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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 2156. Отображено 100.
12-04-2012 дата публикации

Moisture-thickening heat-conductive silicone grease composition

Номер: US20120085964A1
Принадлежит: Shin Etsu Chemical Co Ltd

A heat-conductive silicone grease composition is obtained by combining (A) a hydroxyl-endcapped organopolysiloxane, (B) a specific organopolysiloxane, (C) a silane compound having at least three hydrolyzable radicals and/or a hydrolyzate thereof, (D) a thickening catalyst, and (E) a heat-conductive filler. The composition is storable at RT, has a low initial viscosity enough to coat, and after coating, thickens with moisture at RT so that it becomes anti-sagging, remains re-workable, and has durable heat resistance.

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12-04-2012 дата публикации

Polymer-Fiber Composite Building Material with Bulk and Aesthetically Functional Fillers

Номер: US20120088858A1
Принадлежит: Individual

Polymer composite roofing materials are provided which contain resin, and about 20-75 wt. % fillers and additives, in which the fillers contain at least one bulk filler for reducing the amount of resin needed to make the roofing material, and at least one aesthetically functional filler for providing the roofing material with an aesthetic appearance. The bulk filler and the aesthetically functional filler of this embodiment are non-toxic, resistant to microbial attack, and have a Mohs hardness of less than about 5.

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03-05-2012 дата публикации

Fuel and base oil blendstocks from a single feedstock

Номер: US20120108869A1
Принадлежит: Chevron USA Inc

A method comprising the steps of providing a quantity of biologically-derived oil comprising triglycerides; processing the biologically derived oil so as to transesterify at least some of the triglycerides contained therein to yield a quantity of saturated monoesters and unsaturated monoesters; oligomerizing at least some of the unsaturated monoesters to yield a quantity of fatty acid ester oligomers; separating at least some of the saturated monoesters from the fatty acid ester oligomers; and hydrotreating at least some of the fatty acid ester oligomers to yield a quantity of alkanes.

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25-07-2013 дата публикации

LUBRICANT BASE STOCKS FROM RENEWABLE SOURCES WITH IMPROVED LOW TEMPERATURE PROPERTIES

Номер: US20130190544A1

Provided are lube base stocks produced from renewable biological sources with improved low temperature properties. In one form, the lube base stock includes from 10 to 35 wt. % paraffins, 40 to 70 wt. % 1-ring naphthenes, and 0 to 40 wt. % combined 2-ring naphthenes and aromatics, and has a ratio of 1-ring naphthenes to paraffins from 1.8 to 5.0, and a Viscosity Index of from 100 to 160. The lube base stock has a C level ranging from 2 to 101% of the modern day C level in the atmosphere, and yields a CCS ratio (Cold Crank Simulator (CCS) viscosity to the predicted CCS viscosity by Walther equation) of less than or equal to 0.85 at −35° C. The base stocks are useful as in formulated lubricant compositions requiring improved low temperature properties. 1. A lube base stock produced from a renewable biological source comprising from 10 to 35 wt. % paraffins , 40 to 70 wt. % 1-ring naphthenes , and 0 to 40 wt. % combined 2-ring naphthenes and aromatics ,wherein the ratio of 1-ring naphthenes to paraffins is from 1.8 to 5.0, andwherein the Viscosity Index of the lube base stock is from 100 to 160.2. The lube base stock of claim 1 , wherein the paraffins range from 15 to 30 wt. %.3. The lube base stock of claim 1 , wherein the 1-ring naphthenes range from 45 to 65 wt. %.4. The lube base stock of claim 1 , wherein the combined 2-ring naphthenes and aromatics range from 5 to 35 wt. %.5. The lube base stock of claim 1 , wherein the ratio of 1-ring naphthene to paraffins is from 1.9 to 4.0.6. The lube base stock of claim 1 , wherein the Viscosity Index of the lube base stock is from 110 to 140.7. The lube base stock of claim 1 , wherein the lube base stock yields a CCS ratio (Cold Crank Simulator (CCS) viscosity to the predicted CCS viscosity by Walther equation) less than or equal to 0.85 at −35° C.8. The lube base stock of claim 1 , wherein the lube base stock yields a CCS ratio (Cold Crank Simulator (CCS) viscosity to the predicted CCS viscosity by Walther equation) less ...

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29-08-2013 дата публикации

Tetrafluoropropene compositions and uses thereof

Номер: US20130221262A1
Принадлежит: EI Du Pont de Nemours and Co

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a tetrafluoropropene and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

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29-08-2013 дата публикации

Low viscosity oligomer oil product, process and composition

Номер: US20130225459A1
Принадлежит: INEOS USA LLC

The present invention relates to a low viscosity lubricant process, product, and composition characterized by low Noack volatility, low pour point, useful low temperature viscometrics, and high viscosity index and more particularly concerns a PAO composition having a kinetic viscosity at 100° C. in the range of about 4 cSt.

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05-09-2013 дата публикации

Transmission lubricant

Номер: US20130229016A1
Принадлежит: Evonik RohMax Additives GmbH

The present invention relates to a transmission lubricant comprising at least 30% by weight of polyalkyl (meth)acrylate. The present invention further describes polyalkyl (meth)acrylates for use in lubricants and also processes for preparing them and their use. The present lubricants can be used particularly in wind turbine transmissions.

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19-09-2013 дата публикации

Poly Alpha Olefin Compositions

Номер: US20130245344A1
Принадлежит:

Poly alpha olefins (PAOs) are characterized by very low viscosity and excellent Noack volatility. A preferred process for synthesizing said PAOs involves first oligomerizing low molecular weight linear alpha olefins in the presence of a single site catalyst at high temperatures without adding hydrogen and then subsequently oligomerizing at least a portion of the product from the first step in the presence of an oligomerization catalyst. 1. A poly alpha olefin , wherein the poly alpha olefin has a kinematic viscosity at 100° C. of not more than 3.2 cSt and a Noack volatility of not more than 19 wt %.2. The poly alpha olefin of claim 1 , wherein the poly alpha olefin has a cold crank simulator value (CCS) at −25° C. of not more than 450 cP.3. The poly alpha olefin of claim 1 , wherein the poly alpha olefin has a portion having a carbon count of C-Cand said portion has a pour point of less than −70° C.4. The poly alpha olefin of claim 1 , wherein the poly alpha olefin is hydrogenated claim 1 , and prior to hydrogenation at least a portion of the poly alpha olefin is comprised of at least 10 wt % of tetra-substituted olefins.5. The poly alpha olefin of claim 1 , wherein the poly alpha olefin is hydrogenated claim 1 , and prior to hydrogenation at least a portion of the poly alpha olefin is comprised of at least 60 wt % tri-substituted olefins.6. A poly alpha olefin wherein the poly alpha olefin has a kinematic viscosity at 100° C. of not more than 4.1 cSt and a Noack volatility of not more than 9 wt %.7. The poly alpha olefin of claim 6 , wherein the poly alpha olefin has a Noack volatility of not more than 7.5 wt %.8. The poly alpha olefin of claim 6 , wherein the poly alpha olefin has a viscosity index (VI) of more than 136.9. The poly alpha olefin of claim 6 , wherein the poly alpha olefin has a portion having a carbon count of C-Cand said portion has a kinematic viscosity at 100° C. of not more than 10 cSt.10. The poly alpha olefin of claim 6 , wherein the poly ...

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26-09-2013 дата публикации

Process to Produce Improved Poly Alpha Olefin Compositions

Номер: US20130253244A1
Принадлежит:

This invention is directed to a two-step process for the preparation of improved poly alpha olefins wherein the first step involves oligomerizing low molecular weight linear alpha olefins in the presence of a single site catalyst and the second step involves oligomerization of at least a portion of the product from the first step in the presence of an oligomerization catalyst. The dimer product from the first oligomerization is characterized by a tri-substituted vinylene olefin content of at least 25 wt %. 2. The process of claim 1 , including the step of separating the at least a portion of the dimer product from the trimer and optional higher oligomer products prior to feeding said dimer product to the second reactor.3. The process of claim 2 , wherein said separating step comprises distillation.4. The process of claim 1 , wherein said portion of dimer product from the first reactor is fed directly into the second reactor.5. The process of claim 1 , wherein the first reactor effluent further comprises unreacted monomer claim 1 , and the unreacted monomer is fed to the second reactor.7. The process of claim 1 , wherein Rx and Ry are independently selected from a Cto Calkyl group.8. The process of claim 1 , wherein the dimer product of the first reactor effluent contains greater than 50 wt % of tri-substituted vinylene dimer.9. The process of claim 1 , wherein the second reactor effluent has a product having a carbon count of C-C claim 1 , wherein said product comprises at least 70 wt % of said second reactor effluent.10. The process of claim 1 , wherein the second reactor effluent has a kinematic viscosity at 100° C. in the range selected from 1 to 150 cSt claim 1 , 1 to 20 cSt claim 1 , 1 to 3.6 cSt claim 1 , 40 to 150 cSt claim 1 , or 60 to 100 cSt.11. The process of claim 1 , wherein monomer is fed into the second reactor claim 1 , and the monomer is a linear alpha olefin selected from the group including 1-hexene claim 1 , 1-octene claim 1 , 1-nonene claim 1 , ...

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19-12-2013 дата публикации

LUBRICATING COMPOSITION

Номер: US20130333654A1
Автор: Wedlock David

A lubricating composition comprising a base oil blend and one or more additives wherein the base oil blend comprises: a distillate naphthenic base oil having a saturates content as measured by IP368 of greater than 92 wt % and comprising less than 10 ppm of sulphur; and a Fischer-Tropsch derived base oil. The lubricating composition of the present invention exhibits improved detergency and engine cleanliness properties. 1. A lubricating composition comprising a base oil blend and one or more additives wherein the base oil blend comprises:a distillate naphthenic base oil having a saturates content as measured by IP368 of greater than 92wt % and comprising less than 10 ppm of sulphur; anda Fischer-Tropsch derived base oil.2. A lubricating composition according to wherein the weight ratio of the distillate naphthenic base oil to the Fischer-Tropsch derived base oil is in the range of from 10:90 to 50:50.3. A lubricating composition according to wherein the weight ratio of the distillate naphthenic base oil to the Fischer-Tropsch derived base oil is in the range of from 10:90 to 40:60.4. A lubricating composition according to wherein the weight ratio of the distillate naphthenic base oil to the Fischer-Tropsch derived base oil is in the range of from 10:90 to 30:70.5. A lubricating composition according to wherein the base oil blend has a pour point of less than -24° C. (according to ASTM D 5950).6. A lubricating composition according to wherein the base oil blend has a Viscosity Index (according to ASTM D 2270) of greater than 95.7. A lubricating composition according to wherein the base oil blend has a kinematic viscosity at 100° C. in the range of from 2.5 mm/s to 35 mm/s (according to ASTM D445).8. A lubricating composition according to wherein the Fischer-Tropsch derived base oil has a kinematic viscosity at 100° C. in the range of from 2.5 mm/s to 14 mm/s (according to ASTM D445).9. A lubricating composition according to wherein the lubricating composition has a ...

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13-03-2014 дата публикации

BASE OIL UPGRADING BY CO-FEEDING A KETONE OR BETA-KETO-ESTER FEEDSTOCK

Номер: US20140073826A1
Принадлежит: Chevron U.S.A. INC.

This invention discloses a process for making high viscosity index lubricating base oils having a viscosity index of at least 110 by co-feeding a ketone or a beta-keto-ester feedstock with a lubricant oil feedstock directly to a hydrocracking unit to produce a hydrocracked stream. Then at least a portion of the hydrocracked stream is treated under hydroisomerization conditions to produce a high viscosity index lubricating base oil. The process may involve bypassing a hydrotreating or hydrofinishing step, which may result in improved efficiency and economics in producing high viscosity index lubricating base oils. 1. A process for increasing the viscosity index of a base oil , comprising: i. one or more fatty acids which can be the same or different and a decarboxylation-coupling catalyst, or', 'ii. one or more esters of fatty acids which can be the same or different and a base;, 'a) providing a ketone or a beta-keto-ester feedstock from a reaction in a decarboxylation-coupling zone with one or more reactants comprisingb) providing a blend by co-feeding the ketone or the beta-keto-ester feedstock of Step a) with a lubricant oil feedstock together or separately into a hydrocracking zone;c) hydrocracking the blend of Step b) in a lubricant hydrocracking zone in the presence of a hydrocracking catalyst and hydrogen under lubricant hydrocracking conditions to produce a hydrocracked stream; andd) dewaxing at least a portion of the hydrocracked stream in a hydroisomerization zone in the presence of a hydroisomerization catalyst and hydrogen under hydroisomerization conditions to produce a base oil.2. The process of claim 1 , wherein the ketone feedstock is aliphatic having from 20 to 48 carbon atoms and combinations thereof.3. The process of claim 1 , wherein the beta-keto-ester feedstock is aliphatic having from 20 to 60 carbon atoms and combinations thereof.4. The process of claim 1 , further comprising distilling the hydrocracked stream of Step c) to separate at least ...

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27-03-2014 дата публикации

Synthetic lubricant basestocks and methods of preparation thereof

Номер: US20140087984A1
Принадлежит: ExxonMobil Research and Engineering Co

This disclosure relates to vinyl terminated macromer (VTM) based synthetic basestocks and their methods of preparation, lubricant compositions, methods of lubrication and products so lubricated. The VTM based synthetic basestocks useful for fuels and lubricants include oligomerization or polymerization products of one or more allylic vinyl terminated macromers (VTMs) having a molecular weight from 84 to 10080. The one or more allylic VTMs are oligomerized or polymerized in the presence of a catalyst under oligomerization or polymerization conditions sufficient to give the VTM based synthetic basestock. The catalyst can be a metallocene catalyst or an acid catalyst, e.g., Lewis acid. The one or more allylic vinyl terminated macromers (VTMs) can be one or more allylic vinyl terminated atactic polypropylene macromers (VTM aPP) having a molecular weight from 84 to 2250 and having a terminal allylic vinyl olefin content of at least 90%.

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27-03-2014 дата публикации

CATALYTIC SYSTEM FOR PREPARATION OF HIGH BRANCHED ALKANE FROM OLEFINS

Номер: US20140088319A1

The present invention discloses a catalytic system for preparing highly branched alkane from olefin, which contains novel nickel or palladium complexes. In the presence of the catalytic system, highly branched oily alkane mixture can be efficiently obtained from olefins (such as ethylene) under mild conditions. The alkane mixture has a low bromine number, and can be used as a processing aid(s) and lubricant base oil with high-performance. Provides also was a method for preparing the catalyst and a method for preparing an oily olefin polymer. 2. The compound of claim 1 , wherein claim 1 , 1-3 substituent(s) of R claim 1 , R claim 1 , Rand Ris C-Calkyl claim 1 , C-Chaloalkyl or unsubstituted or substituted phenyl claim 1 , and 1-3 of substituent(s) is hydrogen or halogen.3. The compound of claim 1 , wherein claim 1 , Z and Y together with the adjacent carbon atom form unsubstituted or substituted acenaphthylene group.4. A complex claim 1 , wherein claim 1 , that is formed by the compound of and a salt(s) of divalent metal selected from the following group: nickel claim 1 , palladium or the combination thereof.6. A method for preparing the complex of claim 1 , wherein claim 1 , comprising a step of: in inert solvent claim 1 , reacting the compound of with a salt(s) of divalent metal as a metal precursor claim 1 , thereby forming the complex of claim 1 , wherein the metal precursor is divalent nickel compound or divalent palladium compound.7. The method of claim 6 , wherein claim 6 , the metal precursor contains NiCl claim 6 , NiBr claim 6 , NiI claim 6 , (DME)NiBr claim 6 , PdCl claim 6 , PdBr claim 6 , Pd(OTf) claim 6 , Pd(OAc)or the combination thereof.9. A method for preparing oily polyolefin claim 6 , wherein claim 6 , comprising a step of:{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, '(a) in the presence of the complex(es) of as a catalyst for olefin polymerization, catalyzing olefin polymerization, thereby forming an oily polyolefin.'}10. The method of claim ...

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07-01-2021 дата публикации

LUBRICATING OIL COMPOSITION, METHOD FOR PRODUCING LUBRICATING OIL COMPOSITION, AND CONTINUOUSLY VARIABLE TRANSMISSION

Номер: US20210002572A1
Принадлежит: IDEMITSU KOSAN CO.,LTD.

To provide a lubricating oil composition achieving both of high traction coefficient and excellent low temperature fluidity at a higher level and having a high flash point, which contains a naphthene-based synthetic oil (A) having a flash point of 140° C. or higher, a longifolene (B), and a predetermined monoester-based synthetic oil (C), a method for producing the lubricating oil composition, and a continuously variable transmission using the lubricating oil composition. 2: The lubricating oil composition according to claim 1 , wherein the naphthene-based synthetic oil (A) is a synthetic oil having at least one ring selected from a cyclohexane ring claim 1 , a bicycloheptane ring claim 1 , and a bicyclooctane ring.3: The lubricating oil composition according to claim 1 , wherein the naphthene-based synthetic oil (A) is a synthetic oil represented by the following general formula (2):{'br': None, 'sup': 21', '22', '23, 'sub': p', {'sub2': '21'}, '21', '22', 'p', {'sub2': '22'}], 'R—X—R—X—R\u2003\u2003(2)'}{'sup': 21', '23', '22, 'sub': 21', '22', '21', '22, 'wherein Rand Reach independently represent a hydrocarbon group, Rrepresents a hydrocarbon group, Xand Xeach independently represent a cyclohexane ring, a bicycloheptane ring, or a bicyclooctane ring, and pand peach independently represent an integer of 1 or more and 6 or less.'}4: The lubricating oil composition according to claim 3 , wherein in the general formula (2) claim 3 , Xand Xare each independently a cyclohexane ring claim 3 , a bicyclo[2.2.1]heptane ring claim 3 , a bicyclo[3.2.1]octane ring claim 3 , or a bicyclo[2.2.2]octane ring.5: The lubricating oil composition according to claim 3 , wherein in the general formula (2) claim 3 , Rand Reach independently represent an alkyl group or an alkenyl group claim 3 , and Rrepresents an alkylene group or an alkenylene group.6: The lubricating oil composition according to claim 3 , wherein in the general formula (2) claim 3 , Rand Reach independently represent ...

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03-01-2019 дата публикации

PROCESS FOR PREPARING A BASE OIL HAVING A REDUCED CLOUD POINT

Номер: US20190002773A1
Принадлежит:

The present invention relates to a process for preparing a residual base oil from a hydrocarbon feed which is derived from a Fischer-Tropsch process, the process comprises the steps of: (a) providing a hydrocarbon feed which is derived from a Fischer-Tropsch process; (b) subjecting the hydrocarbon feed of step (a) to a hydrocracking/hydroisomerisation step to obtain an at least partially isomerised product; (c) separating at least part of the at least partially isomerised product as obtained in step (b) into one or more lower boiling fractions and a hydrowax residue fraction; (d) catalytic dewaxing of the hydrowax residue fraction of step (c) to obtain a highly isomerised product; (e) separating the highly isomerised product of step (d) into one or more light fractions and a isomerised residual fraction; (f) mixing of the isomerised residual fraction of step (e) with a diluent to obtain a diluted isomerised residual fraction; (g) cooling the diluted isomerised residual fraction of step (f) to a temperature between 0° C. and −60° C.; (i) subjecting the mixture of step (g) to a centrifuging step at a temperature between 0° C. and −60° C. to isolate the wax from the diluted isomerised residual fraction; (j) separating the diluent from the diluted isomerised residual fraction to obtain a residual base oil. 1. A process for preparing a residual base oil from a hydrocarbon feed which is derived from a Fischer-Tropsch process , the process comprising the steps of:(a) providing a hydrocarbon feed which is derived from a Fischer-Tropsch process;(b) subjecting the hydrocarbon feed of step (a) to a hydrocracking/hydroisomerisation step to obtain an at least partially isomerised product;(c) separating at least part of the at least partially isomerised product as obtained in step (b) into one or more lower boiling fractions and a hydrowax residue fraction;(d) catalytic dewaxing of the hydrowax residue fraction of step (c) to obtain a highly isomerised product;(e) separating the ...

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03-01-2019 дата публикации

RESIDUAL BASE OIL

Номер: US20190002774A1
Принадлежит:

The present invention relates to a Fischer-Tropsch derived residual base oil having a kinematic viscosity at 100° C. according to ASTM D445 in the range of from 15 to 35 mm/s, an average number of carbon atoms per molecule Fischer-Tropsch derived residual base oil according to C-NMR in a range of from 25 to 50. 1. A Fischer-Tropsch derived residual base oil having a kinematic viscosity at 100° C. in the range of from 15 to 35 mm/s according to ASTM D445 , an average number of carbon atoms per molecule Fischer-Tropsch derived residual base oil according to C-NMR in a range of from 25 to 50.2. The Fischer-Tropsch derived residual base oil according to claim 1 , having an average number of carbon atoms per molecule Fischer-Tropsch derived residual base oil according to C-NMR of from 30 to 45 carbon atoms.3. The Fischer-Tropsch derived residual base oil according to claim 1 , having an average number of carbon atoms per molecule Fischer-Tropsch derived residual base oil according to C-NMR of from 31 to 45 carbon atoms.4. The Fischer-Tropsch derived residual base oil according to claim 1 , having an average number of carbons in the non-branched segment according to C-NMR of less than 14 carbon atoms.5. The Fischer-Tropsch derived residual base oil according to claim 1 , having an average number of branches normalized for a molecule of 50 carbon atoms in according to 13 C-NMR of at least 3.5.6. The Fischer-Tropsch derived residual base oil according to claim 1 , having a T10 wt. % recovery point in the range of from 470 to 590° C. claim 1 , a T50 wt. % recovery point in the range of from 550 to 710° C. claim 1 , a T80 wt. % recovery point of at least 630° C. and a T90 wt. % recovery point of at least 700° C. as measured with ASTM D7169.7. The Fischer-Tropsch derived residual base oil according claim 1 , having a pour point of less than −10 as measured according to ASTM D97.8. The Fischer-Tropsch derived residual base oil according to claim 1 , having a cloud point of ...

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03-01-2019 дата публикации

13C-NMR-BASED COMPOSITION OF HIGH QUALITY LUBE BASE OILS AND A METHOD TO ENABLE THEIR DESIGN AND PRODUCTION AND THEIR PERFORMANCE IN FINISHED LUBRICANTS

Номер: US20190002782A1
Принадлежит:

A lubricant base oil is provided. The lubricant base oil has a low temperature property determined using a stepwise regression of carbon-13 nuclear magnetic resonance (NMR) spectroscopy peak values. A method of selecting candidate lubricant base oils, or mixtures thereof, having acceptable low temperature performance is also provided. An online method of blending a lubricant base oil and a finished lubricant are also provided. 1. A finished lubricant comprising: a lubricant base oil having a low temperature property determined using a data analytics/machine learning technique on carbon-13 nuclear magnetic resonance (NMR) spectroscopy peak values.2. The finished lubricant of claim 1 , wherein the data analytics/machine learning technique comprises stepwise regression claim 1 , Bayesian regression claim 1 , LASSO/Ridge regression claim 1 , random forest claim 1 , support vector machine claim 1 , or deep learning techniques.3. The finished lubricant of claim 2 , wherein the data analytics/machine learning technique comprises stepwise regression and the spectroscopy peak values used in the stepwise regression are significant at the 90 percent confidence level.4. The finished lubricant of claim 3 , wherein the spectroscopy peak values used in the stepwise regression are significant at the 95 percent confidence level.5. The finished lubricant of claim 4 , wherein the finished lubricant is an industrial oil.6. The finished lubricant of claim 5 , wherein the stepwise regression utilizes at least three spectroscopy peak values.7. The finished lubricant of claim 6 , wherein the stepwise regression equation is a−b*P15+c*P17−d*P18+e*(P2+P4+P10) Подробнее

04-01-2018 дата публикации

Grease wear resistance

Номер: US20180003692A1
Принадлежит: Tannas Company

Grease wear test device includes a body in a form of a collar having an outer surface, a first side and an opposing second side, which are open to form a hollow, open channel through the body, which has a center axis, into which opposing vee blocks can be inserted; and perpendicular to the center axis, a pair of opposing holes through and open to the outer surface of the body and the cylindrical inside wall, through which a cylindrical test journal (falex pin) can be inserted for contact in general with opposing vee-shaped channels of the inserted, opposing vee blocks, and for rotation during testing. The device can be used to modify a falex pin and vee block device, to receive and contain a small sample of grease or another organic paste product for testing such as a modified version of an ASTM D2670 test method for measuring wear properties of fluid lubricants (falex pin and vee block method). 1. A method for evaluating wear resistance and its effects on a grease or another organic paste product , which comprises carrying out the following steps , which are not necessarily conducted in series: a body in a form of a collar having an outer surface, a first side and an opposing second side;', 'the first and second sides being open so as to form a hollow, open channel through the body having a center axis, into which opposing vee blocks can be inserted; and', 'perpendicular to the center axis, a pair of opposing holes through and open to the outer surface of the body and the cylindrical inside wall, through which a cylindrical test journal (falex pin) can be inserted for contact in general with opposing vee-shaped channels of the inserted, opposing vee blocks, and for rotation during testing—, 'providing a modified falex pin and vee block device so as to further include a grease wear test device, the grease wear test device includingwherein the modified falex pin and vee block device can receive and contain a small sample of grease or another organic paste product ...

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12-01-2017 дата публикации

COMPOSITION COMPRISING PARAFFIN FRACTIONS OBTAINED FROM BIOLOGICAL RAW MATERIALS AND METHOD OF PRODUCING SAME

Номер: US20170009144A1
Принадлежит: Neste Oyj

A composition, including 40-50 wt-% C14 paraffins, based on the total weight of the composition, and 35-45 wt-% C15 paraffins, based on the total weight of the composition, wherein the C14 and C15 paraffins are produced from a biological raw material. 119-. (canceled)20. A composition , comprising:40-50 wt-% C14 isoparaffins, based on the total weight of the composition, and35-45 wt-% C15 isoparaffins, based on the total weight of the composition,wherein the C14 and C15 isoparaffins are produced from a biological raw material,wherein the total C14 and C15 isoparaffinic content of the composition is in a range from 80.36 wt-% to 95 wt-%, based on the total weight of the composition.21. The composition according to claim 20 , wherein the composition comprises 45-50 wt-% C14 isoparaffins claim 20 , and 40-45 wt-% C15 isoparaffins claim 20 , based on the total weight of the composition.22. The composition according to claim 20 , wherein the composition comprises less than 9 wt-% C13 and lighter paraffins and less than 7 wt-% C16 and heavier paraffins claim 20 , based on the total weight of the composition.23. The composition according to claim 20 , wherein the composition comprises less than 5 wt-% C13 and lighter paraffins and less than 3 wt-% C16 and heavier paraffins claim 20 , based on the total weight of the composition.24. The composition according to claim 20 , wherein the total isoparaffinic content of the composition is more than 93 wt-% claim 20 , based on the total weight of the composition.25. The composition according to claim 20 , wherein the total isoparaffinic content of the composition is more than 97 wt-% claim 20 , based on the total weight of the composition.26. The composition according to claim 20 , wherein the total aromatic hydrocarbon content of the composition is less than 1500 ppm weight basis.27. The composition according to claim 20 , wherein the total aromatic hydrocarbon content of the composition is less than 1300 ppm weight basis.28. The ...

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12-01-2017 дата публикации

BIO-BASED SYNTHETIC FLUIDS

Номер: US20170009148A1
Принадлежит:

A method is provided involving altering the viscosity of bio-derived paraffins to produce a paraffinic fluid, where the altering step includes chlorinating the bio-derived paraffins; the bio-derived paraffins include a hydrodeoxygenated product produced by hydrodeoxygenating a bio-based feed where the bio-based feed includes bio-derived fatty acids, fatty acid esters, or a combination thereof; the bio-derived paraffins include n-paraffins; and the n-paraffins have a biodegradability of at least 40% after about 23 days of exposure to microorganisms. Also provided are methods of protecting and/or cleaning a substance by applying the paraffinic fluid. 1. A method comprising altering the viscosity of bio-derived paraffins to produce a paraffinic fluid , whereinthe altering step comprises oligomerizing the bio-derived paraffins to produce an oligomerized product, wherein the oligomerized product has a kinematic viscosity of at least about 10 cSt at 40° C.;the paraffinic fluid comprises the oligomerized product;the bio-derived paraffins comprise a hydrodeoxygenated product produced by hydrodeoxygenating a bio-based feed where the bio-based feed comprises bio-derived fatty acids, fatty acid esters, or a combination thereof; and have a kinematic viscosity of less than about 10 cSt at 40° C.; and', 'have a biodegradability of at least about 40% after about 23 days of exposure to microorganisms., 'the bio-derived paraffins comprise n-paraffins where the n-paraffins'}2. The method of claim 1 , wherein the oligomerized product comprises less than about 1 wt % aromatics.3. The method of claim 1 , wherein the oligomerized product comprises less than about 0.1 wt % aromatics.4. The method of claim 1 , wherein the oligomerized product is free of benzene.5. The method of claim 1 , wherein the altering step comprises oligomerizing bio-derived paraffins within the C-Crange.6. The method of claim 1 , wherein oligomerizing bio-derived paraffins comprises contacting the bio-derived ...

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11-01-2018 дата публикации

GREASE, ANTIFRICTION BEARING, ANTIFRICTION BEARING DEVICE, AND INFORMATION RECORDING/REPRODUCING DEVICE

Номер: US20180010642A1
Принадлежит:

The invention has an object of providing grease reduced in an amount of the flying grease and an amount of the outgas, and superior in low-temperature characteristic, an antifriction bearing using the grease, an antifriction bearing device, and an information recording/reproducing device. A grease includes a base oil, and a thickener, the base oil includes mineral oil and poly-α-olefin, the poly-α-olefin is higher in mass than the mineral oil, the poly-α-olefin includes poly-α-olefin higher in kinetic viscosity than the mineral oil, the kinetic viscosity of the base oil at 40° C. is in a range of 40 through 90 mm/s, and worked penetration is in a range of 200 through 250. Further, an antifriction bearing, an antifriction bearing device, and an information recording/reproducing device use the grease. 1. A grease comprising:a base oil; anda thickener,wherein the base oil includes mineral oil and poly-α-olefin,the poly-α-olefin is higher in mass than the mineral oil,the poly-α-olefin includes poly-α-olefin higher in kinetic viscosity than the mineral oil,{'sup': '2', 'the kinetic viscosity of the base oil at 40° C. is in a range of 40 through 90 mm/s, and'}worked penetration is in a range of 200 through 250.2. The grease according to claim 1 , whereina proportion of the mass of the mineral oil to a gross mass of the base oil is in a range of 10 through 40 mass %.3. The grease according to claim 2 , whereinthe mineral oil includes refined oil classified into group III in a base oil category defined by American Petroleum Institute.4. The grease according claim 1 , whereinthe mineral oil includes refined oil classified into group III in a base oil category defined by American Petroleum Institute.5. The grease according to claim 1 , whereinthe poly-α-olefin higher in kinetic viscosity than the mineral oil includes a mixture of a multimeric complex of α-olefin with a carbon number in a range of 0.8 through 12.6. The grease according to claim 1 , whereinthe poly-α-olefin ...

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18-01-2018 дата публикации

LUBRICATING OIL COMPOSITION

Номер: US20180016518A1
Автор: KANEKO Masato
Принадлежит: IDEMITSU KOSAN CO., LTD.

A lubricating oil composition according to one embodiment of the present invention contains an oxygen-containing synthetic base oil having an oxygen content (A) of from 15 to 40 mass % and a kinetic viscosity at 100° C. of from 0.5 to 50 mm/s, and a viscosity index improver that is an oxygen-containing compound having an oxygen content (B) of from 15 to 40 mass % and a kinetic viscosity at 100° C. of 11,000 mm/s or more, a mass ratio of the oxygen-containing synthetic base oil and the viscosity index improver being from 99.5:0.5 to 75:25, and a ratio (A/B) of the oxygen content (A) of the oxygen-containing synthetic base oil to the oxygen content (B) of the viscosity index improver being in a range of from 0.5 to 2. 1. A lubricating oil composition , comprising:{'sup': '2', 'an oxygen-containing synthetic base oil having an oxygen content (A) of from 15 to 40 mass % and a kinetic viscosity at 100° C. of from 0.5 to 50 mm/s; and'}{'sup': '2', 'a viscosity index improver that is an oxygen-containing compound having an oxygen content (B) of from 15 to 40 mass % and a kinetic viscosity at 100° C. of 11,000 mm/s or more,'}wherein:a mass ratio of the oxygen-containing synthetic base oil and the viscosity index improver is from 99.5:0.5 to 75:25; anda ratio (AB) of the oxygen content (A) of the oxygen-containing synthetic base oil to the oxygen content (B) of the viscosity index improver ranges from 0.5 to 2.2. The lubricating oil composition according to claim 1 , wherein the viscosity index improver is at least one oxygen-containing compound selected from the group consisting of a polyvinyl ether compound claim 1 , a polyoxyalkylene glycol compound claim 1 , and a copolymer having a structure of a poly(oxy)alkylene glycol or a monoether thereof and a polyvinyl ether.3. The lubricating oil composition according to claim 2 , wherein the viscosity index improver is a polyoxyalkylene glycol compound.4. The lubricating oil composition according to claim 1 , wherein the oxygen ...

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15-01-2015 дата публикации

Simultaneous Production of Base Oil and Fuel Components from Renewable Feedstock

Номер: US20150018581A1
Принадлежит: NESTE OIL OYJ

The present invention provides a method for simultaneous production of components suitable for production of base oil and fuel components. In the method a feedstock comprising fatty acids and/or fatty acid esters is entered into a reaction zone and subjected to a ketonisation reaction in the presence of a dual catalyst system. This system is configured to perform a ketonisation reaction and a hydrotreatment reaction, under hydrogen pressure. Subsequently ketones are obtained. 1. A method for simultaneous production of components suitable for production of base oil and fuel components , comprising the steps of:a) introducing a feedstock comprising fatty acids and/or fatty acid esters into a reaction zone, andb) subjecting said feedstock to a ketonisation reaction in said reaction zone in the presence of a dual catalyst system configured to perform a ketonisation reaction and a hydrotreatment reaction, under hydrogen pressure, andc) obtaining from said ketonisation reaction ketones in addition to linear hydrocarbons from said fatty acids and/or fatty acid esters.2. The method according to claim 1 , wherein said obtained ketones are further hydrodeoxygenated to form linear hydrocarbons.3. The method according to claim 1 , wherein said fatty acid esters are triglycerides.4. The method according to claim 1 , wherein said feedstock is at least partly claim 1 , preferably completely claim 1 , in liquid form when entered into said reaction zone.5. The method according to claim 1 , wherein the pressure in said reaction zone is less than 10 MPa claim 1 , preferably from 0.1 to 5 MPa.6. The method according to claim 1 , wherein the temperature in said reaction zone is from 200 to 450° C.7. The method according to claim 1 , wherein the ratio of hydrogen to feedstock is from 100 to 600 NI/I claim 1 , preferably from 100 to 500 NI/I.8. A method for simultaneous production of base oil components and fuel components claim 1 , comprising the steps of(i) introducing a feedstock ...

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26-01-2017 дата публикации

Liquid Propylene Oligomers and Methods of Making Same

Номер: US20170022439A1
Принадлежит:

Disclosed herein are oligomerization processes using feedstocks containing propylene to produce an oligomer product, and methods for recovering a propylene oligomer from the oligomer product. The resultant propylene oligomer can be characterized by a Mn in a range from 250 to 10,000 g/mol, a viscosity index of at least 85, and a pour point in a range from −5 to −60° C. 1. A propylene oligomer having:a Mn in a range from 250 to 10,000 g/mol;a viscosity index of at least 85; anda pour point in a range from −5 to −60° C.2. The oligomer of claim 1 , wherein the propylene oligomer has:a Mn in a range from 500 to 5000 g/mol;a viscosity index in a range from 85 to 175; anda pour point in a range from −10 to −35° C.3. The oligomer of claim 1 , wherein the propylene oligomer has:a Mn in a range from 500 to 2500 g/mol;a viscosity index in a range from 88 to 135; anda pour point in a range from −15 to −40° C.4. The oligomer of claim 1 , wherein the propylene oligomer has:a kinematic viscosity at 100° C. in a range from 6 to 200 cSt;a kinematic viscosity at 40° C. in a range from 25 to 8000 cSt; anda flash point in a range from 140 to 300° C.5. The oligomer of claim 1 , wherein the propylene oligomer has:a kinematic viscosity at 100° C. in a range from 12 to 80 cSt;a kinematic viscosity at 40° C. in a range from 200 to 1500 cSt; anda flash point in a range from 160 to 200° C.6. The oligomer of claim 1 , wherein the propylene oligomer comprises at least 98 mol % propylene.7. The oligomer of claim 1 , wherein the propylene oligomer comprises at least 99.5 mol % propylene.8. The oligomer of claim 1 , wherein the propylene oligomer is a liquid at standard temperature and pressure.9. The oligomer of claim 1 , wherein the propylene oligomer is a hydrogenated propylene oligomer.10. A base oil or lubricant composition comprising the propylene oligomer of .11. A propylene oligomer having:a Mn in a range from 250 to 10,000 g/mol;a ratio of Mz/Mw in a range from 1.9 to 8; anda viscosity ...

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25-01-2018 дата публикации

AMORPHOUS HYDROCARBON BASED FILM, AND SLIDING MEMBER AND SLIDING SYSTEM PROVIDED WITH SAID FILM

Номер: US20180023016A1
Принадлежит:

A low-friction coating includes: an aliphatic hydrocarbon group showing a peak in a region of 2,900 cmto 3000 cmin an infrared absorption spectrum; a carbonyl group showing a peak in a region of 1,650 cmto 1,800 cmin an infrared absorption spectrum; an aromatic component (CH) showing a peak at mass 91.1 in a positive ion spectrum obtained by TOF-SIMS; and a condensed ring based component (CH) showing a peak at mass 115.2 in the positive ion spectrum obtained by TOF-SIMS. 1. An amorphous hydrocarbon based film comprising:{'sup': −1', '−1, 'an aliphatic hydrocarbon group showing a peak in a region of from 2,900 cmto 3,000 cmin an infrared absorption spectrum; and'}at least one of an aromatic component showing a peak at a mass of 91.1 in a positive ion spectrum obtained by time-of-flight secondary ion mass spectrometry and a condensed ring based component showing a peak at a mass of 115.2 in the positive ion spectrum obtained by the time-of-flight secondary ion mass spectrometry.2. The amorphous hydrocarbon based film according to claim 1 , further comprising:{'sup': −1', '−1, 'a carbonyl group showing a peak in a region of from 1,650 cmto 1,800 cmin an infrared absorption spectrum.'}3. The amorphous hydrocarbon based film according to claim 1 , comprising both the aromatic component and the condensed ring based component.4. The amorphous hydrocarbon based film according to claim 1 ,wherein an average thickness is 2 nm to 1,000 nm.5. A sliding member comprising:a sliding surface comprising a first coating,wherein the sliding member is formed of at least one of metal and ceramics, and{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'wherein the first coating comprises the amorphous hydrocarbon based film according to .'}6. The sliding member according to claim 5 ,{'sub': '2', 'wherein the sliding member is formed of ZrO.'}7. A sliding system comprising:{'claim-ref': {'@idref': 'CLM-00005', 'claim 5'}, 'the sliding member according to ; and'}a slid member comprising a ...

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25-01-2018 дата публикации

Shear-Stable Oil Compositions and Processes for Making the Same

Номер: US20180023017A1
Принадлежит:

An oil composition comprising a first component having pendant groups and a second component but free of a third component and process for making such oil composition, where a single molecule of the third component can form large shearable stable complex structure with two molecules of the first component via van der Waals force between pendant groups and the terminal carbon chains, and a single molecule of the second component is capable of adjoining no more than one molecule of the first type. The oil composition has high shear stability making it suitable for use in lubricants subject to repeated high shear stress events. 1. An oil composition comprising a first component and a second component differing from the first component and free of a third component , wherein:the first component is a base stock comprising multiple molecules of a first type each having multiple pendant groups, where (i) the average pendant group length of the longest 5%, by mole, of the pendant groups of all of the molecules of the first type have an average pendant group length of Lpg(5%), where Lpg(5%)≧5.0; and (ii) a portion of the molecules of the first type have molecular weight greater than or equal to 20,000;the second component comprises multiple molecules of a second type each of which individually is capable of adjoining no more than one molecule of the first type via van der Waals force between straight carbon chains to form a stable first complex structure; andthe third component comprises molecules of a third type each comprising two terminal carbon chains, where (i) the number average molecular weight of the third component is no greater than 2,000; and (ii) the two terminal carbon chains have chain lengths equal to or greater than 5.0 and do not share a common carbon atom.2. The oil composition of claim 1 , wherein:the molecules of the second type comprise one or zero terminal carbon chain that has a chain length equal to or greater than 5.0.3. The oil composition of claim ...

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25-01-2018 дата публикации

Use of a Boron-Containing Additive as an Inhibitor of Lead Corrosion

Номер: US20180023019A1
Принадлежит:

This invention relates to the use of a boron-containing additive in a non-aqueous lubricant composition as an inhibit or of lead corrosion associated with ashless, organic ester, anti-wear additives and/or friction modifiers. 114-. (canceled)15. A method of improving anti-corrosion properties of a non-aqueous lubricant composition comprising admixing the non-aqueous lubricant composition with a boron-containing additive.16. The method of claim 15 , wherein the non-aqueous lubricant composition is used to lubricate an internal combustion engine.17. The method of claim 15 , wherein the non-aqueous lubricant composition comprises an ashless claim 15 , organic ester claim 15 , anti-wear additive and/or friction modifier.18. The method of claim 16 , wherein an ashless claim 16 , organic ester claim 16 , anti-wear additive and/or friction modifier is provided in a liquid fuel composition used to operate the internal combustion engine claim 16 , and a portion of said ashless claim 16 , organic ester claim 16 , anti-wear and/or friction modifier ingresses into the non-aqueous lubricant composition during operation of said engine.19. The method of claim 15 , wherein the boron-containing additive is a borated dispersant.20. The method of claim 19 , wherein the borated dispersant is a borated ester.21. The method of claim 20 , wherein the borated ester is a borated succinate ester or a borated succinate ester amide.22. The method of wherein the ashless claim 15 , organic ester claim 15 , anti-wear additive and/or friction modifier isi) at least one fatty acid ester of a polyol,ii) at least one oil-soluble mono, di-, or tri-glyceride of at least one hydroxy polycarboxylic acid, or a derivative thereof;iii) at least one long chain fatty acid ester of a hydroxy carboxylic acid in which the long chain fatty acid has at least 4 carbon atoms and the ester is an oil-soluble ester of a mono- or poly-hydroxy carboxylic acid containing 1 to 4 groups which are independently carboxylic ...

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25-01-2018 дата публикации

NOVEL ORGANIC FRICTION MODIFIERS

Номер: US20180023020A1
Автор: Zhao Haibo
Принадлежит:

The present disclosure relates to novel organic friction modifiers for use in non-aqueous lubricant compositions, the organic friction modifiers comprising a product formed from the reaction of polyisobutylene succinic anhydride and a hydrophilic polyetheramine. 1. An organic friction modifier comprising a product formed from the reaction of polyisobutylene succinic anhydride and a hydrophilic polyetheramine.2. The organic friction modifier of claim 1 , wherein the hydrophilic polyetheramine is a polyether monoamine.4. The organic friction modifier of claim 1 , wherein the hydrophilic polyetheramine is a polyether diamine.6. The organic friction modifier of claim 1 , wherein the hydrophilic polyetheramine is a polyether triamine.9. The organic friction modifier of claim 1 , wherein the hydrophilic polyetheramine is a polyether tetraamine or a multi-functional polyetheramine.10. A non-aqueous lubricant composition comprising a base oil and the organic friction modifier of .11. The non-aqueous lubricant composition of claim 10 , wherein the base oil is a synthetic oil.12. The non-aqueous lubricant composition of claim 10 , wherein the base oil is a mineral oil.13. A non-aqueous lubricant composition comprising:A) from 70 wt. % to 99.9 wt. % of a base oil, based on the total weight of the non-aqueous lubricant composition;{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'B) the organic friction modifier of ; and'}C) one or more additional additives.wherein the combined amount of B) and C) present in the non-aqueous lubricant composition is from 0.1 to 30 weight percent based on the total weight of the non-aqueous lubricant composition.14. An additive package comprising the organic friction modifier of and one or more additives selected from anti-oxidants claim 1 , anti-wear additives claim 1 , detergents claim 1 , dispersants claim 1 , other friction modifiers claim 1 , viscosity index improvers claim 1 , pour point depressants claim 1 , corrosion inhibitors claim 1 , ...

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25-01-2018 дата публикации

HEAT TREATMENT OIL COMPOSITION

Номер: US20180023022A1
Принадлежит: IDEMITSU KOSAN CO., LTD.

A heat treatment oil composition is provided that suppresses the decrease of luster in a heat treatment of a metal material, and is capable of suppressing the increase of the number of second (characteristic number of second) until reaching the temperature where the vapor blanket stage ends with the lapse of time and the decrease of the kinetic viscosity with the lapse of time. The heat treatment oil composition contains (A) a base oil and (B) a vapor blanket breaking agent selected from one or more of a petroleum resin, a terpene resin, rosin, and derivatives thereof. 1. A heat treatment oil composition , comprising(A) a base oil, and(B) at least one vapor blanket breaking agent selected from the group consisting of a petroleum resin, a terpene resin, a rosin, and derivatives thereof.2. The heat treatment oil composition according to claim 1 , wherein the vapor blanket breaking agent as the component (B) has a softening point measured by the ring and ball method of JIS K2207:2006 of 40° C. or more.3. The heat treatment oil composition according to claim 2 , wherein the vapor blanket breaking agent as the component (B) has a softening point measured by the ring and ball method of JIS K2207:2006 of 60° C. or more and 150° C. or less.4. The heat treatment oil composition according to claim 1 , wherein the base oil as the component (A) has a 40° C. kinetic viscosity of from 5 to 500 mm/s.5. The heat treatment oil composition according to claim 1 , comprising:80% by mass or more and less than 100% by mass of the base oil, andmore than 0% by mass and 20% by mass or less of the vapor blanket breaking agent,based on a total mass the total amount of the heat treatment oil composition.6. The heat treatment oil composition according to claim 1 , wherein the heat treatment oil composition has a characteristic number of second obtained from a cooling curve obtained according to the cooling capability test method of JIS K2242:2012 of 3.00 seconds or less. The present invention ...

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25-01-2018 дата публикации

Lubricating Grease Composition

Номер: US20180023023A1
Автор: Fish Gareth
Принадлежит:

The invention provides a lubricating grease composition comprising an oil of lubricating viscosity, a metallic soap thickener and a boron-containing compound, wherein the boron containing compound comprises a borate ester comprising at least one alkyl group having a branch at the β position or higher. The invention further relates to a method of lubricating a mechanical device with the lubricant composition. 1. A lubricating grease composition comprising:(a) an oil of lubricating viscosity, and(b) a metallic soap thickener(c) a borate ester comprising at least one alkyl group having 10 to about 32 carbon atoms, said alkyl group having a branch at the β or higher position.2. The lubricating grease composition of wherein the borate ester comprises multiple alkyl groups each independently having 10 to about 32 carbon atoms claim 1 , said alkyl groups having a branch at the β or higher position.3. The lubricating grease composition of wherein the alkyl group is branched at the β position.4. The lubricating grease composition of wherein the alkyl group has a structure represented by —CH—C(R)(R)H claim 1 , where Ris an alkyl group of 7 to about 18 carbon atoms and Ris an alkyl group having fewer carbon atoms than R.5. The lubricating grease composition of wherein the alkyl group has a structure represented by —CH—C(R)(R)H claim 1 , where Ris an alkyl group of 7 to about 18 carbon atoms and Ris an alkyl group having 4 fewer carbon atoms than R.6. The lubricating grease composition of wherein the alkyl group is a 2-propylheptyl group claim 1 , a 2-butyloctyl group claim 1 , a 2-hexyldecyl group claim 1 , or a 2-octyldodecyl group.7. The lubricating grease composition of wherein the alkyl group is derived from a Guerbet alcohol.9. The lubricating grease composition of wherein the borate ester comprises a trialkylborate.11. The lubricating grease of wherein the metallic soap is reaction of an alkali or alkaline earth metal with a fatty acid.12. The lubricating grease ...

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25-01-2018 дата публикации

Lubricating oil composition for internal combustion engine

Номер: US20180023026A1
Автор: Shintaro KUSUHARA
Принадлежит: JXTG Nippon Oil and Energy Corp

Provided is a lubricating oil composition for internal combustion engine, which further reduces the friction to exhibit excellent fuel efficiency performance. A lubricating oil composition for internal combustion engine, which contains (A) a lubricant base oil having a dynamic viscosity of 2.0 to mm 2 /s at 100° C., (B) a molybdenum-based friction modifier in an amount of 0.005 to 0.2% by mass, in terms of a molybdenum content, based on the mass of the composition, (C) a salicylate-based metal detergent in an amount of 0.01 to 1% by mass, in terms of a metal content, based on the mass of the composition, and (D) at least one compound selected from amino acids having an alkyl group, alkenyl group, or acyl group having 15 to 24 carbon atoms and/or derivatives thereof in an amount of 0.01 to 10% by mass.

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25-01-2018 дата публикации

Compositions of thermoassociative additives with controlled association and lubricant compositions containing them

Номер: US20180023028A1

The present disclosure relates to novel compositions of additives that result from mixing at least two thermoassociative and exchangeable copolymers and at least one compound for controlling the association of these two copolymers. A lubricant composition results from mixing at least one lubricating base oil, at least two thermoassociative and exchangeable copolymers and at least one compound for controlling the association of these two copolymers. The present disclosure also relates to a process for modulating the viscosity of a lubricant composition that results from mixing at least one lubricating base oil, at least two thermoassociative and exchangeable copolymers; as well as the use of a diol compound for modulating the viscosity of a lubricant composition.

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24-01-2019 дата публикации

Lubricant composition promoting sustained fuel economy

Номер: US20190024015A1
Принадлежит: ExxonMobil Research and Engineering Co

A lubricant composition includes a controlled release friction modifier (CRFM), a highly paraffinic base stock, a dispersant and a detergent. The CRFM includes an ionic tetrahedral borate compound including a cation and a tetrahedral borate anion, wherein the tetrahedral borate anion comprises a boron atom having two bidentate di-oxo ligands of C18 tartrimide. The lubricant composition can also include at least one of a Group V co-base stock, an inorganic friction modifier, a viscosity modifier, and a cleanliness booster.

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23-01-2020 дата публикации

LUBRICATING OIL COMPOSITIONS WITH OXIDATIVE STABILITY IN DIESEL ENGINES USING BIODIESEL FUEL

Номер: US20200024538A1
Принадлежит:

A method for improving oxidative stability of a lubricating oil in a diesel engine, in which biodiesel fuel is used with diesel fuel in the diesel engine, by using as the lubricating oil a formulated oil. The formulated oil has a composition including at least one Group V lubricating oil base stock. The at least one Group V lubricating oil base stock is present in an amount from 1 to 75 weight percent, based on the total weight of the lubricating oil. Oxidative stability is improved in a diesel engine lubricated with the lubricating oil, as compared to oxidative stability achieved in a diesel engine lubricated with a lubricating oil not having the at least one Group V lubricating oil base stock, as determined by a CEC L-109-16 Bio-Diesel Oxidation Bench test. The lubricating oils are useful as passenger vehicle engine oil (PVEO) products or commercial vehicle engine oil (CVEO) products. 1. A method for improving oxidative stability of a lubricating oil in a diesel engine , wherein biodiesel fuel is used with diesel fuel in the diesel engine , by using as the lubricating oil a formulated oil , said formulated oil having a composition comprising at least one Group V lubricating oil base stock; wherein the at least one Group V lubricating oil base stock is present in an amount from 1 to 75 weight percent , based on the total weight of the lubricating oil; and wherein oxidative stability is improved in a diesel engine lubricated with the lubricating oil , as compared to oxidative stability achieved in a diesel engine lubricated with a lubricating oil not having the at least one Group V lubricating oil base stock , as determined by a CEC L-109-16 Bio-Diesel Oxidation Bench test.2. The method of wherein claim 1 , in a CEC L-109-16 Bio-Diesel Oxidation Bench test claim 1 , the time for a relative kinematic viscosity at 100° C. (KV100) increase of 100% of said lubricating oil claim 1 , is greater than the time for a relative kinematic viscosity at 100° C. (KV100) increase ...

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28-01-2021 дата публикации

Bio-based synthetic fluids

Номер: US20210024835A1
Принадлежит: Reg Synthetic Fuels Llc

A method is provided involving altering the viscosity of bio-derived paraffins to produce a paraffinic fluid, where the altering step includes chlorinating the bio-derived paraffins; the bio-derived paraffins include a hydrodeoxygenated product produced by hydrodeoxygenating a bio-based feed where the bio-based feed includes bio-derived fatty acids, fatty acid esters, or a combination thereof; the bio-derived paraffins include n-paraffins; and the n-paraffins have a biodegradability of at least 40% after about 23 days of exposure to microorganisms. Also provided are methods of protecting and/or cleaning a substance by applying the paraffinic fluid.

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02-02-2017 дата публикации

Lubricant for preventing and removing carbon deposits in internal combustion engines

Номер: US20170029734A1

A lubricant formulation which is effective to remove or prevent carbon deposits in internal combustion engines has a solvency as defined by aniline point from about 20 to about 115, a volatility (as measured by NOACK) of less than 15%, an oxidative stability (as measured by PDSC) of above 40 minutes and a base oil viscosity of above 2 and below 10 cSt. The lubricant formulation can be formed from a blend of Group III, IV and V lubricants, in particularly polyalphaolefins, alkylated naphthalenes and polar Group V base stocks such as polyol esters. The carbon deposits can be removed from the engine piston by simply running the engine with the lubricant for one required cycle, or can be used continuously in the engine to prevent buildup.

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01-02-2018 дата публикации

GREASE COMPOSITION

Номер: US20180030367A1
Принадлежит:

A grease composition comprises a base oil and an aluminium complex soap thickener, with graphite, molybdenum di-sulphide, calcium carbonate and bismuth sulphide all included as additives. The composition exhibits advantageous load, wear and friction performance, especially in extreme pressure environments, and is particularly suitable for use on open gears. 1. A grease composition comprising a base oil and an aluminium complex soap as a thickening agent , wherein the composition further includes as additives (i) graphite , (ii) molybdenum disulphide , (iii) calcium carbonate and (iv) bismuth sulphide.2. The grease composition according to claim 1 , comprising graphite in an amount of from 1 to 15 wt. based upon the total weight of the grease composition.3. The grease composition according to claim 1 , comprising molybdenum disulphide in an amount of from 1 to 15 wt. % claim 1 , based upon the total weight of the grease composition.4. The grease composition according to claim 1 , comprising calcium carbonate in an amount of from 1 to 15 wt. % claim 1 , based upon the total weight of the grease composition.5. The grease composition claim 1 , comprising bismuth sulphide in an amount of from 0.1 to 15 wt. % claim 1 , based upon the total weight of the grease composition.6. The grease composition according to claim 1 , wherein bismuth sulphide has a particle size at least about 50% greater than the particle sizes of graphite claim 1 , calcium carbonate and molybdenum disulphide.7. The grease composition according to claim 1 , wherein bismuth sulphide has a particle size D50 of 10 μm or greater and D90 of 40 μm or greater.8. The grease composition according to claim 1 , wherein the base oil comprises a blend of a polybutene claim 1 , a paraffinic base oil and a naphthenic base oil.9. The grease composition according to claim 1 , comprising aluminium complex soap thickener in an amount of from 0.5 wt. % to 15 wt. % claim 1 , based upon the total weight of the grease ...

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01-02-2018 дата публикации

AROMATIC TETRAHEDRAL BORATE COMPOUNDS FOR LUBRICATING COMPOSITIONS

Номер: US20180030369A1
Принадлежит: THE LUBRIZOL CORPORATION

A lubricating composition includes an oil of lubricating viscosity and an ionic tetrahedral borate compound which includes a cation and a tetrahedral borate anion which includes a boron atom, the boron atom having at least one aromatic bidentate di-oxo ligand. The compound may be represented by formula (I), where Rand Rare selected from Chydrocarbyl groups or together form a substituted or unsubstituted 5- or 6-membered ring; Rand Rtogether represent a substituted or unsubstituted aromatic ring; m is 0 or 1; X is hydrogen, a Chydrocarbyl group, —OR, —NHR, or=O, Ris a Chydrocarbyl group; M represents the cation; and n is at least 1. The cation may be selected to provide detergent and/or dispersant properties to the lubricating composition. In the case of ammonium cations, the molecular weight may be 260 g/mol or higher for providing a highly soluble compound, particularly when X is=O. 1. A lubricating composition comprising:an oil of lubricating viscosity; andan ionic tetrahedral borate compound comprising a cation and a tetrahedral borate anion which comprises a boron atom, the boron atom having at least one aromatic bidentate di-oxo ligand, andwherein when the cation is an ammonium cation, the ammonium cation has a molecular weight of at least 260 g/mol.3. The lubricating composition of claim 2 , wherein the substituted 5-membered or 6-membered ring is substituted with at least one substituent selected from aliphatic hydrocarbyl groups claim 2 , aromatic hydrocarbyl groups claim 2 , aliphatic hydrocarbyl groups comprising at least one heteroatom claim 2 , aromatic hydrocarbyl groups comprising at least one heteroatom claim 2 , and combinations thereof.4. (canceled)6. (canceled)7. (canceled)8. (canceled)10. The lubricating composition of claim 9 , wherein when X is =O and wherein the cation in the compound is an ammonium cation with a molecular weight of at least 300 g/mol.11. (canceled)12. The lubricating composition of claim 2 , wherein Rand Rtogether form a ...

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01-02-2018 дата публикации

Enhanced extreme pressure lubricant formulations

Номер: US20180030370A1
Принадлежит: Dow Global Technologies LLC

A lubricant formulation contains: (a) at least 50 weight-percent hydrocarbon base oil; (b) five to 50 weight-percent of an oil soluble polyalkylene glycol selected from monol, diol and triol initiated 1,2-butylene oxide homopolymer and monol initiated copolymers of 1,2-butylene oxide and propylene oxide; and (c) 0.1 to five weight-percent or less of a sulfurized olefin; where weight-percent is based on total lubricant formulation weight.

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31-01-2019 дата публикации

LUBRICATING OIL COMPOSITION

Номер: US20190031973A1
Принадлежит:

Provided is a lubricating oil composition, which has low viscosity but also prolonged anti-shudder life without reduction of intermetallic friction coefficient. The lubricating oil composition is characterized in comprising (A) a lubricating base oil, and (C) (C-1) a borated succinimide compound with a mass average molecular weight of 4,000-7,000 and (C-2) a borated succinimide compound with a mass average molecular weight of greater than 7,000-10,000. 1. A lubricating oil composition , comprising:(A) a lubricating base oil; and '(C-2) a boronated succinimide compound having a weight-average molecular weight of more than 7,000 and not more than 10,000.', '(C) (C-1) a boronated succinimide compound having a weight-average molecular weight of 4,000 to 7,000 and'}2. The lubricating oil composition according to claim 1 , wherein part or all of component (A) comprises a poly(α-olefin) or α-olefin copolymer having a kinematic viscosity at 100° C. of 6 to 80 mm/s in an amount of 5 to 30% by weight based on a total weight of the lubricating oil composition; andwherein the lubricating oil composition further comprises (B) a polymethacrylate having a weight-average molecular weight of 15,000 to 40,000.3. The lubricating oil composition according to claim 1 , wherein each of component (C-1) and component (C-2) contains 0.1 to 3% by weight of boron based on a weight of component (C-1) or component (C-2).4. The lubricating oil composition according to claim 1 , wherein a weight ratio of component (C-2) to component (C-1) claim 1 , i.e. claim 1 , (C-2)/(C-1) is 1 to 10.5. The lubricating oil composition according to claim 1 , wherein the lubricating oil composition has a kinematic viscosity at 100° C. of 3 to 10 mm /s.6. The lubricating oil composition according to claim 1 , wherein the lubricating oil composition has a viscosity index of 150 or more.7. The lubricating oil composition according to claim 1 , further comprising (D) a metal detergent.8. The lubricating oil ...

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31-01-2019 дата публикации

Fluids for Extreme Pressure and Wear Applications

Номер: US20190031974A1
Автор: Ricks William F.
Принадлежит:

Provided are compositions, additives for forming compositions, methods of operating apparatus in fluid communication with the compositions, and apparatus comprising the compositions. For example, the composition may include a polyalphaolefin component of from about 95% to about 99.5% w/w. The composition may include an additive component. The additive component may include an anti-wear agent. The anti-wear agent may be from about 0.1% to about 2% w/w. The anti-wear component may be characterized by an acid value of at least about 1 mg KOH/g. The additive component may include an aryl amine antioxidant agent, an anti-rust agent, and a metal deactivator agent. The composition may be characterized by a kinematic viscosity at 100° C. of at least about 5 centiStokes, a viscosity index of at least about 80, and an acid value in mg KOH/g of between about 0.1 and about 1. 1. A composition , comprising:a polyalphaolefin component in a percentage, w/w of the composition, of from about 95% to about 99.5%; and an anti-wear agent in a percentage, w/w of the composition, of from about 0.1% to about 2%, the anti-wear component characterized by an acid value of at least about 1 mg KOH/g;', 'an aryl amine antioxidant agent;', 'an anti-rust agent; and', 'a metal deactivator agent;, 'an additive component, comprising a kinematic viscosity at 100° C. of at least about 5 centiStokes;', 'a viscosity index of at least about 80; and', 'an acid value in mg KOH/g of between about 0.1 and about 1., 'the composition being characterized by2. The composition of claim 1 , comprising the additive component claim 1 , in a percentage claim 1 , w/w of the composition claim 1 , of from about 0.5% to about 5%.3. The composition of claim 1 , the anti-wear agent comprising a partly esterified phosphate ester.4. The composition of claim 1 , the anti-wear agent comprising one or more of: a C-Calkylated triarylphosphate claim 1 , a C-Calkyl phosphate claim 1 , a diarylether phosphate ester and a diarylether ...

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04-02-2021 дата публикации

METHOD FOR PRODUCING WAX ISOMERIZED OIL

Номер: US20210032550A1
Принадлежит: ENEOS CORPORATION

A method for producing a wax isomerized oil, comprising a step of providing an ethylene polymer wax, a step of hydrocracking the ethylene polymer wax by a hydrocracking catalyst to obtain a cracked product, and a step of isomerization dewaxing the cracked product by a hydroisomerization catalyst to obtain a wax isomerized oil. 1a step of providing an ethylene polymer wax,a step of hydrocracking the ethylene polymer wax by a hydrocracking catalyst to obtain a cracked product, anda step of isomerization dewaxing the cracked product by a hydroisomerization catalyst to obtain a wax isomerized oil.. A method for producing a wax isomerized oil, comprising The present invention relates to a method for producing a wax isomerized oil.Conventionally, there has been wax isomerized oil in addition to mineral base oil, as lubricating base oil. As the examples of wax for a raw material of wax isomerized oil, natural wax such as petroleum slack wax obtained by solvent dewaxing of hydrocarbon oil, or synthetic wax such as one produced by Fischer Tropsch synthesis by use of synthetic gas (FT wax), are included. There is known, as a method for producing a high-quality lubricating base oil, for example, a method involving performing hydrotreatment and dewaxing treatment of a raw material oil derived from the above-described wax or the like (see, for example, Patent Literature 1).[Patent Literature 1] Japanese Unexamined Patent Publication No. 2007-510798While a lubricating base oil prepared using conventional raw material wax or the like can satisfy requirements such as an improvement in fuel economy and a reduction in amount of discharge to some extent, as described above, it has been found by studies of the present inventor that even the lubricating base oil still has room for improvement in terms of a reduction in traction coefficient.An object of the present invention is then to provide a method for producing a wax isomerized oil having low in traction coefficient.The present ...

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08-02-2018 дата публикации

Refrigerator oil and working fluid composition for refrigerators

Номер: US20180037836A1
Принадлежит: JXTG Nippon Oil and Energy Corp

The invention provides a refrigerating machine oil comprising as a base oil at least one oxygen-containing oil having a carbon/oxygen molar ratio of 2.5 or more and 5.8 or less, and being used in combination with a (Z)-1,1,1,4,4,4-hexafluoro-2-butene refrigerant.

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08-02-2018 дата публикации

THERMOCLEAVABLE FRICTION MODIFIERS AND METHODS THEREOF

Номер: US20180037840A1
Принадлежит:

Certain embodiments of the invention provide a lubricating oil composition comprising a lubricating oil base stock and a compound of formula (I): 2. The lubricating oil composition of claim 1 , wherein Rand Rare each H or wherein Rand Rare each tert-butyl.37-. (canceled)8. The lubricating oil composition of claim 1 , wherein Ris OR claim 1 , wherein Ris (C-C)alkyl claim 1 , (C-C)alkanoyl claim 1 , (C-C)alkenyl or (C-C)alkenoyl.9. The lubricating oil composition of claim 1 , wherein Ris OR claim 1 , wherein Ris (C-C)alkyl.1012-. (canceled)13. The lubricating oil composition of claim 1 , wherein Ris OR claim 1 , wherein Ris (C-C)alkanoyl.1424-. (canceled)25. The lubricating oil composition of claim 1 , wherein Ris (C-C)alkyl.2628-. (canceled)29. The lubricating oil composition of claim 1 , wherein Ris (C-C)alkanoyl.3040-. (canceled)44. The lubricating oil composition of claim 1 , wherein the lubricating oil base stock comprises a Group I claim 1 , Group II claim 1 , Group III claim 1 , Group IV or Group V base oil.45. The lubricating oil composition of claim 1 , comprising a mixture of two or more compounds of formula (I) claim 1 , or salts thereof claim 1 , wherein the two or more compounds of formula (I) claim 1 , or salts thereof claim 1 , have different thermal release temperatures.4648-. (canceled)49. The lubricating oil composition of claim 1 , further comprising one or more lubricating oil performance additives selected from the group consisting of an anti-wear additive claim 1 , viscosity modifier claim 1 , antioxidant claim 1 , detergent claim 1 , dispersant claim 1 , pour point depressant claim 1 , corrosion inhibitor claim 1 , metal deactivator claim 1 , seal compatibility additive claim 1 , anti-foam agent claim 1 , other friction modifier and anti-rust additive/inhibitor.50. (canceled)52. (canceled)5564-. (canceled)6673-. (canceled)75105-. (canceled)106. A method of reducing friction in an engine or other mechanical component lubricated with a lubricating ...

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06-02-2020 дата публикации

COMPOSITION FOR HEAT CYCLE SYSTEM, AND HEAT CYCLE SYSTEM

Номер: US20200040242A1
Принадлежит: AGC Inc.

To provide a composition for a heat cycle system, which comprises a working fluid for heat cycle which has a low global warming potential and high stability, and which can replace R410A, and a heat cycle system employing the composition. A composition for a heat cycle system, which comprises a working fluid for heat cycle containing trifluoroethylene, and a stabilizer for preventing deterioration of the working fluid for heat cycle, such as an oxidation resistance-improving agent, a heat resistance-improving agent or a metal deactivator, and a heat cycle system employing the composition for a heat cycle system. 1. A composition for a heat cycle system , comprising:a working fluid for heat cycle comprising trifluoroethylene and a hydrofluoroolefin other than trifluoroethylene; anda stabilizer for preventing deterioration of the working fluid for heat cycle.2. The composition for a heat cycle system according to claim 1 , wherein the stabilizer is at least one stabilizer selected from an oxidation resistance-improving agent claim 1 , a heat resistance-improving agent and a metal deactivator.3. The composition for a heat cycle system according to claim 2 , wherein the stabilizer is at least one compound selected from the group consisting of a phenol compound claim 2 , an unsaturated hydrocarbon group-containing aromatic compound claim 2 , an aromatic amine compound claim 2 , an aromatic thiazine compound claim 2 , a terpene compound claim 2 , a quinone compound claim 2 , a nitro compound claim 2 , an epoxy compound claim 2 , a lactone compound claim 2 , an orthoester compound claim 2 , a mono- or di-alkali metal salt compound of phthalic acid claim 2 , and a thiodiphenyl ether hydroxide compound.4. The composition for a heat cycle system according to claim 1 , wherein a content of the stabilizer in the composition is at least 1 mass ppm.5. The composition for a heat cycle system according to claim 1 , further comprising a refrigerant oil.6. The composition for a heat ...

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18-02-2021 дата публикации

METHOD FOR IMPROVING ENGINE PERFORMANCE WITH RENEWABLE LUBRICANT COMPOSITIONS

Номер: US20210047577A1
Принадлежит:

Provided herein are lubricant compositions comprising renewable base oils as embodied by hydrocarbon mixtures with controlled structure characteristics in combination with lubricant additives that address performance requirements and stricter environmental and fuel economy regulations. The lubricant composition provides performance in the cold crank simulated viscosity (CCS) vs Noack volatility relationship, which allows for the formulation of lower viscosity engine oils with improved fuel economy, improved fuel economy retention, and retained LSPI prevention additionally conferring improved characteristics to other devices or apparatus requiring lubrication. 1. A method of improving fuel economy comprising lubricating an internal combustion engine with a lubricant that comprises: i. the percentage of molecules with even carbon number is ≥80% according to FIMS;', 'ii. the BP/BI≥−0.6037 (Internal alkyl branching per molecule)+2.0;', 'iii. on average there are 0.3 to 1.5 5+ methyl per molecule;, 'a. (a) a mixture of base oil having at least 25 wt. % renewable base oil comprising a hydrocarbon mixture in which i. dispersants', 'ii. detergents', 'iii. Inhibitors', 'iv. Friction Modifiers', 'v. Pour Point Depressants', 'vi. Viscosity Modifiers, 'b. at least one of the following additives'}2. The method of claim 1 , wherein the lubricating oil composition comprises from about 5 wt. % to about 30 wt. % total additive concentration and from about 70 to about 95 wt. % of the base oil mixture.3. The method of claim 1 , wherein the composition has a lubricating high temperature high shear viscosity less than 2.3 cP claim 1 , based on ASTM D5481.4. The method of claim 1 , wherein the composition has a lubricating kinematic viscosity at 100° C. less than or equal to 7.1 cSt claim 1 , based on ASTM D445.5. The method of claim 1 , wherein the composition has a lubricating low temperature cold cranking viscosity at −35° C. less than or equal to 6200 mPa·s claim 1 , based on ASTM ...

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16-02-2017 дата публикации

REFRIGERATING-MACHINE OIL AND WORKING-FLUID COMPOSITION FOR REFRIGERATING MACHINE

Номер: US20170044462A1
Принадлежит: JX NIPPON OIL & ENERGY CORPORATION

The invention provides a refrigerating machine oil comprising a hydrocarbon-based base oil, the refrigerating machine oil having a viscosity index of 120 or less, and being used with a 1-chloro-3,3,3-trifluoropropene refrigerant. 1. A refrigerating machine oil comprising a hydrocarbon-based base oil ,the refrigerating machine oil having a viscosity index of 120 or less, and being utilized with a 1-chloro-3,3,3-trifluoropropene refrigerant.2. The refrigerating machine oil according to claim 1 , wherein the hydrocarbon-based base oil has a viscosity index of 120 or less.3. The refrigerating machine oil according to claim 1 , wherein the hydrocarbon-based base oil has a % Cof 10 or more and 75 or less.4. The refrigerating machine oil according to claim 1 , wherein the 1-chloro-3 claim 1 ,3 claim 1 ,3-trifluoropropene refrigerant is a trans-1-chloro-3 claim 1 ,3 claim 1 ,3-trifluoropropene refrigerant.5. A working fluid composition for a refrigerating machine claim 1 , comprising:a refrigerating machine oil comprising a hydrocarbon-based base oil, the refrigerating machine oil having a viscosity index of 120 or less, anda 1-chloro-3,3,3-trifluoropropene refrigerant.6. The working fluid composition for a refrigerating machine according to claim 5 , wherein the hydrocarbon-based base oil has a viscosity index of 120 or less.7. The working fluid composition for a refrigerating machine according to claim 5 , wherein the hydrocarbon-based base oil has a % Cof 10 or more and 75 or less.8. The working fluid composition for a refrigerating machine according to claim 5 , wherein the 1-chloro-3 claim 5 ,3 claim 5 ,3-trifluoropropene refrigerant is a trans-1-chloro-3 claim 5 ,3 claim 5 ,3-trifluoropropene refrigerant.9. (canceled)10. (canceled) The present invention relates to a refrigerating machine oil, and a working fluid composition for a refrigerating machine; use of a composition containing a hydrocarbon-based base oil for a refrigerating machine oil or a working fluid ...

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25-02-2016 дата публикации

OLIGOMERISATION PROCESS

Номер: US20160052838A1
Принадлежит: The Queen's University of Belfast

This invention relates to base oils for lubricating compositions. In particular, the present invention provides a process for the selective oligomerisation of C5 to C20 alpha-olefins to produce polyalphaolefin oligomers with a molecular weight distribution that is suitable for use in lubricant base oils. 2. A process according to claim 1 , wherein M represents aluminium.3. A process according to claim 2 , wherein the molar ratio of the at least one metal halide salt to the at least one Lewis basic donor ligand is in the range of from 1:1 to 2:1.4. A process according to claim 3 , wherein the molar ratio of the metal halide salt to the at least one Lewis basic donor ligand is from about 55:45 to about 65:35.5. A process according to claim 4 , wherein the molar ratio of the metal halide salt to the at least one Lewis basic donor ligand is about 3:2.6. A process according to any one of the preceding claims claim 4 , wherein X represents bromine or chlorine claim 4 , preferably chlorine.7. A process according to claim 6 , wherein MXrepresents AlCl.8. A process according to any one of the preceding claims claim 6 , wherein the at least one Lewis basic donor ligand is selected from ligands containing a donor atom selected from oxygen claim 6 , sulphur claim 6 , nitrogen and phosphorus.9. A process according to claim 8 , wherein the at least one Lewis basic donor ligand is selected from the group of compounds consisting of ketones claim 8 , sulfoxides claim 8 , phosphine-oxides claim 8 , ureas claim 8 , esters claim 8 , amides claim 8 , ethers claim 8 , thioketones claim 8 , thioureas claim 8 , thioamides claim 8 , thioethers claim 8 , amines claim 8 , nitriles and phosphines.10. A process according to claim 9 , wherein the at least one Lewis basic donor ligand is selected from amides and ureas.11. A process according to claim 9 , wherein the at least one Lewis basic donor ligand is selected from compounds having a formula selected from R—C(O)—R claim 9 , R—S(O)—R claim 9 ...

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25-02-2016 дата публикации

BRIGHT STOCK BASE OIL BLEND

Номер: US20160053192A1
Автор: Miller Stephen Joseph
Принадлежит: Chevron U.S.A. INC.

A method is disclosed for making a bright stock base oil blend meeting API Group II specifications. The method comprises blending (a) a major amount of a petroleum-derived bright stock component having kinematic viscosity at 100° C. of from 20 to 50 mm/s with a sufficient amount of (b) a propylene oligomer component having a viscosity index of from 30 to 60, to provide a bright stock base oil blend having a higher viscosity than the petroleum-derived bright stock component and a higher viscosity index than the propylene oligomer component. 1. A method for making a bright stock base oil blend meeting API Group II specifications comprising: blending (a) a major amount of a petroleum-derived bright stock component having kinematic viscosity at 100° C. of from 20 to 50 mm/s with a sufficient amount of (b) a propylene oligomer component having a viscosity index of from 30 to 60 , to provide a bright stock base oil blend having a higher viscosity than the petroleum-derived bright stock component and a higher viscosity index than the propylene oligomer component.2. The method of claim 1 , wherein the blend comprises from 60 to 90% of the petroleum-derived bright stock component and from 40 wt. % to 10 wt. % of the propylene oligomer component claim 1 , based on the total weight of the blend.3. The method of claim 1 , wherein the blend comprises from 70 to 85% of the petroleum-derived bright stock component and from 30 wt. % to 15 wt. % of the propylene oligomer component claim 1 , based on the total weight of the blend.4. The method of claim 1 , wherein the blend has a kinematic viscosity at 100° C. that is at least 3 mm/s higher than that of the petroleum-derived bright stock component.5. The method of claim 1 , wherein the blend has a viscosity index that is at least 20 higher than that of the propylene oligomer component.6. The method of claim 1 , wherein the blend has a pour point that is at least 1° C. lower than that of the petroleum-derived bright stock component.7. ...

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13-02-2020 дата публикации

USE OF BIODEGRADABLE HYDROCARBON FLUIDS AS DRILLING FLUIDS

Номер: US20200048525A1
Принадлежит: TOTAL MARKETING SERVICES

The invention is a fluid having a kinematic viscosity from 3 to 6 mm/s, a flash point of higher than 120° C. and a pour point lower than −40° C., having a boiling point in the range of from 200° C. to 400° C. and a boiling range below 80° C., said fluid comprising more than 95% isoparaffins and less than 3% of naphthens by weight, a biocarbon content of at least 95% by weight, containing less than 100 ppm aromatics by weight. The invention is also a drilling fluid and the use of the fluid to improve the viscosity of the drilling fluid. 116.-. (canceled)17. Fluid having a kinematic viscosity at 40° C. from 3 to 6 mm2/s , a flash point of higher than 120° C. and a pour point lower than −40° C. , having a boiling point in the range of from 200° C. to 400° C. and a boiling range below 80° C. , said fluid comprising more than 95% isoparaffins and less than 3% of naphthens by weight , a biocarbon content of at least 95% by weight , containing less than 100 ppm aromatics by weight.18. Fluid of claim 17 , having a pour point lower than −50° C.19. Fluid of claim 17 , consisting of one fraction having an initial boiling point of at least 260° C. and a final boiling point of about less than about 320° C.20. Fluid of claim 17 , consisting of a mixture of two fractions claim 17 , each fraction having a boiling point in the range 220° C.-340° C. claim 17 , and a boiling range of less than 80° C. claim 17 ,where at least one fraction has an initial boiling point higher than 250° C., orwhere at least one fraction has an initial boiling point lower than 250° C.21. Fluid of claim 17 , consisting of a mixture of three fractions claim 17 , each fraction having a boiling point in the range 220° C.-340° C. claim 17 , and a boiling range of less than 80° C. claim 17 ,where at least one fraction has an initial boiling point higher than 250° C.,where at least one fraction has an initial boiling point lower than 250° C.22. Fluid of claim 17 , wherein the fluid is obtainable by the process ...

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22-02-2018 дата публикации

FLOODING COMPOUNDS FOR TELECOMMUNICATION CABLES

Номер: US20180051225A1
Принадлежит:

Flooding compounds for telecommunications cables. Such flooding compounds contain a polyolefin elastomer and a hydrocarbon oil. The polyolefin elastomer has a crystallinity ranging from 10 less than 50 weight percent and a dynamic viscosity of 50,000 centipoise or less at 177° C. The hydrocarbon oil has a kinematic viscosity of 200 centistokes or less at 40° C. 1. A flooding compound for a telecommunications cable , said flooding compound comprising:(a) a polyolefin elastomer; and(b) a hydrocarbon oil,wherein said polyolefin elastomer has a crystallinity in the range of from 10 to less than 50 weight percent,wherein said polyolefin elastomer has a dynamic viscosity of 50,000 centipoise or less at 177° C.,wherein said hydrocarbon oil has a kinematic viscosity of 200 centistokes or less at 40° C.2. The flooding compound of claim 1 , wherein said flooding compound has an apparent viscosity in the range of from 20 to 400 centipoise at 150° C. claim 1 , as determined according to ASTM D3236.3. The flooding compound of claim 1 , wherein said polyolefin elastomer has an Mn of greater than 5 claim 1 ,000 g/mol; wherein said polyolefin elastomer has a weight-average molecular weight (“Mw”) in the range of from 5 claim 1 ,000 to 50 claim 1 ,000 g/mol; wherein said polyolefin elastomer has a polydispersity index (“Mw/Mn”) in the range of from 1 to 5.4. The flooding compound of claim 1 , wherein said polyolefin elastomer has a density of less than 0.910 g/cm; wherein said polyolefin elastomer has a melting point of at least 70° C.5. The flooding compound of claim 1 , wherein said polyolefin elastomer is selected from the group consisting of an ethylene-based polyolefin elastomer claim 1 , a propylene-based polyolefin elastomer claim 1 , and combinations thereof.6. The flooding compound of claim 5 , wherein said ethylene-based polyolefin elastomer is an ethylene/octene copolymer claim 5 , wherein said propylene-based polyolefin elastomer is a propylene/ethylene copolymer.7. The ...

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23-02-2017 дата публикации

Catalytic system for preparation of high branched alkane from olefins

Номер: US20170051222A1

The present invention discloses a catalytic system for preparing highly branched alkane from olefin, which contains novel nickel or palladium complexes. In the presence of the catalytic system, highly branched oily alkane mixture can be efficiently obtained from olefins (such as ethylene) under mild conditions. The alkane mixture has a low bromine number, and can be used as a processing aid(s) and lubricant base oil with high-performance. Provides also was a method for preparing the catalyst and a method for preparing an oily olefin polymer.

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23-02-2017 дата публикации

High-Viscosity Metallocene Polyalpha-Olefins with High Electrohydrodynamic Performance

Номер: US20170051223A1
Автор: Han Wenning W.
Принадлежит:

A PAO lubricant base stock having a KV100 of at least 200 cSt and comprising multiple PAO molecules comprising at least 200 carbon atoms per molecule, wherein each of the PAO molecules comprises multiple pendant groups; and the average pendant group length of all the pendant groups excluding one methyl on each of the PAO molecules among at least 90 mol % of all of the PAO molecules, if one or more methyl is present, is at least 6.0. The PAO base stock exhibits high EHL thicknesses at 40° C., 80° C., and 120° C., rendering it particularly useful in lubricant compositions experiencing high-stress events such as gear oils, automotive transmission oils, and the like. 1. A PAO base stock having a KV100 of at least 200 cSt and comprising multiple PAO molecules comprising at least 200 carbon atoms per molecule , wherein:each of the PAO molecules comprises multiple pendant groups; andthe average pendant group length of all the pendant groups on each PAO molecule among at least 90 mol % of all of the PAO molecules is at least 6.0.2. The PAO base stock of having a KV100 of at most 600 cSt.3. The PAO base stock of claim 1 , wherein at least 90 mol % of all of the PAO molecules contained therein comprise at least 300 carbon atoms per molecule.4. The PAO base stock of claim 1 , wherein at least 90 mol % of all of the PAO molecules comprise at most 1000 carbon atoms per molecule.5. The PAO base stock of claim 1 , wherein:in at least 90 mol % of all of the PAO molecules, at most 5 mol % of the pendant groups are bonded to adjacent carbon atoms on the main carbon chain of the respective PAO molecule.6. The PAO base stock of claim 1 , wherein:in at least 90 mol % of all of the PAO molecules, at least 90 mol % of the pendant groups are bonded to carbon atoms on the main carbon chain of the PAO molecule that is separated by only one intermediate carbon atom from the next carbon atom to which a pendant group is attached.7. The PAO base stock of claim 1 , wherein:in at least 90 mol % of ...

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23-02-2017 дата публикации

USE OF A LUBRICANT COMPOSITION FOR REDUCING KNOCKING

Номер: US20170051226A1
Принадлежит: TOTAL MARKETING SERVICES

The present disclosure relates to a lubricant composition including at least one base oil and at least one organic compound. The lubricant composition thus makes it possible to reduce, or even to eliminate knock in a vehicle engine, preferably a motor vehicle engine. 2. The method according to in which R1 represents:a saturated or unsaturated, substituted or unsubstituted, linear or branched alkyl group, comprising from 1 to 10 carbon atoms;an —OR7 group in which R7 represents a saturated or unsaturated, substituted or unsubstituted, linear or branched alkyl group, comprising from 1 to 10 carbon atoms; andan —NR8R9 group in which R8 and R9, identical or different, represent independently a hydrogen atom or a saturated or unsaturated, substituted or unsubstituted alkyl group, comprising from 1 to 3 carbon atoms3. The method according to in which R5 represents a hydrogen atom.4. The method according to in which R6 represents a hydrogen atom.5. The method according to in which R1 represents:a saturated, linear or branched alkyl group, comprising from 1 to 5 carbon atoms;an —OR7 group in which R7 represents a saturated, linear or branched alkyl group, comprising from 1 to 5 carbon atoms; and R8 represents a hydrogen atom or a saturated alkyl group, comprising from 1 to 3 carbon atoms;', 'R9 represents a hydrogen atom or a saturated alkyl group, comprising from 1 to 3 carbon atoms., 'an —NR8R9 group in which6. The method according to in which R2 represents:a hydrogen atom;a saturated, linear or branched alkyl group, comprising from 1 to 5 carbon atoms; R11 represents a hydrogen atom or a saturated alkyl group, comprising from 1 to 3 carbon atoms; and', 'R12 represents a hydrogen atom or a saturated alkyl group, comprising from 1 to 3 carbon atoms., 'an —NR11R12 group in which7. The method according to in which R3 represents:a hydrogen atom;a saturated, linear or branched alkyl group, comprising from 1 to 5 carbon atoms; R14 represents a hydrogen atom or a saturated alkyl ...

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26-02-2015 дата публикации

HIGHLY AROMATIC BASE OIL AND METHOD FOR PRODUCING HIGHLY AROMATIC BASE OIL

Номер: US20150057205A1
Принадлежит:

A method for producing a highly aromatic base oil of the present invention includes a step of hydrorefining a clarified oil to obtain a highly aromatic base oil having an aromatic content of 50% by mass or more determined by a column chromatography analysis method. The step of hydrorefining a clarified oil is preferably performed under conditions of a hydrogen pressure of 5.0 to 20.0 MPa, a temperature of 280 to 400° C., a hydrogen oil ratio of 300 to 750 NL/L, and a space velocity of 0.3 to 2.0 h. According to the present invention, a highly aromatic base oil used for rubber processing, asphalt reclamation and the like, and a novel method for producing a highly aromatic base oil can be provided. 1. A method for producing a highly aromatic base oil comprising:a step of hydrorefining a clarified oil to obtain a highly aromatic base oil having an aromatic content of 50% by mass or more determined by a column chromatography analysis method.2. The method for producing a highly aromatic base oil according to claim 1 , wherein the step of hydrorefining a clarified oil is performed under conditions of a hydrogen pressure of 5.0 to 20.0 MPa claim 1 , a temperature of 280 to 400° C. claim 1 , a hydrogen oil ratio of 300 to 750 NL/L claim 1 , and a space velocity of 0.3 to 2.0 h.3. A method for producing a mixed-base oil comprising:a first step of hydrorefining a clarified oil to obtain a highly aromatic base oil having an aromatic content of 50% by mass or more determined by a column chromatography analysis method; and{'sub': 'A', 'a second step of mixing the highly aromatic base oil and one or more base oils selected from a mineral oil and a synthetic oil other than the highly aromatic base oil to obtain a mixed-base oil having an aromatic content of 50% by mass or more determined by a column chromatography analysis method, an aniline point of 100° C. or less, % Cof 20 to 80 according to ASTM D2140, a pour point of +10° C. or less, a glass-transition point of −30° C. to −60 ...

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01-03-2018 дата публикации

ALKYLATE BASE OIL OF BIOLOGICAL ORIGIN

Номер: US20180057421A1
Автор: Hommeltoft Sven Ivar
Принадлежит:

An alkylate base oil of a biological origin having a kinematic viscosity at 100° C. from 3 mm/s to 20 mm/s, and characterized by having a total integral of a C NMR spectrum wherein 25-60% of the total integral of the C NMR spectrum falls within C NMR resonances in ranges for linear long chain alkyl groups given by: C1(13.9-14.2 ppm), C2(22.6-22.8 ppm), C3(31.9-32.05 ppm), C4(29.35-29.45 ppm), and C5+(29.6-29.8 ppm). 1. An alkylate base oil of a biological origin having a kinematic viscosity at 100° C. from 3 mm/s to 20 mm/s , and characterized by having a total integral of a C NMR spectrum wherein 25-60% of the total integral of the C NMR spectrum falls within C NMR resonances in ranges for linear long chain alkyl groups given by: C1(13.9-14.2 ppm) , C2(22.6-22.8 ppm) , C3(31.9-32.05 ppm) , C4(29.35-29.45 ppm) , and C5+(29.6-29.8 ppm).2. The alkylate base oil of claim 1 , additionally having a viscosity index of 50 to 140.3. The alkylate base oil of claim 1 , additionally having a viscosity index of 80 or greater.4. The alkylate base oil of claim 1 , wherein the alkylate base oil is saturated.5. The alkylate base oil of claim 1 , additionally having a bromine index less than 500 mg Br/100 g.6. The alkylate base oil of claim 5 , wherein the bromine index is less than 100 mg Br/100 g.7. The alkylate base oil of claim 1 , additionally having a long straight backbone with two long chain alkyl ends.8. The alkylate base oil of claim 1 , additionally having a pour point less than −15° C.9. The alkylate base oil of claim 1 , additionally having a cloud point less than −20° C.10. The alkylate base oil of claim 1 , wherein the biological origin is at least 95%.11. The alkylate base oil of claim 1 , wherein the alkylate base oil of the biological origin is an alkylation product of a farnesane that was made from a biologically derived feedstock.12. A finished lubricant claim 1 , comprising: the alkylate base oil of and at least one additive selected from the group consisting of ...

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02-03-2017 дата публикации

COMPOSITION FOR HEAT CYCLE SYSTEM AND HEAT CYCLE SYSTEM

Номер: US20170058172A1
Принадлежит: Asahi Glass Company, Limited

To provide a composition for a heat cycle system having favorable lubricating properties and comprising a working fluid for heat cycle which has a low global warming potential and which can replace R410A and a heat cycle system employing the composition. 1. A composition for a heat cycle system comprising a working fluid for heat cycle containing 1 ,2-difluoroethylene , and a refrigerant oil.2. The composition for a heat cycle system according to claim 1 , wherein 1 claim 1 ,2-difluoroethylene is trans-1 claim 1 ,2-difluoroethylene claim 1 , cis-1 claim 1 ,2-difluoroethylene or a mixture thereof.3. The composition for a heat cycle system according to claim 1 , wherein the refrigerant oil is at least one member selected from an ester refrigerant oil claim 1 , an ether refrigerant oil and a hydrocarbon refrigerant oil.4. The composition for a heat cycle system according to claim 1 , wherein the kinematic viscosity of the refrigerant oil at 40° C. is from 1 to 750 mm/s.5. The composition for a heat cycle system according to claim 1 , wherein the proportion (carbon/oxygen molar ratio) of carbon atoms to oxygen atoms of the refrigerant oil is from 2 to 7.5.6. The composition for a heat cycle system according to claim 1 , wherein the working fluid for heat cycle further contains at least one member selected from a saturated hydrofluorocarbon.7. The composition for a heat cycle system according to claim 6 , wherein the saturated hydrofluorocarbon is at least one member selected from difluoromethane claim 6 , 1 claim 6 ,1-difluoroethane claim 6 , 1 claim 6 ,1 claim 6 ,1 claim 6 ,2-tetrafluoroethane and pentafluoroethane.8. The composition for a heat cycle system according to claim 1 , wherein the working fluid for heat cycle further contains at least one member selected from a hydrofluorocarbon having a carbon-carbon double bond other than 1 claim 1 ,2-difluoroethylene.9. The composition for a heat cycle system according to claim 8 , wherein the hydrofluorocarbon having a ...

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02-03-2017 дата публикации

COMPOSITION FOR HEAT CYCLE SYSTEM AND HEAT CYCLE SYSTEM

Номер: US20170058174A1
Принадлежит: Asahi Glass Company, Limited

To provide a composition for a heat cycle system, which comprises a working fluid for heat cycle which has a low global warming potential and high stability, and which can replace R410A, and a heat cycle system employing the composition. 1. A composition for a heat cycle system comprising a working fluid for heat cycle containing 1 ,2-difluoroethylene , and a stabilizer for preventing deterioration of the working fluid for heat cycle.2. The composition for a heat cycle system according to claim 1 , wherein 1 claim 1 ,2-difluoroethylene is trans-1 claim 1 ,2-difluoroethylene claim 1 , cis-1 claim 1 ,2-difluoroethylene or a mixture thereof.3. The composition for a heat cycle system according to claim 1 , wherein the stabilizer is at least one stabilizer selected from an oxidation resistance-improving agent claim 1 , a heat resistance-improving agent and a metal deactivator.4. The composition for a heat cycle system according to claim 1 , wherein the stabilizer is at least one compound selected from the group consisting of a phenol compound claim 1 , an unsaturated hydrocarbon group-containing aromatic compound claim 1 , an aromatic amine compound claim 1 , an aromatic thiazine compound claim 1 , a terpene compound claim 1 , a quinone compound claim 1 , a nitro compound claim 1 , an epoxy compound claim 1 , a lactone compound claim 1 , an orthoester compound claim 1 , a mono- or di-alkali metal salt compound of phthalic acid claim 1 , and a thiodiphenyl ether hydroxide compound.5. The composition for a heat cycle system according to claim 1 , which contains the stabilizer in an amount of at least 1 mass ppm.6. The composition for a heat cycle system according to claim 1 , wherein the proportion of 1 claim 1 ,2-difluoroethylene is at least 20 mass % based on the working fluid for heat cycle.7. The composition for a heat cycle system according to claim 1 , wherein the proportion of 1 claim 1 ,2-difluoroethylene is from 20 to 80 mass % based on the working fluid for heat ...

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02-03-2017 дата публикации

PROCESSES USING MOLECULAR SIEVE SSZ-91

Номер: US20170058209A1
Принадлежит:

Uses for a family of new crystalline molecular sieves designated SSZ-91 are disclosed. Molecular sieve SSZ-91 is structurally similar to sieves falling within the ZSM-48 family of molecular sieves, and is characterized as: (1) having a low degree of faulting, (2) a low aspect ratio that inhibits hydrocracking as compared to conventional ZSM-48 materials having an aspect ratio of greater than 8, and (3) is substantially phase pure. 1. A process for converting hydrocarbons , comprising contacting a hydrocarbonaceous feed under hydrocarbon converting conditions with a catalyst comprising a molecular sieve , the molecular sieve belonging to the ZSM-48 family of zeolites , wherein the molecular sieve comprises:a silicon oxide to aluminum oxide mole ratio of 40 to 200,at least 70% polytype 6 of the total ZSM-48-type material present in the product, andan additional EUO-type molecular sieve phase in an amount of between 0 and 3.5 percent by weight of the total product; andwherein the molecular sieve has a morphology characterized as polycrystalline aggregates comprising crystallites collectively having an average aspect ratio of between 1 and 8.3. The process of claim 1 , wherein the molecular sieve has a silicon oxide to aluminum oxide mole ratio of 70 to 160.4. The process of claim 1 , wherein the molecular sieve has a silicon oxide to aluminum oxide mole ratio of 80 to 140.5. The process of claim 1 , wherein the crystallites collectively have an average aspect ratio of between 1 and 5.6. The process of claim 1 , wherein the molecular sieve comprises between 0.1 and 2 wt. % EU-1.7. The process of claim 1 , wherein the molecular sieve comprises at least 80% polytype 6 of the total ZSM-48-type material present in the product.8. The process of claim 7 , wherein the crystallites collectively have an average aspect ratio of between 1 and 5.9. The process of claim 8 , wherein the molecular sieve comprises between 0.1 and 2 wt. % EU-1.10. The process of claim 1 , wherein the ...

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05-03-2015 дата публикации

Lubricating oil composition for refrigerating machines

Номер: US20150065407A1
Принадлежит: Idemitsu Kosan Co Ltd

A lubricating oil composition for refrigerating machines contains a base oil and an additive in a form of a hydrocarbon compound having a biphenyl structure or a stilbene structure. When the present lubricating oil composition for refrigerating machines is used in refrigerating equipment such as an open-type automobile air-conditioner, an electric automobile air-conditioner, a gas heat pump, other air-conditioning equipment, a refrigerating machine, a vending machine, a showcase, a water-heating system and a refrigerating/heating system, it is possible to detect the leakage of a refrigerant with a long-lasting stability. Therefore, when an unsaturated chlorofluorocarbon refrigerant with a poor stability is used in the above-listed equipment, the present lubricating oil composition for refrigerating machines is significantly advantageous.

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17-03-2022 дата публикации

Method for producing renewable base oil and renewable fuel components

Номер: US20220081626A1
Принадлежит: Neste Oyj

The present disclosure relates to methods for producing renewable base oil and other valuable renewable fuel components from a feedstock of biological origin comprising free fatty acids and glycerides. The feedstock is first separated to two or more effluent streams containing a fatty acid fraction and glyceride fraction. The glycerides are hydrolyzed to free fatty acids and glycerol, and the fatty acids thus obtained are recycled to the separating. The fatty acids are then converted to the base oil by ketonisation, hydrodeoxygenation and hydroisomerisation. The glycerol is converted to propanols by selective hydrogenolysis.

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17-03-2022 дата публикации

CATALYTIC UPCYCLING OF POLYOLEFINS INTO LUBRICANTS

Номер: US20220081638A1
Принадлежит: UCHICAGO ARGONNE, LLC

A method of upcycling polymers to useful hydrocarbon materials. A catalyst with nanoparticles on a substrate selectively docks and cleaves longer hydrocarbon chains over shorter hydrocarbon chains. The nanoparticles exhibit an edge to facet ratio to provide for more interactions with the facets. 1. A method producing a lubricant comprising:exposing, at a temperature of 150-350° C. and a pressure of 100-200 psi for 12-72 hours, a plurality polymer molecules to a catalyst comprising a substrate having a plurality of catalytic nanoparticles deposited thereon;docking a first polymer molecule of the plurality of polymer molecules to the catalyst;cleaving at least one carbon-carbon bond of the first polymer molecule;forming a plurality of hydrocarbon fragments from the cleaving;selectively docking to the catalyst a second polymer molecule of the plurality of polymer molecules, preferentially over the plurality of hydrocarbon fragments;cleaving at least one carbon-carbon bond of the second polymer molecule; andforming a second plurality of hydrocarbon fragments.2. The method of claim 1 , wherein exposing the plurality of polymer molecules is for at least 24 hours.3. The method of claim 1 , wherein the plurality of catalytic nanoparticles comprise Pt or Ni.4. The method of claim 1 , wherein the substrate comprises a perovskite.5. The method of claim 4 , wherein the substrate comprises strontium titanate.6. The method of claim 3 , wherein the substrate comprises alumina.7. The method of claim 1 , wherein the plurality of polymer molecules are solvent-free.8. The method of claim 1 , wherein the plurality of polymer molecules have a molecular weight ranging from 400-1000 Da.9. The method of claim 8 , wherein the plurality of hydrocarbon fragments are C30 to C76 alkanes.10. The method of claim 9 , wherein the plurality of hydrocarbon fragments have 10 branches per 1000 carbon to 400 branches per 1000 carbon.11. The method of claim 10 , wherein the plurality of hydrocarbon ...

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28-02-2019 дата публикации

NOVEL FORMULATION APPROACH TO EXTEND THE HIGH TEMPERATURE PERFORMANCE OF LITHIUM COMPLEX GREASES IN ROLLING BEARINGS

Номер: US20190062669A1
Принадлежит:

The present disclosure provides a lithium complex grease with high-temperature resistivity and a method of making the same. The lithium complex grease includes: a lithium complex thickener, a friction modifier, a polymer or copolymer, and at least one synthetic base oil with alkylated naphthalene. The lithium complex grease can be substantially free of polytetrafluoroethylene. Furthermore, the lithium complex grease can have a median failure rate with via ball bearing test (e.g., using the FE9 grease life test method of DIN 51 821) performed at 160° C. of no less than 100 hours. 1. A lithium complex grease with high-temperature resistivity , the lithium complex grease comprising:a lithium complex thickener;a friction modifier;a polymer or copolymer; andat least one synthetic base oil having alkylated naphthalene.2. The lithium complex grease of claim 1 , wherein the friction modifier is at least one of a molybdenum (Mo) friction modifier claim 1 , molybdenum dithiocarbamate (MoDTC) claim 1 , molybdenum dithiophosphate (MoDTP) claim 1 , MOLYVAN® 822 claim 1 , MOLYVAN® 855 claim 1 , MOLYVAN® L claim 1 , MOLYVAN® 807 claim 1 , MOLYVAN® A claim 1 , MOLYVAN® 2000 claim 1 , ADEKA SAKURA LUBE 525 claim 1 , MOLYVAN® 3000 claim 1 , or a combination thereof.3. The lithium complex grease of claim 1 , wherein the polymer or copolymer comprises at least one of ethylene claim 1 , propylene claim 1 , an ethylene-propylene co-polymer claim 1 , or a combination thereof.4. The lithium complex grease of claim 3 , wherein the polymer or copolymer is Vistamaxx™ 6202.5. The lithium complex grease of claim 1 , wherein the at least one synthetic base oil includes at least one of an alkylated naphthalene base oil claim 1 , a polyalphaolefin (PAO) base oil claim 1 , alkylated naphthalene in PAO base oil claim 1 , or a combination thereof.6. The lithium complex grease of claim 5 , wherein the alkylated naphthalene base oil is at least one of Synesstic™ 5 claim 5 , Synesstic™ 12 claim 5 , or a ...

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10-03-2016 дата публикации

Oligomerisation process

Номер: US20160068622A1
Принадлежит: Queens University of Belfast

This invention relates to base oils for lubricating compositions. In particular, the present invention provides a process for the selective oligomerisation of C 5 to C 20 alpha-olefins to produce polyalphaolefin oligomers with a molecular weight distribution that is suitable for use in lubricant base oils.

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08-03-2018 дата публикации

COMPOSITION FOR HEAT CYCLE SYSTEM AND HEAT CYCLE SYSTEM

Номер: US20180066170A1
Принадлежит: Asahi Glass Company, Limited

A composition for a heat cycle system contains a working medium for heat cycle containing 1-chloro-2,3,3,3-tetrafluoropropene and a refrigerant oil. 1. A composition for a heat cycle system comprising:a working medium for heat cycle containing 1-chloro-2,3,3,3-tetrafluoropropene; anda refrigerant oil.2. The composition for a heat cycle system according to claim 1 ,wherein the 1-chloro-2,3,3,3-tetrafluoropropene contains (Z)-1-chloro-2,3,3,3-tetrafluoropropene and (E)-1-chloro-2,3,3,3-tetrafluoropropene at a ratio of 51:49 to 100:0 by mass ratio represented by (Z)-1-chloro-2,3,3,3-tetrafluoropropene:(E)-1-chloro-2,3,3,3-tetrafluoropropene.3. The composition for a heat cycle system according to claim 1 ,wherein the refrigerant oil contains at least one type of oil selected from the group consisting of an ester-based refrigerant oil, an ether-based refrigerant oil, a hydrocarbon-based refrigerant oil, and a naphthenic refrigerant oil.4. The composition for a heat cycle system according to claim 3 ,wherein the refrigerant oil contains at least one type of compound selected from the group consisting of a dibasic acid ester, a polyol ester, a complex ester, a polyol carbonic acid ester, polyvinyl ether, a polyalkylene glycol, alkyl benzene, and a naphthene-base oil.5. The composition for a heat cycle system according to claim 1 ,{'sup': 2', '2, 'wherein the refrigerant oil has a kinematic viscosity at 40° C. of 1 mm/s or more and 750 mm/s or less.'}6. The composition for a heat cycle system according to claim 1 ,wherein the refrigerant oil contains carbon atoms and oxygen atoms at a ratio of 2.0 or more and 7.5 or less by molar ratio represented by carbon atoms/oxygen atoms.7. The composition for a heat cycle system according to claim 1 ,wherein the working medium for heat cycle further contains saturated hydrofluorocarbon.8. The composition for a heat cycle system according to claim 1 ,wherein the working medium for heat cycle further contains hydrofluoroolefin.9. The ...

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09-03-2017 дата публикации

LITHIUM-BASED THICKENER AND GREASE COMPOSITION INCLUDING THE SAME

Номер: US20170066992A1
Автор: Kim Jae Hyeon
Принадлежит: HYUNDAI MOTOR COMPANY

A lithium salt thickener that enhances thermal stability at high temperature and operability at low temperature, and a grease composition including the same, is provided. 2. The lithium-based thickener according to claim 1 , wherein m and n are the same or different and are integers of 7 or 8.4. The grease composition according to claim 3 , wherein the grease composition comprises:70 to 85% by weight of the synthetic polyalphaolefin (PAO) base oil;10 to 20% by weight of the lithium-based thickener; and0.1 to 10% by weight of the additives.5. The grease composition according to claim 3 , wherein an ester-based viscosity regulator having a viscosity of 500 to 1000 cSt is included as an additive.6. The grease composition according to claim 4 , wherein the ester-based viscosity regulator is included in a content range of 1 to 7% by weight based on a total weight of the grease composition.7. The grease composition according to claim 3 , wherein one or more styrene-based oil separation regulators selected from the group consisting of a styrene-ethylene/propylene block copolymer and a styrene-isoprene copolymer are included as additives.8. The grease composition according to claim 6 , wherein the styrene-based oil separation regulator is included in a content range of 0.5 to 3% by weight based on a total weight of the grease composition. This application claims the benefit of and priority to Korean Patent Application No. 10-2015-0127544 filed on Sep. 9, 2015, the content of which is incorporated herein by reference in its entirety.The present disclosure relates to lithium salt thickeners, as well as grease compositions including the same. More particularly, it relates to a lithium salt thickener that enhances thermal stability at high temperature and operability at low temperature.The statements in this section merely provide background information related to the present disclosure and may not constitute prior art.Grease is a semisolid-type lubricant used for lubrication ...

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19-03-2015 дата публикации

Working fluid composition for refrigerator

Номер: US20150076393A1
Принадлежит: JX Nippon Oil and Energy Corp

The working fluid composition for a refrigerating machine of the present invention comprises a mixed refrigerant comprising a hydrofluoroethane represented by the following formula (A), difluoromethane and tetrafluoropropene, and a refrigerating machine oil comprising at least one selected from a polyol ester, a polyvinyl ether and a polyalkylene glycol compound as a base oil, wherein a carbon/oxygen molar ratio of the base oil is 2.5 or more and 5.8 or less. C 2 H n F 6-n   (A) [n represents 1 or 2.]

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17-03-2016 дата публикации

Production of hydrocarbons from plant oil and animal fat

Номер: US20160076157A1
Принадлежит: ALTRANEX Corp

Oils from plants and animal fats are hydrolyzed to fatty acids for a Kolbe reaction. The invention relates to a high productivity Kolbe reaction process for electrochemically decarboxylating C4-C28 fatty acids derived from sources selected based on their saturated and unsaturated fatty acid content in order to lower anodic passivation voltage during synthesis of C6-C54 hydrocarbons. The C6-C54 hydrocarbons may undergo olefin metathesis and/or hydroisomerization reaction processes to synthesize heavy fuel oil, diesel fuel, kerosene fuel, lubricant base oil, and linear alpha olefin products useful as precursors for polymers, detergents, and other fine chemicals.

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24-03-2022 дата публикации

COMPOSITION FOR HEAT CYCLE SYSTEM, AND HEAT CYCLE SYSTEM

Номер: US20220089927A1
Принадлежит: AGC Inc.

To provide a composition for a heat cycle system, which comprises a working fluid for heat cycle which has a low global warming potential and high stability, and which can replace R410A, and a heat cycle system employing the composition. 115-. (canceled)16. A composition for a heat cycle system , comprising:a working fluid; anda stabilizer;wherein:the working fluid comprises:30-50 mass % trifluoroethylene based on a total mass of working fluid; and50-70 mass % 1,3,3,3-tetrafluoropropene based on a total mass of the working fluid.17. The composition for a heat cycle system of claim 16 , wherein the 1 claim 16 ,3 claim 16 ,3 claim 16 ,3-tetrafluoropropene is HFO-1234ze(E).18. The composition for a heat cycle system of claim 16 , further comprising a refrigerant oil.19. An air conditioning apparatus claim 16 , comprising the composition for a heat cycle system of .20. An automobile claim 16 , comprising an air conditioning apparatus having the composition for a heat cycle system of contained therein.21. The composition for a heat cycle system of claim 16 , wherein the working fluid comprises:30-40 mass % trifluoroethylene based on a total mass of working fluid; and60-70 mass % 1,3,3,3-tetrafluoropropene based on a total mass of the working fluid.22. The composition for a heat cycle system of claim 21 , wherein the 1 claim 21 ,3 claim 21 ,3 claim 21 ,3-tetrafluoropropene is HFO-1234ze(E).23. The composition for a heat cycle system of claim 21 , further comprising a refrigerant oil.24. An air conditioning apparatus claim 21 , comprising the composition for a heat cycle system of .25. An automobile claim 21 , comprising an air conditioning apparatus having the composition for a heat cycle system of contained therein.26. The composition for a heat cycle system of claim 16 , wherein the working fluid consists of trifluoroethylene and 1 claim 16 ,3 claim 16 ,3 claim 16 ,3-tetrafluoropropene.27. The composition for a heat cycle system of claim 26 , wherein the 1 claim 26 ,3 ...

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16-03-2017 дата публикации

TETRAFLUOROPROPENE COMPOSITIONS AND USES THEREOF

Номер: US20170073561A1
Принадлежит:

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a tetrafluoropropene and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents. 114-. (canceled)15. A composition comprising HFO-1234yf , HFC-32 , HFC-125 , and HFC-134a.16. The composition of wherein the composition comprises from about 20 weight percent to about 98 weight percent HFO-1234yf.17. The composition of further comprising at least one lubricant selected from the group consisting of mineral oils claim 15 , alkylbenzenes claim 15 , synthetic paraffins claim 15 , synthetic naphthenes claim 15 , poly alpha olefins claim 15 , polyalkylene glycols claim 15 , dibasic acid esters claim 15 , polyesters claim 15 , neopentyl esters claim 15 , polyvinyl ethers claim 15 , silicones claim 15 , silicate esters claim 15 , fluorinated compounds claim 15 , phosphate esters and mixtures thereof.181. A process to produce cooling comprising condensing a composition of claim and thereafter evaporating said composition in the vicinity of a body to be cooled.191. A process to produce heat comprising condensing the composition of claim in the vicinity of a body to be heated and thereafter evaporating said composition.20. A method for replacing R12 claim 15 , R134a claim 15 , R22 claim 15 , R404A claim 15 , R407A claim 15 , R407C claim 15 , R410A claim 15 , R422A claim 15 , R422B claim 15 , R422C claim 15 , R422D claim 15 , R438A claim 15 , R502 claim 15 , R507A claim 15 , R507B claim 15 , or R508 claim 15 , in a system that uses claim 15 , used or was designed to use R12 claim 15 , R134a claim 15 , R22 claim 15 , R404A claim 15 , R407A claim 15 , R407C claim 15 , R410A claim 15 , R422A claim 15 , R422B claim 15 , R422C claim 15 , R422D claim 15 , ...

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16-03-2017 дата публикации

GREASE COMPOSITION AND GREASE-FILLED WHEEL BEARING

Номер: US20170074326A1
Принадлежит:

Provided is a grease composition for a wheel bearing, containing (a) a base oil consisting of a mineral oil and a synthetic hydrocarbon oil, wherein the ratio of the synthetic hydrocarbon oil to the total amount of the mineral oil and the synthetic hydrocarbon oil is 40 to 60 mass %, and the base oil has a kinematic viscosity at 40° C. of 40 to 65 mm/s; (b) a thickener of formula (A) wherein Ris diphenylmethane, and Rand R, which may be the same or different from each other, each represent cyclohexyl group or a straight-chain or branched alkyl group having 16 to 20 carbon atoms, with a molar ratio of the cyclohexyl group to the total number of moles of the cyclohexyl group and the alkyl group being 50 to 90 mol %; (c) an amine type antioxidant; and (d) an amine phosphate type antiwear agent. 2. The grease composition of claim 1 , wherein the amine phosphate type antiwear agent is a tertiary alkylamine-dimethyl phosphate claim 1 , which is contained in an amount of 0.05 to 5 mass % based on the total mass of the grease composition.3. The grease composition of claim 1 , further comprising a rust inhibitor comprising an organic sulfonate and an amine compound.4. The grease composition of claim 3 , wherein the organic sulfonate is a calcium sulfonate claim 3 , which is contained in an amount of 0.05 to 5 mass % based on the total mass of the grease composition.5. The grease composition of claim 3 , wherein the amine compound is an amine salt of a fatty acid claim 3 , which is contained in an amount of 0.05 to 5 mass % based on the total mass of the grease composition.6. The grease composition of claim 1 , further comprising zinc dialkyldithiocarbamate claim 1 , which is contained in an amount of 0.05 to 5 mass % based on the total mass of the grease composition.7. A wheel bearing where the grease composition of is enclosed. The present invention relates to a grease composition to be filled in a wheel bearing, which can satisfy the low torque performance, and show the ...

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22-03-2018 дата публикации

ALKYLATED ALKOXYDIARYLAMINE ANTIOXIDANTS

Номер: US20180079984A1
Автор: Rowland Robert G.
Принадлежит:

Alkylated diaryl amines further substituted by an alkoxy group on one or more aryl carbon atoms exhibit excellent antioxidant activity in lubricant compositions. 2. The alkylated alkoxydiarylamine according to wherein m is 0.3. The alkylated alkoxydiarylamine according to wherein x is 0 or 1 and y is 1 or 2.4. The alkylated alkoxydiarylamine according to wherein R′ is Calkyl.5. The alkylated alkoxydiarylamine according to wherein each R is independently Calkyl claim 1 , or two adjacent R groups together with the carbons to which they are attached form a 6 to 8 member non-aromatic carbocyclic ring claim 1 , or said 6 to 8 member non-aromatic carbocyclic ring substituted by Calkyl; and each R″ is independently Calkyl.6. The alkylated alkoxydiarylamine according to wherein R′ is Calkyl and each R is independently Calkyl.7. The alkylated alkoxydiarylamine according to wherein x is 0 or 1 and y is 1 or 2.8. The alkylated alkoxydiarylamine according to wherein R′ is Calkyl.9. The alkylated alkoxydiarylamine according to wherein each R is independently Calkyl claim 8 , or two adjacent R groups together with the carbons to which they are attached form a 6 to 8 member non-aromatic carbocyclic ring claim 8 , or said 6 to 8 member non-aromatic carbocyclic ring substituted by Calkyl; and each R″ is independently Calkyl.10. The alkylated alkoxydiarylamine according to wherein R′ is Calkyl and each R is independently Calkyl.11. The alkylated alkoxydiarylamine according to wherein the total number of carbon atoms of the combined groups R′ claim 1 , R and R″ is 12 or higher.12. The alkylated alkoxydiarylamine according to wherein the total number of carbon atoms of the combined groups R and R″ is 12 or higher.13. The alkylated alkoxydiarylamine according to wherein the total number of carbon atoms of the combined groups R′ claim 7 , R and R″ is 12 or higher.14. The alkylated alkoxydiarylamine according to wherein the total number of carbon atoms of the combined groups R and R″ is ...

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22-03-2018 дата публикации

ALKYLATED 3-HYDROXYDIPHENYLAMINE ANTIOXIDANTS

Номер: US20180079985A1
Автор: Rowland Robert G.
Принадлежит:

Certain alkylated 3-hydroxyphenylamine antioxidants wherein one phenyl is substituted by at least one hydroxyl group at the 3-position relative to the amine and the other phenyl is substituted by at least one substituent having 4 or more carbon atoms are surprisingly effective antioxidants, especially in lubricating oils. 2. The alkylated 3-hydroxydiphenylamine according to wherein n is 0 and m is 0 or 1.3. The alkylated 3-hydroxydiphenylamine according to wherein m is 0.4. The alkylated 3-hydroxydiphenylamine according to wherein x is 0 or 1 and y is 1 or 2.5. The alkylated 3-hydroxydiphenylamine according to wherein each R is independently Calkyl claim 1 , or two adjacent R groups together with the carbons to which they are attached form a 6 to 8 member non-aromatic carbocyclic ring claim 1 , which ring is optionally substituted by Calkyl.6. The alkylated 3-hydroxydiphenylamine according to wherein claim 1 , the total number of carbon atoms of the combined groups R is 12 or higher.7. The alkylated 3-hydroxydiphenylamine according to wherein claim 1 , the total number of carbon atoms of the combined groups R is 16 or higher.8. The alkylated 3-hydroxydiphenylamine according to wherein claim 5 , the total number of carbon atoms of the combined groups R is 12 or higher.9. The alkylated 3-hydroxydiphenylamine according to wherein claim 5 , the total number of carbon atoms of the combined groups R is 16 or higher.10. A lubricating oil composition comprisinga) a lubricating oil, and{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'b) one or more alkylated 3-hydroxydiphenylamine according to .'}11. The lubricating oil composition according to wherein b) is present in an amount of about 0.1 to about 5.0 wt % claim 10 , based on the weight of the lubricating oil composition.12. The lubricating oil composition according to wherein b) is present in an amount of about than 5 to about 50 wt % claim 10 , based on the weight of the lubricating oil composition.13. The lubricating ...

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22-03-2018 дата публикации

LUBRICANT COMPOSITIONS STABILIZED BY MIXTURES OF DIARYLAMINE AND HYDROXYDIARYLAMINE ANTIOXIDANTS

Номер: US20180079987A1
Принадлежит:

Lubricant compositions comprising a lubricating oil and a mixture of one or more alkylated diarylamine and one or more alkylated hydroxydiarylamine exhibit excellent antioxidant and deposit control performance. 3. The lubricating oil composition according to wherein the mixture of b) is present in an amount of about 0.1 to about 5.0 wt % claim 1 , based on the weight of the lubricating oil composition.4. The lubricating oil composition according to wherein the mixture of b) is present in an amount of about than 5 to about 50 wt % claim 1 , based on the weight of the lubricating oil composition5. The lubricating oil composition according to wherein the alkylated hydroxydiarylamine comprises a compound substituted on a phenyl ring by hydroxyl at the 2- or 3-position relative to the amine.6. The lubricating oil composition according to wherein the alkylated hydroxydiarylamine comprises a compound substituted on a phenyl ring by hydroxyl at the 3-position.7. The lubricating oil composition according to wherein n is 1 and m is 0 or 1.8. The lubricating oil composition according to wherein x is 0 or 1 and y is 1 claim 7 , 2 or 3.9. The lubricating oil composition according to wherein each R is independently Calkyl claim 1 , or two adjacent R groups together with the carbons to which they are attached form an unsubstituted carbocyclic ring of 6 to 8 carbons claim 1 , or said carbocyclic ring substituted by Calkyl; and each R′ is independently Calkyl.10. The lubricating oil composition according to wherein n is 1 and m is 0 or 1.11. The lubricating oil composition according to wherein x is 0 or 1 and y is 1 claim 10 , 2 or 3 and each R is independently Calkyl.14. The lubricating oil composition comprising according to wherein each R″ in formula X claim 13 , independently from each other claim 13 , is Calkyl.15. The lubricating oil composition comprising according to wherein claim 12 , in formula III claim 12 , IV claim 12 , V claim 12 , or VI claim 12 ,{'sub': 4-24', '4-24, ...

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26-03-2015 дата публикации

Tribological Synthesis Method for Producing Low-Friction Surface Film Coating

Номер: US20150087566A1
Принадлежит: UChicago Argonne LLC

An article of method of manufacture of a low friction tribological film on a substrate. The article includes a substrate of a steel or ceramic which has been tribologically processed with a lubricant containing selected additives and the additives, temperature, load and time of processing can be selectively controlled to bias formation of a film on the substrate where the film is an amorphous structure exhibiting highly advantageous low friction properties. 1. A method of forming a low friction tribological surface film comprising:providing a substrate having a crystalline structure and an opposing wear member;providing a lubricant; andcontrolling operating conditions during tribological rubbing processing to form a film on the substrate wherein the film comprises an amorphous structure formed by the tribological rubbing processing.2. The method as defined in wherein the operating conditions comprise at least one of maintaining a temperature range for the substrate claim 1 , controlling amounts of selected additives in the lubricant which bias toward formation of the amorphous structure in the film claim 1 , controlling speed and/or time of performing the tribological rubbing processing claim 1 , and controlling load levels applied to the substrate during the tribological rubbing processing.3. The method as defined in wherein the substrate is selected from the group of steel and a ceramic.4. The method as defined in wherein the amorphous structure comprises at least about 40% of the film structure.5. The method as defined in wherein the lubricant comprises a fluid and an additive.6. The method as defined in wherein the additive is selected from the group of an additive material comprising Zn claim 5 , Mo claim 5 , Ca claim 5 , S claim 5 , P claim 5 , O claim 5 , N claim 5 , C claim 5 , B claim 5 , Si claim 5 , Al and Ti.7. The method as defined in wherein the additive material is selected from the group of a compound which releases in the lubricant an elemental form ...

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26-03-2015 дата публикации

Base Oil Upgrading by Co-Feeding a Ketone or Beta-Keto-Ester Feedstock

Номер: US20150087872A1
Принадлежит: Chevron USA Inc

This invention discloses a process for making high viscosity index lubricating base oils having a viscosity index of at least 110 by co-feeding a ketone or a beta-keto-ester feedstock with a lubricant oil feedstock directly to a hydrocracking unit to produce a hydrocracked stream. Then at least a portion of the hydrocracked stream is treated under hydroisomerization conditions to produce a high viscosity index lubricating base oil. The process may involve bypassing a hydrotreating or hydrofinishing step, which may result in improved efficiency and economics in producing high viscosity index lubricating base oils.

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19-06-2014 дата публикации

PROCESS FOR MAKING SATURATED HYDROCARBONS FROM RENEWABLE FEEDS

Номер: US20140171699A1

Provided are processes for making saturated hydrocarbons from renewable feed sources. In an embodiment, a process for producing a lube basestock and/or a diesel fuel from a feedstock of biological origin includes: contacting the feedstock in a single reactor in the presence of hydrogen with catalyst components including a first catalyst and a second catalyst, wherein the first catalyst comprises an acidic material, a basic material, or a combination of both, and wherein the second catalyst is a hydrogenation catalyst including a hydrothermally stable binder. 1. A method for producing a lube basestock and/or a diesel fuel from a feedstock of biological origin , the method comprising:contacting the feedstock in a single reactor in the presence of hydrogen with catalyst components comprising a first catalyst and a second catalyst,wherein the first catalyst comprises an acidic material, a basic material, or a combination of both, andwherein the second catalyst comprises a hydrogenation catalyst and a hydrothermally stable binder.2. The method according to claim 1 , wherein the feedstock of biological origin comprises one or more components selected from the group consisting of fatty acids claim 1 , fatty acid esters claim 1 , fatty alcohols claim 1 , fatty olefins claim 1 , mono-glycerides claim 1 , di-glycerides claim 1 , tri-glycerides claim 1 , phospholipids and saccharolipids.3. The method according to claim 1 , comprising providing the feedstock of biological origin as a solution in a hydrocarbon solvent.4. The method according to claim 1 , wherein the hydrothermally stable binder comprises TiO claim 1 , ZrOor CeO.5. The method according to claim 1 , further comprising hydroisomerizing the hydrocarbon product.6. The method according to claim 1 , comprising contacting the feedstock of biological origin sequentially with the first catalyst in a first zone of the reactor and with the hydrogenation catalyst in a second zone of the reactor.7. The method according to ...

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12-05-2022 дата публикации

APPLICATION OF NANO COPPER IN CUTTING FLUID

Номер: US20220145210A1
Принадлежит:

The present invention provides an application of nano copper in a cutting fluid. The nano copper is self-dispersible nano copper with an organic long-carbon chain, wherein the surface of copper metal is coated with a long carbon chain organic matter, and the long chain organic matter is dialkyl dithiophosphoric acid (HDDP) and a derivative thereof. In the present invention, the nano copper substitutes functional additives which comprises one or more of a preservative, an anti-rust agent, a sterilizing agent, a compression-resisting agent and a lubricant to solve the technical problems of the existing fluid in the prior art being unable to simultaneously have efficient anti-corrosion, anti-rust, compression-resistant, lubricating and sterilizing properties as well as the variety, the relatively high amount, the high cost and the limited selection of added additives. 1. An application of nano copper in a cutting fluid , wherein the nano copper is self-dispersible nano copper with an organic long-carbon chain.2. The application of the nano copper in the cutting fluid according to claim 1 , wherein the nano copper is a copper metal surface coated with a long-carbon chain organic matter; the long-carbon chain organic matter is dialkyl dithiophosphate (HDDP) and a derivative thereof; and the carbon number of the long-carbon chain is greater than 8 claim 1 , and the cutting fluid is an aqueous cutting fluid.3. The application of the nano copper in the cutting fluid according to claim 2 , wherein the mass percentage claim 2 , in the cutting fluid claim 2 , of the nano copper is 1%-10%; and the nano copper is paste with a particle size of10-50 nm .4. The application of the nano copper in the cutting fluid according to claim 3 , wherein the nano copper substitutes part or all of the functional additives in the cutting fluid claim 3 , and the functional additives comprise one or more of a preservative claim 3 , an anti-rust agent claim 3 , a sterilizing agent claim 3 , a ...

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06-04-2017 дата публикации

RAILWAY LUBRICANT

Номер: US20170096618A1
Принадлежит:

A water-based solid lubricant includes water, glycerin, isoalkane, molybdenum disulfide, talc powder, calcium sulfonate, and polyisobutylene is described herein. 1. A water-based lubricant comprising:water;glycerin;synthetic isoalkane, wherein the synthetic isoalkane is at least 75% by weight C19 to C23 isoalkane, wherein the synthetic isoalkane has a polyaromatic hydrocarbon (PAH) content of ≦0.001 percent;molybdenum disulfide;talc powder;calcium sulfonate; andpolyisobutylene, wherein the lubricant contains no lime and no clay, wherein the lubricant has a viscosity of less than 5,000 cP at 22° C.2. A lubricant comprising:water;a freezing point depressant;a viscosity index modifier; anda synthetic fluid, wherein the lubricant has a viscosity of less than 5,000 cP at 22° C., wherein the lubricant contains no non-synthetic fluids, wherein the synthetic fluid has a polyaromatic hydrocarbon (PAH) content of ≦0.001 percent.3. The lubricant of claim 2 , wherein the lubricant further comprises a friction modifier claim 2 , wherein the lubricant contains no lime.4. The lubricant of claim 3 , wherein the lubricant contains no clay claim 3 , wherein the lubricant further comprises a water-based lubricant.5. The lubricant of claim 4 , wherein the lubricant further comprises a suspension stabilizer.6. The lubricant of claim 5 , wherein the freezing point depressant is a diol or triol.7. The lubricant of claim 6 , wherein the synthetic fluid is isoalkane.8. (canceled)9. The lubricant of claim 7 , wherein the viscosity index modifier is polyisobutylene claim 7 , polyethylene claim 7 , polytetrafluoroethylene claim 7 , polypropylene claim 7 , polycarbohydrate claim 7 , or polyuria claim 7 , wherein the suspension stabilizer is lithium complex base grease claim 7 , aluminum complex base grease claim 7 , or calcium sulfonate.10. The lubricant of claim 9 , wherein the diol is a 1 claim 9 ,2-diol or a 1 claim 9 ,3-diol.11. The lubricant of claim 9 , wherein the diol is ethylene glycol ...

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26-03-2020 дата публикации

PROCESS FOR PREPARING HYDROCARBON MIXTURE EXHIBITING UNIQUE BRANCHING STRUCTURE

Номер: US20200095177A1
Принадлежит:

Provided herein is a unique process that prepares a saturated hydrocarbon mixture with well-controlled structural characteristics that address the performance requirements driven by the stricter environmental and fuel economy regulations for automotive engine oils. The process allows for the branching characteristics of the hydrocarbon molecules to be controlled so as to consistently provide a composition that has a surprising CCS viscosity at −35° C. (ASTM D5329) and Noack volatility (ASTM D5800) relationship. The process comprises providing a specific olefinic feedstock, oligomerizing in the presence of a BFcatalyst, and hydroisomerizing in the presence of a noble-metal impregnated, 10-member ring zeolite catalyst. 1. A process for preparing a base stock , comprising:(i) providing an olefinic feedstock comprising C14 to C20 olefins which comprises less than 40 wt % branched olefins and greater than 40 wt % alpha olefins;(ii) oligomerizing the olefinic feedstock in the presence of a boron trifluoride catalyst at a reaction temperature in the range of from 20-60° C. resulting in a saturated dimer intermediate with a branching proximity of 27-35; and(iii) hydroisomerizing the oligomerization product obtained from step (ii) in the presence of a noble-metal impregnated one-dimensional, 10-member ring zeolite catalyst to achieve a C28+ product with BP/BI≥−0.6037 (Internal alkyl branching per molecule)+2.0 and on average 0.3-1.5 5+ methyl branching per molecule.2. The process of claim 1 , wherein the olefinic feedstock comprises greater than 50 wt % alpha olefins.3. The process of claim 2 , wherein the olefinic feedstock comprises less than 8 wt % branched olefins.4. The process of claim 1 , wherein the olefinic feedstock comprises greater than 70 wt % alpha olefins.5. The process of claim 2 , wherein oligomerization is performed using a boron trifluoride oligomerization catalyst claim 2 , an alcohol promoter claim 2 , and an ester promoter.6. The process of claim 2 , ...

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12-04-2018 дата публикации

Lubricant composition

Номер: US20180100112A1

A lubricant composition improves a performance of reducing a formation of compressor deposit. The lubricant composition also ensures low temperature properties of the lubricant composition. The lubricant composition includes 14 mass % or more of a fraction having a boiling point of 500° C. to 550° C. and 5 mass % or more of a fraction having a boiling point of over 550° C.

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19-04-2018 дата публикации

LUBRICANT BASESTOCK PRODUCTION WITH ENHANCED AROMATIC SATURATION

Номер: US20180105761A1
Принадлежит:

Systems and methods are provided for producing lubricant basestocks using a process flow that includes a conversion catalyst that can provide a desired improvement in viscosity index at a reduced or minimized amount of feed conversion. An initial processing stage can be used to produce a lubricant boiling range fraction with a reduced or minimized heteroatom content. After a separation, at least a portion of the lubricant boiling range portion can be exposed to a conversion catalyst that has an effective pore size of at least 8.0 Angstroms, a total surface area of at least 200 m/g, and/or an Alpha value of 20 or less, where the conversion catalyst includes a supported Group 8-10 noble metal. The methods can allow for increased yields of high viscosity index lubricant boiling range products from a process flow for lubricant base stock and/or blend stock production. 1. A method for producing a lubricant boiling range product , comprising:{'sup': '2', 'converting a feedstock comprising a lubricant boiling range portion in the presence of a conversion catalyst under conversion conditions to form a converted effluent, the conversion catalyst comprising a surface area of at least 200 m/g, an Alpha value of 20 or less, and an effective pore size of at least 8.0 Angstroms, the conversion catalyst further comprising 0.01 wt % to 5.0 wt % of a Group 8-10 noble metal supported on the conversion catalyst;'}dewaxing at least a portion of the converted effluent under catalytic dewaxing conditions to form a dewaxed effluent; andfractionating at least a portion of the dewaxed effluent to form at least a lubricant boiling range product.2. The method of claim 1 , wherein the conversion catalyst comprises a surface area of at least 500 m/g claim 1 , or wherein the conversion catalyst comprises an Alpha value of 10 or less claim 1 , or wherein the conversion catalyst comprises an effective pore size of at least 12 Angstroms claim 1 , or a combination thereof.3. The method of claim 1 , ...

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19-04-2018 дата публикации

COMPOSITION OF ISOALKANE ALKYLATE BASE OIL

Номер: US20180105762A1
Автор: Hommeltoft Sven Ivar
Принадлежит:

An isoalkane alkylate base oil consisting predominantly of long carbon chain molecules having a straight chain of no less than 12 carbons and having at least one branch towards the middle of the straight chain, and characterized by: 1. An isoalkane alkylate base oil that is essentially free of olefins and aromatics and consists predominantly of long carbon chain molecules having a straight chain of no less than 12 carbon atoms and having at least one branch towards the middle of the straight chain , and characterized by:a) the isoalkane alkylate base oil contains less than 10 wt % n-alkanes, less than 0.1 wt % olefinic hydrocarbons, and less than 0.1 wt % aromatic hydrocarbons;b) the at least one branch is a branched alkyl group containing 4 or more carbon atoms; andc) the long carbon chain molecules have two terminal linear unbranched alkyl groups each containing at least 4 carbons.2. An isoalkane alkylate base oil , characterized by having a total integral of the C NMR spectrum wherein more than 25% of the total integral of the C NMR spectrum falls within C NMR resonances in ranges for linear long chain alkyl groups given by: C1(13.9-14.2 ppm) , C2(22.6-22.8 ppm) , C3(31.9-32.05 ppm) , C4(29.35-29.45 ppm) , and C5+(29.6-29.8 ppm).3. The isoalkane alkylate base oil of claim 2 , wherein more than 50% of the total integral of the C NMR spectrum falls within the C NMR resonances in the ranges for linear long chain alkyl groups.4. The isoalkane alkylate base oil of claim 2 , wherein the isoalkane alkylate base oil has a viscosity index greater than 90 and the total integral of the C NMR spectrum falling with the C NMR resonances in the ranges for linear long chain alkyl groups is from 26% to 80%.5. The isoalkane alkylate base oil of or claim 2 , wherein the isoalkane alkylate base oil has a viscosity index from 91 to 200.6. The isoalkane alkylate base oil of or claim 2 , wherein the isoalkane alkylate base oil has a bromine index less than 2000 mg Br/100 g.7. The ...

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29-04-2021 дата публикации

Lubricant composition

Номер: US20210122991A1
Принадлежит: Idemitsu Kosan Co Ltd

Provided are: a lubricating oil composition that contains a base oil (A) containing an alkylnaphthalene (A1) and an ester compound (A2), wherein the content ratio of the component (A1) to the component (A2) [(A1)/(A2)] is 15/85 to 85/15 as a ratio by mass, and a tenter device using the lubricating oil composition. The lubricating oil composition has a small evaporation loss, has a suppressed amount of evaporation, maintains good fluidity and hardly causes adherence of residue even in long-term use in high-temperature environments.

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02-04-2020 дата публикации

LOW VISCOSITY LUBRICATING OILS WITH IMPROVED OXIDATIVE STABILITY AND TRACTION PERFORMANCE

Номер: US20200102519A1
Принадлежит:

Provided is lubricating oil composition including from 10 to 90 wt % of a base stock comprising a C28-C32 hydrocarbon fraction (“dimers”) and optionally a C42-C48 hydrocarbon fraction (“trimers”) produced by oligomerization of a linear C14 mono-olefin, a linear C16 mono-olefin, or a mixture thereof, in the presence of a Lewis acid catalyst, and the remainder of the composition including one or more lubricating oil additives. The lubricating oil composition provides an oxidative stability of greater than 100 hours (time to 200% KV@40 deg. C. increase) and a mini traction machine (MTM) average traction coefficient at 100 deg. C. of less than 0.0081. 1. A lubricating oil composition comprisingfrom 10 to 90 wt % of a base stock comprising a C28-C32 hydrocarbon fraction (“dimers”) and optionally a C42-C48 hydrocarbon fraction (“trimers”) produced by oligomerization of a linear C14 mono-olefin, a linear C16 mono-olefin, or a mixture thereof, in the presence of a Lewis acid catalyst, andthe remainder of the composition comprising one or more lubricating oil additives, wherein the lubricating oil composition provides an oxidative stability of greater than 100 hours (time to 200% KV@40 deg. C. increase) and a mini traction machine (MTM) average traction coefficient at 100 deg. C. of less than 0.0081.2. The composition of claim 1 , wherein the base stock exhibits a mole percentage of epsilon-carbons as determined by C NMR of no less than 20 mol % claim 1 , based on the total moles of the carbon atoms therein.3. The composition of claim 1 , wherein the dimers are at a concentration in the range from 80 to 100 wt % claim 1 , and the trimers are at a concentration in the range from 0 to 20 wt % claim 1 , based on the total weight of the base stock.4. The composition of claim 1 , wherein the total concentration of the dimers and the trimers combined is at least 95 wt % claim 1 , based on the total weight of the base stock.5. The composition of claim 1 , wherein the molecules of ...

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26-04-2018 дата публикации

LUBRICATING OIL COMPOSITION FOR GEAR OIL

Номер: US20180112150A1
Автор: Komatsubara Hitoshi
Принадлежит: JXTG NIPPON OIL & ENERGY CORPORATION

Disclosed is a lubricating oil composition for gear oil, comprising a lubricating base oil having a kinematic viscosity at 40° C. of 140 to 350 mm/s, a copolymer of an α-olefin and an ester monomer having a polymerizable unsaturated bond, a performance additive containing phosphorus and sulfur, and a poly(meth)acrylate pour-point depressant. 1. A lubricating oil composition for gear oil , comprising:{'sup': '2', 'a lubricating base oil having a kinematic viscosity at 40° C. of 140 to 350 mm/s;'}a copolymer of an α-olefin and an ester monomer having a polymerizable unsaturated bond;a performance additive comprising phosphorus and sulfur; anda poly(meth)acrylate pour-point depressant.2. The lubricating oil composition for gear oil according to claim 1 , wherein the lubricating base oil comprises a first lubricating base oil component having a kinematic viscosity at 40° C. of 200 to 600 mm/s and a sulfur content of 0.3 to 0.9 mass % claim 1 , and a second lubricating base oil component having a kinematic viscosity at 40° C. of less than 200 mm/s; andthe content of the first lubricating base oil component is 30 to 80 mass %, and the content of the second lubricating base oil component is 70 to 20 mass %, based on the total amount of the base oil.3. The lubricating oil composition for gear oil according to claim 1 , wherein the content of the copolymer is 0.5 mass % or more based on the total amount of the composition.4. The lubricating oil composition for gear oil according to claim 1 , wherein the content of the performance additive satisfies requirements represented by the following formulas (1) and (2):{'br': None, 'i': 'C', 'sub': 'P', '≥0.05\u2003\u2003(1)'}{'br': None, 'i': C', '/C, 'sub': S', 'P, '7≤()≤20\u2003\u2003(2)'}{'sub': P', 'S', 'P', 'S, 'wherein Crepresents the content of phosphorus contained in the performance additive, Crepresents the content of sulfur contained in the performance additive, and Cand Ceach represent an amount (mass %) in terms of ...

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26-04-2018 дата публикации

UNIQUE OIL AS A SERVICE EVENT

Номер: US20180112566A1
Принадлежит: Cummins Inc.

A method of performing a cleanup service on an internal combustion engine. The method involves draining used fleet oil from the engine, filling the engine with cleanup oil, draining the cleanup oil after an operation interval, and filling the engine with fresh fleet oil. The method can be performed as a remedial measure for an engine already exhibiting high oil consumption, or as a preventative measure on a healthy engine. 1. A method of performing a cleanup service on an internal combustion engine , the method comprising:draining used fleet oil from the internal combustion engine;filling the internal combustion engine with a first cleanup oil;draining the first cleanup oil after an operation interval; andfilling the internal combustion engine with fresh fleet oil.2. The method of claim 1 , further comprising claim 1 , before filling the internal combustion engine with the first cleanup oil claim 1 , flushing the internal combustion engine with a second cleanup oil.3. The method of claim 2 , wherein the first cleanup oil or the second cleanup oil comprises an ester-based oil claim 2 , an alkylated naphthalene and a polyalphaolefin base oil.4. The method of claim 2 , wherein the first cleanup oil has a same formulation as the second cleanup oil.5. The method of claim 2 , wherein the first cleanup oil has a different formulation than the second cleanup oil.6. The method of claim 2 , wherein the first cleanup oil or the second cleanup oil comprises a non-petroleum-based oil.7. The method of claim 1 , wherein the operation interval is at least 20 claim 1 ,000 miles.8. The method of claim 1 , wherein the first cleanup oil dissolves at least one of sludge claim 1 , varnish claim 1 , and hard carbon in the internal combustion engine and wherein draining the first cleanup oil after an operation interval includes draining the dissolved at least one of sludge claim 1 , varnish claim 1 , and hard carbon from the internal combustion engine.9. The method of claim 8 , wherein the ...

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13-05-2021 дата публикации

PRODUCTION OF RENEWABLE BASE OIL AND DIESEL BY PRE-FRACTIONATION OF FATTY ACIDS

Номер: US20210139786A1
Автор: NURMI Pekka, Toppinen Sami
Принадлежит: Neste Oyj

Methods are disclosed for producing renewable base oil and a diesel oil from low-value biological oils. Low-value biological oils containing free fatty acids and fatty acid esters can be processed into a renewable base oil and a renewable diesel oil by first separating at least part of the saturated free fatty acids from the feedstock and then processing separately this saturated free acid feed in a ketonisation reaction followed by hydrodeoxygenation and hydroisomerisation reactions to yield a renewable base oil stream. The remaining free fatty acid depleted feed may be processed in a separate hydrodeoxygenation and hydroisomerisation step to yield a renewable diesel stream. 1. A method for producing a renewable base oil from a feedstock of biological origin , the method comprising:a) providing a feedstock, the feedstock containing at least 5 wt % of a mixture of saturated free fatty acids and at most a remainder of one or more compounds selected from the list consisting of: unsaturated free fatty acids, fatty acid esters, fatty amides, fatty alcohols, as well as fatty acid glycerols such as mono-glycerides, di-glycerides and tri-glycerides of fatty acids; {'sub': 'n', 'a saturated fatty acid feed containing at least 90 wt % saturated Cfree fatty acids, no more than 3 wt % unsaturated free fatty acids, where n is selected from one of the integer values; 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24; and one or more saturated fatty acid depleted feed(s);'}, 'b) separating the feedstock into at leastc) subjecting the saturated fatty acid feed to ketonisation reaction conditions where two fatty acids react to yield a ketone stream, the ketone stream including as a major part saturated ketones having a carbon number of 2n−1; andd) subjecting the ketone stream to both hydrodeoxygenation reaction conditions and to hydroisomerisation reaction conditions, simultaneously or in sequence, to yield a deoxygenated and isomerised base oil stream containing the ...

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05-05-2016 дата публикации

Low transition temperature mixtures or deep eutectic solvents and processes for preparation thereof

Номер: US20160122676A1
Принадлежит: ExxonMobil Research and Engineering Co

A low transition temperature mixture (LTTM) or deep eutectic solvent (DES) useful as a lubricating oil base stock and lubricating oil including a eutectic mixture of at least a first component and at least a second component. The at least first component comprises a hydrogen bond acceptor and the at least second component comprises a hydrogen bond donor. The eutectic mixture includes an equilibrium phase between the at least first component and the at least second component. The equilibrium phase does not exhibit physical characteristics of the at least first component in an unmixed state and the at least second component in an unmixed state. The at least first component and the at least second component form an intermolecular interaction between each other sufficient to prevent crystallization of the at least first component and the at least second component in the eutectic mixture. The eutectic mixture is a liquid at 20° C.

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03-05-2018 дата публикации

PROCESS FOR THE MANUFACTURE OF BASE OIL

Номер: US20180119033A1
Принадлежит:

Processes are provided for producing hydrocarbon base oils from alcohols, including by converting one or more alcohols into linear alpha olefins, and then forming branched oligomers with one or more olefin feedstock(s) which are subsequently hydrogenated and fractionated. A process for the preparation of a mixture of branched saturated hydrocarbons can include (a) forming an oligomerization reaction mixture having an oligomerization catalyst system and an olefin monomer mixture, wherein the olefin monomer mixture has an average carbon number in the range of 9.5 to 13, and at least 10% of the olefin monomers in the olefin monomer mixture have a carbon number difference of at least four carbons, (b) oligomerizing the olefin monomers in the oligomerization reaction mixture to produce an oligomer product, (c) separating unreacted olefin monomer from the oligomer product to produce a purified oligomer product, (d) hydrogenating the purified oligomer product, and (e) distilling the hydrogenated oligomer product. 1. A process for the preparation of a mixture of branched saturated hydrocarbons , the process comprising:(a) forming an oligomerization reaction mixture comprising an oligomerization catalyst system and an olefin monomer mixture, wherein the olefin monomer mixture has an average carbon number in the range of 9.5 to 13, and at least 10% of the olefin monomers in the olefin monomer mixture have a carbon number difference of at least four carbons,(b) oligomerizing the olefin monomers in the oligomerization reaction mixture to produce an oligomer product comprising dimers, trimers, and higher oligomers,(c) separating unreacted olefin monomer from the oligomer product to produce a purified oligomer product,(d) hydrogenating the purified oligomer product to form a mixture of branched saturated hydrocarbons having a Bromine Index below 1000 as determined in accordance with ASTM D2710-09, and(e) distilling the hydrogenated oligomer product.2. The process of wherein the ...

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25-08-2022 дата публикации

LOW POUR POINT DERIVATIVES OF DIMER FATTY ACIDS

Номер: US20220267694A1
Автор: PACKET Dirk
Принадлежит:

The present invention relates to specific derivatives of dimer fatty acids, compositions comprising them and a method to reduce pour points. 1. Derivatives of dimer fatty acids obtainable by the process comprising the following steps:i) dimerization of fatty acid(s) feedstock, whose oleic acid content is more than 80 wt % based on weight of fatty acid(s) contained in the feedstock, by heating in the presence of a clay catalyst;ii) separating monomer fatty acids from the dimer fatty acids formed during step i); andiii) derivatizing dimer fatty acids to produce dimer fatty esters, amides, alcohols or alkanes; wherein the derivatization step is an esterification, an amidification, a reduction or a decarboxylation reaction of the carboxylic functions of dimer fatty acids.2. The derivatives of dimer fatty acids of claim 1 , wherein the temperature of dimerization is comprised between 200 and 250° C.3. The derivatives of dimer fatty acids of claim 1 , wherein the clay catalyst is bentonite.4. The derivatives of dimer fatty acids of claim 1 , wherein the fatty acid(s) feedstock is fatty acids obtained from high oleic sunflower oil.5. A base oil comprising the derivatives of dimer fatty acids of .6. (canceled)7. A composition comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'derivatives of dimer fatty acids of ; and'}an additive used in the field of lubricants.8. A lubricant composition comprising the composition of .9. The composition of claim 8 , wherein the lubricant composition is an engine oil claim 8 , an hydraulic fluid claim 8 , a drilling fluid claim 8 , a gear oil or a compressor oil.10. A method to reduce the pour point of derivatives of dimer fatty acids by carrying out an esterification claim 8 , an amidification claim 8 , a reduction or a decarboxylation reaction of the carboxylic functions of dimer fatty acids obtained by the process comprising the following steps:i) dimerizing fatty acid(s) feedstock, whose oleic acid content is more than 80 wt % ...

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25-04-2019 дата публикации

LUBRICANT FOR TWO-STROKE CYCLE ENGINES

Номер: US20190119594A1
Принадлежит:

A lubricant composition adapted for a two stroke cycle engine comprises 5 wt. % to 35 wt. % of an oil of lubricating viscosity, greater than 50 wt. % to 90 wt. % of a hydrocarbon solvent and at least one additive selected from (i) a dispersant and (ii) a friction modifier. 1. A lubricating composition comprising:(a) 5 to 35 wt. % of an oil of lubricating viscosity;(b) 50 to 90 wt. of a hydrocarbon solvent; and(c) at least one additive selected from (i) a dispersant and (ii) a friction modifier.2. The lubricating composition of claim 1 , wherein the composition comprises a friction modifier and a dispersant.3. The lubricating composition of claim 2 , comprising from about 0.2 to 10 wt. % claim 2 , of the dispersant.4. The lubricating composition of claim 2 , wherein the dispersant is selected from a phenolic-type dispersant claim 2 , a Mannich-type dispersant or a succinimide-type dispersant or mixtures thereof.5. The lubricating composition of claim 2 , wherein the dispersant comprises:(a) a Mannich-type dispersant; and(b) a succinimide-type dispersant.6. The lubricating composition of claim 2 , wherein the dispersant further comprises a phenolic-type dispersant.7. The lubricating composition of claim 2 , wherein the dispersant is ashless.8. The lubricating composition of claim 2 , wherein the weight percent ratio of dispersant to oil of lubricating viscosity is 1:6 to 1:2.5.9. The lubricating composition of claim 1 , comprising from 0.1 to 5 wt. % of a friction modifier.10. The lubricating composition of claim 1 , wherein the friction modifier comprises at least one of fatty phosphites claim 1 , fatty acid amides claim 1 , fatty epoxides claim 1 , borated fatty epoxides claim 1 , fatty amines claim 1 , glycerol esters claim 1 , borated glycerol esters claim 1 , alkoxylated fatty amines claim 1 , borated alkoxylated fatty amines claim 1 , metal salts of fatty acids claim 1 , sulfurized olefins claim 1 , fatty imidazolines claim 1 , condensation products of ...

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10-05-2018 дата публикации

COMPOSITION FOR USE IN OILS

Номер: US20180127677A1
Принадлежит: Phillips 66 Company

A composition comprising a sheared antifoam solution/mixture with a mean particle size from about 0.01 microns to about 0.5 microns and a maximum particle size of less than about 1 micron. In this composition the sheared antifoam solution/mixture comprises antifoam solution/mixture comprising an antifoam and a base stock. 1. A composition comprising:a sheared antifoam mixture with a mean particle size from about 0.01 microns to about 0.5 microns and a maximum particle size of less than about 1 micron,wherein the sheared antifoam mixture comprises antifoam mixture comprising an antifoam and a base stock.2. The composition of claim 1 , wherein the antifoam is selected from the group consisting of: organo-modified siloxane claim 1 , silicone claim 1 , flurosilicone claim 1 , polyacrylate and combinations thereof.3. The composition of claim 1 , wherein the base stock is selected from the group consisting of: esters claim 1 , polyalkylene glycols claim 1 , alkylated naphthalenes claim 1 , polyalphaolefins claim 1 , petroleum mineral oils based on aromatic claim 1 , naphthenic or paraffinic crude oils claim 1 , or combinations thereof.4. The composition of claim 1 , wherein the antifoam mixture does not contain a solubilizing agent.5. The composition of claim 1 , wherein the amount of antifoam ranges from about 20 wt % to about 80 wt % of the antifoam mixture.6. The composition of claim 1 , wherein the amount of antifoam ranges from about 40 wt % to about 60 wt % of the antifoam mixture.7. The composition of claim 1 , wherein the amount of base stock ranges from about 20 wt % to about 80 wt % of the antifoam mixture.8. The composition of claim 1 , wherein the amount of base stock ranges from about 30 wt % to about 70 wt % of the antifoam mixture.9. The composition of claim 1 , wherein the amount of base stock ranges from about 40 wt % to about 60 wt % of the antifoam mixture.10. The composition of claim 1 , wherein the antifoam mixture is sheared with a shear device to ...

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31-07-2014 дата публикации

High Temperature Grease

Номер: US20140213492A1
Принадлежит:

The invention relates to a high-temperature grease which is used inter alia in corrugated cardboard plants and comprises exclusively fluorine-free base oil. 1. A high-temperature grease comprising(A) 20 to 88 weight % of fluorine-free base oil,(B) 45 to 10 weight % of thickener(s),(C) 15 to 2 weight % of additives, and(D) 20 to 0 weight % of a further fluorine-free oil component.2. The high-temperature grease as claimed in claim 1 , for which component (A) is selected from the group consisting of alkylated naphthalene claim 1 , dipenta-erythritol esters claim 1 , or mixtures thereof.3. The high-temperature grease as claimed in claim 1 , for which component (B) is selected from the group consisting of PTFE claim 1 , metal soaps claim 1 , more particularly lithium complex soaps claim 1 , aluminum complex soaps claim 1 , sodium complex soaps claim 1 , boron nitride claim 1 , Aerosol claim 1 , silicates claim 1 , such as bentonite claim 1 , organic high-temperature polymers claim 1 , more particularly polyimides and polyamidimides claim 1 , which are used individually or in combination.4. The high-temperature grease as claimed in claim 1 , for which claim 1 , as component (C) claim 1 , additives to counter wear claim 1 , oxidation claim 1 , corrosion and also additives to reduce the friction or improve the high-pressure properties are used.5. The high-temperature grease as claimed in claim 4 , for which claim 4 , as additives claim 4 , antioxidants are used which comprise sulfur and/or nitrogen and/or phosphorus in the molecule claim 4 , which are used individually or in combination and are selected from the group consisting of aromatic aminic antioxidants claim 4 , more particularly alkylated phenyl-alpha-naphthylamine claim 4 , dialkyldiphenylamine claim 4 , aralkylated diphenylamines claim 4 , sterically hindered phenols claim 4 , more particularly butylated hydroxytoluene (BHT) claim 4 , phenolic antioxidants having thioether groups claim 4 , Zn or Mo or W dialkyl- ...

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02-05-2019 дата публикации

TOP OF RAIL APPLICATOR

Номер: US20190126953A1
Принадлежит:

A top of rail (TOR) applicator has a bar positioned in a housing and an exit orifice on the upper portion of the bar for delivering a friction control composition to the crown of a railhead. The upper portion of the bar slopes away from the friction control composition exit orifices. The bar may be composed of an elastomer such as polyurethane. Passageway extend from an inlet or entry orifice to the exit orifices. The friction reduction composition is pumped into the entry orifice, through the passageways to the exit orifices and then onto the crown of the railhead. The friction reduction composition may be thixotropic. 2. The applicator of claim 1 , wherein the slope is from about 5 to about 15 degrees off the horizontal plane defined by the railhead.3. The applicator of claim 2 , wherein the slope is from about 8 to about 10 degrees off the horizontal plane defined by the railhead.4. The applicator of claim 1 , further comprising a platform onto which the bottom of the housing rests.5. The applicator of claim 1 , further comprising a friction control composition entry orifice located on the lower portion of the slope.6. The applicator of claim 5 , further comprising a passageway from the friction control composition entry orifice to the friction control composition exit orifice for transporting the friction control composition.7. An applicator for delivering a friction control composition to a railhead claim 5 , the applicator comprising:(a) a housing;(b) an elastomeric bar positioned in the housing;(c) at least two friction control composition exit orifices on the upper surface of the elastomeric bar, wherein the upper surface of the elastomeric bar, when the applicator is affixed to the railhead, slopes downward away from the railhead;(d) a friction control composition entry orifice on the lower portion of the slope; and(e) a passageway from the friction control composition entry orifice to the friction control composition exit orifices.8. The applicator of ...

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01-09-2022 дата публикации

GREASE COMPOSITION FOR CONSTANT VELOCITY JOINTS

Номер: US20220275302A1
Принадлежит:

A grease composition is intended primarily for use in constant velocity joints (CV joints), especially ball joints and/or tripod joints, which are used in the driveline of motor vehicles. The grease composition for use in constant velocity joints comprises at least one base oil, at least one thickener, zinc sulfide, as well as molybdenum disulfide and/or tungsten disulfide. Further, a constant velocity joint comprises the grease composition. 116-. (canceled)17. A grease composition for use in constant velocity joints comprisinga) at least one base oil;b) at least one thickener;c) zinc sulfide in an amount between approximately 0.1 wt-% and approximately 2.0 wt-% of a total amount of the grease composition; andd) at least one of molybdenum disulfide and tungsten disulfide in an amount between approximately 0.5 wt-% and approximately 5.0 wt-% of the total amount of the grease composition;wherein the ratio between the amount of the at least one of molybdenum disulfide and tungsten disulfide to the amount of zinc sulfide is in a range between approximately 3:1 to approximately 10:1.18. The grease composition of claim 17 , wherein a total amount of zinc sulfide and the at least one of molybdenum disulfide and tungsten disulfide is less than or equal to approximately 7 wt-% of the total amount of the grease composition.19. The grease composition of claim 17 , further comprising at least one organic sulphur-additive in an amount between approximately 0.2 wt-% and approximately 1.0 wt-% of the total amount of the grease composition.20. The grease composition of claim 19 , characterized in that the at least one organic sulphur-additive comprises sulphur in an amount of at least approximately 10 wt-% of the amount of the organic sulphur-additive.21. The grease composition of claim 17 , further comprising at least one organic phosphor-additive in an amount between approximately 0.2 wt-% and approximately 1.0 wt-% of the total amount of the grease composition.22. The grease ...

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01-09-2022 дата публикации

BASE OILS AND METHODS OF MAKING THE SAME

Номер: US20220275306A1
Принадлежит:

A process for the preparation of saturated hydrocarbon base oils is provided, comprising oligomerization of a feed mixture that has an average carbon number in the range of 14 to 18 to produce an oligomer product comprising dimers, trimers, and higher oligomers, where the dimer has a branching proximity (BP) of 20 or greater, isomerization of at least the dimer portion, and hydrogenation of the isomerized product. The dimer portion is separated from the oligomer product, and a saturated hydrocarbon base oil is obtained comprising greater than 90% dimers having an average carbon number in the range of from 29 to 36, and the dimer portion having a weight average molecular weight in the range of 422 to 510, where the dimers have an average Branching Index (BI) in a range of 22 to 26 and an average paraffin branching proximity (BP) in a range of from 18 to 26. 1. A process for the preparation of a saturated hydrocarbon base oil , comprising:forming an oligomerization reaction mixture comprising an oligomerization catalyst system and an olefin monomer feed mixture, wherein the olefin monomer feed mixture has an average carbon number in the range of 14 to 18;oligomerizing the olefin monomer feed mixture in the reaction mixture to produce an oligomer product comprising dimers, trimers, and higher oligomers,isomerizing at least the dimer portion of the oligomer product in the presence of an acid catalyst to form a mixture of branched hydrocarbons;{'sub': '2', 'hydrogenating the isomerized branched hydrocarbons, to a Bromine Index below 1000 mg Br/100 g as determined in accordance with ASTM D2710-09; and'}separating the dimer portion of the hydrogenated oligomer product, whereby a saturated hydrocarbon base oil is obtained comprising greater than 90 wt % dimers having an average carbon number in the range of from 29 to 36, the dimer portion having a weight average molecular weight in the range of from 422 to 510,{'sub': '2', 'wherein the dimers of the oligomer product, in a ...

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02-05-2019 дата публикации

BIO-BASED SYNTHETIC FLUIDS

Номер: US20190127647A1
Принадлежит:

A method is provided involving altering the viscosity of bio-derived paraffins to produce a paraffinic fluid, where the altering step includes chlorinating the bio-derived paraffins; the bio-derived paraffins include a hydrodeoxygenated product produced by hydrodeoxygenating a bio-based feed where the bio-based feed includes bio-derived fatty acids, fatty acid esters, or a combination thereof; the bio-derived paraffins include n-paraffins; and the n-paraffins have a biodegradability of at least 40% after about 23 days of exposure to microorganisms. Also provided are methods of protecting and/or cleaning a substance by applying the paraffinic fluid. 1. A method comprising altering the viscosity of bio-derived paraffms to produce a paraffmic fluid , whereinthe altering step comprises chlorinating the bio-derived paraffms to produce a chlorinated product, where the chlorinated product comprises haloalkanes and has a kinematic viscosity of greater than about 10 cSt at 40° C.;the paraffmic fluid comprises the chlorinated product;the bio-derived paraffms comprise a hydrodeoxygenated product produced by hydrodeoxygenating a bio-based feed where the bio-based feed comprises bio-derived fatty acids, fatty acid esters, or a combination thereof; and 'have a biodegradability of at least about 40% after about 23 days of exposure to microorganisms.', 'the bio-derived paraffms comprise n-paraffms where the n-paraffms have a kinematic viscosity of less than about 10 cSt at 40° C.; and'}2. The method of claim 1 , wherein chlorinating the bio-derived paraffms comprises contacting the bio-derived paraffms with chlorine gas at a temperature between about 60° C. and about 150° C. to produce the chlorinated product.3. The method of claim 2 , wherein the chlorinated product is about 30 wt % to about 70 wt % chlorine.4. The method of claim 2 , wherein the chlorinated product has less than about 1 wt % aromatics.5. The method of claim 2 , wherein the chlorinated product is free of benzene.6 ...

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02-05-2019 дата публикации

LUBRICATING OIL COMPOSITIONS WITH ENGINE WEAR PROTECTION

Номер: US20190127654A1
Принадлежит:

A method for improving wear control of a steel surface lubricated with a lubricating oil through the generation of thick tribofilms. The method includes: (i) using as the lubricating oil a formulated oil, the formulated oil having a composition comprising at least one lubricating oil base stock as a major component; and at least one lubricating oil additive, as a minor component; and (ii) forming a tribofilm on the steel surface. In time-step tribofilm formation measurements of the lubricating oil by a mini-traction machine (MTM) at constant slide-to-roll ratio (SRR), the saturation traction coefficient (f), which correlates to tribofilm thickness on the steel surface, is greater than about 0.11. In the method of this disclosure, elongation of timing chain due to wear of chain link pins is less than about 0.07%, as determined by Ford Chain Wear (FCW) test conducted in accordance with ILSAC GF-6 specification. The lubricating oils are useful in internal combustion engines. 1. A method for improving wear control of a steel surface lubricated with a lubricating oil , said method comprising: (i) using as the lubricating oil a formulated oil , said formulated oil having a composition comprising at least one lubricating oil base stock as a major component; and at least one lubricating oil additive , as a minor component; and (ii) forming a tribofilm on the steel surface; wherein , in time-step tribofilm formation measurements of the lubricating oil by a mini-traction machine (MTM) at constant slide-to-roll ratio (SRR) , the saturation traction coefficient (f) , which correlates to tribofilm thickness on the steel surface , is greater than about 0.11.2. The method of wherein elongation of timing chain due to wear of chain link pins is less than about 0.07% claim 1 , as determined by Ford Chain Wear (FCW) test in accordance with ILSAC GF-6 specification.3. The method of wherein the lubrication regime at the steel surface comprises boundary- and mixed-layer lubrication ...

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02-05-2019 дата публикации

Lubricating oil compositions having improved cleanliness and wear performance

Номер: US20190127655A1
Принадлежит: ExxonMobil Research and Engineering Co

A method for improving wear control, while maintaining or improving deposit control and cleanliness, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and specific combinations of low soap detergents, dispersants, and/or mixtures thereof, as a minor component. The low soap detergents include alkaline earth metal salicylates, alkaline earth metal sulfonates, or mixtures thereof, all having the same or different total base number (TBN). The total amount of soap delivered by the low soap detergent is less than 0.60 weight percent of the lubricating oil. The dispersants include borated and/or non-borated polyisobutylene succinimide (PIMA) having a basic nitrogen content of 1% or greater. The lubricating oils are useful in internal combustion engines.

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