04-07-2019 дата публикации
Номер: US20190203053A1
Принадлежит:
The present invention involves pigments derived from compounds with the LiSbO-type or LiNbO-type structures. These compounds possess the following formulations MMZ, MMMMZ, MMMZ, MMMMZ, MMMZ, MMMZ, or a combination thereof. The cation Mrepresents an element with a valence of +1 or a mixture thereof, the cation Mrepresents an element with a valence of +2 or a mixture thereof, the cation Mrepresents an element with a valence of +3 or a mixture thereof, the cation Mrepresents an element with a valence of +4 or a mixture thereof, the cation Mrepresents an element with a valence of +5 or a mixture thereof, and the cation Mrepresents an element with a valence of +6 or a mixture thereof. The cation M is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, or Te. The anion Z is selected from N, O, S, Se, Cl, F, hydroxide ion or a mixture thereof. Along with the elements mentioned above vacancies may also reside on the M or Z sites of the above formulations such that the structural type is retained. The above formula may also include M dopant additions below 20 atomic %, where the dopant is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, Bi, Te, or mixtures thereof. 2. The use of a pigment of where Mis Li claim 1 , or Li in combination with Cu.3. The use of a pigment of where Mmust include Sb.4. The use of a pigment of where Mis Co claim 1 , or Co in combination with one or more of: Cu claim 1 , Fe claim 1 , Mg claim 1 , Mn claim 1 , Ni claim 1 , or Zn.5. The use of a pigment of where Mis Co claim 1 , or Co in combination with Mg claim 1 , Zn or combinations thereof.6. The use of a pigment of with a hue angle (h°) between 290° and 320°.7. The use of a ...
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