29-04-2021 дата публикации
Номер: US20210122878A1
Принадлежит:
The present invention is directed to supported catalyst having utility in the polymerization and co-polymerization of epoxide monomers, said supported catalyst having the general Formula (I): 1. A supported catalyst having the general Formula (I):{'br': None, 'i': 'b', '[DMCC]*Supp\u2003\u2003(I)'} Supp denotes a hydrophobic support material; and,', 'b represents the average proportion by weight of said support material, based on the total weight of [DMCC] and Supp;', 'wherein the hydrophobic support material is selected from the group consisting of hydrophobic materials having a methanol wettability value of at least 30 vol. %; carbonaceous inorganic solid materials; and inorganic solid materials which are isoelectronic with carbon., 'wherein: [DMCC] denotes a double metal cyanide complex which comprises a double metal cyanide (DMC) compound, at least one organic complexing agent and a metal salt;'}2. The supported catalyst according to claim 1 , wherein b is in the range of 10 wt. %≤b≤70 wt. %.3. The supported catalyst according to claim 1 , wherein said double metal cyanide complex [DMCC] is represented either by the general Formula (II-A){'br': None, 'sup': 1', '2', '3, 'sub': d', 'e', 'f', 'g, 'i': *x', '*y, 'M[M(CN)]M(X)H2O*ωL\u2003\u2003(II-A); or'}{'br': None, 'by general Formula (II){'br': None, 'sup': 1', '2', '3', '1', '2, 'sub': d', 'e', 'f', 'g, 'i': *x', '*y', 'z', '*a, 'M[M(CN)]M(X)H2O*LL\u2003\u2003(II)'}{'sup': '1', 'claim-text': [{'sup': '2', 'Mis a Fe, Co, Mn, Cr, Ir, Rh, Ru or V ion;'}, {'sup': '3', 'Mis a Zn, Fe, Co, Ni, Mn, Cu, Sn, Pb, Cr, Ir, Rh, Ru or V ion;'}, 'X is an anion;', 'L is an organic complexing agent;', {'sup': 1', '2, 'Land Lare distinct from one another and represent respectively first and second organic complexing agents;'}, {'sup': 1', '2', '3, 'sub': d', 'e', 'f', 'g, 'd, e, f and g are each integers >0 but have values such that the complex M[M(CN)]*xM(X)is electrically neutral;'}, '0.1≤x≤5;', '0.1≤y≤1;', '0.0001≤ω≤6;', '0. ...
Подробнее