09-03-2017 дата публикации
Номер: US20170069915A1
The present invention relates to stable catalyst ink formulations comprising am electrospinning polymer selected from halogen-comprising polymers. The present invention further relates to electrospinning of such ink formulation, to the so-obtained electrospun fibrous mat as well as to articles comprising such electrospun fibrous mat. 1. Ink formulation comprising(i) metal supported on a carrier,(ii) an ionomer,(iii) an electrospinning polymer selected from the group of halogen-comprising polymers, and(iv) a solvent.2. Ink formulation according to claim 1 , wherein the metal is selected from the group consisting of Sc claim 1 , Y claim 1 , Ti claim 1 , Zr claim 1 , Hf claim 1 , V claim 1 , Nb claim 1 , Ta claim 1 , Cr claim 1 , Mo claim 1 , W claim 1 , Fe claim 1 , Ru claim 1 , Os claim 1 , Co claim 1 , Rh claim 1 , Ir claim 1 , Ni claim 1 , Pd claim 1 , Pt claim 1 , Cu claim 1 , Ag claim 1 , Au claim 1 , Zn claim 1 , Cd claim 1 , Hg claim 1 , lanthanides claim 1 , actinides and any blend thereof.3. Ink formulation according to claim 1 , wherein the carrier is selected from the group consisting of carbon claim 1 , silica claim 1 , metal oxides claim 1 , metal halides and any blend thereof.4. Ink formulation according to claim 1 , wherein the ionomer comprises electrically neutral repeating units and ionized or ionizable repeating units.5. Ink formulation according to claim 1 , wherein the halogen-comprising polymer comprises fluorine claim 1 , chlorine or both claim 1 , fluorine and chlorine.6. Ink formulation according to claim 5 , wherein the halogen-comprising polymer comprises an alkanediyl monomer unit of general formula (III){'br': None, 'sub': 2', '4-p-q-r', 'p', 'q', 'r, 'sup': 1', '2', '3, '*—[CHYYY]—*\u2003\u2003(III)'}whereinp is selected from the group consisting of 1, 2, 3 and 4;q is selected from the group consisting of 0, 1, 2 and 3;r is selected from the group consisting of 0, 1, 2 and 3;{'sup': '1', 'Yis fluorine;'}{'sup': '2', 'Yis chlorine; and'}{' ...
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