21-03-2013 дата публикации
Номер: US20130072643A1
Fluoroelastomer compositions comprising fluoroelastomers having copolymerized units of a nitrile-containing cure site monomer are cured with certain carbazates. The carbazate is of the general formula ROC(O)NHNHR, wherein Ris 9-fluorenylmethyl, benzyl, aryl, or a heterocycle; Ris H, alkyl, aryl, heterocycle, CORor CHR; Ris alkyl, aryl, benzyl or a heterocycle; and Ris a fluoroalkyl group. 1. A curable composition comprising:A) a fluoroelastomer comprising copolymerized units of a nitrile group-containing cure site monomer; and{'sup': 1', '2', '1', '2', '3', '4', '3', '4, 'sub': 2', '2, 'B) a carbazate of the general formula ROC(O)NHNHR, wherein Ris 9-fluorenylmethyl, benzyl, aryl, or a heterocycle; Ris H, alkyl, aryl, heterocycle, CORor CHR; Ris alkyl, aryl, benzyl or a heterocycle; and Ris a fluoroalkyl group.'}2. A curable composition of wherein Ris H or COR.3. A curable composition of wherein said carbazate is selected from the group consisting of 9-fluorenylmethyl carbazate; diphenylmethyl carbazate; 1-(tert-butoxycarbonyl)-2-phenylhydrazine; phenyl carbazate; and benzyl carbazate.4. A curable composition of wherein said carbazate has at least one oxygen atom replaced by a sulfur atom.5. A curable composition of further comprising a curative accelerator.6. A cured article made from the composition of .7. A cured article of having a volume swell claim 6 , measured according to ASTM D1414 claim 6 , after exposure to 225° C. water for at least 168 hours of less than 5% and a compression set claim 6 , 300° C. claim 6 , 70 hours claim 6 , 15% compression claim 6 , measured according to ASTM D395 of less than 70%. This application claims the benefit of U.S. Provisional Application No. 61/469,856 filed Mar. 31, 2011.This invention relates to curable fluoroelastomer compositions and more particularly to fluoroelastomer compositions containing certain carbazates as curing agents.Fluoroelastomers have achieved outstanding commercial success and are used in a wide variety ...
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