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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 3036. Отображено 100.
19-04-2012 дата публикации

Process for producing middle distillates by hydroisomerization and hydrocracking of a heavy fraction derived from a fischer-tropsch effluent

Номер: US20120091034A1
Автор: Aurelie Dandeu, Vincent Coupard
Принадлежит: Eni Spa, IFP Energies Nouvelles IFPEN

The present invention describes a process for producing middle distillates from a C5+ liquid paraffinic fraction, termed a heavy fraction, with an initial boiling point in the range 15° C. to 40° C. produced by Fischer-Tropsch synthesis, comprising the following steps in succession: passing said C5+ liquid paraffinic fraction, termed a heavy fraction, over at least one ion exchange resin at a temperature in the range 80° C. to 150° C., at a total pressure in the range 0.7 to 2.5 MPa, at an hourly space velocity in the range 0.2 to 2.5 h −1 ; eliminating at least a portion of the water formed in step a); hydrogenating the unsaturated olefinic type compounds of at least a portion of the effluent derived from step b) in the presence of hydrogen and a hydrogenation catalyst; and hydroisomerization/hydrocracking of at least a portion of the hydrotreated effluent derived from step c) in the presence of hydrogen and a hydroisomerization/hydrocracking catalyst.

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Номер записи: 1
03-05-2012 дата публикации

Fuel and base oil blendstocks from a single feedstock

Номер: US20120108869A1
Автор: Paul F. Bryan, Stephen J. Miller
Принадлежит: Chevron USA Inc

A method comprising the steps of providing a quantity of biologically-derived oil comprising triglycerides; processing the biologically derived oil so as to transesterify at least some of the triglycerides contained therein to yield a quantity of saturated monoesters and unsaturated monoesters; oligomerizing at least some of the unsaturated monoesters to yield a quantity of fatty acid ester oligomers; separating at least some of the saturated monoesters from the fatty acid ester oligomers; and hydrotreating at least some of the fatty acid ester oligomers to yield a quantity of alkanes.

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Номер записи: 2
03-05-2012 дата публикации

Fuel and base oil blendstocks from a single feedstock

Номер: US20120108871A1
Автор: Stephen J. Miller
Принадлежит: Chevron USA Inc

A method comprising providing a fatty acyl mixture comprising: (i) a C 10 -C 16 acyl carbon atom chain content of at least 30 wt. % wherein at least 80% of the C 10 -C 16 acyl carbon atom chains are saturated; and (ii) a C 18 -C 22 acyl carbon atom chain content of at least 20 wt. % wherein at least 50% of the acyl C 18 -C 22 carbon atom chains contain at least one double bond; hydrolyzing the mixture to yield a quantity of C 10 -C 16 saturated fatty acids and C 18 -C 22 unsaturated fatty acids; oligomerizing at least some of the C 18 -C 22 unsaturated fatty acids to yield a quantity of C 36+ fatty acid oligomers; hydrotreating at least some of the C 10 -C 16 saturated fatty acids and at least some of the C 36+ fatty acid oligomers to yield a quantity of diesel fuel blendstock and C 36+ alkanes; and separating at least some of the diesel fuel blendstock from the C 36+ alkanes.

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Номер записи: 3
21-06-2012 дата публикации

Increasing fuel smoke point

Номер: US20120152803A1
Автор: Stuart S. Shih
Принадлежит: ExxonMobil Research and Engineering Co

The present invention relates to processes for increasing smoke point of a fuel. The process can be carried out using an upgrading catalyst that contains at least one noble metal supported on an inorganic, porous crystalline phase material. The catalyst is particularly effective in increasing smoke point, while minimizing reduction in total aromatics content, particularly naphthalene content.

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Номер записи: 4
23-08-2012 дата публикации

Process for hydrotreating naphtha fraction and process for producing hydrocarbon oil

Номер: US20120211401A1
Автор: Kazuhiko Tasaka, Marie Iwama, Yuichi Tanaka
Принадлежит: Individual

A process for hydrotreating a naphtha fraction that includes a step of estimating the difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature, based on the reaction temperature of the Fischer-Tropsch synthesis reaction and the ratio of the flow rate of the treated naphtha fraction returned to the naphtha fraction hydrotreating step relative to the flow rate of the treated naphtha fraction discharged from the naphtha fraction hydrotreating step, a step of measuring the difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature, and a step of adjusting the reaction temperature of the naphtha fraction hydrotreating step so that the measured difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature becomes substantially equal to the estimated difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature.

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Номер записи: 5
14-03-2013 дата публикации

Hydrotreating of Aromatic-Extracted Hydrocarbon Streams

Номер: US20130062255A1
Автор: Omer Refa Koseoglu
Принадлежит: Saudi Arabian Oil Co

Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by first subjecting the entire feed to an extraction zone to separate an aromatic-rich fraction containing a substantial amount of the aromatic refractory and sterically hindered sulfur-containing compounds and an aromatic-lean fraction containing a substantial amount of the labile sulfur-containing compounds. The aromatic-rich fraction is contacted with isomerization catalyst, and the isomerized aromatic-rich fraction and the aromatic-lean fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level.

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Номер записи: 6
14-03-2013 дата публикации

Integrated Isomerization and Hydrotreating Process

Номер: US20130062257A1
Автор: Omer Refa Koseoglu
Принадлежит: Saudi Arabian Oil Co

Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A low boiling temperature fraction contains refractory, sterically hindered sulfur-containing compounds, which have a boiling point at or above the target cut point temperature. A high boiling temperature fraction, having a boiling point below the target cut point temperature, is substantially free of refractory sulfur-containing compounds. The high boiling temperature fraction is contacted with isomerization catalyst, and the isomerized effluent and the low boiling temperature fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level.

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Номер записи: 7
21-03-2013 дата публикации

HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF

Номер: US20130068662A1
Автор: Kuperman Alexander E., Maesen Theodorus Ludovicus Michael
Принадлежит:

A method for hydroprocessing a hydrocarbon feedstock is provided. The method comprises contacting the feedstock with a catalyst under hydroprocessing conditions, wherein the catalyst is formed by sulfiding an unsupported catalyst precursor of the general formula A[(M)(OH)(L)](MO), wherein Mis selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof; L is one or more oxygen-containing ligands, and L has a neutral or negative charge n<=0, Mis at least a Group VIB metal having an oxidation state of +6; M: Mhas an atomic ratio between 100:1 and 1:100; v−2+P*z−x*z+n*y*z=0; and 0≦y≦−P/n; 0≦x≦P; 0≦v≦2; 0≦z. In one embodiment, the catalyst precursor further comprises a cellulose-containing material. In another embodiment, the catalyst precursor further comprises at least a diluent (binder). In one embodiment, the diluent is a magnesium aluminosilicate clay. 1. A process for hydroprocessing a hydrocarbon feedstock which comprises contacting the hydrocarbon feedstock with a catalyst under hydroprocessing conditions ,{'sub': v', 'x', 'y', 'Z', '4, 'sup': P', 'n', 'VIB, 'wherein the catalyst is formed by sulfiding an unsupported catalyst precursor composition having a formula A[(M) (OH)(L)](MO),'}whereinA is at least one of an alkali metal cation, an ammonium, an organic ammonium and a phosphonium cation,{'sup': P', 'P', 'P, 'Mis selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, P is oxidation state with Mhaving an oxidation state of either +2 or +4 depending on the selection of M,'}L is at least one organic oxygen-containing ligand,{'sup': 'VIB', 'Mis at least a Group VIB metal, having an oxidation state of +6,'}{'sup': P', 'VIB, 'M: Mhas an atomic ratio of 100:1 to 1:100,'}v−2+P*z−x*z+n*y*z=0; and0 Подробнее

Номер записи: 8
02-05-2013 дата публикации

Diesel fuel production process employing direct and indirect coal liquefaction

Номер: US20130104611A1
Автор: Gerald A. Melin, Kenneth L. Trachte, Richard F. Bauman
Принадлежит: Accelergy Corp

A combined Direct Coal Liquefaction (DCL)/Fischer Tropsch (F-T) process and system for producing high Cetane diesel fuel by converting at least 70% of the feed coal by DCL operating at 50 to 70% conversion and gasifying the bottoms and between 0 and 30% of the feed coal to produce H2 for supply to the DCL and to upgrading and syngas for being converted to diesel by F-T. Diesel blendstocks produced by the DCL and the F-T in a ratio of 3 to 1 to 14 to 1 are blended to produce diesel fuel having a Cetane Number of at least 50.

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Номер записи: 9
05-09-2013 дата публикации

Method for efficiently operating an ebbulated bed reactor and an efficient ebbulated bed reactor

Номер: US20130228494A1
Автор: Lap Keung Lee, Roger K. Lott
Принадлежит: Headwaters Heavy Oil LLC

A hydroprocessing method and system involves introducing heavy oil and well-dispersed metal sulfide catalyst particles, or a catalyst precursor capable of forming the well-dispersed metal sulfide catalyst particles in situ within the heavy oil, into a hydroprocessing reactor. The well-dispersed or in situ metal sulfide catalyst particles are formed by 1) premixing a catalyst precursor with a hydrocarbon diluent to form a precursor mixture, 2) mixing the precursor mixture with heavy oil to form a conditioned feedstock, and 3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil to form the well-dispersed or in situ metal sulfide catalyst particles. The well-dispersed or in situ metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil and hydrogen and eliminates or reduces formation of coke precursors and sediment.

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Номер записи: 10
19-09-2013 дата публикации

Process unit for flexible production of alkylate gasoline and distillate

Номер: US20130243672A1
Автор: Howard Steven Lacheen, Hye Kyung Cho Timken, Shawn Shlomo Winter, Sven Ivar Hommeltoft
Принадлежит: Chevron USA Inc

A process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in an alkylate mode and in a distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.

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Номер записи: 11
03-10-2013 дата публикации

Hydrocarbon conversion process

Номер: US20130256190A1
Автор: Mark Van Wees, Robert Haizmann
Принадлежит: UOP LLC

One exemplary embodiment can be a process for hydrocarbon conversion. The process can include providing a feed to a slurry hydrocracking zone, obtaining a hydrocarbon stream including one or more C16-C45 hydrocarbons from the at least one separator, providing another feed to a hydrocracking zone, and providing hydrogen from a three-stage compressor to the slurry hydrocracking zone and the hydrocracking zone. Moreover, the slurry hydrocracking zone may include a slurry hydrocracking reactor and at least one separator.

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Номер записи: 12
16-01-2014 дата публикации

More energy efficient c5 hydrogenation process

Номер: US20140018584A1
Автор: Gary G. Podrebarac, Yongqiang Xu
Принадлежит: Lummus Technology Inc

A process for the conversion of linear pentenes to propylene is disclosed. The process may include feeding hydrogen and a C5-olefin containing stream comprising linear pentenes, dienes, acetylenes, and cyclopentene to a catalytic distillation reactor system. Concurrently in the catalytic distillation reactor system, the acetylenes and dienes may be hydrogenated and the C5-olefin containing stream may be fractionated, thereby recovering an overheads fraction comprising the linear pentenes, a side draw fraction comprising the cyclopentene, and a bottoms fraction. In some embodiments, at least a portion of the overheads fraction may then be fed to a metathesis reactor for converting the linear pentenes to propylene.

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Номер записи: 13
13-02-2014 дата публикации

Process for passivation by a nitrogen-containing compound of a zeolitic catalyst, in particular a hydrocracking catalyst

Номер: US20140042057A1
Автор: Mickael Bremaud, Pauline Galliou, Pierre Dufresne, Sharath Kirumakki
Принадлежит: Europeene de Retraitement de Catalysateurs EURECAT

The invention relates to a process for ex-situ treatment of a catalyst that contains at least one hydrogenating phase, and at least one amorphous silica-alumina or a zeolite that contains acid sites, whereby said process comprises: A stage for introducing nitrogen by contact at a temperature that is less than 100° C., with at least one basic nitrogen-containing compound that is ammonia or a compound that can be decomposed into ammonia, with said compound being introduced at a rate of 0.5-10% by weight (expressed in terms of N), and A sulfurization/activation stage with a gas that contains hydrogen and hydrogen sulfide at a temperature of at least 250° C., with this stage being carried out before or after the stage for introducing said nitrogen-containing compound, and the catalyst that is obtained is optionally dried. This treatment allows a rapid, effective start-up on the hydrocracking unit.

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Номер записи: 14
13-02-2014 дата публикации

Process for the Production of Hydrocarbons for Fuels, Solvents, and Other Hydrocarbon Products

Номер: US20140046101A1
Автор: Gregory Dicosola, Paul Ratnasamy, Sanjay Wagle
Принадлежит: University of Louisville Research Foundation ULRF

Catalytic processes for converting carboxylic acids obtained from biomass and other natural or industrial sources into paraffinic or olefinic hydrocarbons through decarboxylation, along with products formed from such hydrocarbons, in which the carbon chain length, the ratio of carbon-14 to carbon-12, and the ratio of odd number to even number of carbons in the chain are among factors which are indicative or otherwise useful for the detection of hydrocarbons formed by undergoing the claimed processes.

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Номер записи: 15
20-03-2014 дата публикации

CATALYST FOR USE IN HYDROTREATMENT, COMPRISING METALS FROM GROUPS VIII AND VIB, AND PREPARATION WITH CITRIC ACID AND C1-C4 DIALKYL SUCCINATE

Номер: US20140076780A1
Автор: Dath Jean-Pierre, DE GRANDI Valentina, GUICHARD Bertrand, Minoux Delphine, SIMON Laurent
Принадлежит:

A catalyst which comprises an amorphous support based on alumina, a C1-C4 dialkyl succinate, citric acid and optionally acetic acid, phosphorus and a hydrodehydrogenating function comprising at least one element from group VIII and at least one element from group VIB; the most intense bands comprised in the Raman spectrum of the catalyst are characteristic of Keggin heteropolyanions (974 and/or 990 cm), C1-C4 dialkyl succinate and citric acid (in particular 785 and 956 cm). Also a process for preparing said catalyst in which a catalytic precursor in the dried, calcined or regenerated state containing the elements of the hydrodehydrogenating function, and optionally phosphorus, is impregnated with an impregnation solution comprising at least one C1-C4 dialkyl succinate, citric acid and optionally at least one compound of phosphorus and optionally acetic acid, and is then dried. Further, the use of said catalyst in any hydrotreatment process. 1. A catalyst comprising an amorphous support based on alumina , at least one C1-C4 dialkyl succinate , citric acid , phosphorus and a hydrodehydrogenating function comprising at least one element from group VIB and at least one element from group VIII , with the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm , characteristic of at least one Keggin heteropolyanion , the characteristic bands of said succinate and the principal characteristic bands of citric acid.2. A catalyst according to claim 1 , in which the dialkyl succinate is dimethyl succinate and in which the Raman spectrum of the catalyst has principal bands at 990 and/or 974 cmcharacteristic of Keggin heteropolyanions claim 1 , and at 853 cm claim 1 , characteristic of dimethyl succinate and at 785 and 956 cm claim 1 , characteristic of citric acid.3. A catalyst according to claim 1 , also comprising acetic acid the Raman spectrum of which includes a line at 896 cm claim 1 , characteristic of acetic acid.4. A catalyst according to claim 1 , in which ...

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Номер записи: 16
03-01-2019 дата публикации

METHOD FOR KETONISATION OF BIOLOGICAL MATERIAL

Номер: US20190002382A1
Автор: KETTUNEN Mika, MYLLYOJA Jukka, Piilola Rami
Принадлежит: Neste Oyj

A method for producing ketones includes a) providing a feedstock of biological origin having fatty acids and/or fatty acid derivatives having an average chain length of 24 C-atoms or less; b) subjecting the feedstock to a catalytic ketonisation reaction in the presence of aK2O/TiO2-catalyst; and c) obtaining from the ketonisation reaction a product stream having ketones, which ketones have a longer average hydrocarbon chain length than the average hydrocarbon chain length in the feedstock, wherein step b) is carried out directly on the feedstock and in the presence of the K2O/TiO2-catalyst as the sole catalyst applied in the ketonisation reaction. 1. A method for producing ketones , which method comprises:a) providing a feedstock of biological origin containing fatty acids and/or fatty acid derivatives having an average chain length of 24 C-atoms or less;{'sub': 2', '2, 'b) subjecting said feedstock to a catalytic ketonisation reaction in a presence of a KO/TiO-catalyst; and'}c) obtaining from said ketonisation reaction a product stream containing ketones, which ketones have a longer average hydrocarbon chain length than the average hydrocarbon chain length in said feedstock;{'sub': 2', '2, 'wherein the subjecting is carried out directly on said feedstock and in a presence of said KO/TiO-catalyst as a sole catalyst applied in said ketonisation reaction.'}2. The method according to claim 1 , wherein the subjecting is carried out directly on said feedstock without preceding or simultaneous hydrogenation of double bonds present in the fatty acids and/or fatty acid derivatives in said feedstock.3. The method according to claim 1 , comprising:performing said ketonisation reaction by introducing the feedstock in liquid phase.4. The method according to claim 1 , wherein said feedstock of biological origin contains unsaturated fatty acids and/or fatty acid derivatives claim 1 , or esters.5. The method according to claim 1 , comprising:performing said ketonisation reaction ...

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Номер записи: 17
07-01-2016 дата публикации

COMMERCIAL FISCHER-TROPSCH REACTOR

Номер: US20160002541A1
Автор: BOHN MARK, HOGSETT FRANK, IBSEN Mark, MOHEDAS SERGIO, WRIGHT Harold A.
Принадлежит:

A method for converting synthesis gas into liquid hydrocarbons by introducing a synthesis gas feed into a Fischer-Tropsch system that includes a catalytic reactor fluidly connected with at least two slurry loops, the reactor comprising at least as many reactor product outlets and slurry return inlets as slurry loops; each slurry loop comprising a separation system comprising at least one separator, an inlet of each separator fluidly connected to a reactor product outlet via a slurry offtake, and an outlet of each separator fluidly connected to a slurry return inlet via a slurry return; separating concentrated catalyst slurry from the reaction product via the slurry loops; removing liquid hydrocarbon product from each separator; and returning concentrated catalyst slurry to the catalytic reactor via the slurry returns and slurry return inlets. A system for converting synthesis gas into liquid hydrocarbons via the method is also disclosed. 1. A method for converting synthesis gas into liquid hydrocarbons , the method comprising:introducing a synthesis gas feed into a Fischer-Tropsch reactor of a Fischer-Tropsch system at a superficial gas velocity greater than the average sedimentation velocity and/or greater than the minimum fluidization velocity of catalyst in the catalytic reactor, wherein the Fischer-Tropsch system comprises: a catalytic reactor fluidly connected with at least two slurry loops, wherein the reactor comprises at least as many reactor product outlets and at least as many slurry return inlets as slurry loops; wherein each slurry loop comprises a separation system comprising at least one separator for separating concentrated catalyst slurry from liquid product; an inlet of the at least one separator fluidly connected to one of the reactor product outlets via a slurry offtake, an outlet of the at least one separator fluidly connected to one of the slurry return inlets via a slurry return, and a product outlet of the at least one separator for removal of ...

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Номер записи: 18
27-01-2022 дата публикации

METHODS OF CO-PROCESSING PETROLEUM DISTILLATES AND BIO-BASED MATERIAL THROUGH A REACTION SERIES

Номер: US20220025279A1
Автор: Parker Dean E., Perrott Chad A., Rippstein Ryan A.
Принадлежит:

Methods of processing bio-based material feed (“bio-feed”) and a petroleum feed, using combinations of hydrotreating beds, dewaxing beds, post-treatment beds, and liquid quenching zones. Some methods comprise processing the petroleum feed through first hydrotreating reactor beds; then processing the output with a bio-feed together through second hydrotreating reactor beds; then processing the output through the plurality of dewaxing beds to create a dewaxed stream; and, processing the dewaxed stream through the plurality of post-treatment beds to create a product stream. Other methods comprise processing the petroleum feed through the plurality of first hydrotreating reactor beds; then processing the output through the plurality of dewaxing beds to create a dewaxed stream; and, processing the dewaxed stream and the bio-feed together through the plurality of liquid quenching beds zones to create a mixed stream; and, processing the mixed stream through the plurality of post-treatment beds to create a product stream. 1. A method of processing a bio-based material feed (“bio-feed”) and a petroleum feed , the method comprising: a plurality of first hydrotreating reactor beds;', 'a plurality of second hydrotreating reactor beds;', 'a plurality of dewaxing beds; and', 'a plurality of post-treatment beds; and, 'providing one or more reactors comprising, in seriesprocessing the petroleum feed through the plurality of first hydrotreating reactor beds to create a first hydrotreated stream;processing the first hydrotreated stream and the bio-feed together through the plurality of second hydrotreating reactor beds to create a second hydrotreated stream;processing the second hydrotreated stream through the plurality of dewaxing beds to create a dewaxed stream; and,processing the dewaxed stream through the plurality of post-treatment beds to create a product stream.2. The method of wherein first hydrotreating reactor beds and the second hydrotreating reactor beds each receive a ...

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Номер записи: 19
03-02-2022 дата публикации

MARINE FUEL BLEND

Номер: US20220033717A1
Автор: Kiiski Ulla, KOUVA Merja, KURONEN Markku, Nortio Jenni
Принадлежит: Neste Oyj

A marine fuel blend comprising renewable hydrotreated fuel is disclosed. The present marine fuel blend is environmentally friendly and has good pour point and storage stability. 1. A marine fuel blend comprising:{'sup': '3', 'DMB type or RMB type marine fuel having a density between 860 and 960 kg/mat 15° C.; and'}{'sub': 15', '18, '0.5-50 vol-% renewable hydrotreated fuel, wherein the renewable hydrotreated fuel includes paraffinic components in a carbon number range C-C, said paraffinic components constituting at least 70 vol-% of the renewable hydrotreated fuel; and'}wherein the marine fuel blend has a pour point which is at least 3° C. lower than a calculated pour point expressed as a weighted average of pour points of the marine fuel and the renewable hydrotreated fuel.2. The marine fuel blend of claim 1 , wherein the renewable hydrotreated fuel comprises:{'sub': 15', '18, 'paraffinic components in a carbon number range C-C, said paraffinic components constituting at least 80 vol-% of the renewable hydrotreated fuel.'}3. The marine fuel blend of claim 1 , having a sulphur content of 0.5 wt-% or less.4. The marine fuel blend of claim 1 , having a kinematic viscosity of max 6 cSt at 40° C. claim 1 , density of max 900 kg/mand a pour point of 6° C. or less claim 1 , and being a DMB type marine fuel.5. The marine fuel blend of claim 1 , having kinematic viscosity of max 30 cSt at 50° C. claim 1 , density of max 960 kg/mand pour point of 30° C. or less claim 1 , and being a RMB type marine fuel.6. The marine fuel blend of claim 1 , comprising:0.5-30 vol-% renewable hydrotreated fuel.7. The marine fuel blend of claim 1 , wherein the marine fuel blend has an oxidation stability which is higher than a calculated oxidation stability expressed as a weighted average of oxidation stability values of the marine fuel and the renewable hydrotreated fuel claim 1 , and wherein the oxidation stability is calculated as defined in EN16091 (2011).8. Method of manufacturing a marine ...

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Номер записи: 20
21-01-2021 дата публикации

HYDROPROCESSING OF HEAVY CRUDES BY CATALYSTS IN HOMOGENOUS PHASE

Номер: US20210017457A1
Автор: DOMÍNGUEZ ESQUIVEL José Manuel, PORTALES MARTINEZ Benjamin, SCHACHT HERNANDEZ Persi, SOTO ESCALANTE Ismael
Принадлежит:

This disclosure relates to a procedure, which through the application of a catalyst in homogeneous phase, allows the transformation of heavy hydrocarbons (vacuum residue, atmospheric residue, heavy and extra-heavy crudes) into hydrocarbons of lower molecular weight, characterized because after its application, the hydrocarbons obtain greater API gravity, lower kinematic viscosity and different composition by hydrocarbon families (SARA) that increases the proportion of saturated and aromatic resins and asphalts. The sulphur and nitrogen content is also reduced, resulting in higher yields to high commercial value distillates and a lighter product as compared to the original crude. 1. A catalyst to transform heavy and extra-heavy crude oils into lighter oils , wherein organic metal salts that includes a metal from one of Groups VIIB , VIB or IB are used for preparation of the catalyst.2. A catalyst in accordance with claim 1 , wherein the metal in the metal salt is one of Fe claim 1 , Co claim 1 , Ni claim 1 , Cu claim 1 , Mo claim 1 , or W.3. A procedure for the preparation of a catalyst claim 1 , comprising:1) mixing a mineral acid and ammonium salts, and shaking the mixture at a temperature of 25° C. until a clear solution is obtained, with a pH variation between 1 and 2;2) incorporating Nickel salts into the clear solution and solubilize at 40-100° C., then dissolving in water, and maintaining agitation of the solution for a time of 3 h at a temperature of 25° C., resulting in a green and translucent solution;3) storing the green and translucent solution in a closed container under ambient conditions; and [{'sub': '2', 'wherein the catalyst has a final molar ratio of 1.0 Ni, 0.084 Mo, 0.295 H+, 14.42 HO, at pH 1 to 3;'}, 'and wherein the catalyst transforms heavy and extra-heavy crude oils into lighter oils., '4) dehydrating the catalyst at 90° C.,'}4. The procedure for the preparation of a catalyst claim 3 , in accordance with claim 3 , wherein during preparation ...

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Номер записи: 21
08-02-2018 дата публикации

RAFFINATE HYDROCONVERSION FOR PRODUCTION OF HIGH PERFORMANCE BASE STOCKS

Номер: US20180037829A1
Автор: Calla Jason T., Fisher, Fortney Seth D., Joseck Eric D., JR. Will G.
Принадлежит:

Systems and methods are provided for production of base stocks with a viscosity index of at least 120 and/or a sulfur content of 300 wppm or less and/or a kinematic viscosity at 100° C. of 3.0 cSt to 8.0 cSt by hydroconversion of a raffinate from aromatic extraction of a feed. The base stocks can further have a reduced content of 3+ ring naphthenes, such as 4.0 wt % or less, or 1.0 wt % or less. The base stocks can be produced by performing an elevated amount of feed conversion relative to 370° C. during hydroconversion of the raffinate, and optionally additional conversion during catalytic dewaxing of the hydroconverted raffinate. The base stocks can optionally be blended with additional base stocks and/or lubricant additives for production of lubricant compositions. 1. A method for making a base stock , comprising:performing solvent extraction on a feedstock to form a raffinate comprising a solvent dewaxed viscosity index (VI) of 80 to 105 at a pour point of −18° C.;hydroconverting at least a portion of the raffinate under hydroconversion conditions to form a hydroconverted effluent, the hydroconversion conditions being effective for conversion of at least 15 wt % of the at least a portion of the raffinate relative to a conversion temperature of 370° C., the hydroconverted effluent comprising a VI at least 20 greater than the solvent dewaxed VI of the raffinate, a 343° C.+ portion of the hydroconverted effluent comprising a sulfur content of 50 wppm or less;separating at least a portion of the hydroconverted effluent to form at least a lower boiling fraction and a lubricant boiling range fraction having a T10 distillation point of at least 343° C.;dewaxing at least a portion of the lubricant boiling range fraction under catalytic dewaxing conditions to form a dewaxed effluent; andfractionating at least a portion of the dewaxed effluent to form a base stock comprising a viscosity index of greater than 120, a sulfur content of less than 300 wppm, and a saturates ...

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Номер записи: 22
12-02-2015 дата публикации

Hydrotreating process and apparatus relating thereto

Номер: US20150041365A1
Автор: David M. Bowman, Richard K. Hoehn, Soumendra Mohan Banerjee, Xin X. Zhu
Принадлежит: UOP LLC

One exemplary embodiment can be a process for treating a hydroprocessing fraction. The process can include obtaining a bottom stream from a fractionation zone, and passing at least a portion of the bottom stream to a film generating evaporator zone for separating a first stream containing less heavy polynuclear aromatic compounds than a second stream.

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Номер записи: 23
24-02-2022 дата публикации

METHOD TO PRODUCE HIGH QUALITY COMPONENTS FROM RENEWABLE RAW MATERIAL

Номер: US20220056351A1
Автор: Karvo Anna, Kiiski Ulla, RÄMÖ Virpi, ROUHIAINEN Maija
Принадлежит: Neste Oyj

The present disclosure relates to a method of producing high quality components from renewable raw material. Specifically, the disclosure relates to production of renewable materials which can be employed as high-quality chemicals and/or as high quality drop-in gasoline components. Further, the disclosure relates to drop-in gasoline components and to polymers obtainable by the method. 1. A method for producing renewable component(s) , the method comprising:a provision step of providing an isomeric raw material originating from a renewable source, wherein the isomeric raw material contains at least 60 wt.-% iso-paraffins;a cracking step of thermally cracking the isomeric raw material to produce a biohydrocarbon mixture containing C4 olefins; anda reaction step of reacting at least a part of the C4 olefins to produce the renewable component(s).2. The method according to claim 1 , wherein said renewable component(s) are drop-in gasoline component(s) having a high octane number.3. The method according to claim 1 , wherein said renewable component(s) are bio-monomer(s) or bio-polymer(s) claim 1 , with at least one selected from the group consisting of butyl rubber claim 1 , methyl methacrylate claim 1 , polymethyl methacrylate claim 1 , polyisobutylene claim 1 , substituted phenol claim 1 , and polybutene.4. The method according to claim 1 , wherein the mixture containing C4 olefins contains at least isobutene and the reaction step of reacting at least a part of the C4 olefins is a step of reacting at least a part of the isobutene to produce the renewable component(s).5. The method according to claim 1 , wherein the isomeric raw material is selected to contain at least one or more of at least 70 wt.-% claim 1 , at least 75 wt.-% claim 1 , at least 80 wt.-% claim 1 , at least 83 wt.-% claim 1 , at least 85 wt.-% claim 1 , at least 90 wt.-% claim 1 , and/or at least 95 wt.-% iso-paraffins.6. The method according to claim 1 , wherein the iso-paraffins contain multi-branched ...

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Номер записи: 24
07-02-2019 дата публикации

Process and installation for the conversion of crude oil to petrochemicals having an improved propylene yield

Номер: US20190039969A1
Автор: Andrew Mark Ward, Arno Johannes Maria OPRINS, Egidius Jacoba Maria SCHAERLAECKENS, Raul Velasco Pelaez, Ravichander Narayanaswamy, Vijayanand RAJAGOPALAN
Принадлежит: SABIC Global Technologies BV, Saudi Basic Industries Corp

The present invention relates to an integrated process to convert crude oil into petrochemical products comprising crude oil distillation, aromatic ring opening, and olefins synthesis, which process comprises subjecting a hydrocarbon feed to aromatic ring opening to produce LPG and subjecting the LPG produced in the integrated process to olefins synthesis. Furthermore, the present invention relates to a process installation to convert crude oil into petrochemical products comprising a crude distillation unit comprising an inlet for crude oil and at least one outlet for kerosene and/or gasoil; an aromatic ring opening unit comprising an inlet for a hydrocarbon feed to aromatic ring opening and an outlet for LPG; and a unit for the olefins synthesis comprising an inlet for LPG produced by the integrated petrochemical process installation and an outlet for olefins. The hydrocarbon feed subjected to aromatic ring opening comprises kerosene and/or gasoil produced by crude oil distillation in the process; and refinery unit-derived middle-distillate produced in the process. The process and the process installation of the present invention have an increased production of petrochemicals at the expense of the production of fuels and an improved propylene yield.

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Номер записи: 25
07-02-2019 дата публикации

PROCESS AND INSTALLATION FOR THE CONVERSION OF CRUDE OIL TO PETROCHEMICALS HAVING AN IMPROVED PROPYLENE YIELD

Номер: US20190039970A1
Автор: Narayanaswamy Ravichander, OPRINS Arno Johannes Maria, Rajagopalan Vijayanand, SCHAERLAECKENS Egidius Jacoba Maria, VELASCO PELAEZ Raul, Ward Andrew Mark
Принадлежит:

The present invention relates to an integrated process to convert crude oil into petrochemical products comprising crude oil distillation, aromatic ring opening, and olefins synthesis, which process comprises subjecting a hydrocarbon feed to aromatic ring opening to produce LPG and subjecting the LPG produced in the integrated process to olefins synthesis. Furthermore, the present invention relates to a process installation to convert crude oil into petrochemical products comprising a crude distillation unit comprising an inlet for crude oil and at least one outlet for kerosene and/or gasoil; an aromatic ring opening unit comprising an inlet for a hydrocarbon feed to aromatic ring opening and an outlet for LPG; and a unit for the olefins synthesis comprising an inlet for LPG produced by the integrated petrochemical process installation and an outlet for olefins. The hydrocarbon feed subjected to aromatic ring opening comprises kerosene and/or gasoil produced by crude oil distillation in the process; and refinery unit-derived middle-distillate produced in the process. The process and the process installation of the present invention have an increased production of petrochemicals at the expense of the production of fuels and an improved propylene yield. 17-. (canceled)8. A process installation to convert crude oil into petrochemical products comprisinga crude distillation unit comprising an inlet for crude oil and at least one outlet for kerosene and/or gasoil;an aromatic ring opening unit comprising an inlet for a hydrocarbon feed to aromatic ring opening and an outlet for LPG; anda unit for olefins synthesis comprising an inlet for LPG produced by the integrated petrochemical process installation and an outlet for olefins, kerosene and/or gasoil produced by the crude oil distillation unit; and', 'refinery unit-derived middle-distillate produced the integrated petrochemical process installation., 'wherein said hydrocarbon feed to aromatic ring opening comprises9. The ...

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Номер записи: 26
16-02-2017 дата публикации

Production of alternative gasoline fuels

Номер: US20170044443A1
Автор: Paul Blommel, Richard Price
Принадлежит: Virent Inc

A method for producing an alternative gasoline fuel which contains 60% v/v or more of a combination of (a) a biologically-derived alcohol and (b) a mixture of C 4 to C 12 hydrocarbon fuel components, all of which hydrocarbon fuel components have been derived, whether directly or indirectly, from the catalytic conversion of a non-petroleum or biologically-derived oxygenate component, wherein the concentration of the alcohol (a) in the formulation is from 0.1 to 30% v/v.

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Номер записи: 27
15-02-2018 дата публикации

Methods of Refining Natural Oil Feedstocks

Номер: US20180044597A1
Автор: Balakrishnan Chander, Cohen Steven A., Jr. Melvin L., Luetkens, Snyder Robert
Принадлежит: ELEVANCE RENEWABLE SCIENCES, INC.

Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise hydrogenating the olefins under conditions sufficient to form a fuel composition. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product. 119-. (canceled)20. A method of producing a fuel composition comprising:providing a feedstock comprising natural oil glycerides, and (b) low-molecular-weight olefins;reacting the natural oil glycerides with the low-molecular-weight olefins in the presence of a metathesis catalyst to form a metathesized product comprising olefins and esters;separating at least a portion of the olefins in the metathesized product from the esters in the metathesized product; andhydrogenating the separated olefins to form a fuel composition.21. The method of claim 20 , wherein the fuel composition is: (a) a kerosene-type jet fuel having a carbon number distribution between 8 and 16 claim 20 , a flash point between 38° C. and 66° C. claim 20 , an auto ignition temperature of 210° C. claim 20 , and a freeze point between −47° C. and −40° C.; (b) a naphtha-type jet fuel having a carbon number distribution between 5 and 15 claim 20 , a flash point between −23° C. and 0° C. claim 20 , an auto ignition temperature of 250° C.; and a freeze point of −65° C.; or (c) a diesel fuel having a carbon number distribution between 8 and 25 claim 20 , a specific gravity of between 0.82 and 1.08 at 15.6° C. claim 20 , a cetane number of greater than 40; and a distillation range between 180° C. and 340° C.22. The method of claim 20 , further comprising flash-separating a light end ...

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Номер записи: 28
23-02-2017 дата публикации

Catalytic system for preparation of high branched alkane from olefins

Номер: US20170051222A1
Автор: Junfang Li, Wenjie Tao, Xiuli Sun, Yong Tang, Zheng Wang
Принадлежит: Shanghai Institute of Organic Chemistry of CAS

The present invention discloses a catalytic system for preparing highly branched alkane from olefin, which contains novel nickel or palladium complexes. In the presence of the catalytic system, highly branched oily alkane mixture can be efficiently obtained from olefins (such as ethylene) under mild conditions. The alkane mixture has a low bromine number, and can be used as a processing aid(s) and lubricant base oil with high-performance. Provides also was a method for preparing the catalyst and a method for preparing an oily olefin polymer.

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Номер записи: 29
26-02-2015 дата публикации

Process for producing biofuel and biofuel components

Номер: US20150057474A1
Автор: Andrea Gutierrez, Arto Rissanen, Heli Laumola, Jaakko Nousiainen, Pekka Knuuttila, Teemu Lindberg
Принадлежит: UPM Kymmene Oy

A process for catalytically converting crude tall oil into hydrocarbons suitable as biofuel components. The crude tall oil is treated in a reactor system including a catalytically active guard bed phase and a catalytically active main reaction phase. At least one of the phases includes a catalyst bed with a combination of hydrodeoxygenating (HDO) and hydrodewaxing (HDW) catalysts. The process provides biofuel with acceptable ignition and cold flow properties.

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Номер записи: 30
04-03-2021 дата публикации

APPARATUS FOR CATALYTIC REFORMING HYDROCARBONS HAVING FLOW DISTRIBUTOR AND PROCESS FOR REFORMING HYDROCARBONS

Номер: US20210060509A1
Автор: Grott Jeffrey, Lok Ka Leung, Maley John C., Tiwari Amresh Kumar
Принадлежит:

A reforming reactor and process of using same in which a flow distributor distributes the process gas circumferentially to the reactive zone. Feed is injected into the reactor into a non-reactive zone. The non-reactive zone has two portions, a first portion receiving the feed, and a second portion receiving a purge gas. The purge gas will flow from the second portion to the first portion to prevent flow of the feed from the first portion to the second portion. The combined gas may be passed to a reaction zone for catalytic reforming. The first portion and the second portion may be separated by a flow distributor having two horizontal portions connected to opposite ends of a vertical portion. 1. A radial flow reactor comprising:a non-reactive zone separated into a first portion and a second portion by a flow distributor, wherein the flow distributor comprises a first horizontal portion, a second horizontal portion, and a first vertical portion connecting the first and second horizontal portions, and wherein the second horizontal portion comprises, when viewed from a top, a sector shape;a reaction zone disposed below the non-reactive zone and separated from the non-reactive zone by a plate;an inlet for a hydrocarbon feed stream in the non-reactive zone; and,an outlet for an effluent stream in the non-reactive zone, the outlet in fluid communication with the reaction zone.2. The radial flow reactor of claim 1 , wherein the inlet and the outlet are both disposed within the second portion of the non-reactive zone.3. The radial flow reactor of claim 1 , wherein the second horizontal portion comprises a plurality of sections claim 1 , each having claim 1 , when viewed from a top claim 1 , a sector shape.4. The radial flow reactor of claim 1 , wherein the first horizontal portion comprises an upper horizontal portion and the second horizontal portion comprises a lower horizontal portion.5. The radial flow reactor of claim 4 , wherein the flow distributor further comprises a ...

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Номер записи: 31
04-03-2021 дата публикации

METALLURGY FOR PROCESSING BIORENEWABLE FEED

Номер: US20210060516A1
Автор: Liu Xiaodong, Mucek Mark W., Wexler James T., Wozniak Christopher M.
Принадлежит:

A process and apparatus for hydroprocessing a biorenewable feedstock involves an advantageous metallurgy. The biorenewable feed stream is hydrotreated in a hydrotreating reactor comprising a stainless steel having a composition of at least about 2 wt-% molybdenum which is sufficiently resistant to acidic corrosion. The hydrotreated biorenewable stream is hydroisomerized in a hydroisomerization reactor comprising a stainless steel having a composition of less than about 2 wt-% molybdenum. Most of the free fatty acids are deoxygenated in the hydrotreating reactor to make water, thus avoiding exposure of downstream equipment to acid attack. The stainless steel of said hydrotreating reactor may have a composition of no more than about 0.02 wt-% carbon. 1. A process for hydroprocessing a biorenewable feedstock , the process comprising:hydrotreating a biorenewable feed stream in a hydrotreating reactor in the presence of hydrogen to saturate olefins, deoxygenate oxygenated hydrocarbons and demetallize metallized hydrocarbons to produce a hydrotreated stream, said hydrotreating reactor comprising a stainless steel having a composition of at least about 2 wt-% molybdenum; andhydroisomerizing the hydrotreated stream in a hydroisomerization reactor over a hydroisomerization catalyst in the presence of a hydroisomerization hydrogen stream to provide a hydroisomerized stream, said hydroisomerization reactor comprising a steel having a composition of less than about 2 wt-% molybdenum.2. The process of wherein the steel of said hydroisomerization reactor has a composition of no more than about 1.2 wt-% molybdenum.3. The process of wherein the steel of said hydroisomerization reactor has a composition of no less than about 0.3 wt-% molybdenum.4. The process of wherein the stainless steel of said hydrotreating reactor has a composition of at least about 3 wt-% molybdenum.5. The process of wherein the stainless steel of said hydrotreating reactor has a composition of no more than ...

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Номер записи: 32
03-03-2016 дата публикации

USE OF RENEWABLE OIL IN HYDROTREATMENT PROCESS

Номер: US20160060540A1
Автор: LINDQVIST Petri, OUNI Tuomas, SIPPOLA Väinö
Принадлежит: Neste Oil Oyi

The use of bio oil from at least one renewable source in a hydrotreatment process, in which process hydrocarbons are formed from said glyceride oil in a catalytic reaction, and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron. A bio oil intermediate including bio oil from at least one renewable source and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron. 1. A method for preparing a hydrocarbon , the method comprising:subjecting a bio oil from at least one renewable source to a hydrotreatment process, wherein in the hydrotreatment process, hydrocarbons are formed from said bio oil in a catalytic reaction employing a catalyst,wherein an iron content of said bio oil is less than 1 w-ppm calculated as elemental iron.2. The method according to claim 1 , wherein the iron content of said bio oil is less than 0.5 w-ppm calculated as elemental iron.3. The method according to claim 1 , wherein the bio oil is selected from the group consisting of rapeseed oil claim 1 , colza oil claim 1 , canola oil claim 1 , tall oil claim 1 , sunflower oil claim 1 , soybean oil claim 1 , hempseed oil claim 1 , cottonseed oil claim 1 , corn oil claim 1 , olive oil claim 1 , linseed oil claim 1 , mustard oil claim 1 , palm oil claim 1 , peanut oil claim 1 , castor oil claim 1 , coconut oil claim 1 , camellia oil claim 1 , jatropha oil claim 1 , an oil derived from a microbial source claim 1 , animal fat claim 1 , fish oil claim 1 , lard claim 1 , tallow claim 1 , train oil claim 1 , recycled fat from the food industry claim 1 , and a mixture thereof.4. The method according to claim 1 , wherein the hydrocarbons formed in the hydrotreatment process are further processed in a hydroisomerisation process to iso-paraffins.5. The method according to claim 1 , wherein the hydrotreatment process is a hydrodeoxygenation process using a trickle-bed reactor.6. The method according to claim 1 , wherein plugging of the catalyst used in the ...

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Номер записи: 33
21-02-2019 дата публикации

PROCESS FOR PRODUCING MONOAROMATIC HYDROCARBONS FROM A HYDROCARBON FEED COMPRISING POLYAROMATICS

Номер: US20190055479A1
Автор: Aramburo Luis, VAN KIMMENADE Emiel
Принадлежит:

The present invention relates to a process for producing monoaromatic hydrocarbons from a hydrocarbon feed comprising polyaromatics, the process comprising contacting the feed at process conditions with a catalyst comprising a mixture of zeolite Y and a hydrogenation catalyst comprising one or more hydrogenation metals on a solid catalyst support. 1. A process for producing monoaromatic hydrocarbons from a hydrocarbon feed comprising polyaromatics , the process comprising:{'sup': '−1', 'sub': 2', '2', '2', '3, 'contacting the feed at process conditions comprising a temperature of 350-550° C., a pressure of 2000-7000 kPa, a WHSV of 0.1-10 hand a H/HC molar ratio of 3-12, with a catalyst comprising a mixture of zeolite Y having a SiO/AlOratio of 10-80 and a hydrogenation catalyst comprising a hydrogenation metal on a solid catalyst support, wherein said hydrogenation catalyst is selected from the group consisting ofa catalyst comprising: 1-30 wt-% of Mo and/or W, based on the total weight of the hydrogenation catalyst and, 0.1-10 wt-% of Co and/or Ni, based on the total weight of the hydrogenation catalyst; anda catalyst comprising 0.05-2 wt-% of an element selected from Groups 8-10 of the Periodic Table of Elements, based on the total weight of the hydrogenation catalyst.2. The process according to claim 1 , wherein the process conditions comprise a temperature of 400-475° C.3. The process according to claim 1 , wherein the zeolite Y has a SiO/AlOratio of 10-40 claim 1 , and the process conditions comprise a pressure of 2000-7000 kPa.4. The process according to claim 1 , wherein the zeolite Y has a SiO/AlOratio of 40-80 claim 1 , the hydrogenation catalyst comprises 0.05-2 wt-% based on the total weight of the hydrogenation catalyst of one or more elements selected from Groups 8-10 of the Periodic Table of Elements and the process conditions comprise a pressure of 4000-7000 kPa.5. The process according to claim 1 , wherein the hydrogenation catalyst comprises 3-20 wt ...

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Номер записи: 34
01-03-2018 дата публикации

MIXING DEVICE FOR A DOWN-FLOW HYDROPROCESSING REACTOR

Номер: US20180057757A1
Автор: Breig Timothy D., Krishniah Parimi, Safford Brett Michael, Song Steve Xugi
Принадлежит:

An improved vortex-type mixing device for a down-flow hydroprocessing reactor is described. The device provides improved overall mixing efficiency of an existing mixing volume in the mixing of gas and liquid phases in two-phase systems while reducing the pressure drop through the device, as compared with prior art devices. Typical hydroprocessing applications include hydrotreating, hydrofinishing, hydrocracking and hydrodewaxing. 1. A mixing device for a multi-bed down-flow catalytic reactor , the mixing device comprising:a. a top plate having an inner surface and a periphery;b. a base plate extending parallel to the top plate, the base plate having an inner surface, a periphery, and a base plate aperture, wherein the top and base plates are separated by a distance to define an interior region of the mixing device;c. a plurality of inwardly-directed vanes contained within the interior region of the mixing device extending perpendicular to and interposed between the inner surfaces of the top and base plates, wherein the vanes are inwardly-directed from the periphery of the top and base plates toward the base plate aperture and are spaced around the area extending from the base plate aperture to the periphery of the top and base plates; andd. a mixing region;wherein, the mixing device does not include a weir ring extending from the inner surface of the base plate or a bubble cap extending from the inner surface of the top plate.2. The mixing device of claim 1 , wherein the base plate aperture is circular.3. The mixing device of claim 1 , wherein the vanes are straight or curved.4. The mixing device of claim 3 , wherein the vanes are inwardly-curved.5. The mixing device of claim 1 , wherein each vane comprises an outer end proximal to the periphery of the top plate and an interior end proximal to the mixing region claim 1 , the mixing device further comprising a plurality of inlet regions defined as an area bound by neighboring vanes and the corresponding interior end ...

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Номер записи: 35
02-03-2017 дата публикации

A METHOD OF CONTROLLING THE SUPPLY AND ALLOCATION OF HYDROGEN GAS IN A HYDROGEN SYSTEM OF A REFINERY INTEGRATED IWTH OLEFINS AND AROMATICS PLANTS

Номер: US20170058213A1
Автор: Narayanaswamy Ravichander, OPRINS Arno Johannes Maria, Rajagopalan Vijayanand, SCHAERLAECKENS Egidius Jacoba Maria, VAN WILLIGENBURG Joris, VELASCO PELAEZ Raul, Ward Andrew Mark
Принадлежит: SAUDI BASIC INDUSTRIES CORPORATION

A method of controlling the supply and allocation of hydrogen gas in a hydrogen system of a refinery integrated with olefins and aromatics plants to convert crude oil into petrochemicals. The method includes one or more supply sources that provide hydrogen at individual rates, purities, pressures and costs, multiple consumption sites that consume hydrogen at individual rates, purities and pressures and an interconnecting hydrogen distribution network. The method further includes the integration of hydrogen consuming process units with hydrogen producing process units in which hydrogen recovered from the effluents from the hydrogen consuming process units and hydrogen recovered from the hydrogen producing process units are re-used in the hydrogen consuming process units. 1. A method of controlling supply and allocation of hydrogen gas in a hydrogen system of a refinery integrated with olefins and aromatics plants to convert crude oil into petrochemicals , comprising one or more supply sources that provide hydrogen at individual rates , purities , pressures and costs , multiple consumption sites that consume hydrogen at individual rates , purities and pressures and an interconnecting hydrogen distribution network , said method comprising the integration of hydrogen consuming process units with hydrogen producing process units , wherein both hydrogen recovered from the effluents from the hydrogen consuming process units and hydrogen recovered from the hydrogen producing process units are re-used in the hydrogen consuming process units , wherein a crude oil fraction is used as a feed for the hydrogen consuming process units , wherein at least 25 wt % of said feed is converted into a low boiling hydrocarbon fraction comprising ethane , propane and butanes , wherein said hydrogen producing process units comprise a steam cracking unit and one or more units chosen from propane dehydrogenation unit (PDH) , a butane dehydrogenation unit (BDH) and a combined PDH and BDH unit.2 ...

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Номер записи: 36
02-03-2017 дата публикации

Process and installation for the conversion of crude oil to petrochemicals having an improved ethylene and btx yield

Номер: US20170058214A1
Автор: Andrew Mark Ward, Arno Johannes Maria OPRINS, Egidius Jacoba Maria SCHAERLAECKENS, Joris VAN WILLIGENBURG, Raul Velasco Pelaez, Ravichander Narayanaswamy, Vijayanand RAJAGOPALAN
Принадлежит: Individual

The present invention relates to an integrated process to convert crude oil into petrochemical products comprising crude oil distillation, hydrocracking, aromatization and olefins synthesis. Furthermore, the present invention relates to a process installation to convert crude oil into petrochemical products comprising a crude distillation unit, a hydrocracker, an aromatization unit and a unit for olefins synthesis.

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Номер записи: 37
04-03-2021 дата публикации

A RENEWABLE, HIGHLY ISOPARAFFINIC DISTILLATE FOR SOLVENT USE

Номер: US20210062015A1
Автор: Karvo Anna, Nortio Jenni, RÄMÖ Virpi, Sandberg Kati
Принадлежит: Neste Oyj

A renewable solvent composition having a high i-paraffin content of at least 91.0 wt.-% and a boiling in a range of from 150° C. to 260° C. is disclosed. The solvent composition can provide a good balance between solvency power and cold properties and is usable in a broad application field. 1. A solvent composition , comprising:91.0 wt.-% or more i-paraffins, the solvent composition having a boiling point in a range of 150° C. to 260° C., wherein the solvent composition is a derivation of a renewable raw material.2. The solvent composition according to claim 1 , which comprises:more than 50.0 wt.-% dimethylated, trimethylated or higher methylated i-paraffins relative to all i-paraffins in the solvent composition.3. The solvent composition according to claim 1 , wherein a content of C5 to C16 paraffins is 90 wt.-% or more relative to the solvent composition as a whole.4. The solvent composition according to claim 1 , which has at least one of a freezing point of −50° C. or below claim 1 , or an aniline point of 85° C. or below.5. The solvent composition according to claim 1 , which has an Kauri-butanol (KB) number of 21.5 or higher.6. The solvent composition according to claim 1 , wherein content of i-paraffins in the solvent composition is at least one of 92.0 wt.-% or higher claim 1 , 93.0 wt.-% or higher claim 1 , 94.0 wt.-% or higher claim 1 , 95.0 wt.-% or higher claim 1 , 96.0 wt.-% or higher claim 1 , 97.0 wt.-% or higher claim 1 , 97.5 wt.-% or higher claim 1 , or 98.0 wt.-% or higher.7. The solvent composition according to claim 1 , comprising:at least one of than 55.0 wt.-%, or more than 60.0 wt.-%, dimethylated, trimethylated or higher methylated i-paraffins relative to all i-paraffins in the solvent composition.8. The solvent composition according to claim 1 , wherein the content of C5 to C16 paraffins is at least one of 95 wt.-% or more claim 1 , or 99 wt.-% or more claim 1 , relative to the solvent composition as a whole.9. A method of applying a ...

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Номер записи: 38
04-03-2021 дата публикации

METHOD AND APPARATUS FOR ENCODING AND DECODING HDR IMAGES

Номер: US20210062095A9
Автор: BOITARD Ronan, GUILLEMOT CHRISTINE, LE PENDU MIKAEL, Thoreau Dominique
Принадлежит:

To encode High Dynamic Range (HDR) images, the HDR images can be converted to Low Dynamic Range (LDR) images through tone mapping operation, and the LDR images can be encoded with an LDR encoder. The present principles formulates a rate distortion minimization problem when designing the tone mapping curve. In particular, the tone mapping curve is formulated as a function of the probability distribution function of the HDR images to be encoded and a Lagrangian multiplier that depends on encoding parameters. At the decoder, based on the parameters indicative of the tone mapping function, an inverse tone mapping function can be derived to reconstruct HDR images from decoded LDR images. 1. A method comprising:determining a tone mapping function responsive to images and at least one encoding parameter;determining a lower dynamic range version of said images from said images responsive to the tone mapping function;encoding the lower dynamic range version of said images and information including a parameter used to encode the determined lower dynamic range version of said images, said parameter being intended to be used for generating an inverse ton-mapping function; andtransmitting the encoded lower dynamic range version of said images and information in one or more signals.2. The method of claim 1 , wherein the parameter used to encode the lower dynamic range version of said images is a quantization parameter.3. The method of claim 2 , wherein the tone curve estimator determines a Lagrangian multiplier responsive to the quantization parameter.4. The method of claim 1 , wherein determining a tone mapping function comprises determining at least one of the dynamic range of said images and a probability distribution function of said images.5. The method of claim 1 , wherein determining the tone mapping function is responsive to a rate distortion function.6. The method of further comprising providing said one or more signals signal for storage.7. The method of further ...

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Номер записи: 39
05-03-2015 дата публикации

Diesel fuel or diesel fuel base stock and production method thereof

Номер: US20150065761A1
Автор: Marie Iwama, Takuya Niitsuma
Принадлежит: Cosmo Oil Co Ltd, Inpex Corp, Japan Oil Gas and Metals National Corp, Japan Petroleum Exploration Co Ltd, JX Nippon Oil and Energy Corp, Nippon Steel and Sumikin Engineering Co Ltd

Provided is a hydrotreating step (A) containing a hydroisomerization step (A1) that obtains a hydroisomerized oil (a1) by bringing a FT synthesis oil into contact with a hydroisomerization catalyst and/or a hydrocracking step (A2) that obtains a hydrocracked oil (a2) by bringing it into contact with a hydrocracking catalyst, and a fractionation step (B) that transfers at least a portion of the hydrotreated oil (a) composed of the hydroisomerized oil (a1) and/or the hydrocracked oil (a2) to a fractionator and, at the very least, obtains a middle distillate (b1) with a 5% distillation point of 130 to 170° C. and a 95% distillation point of 240 to 300° C., and a heavy oil (b2) that is heavier than the middle distillate (b1).

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Номер записи: 40
28-02-2019 дата публикации

Crystalline transition metal molybdotungstate process data system

Номер: US20190060880A1
Автор: Stuart R. Miller, Susan C. Koster
Принадлежит: UOP LLC

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed.

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Номер записи: 41
28-02-2019 дата публикации

CRYSTALLINE TRANSITION METAL MOLYBDOTUNGSTATE PROCESS DATA SYSTEM

Номер: US20190060881A1
Автор: Koster Susan C., Miller Stuart R.
Принадлежит:

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of at least one unit or stream in fluid communication with and downstream from or upstream to a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed. 2. The system of further comprising an Input/Output device to collect the data claim 1 , or evaluate the date claim 1 , or correlate the data claim 1 , or any combination thereof.3. The system of further comprising a transmitter to transmit a signal to the conversion process.4. The system of wherein the signal comprises instructions.5. The system of wherein the signal comprises instructions regarding an adjustment to a parameter.6. The system of further comprising collecting data from multiple systems wherein one system is the parameter data system.7. The system of wherein the processor is configured to generate predictive information or quantitative information.8. The system of wherein the at least one unit or stream is not in direct fluid communication with the conversion process.10. The method of wherein the conversion process is hydroprocessing.11. The method of wherein the conversion process is hydrodenitrification claim 9 , or hydrodesulfurization claim 9 , or hydrodemetallation claim 9 , or hydrodesilication claim 9 , or hydrodearomatization claim 9 , or hydroisomerization claim 9 , or hydrotreating claim 9 , or hydrofining ...

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Номер записи: 42
17-03-2022 дата публикации

TWO-STAGE HYDROCRACKING PROCESS COMPRISING A HYDROGENATION STAGE DOWNSTREAM OF THE SECOND HYDROCRACKING STAGE, FOR THE PRODUCTION OF MIDDLE DISTILLATES

Номер: US20220081628A1
Автор: DUBREUIL Anne-Claire, Guillon Emmanuelle, Pirngruber Gerhard
Принадлежит: IFP ENERGIES NOUVELLES

The invention relates to the implementation of a multi-stage hydrocracking process comprising a hydrogenation stage located downstream of the second hydrocracking stage, said hydrogenation stage treating the effluent produced in the second hydrocracking stage, in the presence of a specific hydrogenation catalyst. In addition, the hydrogenation and second hydrocracking stages are implemented under specific operating conditions and particularly under very specific temperature conditions. 1. Process for producing middle distillates from hydrocarbon feedstocks containing at least 20% by volume of compounds boiling above 340° C. , said process comprising the following steps:{'sup': '−1', 'a) a step of hydrotreating said feedstocks in the presence of hydrogen and at least one hydrotreating catalyst, at a temperature of between 200° C. and 450° C., under a pressure of between 2 and 25 MPa, at a space velocity of between 0.1 and 6 hand with an amount of hydrogen introduced such that the litre of hydrogen/litre of hydrocarbon volume ratio is between 100 and 2000 Nl/l,'}{'sup': '−1', 'b) a step of hydrocracking at least one portion of the effluent resulting from step a), the hydrocracking step b) taking place, in the presence of hydrogen and at least one hydrocracking catalyst, at a temperature of between 250° C. and 480° C., under a pressure of between 2 and 25 MPa, at a space velocity of between 0.1 and 6 hand with an amount of hydrogen introduced such that the litre of hydrogen/litre of hydrocarbon volume ratio is between 80 and 2000 Nl/l,'}c) a step of high-pressure separation of the effluent resulting from the hydrocracking step b) to produce at least a gaseous effluent and a liquid hydrocarbon effluent, a gaseous fraction,', 'at least one petroleum fraction having at least 80% by volume of products boiling at a temperature below 150° C.,', 'at least one middle distillates fraction having at least 80% by volume of products having a boiling point between 150° C. and 380° ...

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Номер записи: 43
09-03-2017 дата публикации

Methods of Refining Natural Oil Feedstocks

Номер: US20170066972A1
Автор: Chander Balakrishnan, Melvin L. Luetkens, Jr., Robert Snyder, Steven A. Cohen
Принадлежит: Elevance Renewable Sciences Inc

Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise hydrogenating the olefins under conditions sufficient to form a fuel composition. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.

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Номер записи: 44
28-02-2019 дата публикации

CRYSTALLINE TRANSITION METAL TUNGSTATE PROCESS DATA SYSTEM

Номер: US20190065695A1
Автор: Koster Susan C., Miller Stuart R.
Принадлежит:

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal tungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal tungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed. 2. The system of further comprising an Input/Output device to collect the data claim 1 , or evaluate the date claim 1 , or correlate the data claim 1 , or any combination thereof.3. The system of further comprising a transmitter to transmit a signal to the conversion process.4. The system of wherein the signal comprises instructions.5. The system of wherein the signal comprises instructions regarding an adjustment to a parameter.6. The system of further comprising collecting data from multiple systems wherein one system is the parameter data system.7. The system of wherein the processor is configured to generate predictive information or quantitative information.9. The system of further comprising an Input/Output device to collect the data claim 8 , or evaluate the date claim 8 , or correlate the data claim 8 , or any combination thereof.10. The system of further comprising a transmitter to transmit a signal to the conversion process.11. The system of wherein the signal comprises instructions.12. The system of wherein the signal comprises instructions regarding an adjustment to a parameter.13. The system of further comprising collecting data from multiple systems wherein one system is the parameter data system.14. The system of wherein ...

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Номер записи: 45
17-03-2016 дата публикации

Production of hydrocarbons from plant oil and animal fat

Номер: US20160076157A1
Автор: Dzmitry MALEVICH, Graham Thomas Thornton Gibson
Принадлежит: ALTRANEX Corp

Oils from plants and animal fats are hydrolyzed to fatty acids for a Kolbe reaction. The invention relates to a high productivity Kolbe reaction process for electrochemically decarboxylating C4-C28 fatty acids derived from sources selected based on their saturated and unsaturated fatty acid content in order to lower anodic passivation voltage during synthesis of C6-C54 hydrocarbons. The C6-C54 hydrocarbons may undergo olefin metathesis and/or hydroisomerization reaction processes to synthesize heavy fuel oil, diesel fuel, kerosene fuel, lubricant base oil, and linear alpha olefin products useful as precursors for polymers, detergents, and other fine chemicals.

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Номер записи: 46
07-03-2019 дата публикации

INTEGRATED ISOMERIZATION AND HYDROTREATING APPARATUS

Номер: US20190071609A1
Автор: KOSEOGLU Omer Refa
Принадлежит:

Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by with an apparatus arranged for flashing the feed at a target cut point temperature to obtain two fractions. A low boiling temperature fraction contains refractory, sterically hindered sulfur-containing compounds, which have a boiling point at or above the target cut point temperature. A high boiling temperature fraction, having a boiling point below the target cut point temperature, is substantially free of refractory sulfur-containing compounds. The high boiling temperature fraction is contacted with isomerization catalyst, and the isomerized effluent and the low boiling temperature fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. 1. An apparatus for processing a hydrocarbon feed containing undesired organosulfur compounds comprising:a fractionating column operable to flash the hydrocarbon feed including an inlet for receiving the hydrocarbon feed, a low boiling temperature outlet for discharging a low boiling temperature fraction containing labile organosulfur compounds, and a high boiling temperature outlet for discharging a high boiling temperature fraction containing refractory organosulfur compounds;an isomerization reaction zone in fluid communication with a source of hydrogen and the high boiling temperature outlet, and an isomerization reaction zone outlet for discharging a high boiling temperature fraction having isomerized compounds with steric hindrance removed, the and isomerization reaction zone containing isomerization catalyst possessing an acidity of at least 15 times more than the acidity of amorphous silica-alumina catalyst at a temperature of 260° C. and is selected from the group consisting of ...

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Номер записи: 47
24-03-2022 дата публикации

PROCESS AND A SYSTEM FOR PRODUCTION OF MULTIPLE GRADE DE-AROMATIZED SOLVENTS FROM HYDROCARBON STREAMS

Номер: US20220089960A1
Автор: Butley Ganesh Vitthalrao, HIMA BINDU Vasamsetty Naga Veera, Kapur Gurpreet Singh, KARUMANCHI Ramesh, Kumar Sarvesh, RAMAKUMAR Sankara Sri Venkata, Sarkar Mainak, Sau Madhusudan
Принадлежит: INDIAN OIL CORPORATION LIMITED

A process and a system are used for production of multiple grades of ultralow aromatic solvents/chemicals having preferred boiling range, flash point and viscosity from different hydrocarbon streams. A plurality of hydrotreating steps are used to hydrotreat a plurality of hydrocarbon feedstocks in the presence of a hydrogen gas stream and a catalyst system. Further, at least one dissolved gas stripping step, at least one adsorption step, and a distillation step are included in the process. Desired iso-paraffin molecules are thereby preserved, and the undesired aromatic molecules are converted into desired naphthene molecules. 1. A process for producing a plurality of ultra-low aromatic chemicals from a plurality of low value hydrocarbon streams , the process comprising steps of:a first hydrotreating step performed on a hydrocarbon feedstock-1 doped with 50-500 ppmw of a nitrogen compound in a first reactor unit, wherein, the first reactor unit is loaded with a dual functional catalyst system having desulfurization and hydrogenation properties to provide a first effluent;at least one dissolved gas stripping step performed in at least one stripper unit to remove at least one dissolved gas from the first effluent, wherein, the dissolved gas stripping step provides a stripper effluent;a second hydrotreating step performed on a hydrocarbon feedstock-2 in a second reactor unit, wherein, the second reactor unit is loaded with a hydrogenation catalyst system having aromatic saturation properties to provide a second effluent;at least one adsorption step for a selective adsorption, or a selective desorption of at least one molecule from the second effluent, wherein, the selective adsorption is based on the difference in polarity of the molecules to result in an effluent; anda distillation step for separating out the plurality of ultra-low aromatic chemicals from the effluent.2. The process as claimed in claim 1 , wherein the first hydrotreating step claim 1 , the second ...

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Номер записи: 48
14-03-2019 дата публикации

Hydroprocessing of high density cracked fractions

Номер: US20190078027A1
Автор: Ajit B. Dandekar, Darryl D. Lacy, Mark A. Deimund, Randolph J. Smiley, Samia ILIAS, Scott J. WEIGEL
Принадлежит: ExxonMobil Research and Engineering Co

Systems and methods are provided for upgrading a heavy cracked feedstock in a single reaction stage under fixed bed hydroprocessing conditions, including exposing the feedstock to a first bulk or supported mixed metal catalyst comprising Ni and Mo; exposing the feedstock to a second bulk or supported mixed metal catalyst comprising Ni and W; and exposing the feedstock to a third catalyst comprising a zeolite-based hydrocracking catalyst.

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Номер записи: 49
22-03-2018 дата публикации

METHOD FOR REVAMPING A CONVENTIONAL MINERAL OILS REFINERY TO A BIOREFINERY

Номер: US20180079967A1
Автор: AMOROSO Andrea, POLLESEL PAOLO, PRATI Claudia, Rispoli Giacomo Fernando
Принадлежит: ENI S.p.A

The invention relates to a method for revamping a conventional refinery of mineral oils into a biorefinery, characterized by a production scheme which allows the treatment of raw materials of a biological origin (vegetable oils, animal fats, exhausted cooking oils) for the production of biofuels, prevalently high-quality biodiesel. 117-. (canceled)1812. A biorefinery , comprising a production unit of a hydrocarbon fraction from a mixture of a biological origin comprising a fatty acid ester by means of hydrodeoxygenation and isomerization of the mixture of the biological origin , wherein the biorefinery is obtained from a refinery comprising a system comprising two hydrodesulfurization units , (U) and (U) , by means of a method for revamping the refinery into the biorefinery ,{'b': 1', '2, 'claim-text': [{'b': 1', '1', '2', '2, 'a hydrodesulfurization reactor, (A) for the unit (U) and (A) for the unit (U), wherein the hydrodesulfurization reactor comprises a hydrodesulftirization catalyst;'}, 'a heat exchanger between a feedstock and effluent of the hydrodesulftirization reactor;', 'a heating system of the feedstock upstream of the hydrodesulfurization reactor; and', {'sub': '2', 'b': 1', '1', '2', '2, 'an acid gas treatment unit downstream of the hydrodesulfurization reactor, comprising an absorbent (B) for HS, (T) in the unit (U) and (T) in the unit (U),'}], 'wherein each of the hydrodesulfurization units (U) and (U) comprises [{'b': 1', '2, 'installing a line L between the units (U) and (U) which connects them in series;'}, {'b': 1', '2, 'installing a recycling line of the product for the unit (U) and optionally for the unit (U),'}, {'b': '1', 'substituting the hydrodesulfurization catalyst in the hydrodesulfurization reactor (A) with a hydrodeoxygenation catalyst;'}, {'b': '2', 'substituting the hydrodesulfurization catalyst in the hydrodesulfurization reactor (A) with an isomerization catalyst; and'}, {'b': 2', '2, 'installing a by-pass line X of the acid gas ...

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Номер записи: 50
26-03-2015 дата публикации

Base Oil Upgrading by Co-Feeding a Ketone or Beta-Keto-Ester Feedstock

Номер: US20150087872A1
Автор: Saleh Ali Elomari, Stephen Joseph Miller, Sven Ivar Hommeltoft
Принадлежит: Chevron USA Inc

This invention discloses a process for making high viscosity index lubricating base oils having a viscosity index of at least 110 by co-feeding a ketone or a beta-keto-ester feedstock with a lubricant oil feedstock directly to a hydrocracking unit to produce a hydrocracked stream. Then at least a portion of the hydrocracked stream is treated under hydroisomerization conditions to produce a high viscosity index lubricating base oil. The process may involve bypassing a hydrotreating or hydrofinishing step, which may result in improved efficiency and economics in producing high viscosity index lubricating base oils.

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Номер записи: 51
31-03-2022 дата публикации

CIRCULAR CHEMICALS OR POLYMERS FROM PYROLYZED PLASTIC WASTE AND THE USE OF MASS BALANCE ACCOUNTING TO ALLOW FOR CREDITING THE RESULTANT PRODUCTS AS CIRCULAR

Номер: US20220098490A1
Автор: ABBOTT Ronald G., HORLACHER Steven R., MORRISON Scott G., MURRAY Bruce D., SUTHERLAND Jamie N.
Принадлежит: CHEVRON PHILLIPS CHEMICAL COMPANY LP

This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based, fossil fuel-based, or bio-based feedstock. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways. The use of a mass balance approach which attributes the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit has been developed, which permits ISCC certification agency approval. 1. A process for producing chemicals or polymers from plastic waste , the process comprising:(a) providing a pyrolysis oil from plastic waste;(b) providing a petroleum-based, fossil fuel-based, or bio-based feed;(c) introducing the pyrolysis oil and the petroleum-based, fossil fuel-based, or bio-based feed, each at a known feed rate, into one or more primary processing units, thereby providing one or more primary processing unit feeds, each comprising the pyrolysis oil in a known concentration; and(d) converting the one or more primary processing unit feeds into one or more primary processing unit output streams, a portion of each output stream comprising at least one circular product, wherein the weight or the fraction of each circular product attributable to the pyrolysis oil or plastic waste is determined by mass balance.2. A process for producing chemicals or polymers from plastic waste according to claim 1 , wherein the process further comprises:(e) transferring at least a portion of one, or at least a portion of more than one, of the primary processing unit output streams, each at a known feed rate, into one or more secondary or subsequent processing units, thereby providing one or more secondary or subsequent processing unit feeds, each comprising a circular product ...

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Номер записи: 52
12-06-2014 дата публикации

Hydroconversion of renewable feedstocks

Номер: US20140163249A1
Автор: Alexander E. Kuperman, Cong-Yan Chen, Theodorus Ludovicus Michaael Maesen, William James Cannella
Принадлежит: Chevron USA Inc

A hydroconversion process comprises contacting a feedstock comprising renewable materials under hydroprocessing conditions with a promoted catalyst selected from a self-supported catalyst, a supported catalyst and combinations thereof, wherein the reaction conditions can be tailored to directly convert the renewable feedstock to the desired product(s) including fatty alcohols, esters, normal paraffins, or combinations thereof. The catalyst comprising at least a Group VIB metal selected from molybdenum and tungsten, a Group VIII metal selected from cobalt and nickel to convert the feedstock into any of fatty alcohols, esters, and normal paraffins. In some embodiments, the process further comprising additional steps to generate various desirable products, including α-olefins (or PAO, by dehydrating the fatty alcohol products), lubricants and bright stocks (from the oligomerizing of the PAO), and Group 3 lubricants (from co-oligomerizing of the PAO with some short chain olefins).

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Номер записи: 53
31-03-2022 дата публикации

Production of aromatics by reverse water gas shift, fermentation and recycling to pyrolysis.

Номер: US20220098624A1
Автор: Frederic Feugnet, Jean-Francois Joly
Принадлежит: IFP Energies Nouvelles IFPEN

Device and process for the conversion of a feedstock of aromatic compounds, in which the feedstock is treated notably by means of a fractionation train (4-7), a xylene separation unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO2 and H2; a reverse water gas shift RWGS reaction section (50) treats the pyrolysis gas and produces an RWGS gas enriched in CO and in water; a fermentation reaction section (52) treats the RWGS gas enriched in CO and in water, to produce ethanol and recycle the ethanol to the inlet of the pyrolysis unit.

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Номер записи: 54
12-03-2020 дата публикации

METHOD OF PREPARATION OF HYDROCARBON FUELS FROM POLYOLEFIN WASTE MATERIALS

Номер: US20200080004A1
Автор: BIERNAT Krzysztof, Handerek Adam, KIRAGA Jan, KOWALCZYK Maciej Pawel, MATUSZEWSKA Anna
Принадлежит:

Method of producing hydrocarbon fuels from polyolefin waste materials, wherein: polyolefin waste materials are subjected to continuous depolymerisation in a tower flow reactor with a movable packing, which comprises a heating system for heating the lower half of the reaction chamber, where products of depolymerisation are collected in a gaseous state through an outlet in the upper half of the reaction chamber; and the obtained products of depolymerisation are subjected to catalytic hydrogenation and isomerization in an atmosphere of synthesis gas, under atmospheric pressure, to obtain a mixture of hydrocarbon fuels; characterised in that: polyolefin waste materials are mixed with heated elements constituting the packing of the reactor until the surface of the packing elements is coated with a thin layer of plasticised material, wherein in the depolymerisation process that obtained mixture is fed as a stream into the reaction chamber from the top of the chamber, whereas a synthesis gas is fed in a counter current from the bottom, the gas comprising carbon monoxide (CO) and hydrogen (H) with the molar ratio CO:Hbeing from 0.25 to 1.5: from 0.5 to 3. 2. A method according to claim 1 , wherein depolymerisation is carried out under atmospheric pressure.3. A method according to claim 1 , wherein the packing of the reaction chamber is selected from the group of Raschig rings claim 1 , Pall rings claim 1 , Bialecki rings.4. A method according to claim 1 , wherein the polyolefin waste materials are mixed with the reactor packing at an amount not greater than 1 kg of the material per 1 mof the specific surface area of the packing.5. A method according to claim 1 , wherein the mixture of the reactor packing and the plasticised material is fed into the reaction chamber at a temperature of 240 to 260° C. claim 1 , optionally claim 1 , 250° C.6. A method according to claim 1 , wherein depolymerisation is carried out maintaining a temperature gradient claim 1 , wherein the lower ...

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Номер записи: 55
25-03-2021 дата публикации

Method of producing lubricating base oil from feedstock comprising diesel fraction, and lubricating base oil produced thereby

Номер: US20210087477A1
Автор: Hak Mook Kim, Jin Hee Ok, Seung Eon Lee
Принадлежит: SK Innovation Co Ltd, SK Lubricants Co Ltd

Disclosed is a method of producing a lubricating base oil, including providing a feedstock including a diesel fraction, subjecting the feedstock to catalytic dewaxing, and recovering a lubricating base oil from a product of the catalytic dewaxing. A lubricating base oil produced thereby and a lubricant product including the lubricating base oil are also provided.

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Номер записи: 56
05-05-2022 дата публикации

PURIFICATION OF RECYCLED AND RENEWABLE ORGANIC MATERIAL

Номер: US20220135891A1
Автор: Aalto Pekka, HOVI Meri, JANSSON Kari, KÄLDSTRÖM Mats, LAMMINPÄÄ Kaisa, LIKANDER Salla, LINDBLAD Marina, PAASIKALLIO Ville, Pasanen Antti, PASANEN Jukka-Pekka, Toppinen Sami, TOUKONIITTY Blanka, TOURONEN Jouni
Принадлежит: Neste Oyj

A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material includes more than 1 ppm silicon as silicon compounds and/or more than 10 ppm phosphorous as phosphorous compounds. The method can include providing a feed of the lipid material; heat treating the organic material in presence of an adsorbent and the filtering organic material and hydrotreating the lipid material in a presence of a hydrotreating catalyst to obtain purified hydrotreated organic material having less than 20% organic material and/or less than 30% of the original phosphorous content of the organic material.

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Номер записи: 57
19-06-2014 дата публикации

Apparatuses and methods for separating paraffin isomerization-zone effluents

Номер: US20140171717A1
Автор: Anurag Sinha, David James Shecterle, Douglas A. Becci, Manoj Kumar
Принадлежит: UOP LLC

Embodiments of apparatuses and methods for separating a paraffin isomerization-zone effluent are provided. In one example, an apparatus comprises a DIB column configured for fractionating the paraffin isomerization-zone effluent to form a branched C 4 hydrocarbon-rich stream. The DIB column comprises a vessel. The vessel comprises a cylindrical wall that extends vertically and that encloses an internal cylindrical volume having a lower portion extending to an upper portion. An internal swage is disposed in the lower portion of the internal cylindrical volume. A plurality of fractionation trays includes an upper fractionation tray that is disposed in the internal cylindrical volume above the internal swage and a lower fractionation tray that is disposed in the internal swage. The lower fractionation tray has a smaller diameter than the upper fractionation tray.

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Номер записи: 58
12-04-2018 дата публикации

METHOD FOR PREVENTING OR MINIMIZING ELECTROSTATIC DISCHARGE AND DIELECTRIC BREAKDOWN IN ELECTRIC VEHICLE POWERTRAINS

Номер: US20180100120A1
Автор: Carey James T., Flores-Torres Samuel, HOLT David G.L.
Принадлежит:

This disclosure relates to a method for preventing or minimizing electrostatic discharge and dielectric breakdown in an electric vehicle powertrain by controlling electrical conductivity over a lifetime of a lubricating oil in an electric vehicle powertrain lubricated with the lubricating oil. The lubricating oil has a composition including a lubricating oil base stock as a major component, and an additive package as a minor component comprising one or more lubricating oil additives, and an effective amount of one or more conductivity agents, as a minor component. The lubricating oil has an electrical conductivity from 10 pS/m to 20,000 pS/m, a dielectric constant of 1.6 to 3.6, with a ratio of electrical conductivity-to-dielectric constant from 1,000 to 10,000. Also provided are methods for obtaining a desired electrical conductivity-to-dielectric constant ratio of a lubricating oil for an electric powertrain and powertrain components and methods for lubricating an electric vehicle powertrain and powertrain components. 1. A method for preventing or minimizing electrostatic discharge and dielectric breakdown in an electric vehicle powertrain , said method comprising providing to an electric vehicle powertrain a lubricating oil having a composition comprising: a lubricating base oil as a major component; an additive package , as a minor component , comprising one or more lubricating oil additives; and an effective amount of one or more conductivity agents , as a minor component; wherein the lubricating oil has an electrical conductivity from about 10 pS/m to about 20 ,000 pS/m , a dielectric constant of about 1.6 to about 3.6 , and a ratio of electrical conductivity-to-dielectric constant from about 1 ,000 to about 10 ,000.2. The method of wherein the lubricating oil has an electrical conductivity from about 1 claim 1 ,000 pS/m to about 16 claim 1 ,000 pS/m.3. The method of wherein the lubricating oil has a dielectrical constant from about 1.8 to about 3.5.4. The ...

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Номер записи: 59
02-06-2022 дата публикации

Catalytic conversion process and system for producing gasoline and propylene

Номер: US20220169930A1
Автор: BAI Xuhui, Luo Yibin, Shu Xingtian, WANG Xieqing, WANG Xin, XU Youhao, ZUO Yanfen
Принадлежит:

A catalytic conversion process for producing gasoline and propylene includes the steps of 1) subjecting a feedstock oil to a first catalytic conversion reaction in a first catalytic conversion reaction device to obtain a first reaction product; 2) separating the first reaction product to obtain a propylene fraction, a gasoline fraction and a fraction comprising Colefin; 3) carrying out an oligomerization reaction on the fraction comprising Colefin in an oligomerization reactor to obtain an oligomerization product comprising Colefin, and optionally separating the oligomerization product to obtain a fraction comprising Colefin; 4) recycling the Colefin-containing oligomerization product or fraction to the first catalytic conversion reaction device, and/or sending the Colefin-containing oligomerization product or fraction to a second catalytic conversion reaction device for a second catalytic conversion reaction to obtain a second reaction product comprising propylene. 1. A process for producing gasoline and propylene , comprising the steps of:{'sub': '4', '1) subjecting a feedstock oil to a first catalytic conversion reaction in a first catalytic conversion reaction device to obtain a first reaction product comprising propylene, Colefin and a gasoline component;'}{'sub': '4', '2) separating the first reaction product to obtain a propylene fraction, a gasoline fraction, a fraction comprising Colefin, optionally a light cycle oil fraction and optionally a fluidized catalytic cracking gas oil (FGO) fraction;'}{'sub': 4', '4', '12', '12, '3) subjecting the Colefin-containing fraction obtained in step 2) and optionally a Colefin-containing fraction from an external source to olefin oligomerization in an oligomerization reactor to obtain an oligomerization product comprising Colefin, and optionally separating the oligomerization product to obtain a fraction comprising Colefin;'}{'sub': 12', '12, '4) recycling the Colefin-containing oligomerization product or fraction to the ...

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Номер записи: 60
11-04-2019 дата публикации

Catalysts and methods of making the same

Номер: US20190105647A1
Автор: David C. Calabro, Doron Levin, Kiara M. BENITEZ, Machteld M.W. MERTENS, Paul Podsiadlo, Quanchang Li, Randall D. Partridge, Scott J. WEIGEL
Принадлежит: ExxonMobil Research and Engineering Co

Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.

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Номер записи: 61
28-04-2016 дата публикации

Hydrotreating catalyst, process for preparing the same and use thereof

Номер: US20160115398A1
Автор: Balam Harish KUMAR, Brijesh Kumar, Durlubh Kumar SHARMA, Jayaraj Christopher, Madhusudan Sau, Muniaswamy Rajesh, Ravinder Kumar Malhotra, Santanam Rajagopal
Принадлежит: Indian Oil Corp Ltd

The present invention relates to a hydrotreating catalyst and more particularly to a catalyst comprising of Group VIB and Group VIII metals impregnated on non-refractory oxide as a catalyst support and process for preparing and its use thereof.

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Номер записи: 62
26-04-2018 дата публикации

METHOD FOR PRODUCING OIL-BASED COMPONENTS

Номер: US20180112140A1
Автор: KETTUNEN Mika P., MAKKONEN Jaana
Принадлежит: Neste Corporation

A method of producing oil-based components is disclosed which includes providing VGO and slack wax; combining the VGO as a major component and the slack wax as a minor component to provide a feedstock; subjecting the feedstock to hydrocracking to provide a first effluent; fractionating the first effluent to provide at least a bottom fraction and a middle distillate fraction; recovering the bottom fraction and the middle distillate fraction. A method for improving a viscosity index of base oil includes subjecting the bottom fraction to a dewaxing step to provide a second effluent; fractionating the second effluent to provide at least a middle distillate and base oil; and recovering the middle distillate and the base oil. 1. A method of producing oil-based components , comprising:providing VGO and slack wax;combining the VGO as a major component and the slack wax as a minor component to provide a feedstock;subjecting the feedstock to hydrocracking to provide a first effluent;fractionating the first effluent to provide at least a bottom fraction and a middle distillate fraction; andrecovering the bottom fraction and the middle distillate fraction.2. The method of claim 1 , comprising:subjecting the bottom fraction to dewaxing to provide a second effluent;fractionating the second effluent to provide at least a middle distillate and base oil; andrecovering the middle distillate and the base oil.3. A method for improving a viscosity index of base oil claim 1 , comprising:providing VGO and slack wax;combining the VGO as a major component and the slack wax as a minor component to provide a feedstock;subjecting the feedstock to a hydrocracking step to provide a first effluent;fractionating the first effluent to provide at least a bottom fraction and a middle distillate fraction;subjecting the bottom fraction to dewaxing to provide a second effluent;fractionating the second effluent to provide at least a middle distillate and base oil; andrecovering the middle distillate and ...

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Номер записи: 63
09-04-2020 дата публикации

SEQUENTIAL IMPREGNATION FOR NOBLE METAL ALLOY FORMATION

Номер: US20200108375A1
Автор: Ide Matthew S., McCarthy Stephen J., Scleicher Gary P.
Принадлежит:

Methods are provided for forming noble metal catalysts comprising both platinum and a second Group VIII metal, such as palladium, with improved aromatic saturation activity. Instead of impregnating a catalyst with both platinum and another Group VIII metal at the same time, a sequential impregnation can be used, with the Group VIII metal being impregnated prior to platinum. It has been discovered that by forming a Group VIII metal-impregnated catalyst first, and then impregnating with platinum, the distribution of platinum throughout the catalyst can be improved. The improved distribution of platinum can result in a catalyst with enhanced aromatic saturation activity relative to a catalyst with a similar composition formed by simultaneous impregnation. 19.-. (canceled)10. A supported catalyst comprising:a support comprising at least one of a zeolitic support and a mesoporous support, the support having an Alpha value of at least 100; and0.1 wt % to 5.0 wt %, based on a weight of the supported catalyst, of a combined amount of platinum and Group VIII metal on the support, a weight ratio of platinum and Group VIII metal being from 0.1 to 10, the Group VIII metal comprising Pd, Ni, Rh, Ir, Ru, Co, or a combination thereof,wherein the supported catalyst has a catalyst width and an average platinum content per volume, and wherein a peak platinum content per volume across the catalyst width differs from the average platinum content per volume by less than 100% of the average platinum content per volume.11. The supported catalyst of claim 10 , wherein the supported catalyst has an average combined platinum and Group VIII metal content per volume claim 10 , and wherein a peak combined platinum and Group VIII metal content per volume across the catalyst width differs from the average combined platinum and Group VIII metal content per volume by less than 100% of the average combined platinum and Group VIII metal content per volume.12. The supported catalyst of claim 10 , ...

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Номер записи: 64
13-05-2021 дата публикации

PRODUCTION OF RENEWABLE BASE OIL AND DIESEL BY PRE-FRACTIONATION OF FATTY ACIDS

Номер: US20210139786A1
Автор: NURMI Pekka, Toppinen Sami
Принадлежит: Neste Oyj

Methods are disclosed for producing renewable base oil and a diesel oil from low-value biological oils. Low-value biological oils containing free fatty acids and fatty acid esters can be processed into a renewable base oil and a renewable diesel oil by first separating at least part of the saturated free fatty acids from the feedstock and then processing separately this saturated free acid feed in a ketonisation reaction followed by hydrodeoxygenation and hydroisomerisation reactions to yield a renewable base oil stream. The remaining free fatty acid depleted feed may be processed in a separate hydrodeoxygenation and hydroisomerisation step to yield a renewable diesel stream. 1. A method for producing a renewable base oil from a feedstock of biological origin , the method comprising:a) providing a feedstock, the feedstock containing at least 5 wt % of a mixture of saturated free fatty acids and at most a remainder of one or more compounds selected from the list consisting of: unsaturated free fatty acids, fatty acid esters, fatty amides, fatty alcohols, as well as fatty acid glycerols such as mono-glycerides, di-glycerides and tri-glycerides of fatty acids; {'sub': 'n', 'a saturated fatty acid feed containing at least 90 wt % saturated Cfree fatty acids, no more than 3 wt % unsaturated free fatty acids, where n is selected from one of the integer values; 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24; and one or more saturated fatty acid depleted feed(s);'}, 'b) separating the feedstock into at leastc) subjecting the saturated fatty acid feed to ketonisation reaction conditions where two fatty acids react to yield a ketone stream, the ketone stream including as a major part saturated ketones having a carbon number of 2n−1; andd) subjecting the ketone stream to both hydrodeoxygenation reaction conditions and to hydroisomerisation reaction conditions, simultaneously or in sequence, to yield a deoxygenated and isomerised base oil stream containing the ...

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Номер записи: 65
04-05-2017 дата публикации

METHOD FOR ACTIVATING HYDROTREATING CATALYSTS

Номер: US20170120230A1
Автор: HUMBLOT Francis
Принадлежит: Arkema France

The present invention relates to the use, in a method for in-situ activation of at least one hydrotreating, in particular hydrocracking, catalyst, of at least one nitrogen compound having at least one of the following characteristics: 1. A method for in-situ activation of a hydrotreating catalyst , comprising using at least one nitrogen compound having at least two of the following characteristics:a) a nitrogen content by weight in the range from 15 to 35 wt % relative to the total weight of the nitrogen compound;b) a number of nitrogen atoms in the range from 2 to 20 per molecule;c) a boiling point in the range from 140° C. to 300° C.; andd) said nitrogen compound being in liquid form at room temperature and atmospheric pressure.2. The method according to claim 1 , wherein the nitrogen compound has in addition a molecular weight in the range from 80 g.molto 300 g.moldesignated as characteristic e) hereinafter.3. The method according to claim 1 , wherein the nitrogen compound has a characteristic f) such that said nitrogen compound does not comprise an aromatic or cyclic group.4. The method according to claim 1 , in wherein said at least one nitrogen compound necessarily has characteristic b).5. The method according to claim 1 , in wherein the nitrogen compound is selected from the group consisting of N claim 1 ,N′-diethyl-1 claim 1 ,3-propanediamine (DEAPA) claim 1 , tetramethyl-1 claim 1 ,3-propanediamine (TMPDA) claim 1 , N-methyl-1 claim 1 ,3-propanediamine claim 1 , N claim 1 ,N′-dibutyl-1 claim 1 ,3-propanediamine claim 1 , N-(3-dimethylaminopropyl)propane-1 claim 1 ,3-diamine (DMAPAPA) claim 1 , N-(3-aminopropyl)-1 claim 1 ,3-propanediamine claim 1 , N claim 1 ,N′-1 claim 1 ,2-ethanediyl-bis-1 claim 1 ,3-propanediamine claim 1 , N-(aminopropyl)diethanolamine (APDEA) claim 1 , and mixtures thereof.6. The method of claim 1 , wherein the activity of at least one hydrotreating catalyst is controlled.7. The method of claim 1 , wherein the acid sites of the ...

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Номер записи: 66
25-04-2019 дата публикации

METHOD FOR STARTING UP A METHOD FOR PRODUCING KEROSENE AND DIESEL FUEL FROM HYDROCARBON COMPOUNDS PRODUCED BY FISCHER-TROPSCH SYNTHESIS

Номер: US20190119585A1
Автор: DULOT Hugues, GREZAUD Aline, Heraud Jean-Philippe
Принадлежит: IFP ENERGIES NOUVELLES

Method for starting up a method for producing kerosene and diesel fuel from hydrocarbon compounds produced by Fischer-Tropsch synthesis. 1) Method for starting up a method for producing kerosene and diesel fuel from hydrocarbon compounds produced by Fischer-Tropsch synthesis , in which the following steps are carried out:a) A catalytic reaction of Fischer-Tropsch synthesis is carried out with a synthesis gas to produce a heavy hydrocarbon fraction and a light hydrocarbon fraction,b) A reduction (RE) of a hydrotreatment catalyst is carried out by ensuring contact with a gas comprising hydrogen, and then step c) is carried out,c) The heavy hydrocarbon fraction is brought into contact (DM) with the hydrotreatment catalyst,d) During step c), the temperature (TEMP) of the hydrotreatment catalyst is increased to a temperature of between 260° C. and 360° C., and then step e) is carried out,e) A mixture comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction are brought into contact (TR) with the hydrotreatment catalyst.2) Method according to claim 1 , in whichin step b), a reduction of the hydrotreatment catalyst and a hydrocracking and hydroisomerization catalyst is carried out by ensuring contact with a gas comprising hydrogen, and then step c) is carried out,in step c), the heavy hydrocarbon fraction is brought into contact with the hydrotreatment catalyst and then with the hydrocracking and hydroisomerization catalyst,in step e), the mixture comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction is brought into contact with the hydrotreatment catalyst and then with the hydrocracking and hydroisomerization catalyst.3) Method according to claim 1 , in which step b) is carried out at a temperature of between 300° C. and 500° C. claim 1 , and then the hydrotreatment catalyst is cooled to a temperature of between 120° C. and 170° C. claim 1 , and then step c) is carried out.4) Method according to claim 1 , in which at the beginning ...

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Номер записи: 67
25-04-2019 дата публикации

Process for producing catalytic cracking gasoline with a high octane number

Номер: US20190119586A1
Автор: Anguo Mao, Jianhong Gong, Jinlian TANG, Jiushun Zhang, Jun Long, Yuying Zhang, Zekun LI
Принадлежит: China Petroleum and Chemical Corp, Sinopec Research Institute of Petroleum Processing

The present disclosure relates to a process for producing catalytic cracking gasoline comprising the following steps: i) subjecting a heavy feedstock oil to a catalytic cracking reaction in the presence of a first catalytic cracking catalyst to obtain a first reaction product; ii) subjecting a hydrogenated cycle oil to a catalytic cracking reaction in the presence of a second catalytic cracking catalyst to obtain a second reaction product; iii) separating a mixture of the first reaction product and the second reaction product to obtain a catalytic cracking gasoline and a catalytic cracking light cycle oil; iv) subjecting the catalytic cracking light cycle oil or a fraction thereof to hydrogenation to obtain a hydrogenated product; and v) recycling the hydrogenated product to the step ii) as the hydrogenated cycle oil. The present disclosure also relates to a catalytic cracking system for carrying out the process. The process and system according to the present application are capable of providing optimized reaction conditions for the hydrogenated cycle oil and the heavy feedstock oil, thereby providing a high yield of high-octane gasoline.

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Номер записи: 68
16-04-2020 дата публикации

PROCESS FOR THE MANUFACTURE OF DIESEL RANGE HYDROCARBONS

Номер: US20200115636A1
Автор: Aalto Pekka, ALOPAEUS Ville, GRONQVIST Johan, MYLLYOJA Jukka, PUROLA Veli-Matti, SAVOLAINEN Pekka
Принадлежит: Neste Oyj

The invention relates to a process for the manufacture of diesel range hydrocarbons wherein a feed is hydrotreated in a hydrotreating step and isomerised in an isomerisation step, and a feed comprising fresh feed containing more than 5 wt % of free fatty acids and at least one diluting agent is hydrotreated at a reaction temperature of 200-400° C., in a hydrotreating reactor in the presence of catalyst, and the ratio of the diluting agent/fresh feed is 5-30:1. 1. A process for the manufacture of diesel range hydrocarbons comprising the following steps:introducing a feedstock comprising bio oil and/or fat from renewable sources to a hydrotreatment step in which hydrocarbons are formed,isomerizing the formed hydrocarbons in an isomerization step,whereingas phase impurities formed in the hydrotreatment step are removed from the stream comprising hydrocarbons prior to contacting the hydrocarbons with the isomerization catalyst.2. The process according to claim 1 , further comprising a step of purifying the feedstock prior to the hydrotreatment step so as to remove impurities.3. The process according to claim 1 , wherein the gas phase impurities formed in the hydrotreatment step comprise propane claim 1 , water claim 1 , CO claim 1 , HS claim 1 , NHor mixtures thereof.4. The process according to claim 1 , wherein the removal of the gas phase impurities formed in the hydrotreatment step is performed in a stripping step upstream of the isomerization catalyst.5. The process according to claim 4 , wherein the stripping step is performed by stripping with water vapor or a suitable gas comprising light hydrocarbon claim 4 , nitrogen or hydrogen.6. The process according to claim 4 , wherein the stripping step is carried out in a counter-current manner.7. The process according to claim 1 , in the feedstock comprises more than 10 wt % of free fatty acids.8. The process according to claim 1 , wherein the feedstock contains less than 10 w-ppm alkaline and alkaline earth metals ...

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Номер записи: 69
11-05-2017 дата публикации

METHOD FOR THE HYDROTREATMENT OF DISTILLATE CUTS USING A CATALYST MADE FROM AN AMORPHOUS MESOPOROUS ALUMINA HAVING HIGH CONNECTIVITY

Номер: US20170130142A1
Автор: BOUALLEG Malika, Hugon Antoine
Принадлежит: IFP ENERGIES NOUVELLES

A description is given of a process for hydrotreatment of at least one hydrocarbon feedstock having a weighted average temperature (WAT) of more than 380° C. using at least one catalyst containing at least one metal from Group VIB and/or at least one metal from Group VIII of the periodic table and a support containing an amorphous mesoporous alumina having a connectivity (Z) of more than 2.7, said hydrotreatment process operating at a temperature of between 250° C. and 430° C., at a total pressure of between 4 MPa and 20 MPa with a ratio of volume of hydrogen to volume of hydrocarbon feedstock of between 200 and 2 000 litres per litre and at an Hourly Volume Velocity (HVV) defined by the ratio of the volume flow of liquid hydrocarbon feedstock to the volume of catalyst fed into the reactor of between 0.5 and 5 h. 1. Process for hydrotreatment of at least one hydrocarbon feedstock having a weighted average temperature (WAT) of more than 380° C. using at least one catalyst containing at least one metal from Group VIB and/or at least one metal from Group VIII of the periodic table and a support containing an amorphous mesoporous alumina having a connectivity (Z) of more than 2.7 , the connectivity being determined on the basis of the nitrogen adsorption/desorption isotherms , said hydrotreatment process operating at a temperature of between 250° C. and 430° C. , at a total pressure of between 4 MPa and 20 MPa with a ratio of volume of hydrogen to volume of hydrocarbon feedstock of between 200 and 2 000 litres per litre and at an Hourly Volume Velocity (HVV) defined by the ratio of the volume flow of liquid hydrocarbon feedstock to the volume of catalyst fed into the reactor of between 0.5 and 5 h.2. Process according to claim 1 , wherein said hydrocarbon feedstock is selected from among the vacuum distillates claim 1 , effluents produced by a Fluid Catalytic Cracking (FCC) unit claim 1 , light cycle oil produced in a catalytic cracking unit claim 1 , heavy cycle oil ...

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Номер записи: 70
01-09-2022 дата публикации

Full conversion method and device for producing light aromatic hydrocarbons from light cycle oil

Номер: US20220275294A1
Автор: Dejin Kong, Junlin ZHENG, Qi Song, Xiangdong Jiang
Принадлежит: China Petroleum and Chemical Corp, Sinopec Shanghai Research Institute of Petrochemical Technology

Provided are a full conversion process and a device thereof for producing light aromatic hydrocarbon from LCO. The process includes the steps of: subjecting LCO stream to hydrofining and impurity separation, then performing selective conversion reaction, and separating the mixed aromatic hydrocarbons generated to sequentially separate out light aromatic hydrocarbons such as benzene-toluene and xylene, C9A aromatic hydrocarbons, C10A aromatic hydrocarbons and a bottom heavy tail oil; feeding the bottom heavy tail oil into a post-saturation selective reactor, subjecting to high-selectivity hydrogenation saturation under the conditions of low temperature and low pressure to provide a product having one benzene ring, and then returning the product back to the selective conversion reactor. The full-cut conversion of producing light aromatic hydrocarbon from LCO is achieved, resulting in the technical effects of high yields of monocyclic aromatic hydrocarbons such as benzene-toluene, xylene, C9A aromatic hydrocarbons, C10A aromatic hydrocarbons and the like.

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Номер записи: 71
23-04-2020 дата публикации

RAFFINATE HYDROCONVERSION FOR PRODUCTION OF HIGH PERFORMANCE BASE STOCKS

Номер: US20200123453A1
Автор: Calla Jason T., Fisher, Fortney Seth D., Joseck Eric D., JR. Will G.
Принадлежит:

Systems and methods are provided for production of base stocks with a viscosity index of at least 120 and/or a sulfur content of 300 wppm or less and/or a kinematic viscosity at 100° C. of 3.0 cSt to 8.0 cSt by hydroconversion of a raffinate from aromatic extraction of a feed. The base stocks can further have a reduced content of 3+ ring naphthenes, such as 4.0 wt % or less, or 1.0 wt % or less. The base stocks can be produced by performing an elevated amount of feed conversion relative to 370° C. during hydroconversion of the raffinate, and optionally additional conversion during catalytic dewaxing of the hydroconverted raffinate. The base stocks can optionally be blended with additional base stocks and/or lubricant additives for production of lubricant compositions. 116-. (canceled)17. A base stock comprising a viscosity index (VI) of at least 130 , a sulfur content of 50 wppm or less , a saturates content of at least 90 wt % , a Noack volatility of 14 wt % or less , a pour point of −15° C. or less , and a kinematic viscosity at 100° C. of 3.5 to 4.5 cSt , the base stock further comprising a 3+ ring naphthene content of 1.0 wt % or less.18. The base stock of claim 17 , wherein the 3+ ring aromatic content is 0.5 wt % or less.19. The base stock of claim 17 , wherein the base stock is derived from a feedstock that comprises at least 50 wt % of a mineral feedstock.20. The base stock of claim 17 , wherein the base stock comprises a Group III base stock.21. A lubricant composition comprising the base stock of and at least 5 wt % of a base stock having a kinematic viscosity at 100° C. of 4.5 cSt to 8.0 cSt.22. A base stock comprising a viscosity index (VI) of at least 135 claim 17 , a sulfur content of 50 wppm or less claim 17 , a saturates content of at least 90 wt % claim 17 , a Noack volatility of 14 wt % or less claim 17 , a pour point of −15° C. or less claim 17 , and a kinematic viscosity at 100° C. of 3.5 to 4.5 cSt claim 17 , the base stock further comprising a ...

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Номер записи: 72
18-05-2017 дата публикации

Mixed oxides of transition metals, hydrotreatment catalysts obtained therefrom and preparation process

Номер: US20170136446A1
Автор: Angela Carati, Marcello Marella, Marco Massimo Ferrari, Maria Federica Gagliardi, Michele Tomaselli, Stefano Zanardi
Принадлежит: Eni Spa

New sulfide metal catalysts are described, containing Ni, Mo and W, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by sulfidation of mixed oxide precursors, also new, characterized in that they comprise an amorphous phase and a wolframite iso structural crystalline phase, the crystallinity degree of said mixed oxides being higher than 0 and lower than 100%, preferably higher than 0 and lower than 70%. The catalysts of the invention are useful as hydrotreatment catalysts, and in particular as hydrodesulfurization, hydrodenitrogenation and/or hydrodearomatization catalysts.

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Номер записи: 73
26-05-2016 дата публикации

HYDROPROCESSING FOR DISTILLATE PRODUCTION

Номер: US20160145503A1
Автор: BAUMGARTNER Joseph Ernest, Levin Doron, Miseo Sabato, Soled Stuart Leon, Wilson Keith, XU Xiaochun
Принадлежит: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

Methods are provided for hydrotreating a feed to generate a product with a reduced or minimized aromatics content and/or an increased distillate product yield. A distillate boiling range feed having an elevated content of sulfur and/or nitrogen can be hydrotreated using at least two hydrotreating stages with intermediate separation to produce a hydrotreated distillate boiling range product with a reduced or minimized aromatics content. Additionally or alternately, a mixed metal catalyst formed from a suitable precursor can be used during the hydrotreating. A mixed metal catalyst formed from a suitable precursor can provide an unexpectedly superior activity for aromatic saturation. A still further unexpected benefit can be achieved by combining a multi-stage hydrotreating process with intermediate separation with hydrotreating in the presence of a mixed metal catalyst formed from a suitable precursor. 1. A hydrotreatment process comprising:reacting a feedstream, the feedstream having a sulfur content of about 500 wppm to about 50000 wppm and an aromatics content of at least about 60 wt %, in the presence of a hydrogen-containing treat gas and in the presence of a mixed metal catalyst under effective hydrotreating conditions for converting about 5 wt % or less of the feedstream relative to a conversion temperature of 350° F. (177° C.); andseparating the first liquid effluent to produce a vapor phase stream and a liquid product stream, the liquid product stream having a sulfur content of about 500 wppm or less,wherein the mixed metal catalyst comprises a sulfided mixed metal catalyst formed by sulfiding a mixed metal catalyst precursor composition, the mixed metal catalyst precursor composition being produced bya) heating a composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at ...

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Номер записи: 74
10-06-2021 дата публикации

HYDROPROCESSING OF HYDROCARBON FEEDS WITH A CATALYST COMPRISING AN ALUMINIUM MATERIAL COMPRISING CARBON

Номер: US20210171839A1
Автор: BONDUELLE-SKRZYPCZAK Audrey, Cabiac Amandine, Chaumonnot Alexandra, GIREL Etienne
Принадлежит: IFP ENERGIES NOUVELLES

The invention relates to a method for hydroprocessing a hydrocarbon feed, operated at a temperature of between 180° C. and 450° C., in the presence of a catalyst comprising i) a composite material comprising a compound based on at least one crystalline aluminium solid and carbon, the deposited carbon content being between 1 and 25 wt. % of the total mass of the composite material, and ii) at least one element of group VIB and at least one element of group VIII, in the sulfide form thereof, said catalyst being produced by a method comprising at least: a) a step of bringing a carbon precursor into contact with a compound based on at least one crystalline aluminium solid, b) a step of thermally treating the solid produced by step a), c) repeating steps a) and b) until the desired deposited carbon content is reached, d) depositing at least one element of group VIB and at least one element of group VIII on the surface of the solid produced by step c), and e) a step of sulfidisation of the solid produced in step d). 1. A process for hydrotreating a hydrocarbon feedstock , which is operated at a temperature of between 180° C. and 450° C. and at a pressure of between 0.5 MPa and 30 MPa , in the presence of a catalyst comprising i) a composite material comprising a compound based on at least one crystalline aluminous solid and carbon , the deposited carbon content being between 1 and 25 weight % of the total mass of the composite material , and ii) at least one element from group VIB and at least one element from group VIII , in their sulfide form ,said catalyst being prepared by a process comprising at least:a) a step of contacting a mixture comprising at least one carbon precursor with a compound based on at least one crystalline aluminous solid, at a temperature of between 50 and 300° C. and at a pressure corresponding at least to the autogenous pressure, the concentration of carbon precursor in said mixture being between 2 and 100 g/l, and the mass ratio of carbon ...

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Номер записи: 75
25-05-2017 дата публикации

Process for producing purified aromatic hydrocarbons from a mixed hydrocarbon feedstream

Номер: US20170144948A1
Автор: Dimitri Daniëls, Scott Stevenson
Принадлежит: SABIC Global Technologies BV

The present invention relates to a process for producing benzene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to aromatization to provide a benzene-rich aromatic stream and recovering the benzene from the benzene-rich aromatic stream.

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Номер записи: 76
25-05-2017 дата публикации

Process for the manufacture of diesel range hydrocarbons

Номер: US20170145318A1
Автор: Johan GRÖNQVIST, Jukka Myllyoja, Pekka Aalto, Pekka Savolainen, Veli-Matti Purola, Ville Alopaeus
Принадлежит: Neste Oyj

The invention relates to a process for the manufacture of diesel range hydrocarbons wherein a feed is hydrotreated in a hydrotreating step and isomerised in an isomerisation step, and a feed comprising fresh feed containing more than 5 wt % of free fatty acids and at least one diluting agent is hydrotreated at a reaction temperature of 200-400° C., in a hydrotreating reactor in the presence of catalyst, and the ratio of the diluting agent/fresh feed is 5-30:1.

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Номер записи: 77
15-09-2022 дата публикации

HIGH NANOPORE VOLUME HYDROTREATING CATALYST AND PROCESS

Номер: US20220288565A1
Автор: Lei Guan-Dao, Zhang Yihua
Принадлежит:

An improved hydrotreating catalyst and process for making a base oil product wherein the catalyst comprises a base extrudate that includes a high nanopore volume amorphous silica alumina (ASA) and an alumina. The catalyst and process generally involve the use of a high nanopore volume ASA/alumina based catalyst to produce hydrotreated dewaxed base oil products by contacting the catalyst with a hydrocarbon feedstock. The catalyst base extrudate advantageously comprises an amorphous silica alumina having a pore volume in the 11-20 nm pore diameter range of 0.2 to 0.9 cc/g and an alumina having a pore volume in the 11-20 nm pore diameter range of 0.01 to 1.0 cc/g, with the base extrudate formed from the amorphous silica alumina and the alumina having a total pore volume in the 2-50 nm pore diameter range of 0.12 to 1.80 cc/g. The catalyst further comprises at least one modifier element from Groups 6 to 10 and Group 14 of the Periodic Table. The catalyst and process provide improved aromatics saturation. 1. A hydrotreating catalyst , useful to make dewaxed products including base oils having reduced aromatics content , comprisinga base extrudate comprising an amorphous silica alumina (ASA) and an alumina, whereinthe amorphous silica alumina has a pore volume in the 11-20 nm pore diameter range of 0.2 to 0.9 cc/g;the alumina has a pore volume in the 11-20 nm pore diameter range of 0.01 to 1.0 cc/g; andthe base extrudate has a total pore volume in the 2-50 nm pore diameter range of 0.12 to 1.80 cc/g; andat least one modifier selected from Groups 6 to 10 and Group 14 of the Periodic Table.2. The catalyst of claim 1 , wherein the modifier comprises a Group 8-10 metal of the Periodic Table.3. The catalyst of claim 2 , wherein the modifier is a Group 10 metal comprising Pt claim 2 , Pd claim 2 , or a combination thereof.4. The catalyst of claim 1 , wherein the amorphous silica alumina has a pore volume in the 6-11 nm pore diameter range of 0.1 to 1.2 cc/g claim 1 , or a pore ...

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Номер записи: 78
16-05-2019 дата публикации

NOBLE METAL HYDROGENATION CATALYSTS AND AROMATIC SATURATION METHODS

Номер: US20190144774A1
Автор: Baumgartner Joseph E., Green Thomas E., Guzman Javier, KLIEWER Christine E., KOZIOL Lukasz, LANCI Michael P., Mao Kanmi, Miseo Sabato, OWENS Tracie, Schleicher Gary P., Soled Stuart L., ZHANG LEI
Принадлежит:

Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation. 112.-. (canceled)13. A hydrogenation catalyst , comprising: 1.0 wt % to 2.5 wt %, based on a total catalyst weight, of alumina deposited on the silica support, the catalyst having a ratio of aluminum atoms in tetrahedral sites to octahedral sites of at least 1.0,', 'wherein the silica support comprises an amorphous silica support, a mesoporous silica support, or a combination thereof., '0.1 wt % to 5.0 wt %, based on total catalyst weight, of a Group VIII noble metal on a silica support; and'}14. The hydrogenation catalyst of claim 13 , wherein the Group VIII noble metal comprises Pt claim 13 , Pd claim 13 , or a combination thereof.15. The hydrogenation catalyst of claim 13 , wherein the Group VIII noble metal comprises Pt.16. The hydrogenation catalyst of claim 15 , wherein the Group VIII noble metal further comprises one or more of Pd claim 15 , Ir claim 15 , or Rh claim 15 , a molar ratio of Pt to the one or more of Pd claim 15 , Ir claim 15 , or Rh being at least 1:1.17. The hydrogenation catalyst of claim 13 , wherein the supported catalyst comprises 0.1 wt % to 2.0 wt % of the Group VIII noble metal.18. The hydrogenation catalyst of claim 13 , wherein the ratio of aluminum atoms in tetrahedral sites to octahedral sites is at least 1.5.19. The hydrogenation catalyst of claim 13 , wherein the catalyst comprises 1.0 wt % to 2.1 wt % of alumina deposited on the silica support.20. The hydrogenation catalyst of claim 13 , wherein the catalyst comprises 1.1 wt % to 2.2 wt % of alumina deposited on the silica support. This application is a continuation-in-part application of co-pending U.S. application Ser. No ...

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Номер записи: 79
31-05-2018 дата публикации

PROCESS FOR RECONFIGURING EXISTING TREATING UNITS IN A REFINERY

Номер: US20180148654A1
Автор: Eizenga Donald A., Rojas Jose R., Wexler James
Принадлежит:

Processes for converting existing refinery units and equipment to enable processing of renewable triglyceride feedstock to provide hydrocarbon fuels. Originally, the existing refinery units may have bene configured as hydrotreating, hydrocracking, fixed bed reforming, or isomerization units for a petroleum based feedstock. Hydrogen from a second reaction zone may be provide to the first reaction zone, without or without the use of a compressor. 1. A process for converting petroleum processing units into a renewable fuel processing plant , the process comprising:reconfiguring a first reaction zone configured to treat a petroleum feedstock to a reaction zone for treating a renewable feedstock into hydrocarbons and providing a treated effluent;{'sub': 2', '3', '2', '2, 'providing a stripping zone configured to remove one or more of hydrogen sulfide (HS), ammonia (NH), water (HO), carbon monoxide (CO) and carbon dioxide (CO)from the treated effluent and provide a gaseous stream;'}providing a scrubbing zone configured to remove carbon dioxide from the gaseous stream and provide a scrubbed gaseous stream;reconfiguring a second reaction zone configured to treat a petroleum feedstock to a reaction zone for converting the treated effluent from first reaction zone and providing a converted effluent;separating a hydrogen containing gas from the converted effluent; and,passing the hydrogen containing gas separated from the converted effluent to the first reaction zone.2. The process of wherein a pressure of the first reaction zone is between about 3 claim 1 ,447 and about 17 claim 1 ,240 kPag and a pressure of the second reaction zone is between about 2 claim 1 ,758 to about 4 claim 1 ,826 kPag.3. The process of wherein a pressure of the first reaction zone is between about 3 claim 1 ,447 and about 5 claim 1 ,516 kPag and a pressure of the second reaction zone is between about 4 claim 1 ,137 and about 17 claim 1 ,240 kPag.4. The process of wherein a pressure of the first ...

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Номер записи: 80
17-06-2021 дата публикации

USE OF RENEWABLE OIL IN HYDROTREATMENT PROCESS

Номер: US20210179947A1
Автор: LINDQVIST Petri, OUNI Tuomas, SIPPOLA Väinö
Принадлежит: Neste Oyj

The use of bio oil from at least one renewable source in a hydrotreatment process, in which process hydrocarbons are formed from said glyceride oil in a catalytic reaction, and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron. A bio oil intermediate including bio oil from at least one renewable source and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron. 1. A bio oil intermediate for a hydrotreatment process to form hydrocarbons , the bio oil intermediate comprising:a bio oil from at least one renewable source, wherein an iron content of said bio oil contains:an iron concentration of less than 1 to 0.2 w-ppm calculated as elemental iron;a phosphorous concentration of less than 5 w-ppm; anda cumulative alkali metals concentration and alkali earth metals concentration calculated as elemental metal of less than 1 w-ppm.2. A bio oil intermediate according to claim 1 , wherein said bio oil intermediate is a group of bio oils characterized by a result-effective range of iron concentrations to address plugging in a hydrodeoxygenation reactor claim 1 , the range having a lower bound of 0.2 w-ppm and an upper bound of 1 w-ppm.3. A bio oil intermediate according to claim 1 , in combination with a catalyst bed of a hydrodeoxygenation reactor claim 1 , wherein the catalyst bed comprises:a NiMo catalyst.4. A bio oil intermediate according to claim 1 , in combination with a catalyst bed of a hydrodeoxygenation reactor claim 1 , wherein the catalyst bed comprises:a CoMo catalyst.5. A bio oil intermediate according to claim 1 , in combination with a catalyst bed of a hydrodeoxygenation reactor claim 1 , wherein the catalyst bed comprises:{'sub': 2', '3, 'a NiMo/A1Ocatalyst.'}6. A bio oil intermediate according to claim 1 , in combination with a catalyst bed of a hydrodeoxygenation reactor claim 1 , wherein the catalyst bed comprises:a catalyst containing at least one or more of Pd, Pt, Ni, NiMo and CoMo.7. A bio ...

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Номер записи: 81
09-06-2016 дата публикации

Flexible unit for isomerization and disproportionation of hydrocarbons using solid acid catalysts

Номер: US20160159711A1
Автор: Alakananda Bhattacharyya, Mary Wier, Stuart Smith, Tom N. Kalnes
Принадлежит: UOP LLC

A flexible hydrocarbon conversion process utilizing the same reaction zone for isomerization and disproportionation is described. The feed and type of products are selected. The hydrocarbon feed is contacted with a catalyst and in the presence of hydrogen and an added chloride promoter. The catalyst comprises a solid catalyst comprising a refractory inorganic oxide having a metal halide dispersed thereon. The operating conditions are varied depending on whether isomerization or disproportionation is desired.

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Номер записи: 82
07-06-2018 дата публикации

PROCESS FOR THE PRODUCTION OF BIODEGRADABLE HYDROCARBON FLUIDS BY HYDROGENATION

Номер: US20180155636A1
Автор: DOUCET Clarisse, GERMANAUD Laurent
Принадлежит: TOTAL MARKETING SERVICES

The invention provides for a fluid having a boiling point in the range of from 100 to 400° C. and comprising more than 95% isoparaffins and containing less than 100 ppm aromatics, obtainable by the process comprising the step of catalytically hydrogenating a feed comprising more than 95% by weight of a hydrodeoxygenated isomerized hydrocarbon biomass feedstock, at a temperature from 80 to 180° C. and at a pressure from 50 to 160 bars. The invention also provides for a fluid having a boiling point in the range of from 100 to 400° C. and a boiling range below 80° C., said fluid comprising more than 95% isoparaffins and less than 3% of naphthens by weight and having a ratio of isoparaffins to n-paraffins of at least 12:1, a biodegradability at 28 days of at least 60%, as measured according to the OECD 306 standard, a biocarbon content of at least 95% by weight, and containing less than 100 ppm aromatics by weight. The invention finally provides for uses of the fluid. 1. Fluid having a boiling point in the range of from 100 to 400° C. and comprising more than 95% isoparaffins and containing less than 100 ppm aromatics by weight , obtainable by the process comprising the step of catalytically hydrogenating a feed comprising more than 95% by weight of a hydrodeoxygenated isomerized hydrocarbon biomass feedstock , at a temperature from 80 to 180° C. , at a pressure from 50 to 160 bars , a liquid hourly space velocity of 0.2 to 5 hand an hydrogen treat rate up to 200 Nm/ton of feed.2. Fluid of claim 1 , obtainable by the process wherein the hydrogenation conditions are the following:Pressure: 80 to 150 bars, and preferably 90 to 120 bars;Temperature: 120 to 160° C. and preferably 150 to 160° C.;Liquid hourly space velocity (LHSV): 0.4 to 3, and preferably 0.5 to 0.8;{'sup': '3', 'Hydrogen treat rate be up to 200 Nm/ton of feed.'}3. Fluid of claim 1 , wherein the feed comprises more than 98% claim 1 , preferably more than 99% of a hydrodeoxygenated isomerized hydrocarbon ...

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Номер записи: 83
24-06-2021 дата публикации

CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE AND LUBRICATING OIL VIA CRUDE AND ISOMERIZATION DEWAXING UNITS

Номер: US20210189252A1
Автор: Timken Hye-Kyung
Принадлежит: Chevron U.S.A. INC.

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C-C) fraction or a propane/butane (C-C) fraction is recovered. The straight run naphtha fraction (C-C) or the propane/butane (C-C) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil. 1. A continuous process for converting waste plastic into recycle for polyethylene polymerization comprising:(a) selecting waste plastics containing polyethylene and/or polypropylene;(b) passing the waste plastics from (a) through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent;(c) separating the pyrolyzed effluent into offgas, a naphtha/diesel fraction, a heavy fraction, and char;(d) passing the naphtha/diesel fraction to a crude unit in a refinery;{'sub': 5', '8, '(e) recovering a straight run naphtha (C-C) fraction from the crude unit;'}{'sub': 5', '8, '(f) passing the straight run naphtha fraction (C-C) to a steam cracker for ethylene production; and'}(g) passing the heavy fraction to an isomerization dewaxing unit to produce a base oil.2. The process of claim 1 , wherein the naphtha/diesel fraction of (c) is passed directly to a refinery crude unit and the contaminants are removed in a crude unit desalter.3. The process of claim 1 , wherein contaminants are removed at the pyrolysis site.4. The process of ...

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Номер записи: 84
24-06-2021 дата публикации

CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYPROPYLENE AND LUBRICATING OIL VIA REFINERY FCC AND ISOMERIZATION DEWAXING UNITS

Номер: US20210189254A1
Автор: Timken Hye-Kyung
Принадлежит: Chevron U.S.A. INC.

A continuous process for converting waste plastic into recycle for polypropylene polymerization is provided. The process integrates refinery operations to provide an effective and efficient recycle process. The process comprises selecting waste plastics containing polyethylene and polypropylene and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a refinery FCC unit, from which is recovered a liquid petroleum gas Colefin/paraffin mixture. The Cparaffins and Colefins are separated into different fractions with a propane/propylene splitter. The Colefin fraction is passed to a propylene polymerization reactor. The Cparaffin fraction is optionally passed to a dehydrogenation unit to produce additional propylene and then the resulting Colefin is passed to a propylene polymerization reactor. The heavy fraction of pyrolyzed oil is passed to an isomerization dewaxing unit to produce a lubricating base oil. 1. A continuous process for converting waste plastic into recycle for polypropylene polymerization comprising:(a) selecting waste plastics containing polyethylene and/or polypropylene;(b) passing the waste plastics from (a) through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent;(c) separating the pyrolyzed effluent into offgas, a naphtha/diesel fraction, a heavy fraction, and char;(d) passing the naphtha/diesel fraction to a refinery FCC unit;{'sub': '3', '(e) recovering a liquid petroleum gas Colefin/paraffin mixture from the FCC unit;'}{'sub': 3', '3, '(f) separating the Cparaffin and Colefin into different fractions;'}{'sub': '3', '(g) passing the Colefin to a propylene polymerization reactor; and'}(h) passing the heavy fraction to an isomerization ...

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Номер записи: 85
16-06-2016 дата публикации

Sulfur-resistant Catalyst for Aromatics Saturated Hydrogenation and Preparation Method Thereof

Номер: US20160167017A1
Автор: CHU Hongling, Feng Yuxiao, Gao Shanbin, Guo Jintao, Hu Sheng, JI Yuanyuan, JIANG Lili, LI RUI, Li Ruifeng, LIU Wenyong, Liu Yanfeng, Sun Famin, Sun Ran, Tang Cheng, Wang Xiaofeng, WANG Xinmiao, WU Xianjun, Xie Bin, Yang Xiaodong, Yu Chunmei, ZHANG Guojia, ZHANG Quanguo, Zhang Wencheng, ZHAO Tan
Принадлежит:

The present invention relates to a method for preparing a sulfur-resistant catalyst for aromatics saturated hydrogenation, comprising the steps of: preparing noble metal impregnation solutions from a noble metal and deionized water or an acid solution; impregnating a carrier with the impregnation solutions sequentially from high to low concentrations by incipient impregnation; homogenizing, drying, and calcinating to obtain the sulfur-resistant catalyst for aromatics saturated hydrogenation. The catalyst for aromatics saturated hydrogenation prepared by the method according to the present invention is primarily used in processing low-sulfur and high-aromatics light distillate, middle distillate, atmospheric gas oil, and vacuum gas oil. The method according to the present invention is advantageous in that the catalyst for aromatics saturated hydrogenation exhibits good hydrofining performance, superior aromatics saturation performance, high liquid yield of products, as well as excellent desulfurization and sulfur-resistance, and the catalyst has remarkable effects in use and a great prospect of application. 1. A method for preparing a sulfur-resistant catalyst for aromatics saturated hydrogenation , comprising the steps of:(1) preparing noble metal impregnation solutions from a noble metal and deionized water or an acid solution;(2) impregnating a carrier consisting of an inorganic porous material with the impregnation solutions by incipient impregnation; and(3) homogenizing for 10 min to 3 h, drying at 90 to 140° C. for 3 to 6 h, and calcinating at 350 to 650° C. for 3 to 10 h to obtain a sulfur-resistant catalyst for aromatics saturated hydrogenation;characterized in that, during the impregnation in the above step (2), the carrier is impregnated sequentially with the impregnation solutions from high to low concentrations, or a noble metal impregnation solution at a high concentration is prepared and then the concentration of the active metal-containing impregnation ...

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Номер записи: 86
16-06-2016 дата публикации

AROMATIC HYDROGENATION CATALYSTS AND USES THEREOF

Номер: US20160167032A1
Автор: Afeworki Mobae, Beeckman Jean Willem Lodewijk, Benitez Kiara M., CALABRO David Charles, Ide Matthew Scott, Li Quanchang, McCarthy Stephen John, Podsiadlo Paul, Weston Simon Christopher, ZHANG LEI
Принадлежит: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

Hydrogenation catalysts for aromatic hydrogenation including an organosilica material support, which is a polymer comprising independent units of a monomer of Formula [ZOZOSiCH](I), wherein each Zand Zindependently represent a hydrogen atom, a C-Calkyl group or a bond to a silicon atom of another monomer; and at least one catalyst metal are provided herein. Methods of making the hydrogenation catalysts and processes of using, e.g., aromatic hydrogenation, the hydrogenation catalyst are also provided herein. 1. An aromatics hydrogenation process for a hydrocarbon feedstream comprising:a) contacting a hydrocarbon feedstream comprising aromatics with a hydrogenation catalyst in the presence of a hydrogen-containing treat gas in a reaction stage operated under effective aromatics hydrogenation conditions to produce a reaction product with reduced aromatics content, [{'sup': 1', '2', '1', '2, 'sub': 2', '3', '1', '4, '(i) an organosilica material support, which is a polymer comprising independent units of a monomer of Formula [ZOZOSiCH](I), wherein each Zand Zindependently represent a hydrogen atom, a C-Calkyl group or a bond to a silicon atom of another monomer; and'}, '(ii) at least one catalyst metal selected from the group consisting of a Group 8 metal, a Group 9 metal, a Group 10 metal and a combination thereof., 'wherein the hydrogenation catalyst comprises2. The process of claim 1 , wherein each Zand Zindependently represent a hydrogen atom claim 1 , a C-Calkyl group or a bond to a silicon atom of another monomer.3. The process of claim 2 , wherein each Zand Zindependently represent a hydrogen atom claim 2 , ethyl or a bond to a silicon atom of another monomer.4. The process of claim 1 , wherein the organosilica material support further comprises at least one other monomer selected from the group consisting of:{'sup': 3', '4', '3', '4, 'sub': 2', '3', '1', '4', '1', '6, '(i) an independent unit of Formula [ZOZSiCH](II), wherein each Zrepresents a hydrogen atom, a ...

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Номер записи: 87
16-06-2016 дата публикации

Organosilica materials and uses thereof

Номер: US20160168333A1
Автор: Bal Kaul, Darryl Donald LACY, David Charles Calabro, Himanshu Gupta, James William Gleeson, Kiara M. BENITEZ, Lei Zhang, Paul Podsiadlo, Quanchang Li, Scott J. WEIGEL, Wenyih Frank Lai, Xiaochun Xu
Принадлежит: ExxonMobil Research and Engineering Co

Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula wherein each R 1 is a Z 1 OZ 2 Z 3 SiZ 4 group, wherein each Z 1 represents a hydrogen atom, a C 1 -C 4 alkyl group, or a bond to a silicon atom of another monomer unit; each Z 2 and Z 3 independently represent a hydroxyl group, a C 1 -C 4 alkyl group, a C 1 -C 4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Z 4 represents a C 1 -C 8 alkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.

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Номер записи: 88
15-06-2017 дата публикации

NOVEL MIXED METAL OXIDES

Номер: US20170165644A1
Автор: Koster Susan C., Miller Stuart
Принадлежит:

A novel mixed metal molybdate useful as a hydroprocessing catalyst has been created. The hydroprocessing using the novel mixed metal molybdate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The mixed metal oxide of wherein the mixed metal oxide is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.3. The mixed metal oxide of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The mixed metal oxide of wherein M is nickel or cobalt.5. The mixed metal oxide of wherein M is nickel.6. The mixed metal oxide of wherein the mixed metal oxide is sulfided.8. The method of wherein the recovering is by filtration or centrifugation.9. The method of further comprising adding a binder to the crystalline bis-ammonia metal molybdate precursor claim 7 , or to the mixed metal oxide claim 7 , or both.10. The method of wherein the binder is selected from the group consisting of aluminas claim 9 , silicas claim 9 , and alumina-silicas.11. The method of further comprising sulfiding the crystalline bis-ammonia metal molybdate precursor claim 7 , or the mixed metal oxide claim 7 , or both.12. The method of wherein M is nickel or cobalt.14. The process of wherein the conversion process is hydroprocessing.15. The process of wherein the hydroprocessing process is selected from the group consisting of hydrodenitrification claim 14 , hydrodesulfurization claim 14 , hydrodemetallation claim 14 , hydrodearomatization claim 14 , hydroisomerization claim 14 , hydrodesilication claim 14 , hydrotreating claim 14 , hydrofining claim 14 , and hydrocracking.16. The process of wherein the mixed metal oxide is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.17. The process of wherein the ...

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Номер записи: 89
15-06-2017 дата публикации

NOVEL MIXED METAL OXIDES

Номер: US20170165645A1
Автор: Koster Susan C., Miller Stuart
Принадлежит:

A unique mixed metal molybdotungstate material has been developed. The material may be used as a hydroprocessing catalyst. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodearomatization, hydrodesilication, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The mixed metal oxide material of wherein the mixed metal oxide is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.3. The mixed metal oxide material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The mixed metal oxide material of wherein M is nickel or cobalt.5. The mixed metal oxide material of wherein M is nickel.6. The mixed metal oxide material of wherein the mixed metal oxide is sulfided.8. The method of wherein the recovering is by filtration or centrifugation.9. The method of further comprising adding a binder to the recovered bis-ammonia transition metal molybdotungstate precursor material or to the recovered mixed metal oxide or both.10. The method of wherein the binder is selected from the group consisting of aluminas claim 9 , silicas claim 9 , and alumina-silicas.11. The method of further comprising sulfiding the recovered bis-ammonia transition metal molybdotungstate precursor material or the recovered mixed metal oxide or both.13. The process of wherein the conversion process is hydroprocessing.14. The process of wherein the hydroprocessing process is selected from the group consisting of hydrodenitrification claim 13 , hydrodesulfurization claim 13 , hydrodemetallation claim 13 , hydrodearomatization claim 13 , hydroisomerization claim 13 , hydrotreating claim 13 , hydrofining claim 13 , and hydrocracking.15. The process of wherein the mixed metal oxide is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.16. The process of wherein the binder is ...

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Номер записи: 90
15-06-2017 дата публикации

CRYSTALLINE BIS-AMMONIA METAL MOLYBDATE

Номер: US20170165646A1
Автор: Koster Susan C., Miller Stuart
Принадлежит:

A unique crystalline bis-ammonia metal molybdate material has been developed. The material may be used as a hydroprocessing catalyst. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodearomatization, hydrodesilication, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The crystalline bis-ammonia metal molybdate material of wherein the crystalline bis-ammonia metal molybdate material is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.3. The crystalline bis-ammonia metal molybdate material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The crystalline bis-ammonia metal molybdate material of wherein M is nickel or cobalt.5. The crystalline bis-ammonia metal molybdate material of wherein M is nickel.6. The crystalline bis-ammonia metal molybdate material of wherein the crystalline bis-ammonia metal molybdate material is sulfided.8. The method of wherein the recovering is by filtration or centrifugation.9. The method of further comprising adding a binder to the recovered crystalline bis-ammonia metal molybdate material.10. The method of wherein the binder is selected from the group consisting of aluminas claim 9 , silicas claim 9 , and alumina-silicas.11. The method of further comprising sulfiding the recovered crystalline bis-ammonia metal molybdate material.13. The process of wherein the conversion process is hydroprocessing.14. The process of wherein the hydroprocessing process is selected from the group consisting of hydrodenitrification claim 13 , hydrodesulfurization claim 13 , hydrodemetallation claim 13 , hydrodearomatization claim 13 , hydroisomerization claim 13 , hydrodesilication claim 13 , hydrotreating claim 13 , hydrofining claim 13 , and hydrocracking.15. The process of wherein the crystalline bis-ammonia metal molybdate material is present in a mixture with ...

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Номер записи: 91
15-06-2017 дата публикации

Crystalline transition metal oxy-hydroxide molybdate

Номер: US20170165647A1
Автор: Stuart Miller, Susan C. Koster
Принадлежит: UOP LLC

A hydroprocessing catalyst has been developed. The catalyst is a unique crystalline transition metal oxy-hydroxide molybdate material. The hydroprocessing using the crystalline ammonia transition metal oxy-hydroxide molybdate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

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Номер записи: 92
15-06-2017 дата публикации

CRYSTALLINE TRANSITION METAL OXY-HYDROXIDE MOLYBDOTUNGSTATE

Номер: US20170165648A1
Автор: Koster Susan C., Miller Stuart
Принадлежит:

A hydroprocessing catalyst has been developed. The catalyst is a unique crystalline transition metal oxy-hydroxide molybdotungstate material. The hydroprocessing using the crystalline ammonia transition metal oxy-hydroxide molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The crystalline transition metal oxy-hydroxide molybdotungstate material of wherein the crystalline transition metal oxy-hydroxide molybdotungstate material is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.3. The crystalline transition metal oxy-hydroxide molybdotungstate material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The crystalline transition metal oxy-hydroxide molybdotungstate material of wherein the crystalline transition metal oxy-hydroxide molybdotungstate material is sulfided.6. The method of wherein the reacting is conducted at a temperature of from 10° C. to about 200° C. for a period of time from about 30 minutes to 14 days.7. The method of wherein the recovering is by filtration or centrifugation.8. The method of further comprising adding a binder to the recovered crystalline transition metal oxy-hydroxide molybdotungstate material.9. The method of wherein the binder is selected from the group consisting of aluminas claim 8 , silicas claim 8 , and alumina-silicas.10. The method of further comprising sulfiding the recovered crystalline transition metal oxy-hydroxide molybdotungstate material.12. The process of wherein the conversion process is hydroprocessing.13. The process of wherein the conversion process is selected from the group consisting of hydrodenitrification claim 11 , hydrodesulfurization claim 11 , hydrodemetallation claim 11 , hydrodesilication claim 11 , hydrodearomatization ...

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Номер записи: 93
15-06-2017 дата публикации

CRYSTALLINE AMMONIA TRANSITION METAL MOLYBDATE

Номер: US20170165649A1
Автор: Collins Laura, Miller Stuart
Принадлежит:

A hydroprocessing catalyst has been developed. The catalyst is a unique crystalline ammonia transition metal molybdate material. The hydroprocessing using the crystalline ammonia transition metal molybdate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The crystalline ammonia transition metal molybdate material of wherein the crystalline ammonia transition metal molybdate material is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.3. The crystalline ammonia transition metal molybdate material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The crystalline ammonia transition metal molybdate material of wherein M is nickel or cobalt.5. The crystalline ammonia transition metal molybdate material of wherein M is nickel.6. The crystalline ammonia transition metal molybdate material of wherein the crystalline ammonia transition metal molybdate material is sulfided.8. The method of wherein the recovering is by filtration claim 7 , centrifugation or evaporation of solvent.9. The method of further comprising adding a binder to the recovered crystalline ammonia transition metal molybdate material.10. The method of wherein the binder is selected from the group consisting of aluminas claim 9 , silicas claim 9 , and alumina-silicas.11. The method of further comprising sulfiding the recovered crystalline ammonia transition metal molybdate material.13. The process of wherein the conversion process is hydroprocessing.14. The process of wherein the hydroprocessing process is selected from the group consisting of hydrodenitrification claim 13 , hydrodesulfurization claim 13 , hydrodemetallation claim 13 , hydrodesilication claim 13 , hydrodearomatization claim 13 , hydroisomerization claim 13 , hydrotreating ...

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Номер записи: 94
15-06-2017 дата публикации

CRYSTALLINE TRANSITION METAL TUNGSTATE

Номер: US20170165650A1
Автор: Collins Laura, Miller Stuart
Принадлежит:

A hydroprocessing catalyst has been developed. The catalyst is a unique transition metal tungstate material. The hydroprocessing using the crystalline ammonia transition metal dimolybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 5. The crystalline transition metal tungstate material of wherein M is nickel.6. The crystalline transition metal tungstate material of wherein the crystalline transition metal tungstate material is sulfided.2. The crystalline transition metal tungstate material of wherein the crystalline transition metal tungstate material is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.3. The crystalline transition metal tungstate material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The crystalline transition metal tungstate material of wherein M is nickel or cobalt.(d) recovering the crystalline transition metal tungstate material.8. The method of wherein the reacting is conducted at a temperature of from 30° C. to about 130° C. for a period of time from about 30 minutes to 14 days.9. The method of wherein the recovering is by filtration claim 7 , centrifugation or drying.10. The method of further comprising adding a binder to the recovered crystalline transition metal tungstate material.11. The method of wherein the binder is selected from the group consisting of aluminas claim 10 , silicas claim 10 , and alumina-silicas.12. The method of further comprising sulfiding the recovered crystalline transition metal tungstate material.14. The process of wherein the conversion process is hydroprocessing.15. The process of wherein the conversion process is selected from the group consisting of hydrodenitrification claim 13 , hydrodesulfurization claim 13 , hydrodemetallation ...

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Номер записи: 95
15-06-2017 дата публикации

CRYSTALLINE AMMONIA TRANSITION METAL MOLYBDOTUNGSTATE

Номер: US20170165651A1
Автор: Collins Laura, Miller Stuart
Принадлежит:

A hydroprocessing catalyst has been developed. The catalyst is a unique crystalline ammonia transition metal molybdotungstate material. The hydroprocessing using the crystalline ammonia transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The crystalline ammonia transition metal molybdotungstate material of wherein the crystalline ammonia transition metal molybdotungstate material is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.3. The crystalline ammonia transition metal molybdotungstate material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The crystalline ammonia transition metal molybdotungstate material of wherein M is nickel or cobalt.5. The crystalline ammonia transition metal molybdotungstate material of wherein M is nickel.6. The crystalline ammonia transition metal molybdotungstate material of wherein the crystalline ammonia transition metal molybdotungstate material is sulfided.8. The method of wherein the recovering is by filtration or centrifugation or evaporation of solvent9. The method of further comprising adding a binder to the recovered crystalline ammonia transition metal molybdotungstate material.10. The method of wherein the binder is selected from the group consisting of aluminas claim 7 , silicas claim 7 , and alumina-silicas.11. The method of further comprising sulfiding the recovered crystalline ammonia transition metal molybdotungstate material.13. The process of wherein the conversion process is hydroprocessing.14. The process of wherein the hydroprocessing process is selected from the group consisting of hydrodenitrification claim 13 , hydrodesulfurization claim 13 , hydrodemetallation claim 13 , hydrodesilication claim 13 , ...

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Номер записи: 96
15-06-2017 дата публикации

CRYSTALLINE TRANSITION METAL MOLYBDOTUNGSTATE

Номер: US20170165652A1
Автор: Collins Laura, Miller Stuart
Принадлежит:

A hydroprocessing catalyst has been developed. The catalyst is a unique transition metal tungstate material. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The crystalline transition metal molybdotungstate material of wherein the crystalline transition metal molybdotungstate material is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.3. The crystalline transition metal molybdotungstate material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The crystalline transition metal molybdotungstate material of wherein M is nickel or cobalt.5. The crystalline transition metal molybdotungstate material of wherein M is nickel.6. The crystalline transition metal molybdotungstate material of wherein the crystalline transition metal molybdotungstate material is sulfided.8. The method of wherein the reacting is conducted at a temperature of from 30° C. to about 130° C. for a period of time from about 30 minutes to 14 days.9. The method of wherein the recovering is by filtration claim 7 , centrifugation or drying.10. The method of further comprising adding a binder to the recovered crystalline transition metal molybdotungstate material.11. The method of wherein the binder is selected from the group consisting of aluminas claim 7 , silicas claim 7 , and alumina-silicas.12. The method of further comprising sulfiding the recovered crystalline transition metal molybdotungstate material.14. The process of wherein the conversion process is hydroprocessing.15. The process of wherein the conversion process is selected from the group consisting of hydrodenitrification claim 13 , hydrodesulfurization claim 13 , hydrodemetallation claim 13 , ...

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Номер записи: 97
15-06-2017 дата публикации

TRANSITION METAL TUNGSTEN OXY-HYDROXIDE

Номер: US20170165656A1
Автор: Koster Susan C., Miller Stuart
Принадлежит:

A hydroprocessing catalyst has been developed. The catalyst is a unique transition metal tungsten oxy-hydroxide material. The hydroprocessing using the transition metal tungsten oxy-hydroxide material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The transition metal tungsten oxy-hydroxide material of wherein the transition metal tungsten oxy-hydroxide material is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt % binder.3. The transition metal tungsten oxy-hydroxide material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The transition metal tungsten oxy-hydroxide material of wherein M is nickel or cobalt.5. The transition metal tungsten oxy-hydroxide material of wherein M is nickel.6. The transition metal tungsten oxy-hydroxide material of wherein the transition metal tungsten oxy-hydroxide material is sulfided.8. The method of wherein the reacting is conducted at a temperature ranging from about 60° C. to about 120° C. for a period of time ranging from 30 minutes to around 2 days.9. The method of wherein the recovering is by filtration or centrifugation.10. The method of further comprising adding a binder to the recovered metal tungsten oxy-hydroxide material11. The method of wherein the binder is selected from the group consisting of aluminas claim 10 , silicas claim 10 , and alumina-silicas.12. The method of further comprising sulfiding the recovered transition metal tungsten oxy-hydroxide material.14. The process of wherein the conversion process is hydroprocessing.15. The process of wherein the conversion process is selected from the group consisting of hydrodenitrification claim 13 , hydrodesulfurization claim 13 , hydrodemetallation claim 13 , hydrodesilication claim 13 , hydrodearomatization claim 13 ...

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Номер записи: 98
15-06-2017 дата публикации

RAPID ESTIMATION OF FEED POTENTIAL FOR BASE OIL FORMATION

Номер: US20170166827A1
Автор: Gong Liezhong, Gooding Beatrice M., Joseck Eric D., Powers Corry S.
Принадлежит:

Methods are provided for rapidly characterizing a feedstock being considered for lubricant base oil production in order to determine the viscosity index potential of the feedstock. It has unexpectedly been discovered that the DDVI value for a feedstock at a specified pour point can be predicted based on a) the feed distillate residual wax content at a temperature as determined by Differential Scanning Calorimetry, such as the feed distillate residual wax content at a temperature corresponding to the specified pour point temperature; b) the feed distillate refractive index; c) the feed distillate kinematic viscosity at a temperature, such as kinematic viscosity at 100° C.; and d) the distillate volume-averaged boiling point. Based on this unexpected correlation, the VI potential of a feedstock can be determined based on measurement of properties that can be performed on a time scale corresponding to one or a few days using a few milliliters of feedstock. 1. A method for determining feedstock quality for lubricant base oil production , comprising:determining a wax content of a distillate feedstock fraction by differential scanning calorimetry;obtaining a characteristic boiling point, a characteristic viscosity, and a refractive index for the distillate feedstock fraction;calculating a distillate dewaxed viscosity index (DDVI) at a DDVI-temperature for the distillate feedstock fraction based on the determined wax content and at least two of the obtained characteristic boiling point, the obtained characteristic viscosity, and the obtained refractive index, the calculated DDVI being at least 0 at the DDVI-temperature; andprocessing the feedstock to form a lubricant base oil having a viscosity index of at least 80 and a pour point of 0° C. or less.2. The method of claim 1 , wherein the DDVI-temperature is −9° C.3. The method of claim 1 , wherein the wax content of the distillate feedstock fraction is determined based on the relationship W=ΔH/A(T) claim 1 , where W is the ...

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Номер записи: 99
01-07-2021 дата публикации

Use of renewable oil in hydrotreatment process

Номер: US20210198580A1
Автор: Petri Lindqvist, Tuomas Ouni, Väinö Sippola
Принадлежит: Neste Oyj

The use of bio oil from at least one renewable source in a hydrotreatment process, in which process hydrocarbons are formed from said glyceride oil in a catalytic reaction, and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron. A bio oil intermediate including bio oil from at least one renewable source and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron.

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Номер записи: 100