28-12-2017 дата публикации
Номер: US20170370851A1
Принадлежит:
Disclosed is a method for dosing iron ions, by spectrophotometry, especially ferric and ferrous ions, contained in a used lubricating composition, especially a lubricating composition of a marine engine. The invention also relates to a kit for implementing the method. 111-. (canceled)12. Method for determining iron ions , in particular ferric and ferrous ions , in lubricating compositions , comprising the following steps:a) Taking a sample of the lubricating compositing to be analysed in a first container;b) Placing said first container containing the sample to be analysed on a magnet; [{'b': '1', 'a first aqueous reactive composition (CR) comprising at least one extracting agent of ferric and ferrous ions from the oil phase towards the aqueous phase;'}, {'b': '2', 'sup': 3+', '2+, 'a second aqueous reactive composition (CR) comprising at least one reducing agent of ferric ions (Fe) to ferrous ions (Fe);'}, {'b': '3', 'a third reactive composition (CR) comprising at least one emulsion destabilising agent; and'}, {'b': '4', 'a fourth reactive composition (CR) in an aqueous solution comprising a complexing agent of ferrous ions, wherein this agent changes colour when complexing with ferrous ions;'}], 'c) Adding to a second containerand mixing thereof;d) optionally, photochemical measurement of the absorbance of the mixture obtained at step c);e) Taking a few drops of the lubricating composition contained in the first container, held in position on the magnet, and adding these few drops to the second container comprising the mixture of the first, second, third and fourth reactive compositions obtained at step c);f) Agitating the mixture obtained at step e);g) Conducting photochemical measurement of the absorbance of the mixture obtained at step f);h) Determining the quantity of ferrous ions in the lubricating composition from the measurements obtained at steps d) and g).13. The method according to claim 12 , wherein the extracting agent is selected from among agents ...
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