30-03-2017 дата публикации
Номер: US20170089011A1
Принадлежит:
Paper strength systems including polyamine-polyamidoamine-epihalohydrin (PPAE) resin are disclosed. Also disclosed are methods of forming a paper including applying a strength system comprising PPAE to cellulosic fiber, as well as the resultant paper. 124-. (canceled)25. A composition comprising a polyamine polyamidoamine epihalohydrin resin that is the reaction product of a polyamidoamine , a first polyamine , and an epihalohydrin , wherein the polyamidoamine is prepared by a process comprising reacting a polycarboxylic acid , a polycarboxylic acid derivative , or a combination thereof with a second polyamine to form the polyamidoamine , wherein a molar ratio of the second polyamine to the polycarboxylic acid , polycarboxylic acid derivative , or combination thereof , is from about 1.05 to about 2.0.26. The composition of claim 25 , wherein the polyamine polyamidoamine epihalohydrin resin has a total AOX level of about 400 ppm or less.27. The composition of claim 25 , wherein the polycarboxylic acid and/or the polycarboxylic acid derivative is selected from the group consisting of: malonic acid claim 25 , glutaric acid claim 25 , adipic acid claim 25 , azelaic acid claim 25 , citric acid claim 25 , 1 claim 25 ,2 claim 25 ,3-propanetricarboxylic acid claim 25 , 1 claim 25 ,2 claim 25 ,3 claim 25 ,4 butanetetracarboxylic acid claim 25 , nitrilotriacetic acid claim 25 , N claim 25 ,N claim 25 ,N′ claim 25 ,N′-ethylenediaminetetraacetate claim 25 , 1 claim 25 ,2-cyclohexanedicarboxylic acid claim 25 , 1 claim 25 ,3-cyclohexanedicarboxylic acid claim 25 , 1 claim 25 ,4-cyclohexanedicarboxylic acid claim 25 , itaconic acid claim 25 , phthalic acid claim 25 , isophthalic acid claim 25 , terephthalic acid claim 25 , 1 claim 25 ,2 claim 25 ,4-benzenetricarboxylic acid claim 25 , 1 claim 25 ,2 claim 25 ,4 claim 25 ,5-benzenetetracarboxylic acid claim 25 , dimethyl adipate claim 25 , dimethyl malonate claim 25 , diethyl malonate claim 25 , dimethyl succinate claim 25 , ...
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