26-10-2017 дата публикации
Номер: US20170306070A1
Принадлежит:
A process for the preparation of a fluoroolefin polymer from an azeotropic mixture of monomers having a constant composition, the process including the step of: 1. A process for the preparation of a fluoroolefin polymer , said process comprising the step of:contacting in a reaction zone:an initiator; andan azeotropic mixture of at least two monomers comprising at least one fluoroolefin and, optionally, at least one ethylenically unsaturated comonomer capable of copolymerizing therewith;wherein said contacting is carried out at a temperature, pressure and length of time sufficient to produce said fluoroolefin polymer.2. The process of claim 1 , wherein said reaction zone further comprises a solvent selected from the group consisting of: ethyl acetate claim 1 , butylacetate claim 1 , toluene claim 1 , xylene claim 1 , methyl ethyl ketone claim 1 , 2-heptanone claim 1 , 1-methoxy-2-propanol acetate claim 1 , 1 claim 1 ,1 claim 1 ,1-trichloroethane and mixtures thereof.3. The process of claim 1 , wherein said azeotropic mixture comprises at least two fluoroolefin monomers.5. The process of claim 1 , wherein said fluoroolefin monomer is selected from the group consisting of CFCF═CF claim 1 , CFCH═CF claim 1 , CFCF═CHF claim 1 , CFCH═CH claim 1 , CFCF═CH claim 1 , cis- CFCH═CFH claim 1 , trans- CFCH═CFH claim 1 , CFCFCF═CF claim 1 , CFCFCH═CF claim 1 , CFCFCF═CHF claim 1 , CFCFCH═CH claim 1 , CFCFCF═CH claim 1 , CFCFCFCF═CF claim 1 , CFCFCFCH═CF claim 1 , CFCFCFCF═CHF claim 1 , CFCFCFCH═CH claim 1 , CFCFCFCF═CH claim 1 , CFCH═CHCF claim 1 , CFCH═CFCF claim 1 , CFCF═CFCF claim 1 , HOCHCH═CHF claim 1 , HOCHCH═CF claim 1 , HOCHCF═CH claim 1 , HOCHCF═CHF claim 1 , HOCHCF═CF claim 1 , HOCHCF═CH claim 1 , CFCH═CHCl claim 1 , CFCC1═CH claim 1 , CFCCl═CHF claim 1 , CFCC1═CF claim 1 , CFCF═CHCl claim 1 , CFCH═CFCl claim 1 , CF═CFCl claim 1 , CF═CF claim 1 , CF═CH claim 1 , CFH═CH claim 1 , and mixtures thereof.6. The process of claim 5 , wherein said fluoroolefin monomer is ...
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