26-02-2015 дата публикации
Номер: US20150053908A1
A device with programmable resistance comprising memristive material between conductive electrodes on a substrate or in a film stack on a substrate is provided. During fabrication of a memristive device, a memristive layer may be hydrated after deposition of the memristive layer. The hydration of the memristive layer may be performed utilizing thermal annealing in a reducing ambient, implant or plasma treatment in a reducing ambient, or a deionized water rinse. Additionally, plasma-assisted etching of an electrode may be performed with hydration or in place of hydration to electroform devices in a batch, in situ process. The memristive device may be electroformed at low voltage and passivated to allow for device operation in air. Further, the memristive device is suitable for high throughput manufacturing. 1. A method for fabricating a memristive device comprising:forming a first electrode, wherein the first electrode is formed from a conductive or semiconductive material;depositing a memristive layer, wherein the memristive layer comprises at least one memristive material;{'sub': 2', '2', '2', '2', '3, 'hydrating said memristive layer utilizing a reducing ambient, wherein the reducing ambient is H, D, HO, DO, NH, H or D containing gas mixtures, or a combination thereof; and'}forming a second electrode, wherein said first and second electrodes are separated by said memristive layer.2. The method of claim 1 , wherein said hydrating comprises a thermal anneal of said memristive layer in said reducing ambient.3. The method of claim 1 , wherein said hydrating comprises a plasma treatment of said memristive layer in said reducing ambient.4. The method of claim 1 , wherein said hydrating comprises a deionized water rinse and drying in any inert ambient.5. The method of claim 1 , further comprising electroforming said memristive device claim 1 , wherein electroformation is performed during plasma-assisted etching of said second electrode.6. The method of claim 1 , further ...
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