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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 965. Отображено 100.
21-03-2013 дата публикации

Fluoropolyether phosphate derivatives

Номер: US20130068408A1
Автор: Padigala Mahesh, PICOZZI Rosaldo, Sergio Andrea, TONELLI Claudio Adolfo Pietro
Принадлежит: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

The invention pertains to an aqueous composition comprising at least one mono-functional (per)fluoropolyether monoester phosphate having formula (I) here below: 6. A process for imparting grease and oil repellency to the surface of a cellulose substrate claim 1 , said process comprising applying internally or externally to the surface of the cellulose substrate the aqueous composition of .7. The process of claim 6 , wherein the aqueous composition has a pH value of at least 7.8. The process of claim 6 , wherein the aqueous composition is applied internally by wet-end techniques or externally by size-press techniques. This application is a U.S. national stage entry under 35 U.S.C. §371 of International Application No. PCT/EP2011/058521 filed May 25, 2011, which claims priority to U.S. provisional application No. 61/350,213 filed Jun. 1, 2010, the whole content of this application being incorporated herein by reference for all purposes.The present invention relates to aqueous compositions of (per)fluoropolyether phosphate derivatives, to a process for the manufacture of said compositions and to use of said compositions for imparting grease and oil repellency to cellulose substrates.Use of fluorochemicals for the treatment of packaging substrates, in particular cellulosic substrates, to impart grease and oil repellency thereto is well known in the art.In recent years, there has been an increasing demand for grease/oil resistant paper and paper boards. The demand is attributed to the continuously growing packaging markets for food items such as bakery products, pet food, instant and fast foods.Among commercially available fluorochemical modifiers well-suited for this application, those based on (per)fluoropolyethers have drawn increased attention due to their favourable toxicological profile.Among techniques for conferring oleo-repellency to substrates, in particular cellulosic substrates, treatments with (per)fluoropolyether derivatives comprising (per) ...

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Номер записи: 1
28-03-2013 дата публикации

Printing ink dryer and printing ink using the same

Номер: US20130074726A1
Автор: Shigeki Matsunaga, Takanori Ohtsubo
Принадлежит: DIC Corp

The present invention provides a printing ink dryer including a fatty acid manganese salt (A) and an aminoalcohol (B) represented by general formula (1) below. The printing ink dryer exhibits drying performance equivalent to or higher than the excellent drying performance possessed by cobalt metal carboxylates with using a smaller amount of a cobalt metal soap concerned about the influences on human bodies or without using the cobalt metal soap. (In the formula, R 1 and R 2 each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, X 1 and X 2 each independently represent an alkylene group having 2 to 6 carbon atoms, and Y represents —NR 3 — (wherein R 3 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms) or an oxygen atom.)

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Номер записи: 2
11-04-2013 дата публикации

PROTECTIVE COATINGS FOR ORGANIC SUBSTRATES AND ARTICLES OF MANUFACTURING INCLUDING THE PROTECTIVE COATINGS

Номер: US20130089745A1
Автор: Barrus Kent, Hills Dal N.
Принадлежит: ADVANCED CONCRETE TECHNOLOGIES LLC

A composition for protecting a surface of an organic substrate, such as VCT, wood, or a synthetic laminate material, includes a silicate (i.e., an alkali metal polysilicate or colloidal silica) and a siliconate (e.g., a metal siliconate, such as an alkali metal methyl siliconate, etc.). In addition, the composition may include acrylic latex, a silane coupling agent, and a solvent, such as ethylene glycol monobutyl ether. Such a composition may also include a leveling agent, such as a surfactant. Organic substrates, such as VCT, wood, and synthetic laminate materials, with such a composition on their surfaces are also disclosed. 1. An article of manufacture formed at least in part from organic material , comprising:a substrate comprising an organic substrate and including a surface;at least one polymer on the surface, the at least one polymer formed from at least one of a siliconate, an acrylic latex, and a silane coupling agent from a composition comprising the silconate, the acrylic latex, the silane coupling agent, a silicate and a solvent on the surface; the at least one polymer imparting the surface with a glossiness that, when light is directed toward the composition at an angle of 60° to the surface, about 80% or more of the light is reflected.2. The article of manufacture of claim 1 , further comprising:a product of a reaction of at least one of the silicate and the silane coupling agent with the organic material of the substrate.3. The article of manufacture of claim 2 , wherein the organic material comprises an organic polymer or wood.4. The article of manufacture of claim 2 , wherein the substrate comprises a flooring surface.5. The article of manufacture of claim 4 , wherein the substrate comprises vinyl composition tile claim 4 , wood or a wood laminate claim 4 , a synthetic laminate material claim 4 , or a rubberized flooring surface.6. A floor claim 4 , comprising:an organic substrate defining a floor surface; andat least one product of one or more ...

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Номер записи: 3
11-04-2013 дата публикации

ADDITIVE FOR RECLAMATION OF ASPHALT, RECLAIMED ASPHALT PAVEMENT MATERIAL CONTAINING SAME, MODIFIED ASPHALT, AND ASPHALT PAVEMENT MATERIAL CONTAINING SAME

Номер: US20130090415A1
Автор: Kusano Yukio
Принадлежит:

An additive for reclaiming asphalt of the present invention, which is obtained by adding straight asphalt to a mixture of a waste animal or vegetable oil and a waste mineral oil having a kinematic viscosity at 60° C. of 10 mm/s to 40 mm/s, mixing the materials, and heating the resultant mixture to remove an aromatic component. The additive for reclaiming asphalt can restore the physical properties of a deteriorated asphalt component to the same or greater extent than that of a conventional additive for reclaiming asphalt, and the additive has low content of components that may affect the environment or humans, and high fluidity at room temperature, and is available at an extremely low cost. 1. An additive for reclaiming asphalt , obtained by{'sup': 2', '2, 'adding straight asphalt to a mixture of a waste animal or vegetable oil and a waste mineral oil having a kinematic viscosity at 60° C. of 10 mm/s to 40 mm/s,'}mixing the materials, andheating the resultant mixture to remove an aromatic component.2. A reclaimed asphalt pavement material claim 1 , comprising the additive for reclaiming asphalt according to added to an asphalt pavement waste or a mixture of a fresh aggregate and an asphalt pavement waste.3. A modified asphalt claim 1 , obtained byadding, to molten straight asphalt, a xerogel-like amorphous resin, which is obtained by dissolving an amorphous resin with an organic solvent capable of dissolving the amorphous resin to provide a gel- or dough-like amorphous resin in a saturated state, immersing the resin in alcohol to remove the organic solvent, and drying the remainder, together with a waste animal or vegetable oil, andmixing the materials.4. A modified asphalt claim 1 , obtained byadding, to molten straight asphalt, a product, which is obtained by dissolving an amorphous resin with an organic solvent capable of dissolving the amorphous resin to provide a gel- or dough-like amorphous resin in a saturated state, and heating the resin to melt the resin, ...

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Номер записи: 4
18-04-2013 дата публикации

Liquid Chemical for Forming Water Repellent Protective Film

Номер: US20130092191A1
Автор: Arata Shinobu, Kumon Soichi, Nanai Hidehisa, Saio Takashi, Saito Masanori
Принадлежит: CENTRAL GLASS COMPANY, LIMITED

The present invention relates to a method for cleaning wafers while preventing pattern collapse of the wafers in semiconductor device fabrication, the wafer having at its surface an uneven pattern and containing silicon element at least on surfaces of recessed portions. Provided is: a liquid chemical for forming a protective film which allows efficient cleaning; and a method for cleaning wafers, using the liquid chemical. A liquid chemical for forming a water repellent protective film is provided for forming a protective film on a wafer (having at its surface an uneven pattern and containing silicon element at least at a part of the uneven pattern), the protective film being formed at least on surfaces of recessed portions of the uneven pattern at the time of cleaning the wafer. The liquid chemical contains a dialkylsilyl compound represented by the formula [1] and does not contain an acid and a base. 1. A liquid chemical for forming a water repellent protective film , the liquid chemical being able to form a protective film on a wafer that has at its surface an uneven pattern and contains silicon element at least at surfaces of recessed portions of the uneven pattern , the protective film being formed at least on the surfaces of the recessed portions of the uneven pattern at the time of cleaning the wafer , comprising:a dialkylsilyl compound represented by the following general formula [1], {'br': None, 'sub': '2', 'R(H)SiX \u2003\u2003[1]'}, 'wherein an acid and a base are not contained.'}{'sub': 1', '18', '1', '8, '(In the formula, R mutually independently represents at least one group selected from monovalent organic groups having a C-Chydrocarbon group and monovalent organic groups having a C-Cfluoroalkyl chain. X represents a group selected from halogen groups and monovalent organic groups of which element to be bonded to a silicon element is nitrogen.)'}2. A liquid chemical for forming a water repellent protective film claim 1 , as claimed in claim 1 , ...

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Номер записи: 5
25-04-2013 дата публикации

INK COMPOSITION, INKJET RECORDING METHOD AND COLORED BODY

Номер: US20130101811A1
Автор: Kawaguchi Akira, Matsui Takahiko, Ooshima Kenji, Yoshimoto Takashi
Принадлежит: Nippon Kayaku Kabushiki Kaisha

A water-based black ink composition which exhibits a low intensity, colorless and neutral black color and provides a black recorded image the printed image of which has high density. The ink composition includes at least one compound represented by formula (1) or a salt thereof and an azo compound having λmax within the range of 550-660 nm. In the formula (1), Rto Rindependently represent a hydrogen atom; a halogen atom; a sulfo group; a carboxy group; a sulfamoyl group; a carbamoyl group; a C1-C4 alykyl group; a C1-C4 alkoxy group; and a C1-C4 alkoxy group substituted with at least one group selected from a group consisting of a hydroxy group, a C1-C4 alkoxy group, a hydroxy C1-C4 alkoxy group, a sulfo group and a carboxy group. X represents a bivalent cross-linking group. 3. The ink composition according to claim 1 , wherein in the formula (1) claim 1 , Rto Reach independently represent a hydrogen atom; a halogen atom; a C1-C4 alkyl group; a C1-C4 alkoxy group; a C1-C4 alkoxy group substituted with a sulfo group or a carboxy group; or a C1-C4 alkylcarbonylamino group.4. The ink composition according to claim 1 , wherein in the formula (1) claim 1 , X represents a C1-C8 alkylenediamino group; a C1-C8 alkylenediamino group substituted with a carboxy group; an N—C1-C4 alkyl-C1-C6 alkylenediamino group having its alkyl moiety substituted with a hydroxy group; an amino-C1-C4 alkoxy-C1-C4 alkoxy-C1-C4 alkylamino group; a xylylenediamino group; or a piperazine-1 claim 1 ,4-diyl group.5. The ink composition according to claim 1 , wherein in the formula (1) claim 1 ,{'sup': 1', '2, 'at least one of Rand Ris a sulfopropoxy group,'}{'sup': 3', '4, 'at least one of Rand Ris a sulfopropoxy group,'}{'sup': 5', '8, 'Rto Rare a C1-C4 alkyl group,'}X is a C2-C4 alkylenediamino group; a C2-C6 alkylenediamino group substituted with a carboxy group; an N—C2-C3 alkyl-C2-C3 alkylenediamino group having its alkyl moiety substituted with a hydroxy group; an amino-C2-C3 alkoxy C2-C3 ...

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Номер записи: 6
25-04-2013 дата публикации

Liquid composition, recording method, and recorded matter

Номер: US20130101814A1
Автор: Hidetoshi Fujii, Hiroshi Gotou, Kiyofumi Nagai
Принадлежит: Ricoh Co Ltd

A liquid composition for agglutinating particles having a negative charge which are dispersed in a dispersion liquid, the liquid composition including: an organic acid ammonium salt represented by Formula (1), and water, Formula (1) where R 1 represents a hydroxyl group, a methyl group or a hydrogen atom; and R 2 represents a hydroxyl group or a methyl group.

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Номер записи: 7
25-04-2013 дата публикации

MANGANESE SALT COMPLEX AS DRIER FOR COATING COMPOSITIONS

Номер: US20130102709A1
Автор: BERGMAN Franciscus Adrianus Cornelis, Hage Ronald, Jansen Johan Franz Gradus, Kleuskens Engelina Catharina
Принадлежит:

An air drying auto-oxidisable resin composition comprising components: a) a drier comprising a manganese salt complex, and b) a polymer comprising unsaturated fatty acid residues, wherein the manganese salt complex has the following structure I: wherein the anion is selected from Cl, NOor RCOO, in which case n=2; or the anion is SO, in which case n=1; wherein X,Y,Z are independently selected from O, OH, OH, OC(R)O, and RBOand wherein a and b are independently an integer of value 2, 3 or 4; R═H, C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms; R=C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; and R=C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue. R═C1-C20 alkyl optionally substituted with heteroatoms, or C6-C20 aryl optionally substituted with heteroatoms. 2. An air drying auto-oxidisable resin composition according to wherein the anion is selected from Clor NO claim 1 , in which case n=2; or the anion is SO claim 1 , in which case n=1.3. An air drying auto-oxidisable resin composition according to wherein Z═O.4. An air drying auto-oxidisable resin composition according to wherein X and/or Y is RBO.5. An air drying auto-oxidisable resin composition according to wherein the anion is RCOO.6. An air drying auto-oxidisable resin composition according to wherein R═CHor its substituted analogues.7. An air drying auto-oxidisable resin composition according to wherein X and Y are CHBO claim 6 , and a and b are 4.8. An air drying auto-oxidisable resin composition according to wherein X and Y═O claim 2 , and integers a and b=4.9. An air drying auto-oxidisable resin composition according to wherein X and Y═RCOOand integers a and b=3.10. An air drying auto-oxidisable resin composition according to wherein Ris CH.11. A coating composition comprising the auto- ...

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Номер записи: 8
02-05-2013 дата публикации

COATING MATERIAL, COATING AND COATED OBJECT

Номер: US20130104461A1
Автор: HÄYRYNEN Jukka, KAUPPINEN Mika, MYLLYMÄKI Vesa
Принадлежит:

A coating material is used for coating a substrate by means of laser ablation. The coating material contains graphitic carbon nitride and a dopant in order to alter the properties of the coating produced as compared to a coating of pure carbon nitride. 1. A coating material for coating a substrate by means of laser ablation , wherein:the coating material contains graphitic carbon nitride and a dopant in order to alter the properties of the coating produced as compared to pure carbon nitridethe density of the coating material is at least 70% of the theoretical density of the coating material andthe grain size of the dopant in the coating material is not more than 30 micrometres.2. A coating material according to claim 1 , wherein the dopant contains nanodiamonds.3. A coating material according to claim 2 , wherein the percentage by weight of nanodiamonds in the coating material is 1-50%.4. A coating material according to claim 3 , wherein the percentage by weight of nanodiamonds in the coating material is 1-20%.5. A coating material according to claim 4 , wherein the percentage by weight of nanodiamonds in the coating material is 1-10%.6. A coating material according to claim 1 , wherein the dopant contains a boron compound claim 1 , which comprises at least one of: boron nitride claim 1 , boron carbide.7. A coating material according to claim 6 , wherein the atomic fraction of the boron compound used as a dopant is 10-90% of the coating material claim 6 , and the atomic fraction of carbon nitride is 10-90% of the coating material.8. A coating material according to claim 1 , wherein the dopant contains a fluoropolymer.9. A coating material according to claim 8 , wherein the atomic fraction of the fluoropolymer used as a dopant is 1-99% of the coating material claim 8 , and the atomic fraction of carbon nitride is 1-99% of the coating material.10. A coating containing carbon nitride produced from a target by means of laser ablation claim 8 , wherein the coating ...

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Номер записи: 9
02-05-2013 дата публикации

CATALYST SYSTEM FOR THE PREPARATION OF AN ESTER AND PROCESSES EMPLOYING THIS ESTER

Номер: US20130109763A1
Автор: Daute Peter, Schäfer Martin, Schweichler Thomas
Принадлежит:

The present invention relates to a process for the preparation of an ester in a reactor, wherein at least one of at least two different catalysts is an electron donor and a further catalyst is a sulphur-containing proton donor; a device, a process for the preparation of a thermoplastic composition comprising the ester prepared according to the invention, a process for the production of a shaped article comprising the ester according to the invention or the thermoplastic composition according to the invention, a process for the production of a packed product, a process for the production of an at least partly coated object, and uses of the esters according to the invention as an additive in various compositions. 2. The process according to claim 1 , wherein the carboxylic acid component contains non-metal atoms chosen from the group of carbon claim 1 , oxygen claim 1 , Nitrogen or hydrogen.3. The process according to or claim 1 , wherein the carboxylic acid component comprises more than 5 carbon atoms.4. The process according to one of the preceding claims claim 1 , wherein the amount of electron donor claim 1 , based on the total amount of catalysts claim 1 , is more than 12.5 wt. %.5. The process according to one of the preceding claims claim 1 , whereinaa. sulphuric acid, or{'sub': 1', '10, 'bb. an aliphatic, cycloaliphatic or aromatic C- to C-sulphonic acid,'}or a combination of two or more of these, is chosen as the sulphur-containing proton donor.6. The process according to one of the preceding claims claim 1 , wherein a metal claim 1 , a metal compound claim 1 , or a reducing acid claim 1 , or a combination of two or more of these claim 1 , is employed as the electron donor.7. The process according to one of the preceding claims claim 1 , whereinaa) a metal chosen from the group consisting of: titanium, tin, zirconium, in particular tin, orbb) a metal compound chosen from the group consisting of tetraalkyl titanate, organotitanium complex, titanium salt, tin ...

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Номер записи: 10
16-05-2013 дата публикации

MANGANESE COMPLEX AS DRIER FOR COATING COMPOSITIONS

Номер: US20130123410A1
Автор: BERGMAN Franciscus Adrianus Cornelis, Jansen Johan Franz Gradus, Kleuskens Engelina Catharina
Принадлежит:

An air drying auto-oxidisable resin composition comprising components: a) a drier comprising a manganese carboxylate complex, and b) a polymer comprising unsaturated fatty acid residues, wherein the manganese carboxylate complex a) has the following structure I: wherein R═H, C1-C20 alkyl optionally substituted with heteroatoms, or C6-C20 aryl optionally substituted with heteroatoms; X and Y are independently selected from O and OC(R)O, in which a=4 when X═O, and a=3 when X═OC(R)O, and in which b=4 when Y═O, and b=3 when Y═OC(R3)O; R=C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; and R═C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue. 7. A composition according to wherein Ris CH.8. A composition according to wherein the amount of the cation of the manganese carboxylate complex is in the range from0.00001 wt % to 5 wt % based on the total solids content of the polymer b) comprising unsaturated fatty acid residues.9. A composition according to wherein the polymer b) comprising unsaturated fatty acid residues is selected from the group consisting of alkyds claim 1 , vinyl polymers claim 1 , polyurethane resins claim 1 , hyperbranched resins and mixtures thereof.10. A composition according to wherein the composition further comprises a liquid medium selected from the group consisting of water claim 1 , aliphatic hydrocarbon solvents claim 1 , aromatic hydrocarbon solvents claim 1 , ethers claim 1 , alcohols claim 1 , ketones claim 1 , hydroxyl ethers and mixtures thereof.11. A coating composition comprising the auto-oxidisable resin composition according to .12. A method of coating the auto-oxidisable resin composition according to or the coating composition on a substrate comprising adding to the coating composition the manganese carboxylate complex a) claim 1 , applying the composition on a substrate claim ...

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Номер записи: 11
23-05-2013 дата публикации

Planarization over topography with molecular glass materials

Номер: US20130125787A1
Автор: Mark W. Hart, Ratnam Sooriyakumaran, Robert D. Allen
Принадлежит: International Business Machines Corp

Molecular glass based planarizing compositions for lithographic processing are disclosed. The processes generally include casting the planarizing composition onto a surface comprised of lithographic features, the planarizing composition comprising at least one molecular glass and at least one solvent; and heating the planarizing composition to a temperature greater than a glass transition temperature of the at least one molecular glass. Exemplary molecular glasses include polyhedral oligomeric silsesquioxane derivatives, calixarenes, cyclodextrin derivatives, and other non-polymeric large molecules.

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Номер записи: 12
23-05-2013 дата публикации

ALUMINA DISPERSION FOR MANUFACTURING PARTICULATE MAGNETIC RECORDING MEDIUM, METHOD OF MANUFACTURING PARTICULATE MAGNETIC RECORDING MEDIUM USING THE SAME, AND PARTICULATE MAGNETIC RECORDING MEDIUM

Номер: US20130130064A1
Автор: SATO Masahide
Принадлежит: FUJIFILM Corporation

An aspect of the present invention relates to an alumina dispersion, which is employed to manufacture a particulate magnetic recording medium, comprises alumina, a solvent, and a dispersing agent in the form of an aromatic hydrocarbon compound having a phenolic hydroxyl group, and essentially does not comprise ferromagnetic powder. 1. An alumina dispersion , which is employed to manufacture a particulate magnetic recording medium , comprises alumina , a solvent , and a dispersing agent in the form of an aromatic hydrocarbon compound having a phenolic hydroxyl group , and essentially does not comprise ferromagnetic powder.2. The alumina dispersion according to claim 1 , wherein an aromatic ring contained in the aromatic hydrocarbon compound is a benzene ring or a naphthalene ring.4. The alumina dispersion according to claim 1 , wherein the solvent is an organic solvent.5. The alumina dispersion according to claim 1 , wherein the solvent comprises a ketone solvent.6. The alumina dispersion according to claim 1 , which further comprises a resin component.7. The alumina dispersion according to claim 1 , which further comprises a resin component selected from the group consisting of a polyurethane resin and a vinyl chloride resin.8. The alumina dispersion according to claim 1 , which is employed for preparation of a coating material for forming a magnetic layer of a particulate magnetic recording medium.9. The alumina dispersion according to claim 1 , wherein the alumina is α-alumina.10. The alumina dispersion according to claim 1 , wherein the aromatic hydrocarbon compound is selected from the group consisting of dihydroxylnaphthalene claim 1 , phenol claim 1 , hydroxybenzoic acid claim 1 , and derivatives thereof.11. The alumina dispersion according to claim 4 , wherein the aromatic hydrocarbon compound is selected from the group consisting of dihydroxylnaphthalene claim 4 , phenol claim 4 , hydroxybenzoic acid claim 4 , and derivatives thereof.12. The alumina ...

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Номер записи: 13
06-06-2013 дата публикации

LOW RESIDUAL BISPHENOL A ALKOXYLATED MATERIALS, THEIR PREPARATION AND USE THEREOF

Номер: US20130139721A1
Автор: Ritz Ricky Lee
Принадлежит: MILLIKEN & COMPANY

This invention relates to alkoxylated Bisphenol A compositions containing low residual amounts of Bisphenol A. The present invention also relates to methods for making such alkoxylated compositions containing low residual amounts of Bisphenol A, as well as uses for such compositions. The alkoxylated compositions containing low residual amounts of Bisphenol A may be utilized in packaging applications (such as indirect and/or direct food contact packaging), printing inks, container linings, and the like. 2. The composition of claim 1 , wherein the amount of residual Bisphenol A present in the composition is greater than zero but less than 100 ppm.3. The composition of claim 1 , wherein the amount of residual Bisphenol A present in the composition is greater than zero but less than 60 ppm.5. A packaging material containing the composition of .6. A printing ink containing the composition of .7. A container lining containing the composition of .9. The composition of claim 8 , wherein the ethoxylated Bisphenol A compound is the product of a reaction between Bisphenol A and the equivalent of 2.2 to 50 moles of Ethylene Oxide.10. The composition of claim 8 , wherein the amount of residual Bisphenol A present in the composition is greater than zero but less than 100 ppm.11. The composition of claim 8 , wherein the amount of residual Bisphenol A present in the composition is greater than zero but less than 60 ppm.12. A method for preparing an alkoxylated Bisphenol A composition containing low residual Bisphenol A comprising the steps of:(a) providing a molten Bisphenol A compound;(b) adding a sufficient amount of base catalyst to the molten Bisphenol A compound to form a catalyst-containing mixture;(c) heating and pressurizing the catalyst-containing mixture;(d) adding a first amount of at least one alkylene oxide compound to the catalyst-containing mixture;(e) allowing the mixture of step “d” to equilibrate for a period of about 1 hour to about 6 hours;(f) adding a second ...

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Номер записи: 14
06-06-2013 дата публикации

FILM FORMING COATING COMPOSITIONS CONTAINING CARBOXAMIDE COALESCING SOLVENTS AND METHODS OF USE

Номер: US20130143986A1
Автор: Luebke Gary, Luka Renee, Malec Andrew D., Terry Michael R., Wolfe Patrick Shane
Принадлежит:

A film may be formed from film forming compositions which comprise at least one carboxamide based coalescing solvent. These coalescing solvents impart equivalent or improved wet-scrub resistance, block resistance, gloss, dirt pick-up resistance and leveling characteristics to the films on a substrate, without contributing to total VOC levels, when replacing conventional coalescing solvents. The present invention also includes a method for forming a film comprising applying a film forming composition comprising polyunsaturated reactive carboxamides to a substrate and curing the film under ambient conditions. The coalescing carboxamide solvents are suitable for paint, latex based caulk, adhesives and floor care applications. 2. The film forming composition of claim 1 , wherein the at least one carboxamide is selected from the group consisting of N claim 1 ,N-dimethyl isostearoylamide claim 1 , N claim 1 ,N-dimethyl Calkanoylamide claim 1 , N claim 1 ,N-dimethyl oleoylamide claim 1 , N claim 1 ,N-diethyl Calkanoylamide claim 1 , N-(2-ethylhexyl) Calkanoylamide claim 1 , N-(2-ethylhexyl) 2-ethylhexyl alkanoylamide claim 1 , and mixtures of any two or more thereof.3. The film forming composition of claim 1 , wherein the at least one carboxamide is N claim 1 ,N-dimethyl amide made from vegetable oil claim 1 , vegetable oil-derived fatty acids claim 1 , vegetable oil-derived laity acid methyl esters or mixtures of any two or more thereof.4. The film forming composition of claim 3 , wherein the vegetable oil is selected from the group consisting of soybean oil claim 3 , linseed oil claim 3 , safflower oil claim 3 , palm oil claim 3 , corn oil claim 3 , castor oil claim 3 , coconut oil claim 3 , tall oil claim 3 , tung oil claim 3 , and mixtures of any two or more thereof.5. The film forming composition of claim 1 , wherein the at least one carboxamide is derived from tallow.6. The film forming composition of claim 1 , wherein the at least one carboxamide is N claim 1 ,N- ...

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Номер записи: 15
20-06-2013 дата публикации

Method of modifying surface of powder, coating material, method of manufacturing magnetic recording medium, and magnetic recording medium manufactured by the same

Номер: US20130152822A1
Автор: Kazufumi Omura
Принадлежит: Fujifilm Corp

An aspect of the present invention relates to a method of modifying a surface of a powder, comprising mixing a powder with a compound denoted by general formula (I): wherein, in general formula (I), each of R 10 and R 13 independently denotes a hydrogen atom, alkyl group, or aryl group, each of R 11 and R 12 independently denotes an alkyl group or an aryl group, and L denotes a single bond or an oxygen atom.

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Номер записи: 16
20-06-2013 дата публикации

INK FOR INKJET RECORDING APPARATUSES, AND METHOD FOR FORMING IMAGE

Номер: US20130155143A1
Автор: Ozawa Noriaki
Принадлежит: KYOCERA Document Solutions Inc.

An ink for inkjet recording apparatuses is provided in which an adsorbed resin proportion calculated from a total resin mass and a free resin mass in the ink is at least 0.95 and less than 1.00, the ink containing in specific amounts, respectively: water; a pigment dispersion including a resin with a molecular weight in the range of 35,000 to 140,000 and a specific amount of pigment; glycerin and 1,3-propanediol as humectants; and 1,2-octanediol, which has 8 carbon atoms, as a high penetrating agent, and further containing a C2-C4 monoalkyl ether of a polyhydric alcohol as a penetrating agent. 1. An ink for inkjet recording apparatuses comprising at least water , a pigment dispersion , a high penetrating agent , a penetrating agent and a humectant , whereinthe pigment dispersion contains a resin having a molecular weight in the range of 35,000 to 140,000 and a pigment, {'br': None, 'adsorbed resin proportion=1−(free resin mass/total resin mass),'}, 'an adsorbed resin proportion, obtained using the following formula from the mass of a total amount of the resin in the ink and an amount of resin separated from pigment among the resin, is at least 0.95 and less than 1.00the content of the pigment in the ink is in the range of 4% by mass to 9.5% by mass,the humectant is glycerin and 1,3-propanediol,the content of glycerin in the ink is at least 5% by mass, and the content of 1,3-propanedial is in the range of 10% by mass to 30% by mass,the high penetrating agent is 1,2-octanediol,the content of the high penetrating agent in the ink is in the range of 0.2% by mass to 0.8% by mass, andthe penetrating agent is a C2-C4 monoalkyl ether of a polyhydric alcohol.2. The ink for inkjet recording apparatuses according to claim 1 , wherein the C2-C4 monoalkyl ether of a polyhydric alcohol is triethylene glycol monobutyl ether claim 1 , and the content thereof in the ink is in the range of 2% by mass to 5% by mass.4. A method for forming an image claim 1 , comprising forming an image ...

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Номер записи: 17
27-06-2013 дата публикации

Defoaming Wetting Agents For Aqueous Coating Systems

Номер: US20130160676A1
Автор: Bene Peter, Oestreich Sascha, Wolf Renate
Принадлежит:

Compounds of the structure R—O—(PO)H, in which R is an alkyl radical having 6 to 12 C atoms, and may be saturated or unsaturated, straight-chain or branched, PO is a propylene oxide unit and x is a number in the range from 1 to 7, are outstandingly suitable as defoaming wetting agents in aqueous coating systems, more particularly paints and inks. 2. The method of claim 1 , wherein the aqueous coating system comprises a paint or varnish.3. The method of in transparent varnishes (clearcoats).4. The method of claim 1 , wherein R is a saturated alkyl radical having 7 to 10 C atoms and x is a number in the range from 4 to 6.5. The method of claim 4 , wherein R is a saturated alkyl radical having 8 C atoms and x is the number 6.6. The method of claim 4 , wherein (I) is an adduct of 6 mol of PO with 1 mol of n-octanol.7. The method of claim 1 , wherein the surface tension is decreased by at least 5%.9. The method of claim 8 , wherein the aqueous coating system comprises a paint or varnish.10. The method of in transparent varnishes (clearcoats).11. The method of claim 8 , wherein R is a saturated alkyl radical having 7 to 10 C atoms and x is a number in the range from 4 to 6.12. The method of claim 11 , wherein R is a saturated alkyl radical having 8 C atoms and x is the number 6.13. The method of claim 12 , wherein (I) is an adduct of 6 mol of PO with 1 mol of n-octanol.14. The method of claim 8 , wherein the density is increased by at least 5%. The invention relates to the use of compounds of specific structure as defoaming wetting agents for aqueous coating systems, more particularly paints and varnishes.Substrate wetting agents are interface-active compounds which lower the surface tension especially of aqueous varnish and paint formulations in order thus to promote for example the substrate wetting and also the flow. Substrate wetting agents are especially important for avoiding defects in the coating film when the substrate has a low surface tension (such as polymeric ...

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Номер записи: 18
11-07-2013 дата публикации

FINISHING AGENT FOR CHEMICAL CONVERSION COATING AND METHOD FOR PRODUCING SAME

Номер: US20130177709A1
Автор: Ishikawa Shusaku, SAITO Tomoko
Принадлежит: Yuken Industry Co., Ltd.

The following two means are provided for a finishing agent for a chemical conversion coating wherein the finishing agent is capable of forming a finishing coating having an excellent corrosion resistance and excellent appearance as well as being suppressed in the elution of trivalent chromium: (A) the ratio of the chromium equivalent molar concentration of a water-soluble trivalent chromium-containing substance contained in the finishing agent relative to the phosphorus equivalent molar concentration of a water-soluble phosphoric acid-based compound contained in the finishing agent is 0.5 or more; and (B) a water-soluble aluminum-containing substance and/or a water-soluble zirconium-containing substance are contained in the finishing agent such that the ratio of the total of the chromium equivalent molar concentration of the water-soluble trivalent chromium-containing substance, the aluminum equivalent molar concentration of the water-soluble aluminum-containing substance, and the zirconium equivalent molar concentration of the water-soluble zirconium-containing substance relative to the phosphorus equivalent molar concentration of the water-soluble phosphoric acid-based compound is 0.5 or more. 1. A finishing agent for forming a finishing coating on a member under treatment , the member under treatment being a member a surface of which has been treated with chemical conversion treatment , the finishing agent containing:a water-soluble phosphoric acid-based compound comprising one or more water-soluble substances selected from the group consisting of orthophosphoric acid and condensed phosphoric acid, ions thereof, and salts and coordination compounds including the ions thereof;a water-soluble organic acid compound comprising one or more water-soluble substances selected from organic acids, ions thereof, and salts and coordination compounds including the ions thereof;a water-soluble trivalent chromium-containing substance; andan organic-based material as a matrix- ...

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Номер записи: 19
11-07-2013 дата публикации

ANTISTATIC COATING COMPOSITION, ANTISTATIC FILM COATED WITH THE SAME AND METHOD FOR MANUFACTURING THE ANTISTATIC FILM THEREOF

Номер: US20130178551A1
Автор: TSAI Cheng-Hsin, YEH Yu-Chen
Принадлежит: BENQ MATERIALS CORPORATION

This invention discloses an antistatic coating composition and antistatic film coated with the same. The antistatic coating composition comprises a hard coating solution and an antistatic solution. The hard coating solution comprises from 20 to 35 parts by weight of an acrylic oligomer, from 5 to 10 parts by weight of an acrylic monomer, from 40 to 60 parts by weight of a solvent and from 1 to 5 parts by weight of a photoinitiator. The antistatic solution comprises from 0.5 to 5 parts by weight of polyacrylic acid and from 1 to 20 parts by weight of ionic liquid. The antistatic film formed by coating the antistatic coating composition has a pencil hardness of 2H and an initial surface resistivity in the range of 108˜1011Ω/□, and the surface resistivity will maintain in the range of 1010˜1012Ω/□ after isopropanol (IPA) washing. 1. An antistatic coating composition comprising: from 20 to 35 parts by weight of an acrylic oligomer;', 'from 5 to 10 parts by weight of an acrylic monomer;', 'from 40 to 60 parts by weight of a solvent; and', 'from 1 to 5 parts by weight of a photoinitiator; and, 'a hard coating solution comprising from 0.5 to 5 parts by weight of a polyacrylic acid; and', 'from 1 to 20 parts by weight of an ionic liquid., 'an antistatic solution comprising2. The antistatic coating composition according to claim 1 , wherein from 23 to 29 parts by weight of the acrylic oligomer;', 'from 7 to 10 parts by weight of the acrylic monomer;', 'from 48 to 58 parts by weight of the solvent; and', 'from 1 to 3 parts by weight of the photoinitiator; and, 'the hard coating solution comprising from 0.5 to 2.5 parts by weight of the polyacrylic acid; and', 'from 1 to 15 parts by weight of the ionic liquid., 'the antistatic solution comprising3. The antistatic coating composition according to claim 1 , wherein the acrylic oligomer of the hard coating solution is selected from a group consisting of polyurethane acrylate claim 1 , epoxy acrylate claim 1 , polyester acrylate ...

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Номер записи: 20
01-08-2013 дата публикации

COATING SOLUTION FOR PRODUCING OPTICAL FILM, METHOD FOR PRODUCING THE COATING SOLUTION, METHOD FOR MANUFACTURING OPTICAL COMPONENT, AND IMAGING OPTICAL SYSTEM

Номер: US20130194672A1
Автор: Kobayashi Motokazu, Tanaka Hiroyuki
Принадлежит: CANON KABUSHIKI KAISHA

The present invention provides a coating solution for producing an optical film and a method for producing the coating solution which has improved temporal stability and which is capable of preventing the occurrence of defects in a coating film when a magnesium fluoride film is formed by applying a coating solution containing magnesium fluorocarboxylate and then firing the coating solution. 2. The coating solution for producing an optical film according to claim 1 , wherein the compound represented by the general formula (1) is acetic anhydride.4. A method for manufacturing an optical component comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a step of applying the coating solution for producing an optical film according to to a substrate; and'}a step of heating the substrate to which the coating solution for producing an optical film is applied.5. An imaging optical system comprising an optical component manufactured by the method for manufacturing an optical component according to claim 4 , wherein light from an object is condensed by the optical component to form an object image. The present invention relates to a coating solution for producing an optical film, a method for producing the coating solution, a method for manufacturing an optical component having an excellent antireflection effect, and an imaging optical system.For the purpose of improving light transmittance, an antireflection film is provided on a surface of an optical component constituting an optical device.Reflectance becomes theoretically zero by coating with a low-refractive-index material to an optical thickness of λ/4 based to wavelength λ, the low-refractive-index material having a refractive index (nc) represented by the following relational expression to refractive index ng of a substrate in air:nc=√ng  (Expression 1)As an antireflection film for an optical element which requires a lower-reflection effect, instead of the above-described single layer, a multilayer film is used ...

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Номер записи: 21
01-08-2013 дата публикации

ALKOXYAMINOSILANE COMPOUNDS AND APPLICATIONS THEREOF

Номер: US20130196082A1
Автор: "ONeill Mark Leonard", Chandra Haripin, Ho Richard, Lei Xinjian, Pearlstein Ronald Martin, Spence Daniel P., Xiao Manchao
Принадлежит: AIR PRODUCTS AND CHEMICALS, INC.

Alkoxyaminosilane compounds having formula I, and processes and compositions for depositing a silicon-containing film, are described herein: 2. The alkoxyaminosilane of claim 1 , wherein Ris selected from tert-butyl and tert-pentyl; and Rand Rcomprise Cto Calkyl groups selected from ethyl claim 1 , n-propyl claim 1 , iso-propyl claim 1 , n-butyl claim 1 , sec-butyl claim 1 , iso-butyl claim 1 , and tert-butyl.3. The alkoxyaminosilane of claim 1 , wherein Rcomprise the Cto Calkyl groups selected from ethyl claim 1 , n-propyl claim 1 , iso-propyl claim 1 , n-butyl claim 1 , sec-butyl claim 1 , iso-butyl claim 1 , and tert-butyl;{'sup': 4', '5, 'sub': 3', '5, 'and Rand Rcomprise the branched Cto Calkyl groups selected from iso-propyl, sec-butyl, iso-butyl, tert-butyl, and tert-pentyl.'}4. The alkoxyaminosilane of claim 1 , wherein Rand Rare linked to form a ring.5. The alkoxyaminosilane of comprising diethoxy(tert-butylamino)silane.6. The alkoxyaminosilane of comprising dimethoxy(tert-butylamino)silane.8. The process of claim 7 , wherein Rcomprises H and Ris selected from tert-butyl and tert-pentyl.9. The process of claim 7 , wherein the deposition process is selected from the group consisting of cyclic CVD (CCVD) claim 7 , MOCVD (Metal Organic CVD) claim 7 , thermal chemical vapor deposition claim 7 , plasma enhanced chemical vapor deposition (PECVD) claim 7 , high density PECVD claim 7 , photon assisted CVD claim 7 , plasma-photon assisted (PPECVD) claim 7 , cryogenic chemical vapor deposition claim 7 , chemical assisted vapor deposition claim 7 , hot-filament chemical vapor deposition claim 7 , CVD of a liquid polymer precursor claim 7 , deposition from supercritical fluids claim 7 , and low energy CVD (LECVD) claim 7 , and flowable chemical vapor deposition.10. The process of claim 7 , wherein the deposition process is selected from the group consisting of atomic layer deposition (ALD) claim 7 , plasma enhanced ALD (PEALD) claim 7 , and plasma enhanced cyclic CVD ( ...

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Номер записи: 22
08-08-2013 дата публикации

COMPOSITION FOR SURFACE TREATMENT AND METHOD OF MAKING THE SAME

Номер: US20130203916A1
Автор: Patel Vinay G.
Принадлежит:

A surface treatment composition including statically charged polymeric nanoparticles. The statically charged nanoparticles include hydrogen bonding formed by combination with hydrogen hydroxide. The nanoparticles include one or more pore filling components such as polymeric silicon dioxide. The nanoparticles are encapsulated so as to retain the charge wherein the encapsulant may be a polyacrylate. The charged nanoparticles are retained to the surface to be treated and penetrate most soft and hard surfaces, insulating against oxidation, providing superior protection from soiling, staining and ultra violet degradation. The super smooth surface significantly reduces friction and mitigates static generation. Subsequent applications of the composition bond to previous applications of the composition and improve surface protection. 1. A composition for finishing a surface of a structure , the composition comprising a mixture of a plurality of polymeric nanoparticles and hydrogen hydroxide fused together.2. The composition as claimed in wherein the hydrogen hydroxide and the polymeric nanoparticles are combined together in a weight ratio of about 1.5/1 hydrogen hydroxide to polymeric nanoparticles.3. The composition as claimed in wherein the plurality of polymeric nanoparticles comprises one or more types of polymeric materials.4. The composition as claimed in wherein the polymeric nano particles are no more than 75 nanometers in any dimension.5. The composition as claimed in further comprising a nonionic surfactant.6. The composition as claimed in wherein the nonionic surfactant is a linear ethoxylated alcohol.7. The composition as claimed in wherein the nonionic surfactant comprises about 0.5% by weight of the composition.8. A method for fabricating a composition for finishing a surface of a structure claim 5 , the method comprising the steps of:a. mixing together a pore filling component and carbon nanoparticles to form a carbon-supported pore filling component;b. ...

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Номер записи: 23
15-08-2013 дата публикации

SURFACE TREATMENT AGENT AND SURFACE TREATMENT METHOD

Номер: US20130206039A1
Автор: Ohhashi Takuya, Sugawara Mai
Принадлежит: TOKYO OHKA KOGYO CO., LTD.

A monosilane compound or bissilane compound of a specific structure having dimethylamino groups is contained in a surface treatment agent used in the hydrophobization treatment of substrate surfaces. 1. A surface treatment agent used in hydrophobization treatment of a substrate surface , the surface treatment agent comprising a compound represent by formula (1) or (2) below:{'br': None, 'sup': '1', 'sub': a', '3', '2', '4-a, 'RSi[N(CH)]\u2003\u2003(1)'}{'br': None, 'sup': 2', '4', '3, 'sub': b', '3', '2', '3-b', 'c', '3', '2', '3-c, 'R[N(CH)]Si—R—SiR[N(CH)]\u2003\u2003(2)'}{'sup': '1', 'wherein, in formula (1), Ris each individually a straight chain or branched chain aliphatic hydrocarbon group with 1 to 18 carbon atoms in which a part or all hydrogen atoms may be substituted by fluorine atoms, and a is 1 or 2; and'}{'sup': 2', '3', '4, 'in formula (2), Rand Rare each independently a hydrogen atom, or a straight chain or branched chain alkyl group with 1 to 4 carbon atoms, Ris a straight chain or branched chain alkylene group with 1 to 16 carbon atoms, and b and c are each independently an integer of 0 to 2.'}2. The surface treatment agent according to claim 1 , wherein Ris a straight chain aliphatic hydrocarbon group with 1 to 18 carbon atoms.3. The surface treatment agent according to claim 2 , wherein Ris a straight chain alkyl group with 1 to 18 carbon atoms.4. The surface treatment agent according to claim 1 , wherein b and c are 1.5. The surface treatment agent according to claim 1 , wherein Ris a straight chain alkylene group.6. The surface treatment agent according to claim 1 , wherein Rand Rare a hydrogen atom or methyl group.7. The surface treatment agent according to claim 1 , further comprising a solvent.8. A surface treatment method claim 1 , comprising exposing a substrate surface to the surface treatment agent according to to hydrophobize the substrate surface. This application claims priority to Japanese Patent Application No. 2012-027136, filed on ...

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Номер записи: 24
15-08-2013 дата публикации

Ink jet penetrant, composition for ink jet recording, and recording apparatus

Номер: US20130208063A1
Автор: Hiroko Hayashi, Masahiro Yatake, Tomoyuki Okuyama
Принадлежит: Seiko Epson Corp

An ink jet penetrant contains a compound represented by general formula (1), and this compound is obtained by a block polymerization process for sequentially polymerizing an alcohol represented by general formula (2) with propylene oxide and then with ethylene oxide. The amount of this alcohol in the penetrant is 1% by mass or less. C x H 2x+1 —O—(PO) y -(EO) z —H   (1) (where x denotes an integer of 5 to 10, y an integer of 0 to 7, z an integer of 3 to 10, PO a propylene oxide group, and EO an ethylene oxide group) C x H 2x+1 —OH   (2) (where x denotes an integer of 5 to 10)

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Номер записи: 25
15-08-2013 дата публикации

METHOD FOR PRODUCING A COLOR- AND/OR EFFECT PRODUCING MULTILAYER COATING, IN WHICH THE COLOR-FORMING COATING COMPOUND CONTAINS A SUBSTITUTED CYCLOHEXANOL IN ORDER TO REDUCE THE NUMBER OF PINHOLES

Номер: US20130209697A1
Автор: Steinmetz Bernhard
Принадлежит: BASF COATINGS GMBH

Disclosed is a method for producing a multicoat color and/or effect painting system by applying a pigmented aqueous basecoat material to a substrate, forming a film from the applied coating, applying a clearcoat material to the film, and then curing the film together with the clearcoat material, wherein the pigmented aqueous basecoat material comprises at least one substituted cyclohexanol in an amount of 0.1% to 5% by weight, based on the weight of the pigmented aqueous basecoat material, the substituted cyclohexanol being selected from the group consisting of a cyclohexanol substituted in positions 2 and 5, a cyclohexanol substituted in positions 3 and 5, a monosubstituted cyclohexanol, and mixtures of two or more of the foregoing, wherein the substituents are selected from the group consisting of optionally branched alkyl groups having 1 to 5 C atoms, a bridging isopropylene group and mixtures of two or more of the foregoing. 2. The method of claim 1 , wherein the substituents are selected from the group consisting of methyl groups claim 1 , isopropyl groups claim 1 , tertiary-butyl groups claim 1 , a bridging isopropylene group in the case of substitution in positions 2 and 5 claim 1 , and mixtures of two or more of the foregoing.3. The method of claim 2 , wherein the substituted cyclohexanol is selected from the group consisting of methyl-cyclohexanol claim 2 , tertiary-butylcyclohexanol claim 2 , and mixtures thereof.4. The method of claim 2 , wherein the substituted cyclohexanol is selected from the group consisting of 2-isopropyl-5-methylcyclohexanol (menthol) claim 2 , 3 claim 2 ,3 claim 2 ,5-trimethylcyclohexanol claim 2 , 4-methylcyclohexanol claim 2 , 4-tertiary-butylcyclohexanol claim 2 , 1 claim 2 ,7 claim 2 ,7-trimethylbicyclo[2.2.1]heptan-2-ol (borneol and/or isoborneol) claim 2 , and mixtures of two or more of the foregoing.5. The method of claim 1 , wherein the at least one substituted cyclohexanol is present in the pigmented aqueous basecoat ...

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Номер записи: 26
22-08-2013 дата публикации

HYDROPHOBIC FLUORINATED COATINGS

Номер: US20130216820A1
Автор: Flynn Richard M., Iyer Suresh S., Jing Naiyong, Manske Karl J., Olson Erik D., Riddle Justin A.
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

Articles having hydrophobic fluorinated coatings are provided. More specifically, the articles include a substrate, a primer layer of acid-sintered silica nanoparticles, and a hydrophobic fluorinated layer. The hydrophobic fluorinated coatings can be used on a large variety of substrate and tend to be quite durable even when subjected to repeated rubbing and/or cleaning. 1. An article comprising:(a) a substrate:(b) a primer layer attached to a surface of the substrate, the primer layer comprising a plurality of acid-sintered silica nanoparticles arranged to form a three-continuous dimensional porous network, wherein the primer layer is formed from a primer layer coating composition comprising a silica sol acidified with an acid having a pKa less than 3.5 to a pH in a range of 2 to 5 and that does not contain a tetraalkoxysilane coupling agent; and(c) a hydrophobic fluorinated layer attached to the primer layer, the hydrophobic fluorinated layer comprising a reaction product of a fluorinated silane with a surface of the acid-sintered silica nanoparticles in the primer layer, wherein the fluorinated silane has a reactive silyl group and a hydrophobic fluorinated group.2. The article of claim 1 , wherein the fluorinated group is a perfluorinated group.4. The article of claim 3 , wherein Q comprises an alkylene.5. The article of claim 3 , wherein Q comprises at least one alkylene and further comprises at least one oxy claim 3 , thio claim 3 , —NR— claim 3 , methine claim 3 , tertiary nitrogen claim 3 , quaternary nitrogen claim 3 , carbonyl claim 3 , sulfonyl claim 3 , sulfiryl claim 3 , carbonyloxy claim 3 , carbonylthio claim 3 , carbonylimino claim 3 , sulfonylimino claim 3 , oxycarbonyloxy claim 3 , iminocarbonylimino claim 3 , oxycarbonylimino claim 3 , or a combination thereof claim 3 , wherein Ris hydrogen claim 3 , alkyl claim 3 , aryl claim 3 , or aralkyl.6. The article of claim 1 , wherein the substrate is a polymeric material or a metal.7. The article of ...

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Номер записи: 27
29-08-2013 дата публикации

SURFACE TREATMENT PROCESS, COMPOSITION FOR USE THEREIN, AND TREATED ARTICLE

Номер: US20130220177A1
Автор: Iyer Suresh S., Rajagopal Rama V.
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

A surface treatment process comprises (a) providing at least one substrate; (b) providing a curable surface treatment composition comprising (1) at least one fluorinated organosilane compound comprising (i) a monovalent segment selected from polyfluoroalkyl, polyfluoroether, polyfluoropolyether, and combinations thereof and (ii) a monovalent endgroup comprising at least one silyl moiety comprising at least one group selected from hydrolyzable groups, hydroxyl, and combinations thereof, and (2) at least one organosilane compound comprising (i) a multivalent non-fluorinated segment and (ii) at least two monovalent endgroups, each monovalent endgroup independently comprising at least one silyl moiety comprising at least one group selected from hydroxyl, hydrolyzable groups, and combinations thereof, and/or at least one organosilazane compound; (c) applying the curable surface treatment composition to the substrate; and (d) curing the applied, curable surface treatment composition. 1. A process comprising(a) providing at least one substrate having at least one major surface; (1) at least one fluorinated organosilane compound comprising (i) a monovalent segment comprising a polyfluoropolyether and (ii) a monovalent endgroup comprising at least one silyl moiety comprising at least one group selected from hydrolyzable groups, hydroxyl, and combinations thereof,', '(2) optionally, at least one fluorinated organosilane compound comprising (i) a multivalent segment comprising a polyfluoropolyether and (ii) at least two monovalent endgroups, each said monovalent endgroup independently comprising at least one silyl moiety comprising at least one group selected from hydrolyzable groups, hydroxyl, and combinations thereof, and', '(3) at least one organosilane compound comprising (i) a multivalent non-fluorinated segment and (ii) at least two monovalent endgroups, each said monovalent endgroup independently comprising at least one silyl moiety comprising at least one group ...

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Номер записи: 28
29-08-2013 дата публикации

LED CURING OF RADIATION CURABLE FLOOR COATINGS

Номер: US20130224495A1
Автор: Bishop Timothy, CAO Huimin, Diaz Mark, Gan Keqi, Lee Tai-Yeon
Принадлежит:

A radiation curable coating for a floor comprising: at least one radiation curable oligomer, at least one photoinitiator and at least one reactive diluent monomer, said radiation curable oligomer being selected from the group consisting of Urethane (meth)acrylates, epoxy (meth)acrylates, polyester (meth)acrylates, acrylic (meth)acrylates, and hydrocarbon (meth)acrylates is described and claimed. The composition is capable of undergoing photopolymerization when coated on a floor and when irradiated by a light emitting diode (LED) light, having a wavelength from about 100 nm to about 900 nm, to provide a cured coating on the floor, with the cured coating having an external surface, and the cured coating having a Percent Reacted Acrylate Unsaturation (% RAU) at the external surface of about 60% or greater. Also described and claimed are the process to coat a floor with the LED curable coating for floor and a coated floor where the coating has been cured by application of LED light. 1. A radiation curable floor coating composition , wherein the composition is capable of undergoing photopolymerization when coated on the surface of a floor and when cured by irradiating with light emitted from a light emitting diode (LED) light having a wavelength from 100 nm to 900 nm , to provide a cured coating on the surface of the floor , said cured coating having a surface , said cured coating having a % Reacted Acrylate Unsaturation (% RAU) of about 60% or greater as measured at said surface , preferably from 90% to 99%.2. The radiation curable floor coating composition of claim 1 , wherein the light emitting diode (LED) emits light with a wavelength offrom 100 nm to 300 nm;from 300 nm to 475 nm; orfrom 475 nm to 900 nm.3. The radiation curable floor coating composition of comprising:(a) at least one radiation curable oligomer selected from the group consisting of urethane (meth)acrylates, epoxy (meth)acrylates, polyester (meth)acrylates, acrylic (meth)acrylates, and hydrocarbon ( ...

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Номер записи: 29
05-09-2013 дата публикации

COMPOSITION FOR FORMING ALUMINUM-CONTAINING FILM, AND METHOD FOR FORMING ALUMINUM-CONTAINING FILM

Номер: US20130230666A1
Автор: NAKAGAWA Hisashi, Sakai Tatsuya
Принадлежит: JSR Corporation

A composition for forming an aluminum-containing film includes an organic solvent, and an organic aluminum compound. The organic aluminum compound has a structure represented by a general formula (1). In the general formula (1), each of Rto Ris independently a hydrogen atom or a hydrocarbon group, each of Rs, Rs, Rs, Rs, Rs and Rs is identical or different, and optionally each of Rs, Rs, Rs, Rs, Rs or Rs is linked to one another.

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Номер записи: 30
19-09-2013 дата публикации

Non--voc neutralizing agents for coatings

Номер: US20130239851A1
Автор: Bruce K. Fillipo, Jeffrey K. Politis, Margaret K. Oplinger
Принадлежит: HERCULES LLC

Paint formulations are neutralized with a non-VOC neutralizing agent. The neutralizing agent is a neutralized amino acid or intermediate, an amino phosphate, an amino phosphonate, amino sulfate, or amino sulfonate wherein the neutralizing agent has a pKa 2 of at least 9. These neutralizing agents can be used to provide a paint formulation within a pH range of 8 to 10 and do not add any volatile organic compounds to the paint formulation.

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Номер записи: 31
19-09-2013 дата публикации

ADDUCTS OF ISOCYANATOALKYLTRIALKOXYSILANES AND ALIPHATIC, ALKYL-BRANCHED DIOLS OR POLYOLS

Номер: US20130244043A1
Автор: HERDA Silvia, Lomoelder Rainer, Nacke Christoph, Naumann Sabine, Raukamp Andre
Принадлежит: EVONIK DEGUSSA GmbH

Low molecular mass adduct compositions of isocyanatoalkyltrialkoxysilanes and aliphatic alkyl-branched diols or polyols are provided. The adduct compositions are liquid at temperatures of greater than 0° C. Coating compositions which provide scratch resistant clearcoat coatings upon curing are also provided.

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Номер записи: 32
03-10-2013 дата публикации

TREATMENT LIQUID FOR INHIBITING PATTERN COLLAPSE IN MICROSTRUCTURE AND METHOD OF MANUFACTURING MICROSTRUCTURE USING THE SAME

Номер: US20130260571A1
Автор: AOYAMA Kimihiro, Matsunaga Hiroshi
Принадлежит: MITSUBISHI GAS CHEMICAL COMPANY, INC.

The objects of the present invention are to provide a treatment liquid able to inhibit pattern collapse in a microstructure such as a semiconductor device or a micromachine, as well as a method of manufacturing a microstructure using the same. 1. A treatment liquid for inhibiting pattern collapse in a metal microstructure comprising an alkylphosphonic acid or salt thereof in which said alkyl moiety contains 6 to 18 carbon atoms; water; and a glycol of the following formula (1) or (2):{'br': None, 'sub': 2', '4', 'n, 'sup': '1', 'HO(CHO)R\u2003\u2003(1)'}{'br': None, 'sub': 3', '6', 'm, 'sup': '1', 'HO(CHO)R\u2003\u2003(2)'}{'sup': '1', 'sub': 1', '4, 'wherein Rdenotes a hydrogen atom or a C-Calkyl group, n denotes an integer of 2 to 4, and m denotes an integer of 1 to 3.'}2. The treatment liquid for inhibiting pattern collapse according to claim 1 , wherein the microstructure contains at least one metal selected from among titanium claim 1 , tantalum and aluminum.3. The treatment liquid for inhibiting pattern collapse according to claim 1 , wherein the content of the alkylphosphonic acid is 0.1 ppm to 10 claim 1 ,000 ppm.4. The treatment liquid for inhibiting pattern collapse according to claim 1 , wherein the content of the alkylphosphonic acid is 0.5 ppm to 1 claim 1 ,000 ppm.5. The treatment liquid for inhibiting pattern collapse according to claim 1 , wherein the content of the alkylphosphonic acid is 5 ppm to 800 ppm.6. The treatment liquid for inhibiting pattern collapse according to claim 1 , wherein the content of glycols is 60% by weight to 99% by weight.7. A method of manufacturing a microstructure containing at least one metal selected from among titanium claim 1 , tantalum and aluminum claim 1 , the method comprising: [{'br': None, 'sub': 2', '4', 'n, 'sup': '1', 'HO(CHO)R\u2003\u2003(1)'}, {'br': None, 'sub': 3', '6', 'm, 'sup': '1', 'HO(CHO)R\u2003\u2003(2)'}], 'in rinsing steps following wet-etching or dry-etching, using a treatment liquid for ...

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Номер записи: 33
03-10-2013 дата публикации

PHTHALATE-FREE ISOCYANURATE FORMULATIONS

Номер: US20130261236A1
Автор: Augustin Thomas, Sanders Josef
Принадлежит:

The present invention relates to novel low-monomer low-viscosity high-activity formulations composed of isocyanurate containing isocyanate groups, exclusively based on 2,4-diisocyanatotoluene and phthalate-free plasticizers, to the use thereof as adhesion promoters with improved adhesion for coating compositions based on plasticized polyvinyl chloride, and to coatings and coated substrates. 1. Preparations , characterized in that these compriseA) from 15 to 50% by weight of isocyanurate containing isocyanate groupsB) from 84.99 to 49.99% by weight of n- or isoalkyl monobenzoates andC) a residual content of 2,4-TDI in the range from 0.01 to 0.099% by weight and have a viscosity in the range from 5000 to 18 000 mPas/23° C., with the proviso thati) the isocyanurate containing isocyanate groups is produced exclusively via trimizerization of 2,4-diisocyanatotoluene andii) the total of all of the percentages by weight is 100%.2. Preparations according to claim 1 , characterized in that the n- or isoalkyl monobenzoates comprise >90% by weight of n- or isononyl benzoate.3. Preparations according to or claim 1 , characterized in that they comprise from 20 to 35% by weight of isocyanurate containing isocyanate groups and from 79.99 to 64.99% by weight of n- or isoalkyl monobenzoates claim 1 , preferably n- or isononyl benzoates.4. Use of preparations according to any of to as adhesion promoters for coating compositions based on plasticized polyvinyl chloride.5. Use according to claim 4 , characterized in that the coating compositions are used for the production of substrates.6. Use according to claim 5 , characterized in that the coated substrates are used as tarpaulins claim 5 , billboards claim 5 , air-supported structures and other textile structures claim 5 , flexible containers claim 5 , polygonal roofs claim 5 , awnings claim 5 , protective apparel claim 5 , conveyor belts claim 5 , flock carpets or foamed synthetic leather.7. Use according to or claim 5 , characterized ...

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Номер записи: 34
17-10-2013 дата публикации

DERIVATIVES FOR PERFLUOROALKOXY SULFOSUCCINATES AS SURFACTANTS

Номер: US20130269568A1
Автор: Claus Eckhard, Hierse Wolfgang, Kleineidam Melanie
Принадлежит: Merck Patent GmBH

The present invention relates to novel compounds containing Rf end groups, to the use thereof as surface-active substances, and to processes for the preparation of these compounds. The claimed compounds fall under the following formula: (I), Two examples of claimed compound are: (II), (III). 2. Compounds according to claim 1 , characterised in that at least four claim 1 , preferably four claim 1 , six or nine claim 1 , Rfgroup are present.3. Compounds according to claim 1 , characterised in that Y claim 1 , Yand Yare equal to O.4. Compounds according to claim 1 , characterised in that L=L=Land are equal to linear or branched alkyl having 1 to 10 C atoms.5. Compounds according to claim 1 , characterised in that the fluorinated groups Rfused are branched or unbranched claim 1 , perfluorinated alkyl radicals having 1 to 10 C atoms claim 1 , preferably 1 to 6 C atoms claim 1 , in particular 1-4 C atoms.6. Compounds according to claim 1 , characterised in that X is an anionic group claim 1 , preferably —SO claim 1 , —OSO claim 1 , —PO claim 1 , or OPO claim 1 , in particular —SO.7. Compounds according to claim 1 , characterised in that X is a cationic group claim 1 , preferably —NRRRZ— claim 1 , where R claim 1 , Rand Reach stand claim 1 , independently of one another claim 1 , for H claim 1 , C-alkyl claim 1 , Ar or —CHAr and Ar stands for an unsubstituted or mono- or polysubstituted aromatic ring or condensed ring systems having 6 to 18 C atoms in which claim 1 , in addition claim 1 , one or two CH groups may be replaced by N.8. Compounds according to claim 1 , characterised in that X is a nonionic group claim 1 , preferably linear or branched alkyl claim 1 , where one or more non-adjacent C atoms may be replaced by O claim 1 , S and/or N claim 1 , —OH claim 1 , —OCOCR═CHand —O-(glycoside) claim 1 , wherein o stands for an integer from 1 to 10.9. Compounds according to claim 8 , characterised in that X equal to R—(O—CHCHR)— where m=an integer from the range from 1 to ...

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Номер записи: 35
17-10-2013 дата публикации

Composition for the Production of a Coating with High Adhesive Strength and Scratch Resistance

Номер: US20130274381A1
Автор: Hugenberg Norbert, Peng Bin, Puetz Joerg
Принадлежит:

A coating that includes: 3. The composition of claim 1 , wherein the inorganic oxide is selected from SiO claim 1 , TiO claim 1 , ZrO claim 1 , SnO claim 1 , SbO claim 1 , AlO claim 1 , AlO(OH) or mixed oxides or mixtures or core-shell structures thereof claim 1 , and the inorganic fluoride is MgFwhich is optionally present in a core-shell structure with the inorganic oxide.4. The composition of claim 2 , wherein the inorganic oxide is selected from SiO claim 2 , TiO claim 2 , ZrO claim 2 , SnO claim 2 , SbO claim 2 , AlO claim 2 , AlO(OH) or mixed oxides or mixtures or core-shell structures thereof claim 2 , and the inorganic fluoride is MgFwhich is optionally present in a core-shell structure with the inorganic oxide.5. The composition of claim 1 , wherein the epoxide compound is a polyglycidyl ether compound claim 1 , preferably a diglycidyl ether or triglycidyl ether compound.6. The composition of claim 2 , wherein the epoxide compound is a polyglycidyl ether compound claim 2 , preferably a diglycidyl ether or triglycidyl ether compound.7. The composition of claim 3 , wherein the epoxide compound is a polyglycidyl ether compound claim 3 , preferably a diglycidyl ether or triglycidyl ether compound.8. The composition of claim 4 , wherein the epoxide compound is a polyglycidyl ether compound claim 4 , preferably a diglycidyl ether or triglycidyl ether compound.11. The composition of claim 10 , wherein the epoxide compound of the formula (V) is selected from the group consisting of: trimethylolpropane triglycidyl ether claim 10 , triglycidylglycerol claim 10 , trimethylolethane triglycidyl ether claim 10 , a prepolymer thereof claim 10 , and a mixture thereof.12. The composition of claim 11 , wherein the Lewis acid is selected from the group consisting of: an ammonium salt claim 11 , a metal salt of a metal from one of groups 1 claim 11 , 2 and 13 of the periodic table of the elements claim 11 , a halide of an element of group 13 of the periodic table of the ...

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Номер записи: 36
17-10-2013 дата публикации

BLENDS OF DIBENZOATE PLASTICIZERS

Номер: US20130274396A1
Автор: Arendt William D., McBride Emily L.
Принадлежит: Emerald Kalama Chemical, LLC

Plasticizer blends comprise a triblend of diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and 1,2-propylene glycol dibenzoate, in specified ratios, useful in combination with a multitude of thermoplastic polymers, thermosetting polymers, and elastomeric polymers and numerous applications, including but not limited to plastisols, adhesives, sealants, caulks, architectural coatings, industrial coatings, OEM coatings, inks, overprint varnishes, polishes, and the like. The advantages rendered by the use of the triblend depend on the type of polymer and application in which it is utilized and include among other advantages higher solvating power and lower processing time, low VOC's, reduced plasticizer freeze point, improved gelation and fusion characteristics, higher tensile strength, superior stain and extraction resistance, and improved rheology over traditional diblends of diethylene glycol dibenzoate and dipropylene glycol dibenzoate. 1. A plasticizer triblend composition comprising:a. diethylene glycol dibenzoate present in amounts ranging from about 10 to about 90 wt. %,b. dipropylene glycol dibenzoate present in amounts ranging from about 1 to about 50 wt. %, andc. 1,2-propylene glycol dibenzoate present in amounts ranging from about 10 to about 90 wt. %,based upon the total weight of the triblend composition,wherein the triblend is useful either alone as a primary plasticizer or as a specialty blending plasticizer to improve compatibility and processability of poor solvating plasticizers.2. The plasticizer triblend composition of claim 1 ,wherein the diethylene glycol dibenzoate is present in amounts of at least about 60 wt. %,wherein the dipropylene glycol dibenzoate is present in amounts of at least about 10 wt. %, andwherein the 1,2-dipropylene glycol dibenzoate is present in amounts of at least about 20 wt. %.3. The plasticizer triblend composition of claim 1 , wherein the blend comprises 80 wt. % of a mixture of diethylene glycol dibenzoate and ...

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Номер записи: 37
24-10-2013 дата публикации

Aqueous coating compositions including phenylphenol ethoxylate surfactants

Номер: US20130280433A1
Автор: Arkady L. Krasovskiy, Cynthia L. Rand, Irina V. Graf
Принадлежит: Dow Global Technologies LLC

An aqueous coating composition including an aqueous polymeric dispersion and from 0.1% to 40% by weight, based on the weight of the aqueous polymeric dispersion solids, Phenylphenol-(CH 2 CH 2 O) 2-50 H, isomers thereof, aromatic ring substituted analogues thereof, and mixtures thereof is provided. Also provided are a method for forming a coating therefrom, a method for improving the freeze-thaw stability of an aqueous coating including a polymeric dispersion and alternative uses for Phenylphenol-(CH 2 CH 2 O) 2-50 H, isomers thereof, aromatic ring substituted analogues thereof, and mixtures thereof.

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Номер записи: 38
24-10-2013 дата публикации

Surfactant compositions and use for aqueous compositions

Номер: US20130280434A1
Автор: Arkady L. Krasovskiy, Irina V. Graf
Принадлежит: Dow Global Technologies LLC

A surfactant composition selected from the group consisting of: ArO—(CH 2 CH[CH 2 CH 3 ]O) 1-10 (CH 2 CH 2 O) 5-50 H, isomers, aromatic ring substituted analogues, and mixtures thereof; and an aqueous coating composition including an aqueous polymeric dispersion, and certain other compositions, including the surfactant composition are provided. Also provided are a method for forming a coating and a method for improving the freeze/thaw stability of an aqueous composition including an aqueous polymeric dispersion.

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Номер записи: 39
24-10-2013 дата публикации

COATING COMPOSITION HAVING A TITANIUM-DIOXIDE-PRODUCING AGENT, NANOSCALE TITANIUM-DIOXIDE-BASED COATING, AND PRODUCTION, FURTHER PROCESSING AND USE THEREOF

Номер: US20130280523A1
Автор: Bergmann Ute, Heisterkamp Beate, Muehle Silvia, Schwarz Martin, Worch Hartmut, Wurm Frank-Hendrik
Принадлежит:

The invention relates to a coating composition containing between 51 wt % and 99.9 wt % of a TiO-producing agent, wherein the coating composition contains between 0.1 wt % and 49 wt %, relative to the total composition, of at least one further component which is selected from collagen, chitosans, phenols and/or substituted quaternary ammonium salts of alkylated phosphoric acid. The invention further relates to a nanoscale coating based on titanium dioxide, and to the production, further processing and use thereof. 1. A coating composition containing 51% to 99.9% by weight , preferably 70% to 99% by weight , especially 80% to 98% by weight , of a TiO-producing agent , whereby the coating composition contains 0.1% to 49% by weight , preferably 1% to 30% by weight , especially 2% to 20% by weight , relative to the total composition , of at least one additional component selected from among connective tissue protein , chitosans , phenols and/or substituted quaternary ammonium salts of alkylated phosphoric acid.2. The composition according to claim 1 , characterized in that up to 40 parts by weight claim 1 , preferably 30 parts by weight claim 1 , especially 20 parts by weight of the 100 parts by weight of the TiO-producing agent are replaced by a silicon-dioxide-producing agent.3. The composition according to or claim 1 , characterized in that this additional component is a connective tissue protein claim 1 , especially collagen claim 1 , elastin claim 1 , proteoglycan claim 1 , fibronectin or laminin claim 1 , obtained from vertebrates claim 1 , preferably domesticated animals claim 1 , especially pigs and/or cows and/or from the phylum Porifera claim 1 , preferably of the class Demospongiae claim 1 , particularly of the subclass Tetractinomorpha claim 1 , order Chondrosida.4Chondrosia reniformis.. The composition according to or claim 1 , characterized in that the collagen is obtained from5. The composition according to or claim 1 , characterized in that the ...

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Номер записи: 40
24-10-2013 дата публикации

USE OF POLYGLYCEROL PARTIAL ESTERS AS DEFOAMERS

Номер: US20130281552A1
Автор: Favresse Philippe, Gehrmann Petra, Mettin Thomas, Nilewski Margitta, Scharf André, Schwan Michael, Springer Oliver, Wied Tobias
Принадлежит: Evonik Industries AG

The present invention relates to the use of polyglycerol partial esters as defoamers, in particular in coating and paint applications, to defoamers comprising polyglycerol partial esters, and to corresponding polyglycerol partial esters. 1. A method of defoaming a liquid , comprising:obtaining polyglycerol partial esters by esterification of a polyglycerol mixture with an acid selected from the croup consisting of saturated or unsaturated, linear or branched fatty acids having 4 to 22 carbon atoms, aromatic monocarboxylic acids having 7 to 22 carbon atoms, polyfunctional carboxylic acids having 4 to 54 carbon atoms, and their anhydrides and esters; anddefoaming the liquid by applying the polyglycerol partial esters to the liquid.2. The method according to ;wherein the degree of esterification of the polyglycerol is between 76 and 100%.3. The method according to ;wherein the polyglycerol mixture is based on polyglycerols with an average degree of condensation of 2.4. The method according to ;wherein the saturated or unsaturated, linear or branched fatty acid having 4 to 22 carbon atoms is selected from the group consisting of isostearic acid, oleic acid, and linolenic acid.5. The method according towherein the polyfunctional carboxylic acid is selected from the group consisting of oxalic acid, fumaric acid, rnalonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, phthalic acid, and their anhydrides and esters.6. The method according to ;wherein the polyglycerol partial esters have a polydispersity of at least 2.7. A defoamer comprising:polyglycerol partial esters obtained by esterification of a polyglycerol mixture with an acid selected from the group consisting of saturated or unsaturated, linear or branched fatty acids having 4 to 22 carbon atoms, aromatic monocarboxylic acids having 7 to 22 carbon atoms, polyfunctional carboxylic acids having 4 to 54 carbon atoms, and their anhydrides and ...

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Номер записи: 41
31-10-2013 дата публикации

BIO-RENEWABLE FAST CRYSTALIZING PHASE CHANGE INKS

Номер: US20130284063A1
Автор: BAMSEY NATHAN M., BELELIE Jennifer L., Goredema Adela, Iftime Gabriel, Morimitsu Kentaro, Sacripante Guerino G., Tracy Corey L., TUREK CAROLINE M.
Принадлежит: XEROX CORPORATION

A phase change ink composition suitable for ink jet printing, including printing on coated paper substrates. In embodiments, the phase change ink composition comprises both a crystalline compound and an amorphous compound which are derived from bio-renewable materials. The composition provides for a robust, rapid crystallization ink composition. 2. A phase change ink of wherein R and R′ are alkyl groups with at least eight carbon atoms and no more than 50 carbon atoms.3. The phase change ink of claim 1 , wherein the ink is capable of crystallizing at a total crystallization time of less than 15 seconds as measured by the standardized TROM procedure.4. (canceled)6. The phase change ink of claim 1 , wherein the crystalline compound is present in an amount of from about 60 percent to about 95 percent by weight of the total weight of the phase change ink.7. The phase change ink of claim 1 , wherein the amorphous compound is present in an amount of from about 5 percent to about 40 percent by weight of the total weight of the phase change ink.8. The phase change ink of having a ratio of crystalline to amorphous ratio of from about 60:40 to about 95:5.9. The phase change ink of further comprising a colorant selected from the group consisting of a pigment claim 1 , dye or mixtures thereof.10. The phase change ink of claim 1 , wherein the crystalline component has a viscosity of less than 12 cps at a temperature of about 140° C.11. The phase change ink of claim 1 , wherein the crystalline component has Tof less than 150° C.12. The phase change ink of claim 1 , wherein the crystalline component has Tof greater than 60° C.13. The phase change ink of having a viscosity of from about 1 to about 22 cps in a jetting range of from about 100 to about 140° C.14. The phase change ink of having a viscosity of greater than about 10cps at room temperature.15. The phase change ink of further comprising an additive selected from the group consisting of antioxidant claim 1 , defoamer claim ...

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Номер записи: 42
31-10-2013 дата публикации

METAL SURFACE TREATMENT AQUEOUS SOLUTION AND METHOD FOR INHIBITING WHISKERS ON A METAL SURFACE

Номер: US20130284066A1
Автор: MORII Yutaka
Принадлежит:

A tin or tin alloy plating film surface treatment aqueous solution that can reduce whiskers on the surface of a tin or tin alloy plating film, and can provide a favorable tin or tin alloy plating film using a simple method for tin or tin alloy plating films that are used on electronic components. 15-. (canceled)6. A method comprising:a) providing a composition comprising one or more organic compounds chosen from citric acid, malic acid, maleic acid, oxalic acid, glutaric acid, tartaric acid, lactic acid, gluconic acid, picolinic acid, iminodiacetic acid or salts thereof and a nitrogen containing compound chosen from benzotriazole or imidazole, the pH of the surface treatment aqueous solution is 2.5 or lower; andb) applying the composition to a tin or tin alloy.7. The tin or tin alloy plating film surface treatment aqueous solution of claim 6 , wherein the concentration of the nitrogen containing compound is from 0.1-10 g/L.8. The tin or tin alloy plating film surface treatment aqueous solution of claim 6 , wherein the organic compound is chosen from malic acid claim 6 , maleic acid or salts thereof.9. The tin or tin alloy plating film surface treatment aqueous solution of claim 6 , wherein the organic compound ranges between 0.1 and 50 g/L.10. The tin or tin alloy plating film surface treatment aqueous solution of claim 9 , wherein the organic compound ranges between 5 and 30 g/L.11. The tin or tin alloy plating film surface treatment aqueous solution of claim 10 , wherein the organic compound ranges between 5 and 20 g/L. This application is a Divisional of U.S. Non-Provisional application Ser. No. 12/586,464, filed Sep. 22, 2009 which application claims the benefit of priority of Japanese Application No. 2008-243264, filed Sep. 22, 2008, the entire contents of which application are incorporated herein by reference.The present invention relates to a surface treatment solution for metals, and particularly tin or tin alloy plating films, and to a method for treating ...

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Номер записи: 43
31-10-2013 дата публикации

MIXTURE AND METHOD FOR SIMULATING SOILING AND WEATHERING OF SURFACES

Номер: US20130287966A1
Автор: Akbari Hashem, Berdahl Paul, Destaillats Hugo, KIRCHSTETTER Thomas, Levinson Ronnen, Sleiman Mohamad
Принадлежит: The Regents of the University of California

This disclosure provides systems, methods, and apparatus related to simulated soiling and weathering of materials. In one aspect, a soiling mixture may include an aqueous suspension of various amounts of salt, soot, dust, and humic acid. In another aspect, a method may include weathering a sample of material in a first exposure of the sample to ultraviolet light, water vapor, and elevated temperatures, depositing a soiling mixture on the sample, and weathering the sample in a second exposure of the sample to ultraviolet light, water vapor, and elevated temperatures. 1. A mixture comprising:salt;soot;mineral dust; andhumic acid.2. The mixture of claim 1 , wherein the mixture includes the salt at about 7% to 31% by weight claim 1 , the soot at about 1% to 8% by weight claim 1 , the mineral dust at about 16% to 79% by weight claim 1 , and the humic acid at about 0% to 69% by weight.3. The mixture of claim 1 , wherein the mixture includes the salt at about 18% to 27% by weight claim 1 , the soot at about 4% to 12% by weight claim 1 , the mineral dust at about 28% to 66% by weight claim 1 , and the humic acid at about 8% to 36% by weight.4. The mixture of claim 1 , wherein each component in the mixture is suspended in an aqueous medium.5. A method comprising:(a) weathering a sample of material in a first exposure of the sample to ultraviolet light, water vapor, and elevated temperatures;(b) after operation (a), depositing a soiling mixture on the sample; and(c) after operation (b), weathering the sample in a second exposure of the sample to ultraviolet light, water vapor, and elevated temperatures.6. The method of claim 5 , wherein the first exposure includes:heating the sample to about 60° C. for about 8 hours;cooling the sample from about 60° C. to about 50° C.; andexposing the sample to water vapor at about 50° C. for about 4 hours.7. The method of claim 5 , wherein the ultraviolet light in the first exposure is Ultraviolet A light.8. The method of claim 6 , wherein ...

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Номер записи: 44
07-11-2013 дата публикации

Low Humidity Cure for Moisture Curable Coatings

Номер: US20130295291A1
Автор: Crowley Stephen John
Принадлежит:

The invention is directed to a low humidity cure moisture curable coating composition which includes a moisture cure binder component that includes: a moisture curable binder material and at least one organic solvent; and a humectant component that includes a slow evaporating volatile humectant; wherein the humectant is present in an amount sufficient to increase the cure rate of the coating and to provide a cured coating having acceptable mechanical and cosmetic properties at a relative humidity of 50% or lower; and the invention is also directed to a method for curing moisture curable coating compositions under low humidity conditions. 2. The coating composition according to claim 1 , wherein the moisture curable binder material is chosen from an alkyl silicate based material claim 1 , a hybrid organic alkoxysilane based material claim 1 , a polyisocyanate based material which yields polyurea via moisture curing claim 1 , a polyketamine based material which yields free amines via moisture curing for reaction with epoxies or isocyanates claim 1 , and polyurethane compositions of isocyanate and polyol where the isocyanate is in sufficient excess to the polyol that moisture cure of isocyanate (yielding polyurea) is required to properly cure the coating.3. The coating composition of wherein the moisture curable coating composition is a two part zinc silicate coating composition which further comprises a zinc component in addition to the moisture curable binder and humectant components; wherein the moisture curable binder material is an alkyl silicate hydrolysate intermediate claim 1 , wherein the hydrolysate intermediate is the reaction product of an alkyl silicate and at least one water miscible alcohol functional solvent; wherein the organic solvent is a glycol ether or alcohol solvent claim 1 , wherein the glycol ether or alcohol solvent is a type and is present in an amount that increases the cure rate of the intermediate; and wherein the zinc component is chosen ...

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Номер записи: 45
07-11-2013 дата публикации

FUNCTIONALIZED NANOPARTICLES

Номер: US20130296453A1
Автор: BAUER DIDIER, GIESENBERG Thomas, JUNG Tunja, MICHAU Laurent, MUHLEBACH Andreas, Müller Martin, RIME Francois
Принадлежит:

The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of the formula (I) wherein the nanoparticles are SiO, AlOor mixed SiOand AlOnanoparticles, and wherein the general symbols are as defined in claim . These functionalized nanoparticles are for example useful as stabilizers and/or compatibilizers in organic materials, or as photoinitiators in pre-polymeric or pre-crosslinking formulations, or as reinforcer of coatings and improver of scratch resistance in coating compositions for surfaces.

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Номер записи: 46
28-11-2013 дата публикации

AMINO ACID GENERATOR AND POLYSILOXANE COMPOSITION CONTAINING THE SAME

Номер: US20130313669A1
Автор: KATO Taku, KOBAYASHI Junpei, SAKUMOTO Naoki, TAKANO Satoko
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

A coating film forming composition includes an amino acid generator including a protecting group that is eliminated to generate an amino acid. A coating film forming composition includes a component (A): the amino acid generator; a component (B): a hydrolyzable silane, a hydrolysis product thereof, a hydrolysis-condensation product thereof, or a mixture thereof; and a component (C): a solvent. 1. A coating film forming composition comprising an amino acid generator comprising a protecting group that is eliminated to generate an amino acid.2. The coating film forming composition according to claim 1 , wherein the amino acid generator is a thermo amino acid generator comprising a protecting group that is eliminated by heat to generate an amino acid.3. The coating film forming composition according to claim 1 , wherein the amino acid generator is a photo amino acid generator comprising a protecting group that is eliminated by light to generate an amino acid.4. The coating film forming composition according to claim 1 , wherein the amino acid generator is a compound of Formula (1):{'br': None, 'D-A\u2003\u2003Formula (1)'} D is the protecting group for an amino group, and', 'A is an organic group remaining after subtracting hydrogen atoms from the amino group of the amino acid., 'where6. The coating film fowling composition according to claim 4 , wherein the protecting group D is an esterified carboxy residue having an alkoxycarbonyl structure.7. The coating film forming composition according to claim 4 , wherein the protecting group D is a tert-butoxycarbonyl group or a 9-fluorenylmethoxycarbonyl group.9. A coating film forming composition comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a component (A): the amino acid generator as claimed in ;'}a component (B): a hydrolyzable silane, a hydrolysis product thereof, a hydrolysis-condensation product thereof, or a mixture thereof; anda component (C): a solvent.11. The coating film forming composition ...

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Номер записи: 47
12-12-2013 дата публикации

USE OF ALDEHYDE SCAVENGERS IN INTERIOR BUILDING PRODUCTS

Номер: US20130331494A1
Автор: Immordino Salvatore, Lu Runhai, Rosenstiel Terry L., SONG Weixin D.
Принадлежит: USG INTERIORS, LLC

A coating for application to the surface of an interior building product comprises: a resin formulation such as a melamine formaldehyde resin characterized by its ability to strengthen the interior building product when applied as a coating to the building product; and an aldehyde scavenger selected from the group consisting of; tetraethylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide and a combination of a polyvinyl alcohol and adipic dihydrazide. 1. An interior building product including at least two exterior surfaces and a coating applied to at least one of the at least two exterior surfaces , the coating comprising:a resin formulation characterized by its ability to strengthen the interior building product when applied as a coating to the building product; andan aldehyde scavenger selected from the group consisting of; tetraethylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide and a combination of a polyvinyl alcohol and adipic dihydrazide.2. The coating of wherein the interior building product is selected from the group consisting of ceiling tile claim 1 , fiber panels and wallboard.3. The coating of wherein the resin formulation includes a melamine formaldehyde resin.4. The coating of wherein the aldehyde scavenger comprises a polyvinyl alcohol.5. The coating of wherein the polyvinyl alcohol comprises a polyvinyl alcohol having a CAS ...

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Номер записи: 48
02-01-2014 дата публикации

HYDROPHOBIC AND LIPOPHOBIC COMPOSITION COMPRISING COMPOUNDS HAVING A BISPHOSPHONIC AND THIOL GROUP

Номер: US20140000476A1
Автор: Lecollinet Gregory, Portet David
Принадлежит: SURFACTIS TECHNOLOGIES

The present invention describes the highly advantageous properties of a mixture of thiol-perfluoropolyether (PFPE) molecules with perfluorinated bisphosphonic compounds (BP-PF). This mixture in fact makes it possible to obtain a lipophobic and hydrophobic behaviour on numerous materials, including metals, inter alia gold and alloys thereof. It makes it possible to prevent corrosion, and to limit deposition of soiling and microbiological contamination on these surfaces, while at the same time conferring good mechanical strength and resistance to ageing and to cleaning products. It also makes it possible to lubricate the metal parts that it covers. 5. Composition according to wherein said bisphosphonic and thiol compounds are dissolved in an organic solvent chosen from alcohol solvents claim 1 , aldehydes claim 1 , ketones claim 1 , ethers or alkanes claim 1 , as well as mixtures thereof claim 1 , or in a solvent consisting of hydrotreated naphthas mixed with isopropanol or acetone.6. A method for increasing the hydrophobicity and/or the lipophobicity of a metal surface which comprises applying the composition of to the metal surface.7. A method for limiting the corrosion of a metal surface which comprises applying the composition of to the metal surface.8. A method for limiting dirt deposits and/or microbial contamination of a metal surface which comprises applying the composition of to the metal surface.9. A method for lubricating a metal surface which comprises applying the composition of to the metal surface.10. The method of wherein said metal surface consists of over 50% of:noble metals selected from gold, platinum, silver and copper,oxidised metals selected among iron, titanium, aluminium, ruby, sapphire, nickel, ruthenium, rhodium and tin,alloys selected from steel, stainless steel, brass, nickel-silver, bronze, tin-nickel, nickel-phosphorus, copper-beryllium, palladium-nickel, copper-cobalt, or alloys containing vanadium, chromium, manganese, zinc, tungsten ...

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Номер записи: 49
02-01-2014 дата публикации

Hydrosilylation reaction inhibitors and use thereof for preparing stable curable silicone compositions

Номер: US20140004359A1
Автор: Sébastien MARROT, Yassine Maadadi
Принадлежит: BLUESTAR SILICONES FRANCE SAS

An inhibitor compound suitable for inhibiting the curing of a silicone composition is described. Further, the silicone composition is a silicone-elastomer precursor, obtained by means of a hydrosilylation reaction.

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Номер записи: 50
02-01-2014 дата публикации

AQUEOUS METAL SURFACE TREATMENT AGENT FOR LITHIUM ION SECONDARY BATTERY

Номер: US20140005314A1
Автор: Minowa Takahiro, Shibutani Mitsuo, Tanaka Hiroyuki, Yamazaki Satoshi
Принадлежит:

This is to provide an aqueous metal surface treatment agent for a lithium ion secondary battery which can improve interlaminar adhesiveness between a metal member and a resin coating layer such as a film or a coated film, and solvent resistance without using trivalent chromium. 2. The metal surface treatment agent according to claim 1 , wherein a molar ratio of the polyvinyl alcohol resin:the metallic crosslinking agent is 1:5 to 500:1.3. The metal surface treatment agent according to claim 1 , wherein the metallic crosslinking agent is selected from the group consisting of an oxide claim 1 , a hydroxide claim 1 , a complex compound claim 1 , an organometallic compound claim 1 , an organic acid salt and an inorganic acid salt of titanium claim 1 , aluminum claim 1 , zirconium claim 1 , vanadium claim 1 , molybdenum claim 1 , cerium claim 1 , lanthanum or tungsten.4. The metal surface treatment agent according to claim 2 , wherein the metallic crosslinking agent is selected from the group consisting of an oxide claim 2 , a hydroxide claim 2 , a complex compound claim 2 , an organometallic compound claim 2 , an organic acid salt and an inorganic acid salt of titanium claim 2 , aluminum claim 2 , zirconium claim 2 , vanadium claim 2 , molybdenum claim 2 , cerium claim 2 , lanthanum or tungsten. The present invention relates to an aqueous metal surface treatment agent for a lithium ion secondary battery comprising a modified polyvinyl alcohol having a 1,2-diol structural unit and a metallic crosslinking agent.A treatment agent for treating the surface of a metal has been used in broad fields such as automobiles, home electric appliances, architecture, foods, medicines, etc., in particular, it is useful for improving interlaminar adhesiveness between a metal material such as aluminum, magnesium, copper, iron, zinc, nickel or an alloy thereof, and various resin coating layers provided on the surface thereof, solvent resistance of the resin coating layer and corrosion ...

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Номер записи: 51
09-01-2014 дата публикации

NANOTEXTURED SURFACES

Номер: US20140011938A1
Автор: Guire Patrick E., Lawin Laurie R., Taton Kristin, Wen Jie
Принадлежит: INNOVATIVE SURFACE TECHNOLOGIES, INC.

The invention describes novel compositions that include a cross linking compound, a polymer and a 1 nm to about a 25 micron sized particle optionally with an oxide layer. In particular, the particle is a silica and one which has been pretreated with a silane. 2. The composition of claim 1 , wherein the particles are fabricated from material selected from the group of aluminum oxide claim 1 , titanium oxide claim 1 , zirconium oxide claim 1 , gold claim 1 , silver claim 1 , nickel claim 1 , iron oxide claim 1 , and alloys claim 1 , polystyrene claim 1 , (meth) acrylate claim 1 , PTFE claim 1 , silica claim 1 , polyolefin claim 1 , polycarbonate claim 1 , polysiloxane claim 1 , silicone claim 1 , polyester claim 1 , polyamide claim 1 , polyurethane claim 1 , ethylenically unsaturated polymers claim 1 , polyanhydride claim 1 , polycaprolactone claim 1 , polylactideglycolide claim 1 , or combinations thereof.3. The composition of claim 1 , wherein the particles are selected from the group of nanofibers claim 1 , nanotubes claim 1 , nanowires claim 1 , or combinations thereof.4. The composition of claim 1 , wherein the composition is super hydrophobic and has a water contact angle above 150°.5. The composition of claim 1 , wherein the composition is ultra hydrophobic and has a water contact angle of 120° to 150°.6. A method to modify a substrate comprising the step of applying a composition comprising the compound claim 1 , polymer and particle of to a surface of a substrate claim 1 , such that the substrate surface is modified.7. The method of claim 6 , wherein the compound is photoactivated such that at least one photoactivatable group within the compound forms a bond with the surface of the substrate.9. The composition of claim 8 , wherein the particles are fabricated from material selected from the group of aluminum oxide claim 8 , titanium oxide claim 8 , zirconium oxide claim 8 , gold claim 8 , silver claim 8 , nickel claim 8 , iron oxide claim 8 , and alloys claim ...

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Номер записи: 52
09-01-2014 дата публикации

WETTING AND DISPERSING AGENT, PRODUCTION METHOD AND USE THEREOF

Номер: US20140012036A1
Автор: "OShea Sandra", Krohnen Marcel, Omeis Jürgen, Piestert Frederik, Pritschins Wolfgang
Принадлежит:

The invention relates to a wetting and dispersing agent that can be produced by carrying out step (1): wherein a) an organic polymer containing primary and/or secondary amino groups and h) at least one branched polyhydroxymonocarboxylic acid comprising, in addition to a carboxyl group, at least two hydroxy groups, one of which is not bound to the main chain of the molecule, are reacted by condensation reactions, forming amide linkages; and step (2): wherein at least some of the hydroxy groups of the hydroxy-functional reaction product obtained in step (1) are reacted with at least one organic monoisocyanate, forming urethane linkages. 2. The wetting and dispersing agent as claimed in claim 1 , wherein in step (1) the components are reacted such that the molar ratio of the primary and secondary amino groups of component (a) to component (b) is in the range from 0.01 to 1.3. The wetting and dispersing agent as claimed in claim 2 , wherein in step (1) the components are reacted such that the molar ratio of the primary and secondary amino groups of component (a) to component (b) is in the range from 0.1 to 1.4. The wetting and dispersing agent as claimed in claim 1 , wherein in step (2) more than 5 mol % of the hydroxyl groups of the reaction product obtained in step (1) are reacted with the at least one organic monoisocyanate.5. The wetting and dispersing agent as claimed in claim 4 , wherein in step (2) 40 to 80 mol % of the hydroxyl groups of the reaction product obtained in step (1) are reacted with the at least one organic monoisocyanate.6. The wetting and dispersing agent as claimed in claim 1 , wherein the at least one polyhydroxymonocarboxylic acid (b) claim 1 , before the reaction according to step (1) claim 1 , is reacted with monomers selected from the group of lactones claim 1 , alkyl-substituted lactones claim 1 , and monohydroxymonocarboxylic acids with formation of ester bonds.7. The wetting and dispersing agent as claimed in claim 6 , wherein the molar ...

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Номер записи: 53
16-01-2014 дата публикации

METHODS OF COATING DRINKING WATER PIPELINES AND PIGMENT DISPERSIONS COMPRISING ALKYL PHENYL ESTER COMPOUNDS

Номер: US20140014220A1
Автор: Fores Stuart E., Robinson Ian
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

Methods of coating surfaces of a (e.g. drinking water) pipeline and pigments dispersions are described. The coating composition of the method and pigment dispersion comprise one or more alkyl phenyl ester compounds wherein the alkyl group comprises at least 8 carbon atoms. 1. A method of forming a coating on a surface of a pipeline the method comprising the steps of: a first part comprising at least one aliphatic polyisocyanate, and', 'a second part comprising at least one diamine;, 'a) providing a coating composition comprising'}wherein the coating composition comprises one or more alkyl phenyl ester compounds wherein the alkyl group comprises at least 8 carbon atoms;b) combining the first part and the second part to form a liquid mixture;c) applying the liquid mixture to internal surfaces of the pipeline; andd) allowing the mixture to set forming a cured coating.2. The method of wherein the alkyl phenyl ester compound has the general formula{'br': None, 'R-L-Ph'}wherein R is an alkyl group comprising at least 8 carbon atoms,L is a divalent linking group, andPh is phenyl.4. The method of wherein the alkyl group comprises at least 10 or 12 carbon atoms.5. The method of wherein the alkyl phenyl ester compound comprises a mixture of compounds having alkyl groups ranging from 12 to 20 carbon atoms.6. The method of wherein the coating composition is free of hydroxy-functional compounds.7. The method of wherein the coating composition further comprises a pigment.8. The method of wherein the pigment comprises titanium dioxide.9. The method of wherein the alkyl phenyl ester compounds are present in an amount ranging from 0.2 to 5 wt-% of the total coating composition.10. The method of wherein the mixture of alkyl phenyl ester compounds are present in an amount ranging from 5 wt-% to 20 wt-% of the total coating composition.11. The method of wherein the pipeline is a drinking water pipeline and the cured coating comes in contact with the drinking water.12. (canceled)13. The ...

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Номер записи: 54
23-01-2014 дата публикации

LOW-VOC POLYAMINO ALCOHOLS

Номер: US20140020601A1
Автор: Peera Asghar A., Tomlinson Ian A.
Принадлежит:

A method for adjusting pH in an aqueous coating composition having an initial pH less than 7 by adding to the aqueous coating composition a compound having formula (V) 2. The method of in which Rand Rindependently are methyl or ethyl; Ris hydrogen; Ris methyl or ethyl; and Ris hydrogen or —CHC(R)(NH)CHOH.3. The method of in which the amount of compound (V) is in the range from 10 wt % to 125 wt % of total weight of carboxylic acid groups in the coating composition.4. The method of in which the compound of formula (V) is added to the aqueous coating composition in an amount sufficient to raise pH of the aqueous coating composition to a range from 7.8 to 9.5. This invention relates generally to a polyamine compound useful in coating compositions and other applications for pH adjustment.Compounds with multiple amino and/or hydroxyl groups are known. For example, M. Senkus, (1946), 68, 10-12, discloses a compound having the formulabut this reference does not disclose or suggest a polyamino-polyalcohol compound as claimed in the present application.The problem addressed by this invention is to find new low VOC polyamine compounds useful in coating compositions and other applications for pH adjustment.The present invention is directed to a method for producing a polyamino-polyalcohol. The method comprises steps of: (a) combining an aminoalcohol of formula (I)with a nitro-diol of formula (II)wherein Ris hydrogen, hydroxyethyl or C-Calkyl; Rand Rindependently are hydrogen, methyl, ethyl, hydroxymethyl, or Rand Rcombine with a carbon to which they are attached to form a five-membered or six-membered saturated carbocyclic ring; Ris hydrogen or C-Calkyl; Ris methyl or ethyl; to produce a nitro amino diol; and (b) contacting said nitro amino diol with a reducing agent capable of reducing aliphatic nitro groups.The present invention is further directed to a compound having formula (III)wherein Rand Rindependently are hydrogen, methyl, ethyl, hydroxymethyl, or Rand Rcombine with ...

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Номер записи: 55
23-01-2014 дата публикации

HEPTYL ESTERS OF FURAN DICARBOXYLIC ACID AS SOFTENERS

Номер: US20140024754A1
Автор: Becker Hinnerk Gordon, Grass Michael, Huber Andre, WOELK-FAEHRMANN Michael
Принадлежит: Evonik Oxeno GmbH

The invention relates to the use of heptyl esters of furan dicarboxylic acid as softeners. 1. A heptyl ester of furandicarboxylic acid.2. The heptyl ester according to claim 1 , wherein the heptyl ester is a diheptyl ester.3. The heptyl ester according to claim 1 , wherein the heptyl ester satisfies at least one property selected from the group consisting of:{'sup': '3', 'a density of the heptyl ester at 20° C. is not more than 1.1 g/cm,'}an intrinsic viscosity of the heptyl ester at 25° C. is not more than 120 mPa*s, andwhen analyzed with a differential calorimeter, the heptyl ester has no melting signal at temperatures greater than 20° C.4. The heptyl ester according to claim 3 ,wherein the heptyl ester satisfies at least two of the properties.5. A composition claim 1 , comprising the heptyl ester according to .6. A plasticizer or plasticizer composition claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the heptyl ester according to .'}7. The plasticizer or plasticizer composition according to claim 6 , comprising:two isomeric diheptyl furan-2,5-dicarboxylates.8. The plasticizer or plasticizer composition according to claim 7 , the isomeric diheptyl furan-2 claim 7 ,5-dicarboxylates comprise isomeric heptyl groups.9. The plasticizer or plasticizer composition according to claim 7 , that none of the wherein no isomeric diheptyl furan-2 claim 7 ,5-dicarboxylate has a proportion of more than 99.9% by weight in an ester mixture.10. The plasticizer or plasticizer composition according to claim 8 , wherein at least one isomeric heptyl group is selected from the group consisting of n-heptyl claim 8 , 2-methylhexyl claim 8 , 3-methylhexyl claim 8 , 4-methylhexyl claim 8 , 5-methylhexyl claim 8 , 2 claim 8 ,2-dimethylpentyl claim 8 , 2 claim 8 ,3-dimethylpentyl claim 8 , 3 claim 8 ,3-dimethylpentyl claim 8 , 2 claim 8 ,4-dimethylpentyl claim 8 , 3-ethylpentyl claim 8 , 2 claim 8 ,2 claim 8 ,3-trimethylbutyl claim 8 , and 2-ethyl-3-methylbutyl.11. The ...

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Номер записи: 56
30-01-2014 дата публикации

AQUEOUS FLUOROPOLYMER DISPERSION

Номер: US20140031469A1
Автор: Hirao Takayuki, Iida Junya, Kato Taketo, SHIMONO Takeshi, Tanimoto Kenjiro, TSUDA Nobuhiko
Принадлежит: DAIKIN INDUSTRIES, LTD.

The present invention provides an aqueous fluoropolymer dispersion that shows favorable dispersion stability and is less likely to have a pH decrease even after storage for a long period of time. The present invention provides an aqueous fluoropolymer dispersion including: a fluoropolymer; a fluorine free surfactant; at least one organic electrolyte selected from the group consisting of hydroxy monocarboxylic acids, hydroxy dicarboxylic acids, tricarboxylic acids, and amino acids; and a fluorine-containing anionic surfactant containing not more than 7 carbon atoms. 1. An aqueous fluoropolymer dispersion comprising:a fluoropolymer;a fluorine free surfactant;at least one organic electrolyte selected from the group consisting of hydroxy monocarboxylic acids, hydroxy dicarboxylic acids, tricarboxylic acids, and amino acids; anda fluorine-containing anionic surfactant containing not more than 7 carbon atoms.2. The aqueous fluoropolymer dispersion according to claim 1 ,wherein the organic electrolyte is at least one selected from the group consisting of citric acid, isocitric acid, and lactic acid.3. The aqueous fluoropolymer dispersion according to claim 1 ,wherein the amount of the organic electrolyte is 0.1 to 100 mmol for 1 g of the fluoropolymer.4. The aqueous fluoropolymer dispersion according to claim 1 ,wherein the amount of the organic electrolyte is 0.1 to 10 mmol for 1 g of the fluoropolymer.5. The aqueous fluoropolymer dispersion according to claim 1 ,wherein the concentration of the fluorine-containing anionic surfactant is 0.001 to 2000 ppm based on the solid content mass of the fluoropolymer.6. The aqueous fluoropolymer dispersion according to claim 1 ,wherein the concentration of the fluorine-containing anionic surfactant is 0.001 to 50 ppm based on the solid content mass of the fluoropolymer.7. The aqueous fluoropolymer dispersion according to claim 1 ,wherein the fluoropolymer has a solid content concentration of 35 to 75% by mass.8. The aqueous ...

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Номер записи: 57
30-01-2014 дата публикации

Diamino alcohol and strong base neutralizers for low voc coating compositions

Номер: US20140031470A1
Автор: Anurima Singh, Asghar Peera, Esin Busche, Ian A. Tomlinson, John Quinn, Raymond Swedo
Принадлежит: Angus Chemical Co, Dow Global Technologies LLC

A coating composition comprising a binder, a carrier, a pigment, cations selected from the group consisting of alkali metal cations, ammonium cations, and mixtures thereof, and at least one diamino alcohol selected from the group consisting of compounds of Formula I and compounds of Formula II. The present invention also provides a method for reducing the volatile organic compound (VOC) content of a coating composition having a binder, a carrier, and a pigment, which comprises including in the coating composition the aforesaid A) cations and B) at least one diamino alcohol. The diamino alcohol may be of Formula I: wherein R 1 and R 2 are independently C 1 -C 10 alkyl, or R 1 and R 2 , together with the carbon to which they are attached, form a C 3 -C 12 cycloalkyl ring optionally substituted with C 1 -C 6 alkyl. For example, the compound of Formula I may be 2-(2-amino-2-methylpropylamino)-2-(hydroxymethyl)propane-1,3-diol. Alternatively, the diamino alcohol may be of Formula II: or salt thereof, wherein R 1 and R 2 are independently at each occurrence C 1 -C 6 alkyl; and R 3 is independently at each occurrence H or C 1 -C 6 alkyl. For example, the compound of Formula II may be 2,2′-((2-hydroxytrimethylene)diimino)bis(2-methyl-1-propanol).

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Номер записи: 58
06-02-2014 дата публикации

Metal-Oxide Nanofiller, Method for Synthesising Same, and Use Thereof in a Fluorocarbon-Resin Non-Stick Coating

Номер: US20140034651A1
Автор: Ameduri Bruno, Boutevin Bernard, Durand Nelly, Gantillon Barbara, Loubat Cedric, Perillon Jean-Luc
Принадлежит:

Provided is a metal-oxide nanofiller including at least two graft chains, at least one of the chains being hydrophilic and the other being a hydrophobic chain compatible with fluorinated polymers. The hydrophobic chain is an oligomer, the weight-average molar mass Mw of which is between 300 and 20,000 g/mol. Also provided is a non-stick coating comprising such a filler, as well as to a culinary article provided with such a coating. 1. A nanofiller of a metal-oxide comprising at least two graft chains , at least one of the chains being hydrophilic and the other being a hydrophobic chain compatible with fluorinated polymers , wherein the hydrophobic chain is an oligomer , the weight-average molar mass Mw of which is between 300 and 20.000 g/mol.2. The nanofiller according to claim 1 , wherein the hydrophobic chain is an oligomer claim 1 , the weight-average molar mass Mw of which is between 500 and 10.000 g/mol.3. The nanofiller according to claim 2 , wherein the hydrophobic chain is an oligomer claim 2 , the weight-average molar mass Mw of which is between 1000 and 5000 g/mol.4. The nanofiller according to claim 1 , wherein the metal oxide is selected among the group constituted of silica claim 1 , alumina claim 1 , cerium oxide claim 1 , zinc oxide claim 1 , vanadium oxide claim 1 , zirconium oxide claim 1 , and titanium dioxide.5. The nanofiller according to claim 4 , wherein the metal oxide is silica claim 4 , colloidal silica or pyrogenic silica.6. The nanofiller according to claim 1 , wherein the hydrophilic chain is a derivative of polyalkylene glycol modified by:either an alkoxysilane,or an acid or a phosphonic ester,or an acid or phosphinic ester,or a carboxylic acid.7. The nanofiller according to claim 6 , wherein the polyalkylene glycol derivative is a polyethylene-glycol (PEG) derivative or a polypropylene glycol (PPG) derivative.8. The nanofiller according to claim 6 , wherein the hydrophilic chain is a derivative of polyethylene glycol modified by an ...

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Номер записи: 59
06-02-2014 дата публикации

Synergistic Emulsion Polymer Formulation and Aqueous Coating/ Paint Compositions Involving the Same

Номер: US20140039101A1
Автор: Mitra Avishek, Rao Vattipalli Mohan, Tiwari Vibha
Принадлежит: ASIAN PAINTS LTD.

A synergistic emulsion polymer formulation adapted for facilitating achieving desired open time or wet edge time of any aqueous coating/paint composition on application to thus result in improved workability of the coating/paint composition. The synergistic emulsion polymer formulation and the coating/paint composition including the same comprises a latex polymer derived from copolymerization of mono-ethylenically unsaturated monomers. This in combination with select sorbitol ethoxylates esterified with fatty acids as an ingredient in the formulation/composition favors the slowing down of water evaporation from the composition considerably so that it remains amenable to touch up even after several minutes of application. 1. A synergistic emulsion formulation adapted for facilitating achieving desired open time or wet edge time of any aqueous coating/paint composition on application comprising a latex copolymer in combination with sorbitol ethoxylates esterified with fatty acids.2. The synergistic emulsion formulation according to claim 1 , wherein the sorbitol ethoxylates esterified with fatty acids is selected from a class of sorbitol ethoxylates esterified with fatty acids having the general formula claim 1 , CH(OH)(OCHCH)(RCOO) claim 1 , wherein b is an integer from 1 to 6 claim 1 , Ris a hydrocarbon group comprising a straight chain of alkyl groups having 6 to 22 carbon atoms and m is in the range of 4 to 60.3. The synergistic emulsion formulation according to claim 2 , wherein the number of oxyethylene groups (OCHCH) denoted by the value m is preferably in the range 40 to 60.4. The synergistic emulsion formulation according to claim 1 , wherein the sorbitol ethoxylates esterified with fatty acids are incorporated in the amounts of 0.1% to 10% in the formulation.5. The synergistic emulsion formulation according to claim 1 , wherein the latex copolymer is film forming claim 1 , and wherein the latex copolymer having a glass transition temperature in the range of ...

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Номер записи: 60
13-02-2014 дата публикации

Inert Substrate-Bonded Fluoroelastomer Components and Related Methods

Номер: US20140044974A1
Автор: Campbell Ronald R.
Принадлежит: Greene, Tweed of Delaware, Inc.

Included within the scope of the invention is an article of cured fluoroelastomer composition bonded to an inert substrate. The cured fluoroelastomer composition includes a fluoropolymer, a silica, and an acrylate compound. The fluoroelastomer composition is bonded to the inert substrate with a bind having a bond durability of at least about 1500 pounds load at 20° C. The inert substrate may be a metal substrate or a ketone-based polymer substrate. 1. An article comprising a cured fluoroelastomer composition bonded to an inert substrate , wherein the cured fluoroelastomer composition comprises a fluoropolymer , a silica , and an acrylate compound.2. The article of claim 1 , wherein the bond has a bond durability of at least about 1500 pounds load at 20° C.3. The article of claim 1 , wherein the fluoroelastomer is a perfluoroelastomer.4. The article of claim 1 , wherein the inert substrate is a metal substrate.5. (canceled)6. The article of claim 1 , wherein the inert substrate is chosen from a titanium alloy claim 1 , a copper alloy claim 1 , a beryllium copper alloy claim 1 , a nickel silver alloy claim 1 , a nickel titanium alloy claim 1 , a chromium alloy claim 1 , and steel.7. (canceled)8. The article of claim 1 , wherein the fluoropolymer comprises a monomer chosen from a fluorine-containing ethylenically unsaturated monomer claim 1 , tetrafluoroethylene claim 1 , a perfluorinated olefin claim 1 , hexafluoropropylene claim 1 , and perfluoro (ethyl vinyl ether).911-. (canceled)12. The article of claim 1 , wherein the acrylate compound is a metal acrylate.13. The article of claim 1 , wherein the acrylate compound is zinc diacrylate.14. The article of claim 1 , wherein the acrylate compound is chosen from a methacrylate compound claim 1 , a dimethacrylate compound claim 1 , zinc dimethacrylate claim 1 , and copper diacrylate.15. The article of claim 1 , wherein the fluoroelastomer composition further comprises an additive chosen from a filler claim 1 , a ...

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Номер записи: 61
20-02-2014 дата публикации

BASE COATS FOR OVERBAKED MULTI-LAYER COATINGS

Номер: US20140050927A1
Автор: Steinmetz Bernhard
Принадлежит: BASF COATINGS GMBH

A thermally curable basecoat material comprising at least one polyurethane resin as binder, at least one pigment, 30% to 70% by weight of water, based on the total weight of the basecoat material, and 0.04% to 2.3% by weight, based on the total weight of the basecoat material, of at least one disulfonic acid compound of formula (I). The basecoat material is applied to an overbaked multicoat paint system, and has outstanding adhesion properties. 2. The basecoat material of claim 1 , wherein the compound of formula (I) is present in an amount of 0.04% to 1.60% by weight claim 1 , based on the total weight of the basecoat material.3. The basecoat material of claim 1 , wherein the compound of formula (I) is present in an amount of 0.04% to 1.20% by weight claim 1 , based on the total weight of the basecoat material.4. The basecoat material of claim 1 , wherein at least one of the radicals Ror Ris an alkyl radical.5. The basecoat material of claim 1 , wherein precisely one of radical Ror R claim 1 , is an alkyl radical.6. A process for preparing the basecoat material of claim 1 , which comprises mixing and optionally homogenizing its constituents.7. A multicoat paint system comprising at least one basecoat and at least one clearcoat claim 1 , the at least one basecoat comprising the basecoat material of .8. A dual paint system comprising the multicoat paint system of and also at least one additional basecoat of the basecoat material of and at least one additional clearcoat claim 1 , which are disposed above the multicoat paint system of .9. A method of coating a substrate with a multicoat paint system claim 7 , comprising applying to a substrate the multicoat paint system of .10. A method for producing a multicoat paint system of claim 7 , which comprises successively applying at least one basecoat material of and at least one clearcoat material.11. A method of coating a substrate with a dual paint system claim 7 , comprising applying to a substrate the multicoat paint ...

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Номер записи: 62
20-02-2014 дата публикации

SURFACE-TREATED METAL MATERIAL AND AQUEOUS METAL SURFACE-TREATMENT AGENT

Номер: US20140050939A1
Автор: Kaneto Taihei, KIKUCHI Ikuo, Kimata Yoshio, Morishita Atsushi, Nomura Shinji, Takahashi Akira, Yamaguchi Hidehiro
Принадлежит:

A surface-treated metal material of the present invention has a composite film on the surface of a metal material. The composite film includes an organic silicon compound (W) having cyclic siloxane bonds, at least one metal compound (X) selected from a group consisting of a titanium compound and a zirconium compound, a phosphate compound (Y) and a fluorine compound (Z). In each of the components of the composite film, the ratio of X/Wis from 0.06 to 0.16, where Wis a solid mass of Si derived from the organic silicon compound (W) and Xis a solid mass of at least one metal component selected from a group consisting of Ti and Zr included in the metal compound (X); the ratio of Y/Wis from 0.15 to 0.31, where Wis the solid mass of Si and Yis a solid mass of P derived from the phosphate compound (Y); and the ratio of Z/Wis from 0.08 to 0.50, where Wis the solid mass of Si and Zis a solid mass of F derived from the fluorine compound (Z). 1. A surface-treated metal material comprising:a composite film on a surface of a metal material, the composite film comprisingas a film forming component, (i) an organic silicon compound (W) having cyclic siloxane bonds in the structure thereof; andas inhibitor components, (ii) at least one metal compound (X) selected from a group consisting of a titanium compound and a zirconium compound, (iii) a phosphate compound (Y), and (iv) a fluorine compound (Z);wherein each of the components of the composite film has:{'sub': S', 'S', 'S', 'S, 'a ratio of X/Wfrom 0.06 to 0.16, where Wis a solid mass of Si derived from the organic silicon compound (W) and Xis a solid mass of at least one metal component selected from a group consisting of Ti and Zr included in the metal compound (X);'}{'sub': S', 'S', 'S', 'S, 'a ratio of Y/Wfrom 0.15 to 0.31, where Wis the solid mass of Si derived from the organic silicon compound (W) and Yis a solid mass of P derived from the phosphate compound (Y); and'}{'sub': S', 'S', 'S', 'S, 'a ratio of Z/Wfrom 0.08 to 0.50, ...

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Номер записи: 63
20-02-2014 дата публикации

INSULATING SILICONE RUBBER COMPOSITION

Номер: US20140051788A1
Автор: Suzuki Satoshi
Принадлежит: TOKAI RUBBER INDUSTRIES, LTD.

An insulating silicone rubber composition superior in reliability is provided that has excellent antistatic property while being free from bleeding, blooming, and discoloration. The insulating silicone rubber contains silicone rubber, ionic liquid having an alkoxysilyl group, and preferably a crosslinking agent. The content of the ionic liquid is preferably within a range from 0.001 to 5 parts by mass with respect to 100 parts by mass of the total amount of the silicone rubber and the crosslinking agent. 15-. (canceled)6. An insulating silicone rubber composition , comprising:a silicone rubber; andan ionic liquid having an alkoxysilyl group.7. The insulating silicone rubber composition according to having a volume resistivity of 1×10Ω·cm or more.8. The insulating silicone rubber composition according to claim 6 , {'br': None, 'sub': 1', '2', '3', '3, 'sup': '+', 'R—N—R—Si(OR)\u2003\u2003(1),where, 'Wherein a cationic component of the ionic liquid is represented by the following formula (1);'}{'sub': '1', 'Ris a cyclic organic group or a linear organic group;'}{'sub': 2', '2', 'n, 'Rcontains at least (CH), wherein n represents an integer number; and'}{'sub': '3', 'Ris an alkyl group.'}9. The insulating silicone rubber composition according to claim 7 , {'br': None, 'sub': 1', '2', '3', '3, 'sup': '+', 'R—N—R—Si(OR)\u2003\u2003(1),where, 'Wherein a cationic component of the ionic liquid is represented by the following formula (1);'}{'sub': '1', 'Ris a cyclic organic group or a linear organic group;'}{'sub': 2', '2', 'n, 'Rcontains at least (CH), wherein n represents an integer number; and'}{'sub': '3', 'Ris an alkyl group.'}10. The insulating silicone rubber composition according to further comprising a crosslinking agent.11. The insulating silicone rubber composition according to further comprising a crosslinking agent.12. The insulating silicone rubber composition according to further comprising a crosslinking agent.13. The insulating silicone rubber composition ...

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Номер записи: 64
27-02-2014 дата публикации

CURABLE RESIN COMPOSITION, OPTICAL MEMBER SET, METHOD OF PRODUCING THE SAME, AND SOLID STATE IMAGING DEVICE USING THE SAME

Номер: US20140054738A1
Автор: Kubota Makoto, Shimada Kazuto, YAMAMOTO Keiji
Принадлежит: FUJIFILM Corporation

A curable resin composition, for forming a first optical member of an optical member set, the optical member having the first optical member and a second optical member covered with the first optical member, the first optical member being formed by curing a siloxane resin, comprising: a siloxane resin, a surfactant, and a solvent, the siloxane resin and the surfactant being contained in the solvent, the surfactant having a polyoxyalkylene structure, the siloxane resin being defined in 65% by mass to 100% by mass thereof having a particular polysilsesquioxane structure. 1. A curable resin composition , for forming a first optical member of an optical member set , the optical member set having the first optical member and a second optical member covered with the first optical member set , the first optical member being formed by curing a siloxane resin , the curable resin composition comprising:a siloxane resin, a surfactant, and a solvent,the siloxane resin and the surfactant being contained in the solvent,the surfactant having a polyoxyalkylene structure, and {'br': None, 'sup': '1', 'sub': 3/2', 'n, '—(RSiO)—\u2003\u2003Formula (1)'}, 'the siloxane resin being defined in 65% by mass to 100% by mass thereof having a polysilsesquioxane structure represented by formula (1){'sup': '1', 'wherein Rrepresents an alkyl group having 1 to 3 carbon atom(s); and n represents an integer of 20 to 1,000.'}2. The curable resin composition according to claim 1 ,wherein the content of the surfactant is within a range from 1 part by mass to 30 parts by mass, relative to 100 parts by mass of the siloxane resin.3. The curable resin composition according to claim 1 , wherein the solvent is an organic solvent.5. An optical member set claim 1 , comprising:a first optical member and a second optical member covered with the first optical member, the first optical member formed by curing a siloxane resin;the siloxane resin being defined in a proportion from 65% by mass to 100% by mass ...

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Номер записи: 65
06-03-2014 дата публикации

COATING LAYER AND METHOD FOR FORMING COATING LAYER

Номер: US20140065396A1
Автор: Onai Hiroyuki
Принадлежит: THREEBOND CO., LTD.

The coating layer has excellent water repellency and satisfactory gloss to a base material and provides a method for forming a coating layer in which the agents used have, for example, excellent storage stability and dispersibility. The coating layer has a layer (I) formed by curing a film-forming agent containing predetermined amounts of a polyorganosiloxane having at least one hydrolyzable functional group in its molecule, a curing catalyst, and an organic solvent including a saturated hydrocarbon solvent and an aromatic hydrocarbon solvent each having 8 to 15 carbon atoms at a predetermined ratio and a layer (II) formed by solidifying a finish treatment agent containing predetermined amounts of a polyorganosiloxane having at least one pendant amino group, a polyorganosiloxane having two or more terminal amino groups, a silicone resin emulsion emulsified with a nonionic or anionic surfactant, a hydrophilic group-containing organic solvent, and water. 2. The coating layer according to claim 1 , wherein the layer (I) is disposed on the base material claim 1 , and the layer (II) is disposed on the layer (I).3. The coating layer according to claim 1 , wherein the layer (I) has a thickness of 0.1 to 0.5 μm claim 1 , and the layer (II) has a thickness of 0.1 to 0.5 μm.4. The coating layer according to claim 1 , wherein the saturated hydrocarbon solvent having 8 to 15 carbon atoms in the component (a-3) is an isoparaffin solvent.5. The coating layer according to claim 1 , wherein the component (b-4) is an alcohol.6. The coating layer according to claim 1 , wherein the component (a-1) is a polydimethylsiloxane having hydrolyzable functional groups at both ends of the molecular chain.7. The coating layer according to claim 1 , wherein the base material is the exterior of a vehicle.9. The method for forming a coating layer according to claim 8 , wherein the film-forming agent (A) in step (a) is applied with a dry cloth claim 8 , and the finish treatment agent (B) in step (b ...

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Номер записи: 66
06-03-2014 дата публикации

SILYLATED AMINO RESINS

Номер: US20140066552A1
Автор: Breiner Thomas, HAAF Christina, Noller Bastian, RÖSCH Christine, SCHWALM Reinhold, Stumbe Jean-Francois
Принадлежит: BASF SE

The present invention relates to silylated amino resins, to processes for preparing them, to their use, and to coating compositions comprising them. 114-. (canceled)16. The coating composition of claim 15 , further comprising a binder.17. The coating composition of claim 15 , further comprising a strong acid or a weak acid.18. The coating composition of claim 15 , further comprising a solvent.19. The coating composition of claim 15 , further comprising a pigment.20. The coating composition of claim 15 , further comprising at least one binder selected from the group consisting of a polyetherol claim 15 , a polyesterol claim 15 , a polyacrylate polyol claim 15 , a polycarbonate polyol claim 15 , an alkyd resin claim 15 , and an epoxy resin.21. A method for coating a substrate claim 15 , the method comprising applying the coating composition of to the substrate.22. The method of claim 21 , wherein the substrate comprises a material selected from the group consisting of wood claim 21 , paper claim 21 , a textile claim 21 , a leather claim 21 , a nonwoven claim 21 , a plastic surface claim 21 , a glass claim 21 , a ceramic claim 21 , a mineral building material claim 21 , an uncoated metal claim 21 , and a coated metal.23. The method of claim 21 , wherein the coating composition is at least one member selected from the group consisting of a primer claim 21 , a surface claim 21 , a pigmented topcoat claim 21 , a clearcoat claim 21 , an industrial coating claim 21 , a wood coating claim 21 , an automotive coating claim 21 , an OEM coating claim 21 , and a decorative coating. The present invention relates to silylated amino resins, to processes for preparing them, to their use, and to coating compositions comprising them.Pigmented paints and transparent coating materials comprising or based on amino resins have been known for a number of decades.Römpp's Chemielexikon describes amino resins as “usually relatively low molecular mass polycondensation products formed from ...

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Номер записи: 67
13-03-2014 дата публикации

AQUEOUS SILANE SYSTEMS BASED ON TRIS(ALKOXYSILYLALKYL)AMINES AND THE USE THEREOF

Номер: US20140069293A1
Автор: Albert Philipp, Just Eckhard
Принадлежит: EVONIK DEGUSSA GmbH

The invention relates to an aqueous composition based on tris-silylated amino-functional silicon compounds, which is substantially free of organic solvents and which substantially does not release any alcohol even during the cross-linking process, and to method for the production thereof, and to the use thereof, for example for the hydrophobization of metal, glass or mineral surfaces, such as concrete and bricks, as adhesion promoter or for rock consolidation, among other things. 3. The composition of claim 2 , wherein: {'br': None, 'sup': 1', '11', '11', '1, 'sub': 3-Δ', 'Δ', 'Δ', '3-Δ, '(OR)(R)Si-A-Si(R)(OR)\u2003\u2003(II)'}, 'A is derived from formula (II)'}wherein {'br': None, 'sub': 2', 'f', 'g', '2', 'f*', 'g*, '—Z*—[NH(CH)]NH[(CH)NH]—Z*—\u2003\u2003(III)'}, 'A is a bivalent amino-functional group of the formula (III)'}Z* is independently a bivalent alkylene radical, and f, f*, g or g* are the same or different,f and/or =1, 2 or 3,g and/or g*=0, 1 or 2, and{'sup': '11', 'claim-text': {'br': None, 'sup': 12', '1, 'sub': Ω', '3-Ω', '3, 'N[ZSi(R)(OR)]\u2003\u2003(IX)'}, 'Z is derived from formula (IX)'}, 'Ris a linear, branched and/or cyclic alkyl radical having 1 to 24 carbon atoms or an aryl radical;'}whereinZ is independently a bivalent alkylene radical, and{'sup': '12', 'Ris a linear, branched and/or cyclic alkyl radical having 1 to 24 carbon atoms or an aryl radical, and,'} {'br': None, 'sup': 3', '1, 'sub': x', '3-x, 'B—Si(R)(OR)\u2003\u2003(IV)'}, 'B is derived from formula (IV)'}, 'Ω is, independently, 0 or 1;'}whereinx=0 or 1,{'sup': '3', 'Ris a linear, branched or cyclic alkyl radical having 1 to 24 carbon atoms and/or an aryl radical, and'} {'br': None, 'sup': '10', 'sub': h*', '(2-h*)', '2', 'h', 'j', '2', 'l', 'n', '2', 'k, 'RNH[(CH)(NH)][(CH)(NH)]—(CH)—\u2003\u2003(Va)'}, 'B is one of the following amino-functional groups of formula (Va) or (Vb)'}wherein0≦h≦6,h*=0, 1 or 2,j=0, 1 or 2,0≦1≦6;n=0, 1 or 2,0≦k≦6, and{'sup': '10', 'claim-text': {'br': ...

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Номер записи: 68
13-03-2014 дата публикации

COMPOSITIONS COMPRISING A FLUOROSURFACTANT AND A FLUORO-FREE HYDROTROPE

Номер: US20140073707A1
Автор: Calvarese Thomas G., Gonzalez Yamaira, Qiu Weiming, Raghavanpillai Anilkumar
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

Compositions comprising a fluorosurtactant and a fluoro-free hydrotrope are disclosed. The fluoro-free hydrotropes are cationic aromatic compounds, anionic aromatic compounds, or water soluble azo derivatives. 1. A composition comprising a fluorosurfactant and a fluoro-free hydrotrope , wherein the weight ratio of the fluorosurfactant to the fluoro-free hydrotrope is in the range of 1:10 to 10:1.2. The composition of claim 1 , wherein the concentration of the fluorosurfactant is 0.00005-2 wt %.4. The composition of claim 1 , wherein the fluorosurfactant is an anionic claim 1 , a cationic claim 1 , an amphoteric claim 1 , or a nonionic fluorosurfactant.5. A method of altering the surface behavior of an agent claim 1 , comprising adding to the agent a composition comprising a fluorosurfactant and a fluoro-free hydrotrope claim 1 , wherein the weight ratio of the fluorosurfactant to the fluoro-free hydrotrope is in the range of 1:10 to 10:1.6. The composition of claim 5 , wherein the concentration of the fluorosurfactant is 0.00005-2 wt %.8. The method of claim 5 , wherein the fluorosurfactant is an anionic claim 5 , a cationic claim 5 , an amphoteric claim 5 , or a nonionic fluorosurfactant.9. The method of claim 5 , wherein the agent is selected from the group consisting of coating compositions claim 5 , lattices claim 5 , polymers claim 5 , floor finishes claim 5 , inks claim 5 , emulsifying agents claim 5 , foaming agents claim 5 , release agents claim 5 , repellency agents claim 5 , flow modifiers claim 5 , film evaporation inhibitors claim 5 , wetting agents claim 5 , leveling agents claim 5 , penetrating agents claim 5 , cleaners claim 5 , grinding agents claim 5 , electroplating agents claim 5 , corrosion inhibitors claim 5 , etchant solutions claim 5 , soldering agents claim 5 , dispersion aids claim 5 , antimicrobial agents claim 5 , pulping aids claim 5 , rinsing aids claim 5 , polishing agents claim 5 , personal care compositions claim 5 , drying agents ...

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Номер записи: 69
20-03-2014 дата публикации

FLUID APPLIED SILICONE AIR & WATER BARRIER SYSTEM AND PROCESS THEREOF

Номер: US20140079887A1
Автор: Dorman Gene E.
Принадлежит:

There is provided herein a one-part room temperature vulcanizing (RTV) silicone based air and water barrier composition comprising silanol-terminated diorganopolysiloxane polymer; fumed silica; stearic acid treated ground calcium carbonate extending filler; polyalkoxy crosslinking agent; metal chelate condensation cure catalyst; and, an adhesion promoter. There is also provided a wall assembly comprising said composition. 120-. (canceled)22. The silicone coating composition of claim 21 , wherein the composition is effective to function simultaneously as a sealant claim 21 , an adhesive claim 21 , a water barrier and an air barrier.23. The composition of further comprising up to about 60 wt % of a hydrocarbon processing aid.25. The composition of wherein p is from 10 to about 4000.26. The composition of where in the formula for the polyalkoxy silane crosslinking agent a is zero claim 21 , 1 claim 21 , or 2.27. The composition of wherein the polyalkoxy silane crosslinking agent is selected from the group consisting of methyltrimethoxysilane claim 21 , vinyltrimethoxysilane claim 21 , tetramethoxysilane claim 21 , methyltriethoxysilane claim 21 , vinyltrimethoxysilane and tetraethoxysilane.28. The composition of wherein Me is titanium.29. The composition of wherein Ris propylene claim 21 , Ris hydrogen claim 21 , Rand Rare methyl and Ris ethyl.31. The composition of wherein the adhesion promoter is selected from the group consisting of 1 claim 21 ,3 claim 21 ,5-tristrimethoxysilylpropylisocyanurate claim 21 , bis-1 claim 21 ,3-trimethoxysilylpropylisocyanurate claim 21 , 1 claim 21 ,3 claim 21 ,5-tristrimethoxysilylethylisocyanurate claim 21 , 1 claim 21 ,3 claim 21 ,5-trismethyldimethoxysilylpropylisocyanurate claim 21 , 1 claim 21 ,3 claim 21 ,5-trismethyldiethoxysilylpropylisocyanurate claim 21 , n-2-aminoethyl-3-aminopropyltriethoxysilane claim 21 , methacryloxypropyltrimethoxysilane claim 21 , methylaminopropyltrimethoxysilane claim 21 , γ- ...

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Номер записи: 70
20-03-2014 дата публикации

Fast Drying Aqueous Amine Free Coating Composition(s)

Номер: US20140079888A1
Автор: Greer Robert W., Newell Kevin, Teng George Ganghua
Принадлежит:

Coating compositions and methods providing a high build, fast drying, fast hardening non-amine containing aqueous latex binders are provided, wherein the coating composition is applied to a substrate at a wet film thickness to about 15 mils that ensure drying times of less than 10 minutes. The binder requires the use of at least one specific coalescent solvent with both anionic and non-anionic surfactants. 1. A high build , fast drying and fast hardening amine free aqueous coating composition comprising: (a) an amine free latex binder comprising: (i) 35 to 65% by weight , based on said latex binder weight , of at least one hard monomer; (ii) 25 to 55% by weight , based on said latex binder weight , of at least one soft monomer; and (iii) 0.5 to 15% by weight , based on said latex binder weight , of at least one acid functional monomer; (iv) 0.1% to 4% by weight , based on said latex binder weight , of at least one anionic surfactant; wherein said latex binder has a glass transition temperature less than 45 degrees Centigrade , and wherein said latex binder is also amine free and has an average particle size diameter of between 210 nanometers to 290 nanometers and (b) at least one coalescing solvent that is 2 ,2 ,4-trimethyl-1 ,3-pentanediol monoisobutyrate.2. The aqueous amine free coating composition of claim 1 , wherein said composition exhibits a drying time of less than 10 minutes as measured by ASTM test method D711-2010.3. The aqueous amine free coating composition of claim 1 , wherein said latex binder can exhibit both a high and low carboxyl functional group having a theoretical acid number of about 17 and 5 claim 1 , respectively claim 1 , and wherein the carboxyl functional monomer weight percentage based on the total weight of said latex binder is between 2.5 and 3.1 weight percent and between 0.60 and 0.70 weight percent respectively.4. The composition of claim 1 , wherein said glass transition temperature of the latex binder is between about 23 degrees ...

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Номер записи: 71
20-03-2014 дата публикации

SURFACTANT COMPOSITIONS AND USE FOR AQUEOUS COMPOSITIONS

Номер: US20140080745A1
Автор: Graf Irina V., Krasovskiy Arkady L.
Принадлежит:

A surfactant composition selected from the group consisting of; (RO)CHCH(OCHCH)OHCH(OR) and mixtures thereof; wherein at least one of R1 and R2 are secondary alkyl groups including from 3 to 9 Carbon atoms; an aqueous coating composition including an aqueous polymeric dispersion; and certain other compositions including the surfactant composition are provided. Also provided is a method for forming a coating. 1. A surfactant composition selected from the group consisting of: (RO)CHCH(OCHCH)OHCH(OR) and mixtures thereof; wherein at least one of R1 and R2 are secondary alkyl groups comprising from 3 to 9 Carbon atoms.2. An aqueous coating composition comprising an aqueous polymeric dispersion and from 0.1% to 40% by weight claim 1 , based on the weight of said polymeric dispersion solids claim 1 , said surfactant composition of .3. The aqueous coating composition of wherein said aqueous polymeric dispersion is selected from the group consisting of: aqueous dispersions of epoxies claim 2 , urethanes claim 2 , acrylic polyols claim 2 , polyesters claim 2 , and hybrids and mixtures of these; and addition polymerized emulsion polymers.4. A method for forming a coating comprising{'claim-ref': {'@idref': 'CLM-00002', 'claim 2'}, '(a) forming said aqueous coating composition of ;'}(b) applying said aqueous coating composition to a substrate; and(c) drying, or allowing to dry, said applied aqueous coating composition.5. A composition comprising from 0.1% to 40% by weight claim 2 , based on the weight of said composition claim 2 , a surfactant selected from the group consisting of: (RO)CHCH(OCHCH)OHCH(OR) and mixtures thereof; wherein at least one of R1 and R2 are secondary alkyl groups including from 3 to 9 Carbon atoms; said composition being selected from the group consisting of metal working fluids claim 2 , agricultural formulations claim 2 , oil and gas recovery formulations claim 2 , detergents claim 2 , and emulsifiers. This invention relates to surfactants for aqueous ...

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Номер записи: 72
20-03-2014 дата публикации

POLY-ROTAXANE COMPOUND, PHOTOCURABLE COATING COMPOSITION, AND COATING FILM

Номер: US20140080936A1
Автор: Chang Yeong-Rae, KIM Heon, Kim Hye-Min
Принадлежит: LG CHEM, LTD.

The present invention relates to a novel polyrotaxane compound having a specific chemical structure, a photocurable coating composition that may provide a coating material having excellent mechanical properties such as scratch resistance, chemical resistance, abrasion resistance, and the like, and excellent self-healing capability, and a coating film obtained from the photocurable coating composition. 1. A polyrotaxane compound comprising: a macrocycle to which a lactone-based compound is bonded , wherein a (meth)acrylate-based compound is introduced at the end of the lactone-based compound at a ratio of 40 mol % to 70 mol %; a linear molecule penetrating the macrocycle; and blocking groups arranged at both ends of the linear molecule and preventing the macrocycle from escaping.2. The polyrotaxane compound according to claim 1 ,wherein the ratio of the (meth)acrylate-based compound introduced at the end of the lactone-based compound is 45 mol % to 65 mol %.3. The polyrotaxane compound according to claim 1 ,wherein the macrocycle includes at least one selected from the group consisting of α-cyclodextrin, β-cyclodextrin, and γ-cyclodextrin.4. The polyrotaxane compound according to claim 1 ,wherein the lactone-based compound is bonded to the macrocycle by a direct bond or a C1-10 linear or branched oxyalkylene group.6. The polyrotaxane compound according to claim 1 ,wherein the (meth)acrylate-based compound is bonded to the residue of the lactone-based compound through a direct bond, a urethane bond, an ether bond, a thioester bond, or an ester bond.8. The polyrotaxane compound according to claim 1 ,wherein the linear molecule is a polyoxyalkylene-based compound or a polylactone-based compound.9. The polyrotaxane compound according to claim 1 ,wherein the linear molecule has a weight average molecular weight of 1000 to 50,000.10. The polyrotaxane compound according to claim 1 ,wherein the blocking group includes at least one functional group selected from the group ...

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Номер записи: 73
27-03-2014 дата публикации

Compositions Comprising Siloxane Polymer

Номер: US20140086857A1
Автор: Blizzard John D.
Принадлежит: QUADSIL, INC.

Compositions comprising siloxane polymers are disclosed. The compositions are useful as thixotropic bases for a variety of components, such as antimicrobial agents, sterilants, medicaments, antibiotics, analgesics, essential oils, preservatives, colorants, fragrances, and the like. Methods for preparing the compositions are also disclosed. 1. A composition , comprising: [ i. organic compounds;', 'ii. compounds containing a silicon atom;', 'iii. mixtures of organic compounds;', 'iv. mixtures of compounds containing a silicon atom; and', 'v. mixtures of organic compounds and compounds containing a silicon atom;, 'a. a first solvent selected from the group consisting of, [ [{'sub': 3', '2', 'a', 'b', '3, '(a) RSiO(R′SiO)(R″HSiO)SiR;'}, {'sub': 2', '2', 'c', '2, '(b) HRSiO(R′SiO)SiRH; and'}, {'sub': 2', '2', 'a', 'b', '2, '(c) HRSiO(R′SiO)(R″HSiO)SiRH;'}, 'wherein:', {'sub': 1', '6, 'R, R′, R″ are, each independently, C-Calkyl;'}, 'a is about 0 to about 250;', 'b is about 1 to about 250; and', 'c is about 0 to about 250; and, 'i. an hydridopolysiloxane selected from the group consisting of, [{'br': None, 'sub': 2', '2', 'x', '2, 'CH═CH(CH)CH═CH'}, 'wherein:', 'x is about 1 to about 20;, 'ii. an α,ω-diene having the general formula], 'b. a siloxane copolymer comprising a reaction product of], 'A. a siloxane gel comprising a. organic compounds;', 'b. compounds containing a silicon atom;', 'c. mixtures of organic compounds;', 'd. mixtures of compounds containing a silicon atom; and', 'e. mixtures of organic compounds and compounds containing a silicon atom;, 'B. a first additional solvent selected from the group consisting of a. organic compounds;', 'b. compounds containing a silicon atom;', 'c. mixtures of organic compounds;', 'd. mixtures of compounds containing a silicon atom; and', 'e. mixtures of organic compounds and compounds containing a silicon atom., 'C. a second additional solvent selected from the group consisting of2. A composition of claim 1 , further ...

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Номер записи: 74
27-03-2014 дата публикации

SUSTAINABLE POLY(VINYL CHLORIDE) MIXTURES FOR FLOORING PRODUCTS

Номер: US20140087081A1
Автор: Horton Stephen D.
Принадлежит: POLYONE CORPORATION

A mixture of poly(vinyl chloride) and epoxidized methyl soyate is disclosed. The epoxidized methyl soyate as a plasticizer replaces butyl benzyl phthalate which is conventionally used for the manufacture of multi-layer laminate sheet flooring or single layer tile flooring. The epoxidized methyl soyate, a bio-plasticizer, unexpectedly is a “drop-in” replacement for the butyl benzyl phthalate, both in terms of processing and performance. Also poly(vinyl chloride)-epoxidized methyl soyate mixtures have much better heat stability than poly(vinyl chloride)-butyl benzyl phthalate mixtures. 1. (canceled)2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. (canceled)7. (canceled)8. (canceled)9. (canceled)10. (canceled)11. (canceled)12. (canceled)13. (canceled)14. (canceled)15. (canceled)16. (canceled)17. (canceled)18. (canceled)19. A method of making flooring , comprising the steps of:(a) mixing polyvinyl chloride resin and an effective amount of epoxidized methyl soyate to provide gelation of the mixture substantially as fast as butyl benzyl phthalate provides gelation of a mixture of the polyvinyl chloride resin and the butyl benzyl phthalate,(b) applying to a substrate a mixture of step (a) in the form of a plastisol at a temperature to induce gelation of the plastisol and(c) heating the plastisol and the substrate to fuse the plastisol into a solid layer affixed to the substrate.20. The method of claim 19 , further comprising the step of:(d) applying at least one additional layer on the solid layer.21. (canceled)22. The method of claim 19 , wherein the effective amount epoxidized methyl soyate is enough to provide both gelation and fusion of the mixture substantially as fast as butyl benzyl phthalate provides both gelation and fusion of the mixture of polyvinyl chloride resin and the butyl benzyl phthalate.23. The method of claim 19 , wherein the mixture is a plastisol and the effective amount ranges from about 15 to about 40 weight percent of the plastisol.24. The ...

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Номер записи: 75
27-03-2014 дата публикации

CARBON BLACK COMPOSITION, CARBON BLACK-CONTAINING COATING FILM, AND MAGNETIC RECORDING MEDIUM COMPRISING THE SAME

Номер: US20140087212A1
Автор: Imai Takashi, OMURA Kazufumi
Принадлежит: FUJIFILM Corporation

The carbon black composition includes carbon black and an amine compound denoted by formula (1) in a solvent: 2. The carbon black composition according to claim 1 , wherein claim 1 , in formula (1) claim 1 , each of W and Z independently denote a substituent that comprises at least one carbon atom and binds claim 1 , through the carbon atom claim 1 , to a carbon atom to which the substituent substitutes.3. The carbon black composition according to claim 1 , wherein claim 1 , in formula (1) claim 1 , each of U claim 1 , V claim 1 , X claim 1 , Y claim 1 , W and Z independently denotes an alkyl group.4. The carbon black composition according to claim 1 , wherein claim 1 , in formula (1) claim 1 , n denotes 2.5. The carbon black composition according to claim 1 , wherein claim 1 , in formula (1) claim 1 , each of U claim 1 , V claim 1 , X claim 1 , Y claim 1 , W and Z independently denotes an alkyl group claim 1 , and n denotes 2.6. The carbon black composition according to claim 1 , which further comprises a resin.7. The carbon black composition according to claim 6 , wherein the resin comprises a resin selected from the group consisting of polyurethane and a vinyl copolymer.8. The carbon black composition according to claim 5 , wherein the solvent comprises a ketone solvent.9. The carbon black composition according to claim 1 , wherein claim 1 , in formula (1) claim 1 , all of U claim 1 , V claim 1 , X claim 1 , Y claim 1 , W and Z denote a methyl group.10. The carbon black composition according to claim 1 , wherein claim 1 , in formula (1) claim 1 , all of U claim 1 , V claim 1 , X claim 1 , Y claim 1 , W and Z denote a methyl group claim 1 , and n denotes 2.11. The carbon black composition according to claim 10 , which further comprises a resin.12. The carbon black composition according to claim 11 , wherein the resin comprises a resin selected from the group consisting of polyurethane and a vinyl copolymer.13. The carbon black composition according to claim 10 , ...

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Номер записи: 76
27-03-2014 дата публикации

PLASTISOL COMPOSITIONS INCLUDING ORGANOSILICON COMPOUND(S)

Номер: US20140087612A1
Автор: Grindle Ronny, Hart George
Принадлежит:

Plastisol compositions are provided including a polymeric resin in the form of particulates dispersed within a plasticizer and one or more hydrolyzable organosilicon compounds. A suitable solvent system can be utilized in the plastisol compositions. Also provided are inorganic fibers, and particularly reinforcing scrims, that are at least partially coated with a plastisol composition including one or more hydrolyzable organosilicon compounds. Cementitious boards reinforced with plastisol coated inorganic fibers, such as mesh scrims, are also provided. 1. A plastisol composition , comprising:(i) a plasticizer;(ii) a polymeric resin provided in the form of particulates and dispersed within said plasticizer; and(iii) one or more hydrolyzable organosilicon compounds (“HOC”).2. The composition according to claim 1 , wherein the one or more HOC comprises an organo-functional silane claim 1 , organo-functional siloxane claim 1 , organo-functional polysiloxane claim 1 , or combinations thereof.3. The composition according to claim 2 , wherein the one or more HOC comprises amine functionality.4. The composition according to claim 2 , wherein the one or more HOC comprises epoxide functionality.5. The composition according to claim 2 , wherein the one or more HOC comprises at least one functionality selected from the group consisting of amine claim 2 , epoxide claim 2 , vinyl claim 2 , acrylate claim 2 , ester claim 2 , ether claim 2 , acyl halide claim 2 , carboxylic acid claim 2 , peroxide claim 2 , carbonyl claim 2 , cyanate claim 2 , and nitrile.6. The composition according to claim 3 , wherein the one or more HOC includes an amine functional polysiloxane.7. The composition according to claim 6 , wherein the one or more HOC comprises a cross-linkable amine functional dialkylpolysiloxane.8. The composition according to claim 4 , wherein the one or more HOC comprises a residue of glycidol.9. The composition according to claim 8 , wherein the one or more HOC comprises 3- ...

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Номер записи: 77
03-04-2014 дата публикации

ULTRA CLEAR SCRATCH RESISTANT COATING AND LAMINATE

Номер: US20140093684A1
Автор: Noffke Daniel P., Oscar Dennis Jay, WASSERMAN Charles J.
Принадлежит: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC

An ultra-clear rub and scratch resistant aqueous based coating that provides barrier properties to film and is receptive to flexo, litho, and gravure printing inks includes polyurethane acrylic hybrid dispersion in combination with melamine formaldehyde resin and micronized wax. The coating composition can be formulated with little or no N-methylpyrrolidone. This coating can be applied to a wide variety of different polymers such as polyesters, metalized polyesters, polyamides, metalized polyamides, biaxially oriented polypropylene, and others. 1. A laminate comprising a polymeric film having a first surface coated with an aqueous based coating said coating comprises polyurethane acrylic hybrid dispersion , melamine formaldehyde and micronized wax particles said wax particles having a diameter and said coating having a film thickness formed by the combination of the polyurethane acrylic hybrid and melamine formaldehyde;said coating at least partially coated with ink.2. The laminate claimed in wherein said polymeric film is bonded to paperboard.3. The laminate claimed in wherein said coating comprises less than 10 percent N-methylpyrrolidone.4. The laminate claimed in wherein said coating comprises less than 6 percent N-methylpyrrolidone.5. The laminate claimed in wherein said coating is substantially free of N-methylpyrrolidone.6. The laminate claimed in wherein said coating further comprises glycol ether solvent.7. The laminate claimed in wherein said polymeric film is selected from the group consisting of polyester claim 1 , metalized polyester claim 1 , polyamide claim 1 , metalized polyamide and biaxially oriented polypropylene.8. The laminate claimed in wherein said diameter of said wax particles is greater than said film thickness.9. The laminate claimed in further comprising an outer coating over said ink.10. The laminate claimed in wherein said outer coating comprises a varnish.11. A coating composition comprising water claim 9 , a polyurethane acrylic ...

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Номер записи: 78
01-01-2015 дата публикации

HYDROPHOBING AGENT FOR COATINGS

Номер: US20150000562A1
Автор: Hausberger Albert, Sebald Martin, STEPP Michael
Принадлежит: Wacker Chemie AG

Weathering-resistance and hydrophobicity of paints and coatings are enhanced by addition of a composition comprising an organopolysiloxanes bearing pendent aminoalkyl groups and fatty acid ester-based epoxy group-containing compounds. 113-. (canceled)14. A composition comprising: {'br': None, 'sub': m', 'n', 'o', 'p, 'MDTQ\u2003\u2003(I),'}, 'at least one organosiloxane of the formula (I)'}in which {'br': None, 'sup': 1', '2', '3, 'sub': '1/2', 'RRRSiO\u2003\u2003(Ia),'}, 'M is a terminal group of the formula (Ia)'} {'br': None, 'sup': 4', '5, 'sub': '2/2', 'RRSiO\u2003\u2003(Ib),'}, 'D is a difunctional group of the formula (Ib)'} {'br': None, 'sup': '6', 'sub': '3/2', 'RSiO\u2003\u2003(Ic),'}, 'T is a trifunctional group of the formula (Ic)'}{'sub': '4/2', 'Q is a unit of the formula SiO,'}{'sup': 1', '2', '3', '4', '5', '6', '6, 'where R, R, R, R, Rand Rindependently of one another are hydrocarbon radicals having 1 to 20 C atoms, optionally containing heteroatoms, or are hydroxyl radicals, or alkoxy radicals having 1 to 10 C atoms, where at least one hydrocarbon radical Rcontains at least one amine function, and not more than 25% of all of the radicals are hydroxyl or alkoxy radicals,'}m is an integer 0-20,n is an integer 0-1000,o is an integer 1-30,p is an integer 0-20, andm+n+o+p is an integer which is at least 2, and {'br': None, 'sub': 'q', '(A-B)C\u2003\u2003(II)'}, 'epoxides of the formula (II)'}in whichA independently at each occurrence is a monovalent linear or branched hydrocarbon radical having 1 to 30 C atoms, optionally substituted by heteroatoms or which is optionally interrupted by heteroatoms, and which optionally contains one or more epoxy functions,B independently at each occurrence is a divalent ether, carbonate, or urea function or is an acid, ester, urethane, acid-anhydride, or amide function of a carboxylic acid, thiocarboxylic acid, sulfonic acid, phosphonic acid, or phosphoric acid,q is a number from 1 to 8,C is a q-valent linear or ...

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Номер записи: 79
01-01-2015 дата публикации

METHOD FOR FORMING ORGANIC THIN FILM

Номер: US20150000563A1
Автор: Fujita Yoshitaka, HIDAKA Tomoya, HOSHI Eiji, Kumazawa Kazuhisa, Nakamoto Norifumi
Принадлежит:

A solution for forming an organic thin film wherein the total starting amount of metal surfactants (A) and (B) is 0.05 to 50 wt %, the amount of a hydroxyl group-containing compound generated with the progress of the hydrolysis reaction is 20 ppm to 6 wt %, and the amount of a compound (C) that can interact with the metal surfactant is 0.01 ppm to 8 ppm in terms of metal, relative to the total amount of the solution for forming an organic thin film. 111-. (canceled)12. A solution for forming an organic thin film wherein the total starting amount of metal surfactants (A) and (B) is 0.05 to 50 wt % , the amount of a hydroxyl group-containing compound generated with the progress of the hydrolysis reaction is 20 ppm to 6 wt % , and the amount of a compound (C) that can interact with the metal surfactant is 0.01 ppm to 8 ppm in terms of metal , relative to the total amount of the solution for forming an organic thin film. This application is a divisional application of U.S. application Ser. No. 12/312,096, filed on Apr. 24, 2009, which is a national stage application of International Application No. PCT/JP2007/072020, filed on Nov. 13, 2007, which claims priority to Japanese Patent Application No. 2006-307151, filed on Nov. 13, 2006, Japanese Patent Application No. 2006-351662, filed on Dec. 27, 2006, and Japanese Patent Application No. 2007-062660, filed on Mar. 12, 2007, each of which is incorporated by reference in its entirety.The present invention relates to a method for forming an organic thin film for forming an organic thin film on a substrate surface, particularly to an improved method for forming an organic thin film consisting of hydrolysable products of a metal surfactant.Conventionally, property modification of a surface of a substrate consisting of glass, metal, plastic or ceramics, is performed in various field, according to its purpose. For example, a method comprising coating a fluorine-containing silane coupling agent, in order to confer water ...

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Номер записи: 80
01-01-2015 дата публикации

FIRE RESISTANT GLAZING UNIT

Номер: US20150000825A1
Автор: Ali Muhammad I., Crook Vincent
Принадлежит: C.G.I. International

The present invention relates to a fire resistant glazing unit (), and in particular to novel curable gelling compositions which may form a fire-resistant hydrogel interlayer () between the glass panes () of the glazing unit (). The gelling compositions of the invention comprise 5-40% w/w of a curable hydrogel-forming component (typically an acidic vinyl monomer such as acrylic acid or its metal salt); 20-60% w/w of one or more salts (e.g. magnesium salts); 40-90% w/w of an aqueous vehicle; and the gelling compositions have an acidic p H between p H 1 and 7. Such gelling compositions, when cured to form a hydrogel interlayer, provide excellent fire-resistant properties and also an excellent radiation barrier in the event of a fire. 1. A gelling composition for forming a fire-resistant hydrogel interlayer within a glazing unit , the gelling composition obtained by mixing together:5-40% w/w of a curable hydrogel-forming component;20-60% w/w of one or more salts;40-90% w/w of an aqueous vehicle;wherein the composition has an acidic pH greater than or equal to pH 1 and less than pH 7.2. The gelling composition as claimed in claim 1 , wherein the gelling composition is a curable gelling composition claim 1 , which can be cured to form a polyelectrolyte hydrogel.3. The gelling composition as claimed in claim 1 , wherein the pH of the gelling composition is between 4 and 5.5.4. The gelling composition as claimed in claim 1 , wherein the gelling composition further comprises 0.02-0.08% w/w cross-linking agent.5. The gelling composition as claimed in claim 1 , wherein the one or more salts constitute 35-52% w/w of the gelling composition.6. The gelling composition as claimed in claim 1 , wherein the one or more salt(s) comprise magnesium sulphate.7. The gelling composition as claimed in claim 1 , wherein the one or more salt(s) comprise magnesium acetate.8. The gelling composition as claimed in claim 1 , wherein the one or more salts are or include one or more metal salts ...

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Номер записи: 81
04-01-2018 дата публикации

METHODS FOR POLISHING FLOORING SURFACES

Номер: US20180001430A1
Автор: Barrus Kent, Hills Dal N.
Принадлежит:

A method for treating a surface of flooring includes applying a composition that includes a silicate to a surface of the flooring and, while the composition is present on the surface, polishing or burnishing the surface. The silicate may be a lithium polysilicate and/or a colloidal silica. The composition may further include a surfactant and/or a leveling agent. When the composition is applied to the surface of the flooring, gravity may enable it to spread substantially evenly across the surface. The acts of applying and polishing or burnishing may be repeated. Such a treatment may result in a surface that has a glossiness of at least 80, as measured by a gloss meter set to a 60° angle of incidence. 1. A method for treating a flooring surface , comprising:applying a composition including a silicate to the flooring surface; andwith the composition on the flooring surface, polishing or burnishing the flooring surface, the composition capable of imparting the surface with a glossiness of at least about 80, as measured by a gloss meter set to a 60° angle of incidence.2. The method of claim 1 , wherein applying the composition comprises applying a composition in which the silicate comprises a lithium polysilicate.3. The method of claim 1 , wherein applying the composition comprises applying a composition in which the silicate comprises a colloidal silica.4. The method of claim 1 , wherein applying the composition comprises applying a composition further including a silane coupling agent and an organic component.5. The method of claim 4 , wherein applying the composition comprises applying a composition in which the organic component comprises a siliconate.6. The method of claim 4 , wherein applying the composition comprises applying a composition further including an acrylic latex.7. The method of claim 1 , wherein applying the composition comprises applying a composition further including an acrylic latex.8. The method of claim 1 , wherein applying the composition ...

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Номер записи: 82
05-01-2017 дата публикации

AMINO-CONTAINING ORGANOSILICON COMPOUND AND MAKING METHOD

Номер: US20170002030A1
Автор: Honma Takayuki, Kubota Tohru, TONOMURA Yoichi
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

An amino-containing organosilicon compound having formula (1) is used for surface treatment of an inorganic filler for thereby rendering the filler more compatible with and adhesive to a polymer material. In formula (1), Ris alkyl, alkenyl, aryl or aralkyl, Ris alkenyl, aryl or aralkyl, Rand Reach are a monovalent hydrocarbon group, and n is 0, 1 or 2. 4. The method of wherein the dealcoholization cyclization is effected in the presence of a basic catalyst.5. The method of wherein the dealcoholization cyclization is effected in the presence of a basic catalyst. This non-provisional application claims priority under 35 U.S.C. §119(a) on Patent Application No. 2015-134132 filed in Japan on Jul. 3, 2015, the entire contents of which are hereby incorporated by reference.This invention relates to amino-containing organosilicon compounds which are useful as silane coupling agents, surface treating agents, textile treating agents, adhesives, paint additives, and polymer modifiers, and a method for preparing the same.It is well known in the art that organosilicon compounds containing an amino group are useful as silane coupling agents, surface treating agents, textile treating agents, adhesives, paint additives and the like. Specifically, when an inorganic material such as glass fiber, metal or oxide filler is added to a polymer material for the purpose of improving mechanical properties and heat resistance, the adhesion between the polymer material and the inorganic material and the dispersion of the inorganic material in the polymer material are improved using the amino-containing organosilicon compound. The effect of adding the inorganic material is enhanced beyond expectation.As is also known in the art, silane coupling agents such as the above organosilicon compounds generate a considerable amount of alcohol on use, typically during mixing step. In conjunction with environmental issues associated with global warming and health problems, the recent challenge is a ...

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Номер записи: 83
05-01-2017 дата публикации

Aqueous Primary Dispersions, Process Of Their Production And Use Thereof

Номер: US20170002106A1
Автор: Holtschulte Sabine, Markou Konstantinos, Niegemeier Andreas
Принадлежит: BASF COATINGS GMBH

The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles having a Z-average particle diameter of 5 to 500 nm and which are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A). The emulsion polymerization takes place in the presence of one or more emulsifiers (EQ) having the following general formula: R—N(R)(R)(R)X, where Ris a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from hydroxyl groups, thiol groups, and primary or secondary amino groups, and/or has at least one carbon-carbon multiple bond, R, R, and R, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms, and X stands for the acid anion of an organic or inorganic acid. The invention further relates to a method for producing the primary dispersions, and to coating agents which include the primary dispersions, and to the use of the primary dispersions for producing electrodeposition coatings, and also to conductive substrates coated with the coating compositions. The invention further relates to emulsifiers which are used for producing the primary dispersions according to the invention. 1. An aqueous , cationically stabilized primary dispersion comprising: i. have a Z-average particle diameter of 5 to 500 nm, and', {'br': None, 'sup': 1', '−', '2', '3', '4', '⊖, 'R—N(R)(R)(R)X,'}, 'ii. are the reaction products of an emulsion polymerization of at least one olefinically unsaturated monomer (A), the emulsion polymerization of monomer (A) taking place in the presence of one or more emulsifiers (EQ) having the following formula], '(1) dispersed polymer particles which'}wherein,{'sup': '1', 'Ris a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one ...

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Номер записи: 84
05-01-2017 дата публикации

Aqueous Primary Dispersions, Method For Producing Same, And Use Thereof

Номер: US20170002107A1
Автор: Markou Konstantinos, Niegemeier Andreas
Принадлежит:

The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles having a Z-average particle diameter of 5 to 500 nm and which are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A). The emulsion polymerization takes place in the presence of one or more emulsifiers (E) having the following general formula: R—N(R)(R), where Ris a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from hydroxyl groups, thiol groups, and primary or secondary amino groups, and/or has at least one carbon-carbon multiple bond, and Rand R, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms. The invention further relates to a method for producing the primary dispersions, and to coating agents which include the primary dispersions, and to the use of the primary dispersions for producing electrodeposition coatings, and also to conductive substrates coated with the coating compositions. 1. An aqueous , cationically stabilized primary dispersion comprising dispersed polymer particles which:i. have a Z-average particle diameter of 5 to 500 nm, and [{'br': None, 'sup': 1', '2', '3, 'R—N(R)(R),'}, 'where', {'sup': 1', '2', '3, 'Ris a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from the group consisting of hydroxyl groups, thiol groups, primary amino groups, secondary amino groups, at least one carbon-carbon multiple bond, and mixtures thereof, and Rand R, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms.'}], 'ii. are obtained by an emulsion polymerization of at least one olefinically unsaturated monomer (A), the emulsion polymerization taking place in the ...

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Номер записи: 85
05-01-2017 дата публикации

COMPOSITION

Номер: US20170002232A1
Автор: De Boer Johannes Wietse, Hage Ronald, Maaijen Karin
Принадлежит: CATEXEL LIMITED

The present invention relates to an oxidatively curable coating composition with which a formulation for use in catalysing the curing of oxidatively curable coating compositions, in particular oxidatively curable coating compositions comprising an oxidatively curable alkyd-based resin, has been contacted. The formulations described herein comprise a triazacyclononane-based chelant; a manganese (II), (III) or (IV) salt; and an alcohol or ketone, which alcohol or ketone typically acts as a solvent for the salt and the chelant. The invention also relates to preparing the oxidatively curable coating compositions of the invention, such coating compositions once cured and methods comprising applying such coating compositions to a substrate. 2. The composition of claim 1 , wherein the counteranion is selected from the group consisting of acetate claim 1 , chloride and nitrate.3. The composition of claim 1 , wherein the counteranion is acetate.4. The composition of claim 1 , wherein the salt is selected from optionally hydrated Mn(II)(acetate) claim 1 , Mn(II)Cland Mn(II)(NO).5. The composition of claim 1 , wherein manganese ions are present in the formulation in an amount of about 0.1 to about 10 wt %.6. The composition claim 1 , wherein each R group is the same Calkyl.7. The composition of claim 1 , wherein the chelant is 1 claim 1 ,4 claim 1 ,7-trimethyl-1 claim 1 ,4 claim 1 ,7-triazacyclononane.8. The composition of claim 1 , wherein the formulation comprises an alcohol selected from the group consisting of methanol claim 1 , ethanol claim 1 , glycerol claim 1 , 1-propanol claim 1 , 2-propanol claim 1 , 1-butanol claim 1 , 2-butanol claim 1 , 1 claim 1 ,2-propyleneglycol and 1 claim 1 ,3-propyleneglycol.9. The composition of claim 8 , wherein the alcohol is selected from the group consisting of ethanol claim 8 , 1 claim 8 ,2-propyleneglycol claim 8 , 1 claim 8 ,3-propyleneglycol and glycerol.10. The composition of claim 1 , wherein the formulation comprises a ketone ...

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Номер записи: 86
04-01-2018 дата публикации

Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane ("f-poss")

Номер: US20180002534A1
Автор: Joseph M. Mabry, Sean Ramirez, Timothy S. Haddad
Принадлежит: US Air Force

A method of forming a hydrophobic and oleophobic surface. The method including spin coating an F-POSS with 3,3-dichloro-1,1,1,2,2,-pentafluoropropane/1,3-dichloro-1,1,2,2,3-pentafluoropropane onto an inert surface. The F-POSS has a structure: Each R f represents a nonreactive, fluorinated organic group, R 1 represents a first monovalent organic group comprising at least two carbon atoms, and R 2 represents hydrogen or a second monovalent organic group comprising at least two carbon atoms. The F-POSS with 3,3-dichloro-1,1,1,2,2,-pentafluoropropane/1,3-dichloro-1,1,2,2,3-pentafluoropropane are then dried on the inert surface.

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Номер записи: 87
04-01-2018 дата публикации

Intumescent Composition Comprising a Silicate Modified Epoxy Resin

Номер: US20180002536A1
Автор: Anderson Michael, KITTLE Kevin Jeffrey
Принадлежит:

The present invention relates to an intumescent coating composition comprising (a) the reaction product of a tetra-alkoxylorthosilicate or partially condensed oligomer thereof and an epoxy resin containing hydroxyl groups, wherein the alkoxy groups are independently selected from C-Calkoxy groups (b) one or more spumifics, and (c) one or more metal oxides and/or hydroxides. The intumescent coating composition provides excellent fire performance and char strength. The invention also relates to substrates coated with the intumescent coating composition, and a method of protecting structures from heat/fire. 1. An intumescent coating composition comprising:{'sub': 1', '20, '(a) a reaction product of a tetra-alkoxylorthosilicate or partially condensed oligomer thereof and an epoxy resin containing hydroxyl groups, wherein the alkoxy groups are independently selected from C-Calkoxy groups,'}(b) one or more spumifics, and(c) one or more metal oxides and/or hydroxides.2. The intumescent coating composition of wherein the total weight % of the one or more metal oxides and hydroxides (c) in the coating composition does not exceed 10.0 weight % claim 1 , wherein weight % is calculated on the total weight of the non-volatile components in the coating composition.3. The intumescent coating composition of wherein the epoxy resin containing hydroxyl group comprises (i) one or more aromatic epoxy resins and/or (ii) one or more aliphatic epoxy resins.4. The intumescent coating composition of wherein the metal of the one or more metal oxides and hydroxides (c) is independently selected from Al claim 1 , Ti claim 1 , Mg claim 1 , Zn claim 1 , Zr claim 1 , Na claim 1 , K and Si.5. The intumescent coating composition of wherein the one or more metal oxides and/or hydroxides is independently selected from: AlO claim 1 , Al(OH) claim 1 , TiO claim 1 , ZnO claim 1 , SiO claim 1 , aluminum silicate claim 1 , kaolin and china clay.6. The intumescent coating composition of wherein the alkoxy ...

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Номер записи: 88
04-01-2018 дата публикации

Flame retardant treating agent for kapok-fiber or kapok-nonwoven fabric

Номер: US20180002548A1
Автор: Da Som YANG, Oh Deok KWON, Won Jin Seo, Won Suk CHAE
Принадлежит: Hyundai Motor Co

Provided herein is a flame retardant agent that is useful for treating kapok-fiber or kapok-nonwoven fabric. Kapok-fiber or kapok-nonwoven fabric when treated with the flame retardant agent is capable of reducing the impact of fire and providing flame retardancy. The flame retardant treated kapok-fiber or kapok-nonwoven fabric has desired properties including acid resistance, light resistance, absence of stickiness, and absence of a glaucous appearance. Thus, the flame retardant treating agent is suitable for use with materials used in vehicles, clothes, bedclothes, and the like.

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Номер записи: 89
04-01-2018 дата публикации

RESIN COMPOSITION FOR UNDERLAYER FILM FORMATION, IMPRINT FORMING KIT, LAMINATE, PATTERN FORMING METHOD, AND METHOD FOR PRODUCING DEVICE

Номер: US20180002561A1
Автор: Goto Yuichiro, KITAGAWA Hirotaka, OOMATSU Tadashi
Принадлежит: FUJIFILM Corporation

Disclosed herein are a resin composition for underlayer film formation which is capable of forming an underlayer film having good adhesiveness to a base material and good surface state, an imprint forming kit, a laminate, a pattern forming method, and a method for producing a device. Provided is a resin composition for underlayer film formation, including a resin, a nucleophilic catalyst, and a solvent, in which the content of the nucleophilic catalyst is 0.01 to 0.3 mass % with respect to the solid content of the resin composition for underlayer film formation. 1. A resin composition for underlayer film formation , comprising:a resin;a nucleophilic catalyst; anda solvent,wherein the content of the nucleophilic catalyst is 0.01 to 3 mass % with respect to the solid content of the resin composition for underlayer film formation.2. The resin composition for underlayer film formation according to claim 1 , wherein the nucleophilic catalyst is at least one selected from an ammonium salt claim 1 , a phosphine-based compound claim 1 , a phosphonium salt claim 1 , and a heterocyclic compound.3. The resin composition for underlayer film formation according to claim 1 , wherein the resin includes a resin having a radical reactive group.6. The resin composition for underlayer film formation according to claim 1 , wherein the content of water is 0.01 to 3 mass % with respect to the resin composition for underlayer film formation.7. The resin composition for underlayer film formation according to claim 1 , wherein the content of the solvent is 95 to 99.9 mass % with respect to the resin composition for underlayer film formation.8. The resin composition for underlayer film formation according to claim 1 , which is used for the formation of an underlayer film for photoimprints.9. An imprint forming kit comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the resin composition for underlayer film formation according to ; and'}a photocurable composition.10. A laminate ...

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Номер записи: 90
04-01-2018 дата публикации

AQUEOUS POLYMER COMPOSITIONS AND METHODS

Номер: US20180002565A1
Автор: OVERMAN GREGG R.
Принадлежит: GAPA Enterprises

Aqueous alkyd resin emulsion compositions and methods of applying them for providing exceptionally durable gloss sheen to a variety of surfaces, including, but not limited to, urethane rubber, vehicle tires, and vinyl, The emulsion compositions comprise an alkyd resin, a mixture of alkyd resins, a mixture of alkyd resins and conventional latex resins, or a mixture of all or part of the above and silicone oils. The emulsion compositions also comprise thickeners, metallic driers, defoamers, and/or preservatives. The methods generally comprise applying an alkyd resin emulsion composition to a substrate surface in need of treatment and allowing the composition to cure by oxidative polymerization on and within the surface. 1. An aqueous emulsion composition comprising an alkyd resin emulsion , a drier , a latex emulsion , and a silicone oil.2. The aqueous emulsion composition of further comprising an additive selected from the group consisting of a thickening agent claim 1 , defoamer claim 1 , a siloxane claim 1 , a gum claim 1 , a fluorosurfactant claim 1 , a fluoropolymer claim 1 , a biocide claim 1 , a wax claim 1 , and combinations thereof.3. The aqueous emulsion composition of claim 2 , wherein the thickening agent is in the range of 0.05% to 1.0% by weight of the total aqueous emulsion composition.4. The aqueous emulsion composition of claim 3 , wherein the thickening agent is a cellulosic thickener.5. The aqueous emulsion composition of claim 3 , wherein the thickening agent is an associative thickener.6. The aqueous emulsion composition of claim 3 , wherein the thickening agent is a clay.7. The aqueous emulsion composition of claim 3 , wherein the thickening agent is a gum.8. The aqueous emulsion composition of claim 1 , wherein the aqueous emulsion composition viscosity is in the range of 50 to 50 claim 1 ,000 centipoise.9. The aqueous emulsion composition of claim 1 , wherein the alkyd resin emulsion comprises 30% to 80% of the total solids content of the ...

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Номер записи: 91
04-01-2018 дата публикации

WATERPROOFING MEMBRANE COMPOSITION, PROCESS FOR MANUFACTURING SAID COMPOSITION AND USES THEREOF

Номер: US20180002570A1
Автор: AERTS Hans, MARTIN Caroline, Verdebout Renaud
Принадлежит: IMPERBEL

A waterproofing membrane composition comprising PVB, polymer modified bitumen, a compatibilizing agent selected from the group consisting of a succinate mixed ester of benzyl and of branched nonyl or decyl, a bis(ethoxylated alkyl) succinate, a composition comprising aliphatic polycarboxylic acid esters of formula R′—X—[O—C(O)—R]n, or a mixture thereof. 1. A waterproofing membrane composition comprising active membrane compounds containing:polyvinyl butyral (PVB);polymer modified bitumen, where the polymer of the polymer modified bitumen forms a polymeric matrix wherein bitumen and PVB are retained; and a succinate mixed ester of benzyl and of branched nonyl or decyl;', 'a bis(ethoxylated alkyl) succinate; and', {'br': None, 'i': 'n', 'R′—X—[O—C(O)—R]'}, 'a composition comprising aliphatic polycarboxylic acid esters of formula], 'at least one compatibilizing agent selected from the group consisting of'}wherein{'sup': 1', '2', '1, 'R is selected from the group consisting of epoxidized oleic, epoxidized linoleic, and epoxidized linolenic acid and mixtures thereof, or R is Rbeing a tetrahydrofurfuryl group, or a substituted tetrahydrofurfuryl group, or R is Rbeing an alkoxylated alkyl group, or a substituted alkoxylated alkyl group, different from R;'}{'sub': '2', 'sup': 1', '2', '1, 'R′ is a methyl group when R is selected from the group consisting of epoxidized oleic, linoleic, and linolenic acid and mixtures thereof, X is —CH— and n is 1; or R′ is Y—OC(O)-group wherein Y is Rbeing a tetrahydrofurfuryl group, or a substituted tetrahydrofurfuryl group, or Y is Rbeing an alkoxylated alkyl group, or a substituted alkoxylated alkyl group, different from R;'}X is an alkylene group or an hydroxyl-substituted alkylene group comprising from 1 to 4 carbon atoms; andn is 1 or 2,or a mixture thereof.2. Waterproofing membrane composition according to claim 1 , wherein the aliphatic polycarboxylic acid esters is of formula (II) and of formula (I) or (III):{'br': None, 'sup': '1', ...

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Номер записи: 92
11-01-2018 дата публикации

COMPOSITIONS AND METHODS FOR FORMING STABLE, LIQUID METAL OXIDE/HYDROXIDE FORMULATIONS

Номер: US20180007914A1
Автор: Kissick Calvin Jeffrey, Knappenberger Kyle, Malchesky Paul S., Sanford Bill, Steward Eric, Walker Brandon
Принадлежит:

Dry mixtures and liquid formulations are provided that comprise metal oxide and/or metal hydroxide nanocrystalline particles. The dry mixtures are advantageously formulated with select surfactants to be readily solubilized and stable in liquid carriers. Additional select components are provided in preferred combinations that are capable of achieving improved biocidal and chemical agent efficacy. Notably, the inventive formulations provided herein allow for easier delivery of the formulations and increased shelf stability. 1. A solid powder mixture comprising a quantity of nanocrystalline metal oxide and/or metal hydroxide particles and one or more surfactants selected from the group consisting of ethylene oxide and propylene oxide block copolymers , polysorbates , sodium methacrylates , polyamide-based resin dispersants , sulfosuccinates , and octylphenol ethoxylates.2. The mixture of claim 1 , wherein said nanocrystalline particles are selected from the group consisting of MgO claim 1 , CeO claim 1 , CaO claim 1 , TiO claim 1 , ZrO claim 1 , FeO claim 1 , VO claim 1 , VO claim 1 , MnO claim 1 , FeO claim 1 , NiO claim 1 , CuO claim 1 , AlO claim 1 , ZnO claim 1 , SiO claim 1 , AgO claim 1 , SrO claim 1 , BaO claim 1 , Mg(OH) claim 1 , Ca(OH) claim 1 , Al(OH) claim 1 , Sr(OH) claim 1 , Ba(OH) claim 1 , Fe(OH) claim 1 , Cu(OH) claim 1 , Ni(OH) claim 1 , Co(OH) claim 1 , Zn(OH) claim 1 , AgOH claim 1 , coated metal oxides and hydroxides claim 1 , doped metal oxides and hydroxides claim 1 , biocidal metal oxides and hydroxides claim 1 , and mixtures thereof.3. The mixture of claim 1 , wherein said nanocrystalline particles are present in said mixture at a level of from about 70% to about 99% by weight.4. The mixture of claim 1 , wherein said one or more surfactants are present in said mixture at a level of from about 1% to about 30% by weight.5. The mixture of claim 1 , wherein said one or more surfactants comprises a tri-block copolymer having a central hydrophobic ...

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Номер записи: 93
12-01-2017 дата публикации

SILICONE BASED EMULSION, METHOD FOR MAKING SAME, AND WATERBORNE CO-BINDER RESIN COMPOSITIONS COMPRISING SUCH EMULSIONS

Номер: US20170009099A1
Автор: Jiang Ping, Kumar Vikram, Maio Louisa, Seeber Michael, Tiwary Yogesh, Wusik Martin
Принадлежит:

A crosslinkable silicone based emulsion composition includes a hydroxylated polydiorganopolysiloxane grafted onto at least one colloidal silica dispersion, wherein the at least one hydroxylated polydiorganopolysiloxane grafted onto the least one colloidal silica dispersion contains residual silanol groups from the at least one hydroxylated polydiorganopolysiloxane. Further, a waterborne co-binder silicone-organic resin composition includes (A) the crosslinkable silicone emulsion and (B) an organic resin emulsion which provides improved cured properties including, but not limited to, improved hydrophobicity (water resistance), scratch resistance and gloss retention as well as process for making the emulsions and the compositions. 1. A crosslinkable silicone based emulsion composition comprising:at least one hydroxylated polydiorganopolysiloxane grafted onto at least one colloidal silica dispersion;at least one catalyst;at least one emulsion stabilizer;at least one surfactant; andwater,wherein the at least one hydroxylated polydiorganopolysiloxane grafted onto the at least one colloidal silica dispersion contains residual silanol groups from the at least one hydroxylated polydiorganopolysiloxane.2. The composition of further comprising at least one organic resin.3. The composition of wherein the at least one surfactant is a non-ionic surfactant claim 1 , an anionic surfactant or a combination thereof.4. The composition according to claim 1 , wherein the hydroxylated polydiorganosiloxane has a weight average molecular weight of from about 5 claim 1 ,000 to about 1 claim 1 ,000 claim 1 ,000.5. The composition according to claim 1 , wherein the hydroxylated polydiorganosiloxane has a weight average molecular weight of from about 200 claim 1 ,000 to about 1 claim 1 ,000 claim 1 ,000.6. The composition of claim 1 , wherein the hydroxylated polydiorganosiloxane is a hydroxyl-terminated polydimethylsiloxane.7. The silicone composition according to claim 1 , wherein the ...

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Номер записи: 94
08-01-2015 дата публикации

BASIC COMPOSITIONS INCLUDING INORGANIC OXIDE NANOPARTICLES AND AN ORGANIC BASE, COATED SUBSTRATES, ARTICLES AND METHODS

Номер: US20150010748A1
Автор: Chen Xue-hua, Yang Yu, Yu Bin, Zhou Ping, ZHU DONG-WEI
Принадлежит:

Basic coating compositions including inorganic oxide nanoparticles and an organic base are described. Methods of coating a substrate with the coating compositions, coated substrates prepared using the methods, and articles that include the coated substrates are also disclosed. 18-. (canceled)9. A method of coating a substrate , the method comprising: inorganic oxide nanoparticles having an average primary particle size of 40 nanometers or less; and', 'an organic base; and, 'contacting a surface of a substrate with a coating composition comprisingdrying the coating composition on the substrate to provide a condensed inorganic oxide nanoparticle coating.10. The method of wherein the method comprises: water;', 'inorganic oxide nanoparticles having an average primary particle size of 40 nanometers or less; and', 'an organic base;', 'wherein the coating composition is an aqueous dispersion having a pH of greater than 8; and', 'wherein a surfactant is present in the aqueous coating composition, disposed on the substrate surface prior to contact with the aqueous coating composition, or both in the aqueous coating composition and disposed on the substrate surface prior to contact with the aqueous coating composition; and, 'contacting a surface of a substrate with an aqueous coating composition comprisingdrying the aqueous coating composition on the substrate to provide a condensed inorganic oxide nanoparticle coating.11. The method of wherein the coating composition further comprises a surfactant.12. A coated substrate prepared by the method of .13. The coated substrate of wherein the coating has a static water contact angle of less than 30° or greater than 90°.14. The coated substrate of wherein the condensed inorganic oxide nanoparticle coating does not include an organic binder or film former.15. An article comprising a coated substrate of .16. The method of wherein the organic base is selected from the group consisting of an amidine claim 9 , a guanidine claim 9 , a ...

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Номер записи: 95
14-01-2016 дата публикации

FLUORINE-CONTAINING CALCIUM COMPOSITE PARTICLES, METHOD FOR PRODUCING THE SAME, AND SURFACE-TREATING AGENT COMPRISING THE SAME AS ACTIVE INGREDIENT

Номер: US20160009922A1
Автор: Sato Katsuyuki, Sawada Hideo
Принадлежит:

Fluorine-containing calcium composite particles comprising an aggregate of a fluorine-containing alcohol represented by the general formula: 1. Fluorine-containing calcium composite particles comprising an aggregate of a fluorine-containing alcohol represented by the general formula:{'br': None, 'sub': n', '2n+1', '2', '2', 'a', '2', '2', 'b', '2', '2', 'c, 'CF(CHCF)(CFCF)(CHCH)OH\u2003\u2003[I]'}wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3; and a calcium compound.2. The fluorine-containing calcium composite particles according to claim 1 , wherein the calcium compound is an inorganic calcium salt or an organic acid calcium salt.3. A method for producing fluorine-containing calcium composite particles claim 1 , comprising aggregating the fluorine-containing alcohol [I] according to and a calcium compound using an alkaline or acid catalyst.4. The method for producing fluorine-containing calcium composite particles according to claim 3 , wherein aqueous ammonia is used as the alkaline catalyst.5. The method for producing fluorine-containing calcium composite particles according to claim 3 , wherein calcium hydroxide is used as the calcium compound and the alkaline catalyst.6. Fluorine-containing calcium composite particles comprising a condensate of a fluorine-containing alcohol represented by the general formula:{'br': None, 'sub': 'F', 'R-A-OH\u2003\u2003[Ia]'}{'br': None, 'or the general formula{'br': None, 'sub': 'F', 'HO-A-R′-A-OH\u2003\u2003[Ib]'}{'sub': F', 'F, 'wherein Ris a liner or branched perfluoroalkyl group that may contain an O, S, or N atom, or a polyfluoroalkyl group in which some of the fluorine atoms of the perfluoroalkyl group are replaced by hydrogen atoms; R′ is a linear or branched perfluoroalkylene group containing an O, S, or N atom; and A is an alkylene group having 1 to 6 carbon atoms; alkoxysilane, and a calcium compound.'}7. The fluorine-containing calcium composite ...

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Номер записи: 96
11-01-2018 дата публикации

PHOTOSTABLE COMPOSITIONS COMPRISING PARA-ALKOXYL PHENYL SUBSTITUTED PROPENOIC ACID (APP) COPOLYMER DERIVATIVES

Номер: US20180009923A1
Автор: Feng Hui, Hu Shengkui, Zlotnik Dennis
Принадлежит: HALLSTAR INNOVATIONS CORP.

The present disclosure relates, according to some embodiments, to photostable photoactive compositions comprising (a) at least one photoactive compound that develops within itself an excited state energy when subjected to UV radiation and (b) a block copolymer comprising a plurality of blocks, wherein the block copolymer is operable to quench the excited state energy. 3. A photostable photoactive composition according to claim 1 , wherein the block copolymer is present at a concentration of about 1% by weight to about 20% by weight claim 1 , based on a total weight of the composition.4. A photostable photoactive composition according to claim 1 , wherein the block copolymer is present at a concentration comprising about 15% by weight claim 1 , about 10% by weight claim 1 , about 5% by weight claim 1 , about 1% by weight claim 1 , or a combination thereof claim 1 , based on the total weight of the composition.5. A photostable photoactive composition according to claim 1 , wherein the at least one photoactive compound comprises 4-methyldibenzoylmethane and derivatives thereof; octyl methoxycinnamate and derivatives thereof; octocrylene and derivatives thereof; p-methoxycinnamic acid esters and derivatives thereof; 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1 claim 1 ,3-dione and derivatives thereof; oxybenzone and derivatives thereof; bis-ethylhexyloxyphenol methoxyphenyl triazone and derivatives thereof; methylene bis-benzotriazolyl tetramethylbutylphenol and derivatives thereof; 4-methylbenzylidene camphor and derivatives thereof; diethylamino hydroxyl benzoyl hexyl benzoate and derivatives thereof; drometrizole trisiloxane and derivatives thereof; ethylhexyl triazone claim 1 , diethylhexyl butamido triazone and derivatives thereof; terephthalylidene dicamphor sulfonic acid claim 1 , its salts claim 1 , and derivatives thereof claim 1 , menthyl anthranilate and derivatives thereof; retinol and derivatives thereof; coenzyme Q and derivatives thereof; ...

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Номер записи: 97
11-01-2018 дата публикации

PREPARATION METHOD OF SILICA AEROGEL-CONTAINING BLANKET AND SILICA AEROGEL-CONTAINING BLANKET PREPARED BY USING THE SAME

Номер: US20180010726A1
Автор: Kim Mi Ri, Lee Je Kyun, OH Jin Hee, OH Kyoung Shil
Принадлежит:

Provided are a preparation method of a silica aerogel-containing blanket which includes mixing a water glass solution, a polar organic solvent, and a silazane-based surface modifier to prepare a sol, preparing a silica gel-base material composite by immersion and gelation of a base material for a blanket in the sol, and drying the silica gel-base material composite, and a silica aerogel-containing blanket prepared by using the preparation method. 1. A preparation method of a silica aerogel-containing blanket , the preparation method comprising:mixing a water glass solution, a polar organic solvent, and a silazane-based surface modifier to prepare a sol;preparing a silica gel-base material composite by immersion and gelation of a base material for a blanket in the sol; anddrying the silica gel-base material composite.2. The preparation method of claim 1 , wherein the water glass solution comprises silica in an amount of 0.1 wt % to 30 wt % based on a total weight of the water glass solution.3. The preparation method of claim 1 , wherein the water glass solution further comprises an acid catalyst.4. The preparation method of claim 1 , wherein the polar organic solvent is an alcohol-based solvent.5. The preparation method of claim 1 , wherein the polar organic solvent is a linear monovalent alcohol having 1 to 4 carbon atoms.6. The preparation method of claim 1 , wherein the silazane-based surface modifier comprises a silazane-based compound including two or more alkyl groups in a molecule.8. The preparation method of claim 1 , wherein the silazane-based surface modifier comprises any one selected from the group consisting of tetraalkyldisilazane and hexaalkyldisilazane or a mixture of two or more thereof claim 1 , andthe alkyl is an alkyl group having 1 to 4 carbon atoms.9. The preparation method of claim 1 , wherein the silazane-based surface modifier is used in an amount of 0.6 part by weight to 2 parts by weight based on 1 part by weight of silica included in the ...

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Номер записи: 98
19-01-2017 дата публикации

CHEMICAL ADDITIVES FOR WATER FLUX ENHANCEMENT

Номер: US20170014779A1
Автор: CHOI Hyungsam, JEON Hyung Joon, Koehler Jeff
Принадлежит:

Provided are flux enhancing inclusion complexes for preparing highly permeable thin film composite membranes, and processes that include adding the flux enhancing inclusion complexes to the organic phase or aqueous phase prior to interfacial polymerization of the thin film composite membrane. The thin film composite membranes are suitable for nanofiltration, and reverse and forward osmosis. The provided processes can include contacting a porous support membrane with an aqueous phase containing a polyamine to form a coated support membrane, and applying an organic phase containing a polyfunctional acid halide and a flux enhancing inclusion complex to the coated support membrane to interfacially polymerize the polyamine and the polyfunctional acid halide to form a discrimination layer to form thin film composite membranes. 1. A flux enhancing inclusion complex , comprising:a host component having a cavity; anda guest component within the cavity, wherein the guest component includes a metal chelate containing a metal atom or metal ion, and a bidentate ligand.2. The complex of claim 1 , wherein the host component comprises:a crown ether or derivative thereof; orat least two glyme molecules.3. The complex of claim 2 , wherein the crown ether is selected from among 12-crown-4 claim 2 , 15-crown-5 claim 2 , 18-crown-6 claim 2 , 20-crown-6 claim 2 , 21-crown-7 claim 2 , 24-crown-8 claim 2 , dicyclohexyl-18-crown-6 claim 2 , dibenzo-18-crown-6 claim 2 , 1 claim 2 ,10-diaza-18-crown-6 claim 2 , 1 claim 2 ,7 claim 2 ,13-triaza-18-crown-6 claim 2 , and 1 claim 2 ,4 claim 2 ,10 claim 2 ,13-tetraaza-18-crown-6 claim 2 , and the crown ether is unsubstituted or is substituted with one or more substituents selected from among vinyl claim 2 , benzo claim 2 , amido claim 2 , aryl claim 2 , thia claim 2 , aza claim 2 , alkyl claim 2 , haloalkyl claim 2 , and nitro substituents and combinations thereof.4. The complex of claim 1 , wherein the metal atom or metal ion is selected from ...

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Номер записи: 99
15-01-2015 дата публикации

USE OF OILS WITH HIGH CONCENTRATIONS OF POLYUNSATURATED FATTY ACIDS IN PLASTICS AND SURFACE COATINGS

Номер: US20150017400A1
Автор: Calabotta Beth J., Estep Joann, Heise Jerald, Makadia Vallabh, Morgenstern David A., Nissing Nicholas J.
Принадлежит:

Oil compositions having a high concentration of polyunsaturated fatty acids are described for use in various applications including use as drying oils, in ink compositions and coating compositions. Oil compositions wherein the double bonds of the fatty acids are substantially epoxidized are described and used as plasticizers and thermal stabilizers for various halogenated polymer compositions. 122-. (canceled)23. A printed substrate comprising an ink or coating on at least one surface thereof , the ink or coating comprising an oil composition comprising either:(a) at least about 7.5 wt. % stearidonic acid or a derivative thereof based upon the total weight of fatty acids or derivatives thereof in the oil composition;(b) at least about 0.5 wt. % stearidonic acid or a derivative thereof based upon the total weight of fatty acids or derivatives thereof in the oil composition wherein the stearidonic acid is derived from a transgenic plant source; or(c) at least 20 wt. % gamma-linolenic acid or a derivative thereof based upon the total weight of fatty acids or derivatives thereof in the composition.24. The printed substrate of wherein the oil composition comprises at least about 7.5 wt. % stearidonic acid or a derivative thereof based upon the total weight of fatty acids or derivatives thereof in the oil composition.25. The printed substrate of wherein the oil composition comprises at least about 0.5 wt. % stearidonic acid or a derivative thereof based upon the total weight of fatty acids or derivatives thereof in the oil composition wherein the stearidonic acid is derived from a transgenic plant source.26. The printed substrate of wherein the oil composition comprises at least 20 wt. % gamma-linolenic acid or a derivative thereof based upon the total weight of fatty acids or derivatives thereof in the composition.27. The printed substrate of wherein the oil comprises at least 10 wt. % of at least one polyunsaturated fatty acid having four or more carbon-carbon double ...

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Номер записи: 100