21-03-2019 дата публикации
Номер: US20190084922A1
The present invention relates to novel quaternized ammonium salts of hydrocarbyl epoxides, to the preparation thereof and to the use thereof as a fuel additive and lubricant additive, such as, more particularly, as a detergent additive; for reducing or preventing deposits in the injection systems of direct injection diesel engines, especially in common rail injection systems, for reducing the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimizing power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operation of DISI engines. 1. A reaction product comprising a quaternized nitrogen compound , obtained by a process comprising:{'sub': 'n', 'reacting i) at least one hydrocarbyl epoxide, which is a polyalkylene epoxide that is obtained by epoxidizing a polyalkylene, having a number-average molecular weight (M) of 85 to 20,000;'} {'br': None, 'sub': a', 'b', 'c, 'RRRN \u2003\u2003(II)'}, 'with ii) at least one tertiary amine of formula II{'sub': a', 'b', 'c', 'a', 'b', 'c, 'wherein R, Rand Rare each independently a straight-chain or branched, saturated or unsaturated, optionally substituted hydrocarbyl radical, or two of R, Rand Rtogether with the nitrogen atom to which they are bonded, form an optionally substituted 5- to 7-membered, saturated or unsaturated, nonaromatic or aromatic heterocyclic ring which may optionally bear at least one further ring heteroatom selected from O, S or N;'} {'br': None, 'sup': +', '−, 'HA\u2003\u2003(III)'}, 'in the presence of iii) at least one acid of formula III{'sup': '−', 'sub': 1', '4, 'in which A is the anion of at least one of an inorganic acid and an organic acid selected from the group consisting of C-Cmonocarboxylic acids, aromatic carboxylic acids, caproic acid, enanthic acid, caprylic acid, pelargonic acid, capric acid, undecanoic acid, ...
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