлежит: ZEON CORPORATION

Provided is a resin composition configured to show a small change in the void ratio of hollow resin particles during mold processing and configured to stably mold a lightweight molded product. The resin composition is a resin composition comprising 50 parts by mass to 95 parts by mass of a thermoplastic plastomer and 5 parts by mass to 50 parts by mass of hollow resin particles, wherein the hollow resin particles have a void ratio of from 50% to 85%; wherein the hollow resin particles have a shell containing a resin; and wherein, with respect to 100 parts by mass of repeating units constituting the resin, 30 parts by mass to 100 parts by mass of a crosslinkable monomer unit and 0 part by mass to 70 parts by mass of a non-crosslinkable monomer unit are contained as a polymerizable monomer unit. 1. A resin composition comprising 50 parts by mass to 95 parts by mass of a thermoplastic plastomer and 5 parts by mass to 50 parts by mass of hollow resin particles ,wherein the hollow resin particles have a void ratio of from 50% to 85%;wherein the hollow resin particles have a shell containing a resin; andwherein, with respect to 100 parts by mass of repeating units constituting the resin, 30 parts by mass to 100 parts by mass of a crosslinkable monomer unit and 0 part by mass to 70 parts by mass of a non-crosslinkable monomer unit are contained as a polymerizable monomer unit.2. The resin composition according to claim 1 , wherein the hollow resin particles do not exhibit a glass transition temperature in a range of from 0° C. to 250° C.3. The resin composition according to claim 1 , wherein the hollow resin particles have a volume-based average particle diameter of from 1.0 μm to 20.0 μm.4. A molded product comprising the resin composition defined by .5. The resin composition according to claim 1 , wherein the hollow resin particles have a particle size distribution (the volume average particle diameter (Dv)/the number average particle diameter (Dn)) of from 1.00 to 2.50. ...

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15-01-2015 дата публикации

Fluororubber composition

Номер: US20150017364A1
Принадлежит: Daikin Industries Ltd

A fluororubber composition including a fluororubber having an iodine content of 10 to 90 mol % for the total mole of the polymer end groups and a carbon black (B), wherein a difference (δG′), represented by G′(1%)-G′(100%), is not lower than 120 kPa and not higher than 3,000 kPa, where G′(1%) denotes a shear modulus at a dynamic strain of 1% under an uncrosslinked state and G′(100%) denotes a shear modulus at a dynamic strain of 100% under an uncrosslinked state, and G′(1%) and G′(100%) are determined by a dynamic viscoelasticity test with a rubber process analyzer (RPA) in a condition that the measurement frequency is 1 Hz and the measurement temperature is 100° C.

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19-01-2017 дата публикации

POLYCARBONATE FIBERS AND SUBSTRATES COMPRISING SAME

Номер: US20170015783A1
Принадлежит:

Disclosed herein are polycarbonate fibers and fibrous substrates, such as papers, containing such fibers. The polycarbonate fibers are produced from a polymeric composition comprising a cross-linkable polycarbonate containing endgroups derived from a monofunctional benzophenone or containing repeating units derived from a difunctional benzophenone. The polycarbonate fibers can be combined with other fibers to form the fibrous substrate. Upon exposure to ultraviolet light, crosslinking of the polycarbonate fibers will occur, improving various properties of the fibrous substrate. 1. A cross-linkable polycarbonate fiber , formed from a polymeric composition comprising a cross-linkable polycarbonate resin containing a photoactive group derived from a benzophenone.2. The fiber of claim 1 , having a diameter of about 1 micron to about 40 microns and an aspect ratio of about 3:1 to about 1 million:1.3. The fiber of claim 1 , wherein the benzophenone from which the photoactive group is derived is a monohydroxybenzophenone.4. The fiber of claim 3 , wherein the cross-linkable polycarbonate resin is formed from a reaction of: the monohydroxybenzophenone; a diol chain extender; and a first linker moiety comprising a plurality of linking groups claim 3 , wherein each linking group can react with the hydroxyl groups of the monohydroxybenzophenone and the diol chain extender.5. The fiber of claim 3 , wherein the cross-linkable polycarbonate resin contains from about 0.5 mole % to about 5 mole % of endcap groups derived from the monohydroxybenzophenone and has a polydispersity index (PDI) of between 3.0 and 7.3 as measured by GPC using a UV-VIS detector and polycarbonate standards.6. The fiber of claim 1 , wherein the benzophenone from which the photoactive group is derived is a dihydroxybenzophenone.7. The fiber of claim 6 , wherein the cross-linkable polycarbonate resin is formed from a reaction of: the dihydroxybenzophenone; a diol chain extender; a first linker moiety ...

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19-01-2017 дата публикации

Adhesive composition containing ionic antistatic agent

Номер: US20170015878A1
Автор: Han Young Choi
Принадлежит: Dongwoo Fine Chem Co Ltd

An adhesive composition includes an acryl copolymer, a cross-linking agent, and an ionic antistatic agent represented by Formula 1, thereby exhibiting excellent antistatic property, as well as, significantly improved durability, maintaining excellent adhesiveness under severe conditions such as high temperature and high humidity atmospheres, and securing sufficient antistatic property even if used in a small amount.

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17-01-2019 дата публикации

NOVEL HETERO-DIELS-ALDER CROSS-LINKER AND USE THEREOF IN REVERSIBLY CROSSLINKED POLYMER SYSTEMS

Номер: US20190016676A1
Принадлежит: EVONIK DEGUSSA GmbH

The invention relates to a novel hetero-Diels-Alder crosslinker, to a process for the production thereof and to the use thereof for reversibly crosslinking polymer systems. 2. The formulation according to claim 1 , wherein:at least one of the components A or B comprises more than two functionalities;at least one of the components A or B is present in the form of a polymer, andthe formulation is crosslinkable at room temperature, and the crosslinking is reversible to an extent of at least 50% at a higher temperature.3. The formulation according to claim 1 , wherein:{'sub': '1', 'the component A is a compound having a plurality of the structural unit (Z) and these are bonded to one another with alkylene groups Rhaving between 1 and 5 carbon atoms; and'}{'sub': '2', 'Rhas between 2 and 10 carbon atoms.'}5. The formulation according to claim 1 , wherein the component B is a polymer.6. The formulation according to claim 5 , wherein the polymer is selected from the group consisting of polyacrylates claim 5 , polymethacrylates claim 5 , polystyrenes claim 5 , mixed polymers made of acrylates claim 5 , methacrylates and/or styrenes claim 5 , polyacrylonitrile claim 5 , polyethers claim 5 , polyesters claim 5 , polylactic acids claim 5 , polyamides claim 5 , polyesteramides claim 5 , polyurethanes claim 5 , polycarbonates claim 5 , amorphous or semicrystalline poly-α-olefins claim 5 , EPDM claim 5 , EPM claim 5 , hydrogenated or non-hydrogenated polybutadienes claim 5 , ABS claim 5 , SBR claim 5 , polysiloxanes and block claim 5 , comb and/or star copolymers of these polymers.9. The formulation according to claim 1 , wherein the component B is a polyamide claim 1 , a polyester or a polycarbonate having at least one diene functionality.10. The formulation according to claim 1 , wherein the component A has one of the structural unit (Z) claim 1 , and the component B has one diene group.11. A process for reversible crosslinking claim 1 , the process comprising crosslinking the ...

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17-01-2019 дата публикации

METHOD FOR PRODUCING THERMOPLASTIC ELASTOMER COMPOSITION

Номер: US20190016889A1
Автор: NAKASHIMA Tomonori
Принадлежит: ZEON CORPORATION

A method for producing a thermoplastic elastomer composition, the method including the step of dynamically cross-linking a highly saturated nitrile rubber in the presence of a polyamide-based polymer and a polyamine cross-linking agent. The highly saturated nitrile rubber contains an α,β-ethylenically unsaturated nitrile monomer unit and an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit and has an iodine value of 120 or less. 1. A method for producing a thermoplastic elastomer composition , the method comprising the step of dynamically cross-linking a highly saturated nitrile rubber (A) in the presence of a polyamide-based polymer (B) and a polyamine cross-linking agent (C) , the highly saturated nitrile rubber (A) containing an α ,β-ethylenically unsaturated nitrile monomer unit and an α ,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit and having an iodine value of 120 or less.2. The method for producing a thermoplastic elastomer composition according to claim 1 , wherein the dynamic cross-linking is performed by mixing the highly saturated nitrile rubber (A) claim 1 , the polyamide-based polymer (B) claim 1 , and the polyamine cross-linking agent (C) at 100 to 400° C.3. The method for producing a thermoplastic elastomer composition according to claim 1 , wherein a blending ratio of the highly saturated nitrile rubber (A) and the polyamide-based polymer (B) is 20:80 to 80:20 in terms of a weight ratio of “highly saturated nitrile rubber (A):polyamide-based polymer (B)”.4. The method for producing a thermoplastic elastomer composition according to claim 1 , wherein an amount of the polyamine cross-linking agent (C) blended is 0.1 to 20 parts by weight with respect to 100 parts by weight of the highly saturated nitrile rubber (A).5. The method for producing a thermoplastic elastomer composition according to claim 1 , wherein the polyamide-based polymer (B) is at least one selected from nylon 6 and nylon 66.6. The method ...

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17-01-2019 дата публикации

Preceramic resin formulations, ceramic materials comprising the preceramic resin formulations, and related articles and methods

Номер: US20190016892A1
Автор: Benjamin W.C. Garcia
Принадлежит: Northrop Grumman Innovation Systems LLC

A preceramic resin formulation comprising a polycarbosilane preceramic polymer and an organically modified silicon dioxide preceramic polymer. A ceramic material comprising a reaction product of the polycarbosilane preceramic polymer and organically modified silicon dioxide preceramic polymer is also described. Articles comprising the ceramic material are also described, as are methods of forming the preceramic resin formulation and the ceramic material.

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16-01-2020 дата публикации

WATER-SOLUBLE AND/OR WATER-SWELLABLE HYBRID POLYMER

Номер: US20200017619A1
Принадлежит: CLARIANT INTERNATIONAL LTD.

A water-soluble and/or water-swellable hybrid polymer comprising: 2. The water-soluble and/or water-swellable hybrid polymer according to claim 1 , wherein the monomers resulting in units (a) claim 1 , (b) claim 1 , (c) and/or (d) are/is neutralized with a base prior to the polymerization claim 1 , and/or the hybrid polymer after polymerization is neutralized with a base.3. The water-soluble and/or water-swellable hybrid polymer according to claim 2 , wherein the base is selected from bases comprising an ion selected from the group consisting of Li claim 2 , Na claim 2 , K claim 2 , Ca claim 2 , Mg claim 2 , ZnAland combinations thereof.4. The water-soluble and/or water-swellable hybrid polymer according to claim 1 , wherein the repeating units according to Formula (1) result from the incorporation of a monomer selected from the group consisting of acryloyldimethyltaurates claim 1 , acryloyl-1 claim 1 ,1-dimethyl-2-methyltaurates claim 1 , acryloyltaurates claim 1 , acryloyl-N-methyltaurates claim 1 , and combinations thereof.7. The water-soluble and/or water-swellable hybrid polymer according to claim 1 , wherein the hybrid polymer comprises at least 30 wt.-% polysaccharide polymer claim 1 , by total weight of the hybrid polymer.8. The water-soluble and/or water-swellable hybrid polymer according to claim 1 , wherein the crosslinking or branching units result from the incorporation of a crosslinker selected from the group consisting of methylenebisacrylamide; methylenebismethacrylamide; esters of unsaturated monocarboxylic and polycarboxylic acids with polyols claim 1 , allyl esters of phosphoric acid; and vinylphosphonic acid derivatives.9. The water-soluble and/or water-swellable hybrid polymer according to claim 1 , wherein the polysaccharide polymer is selected from the group consisting of xanthan gum claim 1 , carrageenan claim 1 , guar gum claim 1 , chitosan and alginate.10. The water-soluble and/or water-swellable hybrid polymer according to claim 1 , ...

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16-01-2020 дата публикации

GLASS FLAKES AND RESIN COMPOSITION

Номер: US20200017660A1
Автор: Kato Shinichi, TAI Nobuaki
Принадлежит: NIPPON SHEET GLASS COMPANY, LIMITED

Glass flakes of the present invention include glass flake substrates and a coating covering at least a portion of the surface of each of the glass flake substrates and composed of a binder. The binder includes a silane coupling agent, an epoxy resin, and a carbodiimide compound as essential components and includes, as an optional component, a crosslinking agent other than a carbodiimide compound. The total amount of the carbodiimide compound and the crosslinking agent is 20 mass % or less with respect to the total mass of the binder. 1. Glass flakes comprising:glass flake substrates; anda coating covering at least a portion of the surface of each of the glass flake substrates and composed of a binder, whereinthe binder comprises a silane coupling agent, an epoxy resin, and a carbodiimide compound as essential components and comprises, as an optional component, a crosslinking agent other than a carbodiimide compound, andthe total amount of the carbodiimide compound and the crosslinking agent is 20 mass % or less with respect to the total mass of the binder.2. The glass flakes according to claim 1 , wherein the crosslinking agent comprises at least one selected from the group consisting of a butadiene-maleic anhydride copolymer claim 1 , an itaconic acid-maleic anhydride copolymer claim 1 , an ethylene-maleic anhydride copolymer claim 1 , and a styrene-maleic anhydride copolymer.3. The glass flakes according to claim 1 , wherein the proportion of the coating in the glass flakes is 0.05 to 1.5 mass %.4. The glass flakes according to claim 1 , wherein the glass flake substrates have an average thickness of 0.1 to 10 μm and an average particle diameter of 10 to 2000 μm.5. A resin composition comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the glass flakes according to ; and'}a matrix resin.6. The resin composition according to claim 5 , wherein the matrix resin is a thermoplastic polyester resin.7. The resin composition according to claim 6 , wherein the ...

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21-01-2021 дата публикации

Cross-Linked Polyolefin Separator and Manufacturing Method Thereof

Номер: US20210017351A1
Принадлежит: LG CHEM, LTD.

A method for manufacturing a crosslinked polyolefin separator and the crosslinked polyolefin separator obtained therefrom are provided. The method includes non-grafted polyolefin having a weight average molecular weight of 300,000 or more and silane-grafted polyolefin having a weight average molecular weight of 300,000 or more. The method minimizes gel formation, a side reaction occurring in an extruder during the manufacture of a-the separator, and provides a-the separator having a uniform surface. 1. A method for manufacturing a crosslinked polyolefin separator , comprising:{'b': '1', '(S) mixing non-grafted polyolefin having a weight average molecular weight of 300,000 or more, silane-grafted polyolefin having a weight average molecular weight of 300,000 or more, a diluting agent, an initiator, an alkoxysilane compound containing a carbon-carbon double bonded group and a crosslinking catalyst to an extruder and then carrying out reactive extrusion at 200° C. or higher to obtain a silane-grafted polyolefin composition;'}{'b': '2', '(S) molding and orienting the reactive extruded silane-grafted polyolefin composition in the form of a sheet;'}{'b': '3', '(S) extracting the diluting agent from the oriented sheet to obtain a porous membrane;'}{'b': '4', '(S) thermally fixing the porous membrane; and'}{'b': '5', '(S) crosslinking the porous membrane in the presence of water,'}wherein a content of the alkoxysilane compound containing the carbon-carbon double bonded group is 0.01-2 parts by weight based on 100 parts by weight of a total weight of the non-grafted polyolefin, silane-grafted polyolefin and the diluting agent.2. The method for manufacturing the crosslinked polyolefin separator according to claim 1 , wherein a weight ratio of the non-grafted polyolefin to the silane-grafted polyolefin is 90:10-20:80.3. The method for manufacturing the crosslinked polyolefin separator according to claim 1 , wherein the non-grafted polyolefin has a weight average molecular ...

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16-01-2020 дата публикации

GRAFT COPOLYMER, AND THERMOPLASTIC RESIN COMPOSITION USING SAME

Номер: US20200017686A1
Принадлежит:

A graft copolymer (B-III) includes a rubbery polymer (A-III) that is a miniemulsion polymerization reaction product of an alkyl (meth)acrylate; and at least one monomer selected from aromatic vinyl compounds, (meth)acrylic acid esters, and vinyl cyanide compounds graft-polymerized onto the rubbery polymer (A-III). 1. A graft copolymer (B-III) comprising:a rubbery polymer (A-III) that is a miniemulsion polymerization reaction product of an alkyl (meth)acrylate; andat least one monomer selected from aromatic vinyl compounds, (meth)acrylic acid esters, and vinyl cyanide compounds graft-polymerized onto the rubbery polymer (A-III).2. A thermoplastic resin composition comprising the graft copolymer (B-III) according to .3. A molded article obtained by molding the thermoplastic resin composition according to . This is a divisional Application of Ser. No. 15/771,823 filed on Apr. 27, 2018, which claims priorities of Japanese Patent Applications No. 2015-212024 filed on Oct. 28, 2015, No. 2015-212025 filed on Oct. 28, 2015, No. 2015-212026 filed on Oct. 28, 2015, and No. 2015-212027 filed on Oct. 28, 2015, disclosure of which is incorporated herein.The present invention relates to first to fourth inventions below.The first invention relates to a graft polymer that has an excellent impact-resistance-imparting effect and that can provide a thermoplastic resin composition excellent in weather resistance and color developability, a production method thereof, a thermoplastic resin composition including the graft copolymer, and a molded article thereof.The second invention relates to crosslinked particles and graft crosslinked particles that, as modifiers of a thermoplastic resin, can improve the flowability, impact resistance, and abrasion resistance of the resin without impairing its color developability and mold shrinkage rate, a thermoplastic resin composition including the crosslinked particles and/or the graft crosslinked particles, and a molded article thereof.The third ...

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21-01-2021 дата публикации

Coating Compositions

Номер: US20210017379A1
Принадлежит: PPG Industries Ohio, Inc.

Disclosed herein is a composition comprising: an epoxy-containing component, elastomeric particles in an amount of greater than 11% by weight to 25% by weight based on total weight of the composition; and a curing component activatable by an external energy source, the curing component comprising at least one guanidine having a D90 particle size of 25 μm measured by dynamic light scattering. Also disclosed is the composition in an at least partially cured state. Also disclosed is a method for treating a substrate comprising applying the composition to a surface of a substrate; and applying an external energy source to cure the composition. Also disclosed are substrates comprising the composition. Also disclosed are substrates formed by the method of the present invention. 1. A composition , comprising:an epoxy-containing component;elastomeric particles in an amount of greater than 11% by weight to 25% by weight based on total weight of the composition; anda curing component activatable by an external energy source, the curing component comprising at least one guanidine having a D90 particle size of 25 μm measured by dynamic light scattering.2. The composition of claim 1 , wherein the elastomeric particles are phase-separated from the epoxy-containing component.3. The composition of claim 1 , wherein the epoxy-containing component comprises bisphenol A polyepoxide claim 1 , bisphenol F polyepoxide claim 1 , a novolac resin claim 1 , or combinations thereof.4. The composition of claim 1 , wherein the epoxy-containing component is present in an amount of 45% to 90% by weight based on total weight of the composition.5. The composition of claim 1 , wherein the epoxy-containing component has an average epoxide functionality of greater than 1.0 and less than 3.2.6. The composition of claim 1 , wherein at least 50% by weight of the elastomeric particles comprise a styrene butadiene core based on total weight of the elastomeric particles claim 1 , at least 50% of the ...

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17-04-2014 дата публикации

Composite Structures Using Interpenetrating Polymer Network Adhesives

Номер: US20140103254A1
Автор: Gary Robert Weber
Принадлежит: Boeing Co

A composition is provided that consists essentially of a first polymer system and a second polymer system. The first polymer system has a first modulus of about 180 ksi to about 335 ksi. The first polymer system consists essentially of a thermosetting acrylate. The second polymer system consists essentially of a thermosetting epoxy system and an epoxy curing agent. The thermosetting epoxy system comprises a first epoxy.

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17-01-2019 дата публикации

ELECTRON-ACCEPTING COMPOUND AND COMPOSITION FOR CHARGE-TRANSPORTING FILM, AND LUMINESCENT ELEMENT USING SAME

Номер: US20190019956A1
Принадлежит: MITSUBISHI CHEMICAL CORPORATION

The present invention provides with an electron-accepting compound having a structure of the following formula (1): 2. The electron-accepting compound according to claim 1 , wherein the above k is 0 claim 1 , the above a is 1 claim 1 , and the above Ar is each independently an aromatic ring group which may have a substituent.3. The electron-accepting compound according to claim 2 , wherein Ar of the above formula (1) has four or more fluorine atoms as substituents.7. The electron-accepting compound according to claim 1 , wherein at least one Ar of the above formula (1) has a crosslinkable group.8. A composition for a charge-transporting film claim 1 , comprising the electron-accepting compound according to and a hole-transporting compound.9. The composition for a charge-transporting film according to claim 8 , wherein the hole-transporting compound is an aromatic tertiary amine compound.10. The composition for a charge-transporting film according to claim 8 , which further comprises a solvent.11. The composition for a charge-transporting film according to claim 10 , wherein the solvent contains at least one solvent selected from the group consisting of ether-based solvents and ester-based solvents.12. The composition for a charge-transporting film according to claim 8 , which is used for a hole injection layer of an organic electroluminescent element.13. An organic electroluminescent element comprising a hole injection layer and a luminescent layer between an anode and a cathode and emitting light by electric energy claim 8 , wherein the hole injection layer is a layer formed by applying and drying the composition for a charge-transporting film according to to form a film.14. A display using the organic electroluminescent element according to .15. A lighting device using the organic electroluminescent element according to .16. A light-emitting device using the organic electroluminescent element according to .17. An electron-accepting compound having a crosslinkable ...

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24-01-2019 дата публикации

POLYOLEFIN ELASTOMER COMPOSITIONS AND METHODS OF MAKING THE SAME

Номер: US20190021441A1
Принадлежит: COOPER-STANDARD AUTOMOTIVE INC.

An elastomeric article is provided that includes a composition having a silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm. The elastomeric article can exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.). The silane-crosslinked polyolefin elastomer can include a first polyolefin having a density less than 0.86 g/cm, a second polyolefin having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, and a condensation catalyst. 1. A silane-crosslinked polyolefin elastomer blend comprising:{'sup': '3', 'a first polyolefin having a density less than 0.86 g/cm;'}a second polyolefin having a percent crystallinity less than 40%;a silane crosslinker,{'sup': '3', 'wherein the silane-crosslinked polyolefin elastomer blend exhibits a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.) and wherein the silane-crosslinked polyolefin elastomer blend has a density less than 0.90 g/cm.'}2. The silane-crosslinked polyolefin elastomer blend of further comprising a microencapsulated foaming agent.3. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the density is less than 0.70 g/cm.4. The silane-crosslinked polyolefin elastomer blend of further comprising a foaming agent.5. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the density is less than 0.60 g/cm.6. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the compression set is from about 15.0% to about 35.0% claim 1 , as measured according to ASTM D 395 (22 hrs @ 70° C.).7. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the first polyolefin comprises an ethylene-octene copolymer from about 60 wt % to about 97 wt %.8. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the second polyolefin comprises a polypropylene homopolymer from about 10 wt % to about 35 wt % and/or ...

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10-02-2022 дата публикации

Tire provided with an outer sidewall, the composition of which comprises a derivative of polyethylene oxide

Номер: US20220041013A1

A tire is provided with an external sidewall, the said external sidewall comprising at least one composition based on at least from 15 to 70 phr of isoprene elastomer, from 25 to 85 phr of butadiene elastomer, from 10 to 100 phr of carbon black, from 0.75 to 2.7 phr of polyethylene oxide derivative of general formula (Chem 1) below, in which n is a number within a range extending from 20 to 25, and m is a number within a range extending from 13 to 17, from 0.5 to 10 phr of antiozone wax, and a crosslinking system

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22-01-2015 дата публикации

Polymer Blend Composition Based on Carbon Dioxide and Environment-Friendly Decorating Materials Produced Therefrom

Номер: US20150025163A1
Принадлежит: SK Innovation Co Ltd

The present invention is directed to a polyalkylene carbonate resin composition for producing a decorating material and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom. More particularly, the invention is directed to polyalkylene carbonate resin composition for producing a decorating material in which including a polymer additive to impart heat resistance and shape stability to the decorating material, a crosslinker and a chain extender to improve the processability at the processing temperature, and a flame retardant agent to impart a flame retardant effect, and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom. The environment-friendly polyalkylene carbonate resin decorating material produced using the inventive composition has excellent thermal stability, processability, and dimensional stability.

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24-01-2019 дата публикации

BONDED SILICONE RUBBER OBJECT

Номер: US20190022986A1
Принадлежит: ASAHI RUBBER INC.

A bonded silicone rubber object which achieves little thermal deterioration and has excellent heat resistance and which suffers neither peeling nor tearing even when stretching is provided by bonding a silicone rubber substrate and an adhered substrate each other far more strongly and tenaciously than conventional ones. A bonded silicone rubber object includes: a silicone rubber substrate which includes and configured with silicone rubber; an adhered substrate which includes and configured with a non-glass material and includes an oxide, a sulfide and/or a nitride exposed on a bonding surface thereof; and the silicone rubber substrate and the adhered substrate which are bonded by direct bonding between reactive functional groups on a surface of the silicone rubber substrate and reactive functional groups on a surface of the oxide, the sulfide and/or the nitride. 1. A bonded silicone rubber object comprising:a silicone rubber substrate which comprises and configured with silicone rubber;an adhered substrate which comprises and configured with a non-glass material and includes an oxide, a sulfide and/or a nitride exposed on a bonding surface thereof; andthe silicone rubber substrate and the adhered substrate which are bonded by direct bonding between reactive functional groups on a surface of the silicone rubber substrate and reactive functional groups on a surface of the oxide, the sulfide and/or the nitride.2. The bonded silicone rubber object according to claim 1 , wherein the direct bonding between the silicone rubber substrate and the adhered substrate comprises a covalent bond.3. The bonded silicone rubber object according to claim 1 , wherein the adhered substrate has at least one of an oxide layer claim 1 , a sulfide layer and a nitride layer in the surface thereof claim 1 , or comprises the oxide claim 1 , the sulfide and/or the nitride included in a raw material thereof.4. The bonded silicone rubber object according to claim 3 , wherein the oxide layer is at ...

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10-02-2022 дата публикации

RUBBER COMPOSITION BASED ON EPOXY RESIN, AN AMINE HARDENER AND AN IMIDAZOLE

Номер: US20220041843A1
Принадлежит:

A rubber composition is based on at least a diene elastomer, a reinforcing filler, a crosslinking system, an epoxy resin, an amine hardener comprising at least two primary amine functions, located on at least one six-membered aromatic ring, and an imidazole. 115.-. (canceled)17. The rubber composition according to claim 16 , wherein the diene elastomer is selected from the group consisting of polybutadienes claim 16 , natural rubber claim 16 , synthetic polyisoprenes claim 16 , butadiene copolymers claim 16 , isoprene copolymers claim 16 , and mixtures thereof.18. The rubber composition according to claim 16 , wherein the epoxy resin is selected from aromatic epoxy claim 16 , alicyclic epoxy and aliphatic epoxy resins.19. The rubber composition according to claim 16 , wherein the content of the epoxy resin is between 10 and 25 phr.20. The rubber composition according to claim 16 , wherein the at least one six-membered aromatic ring of the amine hardener comprises at least two Ri radicals claim 16 , which are identical or different claim 16 , selected from the group consisting of linear or branched C1-C6 alkyl radicals claim 16 , halogens claim 16 , ethers claim 16 , tertiary amines claim 16 , and thioethers claim 16 , any of which may be substituted by linear or branched C1-C6 alkyl radicals.21. The rubber composition according to claim 16 , wherein the at least one six-membered aromatic ring of the amine hardener comprises at least two Ri radicals claim 16 , which are identical or different claim 16 , selected from the group consisting of linear or branched C1-C6 alkyl radicals.22. The rubber composition according to claim 16 , wherein the content of amine hardener is within a range extending from 5 to 10 phr.23. The rubber composition according to claim 16 , wherein claim 16 , in the imidazole of general formula (A):{'sub': 'a', 'Ris selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 20 carbon atoms, cycloalkyl groups having from ...

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10-02-2022 дата публикации

Preparation method of organic silicone elastomerscross-linked by polyphenols

Номер: US20220041862A1
Принадлежит:

The invention presents a preparation method of organic silicone elastomers cross-linked bypolyphenols, which comprises steps as follows: (1) Dissolve 15-250 parts (by mass) of amino-polysiloxanes in the organic solvents to get the amino-polysiloxanes solution; then, dissolve 1˜20 parts of polyphenols in 1-60 parts of water to get the aqueous solution of polyphenols; mix the said two solutions, add 2-130 parts of reinforcement fillers, stir evenly, and then pour them into the mold. (2) Cure and cross-link the mold containing the mixed solutions at 80° C.-170° C. for a period of time, and cool it to room temperature to get the organic silicone elastomer. 1. A preparation method of organic silicone elastomers , which comprises steps as follows:with amino-polysiloxanes as base polymers and polyphenols as cross-linking agents, the organic silicone elastomers are prepared by heating the mixture for curing and cross-linking;the mass ratio of the amino-polysiloxanes and the polyphenols is 200-250: 1-9;the said polyphenols are one selected from tannins, resveratrol, quercetin, catechuic acid, taxifolin, morin, gallogen, epigallocatechin and epicatechin, or a combination of any two or more of them;the curing and cross-linking temperature is 80° C.-170° C., and the duration is 1-4 h.2. The said preparation method of organic silicone elastomers according to claim 1 , characterized in that the amino-polysiloxanes are dissolved in the organic solvents to serve as raw materials of base polymers claim 1 , and polyphenols are dissolved in water to serve as raw materials of cross-linking agents.3. The said preparation method of organic silicone elastomers according to claim 1 , characterized in that the mass ratio of the amino-polysiloxanes and the polyphenols is 220-225: 1-6.5. The said preparation method of organic silicone elastomers according to claim 4 , characterized in that the relative molecular mass of the amino-polysiloxane is 1 claim 4 ,000-100 claim 4 ,000 g/mol in ...

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10-02-2022 дата публикации

POLYMER, MECHANICAL STRESS SENSOR, METHOD FOR DETECTING MECHANICAL STRESS, METHOD FOR PREPARING POLYMER, COPPER COMPLEX AND METHOD FOR PREPARING SAME

Номер: US20220041866A1
Принадлежит:

A polymer comprising a polymer chain moiety and a copper complex moiety (1) is useful as a mechanoresponsive luminescent material. Rand Rare linking groups to the polymer chain moiety; Rto Rare H or substituent. 2. The polymer according to claim 1 , wherein Rand Reach comprise a functional group selected from the group consisting of an acryloyl group claim 1 , an epoxy group claim 1 , a triazole group claim 1 , a sulfide group claim 1 , a disulfide group claim 1 , a siloxane bond claim 1 , an amide group claim 1 , an ester group claim 1 , a carbon-carbon single bond claim 1 , a carbon-carbon double bond claim 1 , a carbon-carbon triple bond claim 1 , an azide group claim 1 , a thiol group claim 1 , a hydroxy group claim 1 , a carboxy group claim 1 , an amino group claim 1 , a cyanate group claim 1 , and an isocyanate group.4. The polymer according to claim 1 , wherein Rto Reach independently represent a hydrogen atom claim 1 , an alkyl group claim 1 , an alkenyl group claim 1 , an alkynyl group claim 1 , an alkoxy group claim 1 , a nitro group claim 1 , a cyano group claim 1 , a halogen atom claim 1 , a hydroxy group claim 1 , a thiol group claim 1 , an acyl group claim 1 , a carboxyl group claim 1 , a carboxyamide group claim 1 , an ester group claim 1 , a silane group claim 1 , an alkoxysilane group claim 1 , an amino group claim 1 , an aldehyde group claim 1 , an amide group claim 1 , an isocyanate group claim 1 , a triazole group claim 1 , a sulfide group claim 1 , a disulfide group claim 1 , an aryl-substituted alkyl group claim 1 , a haloalkyl group claim 1 , a halo-alkoxy group claim 1 , an aryl group claim 1 , a heterocycloalkyl group claim 1 , or a heteroaryl group.5. The polymer according to claim 1 , wherein Rand Rare bonded to each other to form an aromatic ring.6. The polymer according to claim 1 , wherein at least one of the pyridine rings in the formula (1) is substituted with a substituent.7. The polymer according to claim 1 , wherein Rand Rare ...

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24-01-2019 дата публикации

Rubber mixture and pneumatic vehicle tire

Номер: US20190023881A1
Принадлежит: CONTINENTAL REIFEN DEUTSCHLAND GMBH

The invention relates to a sulfur-crosslinkable rubber mixture, especially for the sidewall of pneumatic vehicle tires, and to a pneumatic vehicle tire whose sidewall consists at least partly of the sulfur-crosslinked rubber mixture. For reduced hysteresis, hence leading to low rolling resistance when used as a sidewall mixture, the rubber mixture comprises 20 to 80 phr of natural rubber and/or synthetic polyisoprene, 20 to 80 phr of at least one polybutadiene functionalized for attachment to silica and 20 to 50 phr of at least one silica with a CTAB surface area (to ASTM D 3765) of 50 to 130 m 2 /g and a nitrogen surface area (BET surface area) (to DIN ISO 9277 and DIN 66132) of 60 to 140 m 2 /g.

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24-01-2019 дата публикации

COMPOSITION FOR PREPARING A FOAM, FOAM, AND SHOE EMPLOYING THE SAME

Номер: US20190023884A1
Принадлежит: TSRC CORPORATION

A composition for preparing a foam, a foam, and a shoe employing the foam are provided. The composition for preparing a foam includes 3-30 parts by weight of a first polymer and at least one of a second polymer and a third polymer. The first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the second polymer and the third polymer is 70-97 parts by weight. The second polymer is polyolefin, olefin copolymer, or a combination thereof. The third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight. 1. A composition for preparing a foam , comprising:3-30 parts by weight of a first polymer, wherein the first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof; andat least one of a second polymer and a third polymer, wherein the total weight of the second polymer and the third polymer is 70-97 parts by weight, the second polymer is polyolefin, olefin copolymer, or a combination thereof, the third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof, and the total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight.2. The composition for preparing a foam as claimed in claim 1 , wherein the cyclic olefin copolymer is a copolymer of a norbornene-based monomer and an olefin-based monomer.3. The composition for preparing a foam as claimed in claim 2 , wherein the norbornene-based monomer ...

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24-01-2019 дата публикации

PHOSPHORYLCHOLINE-CONTAINING POLY(METH)ACRYLAMIDE-BASED COPOLYMERS

Номер: US20190023891A1
Принадлежит:

The invention is related to a class of hydrophilic poly(meth)acrylamide-based copolymer comprising dangling (i.e., pendant) phosphorylcholine groups and dangling (i.e., pendant) reactive groups or chains each of which comprises one carboxyl group, one thiol group, or one primary or secondary amino group. The hydrophilic copolymers have a relatively high affinity to a base coating of a polyanionic polymer on a medical device or contact lens and are reactive towards azetidinium groups of an azetidinium-containing polymer upon heating. They can find particular use in producing water-soluble highly-branched hydrophilic polymeric material and in producing water gradient contact lenses. 2. The hydrophilic polymer of claim 1 , wherein the poly(meth)acrylamide-based copolymer comprises at least about 50% by mole of the first repeating units relative to all repeating units of the poly(meth)acrylamide-based copolymer.3. The hydrophilic polymer of claim 2 , wherein the poly(meth)acrylamide-based copolymer comprises from about 0.01% to about 40% by mole by mole of the second repeating units relative to all repeating units of the poly(meth)acrylamide-based copolymer.5. The hydrophilic polymer of claim 4 , wherein claim 4 , in formula (3) to (10) claim 4 , Xis —NR— in which Ris hydrogen or a C-Calkyl group.6. The hydrophilic polymer of claim 5 , wherein the poly(meth)acrylamide-based copolymer further comprises third repeating units which are acrylic repeating units of one or more acrylic monomers which are free of any carboxyl group or any primary or secondary amino group.7. The hydrophilic polymer of claim 5 , wherein the third repeating units are selected from the group consisting of 2-(meth)acryloyloxy)ethyl-2′-(trimethylammonio)ethylphosphate claim 5 , 3-((meth)acryloyloxy)propyl-2′-(trimethylammonio)ethylphosphate claim 5 , 4-((meth)acryloyloxy)butyl-2′-(trimethylammonio)ethyl phosphate claim 5 , 5-((meth)acryloyloxy) pentyl-2′-(trimethylammonio)ethyl phosphate claim 5 , 6 ...

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24-01-2019 дата публикации

COMPOSITION FOR HEAT-DISSIPATING MEMBER, HEAT-DISSIPATING MEMBER, ELECTRONIC INSTRUMENT, METHOD FOR PRODUCING COMPOSITION FOR HEAT-DISSIPATING MEMBER, AND METHOD FOR PRODUCING HEAT-DISSIPATING MEMBER

Номер: US20190023900A1
Принадлежит:

The inventions are: a composition capable of forming a heat-dissipating member that has high thermal conductivity and in which the thermal expansion coefficient can be controlled; and a heat-dissipating member. This composition for a heat-dissipating member comprises a thermally conductive first inorganic filler bonded to one end of a first coupling agent, and a thermally conductive second inorganic filler bonded to one end of a second coupling agent, the composition being characterized in that: at least one of the first coupling agent and the second coupling agent is a liquid crystal silane coupling agent; the other end of the first coupling agent and the other end of the second coupling agent each have a functional group bondable with one another; and the other end of the first coupling agent bonds with the other end of the second coupling agent by a curing treatment. 1. A composition for a heat-dissipating member comprising:a thermally conductive first inorganic filler that is bonded to one end of a first coupling agent; anda thermally conductive second inorganic filler that is bonded to one end of a second coupling agent,wherein at least one of the first coupling agent and the second coupling agent is a liquid crystal silane coupling agent,the other end of the first coupling agent and the other end of the second coupling agent have functional groups capable of bonding to each other, andthe other end of the first coupling agent is bonded to the other end of the second coupling agent through curing treatment.2. The composition for a heat-dissipating member according to claim 1 ,wherein the first inorganic filler and the second inorganic filler are at least one selected from the group consisting of boron nitride, boron carbide, boron carbonitride, graphite, carbon fibers, carbon nanotubes, graphene, alumina, silica, aluminum nitride, silicon carbide, zinc oxide, magnesium hydroxide, and iron oxide-based material.3. The composition for a heat-dissipating member ...

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24-01-2019 дата публикации

PROPPANT COMPRISING A CROSSLINKED POLYMER FOR TREATMENT OF SUBTERRANEAN FORMATIONS

Номер: US20190023977A1
Принадлежит: Halliburton Energy Services, Inc.

Various embodiments disclosed relate to proppants comprising crosslinked polymers for treatment of sub-terranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include placing a proppant including a crosslinked polymer in the subterranean formation. 169.-. (canceled)70. A method of treating a subterranean formation , comprising:placing in the subterranean formation a proppant comprising a crosslinked polymer, and{'sup': 3', '3, 'wherein the proppant comprises particles having a density less than 1.0 g/cmand particles having a density greater than 1.0 g/cm.'}71. The method of claim 70 , wherein the proppant comprises particles having a density of about 0.2 g/cmto less than 1.0 g/cmand particles having a density greater than 1.0 g/cmto about 2.3 g/cm.72. The method of claim 70 , wherein the proppant has a tensile strength of about 5 MPa to about 20 MPa claim 70 , and wherein the proppant has a compressive strength of about 50 MPa to about 300 MPa.73. The method of claim 70 , wherein the composition is free of viscosifiers and cross-linked viscosifiers.74. The method of claim 70 , further comprising repeatedly and sequentially placing a pad fluid comprising a cross-linked viscosifier and the composition comprising the proppant in the subterranean formation.75. The method of claim 70 , wherein the crosslinked polymer is about 80 wt % to about 100 wt % of the proppant.76. The method of claim 70 , wherein the crosslinked polymer is a crosslinked polyimide claim 70 , and wherein the proppant comprises at least one other polymer in addition to the crosslinked polyimide.77. The method of claim 76 , wherein the at least one other polymer is selected from the group consisting of a crosslinked polyimide claim 76 , a crosslinked epoxy-based material claim 76 , a crosslinked furan-based resin claim 76 , a crosslinked polyacrylate claim 76 , a crosslinked vinyl polymer claim 76 , a polyaryl ether ...

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28-01-2021 дата публикации

Method of Preparing Superabsorbent Polymer

Номер: US20210023529A1
Принадлежит: LG CHEM, LTD.

Provided is a method of preparing a superabsorbent polymer. More specifically, provided is a method of preparing a superabsorbent polymer capable of exhibiting improved initial absorbency and a rapid absorption rate by polymerizing monomers having acidic groups, of which part is neutralized with a basic material including potassium hydroxide, in the presence of an encapsulated foaming agent. 1. A method of preparing a superabsorbent polymer , comprising:preparing a monomer composition by mixing water-soluble ethylenically unsaturated monomers including (meth)acrylic acid with a basic material including potassium hydroxide, an encapsulated foaming agent, an internal crosslinking agent, and a polymerization initiator, wherein at least part of the acidic groups of the water-soluble ethylenically unsaturated monomers is neutralized with the basic material including potassium hydroxide;forming a water-containing gel polymer by performing thermal polymerization or photo-polymerization of the monomer composition;forming a base polymer in the form of powder by drying and pulverizing the water-containing gel polymer; andforming a surface-crosslinked layer by additionally crosslinking a surface of the base polymer in the presence of a surface crosslinking agent,wherein the encapsulated foaming agent has a structure including a core which contains a hydrocarbon and a shell which surrounds the core and is formed using a thermoplastic resin, and has a mean diameter of 5 μm to 30 μm before expansion and a maximum expansion ratio of 5 times to 15 times in air.2. The method of preparing a superabsorbent polymer of claim 1 ,wherein the basic material includes 50 mol % to 100 mol % of potassium hydroxide and 0 mol % to 50 mol % of sodium hydroxide.3. The method of preparing a superabsorbent polymer of claim 1 ,wherein the basic material is used in an amount of 0.5 mole to 0.9 mole with respect to 1 mole of the water-soluble ethylenically unsaturated monomer.4. The method of preparing ...

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23-01-2020 дата публикации

SEALING MEMBER AND WATERPROOF CONNECTOR

Номер: US20200024404A1
Автор: HAMAGUCHI Takaaki
Принадлежит:

The present invention provides a sealing member () configured such that the occurrence of tearing therein can be suppressed and a waterproof connector () having favorable waterproofness. The sealing member () is formed of a thermosetting silicone rubber that contains, in its molecules; a first unit derived from a first silicone compound that has at least two vinyl groups per molecule; a second unit derived from a second silicone compound that has at least two hydrosilyl groups per molecule; and a third unit derived from an organic compound that has at least two vinyl groups per molecule and is different from the first silicone compound. The waterproof connector () includes the sealing member 1. A sealing member formed of a thermosetting silicone rubber , the thermosetting silicone rubber comprising , in its molecules:a first unit derived from a first silicone compound that has at least two vinyl groups per molecule;a second unit derived from a second silicone compound that has at least two hydrosilyl groups per molecule; anda third unit derived from an organic compound that has at least two vinyl groups per molecule and is different from the first silicone compound.2. The sealing member according to claim 1 ,wherein the organic compound has a carbon number of not less than 8 and not more than 18.3. The sealing member according to claim 1 ,wherein the thermosetting silicone rubber has a modulus at break of 14 MPa or less.4. The sealing member according to claim 1 , whereinthe thermosetting silicone rubber has an elongation at break of more than 550% and not more than 1000%.5. The sealing member according to claim 1 ,wherein the thermosetting silicone rubber is composed of a thermally cured product of a silicone composition that contains 0.01 to 10 parts by mass of the organic compound with respect to 100 parts by mass of a total amount of the first silicone compound and the second silicone compound.6. The sealing member according to claim 1 ,wherein the sealing ...

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