УСТАНОВКА УТИЛИЗАЦИИ ЛЮМИНЕСЦЕНТНЫХ ЛАМП, СОДЕРЖАЩИХ РТУТЬ

1. Установка утилизации люминесцентных ламп, содержащих ртуть, содержащая узел разрушения и утилизации, узел сепарации очищенных отходов с решеткой для отделения цоколей ламп от стеклобоя и вибратор, отличающаяся тем, что узел разрушения и утилизации выполнен в виде цилиндра большого диаметра и двух соосных с ним цилиндров меньшего диаметра, заглушенных с торцов, опирающихся на четыре катка с электроприводом, причем внутри цилиндра большого диаметра смонтирована рубашка-термостат и в боковой части цилиндра большого диаметра и рубашки-термостата вмонтирован герметически закрываемый люк, узел сепарации очищенных отходов выполнен в виде бункера с расширением в верхней его части, сопряженного нижней частью с вертикально расположенной под ним шахтой с установленными внутри в верхней части крупной решеткой и в нижней части мелкой решеткой, снабженными поворотными механизмами, а вибратор установлен в средней части шахты на наружной стороне. 2. Установка утилизации по п.1, отличающаяся тем, что боковые и торцевые части цилиндра большого диаметра с внутренней стороны покрыты слоем теплоизолятора. 3. Установка утилизации по п.1, отличающаяся тем, что в цилиндрической части рубашки-термостата имеется отверстие и к нему для вакуумной разгрузки паров ртути присоединена трубка, которая через последовательно соединенные вентиль, штуцер и гибкий трубопровод подключена к вакуумному насосу и охлаждаемой ловушке. 4. Установка утилизации по пп.1 и 2, отличающаяся тем, что для более глубокого извлечения ртути гибкий трубопровод подключен к промывочному устройству. 5. Установка утилизации по п.1, отличающаяся тем, что в цилиндре большого диаметра выполнено отверстие, к которому присоединена выходная трубка, через выходной вентиль, выходной штуцер и выходной гибкий трубопровод соединенная со входным патрубком байпасной емкости, подключенной, в свою очередь, ко входу теплогенератора, а к отверстию в диаметрально противоположной части цилиндра большого диаметра присоединен входной патрубок, ...

УСТРОЙСТВО ДЛЯ УТИЛИЗАЦИИ РТУТНЫХ ЛАМП

Устройство для утилизации ртутных ламп, содержащее вакуумированную камеру с электронагревателем, охлаждаемую ловушку, установленную перед форвакуумным насосом, отличающееся тем, что оно дополнительно снабжено лазером, а на выходе лазерного излучения расположена фокусирующая линза с возможностью вращения в своей плоскости, установленная эксцентрично во внутренней обойме подшипника, наружная обойма которого жестко установлена на подвижной подставке, при этом на боковой поверхности вакуумированной камеры выполнено оптическое окно, диаметр которого равен разности внутреннего диаметра упомянутой камеры и диаметра утилизируемой ртутной лампы. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C22B 43/00 (13) 126 706 U1 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ 2011141286/02, 11.10.2011 (24) Дата начала отсчета срока действия патента: 11.10.2011 (45) Опубликовано: 10.04.2013 Бюл. № 10 1 2 6 7 0 6 R U Формула полезной модели Устройство для утилизации ртутных ламп, содержащее вакуумированную камеру с электронагревателем, охлаждаемую ловушку, установленную перед форвакуумным насосом, отличающееся тем, что оно дополнительно снабжено лазером, а на выходе лазерного излучения расположена фокусирующая линза с возможностью вращения в своей плоскости, установленная эксцентрично во внутренней обойме подшипника, наружная обойма которого жестко установлена на подвижной подставке, при этом на боковой поверхности вакуумированной камеры выполнено оптическое окно, диаметр которого равен разности внутреннего диаметра упомянутой камеры и диаметра утилизируемой ртутной лампы. Стр.: 1 U 1 U 1 (54) УСТРОЙСТВО ДЛЯ УТИЛИЗАЦИИ РТУТНЫХ ЛАМП 1 2 6 7 0 6 Адрес для переписки: 390013, г.Рязань, Первомайский пр-кт, 80/44, Рязанский институт бизнеса и управления, Н.А. Сесюнину (73) Патентообладатель(и): Негосударственное образовательное учреждение высшего профессионального образования "Рязанский институт бизнеса и управления" (RU) R U ...

КОНЦЕНТРАТОР ДЛЯ ИЗВЛЕЧЕНИЯ РТУТИ ИЗ ГРУНТОВ

Полезная модель относится к способу извлечения металлической ртути из ртутьсодержащих материалов, в частности технологических шламов, загрязненных грунтов, строительных отходов. Техническим результатом предлагаемой полезной модели является упрощение очистки отверстий для вывода ртути, упрощение ремонта, получение возможности калибровки отверстий. Технический результат достигается тем, что концентратор для извлечения ртути из грунтов, содержащий подвижный барабан с отверстиями, стационарный барабан центробежного концентратора, внутренняя поверхность которого изготовлена в виде двух прямых усеченных конусов с общим основанием, расположенным между торцевыми частями барабана, причем в области общего основания и наименьшей толщины барабана выполнено минимум одно отверстие для вывода ртути из стационарного барабана, характеризуется тем, что указанное отверстие выполнено в виде форсунки. Форсунка может выполняться в виде цилиндрической втулки с наружной резьбой и калиброванным отверстием, а в стационарном барабане выполнены соответствующие отверстия с внутренней резьбой. Технический результат - упрощение очистки отверстий для вывода ртути, упрощение ремонта, получение возможности калибровки отверстий достигается тем, что форсунки легко заменяются и ремонтируются в заводских условиях или заменяются при необходимости на новые. Полезная модель может с успехом применяться для сооружения мультироторных сепараторов для выделения металлической ртути из стройматериалов, грунтов и т.д. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 192 206 U1 (51) МПК C22B 43/00 (2006.01) B09C 1/00 (2006.01) B04B 3/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (52) СПК C09B 43/00 (2019.02); B09C 1/00 (2019.02); B04B 3/00 (2019.02) (21)(22) Заявка: 2019104198, 14.02.2019 (24) Дата начала отсчета срока действия патента: Дата регистрации: (73) Патентообладатель(и): Закрытое акционерное общество "ИТОМАК" (RU) 06.09.2019 (56) Список документов, ...

Method for removing mercury contamination from solid surfaces

A method of selecting a mercury-contaminated solid surface followed by heating a cleaning solution to a temperature less than 100° C. The cleaning solution can contain hydrocarbon oil and one or more organic sulfur compounds. Afterwards, the heated cleaning solution is contacted with the mercury-contaminated solid surface to remove the mercury contamination.

Ionic liquid solvents of perhalide type for metals and metal compounds

The present invention relates to a process for dissolving metals in perhalide containing ionic liquids, and to the extraction of metals from mineral ores; the remediation of materials contaminated with heavy, toxic or radioactive metals; and to the removal of heavy and toxic metals from hydrocarbon streams.

Lighting apparatus for capturing and stabilizing mercury

The present invention is a method and material for using a sorbent material to capture and stabilize mercury. The method for using sorbent material to capture and stabilize mercury contains the following steps. First, the sorbent material is provided. The sorbent material, in one embodiment, is nano-particles. In a preferred embodiment, the nano-particles are unstabilized nano-Se. Next, the sorbent material is exposed to mercury in an environment. As a result, the sorbent material captures and stabilizes mercury from the environment. In the preferred embodiment, the environment is an indoor space in which a fluorescent has broken.

Process for Recovering Precious Metals from Clay-Containing Ores

A solution for leaching metals from clay containing ore and a method of leaching ore is described. The solution comprises a cyanide; a wetting agent; and a clay stabilizing polymer. 126-. (canceled)27. A method for heap leaching of metals from clay containing ore comprising:forming a heap of ore on a leach bed; cyanide;', 'a wetting agent; and', 'a clay stabilizing polymer;, 'percolating a leach solution through said heap wherein said leach solution comprisesthereby forming a pregnant leach solution comprising said precious metal; andremoving said precious metal from said pregnant leach solution.28. The method for heap leaching of metals from clay containing ore of wherein said metal is selected from the group consisting of gold claim 27 , silver claim 27 , copper and uranium.29. The method for heap leaching of metals from clay containing ore of wherein said leach solution has a pH of at least 8 to no more than 11.30. The method for heap leaching of metals from clay containing ore of wherein said leach solution has a pH of at least 9.5 to no more than 10.5.31. The method for heap leaching of metals from clay containing ore of wherein said leach solution comprises at least 50 ppm cyanide to no more than 1000 ppm cyanide.32. The method for heap leaching of metals from clay containing ore of wherein said leach solution comprises at least 200 ppm cyanide to no more than 800 ppm cyanide.33. The method for heap leaching of metals from clay containing ore of wherein said clay stabilizing polymer is selected from the group consisting of polyalkylene oxide copolymer; propoxylated glycols; polyamine copolymer comprising dicyandiamide claim 27 , formaldehyde and ammonia; polyvinyl alcohol; partially hydrolyzed polyvinyl acetate; polyacrylamide; quaternary amines and particularly tetramethylammonium salts; carboxymethyl cellulose; methacrylate copolymers; hydroxyaldehydes; hydroxyketones; and copolymers of anionic or cationic monomers.34. The method for heap leaching of metals ...

MERCURY COLLECTION SYSTEM

A system for collecting mercury from feed material that can be tailings comprises: a water inlet for forming a slurry containing the tailings; at least one screen for separating tailings from the slurry to form a screened slurry; a rotatable collection chamber containing at least one plate, a drive for rotating the collection chamber for collecting mercury on the plate to provide a discharge material comprising water and treated tailings, the treated tailings containing less mercury than in the feed material.

MOLECULARLY IMPRINTED POLYMER BEADS FOR EXTRACTION OF LITHIUM, MERCURY, AND SCANDIUM

The present disclosure provides Molecularly Imprinted Polymer (MIP) technology for selectively sequestering one or more target molecules from chemical mixtures. Also disclosed herein are MIP beads and methods of making and using thereof. 1. A plurality of macroreticular polymer beads comprising a copolymer having a plurality of complexing cavities which selectively bind Au(SO) , wherein the copolymer is prepared from:(a) a cationic ligand monomer complexed to a non-metal surrogate ion selected from the group consisting of tetrathionate, pentathionate, hexathionate; hexadionate, heptyldionate, octyidionate; 1,4-phenylene diacetate; butane disulfonate, pentane disulfonate, and hexane disulfonate,(b) a non-ligand monomer, and(c) a crosslinking monomer;whereinthe charge of the copolymer in the complexing cavity is opposite the charge of the target metal ion.2. A plurality of macroreticular polymer beads comprising a copolymer having a plurality of complexing cavities which selectively bind scandium tricarbonate , wherein the copolymer is prepared from:(a) a cationic ligand monomer complexed to a tribasic salt of benzene-1,3,5-triyl-tricarboxylate,(b) a non-ligand monomer, and(c) a crosslinking monomer;wherein the charge of the copolymer in the complexing cavity is opposite the charge of the target metal ion.3. The macroreticular beads of claim 1 , wherein the cationic ligand monomer is a polymerizable cation selected from the group consisting of ammonium claim 1 , pyridinium claim 1 , pyrollidinium claim 1 , imidazolium claim 1 , guanidinium claim 1 , phosphonium and sulfonium.4. The macroreticular beads of claim 3 , wherein the cationic ligand monomer is a 4-vinylbenzyl ammonium.5. The macroreticular beads of claim 4 , wherein the ligand monomer is N-(4-vinylbenzyl)-N claim 4 ,N claim 4 ,N-tri-n-pentyl ammonium or N-(4-vinylbenzyl)-N-decyl-N claim 4 ,N-dimethylammonium.6. The macroreticular beads of claim 4 , wherein the ligand monomer is N-(4-vinylbenzyl)-N claim 4 ,N ...

METHODS OF RECOVERING RARE EARTH ELEMENTS FROM A MATERIAL

A method of recovering rare earth elements from a rare earth-containing material comprises contacting the rare earth-containing material with a solution formulated and configured to dissolve rare earth elements from the rare earth-containing material and form a solution including a plurality of rare earth elements dissolved therein. The method further includes exposing the solution including the plurality of rare earth elements dissolved therein to one of a liquefied gas or a supercritical fluid to isolate the rare earth elements from each other. Related methods of removing and purifying rare earth elements from materials and phosphor lamps are also disclosed. 1. A method of recovering rare earth elements from a rare earth-containing material , the method comprising:contacting the rare earth-containing material with a solution formulated and configured to dissolve rare earth elements from the rare earth-containing material and form a solution including a plurality of rare earth elements dissolved therein; andexposing the solution including the plurality of rare earth elements dissolved therein to one of a liquefied gas or a supercritical fluid to isolate the rare earth elements from each other.2. The method of claim 1 , further comprising:selecting the rare earth-containing material to comprise a phosphor powder; andprior to contacting the phosphor powder with the solution formulated and configured to dissolve rare earth elements from the rare earth-containing material, immersing a glass material including the phosphor powder attached to at least some surfaces thereof in an acoustic medium and sonicating the acoustic medium to remove the phosphor powder from the at least some surfaces.3. The method of claim 2 , further comprising claim 2 , prior to contacting the phosphor powder with the solution claim 2 , adding a metal complexing agent to the acoustic medium and removing mercury from the phosphor powder while sonicating the acoustic medium.4. The method of claim 2 ...

CATALYST MANUFACTURING METHOD

A method for producing a catalyst using an additive layer method includes: 1. A method for producing a catalyst using an additive layer method comprising:(i) forming a layer of a powdered catalyst or catalyst support material,(ii) binding or fusing the powder in said layer according to a predetermined pattern,(iii) repeating (i) and (ii) layer upon layer to form a shaped unit, and(iv) optionally applying a catalytic material to said shaped unit.2. A method according to wherein the powdered material is a catalyst powder.3. A method according to wherein the catalyst powder comprises a metal powder or a powdered metal compound.4. A method according to wherein the catalyst powder comprises one or more metals or metal compounds containing metals selected from the group consisting of Na claim 2 , K claim 2 , Mg claim 2 , Ca claim 2 , Ba claim 2 , Al claim 2 , Si claim 2 , Ti claim 2 , V claim 2 , Cr claim 2 , Mn claim 2 , Fe claim 2 , Co claim 2 , Ni claim 2 , Cu claim 2 , Zn claim 2 , Y claim 2 , Zr claim 2 , Nb claim 2 , Mo claim 2 , Ru claim 2 , Rh claim 2 , Pd claim 2 , Ag claim 2 , Sn claim 2 , Sb claim 2 , La claim 2 , Hf claim 2 , W claim 2 , Re claim 2 , Ir claim 2 , Pt claim 2 , Au claim 2 , Pb claim 2 , or Ce.5. A method according to wherein the catalyst powder comprises a precious metal catalyst powder claim 2 , comprising one or more of Pt claim 2 , Pd claim 2 , Ir claim 2 , Ru or Re.6. A method according to wherein the catalyst powder comprises a transition metal compound selected from a metal oxide claim 2 , metal hydroxide claim 2 , metal carbonate claim 2 , metal hydroxycarbonate or mixture thereof.7. A method according to wherein the transition metal oxide comprises a single or mixed metal oxide or a composition comprising two or more transition metal oxides.8. A method according to wherein the catalyst powder further comprises one or more inert materials.9. A method according to wherein the inert materials are selected from the group consisting of ...

RENEWABLE MERCURY MENISCUS ELECTRODE WITH MERCURY CIRCULATION SYSTEM AND CONTAMINANT REMOVAL

This disclosure provides a voltammetric measurement system predicated on a mercury electrode. To minimize mercury consumption and/or disposal, the disclosed system includes a recirculatory system and mechanisms for cleaning mercury that permit mercury to be reclaimed, purified and reused on a nearly indefinite basis. Optional embodiments provide a modular design including a specially designed measurement cell, and for an automated control system to facilitate these ends. 1. A voltammetric measurement system , comprising:electrodes to measure an electrochemical property of an aqueous solution, wherein one of the electrodes is to form a liquid mercury surface in contact with the aqueous solution;a recirculatory system comprising a trap to collect liquid mercury shed from the one of the electrodes and a pump to recirculate the liquid mercury collected by the trap back to the one of the electrodes; anda cleaning system to remove contaminants from the liquid mercury.2. The voltammetric measurement system of claim 1 , further comprising a control system to:automatically provide the aqueous solution to be measured into a measurement chamber in presence of the electrodes;measure the electrochemical property; and expel liquid mercury from the one of the electrodes such that the expelled liquid mercury collects in the trap,', 'control the pump so as to produce a fresh liquid mercury surface the one of the electrodes, and', 'engage the cleaning system so as to remove the contaminants from the liquid mercury., 'following measurement of the electrochemical property,'}3. The voltammetric measurement system of claim 1 , wherein the cleaning system is to reverse a polarity of current flow between two of the electrodes used for measurement of the aqueous solution claim 1 , to strip metal contaminants accumulated into the liquid mercury.4. The voltammetric measurement system of claim 3 , wherein the voltammetric measurement system further comprises a galvanic wire in contact with the ...

MERCURY REMOVAL

Disclosed is selective removal of mercury from aqueous feeds also including precious metals. In particular, the present invention is useful for removal of mercury from processing waters produced during precious metal mining processes. The process includes contacting the aqueous feed solution with a solid sorbent material including thiol and/or thiolate functional groups, wherein (i) the aqueous feed solution includes at least 10 ppm of free cyanide ions; and/or (ii) the sorbent material is contacted with an aqueous cyanide solution after contact with the aqueous feed solution to selectively desorb precious metal from the sorbent material. 1. A process for selectively removing mercury from an aqueous feed solution , the aqueous feed solution comprising mercury in addition to one or more precious metals , wherein the process comprises contacting the aqueous feed solution with a solid sorbent material comprising thiol and/or thiolate functional groups , wherein(i) the aqueous feed solution comprises at least 10 ppm of free cyanide ions; and/or(ii) the sorbent material is contacted with an aqueous cyanide solution after contact with the aqueous feed solution to selectively desorb precious metal from the sorbent material.2. A process according to wherein the precious metal present in the aqueous feed solution is one or both of gold and silver.3. A process according to wherein the mercury is present as a mercury cyanide complex and each precious metal is present as a precious metal cyanide complex.4. A process according to wherein the aqueous feed solution comprises at least 30 ppm of free cyanide ions.5. A process according to wherein the aqueous cyanide solution comprises at least 30 ppm of cyanide ions.6. A process according to wherein the process further comprises the step of adding cyanide ions to the aqueous feed solution.7. A process according to wherein the aqueous feed solution has a pH in the range from 9 to 13.8. A process according to where in the sorbent ...

Process for Recovering Precious Metals from Clay-Containing Ores

A solution for leaching metals from clay containing ore and a method of leaching ore is described. The solution comprises a cyanide; a wetting agent; and a clay stabilizing polymer. 1. A solution for leaching metals from clay containing ore comprising:cyanide;a wetting agent; anda clay stabilizing polymer.2. The solution for leaching metals from clay containing ore of wherein said metal is selected from the group consisting of gold claim 1 , silver claim 1 , copper and uranium.3. The solution for leaching metals from clay containing ore of with a pH of at least 8 to no more than 11.4. The solution for leaching metals from clay containing ore of with a pH of at least 9.5 to no more than 10.5.5. The solution for leaching metals from clay containing ore of comprising at least 50 ppm cyanide to no more than 1000 ppm cyanide.6. The solution for leaching metals from clay containing ore of comprising at least 200 ppm cyanide to no more than 800 ppm cyanide.7. The solution for leaching metals from clay containing ore of wherein said clay stabilizing polymer is selected from the group consisting of polyalkylene oxide copolymer; propoxylated glycols; polyamine copolymers comprising dicyandiamide claim 1 , formaldehyde and ammonia; polyvinyl alcohol; partially hydrolyzed polyvinyl acetate; polyacrylamide; quaternary amines and particularly tetramethylammonium salts; carboxymethyl cellulose; methacrylate copolymers; hydroxyaldehydes; hydroxyketones; and copolymers of anionic or cationic monomers.8. The solution for leaching metals from clay containing ore of wherein said clay stabilizing polymer is selected from the group consisting ofa polyalkylene oxide copolymer, a propoxylated glycol and a polyamine copolymer.9. The solution for leaching metals from clay containing ore of wherein said polyalkylene oxide copolymer is defined by:{'br': None, 'sup': 1', '2', '3', '4', '5, 'R—R—R—R—R'}wherein:{'sup': 1', '5', '6', '6, 'Rand Rare terminal groups independently selected from the ...

Method of separating mercury from an ore leachate

Described herein are compositions and methods for preferentially separating mercury from a metal product where both are present in an ore leachate. The separation is accomplished by adding a precipitating agent and a coagulant to an ore leachate followed by separating a mercury-laden precipitate therefrom to collect the treated leachate. The treated leachate includes about 0 to 50% by weight of the mercury and about 90% to 100% by weight of the metal product present in the ore leachate. In embodiments, the method further includes adding a flocculant to the ore leachate prior to the separating of the mercury-laden precipitate.

Method and arrangement for removing gaseous elementary mercury from a stream of gas

The invention relates to a method and to an arrangement for removing gaseous elementary mercury from a stream of gas and to an arrangement for carrying out the method. The arrangement comprises a first washing tower ( 2 ) for receiving a stream of gas, a second washing tower ( 6 ) for receiving a stream of once processed gas ( 5 ) from the first washing tower ( 2 ), and a third washing tower ( 9 ) for receiving a stream of twice processed gas ( 23 ) from the second washing tower ( 6 ) and configured for discharging a stream of cleaned gas ( 12 ).

Cement Kiln Dust Treatment System and Method

A system and method for treating cement kiln dust is provided. The method includes the steps of receiving cement kiln dust (CKD) from a kiln; heating the collected CKD; forming a gas stream of vaporized metal and CKD by sufficient heating to separate at least one heavy metal from the collected CKD stream to create a cleaned CKD stream and a metal stream; providing a water soluble alkaline-earth metal polysulfide; combining the heavy metal stream with the water soluble alkaline-earth metal sulfide to create a combined stream; and removing at least a portion of one heavy metal from the combined stream. 1. A method for treating cement kiln dust comprising at least one heavy metal , the method comprising:separating the heavy metal from the cement kiln dust to create a heavy-metal-containing stream;treating the heavy metal stream with a treating fluid containing at least one of an alkaline-earth metal sulfide and an alkaline-earth metal polysulfide; andremoving at least a portion of the heavy metal from the stream.2. The method of claim 1 , wherein the step of separating the heavy metal comprises increasing the kinetic energy of the cement kiln dust by an amount sufficient to release at least a portion of the heavy metal from the cement kiln dust.3. The method of claim 2 , wherein the step of increasing the kinetic energy of the heavy metal comprises heating to a temperature at least as high as the temperature corresponding to the volatilization point of the heavy metal to form a heavy-metal-containing gas stream.4. The method of claim 1 , wherein separating the heavy metal from the cement kiln dust includes forming modified cement kiln dust.5. The method of claim 4 , further comprising recycling the modified cement kiln dust stream.6. The method of claim 1 , wherein the heavy metal comprises mercury claim 1 , and wherein separating the heavy metal from the cement kiln dust includes increasing the kinetic energy of the cement kiln dust by an amount sufficient to release ...

Method of separating mercury from an ore leachate

Described herein are compositions and methods for preferentially separating mercury from a metal product where both are present in an ore leachate. The separation is accomplished by adding a precipitating agent and a coagulant to an ore leachate followed by separating a mercury-laden precipitate therefrom to collect the treated leachate. The treated leachate includes about 0 to 50% by weight of the mercury and about 90% to 100% by weight of the metal product present in the ore leachate. In embodiments, the method further includes adding a flocculant to the ore leachate prior to the separating of the mercury-laden precipitate.

Process for Metals Leaching and Recovery from Radioactive Wastes

Provided is a process for recovering metals from solid radioactive waste, preferably uranium, cesium, mercury, thorium, rare earths or combinations thereof. The process comprises a leaching step and a separation step. The leaching step comprises contacting the solid radioactive waste with an aqueous inorganic acid and a leaching salt to produce a mixture of a metal-rich leachate and a metal-poor waste, which are separated in the separation step. Also provided is a process for recovering metals from solid radioactive waste comprising an attrition step, a leaching step, a washing step, a combination step and a recovery step. 1. A process for recovering metals from solid radioactive waste comprising the metals , the process comprising:a) a leaching step comprising contacting the solid radioactive waste with an aqueous inorganic acid at a concentration between about 0.1 M and about 2 M, and a leaching salt, at a temperature lower than about 100° C., to solubilize at least a portion of the metals present in the solid radioactive waste, thereby producing a mixture of a metal-rich leachate and a metal-poor waste; andb) a separation step comprising separating the metal-rich leachate from the metal-poor waste.2. The process of claim 1 , wherein the leaching salt is at a concentration between about 0.012 M and about 1.2 M.3. The process of claim 1 , wherein the metals comprise uranium claim 1 , cesium claim 1 , mercury claim 1 , thorium claim 1 , rare earth or combinations thereof.4. The process of wherein the solid radioactive waste is a cemented radioactive waste or a radioactive mine waste5. The process of claim 1 , wherein the solid radioactive waste is crushed or screened prior to the leaching step.6. The process of claim 5 , wherein the solid radioactive waste is crushed or screened to provide a particle size inferior to about 1 cm.7. The process of claim 5 , wherein the solid radioactive waste is crushed or screened to provide a particle size inferior to about 2 mm.8. ...

METHOD OF MERCURY DECONTAMINATION

Methods of mercury decontamination are provided that include: contacting elemental mercury with a metal salt having a standard reduction potential sufficient to oxidize elemental mercury to an aqueous salt of mercury. In other aspects, methods of mercury decontamination are provided that include: contacting the metal surface with a solution comprising a metal salt having a standard reduction potential (E0) of greater than 0.85, thereby oxidizing a mercury contaminant to a soluble mercury salt. 1. A method of mercury decontamination comprising:contacting elemental mercury with a metal salt having a standard reduction potential sufficient to oxidize elemental mercury to an aqueous salt of mercury.2085. The method of claim 1 , wherein the metal salt has a standard reduction potential of greater than ..3. The method of claim 1 , wherein the metal salt comprises one or more salts selected from a group consisting of salts of silver claim 1 , gold claim 1 , and platinum.4. The method of claim 1 , wherein the metal salt is a nitrate salt.5. The method of claim 1 , further comprising contacting the elemental mercury with one or more crystal habit modifiers.6. The method of claim 5 , wherein the one or more crystal habit modifiers is one or more selected from a group consisting of glycols and polyvinyl pyrrolidone.7. The method of claim 1 , further comprising recovering the aqueous salt of mercury.8. The method of claim 1 , further comprising recovering a solid metal corresponding to the cation of the metal salt.9. The method of claim 7 , further comprising contacting the aqueous salt of mercury with a precipitating agent to produce a solid mercury-based mineral.10. The method of claim 8 , wherein the precipitating agent is one or more selected from sulfides and elemental sulfur11. The method of claim 7 , further comprising contacting the aqueous salt of mercury with a reducing agent having a standard reduction potential of less than 0.85.12. The method of claim 11 , wherein ...

IONIC LIQUID SOLVENTS OF PERHALIDE TYPE FOR METALS AND METAL COMPOUNDS

The present invention relates to a process for dissolving metals in perhalide containing ionic liquids, and to the extraction of metals from mineral ores; the remediation of materials contaminated with heavy, toxic or radioactive metals; and to the removal of heavy and toxic metals from hydrocarbon streams. 125-. (canceled)26. A method of extracting metals and metal compounds from aqueous solutions comprising contacting the aqueous solution with an ionic liquid having the formula:{'br': None, 'sup': +', '−, '[Cat][X]'}{'sup': '+', 'claim-text': {'sup': '−', '[X] represents one or more perhalide anions,'}, 'wherein: [Cat] represents one or more cationic species, and'}wherein the ionic liquid is free of additional solvents and/or oxidants.27. A method according to claim 26 , wherein [X] comprises at least one perhalide anion selected from [I] claim 26 , [BrI] claim 26 , [BrI] claim 26 , [ClI] claim 26 , [Br] claim 26 , [ClBr] claim 26 , [BrCl] claim 26 , [ICl] claim 26 , or [Cl].28. A method according to claim 27 , wherein [X] comprises at least one perhalide anion selected from [BrI] claim 27 , [BrI] claim 27 , [ClI] claim 27 , [ClBr] claim 27 , [BrCl] claim 27 , or [ICl].29. A method according to claim 27 , wherein [X] comprises at least one perhalide anion selected from [I] claim 27 , [Br] claim 27 , or [Cl].30. A method according to claim 26 , wherein [Cat] is a cationic species selected from the group consisting of: ammonium claim 26 , azaannulenium claim 26 , azathiazolium claim 26 , benzimidazolium claim 26 , benzofuranium claim 26 , benzotriazolium claim 26 , borolium claim 26 , cinnolinium claim 26 , diazabicyclodecenium claim 26 , diazabicyclononenium claim 26 , diazabicyclo-undecenium claim 26 , dithiazolium claim 26 , furanium claim 26 , guanidinium claim 26 , imidazolium claim 26 , indazolium claim 26 , indolinium claim 26 , indolium claim 26 , morpholinium claim 26 , oxaborolium claim 26 , oxaphospholium claim 26 , oxazinium claim 26 , oxazolium claim 26 ...

METHOD FOR DEMERCURISATION

Method of extracting non-ferrous and/or noble metals from aqueous solutions

Изобретение относитс  к способам выделени  цветных металлов из водных растворов, содержащих растворенные соединени  этих металлов. Цель изобретени  - упрощение процесса . Способ предусматривает извлечение цветных металлов из водных растворов. Раствор пропускают через колонну, содержащую слой активированного угл  с размерами зерен 0,0.1-8 мм и слой красного фосфора с размерами зерен 0,01-10 мм или смесь красного фосфора с. активированным углем при содержании его в смеси 15,7 - 98 мас,%. Активированный уголь располагают нижним слоем. Красный (.фосфор активируют гипохлоритом натри . 1 з.п. ф-лы. СО оо о со :о The invention relates to methods for separating non-ferrous metals from aqueous solutions containing dissolved compounds of these metals. The purpose of the invention is to simplify the process. The method involves the extraction of non-ferrous metals from aqueous solutions. The solution is passed through a column containing an activated carbon layer with a grain size of 0.0.1-8 mm and a layer of red phosphorus with a grain size of 0.01-10 mm or a mixture of red phosphorus c. activated carbon with a content of 15.7 - 98 wt.% in a mixture. Activated carbon have a lower layer. Red (. Phosphorus is activated by sodium hypochlorite. 1 Cp of f-ly. CO oo o co: o

Method of producing catalyst

FIELD: technological processes. SUBSTANCE: invention relates to a method of producing a catalyst based on particles with size of cross section in range of 1-50 mm and combination of sizes in range of 0.5-5 using layer of additive produced by 3D printing technology, wherein method includes: (i) forming a layer of a powdered catalyst support material, containing aluminium oxide, metal aluminate, silicon dioxide, aluminosilicate, titanium dioxide, zirconium dioxide, zinc oxide or mixture thereof (ii) binding or fusing powder in said layer according to a predetermined pattern, (iii) repeating (i) and (ii) layer upon layer to form a shaped unit, and (iv) optionally applying a catalytic material to said shaped unit. Invention also relates to a catalyst for ammonium oxidation, obtained using disclosed method. Invention also relates to a method of using said catalyst, involving bringing a mixture of reagents into contact with moulded catalyst unit under conditions which enable to carry out a catalysed reaction, where catalysed reaction is selected from ammonia oxidation and nitrogen oxide decomposition reactions. EFFECT: high catalyst efficiency. 14 cl, 3 dwg, 3 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 598 381 C2 (51) МПК B01J 35/02 (2006.01) B01J 37/00 (2006.01) B22F 3/105 (2006.01) B29C 67/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2013115444/04, 22.08.2011 (24) Дата начала отсчета срока действия патента: 22.08.2011 (72) Автор(ы): КУПЛАНД Дункан Рой (GB) (73) Патентообладатель(и): ДЖОНСОН МЭТТИ ПАБЛИК ЛИМИТЕД КОМПАНИ (GB) Приоритет(ы): (30) Конвенционный приоритет: R U 08.09.2010 GB 1014950.8 (43) Дата публикации заявки: 20.10.2014 Бюл. № 29 (45) Опубликовано: 27.09.2016 Бюл. № 27 2 5 9 8 3 8 1 (56) Список документов, цитированных в отчете о поиске: WO 2009156316 А1, 30.12.2009. WO 2009047141 А1, 16.04.2009. EP 0001366808 А2, 03.12.2003. EP 0000431924 А2, 12.06.1991. RU 2121872 С1, 20.11.1998. ...

Method for decontamination of mercury containing wastes

Изобретение относится к обезвреживанию отходов. Способ обезвреживания ртутьсодержащих отходов включает совместный размол отходов с порошком элементарной серы, воды и гомогенизирующей средой для связывания металлической ртути в водонерастворимое соединение HgS во вращающемся реакторе в виде мельницы барабанного типа. Соотношение массы ртути к массе элементарной серы равно 1:4, в качестве гомогенизирующей среды используют бентонит, в количестве, превышающем массу отходов в 2-2,5 раза, и воду в количестве, превышающем массу бентонита в 10-12 раз. Предварительную гомогенизацию проводят в течение 20-30 минут. Далее загружают ртутьсодержащие отходы и размол ведут до связывания 90% массы металлической ртути в водонерастворимое соединение HgS. Для полного связывания металлической и окисленной ртути в водонерастворимое соединение HgS на завершающей стадии процесса в суспензию добавляют смесь хлорида железа (III) с сульфидом железа (II), причем масса хлорида железа (III) и масса сульфида железа (II), соответственно, в 10 и 20 раз больше оставшейся ртути. Затем образовавшуюся устойчивую подвижную суспензию сливают из мельницы и непосредственно передают на сушку с последующим захоронением как отход IV класса опасности. Обеспечивается упрощение технологии и повышение экологической безопасности процесса обезвреживания и последующего захоронения ртутьсодержащих отходов. 1 табл. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 710 315 C2 (51) МПК C22B 43/00 (2006.01) C22B 7/00 (2006.01) B09B 3/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C22B 43/00 (2019.05); C22B 7/006 (2019.05); B09B 3/0016 (2019.05) (21)(22) Заявка: 2018116212, 28.04.2018 (24) Дата начала отсчета срока действия патента: Дата регистрации: 25.12.2019 (43) Дата публикации заявки: 28.10.2019 Бюл. № 31 (45) Опубликовано: 25.12.2019 Бюл. № 36 2 7 1 0 3 1 5 R U (56) Список документов, цитированных в отчете о поиске: RU 2519320 C1, 10.06.2014. RU 2519203 C1, 10. ...

Method of waste water purification from mercury

Mercury particles which are difficult to strip from sewage waters of industries employing mercury compounds, due to their extremely tiny size, can be coalesced into larger mercury drops by applying a strong magnetic field to the liquor which contains such tiny particles.

Molecularly imprinted polymer granules for extraction of lithium, mercury and scandium

FIELD: molecularly imprinted polymers.SUBSTANCE: group of inventions relates to molecularly imprinted polymers, namely macroporous polymer granules for binding target molecules, methods for producing granules and methods for selective sequestration of one or more target ions from a solution of one or more target metal ions mixed with other ions. The set of macroporous polymer granules contains a copolymer having a set of complexing cavities that selectively bind Au(S2O3)23-, the copolymer being prepared from: (a) a cationic ligand monomer complexed with a non-metallic substitute ion selected from the group consisting of tetrathionate, pentathionate, hexathionate, hexadionate, heptyldionate, octyldionate, 1,4-phenylenediacetate, butanedisulfonate, pentanedisulfonate and hexanedisulfonate, (b) a non-ligand monomer and (c) a crosslinking monomer, the charge of the copolymer being opposite to the charge of the copolymer in the complexing cavity of the metal. In various embodiments, the granules are designed to bind scandium tricarbonate, Li+and Hg2+, while the copolymer can be obtained in particular from a cationic ligand monomer complexed with a tribasic salt of benzene-1,3,5-triyl tricarboxylate, complex 1-(4-vinylpyridin-2-yl) methanimine, optionally substituted with a C4-C24branched or unbranched alkyl group on the imine nitrogen atom, with Li+, and a complex of bis-4-vinylbenzyl dithiocarbamate Ca2+, where R is a C4-C24branched or unbranched alkyl group, respectively. The sequestration method includes first contacting the macroporous polymer granules with a stripping solution, whereby complexed ions are removed from the granules, and then contacting the cleaned granules with the solution.EFFECT: granules are characterized by high performance and low cost, yet they are highly selective and their production is safe and scalable.20 cl, 1 dwg РОССИЙСКАЯ ФЕДЕРАЦИЯ ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) (19) RU (11) (13) 2 748 350 C2 (51) МПК B01J 20/ ...

Process for removal and recovery of mercury from gases

THE CONCENTRATION OF CIRCULATING SULPHURIC ACID IS ADJUSTED TO 80-98% BY WEIGHT AND USED TO WASH HOT GASES CONTAINING MERCURY. THE TEMPERATURE OF THE ACID IS MAINTAINED BETWEEN 70-250*C. AND THE SOLID MATERIAL SEPARATING FROM THE CIRCULATING WASH SOLUTION IS RECOVERED.

Plant for processing fluorescent lamps

FIELD: processing and utilization of waste; lighting equipment. SUBSTANCE: invention relates to processing of fluorescent lamps. Installation includes a lamp separation unit, an exhaust gas cleaning system unit, a dust and gas emission purification system and an adsorber for air purification. Lamp separation unit consists of a device for separating lamps with a loading unit, an air-vibrated separator with a crusher and a cyclone, hopper for collecting crushed glass of lamps, a container for receiving lamp caps and a container for phosphor. Block of the multi-stage exhaust gas cleaning system includes a sequential system for the purification of dust and gas emissions consisting of a cyclone and bag filters. Adsorber for air purification contains a housing with a lid, inside which is installed a glass with insulation and perforated disks in the upper and lower parts of the glass, and adsorbent from activated carbon impregnated with sulfur, located in a glass between the discs. Adsorbent is made in the form of a cylindrical ring, on the lateral inner surface of which are fixed partitions in the form of holes perpendicular to the axis of the ring of washers whose axes are asymmetric to the axis of the ring. EFFECT: increase in efficiency and energy and resource saving of scrap processing of fluorescent lamps and gas purification is ensured. 1 cl, 6 dwg РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 655 400 C1 (51) МПК C22B 7/00 (2006.01) C22B 43/00 (2006.01) C09K 11/01 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ На основании пункта 1 статьи 1366 части четвертой Гражданского кодекса Российской Федерации патентообладатель обязуется заключить договор об отчуждении патента на условиях, соответствующих установившейся практике, с любым гражданином Российской Федерации или российским юридическим лицом, кто первым изъявил такое желание и уведомил об этом патентообладателя и федеральный орган исполнительной власти по ...

Mercury distillation apparatus with electric heat control

MOLECULAR-IMPRINTED POLYMER GRANULES FOR EXTRACTION OF LITHIUM, MERCURY AND SCANDIUM

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2019 115 932 A (51) МПК B01J 20/26 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2019115932, 03.11.2017 (71) Заявитель(и): 6С ВЭЙВ ИННОВЭЙШНС КОРП. (US) Приоритет(ы): (30) Конвенционный приоритет: 03.11.2016 US 62/417,164 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 03.06.2019 R U (43) Дата публикации заявки: 03.12.2020 Бюл. № 34 (72) Автор(ы): САУТАРД, Глен Э. (US), ГЛЮКМАН, Джонатан П. (US) (86) Заявка PCT: (87) Публикация заявки PCT: WO 2018/085626 (11.05.2018) R U (54) МОЛЕКУЛЯРНО-ИМПРИНТИРОВАННЫЕ ПОЛИМЕРНЫЕ ГРАНУЛЫ ДЛЯ ЭКСТРАКЦИИ ЛИТИЯ, РТУТИ И СКАНДИЯ (57) Формула изобретения 1. Множество макропористых полимерных гранул, содержащих сополимер, имеющий множество комплексообразующих полостей, которые селективно связывают Au(S2O3)23-, причем сополимер получен из: (a) мономера катионного лиганда, связанного в комплекс с неметаллическим заменяющим ионом выбранным из группы, состоящей из тетратионата, пентатионата, гексатионата; гексадионата, гептилдионата, октилдионата; 1,4-фенилендиацетата; бутандисульфоната, пентандисульфоната и гександисульфоната, (b) нелигандного мономера и (c) сшивающего мономера; причем заряд сополимера в комплексообразующей полости противоположен заряду целевого иона металла. 2. Множество макропористых полимерных гранул, содержащих сополимер, имеющий множество комплексообразующих полостей, которые селективно связывают трикарбонат скандия, причем сополимер получен из: (a) мономера катионного лиганда, связанного в комплекс с трехосновной солью бензол-1,3,5-триил-трикарбоксилатом, (b) нелигандного мономера и (c) сшивающего мономера; причем заряд сополимера в комплексообразующей полости противоположен заряду Стр.: 1 A 2 0 1 9 1 1 5 9 3 2 A Адрес для переписки: 190000, Санкт-Петербург, БОКС-1125 2 0 1 9 1 1 5 9 3 2 US 2017/059870 (03.11.2017) 2 0 1 9 1 1 5 9 3 2 R U с Li+, (b) необязательного нелигандного мономера и (c) сшивающего ...

Mercury removal method out of solutions contaminated with it

FIELD: processes and equipment for removing mercury out of liquids. SUBSTANCE: method for removing mercury from solutions contaminated at least partially with metallic mercury comprises steps of filtering through filter of electrographite with mean size of particles in range 20 - 1000 micrometers; using electrographite with surface according to BET in range 0.5 - 10 m 2 /g. EFFECT: improved effectiveness of process due to increased useful life period of filter. 5 cl, 3 tbl, 3 ex ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß RU (19) (11) 2 323 269 (13) C2 (51) ÌÏÊ C22B 43/00 (2006.01) C22B 3/22 (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÎÏÈÑÀÍÈÅ ÈÇÎÁÐÅÒÅÍÈß Ê ÏÀÒÅÍÒÓ (21), (22) Çà âêà: 2005120171/02, 17.11.2003 (30) Êîíâåíöèîííûé ïðèîðèòåò: 26.11.2002 DE 10255240.1 (73) Ïàòåíòîîáëàäàòåëü(è): ÁÀÑÔ Àêöèåíãåçåëüøàôò (DE) (43) Äàòà ïóáëèêàöèè çà âêè: 20.01.2006 R U (24) Äàòà íà÷àëà îòñ÷åòà ñðîêà äåéñòâè ïàòåíòà: 17.11.2003 (72) Àâòîð(û): ÁÅÍÄÅÐ Õàíñ-Þðãåí (DE), ÔÐÈÄÐÈÕ Õîëüãåð (DE), ÃÓÒ Éîçåô (DE) (45) Îïóáëèêîâàíî: 27.04.2008 Áþë. ¹ 12 2 3 2 3 2 6 9 (56) Ñïèñîê äîêóìåíòîâ, öèòèðîâàííûõ â îò÷åòå î ïîèñêå: SU 402200 À, 04.03.1974. SU 280440 À, 27.09.1970. FR 2066263 À, 06.08.1971. US 6156214 À, 05.12.2000. DE 3335127 À1, 11.04.1985. US 5164091 A, 17.11.1992. (85) Äàòà ïåðåâîäà çà âêè PCT íà íàöèîíàëüíóþ ôàçó: 27.06.2005 2 3 2 3 2 6 9 R U (87) Ïóáëèêàöè PCT: WO 2004/048624 (10.06.2004) C 2 C 2 (86) Çà âêà PCT: EP 03/12817 (17.11.2003) Àäðåñ äë ïåðåïèñêè: 105064, Ìîñêâà, óë. Êàçàêîâà, 16, ÍÈÈÐ Êàíöåë ðè "Ïàòåíòíûå ïîâåðåííûå Êâàøíèí, Ñàïåëüíèêîâ è ïàðòíåðû", ïàò.ïîâ. Â.Ï.Êâàøíèíó (54) ÑÏÎÑÎÁ ÓÄÀËÅÍÈß ÐÒÓÒÈ ÈÇ ÇÀÃÐßÇÍÅÍÍÛÕ ÐÒÓÒÜÞ ÐÀÑÒÂÎÐΠ(57) Ðåôåðàò: Èçîáðåòåíèå îòíîñèòñ ê ñïîñîáàì óäàëåíè ðòóòè èç æèäêîñòåé. Ñïîñîá óäàëåíè ðòóòè èç çàãð çíåííûõ, ïî ìåíüøåé ìåðå, ÷àñòè÷íî èìåþùåéñ â ìåòàëëè÷åñêîé ôîðìå ðòóòüþ ðàñòâîðîâ âåäóò ïóòåì ôèëüòðàöèè ÷åðåç ôèëüòð èç ýëåêòðîãðàôèòà ñî ñðåäíèì ðàçìåðîì ÷àñòèö â èíòåðâàëå îò 20 äî 1000 ìèêðîìåòðîâ. Ïðè ...

Method for clean, efficient and comprehensive recovery of mercury from mercury-containing flue gas

本发明属于大气污染控制技术及重金属污染控制技术领域，具体公开了一种含汞烟气清洁高效综合回收汞的方法。该方法包括以下步骤：含汞烟气经余热锅炉降温和高温电除尘器除尘后，进入至少一次洗涤塔，经洗涤塔洗涤液喷淋后，喷淋液回收，经固液分离得到富汞渣，烟气进入干燥塔干燥后，进入填料吸附塔，得到富汞吸附剂，烟气经吸附后进入下一步烟气处理后排出，富汞渣和富汞吸附剂为汞产品原料。本发明得到的富汞渣综合回收汞，制备汞产品，除汞效率高达99.8％以上，烟气可以达标排放，烟气出口Hg≤0.02mg/m 3 。

Method of continuous and simultaneous collection and precipitation of mercury from mercury-containing gases

FIELD: separation of mercury from gases, particularly, continuous and simultaneous collection and precipitation of mercury from mercury-containing gases. SUBSTANCE: method includes passing of mercury-containing gas through washing tower to which hydrogen sulfate is injected continuously, or periodically at moment of time coinciding with washing by solution containing complex of mercury (II), for instance, [I 4 Hg] 2- or [(SCN) 4 Hg] 2- , not needing of additional oxidizer. Collection and precipitation of mercury and regeneration of solution containing complex of mercury (II) are carried out simultaneously and in one stage only. EFFECT: simplified process and reduced working costs. 7 cl сб с ПЧ ГЭ (19) 13) ВО ^” 2 139 752'”С1 57 МК В 010 53/34, С 22 В 43/00 РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 95118139/02, 25.10.1995 (71) Заявитель: Астуриана де Синк, СА. (Е $) (24) Дата начала действия патента: 25.10.1995 (72) Изобретатель: Ситхес Менендес Фернандо (30) Приоритет: 26.10.1994 Е$ 9402221 (ЕЗ), | Альварес Тамарго Франсиско (Е$), Гамарго (46) Дата публикации: 20.10.1999 Гарсиа Франсиско (ЕЗ), Родригес Валькарсель (56) Ссылки: И$ 5232488 А, 03.08.93. ЗИ 165900 А, Е (Е5), Мурусабаль Ситхес Ковадонга 26.10.94. ЗИ 587873 А, 05.01.78. СВ 1343797 В1, 16.01.74. ОЕ 2305522 А, 04.04.74. (73) Патентообладатель: (98) Адрес для переписки: Астуриана де Синк, С.А. (ЕЗ) 193036, Санкт-Петербург, а/я 24, НЕВИНПАТ, Поликарпову А.В. (54) СПОСОБ НЕПРЕРЫВНОГО И ОДНОВРЕМЕННОГО СБОРА И ОСАЖДЕНИЯ РТУТИ ИЗ СОДЕРЖАЩИХ ЕЕ ГАЗОВ (57) Реферат: 12 Изобретение может быть использовано 2. для выделения ртути из газов, в частности для непрерывного и одновременного сбора и осаждения ртути из ртутьсодержащих газов. Способ включает пропускание газа, содержащего ртуть, через промывную колонну, в которую инжектируют сероводород постоянно или периодически в моменты времени, совпадающие с — промывкой раствором, содержащим ...

System and method of treatment of cement kiln dust

FIELD: construction. SUBSTANCE: method involves the following stages: obtainment of cement kiln dust (CKD) from a calcination kiln; heating of collected CKD; formation of a gas flow of evaporated metal and CKD by the heating sufficient for release at least of one heavy metal from a flow of collected CKD with creation of a flow of treated CKD and a metal flow; provision of a water-soluble polysulphide of a rare-earth metal; combination of the heavy metal flow with the water-soluble polysulphide so that a combined flow is obtained and removal of at least some part of one heavy metal from the combined flow. EFFECT: invention allows reducing contaminations with heavy metals of cement kiln dust. 19 cl, 1 dwg РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 538 586 C2 (51) МПК B01D 53/14 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2013111776/05, 18.08.2011 (24) Дата начала отсчета срока действия патента: 18.08.2011 Приоритет(ы): (30) Конвенционный приоритет: (72) Автор(ы): ЛЕСНЯК Томас (US), ПОЛИНГ Кристофер (US), Д'АМИКО Питер (US) 18.08.2010 US 61/374,745 (43) Дата публикации заявки: 27.09.2014 Бюл. № 27 R U (73) Патентообладатель(и): МЕРКЬЮТЕК ЭлЭлСи (US) (45) Опубликовано: 10.01.2015 Бюл. № 1 2010000406 A1 07.01.2010. US 2009202407 A1, 13.08.2009. RU 2068730 C1, 10.11.1996 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 18.03.2013 (86) Заявка PCT: 2 5 3 8 5 8 6 (56) Список документов, цитированных в отчете о поиске: US 2009283016 A1 19.11.2009. US 2 5 3 8 5 8 6 R U (87) Публикация заявки PCT: WO 2012/024511 (23.02.2012) Адрес для переписки: 129090, Москва, ул. Б. Спасская, 25, строение 3, ООО "Юридическая фирма Городисский и Партнеры" (54) СИСТЕМА И СПОСОБ ОБРАБОТКИ ЦЕМЕНТНОЙ ПЫЛИ (57) Реферат: Заявлен способ обработки цементной пыли. водорастворимого полисульфида Способ включает следующие стадии. Получение щелочноземельного металла. Объединение цементной пыли ((ЦП) (CKD)) из обжиговой печи ...

Method for reducing mercury content in ecosystems

FIELD: ecology. SUBSTANCE: invention relates to the ecology. Toxicant disinfection is carried out when mixed with sulfur. In ecosystems, mercury-indicating plants are identified. When the content of mercury in them is more than 0.1 mg/kg, an ecosystem area with indicator plants is sprayed with hydrogen sulfide mineral water in an amount of 250–300 l/ha, to which 1–2 % potassium humate is added. EFFECT: reduced levels of toxic elements in the ecosystem and at the same time increased soil fertility is provided. 1 cl, 2 ex, 1 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 683 637 C1 (51) МПК A01C 21/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК A01C 21/00 (2018.08); B09C 1/00 (2018.08); G01N 33/24 (2018.08); C22B 43/00 (2018.08); C01B 7/09 (2018.08) (21)(22) Заявка: 2018108256, 06.03.2018 06.03.2018 Дата регистрации: 29.03.2019 (56) Список документов, цитированных в отчете о поиске: RU 2519203 C1, 10.06.2014. CN 106385925 A, 15.02.2017. CN 106358553 A, 01.02.2017. БЕКУЗАРОВА С.А. Растенияиндикаторы загрязнения почв тяжелыми металлами//Успехи современной науки, 2017, том 1, N 9. UA 6499 U, 15.05.2005. (54) СПОСОБ СНИЖЕНИЯ РТУТИ В ЭКОСИСТЕМАХ (57) Реферат: Изобретение относится к экологии. опрыскивают сероводородной минеральной Осуществляют обеззараживание токсиканта при водой в количестве 250-300 л/га, в которую смешивании с веществом серы. В экосистемах добавляют 1-2% гумата калия. Обеспечивается выявляют растения-индикаторы ртути. При снижение содержания токсических элементов в содержании в них ртути более 0,1 мг/кг участок экосистеме и одновременно повышение экосистемы с растениями-индикаторами плодородия почв. 1 табл., 2 пр. R U 2 6 8 3 6 3 7 Адрес для переписки: 362002, РСО-Алания, г. Владикавказ, ул. Маркова, 93а, Геофизический институт филиал Федерального государственного бюджетного учреждения науки Федерального научного центра "Владикавказский научный центр Российской академии наук" (ГФИ ВНЦ РАН) Стр ...

Method and article for removing mercury from gases contaminated therewith

Mercury is removed from gases contaminated therewith by passing the gases in contact with activated carbon which has been impregnated with sulfuric acid. Carbon impregnation by soaking in a sulfuric acid solution and drying at preferred temperatures as well as mercury adsorption at preferred temperatures is also disclosed.

Patent JPS5323777B2

Method of recovery of mercury from spent catalyst for synthesis of vinylchloride

Method of extracting mercury from gases

Patent DE3335127C2

Method of the purifying of soils and sludges from metal mercury pollutants

Изобретение относится к области разделения материалов, а именно к способам комплексной очистки грунтов и шламов, загрязненных ртутью, и может быть использовано для выделения металлической ртути, а также амальгамы и других соединений ртути. Способ очистки грунтов и шламов от загрязнений металлической ртутью включает выделение фракции крупностью менее 10 мм, формирование на ее основе пульпы, разделение пульпы на компоненты и отделение металлической ртути. Пульпу разделяют на компоненты в отсадочной машине с постелью из стальной дроби размером 1,8-2,2 мм, расположенной над решеткой с размером ячеек от 0,5-1,0 мм. Металлическую ртуть отделяют путем отстаивания нижнего слива отсадочной машины. Под постель отсадочной машины с частотой 130-350 раз/мин подают воду со скоростью 15-20 м/м⋅ч. Технический результат - повышение качества очистки. 1 з.п. ф-лы, 1 ил., 1 пр. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 667 967 C2 (51) МПК B09C 1/00 (2006.01) C22B 43/00 (2006.01) B03B 7/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК B09C 1/00 (2006.01); C22B 43/00 (2006.01); B03B 7/00 (2006.01); B03B 5/10 (2006.01) (21)(22) Заявка: 2017106078, 27.02.2017 (24) Дата начала отсчета срока действия патента: Дата регистрации: (73) Патентообладатель(и): Общество с ограниченной ответственностью "Мерком" (RU) 25.09.2018 (43) Дата публикации заявки: 27.08.2018 Бюл. № 24 (45) Опубликовано: 25.09.2018 Бюл. № 27 (54) СПОСОБ ОЧИСТКИ ГРУНТОВ И ШЛАМОВ ОТ ЗАГРЯЗНЕНИЙ МЕТАЛЛИЧЕСКОЙ РТУТЬЮ (57) Реферат: Изобретение относится к области разделения компоненты в отсадочной машине с постелью из материалов, а именно к способам комплексной стальной дроби размером 1,8-2,2 мм, очистки грунтов и шламов, загрязненных ртутью, расположенной над решеткой с размером ячеек и может быть использовано для выделения от 0,5-1,0 мм. Металлическую ртуть отделяют металлической ртути, а также амальгамы и других путем отстаивания нижнего слива отсадочной соединений ...

Method of mercury removal from mercury-contaminated solutions

FIELD: chemistry. SUBSTANCE: invention refers to method of mercury removal from mercury-contaminated polluted alkali or alkali alcoholate spirit. Mercury-contaminated alkali or alkali alcoholate spirit is filtered through coal at first and then through inert fibrous material. Filtration is followed with introducing distillation column into solution over the bottom. Water or spirit are reduced, while mercury-depleted alkali or spirit are delivered to the column bottom. EFFECT: lower mercury content in solutions to maximum value 3 fractions to billion. 4 cl, 3 tbl, 3 ex ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß RU (19) (11) 2 350 672 (13) C2 (51) ÌÏÊ C22B 43/00 (2006.01) C22B 7/00 (2006.01) B01D 3/00 (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÎÏÈÑÀÍÈÅ ÈÇÎÁÐÅÒÅÍÈß Ê ÏÀÒÅÍÒÓ (21), (22) Çà âêà: 2005120172/02, 17.11.2003 (72) Àâòîð(û): ÃÓÒ Éîçåô (DE), ÔÐÈÄÐÈÕ Õîëüãåð (DE), ÁÅÍÄÅÐ Õàíñ-Þðãåí (DE), ØËÅÔÅÐ Äèòåð (DE) (24) Äàòà íà÷àëà îòñ÷åòà ñðîêà äåéñòâè ïàòåíòà: 17.11.2003 (73) Ïàòåíòîîáëàäàòåëü(è): ÁÀÑÔ Àêöèåíãåçåëüøàôò (DE) (43) Äàòà ïóáëèêàöèè çà âêè: 20.01.2006 R U (30) Êîíâåíöèîííûé ïðèîðèòåò: 26.11.2002 DE 10255239.8 (45) Îïóáëèêîâàíî: 27.03.2009 Áþë. ¹ 9 2 3 5 0 6 7 2 (56) Ñïèñîê äîêóìåíòîâ, öèòèðîâàííûõ â îò÷åòå î ïîèñêå: US 6156214 À, 05.12.2000. SU 1787482 A1, 15.01.1991. SU 280440 A, 27.09.1970. FR 2066263 À, 06.08.1971. DE 3335127 A1, 11.04.1985. US 5164091 A, 17.11.1992. (85) Äàòà ïåðåâîäà çà âêè PCT íà íàöèîíàëüíóþ ôàçó: 27.06.2005 Àäðåñ äë ïåðåïèñêè: 105064, Ìîñêâà, à/ 88 (54) ÑÏÎÑÎÁ ÓÄÀËÅÍÈß ÐÒÓÒÈ ÈÇ ÇÀÃÐßÇÍÅÍÍÛÕ ÐÒÓÒÜÞ ÐÀÑÒÂÎÐΠ(57) Ðåôåðàò: Èçîáðåòåíèå îòíîñèòñ ê ñïîñîáó óäàëåíè ðòóòè èç çàãð çíåííûõ ðòóòüþ ùåëî÷è èëè ñïèðòîâîãî ðàñòâîðà àëêîãîë òà ùåëî÷íîãî ìåòàëëà Çàãð çíåííûå ðòóòüþ ùåëî÷ü èëè ñïèðòîâîé ðàñòâîð àëêîãîë òà ùåëî÷íîãî ìåòàëëà ôèëüòðóþò ñíà÷àëà ÷åðåç óãîëü è ïîòîì ÷åðåç èíåðòíûé âîëîêíèñòûé ìàòåðèàë. Ïîñëå ôèëüòðàöèè ðàñòâîð ââîä ò â äèñòèëë öèîííóþ êîëîííó ïîâåðõ íèæíåé ÷àñòè, îòãîí þò âîäó èëè ñïèðò è ...

Mercury Collecting Method from Waste

본 발명에 따른 폐기물로부터의 수은 회수 공정은 수은이 함유된 폐기물을 고상 또는 액상 폐기물로 분리하여 전처리하는 단계; 상기 전처리 단계를 거친 폐기물에 대하여 열처리를 통해 수은을 회수하는 단계; 상기 수은 회수 단계에서 발생된 중간 폐기물에 대하여 기설정된 기준 수은 함유 농도의 초과 여부를 판단하는 단계; 상기 수은 회수 단계에서 발생한 수은 함유 배가스에 대한 정제를 실시하는 단계; 및 상기 수은 정제 단계를 거친 배가스에 대해서 미량의 수은을 제거하는 단계;를 포함함으로써 수은을 안정적으로 회수할 수 있게 한다. 본 발명은 고상 및 반고상 폐기물을 액상 수은 함유 폐기물로부터 분리하여 전처리 공정을 진행하고 수은 회수 공정도 폐기물의 형태에 따라 별개적으로 진행함으로서 결과적으로 고순도의 수은을 회수하게 한다.

Method for centrifugal separation of mixed substances with different densities

FIELD: mechanical engineering. SUBSTANCE: method is carried out in centrifugal basket having many circular members on periphery surface and outer casing from which water is injected through holes into internal space of basket, into recesses between circular troughs. Supplying materials containing mercury, gold, water and ore wastes are separated so that gold and mercury are collected in recesses. Liquid mercury is discharged through holes of internal basket onto internal surface of external basket on which annular receiver is provided and whose profile ensures accumulation of mercury in receiver axially extended from open throat of basket. Many discharge holes in annular receiver allow discharge of mercury into the second tray inside external tray for main unloading of materials from open throat. Liquid mercury is collected and accumulated separately from heavy solid substances inside the basket and separately from unloaded light materials. EFFECT: higher efficiency. 8 cl, 3 dwg ГОУЗОГс ПЧ ГЭ РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (19) ВИ ^”2 108 401 ' 67 МК” © 22 в 9/02 13) СЛ 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 94019326/02, 02.06.1994 (30) Приоритет: 03.06.1993 1$ 070527 (46) Дата публикации: 10.04.1998 (56) Ссылки: 1. 4$, патент, 473421, кл. С 22 В 902, 1923. 2. ЦЗ, патент, 1283846, кл. С 22 В 9/02, 1919. 3. Ц$, патент, 1557672, кл. С 22В 90.2, 1925. 4. (5, патент, 3192149, кл. С 22 В 902, 1965. 5. ЦЗ, патент, 4966576, кл. С 22В 90.2, 1990. 6. 13, патент, 1190466, кл. С 22 В 9/02, 1916. 7. 05, патент, 2723799, кл. С 22В 902, 1942. 8. ЦЗ, патент, 957478, кл. С 22 В 90.2, 1910. 9. ЦЗ, патент, 1594501, кл. С 22 В 902, 1926. (71) Заявитель: Бенджамин Нельсон[СА] (72) Изобретатель: Бенджамин Нельсон[СА] (73) Патентообладатель: Бенджамин Нельсон[СА] (54) СПОСОБ ДЛЯ ЦЕНТРОБЕЖНОГО ОТДЕЛЕНИЯ СМЕШАННЫХ ВЕЩЕСТВ С РАЗЛИЧНЫМИ УДЕЛЬНЫМИ ВЕСАМИ (57) Реферат: Изобретение относится к способу центробежного разделения смешанных ...

Non-thermal drainless method for neutralising mercury-containing waste

FIELD: treatment of waste. SUBSTANCE: invention relates to environmental protection, namely, to a method for neutralising mercury-containing waste (temperature controllers, thermometers, luminescent lamps, pressure gauges and barometers) containing metallic mercury. The method includes joint grinding of mercury-containing waste with elemental sulphur powder and water in a sealed reactor in the form of a drum- or vibration-type mill. The ratio of the mass of elemental sulphur to the mass of metallic mercury is 3:1. Grinding is executed until 95 to 96% of the mass of metallic mercury is bound to mercury sulphide. At the final stage of grinding, iron (III) chloride and iron (II) sulphide in the form of pyrite are added to the reactor to fully bind the metallic and oxidised mercury into mercury sulphide and produce a suspension. Bentonite in the amount of 1:8 to the solid phase of said waste and water are then introduced into the reactor to bring the S:L ratio to 1:4 forming a stable mobile non-separating suspension subsequently drained from the reactor and held while stirring for 24 to 48 hours. The suspension is then directed for drying into a dryer with a fluidised bed or a spray dryer, producing a dried product with a content of metallic mercury and compounds thereof as calculated for mercury, excluding mercury sulphide, less than MAC = 2.1 mg / kg. EFFECT: invention provides a possibility of transferring mercury from mercury-containing waste into water-insoluble and diluted acid-insoluble environmentally stable mercury sulphide without pretreatment, increase in the temperature of the process and use of additional reagents. 1 cl, 1 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 764 532 C1 (51) МПК C22B 43/00 (2006.01) B09B 3/00 (2006.01) C22B 7/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C22B 43/00 (2021.08); B09B 3/0025 (2021.08); C22B 7/002 (2021.08) (21)(22) Заявка: 2020135331, 28.10.2020 (24) Дата ...

Apparatus for extracting mercury from waste containing plastic material

This process enables the recovery of mercury from waste containing plastic material, e.g. batteries. The waste is slowly heated while an inert gas is being introduced in a vacuum for fractionating extraction of the products of the decomposition of the plastic. The waste gases must pass through an afterburner chamber incorporating a specially shaped burner where the plastic vapors are fully combusted. The waste gases are conducted from the afterburner chamber through a cooling trap and then through a cold trap in which the mercury is condensed and can be drained off. The final stage of the process is carried out in a pulsating vacuum by the inert gas. The device in which the process takes place consists of a heated heat isolated treatment chamber (2), an afterburner chamber (6), a cooling trap (7), a cold trap (18) and a vacuum pump (23, 24) connected with pipelines (5, 12, 21). The system also includes a control unit (14) for regulating the operation of the vacuum pump (23, 24) and the settings of a shut-off valve (16) and a regulation valve (15) for the inert gas. The plastic vapors are combusted in the afterburner chamber (6) by being heated in a flame basket produced with the aid of a concave flame cup (36) made of heat-resistant material.

Method of separating gold from mercury

FIELD: chemistry. SUBSTANCE: ground raw material is heated to the melting point of gold, the molten material is poured out into a container heated to 92-98°C, and after gold is deposited on the bottom of the container as a solid fraction, and mercury is deposited on the gold layer as a liquid fraction, mercury is separated from gold by removing liquid mercury from the container in a separate container. EFFECT: reducing the environmental pollution. 1 cl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 633 670 C1 (51) МПК C22B 3/00 (2006.01) C22B 11/00 (2006.01) C22B 43/00 (2006.01) C22B 1/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2016144610, 14.11.2016 (24) Дата начала отсчета срока действия патента: 14.11.2016 (72) Автор(ы): Галаванишвили Сико Соломонович (RU) (73) Патентообладатель(и): Галаванишвили Сико Соломонович (RU) Дата регистрации: (56) Список документов, цитированных в отчете о поиске: RU 2497963 C1, 10.11.2013. US Приоритет(ы): (22) Дата подачи заявки: 14.11.2016 (45) Опубликовано: 16.10.2017 Бюл. № 29 R U 2 6 3 3 6 7 0 (54) Способ отделения золота от ртути (57) Реферат: Изобретение относится к переработке золотосодержащей руды с примесями ртути. Измельченный исходный материал нагревают до температуры плавления золота, в емкость с нагретой до 92-98°C водой выливают расплавленный материал и после осаждения Стр.: 1 золота на дне емкости в виде твердой фракции, а ртути - на слое золота в виде жидкой фракции, отделяют ртуть от золота удалением жидкой ртути выливанием из упомянутой емкости в отдельную емкость. Обеспечивается снижение загрязнения окружающей среды. C 1 C 1 Адрес для переписки: 443030, г. Самара, ул. Красноармейская, 135, Председателю Самарской областной организации ВОИР Фомину Анатолию Леонидовичу 2 6 3 3 6 7 0 4734270 A, 29.03.1988. RU 2460814 C1, 10.09.2012. RU 2140460 C1, 27.10.1999. US 4671868 A1, 09.06.1987. SU 1759927 A1, 07.09.1992. R U 16.10.2017 RUSSIAN FEDERATION (19) ...

Improvement in processes for treating silver ore

METHOD FOR REMOVING MERCURY FROM MERGIUM CONTAMINATED SOLUTIONS

ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß (19) RU (11) 2005 120 172 (13) A (51) ÌÏÊ C22B 43/00 (2006.01) B01D 3/00 (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÇÀßÂÊÀ ÍÀ ÈÇÎÁÐÅÒÅÍÈÅ (21), (22) Çà âêà: 2005120172/02, 17.11.2003 (71) Çà âèòåëü(è): ÁÀÑÔ Àêöèåíãåçåëüøàôò (DE) (30) Ïðèîðèòåò: 26.11.2002 DE 10255239.8 (43) Äàòà ïóáëèêàöèè çà âêè: 20.01.2006 Áþë. ¹ 02 (86) Çà âêà PCT: EP 03/12818 (17.11.2003) (87) Ïóáëèêàöè PCT: WO 2004/048625 (10.06.2004) Àäðåñ äë ïåðåïèñêè: 105064, Ìîñêâà, óë. Êàçàêîâà, 16, ÍÈÈÐ Êàíöåë ðè "Ïàòåíòíûå ïîâåðåííûå Êâàøíèí, Ñàïåëüíèêîâ è ïàðòíåðû", ïàò.ïîâ. Â.Ï.Êâàøíèíó R U Ôîðìóëà èçîáðåòåíè 1. Ñïîñîá óäàëåíè ðòóòè äèñòèëë öèåé èç çàãð çíåííûõ ðòóòüþ ðàñòâîðîâ, îòëè÷àþùèéñ òåì, ÷òî çàãð çíåííûé ðòóòüþ ðàñòâîð ââîä ò â äèñòèëë öèîííóþ êîëîííó ïîâåðõ íèæíåé ÷àñòè, îòãîí þò ðàñòâîðèòåëü è îáåäíåííûé ðòóòüþ ðàñòâîð îòâîä ò â íèæíåé ÷àñòè êîëîííû. 2. Ñïîñîá ïî ï.1, îòëè÷àþùèéñ òåì, ÷òî ðòóòü óäàë þò èç çàãð çíåííîé ðòóòüþ ùåëî÷è. 3. Ñïîñîá ïî ï.1, îòëè÷àþùèéñ òåì, ÷òî ðòóòü óäàë þò èç çàãð çíåííîãî ðòóòüþ ñïèðòîâîãî ðàñòâîðà àëêîãîë òà ùåëî÷íîãî ìåòàëëà. 4. Ñïîñîá ïî ï.2 èëè 3, îòëè÷àþùèéñ òåì, ÷òî êðîìå çàãð çíåííîãî ðòóòüþ ðàñòâîðà â êîëîííó ïîäàþò åùå äîïîëíèòåëüíûé ðàñòâîðèòåëü. 5. Ñïîñîá ïî ï.4, îòëè÷àþùèéñ òåì, ÷òî çàãð çíåííûé ðòóòüþ ðàñòâîð è äîïîëíèòåëüíûé ðàñòâîðèòåëü ââîä ò â êîëîííó â îáúåìíîì ñîîòíîøåíèè â èíòåðâàëå îò 30:1 äî 1:3. 6. Ñïîñîá ïî ï.1, îòëè÷àþùèéñ òåì, ÷òî çàãð çíåííûé ðòóòüþ ðàñòâîð ïåðåä äèñòèëë öèåé ôèëüòðóþò ÷åðåç óãîëü. 7. Ñïîñîá ïî ï.1, îòëè÷àþùèéñ òåì, ÷òî çàãð çíåííûé ðòóòüþ ðàñòâîð ïåðåä äèñòèëë öèåé ôèëüòðóþò ÷åðåç èíåðòíûé âîëîêíèñòûé ìàòåðèàë. 8. Ñïîñîá ïî ï.6 èëè 7, îòëè÷àþùèéñ òåì, ÷òî çàãð çíåííûé ðòóòüþ ðàñòâîð ïåðåä äèñòèëë öèåé ôèëüòðóþò êàê ÷åðåç óãîëü, òàê è ÷åðåç èíåðòíûé âîëîêíèñòûé ìàòåðèàë. 9. Ñïîñîá ïî ï.8, îòëè÷àþùèéñ òåì, ÷òî çàãð çíåííûé ðòóòüþ ðàñòâîð ôèëüòðóþò ñíà÷àëà ÷åðåç óãîëü è ïîòîì ÷åðåç èíåðòíûé âîëîêíèñòûé ìàòåðèàë. Ñòðàíèöà: 1 RU A 2 0 0 5 1 2 0 1 7 2 ...

Aqueous oxidative scrubber systems for removal of mercury

A scrubber system for removal and recovery of mercury from plated solid substrates comprising a solution of an alkali metal and ammonium dichromate or chromate salts and nitric acid, said salts and acid being in a weight ratio of about 0.2 to 200. A process for removing mercury from cartridge casings and live ammunition utilizing the oxidative scrubber system is also disclosed.

Patent FR2034821B1

Mercury recovery - from aq solns by treating with reducing agent and steam distilling finely divided or colloidal mercury

The finely divided or colloidal mercury is removed by passing live steam into the soln. or by means of steam heated tubes, or by single or multistage flash distillation. Esp. useful for removing traces of mercury from exhausted brine solns. derived from electrolysis cells with mercury cathodes. The mercury is recovered efficiently at low cost.

Method of isolating mercury metal from mercurous chloride-containing products

FIELD: mercury production. SUBSTANCE: mercurous chloride- containing products are treated with hot weakly acidic chloride solution in presence of metal capable of reducing bivalent mercury to its metal form. EFFECT: enabled treatment of stupp containing mercury metal and mercurous chloride in the form of emulsion. 5 cl дс Ьс ПЧ Го (19) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ ВИ” 2 128 237. (51) МПК 13) Сл С 22 В 43/00 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 95118260102, 25.10.1995 (30) Приоритет: 26.10.1994 Е$ 9402220 (46) Дата публикации: 27.03.1999 (56) Ссылки: Ц$ 5232488 А, 03.08.93. ЗЦ 165900 А, 11.01.65. Мельников С.М. Металлургия ртути. - М.: Металлургия, 1971, с. 189 - 191. СВ 1162328 А, 21.08.69. 4$ 4160730 А, 10.07.19. ЕР 0452178 АЛ, 16.10.91. (98) Адрес для переписки: 193036, Санкт-Петербург, а/я 24, НЕВИНПАТ Поликарпову А.В. (71) Заявитель: Астуриана де Синк, СА. (Е $) (72) Изобретатель: Ситхес Менендес Фернандо (Е$), Альварес Тамарго Франсиско (Е$), Гамарго Гарсиа Франсиско (Е$), Родригес Валькарсель Матиас (Е$), Мурусабаль Ситхес Ковадонга (Е$) (73) Патентообладатель: Астуриана де Синк, С.А. (ЕЗ) (54) СПОСОБ ПОЛУЧЕНИЯ МЕТАЛЛИЧЕСКОЙ РТУТИ ИЗ ПРОДУКТОВ, СОДЕРЖАЩИХ ХЛОРИД РТУТИ (1!) (57) Реферат: Способ может быть использован для получения металлической ртути. Продукты, содержащие хлорид ртути (1), обрабатывают водным слабокислым горячим раствором хлорида в присутствии металла, способного к восстановлению двухвалентной ртути до металлической формы, обеспечивается возможность обработки ступпы, содержащей металлическую ртуть и хлорид ртути в форме эмульсии! 4 з. п.ф-лы. 2128237 С1 КО дс Ьс ПЧ Го КУЗЗАМ АСЕМСУ ГОК РАТЕМТ$ АМО ТКАОЕМАКК$ (19) ВИ” 2 128 237. 13) СЛ (51) п. С1.6 С 22 В 43/00 12) АВЗТКАСТ ОЕ 1МУЕМТОМ (21), (22) АррИсаНоп: 95118260/02, 25.10.1995 (30) Рношу: 26.10.1994 ЕЗ$ 9402220 (46) Рае ог рибИсаНоп: 27.03.1999 (98) Май адагез$$: 193036, ЗапК-РаегБчуга, айа 24, МЕМ!МРАТ РойЙКагроми А.М. (71) ...

PROCESS FOR THE PREPARATION OF METAL MERCURY FROM CALOMEL.

Purifying mercury - by contact with electrolyte using AC/DC current

Metallic impurities are removed from Hg, in the presence of an electrolyte, with a periodic electric wave of which a continuous component is maintained at a constant value. The wave is opt. a current, or a potential whose continuous component is held constant with respect to a reference electrode. The wave is opt. programmed by a potentiostatic circuit. The electrolyte is opt. an aq. soln. of pH above 7 (above 12) preF. 14, e.g. NaOH soln. The wave opt. comprises a sinusoidal, rectangular, square, or triangular component. It opt. has frequency 5-100,000 (50 or 60) Hz. The process is rapid and effective and Hg losses are minimized.

METHOD AND DEVICE FOR REPROCESSING BATTERIES FROM WASTE DEVICES.

Patent FR2215477A1

METHOD AND ARTICLE FOR COLLECTING THE SPRAYS OF LIQUID ELEMENTARY MERCURY

On utilise selon l'invention une laine de métal doublée avec au moins 0,5 % en poids de zinc, que l'on active par trempage dans une solution d'activateur acide contenant environ 0,5 à 3 % en poids d'acide. According to the invention, a metal wool lined with at least 0.5% by weight of zinc is used, which is activated by soaking in an acid activator solution containing about 0.5 to 3% by weight of acid. .

PROCESS FOR REMOVING MERCURY FROM ELECTRONIC WASTE

Patent FR2310317B1

Patent FR2208843A1

PROCESS FOR SEPARATING POLLUTANT MERCURY CONTAINED IN SOLID MATERIALS, AND DEVICE FOR ITS IMPLEMENTATION

a. Procédé et dispositif pour séparer le mercure de matières solides, par distillation sous vide. b. On place la matière à traiter dans une enceinte placée à son tour dans une chambre où l'on crée le vide et que l'on chauffe; cette chambre est donc reliée à une pompe à vide mais par l'intermédiaire d'un collecteur à refroidissement; on introduit dans l'installation, entre l'enceinte et le collecteur, un gaz inerte, par exemple de l'azote, dont la pression subit des variations intermittentes entre 40 et 80 kPa, et de préférence entre 40 et 53 kPa, la chambre étant chauffée jusqu'à une température supérieure au point d'ébullition du mercure. c. Application à tous déchets, résidus et ordures contenant du mercure, d'origine tant urbaine qu'industrielle. at. Method and device for separating mercury from solids by vacuum distillation. b. The material to be treated is placed in an enclosure placed in turn in a chamber where a vacuum is created and which is heated; this chamber is therefore connected to a vacuum pump but via a cooling manifold; an inert gas, for example nitrogen, the pressure of which undergoes intermittent variations between 40 and 80 kPa, and preferably between 40 and 53 kPa, is introduced into the installation, between the enclosure and the collector, the chamber being heated to a temperature above the boiling point of mercury. vs. Application to all waste, residues and garbage containing mercury, of both urban and industrial origin.

Reclaiming mercury from a spent, impure catalyst - contg. mercuric chloride and carbon, by combustion and washing

The active carbon is burnt with a controlled amt. of air of O2 so the combustion gases contain, in addn. to metallic Hg vapour, 0.5-5 vol. % O2 and 2-15 vol. % CO; the gases travel through a condensation zone for sepg. the Hg with water and are then washed with alkali before release to the atmos. The combustion gases pref. contain (vol. %) 1-3 O2, 4-10 CO, and the alkali is pref. caustic soda. Process is esp. for recovery of Hg from catalyst used in mfg. vinyl chloride from acetylene and HCl. The Hg obtd. is free from phosphorous cpds. and the P2O5 and SO2 are effectively removed.

Purification of gases containing mercury and recovery of metallic mercury

ABSTRACT A method for the purification of gases containing mercury and simultaneous recovery of the mercury in metallic form by a process where primarily a reactiontakes place between metallic vapory mercury and mercury (II)-chloride com-pounds in solution in a liquid phase, during which the formation and deposition of only slightly soluble Hg (I)-chloride (calomel) occur, the deposited calomel being oxidized to easily soluble Hg (II)-chloride compounds by the adding of chlorine, and metallic mercury and at least some of the chlorine used being recovered by electrolysis of said formed Hg(II)-chloride..

Process for isolating metals from solutions containing them and active agents used therefor

Removal of mercury - from aqs solns esp from wash waters from electrolytic processes

The aqs. soln. which is depleted of its O2 and Cl2 is circulated through a pile of Fe and Cu particles, the Fe particles cathodically protecting the Cu particles and the Cu particles retaining the Hg and forming an amalgam.

Patent FR2208843B1

PROCESS FOR THE PREPARATION OF METAL MERCURY FROM CALOMEL

L'invention a pour objet un procédé et une installation pour la production du mercure par réduction du calomel par mise en œuvre d'un procédé de préparation de mercure métallique. Cette installation comporte: - un réacteur 2 à fond incliné 4 pour la réduction muni d'agitateur 3, relié par une canalisation 5 audit décanteur 1 et pourvu de moyens d'alimentation en eau 7 et en acide sulfurique 8; et - une cuve de récupération du mercure 11, reliée à la partie basse du réacteur. The subject of the invention is a process and an installation for the production of mercury by reduction of calomel by implementing a process for the preparation of metallic mercury. This installation comprises: - a reactor 2 with an inclined bottom 4 for the reduction equipped with an agitator 3, connected by a pipe 5 to said decanter 1 and provided with means for supplying water 7 and sulfuric acid 8; and - a mercury recovery tank 11, connected to the lower part of the reactor.

Method for the removal of mercury from sludges containing same

ABSTRACT OF THE DISCLOSURE: Elemental mercury is recovered from a mercury-occluding sludge containing no more than 50% moisture by heating the sludge to a temperature of from 200 to 350°C under a negative pressure of from 0.06 to 0.1 effective atmospheres to convert the sludge into a powdered ashy mass, discharging the ashes into a mass of water circulated in a closed loop, superheating the water vapor evolved from the water mass so as to keep all the mercury values in the vapor phase, condensing the water and mercury vapors and gravimetrically separating the water and the mercury condensates from one another. The invention enables one to achieve a high efficiency of recovery.

PROCESS FOR SEPARATING POLLUTANT MERCURY FROM SOLID MATERIALS, AND DEVICE FOR CARRYING OUT SAID METHOD

PROCESS FOR STABILIZING SULFUR METAL MERCURY

Patent FR2101535A5

Patent FR2279675B1

Method of and device for centrifugal separation of mixed substances with different specific gravities

Аппарат для центробежного разделения смешанных веществ с различными удельными весами содержит корзину центрифуги, имеющую множество кольцевых элементов на периферийной поверхности. Наружная корзина имеет кожух, из которого вода инжектируется через отверстия во внутреннюю полость корзины в выемки между кольцевыми элементами. Питающие материалы, содержащие золото и ртуть, разделяют таким образом, что золото и ртуть собираются в выемках. Жидкую ртуть выпускают через отверстия во внутренней корзине на внутреннюю поверхность наружной корзины, на которой предусмотрен кольцевой приемник и которая спрофилирована для обеспечения накапливания ртути в приемнике, аксиально разнесенном от открытой горловины корзины. Множество выпускных отверстий в кольцевом приемнике позволяет выпускать ртуть во второй лоток внутри наружного лотка для основной выгрузки материалов из открытой горловины. Жидкая ртуть поэтому собирается и накапливается раздельно от тяжелых твердых веществ внутри корзины и раздельно от выгружаемых легких материалов.

Mercury absorbing zeolite clay compsn - to remove mercury from gas or liq., preventing pollution

Mercury is absorbed from liqs. or gases in a vacuum chamber at -50 to 150 degrees C by a sorbent in a moist state of formula Men+O. X Al2O3. Y. SiO2. xH2O. (where X, Y and x are numbers characterised by the sorbents; Me is Cu, Te, Hg, Ag, Pd and/or Au). The pref. metal Me is Ag and the sorbent is pref. a zeolite of molecular sieve characteristics mixed with a clay. Mercury is detected by a colour change in the sorbent.

MERCURY RECOVERY PROCESS AND NEW PRODUCT THUS OBTAINED

Method of removing mercury from mercury contaminated materials

A method of reducing mercury levels in a mercury contaminated material using microwave energy. The method comprises the steps of (a) placing the mercury contaminated material in a microwave reactor; (b) providing a stream of gas in the microwave reactor, the stream causing agitation of the mercury contaminated material; and (c) exposing the mercury contaminated material to microwave radiation so as to raise the temperature to at least 357°C, producing a vapour phase which contains mercury and a treated material. The method also allows for a simultaneous reduction of mercury and carbon levels in the material to be treated as well as the use of a carbon-free material in the reactor.

Patent FR2244837B1

Patent FR2215477B1

Apparatus for the distillation of mercury

Process for the recovery of metallic mercury

Continuous procedure for the simultaneous collection and precipitacion of mercury in gases containing it

Procedure for the simultaneous collection and precipitation of mercury in gases containing it. It consists on passing the mercury gas through a washing tower where hydrogen sulphur (gas) is continuously and intermittently injected at the same time that it is watered with a solution containing a mercury complex (II) stable in semi acid, such as [I₂Hg]⁻ or [(SCN)₄HG]⁻, without requiring the use of an additional oxidant. Both the collection and precipitation of the mercury and the regeneration of the solution containing the mercury complex (II) take place simultaneously in just one stage.

Patent FR2216357A1

Method for purifying mercury

An apparatus for atomizing liquid materials comprises a solid cylindrical body having a rotation means attached to one end and a chamber formed in the other end thereof. Passageways extending through the cylindrical body to the chamber are so arranged that their vertical axes are parallel to and adjacent the sides of the body. An opening is provided into the chamber which has complementary ribs formed in its top and bottom. The apparatus can be employed in a variety of mixing and liquid contacting operations, but it is particularly useful for effecting contact between mercury and agents used in its purification.

Patent FR2237979B3

System and process for removal of pollutants from a gas stream

System for removal of targeted pollutants, such as oxides of sulfur, oxides of nitrogen, mercury compounds and ash, from combustion and other industrial process gases and processes utilizing the system. Oxides of manganese are utilized as the primary sorbent in the system for removal or capture of pollutants. The oxides of manganese are introduced from feeders into reactio n zones of the system where they are contacted with a gas from which pollutant s are to be removed. With respect to pollutant removal, the sorbent may intera ct with a pollutant as a catalyst, reactant, adsorbent or absorbent. Removal ma y occur in single-stage, dual stage, or multi-stage systems with a variety of different configurations and reaction zones, e.g., bag house, cyclones, fluidized beds, and the like. Process parameters, particularly system differential pressure, are controlled by electronic controls to maintain minimal system differential pressure, and to monitor and adjust pollutant removal efficiencies. Reacted sorbent may be removed from the reaction actio n zones for recycling or recycled or regenerated with useful and marketable by - products being recovered during regeneration.

Patent DE1194583C2

A method for separating gaseous, elementary mercury and gaseous halogenides of mercury and other heavy metals from a gas.

The invention relates to a method for separating gaseous elementary mercury from a gas in conjunction with a wet-gas cleaning process comprising a plurality of washing stages. The mercury-containing gas is treated with an aqueous washing liquid conducted in a closed circuit, the liquid containing 0.1-300 mmol/1 mercury (II) ions and at least twice this amount of ions having the ability of forming complexes with mercury (II) ions, the mercury in the gas being oxidized and absorbed in the washing liquid. The invention is characterized in that the treatment process is carried out in conjunction with a gas-cooling process effected after the last washing stage of the wet-gas cleaning process, to form a condensate for absorbing the halogens contained in the gas. The resultant condensate is transferred to the washing liquid and the mercury (II) content of the washing liquid is maintained by contacting the washing liquid with an oxidizing agent for mercury (I) ions. The agent used to oxidize mercury (I) ions is preferably chlorine gas.

Patent FR2287525B3

Deep purification and mercury recovery process for mercury in lead-zinc smelting flue gas

本发明公开了一种铅锌冶炼烟气中汞深度净化和汞回收工艺，采用高分子纳米材料脱汞剂KH添加到一级高效洗涤脱汞塔和二级深度洗涤脱汞塔中，控制一定的工艺条件实现汞的深度净化并将烟气中尘及其它重金属洗涤下来，再利用气体冷却塔、动力波、电除雾对烟气深度净化，烟气经过处理后其中Hg<0.03mg/Nm3，烟气制酸的硫酸中汞含量小于0.0005%，本发明满足烟气中汞达标排放的要求同时，烟气中汞的资源化回收率在90%以上，有良好的环保效益。

Patent FR2220294B3

Process for separating gaseous elemental mercury from a gas.

The method of disposal of mercury-containing waste

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2018 116 212 A (51) МПК C22B 43/00 (2006.01) C22B 7/00 (2006.01) B09B 3/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2018116212, 28.04.2018 Приоритет(ы): (22) Дата подачи заявки: 28.04.2018 (43) Дата публикации заявки: 28.10.2019 Бюл. № 31 R U (57) Формула изобретения Способ обезвреживания ртутьсодержащих отходов, включающий совместный размол отходов с порошком элементарной серы, воды и гомогенизирующей средой для связывания металлической ртути в водонерастворимое соединение HgS во вращающемся реакторе, отличающийся тем, что соотношение массы ртути к массе элементарной серы равно 1:4, в качестве реактора используют мельницу барабанного типа, в качестве гомогенизирующей среды используют бентонит, в количестве превышающем массу отходов в 2-2,5 раза, и воду, в количестве превышающем массу бентонита в 10-12 раз, предварительную гомогенизацию проводят в течение 20-30 минут, далее загружают ртутьсодержащие отходы и размол ведут до связывания 90% массы металлической ртути в водонерастворимое соединение HgS, а для полного связывания металлической и окисленной ртути в водонерастворимое соединение HgS на завершающей стадии процесса в суспензию добавляют хлорид железа (III) и сульфид железа (II), а затем образовавшуюся устойчивую подвижную суспензию сливают из мельницы и непосредственно передают на сушку с последующим захоронением как отход - IV класса опасности. Стр.: 1 A 2 0 1 8 1 1 6 2 1 2 A (54) Способ обезвреживания ртутьсодержащих отходов 2 0 1 8 1 1 6 2 1 2 (72) Автор(ы): Макаров Сергей Вадимович (RU), Черкасова Татьяна Александровна (RU), Макарова Анна Сергеевна (RU), Тимербаева Юлия Римовна (RU) R U Адрес для переписки: 125047, Москва, Миусская пл., 9, Российский химико-технологический университет имени Д.И. Менделеева, патентно-лицензионный отдел (71) Заявитель(и): Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский ...

PROCESS FOR THE TREATMENT OF ORGANIC RESIDUES CONTAINING MERCURY

Method of adsorbing metals and organic compounds from vaporous streams

A method for the removal of mercury and other metals, as well as furans and other organic compounds from high temperature and moisture gaseous streams. The method utilizes and adsorption powder characterized as containing a carbon-based powder and an effective amount of cupric chloride suitable to remove metals and organic compounds. The powder may contain calcium hydroxide, sulphur, potassium permanganate, potassium iodide, and combinations thereof. The Figure illustrates the method of the present invention wherein a solid phase (2) is pre-screened and transferred to a cleaning unit (4). A gaseous component is transferred to a dust remover (6), while a solid components transferred to cooling unit (8). The gaseous component is then heated in cleaning unit (10); transferred to a cooling chamber(12); contacted with an adsorption powder; transferred to a baghouse (16); filtered; and exhausted as flue gases at stack (18).

Method and apparatus for monitoring mercury in a gas sample

A converter of the Continuous Emission Monitoring System (CEMS) receives a gas sample containing vaporized mercury from a probe. The converter converts oxidized mercury present within the gas sample into an elemental mercury component and an oxidizing component using thermal cracking. The converter also reduces the pressure of the gas sample to minimize recombination of the elemental mercury component with the oxidizing components. A mercury analyzer of the system receives the reduced pressure gas sample from the converter and detects the fluorescence of the elemental mercury within the sample. The mercury analyzer holds the gas sample at the reduced pressure to reduce an effect of fluorescence quenching on the fluorescence of the elemental mercury within the sample and provides substantially accurate measurement of the concentration of the elemental mercury in the gas sample.

PROCEDURE FOR AA Separate gaseous, elemental mercury from a gas.

Method for eliminating mercury from liquids

A method for eliminating mercury from mercury containing liquids by contacting the mercury-containing liquid with a plurality of fibers wherein the fibers making up the plurality of fibers have a coating of silver on the surface of the fibers, and a silver-coated fiber for use in the method are disclosed.

Apparatus for recycleing activated carbon

The present invention relates to an activated carbon regeneration device used in a mercury recovery process from a waste, which can extend an operation time due to mercury recovery and comprises a preprocessing step (S110); a mercury recovery step (S120); a mercury content determination step (S130); a mercury purification step (S140); and an exhaust gas treatment step (S150).